Sample records for water balance partitioning
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NASA Technical Reports Server (NTRS)
Leonard, J. I.
1977-01-01
The water balance of the Skylab crew was analyzed. Evaporative water loss using a whole body input/output balance equation, water, body tissue, and energy balance was analyzed. The approach utilizes the results of several major Skylab medical experiments. Subsystems were designed for the use of the software necessary for the analysis. A partitional water balance that graphically depicts the changes due to water intake is presented. The energy balance analysis determines the net available energy to the individual crewman during any period. The balances produce a visual description of the total change of a particular body component during the course of the mission. The information is salvaged from metabolic balance data if certain techniques are used to reduce errors inherent in the balance method.
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NASA Astrophysics Data System (ADS)
Zhao, Wenzhi; Liu, Bing; Chang, Xuexiang; Yang, Qiyue; Yang, Yuting; Liu, Zhiling; Cleverly, James; Eamus, Derek
2016-07-01
Partitioning evapotranspiration (ET) into its components reveals details of the processes that underlie ecosystem hydrologic budgets and their feedback to the water cycle. We measured rates of actual evapotranspiration (ETa), canopy transpiration (Tc), soil evaporation (Eg), canopy-intercepted precipitation (EI), and patterns of stomatal conductance of the desert shrub Calligonum mongolicum in northern China to determine the water balance of this ecosystem. The ETa was 251 ± 8 mm during the growing period, while EI, Tc, and Eg accounted for 3.2%, 63.9%, and 31.3%, respectively, of total water use (256 ± 4 mm) during the growing period. In this unique ecosystem, groundwater was the main water source for plant transpiration and soil evaporation, Tc and exceeded 60% of the total annual water used by desert plants. ET was not sensitive to air temperature in this unique desert ecosystem. Partitioning ET into its components improves our understanding of the mechanisms that underlie adaptation of desert shrubs, especially the role of stomatal regulation of Tc as a determinant of ecosystem water balance.
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Toropov, Andrey A; Toropova, Alla P; Raska, Ivan; Benfenati, Emilio
2010-04-01
Three different splits into the subtraining set (n = 22), the set of calibration (n = 21), and the test set (n = 12) of 55 antineoplastic agents have been examined. By the correlation balance of SMILES-based optimal descriptors quite satisfactory models for the octanol/water partition coefficient have been obtained on all three splits. The correlation balance is the optimization of a one-variable model with a target function that provides both the maximal values of the correlation coefficient for the subtraining and calibration set and the minimum of the difference between the above-mentioned correlation coefficients. Thus, the calibration set is a preliminary test set. Copyright (c) 2009 Elsevier Masson SAS. All rights reserved.
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ERIC Educational Resources Information Center
Brusco, Michael; Steinley, Douglas
2010-01-01
Structural balance theory (SBT) has maintained a venerable status in the psychological literature for more than 5 decades. One important problem pertaining to SBT is the approximation of structural or generalized balance via the partitioning of the vertices of a signed graph into "K" clusters. This "K"-balance partitioning problem also has more…
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Partitioning the Water Budget in a Glacierized Basin
NASA Astrophysics Data System (ADS)
O'Neel, S.; Sass, L.; McGrath, D.; McNeil, C.; Myers, K. F.; Bergstrom, A.; Koch, J. C.; Ostman, J. S.; Arendt, A. A.; LeWinter, A.; Larsen, C. F.; Marshall, H. P.
2017-12-01
Glaciers couple to the ecosystems in which they reside through their mass balance and subsequent runoff. The unique timing and composition of glacier runoff notably impacts ecological and socio-economically important processes, including thermal modulation of streams, nearshore primary production, and groundwater exchange. Predicting how these linkages will evolve as glaciers continue to retreat requires a better understanding of basin- to region-scale water budgets. Here we develop a partitioned water balance for Alaska's Wolverine Glacier basin for 2016. Our presentation will highlight mass-balance forcing and sensitivity, as well as analyses of hydrometric and geochemical partitioning. These observations provide constraints for hypsometry-based regional projections of glacier change, which form the basis of future biogeochemical scenarios. Local climate records show relatively minor warming and drying over the 1967 -2016 interval, yet the impact on the glacier was substantial; the average annual balance rate over the study interval is -0.5 m/yr. We performed a sensitivity experiment that suggests that elevation-independent processes drive first-order variability in glacier-wide mass balance solutions Analysis of runoff and precipitation data suggest that previously ignored components of the hydrologic cycle (groundwater, evapotranspiration, off-glacier snowpack storage, and snow redistribution) may substantially contribute to the basin wide water budget. Initial geochemical assessments (carbon, water isotopes, major ions) highlight unique source signatures (glacier-derived, snow-melt, groundwater), which will be further explored using a mixing model approach. Applying a range of climate forcings over centennial time-scales suggests the regional equilibrium line altitude is likely to increase by more than 100 m, which will result in extensive glacier area losses. Such changes will likely modify the runoff from this basin by increasing inter-annual streamflow
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Applying graph partitioning methods in measurement-based dynamic load balancing
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bhatele, Abhinav; Fourestier, Sebastien; Menon, Harshitha
Load imbalance leads to an increasing waste of resources as an application is scaled to more and more processors. Achieving the best parallel efficiency for a program requires optimal load balancing which is a NP-hard problem. However, finding near-optimal solutions to this problem for complex computational science and engineering applications is becoming increasingly important. Charm++, a migratable objects based programming model, provides a measurement-based dynamic load balancing framework. This framework instruments and then migrates over-decomposed objects to balance computational load and communication at runtime. This paper explores the use of graph partitioning algorithms, traditionally used for partitioning physical domains/meshes, formore » measurement-based dynamic load balancing of parallel applications. In particular, we present repartitioning methods developed in a graph partitioning toolbox called SCOTCH that consider the previous mapping to minimize migration costs. We also discuss a new imbalance reduction algorithm for graphs with irregular load distributions. We compare several load balancing algorithms using microbenchmarks on Intrepid and Ranger and evaluate the effect of communication, number of cores and number of objects on the benefit achieved from load balancing. New algorithms developed in SCOTCH lead to better performance compared to the METIS partitioners for several cases, both in terms of the application execution time and fewer number of objects migrated.« less
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NASA Astrophysics Data System (ADS)
Kool, Dilia; Kustas, William P.; Agam, Nurit
2016-04-01
The partitioning of evapotranspiration (ET) into transpiration (T), a productive water use, and soil water evaporation (E), which is generally considered a water loss, is highly relevant to agriculture in the light of increasing desertification and water scarcity. This task is challenged by the complexity of soil and plant interactions, coupled with changes in atmospheric and soil water content conditions. Many of the processes controlling water/energy exchange are not adequately modeled. The two-source energy balance model (TSEB) was evaluated and adapted for independent E and T estimations in an isolated drip-irrigated wine vineyard in the arid Negev desert. The TSEB model estimates ET by computing vegetation and soil energy fluxes using remotely sensed composite surface temperature, local weather data (solar radiation, air temperature and humidity, and wind speed), and vegetation metrics (row spacing, canopy height and width, and leaf area). The soil and vegetation energy fluxes are computed numerically using a system of temperature gradient and resistance equations; where soil and canopy temperatures are derived from the composite surface temperature. For estimation of ET, the TSEB model has been shown to perform well for various agricultural crops under a wide range of environmental conditions, but validation of T and E fluxes is limited to one study in a well-watered cotton crop. Extending the TSEB approach to water-limited vineyards demands careful consideration regarding how the complex canopy structure of vineyards will influence the accuracy of the partitioning between E and T. Data for evaluation of the TSEB model were collected over a season (bud break till harvest). Composite, canopy, and soil surface temperatures were measured using infrared thermometers. The composite vegetation and soil surface energy fluxes were assessed using independent measurements of net radiation, and soil, sensible and latent heat flux. The below canopy energy balance was
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The effects of salinity in the soil water balance: A Budyko's approach
NASA Astrophysics Data System (ADS)
Perri, S.; Viola, F.; Molini, A.
2017-12-01
Soil degradation and water scarcity pose important constraints on productivity and development of arid and semi-arid countries. Among the main causes of loss of soil fertility, aridification and soil salinization are deeply connected threats enhanced by climate change. Assessing water availability is fundamental for a large number of applications especially in arid regions. An approach often adopted to estimate the long-term rainfall partitioning into evapotranspiration and runoff is the Budyko's curve. However, the classical Budyko framework might not be able to properly reproduce the water balance in salt affected basins, especially under elevated soil salinization conditions. Salinity is a limiting factor for plant transpiration (as well as growth) affecting both short and long term soil moisture dynamics and ultimately the hydrologic balance. Soluble salts cause a reduction of soil water potential similar to the one arising from droughts, although plant adaptations to soil salinity show extremely different traits and can vary from species to species. In a similar context, the salt-tolerance plants are expected to control the amount of soil moisture lost to transpiration in saline soils, also because salinity reduces evaporation. We propose a simple framework to include the effects of salinization on the surface energy and water balance within a simple Budyko approach. By introducing the effects of salinity in the stochastic water balance we are able to include the influence of vegetation type (i.e. in terms of salt-tolerance) on evapotranspiration-runoff partitioning under different climatic conditions. The water balance components are thus compared to data obtained from arid salt-affected regions.
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Abraham, Michael H; Gola, Joelle M R; Ibrahim, Adam; Acree, William E; Liu, Xiangli
2014-07-01
There is considerable interest in the blood-tissue distribution of agrochemicals, and a number of researchers have developed experimental methods for in vitro distribution. These methods involve the determination of saline-blood and saline-tissue partitions; not only are they indirect, but they do not yield the required in vivo distribution. The authors set out equations for gas-tissue and blood-tissue distribution, for partition from water into skin and for permeation from water through human skin. Together with Abraham descriptors for the agrochemicals, these equations can be used to predict values for all of these processes. The present predictions compare favourably with experimental in vivo blood-tissue distribution where available. The predictions require no more than simple arithmetic. The present method represents a much easier and much more economic way of estimating blood-tissue partitions than the method that uses saline-blood and saline-tissue partitions. It has the added advantages of yielding the required in vivo partitions and being easily extended to the prediction of partition of agrochemicals from water into skin and permeation from water through skin. © 2013 Society of Chemical Industry.
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Unstructured P2P Network Load Balance Strategy Based on Multilevel Partitioning of Hypergraph
NASA Astrophysics Data System (ADS)
Feng, Lv; Chunlin, Gao; Kaiyang, Ma
2017-05-01
With rapid development of computer performance and distributed technology, P2P-based resource sharing mode plays important role in Internet. P2P network users continued to increase so the high dynamic characteristics of the system determine that it is difficult to obtain the load of other nodes. Therefore, a dynamic load balance strategy based on hypergraph is proposed in this article. The scheme develops from the idea of hypergraph theory in multilevel partitioning. It adopts optimized multilevel partitioning algorithms to partition P2P network into several small areas, and assigns each area a supernode for the management and load transferring of the nodes in this area. In the case of global scheduling is difficult to be achieved, the priority of a number of small range of load balancing can be ensured first. By the node load balance in each small area the whole network can achieve relative load balance. The experiments indicate that the load distribution of network nodes in our scheme is obviously compacter. It effectively solves the unbalanced problems in P2P network, which also improve the scalability and bandwidth utilization of system.
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Dynamic Load Balancing for Grid Partitioning on a SP-2 Multiprocessor: A Framework
NASA Technical Reports Server (NTRS)
Sohn, Andrew; Simon, Horst; Lasinski, T. A. (Technical Monitor)
1994-01-01
Computational requirements of full scale computational fluid dynamics change as computation progresses on a parallel machine. The change in computational intensity causes workload imbalance of processors, which in turn requires a large amount of data movement at runtime. If parallel CFD is to be successful on a parallel or massively parallel machine, balancing of the runtime load is indispensable. Here a framework is presented for dynamic load balancing for CFD applications, called Jove. One processor is designated as a decision maker Jove while others are assigned to computational fluid dynamics. Processors running CFD send flags to Jove in a predetermined number of iterations to initiate load balancing. Jove starts working on load balancing while other processors continue working with the current data and load distribution. Jove goes through several steps to decide if the new data should be taken, including preliminary evaluate, partition, processor reassignment, cost evaluation, and decision. Jove running on a single EBM SP2 node has been completely implemented. Preliminary experimental results show that the Jove approach to dynamic load balancing can be effective for full scale grid partitioning on the target machine IBM SP2.
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Dynamic Load Balancing For Grid Partitioning on a SP-2 Multiprocessor: A Framework
NASA Technical Reports Server (NTRS)
Sohn, Andrew; Simon, Horst; Lasinski, T. A. (Technical Monitor)
1994-01-01
Computational requirements of full scale computational fluid dynamics change as computation progresses on a parallel machine. The change in computational intensity causes workload imbalance of processors, which in turn requires a large amount of data movement at runtime. If parallel CFD is to be successful on a parallel or massively parallel machine, balancing of the runtime load is indispensable. Here a framework is presented for dynamic load balancing for CFD applications, called Jove. One processor is designated as a decision maker Jove while others are assigned to computational fluid dynamics. Processors running CFD send flags to Jove in a predetermined number of iterations to initiate load balancing. Jove starts working on load balancing while other processors continue working with the current data and load distribution. Jove goes through several steps to decide if the new data should be taken, including preliminary evaluate, partition, processor reassignment, cost evaluation, and decision. Jove running on a single IBM SP2 node has been completely implemented. Preliminary experimental results show that the Jove approach to dynamic load balancing can be effective for full scale grid partitioning on the target machine IBM SP2.
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NASA Astrophysics Data System (ADS)
Kheimi, M.; Wang, D.
2017-12-01
Water operating in reservoir system is similar to natural catchment systems in water regulations. The most contributing role in both systems is found to be mitigating of available water deficits from excessive and keeping it away from prolonged droughts. In this paper, Bodyko equation and hedging rule are presented by two stage portioning monthly water balance model. The first stage is the partitioning of precipitation to evapotranspiration (E) plus future storage (S1) and runoff (Q); the second stage is using hedging rule where evapotranspiration and future storage to be recognized by a tradeoff between evapotranspiration and future water storage. The model introduces a linear two point hedging parameters: starting water availability (y1) and ending of water availability (y2).The calibration of the model is based on five parameters: three derived from Budyko equation (S0, ξ, and Yp) and two from hedging rule (y1 and y2).The catchment climate zone along with its physical properties have an effect on the degree of hedging. The y1 and y2 parameters are indicators of the amount of hedging in dry and wet zones. The span between the starting point (y1) and ending point (y2) of hedging indicate there is hedging against future evapotranspiration shortage. Observation of 187 catchments was examined using this model concept for the period of 21 years starting from 1983 to 2003. After calibration and validation using a genetic algorithm it shows that hedging effect in catchment against future evapotranspiration shortages exists with an abundance of hedging effect in dry areas more than wet areas.
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NASA Astrophysics Data System (ADS)
Bowers, W.; Mercer, J.; Pleasants, M.; Williams, D. G.
2017-12-01
Isotopic partitioning of water within soil into tightly and loosely bound fractions has been proposed to explain differences between isotopic water sources used by plants and those that contribute to streams and ground water, the basis for the "two water worlds" hypothesis. We examined the isotope ratio values of water in trees, bulk soil, mobile water collected from soil lysimeters, stream water, and GW at three different hillslopes in a mixed conifer forest in southeastern Wyoming, USA. Hillslopes differed in aspect and topographic position with corresponding differences in surface energy balance, snowmelt timing, and duration of soil moisture during the dry summer. The isotopic results support the partitioning of water within the soil; trees apparently used a different pool of water for transpiration than that recovered from soil lysimeters and the source was not resolved with the isotopic signature of the water that was extracted from bulk soil via cryogenic vacuum distillation. Separating and measuring the isotope ratios values in these pools would test the assumption that the tightly bound water within the soil has the same isotopic signature as the water transpired by the trees. We employed a centrifugation approach to separate water within the soil held at different tensions by applying stepwise increases in rotational velocity and pressures to the bulk soil samples. Effluent and the remaining water (cryogenically extracted) at each step were compared. We first applied the centrifugation method in a simple lab experiment using sandy loam soil and separate introductions of two isotopically distinct waters. We then applied the method to soil collected from the montane hillslopes. For the lab experiment, we predicted that effluents would have distinct isotopic signatures, with the last effluent and extracted water more closely representing the isotopic signature of the first water applied. For our field samples, we predicted that the isotopic signature of the
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Burant, Aniela; Thompson, Christopher; Lowry, Gregory V; Karamalidis, Athanasios K
2016-05-17
Partitioning coefficients of organic compounds between water and supercritical CO2 (sc-CO2) are necessary to assess the risk of migration of these chemicals from subsurface CO2 storage sites. Despite the large number of potential organic contaminants, the current data set of published water-sc-CO2 partitioning coefficients is very limited. Here, the partitioning coefficients of thiophene, pyrrole, and anisole were measured in situ over a range of temperatures and pressures using a novel pressurized batch-reactor system with dual spectroscopic detectors: a near-infrared spectrometer for measuring the organic analyte in the CO2 phase and a UV detector for quantifying the analyte in the aqueous phase. Our measured partitioning coefficients followed expected trends based on volatility and aqueous solubility. The partitioning coefficients and literature data were then used to update a published poly parameter linear free-energy relationship and to develop five new linear free-energy relationships for predicting water-sc-CO2 partitioning coefficients. A total of four of the models targeted a single class of organic compounds. Unlike models that utilize Abraham solvation parameters, the new relationships use vapor pressure and aqueous solubility of the organic compound at 25 °C and CO2 density to predict partitioning coefficients over a range of temperature and pressure conditions. The compound class models provide better estimates of partitioning behavior for compounds in that class than does the model built for the entire data set.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Burant, Aniela; Thompson, Christopher; Lowry, Gregory V.
2016-05-17
Partitioning coefficients of organic compounds between water and supercritical CO2 (sc-CO2) are necessary to assess the risk of migration of these chemicals from subsurface CO2 storage sites. Despite the large number of potential organic contaminants, the current data set of published water-sc-CO2 partitioning coefficients is very limited. Here, the partitioning coefficients of thiophene, pyrrole, and anisole were measured in situ over a range of temperatures and pressures using a novel pressurized batch reactor system with dual spectroscopic detectors: a near infrared spectrometer for measuring the organic analyte in the CO2 phase, and a UV detector for quantifying the analyte inmore » the aqueous phase. Our measured partitioning coefficients followed expected trends based on volatility and aqueous solubility. The partitioning coefficients and literature data were then used to update a published poly-parameter linear free energy relationship and to develop five new linear free energy relationships for predicting water-sc-CO2 partitioning coefficients. Four of the models targeted a single class of organic compounds. Unlike models that utilize Abraham solvation parameters, the new relationships use vapor pressure and aqueous solubility of the organic compound at 25 °C and CO2 density to predict partitioning coefficients over a range of temperature and pressure conditions. The compound class models provide better estimates of partitioning behavior for compounds in that class than the model built for the entire dataset.« less
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Partitioning Evapotranspiration into Green and Blue Water Sources in the Conterminous United States.
Velpuri, Naga Manohar; Senay, Gabriel B
2017-07-21
In this study, we combined two 1 km actual evapotranspiration datasets (ET), one obtained from a root zone water balance model and another from an energy balance model, to partition annual ET into green (rainfall-based) and blue (surface water/groundwater) sources. Time series maps of green water ET (GWET) and blue water ET (BWET) are produced for the conterminous United States (CONUS) over 2001-2015. Our results indicate that average green and blue water for all land cover types in CONUS accounts for nearly 70% and 30% of the total ET, respectively. The ET in the eastern US arises mostly from GWET, and in the western US, it is mostly BWET. Analysis of the BWET in the 16 irrigated areas in CONUS revealed interesting results. While the magnitude of the BWET gradually showed a decline from west to east, the increase in coefficient of variation from west to east confirmed greater use of supplemental irrigation in the central and eastern US. We also established relationships between different hydro-climatology zones and their blue water requirements. This study provides insights on the relative contributions and the spatiotemporal dynamics of GWET and BWET, which could lead to improved water resources management.
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Toward prediction of alkane/water partition coefficients.
Toulmin, Anita; Wood, J Matthew; Kenny, Peter W
2008-07-10
Partition coefficients were measured for 47 compounds in the hexadecane/water ( P hxd) and 1-octanol/water ( P oct) systems. Some types of hydrogen bond acceptor presented by these compounds to the partitioning systems are not well represented in the literature of alkane/water partitioning. The difference, DeltalogP, between logP oct and logP hxd is a measure of the hydrogen bonding potential of a molecule and is identified as a target for predictive modeling. Minimized molecular electrostatic potential ( V min) was shown to be an effective predictor of the contribution of hydrogen bond acceptors to DeltalogP. Carbonyl oxygen atoms were found to be stronger hydrogen bond acceptors for their electrostatic potential than heteroaromatic nitrogen or oxygen bound to hypervalent sulfur or nitrogen. Values of V min calculated for hydrogen-bonded complexes were used to explore polarization effects. Predicted logP hxd and DeltalogP were shown to be more effective than logP oct for modeling brain penetration for a data set of 18 compounds.
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Measuring air-water interfacial area for soils using the mass balance surfactant-tracer method.
Araujo, Juliana B; Mainhagu, Jon; Brusseau, Mark L
2015-09-01
There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. Copyright © 2015 Elsevier Ltd. All rights reserved.
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Climate change impact on the annual water balance in the northwest Florida coastal
NASA Astrophysics Data System (ADS)
Alizad, K.; Wang, D.; Alimohammadi, N.; Hagen, S. C.
2012-12-01
As the largest tributary to the Apalachicola River, the Chipola River originates in southern Alabama, flows through Florida Panhandle and ended to Gulf of Mexico. The Chipola watershed is located in an intermediate climate environment with aridity index around one. Watershed provides habitat for a number of threatened and endangered animal and plant species. However, climate change affects hydrologic cycle of Chipola River watershed at various temporal and spatial scales. Studying the effects of climate variations is of great importance for water and environmental management purposes in this catchment. This research is mainly focuses on assessing climate change impact on the partitioning pattern of rainfall from mean annual to inter-annual and to seasonal scales. At the mean annual scale, rainfall is partitioned into runoff and evaporation assuming negligible water storage changes. Mean annual runoff is controlled by both mean annual precipitation and potential evaporation. Changes in long term mean runoff caused by variations of long term mean precipitation and potential evaporation will be evaluated based on Budyko hypothesis. At the annual scale, rainfall is partitioned into runoff, evaporation, and storage change. Inter-annual variability of runoff and evaporation are mainly affected by the changes of mean annual climate variables as well as their inter-annual variability. In order to model and evaluate each component of water balance at the annual scale, parsimonious but reliable models, are developed. Budyko hypothesis on the existing balance between available water and energy supply is reconsidered and redefined for the sub-annual time scale and reconstructed accordingly in order to accurately model seasonal hydrologic balance of the catchment. Models are built in the seasonal time frame with a focus on the role of storage change in water cycle. Then for Chipola catchment, models are parameterized based on a sufficient time span of historical data and the
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NASA Astrophysics Data System (ADS)
Biel, C.; Molina, A.; Aranda, X.; Llorens, P.; Savé, R.
2012-04-01
Tree plantation for wood production has been proposed to mitigate CO2-related climate change. Although these agroforestry systems can contribute to maintain the agriculture in some areas placed between rainfed crops and secondary forests, water scarcity in Mediterranean climate could restrict its growth, and their presence will affect the water balance. Tree plantations management (species, plant density, irrigation, etc), hence, can be used to affect the water balance, resulting in water availability improvement and buffering of the water cycle. Soil water content and meteorological data are widely used in agroforestry systems as indicators of vegetation water use, and consequently to define water management. However, the available information of ecohydrological processes in this kind of ecosystem is scarce. The present work studies how the temporal and spatial variation of soil water content is affected by transpiration and interception loss fluxes in a Mediterranean rainfed plantation of cherry tree (Prunus avium) located in Caldes de Montbui (Northeast of Spain). From May till December 2011, rainfall partitioning, canopy transpiration, soil water content and meteorological parameters were continuously recorded. Rainfall partitioning was measured in 6 trees, with 6 automatic rain recorders for throughfall and 1 automatic rain recorder for stemflow per tree. Transpiration was monitored in 12 nearby trees by means of heat pulse sap flow sensors. Soil water content was also measured at three different depths under selected trees and at two depths between rows without tree cover influence. This work presents the relationships between rainfall partitioning, transpiration and soil water content evolution under the tree canopy. The effect of tree cover on the soil water content dynamics is also analyzed.
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Withers, Philip C; Cooper, Christine E; Nespolo, Roberto F
2012-08-15
We examine here evaporative water loss, economy and partitioning at ambient temperatures from 14 to 33°C for the monito del monte (Dromiciops gliroides), a microbiotheriid marsupial found only in temperate rainforests of Chile. The monito's standard evaporative water loss (2.58 mg g(-1) h(-1) at 30°C) was typical for a marsupial of its body mass and phylogenetic position. Evaporative water loss was independent of air temperature below thermoneutrality, but enhanced evaporative water loss and hyperthermia were the primary thermal responses above the thermoneutral zone. Non-invasive partitioning of total evaporative water loss indicated that respiratory loss accounted for 59-77% of the total, with no change in respiratory loss with ambient temperature, but a small change in cutaneous loss below thermoneutrality and an increase in cutaneous loss in and above thermoneutrality. Relative water economy (metabolic water production/evaporative water loss) increased at low ambient temperatures, with a point of relative water economy of 15.4°C. Thermolability had little effect on relative water economy, but conferred substantial energy savings at low ambient temperatures. Torpor reduced total evaporative water loss to as little as 21% of normothermic values, but relative water economy during torpor was poor even at low ambient temperatures because of the relatively greater reduction in metabolic water production than in evaporative water loss. The poor water economy of the monito during torpor suggests that negative water balance may explain why hibernators periodically arouse to normothermia, to obtain water by drinking or via an improved water economy.
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OCTANOL/WATER PARTITION COEFFICIENTS AND WATER SOLUBILITIES OF PHTHALATE ESTERS
Measurements of the octanol/water partition coefficients (K-ow) and water solubilities of di-n-octyl phthalate (DnOP) and di-n-decyl phthalate (DnDP) by the slow-stirring method are reported. The water solubility was also measured for di-n-hexyl phthalate (DnHP). The log K-ow val...
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Water Partitioning in Planetary Embryos and Protoplanets with Magma Oceans
NASA Astrophysics Data System (ADS)
Ikoma, M.; Elkins-Tanton, L.; Hamano, K.; Suckale, J.
2018-06-01
The water content of magma oceans is widely accepted as a key factor that determines whether a terrestrial planet is habitable. Water ocean mass is determined as a result not only of water delivery and loss, but also of water partitioning among several reservoirs. Here we review our current understanding of water partitioning among the atmosphere, magma ocean, and solid mantle of accreting planetary embryos and protoplanets just after giant collisions. Magma oceans are readily formed in planetary embryos and protoplanets in their accretion phase. Significant amounts of water are partitioned into magma oceans, provided the planetary building blocks are water-rich enough. Particularly important but still quite uncertain issues are how much water the planetary building blocks contain initially and how water goes out of the solidifying mantle and is finally degassed to the atmosphere. Constraints from both solar-system explorations and exoplanet observations and also from laboratory experiments are needed to resolve these issues.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Bahadur, N.P.; Shiu, W.Y.; Boocock, D.G.B.
1999-01-01
Measurements of partition coefficients between tricaprylin (glyceryl tri-n-octanoate) and water are reported for seven chlorobenzenes (1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,3,5-trichlorobenzene, 1,2,3,4-tetrachlorobenzene, 1,2,3,5-tetrachlorobenzene, pentachlorobenzene, and hexachlorobenzene) between 5 and 45 C. The values are compared with reported data on octanol-water and triolein-water partition coefficients. The van`t Hoff plots of log K{sub OW} versus T{sup {minus}1} exhibit linearity with values of K{sub OW} increasing by 5--8% over this temperature range, and the enthalpy of phase change varies from 9.7 to 16 kJ/mol. Several reasons are suggested why tricaprylin-water partition coefficients may be preferable to octanol-water and triolein-water partition coefficients when quantifying a substance`s hydrophobicity.more » The mutual solubilities of tricaprylin and water are less than that of octanol and water. Tricaprylin is easier to purify than triolein and, because of its lower molecular mass, is easier to analyze by gas chromatography.« less
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Ecohydrology of Graciosa semi-natural grasslands: water use and evapotranspiration partition
NASA Astrophysics Data System (ADS)
Paço, Teresa A.; Paredes, Paula; Azevedo, Eduardo B.; Madruga, João S.; Pereira, Luís S.
2016-04-01
Semi-natural grasslands are a main landscape of Graciosa and other Islands of Azores. The present study aims at calibrate and validate the soil water balance model SIMDualKc for those grasslands aiming at assessing the dynamics of soil water and evapotranspiration. This objective relates with the need to improve knowledge on the ecohydrology of grasslands established in (volcanic) Andosols. This model adopts the dual crop coefficient approach to compute daily crop evapotranspiration (ETc) and to perform its partition into transpiration (T) and soil evaporation (Es). The application refers to a semi-natural grassland sporadically sowed with ryegrass (Lolium multiflorum Lam.). Model calibration and validation were performed comparing simulated against observed grassland evapotranspiration throughout two periods in consecutive years. Daily ET values were derived from eddy covariance data collected at the Eastern North Atlantic (ENA) facility of the ARM programme (established and supported by the U.S. Department of Energy with the collaboration of the local government and University of the Azores), at Graciosa, Azores (Portugal). Various statistical performance indicators were used to assess model accuracy and results show a good adequacy of the model for predicting vegetation ET in such conditions. Surface flux energy balance was also evaluated throughout the observation period (2014-2016). The ratio Es/ET shows that soil evaporation is much small than T/ET due to high soil cover by vegetation. The model was then applied to contrasting climatic conditions (dry vs. wet years) to assess related impacts on water balance components and grassland transpiration.
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NASA Astrophysics Data System (ADS)
Lu, X.; Liang, L.; Wang, L.; Jenerette, D.; Grantz, D. A.
2015-12-01
Agricultural production in the hot and arid low desert systems of southern California relies heavily on irrigation. A better understanding of how much and to what extent the irrigation water is transpired by crops relative to being lost through evaporation will contribute to better management of increasingly limited agricultural water resources. In this study, we examined the evapotranspiration (ET) partitioning over a field of forage sorghum (S. bicolor) during a growing season with several irrigation cycles. In several field campaigns we used continuous measurements of near-surface variations in the stable isotopic composition of water vapor (δ2H). We employed custom built transparent chambers coupled with a laser-based isotope analyzer and used Keeling plot and mass balance methods for surface flux partitioning. The preliminary results show that δT is more enriched than δE in the early growing season, and becomes less enriched than δE later in the season as canopy cover increases. There is an increase in the contribution of transpiration to ET as (1) leaf area index increases, and (2) as soil surface moisture declines. These results are consistent with theory, and extend these measurements to an environment that experiences extreme soil surface temperatures. The data further support the use of chamber based methods with stable isotopic analysis for characterization of ET partitioning in challenging field environments.
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Effects of partitioning and scheduling sparse matrix factorization on communication and load balance
NASA Technical Reports Server (NTRS)
Venugopal, Sesh; Naik, Vijay K.
1991-01-01
A block based, automatic partitioning and scheduling methodology is presented for sparse matrix factorization on distributed memory systems. Using experimental results, this technique is analyzed for communication and load imbalance overhead. To study the performance effects, these overheads were compared with those obtained from a straightforward 'wrap mapped' column assignment scheme. All experimental results were obtained using test sparse matrices from the Harwell-Boeing data set. The results show that there is a communication and load balance tradeoff. The block based method results in lower communication cost whereas the wrap mapped scheme gives better load balance.
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Estimation of octanol/water partition coefficients using LSER parameters
Luehrs, Dean C.; Hickey, James P.; Godbole, Kalpana A.; Rogers, Tony N.
1998-01-01
The logarithms of octanol/water partition coefficients, logKow, were regressed against the linear solvation energy relationship (LSER) parameters for a training set of 981 diverse organic chemicals. The standard deviation for logKow was 0.49. The regression equation was then used to estimate logKow for a test of 146 chemicals which included pesticides and other diverse polyfunctional compounds. Thus the octanol/water partition coefficient may be estimated by LSER parameters without elaborate software but only moderate accuracy should be expected.
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NASA Astrophysics Data System (ADS)
Abatzoglou, John T.; Ficklin, Darren L.
2017-09-01
The geographic variability in the partitioning of precipitation into surface runoff (Q) and evapotranspiration (ET) is fundamental to understanding regional water availability. The Budyko equation suggests this partitioning is strictly a function of aridity, yet observed deviations from this relationship for individual watersheds impede using the framework to model surface water balance in ungauged catchments and under future climate and land use scenarios. A set of climatic, physiographic, and vegetation metrics were used to model the spatial variability in the partitioning of precipitation for 211 watersheds across the contiguous United States (CONUS) within Budyko's framework through the free parameter ω. A generalized additive model found that four widely available variables, precipitation seasonality, the ratio of soil water holding capacity to precipitation, topographic slope, and the fraction of precipitation falling as snow, explained 81.2% of the variability in ω. The ω model applied to the Budyko equation explained 97% of the spatial variability in long-term Q for an independent set of watersheds. The ω model was also applied to estimate the long-term water balance across the CONUS for both contemporary and mid-21st century conditions. The modeled partitioning of observed precipitation to Q and ET compared favorably across the CONUS with estimates from more sophisticated land-surface modeling efforts. For mid-21st century conditions, the model simulated an increase in the fraction of precipitation used by ET across the CONUS with declines in Q for much of the eastern CONUS and mountainous watersheds across the western United States.
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Climate, soil water storage, and the average annual water balance
Milly, P.C.D.
1994-01-01
This paper describes the development and testing of the hypothesis that the long-term water balance is determined only by the local interaction of fluctuating water supply (precipitation) and demand (potential evapotranspiration), mediated by water storage in the soil. Adoption of this hypothesis, together with idealized representations of relevant input variabilities in time and space, yields a simple model of the water balance of a finite area having a uniform climate. The partitioning of average annual precipitation into evapotranspiration and runoff depends on seven dimensionless numbers: the ratio of average annual potential evapotranspiration to average annual precipitation (index of dryness); the ratio of the spatial average plant-available water-holding capacity of the soil to the annual average precipitation amount; the mean number of precipitation events per year; the shape parameter of the gamma distribution describing spatial variability of storage capacity; and simple measures of the seasonality of mean precipitation intensity, storm arrival rate, and potential evapotranspiration. The hypothesis is tested in an application of the model to the United States east of the Rocky Mountains, with no calibration. Study area averages of runoff and evapotranspiration, based on observations, are 263 mm and 728 mm, respectively; the model yields corresponding estimates of 250 mm and 741 mm, respectively, and explains 88% of the geographical variance of observed runoff within the study region. The differences between modeled and observed runoff can be explained by uncertainties in the model inputs and in the observed runoff. In the humid (index of dryness <1) parts of the study area, the dominant factor producing runoff is the excess of annual precipitation over annual potential evapotranspiration, but runoff caused by variability of supply and demand over time is also significant; in the arid (index of dryness >1) parts, all of the runoff is caused by variability
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PARTITION COEFFICIENTS FOR METALS IN SURFACE WATER, SOIL, AND WASTE
This report presents metal partition coefficients for the surface water pathway and for the source model used in the Multimedia, Multi-pathway, Multi-receptor Exposure and Risk Assessment (3MRA) technology under development by the U.S. Environmental Protection Agency. Partition ...
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Partitioning of monomethylmercury between freshwater algae and water.
Miles, C J; Moye, H A; Phlips, E J; Sargent, B
2001-11-01
Phytoplankton-water monomethylmercury (MeHg) partition constants (KpI) have been determined in the laboratory for two green algae Selenastrum capricornutum and Cosmarium botrytis, the blue-green algae Schizothrix calcicola, and the diatom Thallasiosira spp., algal species that are commonly found in natural surface waters. Two methods were used to determine KpI, the Freundlich isotherm method and the flow-through/dialysis bag method. Both methods yielded KpI values of about 10(6.6) for S. capricornutum and were not significantly different. The KpI for the four algae studied were similar except for Schizothrix, which was significantly lower than S. capricornutum. The KpI for MeHg and S. capricornutum (exponential growth) was not significantly different in systems with predominantly MeHgOH or MeHgCl species. This is consistent with other studies that show metal speciation controls uptake kinetics, but the reactivity with intracellular components controls steady-state concentrations. Partitioning constants determined with exponential and stationary phase S. capricornutum cells at the same conditions were not significantly different, while the partitioning constant for exponential phase, phosphorus-limited cells was significantly lower, suggesting that P-limitation alters the ecophysiology of S. capricornutum sufficiently to impact partitioning, which may then ultimately affect mercury levels in higher trophic species.
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A novel method for measuring polymer-water partition coefficients.
Zhu, Tengyi; Jafvert, Chad T; Fu, Dafang; Hu, Yue
2015-11-01
Low density polyethylene (LDPE) often is used as the sorbent material in passive sampling devices to estimate the average temporal chemical concentration in water bodies or sediment pore water. To calculate water phase chemical concentrations from LDPE concentrations accurately, it is necessary to know the LDPE-water partition coefficients (KPE-w) of the chemicals of interest. However, even moderately hydrophobic chemicals have large KPE-w values, making direct measurement experimentally difficult. In this study we evaluated a simple three phase system from which KPE-w can be determined easily and accurately. In the method, chemical equilibrium distribution between LDPE and a surfactant micelle pseudo-phase is measured, with the ratio of these concentrations equal to the LDPE-micelle partition coefficient (KPE-mic). By employing sufficient mass of polymer and surfactant (Brij 30), the mass of chemical in the water phase remains negligible, albeit in equilibrium. In parallel, the micelle-water partition coefficient (Kmic-w) is determined experimentally. KPE-w is the product of KPE-mic and Kmic-w. The method was applied to measure values of KPE-w for 17 polycyclic aromatic hydrocarbons, 37 polychlorinated biphenyls, and 9 polybrominated diphenylethers. These values were compared to literature values. Mass fraction-based chemical activity coefficients (γ) were determined in each phase and showed that for each chemical, the micelles and LDPE had nearly identical affinity. Copyright © 2014 Elsevier Ltd. All rights reserved.
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NASA Astrophysics Data System (ADS)
Velpuri, N. M.; Senay, G. B.
2017-12-01
Information on how much of direct rain water (green water) and/or non-rain water (blue water) are being productively used by the crops/vegetation is critical for efficient water resources management. In this study, we developed a simple but robust methodology to partition actual evapotranspiration (ET) into green (rainfall-based) and blue (surface water/groundwater) sources. We combined two 1 km MODIS-based actual evapotranspiration datasets, one obtained from a root zone water balance model and another from an energy balance model, to partition annual ET into green water ET (GWET) and blue water ET (BWET). Time series maps of GWET and BWET were produced for the conterminous United States (CONUS) over 2001-2015 and spatial variability and dynamics of blue and green water ET were analyzed. Our results indicate that average green and blue water sources for all land cover types in CONUS account for nearly 70% and 30% of the total ET, respectively. The ET in the eastern US arises mostly from green water, and in the western US, it is mostly from blue water sources. Analysis of the BWET in the 16 selected irrigated areas in CONUS revealed interesting results. While the magnitude of the BWET showed a gradual decline from west to east, the increase in coefficient of variation from west to east confirmed greater use of supplemental irrigation in the central and eastern US. We also established relationships between hydro-climatic regions and their blue water requirements. This study provides insights into the relative contributions and the spatiotemporal dynamics of GWET and BWET, which could lead to improved water resources management.
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Chiou, C.T.
1985-01-01
Triolein-water partition coefficients (KtW) have been determined for 38 slightly water-soluble organic compounds, and their magnitudes have been compared with the corresponding octanol-water partition coefficients (KOW). In the absence of major solvent-solute interaction effects in the organic solvent phase, the conventional treatment (based on Raoult's law) predicts sharply lower partition coefficients for most of the solutes in triolein because of its considerably higher molecular weight, whereas the Flory-Huggins treatment predicts higher partition coefficients with triolein. The data are in much better agreement with the Flory-Huggins model. As expected from the similarity in the partition coefficients, the water solubility (which was previously found to be the major determinant of the KOW) is also the major determinant for the Ktw. When the published BCF values (bioconcentration factors) of organic compounds in fish are based on the lipid content rather than on total mass, they are approximately equal to the Ktw, which suggests at least near equilibrium for solute partitioning between water and fish lipid. The close correlation between Ktw and Kow suggests that Kow is also a good predictor for lipid-water partition coefficients and bioconcentration factors.
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NASA Astrophysics Data System (ADS)
Wang, Hailong; Tetzlaff, Doerthe; Soulsby, Chris
2018-03-01
Climate and land cover are two major factors affecting the water fluxes and balance across spatiotemporal scales. These two factors and their impacts on hydrology are often interlinked. The quantification and differentiation of such impacts is important for developing sustainable land and water management strategies. Here, we calibrated the well-known Hydrus-1D model in a data-rich boreal headwater catchment in Scotland to assess the role of two dominant vegetation types (shrubs vs. trees) in regulating the soil water partitioning and balance. We also applied previously established climate projections for the area and replaced shrubs with trees to imitate current land use change proposals in the region, so as to quantify the potential impacts of climate and land cover changes on soil hydrology. Under tree cover, evapotranspiration and deep percolation to recharge groundwater was about 44% and 57% of annual precipitation, whilst they were about 10% lower and 9% higher respectively under shrub cover in this humid, low energy environment. Meanwhile, tree canopies intercepted 39% of annual precipitation in comparison to 23% by shrubs. Soils with shrub cover stored more water than tree cover. Land cover change was shown to have stronger impacts than projected climate change. With a complete replacement of shrubs with trees under future climate projections at this site, evapotranspiration is expected to increase by ∼39% while percolation to decrease by 21% relative to the current level, more pronounced than the modest changes in the two components (<8%) with climate change only. The impacts would be particularly marked in warm seasons, which may result in water stress experienced by the vegetation. The findings provide an important evidence base for adaptive management strategies of future changes in low-energy humid environments, where vegetation growth is usually restricted by radiative energy and not water availability while few studies that quantify soil water
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Dissipative particle dynamics: Systematic parametrization using water-octanol partition coefficients
NASA Astrophysics Data System (ADS)
Anderson, Richard L.; Bray, David J.; Ferrante, Andrea S.; Noro, Massimo G.; Stott, Ian P.; Warren, Patrick B.
2017-09-01
We present a systematic, top-down, thermodynamic parametrization scheme for dissipative particle dynamics (DPD) using water-octanol partition coefficients, supplemented by water-octanol phase equilibria and pure liquid phase density data. We demonstrate the feasibility of computing the required partition coefficients in DPD using brute-force simulation, within an adaptive semi-automatic staged optimization scheme. We test the methodology by fitting to experimental partition coefficient data for twenty one small molecules in five classes comprising alcohols and poly-alcohols, amines, ethers and simple aromatics, and alkanes (i.e., hexane). Finally, we illustrate the transferability of a subset of the determined parameters by calculating the critical micelle concentrations and mean aggregation numbers of selected alkyl ethoxylate surfactants, in good agreement with reported experimental values.
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NASA Astrophysics Data System (ADS)
Tian, Siyuan; Tregoning, Paul; Renzullo, Luigi J.; van Dijk, Albert I. J. M.; Walker, Jeffrey P.; Pauwels, Valentijn R. N.; Allgeyer, Sébastien
2017-03-01
The accuracy of global water balance estimates is limited by the lack of observations at large scale and the uncertainties of model simulations. Global retrievals of terrestrial water storage (TWS) change and soil moisture (SM) from satellites provide an opportunity to improve model estimates through data assimilation. However, combining these two data sets is challenging due to the disparity in temporal and spatial resolution at both vertical and horizontal scale. For the first time, TWS observations from the Gravity Recovery and Climate Experiment (GRACE) and near-surface SM observations from the Soil Moisture and Ocean Salinity (SMOS) were jointly assimilated into a water balance model using the Ensemble Kalman Smoother from January 2010 to December 2013 for the Australian continent. The performance of joint assimilation was assessed against open-loop model simulations and the assimilation of either GRACE TWS anomalies or SMOS SM alone. The SMOS-only assimilation improved SM estimates but reduced the accuracy of groundwater and TWS estimates. The GRACE-only assimilation improved groundwater estimates but did not always produce accurate estimates of SM. The joint assimilation typically led to more accurate water storage profile estimates with improved surface SM, root-zone SM, and groundwater estimates against in situ observations. The assimilation successfully downscaled GRACE-derived integrated water storage horizontally and vertically into individual water stores at the same spatial scale as the model and SMOS, and partitioned monthly averaged TWS into daily estimates. These results demonstrate that satellite TWS and SM measurements can be jointly assimilated to produce improved water balance component estimates.
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Latency Hiding in Dynamic Partitioning and Load Balancing of Grid Computing Applications
NASA Technical Reports Server (NTRS)
Das, Sajal K.; Harvey, Daniel J.; Biswas, Rupak
2001-01-01
The Information Power Grid (IPG) concept developed by NASA is aimed to provide a metacomputing platform for large-scale distributed computations, by hiding the intricacies of highly heterogeneous environment and yet maintaining adequate security. In this paper, we propose a latency-tolerant partitioning scheme that dynamically balances processor workloads on the.IPG, and minimizes data movement and runtime communication. By simulating an unsteady adaptive mesh application on a wide area network, we study the performance of our load balancer under the Globus environment. The number of IPG nodes, the number of processors per node, and the interconnected speeds are parameterized to derive conditions under which the IPG would be suitable for parallel distributed processing of such applications. Experimental results demonstrate that effective solution are achieved when the IPG nodes are connected by a high-speed asynchronous interconnection network.
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n-Alcohol/Water Partition Coefficients for Decachlorobiphenyl (PCB 209)
Measurements of n-octanol/water partition coefficients (Kow) for highly hydrophobic chemicals are extremely difficult and are rarely made, in part due to the large volumes of water typically needed to quantify these compounds in the aqueous phase. An extrapolation approach using ...
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NASA Astrophysics Data System (ADS)
Majozi, Nobuhle P.; Mannaerts, Chris M.; Ramoelo, Abel; Mathieu, Renaud; Nickless, Alecia; Verhoef, Wouter
2017-07-01
Flux towers provide essential terrestrial climate, water, and radiation budget information needed for environmental monitoring and evaluation of climate change impacts on ecosystems and society in general. They are also intended for calibration and validation of satellite-based Earth observation and monitoring efforts, such as assessment of evapotranspiration from land and vegetation surfaces using surface energy balance approaches. In this paper, 15 years of Skukuza eddy covariance data, i.e. from 2000 to 2014, were analysed for surface energy balance closure (EBC) and partitioning. The surface energy balance closure was evaluated using the ordinary least squares regression (OLS) of turbulent energy fluxes (sensible (H) and latent heat (LE)) against available energy (net radiation (Rn) less soil heat (G)), and the energy balance ratio (EBR). Partitioning of the surface energy during the wet and dry seasons was also investigated, as well as how it is affected by atmospheric vapour pressure deficit (VPD), and net radiation. After filtering years with low-quality data (2004-2008), our results show an overall mean EBR of 0.93. Seasonal variations of EBR also showed the wet season with 1.17 and spring (1.02) being closest to unity, with the dry season (0.70) having the highest imbalance. Nocturnal surface energy closure was very low at 0.26, and this was linked to low friction velocity during night-time, with results showing an increase in closure with increase in friction velocity. The energy partition analysis showed that sensible heat flux is the dominant portion of net radiation, especially between March and October, followed by latent heat flux, and lastly the soil heat flux, and during the wet season where latent heat flux dominated sensible heat flux. An increase in net radiation was characterized by an increase in both LE and H, with LE showing a higher rate of increase than H in the wet season, and the reverse happening during the dry season. An increase in
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Raevsky, O A; Grigor'ev, V J; Raevskaja, O E; Schaper, K-J
2006-06-01
QSPR analyses of a data set containing experimental partition coefficients in the three systems octanol-water, water-gas, and octanol-gas for 98 chemicals have shown that it is possible to calculate any partition coefficient in the system 'gas phase/octanol/water' by three different approaches: (1) from experimental partition coefficients obtained in the corresponding two other subsystems. However, in many cases these data may not be available. Therefore, a solution may be approached (2), a traditional QSPR analysis based on e.g. HYBOT descriptors (hydrogen bond acceptor and donor factors, SigmaCa and SigmaCd, together with polarisability alpha, a steric bulk effect descriptor) and supplemented with substructural indicator variables. (3) A very promising approach which is a combination of the similarity concept and QSPR based on HYBOT descriptors. In this approach observed partition coefficients of structurally nearest neighbours of a compound-of-interest are used. In addition, contributions arising from differences in alpha, SigmaCa, and SigmaCd values between the compound-of-interest and its nearest neighbour(s), respectively, are considered. In this investigation highly significant relationships were obtained by approaches (1) and (3) for the octanol/gas phase partition coefficient (log Log).
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Partitioning of Aromatic Constituents into Water from Jet Fuels.
Tien, Chien-Jung; Shu, Youn-Yuen; Ciou, Shih-Rong; Chen, Colin S
2015-08-01
A comprehensive study of the most commonly used jet fuels (i.e., Jet A-1 and JP-8) was performed to properly assess potential contamination of the subsurface environment from a leaking underground storage tank occurred in an airport. The objectives of this study were to evaluate the concentration ranges of the major components in the water-soluble fraction of jet fuels and to estimate the jet fuel-water partition coefficients (K fw) for target compounds using partitioning experiments and a polyparameter linear free-energy relationship (PP-LFER) approach. The average molecular weight of Jet A-1 and JP-8 was estimated to be 161 and 147 g/mole, respectively. The density of Jet A-1 and JP-8 was measured to be 786 and 780 g/L, respectively. The distribution of nonpolar target compounds between the fuel and water phases was described using a two-phase liquid-liquid equilibrium model. Models were derived using Raoult's law convention for the activity coefficients and the liquid solubility. The observed inverse, log-log linear dependence of the K fw values on the aqueous solubility were well predicted by assuming jet fuel to be an ideal solvent mixture. The experimental partition coefficients were generally well reproduced by PP-LFER.
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W.J. Mattson; R. Julkunen-Tiitto; D.A. Herms
2005-01-01
Rising levels of atmospheric CO2 can alter plant growth and partitioning to secondary metabolites. The protein competition model (PCM) and the extended growth/differentiation balance model (GDBe) are similar but alternative models that address ontogenetic and environmental effects on whole-plant carbon partitioning to the...
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Buttle, James; Carey, Sean K.; van Huijgevoort, Marjolein H. J.; Laudon, Hjalmar; McNamara, James P.; Mitchell, Carl P. J.; Spence, Chris; Gabor, Rachel S.; Soulsby, Chris
2015-01-01
Abstract We combined a conceptual rainfall‐runoff model and input–output relationships of stable isotopes to understand ecohydrological influences on hydrological partitioning in snow‐influenced northern catchments. Six sites in Sweden (Krycklan), Canada (Wolf Creek; Baker Creek; Dorset), Scotland (Girnock) and the USA (Dry Creek) span moisture and energy gradients found at high latitudes. A meta‐analysis was carried out using the Hydrologiska Byråns Vattenbalansavdelning (HBV) model to estimate the main storage changes characterizing annual water balances. Annual snowpack storage importance was ranked as Wolf Creek > Krycklan > Dorset > Baker Creek > Dry Creek > Girnock. The subsequent rate and longevity of melt were reflected in calibrated parameters that determine partitioning of waters between more rapid and slower flowpaths and associated variations in soil and groundwater storage. Variability of stream water isotopic composition depends on the following: (i) rate and duration of spring snowmelt; (ii) significance of summer/autumn rainfall; and (iii) relative importance of near‐surface and deeper flowpaths in routing water to the stream. Flowpath partitioning also regulates influences of summer evaporation on drainage waters. Deviations of isotope data from the Global Meteoric Water Line showed subtle effects of internal catchment processes on isotopic fractionation most likely through evaporation. Such effects are highly variable among sites and with seasonal differences at some sites. After accounting for climate, evaporative fractionation is strongest at sites where lakes and near‐surface runoff processes in wet riparian soils can mobilize isotopically enriched water during summer and autumn. Given close soil–vegetation coupling, this may result in spatial variability in soil water isotope pools available for plant uptake. We argue that stable isotope studies are crucial in addressing the many open questions on
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Effect of demulsifier partitioning on the destabilization of water-in-oil emulsions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kim, Y.H.; Wasan, D.T.
1996-04-01
The factors affecting the demulsification and interfacial behavior of water-in-oil emulsions in the presence of oil-soluble demulsifiers were investigated. Using both model water-in-oil and water-in-crude oil emulsion systems with demulsifiers with different chemical structures, the effects of demulsifier partitioning on the interfacial and film rheological properties were studied. The experimental results were compared and related with the demulsifier performance. There is a one-to-one correlation between the performance of demulsifier and the interfacial activity of the partitioned demulsifier; the partitioned demulsifier components exhibit an increase in static and dynamic interfacial activity, low dynamic interfacial and film tension, and a low filmmore » dilational modulus with a high adsorption rate - low interfacial tension gradient (Marangoni-Gibbs stabilizing effect) and have excellent demulsification performance.« less
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Multi-A Graph Patrolling and Partitioning
NASA Astrophysics Data System (ADS)
Elor, Y.; Bruckstein, A. M.
2012-12-01
We introduce a novel multi agent patrolling algorithm inspired by the behavior of gas filled balloons. Very low capability ant-like agents are considered with the task of patrolling an unknown area modeled as a graph. While executing the proposed algorithm, the agents dynamically partition the graph between them using simple local interactions, every agent assuming the responsibility for patrolling his subgraph. Balanced graph partition is an emergent behavior due to the local interactions between the agents in the swarm. Extensive simulations on various graphs (environments) showed that the average time to reach a balanced partition is linear with the graph size. The simulations yielded a convincing argument for conjecturing that if the graph being patrolled contains a balanced partition, the agents will find it. However, we could not prove this. Nevertheless, we have proved that if a balanced partition is reached, the maximum time lag between two successive visits to any vertex using the proposed strategy is at most twice the optimal so the patrol quality is at least half the optimal. In case of weighted graphs the patrol quality is at least (1)/(2){lmin}/{lmax} of the optimal where lmax (lmin) is the longest (shortest) edge in the graph.
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NASA Astrophysics Data System (ADS)
Bateman, J. B.; Fendorf, S. E.; Vitousek, P.
2017-12-01
Iron (Fe) and Aluminum (Al) are major components of volcanic soils, and strongly influence the stability of soil carbon (C). The stability of Fe and Al phases is dictated by the redox conditions and pH of soils, respectively. The water balance of a soil, defined as annual precipitation minus evapotranspiration, ultimately controls pH and redox conditions. Consequently, we hypothesize that water balance influences Fe/Al solid phase dynamics in volcanic soils when the climatic regime has persisted on timescales of 20 ky. To test this hypothesis, we collected soils from a naturally occurring water balance gradient on the windward side of Mauna Kea Volcano in Hawaii, across which water balance ranges from -1270 mm/y to +2000 mm/y. Sampling included complete soil profiles, and 30 cm surface soil samples. We determined the solid phases of Fe/Al with selective extractions and total C via combustion. Extracted Fe/Al were then partitioned into operational pools: organically bound, amorphous, crystalline, primary mineral, primary glass, and residual. All soils in the study were acidic, with pH between 3.4 and 6.4. Soil C varied considerably across the gradient, from <1% C to >15% C by weight. Across sites, soil pH, Fe in primary minerals and glasses, and residual Al are negatively correlated with water balance, while soil C, organic Fe and Al, and crystalline Fe correlated positively with water balance. Organically bound Al increases linearly with water balance, while organically bound Fe is uncorrelated with water balance in soils where water balance is negative and is positively correlated with water balance in wetter sites. These results show that soils developing from the same parent material, though under different water balance regimes, range from lightly weathered ash deposits with little C accumulation in the driest regions, to heavily weathered soils composed of crystalline Fe, organic matter, and organically bound Fe/Al in the wettest regions. Al appears to be the
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Effect of water saturation in soil organic matter on the partition of organic compounds
Rutherford, D.W.; Chlou, G.T.
1992-01-01
The sorption of benzene, trichloroethylene, and carbon tetrachloride at room temperature from water solution and from vapor on two high-organic-content soils (peat and muck) was determined in order to evaluate the effect of water saturation on the solute partition in soil organic matter (SOM). The uptake of water vapor was similarly determined to define the amounts of water in the saturated soil samples. In such high-organic-content soils the organic vapor sorption and the respective solute sorption from water exhibit linear isotherms over a wide range of relative concentrations. This observation, along with the low BET surface areas of the samples, suggests that partition in the SOM of the samples is the dominant process in the uptake of these liquids. A comparison of the sorption from water solution and from vapor phase shows that water saturation reduces the sorption (partition) efficiency of SOM by ?? 42%; the saturated water content is ??38% by weight of dry SOM. This reduction is relatively small when compared with the almost complete suppression by water of organic compound adsorption on soil minerals. While the effect of water saturation on solute uptake by SOM is much expected in terms of solute partition in SOM, the influence of water on the solubility behavior of polar SOM can be explained only qualitatively by regular solution theory. The results suggest that the major effect of water in a drying-wetting cycle on the organic compound uptake by normal low-organic-content soils (and the associated compound's activity) is the suppression of adsorption by minerals rather than the mitigation of the partition effect in SOM.
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Water partitioning in the Earth's mantle
NASA Astrophysics Data System (ADS)
Inoue, Toru; Wada, Tomoyuki; Sasaki, Rumi; Yurimoto, Hisayoshi
2010-11-01
We have conducted H2O partitioning experiments between wadsleyite and ringwoodite and between ringwoodite and perovskite at 1673 K and 1873 K, respectively. These experiments were performed in order to constrain the relative distribution of H2O in the upper mantle, the mantle transition zone, and the lower mantle. We successfully synthesized coexisting mineral assemblages of wadsleyite-ringwoodite and ringwoodite-perovskite that were large enough to measure the H2O contents by secondary ion mass spectrometry (SIMS). Combining our previous H2O partitioning data (Chen et al., 2002) with the present results, the determined water partitioning between olivine, wadsleyite, ringwoodite, and perovskite under H2O-rich fluid saturated conditions are 6:30:15:1, respectively. Because the maximum H2O storage capacity in wadsleyite is ∼3.3 wt% (e.g. Inoue et al., 1995), the possible maximum H2O storage capacity in the olivine high-pressure polymorphs are as follows: ∼0.7 wt% in olivine (upper mantle just above 410 km depth), ∼3.3 wt% in wadsleyite (410-520 km depth), ∼1.7 wt% in ringwoodite (520-660 km depth), and ∼0.1 wt% in perovskite (lower mantle). If we assume ∼0.2 wt% of the H2O content in wadsleyite in the mantle transition zone estimated by recent electrical conductivity measurements (e.g. Dai and Karato, 2009), the estimated H2O contents throughout the mantle are as follows; ∼0.04 wt% in olivine (upper mantle just above 410 km depth), ∼0.2 wt% in wadsleyite (410-520 km depth), ∼0.1 wt% in ringwoodite (520-660 km depth) and ∼0.007 wt% in perovskite (lower mantle). Thus, the mantle transition zone should contain a large water reservoir in the Earth's mantle compared to the upper mantle and the lower mantle.
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An Energy Balance Model to Predict Chemical Partitioning in a Photosynthetic Microbial Mat
NASA Technical Reports Server (NTRS)
Hoehler, Tori M.; Albert, Daniel B.; DesMarais, David J.
2006-01-01
Studies of biosignature formation in photosynthetic microbial mat communities offer potentially useful insights with regards to both solar and extrasolar astrobiology. Biosignature formation in such systems results from the chemical transformation of photosynthetically fixed carbon by accessory microorganisms. This fixed carbon represents a source not only of reducing power, but also energy, to these organisms, so that chemical and energy budgets should be coupled. We tested this hypothesis by applying an energy balance model to predict the fate of photosynthetic productivity under dark, anoxic conditions. Fermentation of photosynthetically fixed carbon is taken to be the only source of energy available to cyanobacteria in the absence of light and oxygen, and nitrogen fixation is the principal energy demand. The alternate fate for fixed carbon is to build cyanobacterial biomass with Redfield C:N ratio. The model predicts that, under completely nitrogen-limited conditions, growth is optimized when 78% of fixed carbon stores are directed into fermentative energy generation, with the remainder allocated to growth. These predictions were compared to measurements made on microbial mats that are known to be both nitrogen-limited and populated by actively nitrogen-fixing cyanobacteria. In these mats, under dark, anoxic conditions, 82% of fixed carbon stores were diverted into fermentation. The close agreement between these independent approaches suggests that energy balance models may provide a quantitative means of predicting chemical partitioning within such systems - an important step towards understanding how biological productivity is ultimately partitioned into biosignature compounds.
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Feng, Chenghong; Guo, Xiaoyu; Yin, Su; Tian, Chenhao; Li, Yangyang; Shen, Zhenyao
2017-10-01
The partitioning of ten heavy metals (As, Cd, Co, Cr, Cu, Hg, Ni, Pb, Sb, and Zn) between the water, suspended particulate matter (SPM), and sediments in seven channel sections during three hydrologic seasons in the Yangtze Estuary was comprehensively investigated. Special attention was paid to the role of tides, influential factors (concentrations of SPM and dissolved organic carbon, and particle size), and heavy metal speciation. The SPM-water and sediment-water partition coefficients (K p ) of the heavy metals exhibited similar changes along the channel sections, though the former were larger throughout the estuary. Because of the higher salinity, the K p values of most of the metals were higher in the north branch than in the south branch. The K p values of Cd, Co, and As generally decreased from the wet season to the dry season. Both the diagonal line method and paired samples t-test showed that no specific phase transfer of heavy metals existed during the flood and ebb tides, but the sediment-water K p was more concentrated for the diagonal line method, owing to the relatively smaller tidal influences on the sediment. The partition coefficients (especially the K p for SPM-water) had negative correlations with the dissolved organic carbon (DOC) but positive correlations were noted with the particle size for most of the heavy metals in sediment. Two types of significant correlations were observed between K p and metal speciation (i.e., exchangeable, carbonate, reducible, organic, and residual fractions), which can be used to identify the dominant phase-partition mechanisms (e.g., adsorption or desorption) of heavy metals. Copyright © 2017 Elsevier Ltd. All rights reserved.
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An Approach to Modeling the Water Balance Sensitivity to Landscape Vegetation Changes
NASA Astrophysics Data System (ADS)
Mohammed, I. N.; Tarboton, D. G.
2008-12-01
Watershed development and management require an understanding of how hydrological processes affect water balance components. The study of water resources management, especially in Western United States, is currently motivated by climate change, the impact of vegetation cover change on water production, and the need to manage water supplies. Vegetation management and its relation to runoff has been well documented, as reduction of forest cover, reducing evapotranspiration, increases water yield and in contrast the establishment of forest cover on sparsely vegetated land, increasing evapotranspiration, deceases water yield. This paper presents a water balance model developed to quantify the sensitivity of runoff production to changes in vegetation based on differences in evapotranspiration from different land cover types. The model is intended to provide a simple framework for estimating long term yield changes due to managed vegetation change. The model assumes that relative potential evapotranspiration from specific land cover can be quantified by a set of potential evapotranspiration coefficients for each land cover type. The model uses the Budyko curve to partition precipitation into evapotranspiration and runoff over the long term. Potential evapotranspiration is estimated from the Budyko curve for present conditions, then adjusted for land cover changes using the relative potential evapotranspiration coefficients for each land cover type. The adjusted potential evapotranspiration is then partitioned using the Budyko curve to provide estimates of long term runoff and evapotranspiration for the changed conditions. We found that the changes in runoff were in general close to being linearly proportional to the changes in land cover. In Utah study watersheds, reducing 50% of the present coniferous forests resulted in runoff increase that ranged from 0.5 to 38 mm/year, while the transition of 50% of area present as range/shrub/other to forest resulted in runoff
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Chiou, C.T.; Schmedding, D.W.; Manes, M.
2005-01-01
A volume-fraction-based solvent-water partition model for dilute solutes, in which the partition coefficient shows a dependence on solute molar volume (V??), is adapted to predict the octanol-water partition coefficient (K ow) from the liquid or supercooled-liquid solute water solubility (Sw), or vice versa. The established correlation is tested for a wide range of industrial compounds and pesticides (e.g., halogenated aliphatic hydrocarbons, alkylbenzenes, halogenated benzenes, ethers, esters, PAHs, PCBs, organochlorines, organophosphates, carbamates, and amidesureas-triazines), which comprise a total of 215 test compounds spanning about 10 orders of magnitude in Sw and 8.5 orders of magnitude in Kow. Except for phenols and alcohols, which require special considerations of the Kow data, the correlation predicts the Kow within 0.1 log units for most compounds, much independent of the compound type or the magnitude in K ow. With reliable Sw and V data for compounds of interest, the correlation provides an effective means for either predicting the unavailable log Kow values or verifying the reliability of the reported log Kow data. ?? 2005 American Chemical Society.
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Alternative measures of lipophilicity: from octanol-water partitioning to IAM retention.
Giaginis, Costas; Tsantili-Kakoulidou, Anna
2008-08-01
This review describes lipophilicity parameters currently used in drug design and QSAR studies. After a short historical overview, the complex nature of lipophilicity as the outcome of polar/nonpolar inter- and intramolecular interactions is analysed and considered as the background for the discussion of the different lipophilicity descriptors. The first part focuses on octanol-water partitioning of neutral and ionisable compounds, evaluates the efficiency of predictions and provides a short description of the experimental methods for the determination of distribution coefficients. A next part is dedicated to reversed-phase chromatographic techniques, HPLC and TLC in lipophilicity assessment. The two methods are evaluated for their efficiency to simulate octanol-water and the progress achieved in the refinement of suitable chromatographic conditions, in particular in the field of HPLC, is outlined. Liposomes as direct models of biological membranes are examined and phospolipophilicity is compared to the traditional lipophilicity concept. Difficulties associated with liposome-water partitioning are discussed. The last part focuses on Immobilised Artificial Membrane (IAM) chromatography as an alternative which combines membrane simulation with rapid measurements. IAM chromatographic retention is compared to octanol-water and liposome-water partitioning as well as to reversed-phase retention and its potential to predict biopartitioning and biological activities is discussed.
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A partition-limited model for the plant uptake of organic contaminants from soil and water
Chiou, C.T.; Sheng, G.; Manes, M.
2001-01-01
In dealing with the passive transport of organic contaminants from soils to plants (including crops), a partition-limited model is proposed in which (i) the maximum (equilibrium) concentration of a contaminant in any location in the plant is determined by partition equilibrium with its concentration in the soil interstitial water, which in turn is determined essentially by the concentration in the soil organic matter (SOM) and (ii) the extent of approach to partition equilibrium, as measured by the ratio of the contaminant concentrations in plant water and soil interstitial water, ??pt (??? 1), depends on the transport rate of the contaminant in soil water into the plant and the volume of soil water solution that is required for the plant contaminant level to reach equilibrium with the external soil-water phase. Through reasonable estimates of plant organic-water compositions and of contaminant partition coefficients with various plant components, the model accounts for calculated values of ??pt in several published crop-contamination studies, including near-equilibrium values (i.e., ??pt ??? 1) for relatively water-soluble contaminants and lower values for much less soluble contaminants; the differences are attributed to the much higher partition coefficients of the less soluble compounds between plant lipids and plant water, which necessitates much larger volumes of the plant water transport for achieving the equilibrium capacities. The model analysis indicates that for plants with high water contents the plant-water phase acts as the major reservoir for highly water-soluble contaminants. By contrast, the lipid in a plant, even at small amounts, is usually the major reservoir for highly water-insoluble contaminants.
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A Four-parameter Budyko Equation for Mean Annual Water Balance
NASA Astrophysics Data System (ADS)
Tang, Y.; Wang, D.
2016-12-01
In this study, a four-parameter Budyko equation for long-term water balance at watershed scale is derived based on the proportionality relationships of the two-stage partitioning of precipitation. The four-parameter Budyko equation provides a practical solution to balance model simplicity and representation of dominated hydrologic processes. Under the four-parameter Budyko framework, the key hydrologic processes related to the lower bound of Budyko curve are determined, that is, the lower bound is corresponding to the situation when surface runoff and initial evaporation not competing with base flow generation are zero. The derived model is applied to 166 MOPEX watersheds in United States, and the dominant controlling factors on each parameter are determined. Then, four statistical models are proposed to predict the four model parameters based on the dominant controlling factors, e.g., saturated hydraulic conductivity, fraction of sand, time period between two storms, watershed slope, and Normalized Difference Vegetation Index. This study shows a potential application of the four-parameter Budyko equation to constrain land-surface parameterizations in ungauged watersheds or general circulation models.
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Partitioning studies of coal-tar constituents in a two-phase contaminated ground-water system
Rostad, C.E.; Pereira, W.E.; Hult, M.F.
1985-01-01
Organic compounds derived from coal-tar wastes in a contaminated aquifer in St. Louis Park, Minnesota, were identified, and their partition coefficients between the tar phase and aqueous phase were determined and compared with the corresponding n-octanol/water partition coefficients. Coal tar contains numerous polycyclic aromatic compounds, many of which are suspected carcinogens or mutagens. Groundwater contamination by these toxic compounds may pose an environmental health hazard in nearby public water-supply wells. Fluid samples from this aquifer developed two phases upon settling: an upper aqueous phase, and a lower oily-tar phase. After separating the phases, polycyclic aromatic compounds in each phase were isolated using complexation with N-methyl-2-pyrrolidone and identified by fused-silica capillary gas chromatography/mass spectrometry. Thirty-one of the polycyclic aromatic compounds were chosen for further study from four different classes: 12 polycyclic aromatic hydrocarbons, 10 nitrogen heterocycles, 5 sulfur heterocycles, and 4 oxygen heterocycles. Within each compound class, the tar/water partition coefficients of these compounds were reasonably comparable with the respective n-octanol/water partition coefficient.
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Skylab water balance error analysis
NASA Technical Reports Server (NTRS)
Leonard, J. I.
1977-01-01
Estimates of the precision of the net water balance were obtained for the entire Skylab preflight and inflight phases as well as for the first two weeks of flight. Quantitative estimates of both total sampling errors and instrumentation errors were obtained. It was shown that measurement error is minimal in comparison to biological variability and little can be gained from improvement in analytical accuracy. In addition, a propagation of error analysis demonstrated that total water balance error could be accounted for almost entirely by the errors associated with body mass changes. Errors due to interaction between terms in the water balance equation (covariances) represented less than 10% of the total error. Overall, the analysis provides evidence that daily measurements of body water changes obtained from the indirect balance technique are reasonable, precise, and relaible. The method is not biased toward net retention or loss.
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Lee, Kil Yong; Burnett, William C
A simple method for the direct determination of the air-loop volume in a RAD7 system as well as the radon partition coefficient was developed allowing for an accurate measurement of the radon activity in any type of water. The air-loop volume may be measured directly using an external radon source and an empty bottle with a precisely measured volume. The partition coefficient and activity of radon in the water sample may then be determined via the RAD7 using the determined air-loop volume. Activity ratios instead of absolute activities were used to measure the air-loop volume and the radon partition coefficient. In order to verify this approach, we measured the radon partition coefficient in deionized water in the temperature range of 10-30 °C and compared the values to those calculated from the well-known Weigel equation. The results were within 5 % variance throughout the temperature range. We also applied the approach for measurement of the radon partition coefficient in synthetic saline water (0-75 ppt salinity) as well as tap water. The radon activity of the tap water sample was determined by this method as well as the standard RAD-H 2 O and BigBottle RAD-H 2 O. The results have shown good agreement between this method and the standard methods.
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Partitioning Behavior of Petrodiesel/Biodiesel Blends in Water
The partitioning behavior of six petrodiesel/soybean-biodiesel blends (B0, B20, B40, B60, B80, and B100, where B100 is 100% unblended biodiesel) in water was investigated at various oil loads by the 10-fold dilution method. Five fatty acid methyl esters (FAMEs), C10 - C20 n
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Saranjampour, Parichehr; Vebrosky, Emily N; Armbrust, Kevin L
2017-09-01
Salinity has been reported to influence the water solubility of organic chemicals entering marine ecosystems. However, limited data are available on salinity impacts for chemicals potentially entering seawater. Impacts on water solubility would correspondingly impact chemical sorption as well as overall bioavailability and exposure estimates used in the regulatory assessment. The pesticides atrazine, fipronil, bifenthrin, and cypermethrin, as well as the crude oil constituent dibenzothiophene together with 3 of its alkyl derivatives, all have different polarities and were selected as model compounds to demonstrate the impact of salinity on their solubility and partitioning behavior. The n-octanol/water partition coefficient (K OW ) was measured in both distilled-deionized water and artificial seawater (3.2%). All compounds had diminished solubility and increased K OW values in artificial seawater compared with distilled-deionized water. A linear correlation curve estimated salinity may increase the log K OW value by 2.6%/1 log unit increase in distilled water (R 2 = 0.97). Salinity appears to generally decrease the water solubility and increase the partitioning potential. Environmental fate estimates based on these parameters indicate elevated chemical sorption to sediment, overall bioavailability, and toxicity in artificial seawater. These dramatic differences suggest that salinity should be taken into account when exposure estimates are made for marine organisms. Environ Toxicol Chem 2017;36:2274-2280. © 2017 SETAC. © 2017 SETAC.
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NASA Astrophysics Data System (ADS)
Song, Lisheng; Kustas, William P.; Liu, Shaomin; Colaizzi, Paul D.; Nieto, Hector; Xu, Ziwei; Ma, Yanfei; Li, Mingsong; Xu, Tongren; Agam, Nurit; Tolk, Judy A.; Evett, Steven R.
2016-09-01
In this study ground measured soil and vegetation component temperatures and composite temperature from a high spatial resolution thermal camera and a network of thermal-IR sensors collected in an irrigated maize field and in an irrigated cotton field are used to assess and refine the component temperature partitioning approach in the Two-Source Energy Balance (TSEB) model. A refinement to TSEB using a non-iterative approach based on the application of the Priestley-Taylor formulation for surface temperature partitioning and estimating soil evaporation from soil moisture observations under advective conditions (TSEB-A) was developed. This modified TSEB formulation improved the agreement between observed and modeled soil and vegetation temperatures. In addition, the TSEB-A model output of evapotranspiration (ET) and the components evaporation (E), transpiration (T) when compared to ground observations using the stable isotopic method and eddy covariance (EC) technique from the HiWATER experiment and with microlysimeters and a large monolithic weighing lysimeter from the BEAREX08 experiment showed good agreement. Difference between the modeled and measured ET measurements were less than 10% and 20% on a daytime basis for HiWATER and BEAREX08 data sets, respectively. The TSEB-A model was found to accurately reproduce the temporal dynamics of E, T and ET over a full growing season under the advective conditions existing for these irrigated crops located in arid/semi-arid climates. With satellite data this TSEB-A modeling framework could potentially be used as a tool for improving water use efficiency and conservation practices in water limited regions. However, TSEB-A requires soil moisture information which is not currently available routinely from satellite at the field scale.
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Water balance model for Kings Creek
NASA Technical Reports Server (NTRS)
Wood, Eric F.
1990-01-01
Particular attention is given to the spatial variability that affects the representation of water balance at the catchment scale in the context of macroscale water-balance modeling. Remotely sensed data are employed for parameterization, and the resulting model is developed so that subgrid spatial variability is preserved and therefore influences the grid-scale fluxes of the model. The model permits the quantitative evaluation of the surface-atmospheric interactions related to the large-scale hydrologic water balance.
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Buckminsterfullerene's (C60) octanol-water partition coefficient (Kow) and aqueous solubility.
Jafvert, Chad T; Kulkarni, Pradnya P
2008-08-15
To assess the risk and fate of fullerene C60 in the environment, its water solubility and partition coefficients in various systems are useful. In this study, the log Kow of C60 was measured to be 6.67, and the toluene-water partition coefficient was measured at log Ktw = 8.44. From these values and the respective solubilities of C60 in water-saturated octanol and water-saturated toluene, C60's aqueous solubility was calculated at 7.96 ng/L(1.11 x 10(-11) M) for the organic solvent-saturated aqueous phase. Additionally, the solubility of C60 was measured in mixtures of ethanol-water and tetrahydrofuran-water and modeled with Wohl's equation to confirm the accuracy of the calculated solubility value. Results of a generator column experiment strongly support the hypothesis that clusters form at aqueous concentrations below or near this calculated solubility. The Kow value is compared to those of other hydrophobic organic compounds, and bioconcentration factors for C60 were estimated on the basis of Kow.
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Biodiversity effects on the water balance of an experimental grassland
NASA Astrophysics Data System (ADS)
Leimer, Sophia; Kreutziger, Yvonne; Rosenkranz, Stephan; Beßler, Holger; Engels, Christof; Oelmann, Yvonne; Weisser, Wolfgang W.; Wirth, Christian; Wilcke, Wolfgang
2013-04-01
Plant species richness increases aboveground biomass production in biodiversity experiments. Biomass production depends on and feeds back to the water balance, but it remains unclear how plant species richness influences soil water contents and water fluxes (actual evapotranspiration (ETa), downward flux (DF), and upward flux (UF)). Our objective was to determine the effects of plant species and functional richness and functional identity on soil water contents and water fluxes for two soil depths (0-0.3 and 0.3.-0.7 m). To achieve this, we used a water balance model in connection with Bayesian hierarchical modeling. We monitored soil water contents on 86 plots of a grassland plant diversity experiment in Jena, Germany between July 2002 and January 2006. In the field experiment, plant species richness (0, 1, 2, 4, 8, 16, 60) and functional group composition (0-4 functional groups: legumes, grasses, non-leguminous tall herbs, non-leguminous small herbs) were manipulated in a factorial design. Climate data (air temperature, precipitation, wind velocity, relative humidity, global radiation, soil moisture) was measured at a central climate station between July 2002 and December 2007. Root biomass data from July 2006 was available per plot. Missing water contents per plot and depth were estimated in weekly resolution for the years 2003-2007 with a Bayesian hierarchical model using measured water contents per plot and centrally measured soil moisture. To obtain ETa, DF, and UF of the two different soil depths, we modified a soil water balance model which had been developed for our study site. The model is based on changes in soil water content between subsequent observation dates and modeled potential evapotranspiration which was partitioned between soil layers according to percentage of root biomass. The presence of specific functional groups significantly changed water contents and fluxes with partly opposing effects in the two soil depths. Presence of grasses
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47 CFR 90.813 - Partitioned licenses and disaggregated spectrum.
Code of Federal Regulations, 2010 CFR
2010-10-01
... defined by coordinate points at every 3 degrees along the partitioned service area unless an FCC... disaggregation. (c) Installment payments—(1) Apportioning the balance on installment payment plans. When a... partitions its licensed area or disaggregates spectrum to another party, the outstanding balance owed by the...
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Influence of vegetation on water isotope partitioning across different northern headwater catchments
NASA Astrophysics Data System (ADS)
Gabor, R. S.; Tetzlaff, D.; Buttle, J. M.; Carey, S. K.; Laudon, H.; Mitchell, C. P. J.; McNamara, J. P.; Soulsby, C.
2014-12-01
The hydrology of high latitude catchments is sensitive to small changes in temperature, and likely to be impacted by changes in climate. Vegetation water usage can play a large role in catchment hydrologic pathways, affecting how water is stored, released, and partitioned within a landscape. Thus a better understanding of how vegetation impacts water partitioning in northern catchments can help us understand how climate change will impact high-latitude hydrology. As part of the VeWa project, five catchments were chosen between 44oN and 64oN in Europe and North America, to compare the role of vegetation in the movement of water across northern landscapes. These catchments vary in aspect as well as extent of snowpack and their vegetative landscapes include heather moorland, coniferous and deciduous forests, mixed grass, and tundra landscapes. Importantly, all the catchments have records of stable isotopes in different waters of the system. An initial comparison of the water isotopes in these catchments demonstrates variation between the catchments, with the lower latitude sites showing more fractionation suggestive of evapotranspiration. While all catchments show a depletion of heavy isotopes in the spring, the depletion is most evident in catchments with a heavier snowpack. The vegetative growing season during the summer months shows the greatest impact of evapotranspiration on isotopes, indicating that an increased summer in a warmer climate would likely alter water partitioning and storage dynamics in these regions.
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Partitioning GRACE ice loss for the Juneau Icefield using modeling, airborne and ground observations
NASA Astrophysics Data System (ADS)
Young, J. C.; Arendt, A. A.; Pettit, E. C.
2017-12-01
Glaciers of Alaska and Northwestern Canada are losing mass at one of the highest rates of any mountain glacier system globally. High-precision measurements from NASA's Gravity Recovery and Climate Experiment (GRACE) satellites have revealed changes in the local gravitational field along the Gulf of Alaska due to changes in these ice masses since 2003. In previous studies on Alaska glaciers, mass change estimates derived from GRACE compare well to time series' of Gulf of Alaska runoff from mass balance modeling. However, these studies did not adequately partition glacier and terrestrial snow pack mass change signals due to limited modeling capabilities and lack of sufficient ground observations. Our study focuses on the Juneau Icefield, one of the best-monitored areas in Alaska in terms of glacier mass balance, as a case study for partitioning GRACE glacier mass changes from terrestrial water storage changes both seasonally and in long-term trends. We leverage the modeling tool SnowModel to generate a time series of mass changes using assimilated field observations and airborne laser altimetry, and we compare to an iterated mass concentration GRACE solution from the NASA Goddard Space Flight Center Geodesy Laboratory ( 30-day intervals and 12,390 km2 resolution). The GRACE solution forward-models all mass signals other than those due to terrestrial water storage and the cryosphere, therefore requiring additional analysis to partition glacier mass balance and water storage signals. Our approach is one of the first to analyze GRACE at the sub-mountain range scale, and to examine terrestrial water storage trends at a smaller scale than the full Gulf of Alaska. Ultimately, this study points to refinements in the forward-modeling of terrestrial water storage in the GRACE processing chain, and provides best estimates for the timing and magnitude of subannual and long-term changes of the Juneau Icefield from 2003 to present.
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Balancing a U-Shaped Assembly Line by Applying Nested Partitions Method
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bhagwat, Nikhil V.
2005-01-01
In this study, we applied the Nested Partitions method to a U-line balancing problem and conducted experiments to evaluate the application. From the results, it is quite evident that the Nested Partitions method provided near optimal solutions (optimal in some cases). Besides, the execution time is quite short as compared to the Branch and Bound algorithm. However, for larger data sets, the algorithm took significantly longer times for execution. One of the reasons could be the way in which the random samples are generated. In the present study, a random sample is a solution in itself which requires assignment ofmore » tasks to various stations. The time taken to assign tasks to stations is directly proportional to the number of tasks. Thus, if the number of tasks increases, the time taken to generate random samples for the different regions also increases. The performance index for the Nested Partitions method in the present study was the number of stations in the random solutions (samples) generated. The total idle time for the samples can be used as another performance index. ULINO method is known to have used a combination of bounds to come up with good solutions. This approach of combining different performance indices can be used to evaluate the random samples and obtain even better solutions. Here, we used deterministic time values for the tasks. In industries where majority of tasks are performed manually, the stochastic version of the problem could be of vital importance. Experimenting with different objective functions (No. of stations was used in this study) could be of some significance to some industries where in the cost associated with creation of a new station is not the same. For such industries, the results obtained by using the present approach will not be of much value. Labor costs, task incompletion costs or a combination of those can be effectively used as alternate objective functions.« less
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Evapotranspiration partitioning in a semi-arid African savanna using stable isotopes of water vapor
NASA Astrophysics Data System (ADS)
Soderberg, K.; Good, S. P.; O'Connor, M.; King, E. G.; Caylor, K. K.
2012-04-01
Evapotranspiration (ET) represents a major flux of water out of semi-arid ecosystems. Thus, understanding ET dynamics is central to the study of African savanna health and productivity. At our study site in central Kenya (Mpala Research Centre), we have been using stable isotopes of water vapor to partition ET into its constituent parts of plant transpiration (T) and soil evaporation (E). This effort includes continuous measurement (1 Hz) of δ2H and δ18O in water vapor using a portable water vapor isotope analyzer mounted on a 22.5 m eddy covariance flux tower. The flux tower has been collecting data since early 2010. The isotopic end-member of δET is calculated using a Keeling Plot approach, whereas δT and δE are measured directly via a leaf chamber and tubing buried in the soil, respectively. Here we report on a two recent sets of measurements for partitioning ET in the Kenya Long-term Exclosure Experiment (KLEE) and a nearby grassland. We combine leaf level measurements of photosynthesis and water use with canopy-scale isotope measurements for ET partitioning. In the KLEE experiment we compare ET partitioning in a 4 ha plot that has only seen cattle grazing for the past 15 years with an adjacent plot that has undergone grazing by both cattle and wild herbivores (antelope, elephants, giraffe). These results are compared with a detailed study of ET in an artificially watered grassland.
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Partitioning Carbon Dioxide and Water Vapor Fluxes Using Correlation Analysis
USDA-ARS?s Scientific Manuscript database
Partitioning of eddy covariance flux measurements is routinely done to quantify the contributions of separate processes to the overall fluxes. Measurements of carbon dioxide fluxes represent the difference between gross ecosystem photosynthesis and total respiration, while measurements of water vapo...
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Wells, P.G.; Abernethy, S.; Mackay, D.
1982-01-01
The toxicity of seawater dispersions of a chemical dispersant to two marine crustaceans was investigated in the presence and absence of various quantities of a non-toxic mineral oil. From the results and a physical-chemical partitioning analysis, a limiting value of the oil-water partition coefficient of the toxic compounds is deduced suggesting that essentially all of the toxic compounds in the dispersant will partition into solution in water following dispersant application to an oil spill. This conclusion simplifies interpretation and prediction of the toxic effects of a dispersed oil spill. The combined bioassay-partitioning procedure may have applications to the study ofmore » the toxicity of other complex mixtures such as industrial effluents.« less
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Practical deviations from Henry`s law for water/air partitioning of volatile organic compounds
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schabron, J.F.; Rovani, J.F. Jr.
A study was conducted to define parameters relating to the use of a down hole submersible photoionization detector (PID) probe to measure volatile organic compounds (VOCs) in an artificial headspace. The partitioning of toluene and trichloroethylene between water and air was studied as a function of analyte concentration and water temperature. The Henry`s law constant governing this partitioning represents an ideal condition at infinite dilution for a particular temperature. The results show that in practice. this partitioning is far from ideal. Conditions resulting in apparent, practical deviations from Henry`s law include temperature and VOC concentration. Thus, a single value ofmore » Henry`s law constant for a particular VOC such as toluene can provide only an approximation of concentration in the field. Detector response in saturated humidity environments as a function of water temperature and analyte concentration was studied also.« less
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Zhang, Kun; Pereira, Alberto S; Martin, Jonathan W
2015-07-21
In this study, the octanol-water distribution ratios (DOW, that is, apparent KOW at pH 8.4) of 2114 organic species in oil sands process-affected water were estimated by partitioning to polydimethylsiloxane (PDMS) coated stir bars and analysis by ultrahigh resolution orbitrap mass spectrometry in electrospray positive ((+)) and negative ((-)) ionization modes. At equilibrium, the majority of species in OSPW showed negligible partitioning to PDMS (i.e., DOW <1), however estimated DOW's for some species ranged up to 100,000. Most organic acids detected in ESI- had negligible partitioning, although some naphthenic acids (O2(-) species) had estimated DOW ranging up to 100. Polar neutral and basic compounds detected in ESI+ generally partitioned to PDMS to a greater extent than organic acids. Among these species, DOW was greatest among 3 groups: up to 1000 for mono-oxygenated species (O(+) species), up to 127,000 for NO(+) species, and up to 203,000 for SO(+) species. A positive relationship was observed between DOW and carbon number, and a negative relationship was observed with the number of double bonds (or rings). The results highlight that nonacidic compounds in OSPW are generally more hydrophobic than naphthenic acids and that some may be highly bioaccumulative and contribute to toxicity.
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Water and sodium balance in space.
Drummer, C; Norsk, P; Heer, M
2001-09-01
We have previously shown that fluid balances and body fluid regulation in microgravity (microG) differ from those on Earth (Drummer et al, Eur J Physiol 441:R66-R72, 2000). Arriving in microG leads to a redistribution of body fluid-composed of a shift of fluid to the upper part of the body and an exaggerated extravasation very early in-flight. The mechanisms for the increased vascular permeability are not known. Evaporation, oral hydration, and urinary fluid excretion, the major components of water balance, are generally diminished during space flight compared with conditions on Earth. Nevertheless, cumulative water balance and total body water content are stable during flight if hydration, nutritional energy supply, and protection of muscle mass are at an acceptable level. Recent water balance data disclose that the phenomenon of an absolute water loss during space flight, which has often been reported in the past, is not a consequence of the variable microG. The handling of sodium, however, is considerably affected by microG. Sodium-retaining endocrine systems, such as renin-aldosterone and catecholamines, are much more activated during microG than on Earth. Despite a comparable oral sodium supply, urinary sodium excretion is diminished and a considerable amount of sodium is retained-without accumulating in the intravascular space. An enormous storage capacity for sodium in the extravascular space and a mechanism that allows the dissociation between water and sodium handling likely contribute to the fluid balance adaptation in weightlessness.
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Malisova, Olga; Bountziouka, Vassiliki; Panagiotakos, Demosthenes B; Zampelas, Antonis; Kapsokefalou, Maria
2012-03-01
There is a need to develop a questionnaire as a research tool for the evaluation of water balance in the general population. The water balance questionnaire (WBQ) was designed to evaluate water intake from fluid and solid foods and drinking water, and water loss from urine, faeces and sweat at sedentary conditions and physical activity. For validation purposes, the WBQ was administrated in 40 apparently healthy participants aged 22-57 years (37.5% males). Hydration indices in urine (24 h volume, osmolality, specific gravity, pH, colour) were measured through established procedures. Furthermore, the questionnaire was administered twice to 175 subjects to evaluate its reliability. Kendall's τ-b and the Bland and Altman method were used to assess the questionnaire's validity and reliability. The proposed WBQ to assess water balance in healthy individuals was found to be valid and reliable, and it could thus be a useful tool in future projects that aim to evaluate water balance.
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Rao, Xiao-Yong; Yin, Shan; Zhang, Guo-Song; Luo, Xiao-Jian; Jian, Hui; Feng, Yu-Lin; Yang, Shi-Lin
2014-05-01
To determine the equilibrium solubility of pulchinenosiden D in different solvents and its n-octanol/water partition coefficients. Combining shaking flask method and high performance liquid chromatography (HPLC) to detect the n-octanol/water partition coefficients of pulchinenosiden D, the equilibrium solubility of pulchinenosiden D in six organic solvents and different pH buffer solution were determined by HPLC analysis. n-Octanol/water partition coefficients of pulchinenosiden D in different pH were greater than zero, the equilibrium solubility of pulchinenosiden D was increased with increase the pH of the buffer solution. The maximum equilibrium solubility of pulchinenosiden D was 255.89 g x L(-1) in methanol, and minimum equilibrium solubility of pulchinenosiden D was 0.20 g x L(-1) in acetonitrile. Under gastrointestinal physiological conditions, pulchinenosiden D exists in molecular state and it has good absorption but poor water-solubility, so increasing the dissolution rate of pulchinenosiden D may enhance its bioavailability.
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Malisova, O; Bountziouka, V; Panagiotakos, D Β; Zampelas, A; Kapsokefalou, M
2013-07-01
Water balance is achieved when water intake from solid and fluid foods and drinking water meets water losses, mainly in sweat, urine and faeces. Seasonality, particularly in Mediterranean countries that have a hot summer, may affect water loss and consequently water balance. Water balance has not been estimated before on a population level and the effect of seasonality has not been evaluated. The present study aimed to compare water balance, intake and loss in summer and winter in a sample of the general population in Greece. The Water Balance Questionnaire (WBQ) was used to evaluate water balance, estimating water intake and loss in summer (n = 480) and in winter (n = 412) on a stratified sample of the general population in Athens, Greece. In winter, mean (SD) water balance was -63 (1478) mL/day(-1) , mean (SD)water intake was 2892 (987) mL/day(-1) and mean (quartile range) water loss was 2637 (1810-3922) mL/day(-1) . In summer, mean (SD) water balance was -58 (2150) mL/day(-1) , mean (SD) water intake was 3875 (1373) mL/day(-1) and mean (quartile range) water loss was 3635 (2365-5258) mL/day(-1) . Water balance did not differ between summer and winter (P = 0.96); however, the data distribution was different; in summer, approximately 8% more participants were falling in the low and high water balance categories. Differences in water intake from different sources were identified (P < 0.05). Water balance in summer and winter was not different. However, water intake and loss were approximately 40% higher in summer than in winter. More people were falling in the low and high water balance categories in summer when comparing the distribution on water balance in winter. © 2013 The Authors Journal of Human Nutrition and Dietetics © 2013 The British Dietetic Association Ltd.
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Cumulative soil water evaporation as a function of depth and time
USDA-ARS?s Scientific Manuscript database
Soil water evaporation is an important component of the surface water balance and the surface energy balance. Accurate and dynamic measurements of soil water evaporation enhance the understanding of water and energy partitioning at the land-atmosphere interface. The objective of this study is to mea...
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USDA-ARS?s Scientific Manuscript database
The thermal-based Two Source Energy Balance (TSEB) model partitions the water and energy fluxes from vegetation and soil components providing thus the ability for estimating soil evaporation (E) and canopy transpiration (T) separately. However, it is crucial for ET partitioning to retrieve reliable ...
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USDA-ARS?s Scientific Manuscript database
Accurate partitioning of the evaporation (E) and transpiration (T) components of evapotranspiration (ET) in remote sensing models is important for evaluating strategies aimed at increasing crop water productivity. The two-source energy balance (TSEB) model solves the energy balance of the soil-plant...
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Joachim, Bastian; Stechern, André; Ludwig, Thomas; Konzett, Jürgen; Pawley, Alison; Ruzié-Hamilton, Lorraine; Clay, Patricia L; Burgess, Ray; Ballentine, Christopher J
2017-01-01
Halogens show a range from moderate (F) to highly (Cl, Br, I) volatile and incompatible behavior, which makes them excellent tracers for volatile transport processes in the Earth's mantle. Experimentally determined fluorine and chlorine partitioning data between mantle minerals and silicate melt enable us to estimate Mid Ocean Ridge Basalt (MORB) and Ocean Island Basalt (OIB) source region concentrations for these elements. This study investigates the effect of varying small amounts of water on the fluorine and chlorine partitioning behavior at 1280 °C and 0.3 GPa between olivine and silicate melt in the Fe-free CMAS+F-Cl-Br-I-H 2 O model system. Results show that, within the uncertainty of the analyses, water has no effect on the chlorine partitioning behavior for bulk water contents ranging from 0.03 (2) wt% H 2 O (D Cl ol/melt = 1.6 ± 0.9 × 10 -4 ) to 0.33 (6) wt% H 2 O (D Cl ol/melt = 2.2 ± 1.1 × 10 -4 ). Consequently, with the effect of pressure being negligible in the uppermost mantle (Joachim et al. Chem Geol 416:65-78, 2015), temperature is the only parameter that needs to be considered for the determination of chlorine partition coefficients between olivine and melt at least in the simplified iron-free CMAS+F-Cl-Br-I-H 2 O system. In contrast, the fluorine partition coefficient increases linearly in this range and may be described at 1280 °C and 0.3 GPa with ( R 2 = 0.99): [Formula: see text]. The observed fluorine partitioning behavior supports the theory suggested by Crépisson et al. (Earth Planet Sci Lett 390:287-295, 2014) that fluorine and water are incorporated as clumped OH/F defects in the olivine structure. Results of this study further suggest that fluorine concentration estimates in OIB source regions are at least 10% lower than previously expected (Joachim et al. Chem Geol 416:65-78, 2015), implying that consideration of the effect of water on the fluorine partitioning behavior between Earth's mantle minerals and
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Ali, Usman; Sweetman, Andrew James; Jones, Kevin C; Malik, Riffat Naseem
2018-06-18
This study was designed to monitor organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in riverine water of Lesser Himalaya along the altitude. Further, the sediment-water partitioning employing organic carbon and black carbon models were assessed. Results revealed higher water levels of organochlorine pesticides (0.07-41.4 ng L -1 ) and polychlorinated biphenyls (0.671-84.5 ng L -1 ) in Lesser Himalayan Region (LHR) of Pakistan. Spatially, elevated levels were observed in the altitudinal zone (737-975 masl) which is influenced by anthropogenic and industrial activities. Sediment-water partitioning of OCPs and PCBs were deduced using field data by employing one-carbon (f OC K OC ) and two-carbon Freundlich models (f OC K OC + f BC K BC C W nF-1 ). Results suggested improved measured vs predicted model concentrations when black carbon was induced in the model and suggested adsorption to be the dominant mechanism in phase partitioning of organochlorines in LHR.
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NASA Astrophysics Data System (ADS)
de Blécourt, Marleen; Gaj, Marcel; Holtorf, Kim-Kirsten; Gröngröft, Alexander; Brokate, Ralph; Himmelsbach, Thomas; Eschenbach, Annette
2016-04-01
In dry environments with a sparse vegetation cover, understory evapotranspiration is a major component of the ecosystem water balance. Consequently, knowledge on the size of evapotranspiration fluxes and the driving factors is important for our understanding of the hydrological cycle. Understory evapotranspiration is made up of soil evaporation and plant transpiration. Soil evaporation can be measured directly from patches free of vegetation. However, when understory vegetation is present distinguishing between soil evaporation and plant transpiration is challenging. In this study, we aim to partition understory evapotranspiration based on an approach that combines the measurements of water-vapour fluxes using the closed chamber method with measurements of the isotopic composition of water vapour. The measurements were done in the framework of SASSCAL (Southern African Science Service Centre for Climate Change and Adaptive Land Management). The study sites were located in three different semi-arid ecosystems in Namibia: thornbush savanna, Baikiaea woodland and shrubland. At each site measurements were done under tree canopies as well as at unshaded areas between the canopies. We measured evaporation from the bare soil and evapotranspiration from patches covered with herbaceous species and shrubs using a transparent chamber connected with an infrared gas analyser (LI-8100A, LICOR Inc.). The stable isotope composition of water vapour inside the chamber and depth profiles of soil water stable isotopes were determined in-situ using a tuneable off-axis integrated cavity output spectroscope (OA-ICOS, Los Gatos Research, DLT 100). Xylem samples were extracted using the cryogenic vacuum extraction method and the isotopic composition of the extracted water was measured subsequently with a cavity-ring-down spectrometer (CRDS L2120-i, Picarro Inc.). We will present the quantified fluxes of understory evapotranspiration measured in the three different ecosystems, show the
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Partitioning of water flux in a Sierra Nevada ponderosa pine plantation
Kurpius, M.R.; Panek, J.A.; Nikolov, N.T.; McKay, M.; Goldstein, Allen H.
2003-01-01
The weather patterns of the west side of the Sierra Nevada Mountains (cold, wet winters and hot, dry summers) strongly influence how water is partitioned between transpiration and evaporation and result in a specific strategy of water use by ponderosa pine trees (Pinus ponderosa) in this region. To investigate how year-round water fluxes were partitioned in a young ponderosa pine ecosystem in the Sierra Nevada Mountains, water fluxes were continually measured from June 2000 to May 2001 using a combination of sap flow and eddy covariance techniques (above- and below-canopy). Water fluxes were modeled at our study site using a biophysical model, FORFLUX. During summer and fall water fluxes were equally partitioned between transpiration and soil evaporation while transpiration dominated the water fluxes in winter and spring. The trees had high rates of canopy conductance and transpiration in the early morning and mid-late afternoon and a mid-day depression during the dry season. We used a diurnal centroid analysis to show that the timing of high canopy conductance and transpiration relative to high vapor pressure deficit (D) shifted with soil moisture: during periods of low soil moisture canopy conductance and transpiration peaked early in the day when D was low. Conversely, during periods of high soil moisture canopy conductance and transpiration peaked at the same time or later in the day than D. Our observations suggest a general strategy by the pine trees in which they maximize stomatal conductance, and therefore carbon fixation, throughout the day on warm sunny days with high soil moisture (i.e. warm periods in winter and late spring) and maximize stomatal conductance and carbon fixation in the morning through the dry periods. FORFLUX model estimates of evaporation and transpiration were close to measured/calculated values during the dry period, including the drought, but underestimated transpiration and overestimated evaporation during the wet period. ?? 2003
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Bhatnagar, Navendu; Kamath, Ganesh; Chelst, Issac; Potoff, Jeffrey J
2012-07-07
The 1-octanol-water partition coefficient log K(ow) of a solute is a key parameter used in the prediction of a wide variety of complex phenomena such as drug availability and bioaccumulation potential of trace contaminants. In this work, adaptive biasing force molecular dynamics simulations are used to determine absolute free energies of hydration, solvation, and 1-octanol-water partition coefficients for n-alkanes from methane to octane. Two approaches are evaluated; the direct transfer of the solute from 1-octanol to water phase, and separate transfers of the solute from the water or 1-octanol phase to vacuum, with both methods yielding statistically indistinguishable results. Calculations performed with the TIP4P and SPC∕E water models and the TraPPE united-atom force field for n-alkanes show that the choice of water model has a negligible effect on predicted free energies of transfer and partition coefficients for n-alkanes. A comparison of calculations using wet and dry octanol phases shows that the predictions for log K(ow) using wet octanol are 0.2-0.4 log units lower than for dry octanol, although this is within the statistical uncertainty of the calculation.
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Jang, Jiyi; Kim, Hyunji; Han, Seunghee
2014-02-01
It is known that particle scavenging of mercury (Hg) can be affected by the abundance of particulate organic matter in coastal waters. However, the role of living organic particles in Hg scavenging is not yet completely understood. In this study, we hypothesized that an abundance of living organic particles (i.e., phytoplankton and bacteria) would influence the particle-water partitioning of Hg in coastal waters. Surface seawater samples were collected from eight stations in Gwangyang Bay, Korea, in three seasons (November 2009, April 2010, and October 2010) for the determination of concentrations of suspended particulate matter (including chlorophyll-a and bacteria), and Hg in unfiltered and filtered waters. We found that more Hg partitioned toward particulate matter when phytoplankton biomass, indicated from the chlorophyll-a concentration in a particle, was higher. In the low algal season, when [chlorophyll-a]<0.6 μg L(-1), the bacterial number, instead of chlorophyll-a concentration in particle, showed a positive correlation with the particle-water partition coefficient of Hg. Overall, microbial abundance seems to play a critical role in particle scavenging of Hg in coastal water. Taking this result in light of Hg in pristine coastal zones, we predict that increases in algal biomass amplify the potential for algae to transfer Hg to marine food chains. © 2013.
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Lin, Jianfeng; Dang, Haijun; Xie, Jinchuan; Zhou, Guoqing; Li, Mei; Zhang, Jihong
2015-09-01
Traditional sorption experiments commonly treat the colloidal species of low-solubility contaminants as immobile species when separated by centrifugation or ultrafiltration. This study shows that, from a viewpoint of a three-phase system, the mobile Pu species, especially the colloidal species, play an important role in Pu partitioning in water-granite and water-α-FeOOH systems. A new distribution coefficient term Ks/(d+c) was defined to take the mobile colloidal species into consideration, and it differs to the traditional distribution coefficient Ks/d by orders of magnitude in the water-granite and water-α-FeOOH systems. This term, Ks/(d+c), can quantitatively describe Pu partitioning in the suspension, in particular the fraction of mobile species that dominate Pu migration in the environment. The effects of ionic strength (I) and pH on the Pu partitioning in water-granite and water-α-FeOOH systems are well interpreted with respect to the zeta potential change of granite grains, α-FeOOH colloid particles and polymeric Pu. It is concluded that the presence of the α-FeOOH colloid with a low concentration (<10 mg L(-1)) is favorable for the stability of colloidal Pu and leads to large proportion of mobile Pu, especially colloid-associated Pu, which will migrate much faster than dissolved Pu in groundwater.
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Hoggan, James L; Bae, Keonbeom; Kibbey, Tohren C G
2007-08-15
Trapped organic solvents, in both the vadose zone and below the water table, are frequent sources of environmental contamination. A common source of organic solvent contamination is spills, leaks, and improper solvent disposal associated with dry cleaning processes. Dry cleaning solvents, such as tetrachloroethylene (PCE), are typically enhanced with the addition of surfactants to improve cleaning performance. The objective of this work was to examine the partitioning behavior of surfactants from PCE in contact with water. The relative rates of surfactants partitioning and PCE dissolution are important for modeling the behavior of waste PCE in the subsurface, in that they influence the interfacial tension of the PCE, and how (or if) interfacial tension changes over time in the subsurface. The work described here uses a flow-through system to examine simultaneous partitioning and PCE dissolution in a porous medium. Results indicate that both nonylphenol ethoxylate nonionic surfactants and a sulfosuccinate anionic surfactant partition out of residual PCE much more rapidly than the PCE dissolves, suggesting that in many cases interfacial tension changes caused by partitioning may influence infiltration and distribution of PCE in the subsurface. Non-steady-state partitioning is found to be well-described by a linear driving force model incorporating measured surfactant partition coefficients.
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Verplanck, P.L.; Nordstrom, D. Kirk; Taylor, Howard E.; Kimball, B.A.
2004-01-01
Ferrous iron rapidly oxidizes to Fe (III) and precipitates as hydrous Fe (III) oxides in acid mine waters. This study examines the effect of Fe precipitation on the rare earth element (REE) geochemistry of acid mine waters to determine the pH range over which REEs behave conservatively and the range over which attenuation and fractionation occur. Two field studies were designed to investigate REE attenuation during Fe oxidation in acidic, alpine surface waters. To complement these field studies, a suite of six acid mine waters with a pH range from 1.6 to 6.1 were collected and allowed to oxidize in the laboratory at ambient conditions to determine the partitioning of REEs during Fe oxidation and precipitation. Results from field experiments document that even with substantial Fe oxidation, the REEs remain dissolved in acid, sulfate waters with pH below 5.1. Between pH 5.1 and 6.6 the REEs partitioned to the solid phases in the water column, and heavy REEs were preferentially removed compared to light REEs. Laboratory experiments corroborated field data with the most solid-phase partitioning occurring in the waters with the highest pH. ?? 2004 Elsevier Ltd. All rights reserved.
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Catchment Water-Energy Balance Model: Development and Applications
NASA Astrophysics Data System (ADS)
Yang, D.; Yang, H.
2017-12-01
International Hydrological community has widely recognized that the catchment water-energy balance exists, which can be expressed as a general form of E/P = f(E0/P, c), where P is precipitation, E0 is potential evaporation, and c is a parameter. Many empirical/rational formulations of the catchment water-energy balance have been proposed. Several analytical solutions of the water-energy balance equation E/P = f(E0/P, c) have been derived by using dimensional analysis and mathematic reasoning and introducing additional boundary conditions. This paper will summarize the catchment water-energy balance equations and discuss their advantages and limitations. Catchment hydrology has been greatly influenced by the intensive variability in land use/cover, precipitation and air temperature due to climate change and local human activities. The water-energy balance equation, which are usually called the Budyko framework is widely used to analyze the impacts of climate and landscape changes on regional hydrology especially the annual runoff change. In order to quantify impacts of climate change and landscape change on the catchment runoff, the climate elasticity and landscape elasticity are estimated theoretically from the catchment water-energy balance equation. The elasticity of runoff has less of a dependency on the aridity index when the climate is drier (larger aridity index). The precipitation elasticity of runoff was close to 1.0 and that of potential evaporation close to 0.0 in the extreme humid climate with no relation to the landscape conditions, which implies that catchment water balance under extremely wet condition is controlled mainly by the climate condition. We establishes a relationship between the change in the landscape parameter in the catchment water-energy balance equation and vegetation change represented by fPAR, the fraction of Photosynthetically Active Radiation absorbed by vegetation. The fPAR elasticity of runoff is introduced and estimated over
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Gas-particle partitioning of alcohol vapors on organic aerosols.
Chan, Lap P; Lee, Alex K Y; Chan, Chak K
2010-01-01
Single particle levitation using an electrodynamic balance (EDB) has been found to give accurate and direct hygroscopic measurements (gas-particle partitioning of water) for a number of inorganic and organic aerosol systems. In this paper, we extend the use of an EDB to examine the gas-particle partitioning of volatile to semivolatile alcohols, including methanol, n-butanol, n-octanol, and n-decanol, on levitated oleic acid particles. The measured K(p) agreed with Pankow's absorptive partitioning model. At high n-butanol vapor concentrations (10(3) ppm), the uptake of n-butanol reduced the average molecular-weight of the oleic acid particle appreciably and hence increased the K(p) according to Pankow's equation. Moreover, the hygroscopicity of mixed oleic acid/n-butanol particles was higher than the predictions given by the UNIFAC model (molecular group contribution method) and the ZSR equation (additive rule), presumably due to molecular interactions between the chemical species in the mixed particles. Despite the high vapor concentrations used, these findings warrant further research on the partitioning of atmospheric organic vapors (K(p)) near sources and how collectively they affect the hygroscopic properties of organic aerosols.
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Improving Unstructured Mesh Partitions for Multiple Criteria Using Mesh Adjacencies
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smith, Cameron W.; Rasquin, Michel; Ibanez, Dan
The scalability of unstructured mesh based applications depends on partitioning methods that quickly balance the computational work while reducing communication costs. Zhou et al. [SIAM J. Sci. Comput., 32 (2010), pp. 3201{3227; J. Supercomput., 59 (2012), pp. 1218{1228] demonstrated the combination of (hyper)graph methods with vertex and element partition improvement for PHASTA CFD scaling to hundreds of thousands of processes. Our work generalizes partition improvement to support balancing combinations of all the mesh entity dimensions (vertices, edges, faces, regions) in partitions with imbalances exceeding 70%. Improvement results are then presented for multiple entity dimensions on up to one million processesmore » on meshes with over 12 billion tetrahedral elements.« less
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Improving Unstructured Mesh Partitions for Multiple Criteria Using Mesh Adjacencies
Smith, Cameron W.; Rasquin, Michel; Ibanez, Dan; ...
2018-02-13
The scalability of unstructured mesh based applications depends on partitioning methods that quickly balance the computational work while reducing communication costs. Zhou et al. [SIAM J. Sci. Comput., 32 (2010), pp. 3201{3227; J. Supercomput., 59 (2012), pp. 1218{1228] demonstrated the combination of (hyper)graph methods with vertex and element partition improvement for PHASTA CFD scaling to hundreds of thousands of processes. Our work generalizes partition improvement to support balancing combinations of all the mesh entity dimensions (vertices, edges, faces, regions) in partitions with imbalances exceeding 70%. Improvement results are then presented for multiple entity dimensions on up to one million processesmore » on meshes with over 12 billion tetrahedral elements.« less
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Sparkle L. Malone; Christina L. Staudhammer; Henry W. Loescher; Paulo Olivas; Steven F. Oberbauer; Michael G. Ryan; Jessica Schedlbauer; Gregory Starr
2014-01-01
We analyzed energy partitioning in short- and long-hydroperiod freshwater marsh ecosystems in the Florida Everglades by examining energy balance components (eddy covariance derived latent energy (LE) and sensible heat (H) flux). The study period included several wet and dry seasons and variable water levels, allowing us to gain better mechanistic information about the...
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A one-dimensional water balance model was developed and used to simulate water balance for the Columbia River Basin. he model was run over a 10 km X 10 km grid for the United State's portion of the basin. he regional water balance was calculated using a monthly time-step for a re...
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Wang, Pei; Li, Xiao-Yan; Wang, Lixin; Wu, Xiuchen; Hu, Xia; Fan, Ying; Tong, Yaqin
2018-06-04
Previous evapotranspiration (ET) partitioning studies have usually neglected competitions and interactions between antagonistic plant functional types. This study investigated whether shrubs and grasses have divergent ET partition dynamics impacted by different water-use patterns, canopy structures, and physiological properties in a shrub-encroached steppe ecosystem in Inner Mongolia, China. The soil water-use patterns of shrubs and grasses have been quantified by an isotopic tracing approach and coupled into an improved multisource energy balance model to partition ET fluxes into soil evaporation, grass transpiration, and shrub transpiration. The mean fractional contributions to total ET were 24 ± 13%, 20 ± 4%, and 56 ± 16% for shrub transpiration, grass transpiration, and soil evaporation respectively during the growing season. Difference in ecohydrological connectivity and leaf development both contributed to divergent transpiration partitioning between shrubs and grasses. Shrub-encroachment processes result in larger changes in the ET components than in total ET flux, which could be well explained by changes in canopy resistance, an ecosystem function dominated by the interaction of soil water-use patterns and ecosystem structure. The analyses presented here highlight the crucial effects of vegetation structural changes on the processes of land-atmosphere interaction and climate feedback. © 2018 The Authors. New Phytologist © 2018 New Phytologist Trust.
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Landscape-Scale water balance of cotton fields
USDA-ARS?s Scientific Manuscript database
Information on the temporal and spatial distribution of the components of the water balance of a production field is necessary to manage agronomic inputs. Furthermore, factors that determine crop yield require knowledge of the energy, water, nutrient and carbon balance and their interaction. The in...
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Quantifying catchment water balances and their uncertainties by expert elicitation
NASA Astrophysics Data System (ADS)
Sebok, Eva; Refsgaard, Jens Christian; Warmink, Jord J.; Stisen, Simon; Høgh Jensen, Karsten
2017-04-01
The increasing demand on water resources necessitates a more responsible and sustainable water management requiring a thorough understanding of hydrological processes both on small scale and on catchment scale. On catchment scale, the characterization of hydrological processes is often carried out by calculating a water balance based on the principle of mass conservation in hydrological fluxes. Assuming a perfect water balance closure and estimating one of these fluxes as a residual of the water balance is a common practice although this estimate will contain uncertainties related to uncertainties in the other components. Water balance closure on the catchment scale is also an issue in Denmark, thus, it was one of the research objectives of the HOBE hydrological observatory, that has been collecting data in the Skjern river catchment since 2008. Water balance components in the 1050 km2 Ahlergaarde catchment and the nested 120 km2 Holtum catchment, located in the glacial outwash plan of the Skjern catchment, were estimated using a multitude of methods. As the collected data enables the complex assessment of uncertainty of both the individual water balance components and catchment-scale water balances, the expert elicitation approach was chosen to integrate the results of the hydrological observatory. This approach relies on the subjective opinion of experts whose available knowledge and experience about the subject allows to integrate complex information from multiple sources. In this study 35 experts were involved in a multi-step elicitation process with the aim of (1) eliciting average annual values of water balance components for two nested catchments and quantifying the contribution of different sources of uncertainties to the total uncertainty in these average annual estimates; (2) calculating water balances for two catchments by reaching consensus among experts interacting in form of group discussions. To address the complex problem of water balance closure
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USDA-ARS?s Scientific Manuscript database
Accurate partitioning of the evaporation (E) and transpiration (T) components of evapotranspiration (ET) in remote sensing models is important for evaluating strategies aimed at increasing crop water productivity. The two-source energy balance (TSEB) model solves the energy balance of the soil-plant...
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Tamaru, Shunji; Igura, Noriyuki; Shimoda, Mitsuya
2018-01-15
Flavor release from food matrices depends on the partition of volatile flavor compounds between the food matrix and the vapor phase. Thus, we herein investigated the relationship between released flavor concentrations and three different partition coefficients, namely octanol-water, octanol-air, and water-air, which represented the oil, water, and air phases present in emulsions. Limonene, 2-methylpyrazine, nonanal, benzaldehyde, ethyl benzoate, α-terpineol, benzyl alcohol, and octanoic acid were employed. The released concentrations of these flavor compounds from oil-in-water (O/W) emulsions were measured under equilibrium using static headspace gas chromatography. The results indicated that water-air and octanol-air partition coefficients correlated with the logarithms of the released concentrations in the headspace for highly lipophilic flavor compounds. Moreover, the same tendency was observed over various oil volume ratios in the emulsions. Our findings therefore suggest that octanol-air and water-air partition coefficients can be used to predict the released concentration of lipophilic flavor compounds from O/W emulsions. Copyright © 2017 Elsevier Ltd. All rights reserved.
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Water-Sediment Partition of Polycyclic Aromatic Hydrocarbons (PAHs) in Nansi Lake
NASA Astrophysics Data System (ADS)
Zhang, Guizhai; Diao, Youjiang
2018-06-01
Based on field data of polycyclic aromatic hydrocarbons (PAHs) in water and sediment in Nansi Lake. The concentrations and the partitioning characteristic of PAHs in the water and sediment were studied. The lgKd of high molecular weight PAHs were higher than the low molecular weight PAHs. The most of PAHs Kd values were negligible correlated with TOC, soluble salt, clay and pH of the sediment in Nansi Lake.
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PARTITIONING OF WATER FLUX IN A SIERRA NEVADA PONDEROSA PINE PLANTATION. (R826601)
The weather patterns of the west side of the Sierra Nevada Mountains (cold, wet winters and hot, dry summers) strongly influence how water is partitioned between transpiration and evaporation and result in a specific strategy of water use by ponderosa pine trees (Pinus pond...
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From Budyko to biodiversity: Macroecological insights from evapotranspiration partitioning
NASA Astrophysics Data System (ADS)
Collins, Daniel
2010-05-01
Transpiration is the cog that connects the water cycle to the carbon cycle. Yet in the majority of hydrological studies, transpiration is lumped together with evaporation, as if it did not matter exactly how the water moved from the land surface to atmosphere. However, as techniques are developed to partition the two, it is increasingly possible and useful to examine how transpiration varies among catchments, and to explore what hydrological and ecological theory may provide one another as a result. The framework for this study begins with the Budyko curve - the curve, or more accurately the cloud of data, that traces how precipitation (P) is partitioned into runoff and evapotranspiration (ET) along an aridity gradient. The first question becomes: How does a catchment's transpiration fraction (T/P) vary with aridity? Four lines of analysis are used to answer this question. They include basic logic, a numerical ecohydrological toy model, a global land surface model, and the limited observational data that exist. Together, these lines of analysis strongly suggest that the transpiration fraction (T/P) of a catchment's water balance is a maximum at intermediate values of aridity, dropping off to zero as aridity either increases or decreases from that point. The evaporation fraction (E/T), conversely, increases monotonically with aridity. The precise location of the T/P peak is as yet unclear, but does not appear to be far from the boundary between water- and energy-limited conditions. The peak in transpiration fraction reflects an ecosystem's resource limits in terms of both water and energy supply. As energy increases beyond the water available, as in water-limited ecosystems, transpiration will increasingly lose out to evaporation. Conversely as water increases beyond the energy available, the transpiration will increasingly lose out to runoff and groundwater recharge in energy-limited ecosystems. Because of the centrality of transpiration to both hydrology and
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Partitioning Algorithms for Simultaneously Balancing Iterative and Direct Methods
2004-03-03
is defined as 57698&:&;=<$>?8A@B8 DC E & /F <G8H IJ0 K L 012 1NM? which is the ratio of the highest partition weight over the average...OQPSR , 57698T:;=<$>U8T@B8 DC E & /VXWZYK[\\O , and E :^] E_CU`4ab /V is minimized. The load imbalance is the constraint we have to satisfy, and...that the initial partitioning can be improved [16, 19, 20]. 3 Problem Definition and Challenges Consider a graph )c2 with d e f vertices
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NASA Astrophysics Data System (ADS)
Irmak, A.
2009-12-01
Surface energy fluxes, including net radiation (Rn), sensible heat (H), latent heat (LE), and soil heat flux (G) are critical in surface energy balance of any terrain or landscapes. Estimation or measurement of these energy fluxes is important for completing the water balance in terrestrial ecosystems, and therefore accurately predicting the effects of global climate and land use change. The objectives of this study were to (1) use METRICtm (Mapping Evapotranspiration at high Resolution using Internalized Calibration) model for estimating land surface energy fluxes in Nebraska (NE) by utilizing satellite remote sensing data, (2) identify model bias in energy balance components compared with measurements from Bowen Ratio Energy Balance System (BREBS) in a subsurface drip-irrigated maize field in South-central Nebraska, and (3) understand the partitioning of available energy into latent heat for corn and soybean cropping systems at large scale. A total of 15 Landsat images were processed to estimate instantaneous surface energy fluxes at Landsat overpasses with METRIC model. Results showed that the model predictions of the surface energy fluxes and daily evapotranspiration were correlated well with the BREBS measurements. There is a need, however, to test the performance of the model with in-situ observations in other locations with different dataset before utilizing it for crucial water regulatory and policy decisions. The METRICtm approach illustrated how an ‘off-the-shelf’ model can be applied operationally over a significant time period and how that model behaves. The findings makes considerable contribution to our understanding of estimating land surface energy fluxes using remote sensing approach and experimentally describes the operational characteristics of METRICtm and presents its limitations.
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A Stochastic Water Balance Framework for Lowland Watersheds
NASA Astrophysics Data System (ADS)
Thompson, Sally; MacVean, Lissa; Sivapalan, Murugesu
2017-11-01
The water balance dynamics in lowland watersheds are influenced not only by local hydroclimatic controls on energy and water availability, but also by imports of water from the upstream watershed. These imports result in a stochastic extent of inundation in lowland watersheds that is determined by the local flood regime, watershed topography, and the rate of loss processes such as drainage and evaporation. Thus, lowland watershed water balances depend on two stochastic processes—rainfall and local inundation dynamics. Lowlands are high productivity environments that are disproportionately associated with urbanization, high productivity agriculture, biodiversity, and flood risk. Consequently, they are being rapidly altered by human development—generally with clear economic and social motivation—but also with significant trade-offs in ecosystem services provision, directly related to changes in the components and variability of the lowland water balance. We present a stochastic framework to assess the lowland water balance and its sensitivity to two common human interventions—replacement of native vegetation with alternative land uses, and construction of local flood protection levees. By providing analytical solutions for the mean and PDF of the water balance components, the proposed framework provides a mechanism to connect human interventions to hydrologic outcomes, and, in conjunction with ecosystem service production estimates, to evaluate trade-offs associated with lowland watershed development.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Platts, J.A.; Abraham, M.H.
The partitioning of organic compounds between air and foliage and between water and foliage is of considerable environmental interest. The purpose of this work is to show that partitioning into the cuticular matrix of one particular species can be satisfactorily modeled by general equations the authors have previously developed and, hence, that the same general equations could be used to model partitioning into other plant materials of the same or different species. The general equations are linear free energy relationships that employ descriptors for polarity/polarizability, hydrogen bond acidity and basicity, dispersive effects, and volume. They have been applied to themore » partition of 62 very varied organic compounds between cuticular matrix of the tomato fruit, Lycopersicon esculentum, and either air (MX{sub a}) or water (MX{sub w}). Values of log MX{sub a} covering a range of 12.4 log units are correlated with a standard deviation of 0.232 log unit, and values of log MX{sub w} covering a range of 7.6 log unit are correlated with an SD of 0.236 log unit. Possibilities are discussed for the prediction of new air-plant cuticular matrix and water-plant cuticular matrix partition values on the basis of the equations developed.« less
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Thermodynamics of phenanthrene partition into solid organic matter from water.
Chen, Bao-liang; Zhu, Li-zhong; Tao, Shu
2005-01-01
The thermodynamic behavior of organic contaminants in soils is essential to develop remediation technologies and assess risk from alternative technologies. Thermodynamics of phenanthrene partition into four solids(three soils and a bentonite) from water were investigated. The thermodynamics parameters (deltaH, deltaG degrees, deltaS degrees) were calculated according to experimental data. The total sorption heats of phenanthrene to solids from water ranged from -7.93 to -17.1 kJ/mol, which were less exothermic than the condensation heat of phenanthrene-solid (i.e., -18.6 kJ/mol). The partition heats of phenanthrene dissolved into solid organic matter ranged from 23.1 to 32.2 kJ/mol, which were less endothermic than the aqueous dissolved heat of phenanthrene (i.e., 40.2 kJ/mol), and were more endothermic than the fusion heat of phenanthrene-solid (i.e., 18.6 kJ/mol). The standard free energy changes, deltaG degrees, are all negative which suggested that phenanthrene sorption into solid was a spontaneous process. The positive values of standard entropy changes, deltaS degrees, show a gain in entropy for the transfer of phenanthrene at the stated standard state. Due to solubility-enhancement of phenanthrene, the partition coefficients normalized by organic carbon contents decrease with increasing system temperature (i.e., ln Koc = -0.284 ln S + 9.82 (n = 4, r2 = 0.992)). The solubility of phenanthrene in solid organic matter increased with increasing temperatures. Transports of phenanthrene in different latitude locations and seasons would be predicted according to its sorption thermodynamics behavior.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Johnson, Timothy C.; Oostrom, Martinus; Truex, Michael J.
2013-05-21
Water saturation is an important indicator of contaminant distribution and plays a governing role in contaminant transport within the vadose zone. Understanding the water saturation distribution is critical for both remediation and contaminant flux monitoring in unsaturated environments. In this work we propose and demonstrate a method of remotely determining water saturation levels using gas phase partitioning tracers and time-lapse bulk electrical conductivity measurements. The theoretical development includes the partitioning chemistry for the tracers we demonstrate (ammonia and carbon dioxide), as well as a review of the petrophysical relationship governing how these tracers influence bulk conductivity. We also investigate methodsmore » of utilizing secondary information provided by electrical conductivity breakthrough magnitudes induced by the tracers. We test the method on clean, well characterized, intermediate-scale sand columns under controlled conditions. Results demonstrate the capability to predict partitioning coefficients and accurately monitor gas breakthrough curves along the length of the column according to the corresponding electrical conductivity response, leading to accurate water saturation estimates. This work is motivated by the need to develop effective characterization and monitoring techniques for contaminated deep vadose zone environments, and provides a proof-of-concept toward uniquely characterizing and monitoring water saturation levels at the field scale and in three-dimensions using electrical resistivity tomography.« less
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Gilbert, Dorothea; Witt, Gesine; Smedes, Foppe; Mayer, Philipp
2016-06-07
Polymers are increasingly applied for the enrichment of hydrophobic organic chemicals (HOCs) from various types of samples and media in many analytical partitioning-based measuring techniques. We propose using polymers as a reference partitioning phase and introduce polymer-polymer partitioning as the basis for a deeper insight into partitioning differences of HOCs between polymers, calibrating analytical methods, and consistency checking of existing and calculation of new partition coefficients. Polymer-polymer partition coefficients were determined for polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and organochlorine pesticides (OCPs) by equilibrating 13 silicones, including polydimethylsiloxane (PDMS) and low-density polyethylene (LDPE) in methanol-water solutions. Methanol as cosolvent ensured that all polymers reached equilibrium while its effect on the polymers' properties did not significantly affect silicone-silicone partition coefficients. However, we noticed minor cosolvent effects on determined polymer-polymer partition coefficients. Polymer-polymer partition coefficients near unity confirmed identical absorption capacities of several PDMS materials, whereas larger deviations from unity were indicated within the group of silicones and between silicones and LDPE. Uncertainty in polymer volume due to imprecise coating thickness or the presence of fillers was identified as the source of error for partition coefficients. New polymer-based (LDPE-lipid, PDMS-air) and multimedia partition coefficients (lipid-water, air-water) were calculated by applying the new concept of a polymer as reference partitioning phase and by using polymer-polymer partition coefficients as conversion factors. The present study encourages the use of polymer-polymer partition coefficients, recognizing that polymers can serve as a linking third phase for a quantitative understanding of equilibrium partitioning of HOCs between any two phases.
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Sediment-water partitioning of inorganic mercury in estuaries.
Turner, A; Millward, G E; Le Roux, S M
2001-12-01
The sediment-water partitioning and speciation of inorganic mercury have been studied under simulated estuarine conditions by monitoring the hydrophobicity and uptake of dissolved 203Hg(II) in samples from a variety of estuarine environments. A persistent increase in the distribution coefficientwith increasing salinity is inconsistent with inorganic speciation calculations, which predict an increase in the concentration of the soluble HgCl4(2-) complex (or reduction in sediment-water distribution coefficient) with increasing salinity. Partition data are, however, defined by an empirical equation relating to the salting out of nonelectrolytes via electrostriction and are characterized by salting constants between about 1.4 and 2.0 L mol(-1). Salting out of the neutral, covalent chloro-complex, HgCl2(0), is predicted but cannot account for the magnitude of salting out observed. Since Hg(II) strongly complexes with dissolved (and particulate) organic matter in natural environments, of more significance appears to be the salting out of Hg(II)-organic complexes. Operational measurements of the speciation of dissolved Hg(II) using Sep-Pak C18 columns indicate a reduction in the proportion of hydrophobic (C18-retained) dissolved Hg(II) complexes with increasing salinity, both in the presence and absence of suspended particles. Ratios of hydrophobic Hg(ll) before and after particle addition suggest a coupled salting out-sorption mechanism, with the precise nature of Hg(II) species salted out being determined bythe characteristics and concentrations of dissolved and sediment organic matter.
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Elsayed, Mustafa M A; Vierl, Ulrich; Cevc, Gregor
2009-06-01
Potentiometric lipid membrane-water partition coefficient studies neglect electrostatic interactions to date; this leads to incorrect results. We herein show how to account properly for such interactions in potentiometric data analysis. We conducted potentiometric titration experiments to determine lipid membrane-water partition coefficients of four illustrative drugs, bupivacaine, diclofenac, ketoprofen and terbinafine. We then analyzed the results conventionally and with an improved analytical approach that considers Coulombic electrostatic interactions. The new analytical approach delivers robust partition coefficient values. In contrast, the conventional data analysis yields apparent partition coefficients of the ionized drug forms that depend on experimental conditions (mainly the lipid-drug ratio and the bulk ionic strength). This is due to changing electrostatic effects originating either from bound drug and/or lipid charges. A membrane comprising 10 mol-% mono-charged molecules in a 150 mM (monovalent) electrolyte solution yields results that differ by a factor of 4 from uncharged membranes results. Allowance for the Coulombic electrostatic interactions is a prerequisite for accurate and reliable determination of lipid membrane-water partition coefficients of ionizable drugs from potentiometric titration data. The same conclusion applies to all analytical methods involving drug binding to a surface.
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NASA Astrophysics Data System (ADS)
Hauffe, Corina; Schwarze, Robert; Röhm, Patric; Müller, Ruben; Dröge, Werner; Gurova, Anastasia; Winkler, Peter; Baldy, Agnes
2016-04-01
Changes in weather and climate lead to increasing discussions about reasons and possible future impacts on the hydrological cycle. The question of a changed distribution of water also concerns the federal state of Saxony in the eastern part of Germany. Especially with a look at the different and increased requirements for water authorities, water economy and the public. To define and prepare these future requirements estimations of the future development of the natural water resources are necessary. Therefore data, information, and forecast concerning the development of the several components of the water balance are needed. And to make the obtained information easily available for experts and the public, tools like the internet have to be used. Under these frame conditions the water balance portal Saxony (www.wasserhaushaltsportal.sachsen.de) was developed within the project KliWES. The overall approach of the project was devided into the so-called „3 pillars".The first pillar focused on the evaluation of the status quo water balance from 1951-2005 by using a complex area-wide analysis of measured data. Also it contained the generating of a database and the development of a physically based parameter model. Furthermore an extensive model evaluation has been conducted with a number of objective assessment criteria, to select an appropriate model for the project. The second pillar included the calibration of the water balance model and the impact study of climate and land use change (1961-2100) on the water balance of Saxonian catchments. In this context 13 climate scenarios and three land use scenarios were simulated. The web presence of these two pillars represents a classical information service, which provides finalized results at the spatial resolution of sub-catchments using GIS-based webpages. The third pillar focused on the development of an interactive expert system. It allows the user (public, officials and consulting engineers) to simulate the water
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A dynamic re-partitioning strategy based on the distribution of key in Spark
NASA Astrophysics Data System (ADS)
Zhang, Tianyu; Lian, Xin
2018-05-01
Spark is a memory-based distributed data processing framework, has the ability of processing massive data and becomes a focus in Big Data. But the performance of Spark Shuffle depends on the distribution of data. The naive Hash partition function of Spark can not guarantee load balancing when data is skewed. The time of job is affected by the node which has more data to process. In order to handle this problem, dynamic sampling is used. In the process of task execution, histogram is used to count the key frequency distribution of each node, and then generate the global key frequency distribution. After analyzing the distribution of key, load balance of data partition is achieved. Results show that the Dynamic Re-Partitioning function is better than the default Hash partition, Fine Partition and the Balanced-Schedule strategy, it can reduce the execution time of the task and improve the efficiency of the whole cluster.
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Stochastic soil water balance under seasonal climates
Feng, Xue; Porporato, Amilcare; Rodriguez-Iturbe, Ignacio
2015-01-01
The analysis of soil water partitioning in seasonally dry climates necessarily requires careful consideration of the periodic climatic forcing at the intra-annual timescale in addition to daily scale variabilities. Here, we introduce three new extensions to a stochastic soil moisture model which yields seasonal evolution of soil moisture and relevant hydrological fluxes. These approximations allow seasonal climatic forcings (e.g. rainfall and potential evapotranspiration) to be fully resolved, extending the analysis of soil water partitioning to account explicitly for the seasonal amplitude and the phase difference between the climatic forcings. The results provide accurate descriptions of probabilistic soil moisture dynamics under seasonal climates without requiring extensive numerical simulations. We also find that the transfer of soil moisture between the wet to the dry season is responsible for hysteresis in the hydrological response, showing asymmetrical trajectories in the mean soil moisture and in the transient Budyko's curves during the ‘dry-down‘ versus the ‘rewetting‘ phases of the year. Furthermore, in some dry climates where rainfall and potential evapotranspiration are in-phase, annual evapotranspiration can be shown to increase because of inter-seasonal soil moisture transfer, highlighting the importance of soil water storage in the seasonal context. PMID:25663808
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Kitt, Jay P; Bryce, David A; Minteer, Shelley D; Harris, Joel M
2018-06-05
The phospholipid-water partition coefficient is a commonly measured parameter that correlates with drug efficacy, small-molecule toxicity, and accumulation of molecules in biological systems in the environment. Despite the utility of this parameter, methods for measuring phospholipid-water partition coefficients are limited. This is due to the difficulty of making quantitative measurements in vesicle membranes or supported phospholipid bilayers, both of which are small-volume phases that challenge the sensitivity of many analytical techniques. In this work, we employ in situ confocal Raman microscopy to probe the partitioning of a model membrane-active compound, 2-(4-isobutylphenyl) propionic acid or ibuprofen, into both hybrid- and supported-phospholipid bilayers deposited on the pore walls of individual chromatographic particles. The large surface-area-to-volume ratio of chromatographic silica allows interrogation of a significant lipid bilayer area within a very small volume. The local phospholipid concentration within a confocal probe volume inside the particle can be as high as 0.5 M, which overcomes the sensitivity limitations of making measurements in the limited membrane areas of single vesicles or planar supported bilayers. Quantitative determination of ibuprofen partitioning is achieved by using the phospholipid acyl-chains of the within-particle bilayer as an internal standard. This approach is tested for measurements of pH-dependent partitioning of ibuprofen into both hybrid-lipid and supported-lipid bilayers within silica particles, and the results are compared with octanol-water partitioning and with partitioning into individual optically trapped phospholipid vesicle membranes. Additionally, the impact of ibuprofen partitioning on bilayer structure is evaluated for both within-particle model membranes and compared with the structural impacts of partitioning into vesicle lipid bilayers.
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Fluxpart: Open source software for partitioning carbon dioxide and water vapor fluxes
USDA-ARS?s Scientific Manuscript database
The eddy covariance method is regularly used for measuring gas fluxes over agricultural fields and natural ecosystems. For many applications, it is desirable to partition the measured fluxes into constitutive components: the water vapor flux into transpiration and direct evaporation components, and ...
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Climate Change Impact on Water Balance at the Chipola River Watershed in Florida
NASA Astrophysics Data System (ADS)
Griffen, J. M.; Chen, X.; Wang, D.; Hagen, S. C.
2013-12-01
As the largest tributary to the Apalachicola River, the Chipola River originates in southern Alabama, flows through the Florida Panhandle and drains into the Gulf of Mexico. The Chipola watershed is located in an intermediate climate environment with an aridity index of approximately 1.0. However, climate change affects the hydrologic cycle of Chipola River watershed at various temporal and spatial scales. Studying the effects of climate variations is of great importance for water and environmental management purposes in this watershed. This research is mainly focused on assessing climate change impact on the partitioning of rainfall and the following runoff generation in Chipola watershed, from long-term mean annual to inter-annual and to seasonal and monthly scales. A comprehensive water balance model at inter-annual scale is built in this study based on Budyko's framework, two-stage runoff theory and proportionality hypothesis. The inter-annual scale model considers the impact of storage change, seasonality and landscape controls, which are normally assumed to be negligible on a long-term scale. The model is applied to the Chipola River Watershed in Florida to project future water balance pattern with the input from a Regional Climate Model projection. Based on the projection results: evaporation will increase in the future in all 12 months; runoff will increase only in dry months of July to October, while significantly decrease in wet months of December to April; storage change will increase in wet months of January to April, while decrease in the dry months of August to November.
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Babiarz, Christopher L.; Hurley, J.P.; Krabbenhoft, D.P.; Gilmour, C.; Branfireun, B.A.
2003-01-01
Results from pilot studies on colloidal phase transport of newly deposited mercury in lake water and overland runoff demonstrate that the combination of ultrafiltration, and stable isotope amendment techniques is a viable tool for the study of mercury partitioning to filterable carbon. Ultrafiltration mass balance calculations were generally excellent, averaging 97.3, 96.1 and 99.8% for dissolved organic carbon (DOC), total mercury (HgT), and methylmercury (MeHg), respectively. Sub nanogram per liter quantities of isotope were measurable, and the observed phase distribution from replicate ultrafiltration separations on lake water agreed within 20%. We believe the data presented here are the first published colloidal phase mercury data on lake water and overland runoff from uncontaminated sites. Initial results from pilot-scale lake amendment experiments indicate that the choice of matrix used to dissolve the isotope did not affect the initial phase distribution of the added mercury in the lake. In addition there was anecdotal evidence that native MeHg was either recently produced in the system, or at a minimum, that this 'old' MeHg partitions to the same subset of DOC that binds the amended mercury. Initial results from pilot-scale overland runoff experiments indicate that less than 20% of newly deposited mercury was transported in the filterable fraction (<0.7 ??m). There is some indication of colloidal phase enrichment of mercury in runoff compared to the phase distribution of organic carbon, but the mechanism of this enrichment is unclear. The phase distribution of newly deposited mercury can differ from that of organic carbon and native mercury, suggesting that the quality of the carbon (available ligands), not the quantity of carbon, regulates partitioning. Further characterization of DOC is needed to clarify the underlying mechanisms. ?? 2002 Elsevier Science B.V. All rights reserved.
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Babiarz, Christopher L; Hurley, James P; Krabbenhoft, David P; Gilmour, Cynthia; Branfireun, Brian A
2003-03-20
Results from pilot studies on colloidal phase transport of newly deposited mercury in lake water and overland runoff demonstrate that the combination of ultrafiltration, and stable isotope amendment techniques is a viable tool for the study of mercury partitioning to filterable carbon. Ultrafiltration mass balance calculations were generally excellent, averaging 97.3, 96.1 and 99.8% for dissolved organic carbon (DOC), total mercury (Hg(T)), and methylmercury (MeHg), respectively. Sub nanogram per liter quantities of isotope were measurable, and the observed phase distribution from replicate ultrafiltration separations on lake water agreed within 20%. We believe the data presented here are the first published colloidal phase mercury data on lake water and overland runoff from uncontaminated sites. Initial results from pilot-scale lake amendment experiments indicate that the choice of matrix used to dissolve the isotope did not affect the initial phase distribution of the added mercury in the lake. In addition there was anecdotal evidence that native MeHg was either recently produced in the system, or at a minimum, that this 'old' MeHg partitions to the same subset of DOC that binds the amended mercury. Initial results from pilot-scale overland runoff experiments indicate that less than 20% of newly deposited mercury was transported in the filterable fraction (<0.7 microm). There is some indication of colloidal phase enrichment of mercury in runoff compared to the phase distribution of organic carbon, but the mechanism of this enrichment is unclear. The phase distribution of newly deposited mercury can differ from that of organic carbon and native mercury, suggesting that the quality of the carbon (available ligands), not the quantity of carbon, regulates partitioning. Further characterization of DOC is needed to clarify the underlying mechanisms.
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NASA Astrophysics Data System (ADS)
Ficklin, D. L.; Abatzoglou, J. T.
2017-12-01
The spatial variability in the balance between surface runoff (Q) and evapotranspiration (ET) is critical for understanding water availability. The Budyko framework suggests that this balance is solely a function of aridity. Observed deviations from this framework for individual watersheds, however, can vary significantly, resulting in uncertainty in using the Budyko framework in ungauged catchments and under future climate and land use scenarios. Here, we model the spatial variability in the partitioning of precipitation into Q and ET using a set of climatic, physiographic, and vegetation metrics for 211 near-natural watersheds across the contiguous United States (CONUS) within Budyko's framework through the free parameter ω. Using a generalized additive model, we found that precipitation seasonality, the ratio of soil water holding capacity to precipitation, topographic slope, and the fraction of precipitation falling as snow explained 81.2% of the variability in ω. This ω model applied to the Budyko framework explained 97% of the spatial variability in long-term Q for an independent set of near-natural watersheds. The developed ω model was also used to estimate the entire CONUS surface water balance for both contemporary and mid-21st century conditions. The contemporary CONUS surface water balance compared favorably to more sophisticated land-surface modeling efforts. For mid-21st century conditions, the model simulated an increase in the fraction of precipitation used by ET across the CONUS with declines in Q for much of the eastern CONUS and mountainous watersheds across the western US. The Budyko framework using the modeled ω lends itself to an alternative approach for assessing the potential response of catchment water balance to climate change to complement other approaches.
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R package CityWaterBalance | Science Inventory | US EPA
CityWaterBalance provides a reproducible workflow for studying an urban water system. The network of urban water flows and storages can be modeled and visualized. Any city may be modeled with preassembled data, but data for US cities can be gathered via web services using this package and dependencies, geoknife and dataRetrieval. Urban water flows are difficult to comprehensively quantify. Although many important data sources are openly available, they are published by a variety of agencies in different formats, units, spatial and temporal resolutions. Increasingly, open data are made available via web services, which allow for automated, current retrievals. Integrating data streams and estimating the values of unmeasured urban water flows, however, remains needlessly time-consuming. In order to streamline a reproducible analysis, we have developed the CityWaterBalance package for the open source R language. The CityWaterBalance package for R is based on a simple model of the network of urban water flows and storages. The model may be run with data that has been pre-assembled by the user, or data can be retrieved by functions in CityWaterBalance and dependencies. CityWaterBalance can be used to quickly assemble a quantitative portrait of any urban water system. The systemic effects of water management decisions can be readily explored. Much of the data acquisition process for US cities can already be automated, while the package serves as a place-hold
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Kitt, Jay P.; Bryce, David A.; Minteer, Shelley D.
The phospholipid-water partition coefficient is a commonly measured parameter that correlates with drug efficacy, small-molecule toxicity, and accumulation of molecules in biological systems in the environment. Despite the utility of this parameter, methods for measuring phospholipid-water partition coefficients are limited. This is due to the difficulty of making quantitative measurements in vesicle membranes or supported phospholipid bilayers, both of which are small-volume phases that challenge the sensitivity of many analytical techniques. In this paper, we employ in-situ confocal Raman microscopy to probe the partitioning of a model membrane-active compound, 2-(4-isobutylphenyl) propionic acid or ibuprofen, into both hybrid- and supported-phospholipid bilayersmore » deposited on the pore walls of individual chromatographic particles. The large surface-area-to-volume ratio of chromatographic silica allows interrogation of a significant lipid bilayer area within a very small volume. The local phospholipid concentration within a confocal probe volume inside the particle can be as high as 0.5 M, which overcomes the sensitivity limitations of making measurements in the limited membrane areas of single vesicles or planar supported bilayers. Quantitative determination of ibuprofen partitioning is achieved by using the phospholipid acyl-chains of the within-particle bilayer as an internal standard. This approach is tested for measurements of pH-dependent partitioning of ibuprofen into both hybrid-lipid and supported-lipid bilayers within silica particles, and the results are compared with octanol-water partitioning and with partitioning into individual optically-trapped phospholipid vesicle membranes. Finally and additionally, the impact of ibuprofen partitioning on bilayer structure is evaluated for both within-particle model membranes and compared with the structural impacts of partitioning into vesicle lipid bilayers.« less
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Kitt, Jay P.; Bryce, David A.; Minteer, Shelley D.; ...
2018-05-14
The phospholipid-water partition coefficient is a commonly measured parameter that correlates with drug efficacy, small-molecule toxicity, and accumulation of molecules in biological systems in the environment. Despite the utility of this parameter, methods for measuring phospholipid-water partition coefficients are limited. This is due to the difficulty of making quantitative measurements in vesicle membranes or supported phospholipid bilayers, both of which are small-volume phases that challenge the sensitivity of many analytical techniques. In this paper, we employ in-situ confocal Raman microscopy to probe the partitioning of a model membrane-active compound, 2-(4-isobutylphenyl) propionic acid or ibuprofen, into both hybrid- and supported-phospholipid bilayersmore » deposited on the pore walls of individual chromatographic particles. The large surface-area-to-volume ratio of chromatographic silica allows interrogation of a significant lipid bilayer area within a very small volume. The local phospholipid concentration within a confocal probe volume inside the particle can be as high as 0.5 M, which overcomes the sensitivity limitations of making measurements in the limited membrane areas of single vesicles or planar supported bilayers. Quantitative determination of ibuprofen partitioning is achieved by using the phospholipid acyl-chains of the within-particle bilayer as an internal standard. This approach is tested for measurements of pH-dependent partitioning of ibuprofen into both hybrid-lipid and supported-lipid bilayers within silica particles, and the results are compared with octanol-water partitioning and with partitioning into individual optically-trapped phospholipid vesicle membranes. Finally and additionally, the impact of ibuprofen partitioning on bilayer structure is evaluated for both within-particle model membranes and compared with the structural impacts of partitioning into vesicle lipid bilayers.« less
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Huang, WenJuan; Blinov, Nikolay; Kovalenko, Andriy
2015-04-30
The octanol-water partition coefficient is an important physical-chemical characteristic widely used to describe hydrophobic/hydrophilic properties of chemical compounds. The partition coefficient is related to the transfer free energy of a compound from water to octanol. Here, we introduce a new protocol for prediction of the partition coefficient based on the statistical-mechanical, 3D-RISM-KH molecular theory of solvation. It was shown recently that with the compound-solvent correlation functions obtained from the 3D-RISM-KH molecular theory of solvation, the free energy functional supplemented with the correction linearly related to the partial molar volume obtained from the Kirkwood-Buff/3D-RISM theory, also called the "universal correction" (UC), provides accurate prediction of the hydration free energy of small compounds, compared to explicit solvent molecular dynamics [ Palmer , D. S. ; J. Phys.: Condens. Matter 2010 , 22 , 492101 ]. Here we report that with the UC reparametrized accordingly this theory also provides an excellent agreement with the experimental data for the solvation free energy in nonpolar solvent (1-octanol) and so accurately predicts the octanol-water partition coefficient. The performance of the Kovalenko-Hirata (KH) and Gaussian fluctuation (GF) functionals of the solvation free energy, with and without UC, is tested on a large library of small compounds with diverse functional groups. The best agreement with the experimental data for octanol-water partition coefficients is obtained with the KH-UC solvation free energy functional.
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Crystal-chemistry and partitioning of REE in whitlockite
NASA Technical Reports Server (NTRS)
Colson, R. O.; Jolliff, B. L.
1993-01-01
Partitioning of Rare Earth Elements (REE) in whitlockite is complicated by the fact that two or more charge-balancing substitutions are involved and by the fact that concentrations of REE in natural whitlockites are sufficiently high such that simple partition coefficients are not expected to be constant even if mixing in the system is completely ideal. The present study combines preexisting REE partitioning data in whitlockites with new experiments in the same compositional system and at the same temperature (approximately 1030 C) to place additional constraints on the complex variations of REE partition coefficients and to test theoretical models for how REE partitioning should vary with REE concentration and other compositional variables. With this data set, and by combining crystallographic and thermochemical constraints with a SAS simultaneous-equation best-fitting routine, it is possible to infer answers to the following questions: what is the speciation on the individual sites Ca(B), Mg, and Ca(IIA) (where the ideal structural formula is Ca(B)18 Mg2Ca(IIA)2P14O56); how are REE's charge-balanced in the crystal; and is mixing of REE in whitlockite ideal or non-ideal. This understanding is necessary in order to extrapolate derived partition coefficients to other compositional systems and provides a broadened understanding of the crystal chemistry of whitlockite.
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Xu, Xiao Wu; Yu, Xin Xiao; Jia, Guo Dong; Li, Han Zhi; Lu, Wei Wei; Liu, Zi Qiang
2017-07-18
Soil-vegetation-atmosphere continuum (SPAC) is one of the important research objects in the field of terrestrial hydrology, ecology and global change. The process of water and carbon cycling, and their coupling mechanism are frontier issues. With characteristics of tracing, integration and indication, stable isotope techniques contribute to the estimation of the relationship between carbon sequestration and water consumption in ecosystems. In this review, based on a brief introduction of stable isotope principles and techniques, the applications of stable isotope techniques to water and carbon exchange in SPAC using optical stable isotope techniques were mainly explained, including: partitioning of net carbon exchange into photosynthesis and respiration; partitioning of evapotranspiration into transpiration and evaporation; coupling of water and carbon cycle at the ecosystem scale. Advanced techniques and methods provided long-term and high frequency measurements for isotope signals at the ecosystem scale, but the issues about the precision and accuracy for measurements, partitioning of ecosystem respiration, adaptability for models under non-steady state, scaling up, coupling mechanism of water and carbon cycles, were challenging. The main existing research findings, limitations and future research prospects were discussed, which might help new research and technology development in the field of stable isotope ecology.
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Computational prediction of ionic liquid 1-octanol/water partition coefficients.
Kamath, Ganesh; Bhatnagar, Navendu; Baker, Gary A; Baker, Sheila N; Potoff, Jeffrey J
2012-04-07
Wet 1-octanol/water partition coefficients (log K(ow)) predicted for imidazolium-based ionic liquids using adaptive bias force-molecular dynamics (ABF-MD) simulations lie in excellent agreement with experimental values. These encouraging results suggest prospects for this computational tool in the a priori prediction of log K(ow) values of ionic liquids broadly with possible screening implications as well (e.g., prediction of CO(2)-philic ionic liquids).
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NASA Astrophysics Data System (ADS)
Quade, M. E.; Brueggemann, N.; Graf, A.; Rothfuss, Y.
2017-12-01
Water stable isotopes are powerful tools for partitioning net into raw water fluxes such as evapotranspiration (ET) into soil evaporation (E) and plant transpiration (T). The isotopic methodology for ET partitioning is based on the fact that E and T have distinct water stable isotopic compositions, which in turn relies on the fact that each flux is differently affected by isotopic kinetic effects. An important work to be performed in parallel to field measurements is to better characterize these kinetic effects in the laboratory under controlled conditions. A soil evaporation laboratory experiment was conducted to retrieve characteristic values of the kinetic fractionation factor (αK) under varying soil and atmospheric water conditions. For this we used a combined soil and atmosphere column to monitor the soil and atmospheric water isotopic composition profiles at a high temporal and vertical resolution in a nondestructive manner by combining micro-porous membranes and laser spectroscopy. αK was calculated by using a well-known isotopic evaporation model in an inverse mode with the isotopic composition of E as one input variable, which was determined using a micro-Keeling regression plot. Knowledge on αK was further used in the field (Selhausen, North Rhine-Westphalia, Germany) to partition ET of catch crops and sugar beet (Beta vulgaris) during one growing season. Soil and atmospheric water isotopic profiles were measured automatically across depths and heights following a similar modus operandi as in the laboratory experiment. Additionally, a newly developed continuously moving elevator was used to obtain water vapor isotopic composition profiles with a high vertical resolution between soil surface, plant canopy and atmosphere. Finally, soil and plant samples were collected destructively to provide a comparison with the traditional isotopic methods. Our results illustrate the changing proportions of T and E along the growing season and demonstrate the
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NASA Astrophysics Data System (ADS)
Salazar, J. F.; Villegas, J. C.; Bettin, D. M.; Molina, R.; Henao, J. J.; Rodríguez, E.; Rendón, A.; Hoyos, I.; Poveda, G.
2016-12-01
moisture during the wet and dry seasons in the Amazon, and discuss its potential implications for the partitioning of evapotranspiration and the regulation of the surface energy and water balances. Collectively, our findings suggest that forests are more important to the regulation of the surface water and energy balances than generally assumed.
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Although tree- and stand-level estimates of forest water use are increasingly common, relatively little is known about partitioning of soil water resources among co-occurring tree species. We studied seasonal courses of soil water utilization in a 450-year-old Pseudotsuga menzies...
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The effect of oil-water-rock partitioning on the occurrence of alkylphenols in petroleum systems
DOE Office of Scientific and Technical Information (OSTI.GOV)
Taylor, P.; Larter, S.; Jones, M.
1997-05-01
Low molecular weight (C{sub 0}-C{sub 3}) alkylphenols are ubiquitous constituents of crude oils and formation waters of petroleum systems, and they represent legislatively monitored pollutants in produced oils and waters from offshore petroleum facilities. Their origin and the controls on their abundance are uncertain. Analysis of forty-four oils from various petroleum provinces, together with laboratory partitioning experiments, has provided further information on these controls. Although phenols are clearly partitioned between oil and water in petroleum systems, the consistency of most nondegraded petroleum phenol distributions (despite the apparent decrease of phenol concentrations in petroleums with increasing secondary migration distance) requires phenolmore » partitioning between petroleum, water, and solid phases-chiefly kerogen in the carrier bed. The retention of significant phenol concentrations in petroleums that have migrated tens of kilometres does indicate that petroleum typically only equilibrates with minor volumes of rock and associated waters. Laboratory experiments indicate that oils which have migrated approximately 25 km in the North Sea Tampen Spur through Jurassic sandstones may have equilibrated with less than 20 vol of rock and water, and possibly much less than 1 vol, depending on the sorbing phases within the rock (i.e., mineral or organic matter) and the wetting phase (oil or water). We conclude, supporting the hypothesis of Ioppolo-Armanios et al. (1995), that although ortho-substituted isomers dominate the phenol distributions of many petroleums, this reflects catalytic alkylation/isomerisation of unknown alkylphenol precursors in source rocks, rather than selective removal of meta- and para-substituted alkylphenol isomers from petroleum by water washing. 35 refs., 7 figs., 2 tabs.« less
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Stable isotope measurements of evapotranspiration partitioning in a maize field
NASA Astrophysics Data System (ADS)
Hogan, Patrick; Parajka, Juraj; Oismüller, Markus; Strauss, Peter; Heng, Lee; Blöschl, Günter
2017-04-01
Evapotranspiration (ET) is one of the most important processes in describing land surface - atmosphere interactions as it connects the energy and water balances. Furthermore knowledge of the individual components of evapotranspiration is important for ecohydrological modelling and agriculture, particularly for irrigation efficiency and crop productivity. In this study, we tested the application of the stable isotope method for evapotranspiration partitioning to a maize crop during the vegetative stage, using sap flow sensors as a comparison technique. Field scale ET was measured using an eddy covariance device and then partitioned using high frequency in-situ measurements of the isotopic signal of the canopy water vapor. The fraction of transpiration (Ft) calculated with the stable isotope method showed good agreement with the sap flow method. High correlation coefficient values were found between the two techniques, indicating the stable isotope method can successfully be applied in maize. The results show the changes in transpiration as a fraction of evapotranspiration after rain events and during the subsequent drying conditions as well as the relationship between transpiration and solar radiation and vapor pressure deficit.
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Atrazine and Diuron partitioning within a soil-water-surfactant system
NASA Astrophysics Data System (ADS)
Wang, P.; Keller, A.
2006-12-01
The interaction between pesticide and soil and water is even more complex in the presence of surfactants. In this study, batch equilibrium was employed to study the sorption of surfactants and the partitioning behaviors of Atrazine and Diuron within a soil-water-surfactant system. Five soils and four surfactants (nonionic Triton- 100, cationic Benzalkonium Chloride (BC), anionic Linear Alkylbenzenesulfonate (LAS), and anionic Sodium Dodecyl Sulfate (SDS)) were used. All surfactant sorption isotherms exhibited an initial linear increase at low surfactant concentrations but reached an asymptotic value as the surfactant concentrations increased. Among the surfactants, BC had the highest sorption onto all soils, followed by Triton-100 and then by LAS and SDS, implying that the nature of the charge significantly influences surfactant sorption. Sorption of either Triton-100 or BC was highly correlated with soil Cation Exchange Capacity (CEC) while that of LAS and SDS was complicated by the presence of Ca2+ and Mg2+ in the aqueous phase and the CEC sites. Both LAS and SDS formed complexes with Ca2+ and Mg2+, resulting in a significant decrease in the detergency of the surfactants. At high surfactant concentrations and with micelles present in the aqueous phase, the micelles formed a more competitive partitioning site for the pesticides, resulting in less pesticide sorbed to the soil. At low Triton-100 and BC concentration, the sorption of the surfactants first resulted in less Atrazine sorption but more Diuron sorption, implying competition between the surfactants and Atrazine, which serves as an indirect evidence that there is a different sorption mechanism for Atrazine. Atrazine is a weak base and it protonates and becomes positively charged near particle surfaces where the pH is much lower than in the bulk solution. The protonated Atrazine may then be held on the CEC sites via electrostatic attraction. Triton-100, LAS and SDS sorbed on the soil showed similar
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Water balance models in one-month-ahead streamflow forecasting
Alley, William M.
1985-01-01
Techniques are tested that incorporate information from water balance models in making 1-month-ahead streamflow forecasts in New Jersey. The results are compared to those based on simple autoregressive time series models. The relative performance of the models is dependent on the month of the year in question. The water balance models are most useful for forecasts of April and May flows. For the stations in northern New Jersey, the April and May forecasts were made in order of decreasing reliability using the water-balance-based approaches, using the historical monthly means, and using simple autoregressive models. The water balance models were useful to a lesser extent for forecasts during the fall months. For the rest of the year the improvements in forecasts over those obtained using the simpler autoregressive models were either very small or the simpler models provided better forecasts. When using the water balance models, monthly corrections for bias are found to improve minimum mean-square-error forecasts as well as to improve estimates of the forecast conditional distributions.
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Virtual water balance estimation in Tunisia
NASA Astrophysics Data System (ADS)
Stambouli, Talel; Benalaya, Abdallah; Ghezal, Lamia; Ali, Chebil; Hammami, Rifka; Souissi, Asma
2015-04-01
The water in Tunisia is limited and unevenly distributed in the different regions, especially in arid zones. In fact, the annual rainfall average varies from less than 100 mm in the extreme South to over 1500 mm in the extreme North of the country. Currently, the conventional potential of water resources of the country is estimated about 4.84 billion m³ / year of which 2.7 billion cubic meters / year of surface water and 2.14 billion cubic meters / year of groundwater, characterizing a structural shortage for water safety in Tunisia (under 500m3/inhabitant/year). With over than 80% of water volumes have been mobilized for agriculture. The virtual water concept, defined by Allan (1997), as the amount of water needed to generate a product of both natural and artificial origin, this concept establish a similarity between product marketing and water trade. Given the influence of water in food production, virtual water studies focus generally on food products. At a global scale, the influence of these product's markets with water management was not seen. Influence has appreciated only by analyzing water-scarce countries, but at the detail level, should be increased, as most studies consider a country as a single geographical point, leading to considerable inaccuracies. The main objective of this work is the virtual water balance estimation of strategic crops in Tunisia (both irrigated and dry crops) to determine their influence on the water resources management and to establish patterns for improving it. The virtual water balance was performed basing on farmer's surveys, crop and meteorological data, irrigation management and regional statistics. Results show that the majority of farmers realize a waste of the irrigation water especially at the vegetable crops and fruit trees. Thus, a good control of the cultural package may result in lower quantities of water used by crops while ensuring good production with a suitable economic profitability. Then, the virtual water
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Simpson, Stuart L; Batley, Graeme E
2003-02-01
Metal partitioning is altered when suboxic estuarine sediments containing Fe(II)-rich pore waters are disturbed during collection, preparation, and toxicity testing. Experiments with model Fe(II)-rich pore waters demonstrated the rates at which adsorptive losses of Cd, Cu, Ni, Mn, Pb, and Zn occur upon exposure to air. Experiments with Zn-contaminated estuarine sediments demonstrated large and often unpredictable changes to metal partitioning during sediment storage, removal of organisms, and homogenization before testing. Small modifications to conditions, such as aeration of overlying waters, caused large changes to the metal partitioning. Disturbances caused by sediment collection required many weeks for reestablishment of equilibrium. Bioturbation by benthic organisms led to oxidation of pore-water Fe(II) and lower Zn fluxes because of the formation of Fe hydroxide precipitates that adsorb pore-water Zn. For five weeks after the addition of organisms to sediments, Zn fluxes increased slowly as the organisms established themselves in the sediments, indicating that the establishment of equilibrium was not rapid. The results are discussed in terms of the dynamic nature of suboxic, Fe(II)-rich estuarine sediments, how organisms perturb their environment, and the importance of understanding chemistry in toxicity testing with whole sediments or pore water. Recommendations are provided for the handling of sediments for toxicity testing.
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NASA Astrophysics Data System (ADS)
Good, Stephen P.; Soderberg, Keir; Guan, Kaiyu; King, Elizabeth G.; Scanlon, Todd M.; Caylor, Kelly K.
2014-02-01
The partitioning of surface vapor flux (FET) into evaporation (FE) and transpiration (FT) is theoretically possible because of distinct differences in end-member stable isotope composition. In this study, we combine high-frequency laser spectroscopy with eddy covariance techniques to critically evaluate isotope flux partitioning of FET over a grass field during a 15 day experiment. Following the application of a 30 mm water pulse, green grass coverage at the study site increased from 0 to 10% of ground surface area after 6 days and then began to senesce. Using isotope flux partitioning, transpiration increased as a fraction of total vapor flux from 0% to 40% during the green-up phase, after which this ratio decreased while exhibiting hysteresis with respect to green grass coverage. Daily daytime leaf-level gas exchange measurements compare well with daily isotope flux partitioning averages (RMSE = 0.0018 g m-2 s-1). Overall the average ratio of FT to FET was 29%, where uncertainties in Keeling plot intercepts and transpiration composition resulted in an average of uncertainty of ˜5% in our isotopic partitioning of FET. Flux-variance similarity partitioning was partially consistent with the isotope-based approach, with divergence occurring after rainfall and when the grass was stressed. Over the average diurnal cycle, local meteorological conditions, particularly net radiation and relative humidity, are shown to control partitioning. At longer time scales, green leaf area and available soil water control FT/FET. Finally, we demonstrate the feasibility of combining isotope flux partitioning and flux-variance similarity theory to estimate water use efficiency at the landscape scale.
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Singer, Michael Bliss; Sargeant, Christopher I; Piégay, Hervé; Riquier, Jérémie; Wilson, Rob J S; Evans, Cristina M
2014-05-01
Seasonal and annual partitioning of water within river floodplains has important implications for ecohydrologic links between the water cycle and tree growth. Climatic and hydrologic shifts alter water distribution between floodplain storage reservoirs (e.g., vadose, phreatic), affecting water availability to tree roots. Water partitioning is also dependent on the physical conditions that control tree rooting depth (e.g., gravel layers that impede root growth), the sources of contributing water, the rate of water drainage, and water residence times within particular storage reservoirs. We employ instrumental climate records alongside oxygen isotopes within tree rings and regional source waters, as well as topographic data and soil depth measurements, to infer the water sources used over several decades by two co-occurring tree species within a riparian floodplain along the Rhône River in France. We find that water partitioning to riparian trees is influenced by annual (wet versus dry years) and seasonal (spring snowmelt versus spring rainfall) fluctuations in climate. This influence depends strongly on local (tree level) conditions including floodplain surface elevation and subsurface gravel layer elevation. The latter represents the upper limit of the phreatic zone and therefore controls access to shallow groundwater. The difference between them, the thickness of the vadose zone, controls total soil moisture retention capacity. These factors thus modulate the climatic influence on tree ring isotopes. Additionally, we identified growth signatures and tree ring isotope changes associated with recent restoration of minimum streamflows in the Rhône, which made new phreatic water sources available to some trees in otherwise dry years. Water shifts due to climatic fluctuations between floodplain storage reservoirsAnthropogenic changes to hydrology directly impact water available to treesEcohydrologic approaches to integration of hydrology afford new possibilities.
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Singer, Michael Bliss; Sargeant, Christopher I; Piégay, Hervé; Riquier, Jérémie; Wilson, Rob J S; Evans, Cristina M
2014-01-01
Seasonal and annual partitioning of water within river floodplains has important implications for ecohydrologic links between the water cycle and tree growth. Climatic and hydrologic shifts alter water distribution between floodplain storage reservoirs (e.g., vadose, phreatic), affecting water availability to tree roots. Water partitioning is also dependent on the physical conditions that control tree rooting depth (e.g., gravel layers that impede root growth), the sources of contributing water, the rate of water drainage, and water residence times within particular storage reservoirs. We employ instrumental climate records alongside oxygen isotopes within tree rings and regional source waters, as well as topographic data and soil depth measurements, to infer the water sources used over several decades by two co-occurring tree species within a riparian floodplain along the Rhône River in France. We find that water partitioning to riparian trees is influenced by annual (wet versus dry years) and seasonal (spring snowmelt versus spring rainfall) fluctuations in climate. This influence depends strongly on local (tree level) conditions including floodplain surface elevation and subsurface gravel layer elevation. The latter represents the upper limit of the phreatic zone and therefore controls access to shallow groundwater. The difference between them, the thickness of the vadose zone, controls total soil moisture retention capacity. These factors thus modulate the climatic influence on tree ring isotopes. Additionally, we identified growth signatures and tree ring isotope changes associated with recent restoration of minimum streamflows in the Rhône, which made new phreatic water sources available to some trees in otherwise dry years. Key Points Water shifts due to climatic fluctuations between floodplain storage reservoirs Anthropogenic changes to hydrology directly impact water available to trees Ecohydrologic approaches to integration of hydrology afford new
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Trophic Magnification of PCBs and Its Relationship to the Octanol−Water Partition Coefficient
We investigated polychlorinated biphenyl (PCB) bioaccumulation relative to octanol-water partition coefficient (KOW) and organism trophic position (TP) at the Lake Hartwell Superfund (South Carolina, USA). We measured PCBs (127 congeners) and stable isotopes (δ15...
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NASA Astrophysics Data System (ADS)
Gibson, J. J.; Birks, S. J.; Stadnyk, T.; Delavau, C. J.
2017-12-01
Stable isotopes of water have been measured since the 1990's as part of hydrometric monitoring programs within Canada's Water Survey of Canada gauging network and Alberta's Long-Term River Network. These datasets are being applied for hydrograph separation of streamflow sources, including rain, snow, groundwater, and surface water, as well as for estimation of watershed evaporation losses and evaporation/transpiration partitioning. Here we describe an innovative isotope mass balance approach, discuss benefits and limitations of the method, and present selected results that illustrate important regional trends in the contemporary hydrology of Canada. Overall, isotopes are shown to be useful for constraining water balance variations across regions with low monitoring density. Recommendations for future activities are identified, including regional comparisons with outputs from isotope-capable distributed hydrologic models.
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A partitioning strategy for nonuniform problems on multiprocessors
NASA Technical Reports Server (NTRS)
Berger, M. J.; Bokhari, S.
1985-01-01
The partitioning of a problem on a domain with unequal work estimates in different subddomains is considered in a way that balances the work load across multiple processors. Such a problem arises for example in solving partial differential equations using an adaptive method that places extra grid points in certain subregions of the domain. A binary decomposition of the domain is used to partition it into rectangles requiring equal computational effort. The communication costs of mapping this partitioning onto different microprocessors: a mesh-connected array, a tree machine and a hypercube is then studied. The communication cost expressions can be used to determine the optimal depth of the above partitioning.
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A study of water balances over the Tigris-Euphrates watershed
NASA Astrophysics Data System (ADS)
Kavvas, M. L.; Chen, Z. Q.; Anderson, M. L.; Ohara, N.; Yoon, J. Y.; Xiang, Fu
Tigris-Euphrates watershed was considered as one hydrologic unit, and a scientific assessment of its water resources was performed. Accordingly, (a) an inventory of land use/land cover, vegetation, soils, and existing hydraulic structures in the watershed was performed; (b) a regional hydroclimate model, RegHCM-TE, of the watershed was developed, and used to reconstruct historical precipitation data, to perform land hydrologic water balance computations for infiltration, soil water storage, actual evapotranspiration, direct runoff as input for streamflow computations, and to estimate irrigation water demands; and (c) a hydrologic model was developed to route streamflows within the river network of the watershed. Also, an algorithm for operating the reservoirs within the watershed was developed, and utilized to perform dynamic water balance studies under various water supply/demand scenarios to establish efficient utilization of the watershed’s water resources to meet the water demands of the riparian countries in the basin. Within this dynamic water balance framework, it is possible to assess and quantify the effect of sequential river flows on the chronologically sequential water balances over the watershed. The water balance study for the natural flow conditions prior to the development of large dams within TE basin, during the 1957-1969 critical period is presented.
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Liang, Yuzhen; Kuo, Dave T F; Allen, Herbert E; Di Toro, Dominic M
2016-10-01
There is concern about the environmental fate and effects of munition constituents (MCs). Polyparameter linear free energy relationships (pp-LFERs) that employ Abraham solute parameters can aid in evaluating the risk of MCs to the environment. However, poor predictions using pp-LFERs and ABSOLV estimated Abraham solute parameters are found for some key physico-chemical properties. In this work, the Abraham solute parameters are determined using experimental partition coefficients in various solvent-water systems. The compounds investigated include hexahydro-1,3,5-trinitro-1,3,5-triazacyclohexane (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX), hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine (MNX), hexahydro-1,3,5-trinitroso-1,3,5-triazine (TNX), hexahydro-1,3-dinitroso-5- nitro-1,3,5-triazine (DNX), 2,4,6-trinitrotoluene (TNT), 1,3,5-trinitrobenzene (TNB), and 4-nitroanisole. The solvents in the solvent-water systems are hexane, dichloromethane, trichloromethane, octanol, and toluene. The only available reported solvent-water partition coefficients are for octanol-water for some of the investigated compounds and they are in good agreement with the experimental measurements from this study. Solvent-water partition coefficients fitted using experimentally derived solute parameters from this study have significantly smaller root mean square errors (RMSE = 0.38) than predictions using ABSOLV estimated solute parameters (RMSE = 3.56) for the investigated compounds. Additionally, the predictions for various physico-chemical properties using the experimentally derived solute parameters agree with available literature reported values with prediction errors within 0.79 log units except for water solubility of RDX and HMX with errors of 1.48 and 2.16 log units respectively. However, predictions using ABSOLV estimated solute parameters have larger prediction errors of up to 7.68 log units. This large discrepancy is probably due to the missing R2NNO2
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Toropov, A A; Toropova, A P; Raska, I
2008-04-01
Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and organic compounds of different classes by optimal descriptors. Statistical characteristics of the best model (vitamins) are the following: n=17, R(2)=0.9841, s=0.634, F=931 (training set); n=7, R(2)=0.9928, s=0.773, F=690 (test set). Using this approach for modeling octanol/water partition coefficient for a set of organic compounds gives a model that is statistically characterized by n=69, R(2)=0.9872, s=0.156, F=5184 (training set) and n=70, R(2)=0.9841, s=0.179, F=4195 (test set).
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Development of a 5-Component Balance for Water Tunnel Applications
NASA Technical Reports Server (NTRS)
Suarez, Carlos J.; Kramer, Brian R.; Smith, Brooke C.
1999-01-01
The principal objective of this research/development effort was to develop a multi-component strain gage balance to measure both static and dynamic forces and moments on models tested in flow visualization water tunnels. A balance was designed that allows measuring normal and side forces, and pitching, yawing and rolling moments (no axial force). The balance mounts internally in the model and is used in a manner typical of wind tunnel balances. The key differences between a water tunnel balance and a wind tunnel balance are the requirement for very high sensitivity since the loads are very low (typical normal force is 90 grams or 0.2 lbs), the need for water proofing the gage elements, and the small size required to fit into typical water tunnel models. The five-component balance was calibrated and demonstrated linearity in the responses of the primary components to applied loads, very low interactions between the sections and no hysteresis. Static experiments were conducted in the Eidetics water tunnel with delta wings and F/A-18 models. The data were compared to forces and moments from wind tunnel tests of the same or similar configurations. The comparison showed very good agreement, providing confidence that loads can be measured accurately in the water tunnel with a relatively simple multi-component internal balance. The success of the static experiments encouraged the use of the balance for dynamic experiments. Among the advantages of conducting dynamic tests in a water tunnel are less demanding motion and data acquisition rates than in a wind tunnel test (because of the low-speed flow) and the capability of performing flow visualization and force/moment (F/M) measurements simultaneously with relative simplicity. This capability of simultaneous flow visualization and for F/M measurements proved extremely useful to explain the results obtained during these dynamic tests. In general, the development of this balance should encourage the use of water tunnels for a
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Management of the water balance and quality in mining areas
NASA Astrophysics Data System (ADS)
Pasanen, Antti; Krogerus, Kirsti; Mroueh, Ulla-Maija; Turunen, Kaisa; Backnäs, Soile; Vento, Tiia; Veijalainen, Noora; Hentinen, Kimmo; Korkealaakso, Juhani
2015-04-01
Although mining companies have long been conscious of water related risks they still face environmental management problems. These problems mainly emerge because mine sites' water balances have not been adequately assessed in the stage of the planning of mines. More consistent approach is required to help mining companies identify risks and opportunities related to the management of water resources in all stages of mining. This approach requires that the water cycle of a mine site is interconnected with the general hydrologic water cycle. In addition to knowledge on hydrological conditions, the control of the water balance in the mining processes require knowledge of mining processes, the ability to adjust process parameters to variable hydrological conditions, adaptation of suitable water management tools and systems, systematic monitoring of amounts and quality of water, adequate capacity in water management infrastructure to handle the variable water flows, best practices to assess the dispersion, mixing and dilution of mine water and pollutant loading to receiving water bodies, and dewatering and separation of water from tailing and precipitates. WaterSmart project aims to improve the awareness of actual quantities of water, and water balances in mine areas to improve the forecasting and the management of the water volumes. The study is executed through hydrogeological and hydrological surveys and online monitoring procedures. One of the aims is to exploit on-line water quantity and quality monitoring for the better management of the water balances. The target is to develop a practical and end-user-specific on-line input and output procedures. The second objective is to develop mathematical models to calculate combined water balances including the surface, ground and process waters. WSFS, the Hydrological Modeling and Forecasting System of SYKE is being modified for mining areas. New modelling tools are developed on spreadsheet and system dynamics platforms to
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Water Balance Covers For Waste Containment: Principles and Practice
Water Balance Covers for Waste Containment: Principles and Practices introduces water balance covers and compares them with conventional approaches to waste containment. The authors provided detailed analysis of the fundamentals of soil physics and design issues, introduce appl...
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Measurements of n-octanol/water partition coefficients (KOW) for highly hydrophobic chemicals, i.e., greater than 108, are extremely difficult and are rarely made, in part because the vanishingly small concentrations in the water phase require extraordinary analytical sensitivity...
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Chávez-Capilla, Teresa; Maher, William; Kelly, Tamsin; Foster, Simon
2016-11-01
Arsenic metabolism in living organisms is dependent on the ability of different arsenic species to traverse biological membranes. Simple diffusion provides an alternative influx and efflux route to mediated transport mechanisms that can increase the amount of arsenic available for metabolism in cells. Using octanol-water and liposome-water partition coefficients, the ability of arsenous acid, arsenate, methylarsonate, dimethylarsinate, thio-methylarsonate, thio-dimethylarsinic acid, arsenotriglutathione and monomethylarsonic diglutathione to diffuse through the lipid bilayer of cell membranes was investigated. Molecular modelling of arsenic species was used to explain the results. All arsenic species with the exception of arsenate, methylarsonate and thio-methylarsonate were able to diffuse through the lipid bilayer of liposomes, with liposome-water partition coefficients between 0.04 and 0.13. Trivalent arsenic species and thio-pentavalent arsenic species showed higher partition coefficients, suggesting that they can easily traverse cell membranes by passive simple diffusion. Given the higher toxicity of these species compared to oxo-pentavalent arsenic species, this study provides evidence supporting the risk associated with human exposure to trivalent and thio-arsenic species. Copyright © 2016. Published by Elsevier B.V.
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Roth, Michal
2016-12-06
High-pressure phase behavior of systems containing water, carbon dioxide and organics has been important in several environment- and energy-related fields including carbon capture and storage, CO 2 sequestration and CO 2 -assisted enhanced oil recovery. Here, partition coefficients (K-factors) of organic solutes between water and supercritical carbon dioxide have been correlated with extended linear solvation energy relationships (LSERs). In addition to the Abraham molecular descriptors of the solutes, the explanatory variables also include the logarithm of solute vapor pressure, the solubility parameters of carbon dioxide and water, and the internal pressure of water. This is the first attempt to include also the properties of water as explanatory variables in LSER correlations of K-factor data in CO 2 -water-organic systems. Increasing values of the solute hydrogen bond acidity, the solute hydrogen bond basicity, the solute dipolarity/polarizability, the internal pressure of water and the solubility parameter of water all tend to reduce the K-factor, that is, to favor the solute partitioning to the water-rich phase. On the contrary, increasing values of the solute characteristic volume, the solute vapor pressure and the solubility parameter of CO 2 tend to raise the K-factor, that is, to favor the solute partitioning to the CO 2 -rich phase.
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40 CFR 799.6756 - TSCA partition coefficient (n-octanol/water), generator column method.
Code of Federal Regulations, 2013 CFR
2013-07-01
... method, or any other reliable quantitative procedure must be used for those compounds that do not absorb... any other reliable quantitative method, aqueous solutions from the generator column enter a collecting... Solubilities and Octanol-Water Partition Coefficients of Hydrophobic Substances,” Journal of Research of the...
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40 CFR 799.6756 - TSCA partition coefficient (n-octanol/water), generator column method.
Code of Federal Regulations, 2014 CFR
2014-07-01
... method, or any other reliable quantitative procedure must be used for those compounds that do not absorb... any other reliable quantitative method, aqueous solutions from the generator column enter a collecting... Solubilities and Octanol-Water Partition Coefficients of Hydrophobic Substances,” Journal of Research of the...
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USDA-ARS?s Scientific Manuscript database
Partitioned observations of evapotranspiration (ET) into its constituent components of soil and canopy evaporation (E) and plant transpiration (T) are needed to validate many agricultural water use models. E and T observations are also useful for assessing management practices to reduce crop water ...
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NASA Astrophysics Data System (ADS)
Padrón, Ryan S.; Gudmundsson, Lukas; Greve, Peter; Seneviratne, Sonia I.
2017-11-01
The long-term surface water balance over land is described by the partitioning of precipitation (P) into runoff and evapotranspiration (ET), and is commonly characterized by the ratio ET/P. The ratio between potential evapotranspiration (PET) and P is explicitly considered to be the primary control of ET/P within the Budyko framework, whereas all other controls are often integrated into a single parameter, ω. Although the joint effect of these additional controlling factors of ET/P can be significant, a detailed understanding of them is yet to be achieved. This study therefore introduces a new global data set for the long-term mean partitioning of P into ET and runoff in 2,733 catchments, which is based on in situ observations and assembled from a systematic examination of peer-reviewed studies. A total of 26 controls of ET/P that are proposed in the literature are assessed using the new data set. Results reveal that: (i) factors controlling ET/P vary between regions with different climate types; (ii) controls other than PET/P explain at least 35% of the ET/P variance in all regions, and up to ˜90% in arid climates; (iii) among these, climate factors and catchment slope dominate over other landscape characteristics; and (iv) despite the high attention that vegetation-related indices receive as controls of ET/P, they are found to play a minor and often nonsignificant role. Overall, this study provides a comprehensive picture on factors controlling the partitioning of P, with valuable insights for model development, watershed management, and the assessment of water resources around the globe.
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NASA Astrophysics Data System (ADS)
Farhadi, L.; Abdolghafoorian, A.
2015-12-01
The land surface is a key component of climate system. It controls the partitioning of available energy at the surface between sensible and latent heat, and partitioning of available water between evaporation and runoff. Water and energy cycle are intrinsically coupled through evaporation, which represents a heat exchange as latent heat flux. Accurate estimation of fluxes of heat and moisture are of significant importance in many fields such as hydrology, climatology and meteorology. In this study we develop and apply a Bayesian framework for estimating the key unknown parameters of terrestrial water and energy balance equations (i.e. moisture and heat diffusion) and their uncertainty in land surface models. These equations are coupled through flux of evaporation. The estimation system is based on the adjoint method for solving a least-squares optimization problem. The cost function consists of aggregated errors on state (i.e. moisture and temperature) with respect to observation and parameters estimation with respect to prior values over the entire assimilation period. This cost function is minimized with respect to parameters to identify models of sensible heat, latent heat/evaporation and drainage and runoff. Inverse of Hessian of the cost function is an approximation of the posterior uncertainty of parameter estimates. Uncertainty of estimated fluxes is estimated by propagating the uncertainty for linear and nonlinear function of key parameters through the method of First Order Second Moment (FOSM). Uncertainty analysis is used in this method to guide the formulation of a well-posed estimation problem. Accuracy of the method is assessed at point scale using surface energy and water fluxes generated by the Simultaneous Heat and Water (SHAW) model at the selected AmeriFlux stations. This method can be applied to diverse climates and land surface conditions with different spatial scales, using remotely sensed measurements of surface moisture and temperature states
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Evolving bipartite authentication graph partitions
Pope, Aaron Scott; Tauritz, Daniel Remy; Kent, Alexander D.
2017-01-16
As large scale enterprise computer networks become more ubiquitous, finding the appropriate balance between user convenience and user access control is an increasingly challenging proposition. Suboptimal partitioning of users’ access and available services contributes to the vulnerability of enterprise networks. Previous edge-cut partitioning methods unduly restrict users’ access to network resources. This paper introduces a novel method of network partitioning superior to the current state-of-the-art which minimizes user impact by providing alternate avenues for access that reduce vulnerability. Networks are modeled as bipartite authentication access graphs and a multi-objective evolutionary algorithm is used to simultaneously minimize the size of largemore » connected components while minimizing overall restrictions on network users. Lastly, results are presented on a real world data set that demonstrate the effectiveness of the introduced method compared to previous naive methods.« less
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Evolving bipartite authentication graph partitions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Pope, Aaron Scott; Tauritz, Daniel Remy; Kent, Alexander D.
As large scale enterprise computer networks become more ubiquitous, finding the appropriate balance between user convenience and user access control is an increasingly challenging proposition. Suboptimal partitioning of users’ access and available services contributes to the vulnerability of enterprise networks. Previous edge-cut partitioning methods unduly restrict users’ access to network resources. This paper introduces a novel method of network partitioning superior to the current state-of-the-art which minimizes user impact by providing alternate avenues for access that reduce vulnerability. Networks are modeled as bipartite authentication access graphs and a multi-objective evolutionary algorithm is used to simultaneously minimize the size of largemore » connected components while minimizing overall restrictions on network users. Lastly, results are presented on a real world data set that demonstrate the effectiveness of the introduced method compared to previous naive methods.« less
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A Monthly Water-Balance Model Driven By a Graphical User Interface
McCabe, Gregory J.; Markstrom, Steven L.
2007-01-01
This report describes a monthly water-balance model driven by a graphical user interface, referred to as the Thornthwaite monthly water-balance program. Computations of monthly water-balance components of the hydrologic cycle are made for a specified location. The program can be used as a research tool, an assessment tool, and a tool for classroom instruction.
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Water balance at a low-level radioactive-waste disposal site
Healy, R.W.; Gray, J.R.; De Vries, G. M.; Mills, P.C.
1989-01-01
The water balance at a low-level radioactive-waste disposal site in northwestern Illinois was studied from July 1982 through June 1984. Continuous data collection allowed estimates to be made for each component of the water-balance equation independent of other components. The average annual precipitation was 948 millimeters. Average annual evapotranspiration was estimated at 637 millimeters, runoff was 160 millimeters, change in water storage in a waste-trench cover was 24 millimeters, and deep percolation was 208 millimeters. The magnitude of the difference between precipitation and all other components (81 millimeters per year) indicates that, in a similar environment, the water-budget method would be useful in estimating evapotranspiration, but questionable for estimation of other components. Precipitation depth and temporal distribution had a very strong effect on all other components of the water-balance equation. Due to the variability of precipitation from year to year, it appears that two years of data are inadequate for characterization of the long-term average water balance at the site.
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NASA Astrophysics Data System (ADS)
Miller, J. N.; Black, C. K.; Bernacchi, C.
2014-12-01
Global demand for renewable energy is accelerating land conversion from common row crops such as maize and soybean to cellulosic biofuel crops such as miscanthus and switchgrass. This land conversion is expected to alter ecohydrology via changes in evapotranspiration (ET). However, the direction in which evapotranspiration will shift, either partitioning more moisture through soil evaporation (E) or through plant transpiration (T) is uncertain. To investigate how land conversion from maize to miscanthus affects ET partitioning we measured the isotopic composition of water vapor via continuous air sampling. We obtained continuous diurnal measurements of δ2H and δ18O for miscanthus and maize on multiple days over the course of the growing season. Water vapor isotopes drawn from two heights were measured at 2 Hz using a cavity ringdown spectrometer and partitioned into components of E and T using a simple mixing equation. A second approach to partitioning was accomplished by subtracting transpiration measurements, obtained through sap flow sensors, from total ET, measured via eddy covariance. Preliminary results reveal that both methods compare favorably and that transpiration dominates variations in ET in miscanthus fields more so than in fields of maize.
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Regulation of water balance in mangroves
Reef, Ruth; Lovelock, Catherine E.
2015-01-01
Background Mangroves are a group of highly salt-tolerant woody plants. The high water use efficiency of mangroves under saline conditions suggests that regulation of water transport is a crucial component of their salinity tolerance. Scope This review focuses on the processes that contribute to the ability of mangroves to maintain water uptake and limit water loss to the soil and the atmosphere under saline conditions, from micro to macro scales. These processes include: (1) efficient filtering of the incoming water to exclude salt; (2) maintenance of internal osmotic potentials lower than that of the rhizosphere; (3) water-saving properties; and (4) efficient exploitation of less-saline water sources when these become available. Conclusions Mangroves are inherently plastic and can change their structure at the root, leaf and stand levels in response to salinity in order to exclude salt from the xylem stream, maintain leaf hydraulic conductance, avoid cavitation and regulate water loss (e.g. suberization of roots and alterations of leaf size, succulence and angle, hydraulic anatomy and biomass partitioning). However, much is still unknown about the regulation of water uptake in mangroves, such as how they sense and respond to heterogeneity in root zone salinity, the extent to which they utilize non-stomatally derived CO2 as a water-saving measure and whether they can exploit atmospheric water sources. PMID:25157072
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Salazar-Parra, Carolina; Aranjuelo, Iker; Pascual, Inmaculada; Erice, Gorka; Sanz-Sáez, Álvaro; Aguirreolea, Jone; Sánchez-Díaz, Manuel; Irigoyen, Juan José; Araus, José Luis; Morales, Fermín
2015-02-01
Although plant performance under elevated CO2 has been extensively studied in the past little is known about photosynthetic performance changing simultaneously CO2, water availability and temperature conditions. Moreover, despite of its relevancy in crop responsiveness to elevated CO2 conditions, plant level C balance is a topic that, comparatively, has received little attention. In order to test responsiveness of grapevine photosynthetic apparatus to predicted climate change conditions, grapevine (Vitis vinifera L. cv. Tempranillo) fruit-bearing cuttings were exposed to different CO2 (elevated, 700ppm vs. ambient, ca. 400ppm), temperature (ambient vs. elevated, ambient +4°C) and irrigation levels (partial vs. full irrigation). Carbon balance was followed monitoring net photosynthesis (AN, C gain), respiration (RD) and photorespiration (RL) (C losses). Modification of environment (13)C isotopic composition (δ(13)C) under elevated CO2 (from -10.30 to -24.93‰) enabled the further characterization of C partitioning into roots, cuttings, shoots, petioles, leaves, rachides and berries. Irrespective of irrigation level and temperature, exposure to elevated CO2 induced photosynthetic acclimation of plants. C/N imbalance reflected the inability of plants grown at 700ppm CO2 to develop strong C sinks. Partitioning of labeled C to storage organs (main stem and roots) did not avoid accumulation of labeled photoassimilates in leaves, affecting negatively Rubisco carboxylation activity. The study also revealed that, after 20 days of treatment, no oxidative damage to chlorophylls or carotenoids was observed, suggesting a protective role of CO2 either at current or elevated temperatures against the adverse effect of water stress. Copyright © 2014 Elsevier GmbH. All rights reserved.
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Temporal and spatial variability of global water balance
McCabe, Gregory J.; Wolock, David M.
2013-01-01
An analysis of simulated global water-balance components (precipitation [P], actual evapotranspiration [AET], runoff [R], and potential evapotranspiration [PET]) for the past century indicates that P has been the primary driver of variability in R. Additionally, since about 2000, there have been increases in P, AET, R, and PET for most of the globe. The increases in R during 2000 through 2009 have occurred despite unprecedented increases in PET. The increases in R are the result of substantial increases in P during the cool Northern Hemisphere months (i.e. October through March) when PET increases were relatively small; the largest PET increases occurred during the warm Northern Hemisphere months (April through September). Additionally, for the 2000 through 2009 period, the latitudinal distribution of P departures appears to co-vary with the mean P departures from 16 climate model projections of the latitudinal response of P to warming, except in the high latitudes. Finally, changes in water-balance variables appear large from the perspective of departures from the long-term means. However, when put into the context of the magnitudes of the raw water balance variable values, there appears to have been little change in any of the water-balance variables over the past century on a global or hemispheric scale.
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NASA Astrophysics Data System (ADS)
Nagler, P. L.; Glenn, E. P.
2012-12-01
With increased demand on water sources for human use and likely diminished supplies due to climate change, it is important to understand the variation in evapotranspiration (ET) and vegetation water use by transpiration (T) in arid and semi-arid zone riparian areas in the western U.S. Understanding riparian plant water use is critical for accuracy of climate models, predictions used in water resources management, and assessment of land use change impacts on the water balance of ecosystems. Moore and Heilman (2011) suggested the following three principles for predicting when vegetation changes will impact the local or regional water budget: (i) variation will result if energy balance partitioning has been altered, (ii) if deeper or shallower active rooting depth has changed the amount of soil moisture accessible to plants, or (iii) if temporary changes in water use add up over longer time scales. They note that large changes in vegetation types do not necessarily result in changes in water discharge. We will use these principles to consider the case of saltcedar (Tamarix spp.) on western U.S. rivers. Once considered a high-water-use plant that out-competed native trees, research over the past two decades has shown that saltcedar water use is low to moderate, and less than native trees. Consequently, the prospects of salvaging water for human use by replacing saltcedar with native trees, once thought to be bright, now appear questionable. Furthermore, saltcedar has come to occupy ecohydrological niches on altered river systems that are no longer available to native plants. However, with the widespread introduction and spread of saltcedar leaf beetles (Diorhabda carinulata) on western rivers, introduced in part to reduce riparian water use through reduction of saltcedar abundance, saltcedar ecology has now entered a new phase. The talk will present a synthesis of the recent literature on saltcedar water use and provide an overview of saltcedar ecohydrology in terms of
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NASA Astrophysics Data System (ADS)
Ryerson, T. B.; Aikin, K. C.; Angevine, W. M.; Atlas, E. L.; Blake, D. R.; Brock, C. A.; Fehsenfeld, F. C.; Gao, R.-S.; de Gouw, J. A.; Fahey, D. W.; Holloway, J. S.; Lack, D. A.; Lueb, R. A.; Meinardi, S.; Middlebrook, A. M.; Murphy, D. M.; Neuman, J. A.; Nowak, J. B.; Parrish, D. D.; Peischl, J.; Perring, A. E.; Pollack, I. B.; Ravishankara, A. R.; Roberts, J. M.; Schwarz, J. P.; Spackman, J. R.; Stark, H.; Warneke, C.; Watts, L. A.
2011-04-01
The fate of deepwater releases of gas and oil mixtures is initially determined by solubility and volatility of individual hydrocarbon species; these attributes determine partitioning between air and water. Quantifying this partitioning is necessary to constrain simulations of gas and oil transport, to predict marine bioavailability of different fractions of the gas-oil mixture, and to develop a comprehensive picture of the fate of leaked hydrocarbons in the marine environment. Analysis of airborne atmospheric data shows massive amounts (˜258,000 kg/day) of hydrocarbons evaporating promptly from the Deepwater Horizon spill; these data collected during two research flights constrain air-water partitioning, thus bioavailability and fate, of the leaked fluid. This analysis quantifies the fraction of surfacing hydrocarbons that dissolves in the water column (˜33% by mass), the fraction that does not dissolve, and the fraction that evaporates promptly after surfacing (˜14% by mass). We do not quantify the leaked fraction lacking a surface expression; therefore, calculation of atmospheric mass fluxes provides a lower limit to the total hydrocarbon leak rate of 32,600 to 47,700 barrels of fluid per day, depending on reservoir fluid composition information. This study demonstrates a new approach for rapid-response airborne assessment of future oil spills.
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The Great Lakes Water Balance: Data availability and annotated bibliography of selected references
Neff, Brian P.; Killian, Jason R.
2003-01-01
Water balance calculations for the Great Lakes have been made for several decades and are a key component of Great Lakes water management. Despite the importance of the water balance, little has been done to inventory and describe the data available for use in water balance calculations. This report provides a catalog and brief description of major datasets that are used to calculate the Great Lakes water balance. Several additional datasets are identified that could be used to calculate parts of the water balance but currently are not being used. Individual offices and web pages that are useful for attaining these datasets are included. Four specific data gaps are also identified. An annotated bibliography of important publications dealing with the Great Lakes water balance is included. The findings of this investigation permit resource managers and scientists to access data more easily, assess shortcomings of current datasets, and identify which data are not currently being utilized in water balance calculations.
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CityWaterBalance: Track Flows of Water Through an Urban System
CityWaterBalance provides a reproducible workflow for studying an urban water system. The network of urban water flows and storages can be modeled and visualized. Any city may be modeled with preassembled data, but data for US cities can be gathered via web services using this p...
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The climatic water balance in an ecological context
NASA Astrophysics Data System (ADS)
Stephenson, N. L.
2011-12-01
Because the climatic water balance describes the seasonal interactions of energy (heat and solar radiation) and water in biologically meaningful ways, it provides a powerful tool for understanding and predicting the effects of climatic changes on the terrestrial biosphere. I begin with a brief overview of the definitions and interpretations of the biologically most important water balance parameters -- actual evapotranspiration (AET) and climatic water deficit (Deficit) -- and how the particular approach used to calculate these parameters depends both on the goals of the study and on the available climatic data. Some authors have attempted to represent aspects of the climatic water balance with indices based on annual potential evapotranspiration (PET) and precipitation (P), such at P/PET or PET - P. However, these and related indices do not reflect soil water dynamics, snow dynamics, or the seasonal interactions of energy and water, and therefore have no biological interpretation. Consequently, such indices are more poorly correlated with ecological patterns and processes than AET and Deficit. Of critical importance, the effects of changing energy and water supplies on the climatic water balance are nearly orthogonal. For example, a plant community growing on shallow soils on a shaded slope and one growing on deep soils on a sunward slope often may have the same amount of measured soil moisture available to them. However, the dynamics of energy and water that resulted in the identical soil moistures were fundamentally different (decreased evaporative demand on the shaded slope versus increased water supply on the deep soils); the associated differences in AET and Deficit will therefore result in different plant communities occupying the sites, in spite of identical soil moistures. In the context of climatic change, the orthogonal effects of energy and water mean that increasing precipitation cannot be expected to counteract the effects of increasing temperature
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The influence of hydrogen bonding on partition coefficients
NASA Astrophysics Data System (ADS)
Borges, Nádia Melo; Kenny, Peter W.; Montanari, Carlos A.; Prokopczyk, Igor M.; Ribeiro, Jean F. R.; Rocha, Josmar R.; Sartori, Geraldo Rodrigues
2017-02-01
This Perspective explores how consideration of hydrogen bonding can be used to both predict and better understand partition coefficients. It is shown how polarity of both compounds and substructures can be estimated from measured alkane/water partition coefficients. When polarity is defined in this manner, hydrogen bond donors are typically less polar than hydrogen bond acceptors. Analysis of alkane/water partition coefficients in conjunction with molecular electrostatic potential calculations suggests that aromatic chloro substituents may be less lipophilic than is generally believed and that some of the effect of chloro-substitution stems from making the aromatic π-cloud less available to hydrogen bond donors. Relationships between polarity and calculated hydrogen bond basicity are derived for aromatic nitrogen and carbonyl oxygen. Aligned hydrogen bond acceptors appear to present special challenges for prediction of alkane/water partition coefficients and this may reflect `frustration' of solvation resulting from overlapping hydration spheres. It is also shown how calculated hydrogen bond basicity can be used to model the effect of aromatic aza-substitution on octanol/water partition coefficients.
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Multi-jagged: A scalable parallel spatial partitioning algorithm
Deveci, Mehmet; Rajamanickam, Sivasankaran; Devine, Karen D.; ...
2015-03-18
Geometric partitioning is fast and effective for load-balancing dynamic applications, particularly those requiring geometric locality of data (particle methods, crash simulations). We present, to our knowledge, the first parallel implementation of a multidimensional-jagged geometric partitioner. In contrast to the traditional recursive coordinate bisection algorithm (RCB), which recursively bisects subdomains perpendicular to their longest dimension until the desired number of parts is obtained, our algorithm does recursive multi-section with a given number of parts in each dimension. By computing multiple cut lines concurrently and intelligently deciding when to migrate data while computing the partition, we minimize data movement compared to efficientmore » implementations of recursive bisection. We demonstrate the algorithm's scalability and quality relative to the RCB implementation in Zoltan on both real and synthetic datasets. Our experiments show that the proposed algorithm performs and scales better than RCB in terms of run-time without degrading the load balance. Lastly, our implementation partitions 24 billion points into 65,536 parts within a few seconds and exhibits near perfect weak scaling up to 6K cores.« less
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Calculation of the octanol-water partition coefficient of armchair polyhex BN nanotubes
NASA Astrophysics Data System (ADS)
Mohammadinasab, E.; Pérez-Sánchez, H.; Goodarzi, M.
2017-12-01
A predictive model for determination partition coefficient (log P) of armchair polyhex BN nanotubes by using simple descriptors was built. The relationship between the octanol-water log P and quantum chemical descriptors, electric moments, and topological indices of some armchair polyhex BN nanotubes with various lengths and fixed circumference are represented. Based on density functional theory electric moments and physico-chemical properties of those nanotubes are calculated.
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Regulation of water balance in mangroves.
Reef, Ruth; Lovelock, Catherine E
2015-02-01
Mangroves are a group of highly salt-tolerant woody plants. The high water use efficiency of mangroves under saline conditions suggests that regulation of water transport is a crucial component of their salinity tolerance. This review focuses on the processes that contribute to the ability of mangroves to maintain water uptake and limit water loss to the soil and the atmosphere under saline conditions, from micro to macro scales. These processes include: (1) efficient filtering of the incoming water to exclude salt; (2) maintenance of internal osmotic potentials lower than that of the rhizosphere; (3) water-saving properties; and (4) efficient exploitation of less-saline water sources when these become available. Mangroves are inherently plastic and can change their structure at the root, leaf and stand levels in response to salinity in order to exclude salt from the xylem stream, maintain leaf hydraulic conductance, avoid cavitation and regulate water loss (e.g. suberization of roots and alterations of leaf size, succulence and angle, hydraulic anatomy and biomass partitioning). However, much is still unknown about the regulation of water uptake in mangroves, such as how they sense and respond to heterogeneity in root zone salinity, the extent to which they utilize non-stomatally derived CO2 as a water-saving measure and whether they can exploit atmospheric water sources. © The Author 2014. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.
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Development of a simplified urban water balance model (WABILA).
Henrichs, M; Langner, J; Uhl, M
2016-01-01
During the last decade, water sensitive urban design (WSUD) has become more and more accepted. However, there is not any simple tool or option available to evaluate the influence of these measures on the local water balance. To counteract the impact of new settlements, planners focus on mitigating increases in runoff through installation of infiltration systems. This leads to an increasing non-natural groundwater recharge and decreased evapotranspiration. Simple software tools which evaluate or simulate the effect of WSUD on the local water balance are still needed. The authors developed a tool named WABILA (Wasserbilanz) that could support planners for optimal WSUD. WABILA is an easy-to-use planning tool that is based on simplified regression functions for established measures and land covers. Results show that WSUD has to be site-specific, based on climate conditions and the natural water balance.
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Partition of nonionic organic compounds in aquatic systems
Smith, James A.; Witkowski, Patrick J.; Chiou, Cary T.
1988-01-01
In aqueous systems, the distribution of many nonionic organic solutes in soil-sediment, aquatic organisms, and dissolved organic matter can be explained in terms of a partition model. The nonionic organic solute is distributed between water and different organic phases that behave as bulk solvents. Factors such as polarity, composition, and molecular size of the solute and organic phase determine the relative importance of partition to the environmental distribution of the solute. This chapter reviews these factors in the context of a partition model and also examines several environmental applications of the partition model for surface- and ground-water systems.
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A Layer Model of Ethanol Partitioning into Lipid Membranes
Nizza, David T.; Gawrisch, Klaus
2013-01-01
The effect of membrane composition on ethanol partitioning into lipid bilayers was assessed by headspace gas chromatography. A series of model membranes with different compositions have been investigated. Membranes were exposed to a physiological ethanol concentration of 20 mmol/l. The concentration of membranes was 20 wt% which roughly corresponds to values found in tissue. Partitioning depended on the chemical nature of polar groups at the lipid-water interface. Compared to phosphatidylcholine, lipids with headgroups containing phosphatidylglycerol, phosphatidylserine, and sphingomyelin showed enhanced partitioning while headgroups containing phosphatidylethanolamine resulted in a lower partition coefficient. The molar partition coefficient was independent of a membrane’s hydrophobic volume. This observation is in agreement with our previously published NMR results which showed that ethanol resides almost exclusively within the membrane-water interface. At an ethanol concentration of 20 mmol/l in water, ethanol concentrations at the lipid/water interface are in the range from 30 – 15 mmol/l, corresponding to one ethanol molecule per 100–200 lipids. PMID:19592710
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A layer model of ethanol partitioning into lipid membranes.
Nizza, David T; Gawrisch, Klaus
2009-06-01
The effect of membrane composition on ethanol partitioning into lipid bilayers was assessed by headspace gas chromatography. A series of model membranes with different compositions have been investigated. Membranes were exposed to a physiological ethanol concentration of 20 mmol/l. The concentration of membranes was 20 wt% which roughly corresponds to values found in tissue. Partitioning depended on the chemical nature of polar groups at the lipid/water interface. Compared to phosphatidylcholine, lipids with headgroups containing phosphatidylglycerol, phosphatidylserine, and sphingomyelin showed enhanced partitioning while headgroups containing phosphatidylethanolamine resulted in a lower partition coefficient. The molar partition coefficient was independent of a membrane's hydrophobic volume. This observation is in agreement with our previously published NMR results which showed that ethanol resides almost exclusively within the membrane/water interface. At an ethanol concentration of 20 mmol/l in water, ethanol concentrations at the lipid/water interface are in the range from 30-15 mmol/l, corresponding to one ethanol molecule per 100-200 lipids.
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The oxygen isotope partition function ratio of water and the structure of liquid water
O'Neil, J.R.; Adami, L.H.
1969-01-01
By means of the CO2-equilibration technique, the temperature dependence and absolute values of the oxygen isotope partition function ratio of liquid water have been determined, often at 1?? intervals, from -2 to 85??. A linear relationship between In (Q2/Q1) (H2O) and T-1 was obtained that is explicable in terms of the Bigeleisen-Mayer theory of isotopic fractionation. The data are incompatible with conventional, multicomponent mixture models of water because liquid water behaves isotopically as a singly structured homogeneous substance over the entire temperature range studied. A two-species model of water is proposed in which approximately 30% of the hydrogen bonds in ice are broken on melting at 0?? and in which this per cent of monomer changes by only a small amount over the entire liquid range. Because of the high precision and the fundamental property determined, the isotopic fractionation technique is particularly well suited to the detection of thermal anomalies. No anomalies were observed and those previously reported are ascribed to under-estimates of experimental error.
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Water balance dynamics in the Nile Basin
Senay, Gabriel B.; Asante, Kwabena; Artan, Guleid A.
2009-01-01
Understanding the temporal and spatial dynamics of key water balance components of the Nile River will provide important information for the management of its water resources. This study used satellite-derived rainfall and other key weather variables derived from the Global Data Assimilation System to estimate and map the distribution of rainfall, actual evapotranspiration (ETa), and runoff. Daily water balance components were modelled in a grid-cell environment at 0·1 degree (∼10 km) spatial resolution for 7 years from 2001 through 2007. Annual maps of the key water balance components and derived variables such as runoff and ETa as a percent of rainfall were produced. Generally, the spatial patterns of rainfall and ETa indicate high values in the upstream watersheds (Uganda, southern Sudan, and southwestern Ethiopia) and low values in the downstream watersheds. However, runoff as a percent of rainfall is much higher in the Ethiopian highlands around the Blue Nile subwatershed. The analysis also showed the possible impact of land degradation in the Ethiopian highlands in reducing ETa magnitudes despite the availability of sufficient rainfall. Although the model estimates require field validation for the different subwatersheds, the runoff volume estimate for the Blue Nile subwatershed is within 7·0% of a figure reported from an earlier study. Further research is required for a thorough validation of the results and their integration with ecohydrologic models for better management of water and land resources in the various Nile Basin ecosystems.
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Panagopoulos, Dimitri; Jahnke, Annika; Kierkegaard, Amelie; MacLeod, Matthew
2015-10-20
The sorption of cyclic volatile methyl siloxanes (cVMS) to organic matter has a strong influence on their fate in the aquatic environment. We report new measurements of the partition ratios between freshwater sediment organic carbon and water (KOC) and between Aldrich humic acid dissolved organic carbon and water (KDOC) for three cVMS, and for three polychlorinated biphenyls (PCBs) that were used as reference chemicals. Our measurements were made using a purge-and-trap method that employs benchmark chemicals to calibrate mass transfer at the air/water interface in a fugacity-based multimedia model. The measured log KOC of octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) were 5.06, 6.12, and 7.07, and log KDOC were 5.05, 6.13, and 6.79. To our knowledge, our measurements for KOC of D6 and KDOC of D4 and D6 are the first reported. Polyparameter linear free energy relationships (PP-LFERs) derived from training sets of empirical data that did not include cVMS generally did not predict our measured partition ratios of cVMS accurately (root-mean-squared-error (RMSE) for logKOC 0.76 and for logKDOC 0.73). We constructed new PP-LFERs that accurately describe partition ratios for the cVMS as well as for other chemicals by including our new measurements in the existing training sets (logKOC RMSEcVMS: 0.09, logKDOC RMSEcVMS: 0.12). The PP-LFERs we have developed here should be further evaluated and perhaps recalibrated when experimental data for other siloxanes become available.
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Myths and methodologies: Making sense of exercise mass and water balance.
Cheuvront, Samuel N; Montain, Scott J
2017-09-01
What is the topic of this review? There is a need to revisit the basic principles of exercise mass and water balance, the use of common equations and the practice of interpreting outcomes. What advances does it highlight? We propose use of the following equation as a way of simplifying exercise mass and water balance calculations in conditions where food is not consumed and waste is not excreted: ∆body mass - 0.20 g/kcal -1 = ∆body water. The relative efficacy of exercise drinking behaviours can be judged using the following equation: percentage dehydration = [(∆body mass - 0.20 g kcal -1 )/starting body mass] × 100. Changes in body mass occur because of flux in liquids, solids and gases. This knowledge is crucial for understanding metabolism, health and human water needs. In exercise science, corrections to observed changes in body mass to estimate water balance are inconsistently applied and often misinterpreted, particularly after prolonged exercise. Although acute body mass losses in response to exercise can represent a close surrogate for body water losses, the discordance between mass and water balance equivalence becomes increasingly inaccurate as more and more energy is expended. The purpose of this paper is briefly to clarify the roles that respiratory water loss, gas exchange and metabolic water production play in the correction of body mass changes for fluid balance determinations during prolonged exercise. Computations do not include waters of association with glycogen because any movement of water among body water compartments contributes nothing to water or mass flux from the body. Estimates of sweat loss from changes in body mass should adjust for non-sweat losses when possible. We propose use of the following equation as a way of simplifying the study of exercise mass and water balance: ∆body mass - 0.20 g kcal -1 = ∆body water. This equation directly controls for the influence of energy expenditure on body mass
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Kitt, Jay P; Harris, Joel M
2015-05-19
Octanol-water partitioning is one of the most widely used predictors of hydrophobicity and lipophilicity. Traditional methods for measuring octanol-water partition coefficients (K(ow)), including shake-flasks and generator columns, require hours for equilibration and milliliter quantities of sample solution. These challenges have led to development of smaller-scale methods for measuring K(ow). Recent advances in microfluidics have produced faster and smaller-volume approaches to measuring K(ow). As flowing volumes are reduced, however, separation of water and octanol prior to measurement and detection in small volumes of octanol phase are especially challenging. In this work, we reduce the receiver volume of octanol-water partitioning measurements from current practice by six-orders-of-magnitude, to the femtoliter scale, by using a single octanol-filled reversed-phase, octadecylsilane-modified (C18-silica) chromatographic particle as a collector. The fluid-handling challenges of working in such small volumes are circumvented by eliminating postequilibration phase separation. Partitioning is measured in situ within the pore-confined octanol phase using confocal Raman microscopy, which is capable of detecting and quantifying a wide variety of molecular structures. Equilibration times are fast (less than a minute) because molecular diffusion is efficient over distance scales of micrometers. The demonstrated amount of analyte needed to carry out a measurement is very small, less than 50 fmol, which would be a useful attribute for drug screening applications or testing of small quantities of environmentally sensitive compounds. The method is tested for measurements of pH-dependent octanol-water partitioning of naphthoic acid, and the results are compared to both traditional shake-flask measurements and sorption onto C18-modified silica without octanol present within the pores.
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NASA Astrophysics Data System (ADS)
Malone, Sparkle L.; Staudhammer, Christina L.; Loescher, Henry W.; Olivas, Paulo; Oberbauer, Steven F.; Ryan, Michael G.; Schedlbauer, Jessica; Starr, Gregory
2014-08-01
We analyzed energy partitioning in short- and long-hydroperiod freshwater marsh ecosystems in the Florida Everglades by examining energy balance components (eddy covariance derived latent energy (LE) and sensible heat (H) flux). The study period included several wet and dry seasons and variable water levels, allowing us to gain better mechanistic information about the control of and changes in marsh hydroperiods. The annual length of inundation is 5 months at the short-hydroperiod site (25°26'16.5″N, 80°35'40.68″W), whereas the long-hydroperiod site (25°33'6.72″N, 80°46'57.36″W) is inundated for 12 months annually due to differences in elevation and exposure to surface flow. In the Everglades, surface fluxes feed back to wet season precipitation and affect the magnitude of seasonal change in water levels through water loss as LE (evapotranspiration (ET)). At both sites, annual precipitation was higher than ET (1304 versus 1008 at the short-hydroperiod site and 1207 versus 1115 mm yr-1 at the long-hydroperiod site), though there were seasonal differences in the ratio of ET:precipitation. Results also show that energy balance closure was within the range found at other wetland sites (60 to 80%) and was lower when sites were inundated (60 to 70%). Patterns in energy partitioning covaried with hydroperiods and climate, suggesting that shifts in any of these components could disrupt current water and biogeochemical cycles throughout the Everglades region. These results suggest that the complex relationships between hydroperiods, energy exchange, and climate are important for creating conditions sufficient to maintain Everglades ecosystems.
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Water-soluble drug partitioning and adsorption in HEMA/MAA hydrogels.
Dursch, Thomas J; Taylor, Nicole O; Liu, David E; Wu, Rong Y; Prausnitz, John M; Radke, Clayton J
2014-01-01
Two-photon confocal microscopy and back extraction with UV/Vis-absorption spectrophotometry quantify equilibrium partition coefficients, k, for six prototypical drugs in five soft-contact-lens-material hydrogels over a range of water contents from 40 to 92%. Partition coefficients were obtained for acetazolamide, caffeine, hydrocortisone, Oregon Green 488, sodium fluorescein, and theophylline in 2-hydroxyethyl methacrylate/methacrylic acid (HEMA/MAA, pKa≈5.2) copolymer hydrogels as functions of composition, aqueous pH (2 and 7.4), and salinity. At pH 2, the hydrogels are nonionic, whereas at pH 7.4, hydrogels are anionic due to MAA ionization. Solute adsorption on and nonspecific electrostatic interaction with the polymer matrix are pronounced. To express deviation from ideal partitioning, we define an enhancement or exclusion factor, E ≡ k/φ1, where φ1 is hydrogel water volume fraction. All solutes exhibit E > 1 in 100 wt % HEMA hydrogels owing to strong specific adsorption to HEMA strands. For all solutes, E significantly decreases upon incorporation of anionic MAA into the hydrogel due to lack of adsorption onto charged MAA moieties. For dianionic sodium fluorescein and Oregon Green 488, and partially ionized monoanionic acetazolamide at pH 7.4, however, the decrease in E is more severe than that for similar-sized nonionic solutes. Conversely, at pH 2, E generally increases with addition of the nonionic MAA copolymer due to strong preferential adsorption to the uncharged carboxylic-acid group of MAA. For all cases, we quantitatively predict enhancement factors for the six drugs using only independently obtained parameters. In dilute solution for solute i, Ei is conveniently expressed as a product of individual enhancement factors for size exclusion (Ei(ex)), electrostatic interaction (Ei(el)), and specific adsorption (Ei(ad)):Ei≡Ei(ex)Ei(el)Ei(ad). To obtain the individual enhancement factors, we employ an extended Ogston mesh-size distribution for Ei
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Padró, Juan M; Pellegrino Vidal, Rocío B; Reta, Mario
2014-12-01
The partition coefficients, P IL/w, of several compounds, some of them of biological and pharmacological interest, between water and room-temperature ionic liquids based on the imidazolium, pyridinium, and phosphonium cations, namely 1-octyl-3-methylimidazolium hexafluorophosphate, N-octylpyridinium tetrafluorophosphate, trihexyl(tetradecyl)phosphonium chloride, trihexyl(tetradecyl)phosphonium bromide, trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)imide, and trihexyl(tetradecyl)phosphonium dicyanamide, were accurately measured. In this way, we extended our database of partition coefficients in room-temperature ionic liquids previously reported. We employed the solvation parameter model with different probe molecules (the training set) to elucidate the chemical interactions involved in the partition process and discussed the most relevant differences among the three types of ionic liquids. The multiparametric equations obtained with the aforementioned model were used to predict the partition coefficients for compounds (the test set) not present in the training set, most being of biological and pharmacological interest. An excellent agreement between calculated and experimental log P IL/w values was obtained. Thus, the obtained equations can be used to predict, a priori, the extraction efficiency for any compound using these ionic liquids as extraction solvents in liquid-liquid extractions.
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Regenerative (Regen) ECLSS Operations Water Balance
NASA Technical Reports Server (NTRS)
Tobias, Barry
2010-01-01
In November 2008, the Water Regenerative System racks were launched aboard Space Shuttle flight, STS-126 (ULF2) and installed and activated on the International Space Station (ISS). These racks, consisting of the Water Processor Assembly (WPA) and Urine Processor Assembly (UPA), completed the installation of the Regenerative (Regen) ECLSS systems which includes the Oxygen Generator Assembly (OGA) that was launched 2 years prior. With the onset of active water management on the US segment of the ISS, a new operational concept was required, that of "water balance." Even more recently, in 2010 the Sabatier system came online which converts H2 and CO2 into water and methane. The Regen ECLSS systems accept condensation from the atmosphere, urine from crew, and processes that fluid via various means into potable water which is used for crew drinking, building up skip-cycle water inventory, and water for electrolysis to produce oxygen. Specification rates of crew urine output, condensate output, O2 requirements, toilet flush water and drinking needs are well documented and used as a general plan when Regen ECLSS came online. Spec rates are useful in long term planning, however, daily or weekly rates are dependent on a number of variables. The constantly changing rates created a new challenge for the ECLSS flight controllers, who are responsible for operating the ECLSS systems onboard ISS. This paper will review the various inputs to rate changes and inputs to planning events, including but not limited to; crew personnel makeup, Regen ECLSS system operability, vehicle traffic, water containment availability, and Carbon Dioxide Removal Assembly (CDRA) capability. Along with the inputs that change the various rates, the paper will review the different systems, their constraints and finally the operational means by which flight controllers manage this new challenge of "water balance."
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Hydrology and empire: the Nile, water imperialism and the partition of Africa.
Tvedt, Terje
2011-01-01
Why did the British march up the Nile in the 1890s? The answers to this crucial question of imperial historiography have direct relevance for narratives and theories about imperialism, in general, and the partition of Africa in the nineteenth century, in particular. They will also influence our understanding of some of the main issues in the modern history of the whole region, including state developments and resource utilisation. This article presents an alternative to dominant interpretations of the partition of Africa and the role of British Nile policies in this context. It differs from mainstream diplomatic history, which dominates this research field, in its emphasis on how geographical factors and the hydrological characteristics of the Nile influenced and framed British thinking and actions in the region. Realising the importance of such factors and the specific character of the regional water system does not imply less attention to traditional diplomatic correspondence or to the role of individual imperial entrepreneurs. The strength of this analytical approach theoretically is that it makes it possible to locate the intentions and acts of historical subjects within specific geographical contexts. Empirically, it opens up a whole new set of source material, embedding the reconstruction of the British Nile discourse in a world of Nile plans, water works and hydrological discourses.
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Spacebased Observation of Water Balance Over Global Oceans
NASA Astrophysics Data System (ADS)
Liu, W.; Xie, X.
2008-12-01
We demonstrated that ocean surface fresh water flux less the water discharge into the ocean from river and ice melt balances the mass loss in the ocean both in magnitude and in the phase of annual variation. The surface water flux was computed from the divergence of the water transport integrated over the depth of the atmosphere. The atmospheric water transport is estimated from the precipitable water measured by Special Sensor Microwave Imager, the surface wind vector by QuikSCAT, and the NOAA cloud drift wind through a statistical model. The transport has been extensively validated using global radiosonde and data and operational numerical weather prediction results. Its divergence has been shown to agree with the difference between evaporation estimated from the Advanced Microwave Scanning Radiometer data and the precipitation measured by Tropical Rain Measuring Mission over the global tropical and subtropical oceans both in magnitude and geographical distribution for temporal scales ranging from intraseasonal to interannual. The water loss rate in the ocean is estimated by two methods, one is from Gravity Recovery and Climate Experiment and the other is by subtracting the climatological steric change from the sea level change measured by radar altimeter on Jason. Only climatological river discharge and ice melt from in situ measurements are available and the lack of temporal variation may contribute to discrepancies in the balance. We have successfully used the spacebased surface fluxes to estimate to climatological mean heat transport in the Atlantic ocean and is attempting to estimate the meridional fresh water (or salt) transport from the surface flux. The approximate closure of the water balance gives a powerful indirect validation of the spacebased products.
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NASA Astrophysics Data System (ADS)
Carbone, E.; Small, E. E.; Badger, A.; Livneh, B.
2016-12-01
Evapotranspiration (ET) is fundamental to the water, energy and carbon cycles. However, our ability to measure ET and partition the total flux into transpiration and evaporation from soil is limited. This project aims to generate a global, observationally-based soil evaporation dataset (E-SMAP): using SMAP surface soil moisture data in conjunction with models and auxiliary observations to observe or estimate each component of the surface water balance. E-SMAP will enable a better understanding of water balance processes and contribute to forecasts of water resource availability. Here we focus on the flux between the soil surface and root zone layers (qbot), which dictates the proportion of water that is available for soil evaporation. Any water that moves from the surface layer to the root zone contributes to transpiration or groundwater recharge. The magnitude and direction of qbot are driven by gravity and the gradient in matric potential. We use a highly discretized Richards Equation-type model (e.g. Hydrus 1D software) with meteorological forcing from the North American Land Data Assimilation System (NLDAS) to estimate qbot. We verify the simulations using SMAP L4 surface and root zone soil moisture data. These data are well suited for evaluating qbot because they represent the most advanced estimate of the surface to root zone soil moisture gradient at the global scale. Results are compared with similar calculations using NLDAS and in situ soil moisture data. Preliminary calculations show that the greatest amount of variability between qbot determined from NLDAS, in situ and SMAP occurs directly after precipitation events. At these times, uncertainties in qbot calculations significantly affect E-SMAP estimates.
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Evaluation of a spatially-distributed Thornthwaite water-balance model
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lough, J.A.
1993-03-01
A small watershed of low relief in coastal New Hampshire was divided into hydrologic sub-areas in a geographic information system on the basis of soils, sub-basins and remotely-sensed landcover. Three variables were spatially modeled for input to 49 individual water-balances: available water content of the root zone, water input and potential evapotranspiration (PET). The individual balances were weight-summed to generate the aggregate watershed-balance, which saw 9% (48--50 mm) less annual actual-evapotranspiration (AET) compared to a lumped approach. Analysis of streamflow coefficients suggests that the spatially-distributed approach is more representative of the basin dynamics. Variation of PET by landcover accounted formore » the majority of the 9% AET reduction. Variation of soils played a near-negligible role. As a consequence of the above points, estimates of landcover proportions and annual PET by landcover are sufficient to correct a lumped water-balance in the Northeast. If remote sensing is used to estimate the landcover area, a sensor with a high spatial resolution is required. Finally, while the lower Thornthwaite model has conceptual limitations for distributed application, the upper Thornthwaite model is highly adaptable to distributed problems and may prove useful in many earth-system models.« less
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A continuous high resolution water isotope dataset to constrain Alpine water balance estimates
NASA Astrophysics Data System (ADS)
Michelon, Anthony; Ceperley, Natalie; Beria, Harsh; Larsen, Josh; Schaefli, Bettina
2017-04-01
Water delivered from Alpine environments is a crucial resource for many countries around the world. Precipitation accumulated during cold seasons as snowpack or glaciers is often an important source of water during warm (dry) season but also a dominant contributor to the annual water balance. In Switzerland, water from high Alpine, glacier-fed catchments provides a large portion of both the hydroelectric power and water supply. However, large uncertainties regarding changes in glacier volume and snow accumulation can have significant impacts on hydrologic, biologic, physical and economic understanding, modeling, and predictions. Accurately quantifying these water resources is therefore an on-going challenge. Given the well-known difficulty observing solid precipitation (snowfall), it can be assumed that most of the uncertainty in water balance estimates for snow-dominated environments is due to: 1) Poor measurement of winter precipitation and 2) A poor estimation of timing and amount of snow melt. It is noteworthy that the timing of melt plays a crucial role even for annual water balance estimates since it might significantly influence melt runoff flow paths and thereby groundwater recharge. We use continuous monitoring of water stable isotopes over the entire annual cycle in an Alpine catchment to shed light on how such observations can constrain water balance estimates. The selected catchment is the experimental Vallon de Nant catchment in the Vaud Alps of Switzerland, where detailed hydrologic observations have recently started in addition to the existing vegetation and soil investigations. The Vallon de Nant (14 km2, and an altitude ranging from 1200 to 3051 m) is a narrow valley that accumulates large amounts of snow during winter. In spring and summer, the river discharge is mainly supplied by snowmelt, with additional inputs from a small glacier and rainfall. Continuous monitoring of water stable isotopes (δO18 and δD) is combined with measurements of
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Spatial coding-based approach for partitioning big spatial data in Hadoop
NASA Astrophysics Data System (ADS)
Yao, Xiaochuang; Mokbel, Mohamed F.; Alarabi, Louai; Eldawy, Ahmed; Yang, Jianyu; Yun, Wenju; Li, Lin; Ye, Sijing; Zhu, Dehai
2017-09-01
Spatial data partitioning (SDP) plays a powerful role in distributed storage and parallel computing for spatial data. However, due to skew distribution of spatial data and varying volume of spatial vector objects, it leads to a significant challenge to ensure both optimal performance of spatial operation and data balance in the cluster. To tackle this problem, we proposed a spatial coding-based approach for partitioning big spatial data in Hadoop. This approach, firstly, compressed the whole big spatial data based on spatial coding matrix to create a sensing information set (SIS), including spatial code, size, count and other information. SIS was then employed to build spatial partitioning matrix, which was used to spilt all spatial objects into different partitions in the cluster finally. Based on our approach, the neighbouring spatial objects can be partitioned into the same block. At the same time, it also can minimize the data skew in Hadoop distributed file system (HDFS). The presented approach with a case study in this paper is compared against random sampling based partitioning, with three measurement standards, namely, the spatial index quality, data skew in HDFS, and range query performance. The experimental results show that our method based on spatial coding technique can improve the query performance of big spatial data, as well as the data balance in HDFS. We implemented and deployed this approach in Hadoop, and it is also able to support efficiently any other distributed big spatial data systems.
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A novel partitioning method for block-structured adaptive meshes
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fu, Lin, E-mail: lin.fu@tum.de; Litvinov, Sergej, E-mail: sergej.litvinov@aer.mw.tum.de; Hu, Xiangyu Y., E-mail: xiangyu.hu@tum.de
We propose a novel partitioning method for block-structured adaptive meshes utilizing the meshless Lagrangian particle concept. With the observation that an optimum partitioning has high analogy to the relaxation of a multi-phase fluid to steady state, physically motivated model equations are developed to characterize the background mesh topology and are solved by multi-phase smoothed-particle hydrodynamics. In contrast to well established partitioning approaches, all optimization objectives are implicitly incorporated and achieved during the particle relaxation to stationary state. Distinct partitioning sub-domains are represented by colored particles and separated by a sharp interface with a surface tension model. In order to obtainmore » the particle relaxation, special viscous and skin friction models, coupled with a tailored time integration algorithm are proposed. Numerical experiments show that the present method has several important properties: generation of approximately equal-sized partitions without dependence on the mesh-element type, optimized interface communication between distinct partitioning sub-domains, continuous domain decomposition which is physically localized and implicitly incremental. Therefore it is particularly suitable for load-balancing of high-performance CFD simulations.« less
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A novel partitioning method for block-structured adaptive meshes
NASA Astrophysics Data System (ADS)
Fu, Lin; Litvinov, Sergej; Hu, Xiangyu Y.; Adams, Nikolaus A.
2017-07-01
We propose a novel partitioning method for block-structured adaptive meshes utilizing the meshless Lagrangian particle concept. With the observation that an optimum partitioning has high analogy to the relaxation of a multi-phase fluid to steady state, physically motivated model equations are developed to characterize the background mesh topology and are solved by multi-phase smoothed-particle hydrodynamics. In contrast to well established partitioning approaches, all optimization objectives are implicitly incorporated and achieved during the particle relaxation to stationary state. Distinct partitioning sub-domains are represented by colored particles and separated by a sharp interface with a surface tension model. In order to obtain the particle relaxation, special viscous and skin friction models, coupled with a tailored time integration algorithm are proposed. Numerical experiments show that the present method has several important properties: generation of approximately equal-sized partitions without dependence on the mesh-element type, optimized interface communication between distinct partitioning sub-domains, continuous domain decomposition which is physically localized and implicitly incremental. Therefore it is particularly suitable for load-balancing of high-performance CFD simulations.
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Liu, Huihui; Wei, Mengbi; Yang, Xianhai; Yin, Cen; He, Xiao
2017-01-01
Partition coefficients are vital parameters for measuring accurately the chemicals concentrations by passive sampling devices. Given the wide use of low density polyethylene (LDPE) film in passive sampling, we developed a theoretical linear solvation energy relationship (TLSER) model and a quantitative structure-activity relationship (QSAR) model for the prediction of the partition coefficient of chemicals between LDPE and water (K pew ). For chemicals with the octanol-water partition coefficient (log K ow ) <8, a TLSER model with V x (McGowan volume) and qA - (the most negative charge on O, N, S, X atoms) as descriptors was developed, but the model had relatively low determination coefficient (R 2 ) and cross-validated coefficient (Q 2 ). In order to further explore the theoretical mechanisms involved in the partition process, a QSAR model with four descriptors (MLOGP (Moriguchi octanol-water partition coeff.), P_VSA_s_3 (P_VSA-like on I-state, bin 3), Hy (hydrophilic factor) and NssO (number of atoms of type ssO)) was established, and statistical analysis indicated that the model had satisfactory goodness-of-fit, robustness and predictive ability. For chemicals with log K OW >8, a TLSER model with V x and a QSAR model with MLOGP as descriptor were developed. This is the first paper to explore the models for highly hydrophobic chemicals. The applicability domain of the models, characterized by the Euclidean distance-based method and Williams plot, covered a large number of structurally diverse chemicals, which included nearly all the common hydrophobic organic compounds. Additionally, through mechanism interpretation, we explored the structural features those governing the partition behavior of chemicals between LDPE and water. Copyright © 2016 Elsevier B.V. All rights reserved.
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Assessment of Cropland Water and Nitrogen Balance from Climate Change in Korea Peninsular
NASA Astrophysics Data System (ADS)
Lim, C. H.; Song, C.; Kim, T.; Lee, W. K.; Jeon, S. W.
2015-12-01
If crop growth is based on cropland productivity, the changes are due to changes in water and nitrogen balance from climate. In this study, order to estimation the change in cropland water and nitrogen balance in Korea peninsular using meteorological data observed last 30 years(1984-2013y). And we used soil, topography and management data about cropland. So as to estimating water and nitrogen variables, we used to the GIS based EPIC model that is major crop model in agro-ecosystem modelling field. Among the much of water and nitrogen variables, we selected to evapotranspiration, runoff, precipitation, nitrification, N lost, N contents and denitrification for this analysis. This selected variables associate with cropland water and nitrogen balance.First result, we can found the water balance changes in Korea peninsular, especially South Korea better condition than North Korea. In North Korea, evapotranspiration and precipitation result were lower than South Korea, but runoff result was bigger than South Korea. And we got a result about nitrogen balance changes in Korea peninsular from climate. In spatially, South and North Korea showed to similar condition on nitrogen balance in whole period. But in temporally, showed negative trends as time goes on, it caused by climate change. Overall condition of water and nitrogen balance on last 30 years in Korea peninsular, South Korea showed better condition than North Korea. Water and nitrogen balance change means have to be changed on agriculture management action, such as irrigation and fertilizer. In future period, climate change will cause a large effect to cropland water and nitrogen balance in mid-latitude area, so we have to prepare the change of this field for wise adaptation by climate change.
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International Space Station Water Balance Operations
NASA Technical Reports Server (NTRS)
Tobias, Barry; Garr, John D., II; Erne, Meghan
2011-01-01
In November 2008, the Water Regenerative System racks were launched aboard Space Shuttle flight, STS-126 (ULF2) and installed and activated on the International Space Station (ISS). These racks, consisting of the Water Processor Assembly (WPA) and Urine Processor Assembly (UPA), completed the installation of the Regenerative (Regen) Environmental Control and Life Support Systems (ECLSS), which includes the Oxygen Generation Assembly (OGA) that was launched 2 years prior. With the onset of active water management on the US segment of the ISS, a new operational concept was required, that of water balance . In November of 2010, the Sabatier system, which converts H2 and CO2 into water and methane, was brought on line. The Regen ECLSS systems accept condensation from the atmosphere, urine from crew, and processes that fluid via various means into potable water, which is used for crew drinking, building up skip-cycle water inventory, and water for electrolysis to produce oxygen. Specification (spec) rates of crew urine output, condensate output, O2 requirements, toilet flush water, and drinking needs are well documented and used as the best guess planning rates when Regen ECLSS came online. Spec rates are useful in long term planning, however, daily or weekly rates are dependent upon a number of variables. The constantly changing rates created a new challenge for the ECLSS flight controllers, who are responsible for operating the ECLSS systems onboard ISS from Mission Control in Houston. This paper reviews the various inputs to water planning, rate changes, and dynamic events, including but not limited to: crew personnel makeup, Regen ECLSS system operability, vehicle traffic, water storage availability, and Carbon Dioxide Removal Assembly (CDRA), Sabatier, and OGA capability. Along with the inputs that change the various rates, the paper will review the different systems, their constraints, and finally the operational challenges and means by which flight controllers
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NASA Astrophysics Data System (ADS)
Meuth, J. A.; Dominguez, F.
2011-12-01
Evapotranspiration partitioning into transpiration and evaporation is an important step in understanding the relative contribution of the vegetated land surface to total atmospheric moisture in an area. This type of study has rarely been done over long time periods focusing on small time scales of variation. The relative contributions of whole canopy transpiration and soil evaporation to total evapotranspiration were determined in a mid-latitude semi arid evergreen forest using stable isotope measurements of atmospheric water vapor. We used a cavity ringdown spectrometer to collect continuous 5-second average isotopic and water vapor measurements throughout the ecosystem boundary layer. In addition, we analyzed the isotopic composition of liquid water extracted from soil, leaf and stem samples to obtain relative contributions of transpiration and evaporation to whole canopy evapotranspriation. The results from this method provided many time periods throughout the day with statistically significant data. This method can be used to follow daily, monthly, or yearly cycles of evapotranspiration partitioning with relative ease and accuracy.
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NASA Technical Reports Server (NTRS)
Fendler, J. H.; Nome, F.; Nagyvary, J.
1975-01-01
The partitioning of amino acids (glycine, alanine, leucine, phenylalanine, histidine, aspartic acid, glutamic acid, lysine, isoleucine, threonine, serine, valine, proline, arginine) in aqueous and nonaqueous micellar systems was studied experimentally. Partitioning from neat hexane into dodecylammonium propionate trapped water in hexane was found to be dependent on both electrostatic and hydrophobic interactions, which implies that the interior of dodecylammonium propionate aggregates is negatively charged and is capable of hydrogen bonding in addition to providing a hydrophobic environment. Unitary free energies of transfer of amino acid side chains from hexane to water were determined and solubilities of amino acids in neat hexane substantiated the amino acid hydrophobicity scale. The relevance of the experiments to prebiotic chemistry was examined.
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Bryce, David A.; Shao, Hongbo; Cantrell, Kirk J.
2016-06-07
CO2 injected into depleted oil or gas reservoirs for long-term storage has the potential to mobilize organic compounds and distribute them between sediments and reservoir brines. Understanding this process is important when considering health and environmental risks, but little quantitative data currently exists on the partitioning of organics between supercritical CO2 and water. In this work, a high-pressure, in situ measurement capability was developed to assess the distribution of organics between CO2 and water at conditions relevant to deep underground storage of CO2. The apparatus consists of a titanium reactor with quartz windows, near-infrared and UV spectroscopic detectors, and switchingmore » valves that facilitate quantitative injection of organic reagents into the pressurized reactor. To demonstrate the utility of the system, partitioning coefficients were determined for benzene in water/supercritical CO2 over the range 35-65 °C and approximately 25-150 bar. Density changes in the CO2 phase with increasing pressure were shown to have dramatic impacts on benzene's partitioning behavior. Our partitioning coefficients were approximately 5-15 times lower than values previously determined by ex situ techniques that are prone to sampling losses. The in situ methodology reported here could be applied to quantify the distribution behavior of a wide range of organic compounds that may be present in geologic CO2 storage scenarios.« less
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Bryce, David A; Shao, Hongbo; Cantrell, Kirk J; Thompson, Christopher J
2016-06-07
CO2 injected into depleted oil or gas reservoirs for long-term storage has the potential to mobilize organic compounds and distribute them between sediments and reservoir brines. Understanding this process is important when considering health and environmental risks, but little quantitative data currently exists on the partitioning of organics between supercritical CO2 and water. In this work, a high-pressure, in situ measurement capability was developed to assess the distribution of organics between CO2 and water at conditions relevant to deep underground storage of CO2. The apparatus consists of a titanium reactor with quartz windows, near-infrared and UV spectroscopic detectors, and switching valves that facilitate quantitative injection of organic reagents into the pressurized reactor. To demonstrate the utility of the system, partitioning coefficients were determined for benzene in water/supercritical CO2 over the range 35-65 °C and approximately 25-150 bar. Density changes in the CO2 phase with increasing pressure were shown to have dramatic impacts on benzene's partitioning behavior. Our partitioning coefficients were approximately 5-15 times lower than values previously determined by ex situ techniques that are prone to sampling losses. The in situ methodology reported here could be applied to quantify the distribution behavior of a wide range of organic compounds that may be present in geologic CO2 storage scenarios.
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Semi-arid vegetation response to antecedent climate and water balance windows
Thoma, David P.; Munson, Seth M.; Irvine, Kathryn M.; Witwicki, Dana L.; Bunting, Erin
2016-01-01
Questions Can we improve understanding of vegetation response to water availability on monthly time scales in semi-arid environments using remote sensing methods? What climatic or water balance variables and antecedent windows of time associated with these variables best relate to the condition of vegetation? Can we develop credible near-term forecasts from climate data that can be used to prepare for future climate change effects on vegetation? Location Semi-arid grasslands in Capitol Reef National Park, Utah, USA. Methods We built vegetation response models by relating the normalized difference vegetation index (NDVI) from MODIS imagery in Mar–Nov 2000–2013 to antecedent climate and water balance variables preceding the monthly NDVI observations. We compared how climate and water balance variables explained vegetation greenness and then used a multi-model ensemble of climate and water balance models to forecast monthly NDVI for three holdout years. Results Water balance variables explained vegetation greenness to a greater degree than climate variables for most growing season months. Seasonally important variables included measures of antecedent water input and storage in spring, switching to indicators of drought, input or use in summer, followed by antecedent moisture availability in autumn. In spite of similar climates, there was evidence the grazed grassland showed a response to drying conditions 1 mo sooner than the ungrazed grassland. Lead times were generally short early in the growing season and antecedent window durations increased from 3 mo early in the growing season to 1 yr or more as the growing season progressed. Forecast accuracy for three holdout years using a multi-model ensemble of climate and water balance variables outperformed forecasts made with a naïve NDVI climatology. Conclusions We determined the influence of climate and water balance on vegetation at a fine temporal scale, which presents an opportunity to forecast vegetation
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Hypothalamic AgRP-neurons control peripheral substrate utilization and nutrient partitioning
Joly-Amado, Aurélie; Denis, Raphaël G P; Castel, Julien; Lacombe, Amélie; Cansell, Céline; Rouch, Claude; Kassis, Nadim; Dairou, Julien; Cani, Patrice D; Ventura-Clapier, Renée; Prola, Alexandre; Flamment, Melissa; Foufelle, Fabienne; Magnan, Christophe; Luquet, Serge
2012-01-01
Obesity-related diseases such as diabetes and dyslipidemia result from metabolic alterations including the defective conversion, storage and utilization of nutrients, but the central mechanisms that regulate this process of nutrient partitioning remain elusive. As positive regulators of feeding behaviour, agouti-related protein (AgRP) producing neurons are indispensible for the hypothalamic integration of energy balance. Here, we demonstrate a role for AgRP-neurons in the control of nutrient partitioning. We report that ablation of AgRP-neurons leads to a change in autonomic output onto liver, muscle and pancreas affecting the relative balance between lipids and carbohydrates metabolism. As a consequence, mice lacking AgRP-neurons become obese and hyperinsulinemic on regular chow but display reduced body weight gain and paradoxical improvement in glucose tolerance on high-fat diet. These results provide a direct demonstration of a role for AgRP-neurons in the coordination of efferent organ activity and nutrient partitioning, providing a mechanistic link between obesity and obesity-related disorders. PMID:22990237
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Padró, Juan M; Ponzinibbio, Agustín; Mesa, Leidy B Agudelo; Reta, Mario
2011-03-01
The partition coefficients, P(IL/w), for different probe molecules as well as for compounds of biological interest between the room-temperature ionic liquids (RTILs) 1-butyl-3-methylimidazolium hexafluorophosphate, [BMIM][PF(6)], 1-hexyl-3-methylimidazolium hexafluorophosphate, [HMIM][PF(6)], 1-octyl-3-methylimidazolium tetrafluoroborate, [OMIM][BF(4)] and water were accurately measured. [BMIM][PF(6)] and [OMIM][BF(4)] were synthesized by adapting a procedure from the literature to a simpler, single-vessel and faster methodology, with a much lesser consumption of organic solvent. We employed the solvation-parameter model to elucidate the general chemical interactions involved in RTIL/water partitioning. With this purpose, we have selected different solute descriptor parameters that measure polarity, polarizability, hydrogen-bond-donor and hydrogen-bond-acceptor interactions, and cavity formation for a set of specifically selected probe molecules (the training set). The obtained multiparametric equations were used to predict the partition coefficients for compounds not present in the training set (the test set), most being of biological interest. Partial solubility of the ionic liquid in water (and water into the ionic liquid) was taken into account to explain the obtained results. This fact has not been deeply considered up to date. Solute descriptors were obtained from the literature, when available, or else calculated through commercial software. An excellent agreement between calculated and experimental log P(IL/w) values was obtained, which demonstrated that the resulting multiparametric equations are robust and allow predicting partitioning for any organic molecule in the biphasic systems studied.
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Target Water Consumption Calculation for Human Water Management based on Water Balance
NASA Astrophysics Data System (ADS)
Sang, X.; Zhai, Z.; Ye, Y.; Zhai, J.
2016-12-01
Degradation of the regional ecological environment has become increasingly serious due to the rapid increase of water usage. Critical to water consumption management is a good approach to control the growth of water usage. Through the identification and analysis of water consumption for various sectors in the hydrosocial cycle, the method for calculating the regional target water consumption also is derived based on water balance theory. Analysis shows that during 1980 - 2004 in Tianjin City, there were 22 years in which the actual water consumption of Tianjin exceeded its target water consumption, with an average excess of 66 million m3 annually. Moreover, calculations show that the maximum human target water consumption water supply is 1.91 billion m3/a. If water consumption is controlled according to the target, the sustainable development of water resource, economic and social growth, and ecological environment in this region can be expected to be achieved.
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Water, ice, and meteorological measurements at South Cascade glacier, Washington, balance year 2003
Bidlake, William R.; Josberger, Edward G.; Savoca, Mark E.
2005-01-01
Winter snow accumulation and summer snow and ice ablation were measured at South Cascade Glacier, Washington, to estimate glacier mass-balance quantities for balance year 2003. The 2003 glacier-average maximum winter snow balance was 2.66 meters water equivalent, which was about equal to the average of such balances for the glacier since balance year 1959. The 2003 glacier summer balance (-4.76 meters water equivalent) was the most negative reported for the glacier, and the 2003 net balance (-2.10 meters water equivalent), was the second-most negative reported. The glacier 2003 annual (water year) balance was -1.89 meters water equivalent. The area of the glacier near the end of the balance year was 1.89 square kilometers, a decrease of 0.03 square kilometer from the previous year. The equilibrium-line altitude was higher than any part of the glacier; however, because snow remained along part of one side of the upper glacier, the accumulation-area ratio was 0.07. During September 13, 2002-September 13, 2003, the glacier terminus retreated at a rate of about 15 meters per year. Average speed of surface ice, computed using a series of vertical aerial photographs dating back to 2001, ranged from 2.2 to 21.8 meters per year. Runoff from the subbasin containing the glacier and from an adjacent non-glacierized basin was gaged during part of water year 2003. Air temperature, precipitation, atmospheric water-vapor pressure, wind speed, and incoming solar radiation were measured at selected locations on and near the glacier. Summer 2003 at the glacier was among the warmest for which data are available.
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NASA Astrophysics Data System (ADS)
Müller Schmied, Hannes; Döll, Petra
2017-04-01
The estimation of the World's water resources has a long tradition and numerous methods for quantification exists. The resulting numbers vary significantly, leaving room for improvement. Since some decades, global hydrological models (GHMs) are being used for large scale water budget assessments. GHMs are designed to represent the macro-scale hydrological processes and many of those models include human water management, e.g. irrigation or reservoir operation, making them currently the first choice for global scale assessments of the terrestrial water balance within the Anthropocene. The Water - Global Assessment and Prognosis (WaterGAP) is a model framework that comprises both the natural and human water dimension and is in development and application since the 1990s. In recent years, efforts were made to assess the sensitivity of water balance components to alternative climate forcing input data and, e.g., how this sensitivity is affected by WaterGAP's calibration scheme. This presentation shows the current best estimate of terrestrial water balance components as simulated with WaterGAP by 1) assessing global and continental water balance components for the climate period 1971-2000 and the IPCC reference period 1986-2005 for the most current WaterGAP version using a homogenized climate forcing data, 2) investigating variations of water balance components for a number of state-of-the-art climate forcing data and 3) discussing the benefit of the calibration approach for a better observation-data constrained global water budget. For the most current WaterGAP version 2.2b and a homogenized combination of the two WATCH Forcing Datasets, global scale (excluding Antarctica and Greenland) river discharge into oceans and inland sinks (Q) is assessed to be 40 000 km3 yr-1 for 1971-2000 and 39 200 km3 yr-1 for 1986-2005. Actual evapotranspiration (AET) is close to each other with around 70 600 (70 700) km3 yr-1 as well as water consumption with 1000 (1100) km3 yr-1. The
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DOE Office of Scientific and Technical Information (OSTI.GOV)
van Gestel, C.A.; Otermann, K.; Canton, J.H.
1985-12-01
A survey was made of the literature describing relations between water solubility (S), the octanol-water partition coefficient (Poct), and the bioconcentration factor (BCF) of organic chemicals. Based on the relations between BCF and Poct it can be concluded that mostly BCF is log BCF = 0.79 log Poct-0.40. From relations between Poct and S it can be concluded that for most organic chemicals log Poct will not exceed 3 if S is greater than ca. 3 mmol/liter. This limit is far more reliable than the value of 2000 mg/liter which has been proposed by OECD Experts and confirmed by othermore » authors.43 references.« less
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Storing and sharing water in sand rivers: a water balance modelling approach
NASA Astrophysics Data System (ADS)
Love, D.; van der Zaag, P.; Uhlenbrook, S.
2009-04-01
Sand rivers and sand dams offer an alternative to conventional surface water reservoirs for storage. The alluvial aquifers that make up the beds of sand rivers can store water with minimal evaporation (extinction depth is 0.9 m) and natural filtration. The alluvial aquifers of the Mzingwane Catchment are the most extensive of any tributaries in the Limpopo Basin. The lower Mzingwane aquifer, which is currently underutilised, is recharged by managed releases from Zhovhe Dam (capacity 133 Mm3). The volume of water released annually is only twice the size of evaporation losses from the dam; the latter representing nearly one third of the dam's storage capacity. The Lower Mzingwane valley currently support commercial agro-businesses (1,750 ha irrigation) and four smallholder irrigation schemes (400 ha with provision for a further 1,200 ha). In order to support planning for optimising water use and storage over evaporation and to provide for more equitable water allocation, the spreadsheet-based balance model WAFLEX was used. It is a simple and userfriendly model, ideal for use by institutions such as the water management authorities in Zimbabwe which are challenged by capacity shortfalls and inadequate data. In this study, WAFLEX, which is normally used for accounting the surface water balance, is adapted to incorporate alluvial aquifers into the water balance, including recharge, baseflow and groundwater flows. Results of the WAFLEX modelling suggest that there is surplus water in the lower Mzingwane system, and thus there should not be any water conflicts. Through more frequent timing of releases from the dam and maintaining the alluvial aquifers permanently saturated, less evaporation losses will occur in the system and the water resources can be better shared to provide more irrigation water for smallholder farmers in the highly resource-poor communal lands along the river. Sand dams are needed to augment the aquifer storage system and improve access to water. An
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Persona, Marek; Kutarov, Vladimir V; Kats, Boris M; Persona, Andrzej; Marczewska, Barbara
2007-01-01
The paper describes the new prediction method of octanol-water partition coefficient, which is based on molecular graph theory. The results obtained using the new method are well correlated with experimental values. These results were compared with the ones obtained by use of ten other structure correlated methods. The comparison shows that graph theory can be very useful in structure correlation research.
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Assessing the urban water balance: the Urban Water Flow Model and its application in Cyprus.
Charalambous, Katerina; Bruggeman, Adriana; Lange, Manfred A
2012-01-01
Modelling the urban water balance enables the understanding of the interactions of water within an urban area and allows for better management of water resources. However, few models today provide a comprehensive overview of all water sources and uses. The objective of the current paper was to develop a user-friendly tool that quantifies and visualizes all water flows, losses and inefficiencies in urban environments. The Urban Water Flow Model was implemented in a spreadsheet and includes a water-savings application that computes the contributions of user-selected saving options to the overall water balance. The model was applied to the coastal town of Limassol, Cyprus, for the hydrologic years 2003/04-2008/09. Data were collected from the different authorities and hydrologic equations and estimations were added to complete the balance. Average precipitation was 363 mm/yr, amounting to 25.4 × 10(6)m(3)/yr, more than double the annual potable water supply to the town. Surface runoff constituted 29.6% of all outflows, while evapotranspiration from impervious areas was 21.6%. Possible potable water savings for 2008/09 were estimated at 5.3 × 10(3) m(3), which is 50% of the total potable water provided to the area. This saving would also result in a 6% reduction of surface runoff.
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NASA Astrophysics Data System (ADS)
Bales, R.; Brookshire, D.; Brown, C.; Gupta, H.; Hogan, J.; Phillips, F.; Sorooshian, S.; Villinski, J.; Washburne, J.; Woodard, G.
2003-04-01
Water resources managers in the rapidly growing southwestern U.S. are increasingly addressing over-stressed rivers and aquifers as population and water demands grow. A current regional drought (1999-2002) has raised new concerns about how to sustain the combination of agricultural, urban and in-stream uses of water that underlie the socio-economic and ecological structure in the region. Sustainability implies that supply and demand balance through a basin, not just for the basin as a whole. The need to move water around a basin such as the Rio Grande or Colorado River to achieve this balance has created the stimulus for water transfers, and for accurate hydrologic information to sustain transfers. Key within-basin fluxes of water are poorly known, including: i) the amount and variability in time and space of precipitation and evapotranspiration/sublimation across the basin, ii) groundwater-surface water exchange, and iii) the partitioning of snowmelt and rain between runoff, infiltration, evapotranspiration and recharge. Given the strong physical linkages between these processes, and the physical-social and ecophysiological interactions that influence basin-scale water cycles, a research agenda with a high degree of integration was needed to address the critical knowledge gaps in these areas. Beginning in 1999, natural and social science researchers at several universities in the region began collaborative research to address these supply and demand issues in an integrated framework, under the Science and Technology Center for the Sustainability of semi-Arid Hydrology and Riparian Areas (SAHRA). Recent scientific advances are narrowing critical knowledge gaps, and providing a better quantitative understanding of water supply, water-demand and water-quality characteristics. Examples include: i) more accurate snowpack, rainfall and evapotranspiration estimates through improved and targeted remote-sensing and ground-based measurements, ii) the role of vegetation type
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Purification of biomaterials by phase partitioning
NASA Technical Reports Server (NTRS)
Harris, J. M.
1984-01-01
A technique which is particularly suited to microgravity environments and which is potentially more powerful than electrophoresis is phase partitioning. Phase partitioning is purification by partitioning between the two immiscible aqueous layers formed by solution of the polymers poly(ethylene glycol) and dextran in water. This technique proved to be very useful for separations in one-g but is limited for cells because the cells are more dense than the phase solutions thus tend to sediment to the bottom of the container before reaching equilibrium with the preferred phase. There are three phases to work in this area: synthesis of new polymers for affinity phase partitioning; development of automated apparatus for ground-based separations; and design of apparatus for performing simple phase partitioning space experiments, including examination of mechanisms for separating phases in the absence of gravity.
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NASA Astrophysics Data System (ADS)
Niemand, C.; Kuhn, K.; Schwarze, R.
2010-12-01
SHARP is a European INTERREG IVc Program. It focuses on the exchange of innovative technologies to protect groundwater resources for future generations by considering the climate change and the different geological and geographical conditions. Regions involved are Austria, United Kingdom, Poland, Italy, Macedonia, Malta, Greece and Germany. They will exchange practical know-how and also determine know-how demands concerning SHARP’s key contents: general groundwater management tools, artificial groundwater recharge technologies, groundwater monitoring systems, strategic use of groundwater resources for drinking water, irrigation and industry, techniques to save water quality and quantity, drinking water safety plans, risk management tools and water balance models. SHARP Outputs & results will influence the regional policy in the frame of sustainable groundwater management to save and improve the quality and quantity of groundwater reservoirs for future generations. The main focus of the Saxon State Office for Environment, Agriculture and Landscape in this project is the enhancement and purposive use of water balance models. Already since 1992 scientists compare different existing water balance models on different scales and coupled with groundwater models. For example in the KLIWEP (Assessment of Impacts of Climate Change Projections on Water and Matter Balance for the Catchment of River Parthe in Saxony) project the coupled model WaSiM-ETH - PCGEOFIM® has been used to study the impact of climate change on water balance and water supplies. The project KliWES (Assessment of the Impacts of Climate Change Projections on Water and Matter Balance for Catchment Areas in Saxony) still running, comprises studies of fundamental effects of climate change on catchments in Saxony. Project objective is to assess Saxon catchments according to the vulnerability of their water resources towards climate change projections in order to derive region-specific recommendations for
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The Refinement-Tree Partition for Parallel Solution of Partial Differential Equations.
Mitchell, William F
1998-01-01
Dynamic load balancing is considered in the context of adaptive multilevel methods for partial differential equations on distributed memory multiprocessors. An approach that periodically repartitions the grid is taken. The important properties of a partitioning algorithm are presented and discussed in this context. A partitioning algorithm based on the refinement tree of the adaptive grid is presented and analyzed in terms of these properties. Theoretical and numerical results are given.
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Load Balancing Unstructured Adaptive Grids for CFD Problems
NASA Technical Reports Server (NTRS)
Biswas, Rupak; Oliker, Leonid
1996-01-01
Mesh adaption is a powerful tool for efficient unstructured-grid computations but causes load imbalance among processors on a parallel machine. A dynamic load balancing method is presented that balances the workload across all processors with a global view. After each parallel tetrahedral mesh adaption, the method first determines if the new mesh is sufficiently unbalanced to warrant a repartitioning. If so, the adapted mesh is repartitioned, with new partitions assigned to processors so that the redistribution cost is minimized. The new partitions are accepted only if the remapping cost is compensated by the improved load balance. Results indicate that this strategy is effective for large-scale scientific computations on distributed-memory multiprocessors.
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Hydrogen incorporation and charge balance in natural zircon
NASA Astrophysics Data System (ADS)
De Hoog, J. C. M.; Lissenberg, C. J.; Brooker, R. A.; Hinton, R.; Trail, D.; Hellebrand, E.
2014-09-01
The water and trace element contents of natural igneous zircons were determined to constrain the mechanism of hydrogen incorporation. The low radiation-damage zircons were derived from Fe-Ti oxide gabbros from the Vema Fracture Zone (11°N, Mid-Atlantic Ridge). They contain up to 1212 ppmw H2O, 1.9 wt.% Y2O3 and 0.6 wt.% P2O5 and are generally strongly zoned. REE + Y are partially charge-balanced by P (Y, REE3+ + P5+ = Zr4+ + Si4+), but a large REE excess is present. On an atomic basis, this excess is closely approximated by the amount of H present in the zircons. We therefore conclude that H is incorporated by a charge-balance mechanism (H+ + REE3+ = Zr4+). This interpretation is consistent with FTIR data of the Vema zircons, which shows a strongly polarised main absorption band at ca. 3100 cm-1, similar to experimentally grown Lu-doped hydrous zircon. The size of this 3100 cm-1 band scales with H and REE contents. Apart from a small overlapping band at 3200 cm-1, no other absorption bands are visible, indicating that a hydrogrossular-type exchange mechanism does not appear to be operating in these zircons. Because of charge-balanced uptake of H, P and REE in zircon, the partitioning of these elements into zircon is dependent on each of their concentrations. For instance, DREEzrc/melt increases with increasing H and P contents of the melt, whereas DHzrc/melt increases with increasing REE content but decreases with increasing P content. In addition, H-P-REE systematics of sector zoning indicate kinetic effects may play an important role. Hence, using H in zircon to determine the water content of melts is problematic, and REE partitioning studies need to take into account P and H2O contents of the melt.
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NASA Astrophysics Data System (ADS)
Sivapalan, Murugesu; Ruprecht, John K.; Viney, Neil R.
1996-03-01
A long-term water balance model has been developed to predict the hydrological effects of land-use change (especially forest clearing) in small experimental catchments in the south-west of Western Australia. This small catchment model has been used as the building block for the development of a large catchment-scale model, and has also formed the basis for a coupled water and salt balance model, developed to predict the changes in stream salinity resulting from land-use and climate change. The application of the coupled salt and water balance model to predict stream salinities in two small experimental catchments, and the application of the large catchment-scale model to predict changes in water yield in a medium-sized catchment that is being mined for bauxite, are presented in Parts 2 and 3, respectively, of this series of papers.The small catchment model has been designed as a simple, robust, conceptually based model of the basic daily water balance fluxes in forested catchments. The responses of the catchment to rainfall and pan evaporation are conceptualized in terms of three interdependent subsurface stores A, B and F. Store A depicts a near-stream perched aquifer system; B represents a deeper, permanent groundwater system; and F is an intermediate, unsaturated infiltration store. The responses of these stores are characterized by a set of constitutive relations which involves a number of conceptual parameters. These parameters are estimated by calibration by comparing observed and predicted runoff. The model has performed very well in simulations carried out on Salmon and Wights, two small experimental catchments in the Collie River basin in south-west Western Australia. The results from the application of the model to these small catchments are presented in this paper.
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One-Step Quenching and Partitioning Heat Treatment of Medium Carbon Low Alloy Steel
NASA Astrophysics Data System (ADS)
Tariq, Fawad; Baloch, Rasheed Ahmed
2014-05-01
This paper presents the results of novel one-step quenching and partitioning (Q&P) heat treatment conducted on medium carbon low alloy steel sheet. Samples were austenitised at 1193 K followed by interrupted quenching at 473 K for different partitioning times and finally they were quenched in water. Dilatometry was employed for selection of treatment temperatures. Optical and scanning electron microscopy was carried out to examine the microstructural changes. Volume fraction of retained austenite was measured by x-ray diffraction technique. Resulting microstructures were correlated with the mechanical properties such hardness, tensile strength, elongation, impact absorbed energy, etc. The notch tensile and fracture toughness properties of Q&P steels are still lacking therefore notch tensile strength and plain strain fracture toughness tests were conducted and results are reported here. Results of Q&P treatments were also compared with the properties obtained by conventional Quenching and Tempering (Q&T) and normalizing treatments. Optimum strength-ductility balance of about 2000 MPa tensile strength with 11% elongation was achieved in samples quenched at 473 K and isothermally partitioned for 100 s. Higher ductility of Q&P steel was attributed to the presence of 6.8% film-type interlath retained austenite. Fine-grained martensitic structure with high density of interphase boundaries imparted ultrahigh strength. It was further noted that the impact toughness, notch tensile strength and fracture toughness of 1000 s partitioned samples was higher than 100 s partitioned samples. Possible reasons for high toughness are synergetic effect of recovery of dislocations, partial loss of martensite tetragonality and precipitation of fine transition carbides.
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ESTIMATING DISSOLVED ORGANIC CARBON PARTITION COEFFICIENTS FOR NONIONIC ORGANIC CHEMICALS
A literature search was performed for dissolved organic carbon/water partition coefficients for nonionic chemicals (Kdoc) and Kdoc data was taken from more than sixty references. The Kdoc data were evaluated as a function of the n-octanol/water partition coefficients (Kow). A pre...
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Hormonal Contraception, Body Water Balance and Thermoregulation
1997-10-01
Schreiber, and M. D. Lindheimer. Effect of ovarian sex steroids on osmoregulation and vasopressin secretion in the rat. Am. J. Physiol. 250 (Endocrinol...two widely used oral contraceptive preparations differ significantly in their estrogenicity. Estrogens have potent effects on the regulation of body...water balance (1, 4), so these two forms of oral contraceptive pills may differ in their effects on water regulation, and hence on physical performance
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Water and Energy Balances of Loblolly Pine Plantation Forests during a Full Stand Rotation
NASA Astrophysics Data System (ADS)
Sun, G.; Mitra, B.; Domec, J. C.; Gavazi, M.; Yang, Y.; Tian, S.; Zietlow, D.; McNulty, S.; King, J.; Noormets, A.
2017-12-01
partitioning of precipitation and solar energy in pine forests. In addition, we conclude that accessible groundwater was important factor for stabilizing forest water and energy balances during a drought in the lower coastal ecosystems.
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Román, Iván P; Mastromichali, Anna; Tyrovola, Konstantina; Canals, Antonio; Psillakis, Elefteria
2014-02-21
Vortex-assisted liquid-liquid microextraction (VALLME) coupled with high-performance liquid chromatography (HPLC) is proposed here for the rapid determination of octanol-water partitioning coefficients (Kow). VALLME uses vortex agitation, a mild emulsification procedure, to disperse microvolumes of octanol in the aqueous phase thus increasing the interfacial contact area and ensuring faster partitioning rates. With VALLME, 2min were enough to achieve equilibrium conditions between the octanolic and aqueous phases. Upon equilibration, separation was achieved using centrifugation and the octanolic microdrop was collected and analyzed in a HPLC system. Six model compounds with logKow values ranging between ∼0.5 and 3.5 were used during the present investigations. The proposed method produced logKow values that were consistent with previously published values and the recorded uncertainty was well within the acceptable log unit range. Overall, the key features of the proposed Kow determination procedure comprised speed, reliability, simplicity, low cost and minimal solvent consumption. Copyright © 2014 Elsevier B.V. All rights reserved.
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Impact of Water Recovery from Wastes on the Lunar Surface Mission Water Balance
NASA Technical Reports Server (NTRS)
Fisher, John W.; Hogan, John Andrew; Wignarajah, Kanapathipi; Pace, Gregory S.
2010-01-01
Future extended lunar surface missions will require extensive recovery of resources to reduce mission costs and enable self-sufficiency. Water is of particular importance due to its potential use for human consumption and hygiene, general cleaning, clothes washing, radiation shielding, cooling for extravehicular activity suits, and oxygen and hydrogen production. Various water sources are inherently present or are generated in lunar surface missions, and subject to recovery. They include: initial water stores, water contained in food, human and other solid wastes, wastewaters and associated brines, ISRU water, and scavenging from residual propellant in landers. This paper presents the results of an analysis of the contribution of water recovery from life support wastes on the overall water balance for lunar surface missions. Water in human wastes, metabolic activity and survival needs are well characterized and dependable figures are available. A detailed life support waste model was developed that summarizes the composition of life support wastes and their water content. Waste processing technologies were reviewed for their potential to recover that water. The recoverable water in waste is a significant contribution to the overall water balance. The value of this contribution is discussed in the context of the other major sources and loses of water. Combined with other analyses these results provide guidance for research and technology development and down-selection.
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Monitoring the water balance of Lake Victoria, East Africa, from space
NASA Astrophysics Data System (ADS)
Swenson, Sean; Wahr, John
2009-05-01
SummaryUsing satellite gravimetric and altimetric data, we examine trends in water storage and lake levels of multiple lakes in the Great Rift Valley region of East Africa for the years 2003-2008. GRACE total water storage estimates reveal that water storage declined in much of East Africa, by as much as 60 {mm}/{year}, while altimetric data show that lake levels in some large lakes dropped by as much as 1-2 m. The largest declines occurred in Lake Victoria, the Earth's second largest freshwater body. Because the discharge from the outlet of Lake Victoria is used to generate hydroelectric power, the role of human management in the lake's decline has been questioned. By comparing catchment water storage trends to lake level trends, we confirm that climatic forcing explains only about 50decline. This analysis provides an independent means of assessing the relative impacts of climate and human management on the water balance of Lake Victoria that does not depend on observations of dam discharge, which may not be publically available. In the second part of the study, the individual components of the lake water balance are estimated. Satellite estimates of changes in lake level, precipitation, and evaporation are used with observed lake discharge to develop a parameterization for estimating subsurface inflows due to changes in groundwater storage estimated from satellite gravimetry. At seasonal timescales, this approach provides closure to Lake Victoria's water balance to within 17 {mm}/{month}. The third part of this study uses the water balance of a downstream water body, Lake Kyoga, to estimate the outflow from Lake Victoria remotely. Because Lake Kyoga is roughly 20 times smaller in area than Lake Victoria, its water balance is strongly influenced by inflow from Lake Victoria. Lake Kyoga has been shown to act as a linear reservoir, where its outflow is proportional to the height of the lake. This model can be used with satellite altimetric lake levels to estimate a
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A TEN-YEAR WATER BALANCE OF A MOUNTAINOUS SEMI-ARID WATERSHED. (R824784)
Quantifying water balance components, which is particularly challenging in snow-fed, semi-arid regions, is crucial to understanding the basic hydrology of a watershed. In this study, a water balance was computed using 10 years of data collected at the Upper Sheep Creek Water...
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Octanol-water partition coefficients for predicting the effects of tannins in ruminant nutrition.
Mueller-Harvey, Irene; Mlambo, Victor; Sikosana, Joe L N; Smith, Tim; Owen, Emyr; Brown, Ron H
2007-07-11
Tannins can cause beneficial or harmful nutritional effects, but their great diversity has until now prevented a rational distinction between tannin structures and their nutritional responses. An attempt has been made to study this problem by examining the octanol-water solubilities of tannins. A relatively simple HPLC method has been developed for screening mixtures of plant tannins for their octanol-water partition coefficients (Kow coefficients). Tannins were isolated from the fruits and leaves of different Acacia, Calliandra, Dichrostachys, and Piliostigma species, which are known to produce beneficial or harmful effects. The Kow coefficients of these tannins ranged from 0.061 to 13.9, average coefficients of variation were 9.2% and recoveries were 107%. Acacia nilotica fruits and leaves had the highest Kow coefficients, that is, 2.0 and 13.9, respectively. These A. nilotica products also have high concentrations of tannins. The combined effects of high octanol solubilities and high tannin concentrations may explain their negative effects on animal nutrition and health. It is known that compounds with high octanol solubilities are more easily absorbed into tissues, and it is, therefore, proposed that such compounds are more likely to cause toxicity problems especially if consumed in large quantities. According to the literature, tannins in human foods tend to have low Kow coefficients, and this was confirmed for the tannins in Piliostigma thonningii fruits. Therefore, unconventional feeds or browse products should be screened not only for their tannin concentrations but also for low octanol-water partition coefficients in order to identify nutritionally safe feeds and to avoid potentially toxic feeds.
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Partitioning water and carbon fluxes in a Mediterranean oak woodland using stable oxygen isotopes
NASA Astrophysics Data System (ADS)
Dubbert, Maren; Piayda, Arndt; Cuntz, Matthias; Correia, Alexandra; Silva, Filipe Costa e.; Pereira, Joao; Werner, Christiane
2014-05-01
evaporation (Dubbert et al. 2013). Moreover, we found continuously strong deviations from isotopic steady-state in plant transpiration combined with large isoforcing on the atmosphere. This implies that assuming plant transpiration to be in the steady-state can have a huge impact at least for studies that distinguish relatively short time intervals (hours, e.g. partitioning studies). Finally. partitioning ecosystem ET and NEE into its three sources revealed a strong contribution of soil evaporation (E) and herbaceous transpiration (T) to ecosystem ET during spring and fall. In contrast, soil respiration (R) and herbaceous net carbon gain contributed to a lesser amount to ecosystem NEE during spring and fall, leading to consistently smaller water use efficiencies (WUE) of the herbaceous understory compared to the cork-oaks. Craig H, Gordon, LI. 1965. Deuterium and oxygen-18 variations in the ocean and the marine atmosphere. Paper presented at the Stable Isotopes in Oceanographic Studies and Paleotemperatures, Spoleto, Italy. Dubbert M, Cuntz M, Piayda A, Maguas C, Werner C, 2013: Partitioning evapotranspiration - Testing the Craig and Gordon model with field measurements of oxygen isotope ratios of evaporative fluxes. J Hydrol.
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Seasonal Water Balance Forecasts for Drought Early Warning in Ethiopia
NASA Astrophysics Data System (ADS)
Spirig, Christoph; Bhend, Jonas; Liniger, Mark
2016-04-01
Droughts severely impact Ethiopian agricultural production. Successful early warning for drought conditions in the upcoming harvest season therefore contributes to better managing food shortages arising from adverse climatic conditions. So far, however, meteorological seasonal forecasts have not been used in Ethiopia's national food security early warning system (i.e. the LEAP platform). Here we analyse the forecast quality of seasonal forecasts of total rainfall and of the meteorological water balance as a proxy for plant available water. We analyse forecast skill of June to September rainfall and water balance from dynamical seasonal forecast systems, the ECMWF System4 and EC-EARTH global forecasting systems. Rainfall forecasts outperform forecasts assuming a stationary climate mainly in north-eastern Ethiopia - an area that is particularly vulnerable to droughts. Forecasts of the water balance index seem to be even more skilful and thus more useful than pure rainfall forecasts. The results vary though for different lead times and skill measures employed. We further explore the potential added value of dynamically downscaling the forecasts through several dynamical regional climate models made available through the EU FP7 project EUPORIAS. Preliminary results suggest that dynamically downscaled seasonal forecasts are not significantly better compared with seasonal forecasts from the global models. We conclude that seasonal forecasts of a simple climate index such as the water balance have the potential to benefit drought early warning in Ethiopia, both due to its positive predictive skill and higher usefulness than seasonal mean quantities.
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The Refinement-Tree Partition for Parallel Solution of Partial Differential Equations
Mitchell, William F.
1998-01-01
Dynamic load balancing is considered in the context of adaptive multilevel methods for partial differential equations on distributed memory multiprocessors. An approach that periodically repartitions the grid is taken. The important properties of a partitioning algorithm are presented and discussed in this context. A partitioning algorithm based on the refinement tree of the adaptive grid is presented and analyzed in terms of these properties. Theoretical and numerical results are given. PMID:28009355
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The evolution of water balance in Glossina (Diptera: Glossinidae): correlations with climate.
Kleynhans, Elsje; Terblanche, John S
2009-02-23
The water balance of tsetse flies (Diptera: Glossinidae) has significant implications for understanding biogeography and climate change responses in these African disease vectors. Although moisture is important for tsetse population dynamics, evolutionary responses of Glossina water balance to climate have been relatively poorly explored and earlier studies may have been confounded by several factors. Here, using a physiological and GIS climate database, we investigate potential interspecific relationships between traits of water balance and climate. We do so in conventional and phylogenetically independent approaches for both adults and pupae. Results showed that water loss rates (WLR) were significantly positively related to precipitation in pupae even after phylogenetic adjustment. Adults showed no physiology-climate correlations. Ancestral trait reconstruction suggests that a reduction in WLR and increased size probably evolved from an intermediate ancestral state and may have facilitated survival in xeric environments. The results of this study therefore suggest an important role for water balance physiology of pupae in determining interspecific variation and lend support to conclusions reached by early studies of tsetse physiology.
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Climate, interseasonal storage of soil water, and the annual water balance
Milly, P.C.D.
1994-01-01
The effects of annual totals and seasonal variations of precipitation and potential evaporation on the annual water balance are explored. It is assumed that the only other factor of significance to annual water balance is a simple process of water storage, and that the relevant storage capacity is the plant-available water-holding capacity of the soil. Under the assumption that precipitation and potential evaporation vary sinusoidally through the year, it is possible to derive an analytic solution of the storage problem, and this yields an expression for the fraction of precipitation that evaporates (and the fraction that runs off) as a function of three dimensionless numbers: the ratio of annual potential evaporation to annual precipitation (index of dryness); an index of the seasonality of the difference between precipitation and potential evaporation; and the ratio of plant-available water-holding capacity to annual precipitation. The solution is applied to the area of the United States east of 105??W, using published information on precipitation, potential evaporation, and plant-available water-holding capacity as inputs, and using an independent analysis of observed river runoff for model evaluation. The model generates an areal mean annual runoff of only 187 mm, which is about 30% less than the observed runoff (263 mm). The discrepancy is suggestive of the importance of runoff-generating mechanisms neglected in the model. These include intraseasonal variability (storminess) of precipitation, spatial variability of storage capacity, and finite infiltration capacity of land. ?? 1994.
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30 CFR 816.42 - Hydrologic balance: Water quality standards and effluent limitations.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Hydrologic balance: Water quality standards and effluent limitations. 816.42 Section 816.42 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND... STANDARDS-SURFACE MINING ACTIVITIES § 816.42 Hydrologic balance: Water quality standards and effluent...
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30 CFR 817.42 - Hydrologic balance: Water quality standards and effluent limitations.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Hydrologic balance: Water quality standards and effluent limitations. 817.42 Section 817.42 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND... STANDARDS-UNDERGROUND MINING ACTIVITIES § 817.42 Hydrologic balance: Water quality standards and effluent...
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30 CFR 817.42 - Hydrologic balance: Water quality standards and effluent limitations.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Hydrologic balance: Water quality standards and effluent limitations. 817.42 Section 817.42 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND... STANDARDS-UNDERGROUND MINING ACTIVITIES § 817.42 Hydrologic balance: Water quality standards and effluent...
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30 CFR 816.42 - Hydrologic balance: Water quality standards and effluent limitations.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Hydrologic balance: Water quality standards and effluent limitations. 816.42 Section 816.42 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND... STANDARDS-SURFACE MINING ACTIVITIES § 816.42 Hydrologic balance: Water quality standards and effluent...
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Liang, Yuzhen; Xiong, Ruichang; Sandler, Stanley I; Di Toro, Dominic M
2017-09-05
Polyparameter Linear Free Energy Relationships (pp-LFERs), also called Linear Solvation Energy Relationships (LSERs), are used to predict many environmentally significant properties of chemicals. A method is presented for computing the necessary chemical parameters, the Abraham parameters (AP), used by many pp-LFERs. It employs quantum chemical calculations and uses only the chemical's molecular structure. The method computes the Abraham E parameter using density functional theory computed molecular polarizability and the Clausius-Mossotti equation relating the index refraction to the molecular polarizability, estimates the Abraham V as the COSMO calculated molecular volume, and computes the remaining AP S, A, and B jointly with a multiple linear regression using sixty-five solvent-water partition coefficients computed using the quantum mechanical COSMO-SAC solvation model. These solute parameters, referred to as Quantum Chemically estimated Abraham Parameters (QCAP), are further adjusted by fitting to experimentally based APs using QCAP parameters as the independent variables so that they are compatible with existing Abraham pp-LFERs. QCAP and adjusted QCAP for 1827 neutral chemicals are included. For 24 solvent-water systems including octanol-water, predicted log solvent-water partition coefficients using adjusted QCAP have the smallest root-mean-square errors (RMSEs, 0.314-0.602) compared to predictions made using APs estimated using the molecular fragment based method ABSOLV (0.45-0.716). For munition and munition-like compounds, adjusted QCAP has much lower RMSE (0.860) than does ABSOLV (4.45) which essentially fails for these compounds.
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Bidlake, William R.; Josberger, Edward G.; Savoca, Mark E.
2007-01-01
Winter snow accumulation and summer snow and ice ablation were measured at South Cascade Glacier, Washington, to estimate glacier mass-balance quantities for balance years 2004 and 2005. The North Cascade Range in the vicinity of South Cascade Glacier accumulated smaller than normal winter snowpacks during water years 2004 and 2005. Correspondingly, the balance years 2004 and 2005 maximum winter snow balances of South Cascade Glacier, 2.08 and 1.97 meters water equivalent, respectively, were smaller than the average of such balances since 1959. The 2004 glacier summer balance (-3.73 meters water equivalent) was the eleventh most negative during 1959 to 2005 and the 2005 glacier summer balance (-4.42 meters water equivalent) was the third most negative. The relatively small winter snow balances and unusually negative summer balances of 2004 and 2005 led to an overall loss of glacier mass. The 2004 and 2005 glacier net balances, -1.65 and -2.45 meters water equivalent, respectively, were the seventh and second most negative during 1953 to 2005. For both balance years, the accumulation area ratio was less than 0.05 and the equilibrium line altitude was higher than the glacier. The unusually negative 2004 and 2005 glacier net balances, combined with a negative balance previously reported for 2003, resulted in a cumulative 3-year net balance of -6.20 meters water equivalent. No equal or greater 3-year mass loss has occurred previously during the more than 4 decades of U.S. Geological Survey mass-balance measurements at South Cascade Glacier. Accompanying the glacier mass losses were retreat of the terminus and reduction of total glacier area. The terminus retreated at a rate of about 17 meters per year during balance year 2004 and 15 meters per year during balance year 2005. Glacier area near the end of balance years 2004 and 2005 was 1.82 and 1.75 square kilometers, respectively. Runoff from the basin containing the glacier and from an adjacent nonglacierized basin was
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NASA Astrophysics Data System (ADS)
Anderson, Ray; Skaggs, Todd; Alfieri, Joseph; Kustas, William; Wang, Dong; Ayars, James
2016-04-01
Partitioned land surfaces fluxes (e.g. evaporation, transpiration, photosynthesis, and ecosystem respiration) are needed as input, calibration, and validation data for numerous hydrological and land surface models. However, one of the most commonly used techniques for measuring land surface fluxes, Eddy Covariance (EC), can directly measure net, combined water and carbon fluxes (evapotranspiration and net ecosystem exchange/productivity). Analysis of the correlation structure of high frequency EC time series (hereafter flux partitioning or FP) has been proposed to directly partition net EC fluxes into their constituent components using leaf-level water use efficiency (WUE) data to separate stomatal and non-stomatal transport processes. FP has significant logistical and spatial representativeness advantages over other partitioning approaches (e.g. isotopic fluxes, sap flow, microlysimeters), but the performance of the FP algorithm is reliant on the accuracy of the intercellular CO2 (ci) concentration used to parameterize WUE for each flux averaging interval. In this study, we tested several parameterizations for ci as a function of atmospheric CO2 (ca), including (1) a constant ci/ca ratio for C3 and C4 photosynthetic pathway plants, (2) species-specific ci/ca-Vapor Pressure Deficit (VPD) relationships (quadratic and linear), and (3) generalized C3 and C4 photosynthetic pathway ci/ca-VPD relationships. We tested these ci parameterizations at three agricultural EC towers from 2011-present in C4 and C3 crops (sugarcane - Saccharum officinarum L. and peach - Prunus persica), and validated again sap-flow sensors installed at the peach site. The peach results show that the species-specific parameterizations driven FP algorithm came to convergence significantly more frequently (~20% more frequently) than the constant ci/ca ratio or generic C3-VPD relationship. The FP algorithm parameterizations with a generic VPD relationship also had slightly higher transpiration (5 Wm-2
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Effect of low sea water temperature on water balance in the Atlantic salmon, (Salmo salar L.).
Lega, Y V; Chernitsky, A G; Belkovsky, N M
1992-08-01
The water balance in Atlantic salmon (Salmo salar L.) overwintering in sea water (34 ‰) was investigated. With a decrease of temperature from 5.6 to 1.0°C the drinking rate decreased from 13.9 to 5.7 ml/kg/day, and the absolute amount of water absorbed decreased from 8.9 to 5.0 ml/kg/day. A decrease in temperature led, however, to an increase in the proportion of water absorbed in the intestines from 60 to 96%. Blood serum osmolarity increased from 320 to 440 mosm/1 with decreasing temperature and there was a reduction in tissue water content from 75 to 69% The disturbance of water balance at low temperature may be one of the factors responsible for mortality of salmon overwintering in sea water.
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Pfeifer, O; Lohmann, U; Ballschmiter, K
2001-11-01
Halogenated methyl-phenyl ethers (methoxybenzenes, anisoles) are ubiquitous organics in the environment although they are not produced in industrial quantities. Modelling the fate of organic pollutants such as halogenated anisoles requires a knowledge of the fundamental physico-chemical properties of these compounds. The isomer-specific separation and detection of 60 of the 134 possible congeners allowing an environmental fingerprinting are reported in this study. The vapor pressure p0(L) of more than 60 and further physico-chemical properties of 26 available congeners are given. Vapor pressures p0(L), water solubilities S(L)W, and n-octanol/water partition coefficients Kow were determined by capillary HR-GC (High Resolution Gas Chromatography) on a non-polar phase and by RP-HPLC (Reversed Phase High Performance Liquid Chromatography) on a C18 phase with chlorobenzenes as reference standards. From these experimental data the Henry's law constants H, and the gas/water Kgw and gas/n-octanol Kgo partition coefficients were calculated. We found that vapor pressures, water solubilities, and n-octanol/water partition coefficients of the halogenated anisoles are close to those of the chlorobenzenes. A similar environmental fate of both groups can, therefore, be predicted.
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Student Misconceptions in Writing Balanced Equations for Dissolving Ionic Compounds in Water
ERIC Educational Resources Information Center
Naah, Basil M.; Sanger, Michael J.
2012-01-01
The goal of this study was to identify student misconceptions and difficulties in writing symbolic-level balanced equations for dissolving ionic compounds in water. A sample of 105 college students were asked to provide balanced equations for dissolving four ionic compounds in water. Another 37 college students participated in semi-structured…
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ERIC Educational Resources Information Center
Ewert, Alan
Outdoor leaders constantly face problems created by water shortage and, to act effectively, must thoroughly understand the body's use of water and the ways to delay dehydration when water shortage occurs. Dehydration begins when there is a negative water balance, or more water lost than ingested, and progresses from the stage of dryness, to the…
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Using Electrolyte Free Water Balance to Rationalize and Treat Dysnatremias.
Shah, Sanjeev R; Bhave, Gautam
2018-01-01
Dysnatremias or abnormalities in plasma [Na + ] are often termed disorders of water balance, an unclear physiologic concept often confused with changes in total fluid balance. However, most clinicians clearly recognize that hypertonic or hypotonic gains or losses alter plasma [Na + ], while isotonic changes do not modify plasma [Na + ]. This concept can be conceptualized as the electrolyte free water balance (EFWB), which defines the non-isotonic components of inputs and outputs to determine their effect on plasma [Na + ]. EFWB is mathematically proportional to the rate of change in plasma [Na + ] (dP Na /dt) and, therefore, is actively regulated to zero so that plasma [Na + ] remains stable at its homeostatic set point. Dysnatremias are, therefore, disorders of EFWB and the relationship between EFWB and dP Na /dt provides a rationale for therapeutic strategies incorporating mass and volume balance. Herein, we leverage dP Na /dt as a desired rate of correction of plasma [Na + ] to define a stepwise approach for the treatment of dysnatremias.
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Using Electrolyte Free Water Balance to Rationalize and Treat Dysnatremias
Shah, Sanjeev R.; Bhave, Gautam
2018-01-01
Dysnatremias or abnormalities in plasma [Na+] are often termed disorders of water balance, an unclear physiologic concept often confused with changes in total fluid balance. However, most clinicians clearly recognize that hypertonic or hypotonic gains or losses alter plasma [Na+], while isotonic changes do not modify plasma [Na+]. This concept can be conceptualized as the electrolyte free water balance (EFWB), which defines the non-isotonic components of inputs and outputs to determine their effect on plasma [Na+]. EFWB is mathematically proportional to the rate of change in plasma [Na+] (dPNa/dt) and, therefore, is actively regulated to zero so that plasma [Na+] remains stable at its homeostatic set point. Dysnatremias are, therefore, disorders of EFWB and the relationship between EFWB and dPNa/dt provides a rationale for therapeutic strategies incorporating mass and volume balance. Herein, we leverage dPNa/dt as a desired rate of correction of plasma [Na+] to define a stepwise approach for the treatment of dysnatremias. PMID:29740578
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Fluorescent solute-partitioning characterization of layered soft contact lenses.
Dursch, T J; Liu, D E; Oh, Y; Radke, C J
2015-03-01
Partitioning of aqueous packaging, wetting, and care-solution agents into and out of soft contact lenses (SCLs) is important for improving wear comfort and also for characterizing lens physico-chemical properties. We illustrate both features of partitioning by application of fluorescent-solute partitioning into DAILIES TOTAL1® (delefilcon A) water-gradient SCLs, which exhibit a layered structure of a silicone-hydrogel (SiHy) core sandwiched between thin surface-gel layers. Two-photon fluorescence confocal laser-scanning microscopy and attenuated total-reflectance Fourier-transform infrared spectroscopy (ATR-FTIR) characterize the lens and assess uptake profiles of six prototypical fluorescent solutes. Comparison of solute uptake in a SiHy-core prototype lens (i.e., O2OPTIX(TM)) validates the core SiHy structure of DAILIESTOTAL1®. To establish surface-layer charge, partition coefficients and water contents are obtained for aqueous pH values of 4 and 7.4. Solute fluorescence-intensity profiles clearly confirm a layered structure for the DAILIES TOTAL1® lenses. In all cases, aqueous solute partition coefficients are greater in the surface layers than in the SiHy core, signifying higher water in the surface gels. ATR-FTIR confirms surface-layer mass water contents of 82±3%. Water uptake and hydrophilic-solute uptake at pH 4 compared with that at pH 7.4 reveal that the surface-gel layers are anionic at physiologic pH 7.4, whereas both the SiHy core and O2OPTIX™ (lotrafilcon B) are nonionic. We successfully confirm the layered structure of DAILIES TOTAL1®, consisting of an 80-μm-thick SiHy core surrounded by 10-μm-thick polyelectrolyte surface-gel layers of significantly greater water content and aqueous solute uptake compared with the core. Accordingly, fluorescent-solute partitioning in SCLs provides information on gel structure and composition, in addition to quantifying uptake and release amounts and rates. Copyright © 2014 Acta Materialia Inc. Published by
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Event Water Balance and Recharge at the Panola Mountain Research Watershed, Georgia, U.S.A.
NASA Astrophysics Data System (ADS)
Riley, J. W.; Aulenbach, B. T.
2016-12-01
Investigating catchment storage and runoff pathways allows a better mechanistic understanding of stream flow generation processes. This information can be used to elucidate processes such as those influencing baseflow that support human consumption and ecological needs. Here we describe storm runoff water budgets from 483 rain events to determine the conditions under which precipitation infiltrates to deeper storage that supports baseflow. Further, we examine the storage and recharge behavior of different storm characteristics and antecedent conditions. We use a simple water budget approach to achieve this in which Deep Recharge = (Precipitation) - (Storm Runoff) - (Event Change in Soil Storage). Hydrograph separation was used to determine the storm periods and split storm runoff into baseflow and quickflow. Quickflow was assumed to account for the event water lost to the stream. Data from volumetric water content sensors were used to calculate the soil profile water storage and the change in water storage over the course of an event. The remaining water after these two components was assumed to represent water available for deeper recharge. The median event quickflow:precipitation ratio was 11.8%. Event soil moisture recharge in the top one meter of soil accounted for a median of 65.3% of precipitation. Quickflow and shallow soil moisture recharge accounted for a median of 77.1% of the precipitation delivered to the watershed. Water budgets indicated that 43% of the events provided water for deeper recharge. Of these events, however, only 28% provided 50 mm or more of deep recharge. Because the focus was on events, when humidity was high and the vapor pressure deficit (VPD) was low, we ignored the role of evapotranspiration. However, interception, which was not accounted for, would have resulted in less storm precipitation than was measured at the watershed rain gage. Furthermore, transpiration may have altered the post-storm water balance when VPD increased and
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Seasonal energy and evapotranspiration partitioning in a desert vineyard
USDA-ARS?s Scientific Manuscript database
The challenge of partitioning energy and evapotranspiration (ET) components was addressed over a season (bud break till harvest) in a wine grape vineyard located in an extreme arid region. A below canopy energy balance approach was applied to continuously estimate evaporation from the soil (E) while...
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Surface Mass Balance of the Columbia Glacier, Alaska, 1978 and 2010 Balance Years
O'Neel, Shad
2012-01-01
Although Columbia Glacier is one of the largest sources of glacier mass loss in Alaska, surface mass balance measurements are sparse, with only a single data set available from 1978. The dearth of surface mass-balance data prohibits partitioning of the total mass losses between dynamics and surface forcing; however, the accurate inclusion of calving glaciers into predictive models requires both dynamic and climatic forcing of total mass balance. During 2010, the U.S. Geological Survey collected surface balance data at several locations distributed over the surface of Columbia Glacier to estimate the glacier-wide annual balance for balance year 2010 using the 2007 area-altitude distribution. This report also summarizes data collected in 1978, calculates the 1978 annual surface balance, and uses these observations to constrain the 2010 values, particularly the shape of the balance profile. Both years exhibit balances indicative of near-equilibrium surface mass-balance conditions, and demonstrate the importance of dynamic processes during the rapid retreat.
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An Evaluation Tool for CONUS-Scale Estimates of Components of the Water Balance
NASA Astrophysics Data System (ADS)
Saxe, S.; Hay, L.; Farmer, W. H.; Markstrom, S. L.; Kiang, J. E.
2016-12-01
Numerous research groups are independently developing data products to represent various components of the water balance (e.g. runoff, evapotranspiration, recharge, snow water equivalent, soil moisture, and climate) at the scale of the conterminous United States. These data products are derived from a range of sources, including direct measurement, remotely-sensed measurement, and statistical and deterministic model simulations. An evaluation tool is needed to compare these data products and the components of the water balance they contain in order to identify the gaps in the understanding and representation of continental-scale hydrologic processes. An ideal tool will be an objective, universally agreed upon, framework to address questions related to closing the water balance. This type of generic, model agnostic evaluation tool would facilitate collaboration amongst different hydrologic research groups and improve modeling capabilities with respect to continental-scale water resources. By adopting a comprehensive framework to consider hydrologic modeling in the context of a complete water balance, it is possible to identify weaknesses in process modeling, data product representation and regional hydrologic variation. As part of its National Water Census initiative, the U.S. Geological survey is facilitating this dialogue to developing prototype evaluation tools.
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Paranahewage, S Shanaka; Gierhart, Cassidy S; Fennell, Christopher J
2016-11-01
Alchemical transformation of solutes using classical fixed-charge force fields is a popular strategy for assessing the free energy of transfer in different environments. Accurate estimations of transfer between phases with significantly different polarities can be difficult because of the static nature of the force fields. Here, we report on an application of such calculations in the SAMPL5 experiment that also involves an effort in balancing solute and solvent interactions via their expected static dielectric constants. This strategy performs well with respect to predictive accuracy and correlation with unknown experimental values. We follow this by performing a series of retrospective investigations which highlight the potential importance of proper balancing in these systems, and we use a null hypothesis analysis to explore potential biases in the comparisons with experiment. The collective findings indicate that considerations of force field compatibility through dielectric behavior is a potential strategy for future improvements in transfer processes between disparate environments.
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NASA Astrophysics Data System (ADS)
Zhou, Sha; Yu, Bofu; Zhang, Yao; Huang, Yuefei; Wang, Guangqian
2017-04-01
Evapotranspiration (ET) is dominated by transpiration (T) in the terrestrial water cycle. However, continuous measurement of transpiration is still difficult, and the effect of vegetation on ET partitioning is unclear. The concept of underlying water use efficiency (uWUE) was used to develop a new method for ET partitioning by assuming that the maximum, or the potential uWUE is related to T while the averaged or apparent uWUE is related to ET. T/ET was thus estimated as the ratio of the apparent over the potential uWUE using half-hourly flux data from 17 AmeriFlux sites. The estimated potential uWUE was shown to be essentially constant for the 14 sites with a single vegetation type, and was broadly consistent with the uWUE evaluated at the leaf scale. The annual T/ET was the highest for croplands, i.e., 0.69 for corn and 0.62 for soybean, followed by grasslands (0.60) and evergreen needle leaf forests (0.56), and was the lowest for deciduous broadleaf forests (0.52). The enhanced vegetation index (EVI) was shown to be significantly correlated with T/ET and could explain about 75% of the variation in T/ET among the 71 site-years. The coefficients of determination between EVI and T/ET were 0.84 and 0.82 for corn and soybean, respectively, and 0.77 for deciduous broadleaf forests and grasslands, but only 0.37 for evergreen needle leaf forests. This ET partitioning method is sound in principle and simple to apply in practice, and would enhance the value and role of global FLUXNET in estimating T/ET variations and monitoring ecosystem dynamics.
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Bischoff, James L.; Israde-Alcántara, Isabel; Garduno-Monroy, Victor H.; Shanks, Wayne C.
2004-01-01
Lake Pa??tzcuaro, the center of the ancient Tarascan civilization located in the Mexican altiplano west of the city of Morelia, has neither river input nor outflow. The relatively constant lake-salinity over the past centuries indicates the lake is in chemical steady state. Springs of the south shore constitute the primary visible input to the lake, so influx and discharge must be via sub-lacustrine ground water. The authors report on the chemistry and stable isotope composition of the springs, deeming them representative of ground-water input. The springs are dominated by Ca, Mg and Na, whereas the lake is dominated by Na. Combining these results with previously published precipitation/rainfall measurements on the lake, the authors calculate the chemical evolution from spring water to lake water, and also calculate a salt balance of the ground-water-lake system. Comparing Cl and ??18O compositions in the springs and lake water indicates that 75-80% of the spring water is lost evaporatively during evolution toward lake composition. During evaporation Ca and Mg are lost from the water by carbonate precipitation. Each liter of spring water discharging into the lake precipitates about 18.7 mg of CaCO3. Salt balance calculations indicate that ground water input to the lake is 85.9??106 m3/a and ground water discharge from the lake is 23.0??106 m3/a. Thus, the discharge is about 27% of the input, with the rest balanced by evaporation. A calculation of time to reach steady-state ab initio indicates that the Cl concentration of the present day lake would be reached in about 150 a. ?? 2004 Elsevier Ltd. All rights reserved.
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Water and solute balances as a basis for sustainable irrigation agriculture
NASA Astrophysics Data System (ADS)
Pla-Sentís, Ildefonso
2015-04-01
The growing development of irrigated agriculture is necessary for the sustainable production of the food required by the increasing World's population. Such development is limited by the increasing scarcity and low quality of the available water resources and by the competitive use of the water for other purposes. There are also increasing problems of contamination of surface and ground waters to be used for other purposes by the drainage effluents of irrigated lands. Irrigation and drainage may cause drastic changes in the regime and balance of water and solutes (salts, sodium, contaminants) in the soil profile, resulting in problems of water supply to crops and problems of salinization, sodification and contamination of soils and ground waters. This is affected by climate, crops, soils, ground water depth, irrigation and groundwater composition, and by irrigation and drainage management. In order to predict and prevent such problems for a sustainable irrigated agriculture and increased efficiency in water use, under each particular set of conditions, there have to be considered both the hydrological, physical and chemical processes determining such water and solute balances in the soil profile. In this contribution there are proposed the new versions of two modeling approaches (SOMORE and SALSODIMAR) to predict those balances and to guide irrigation water use and management, integrating the different factors involved in such processes. Examples of their application under Mediterranean and tropical climate conditions are also presented.
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NASA Astrophysics Data System (ADS)
Chen, Yiying; Ryder, James; Naudts, Kim; McGrath, Matthew J.; Otto, Juliane; Bastriko, Vladislav; Valade, Aude; Launiainen, Samuli; Ogée, Jérôme; Elbers, Jan A.; Foken, Thomas; Tiedemann, Frank; Heinesch, Bernard; Black, Andrew; Haverd, Vanessa; Loustau, Denis; Ottlé, Catherine; Peylin, Philippe; Polcher, Jan; Luyssaert, Sebastiaan
2015-04-01
Canopy structure is one of the most important vegetation characteristics for land-atmosphere interactions as it determines the energy and scalar exchanges between land surface and overlay air mass. In this study we evaluated the performance of a newly developed multi-layer energy budget (Ryder et al., 2014) in a land surface model, ORCHIDEE-CAN (Naudts et al., 2014), which simulates canopy structure and can be coupled to an atmospheric model using an implicit procedure. Furthermore, a vertical discrete drag parametrization scheme was also incorporated into this model, in order to obtain a better description of the sub-canopy wind profile simulation. Site level datasets, including the top-of-the-canopy and sub-canopy observations made available from eight flux observation sites, were collected in order to conduct this evaluation. The geo-location of the collected observation sites crossed climate zones from temperate to boreal and the vegetation types included deciduous, evergreen broad leaved and evergreen needle leaved forest with maximum LAI ranging from 2.1 to 7.0. First, we used long-term top-of-the-canopy measurements to analyze the performance of the current one-layer energy budget in ORCHIDEE-CAN. Three major processes were identified for improvement through the implementation of a multi-layer energy budget: 1) night time radiation balance, 2) energy partitioning during winter and 3) prediction of the ground heat flux. Short-term sub-canopy observations were used to calibrate the parameters in sub-canopy radiation, turbulence and resistances modules with an automatic tuning process following the maximum gradient of the user-defined objective function. The multi-layer model is able to capture the dynamic of sub-canopy turbulence, temperature and energy fluxes with imposed LAI profile and optimized parameter set at a site level calibration. The simulation result shows the improvement both on the nighttime energy balance and energy partitioning during winter
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Partitioning of Nanoparticles into Organic Phases and Model Cells
DOE Office of Scientific and Technical Information (OSTI.GOV)
Posner, J.D.; Westerhoff, P.; Hou, W-C.
2011-08-25
There is a recognized need to understand and predict the fate, transport and bioavailability of engineered nanoparticles (ENPs) in aquatic and soil ecosystems. Recent research focuses on either collection of empirical data (e.g., removal of a specific NP through water or soil matrices under variable experimental conditions) or precise NP characterization (e.g. size, degree of aggregation, morphology, zeta potential, purity, surface chemistry, and stability). However, it is almost impossible to transition from these precise measurements to models suitable to assess the NP behavior in the environment with complex and heterogeneous matrices. For decades, the USEPA has developed and applies basicmore » partitioning parameters (e.g., octanol-water partition coefficients) and models (e.g., EPI Suite, ECOSAR) to predict the environmental fate, bioavailability, and toxicity of organic pollutants (e.g., pesticides, hydrocarbons, etc.). In this project we have investigated the hypothesis that NP partition coefficients between water and organic phases (octanol or lipid bilayer) is highly dependent on their physiochemical properties, aggregation, and presence of natural constituents in aquatic environments (salts, natural organic matter), which may impact their partitioning into biological matrices (bioaccumulation) and human exposure (bioavailability) as well as the eventual usage in modeling the fate and bioavailability of ENPs. In this report, we use the terminology "partitioning" to operationally define the fraction of ENPs distributed among different phases. The mechanisms leading to this partitioning probably involve both chemical force interactions (hydrophobic association, hydrogen bonding, ligand exchange, etc.) and physical forces that bring the ENPs in close contact with the phase interfaces (diffusion, electrostatic interactions, mixing turbulence, etc.). Our work focuses on partitioning, but also provides insight into the relative behavior of ENPs as either
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SWB-A modified Thornthwaite-Mather Soil-Water-Balance code for estimating groundwater recharge
Westenbroek, S.M.; Kelson, V.A.; Dripps, W.R.; Hunt, R.J.; Bradbury, K.R.
2010-01-01
A Soil-Water-Balance (SWB) computer code has been developed to calculate spatial and temporal variations in groundwater recharge. The SWB model calculates recharge by use of commonly available geographic information system (GIS) data layers in combination with tabular climatological data. The code is based on a modified Thornthwaite-Mather soil-water-balance approach, with components of the soil-water balance calculated at a daily timestep. Recharge calculations are made on a rectangular grid of computational elements that may be easily imported into a regional groundwater-flow model. Recharge estimates calculated by the code may be output as daily, monthly, or annual values.
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NASA Astrophysics Data System (ADS)
Brooks, Paul D.; Chorover, Jon; Fan, Ying; Godsey, Sarah E.; Maxwell, Reed M.; McNamara, James P.; Tague, Christina
2015-09-01
Hydrology is an integrative discipline linking the broad array of water-related research with physical, ecological, and social sciences. The increasing breadth of hydrological research, often where subdisciplines of hydrology partner with related sciences, reflects the central importance of water to environmental science, while highlighting the fractured nature of the discipline itself. This lack of coordination among hydrologic subdisciplines has hindered the development of hydrologic theory and integrated models capable of predicting hydrologic partitioning across time and space. The recent development of the concept of the critical zone (CZ), an open system extending from the top of the canopy to the base of groundwater, brings together multiple hydrological subdisciplines with related physical and ecological sciences. Observations obtained by CZ researchers provide a diverse range of complementary process and structural data to evaluate both conceptual and numerical models. Consequently, a cross-site focus on "critical zone hydrology" has potential to advance the discipline of hydrology and to facilitate the transition of CZ observatories into a research network with immediate societal relevance. Here we review recent work in catchment hydrology and hydrochemistry, hydrogeology, and ecohydrology that highlights a common knowledge gap in how precipitation is partitioned in the critical zone: "how is the amount, routing, and residence time of water in the subsurface related to the biogeophysical structure of the CZ?" Addressing this question will require coordination among hydrologic subdisciplines and interfacing sciences, and catalyze rapid progress in understanding current CZ structure and predicting how climate and land cover changes will affect hydrologic partitioning.
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Optimization of water balance within the martian crew life support system
NASA Astrophysics Data System (ADS)
Sychev, V.; Levinskikh, M.
The present-day scenarios of the first exploration mission differ in the total length crew size period of the stay on Mars etc However no matter the scenario one of the common problems is optimization of water balance within the crew life support system Water balance optimization implies in addition to regeneration of atmospheric moisture and urine also dehydration of biowastes In this mission all wastes will be stored and for this reason safe storage is prerequisite Investigations of two-component laboratory BLSS in which the autotrophic component was composed of algae Spirulina platensis and the heterotrophic component was represented by Japanese quail Coturnix coturnix japonica dom showed that optimization of the autotrophic and heterotrophic gas exchange and water regeneration from quail biowastes could raise the system susbstance balance to 76 of the total balance during autonomic cultivation of algae and birds In these investigations dehydration of quail biowastes caused significant pollution of water and air by organics toxic for humans It was demonstrated that the sorption technologies applied on the Russian space station MIR and ISS cannot fully absorb organic contaminants released in the process of quail wastes drying Algal suspension as a hydrobiological filter was able to control the organic pollination of both air and water These results are in agreement with the data of ground-based simulation studies with participation of human subjects at IBMP According to the simulation data intensive
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Water balance of a lake with floodplain buffering: Lake Tana, Blue Nile Basin, Ethiopia
NASA Astrophysics Data System (ADS)
Dessie, Mekete; Verhoest, Niko E. C.; Pauwels, Valentijn R. N.; Adgo, Enyew; Deckers, Jozef; Poesen, Jean; Nyssen, Jan
2015-03-01
Lakes are very important components of the earth's hydrological cycle, providing a variety of services for humans and ecosystem functioning. For a sustainable use of lakes, a substantial body of knowledge on their water balance is vital. We present here a detailed daily water balance analysis for Lake Tana, the largest lake in Ethiopia and the source of the Blue Nile. Rainfall on the lake is determined by Thiessen polygon procedure, open water evaporation is estimated by the Penman-combination equation and observed inflows for the gauged catchments as well as outflow data at the two lake outlets are directly used. Runoff from ungauged catchments is estimated using a simple rainfall-runoff model and runoff coefficients. Hillslope catchments and floodplains are treated separately, which makes this study unique compared to previous water balance studies. Impact of the floodplain on the lake water balance is analyzed by conducting scenario-based studies. We found an average yearly abstraction of 420 × 106 m3 or 6% of river inflows to the lake by the floodplain in 2012 and 2013. Nearly 60% of the inflow to the lake is from the Gilgel Abay River. Simulated lake levels compare well with the observed lake levels (R2 = 0.95) and the water balance can be closed with a closure error of 82 mm/year (3.5% of the total lake inflow). This study demonstrates the importance of floodplains and their influence on the water balance of the lake and the need of incorporating the effects of floodplains and water abstraction for irrigation to improve predictions.
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Reppas-Chrysovitsinos, Efstathios; Sobek, Anna; MacLeod, Matthew
2016-06-15
Polymeric materials flowing through the technosphere are repositories of organic chemicals throughout their life cycle. Equilibrium partition ratios of organic chemicals between these materials and air (KMA) or water (KMW) are required for models of fate and transport, high-throughput exposure assessment and passive sampling. KMA and KMW have been measured for a growing number of chemical/material combinations, but significant data gaps still exist. We assembled a database of 363 KMA and 910 KMW measurements for 446 individual compounds and nearly 40 individual polymers and biopolymers, collected from 29 studies. We used the EPI Suite and ABSOLV software packages to estimate physicochemical properties of the compounds and we employed an empirical correlation based on Trouton's rule to adjust the measured KMA and KMW values to a standard reference temperature of 298 K. Then, we used a thermodynamic triangle with Henry's law constant to calculate a complete set of 1273 KMA and KMW values. Using simple linear regression, we developed a suite of single parameter linear free energy relationship (spLFER) models to estimate KMA from the EPI Suite-estimated octanol-air partition ratio (KOA) and KMW from the EPI Suite-estimated octanol-water (KOW) partition ratio. Similarly, using multiple linear regression, we developed a set of polyparameter linear free energy relationship (ppLFER) models to estimate KMA and KMW from ABSOLV-estimated Abraham solvation parameters. We explored the two LFER approaches to investigate (1) their performance in estimating partition ratios, and (2) uncertainties associated with treating all different polymers as a single "bulk" polymeric material compartment. The models we have developed are suitable for screening assessments of the tendency for organic chemicals to be emitted from materials, and for use in multimedia models of the fate of organic chemicals in the indoor environment. In screening applications we recommend that KMA and KMW be
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Evaluating the spatial distribution of water balance in a small watershed, Pennsylvania
NASA Astrophysics Data System (ADS)
Yu, Zhongbo; Gburek, W. J.; Schwartz, F. W.
2000-04-01
A conceptual water-balance model was modified from a point application to be distributed for evaluating the spatial distribution of watershed water balance based on daily precipitation, temperature and other hydrological parameters. The model was calibrated by comparing simulated daily variation in soil moisture with field observed data and results of another model that simulates the vertical soil moisture flow by numerically solving Richards' equation. The impacts of soil and land use on the hydrological components of the water balance, such as evapotranspiration, soil moisture deficit, runoff and subsurface drainage, were evaluated with the calibrated model in this study. Given the same meteorological conditions and land use, the soil moisture deficit, evapotranspiration and surface runoff increase, and subsurface drainage decreases, as the available water capacity of soil increases. Among various land uses, alfalfa produced high soil moisture deficit and evapotranspiration and lower surface runoff and subsurface drainage, whereas soybeans produced an opposite trend. The simulated distribution of various hydrological components shows the combined effect of soil and land use. Simulated hydrological components compare well with observed data. The study demonstrated that the distributed water balance approach is efficient and has advantages over the use of single average value of hydrological variables and the application at a single point in the traditional practice.
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Feller, Chrystel; Favre, Patrick; Janka, Ales; Zeeman, Samuel C; Gabriel, Jean-Pierre; Reinhardt, Didier
2015-01-01
Plants are highly plastic in their potential to adapt to changing environmental conditions. For example, they can selectively promote the relative growth of the root and the shoot in response to limiting supply of mineral nutrients and light, respectively, a phenomenon that is referred to as balanced growth or functional equilibrium. To gain insight into the regulatory network that controls this phenomenon, we took a systems biology approach that combines experimental work with mathematical modeling. We developed a mathematical model representing the activities of the root (nutrient and water uptake) and the shoot (photosynthesis), and their interactions through the exchange of the substrates sugar and phosphate (Pi). The model has been calibrated and validated with two independent experimental data sets obtained with Petunia hybrida. It involves a realistic environment with a day-and-night cycle, which necessitated the introduction of a transitory carbohydrate storage pool and an endogenous clock for coordination of metabolism with the environment. Our main goal was to grasp the dynamic adaptation of shoot:root ratio as a result of changes in light and Pi supply. The results of our study are in agreement with balanced growth hypothesis, suggesting that plants maintain a functional equilibrium between shoot and root activity based on differential growth of these two compartments. Furthermore, our results indicate that resource partitioning can be understood as the emergent property of many local physiological processes in the shoot and the root without explicit partitioning functions. Based on its encouraging predictive power, the model will be further developed as a tool to analyze resource partitioning in shoot and root crops.
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Feller, Chrystel; Favre, Patrick; Janka, Ales; Zeeman, Samuel C.; Gabriel, Jean-Pierre; Reinhardt, Didier
2015-01-01
Plants are highly plastic in their potential to adapt to changing environmental conditions. For example, they can selectively promote the relative growth of the root and the shoot in response to limiting supply of mineral nutrients and light, respectively, a phenomenon that is referred to as balanced growth or functional equilibrium. To gain insight into the regulatory network that controls this phenomenon, we took a systems biology approach that combines experimental work with mathematical modeling. We developed a mathematical model representing the activities of the root (nutrient and water uptake) and the shoot (photosynthesis), and their interactions through the exchange of the substrates sugar and phosphate (Pi). The model has been calibrated and validated with two independent experimental data sets obtained with Petunia hybrida. It involves a realistic environment with a day-and-night cycle, which necessitated the introduction of a transitory carbohydrate storage pool and an endogenous clock for coordination of metabolism with the environment. Our main goal was to grasp the dynamic adaptation of shoot:root ratio as a result of changes in light and Pi supply. The results of our study are in agreement with balanced growth hypothesis, suggesting that plants maintain a functional equilibrium between shoot and root activity based on differential growth of these two compartments. Furthermore, our results indicate that resource partitioning can be understood as the emergent property of many local physiological processes in the shoot and the root without explicit partitioning functions. Based on its encouraging predictive power, the model will be further developed as a tool to analyze resource partitioning in shoot and root crops. PMID:26154262
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Partition characteristics of polycyclic aromatic hydrocarbons on soils and sediments
Chiou, C.T.; Mcgroddy, S.E.; Kile, D.E.
1998-01-01
The partition behavior was determined for three polycyclic aromatic hydrocarbons (PAHs), i.e., naphthalene, phenanthrene, and pyrene, from water to a range of soil and sediment samples. The measured partition coefficients of the individual PAHs between soil/sediment organic matter (SOM) and water (i.e., K(oc) values) are relatively invariant either for the 'clean' (uncontaminated) soils or for the clean sediments; however, the mean K(oc) values on the sediments are about twice the values on the soils. This disparity is similar to the earlier observation for other nonpolar solutes and reflects the compositional differences between soil and sediment organic matters. No significant differences in K(oc) are observed between a clean coastal marine sediment and freshwater sediments. The coastal sediments that are significantly impacted by organic contaminants exhibit higher K(oc) values. At given K(ow) values (octanol-water), the PAHs exhibit much higher K(oc) values than other relatively nonpolar solutes (e.g., chlorinated hydrocarbons). This effect is shown to result from the enhanced partition of PAHs to SOM rather than from lower K(ow) values of PAHs at given supercooled liquid solute solubilities in water. The enhanced partition of PAHs over other nonpolar solutes in SOM provides an account of the markedly different correlations between log K(oc) and log K(ow) for PAHs and for other nonpolar solutes. The improved partition of PAHs in SOM stems apparently from the enhanced compatibility of their cohesive energy densities with those of the aromatic components in SOM. The approximate aromatic fraction in soil/sediment organic matter has been assessed by solid-state 13C-NMR spectroscopy.The partition behavior was determined for three polycyclic aromatic hydrocarbons (PAHs), i.e., naphthalene, phenanthrene, and pyrene, from water to a range of soil and sediment samples. The measured partition coefficients of the individual PAHs between soil/sediment organic matter (SOM
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NASA Astrophysics Data System (ADS)
Schwerdtfeger, J.; Johnson, M. S.; Weiler, M.; Couto, E. G.
2009-12-01
The Pantanal is the largest and most pristine wetland of the world, yet hydrological research there is still in its infancy. In particular the water balance of the millions of lakes and ponds and their interaction with the groundwater and the rivers are not known. The aim of this study was to assess the hydrological behaviour between different water bodies in the dry season of the northern Pantanal wetland, Brazil, to provide a more general understanding of the hydrological functioning of tropical floodplain lakes and surface water-groundwater interactions of wetlands. In the field 6-9 water sample of seven different lakes were taken during 3 months and were analyzed for stable water isotopes and chloride. In addition meteorological data from a nearby station was used to estimate daily evaporation from the water surface. This information was then used to predict the hydrological dynamics to determine whether the lakes are evaporation-controlled or throughflow-dominated systems. A chloride mass balance served to evaluate whether Cl- enrichment took place due to evaporation only, or whether the system has significant inflow and/or outflow rates. The results of those methods showed that for all lakes the water budget in the dry season, output was controlled by strong evaporation while significant inflow rates were also apparent. Inflow rates and their specific concentrations in stable isotopes and chloride were successfully estimated using the simple mass balance model MINA TrêS. This approach enabled us to calculate the water balance for the lakes as well as providing an information on source water flowing into the lakes.
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Yu, S; Gao, S; Gan, Y; Zhang, Y; Ruan, X; Wang, Y; Yang, L; Shi, J
2016-04-01
Quantitative structure-property relationship modelling can be a valuable alternative method to replace or reduce experimental testing. In particular, some endpoints such as octanol-water (KOW) and organic carbon-water (KOC) partition coefficients of polychlorinated biphenyls (PCBs) are easier to predict and various models have been already developed. In this paper, two different methods, which are multiple linear regression based on the descriptors generated using Dragon software and hologram quantitative structure-activity relationships, were employed to predict suspended particulate matter (SPM) derived log KOC and generator column, shake flask and slow stirring method derived log KOW values of 209 PCBs. The predictive ability of the derived models was validated using a test set. The performances of all these models were compared with EPI Suite™ software. The results indicated that the proposed models were robust and satisfactory, and could provide feasible and promising tools for the rapid assessment of the SPM derived log KOC and generator column, shake flask and slow stirring method derived log KOW values of PCBs.
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Analysis of Different Cost Functions in the Geosect Airspace Partitioning Tool
NASA Technical Reports Server (NTRS)
Wong, Gregory L.
2010-01-01
A new cost function representing air traffic controller workload is implemented in the Geosect airspace partitioning tool. Geosect currently uses a combination of aircraft count and dwell time to select optimal airspace partitions that balance controller workload. This is referred to as the aircraft count/dwell time hybrid cost function. The new cost function is based on Simplified Dynamic Density, a measure of different aspects of air traffic controller workload. Three sectorizations are compared. These are the current sectorization, Geosect's sectorization based on the aircraft count/dwell time hybrid cost function, and Geosect s sectorization based on the Simplified Dynamic Density cost function. Each sectorization is evaluated for maximum and average workload along with workload balance using the Simplified Dynamic Density as the workload measure. In addition, the Airspace Concept Evaluation System, a nationwide air traffic simulator, is used to determine the capacity and delay incurred by each sectorization. The sectorization resulting from the Simplified Dynamic Density cost function had a lower maximum workload measure than the other sectorizations, and the sectorization based on the combination of aircraft count and dwell time did a better job of balancing workload and balancing capacity. However, the current sectorization had the lowest average workload, highest sector capacity, and the least system delay.
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Wright, Christian D; Jackson, Marin L; DeNardo, Dale F
2013-04-15
Many xeric organisms maintain water balance by relying on dietary and metabolic water rather than free water, even when free water may be available. For such organisms, hydric state may influence foraging decisions, since meal consumption is meeting both energy and water demands. To understand foraging decisions it is vital to understand the role of dietary water in maintaining water balance. We investigated whether meal consumption was sufficient to maintain water balance in captive Gila monsters (Heloderma suspectum) at varying levels of dehydration. Gila monsters could not maintain water balance over long time scales through meal consumption alone. Animals fed a single meal took no longer to dehydrate than controls when both groups were deprived of free water. Additionally, meal consumption imparts an acute short-term hydric cost regardless of hydration state. Meal consumption typically resulted in a significant elevation in osmolality at 6 h post-feeding, and plasma osmolality never fell below pre-feeding levels despite high water content (~70%) of meals. These results failed to support our hypothesis that dietary water is valuable to Gila monsters during seasonal drought. When considered in conjunction with previous research, these results demonstrate that Gila monsters, unlike many xeric species, are heavily reliant on seasonal rainfall and the resulting free-standing water to maintain water balance.
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Octanol/water partition coefficient (logP) and aqueous solubility (logS) are two important parameters in pharmacology and toxicology studies, and experimental measurements are usually time-consuming and expensive. In the present research, novel methods are presented for the estim...
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Habitat assortment of sexes and water balance in a dioecious grass.
Fox, J F; Harrison, A Tyrone
1981-05-01
For a dioecious plant species in which males are associated with more xeric habitats and females with more mesic ones, (a) the xeric-mesic habitat difference was confirmed by measuring plant water potential, (b) and males and females had similar water balances and seemed to have no different adaptations to drought. There are slight differences in water potential between the sexes of dioecious plant species, but water balance can be more favorable in either the male or the female. On this account, we reject the "disruptive selection" hypothesis of Freeman et al. (1975) as an explanation for habitat assortment of sexes in dioecious plants. Alternative explanations, based upon parental determination of offspring sex ratios, or environmentally determined sex change, seem more likely.
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NASA Astrophysics Data System (ADS)
Barker, J. Burdette
Spatially informed irrigation management may improve the optimal use of water resources. Sub-field scale water balance modeling and measurement were studied in the context of irrigation management. A spatial remote-sensing-based evapotranspiration and soil water balance model was modified and validated for use in real-time irrigation management. The modeled ET compared well with eddy covariance data from eastern Nebraska. Placement and quantity of sub-field scale soil water content measurement locations was also studied. Variance reduction factor and temporal stability were used to analyze soil water content data from an eastern Nebraska field. No consistent predictor of soil water temporal stability patterns was identified. At least three monitoring locations were needed per irrigation management zone to adequately quantify the mean soil water content. The remote-sensing-based water balance model was used to manage irrigation in a field experiment. The research included an eastern Nebraska field in 2015 and 2016 and a western Nebraska field in 2016 for a total of 210 plot-years. The response of maize and soybean to irrigation using variations of the model were compared with responses from treatments using soil water content measurement and a rainfed treatment. The remote-sensing-based treatment prescribed more irrigation than the other treatments in all cases. Excessive modeled soil evaporation and insufficient drainage times were suspected causes of the model drift. Modifying evaporation and drainage reduced modeled soil water depletion error. None of the included response variables were significantly different between treatments in western Nebraska. In eastern Nebraska, treatment differences for maize and soybean included evapotranspiration and a combined variable including evapotranspiration and deep percolation. Both variables were greatest for the remote-sensing model when differences were found to be statistically significant. Differences in maize yield in
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NASA Astrophysics Data System (ADS)
Garatuza-Payan, J.; Yepez, E. A.; Watts, C.; Rodriguez, J. C.; Valdez-Torres, L. C.; Robles-Morua, A.
2013-05-01
Water security, can be defined as the reliable supply in quantity and quality of water to help sustain future populations and maintaining ecosystem health and productivity. Water security is rapidly declining in many parts of the world due to population growth, drought, climate change, salinity, pollution, land use change, over-allocation and over-utilization, among other issues. Governmental offices (such as the Comision Nacional del Agua in Mexico, CONAGUA) require and conduct studies to estimate reliable water balances at regional or continental scales in order to provide reasonable assessments of the amount of water that can be provided (from surface or ground water sources) to supply all the human needs while maintaining natural vegetation, on an operational basis and, more important, under disturbances, such as droughts. Large scale estimates of evapotranspiration (ET), a critical component of the water cycle, are needed for a better comprehension of the hydrological cycle at large scales, which, in most water balances is left as the residual. For operational purposes, such water balance estimates can not rely on ET measurements since they do not exist, should be simple and require the least ground information possible, information that is often scarce or does not exist at all. Given this limitation, the use of remotely sensed data to estimate ET could supplement the lack of ground information, particularly in remote regions In this study, a simple method, based on the Makkink equation is used to estimate ET for large areas at high spatial resolutions (1 km). The Makkink model used here is forced using three remotely sensed datasets. First, the model uses solar radiation estimates obtained from the Geostationary Operational Environmental Satellite (GOES); Second, the model uses an Enhanced Vegetation Index (EVI) obtained from the Moderate-resolution Imaging Spectroradiometer (MODIS) normalized to get an estimate for vegetation amount and land use which was
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Improved parallel data partitioning by nested dissection with applications to information retrieval.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wolf, Michael M.; Chevalier, Cedric; Boman, Erik Gunnar
The computational work in many information retrieval and analysis algorithms is based on sparse linear algebra. Sparse matrix-vector multiplication is a common kernel in many of these computations. Thus, an important related combinatorial problem in parallel computing is how to distribute the matrix and the vectors among processors so as to minimize the communication cost. We focus on minimizing the total communication volume while keeping the computation balanced across processes. In [1], the first two authors presented a new 2D partitioning method, the nested dissection partitioning algorithm. In this paper, we improve on that algorithm and show that it ismore » a good option for data partitioning in information retrieval. We also show partitioning time can be substantially reduced by using the SCOTCH software, and quality improves in some cases, too.« less
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A water balance model to estimate flow through the Old and Middle River corridor
Andrews, Stephen W.; Gross, Edward S.; Hutton, Paul H.
2016-01-01
We applied a water balance model to predict tidally averaged (subtidal) flows through the Old River and Middle River corridor in the Sacramento–San Joaquin Delta. We reviewed the dynamics that govern subtidal flows and water levels and adopted a simplified representation. In this water balance approach, we estimated ungaged flows as linear functions of known (or specified) flows. We assumed that subtidal storage within the control volume varies because of fortnightly variation in subtidal water level, Delta inflow, and barometric pressure. The water balance model effectively predicts subtidal flows and approaches the accuracy of a 1–D Delta hydrodynamic model. We explore the potential to improve the approach by representing more complex dynamics and identify possible future improvements.
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A Water Balance Approach to Characterizing the Hydroclimatology of a Mountainous Semi-arid Catchment
NASA Astrophysics Data System (ADS)
Chauvin, G.; Flerchinger, G.; Marks, D.; Link, T.
2004-12-01
A long-term water balance is needed to understand the hydrology of mountainous semi-arid catchments, which exhibit considerable interannual variability in precipitation and temperature as well as spatial variation in snow accumulation, soils, and vegetation. Long-term data sets reduce the uncertainty associated with estimating water balance quantities that are difficult to measure in practice. In this study, the data required to compute a long-term water balance are assembled from on-site and nearby locations to create a continuous 21-year hourly record of precipitation, meteorological parameters, and streamflow for the Upper Sheep Creek (USC) catchment, a 26 ha, snow-fed, semi-arid rangeland headwater drainage within the Reynolds Creek Experimental Watershed in southwestern Idaho, USA. This study will allow us to extend a previous 10-year water balance (water years 1985-1994) computed for the USC catchment, enabling a more thorough consideration of climate variability including periods of drought and flood. It also sets the stage for analyzing the hydrologic response of the USC catchment to a prescribed fire planned for 2006. Statistical correlations between on-site and nearby meteorological stations were used to develop a complete 21-year hourly data set (water years 1984-2004) of climate and precipitation records. These data will be used to drive the Simultaneous Heat and Water (SHAW) model to simulate evaporation and transpiration, precipitation, storage, and stream discharge. Water balance quantities will be computed for separate landscape units and then aggregated for the overall watershed. This research will improve our ability to manage water resources in semi-arid mountain regions.
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Estimating basin scale evapotranspiration (ET) by water balance and remote sensing methods
Senay, G.B.; Leake, S.; Nagler, P.L.; Artan, G.; Dickinson, J.; Cordova, J.T.; Glenn, E.P.
2011-01-01
Evapotranspiration (ET) is an important hydrological process that can be studied and estimated at multiple spatial scales ranging from a leaf to a river basin. We present a review of methods in estimating basin scale ET and its applications in understanding basin water balance dynamics. The review focuses on two aspects of ET: (i) how the basin scale water balance approach is used to estimate ET; and (ii) how ‘direct’ measurement and modelling approaches are used to estimate basin scale ET. Obviously, the basin water balance-based ET requires the availability of good precipitation and discharge data to calculate ET as a residual on longer time scales (annual) where net storage changes are assumed to be negligible. ET estimated from such a basin water balance principle is generally used for validating the performance of ET models. On the other hand, many of the direct estimation methods involve the use of remotely sensed data to estimate spatially explicit ET and use basin-wide averaging to estimate basin scale ET. The direct methods can be grouped into soil moisture balance modelling, satellite-based vegetation index methods, and methods based on satellite land surface temperature measurements that convert potential ET into actual ET using a proportionality relationship. The review also includes the use of complementary ET estimation principles for large area applications. The review identifies the need to compare and evaluate the different ET approaches using standard data sets in basins covering different hydro-climatic regions of the world.
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Partitioning evapotranspiration using long-term carbon dioxide and water vapor fluxes
NASA Astrophysics Data System (ADS)
Scott, Russell L.; Biederman, Joel A.
2017-07-01
The separate components of evapotranspiration (ET) elucidate the pathways and time scales over which water is returned to the atmosphere, but ecosystem-scale measurements of transpiration (
T ) and evaporation (E ) remain elusive. We propose a novel determination ofE andT using multiyear eddy covariance estimates of ET and gross ecosystem photosynthesis (GEP). The method is applicable at water-limited sites over time periods during which a linear regression between GEP (abscissa) and ET (ordinate) yields a positive ET axis intercept, an estimate ofE . At four summer-rainfall semiarid sites,T /ET increases to a peak coincident with maximum GEP and remains elevated as the growing season progresses, consistent with previous, direct measurements. The seasonal course ofT /ET is related to increasing leaf area index and declining frequency of rainy days—an index of the wet surface conditions that promoteE —suggesting both surface and climatic controls on ET partitioning. -
Water, ice, and meteorological measurements at South Cascade Glacier, Washington, balance year 2002
Bidlake, William R.; Josberger, Edward G.; Savoca, Mark E.
2004-01-01
Winter snow accumulation and summer snow and ice ablation were measured at South Cascade Glacier, Washington, to estimate glacier mass balance quantities for balance year 2002. The 2002 glacier-average maximum winter snow balance was 4.02 meters, the second largest since 1959. The 2002 glacier summer, net, and annual (water year) balances were -3.47, 0.55, and 0.54 meters, respectively. The area of the glacier near the end of the balance year was 1.92 square kilometers, and the equilibrium-line altitude and the accumulation area ratio were 1,820 meters and 0.84, respectively. During September 20, 2001 to September 13, 2002, the terminus retreated 4 meters, and computed average ice speeds in the ablation area ranged from 7.8 to 20.7 meters per year. Runoff from the subbasin containing the glacier and from an adjacent non-glacierized basin were measured during part of the 2002 water year. Air temperature, precipitation, atmospheric water-vapor pressure, wind speed and incoming solar radiation were measured at selected locations near the glacier.
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Effects of Water-Based Training on Static and Dynamic Balance of Older Women.
Bento, Paulo Cesar Barauce; Lopes, Maria de Fátima A; Cebolla, Elaine Cristine; Wolf, Renata; Rodacki, André L F
2015-08-01
The aim of this study was to evaluate the effects of a water-based exercise program on static and dynamic balance. Thirty-six older women were randomly assigned to a water-based training (3 days/week for 12 weeks) or control group. Water level was kept at the level of the xiphoid process and temperature at ∼28-30°C. Each session included aerobic activities and lower limb strength exercises. The medial-lateral, the anterior-posterior amplitude, and displacement of the center of pressure (CP-D) were measured in a quiet standing position (60 sec eyes opened and closed). The dynamic balance and 8-Foot Up-and-Go tests were also applied. Group comparisons were made using two-way analysis of variance (ANOVA) with repeated measures. No differences were found in the center of pressure variables; however, the WBT group showed better performance in the 8 Foot Up-and-Go Test after training (5.61±0.76 vs. 5.18±0.42; p<0.01). The water-based training was effective in improving dynamic balance, but not static balance.
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Partition thermodynamics of ionic surfactants between phosphatidylcholine vesicle and water phases
NASA Astrophysics Data System (ADS)
Chu, Shin-Chi; Hung, Chia-Hui; Wang, Shun-Cheng; Tsao, Heng-Kwong
2003-08-01
The partition of ionic surfactants (sodium alkyl sulfate and alkyl trimethyl ammonium bromide) between phosphatidylcholine vesicles and aqueous phase is investigated by simple conductometry under different temperatures. The experimental results can be well represented by the proposed regular solution theory and the thermodynamic parameters satisfy the thermodynamic consistency. The deviation from ideal partition is manifested through the effective interaction energy between lipid and surfactant wb, which is O(kT) large. It is found that wb rises as the alkyl chain is decreased for a specified head group. This is attributed to significant mismatch of chain lengths between surfactant and lipid molecules. The partition coefficient K declines with increasing temperature. The energy barrier from bilayer to aqueous phase, Δμ/kT∝ln K, is in the range of 16-26 kJ/mol. As the alkyl chain length is decreased for a given head group, Δμ is lowered by 1.3-1.5 kJ/mol per methylene group. Two independent analyses are employed to confirm this result. Using the thermodynamic parameters determined from experiments, the internal energy, entropy, and free energy of the partition process can be derived. Partition is essentially driven by the internal energy gain. The solubilizing ability, which is represented by the maximum surfactant-lipid ratio in the bilayer, Reb also decreases in accord with the K parameter. It is because the change in temperature influences the surfactant incorporation into the bilayer more than the formation of micelles.
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Meta-Analysis of Mass Balances Examining Chemical Fate during Wastewater Treatment
2008-01-01
Mass balances are an instructive means for investigating the fate of chemicals during wastewater treatment. In addition to the aqueous-phase removal efficiency (Φ), they can inform on chemical partitioning, transformation, and persistence, as well as on the chemical loading to streams and soils receiving, respectively, treated effluent and digested sewage sludge (biosolids). Release rates computed on a per-capita basis can serve to extrapolate findings to a larger scale. This review examines over a dozen mass balances conducted for various organic wastewater contaminants, including prescription drugs, estrogens, fragrances, antimicrobials, and surfactants of differing sorption potential (hydrophobicity), here expressed as the 1-octanol−water partition coefficient (KOW) and the organic carbon normalized sorption coefficient (KOC). Major challenges to mass balances are the collection of representative samples and accurate quantification of chemicals in sludge. A meta-analysis of peer-reviewed data identified sorption potential as the principal determinant governing chemical persistence in biosolids. Occurrence data for organic wastewater compounds detected in digested sludge followed a simple nonlinear model that required only KOW or KOC as the input and yielded a correlation coefficient of 0.9 in both instances. The model predicted persistence in biosolids for the majority (>50%) of the input load of organic wastewater compounds featuring a log10KOW value of greater than 5.2 (log10KOC > 4.4). In contrast, hydrophobicity had no or only limited value for estimating, respectively, Φ and the overall persistence of a chemical during conventional wastewater treatment. PMID:18800497
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Partitioning behavior of aromatic components in jet fuel into diverse membrane-coated fibers.
Baynes, Ronald E; Xia, Xin-Rui; Barlow, Beth M; Riviere, Jim E
2007-11-01
Jet fuel components are known to partition into skin and produce occupational irritant contact dermatitis (OICD) and potentially adverse systemic effects. The purpose of this study was to determine how jet fuel components partition (1) from solvent mixtures into diverse membrane-coated fibers (MCFs) and (2) from biological media into MCFs to predict tissue distribution. Three diverse MCFs, polydimethylsiloxane (PDMS, lipophilic), polyacrylate (PA, polarizable), and carbowax (CAR, polar), were selected to simulate the physicochemical properties of skin in vivo. Following an appropriate equilibrium time between the MCF and dosing solutions, the MCF was injected directly into a gas chromatograph/mass spectrometer (GC-MS) to quantify the amount that partitioned into the membrane. Three vehicles (water, 50% ethanol-water, and albumin-containing media solution) were studied for selected jet fuel components. The more hydrophobic the component, the greater was the partitioning into the membranes across all MCF types, especially from water. The presence of ethanol as a surrogate solvent resulted in significantly reduced partitioning into the MCFs with discernible differences across the three fibers based on their chemistries. The presence of a plasma substitute (media) also reduced partitioning into the MCF, with the CAR MCF system being better correlated to the predicted partitioning of aromatic components into skin. This study demonstrated that a single or multiple set of MCF fibers may be used as a surrogate for octanol/water systems and skin to assess partitioning behavior of nine aromatic components frequently formulated with jet fuels. These diverse inert fibers were able to assess solute partitioning from a blood substitute such as media into a membrane possessing physicochemical properties similar to human skin. This information may be incorporated into physiologically based pharmacokinetic (PBPK) models to provide a more accurate assessment of tissue dosimetry of
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The role of natural solidification paths on REE partitioning between clinopyroxene and melt
NASA Astrophysics Data System (ADS)
Scarlato, P.; Mollo, S.; Blundy, J. D.; Iezzi, G.; Tiepolo, M.
2014-03-01
We document for the first time the role played by natural solidification paths on the partitioning of rare earth elements (REE) between clinopyroxene and melt. To do this, we investigated the compositional variation of clinopyroxenes formed under increasing cooling rate conditions from core to rim of a dike at Mt. Etna volcano. As the rate of cooling increases, clinopyroxenes are progressively depleted in Si + Ca + Mg counter-balanced by enrichments in Al + Na + Ti. Consequently, the concentration of REE in clinopyroxene increases due to an increased ease of locally balancing the excess charge at the M2 site as the number of surrounding tetrahedral aluminium atoms increases. Since Aliv in clinopyroxene is a charge-balancing cation for REE, the partition coefficients (DREE) measured at the dike chilled margin are distinctly higher than those from the dike interior. We conclude that, in naturally solidifying magmas, kinetically controlled cation substitution reactions can be treated in terms of the energetics of the various charge-imbalanced configurations. This finding is corroborated by the near-parabolic dependence of DREE on cation radius due to charge-balance mechanisms described by the lattice strain model.
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NASA Astrophysics Data System (ADS)
Wang, L.; Good, S. P.; Caylor, K. K.
2010-12-01
Characterizing the constituent components of evapotranspiration is crucial to better understand ecosystem-level water budgets and water use dynamics. Isotope based evapotranspiration partitioning methods are promising but their utility lies in the accurate estimation of the isotopic composition of underlying transpiration and evaporation. Here we report a new method to quantify the isotopic signature of leaf transpiration under field conditions. This method utilizes a commercially available laser-based isotope analyzer and a transparent leaf chamber, modified from Licor conifer leaf chamber. The method is based on the water mass balance in ambient air and leaf transpired air. We verified the method using “artificial leaves” and glassline extracted samples. The method provides a new and direct way to estimate leaf transpiration isotopic signatures and it has wide applications in ecology, hydrology and plant physiology.
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Water balance of pine forests: Synthesis of new and published results
Pantana Tor-ngern; Ram Oren; Sari Palmroth; Kimberly Novick; Andrew Oishi; Sune Linder; Mikaell Ottosson-Lofvenius; Torgny Nasholm
2018-01-01
The forest hydrologic cycle is expected to have important feedback responses to climate change, impacting processes ranging from local water supply and primary productivity to global water and energy cycles. Here, we analyzed water budgets of pine forests worldwide. We first estimated local water balance of forests dominated by two wide-ranging species:Â Pinus...
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A review of approaches for evapotranspiration partitioning
USDA-ARS?s Scientific Manuscript database
Partitioning of evapotranspiration (ET) into evaporation from the soil surface (E) and transpiration (T) is challenging but important in order to assess biomass production and the allocation of increasingly scarce water resources. Generally T is the desired component with the water being used to enh...
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Simulation of Boreal Ecosystem Carbon and Water Budgets: Scaling from Local to Regional Extents
NASA Technical Reports Server (NTRS)
Wood, Eric F.
1997-01-01
A coupled water and energy balance model is developed. This model can predict the partitioning of water and energy between major source, sink and storage elements within the Boreal-Ecosystem-Atmospheric Study (BOREAS) areas. The results of testing the model against data collected at BOREAS tower sites during Intensive Field Campaigns and remotely sensed data collected across the BOREAS region are presented.
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Sensible heat balance measurements of soil water evaporation beneath a maize canopy
USDA-ARS?s Scientific Manuscript database
Soil water evaporation is an important component of the water budget in a cropped field. Few methods are available for continuous and independent measurement of soil water evaporation. A sensible heat balance (SHB) approach has recently been demonstrated for continuously determining soil water evapo...
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We investigated polychlorinated biphenyl (PCB) bioaccumulation relative to octanol-water partition coefficient (KOW) and organism tropic position (TP) at the Lake Hartwell Superfund site (South Carolina, USA). We measured PCBs (127 congeners) and stable isotopes (δ
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R.A. Payn; M.N. Gooseff; B.L. McGlynn; K.E. Bencala; S.M. Wondzell
2009-01-01
Channel water balances of contiguous reaches along streams represent a poorly understood scale of stream-subsurface interaction. We measured reach water balances along a headwater stream in Montana, United States, during summer base flow recessions. Reach water balances were estimated from series of tracer tests in 13 consecutive reaches delineated evenly along a 2.6-...
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Dupoué, Andréaz; Rutschmann, Alexis; Le Galliard, Jean François; Miles, Donald B; Clobert, Jean; DeNardo, Dale F; Brusch, George A; Meylan, Sandrine
2017-12-01
Water conservation strategies are well documented in species living in water-limited environments, but physiological adaptations to water availability in temperate climate environments are still relatively overlooked. Yet, temperate species are facing more frequent and intense droughts as a result of climate change. Here, we examined variation in field hydration state (plasma osmolality) and standardized evaporative water loss rate (SEWL) of adult male and pregnant female common lizards (Zootoca vivipara) from 13 natural populations with contrasting air temperature, air humidity, and access to water. We found different patterns of geographic variation between sexes. Overall, males were more dehydrated (i.e. higher osmolality) than pregnant females, which likely comes from differences in field behaviour and water intake since the rate of SEWL was similar between sexes. Plasma osmolality and SEWL rate were positively correlated with environmental temperature in males, while plasma osmolality in pregnant females did not correlate with environmental conditions, reproductive stage or reproductive effort. The SEWL rate was significantly lower in populations without access to free standing water, suggesting that lizards can adapt or adjust physiology to cope with habitat dryness. Environmental humidity did not explain variation in water balance. We suggest that geographic variation in water balance physiology and behaviour should be taken account to better understand species range limits and sensitivity to climate change.
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Equilibrium Partitioning Sediment Benchmarks (ESBs) for the ...
This document describes procedures to determine the concentrations of nonionic organic chemicals in sediment interstitial waters. In previous ESB documents, the general equilibrium partitioning (EqP) approach was chosen for the derivation of sediment benchmarks because it accounts for the varying bioavailability of chemicals in different sediments and allows for the incorporation of the appropriate biological effects concentration. This provides for the derivation of benchmarks that are causally linked to the specific chemical, applicable across sediments, and appropriately protective of benthic organisms. This equilibrium partitioning sediment benchmark (ESB) document was prepared by scientists from the Atlantic Ecology Division, Mid-Continent Ecology Division, and Western Ecology Division, the Office of Water, and private consultants. The document describes procedures to determine the interstitial water concentrations of nonionic organic chemicals in contaminated sediments. Based on these concentrations, guidance is provided on the derivation of toxic units to assess whether the sediments are likely to cause adverse effects to benthic organisms. The equilibrium partitioning (EqP) approach was chosen because it is based on the concentrations of chemical(s) that are known to be harmful and bioavailable in the environment. This document, and five others published over the last nine years, will be useful for the Program Offices, including Superfund, a
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Data Partitioning and Load Balancing in Parallel Disk Systems
NASA Technical Reports Server (NTRS)
Scheuermann, Peter; Weikum, Gerhard; Zabback, Peter
1997-01-01
Parallel disk systems provide opportunities for exploiting I/O parallelism in two possible waves, namely via inter-request and intra-request parallelism. In this paper we discuss the main issues in performance tuning of such systems, namely striping and load balancing, and show their relationship to response time and throughput. We outline the main components of an intelligent, self-reliant file system that aims to optimize striping by taking into account the requirements of the applications and performs load balancing by judicious file allocation and dynamic redistributions of the data when access patterns change. Our system uses simple but effective heuristics that incur only little overhead. We present performance experiments based on synthetic workloads and real-life traces.
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Evaluation of water balance in a population of older adults. A case control study.
Malisova, Olga; Poulia, Kalliopi-Anna; Kolyzoi, Kleoniki; Lysandropoulos, Athanasios; Sfendouraki, Kalliopi; Kapsokefalou, Maria
2018-04-01
Older adults are at risk for dehydration and its' potentially life-threatening consequences. Unrecognized dehydration can complicate chronic medical problems and increase morbidity. The objective of the study was to estimate water balance, intake and loss in elderly people living in Greece using the Water Balance Questionnaire (WBQ). WBQ was administered in winter to 108 independents (65-81yrs) (Group A), 94 independents (82-92yrs) (Group B) and 51 hospitalized (65-92yrs) (Group C). A database from previous study of 335 adults (18-65yrs) (Control Group) used for comparison. Mean estimates of water balance, intake and loss were, respectively, for Group A -749 ± 1386 mL/day, 2571 ± 739 mL/day and 3320 ± 1216 mL/day, for Group B -38 ± 933 mL/day, 2571 ± 739 mL/day and 3320 ± 1216 mL/day, for Group C 64 ± 1399 mL/day, 2586 ± 1071 mL/day and 2522 ± 1048 mL/day and for Control Group -253 ± 1495 mL/day, 2912 ± 1025 mL/day and 3492 ± 2099 mL/day. Significant differences were detected in water balance, intake and loss (p < 0.01). Water balance and water intake in Group A was the lowest. For Groups A, B, C and Control, contribution of solid foods to water intake was 36%, 29%, 32%, 25%, of drinking water was 32%, 48%, 45%, 47%, of beverages was 32%, 23%, 23% and 28% respectively. Significant differences observed in the contribution of drinking water and beverages (p < 0.01). Group A had lower water balance and water intake. Groups B and C had lower water intake from beverages. Copyright © 2018 European Society for Clinical Nutrition and Metabolism. Published by Elsevier Ltd. All rights reserved.
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NASA Astrophysics Data System (ADS)
Yamanaka, T.; Sato, R.
2017-12-01
Transpiration (T) through plants (i.e., green water) does not induce isotopic fractionation, although evaporation (E) from soils and water surfaces do. Therefore, water stable isotopes offer a powerful tool to partition evapotranspiration (ET) components. We attempted to evaluate catchment-scale T/ET for five mountainous catchments in the central Japan, using river water isotopes and isotope maps of precipitation and soil water as well as climatic and radar precipitation maps. The estimated T/ET ranged from 56% to 79% (ET not including interception loss), and negatively correlated with mean elevation of the catchments (r = -0.88). This is due to decreasing transpiration (-82 mm/yr per 100 m) and slightly increasing evaporation (8 mm/yr per 100 m) with increasing elevation. Another estimation scheme using isotope data only showed a positive correlation between elevation and E/P*, where P* is effective precipitation defined by gross precipitation minus interception. Because the forest coverage within the catchments has positive correlation with catchment-mean-elevation, both decrease in transpiration and increase in soil evaporation seem to reflect structural change in forests (e.g., dense to sparse) along elevation and thus temperature gradients. Applying the space-for-time substitution, our results indicates that global warming will increase transpiration (and thus carbon intake) at mid-latitude mountainous landscapes.
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Ma, Guangcai; Yuan, Quan; Yu, Haiying; Lin, Hongjun; Chen, Jianrong; Hong, Huachang
2017-04-01
The binding of organic chemicals to serum albumin can significantly reduce their unbound concentration in blood and affect their biological reactions. In this study, we developed a new QSAR model for bovine serum albumin (BSA) - water partition coefficients (K BSA/W ) of neutral organic chemicals with large structural variance, logK BSA/W values covering 3.5 orders of magnitude (1.19-4.76). All chemical geometries were optimized by semi-empirical PM6 algorithm. Several quantum chemical parameters that reflect various intermolecular interactions as well as hydrophobicity were selected to develop QSAR model. The result indicates the regression model derived from logK ow , the most positive net atomic charges on an atom, Connolly solvent excluded volume, polarizability, and Abraham acidity could explain the partitioning mechanism of organic chemicals between BSA and water. The simulated external validation and cross validation verifies the developed model has good statistical robustness and predictive ability, thus can be used to estimate the logK BSA/W values for chemicals in application domain, accordingly to provide basic data for the toxicity assessment of the chemicals. Copyright © 2016 Elsevier Inc. All rights reserved.
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Multidimensional spectral load balancing
Hendrickson, Bruce A.; Leland, Robert W.
1996-12-24
A method of and apparatus for graph partitioning involving the use of a plurality of eigenvectors of the Laplacian matrix of the graph of the problem for which load balancing is desired. The invention is particularly useful for optimizing parallel computer processing of a problem and for minimizing total pathway lengths of integrated circuits in the design stage.
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Prediction of Partition Coefficients of Organic Compounds between SPME/PDMS and Aqueous Solution
Chao, Keh-Ping; Lu, Yu-Ting; Yang, Hsiu-Wen
2014-01-01
Polydimethylsiloxane (PDMS) is commonly used as the coated polymer in the solid phase microextraction (SPME) technique. In this study, the partition coefficients of organic compounds between SPME/PDMS and the aqueous solution were compiled from the literature sources. The correlation analysis for partition coefficients was conducted to interpret the effect of their physicochemical properties and descriptors on the partitioning process. The PDMS-water partition coefficients were significantly correlated to the polarizability of organic compounds (r = 0.977, p < 0.05). An empirical model, consisting of the polarizability, the molecular connectivity index, and an indicator variable, was developed to appropriately predict the partition coefficients of 61 organic compounds for the training set. The predictive ability of the empirical model was demonstrated by using it on a test set of 26 chemicals not included in the training set. The empirical model, applying the straightforward calculated molecular descriptors, for estimating the PDMS-water partition coefficient will contribute to the practical applications of the SPME technique. PMID:24534804
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Evaluation of alternative model-data fusion approaches in water balance estimation across Australia
NASA Astrophysics Data System (ADS)
van Dijk, A. I. J. M.; Renzullo, L. J.
2009-04-01
Australia's national agencies are developing a continental modelling system to provide a range of water information services. It will include rolling water balance estimation to underpin national water accounts, water resources assessments that interpret current water resources availability and trends in a historical context, and water resources predictions coupled to climate and weather forecasting. The nation-wide coverage, currency, accuracy, and consistency required means that remote sensing will need to play an important role along with in-situ observations. Different approaches to blending models and observations can be considered. Integration of on-ground and remote sensing data into land surface models in atmospheric applications often involves state updating through model-data assimilation techniques. By comparison, retrospective water balance estimation and hydrological scenario modelling to date has mostly relied on static parameter fitting against observations and has made little use of earth observation. The model-data fusion approach most appropriate for a continental water balance estimation system will need to consider the trade-off between computational overhead and the accuracy gains achieved when using more sophisticated synthesis techniques and additional observations. This trade-off was investigated using a landscape hydrological model and satellite-based estimates of soil moisture and vegetation properties for aseveral gauged test catchments in southeast Australia.
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Li, Linnan; Xie, Shaodong; Cai, Hao; Bai, Xuetao; Xue, Zhao
2008-08-01
Theoretical molecular descriptors were tested against logK(OW) values for polybrominated diphenyl ethers (PBDEs) using the Partial Least-Squares Regression method which can be used to analyze data with many variables and few observations. A quantitative structure-property relationship (QSPR) model was successfully developed with a high cross-validated value (Q(cum)(2)) of 0.961, indicating a good predictive ability and stability of the model. The predictive power of the QSPR model was further cross-validated. The values of logK(OW) for PBDEs are mainly governed by molecular surface area, energy of the lowest unoccupied molecular orbital and the net atomic charges on the oxygen atom. All these descriptors have been discussed to interpret the partitioning mechanism of PBDE chemicals. The bulk property of the molecules represented by molecular surface area is the leading factor, and K(OW) values increase with the increase of molecular surface area. Higher energy of the lowest unoccupied molecular orbital and higher net atomic charge on the oxygen atom of PBDEs result in smaller K(OW). The energy of the lowest unoccupied molecular orbital and the net atomic charge on PBDEs oxygen also play important roles in affecting the partition of PBDEs between octanol and water by influencing the interactions between PBDEs and solvent molecules.
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Increased fat catabolism sustains water balance during fasting in zebra finches.
Rutkowska, Joanna; Sadowska, Edyta T; Cichoń, Mariusz; Bauchinger, Ulf
2016-09-01
Patterns of physiological flexibility in response to fasting are well established, but much less is known about the contribution of water deprivation to the observed effects. We investigated body composition and energy and water budget in three groups of zebra finches: birds with access to food and water, food-deprived birds having access to drinking water and food-and-water-deprived birds. Animals were not stimulated by elevated energy expenditure and they were in thermoneutral conditions; thus, based on previous studies, water balance of fasting birds was expected to be maintained by increased catabolism of proteins. In contrast to this expectation, we found that access to water did not prevent reduction of proteinaceous tissue, but it saved fat reserves of the fasting birds. Thus, water balance of birds fasting without access to water seemed to be maintained by elevated fat catabolism, which generated 6 times more metabolic water compared with that in birds that had access to water. Therefore, we revise currently established views and propose fat to serve as the primary source for metabolic water production. Previously assumed increased protein breakdown for maintenance of water budget would occur if fat stores were depleted or if fat catabolism reached its upper limits due to high energy demands. © 2016. Published by The Company of Biologists Ltd.
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NASA Astrophysics Data System (ADS)
Aouade, Ghizlane; Jarlan, Lionel; Ezzahar, Jamal; Er-raki, Salah; Napoly, Adrien; Benkaddour, Abdelfettah; Khabba, Said; Boulet, Gilles; Chehbouni, Abdelghani; Boone, Aaron
2016-04-01
The Haouz region, typical of southern Mediterranean basins, is characterized by a semi-arid climate, with average annual rainfall of 250, whilst evaporative demand is about 1600 mm per year. Under these conditions, crop irrigation is inevitable for growth and development. Irrigated agriculture currently consumes the majority of total available water (up to 85%), making it critical for more efficient water use. Flood irrigation is widely practiced by the majority of the farmers (more than 85 %) with an efficiency which does not exceed 50%. In this context, a good knowledge of the partitioning of evapotranspiration (ET) into soil evaporation and plant transpiration is of crucial need for improving the irrigation scheduling and thus water use efficiency. In this study, the ISBA (Interactions Soil-Biosphere-Atmosphere) model was used for estimating ET and its partition over an olive orchard and a wheat field located near to the Marrakech City (Centre of Morocco). Two versions were evaluated: standard version which simulates a single energy balance for the soil and vegetation and the recently developed multiple energy balance (MEB) version which solves a separate energy balance for each of the two sources. Eddy covariance system, which provides the sensible and latent heat fluxes and meteorological instruments were operated during years 2003-2004 for the Olive Orchard and during years 2013 for wheat. The transpiration component was measured using a Sap flow system during summer over the wheat crop and stable isotope samples were gathered over wheat. The comparison between ET estimated by ISBA model and that measured by the Eddy covariance system showed that MEB version yielded a remarkable improvement compared to the standard version. The root mean square error (RMSE) and the correlation coefficient (R²) were about 45wm-2 and 0.8 for MEB version. By contrast, for the standard version, the RMSE and R² were about 60wm-2 and 0.7, respectively. The result also showed that
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NASA Astrophysics Data System (ADS)
Turner, K.; Wolfe, B. B.; Edwards, T. W.
2010-12-01
The Old Crow Flats (OCF), Yukon Territory, is a wetland of international significance that comprises approximately 2700 shallow thermokarst lakes. Located near the northern limit of the boreal forest, the OCF provides vital habitat for abundant wildlife including waterfowl, moose, muskrat, and the Porcupine Caribou Herd, which support the traditional lifestyle of the Vuntut Gwitchin First Nation. Thermokarst lakes, which occupy vast northern regions, are greatly influenced by climate conditions. In the OCF and other regions there have been observations of decreasing water levels and an increase in frequency of lake drainage events over recent decades. Though there is widespread concern that thermokarst landscape changes are accelerating as a result of ongoing climate change, there are few studies that have investigated current and past variability of lake water balances and climate interactions at the landscape scale. As part of a Government of Canada International Polar Year multidisciplinary project, the present and past hydrology of lakes spanning the OCF are being investigated using water isotope tracers and paleolimnological approaches. Water samples were obtained from 57 lakes three times over three ice-free seasons (2007-09) and analyzed for oxygen and hydrogen isotope composition in order to capture seasonal and interannual changes in water balance conditions. Results highlight strong diversity in the hydrology of lakes throughout the OCF. Based on patterns of isotopic evolution and calculations of input source compositions and evaporation-to-inflow ratios, we identified snowmelt-dominated, rainfall-dominated, groundwater-influenced, evaporation-dominated and drained lake types, which represent the dominant hydrological processes influencing lake water balances. Lake physical and catchment land cover characteristics influence dominant input type (rain or snow). Snowmelt-dominated catchments are large relative to lake surface areas and typically contain
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Yang, Shi-Jian; Sun, Mei; Yang, Qiu-Yun; Ma, Ren-Yi; Zhang, Jiao-Lin; Zhang, Shi-Bao
2016-01-01
Epiphytes are an important component of tropical and subtropical flora, and serve vital ecological functions in forest hydrology and nutrient fluxes. However, they often encounter water deficits because there is no direct contact between their roots and the soil. The strategies employed by epiphytes for maintaining water balance in relatively water-limited habitats are not completely understood. In the present study, we investigated the anatomical traits, water loss rates, and physiology of leaves and pseudobulbs of four Dendrobium species with different pseudobulb morphologies to understand the roles of leaf and pseudobulb in maintaining water balance of epiphytic orchids. Our results showed that two species (D. chrysotoxum and D. officinale), with lower rates of water loss, have thicker leaves and upper cuticles, but lower epidermal thickness and leaf dry mass per area. In contrast, the other two species (D. chrysanthum and D. crystallinum) with thinner cuticles and higher rates of water loss, have less tissue density and greater saturated water contents in their pseudobulbs. Therefore, our results indicate that these latter two species may resist drought by storing water in the pseudobulbs to compensate for their thin cuticles and rapid water loss through the leaves. Under the same laboratory conditions, excised pseudobulbs with attached leaves had lower rates of water loss when compared with samples comprising only excised leaves. This implies that epiphytic orchids utilize two different strategies for sustaining water balance: thick cuticles to conserve water in leaves and water storage in pseudobulbs. Our results also show that Dendrobium species with thin cuticles tend to have pseudobulbs with high water storage capacity that compensates for their faster rates of water loss. These outcomes contribute to our understanding of the adaptive water-use strategies in Dendrobium species, which is beneficial for the conservation and cultivation of epiphytic orchids
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Yang, Shi-Jian; Sun, Mei; Yang, Qiu-Yun; Ma, Ren-Yi; Zhang, Jiao-Lin; Zhang, Shi-Bao
2016-01-01
Epiphytes are an important component of tropical and subtropical flora, and serve vital ecological functions in forest hydrology and nutrient fluxes. However, they often encounter water deficits because there is no direct contact between their roots and the soil. The strategies employed by epiphytes for maintaining water balance in relatively water-limited habitats are not completely understood. In the present study, we investigated the anatomical traits, water loss rates, and physiology of leaves and pseudobulbs of four Dendrobium species with different pseudobulb morphologies to understand the roles of leaf and pseudobulb in maintaining water balance of epiphytic orchids. Our results showed that two species (D. chrysotoxum and D. officinale), with lower rates of water loss, have thicker leaves and upper cuticles, but lower epidermal thickness and leaf dry mass per area. In contrast, the other two species (D. chrysanthum and D. crystallinum) with thinner cuticles and higher rates of water loss, have less tissue density and greater saturated water contents in their pseudobulbs. Therefore, our results indicate that these latter two species may resist drought by storing water in the pseudobulbs to compensate for their thin cuticles and rapid water loss through the leaves. Under the same laboratory conditions, excised pseudobulbs with attached leaves had lower rates of water loss when compared with samples comprising only excised leaves. This implies that epiphytic orchids utilize two different strategies for sustaining water balance: thick cuticles to conserve water in leaves and water storage in pseudobulbs. Our results also show that Dendrobium species with thin cuticles tend to have pseudobulbs with high water storage capacity that compensates for their faster rates of water loss. These outcomes contribute to our understanding of the adaptive water-use strategies in Dendrobium species, which is beneficial for the conservation and cultivation of epiphytic orchids
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Guédron, Stéphane; Devin, Simon; Vignati, Davide A L
2016-02-01
Tangential flow ultrafiltration was used to determine the partitioning of total mercury (THg) and monomethylmercury (MMHg) between colloids and true solution in sediment overlying and porewaters collected in Lake Geneva (Switzerland and France), Venice Lagoon (Italy), and Baihua Reservoir (China). Overlying water and porewater spanned different ranges of THg and MMHg concentrations, redox conditions, and salinity. Total Hg, MMHg, and dissolved organic carbon (DOC) concentrations were measured in filter-passing (<0.45 μm), colloidal (3 kDa-0.45 μm), and truly dissolved (<3 kDa) fractions. The percentages of filterable Hg and MMHg associated with colloids (arithmetic means ±1 standard deviation [SD]) were 29 ± 11% for THg (range, 4-60%) and 44 ± 17% for MMHg (range, 15-65%). Ultrafiltration DOC mass balances were often not satisfactory. However, this was apparently without consequences on THg/MMHg fractionation, suggesting that only a part of total DOC controlled THg/MMHg partitioning in overlying water and porewater. Linear relationships existed between filter passing and truly dissolved concentrations of THg and MMHg, suggesting that mechanisms controlling their partitioning are, at least partly, similar across aquatic systems. These linear relationships could be extended to data from published studies and ultrafilterable concentrations often could be predicted, within a factor of 2, from the measurement of filter-passing ones. The possibility to easily model THg/MMHg partitioning across aquatic systems will facilitate its consideration in general biogeochemical THg/MMHg models. © 2015 SETAC.
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Atmospheric Water Balance and Variability in the MERRA-2 Reanalysis
NASA Technical Reports Server (NTRS)
Bosilovich, Michael G.; Robertson, Franklin R.; Takacs, Lawrence; Molod, Andrea; Mocko, David
2017-01-01
Closing and balancing Earths global water cycle remains a challenge for the climate community. Observations are limited in duration, global coverage, and frequency, and not all water cycle terms are adequately observed. Reanalyses aim to fill the gaps through the assimilation of as many atmospheric water vapor observations as possible. Former generations of reanalyses have demonstrated a number of systematic problems that have limited their use in climate studies, especially regarding low-frequency trends. This study characterizes the NASA Modern-Era Retrospective Analysis for Research and Applications version 2 (MERRA-2) water cycle relative to contemporary reanalyses and observations. MERRA-2 includes measures intended to minimize the spurious global variations related to in homogeneity in the observational record. The global balance and cycling of water from ocean to land is presented, with special attention given to the water vapor analysis increment and the effects of the changing observing system. While some systematic regional biases can be identified,MERRA-2 produces temporally consistent time series of total column water and transport of water from ocean to land. However, the interannual variability of ocean evaporation is affected by the changing surface-wind-observing system, and precipitation variability is closely related to the evaporation. The surface energy budget is also strongly influenced by the interannual variability of the ocean evaporation. Furthermore, evaluating the relationship of temperature and water vapor indicates that the variations of water vapor with temperature are weaker in satellite data reanalyses, not just MERRA-2, than determined by observations, atmospheric models, or reanalyses without water vapor assimilation.
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Mechanical Balance Laws for Boussinesq Models of Surface Water Waves
NASA Astrophysics Data System (ADS)
Ali, Alfatih; Kalisch, Henrik
2012-06-01
Depth-integrated long-wave models, such as the shallow-water and Boussinesq equations, are standard fare in the study of small amplitude surface waves in shallow water. While the shallow-water theory features conservation of mass, momentum and energy for smooth solutions, mechanical balance equations are not widely used in Boussinesq scaling, and it appears that the expressions for many of these quantities are not known. This work presents a systematic derivation of mass, momentum and energy densities and fluxes associated with a general family of Boussinesq systems. The derivation is based on a reconstruction of the velocity field and the pressure in the fluid column below the free surface, and the derivation of differential balance equations which are of the same asymptotic validity as the evolution equations. It is shown that all these mechanical quantities can be expressed in terms of the principal dependent variables of the Boussinesq system: the surface excursion η and the horizontal velocity w at a given level in the fluid.
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Altinok, Ilhan; Capkin, Erol; Boran, Halis
2011-06-01
Effects of water volume and water column height on toxicity of cypermethrin, carbaryl, dichlorvos, tetradifon, maneb, captan, carbosulfan endosulfan and HgCl₂ to juvenile rainbow trout (Oncorhynchus mykiss, 3.2 ± 0.7 g) were evaluated in different glass aquaria under static conditions. When fish were exposed to the chemical compounds in 23 cm water column height (25 L), their mortality ranged between 0% and 58%. At the same water volume, but lower water column height (9 cm), mortality of fish increased significantly and was in a range from 60% to 95%. At the same water column height, toxic effects of chemicals were significantly higher in 25 L water volume than that of 8.5 L, water except maneb which has lowest (-0.45) octanol-water partition coefficient value. Mortality rates ratio of 9 and 23 cm water column height ranged between 1.12 and 90 while mortality rates ratio of 9 and 25 L water volume ranged between 1.20 and 4.0. Because actual exposure concentrations were not affected by either water volume or water column height, we propose that increased pesticides' toxicity was related to an increase in bioassay volume, since more pesticide molecules were able to interact with or accumulate the fish. However, there seem to be no relationship between the effects of water volume, water column height and Kow value of chemicals with regard to toxicity in juvenile rainbow trout.
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Dynamic Load Balancing for Adaptive Computations on Distributed-Memory Machines
NASA Technical Reports Server (NTRS)
1999-01-01
Dynamic load balancing is central to adaptive mesh-based computations on large-scale parallel computers. The principal investigator has investigated various issues on the dynamic load balancing problem under NASA JOVE and JAG rants. The major accomplishments of the project are two graph partitioning algorithms and a load balancing framework. The S-HARP dynamic graph partitioner is known to be the fastest among the known dynamic graph partitioners to date. It can partition a graph of over 100,000 vertices in 0.25 seconds on a 64- processor Cray T3E distributed-memory multiprocessor while maintaining the scalability of over 16-fold speedup. Other known and widely used dynamic graph partitioners take over a second or two while giving low scalability of a few fold speedup on 64 processors. These results have been published in journals and peer-reviewed flagship conferences.
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Wan Mohamad, W A Fahmi; Buckow, Roman; Augustin, MaryAnn; McNaughton, Don
2017-10-15
Confocal Raman microscopy (CRM) was able to quantify the β-carotene concentration in oil droplets and determine the partitioning characteristics of β-carotene within the emulsion system in situ. The results were validated by a conventional method involving solvent extraction of β-carotene separately from the total emulsion as well as the aqueous phase separated by centrifugation, and quantification by absorption spectrophotometry. CRM also enabled the localization of β-carotene in an emulsion. From the Raman image, the β-carotene partitioning between the aqueous and oil phases of palm olein-in-water emulsions stabilized by whey protein isolate (WPI) was observed. Increasing the concentration of β-carotene in an emulsion (from 0.1 to 0.3g/kg emulsion) with a fixed gross composition (10% palm olein:2% WPI) decreased the concentration of β-carotene in the oil droplet. CRM is a powerful tool for in situ analyses of components in heterogeneous systems such as emulsions. Copyright © 2017 Elsevier Ltd. All rights reserved.
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Vascular functioning and the water balance of ripening kiwifruit (Actinidia chinensis) berries
Clearwater, Michael J.; Luo, Zhiwei; Ong, Sam Eng Chye; Blattmann, Peter; Thorp, T. Grant
2012-01-01
Indirect evidence suggests that water supply to fleshy fruits during the final stages of development occurs through the phloem, with the xylem providing little water, or acting as a pathway for water loss back to the plant. This inference was tested by examining the water balance and vascular functioning of ripening kiwifruit berries (Actinidia chinensis var. chinensis ‘Hort16A’) exhibiting a pre-harvest ‘shrivel’ disorder in California, and normal development in New Zealand. Dye labelling and mass balance experiments indicated that the xylem and phloem were both functional and contributed approximately equally to the fruit water supply during this stage of development. The modelled fruit water balance was dominated by transpiration, with net water loss under high vapour pressure deficit (Da) conditions in California, but a net gain under cooler New Zealand conditions. Direct measurement of pedicel sap flow under controlled conditions confirmed inward flows in both the phloem and xylem under conditions of both low and high Da. Phloem flows were required for growth, with gradual recovery after a step increase in Da. Xylem flows alone were unable to support growth, but did supply transpiration and were responsive to Da-induced pressure fluctuations. The results suggest that the shrivel disorder was a consequence of a high fruit transpiration rate, and that the perception of complete loss or reversal of inward xylem flows in ripening fruits should be re-examined. PMID:22155631
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Brooks, Paul D.; Chorover, Jon; Fan, Ying; ...
2015-08-07
Here, hydrology is an integrative discipline linking the broad array of water–related research with physical, ecological, and social sciences. The increasing breadth of hydrological research, often where subdisciplines of hydrology partner with related sciences, reflects the central importance of water to environmental science, while highlighting the fractured nature of the discipline itself. This lack of coordination among hydrologic subdisciplines has hindered the development of hydrologic theory and integrated models capable of predicting hydrologic partitioning across time and space. The recent development of the concept of the critical zone (CZ), an open system extending from the top of the canopy tomore » the base of groundwater, brings together multiple hydrological subdisciplines with related physical and ecological sciences. Observations obtained by CZ researchers provide a diverse range of complementary process and structural data to evaluate both conceptual and numerical models. Consequently, a cross–site focus on “critical zone hydrology” has potential to advance the discipline of hydrology and to facilitate the transition of CZ observatories into a research network with immediate societal relevance. Here we review recent work in catchment hydrology and hydrochemistry, hydrogeology, and ecohydrology that highlights a common knowledge gap in how precipitation is partitioned in the critical zone: “how is the amount, routing, and residence time of water in the subsurface related to the biogeophysical structure of the CZ?” Addressing this question will require coordination among hydrologic subdisciplines and interfacing sciences, and catalyze rapid progress in understanding current CZ structure and predicting how climate and land cover changes will affect hydrologic partitioning.« less
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Sabo, John L.
2016-01-01
Despite the clear importance of water balance to the evolution of terrestrial life, much remains unknown about the effects of animal water balance on food webs. Based on recent research suggesting animal water imbalance can increase trophic interaction strengths in cages, we hypothesized that water availability could drive top-down effects in open environments, influencing the occurrence of trophic cascades. We manipulated large spider abundance and water availability in 20 × 20 m open-air plots in a streamside forest in Arizona, USA, and measured changes in cricket and small spider abundance and leaf damage. As expected, large spiders reduced both cricket abundance and herbivory under ambient, dry conditions, but not where free water was added. When water was added (free or within moist leaves), cricket abundance was unaffected by large spiders, but spiders still altered herbivory, suggesting behavioural effects. Moreover, we found threshold-type increases in herbivory at moderately low soil moisture (between 5.5% and 7% by volume), suggesting the possibility that water balance may commonly influence top-down effects. Overall, our results point towards animal water balance as an important driver of direct and indirect species interactions and food web dynamics in terrestrial ecosystems. PMID:27534953
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High performance genetic algorithm for VLSI circuit partitioning
NASA Astrophysics Data System (ADS)
Dinu, Simona
2016-12-01
Partitioning is one of the biggest challenges in computer-aided design for VLSI circuits (very large-scale integrated circuits). This work address the min-cut balanced circuit partitioning problem- dividing the graph that models the circuit into almost equal sized k sub-graphs while minimizing the number of edges cut i.e. minimizing the number of edges connecting the sub-graphs. The problem may be formulated as a combinatorial optimization problem. Experimental studies in the literature have shown the problem to be NP-hard and thus it is important to design an efficient heuristic algorithm to solve it. The approach proposed in this study is a parallel implementation of a genetic algorithm, namely an island model. The information exchange between the evolving subpopulations is modeled using a fuzzy controller, which determines an optimal balance between exploration and exploitation of the solution space. The results of simulations show that the proposed algorithm outperforms the standard sequential genetic algorithm both in terms of solution quality and convergence speed. As a direction for future study, this research can be further extended to incorporate local search operators which should include problem-specific knowledge. In addition, the adaptive configuration of mutation and crossover rates is another guidance for future research.
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A Measurement and Modeling Study of Hair Partition of Neutral, Cationic, and Anionic Chemicals.
Li, Lingyi; Yang, Senpei; Chen, Tao; Han, Lujia; Lian, Guoping
2018-04-01
Various neutral, cationic, and anionic chemicals contained in hair care products can be absorbed into hair fiber to modulate physicochemical properties such as color, strength, style, and volume. For environmental safety, there is also an interest in understanding hair absorption to wide chemical pollutants. There have been very limited studies on the absorption properties of chemicals into hair. Here, an experimental and modeling study has been carried out for the hair-water partition of a range of neutral, cationic, and anionic chemicals at different pH. The data showed that hair-water partition not only depends on the hydrophobicity of the chemical but also the pH. The partition of cationic chemicals to hair increased with pH, and this is due to their electrostatic interaction with hair increased from repulsion to attraction. For anionic chemicals, their hair-water partition coefficients decreased with increasing pH due to their electrostatic interaction with hair decreased from attraction to repulsion. Increase in pH did not change the partition of neutral chemicals significantly. Based on the new physicochemical insight of the pH effect on hair-water partition, a new quantitative structure property relationship model has been proposed, taking into account of both the hydrophobic interaction and electrostatic interaction of chemical with hair fiber. Copyright © 2018 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.
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The U.S. Geological Survey Monthly Water Balance Model Futures Portal
Bock, Andrew R.; Hay, Lauren E.; Markstrom, Steven L.; Emmerich, Christopher; Talbert, Marian
2017-05-03
The U.S. Geological Survey Monthly Water Balance Model Futures Portal (https://my.usgs.gov/mows/) is a user-friendly interface that summarizes monthly historical and simulated future conditions for seven hydrologic and meteorological variables (actual evapotranspiration, potential evapotranspiration, precipitation, runoff, snow water equivalent, atmospheric temperature, and streamflow) at locations across the conterminous United States (CONUS).The estimates of these hydrologic and meteorological variables were derived using a Monthly Water Balance Model (MWBM), a modular system that simulates monthly estimates of components of the hydrologic cycle using monthly precipitation and atmospheric temperature inputs. Precipitation and atmospheric temperature from 222 climate datasets spanning historical conditions (1952 through 2005) and simulated future conditions (2020 through 2099) were summarized for hydrographic features and used to drive the MWBM for the CONUS. The MWBM input and output variables were organized into an open-access database. An Open Geospatial Consortium, Inc., Web Feature Service allows the querying and identification of hydrographic features across the CONUS. To connect the Web Feature Service to the open-access database, a user interface—the Monthly Water Balance Model Futures Portal—was developed to allow the dynamic generation of summary files and plots based on plot type, geographic location, specific climate datasets, period of record, MWBM variable, and other options. Both the plots and the data files are made available to the user for download
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Noda, Yumi
2014-08-01
The human body is two-thirds water. The ability of ensuring the proper amount of water inside the body is essential for the survival of mammals. The key event for maintenance of body water balance is water reabsorption in the kidney collecting ducts, which is regulated by aquaporin-2 (AQP2). AQP2 is a channel that is exclusively selective for water molecules and never allows permeation of ions or other small molecules. Under normal conditions, AQP2 is restricted within the cytoplasm of the collecting duct cells. However, when the body is dehydrated and needs to retain water, AQP2 relocates to the apical membrane, allowing water reabsorption from the urinary tubule into the cell. Its impairments result in various water balance disorders including diabetes insipidus, which is a disease characterized by a massive loss of water through the kidney, leading to severe dehydration in the body. Dysregulation of AQP2 is also a common cause of water retention and hyponatremia that exacerbate the prognosis of congestive heart failure and hepatic cirrhosis. Many studies have uncovered the regulation mechanisms of AQP2 at the single-molecule level, the whole-body level, and the clinical level. In clinical practice, urinary AQP2 is a useful marker for body water balance (hydration status). Moreover, AQP2 is now attracting considerable attention as a potential therapeutic target for water balance disorders which commonly occur in many diseases.
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NASA Astrophysics Data System (ADS)
Mendes Godinho, R.; Raimundo, J.; Vale, C.; Anes, B.; Brito, P.; Alves, L. C.; Pinheiro, T.
2013-07-01
In the scope of a monitoring program to assess the environmental impact of automobile traffic over one main bridge in Lisbon, both water and duckweed (Lemna minor L.) were sampled from the road drainage tanks and analyzed for chemical elements. Plants uptake Cr, Mn, Cu, and Zn metals from rain water draining the bridge road. Nuclear microprobe elemental maps of cryosections of L. minor tissues showed that incorporated elements were internalized in fronds of the plant. This approach at micrometer level allows a better knowledge of the elemental tissue partitioning in this biomonitor organism.
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The effect of exercise on water balance in premenopausal physically active women.
Weinheimer, Eileen M; Martin, Berdine R; Weaver, Connie M; Welch, Jo M; Campbell, Wayne W
2008-10-01
This controlled feeding study examined the effects of exercise on daily water intake (particularly ad libitum water intake), water output, whole-body water balance, and hydration status in physically active, premenopausal women. The randomized crossover design consisted of three 8-day trials: placebo and no exercise, placebo and exercise (1-hour cycling bout per day at 65%-70% of heart rate reserve), and 800 mg calcium supplementation and exercise. During each trial, controlled quantities of the same foods and beverages were provided and ad libitum water intake was quantified. Water input included measured water from foods and beverages, measured ad libitum intake, and estimated metabolic production. Water output included measured losses in urine and stool, and estimated insensible losses from respiration and non-sweating perspiration (insensible diffusion through the skin). Participants were 26 women, age 25+/-5 years, body mass index 22+/-2, and VO(2peak) 43+/-6 mLxkg(-1)xmin(-1) (mean+/-standard deviation). Ad libitum water intake was 363 g/day more (P<0.05) for the placebo and exercise (1,940+/-654 g/day) and calcium supplementation and exercise (1,935+/-668 g/day) trials, compared with placebo and no exercise trial (1,575+/-667 g/day), and total water input was correspondingly higher in placebo and exercise and calcium supplementation and exercise trials compared with the placebo and no exercise trial. Urine, stool, and total water outputs were not different among trials. Apparent net water balance (representative of sweat water output) was 367 g/day more (P<0.05) in placebo and exercise (679+/-427 g/day) and calcium supplementation and exercise (641+/-519 g/day) trials compared with placebo and no exercise trial (293+/-419 g/day). Hydration status was clinically normal during all three trials. Calcium supplementation did not influence water balance. These results support that young, physically active women can completely compensate for exercise-induced sweat
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Philip E. Dennison; Dar A. Roberts; Sommer R. Thorgusen; Jon C. Regelbrugge; David Weise; Christopher Lee
2003-01-01
Live fuel moisture, an important determinant of fire danger in Mediterranean ecosystems, exhibits seasonal changes in response to soil water availability. Both drought stress indices based on meteorological data and remote sensing indices based on vegetation water absorption can be used to monitor live fuel moisture. In this study, a cumulative water balance index (...
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Water in the critical zone: soil, water and life from profile to planet
NASA Astrophysics Data System (ADS)
Kirkby, Mike
2015-04-01
Water is essential to the critical zone between bedrock and the atmosphere, and without water the soil is dead. Water provides the basis for the abundant life within the soil and, interacting with micro-organisms, drives the key processes in the critical zone. This review looks at the balances that control the flow of water through the soil, and how water movement is one of the major controls on the fluxes and transformations that control the formation, evolution and loss of material that controls the 'life' and 'health' of the soil. At regional scales, climate, acting largely through the soil hydrology, plays a major part in determining the type of soils developed - from hyper arid soils dominated by aeolian inputs, through arid and semi-arid soils with largely vertical water exchanges with the atmosphere, to temperate soils with substantial lateral drainage, and humid soils dominated by organic peats. Soil water balance controls the partition of precipitation between evaporative loss, lateral subsurface flow and groundwater recharge, and, in turn, has a major influence on the potential for plant growth and on the lateral connectivity between soils on a hillslope. Sediment and solute balances distinguish soils of accumulation from soils that tend towards a stable chemical depletion ratio. Reflecting the availability of water and the soil material, carbon balance plays a major role in soil horizonation and distinguishes soils dominated by mineral or organic components. At finer catena and catchment scales, lateral connectivity, or its absence, determines how soils evolve through the transfer of water and sediment downslope, creating more or less integrated landscapes in a balance between geomorphological and pedological processes. Within single soil profiles, the movement of water controls the processes of weathering and soil horizonation by ion diffusion, advective leaching and bioturbation, creating horizonation that, in turn, modifies the hydrological responses
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An attempt to perform water balance in a Brazilian municipal solid waste landfill.
São Mateus, Maria do Socorro Costa; Machado, Sandro Lemos; Barbosa, Maria Cláudia
2012-03-01
This paper presents an attempt to model the water balance in the metropolitan center landfill (MCL) in Salvador, Brazil. Aspects such as the municipal solid waste (MSW) initial water content, mass loss due to decomposition, MSW liquid expelling due to compression and those related to weather conditions, such as the amount of rainfall and evaporation are considered. Superficial flow and infiltration were modeled considering the waste and the hydraulic characteristics (permeability and soil-water retention curves) of the cover layer and simplified uni-dimensional empirical models. In order to validate the modeling procedure, data from one cell at the landfill were used. Monthly waste entry, volume of collected leachate and leachate level inside the cell were monitored. Water balance equations and the compressibility of the MSW were used to calculate the amount of leachate stored in the cell and the corresponding leachate level. Measured and calculated values of the leachate level inside the cell were similar and the model was able to capture the main trends of the water balance behavior during the cell operational period. Copyright © 2011 Elsevier Ltd. All rights reserved.
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Influence of biochar on isoproturon partitioning and bioaccessibility in soil.
Reid, B J; Pickering, F L; Freddo, A; Whelan, M J; Coulon, F
2013-10-01
The influence of biochar (5%) on the loss, partitioning and bioaccessibility of (14)C-isoproturon ((14)C-IPU) was evaluated. Results indicated that biochar had a dramatic effect upon (14)C-IPU partitioning: (14)C-IPU extractability (0.01 M CaCl2) in biochar-amended treatments was reduced to <2% while, (14)C-IPU extractability in biochar free treatments decreased with ageing from 90% to 40%. A partitioning model was constructed to derive an effective partition coefficient for biochar:water (KBW of 7.82 × 10(4) L kg(-1)). This was two orders of magnitude greater than the apparent Kfoc value of the soil organic carbon:water (631 L kg(-1)). (14)C-radiorespirometry assays indicated high competence of microorganisms to mineralise (14)C-IPU in the absence of biochar (40.3 ± 0.9%). Where biochar was present (14)C-IPU mineralisation never exceeded 2%. These results indicate reduced herbicide bioaccessibility. Increasing IPU application to ×10 its recommended dose was ineffective at redressing IPU sequestration and its low bioaccessibility. Copyright © 2013 Elsevier Ltd. All rights reserved.
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Bioconcentration factors and plant-water partition coefficients of munitions compounds in barley.
Torralba-Sanchez, Tifany L; Kuo, Dave T F; Allen, Herbert E; Di Toro, Dominic M
2017-12-01
Plants growing in the soils at military ranges and surrounding locations are exposed, and potentially able to uptake, munitions compounds (MCs). The extent to which a compound is transferred from the environment into organisms such as plants, referred to as bioconcentration, is conventionally measured through uptake experiments with field/synthetic soils. Multiple components/phases that vary among different soil types and affect the bioavailability of the MC, however, hinder the ability to separate the effects of soil characteristics from the MC chemical properties on the resulting plant bioconcentration. To circumvent the problem, this work presents a protocol to measure steady state bioconcentration factors (BCFs) for MCs in barley (Hordeum vulgare L.) using inert laboratory sand rather than field/synthetic soils. Three MCs: 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (2,4-DNT), and 2,4-dinitroanisole (2,4-DNAN), and two munition-like compounds (MLCs): 4-nitroanisole (4-NAN) and 2-methoxy-5-nitropyridine (2-M-5-NPYNE) were evaluated. Approximately constant plant biomass and exposure concentrations were achieved within a one-month period that produced steady state log BCF values: 0.62 ± 0.02, 0.70 ± 0.03, 1.30 ± 0.06, 0.52 ± 0.03, and 0.40 ± 0.05 L kg plant dwt -1 for TNT, 2,4-DNT, 2,4-DNAN, 4-NAN, and 2-M-5-NPYNE, respectively. Furthermore, results suggest that the upper-bounds of the BCFs can be estimated within an order of magnitude by measuring the partitioning of the compounds between barley biomass and water. This highlights the importance of partition equilibrium as a mechanism for the uptake of MCs and MLCs by barley from interstitial water. The results from this work provide chemically meaningful data for prediction models able to estimate the bioconcentration of these contaminants in plants. Copyright © 2017 Elsevier Ltd. All rights reserved.
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A balanced water layer concept for subglacial hydrology in large scale ice sheet models
NASA Astrophysics Data System (ADS)
Goeller, S.; Thoma, M.; Grosfeld, K.; Miller, H.
2012-12-01
There is currently no doubt about the existence of a wide-spread hydrological network under the Antarctic ice sheet, which lubricates the ice base and thus leads to increased ice velocities. Consequently, ice models should incorporate basal hydrology to obtain meaningful results for future ice dynamics and their contribution to global sea level rise. Here, we introduce the balanced water layer concept, covering two prominent subglacial hydrological features for ice sheet modeling on a continental scale: the evolution of subglacial lakes and balance water fluxes. We couple it to the thermomechanical ice-flow model RIMBAY and apply it to a synthetic model domain inspired by the Gamburtsev Mountains, Antarctica. In our experiments we demonstrate the dynamic generation of subglacial lakes and their impact on the velocity field of the overlaying ice sheet, resulting in a negative ice mass balance. Furthermore, we introduce an elementary parametrization of the water flux-basal sliding coupling and reveal the predominance of the ice loss through the resulting ice streams against the stabilizing influence of less hydrologically active areas. We point out, that established balance flux schemes quantify these effects only partially as their ability to store subglacial water is lacking.
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On the sources of vegetation activity variation, and their relation with water balance in Mexico
F. Mora; L.R. Iverson
1998-01-01
Natural landscape surface processes are largely controlled by the relationship between climate and vegetation. Water balance integrates the effects of climate on patterns of vegetation distribution and productivity, and for that season, functional relationships can be established using water balance variables as predictors of vegetation response. In this study, we...
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McCluney, Kevin E; Sabo, John L
2016-08-17
Despite the clear importance of water balance to the evolution of terrestrial life, much remains unknown about the effects of animal water balance on food webs. Based on recent research suggesting animal water imbalance can increase trophic interaction strengths in cages, we hypothesized that water availability could drive top-down effects in open environments, influencing the occurrence of trophic cascades. We manipulated large spider abundance and water availability in 20 × 20 m open-air plots in a streamside forest in Arizona, USA, and measured changes in cricket and small spider abundance and leaf damage. As expected, large spiders reduced both cricket abundance and herbivory under ambient, dry conditions, but not where free water was added. When water was added (free or within moist leaves), cricket abundance was unaffected by large spiders, but spiders still altered herbivory, suggesting behavioural effects. Moreover, we found threshold-type increases in herbivory at moderately low soil moisture (between 5.5% and 7% by volume), suggesting the possibility that water balance may commonly influence top-down effects. Overall, our results point towards animal water balance as an important driver of direct and indirect species interactions and food web dynamics in terrestrial ecosystems. © 2016 The Author(s).
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Chan, Kelvin; Phadke, Chetan P; Stremler, Denise; Suter, Lynn; Pauley, Tim; Ismail, Farooq; Boulias, Chris
2017-05-01
Water-based exercises have been used in the rehabilitation of people with stroke, but little is known about the impact of this treatment on balance. This study examined the effect of water-based exercises compared to land-based exercises on the balance of people with sub-acute stroke. In this single-blind randomized controlled study, 32 patients with first-time stroke discharged from inpatient rehabilitation at West Park Healthcare Centre were recruited. Participants were randomized into W (water-based + land; n = 17) or L (land only; n = 15) exercise groups. Both groups attended therapy two times per week for six weeks. Initial and progression protocols for the water-based exercises (a combination of balance, stretching, and strengthening and endurance training) and land therapy (balance, strength, transfer, gait, and stair training) were devised. Outcomes included the Berg Balance Score, Community Balance and Mobility Score, Timed Up and Go Test, and 2 Minute Walk Test. Baseline characteristics of groups W and L were similar in age, side of stroke, time since stroke, and wait time between inpatient discharge and outpatient therapy on all four outcomes. Pooled change scores from all outcomes showed that significantly greater number of patients in the W-group showed improvement post-training compared to the L-group (p < 0.05). More patients in W-group showed change scores exceeding the published minimal detectable change scores. A combination of water- and land-based exercises has potential for improving balance. The results of this study extend the work showing benefit of water-based exercise in chronic and less-impaired stroke groups to patients with sub-acute stroke.
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Gangopadhyay, Subhrendu; McCabe, Gregory J.; Woodhouse, Connie A.
2015-01-01
In this paper, we present a methodology to use annual tree-ring chronologies and a monthly water balance model to generate annual reconstructions of water balance variables (e.g., potential evapotrans- piration (PET), actual evapotranspiration (AET), snow water equivalent (SWE), soil moisture storage (SMS), and runoff (R)). The method involves resampling monthly temperature and precipitation from the instrumental record directed by variability indicated by the paleoclimate record. The generated time series of monthly temperature and precipitation are subsequently used as inputs to a monthly water balance model. The methodology is applied to the Upper Colorado River Basin, and results indicate that the methodology reliably simulates water-year runoff, maximum snow water equivalent, and seasonal soil moisture storage for the instrumental period. As a final application, the methodology is used to produce time series of PET, AET, SWE, SMS, and R for the 1404–1905 period for the Upper Colorado River Basin.
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Modeling the Impact of Soil Conditions on Global Water Balance
NASA Astrophysics Data System (ADS)
Wang, P. L.; Feddema, J. J.
2016-12-01
The amount of water the soil can hold for plant use, defined as soil water-holding capacity (WHC), has a large influence on the water cycle and climatic variables. Although soil properties vary widely worldwide, many climate modeling applications assume WHC to be spatially invariant. This study explores how a more realistic soil WHC estimate affects the global water balance relative to commonly assumed soil properties. We use a modified Thornthwaite water balance model combined with a newly developed soil WHC and soil thickness data at a 30 arc second resolution. The soil WHC data was obtained by integrating WHCs to a depth of 2 m and modified by the soil thickness data on a grid-by-grid basis, and then resampling to the 0.5 degree climatology data. We observed that down scaling soils data before modifying soil depths greatly increases global soil WHCs. This new dataset is compared to WHC information with a fixed 2-m soil depth, and a constant 150-mm soil WHC. Results indicate higher soil WHC results in increased soil moisture, decreased moisture surplus and deficits, and increased actual evapotranspiration (AE), and vice-versa. However, due to high variability in soil characteristics across climate gradients, this generalization does not hold true for regionally averaged outcomes. Compared to using a constant 150-mm WHC, more realistic soil WHC increases global averaged AE 1%, and decreases deficit 2% and surplus 3%. Most change is observed in areas with pronounced wet and dry seasons; using a constant 2-m soil depth doubles the differences. Regionally, Europe was most affected: AE increases 4%, and the deficit and surplus decrease 20% and 12%. Australia shows that regionally averaged results are not equivocal for moisture surplus and deficit; deficit decreases 0.4%, while surplus decreases 9%. This research highlights the importance of soil condition for climate modeling and how a better representation of soil moisture conditions affects global water balance
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Ogata, Koji; Hatakeyama, Makoto; Nakamura, Shinichiro
2018-02-15
The octanol-water partition coefficient (log P ow ) is an important index for measuring solubility, membrane permeability, and bioavailability in the drug discovery field. In this paper, the log P ow values of 58 compounds were predicted by alchemical free energy calculation using molecular dynamics simulation. In free energy calculations, the atomic charges of the compounds are always fixed. However, they must be recalculated for each solvent. Therefore, three different sets of atomic charges were tested using quantum chemical calculations, taking into account vacuum, octanol, and water environments. The calculated atomic charges in the different environments do not necessarily influence the correlation between calculated and experimentally measured ∆ G water values. The largest correlation coefficient values of the solvation free energy in water and octanol were 0.93 and 0.90, respectively. On the other hand, the correlation coefficient of log P ow values calculated from free energies, the largest of which was 0.92, was sensitive to the combination of the solvation free energies calculated from the calculated atomic charges. These results reveal that the solvent assumed in the atomic charge calculation is an important factor determining the accuracy of predicted log P ow values.
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Ward, Adam S.; Payn, Robert A.; Gooseff, Michael N.; McGlynn, Brian L.; Bencala, Kenneth E.; Kelleher, Christa A.; Wondzell, Steven M.; Wagener, Thorsten
2013-01-01
The accumulation of discharge along a stream valley is frequently assumed to be the primary control on solute transport processes. Relationships of both increasing and decreasing transient storage, and decreased gross losses of stream water have been reported with increasing discharge; however, we have yet to validate these relationships with extensive field study. We conducted transient storage and mass recovery analyses of artificial tracer studies completed for 28 contiguous 100 m reaches along a stream valley, repeated under four base-flow conditions. We calculated net and gross gains and losses, temporal moments of tracer breakthrough curves, and best fit transient storage model parameters (with uncertainty estimates) for 106 individual tracer injections. Results supported predictions that gross loss of channel water would decrease with increased discharge. However, results showed no clear relationship between discharge and transient storage, and further analysis of solute tracer methods demonstrated that the lack of this relation may be explained by uncertainty and equifinality in the transient storage model framework. Furthermore, comparison of water balance and transient storage approaches reveals complications in clear interpretation of either method due to changes in advective transport time, which sets a the temporal boundary separating transient storage and channel water balance. We have little ability to parse this limitation of solute tracer methods from the physical processes we seek to study. We suggest the combined analysis of both transient storage and channel water balance more completely characterizes transport of solutes in stream networks than can be inferred from either method alone.
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DiFilippo, Erica L.; Eganhouse, Robert P.
2010-01-01
Solid-phase microextraction (SPME) has shown potential as an in situ passive-sampling technique in aquatic environments. The reliability of this method depends upon accurate determination of the partition coefficient between the fiber coating and water (Kf). For some hydrophobic organic compounds (HOCs), Kf values spanning 4 orders of magnitude have been reported for polydimethylsiloxane (PDMS) and water. However, 24% of the published data examined in this review did not pass the criterion for negligible depletion, resulting in questionable Kf values. The range in reported Kf is reduced to just over 2 orders of magnitude for some polychlorinated biphenyls (PCBs) when these questionable values are removed. Other factors that could account for the range in reported Kf, such as fiber-coating thickness and fiber manufacturer, were evaluated and found to be insignificant. In addition to accurate measurement of Kf, an understanding of the impact of environmental variables, such as temperature and ionic strength, on partitioning is essential for application of laboratory-measured Kf values to field samples. To date, few studies have measured Kf for HOCs at conditions other than at 20 degrees or 25 degrees C in distilled water. The available data indicate measurable variations in Kf at different temperatures and different ionic strengths. Therefore, if the appropriate environmental variables are not taken into account, significant error will be introduced into calculated aqueous concentrations using this passive sampling technique. A multiparameter linear solvation energy relationship (LSER) was developed to estimate log Kf in distilled water at 25 degrees C based on published physicochemical parameters. This method provided a good correlation (R2 = 0.94) between measured and predicted log Kf values for several compound classes. Thus, an LSER approach may offer a reliable means of predicting log Kf for HOCs whose experimental log Kf values are presently unavailable. Future
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Consequences of declining snow accumulation for water balance of mid-latitude dry regions
Schlaepfer, Daniel R.; Lauenroth, William K.; Bradford, John B.
2012-01-01
Widespread documentation of positive winter temperature anomalies, declining snowpack and earlier snow melt in the Northern Hemisphere have raised concerns about the consequences for regional water resources as well as wildfire. A topic that has not been addressed with respect to declining snowpack is effects on ecosystem water balance. Changes in water balance dynamics will be particularly pronounced at low elevations of mid-latitude dry regions because these areas will be the first to be affected by declining snow as a result of rising temperatures. As a model system, we used simulation experiments to investigate big sagebrush ecosystems that dominate a large fraction of the semiarid western United States. Our results suggest that effects on future ecosystem water balance will increase along a climatic gradient from dry, warm and snow-poor to wet, cold and snow-rich. Beyond a threshold within this climatic gradient, predicted consequences for vegetation switched from no change to increasing transpiration. Responses were sensitive to uncertainties in climatic prediction; particularly, a shift of precipitation to the colder season could reduce impacts of a warmer and snow-poorer future, depending on the degree to which ecosystem phenology tracks precipitation changes. Our results suggest that big sagebrush and other similar semiarid ecosystems could decrease in viability or disappear in dry to medium areas and likely increase only in the snow-richest areas, i.e. higher elevations and higher latitudes. Unlike cold locations at high elevations or in the arctic, ecosystems at low elevations respond in a different and complex way to future conditions because of opposing effects of increasing water-limitation and a longer snow-free season. Outcomes of such nonlinear interactions for future ecosystems will likely include changes in plant composition and productivity, dynamics of water balance, and availability of water resources.
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Mantle Mineral/Silicate Melt Partitioning
NASA Astrophysics Data System (ADS)
McFarlane, E. A.; Drake, M. J.
1992-07-01
Introduction: The partitioning of elements among mantle phases and silicate melts is of interest in unraveling the early thermal history of the Earth. It has been proposed that the elevated Mg/Si ratio of the upper mantle of the Earth is a consequence of the flotation of olivine into the upper mantle (Agee and Walker, 1988). Agee and Walker (1988) have generated a model via mass balance by assuming average mineral compositions to generate upper mantle peridotite. This model determines that upper mantle peridotite could result from the addition of 32.7% olivine and 0.9% majorite garnet into the upper mantle, and subtraction of 27.6% perovskite from the upper mantle (Agee and Walker, 1988). The present contribution uses experimental data to examine the consequences of such multiple phase fractionations enabling an independent evaluation of the above mentioned model. Here we use Mg-perovskite/melt partition coefficients from both a synthetic and a natural system (KLB-1) obtained from this laboratory. Also used are partition coefficient values for majorite garnet/melt, beta spinel/melt and olivine/melt partitioning (McFarlane et al., 1991b; McFarlane et al., 1992). Multiple phase fractionations are examined using the equilibrium crystallization equation and partition coefficient values. The mineral proportions determined by Agee and Walker (1988) are converted into weight fractions and used to compute a bulk partition coefficient value. Discussion: There has been a significant debate concerning whether measured values of trace element partition coefficients permit large-scale fractionation of liquidus phases from an early terrestrial magma ocean (Kato et al., 1988a,b; Walker and Agee, 1989; Drake, 1989; Drake et al., 1991; McFarlane et al., 1990, 1991). It should be noted that it is unclear which, if any, numerical values of partition coefficients are appropriate for examining this question, and certainly the assumptions for the current model must be more fully
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NASA Astrophysics Data System (ADS)
Rezaei, Abolfazl; Mohammadi, Zargham
2017-10-01
The safe groundwater yield plays a major role in the appropriate management of groundwater systems, particularly in (semi-)arid areas like Iran. This study incorporates both the water balance equation and the water table fluctuation to estimate the annual safe yield of the unconfined aquifer in the eastern part of the Kaftar Lake, an Iranian semiarid region. Firstly, the water balance year 2002-03, owing same water table elevation at the beginning and year-end, was chosen from the monthly representative groundwater hydrograph of the aquifer to be taken into account as a basic water year for determining the safe yield. Then the ratio of the total groundwater pumping to the annual groundwater recharge in the selected water balance year together with the quantity of total recharge occurred in the wet period (October to May) of the year of interest were applied to evaluate the annual safe yield at the initiation of the dry period (June to September) of the year of interest. Knowing the annual safe groundwater withdrawal rate at the initiation of each dry period could be helpful to decision makers in managing groundwater resources conservation. Analysis results indicate that to develop a safe management strategy in the aquifer; the ratio of the annual groundwater withdrawal to the annually recharged volume should not exceed 0.69. In the water year 2003-04 where the ratio is equal to 0.52, the water table raised up (about 0.48 m) while the groundwater level significantly declined (about 1.54 m) over the water year 2007-08 where the ratio of the annual groundwater withdrawal to the annually recharged volume (i.e., 2.76) is larger than 0.69.
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Does plant diversity affect the water balance of established grassland systems?
NASA Astrophysics Data System (ADS)
Leimer, Sophia; Bischoff, Sebastian; Blaser, Stefan; Boch, Steffen; Busch, Verena; Escher, Peter; Fischer, Markus; Kaupenjohann, Martin; Kerber, Katja; Klaus, Valentin; Michalzik, Beate; Prati, Daniel; Schäfer, Deborah; Schmitt, Barbara; Schöning, Ingo; Schwarz, Martin T.; Siemens, Jan; Thieme, Lisa; Wilcke, Wolfgang
2017-04-01
The water cycle drives nutrient cycles and plant productivity. The impact of land use on the water cycle has been extensively studied and there is experimental evidence that biodiversity modifies the water cycle in grasslands. However, the combined influences of land-use and associated biodiversity on the water cycle in established land-use systems are unclear. Therefore, we investigated how evapotranspiration (ETa), downward water flux (DF), and capillary rise (CR) in topsoil and subsoil are related to land-use and plant diversity in established, commercially managed grassland and compared these results to findings from experiments where plant diversity was manipulated. In three Central European regions ("Biodiversity Exploratories"), we studied 29 grassland plots (50 m x 50 m; 9-11 plots per region) from 2010 to 2015. The land-use types cover pasture, mown pasture, and meadow in at least triplicate per region. On each plot, we measured soil water contents, meteorological data (hourly resolution), cumulative precipitation (biweekly), plant species richness, the number of plants in the functional groups of grasses, herbs, and legumes (annually), and root biomass (once). Potential evapotranspiration (ETp) was calculated from meteorological data per plot. Missing data points of ETp and soil water contents were estimated with Bayesian hierarchical models. ETa, DF, and CR were calculated for two soil layers with a soil water balance model. The model is based on changes in soil water storage between subsequent observation dates and ETp, which was partitioned between soil layers according to root distribution. Water fluxes in annual resolution were statistically analyzed for land-use and biodiversity effects using repeated-measures analysis of variance (ANOVA). Land-use type did not affect water fluxes. Species richness did not influence DF and CR. DF from topsoil was higher on plots with more grass species, which is opposite to the results from a manipulative
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Effect of Strain, Region, and Tissue Composition on Glucose Partitioning in Meniscus Fibrocartilage.
Kleinhans, Kelsey L; Jackson, Alicia R
2017-03-01
A nearly avascular tissue, the knee meniscus relies on diffusive transport for nutritional supply to cells. Nutrient transport depends on solute partitioning in the tissue, which governs the amount of nutrients that can enter a tissue. The purpose of the present study was to investigate the effects of mechanical strain, tissue region, and tissue composition on the partition coefficient of glucose in meniscus fibrocartilage. A simple partitioning experiment was employed to measure glucose partitioning in porcine meniscus tissues from two regions (horn and central), from both meniscal components (medial and lateral), and at three levels of compression (0%, 10%, and 20%). Partition coefficient values were correlated to strain level, water volume fraction, and glycosaminoglycan (GAG) content of tissue specimens. Partition coefficient values ranged from 0.47 to 0.91 (n = 48). Results show that glucose partition coefficient is significantly (p < 0.001) affected by compression, decreasing with increasing strain. Furthermore, we did not find a statistically significant effect of tissue when comparing medial versus lateral (p = 0.181) or when comparing central and horn regions (p = 0.837). There were significant positive correlations between tissue water volume fraction and glucose partitioning for all groups. However, the correlation between GAG content and partitioning was only significant in the lateral horn group. Determining how glucose partitioning is affected by tissue composition and loading is necessary for understanding nutrient availability and related tissue health and/or degeneration. Therefore, this study is important for better understanding the transport and nutrition-related mechanisms of meniscal degeneration.
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ANALYTICAL METHOD DEVELOPMENTS TO SUPPORT PARTITIONING INTERWELL TRACER TESTING
Partitioning Interwell Tracer Testing (PITT) uses alcohol tracer compounds in estimating subsurface contamination from non-polar pollutants. PITT uses the analysis of water samples for various alcohols as part of the overall measurement process. The water samples may contain many...
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NASA Astrophysics Data System (ADS)
Wu, S.; Zhao, J.; Wang, H.
2017-12-01
This paper develops a seasonal water balance model based on the hypothesis that natural catchments utilize hedging strategy on evapotranspiration for climate seasonality. According to the monthly aridity index, one year is split into wet season and dry season. A seasonal water balance model is developed by analogy to a two-stage reservoir operation model, in which seasonal rainfall infiltration, evapotranspiration and saturation-excess runoff is corresponding to the inflow, release and surplus of the catchment system. Then the optimal hedging between wet season and dry season evapotranspiration is analytically derived with marginal benefit principle. Water budget data sets of 320 catchments in the United States covering the period from 1980 to 2010 are used to evaluate the performance of this model. The Nash-Sutcliffe Efficiency coefficient for evapotranspiration is higher than 0.5 in 84% of the study catchments; while the runoff is 87%. This paper validates catchments' hedging strategy on evapotranspiration for climate seasonality and shows its potential application for seasonal water balance, which is valuable for water resources planning and management.
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NASA Astrophysics Data System (ADS)
Wang, Weiguang; Li, Jinxing; Yu, Zhongbo; Ding, Yimin; Xing, Wanqiu; Lu, Wenjun
2018-04-01
As the only connecting term between water balance and energy budget in the earth-atmospheric system, evapotranspiration (ET) is considered the most excellent indicator for the activity for the water and energy cycle. Under the background of global change, regional ET estimates, components partitioning as well as their spatial and temporal patterns recognition are of great importance in understanding the hydrological processes and improving water management practices. This is particularly true for the Tibetan Plateau (TP), one of most sensitive and vulnerable region in response to the environment change in the earth. In this study, with flux site observation data and monthly ET data from the monthly water balance method incorporating the terrestrial water storage changes from the Gravity Recovery and Climate Experiment satellite (GRACE) production as the multiple validations, the long-term daily ET in the TP was retrieved by a modified Penman-Monteith-Leuning (PML) model with considering evapotranspiration over snow covered area during 1982-2012. The spatial and temporal changes of partitioned three components of ET, i.e., soil evaporation (Es), transpiration through the stomata of plant (Ec) and canopy interception (Ei), were investigated in the TP. Meanwhile, how the ET components contribute to ET changes and respond to the change in environmental factors in the TP was revealed and discussed. The results indicate that Es dominates ET in most areas of the TP with the mean annual ratio of 65.7%, except southeastern regions where the vegetation coverage is high. Although regional average ET and three main components all present obvious increase trends during the past decades, high spatial heterogeneity for their trends are identified in the TP. Moreover, a mixed changing pattern can be apparently found for Es in southeastern area, Ec and Ei in northwestern and southeastern area. Spatially, the ET variation are mainly attributed to change in Es, followed by Ec and Ei
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Partitioning of H2O on high pressure phase transformation of olivine
NASA Astrophysics Data System (ADS)
Inoue, T.; Wada, T.; Sasaki, R.; Irifune, T.; Yurimoto, H.
2003-12-01
Water is the most abundant volatile component on the Earth's surface, and it has been supplied to the Earth's interiors by subducted slab. Water influences the physical properties and melting temperature of minerals. Olivine is the most abundant mineral in the mantle, and it is clarified that the high-pressure polymorphs of olivine, wadsleyite and ringwoodite, can contain 3wt% of H2O in their crystal structures (e.g. Inoue et al., 1995, 1998). However, the partitioning of H2O among these minerals has not been clarified yet except for olivine-wadsleyite transformation (Chen et al., 2003). We have determined the partitioning of H2O between wadsleyite and ringwoodite and between ringwoodite and perovskite, and clarified the distribution of H2O among upper mantle, mantle transition zone and lower mantle. High-pressure experiments were conducted by MA-8 type (Kawai-type) high-pressure apparatus in Ehime University, and the chemical compositions were determined by EPMA. The water contents of minerals were measured by SIMS in Tokyo Institute of Technology. We succeeded to synthesize large (approximately 50 μ m) coexisting crystals of wadsleyite and ringwoodite, and of ringwoodite and perovskite, and we could clarify the partitioning of H2O between those coexisting minerals. The partition coefficients between wadsleyite and ringwoodite and between ringwoodite and perovskite were about 2 and about 10 or more, respectively. We (Chen et al., 2003) have already determined that the partition coefficients between wadsleyite and olivine is about 5, so the partitioning among upper mantle, 410-520km and 520-660km of mantle transition zone, and lower mantle are 4:20:10:1. Thus the mantle transition zone should be a strong water reservoir in the Earth's interiors.
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NASA Astrophysics Data System (ADS)
Chirouze, J.; Boulet, G.; Jarlan, L.; Fieuzal, R.; Rodriguez, J. C.; Ezzahar, J.; Er-Raki, S.; Bigeard, G.; Merlin, O.; Garatuza-Payan, J.; Watts, C.; Chehbouni, G.
2014-03-01
Instantaneous evapotranspiration rates and surface water stress levels can be deduced from remotely sensed surface temperature data through the surface energy budget. Two families of methods can be defined: the contextual methods, where stress levels are scaled on a given image between hot/dry and cool/wet pixels for a particular vegetation cover, and single-pixel methods, which evaluate latent heat as the residual of the surface energy balance for one pixel independently from the others. Four models, two contextual (S-SEBI and a modified triangle method, named VIT) and two single-pixel (TSEB, SEBS) are applied over one growing season (December-May) for a 4 km × 4 km irrigated agricultural area in the semi-arid northern Mexico. Their performance, both at local and spatial standpoints, are compared relatively to energy balance data acquired at seven locations within the area, as well as an uncalibrated soil-vegetation-atmosphere transfer (SVAT) model forced with local in situ data including observed irrigation and rainfall amounts. Stress levels are not always well retrieved by most models, but S-SEBI as well as TSEB, although slightly biased, show good performance. The drop in model performance is observed for all models when vegetation is senescent, mostly due to a poor partitioning both between turbulent fluxes and between the soil/plant components of the latent heat flux and the available energy. As expected, contextual methods perform well when contrasted soil moisture and vegetation conditions are encountered in the same image (therefore, especially in spring and early summer) while they tend to exaggerate the spread in water status in more homogeneous conditions (especially in winter). Surface energy balance models run with available remotely sensed products prove to be nearly as accurate as the uncalibrated SVAT model forced with in situ data.
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NASA Astrophysics Data System (ADS)
Beamer, J. P.; Hill, D. F.; Arendt, A.; Liston, G. E.
2016-05-01
A comprehensive study of the Gulf of Alaska (GOA) drainage basin was carried out to improve understanding of the coastal freshwater discharge (FWD) and glacier volume loss (GVL). Hydrologic processes during the period 1980-2014 were modeled using a suite of physically based, spatially distributed weather, energy-balance snow/ice melt, soil water balance, and runoff routing models at a high-resolution (1 km horizontal grid; daily time step). Meteorological forcing was provided by the North American Regional Reanalysis (NARR), Modern Era Retrospective Analysis for Research and Applications (MERRA), and Climate Forecast System Reanalysis (CFSR) data sets. Streamflow and glacier mass balance modeled using MERRA and CFSR compared well with observations in four watersheds used for calibration in the study domain. However, only CFSR produced regional seasonal and long-term trends in water balance that compared favorably with independent Gravity Recovery and Climate Experiment (GRACE) and airborne altimetry data. Mean annual runoff using CFSR was 760 km3 yr-1, 8% of which was derived from the long-term removal of stored water from glaciers (glacier volume loss). The annual runoff from CFSR was partitioned into 63% snowmelt, 17% glacier ice melt, and 20% rainfall. Glacier runoff, taken as the sum of rainfall, snow, and ice melt occurring each season on glacier surfaces, was 38% of the total seasonal runoff, with the remaining runoff sourced from nonglacier surfaces. Our simulations suggests that existing GRACE solutions, previously reported to represent glacier mass balance alone, are actually measuring the full water budget of land and ice surfaces.
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Du, Zhiyou; Chen, Aizhong; Chen, Wenhu; Liao, Qiansheng; Zhang, Hengmu; Bao, Yiming; Roossinck, Marilyn J; Carr, John P
2014-05-01
The Cucumber Mosaic Virus (CMV) 2b protein is an RNA-silencing suppressor that plays roles in CMV accumulation and virulence. The 2b proteins of subgroup IA CMV strains partition between the nucleus and cytoplasm, but the biological significance of this is uncertain. We fused an additional nuclear localization signal (NLS) to the 2b protein of subgroup IA strain Fny-CMV to create 2b-NLS and tested its effects on subcellular distribution, silencing, and virulence. The additional NLS enhanced 2b protein nuclear and nucleolar accumulation, but nuclear and nucleolar enrichment correlated with markedly diminished silencing suppressor activity in patch assays and abolished 2b protein-mediated disruption of microRNA activity in transgenic Arabidopsis. Nucleus/nucleolus-localized 2b protein possesses at least some ability to inhibit antiviral silencing, but this was not sufficient to prevent recovery from disease in younger, developing leaves in Arabidopsis. However, enhanced nuclear and nucleolar accumulation of 2b increased virulence and accelerated symptom appearance in older leaves. Experiments with Arabidopsis lines carrying mutant Dicer-like alleles demonstrated that compromised suppressor activity explained the diminished ability of 2b-NLS to enhance virus accumulation. Remarkably, the increased virulence that 2b-NLS engendered was unrelated to effects on microRNA- or short interfering RNA-regulated host functions. Thus, although nucleus- and nucleolus-localized 2b protein is less efficient at silencing suppression than cytoplasm-localized 2b, it enhances CMV virulence. We propose that partitioning of the 2b protein between the cytoplasmic and nuclear/nucleolar compartments allows CMV to regulate the balance between virus accumulation and damage to the host, presumably to maximize the benefit for the virus. In this work, the main finding is that nucleus/nucleolus-localized 2b protein is strongly associated with CMV virulence, which is independent of its effect on
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Assessment of check-dam groundwater recharge with water-balance calculations
NASA Astrophysics Data System (ADS)
Djuma, Hakan; Bruggeman, Adriana; Camera, Corrado; Eliades, Marinos
2017-04-01
Studies on the enhancement of groundwater recharge by check-dams in arid and semi-arid environments mainly focus on deriving water infiltration rates from the check-dam ponding areas. This is usually achieved by applying simple water balance models, more advanced models (e.g., two dimensional groundwater models) and field tests (e.g., infiltrometer test or soil pit tests). Recharge behind the check-dam can be affected by the built-up of sediment as a result of erosion in the upstream watershed area. This natural process can increase the uncertainty in the estimates of the recharged water volume, especially for water balance calculations. Few water balance field studies of individual check-dams have been presented in the literature and none of them presented associated uncertainties of their estimates. The objectives of this study are i) to assess the effect of a check-dam on groundwater recharge from an ephemeral river; and ii) to assess annual sedimentation at the check-dam during a 4-year period. The study was conducted on a check-dam in the semi-arid island of Cyprus. Field campaigns were carried out to measure water flow, water depth and check-dam topography in order to establish check-dam water height, volume, evaporation, outflow and recharge relations. Topographic surveys were repeated at the end of consecutive hydrological years to estimate the sediment built up in the reservoir area of the check dam. Also, sediment samples were collected from the check-dam reservoir area for bulk-density analyses. To quantify the groundwater recharge, a water balance model was applied at two locations: at the check-dam and corresponding reservoir area, and at a 4-km stretch of the river bed without check-dam. Results showed that a check-dam with a storage capacity of 25,000 m3 was able to recharge to the aquifer, in four years, a total of 12 million m3 out of the 42 million m3 of measured (or modelled) streamflow. Recharge from the analyzed 4-km long river section without
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Development of a multicomponent force and moment balance for water tunnel applications, volume 1
NASA Technical Reports Server (NTRS)
Suarez, Carlos J.; Malcolm, Gerald N.; Kramer, Brian R.; Smith, Brooke C.; Ayers, Bert F.
1994-01-01
The principal objective of this research effort was to develop a multicomponent strain gauge balance to measure forces and moments on models tested in flow visualization water tunnels. An internal balance was designed that allows measuring normal and side forces, and pitching, yawing and rolling moments (no axial force). The five-components to applied loads, low interactions between the sections and no hysteresis. Static experiments (which are discussed in this Volume) were conducted in the Eidetics water tunnel with delta wings and a model of the F/A-18. Experiments with the F/A-18 model included a thorough baseline study and investigations of the effect of control surface deflections and of several Forebody Vortex Control (FVC) techniques. Results were compared to wind tunnel data and, in general, the agreement is very satisfactory. The results of the static tests provide confidence that loads can be measured accurately in the water tunnel with a relatively simple multicomponent internal balance. Dynamic experiments were also performed using the balance, and the results are discussed in detail in Volume 2 of this report.
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Balanced Central Schemes for the Shallow Water Equations on Unstructured Grids
NASA Technical Reports Server (NTRS)
Bryson, Steve; Levy, Doron
2004-01-01
We present a two-dimensional, well-balanced, central-upwind scheme for approximating solutions of the shallow water equations in the presence of a stationary bottom topography on triangular meshes. Our starting point is the recent central scheme of Kurganov and Petrova (KP) for approximating solutions of conservation laws on triangular meshes. In order to extend this scheme from systems of conservation laws to systems of balance laws one has to find an appropriate discretization of the source terms. We first show that for general triangulations there is no discretization of the source terms that corresponds to a well-balanced form of the KP scheme. We then derive a new variant of a central scheme that can be balanced on triangular meshes. We note in passing that it is straightforward to extend the KP scheme to general unstructured conformal meshes. This extension allows us to recover our previous well-balanced scheme on Cartesian grids. We conclude with several simulations, verifying the second-order accuracy of our scheme as well as its well-balanced properties.
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NASA Astrophysics Data System (ADS)
Chitu, Zenaida; Villani, Giulia; Tomei, Fausto; Minciuna, Marian; Aldea, Adrian; Dumitrescu, Alexandru; Trifu, Cristina; Neagu, Dumitru
2017-04-01
Balta Brailei is one of the largest agriculture area in the Danube floodplain, located in SE of Romania. An impressive irrigation system, that covered about 53.500 ha and transferred water from the Danube River, was carried out in the period 1960-1980. Even if the water resources for agriculture in this area cover in most of the cases the volumes required by irrigation water users, the irrigation infrastructure issues as the position of the pumping stations against the river levels hinder the use of the water during low flows periods. An efficient optimization of water allocation in agriculture could avoid periods with water deficit in the irrigation systems. Hydrological processes are essentials in describing the mass and energy exchanges in the atmosphere-plant-soil system. Furthermore, the hydrological regime in this area is very dynamic with many feedback mechanisms between the various parts of the surface and subsurface water regimes. Agricultural crops depend on capillary rise from the shallow groundwater table and irrigation. For an effective optimization of irrigation water in Balta Brailei, we propose to analyse the water balance taking into consideration the water movement into the root zone and the influence of the Danube river, irrigation channel system and the shallow aquifer by combining the soil water balance model CRITERIA and GMS hydrogeological model. CRITERIA model is used for simulating water movement into the soil, while GMS model is used for simulating the shallow groundwater level variation. The understanding of the complex feedbacks between atmosphere, crops and the various parts of the surface and subsurface water regimes in the Balta Brailei will bring more insights for predicting crop water need and water resources for irrigation and it will represent the basis for implementing Moses Platform in this specific area. Moses Platform is a GIS based system devoted to water procurement and management agencies to facilitate planning of
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Polania, Jose A.; Poschenrieder, Charlotte; Beebe, Stephen; Rao, Idupulapati M.
2016-01-01
Common bean (Phaseolus vulgaris L.) is the most important food legume in the diet of poor people in the tropics. Drought causes severe yield loss in this crop. Identification of traits associated with drought resistance contributes to improving the process of generating bean genotypes adapted to these conditions. Field studies were conducted at the International Center for Tropical Agriculture (CIAT), Palmira, Colombia, to determine the relationship between grain yield and different parameters such as effective use of water (EUW), canopy biomass, and dry partitioning indices (pod partitioning index, harvest index, and pod harvest index) in elite lines selected for drought resistance over the past decade. Carbon isotope discrimination (CID) was used for estimation of water use efficiency (WUE). The main objectives were: (i) to identify specific morpho-physiological traits that contribute to improved resistance to drought in lines developed over several cycles of breeding and that could be useful as selection criteria in breeding; and (ii) to identify genotypes with desirable traits that could serve as parents in the corresponding breeding programs. A set of 36 bean genotypes belonging to the Middle American gene pool were evaluated under field conditions with two levels of water supply (irrigated and drought) over two seasons. Eight bean lines (NCB 280, NCB 226, SEN 56, SCR 2, SCR 16, SMC 141, RCB 593, and BFS 67) were identified as resistant to drought stress. Resistance to terminal drought stress was positively associated with EUW combined with increased dry matter partitioned to pod and seed production and negatively associated with days to flowering and days to physiological maturity. Differences in genotypic response were observed between grain CID and grain yield under irrigated and drought stress. Based on phenotypic differences in CID, leaf stomatal conductance, canopy biomass, and grain yield under drought stress, the lines tested were classified into two
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Salinity controls on plant transpiration and soil water balance
NASA Astrophysics Data System (ADS)
Perri, S.; Molini, A.; Suweis, S. S.; Viola, F.; Entekhabi, D.
2017-12-01
Soil salinization and aridification represent a major threat for the food security and sustainable development of drylands. The two problems are deeply connected, and their interplay is expected to be further enhanced by climate change and projected population growth. Salt-affected land is currently estimated to cover around 1.1 Gha, and is particularly widespread in semi-arid to hyper-arid climates. Over 900 Mha of these saline/sodic soils are potentially available for crop or biomass production. Salt-tolerant plants have been recently proposed as valid solution to exploit or even remediate salinized soils. However the effects of salinity on evapotranspiration, soil water balance and the long-term salt mass balance in the soil, are still largely unexplored. In this contribution we analyze the feedback of evapotranspiration on soil salinization, with particular emphasis on the role of vegetation and plant salt-tolerance. The goal is to introduce a simple modeling framework able to shed some light on how (a) soil salinity controls plant transpiration, and (b) salinization itself is favored/impeded by different vegetation feedback. We introduce at this goal a spatially lumped stochastic model of soil moisture and salt mass dynamics averaged over the active soil depth, and accounting for the effect of salinity on evapotranspiration. Here, the limiting effect of salinity on ET is modeled through a simple plant response function depending on both salt concentration in the soil and plant salt-tolerance. The coupled soil moisture and salt mass balance is hence used to obtain the conditional steady-state probability density function (pdf) of soil moisture for given salt tolerance and salinization level, Our results show that salinity imposes a limit in the soil water balance and this limit depends on plant salt-tolerance mainly through the control of the leaching occurrence (tolerant plants exploit water more efficiently than the sensitive ones). We also analyzed the
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Hydrological balance and water transport processes of partially sealed soils
NASA Astrophysics Data System (ADS)
Timm, Anne; Wessolek, Gerd
2017-04-01
With increased urbanisation, soil sealing and its drastic effects on hydrological processes have received a lot of attention. Based on safety concerns, there has been a clear focus on urban drainage and prevention of urban floods caused by storm water events. For this reason, any kind of sealing is often seen as impermeable runoff generator that prevents infiltration and evaporation. While many hydrological models, especially storm water models, have been developed, there are only a handful of empirical studies actually measuring the hydrological balance of (partially) sealed surfaces. These challenge the general assumption of negligible infiltration and evaporation and show that these processes take place even for severe sealing such as asphalt. Depending on the material, infiltration from partially sealed surfaces can be equal to that of vegetated ones. Therefore, more detailed knowledge is needed to improve our understanding and models. In Berlin, two partially sealed weighable lysimeters were equipped with multiple temperature and soil moisture sensors in order to study their hydrological balance, as well as water and heat transport processes within the soil profile. This combination of methods affirms previous observations and offers new insights into altered hydrological processes of partially sealed surfaces at a small temporal scale. It could be verified that not all precipitation is transformed into runoff. Even for a relatively high sealing degree of concrete slabs with narrow seams, evaporation and infiltration may exceed runoff. Due to the lack of plant roots, the hydrological balance is mostly governed by precipitation events and evaporation generally occurs directly after rainfall. However, both surfaces allow for upward water transport from the upper underlying soil layers, sometimes resulting in relatively low evaporation rates on days without precipitation. The individual response of the surfaces differs considerably, which illustrates how
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Evaluating Water Conservation and Reuse Policies Using a Dynamic Water Balance Model
NASA Astrophysics Data System (ADS)
Qaiser, Kamal; Ahmad, Sajjad; Johnson, Walter; Batista, Jacimaria R.
2013-02-01
A dynamic water balance model is created to examine the effects of different water conservation policies and recycled water use on water demand and supply in a region faced with water shortages and significant population growth, the Las Vegas Valley (LVV). The model, developed using system dynamics approach, includes an unusual component of the water system, return flow credits, where credits are accrued for returning treated wastewater to the water supply source. In LVV, Lake Mead serves as, both the drinking water source and the receiving body for treated wastewater. LVV has a consumptive use allocation from Lake Mead but return flow credits allow the water agency to pull out additional water equal to the amount returned as treated wastewater. This backdrop results in a scenario in which conservation may cause a decline in the available water supply. Current water use in LVV is 945 lpcd (250 gpcd), which the water agency aims to reduce to 752 lpcd (199 gpcd) by 2035, mainly through water conservation. Different conservation policies focused on indoor and outdoor water use, along with different population growth scenarios, are modeled for their effects on the water demand and supply. Major contribution of this study is in highlighting the importance of outdoor water conservation and the effectiveness of reducing population growth rate in addressing the future water shortages. The water agency target to decrease consumption, if met completely through outdoor conservation, coupled with lower population growth rate, can potentially satisfy the Valley's water demands through 2035.
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Evaluating water conservation and reuse policies using a dynamic water balance model.
Qaiser, Kamal; Ahmad, Sajjad; Johnson, Walter; Batista, Jacimaria R
2013-02-01
A dynamic water balance model is created to examine the effects of different water conservation policies and recycled water use on water demand and supply in a region faced with water shortages and significant population growth, the Las Vegas Valley (LVV). The model, developed using system dynamics approach, includes an unusual component of the water system, return flow credits, where credits are accrued for returning treated wastewater to the water supply source. In LVV, Lake Mead serves as, both the drinking water source and the receiving body for treated wastewater. LVV has a consumptive use allocation from Lake Mead but return flow credits allow the water agency to pull out additional water equal to the amount returned as treated wastewater. This backdrop results in a scenario in which conservation may cause a decline in the available water supply. Current water use in LVV is 945 lpcd (250 gpcd), which the water agency aims to reduce to 752 lpcd (199 gpcd) by 2035, mainly through water conservation. Different conservation policies focused on indoor and outdoor water use, along with different population growth scenarios, are modeled for their effects on the water demand and supply. Major contribution of this study is in highlighting the importance of outdoor water conservation and the effectiveness of reducing population growth rate in addressing the future water shortages. The water agency target to decrease consumption, if met completely through outdoor conservation, coupled with lower population growth rate, can potentially satisfy the Valley's water demands through 2035.
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NASA Astrophysics Data System (ADS)
Güntner, Andreas; Reich, Marvin; Mikolaj, Michal; Creutzfeldt, Benjamin; Schroeder, Stephan; Wziontek, Hartmut
2017-04-01
In spite of the fundamental role of the landscape water balance for the Earth's water and energy cycles, monitoring the water balance and its components beyond the point scale is notoriously difficult due to the multitude of flow and storage processes and their spatial heterogeneity. Here, we present the first deployment of an iGrav superconducting gravimeter (SG) in a minimized field enclosure on a grassland site for integrative monitoring of water storage changes. Results of the field SG were compared to data provided by a nearby SG located in the controlled environment of an observatory building. For wet-temperate climate conditions, the system proves to provide gravity time series that are similarly precise as those of the observatory SG. At the same time, the field SG is more sensitive to hydrological variations than the observatory SG. We demonstrate that the gravity variations observed by the field setup are almost independent of the depth below the terrain surface where water storage changes occur (contrary to SGs in buildings), and thus the field SG system directly observes the total water storage change, i.e., the water balance, in its surroundings in an integrative way. We provide a framework to single out the water balance components actual evapotranspiration and lateral subsurface discharge from the gravity time series on annual to daily time scales. With about 99% and 85% of the gravity signal originating within a radius of 4000 and 200 meter around the instrument, respectively, this setup paves the road towards gravimetry as a continuous hydrological field monitoring technique at the landscape scale.
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NASA Astrophysics Data System (ADS)
Wu, Guocan; Zheng, Xiaogu; Dan, Bo
2016-04-01
The shallow soil moisture observations are assimilated into Common Land Model (CoLM) to estimate the soil moisture in different layers. The forecast error is inflated to improve the analysis state accuracy and the water balance constraint is adopted to reduce the water budget residual in the assimilation procedure. The experiment results illustrate that the adaptive forecast error inflation can reduce the analysis error, while the proper inflation layer can be selected based on the -2log-likelihood function of the innovation statistic. The water balance constraint can result in reducing water budget residual substantially, at a low cost of assimilation accuracy loss. The assimilation scheme can be potentially applied to assimilate the remote sensing data.
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Ion and water balance in Gryllus crickets during the first twelve hours of cold exposure.
Des Marteaux, Lauren E; Sinclair, Brent J
2016-06-01
Insects lose ion and water balance during chilling, but the mechanisms underlying this phenomenon are based on patterns of ion and water balance observed in the later stages of cold exposure (12 or more hours). Here we quantified the distribution of ions and water in the hemolymph, muscle, and gut in adult Gryllus field crickets during the first 12h of cold exposure to test mechanistic hypotheses about why homeostasis is lost in the cold, and how chill-tolerant insects might maintain homeostasis to lower temperatures. Unlike in later chill coma, hemolymph [Na(+)] and Na(+) content in the first few hours of chilling actually increased. Patterns of Na(+) balance suggest that Na(+) migrates from the tissues to the gut lumen via the hemolymph. Imbalance of [K(+)] progressed gradually over 12h and could not explain chill coma onset (a finding consistent with recent studies), nor did it predict survival or injury following 48h of chilling. Gryllus veletis avoided shifts in muscle and hemolymph ion content better than Gryllus pennsylvanicus (which is less chill-tolerant), however neither species defended water, [Na(+)], or [K(+)] balance during the first 12h of chilling. Gryllus veletis better maintained balance of Na(+) content and may therefore have greater tissue resistance to ion leak during cold exposure, which could partially explain faster chill coma recovery for that species. Copyright © 2016 Elsevier Ltd. All rights reserved.
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Quinn, Cristina L; van der Heijden, Stephan A; Wania, Frank; Jonker, Michiel T O
2014-05-20
Whereas octanol, triacylglycerides, and liposomes have all been proposed as surrogates for measuring the affinity of hydrophobic organic contaminants to human lipids, no comparative evaluation of their suitability exists. Here we conducted batch sorption experiments with polyoxymethylene passive samplers to determine the partition coefficients at 37 °C of 18 polychlorinated biphenyls (PCBs) from water into (i) triolein (Ktriolein/water), (ii) eight types of liposomes (Kliposome/water), (iii) human abdominal fat tissues (KAFT/water) from seven individuals, and (iv) human MCF-7 cells cultured in vitro (Kcell/water). Differences between KAFT/water among individuals and between Kliposome/water among liposome types were very small and not correlated to structural attributes of the PCBs. Similarly, the length and degree of saturation of the phospholipid carbon chains, the headgroup, and the composition of the liposome did not affect the partitioning of PCBs into the studied liposomes. Whereas Kliposome/water values were similar to literature values of Koctanol/water adjusted to 37 °C, they both were lower than KAFT/water and Kcell/water by a factor of 3 on average. Partitioning of PCBs into triolein on the other hand closely mimicked that into human lipids, for which triolein is thus a better surrogate than either octanol or liposomes. Previously published polyparameter linear free energy relationships for partitioning from water into storage lipids and liposomes predicted the measured partition coefficients with a root-mean-square error of less than 0.15 log units, if the chosen equations and solute descriptors do not allow chlorine substitution in the ortho-position to influence the prediction. By guiding the selection of (i) a surrogate for the experimental determination and (ii) a method for the prediction of partitioning into human lipids, this study contributes to a better assessment of hydrophobic organic contaminant bioaccumulation in humans.
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Gros, Jonas; Reddy, Christopher M; Nelson, Robert K; Socolofsky, Scott A; Arey, J Samuel
2016-07-19
With the expansion of offshore petroleum extraction, validated models are needed to simulate the behaviors of petroleum compounds released in deep (>100 m) waters. We present a thermodynamic model of the densities, viscosities, and gas-liquid-water partitioning of petroleum mixtures with varying pressure, temperature, and composition based on the Peng-Robinson equation-of-state and the modified Henry's law (Krychevsky-Kasarnovsky equation). The model is applied to Macondo reservoir fluid released during the Deepwater Horizon disaster, represented with 279-280 pseudocomponents, including 131-132 individual compounds. We define >n-C8 pseudocomponents based on comprehensive two-dimensional gas chromatography (GC × GC) measurements, which enable the modeling of aqueous partitioning for n-C8 to n-C26 fractions not quantified individually. Thermodynamic model predictions are tested against available laboratory data on petroleum liquid densities, gas/liquid volume fractions, and liquid viscosities. We find that the emitted petroleum mixture was ∼29-44% gas and ∼56-71% liquid, after cooling to local conditions near the broken Macondo riser stub (∼153 atm and 4.3 °C). High pressure conditions dramatically favor the aqueous dissolution of C1-C4 hydrocarbons and also influence the buoyancies of bubbles and droplets. Additionally, the simulated densities of emitted petroleum fluids affect previous estimates of the volumetric flow rate of dead oil from the emission source.
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NASA Astrophysics Data System (ADS)
Wright, N.; Polashenski, C. M.; Deeb, E. J.; Morriss, B. F.; Song, A.; Chen, J.
2015-12-01
One of the key processes controlling sea ice mass balance in the Arctic is the partitioning of solar energy between reflection back to the atmosphere and absorption into the ice and upper ocean. We investigate the solar energy balance in the ice-ocean system using in-situ data collected from Arctic Observing Network (AON) sea ice sites and imagery from high resolution optical satellites. AON assets, including ice mass balance buoys and ice tethered profilers, monitor the storage and fluxes of heat in the ice-ocean system. High resolution satellite imagery, processed using object-based image classification techniques, allows us to quantify the evolution of surrounding ice conditions, including melt pond coverage and floe size distribution, at aggregate scale. We present results from regionally representative sites that constrain the partitioning of absorbed solar energy between ice melt and ocean storage, and quantify the strength of the ice-albedo feedback. We further demonstrate how the results can be used to validate model representations of the physical processes controlling ice-albedo feedbacks. The techniques can be extended to understand solar partitioning across the Arctic basin using additional sites and model based data integration.
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NASA Astrophysics Data System (ADS)
Güntner, Andreas; Reich, Marvin; Mikolaj, Michal; Creutzfeldt, Benjamin; Schroeder, Stephan; Wziontek, Hartmut
2017-06-01
In spite of the fundamental role of the landscape water balance for the Earth's water and energy cycles, monitoring the water balance and its components beyond the point scale is notoriously difficult due to the multitude of flow and storage processes and their spatial heterogeneity. Here, we present the first field deployment of an iGrav superconducting gravimeter (SG) in a minimized enclosure for long-term integrative monitoring of water storage changes. Results of the field SG on a grassland site under wet-temperate climate conditions were compared to data provided by a nearby SG located in the controlled environment of an observatory building. The field system proves to provide gravity time series that are similarly precise as those of the observatory SG. At the same time, the field SG is more sensitive to hydrological variations than the observatory SG. We demonstrate that the gravity variations observed by the field setup are almost independent of the depth below the terrain surface where water storage changes occur (contrary to SGs in buildings), and thus the field SG system directly observes the total water storage change, i.e., the water balance, in its surroundings in an integrative way. We provide a framework to single out the water balance components actual evapotranspiration and lateral subsurface discharge from the gravity time series on annual to daily timescales. With about 99 and 85 % of the gravity signal due to local water storage changes originating within a radius of 4000 and 200 m around the instrument, respectively, this setup paves the road towards gravimetry as a continuous hydrological field-monitoring technique at the landscape scale.
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NASA Astrophysics Data System (ADS)
Wrzesien, M.; Durand, M. T.; Pavelsky, T.
2017-12-01
The hydrologic cycle is a key component of many aspects of daily life, yet not all water cycle processes are fully understood. In particular, water storage in mountain snowpacks remains largely unknown. Previous work with a high resolution regional climate model suggests that global and continental models underestimate mountain snow accumulation, perhaps by as much as 50%. Therefore, we hypothesize that since snow water equivalent (one aspect of the water balance) is underestimated, accepted water balances for major river basins are likely wrong, particularly for mountainous river basins. Here we examine water balances for four major high latitude North American watersheds - the Columbia, Mackenzie, Nelson, and Yukon. The mountainous percentage of each basin ranges, which allows us to consider whether a bias in the water balance is affected by mountain area percentage within the watershed. For our water balance evaluation, we especially consider precipitation estimates from a variety of datasets, including models, such as WRF and MERRA, and observation-based, such as CRU and GPCP. We ask whether the precipitation datasets provide enough moisture for seasonal snow to accumulate within the basin and whether we see differences in the variability of annual and seasonal precipitation from each dataset. From our reassessment of high-latitude water balances, we aim to determine whether the current understanding is sufficient to describe all processes within the hydrologic cycle or whether datasets appear to be biased, particularly in high-elevation precipitation. Should currently-available datasets appear to be similarly biased in precipitation, as we have seen in mountain snow accumulation, we discuss the implications for the continental water budget.
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Assessment of Seasonal Water Balance Components over India Using Macroscale Hydrological Model
NASA Astrophysics Data System (ADS)
Joshi, S.; Raju, P. V.; Hakeem, K. A.; Rao, V. V.; Yadav, A.; Issac, A. M.; Diwakar, P. G.; Dadhwal, V. K.
2016-12-01
Hydrological models provide water balance components which are useful for water resources assessment and for capturing the seasonal changes and impact of anthropogenic interventions and climate change. The study under description is a national level modeling framework for country India using wide range of geo-spatial and hydro-meteorological data sets for estimating daily Water Balance Components (WBCs) at 0.15º grid resolution using Variable Infiltration Capacity model. The model parameters were optimized through calibration of model computed stream flow with field observed yielding Nash-Sutcliffe efficiency between 0.5 to 0.7. The state variables, evapotranspiration (ET) and soil moisture were also validated, obtaining R2 values of 0.57 and 0.69, respectively. Using long-term meteorological data sets, model computation were carried to capture hydrological extremities. During 2013, 2014 and 2015 monsoon seasons, WBCs were estimated and were published in web portal with 2-day time lag. In occurrence of disaster events, weather forecast was ingested, high surface runoff zones were identified for forewarning and disaster preparedness. Cumulative monsoon season rainfall of 2013, 2014 and 2015 were 105, 89 and 91% of long period average (LPA) respectively (Source: India Meteorological Department). Analysis of WBCs indicated that corresponding seasonal surface runoff was 116, 81 and 86% LPA and evapotranspiration was 109, 104 and 90% LPA. Using the grid-wise data, the spatial variation in WBCs among river basins/administrative regions was derived to capture the changes in surface runoff, ET between the years and in comparison with LPA. The model framework is operational and is providing periodic account of national level water balance fluxes which are useful for quantifying spatial and temporal variation in basin/sub-basin scale water resources, periodical water budgeting to form vital inputs for studies on water resources and climate change.
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A strategy to load balancing for non-connectivity MapReduce job
NASA Astrophysics Data System (ADS)
Zhou, Huaping; Liu, Guangzong; Gui, Haixia
2017-09-01
MapReduce has been widely used in large scale and complex datasets as a kind of distributed programming model. Original Hash partitioning function in MapReduce often results the problem of data skew when data distribution is uneven. To solve the imbalance of data partitioning, we proposes a strategy to change the remaining partitioning index when data is skewed. In Map phase, we count the amount of data which will be distributed to each reducer, then Job Tracker monitor the global partitioning information and dynamically modify the original partitioning function according to the data skew model, so the Partitioner can change the index of these partitioning which will cause data skew to the other reducer that has less load in the next partitioning process, and can eventually balance the load of each node. Finally, we experimentally compare our method with existing methods on both synthetic and real datasets, the experimental results show our strategy can solve the problem of data skew with better stability and efficiency than Hash method and Sampling method for non-connectivity MapReduce task.
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Bioimpedance measurement of body water correlates with measured volume balance in injured patients.
Rosemurgy, A S; Rodriguez, E; Hart, M B; Kurto, H Z; Albrink, M H
1993-06-01
Bioimpedance technology is being used increasingly to determine drug volume of distribution, body water status, and nutrition repletion. Its accuracy in patients experiencing large volume flux is not established. To address this, we undertook this prospective study in 54 consecutive seriously injured adults who had emergency celiotomy soon after arrival in the emergency department. Bioimpedance measurements were obtained in the emergency department before the patient was transported to the operating room, on completion of celiotomy, and 24 hours and 48 hours after celiotomy. Bioimpedance measurements of body water were compared with measured fluid balance. If insensible losses are subtracted from measured fluid balance, the percentage of body weight, which is body water determined by bioimpedance, closely follows fluid flux. This study supports the use of bioimpedance measurements in determining total body water even during periods of surgery, blood loss, and vigorous resuscitation.
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Scherrer, Robert A; Donovan, Stephen F
2009-04-01
The knowledge base of factors influencing ion pair partitioning is very sparse, primarily because of the difficulty in determining accurate log P(I) values of desirable low molecular weight (MW) reference compounds. We have developed a potentiometric titration procedure in KCl/water-saturated octanol that provides a link to log P(I) through the thermodynamic cycle of ionization and partitioning. These titrations have the advantage of being independent of the magnitude of log P, while maintaining a reproducibility of a few hundredths of a log P in the calculated difference between log P neutral and log P ion pair (diff (log P(N - I))). Simple model compounds can be used. The titration procedure is described in detail, along with a program for calculating pK(a)'' values incorporating the ionization of water in octanol. Hydrogen bonding and steric factors have a greater influence on ion pairs than they do on neutral species, yet these factors are missing from current programs used to calculate log P(I) and log D. In contrast to the common assumption that diff (log P(N - I)) is the same for all amines, they can actually vary more than 3 log units, as in our examples. A major factor affecting log P(I) is the ability of water and the counterion to approach the charge center. Bulky substituents near the charge center have a negative influence on log P(I). On the other hand, hydrogen bonding groups near the charge center have the opposite effect by lowering the free energy of the ion pair. The use of this titration method to determine substituent ion pair stabilization values (IPS) should bring about more accurate log D calculations and encourage species-specific QSAR involving log D(N) and log D(I). This work also brings attention to the fascinating world of nature's highly stabilized ion pairs.
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2009-01-01
The knowledge base of factors influencing ion pair partitioning is very sparse, primarily because of the difficulty in determining accurate log PI values of desirable low molecular weight (MW) reference compounds. We have developed a potentiometric titration procedure in KCl/water-saturated octanol that provides a link to log PI through the thermodynamic cycle of ionization and partitioning. These titrations have the advantage of being independent of the magnitude of log P, while maintaining a reproducibility of a few hundredths of a log P in the calculated difference between log P neutral and log P ion pair (diff (log PN − I)). Simple model compounds can be used. The titration procedure is described in detail, along with a program for calculating pKa′′ values incorporating the ionization of water in octanol. Hydrogen bonding and steric factors have a greater influence on ion pairs than they do on neutral species, yet these factors are missing from current programs used to calculate log PI and log D. In contrast to the common assumption that diff (log PN − I) is the same for all amines, they can actually vary more than 3 log units, as in our examples. A major factor affecting log PI is the ability of water and the counterion to approach the charge center. Bulky substituents near the charge center have a negative influence on log PI. On the other hand, hydrogen bonding groups near the charge center have the opposite effect by lowering the free energy of the ion pair. The use of this titration method to determine substituent ion pair stabilization values (IPS) should bring about more accurate log D calculations and encourage species-specific QSAR involving log DN and log DI. This work also brings attention to the fascinating world of nature’s highly stabilized ion pairs. PMID:19265385
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A worldwide analysis of trends in water-balance evapotranspiration
NASA Astrophysics Data System (ADS)
Ukkola, A. M.; Prentice, I. C.
2013-05-01
Climate change is expected to alter the global hydrological cycle, with inevitable consequences for freshwater availability to people and ecosystems. But the attribution of recent trends in the terrestrial water balance remains disputed. This study attempts to account statistically for both trends and interannual variability in water-balance evapotranspiration (ET), estimated from the annual observed streamflow in 109 river basins during "water years" 1961-1999 and two gridded precipitation datasets. The basins were chosen based on the availability of streamflow time-series data in the Dai et al. (2009) synthesis. They were divided into water-limited "dry" and energy-limited "wet" basins following the Budyko framework. We investigated the potential roles of precipitation, aerosol-corrected solar radiation, land-use change, wind speed, air temperature, and atmospheric CO2. Both trends and variability in ET show strong control by precipitation. There is some additional control of ET trends by vegetation processes, but little evidence for control by other factors. Interannual variability in ET was overwhelmingly dominated by precipitation, which accounted on average for 52-54% of the variation in wet basins (ranging from 0 to 99%) and 84-85% in dry basins (ranging from 13 to 100%). Precipitation accounted for 39-42% of ET trends in wet basins and 69-79% in dry basins. Cropland expansion increased ET in dry basins. Net atmospheric CO2 effects on transpiration, estimated using the Land-surface Processes and eXchanges (LPX) model, did not contribute to observed trends in ET because declining stomatal conductance was counteracted by slightly but significantly increasing foliage cover.
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A worldwide analysis of trends in water-balance evapotranspiration
NASA Astrophysics Data System (ADS)
Ukkola, A. M.; Prentice, I. C.
2013-10-01
Climate change is expected to alter the global hydrological cycle, with inevitable consequences for freshwater availability to people and ecosystems. But the attribution of recent trends in the terrestrial water balance remains disputed. This study attempts to account statistically for both trends and interannual variability in water-balance evapotranspiration (ET), estimated from the annual observed streamflow in 109 river basins during "water years" 1961-1999 and two gridded precipitation data sets. The basins were chosen based on the availability of streamflow time-series data in the Dai et al. (2009) synthesis. They were divided into water-limited "dry" and energy-limited "wet" basins following the Budyko framework. We investigated the potential roles of precipitation, aerosol-corrected solar radiation, land use change, wind speed, air temperature, and atmospheric CO2. Both trends and variability in ET show strong control by precipitation. There is some additional control of ET trends by vegetation processes, but little evidence for control by other factors. Interannual variability in ET was overwhelmingly dominated by precipitation, which accounted on average for 54-55% of the variation in wet basins (ranging from 0 to 100%) and 94-95% in dry basins (ranging from 69 to 100%). Precipitation accounted for 45-46% of ET trends in wet basins and 80-84% in dry basins. Net atmospheric CO2 effects on transpiration, estimated using the Land-surface Processes and eXchanges (LPX) model, did not contribute to observed trends in ET because declining stomatal conductance was counteracted by slightly but significantly increasing foliage cover.
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Pilcher, C M; Arentson, R; Patience, J F
2015-03-01
The objective of this study was to determine if a higher-fiber diet alters the response of finishing pigs to an antimicrobial (tylosin phosphate [TP]) and a nutrient partitioning agent (ractopamine HCl [RAC]) in terms of N and water utilization and energy digestibility. Seventy-two gilts (initial BW = 107.4 ± 4.2 kg) were blocked by weight and allotted to 1 of 8 dietary treatments. Treatments were arranged as a 2 × 2 × 2 factorial: distillers dried grains with solubles (DDGS; 0 vs. 30%), RAC (0 mg of RAC/kg and 0.70% standardized ileal digestible [SID] Lys vs. 5 mg of RAC/kg and 0.95% SID Lys) and TP (0 vs. 44 mg of TP/kg). Pig was the experimental unit, with 9 replications per treatment. Pigs were housed in individual metabolism crates and fed treatment diets for 17 d. Feed was provided twice daily, as much as the pigs could consume within 1 h per meal, and water was provided to the pigs between feeding periods, ad libitum. Fecal and urine collection occurred on d 7 and 8 and on d 15 and 16, for sampling periods 1 and 2, respectively. Pigs fed the DDGS diets had reduced ADG ( < 0.001) and ADFI ( < 0.0001). The apparent total tract digestibility (ATTD) of N and GE were lower for the 30% DDGS diets than the 0% DDGS diets ( < 0.0001). Ractopamine improved ADG ( < 0.0001), G:F ( < 0.0001), and N retention ( < 0.001) and tended to increase daily water intake ( < 0.10). Pigs fed RAC had higher N intake and urinary excretion and lower N retention in Period 2 than in Period 1 ( < 0.05), indicating a decline in the response to RAC over time. Tylosin phosphate did not affect ADFI or G:F but did improve ATTD of N ( < 0.05). There was a tendency for a TP × DDGS interaction ( < 0.10) for ADG, where TP tended to increase ADG in pigs fed 0% DDGS diets ( < 0.10) but not in pigs fed 30% DDGS diets ( > 0.10). Pigs fed DDGS diets had higher N intake ( < 0.01) and higher fecal ( < 0.0001) and urinary ( < 0.01) N excretion with no difference in N retention (g/d). Overall, RAC
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Task-specific image partitioning.
Kim, Sungwoong; Nowozin, Sebastian; Kohli, Pushmeet; Yoo, Chang D
2013-02-01
Image partitioning is an important preprocessing step for many of the state-of-the-art algorithms used for performing high-level computer vision tasks. Typically, partitioning is conducted without regard to the task in hand. We propose a task-specific image partitioning framework to produce a region-based image representation that will lead to a higher task performance than that reached using any task-oblivious partitioning framework and existing supervised partitioning framework, albeit few in number. The proposed method partitions the image by means of correlation clustering, maximizing a linear discriminant function defined over a superpixel graph. The parameters of the discriminant function that define task-specific similarity/dissimilarity among superpixels are estimated based on structured support vector machine (S-SVM) using task-specific training data. The S-SVM learning leads to a better generalization ability while the construction of the superpixel graph used to define the discriminant function allows a rich set of features to be incorporated to improve discriminability and robustness. We evaluate the learned task-aware partitioning algorithms on three benchmark datasets. Results show that task-aware partitioning leads to better labeling performance than the partitioning computed by the state-of-the-art general-purpose and supervised partitioning algorithms. We believe that the task-specific image partitioning paradigm is widely applicable to improving performance in high-level image understanding tasks.
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NASA Astrophysics Data System (ADS)
Chiaradia, Enrico Antonio; Romani, Marco; Facchi, Arianna; Gharsallah, Olfa; Cesari de Maria, Sandra; Ferrari, Daniele; Masseroni, Daniele; Rienzner, Michele; Battista Bischetti, Gian; Gandolfi, Claudio
2014-05-01
In the agricultural seasons 2012 and 2013, a broad monitoring activity was carried out at the Rice Research Centre of Ente Nazionale Risi (CRR-ENR) located in Castello d'Agogna (PV, Italy) with the purpose of comparing the water balance components of paddy rice (Gladio cv.) under different water regimes and assessing the possibility of reducing the high water inputs related to the conventional practice of continuous submergence. The experiments were laid out in six plots of about 20 m x 80 m each, with two replicates for each of the following water regimes: i) continuous flooding with wet-seeded rice (FLD), ii) continuous flooding from around the 3-leaf stage with dry-seeded rice (3L-FLD), and iii) surface irrigation every 7-10 days with dry-seeded rice (IRR). One out of the two replicates of each treatment was instrumented with: water inflow and outflow meters, set of piezometers, set of tensiometers and multi-sensor moisture probes. Moreover, an eddy covariance station was installed on the bund between the treatments FLD and IRR. Data were automatically recorded and sent by a wireless connection to a PC, so as to be remotely controlled thanks to the development of a Java interface. Furthermore, periodic measurements of crop biometric parameters (LAI, crop height and rooting depth) were performed in both 2012 and 2013 (11 and 14 campaigns respectively). Cumulative water balance components from dry-seeding (3L-FLD and IRR), or flooding (FLD), to harvest were calculated for each plot by either measurements (i.e. rainfall, irrigation and surface drainage) or estimations (i.e. difference in the field water storage, evaporation from both the soil and the water surface and transpiration), whereas the sum of percolation and capillary rise (i.e. the 'net percolation') was obtained as the residual term of the water balance. Incidentally, indices of water application efficiency (evapotranspiration over net water input) and water productivity (grain production over net water
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Pintado-Herrera, Marina G; Lara-Martín, Pablo A; González-Mazo, Eduardo; Allan, Ian J
2016-09-01
There is a growing interest in assessing the concentration and distribution of new nonregulated organic compounds (emerging contaminants) in the environment. The measurement of freely dissolved concentrations using conventional approaches is challenging because of the low concentrations that may be encountered and their temporally variable emissions. Absorption-based passive sampling enables the estimation of freely dissolved concentrations of hydrophobic contaminants of emerging concern in water. In the present study, calibration was undertaken for 2 polymers, low-density polyethylene (LDPE) and silicone rubber for 11 fragrances, 5 endocrine-disrupting compounds, 7 ultraviolet (UV) filters, and 8 organophosphate flame retardant compounds. Batch experiments were performed to estimate contaminant diffusion coefficients in the polymers (Dp ), which in general decreased with increasing molecular weight. The values for fragrances, endocrine-disrupting compounds, and UV filters were in ranges similar to those previously reported for polycyclic aromatic hydrocarbons, but were 1 order of magnitude lower for organophosphate flame retardant compounds. Silicone rubber had higher Dp values than LDPE and was therefore selected for further experiments to calculate polymer/water partition coefficients (KPW ). The authors observed a positive correlation between log KPW and log octanol/water partition coefficient values. Field testing of silicone rubber passive samplers was undertaken though exposure in the River Alna (Norway) for an exposure time of 21 d to estimate freely dissolved concentration. Some fragrances and UV filters were predominant over other emerging and regulated contaminants, at levels up to 1600 ng L(-1) for galaxolide and 448 ng L(-1) for octocrylene. Environ Toxicol Chem 2016;35:2162-2172. © 2016 SETAC. © 2016 SETAC.
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Water temperature, voluntary drinking and fluid balance in dehydrated taekwondo athletes.
Khamnei, Saeed; Hosseinlou, Abdollah; Zamanlu, Masumeh
2011-01-01
Voluntary drinking is one of the major determiners of rehydration, especially as regards exercise or workout in the heat. The present study undertakes to search for the effect of voluntary intake of water with different temperatures on fluid balance in Taekwondo athletes. Six young healthy male Taekwondo athletes were dehydrated by moderate exercise in a chamber with ambient temperature at 38-40°C and relative humidity between 20-30%. On four separate days they were allowed to drink ad libitum plane water with the four temperatures of 5, 16, 26, and 58°C, after dehydration. The volume of voluntary drinking and weight change was measured; then the primary percentage of dehydration, sweat loss, fluid deficit and involuntary dehydration were calculated. Voluntary drinking of water proved to be statistically different in the presented temperatures. Water at 16°C involved the greatest intake, while fluid deficit and involuntary dehydration were the lowest. Intake of water in the 5°C trial significantly correlated with the subject's plasma osmolality change after dehydration, yet it showed no significant correlation with weight loss. In conclusion, by way of achieving more voluntary intake of water and better fluid state, recommending cool water (~16°C) for athletes is in order. Unlike the publicly held view, drinking cold water (~5°C) does not improve voluntary drinking and hydration status. Key pointsFor athletes dehydrated in hot environments, maximum voluntary drinking and best hydration state occurs with 16°C water.Provision of fluid needs and thermal needs could be balanced using 16°C water.Drinking 16°C water (nearly the temperature of cool tap water) could be recommended for exercise in the heat.
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Abatzoglou, John T; Dobrowski, Solomon Z; Parks, Sean A; Hegewisch, Katherine C
2018-01-09
We present TerraClimate, a dataset of high-spatial resolution (1/24°, ~4-km) monthly climate and climatic water balance for global terrestrial surfaces from 1958-2015. TerraClimate uses climatically aided interpolation, combining high-spatial resolution climatological normals from the WorldClim dataset, with coarser resolution time varying (i.e., monthly) data from other sources to produce a monthly dataset of precipitation, maximum and minimum temperature, wind speed, vapor pressure, and solar radiation. TerraClimate additionally produces monthly surface water balance datasets using a water balance model that incorporates reference evapotranspiration, precipitation, temperature, and interpolated plant extractable soil water capacity. These data provide important inputs for ecological and hydrological studies at global scales that require high spatial resolution and time varying climate and climatic water balance data. We validated spatiotemporal aspects of TerraClimate using annual temperature, precipitation, and calculated reference evapotranspiration from station data, as well as annual runoff from streamflow gauges. TerraClimate datasets showed noted improvement in overall mean absolute error and increased spatial realism relative to coarser resolution gridded datasets.
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NASA Astrophysics Data System (ADS)
Abatzoglou, John T.; Dobrowski, Solomon Z.; Parks, Sean A.; Hegewisch, Katherine C.
2018-01-01
We present TerraClimate, a dataset of high-spatial resolution (1/24°, ~4-km) monthly climate and climatic water balance for global terrestrial surfaces from 1958-2015. TerraClimate uses climatically aided interpolation, combining high-spatial resolution climatological normals from the WorldClim dataset, with coarser resolution time varying (i.e., monthly) data from other sources to produce a monthly dataset of precipitation, maximum and minimum temperature, wind speed, vapor pressure, and solar radiation. TerraClimate additionally produces monthly surface water balance datasets using a water balance model that incorporates reference evapotranspiration, precipitation, temperature, and interpolated plant extractable soil water capacity. These data provide important inputs for ecological and hydrological studies at global scales that require high spatial resolution and time varying climate and climatic water balance data. We validated spatiotemporal aspects of TerraClimate using annual temperature, precipitation, and calculated reference evapotranspiration from station data, as well as annual runoff from streamflow gauges. TerraClimate datasets showed noted improvement in overall mean absolute error and increased spatial realism relative to coarser resolution gridded datasets.
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Biomass burning and its effects on fine aerosol acidity, water content and nitrogen partitioning
NASA Astrophysics Data System (ADS)
Bougiatioti, Aikaterini; Nenes, Athanasios; Paraskevopoulou, Despina; Fourtziou, Luciana; Stavroulas, Iasonas; Liakakou, Eleni; Myriokefalitakis, Stelios; Daskalakis, Nikos; Weber, Rodney; Kanakidou, Maria; Gerasopoulos, Evangelos; Mihalopoulos, Nikolaos
2017-04-01
Aerosol acidity is an important property that drives the partitioning of semi-volatile species, the formation of secondary particulate matter and metal and nutrient solubility. Aerosol acidity varies considerably between aerosol types, RH, temperature, the degree of atmospheric chemical aging and may also change during transport. Among aerosol different sources, sea salt and dust have been well studied and their impact on aerosol acidity and water uptake is more or less understood. Biomass burning (BB) on the other hand, despite its significance as a source in a regional and global scale, is much less understood. Currently, there is no practical and accurate enough method, to directly measure the pH of in-situ aerosol. The combination of thermodynamic models, with targeted experimental observations can provide reliable predictions of aerosol particle water and pH, using as input the concentration of gas/aerosol species, temperature (T), and relative humidity (RH). As such an example, ISORROPIA-II (Fountoukis and Nenes, 2007) has been used for the thermodynamic analysis of measurements conducted in downtown Athens during winter 2013, in order to evaluate the effect of BB on aerosol water and acidity. Biomass burning, especially during night time, was found to contribute significantly to the increased organics concentrations, but as well to the BC component associated with wood burning, particulate nitrates, chloride, and potassium. These increased concentrations were found to impact on fine aerosol water, with Winorg having an average concentration of 11±14 μg m-3 and Worg 12±19 μg m-3 with the organic component constituting almost 38% of the total calculated submicron water. When investigating the fine aerosol acidity it was derived that aerosol was generally acidic, with average pH during strong BB influence of 2.8±0.5, value similar to the pH observed for regional aerosol influenced by important biomass burning episodes at the remote background site of
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The Effect of Obstacle Training in Water on Static Balance of Chronic Stroke Patients
Jung, JaeHyun; Lee, JiYeun; Chung, EunJung; Kim, Kyoung
2014-01-01
[Purpose] This study evaluated the effects of water and land-based obstacle training on static balance of chronic stroke patients. [Subjects] The subjects were randomly allocated to an aqua group (n=15) and a land group (n=15). [Methods] Both groups trained for 40 minutes, 3 times a week for 12 weeks. Static balance was assessed by measuring the mean velocities of mediolateral (ML) and anteroposterior (AP), and sway area with the eyes closed. [Results] Following the intervention, both groups showed significant changes in ML velocity, AP velocity, and sway area. The static balance of the aqua group was significantly better than the land group. [Conclusion] The results of this study suggest the feasibility and suitability of obstacle training in water for stroke patients. PMID:24707102
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NASA Astrophysics Data System (ADS)
Juniati, A. T.; Sutjiningsih, D.; Soeryantono, H.; Kusratmoko, E.
2018-01-01
The water availability (WA) of a region is one of important consideration in both the formulation of spatial plans and the evaluation of the effectiveness of actual land use in providing sustainable water resources. Information on land-water needs vis-a-vis their availability in a region determines the state of the surplus or deficit to inform effective land use utilization. How to calculate water availability have been described in the Guideline in Determining the Carrying Capacity of the Environment in Regional Spatial Planning. However, the method of determining the supply and demand of water on these guidelines is debatable since the determination of WA in this guideline used a rational method. The rational method is developed the basis for storm drain design practice and it is essentially a peak discharge method peak discharge calculation method. This paper review the literature in methods of water availability estimation which is described descriptively, and present arguments to claim that water balance method is a more fundamental and appropriate tool in water availability estimation. A better water availability estimation method would serve to improve the practice in preparing formulations of Regional Spatial Plan (RSP) as well as evaluating land use capacity in providing sustainable water resources.
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Mauder, Matthias; Genzel, Sandra; Fu, Jin; ...
2017-11-10
Here, we report non-closure of the surface energy balance is a frequently observed phenomenon of hydrometeorological field measurements, when using the eddy-covariance method, which can be ascribed to an underestimation of the turbulent fluxes. Several approaches have been proposed in order to adjust the measured fluxes for this apparent systematic error. However, there are uncertainties about partitioning of the energy balance residual between the sensible and latent heat flux and whether such a correction should be applied on 30-minute data or longer time scales. The data for this study originate from two grassland sites in southern Germany, where measurements frommore » weighable lysimeters are available as reference. The adjusted evapotranspiration rates are also compared with joint energy and water balance simulations using a physically-based distributed hydrological model. We evaluate two adjustment methods: the first one preserves the Bowen ratio and the correction factor is determined on a daily basis. The second one attributes a smaller portion of the residual energy to the latent heat flux than to the sensible heat flux for closing the energy balance for every 30-minute flux integration interval. Both methods lead to an improved agreement of the eddy-covariance based fluxes with the independent lysimeter estimates and the physically-based model simulations. The first method results in a better comparability of evapotranspiration rates, and the second method leads to a smaller overall bias. These results are similar between both sites despite considerable differences in terrain complexity and grassland management. Moreover, we found that a daily adjustment factor leads to less scatter than a complete partitioning of the residual for every half-hour time interval. Lastly, the vertical temperature gradient in the surface layer and friction velocity were identified as important predictors for a potential future parameterization of the energy balance
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Mauder, Matthias; Genzel, Sandra; Fu, Jin
Here, we report non-closure of the surface energy balance is a frequently observed phenomenon of hydrometeorological field measurements, when using the eddy-covariance method, which can be ascribed to an underestimation of the turbulent fluxes. Several approaches have been proposed in order to adjust the measured fluxes for this apparent systematic error. However, there are uncertainties about partitioning of the energy balance residual between the sensible and latent heat flux and whether such a correction should be applied on 30-minute data or longer time scales. The data for this study originate from two grassland sites in southern Germany, where measurements frommore » weighable lysimeters are available as reference. The adjusted evapotranspiration rates are also compared with joint energy and water balance simulations using a physically-based distributed hydrological model. We evaluate two adjustment methods: the first one preserves the Bowen ratio and the correction factor is determined on a daily basis. The second one attributes a smaller portion of the residual energy to the latent heat flux than to the sensible heat flux for closing the energy balance for every 30-minute flux integration interval. Both methods lead to an improved agreement of the eddy-covariance based fluxes with the independent lysimeter estimates and the physically-based model simulations. The first method results in a better comparability of evapotranspiration rates, and the second method leads to a smaller overall bias. These results are similar between both sites despite considerable differences in terrain complexity and grassland management. Moreover, we found that a daily adjustment factor leads to less scatter than a complete partitioning of the residual for every half-hour time interval. Lastly, the vertical temperature gradient in the surface layer and friction velocity were identified as important predictors for a potential future parameterization of the energy balance
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Modeling the Monthly Water Balance of a First Order Coastal Forested Watershed
S. V. Harder; Devendra M. Amatya; T. J. Callahan; Carl C. Trettin
2006-01-01
A study has been conducted to evaluate a spreadsheet-based conceptual Thornthwaite monthly water balance model and the process-based DRAINMOD model for their reliability in predicting monthly water budgets of a poorly drained, first order forested watershed at the Santee Experimental Forest located along the Lower Coastal Plain of South Carolina. Measured precipitation...
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USDA-ARS?s Scientific Manuscript database
Correct prediction of the dynamics of total available water in the root zone (TAWr) is critical for irrigation management as shown in the soil water balance model presented in FAO paper 56 (Allen et al., 1998). In this study, we propose a framework to improve TAWr estimation by incorporating the cro...
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Partition of some key regulating services in terrestrial ecosystems: Meta-analysis and review.
Viglizzo, E F; Jobbágy, E G; Ricard, M F; Paruelo, J M
2016-08-15
Our knowledge about the functional foundations of ecosystem service (ES) provision is still limited and more research is needed to elucidate key functional mechanisms. Using a simplified eco-hydrological scheme, in this work we analyzed how land-use decisions modify the partition of some essential regulatory ES by altering basic relationships between biomass stocks and water flows. A comprehensive meta-analysis and review was conducted based on global, regional and local data from peer-reviewed publications. We analyzed five datasets comprising 1348 studies and 3948 records on precipitation (PPT), aboveground biomass (AGB), AGB change, evapotranspiration (ET), water yield (WY), WY change, runoff (R) and infiltration (I). The conceptual framework was focused on ES that are associated with the ecological functions (e.g., intermediate ES) of ET, WY, R and I. ES included soil protection, carbon sequestration, local climate regulation, water-flow regulation and water recharge. To address the problem of data normality, the analysis included both parametric and non-parametric regression analysis. Results demonstrate that PPT is a first-order biophysical factor that controls ES release at the broader scales. At decreasing scales, ES are partitioned as result of PPT interactions with other biophysical and anthropogenic factors. At intermediate scales, land-use change interacts with PPT modifying ES partition as it the case of afforestation in dry regions, where ET and climate regulation may be enhanced at the expense of R and water-flow regulation. At smaller scales, site-specific conditions such as topography interact with PPT and AGB displaying different ES partition formats. The probable implications of future land-use and climate change on some key ES production and partition are discussed. Copyright © 2016 Elsevier B.V. All rights reserved.
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Partitioning of fluorotelomer alcohols to octanol and different sources of dissolved organic carbon.
Carmosini, Nadia; Lee, Linda S
2008-09-01
Interest in the environmental fate of fluorotelomer alcohols (FTOHs) has spurred efforts to understand their equilibrium partitioning behavior. Experimentally determined partition coefficients for FTOHs between soil/water and air/water have been reported, but direct measurements of partition coefficients for dissolved organic carbon (DOC)/water (K(doc)) and octanol/ water(K(ow)) have been lacking. Here we measured the partitioning of 8:2 and 6:2 FTOH between one or more types of DOC and water using enhanced solubility or dialysis bag techniques, and also quantified K(ow) values for 4:2 to 8:2 FTOH using a batch equilibration method. The range in measured log K(doc) values for 8:2 FTOH using the enhanced solubility technique with DOC derived from two soils, two biosolids, and three reference humic acids is 2.00-3.97 with the lowest values obtained for the biosolids and an average across all other DOC sources (biosolid DOC excluded) of 3.54 +/- 0.29. For 6:2 FTOH and Aldrich humic acid, a log K(doc) value of 1.96 +/- 0.45 was measured using the dialysis technique. These average values are approximately 1 to 2 log units lower than previously indirectly estimated K(doc) values. Overall, the affinity for DOC tends to be slightly lower than that for particulate soil organic carbon. Measured log K(ow) values for 4:2 (3.30 +/- 0.04), 6:2 (4.54 +/- 0.01), and 8:2 FTOH (5.58 +/- 0.06) were in good agreement with previously reported estimates. Using relationships between experimentally measured partition coefficients and C-atom chain length, we estimated K(doc) and K(ow) values for shorter and longer chain FTOHs, respectively, that we were unable to measure experimentally.
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Partitioning of a Falling Droplet's Energy After Surface Impact
NASA Astrophysics Data System (ADS)
Kern, Vanessa; Steen, Paul
2017-11-01
Understanding energy partitioning post-impact is a first step to understanding immersive flow-forming processes. Here we investigate the partitioning of kinetic energy into surface energies for capillary water droplets falling onto homogeneous prepared hydrophilic, hydrophobic and super-hydrophobic surfaces. We analyze high-speed images of the impact event. Pre-impact Weber numbers range from 0-15. After impact and initial spreading, the droplet's contact line pins. After pinning, there is a slow decay to the rest state. During this underdamped decay, the droplet's remaining kinetic energy partitions into a linear combination of mode shape energies. These mode shapes and their frequencies correspond to those of pinned sessile droplets from theory. The influence of impact energy on modes excited will be discussed.
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NASA Astrophysics Data System (ADS)
Chen, W. A.; Woods, C. P.; Li, J. F.; Waliser, D. E.; Chern, J.; Tao, W.; Jiang, J. H.; Tompkins, A. M.
2010-12-01
CloudSat provides important estimates of vertically resolved ice water content (IWC) on a global scale based on radar reflectivity. These estimates of IWC have proven beneficial in evaluating the representations of ice clouds in global models. An issue when performing model-data comparisons of IWC particularly germane to this investigation, is the question of which component(s) of the frozen water mass are represented by retrieval estimates and how they relate to what is represented in models. The present study developed and applied a new technique to partition CloudSat total IWC into small and large ice hydrometeors, based on the CloudSat-retrieved ice particle size distribution (PSD) parameters. The new method allows one to make relevant model-data comparisons and provides new insights into the model’s representation of atmospheric IWC. The partitioned CloudSat IWC suggests that the small ice particles contribute to 20-30% of the total IWC in the upper troposphere when a threshold size of 100 μm is used. Sensitivity measures with respect to the threshold size, the PSD parameters, and the retrieval algorithms are presented. The new dataset is compared to model estimates, pointing to areas for model improvement. Cloud ice analyses from the European Centre for Medium-Range Weather Forecasts model agree well with the small IWC from CloudSat. The finite-volume multi-scale modeling framework model underestimates total IWC at 147 and 215 hPa, while overestimating the fractional contribution from the small ice species. These results are discussed in terms of their applications to, and implications for, the evaluation of global atmospheric models, providing constraints on the representations of cloud feedback and precipitation in global models, which in turn can help reduce uncertainties associated with climate change projections. Figure 1. A sample lognormal ice number distribution (red curve), and the corresponding mass distribution (black curve). The dotted line
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Liang, Ximei; Chen, Baowei; Nie, Xiangping; Shi, Zhen; Huang, Xiaoping; Li, Xiangdong
2013-09-01
Antibiotics released into the aquatic environment play an important role in the spread of antibiotic resistance. In the Pearl River Estuary (PRE) and the coastal zone, the concentrations of antibiotics decreased from the Pearl River to the estuary, suggesting that antibiotics primarily originated from river tributaries and terrigenous sources. Within the PRE area, the concentrations of antibiotics in water were higher in the west coast than the east side, reflecting the high density of anthropogenic activities and hydraulic conditions along the west riverbank. Seasonal variations were also observed for most of detected antibiotics in water. The pseudo-partitioning coefficient of norfloxacin had a good correlation with the TOC content of sediments, as did erythromycin-H2O with the pH of water. The results suggest that environmental conditions can significantly affect the distribution of antibiotics between water and sediment. Copyright © 2013 Elsevier Ltd. All rights reserved.
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Potter, N.J.; Zhang, L.; Milly, P.C.D.; McMahon, T.A.; Jakeman, A.J.
2005-01-01
An important factor controlling catchment‐scale water balance is the seasonal variation of climate. The aim of this study is to investigate the effect of the seasonal distributions of water and energy, and their interactions with the soil moisture store, on mean annual water balance in Australia at catchment scales using a stochastic model of soil moisture balance with seasonally varying forcing. The rainfall regime at 262 catchments around Australia was modeled as a Poisson process with the mean storm arrival rate and the mean storm depth varying throughout the year as cosine curves with annual periods. The soil moisture dynamics were represented by use of a single, finite water store having infinite infiltration capacity, and the potential evapotranspiration rate was modeled as an annual cosine curve. The mean annual water budget was calculated numerically using a Monte Carlo simulation. The model predicted that for a given level of climatic aridity the ratio of mean annual evapotranspiration to rainfall was larger where the potential evapotranspiration and rainfall were in phase, that is, in summer‐dominant rainfall catchments, than where they were out of phase. The observed mean annual evapotranspiration ratios have opposite results. As a result, estimates of mean annual evapotranspiration from the model compared poorly with observational data. Because the inclusion of seasonally varying forcing alone was not sufficient to explain variability in the mean annual water balance, other catchment properties may play a role. Further analysis showed that the water balance was highly sensitive to the catchment‐scale soil moisture capacity. Calibrations of this parameter indicated that infiltration‐excess runoff might be an important process, especially for the summer‐dominant rainfall catchments; most similar studies have shown that modeling of infiltration‐excess runoff is not required at the mean annual timescale.
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Ahmadi, Fardin; Sparham, Chris; Pawliszyn, Janusz
2017-11-01
In this paper problems associated with preparation of aqueous standard of highly hydrophobic compounds such as partial precipitation, being lost on the surfaces, low solubility in water and limited sample volume for accurate determination of their distribution coefficients are addressed. The following work presents two approaches that utilize blade thin film microextraction (TFME) to investigate partitioning of UV filters and biocides to humic acid (dissolved organic carbon) and sediment. A steady-state concentration of target analytes in water was generated using a flow-through aqueous standard generation (ASG) system. Dialysis membranes, a polytetrafluoroethylene permeation tube, and a frit porous (0.5 μm) coated by epoxy glue were basic elements used for preparation of the ASG system. In the currently presented study, negligible depletion TFME using hydrophilic-lipophilic balance (HLB) and octadecyl silica-based (C18) sorbents was employed towards the attainment of free concentration values of target analytes in the studied matrices. Thin film geometry provided a large volume of extraction phase, which improved the sensitivity of the method towards highly matrix-bound analytes. Extractions were performed in the equilibrium regime so as to prevent matrix effects and with aims to reach maximum method sensitivity for all analytes under study. Partitioning of analytes on dissolved organic carbon (DOC) was investigated in ASG to facilitate large sample volume conditions. Binding percentages and DOC distribution coefficients (Log K DOC ) ranged from 20 to 98% and 3.71-6.72, respectively. Furthermore, sediment-water partition coefficients (K d ), organic-carbon normalized partition coefficients (Log K OC ), and DOC distribution coefficients (Log K DOC ) were investigated in slurry sediment, and ranged from 33 to 2860, 3.31-5.24 and 4.52-5.75 Lkg -1 , respectively. The obtained results demonstrated that investigations utilizing ASG and TFME can yield reliable binding
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Water balance and soil losses in an irrigated catchment under conservation tillage in Southern Spain
NASA Astrophysics Data System (ADS)
Cid, Patricio; Mateos, Luciano; Taguas, Encarnación V.; Gómez-Macpherson, Helena
2013-04-01
Conservation tillage based on permanent beds with crop-residue retention and controlled traffic has been recently introduced in irrigated annual crops in Southern Spain as one way to improve water infiltration, reduce soil losses, and save energy. The water balance and soil losses in water runoff have been monitored during 4 years in a 28-ha catchment within a production farm where this kind of soil conservation practice was established in 2004 for a maize-cotton-wheat rotation. The catchment average slope is 6 %. Soils are Typic Calcixerept and Typic Haploxerert. The water balance components that were measured include: applied irrigation water, rainfall, and runoff. Runoff was measured at the outlet of the catchment by means of a hydrological station that consisted of long-throated flume, ultrasonic water level sensor, automatic water sampler, data logger and transmission system, weather station, and ancillary equipment. We present here results from three hydrological seasons (October to September): 2009-10, 2010-11, and 2011-12. The first season the catchment was grown with wheat, thus the irrigation depth was small (25 mm); rainfall above average, 1103 mm; and the runoff coefficient was 26 %. In the season 2010-11, the catchment was grown with cotton, the irrigation depth was 503 mm, rainfall was 999 mm, and the seasonal runoff coefficient was 7 %. The last season, the crop was maize, rainfall was below average (368 mm), irrigation 590 mm, and the runoff coefficient as the previous year, 7 %. Soil losses were very small: 0.05, 1.26, and 1.33 t per ha and year, the first, second, and third monitored seasons, respectively. A simple water balance model allowed simulating evapotranspiration, deep percolation and runoff. The Curve Number for the catchment was calibrated using the balance model.
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NASA Astrophysics Data System (ADS)
Journaux, Baptiste; Daniel, Isabelle; Petitgirard, Sylvain; Cardon, Hervé; Perrillat, Jean-Philippe; Caracas, Razvan; Mezouar, Mohamed
2017-04-01
Water-rich planetary bodies including large icy moons and ocean exoplanets may host a deep liquid water ocean underlying a high-pressure icy mantle. The latter is often considered as a limitation to the habitability of the uppermost ocean because it would limit the availability of nutrients resulting from the hydrothermal alteration of the silicate mantle located beneath the deep ice layer. To assess the effects of salts on the physical properties of high-pressure ices and therefore the possible chemical exchanges and habitability inside H2O-rich planetary bodies, we measured partitioning coefficients and densities in the H2O-RbI system up to 450 K and 4 GPa; RbI standing as an experimentally amenable analog of NaCl in the H2O-salt solutions. We measured the partitioning coefficient of RbI between the aqueous fluid and ices VI and VII, using in-situ Synchrotron X-ray Fluorescence (XRF). With in-situ X-ray diffraction, we measured the unit-cell parameters and the densities of the high-pressure ice phases in equilibrium with the aqueous fluid, at pressures and temperatures relevant to the interior of planetary bodies. We conclude that RbI is strongly incompatible towards ice VI with a partitioning coefficient Kd(VI-L) = 5.0 (± 2.1) ṡ10-3 and moderately incompatible towards ice VII, Kd(VII-L) = 0.12 (± 0.05). RbI significantly increases the unit-cell volume of ice VI and VII by ca. 1%. This implies that RbI-poor ice VI is buoyant compared to H2O ice VI while RbI-enriched ice VII is denser than H2O ice VII. These new experimental results might profoundly impact the internal dynamics of water-rich planetary bodies. For instance, an icy mantle at moderate conditions of pressure and temperature will consist of buoyant ice VI with low concentration of salt, and would likely induce an upwelling current of solutes towards the above liquid ocean. In contrast, a deep and/or thick icy mantle of ice VII will be enriched in salt and hence would form a stable chemical boundary
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Jonker, Michiel T O
2016-06-01
Octanol-water partition coefficients (KOW ) are widely used in fate and effects modeling of chemicals. Still, high-quality experimental KOW data are scarce, in particular for very hydrophobic chemicals. This hampers reliable assessments of several fate and effect parameters and the development and validation of new models. One reason for the limited availability of experimental values may relate to the challenging nature of KOW measurements. In the present study, KOW values for 13 polycyclic aromatic hydrocarbons were determined with the gold standard "slow-stirring" method (log KOW 4.6-7.2). These values were then used as reference data for the development of an alternative method for measuring KOW . This approach combined slow stirring and equilibrium sampling of the extremely low aqueous concentrations with polydimethylsiloxane-coated solid-phase microextraction fibers, applying experimentally determined fiber-water partition coefficients. It resulted in KOW values matching the slow-stirring data very well. Therefore, the method was subsequently applied to a series of 17 moderately to extremely hydrophobic petrochemical compounds. The obtained KOW values spanned almost 6 orders of magnitude, with the highest value measuring 10(10.6) . The present study demonstrates that the hydrophobicity domain within which experimental KOW measurements are possible can be extended with the help of solid-phase microextraction and that experimentally determined KOW values can exceed the proposed upper limit of 10(9) . Environ Toxicol Chem 2016;35:1371-1377. © 2015 SETAC. © 2015 SETAC.
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River Basin Water Assessment and Balance in fast developing areas in Viet Nam
NASA Astrophysics Data System (ADS)
Le, Van Chin; Ranzi, Roberto
2010-05-01
Uneven precipitation in space and time together with mismanagement and lack of knowledge about quantity and quality of water resources, have caused water shortages for water supply to large cities and irrigation areas in many regions of Viet Nam in the dry season. The rainy season (from June to October) counts for 80% of the total annual rainfall, while the water volume of dry season (from November to May of the following year) accounts for 20% only. Lack of sufficient water volumes occurs in some areas where the pressure of a fast increasing population (1.3% per year on average in the last decade in Viet Nam), intensive agricultural and industrial uses is one of the major problems facing sustainable development. For those areas an accurate water assessment and balance at the riverbasin scale is needed to manage the exploitation and appropriate use of water resources and plan future development. The paper describes the preliminary phase of the pilot development of the river basin water balance for the Day River Basin in the Red River delta in Viet Nam. The Day river basin includes a 7,897 km² area in the south-western part of the Red River in Viet Nam. The total population in the Day river basin exceeds 8 millions inhabitants, including the Hanoi capital, Nam Dinh and other large towns. Agricultural land covered 390,294 ha in 2000 and this area is going to be increased by 14,000 ha in 2010 due to land reclamation and expansion toward the sea. Agricultural uses exploit about 90% of surface water resources in the Day river basin but have to compete with industrial and civil needs in the recent years. At the background of the brief characterization of the Day River Basin, we concentrate on the application of a water balance model integrated by an assessment of water quality after consumptive uses for civil, agricultural and industrial needs to assist water management in the basin. In addition, future development scenarios are taken into account, considering less
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NASA Astrophysics Data System (ADS)
de Lavenne, Alban; Andréassian, Vazken
2018-03-01
This paper examines the hydrological impact of the seasonality of precipitation and maximum evaporation: seasonality is, after aridity, a second-order determinant of catchment water yield. Based on a data set of 171 French catchments (where aridity ranged between 0.2 and 1.2), we present a parameterization of three commonly-used water balance formulas (namely, Turc-Mezentsev, Tixeront-Fu and Oldekop formulas) to account for seasonality effects. We quantify the improvement of seasonality-based parameterization in terms of the reconstitution of both catchment streamflow and water yield. The significant improvement obtained (reduction of RMSE between 9 and 14% depending on the formula) demonstrates the importance of climate seasonality in the determination of long-term catchment water balance.
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Bao, Quan-Ying; Liu, Ai-Yun; Ma, Yu; Chen, Huan; Hong, Jin; Shen, Wen-Bin; Zhang, Can; Ding, Ya
2016-10-01
The shape, size, and surface features of nanoparticles greatly influence the structure and properties of resulting hybrid nanosystems. In this work, gold nanoparticles (GNPs) were modified via S-Au covalent bonding by glycol monomethyl ether thioctate with poly(ethylene glycol) methyl ether of different molecular weights (i.e., 350, 550, and 750Da). These modified GNPs (i.e., GNP350, GNP550, and GNP750) showed different oil-water partition coefficients (Kp), as detected using inductively coupled plasma-atomic emission spectroscopy. The different Kp values of the gold conjugates (i.e., 13.98, 2.11, and 0.036 for GNP350, GNP550, and GNP750, respectively) resulted in different conjugate localization within liposomes, as observed by transmission electron microscopy. In addition, the cellular uptake of hybrid liposomes co-encapsulating gold conjugates and Nile red was evaluated using intracellular fluorescence intensity. The results indicated that precise GNP localization in the hydrophilic or hydrophobic liposome cavity could be achieved by regulating the GNP oil-water partition coefficient via surface modification; such localization could further affect the properties and functions of hybrid liposomes, including their cellular uptake profiles. This study furthers the understanding not only of the interaction between liposomes and inorganic nanoparticles but also of adjusting liposome-gold hybrid nanostructure properties via the surface chemistry of gold materials. Copyright © 2016 Elsevier B.V. All rights reserved.
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Below-ground carbon flux and partitioning: global patterns and response to temperature
C.M. Litton; C.P. Giardina
2008-01-01
1. The fraction of gross primary production (GPP) that is total below-ground carbon flux (TBCF) and the fraction of TBCF that is below-ground net primary production (BNPP) represent globally significant C fluxes that are fundamental in regulating ecosystem C balance. However, global estimates of the partitioning of GPP to TBCF and of TBCF to BNPP, as well as the...
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Krimmel, Robert M.
2000-01-01
Mass balance and climate variables are reported for South Cascade Glacier, Washington, for the years 1986-91. These variables include air temperature, precipitation, water runoff, snow accumulation, snow and ice melt terminus position, surface level, and ice speed. Data are reduced to daily and monthly values where appropriate. The glacier-averaged values of spring snow accumulation and fall net balance given in this report differ from previous results because amore complete analysis is made. Snow accumulation values for the1986-91 period ranged from 3.54 (water equivalent) meters in 1991 to2.04 meters in 1987. Net balance values ranged from 0.07 meters in1991 to -2.06 meters in 1987. The glacier became much smaller during the 1986-91 period and retreated a cumulative 50 meters.
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Xu, Feng; Liang, Xinmiao; Lin, Bingcheng; Schramm, Karl-Werner; Kettrup, Antonius
2002-08-30
The retention factors (k) of 104 hydrophobic organic chemicals (HOCs) were measured in soil column chromatography (SCC) over columns filled with three naturally occurring reference soils and eluted with Milli-Q water. A novel method for the estimation of soil organic partition coefficient (Koc) was developed based on correlations with k in soil/water systems. Strong log Koc versus log k correlations (r>0.96) were found. The estimated Koc values were in accordance with the literature values with a maximum deviation of less than 0.4 log units. All estimated Koc values from three soils were consistent with each other. The SCC approach is promising for fast screening of a large number of chemicals in their environmental applications.
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Reitz, Meredith; Senay, Gabriel; Sanford, Ward E.
2017-01-01
Evapotranspiration (ET) is a key component of the hydrologic cycle, accounting for ~70% of precipitation in the conterminous U.S. (CONUS), but it has been a challenge to predict accurately across different spatio-temporal scales. The increasing availability of remotely sensed data has led to significant advances in the frequency and spatial resolution of ET estimates, derived from energy balance principles with variables such as temperature used to estimate surface latent heat flux. Although remote sensing methods excel at depicting spatial and temporal variability, estimation of ET independently of other water budget components can lead to inconsistency with other budget terms. Methods that rely on ground-based data better constrain long-term ET, but are unable to provide the same temporal resolution. Here we combine long-term ET estimates from a water-balance approach with the SSEBop (operational Simplified Surface Energy Balance) remote sensing-based ET product for 2000–2015. We test the new combined method, the original SSEBop product, and another remote sensing ET product (MOD16) against monthly measurements from 119 flux towers. The new product showed advantages especially in non-irrigated areas where the new method showed a coefficient of determination R2 of 0.44, compared to 0.41 for SSEBop or 0.35 for MOD16. The resulting monthly data set will be a useful, unique contribution to ET estimation, due to its combination of remote sensing-based variability and ground-based long-term water balance constraints.
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NASA Astrophysics Data System (ADS)
Qian, Shouguo; Li, Gang; Shao, Fengjing; Xing, Yulong
2018-05-01
We construct and study efficient high order discontinuous Galerkin methods for the shallow water flows in open channels with irregular geometry and a non-flat bottom topography in this paper. The proposed methods are well-balanced for the still water steady state solution, and can preserve the non-negativity of wet cross section numerically. The well-balanced property is obtained via a novel source term separation and discretization. A simple positivity-preserving limiter is employed to provide efficient and robust simulations near the wetting and drying fronts. Numerical examples are performed to verify the well-balanced property, the non-negativity of the wet cross section, and good performance for both continuous and discontinuous solutions.
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Conjoint Analysis of the Surface and Atmospheric Water Balances of the Andes-Amazon System
NASA Astrophysics Data System (ADS)
Builes-Jaramillo, Alejandro; Poveda, Germán
2017-04-01
Acknowledging the interrelation between the two branches of the hydrological cycle, we perform a comprehensive analysis of the long-term mean surface and atmospheric water balances in the Amazon-Andes River basins system. We estimate the closure of the water budgets based on the long-term approximation of the water balance equations, and estimate the imbalance between both atmospheric and surface budgets. The analysis was performed with observational and reanalysis datasets for the entire basin, for several sub-catchments inside the entire Amazon River basin and for two physical and geographical distinctive subsystems of the basin, namely upper Andean the low-lying Amazon River basin. Our results evidence that for the entire Amazon River basin the surface water balance can be considered to be in balance (P = 2225 mm.yr-1, ET= 1062 mm.yr-1, R= 965 mm.yr-1), whereas for the separated subsystems it not so clear, showing high discrepancies between observations and reanalysis datasets. In turn, the atmospheric budget does not close regardless of datasets or geographical disaggregation. Our results indicate that the amount of imbalance of the atmospheric branch of the water balance depends on the evaporation data source used. The imbalance calculated as I=(C/R)-1, where C is net moisture convergence (C= -∇Q where ∇Q is the net vertically integrated moisture divergence) and R the runoff,represents the difference between the two branches of the hydrological cycle. For the entire Amazon River basin we found a consistent negative imbalance driven by higher values of runoff, and when calculated for monthly time scales the imbalance is characterized by a high dependence on the Amazon dry season. The separated analysis performed to the Andes and Low-lying Amazonia subsystems unveils two shortcomings of the available data, namely a poor quality of the representation of surface processes in the reanalysis models (including precipitation and evapotranspiration), and the
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Brooks, Paul D.; Chorover, Jon; Fan, Ying; ...
2015-09-01
Hydrology is an integrative discipline linking the broad array of water‐related research with physical, ecological, and social sciences. The increasing breadth of hydrological research, often where subdisciplines of hydrology partner with related sciences, reflects the central importance of water to environmental science, while highlighting the fractured nature of the discipline itself. This lack of coordination among hydrologic subdisciplines has hindered the development of hydrologic theory and integrated models capable of predicting hydrologic partitioning across time and space. The recent development of the concept of the critical zone (CZ), an open system extending from the top of the canopy to themore » base of groundwater, brings together multiple hydrological subdisciplines with related physical and ecological sciences. Observations obtained by CZ researchers provide a diverse range of complementary process and structural data to evaluate both conceptual and numerical models. Consequently, a cross‐site focus on “critical zone hydrology” has potential to advance the discipline of hydrology and to facilitate the transition of CZ observatories into a research network with immediate societal relevance. Here we review recent work in catchment hydrology and hydrochemistry, hydrogeology, and ecohydrology that highlights a common knowledge gap in how precipitation is partitioned in the critical zone: “how is the amount, routing, and residence time of water in the subsurface related to the biogeophysical structure of the CZ?” Addressing this question will require coordination among hydrologic subdisciplines and interfacing sciences, and catalyze rapid progress in understanding current CZ structure and predicting how climate and land cover changes will affect hydrologic partitioning.« less
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[Water balance of different density artificial Caragana microphylla shrubs in Horqin sand land].
Lamusa, A; Longjun, C I; Yang, Xiaohui; Jiang, Deming
2006-01-01
Employing water balance equation, this paper estimated the evapotranspiration of different density Caragana microphylla shrubs during their growing season. The results showed that during this season, the soil water content under artificial C. microphylla shrubs decreased with their increasing planting density. The average soil water content of 0.5 m x 1 m and 1 m x 2 m density artificial C. microphylla shrubs was below wilting humidity (1.55%), while that of 2 m x 2 m density and natural shrubs was kept above 1.60% which could meet the demand of shrubs growth. The evapotranspiration increased with increasing planting densities, being the highest (297.81 mm) in 0.5 m x 1 m density artificial C. microphylla shrubs, which accounted for 97.90% of the total rainfall during growing season, and the lowest (279.71 mm) in 2 m x 2 m density shrubs. By the end of growth phase, soil water content had a surplus of 24.49 mm. According to the soil water status and water balance theory, the appropriate planting density of C. microphylla shrubs in Horqin sand land should be 2 m x 2 m.
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Nie, Zhiqiang; Die, Qingqi; Yang, Yufei; Tang, Zhenwu; Wang, Qi; Huang, Qifei
2014-01-01
Polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/PCDF) were overall measured and compared in ambient air, water, soils, and sediments along the upper reaches of the Haihe River of North China, so as to evaluate their concentrations, profiles, and to understand the processes of gas-particle partitioning and air-water/soil exchange. The following results were obtained: (1) The average concentrations (toxic equivalents, TEQs) of 2,3,7,8-PCDD/PCDF in air, water, sediment, and soil samples were 4,855 fg/m(3), 9.5 pg/L, 99.2 pg/g dry weight (dw), and 56.4 pg/g (203 fg TEQ/m(3), 0.46 pg TEQ/L, 2.2 pg TEQ/g dw, and 1.3 pg TEQ/g, respectively), respectively. (2) Although OCDF, 1,2,3,4,6,7,8-HpCDF, OCDD, and 1,2,3,4,6,7,8-HpCDD were the dominant congeners among four environmental sinks, obvious discrepancies of these congener and homologue patterns of PCDD/PCDF were observed still. (3) Significant linear correlations for PCDD/PCDF were observed between the gas-particle partition coefficient (K p) and the subcooled liquid vapor pressure (P L (0)) and octanol-air partition coefficient (K oa). (4) Fugacity fraction values of air-water exchange indicated that most of PCDD/PCDF homologues were dominated by net volatilization from water into air. The low-chlorinated PCDD/PCDF (tetra- to hexa-) presented a strong net volatilization from the soil into air, while high-chlorinated PCDD/PCDF (hepta- to octa-) were mainly close to equilibrium for air-soil exchange.
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Water-Balance Model to Simulate Historical Lake Levels for Lake Merced, California
NASA Astrophysics Data System (ADS)
Maley, M. P.; Onsoy, S.; Debroux, J.; Eagon, B.
2009-12-01
Lake Merced is a freshwater lake located in southwestern San Francisco, California. In the late 1980s and early 1990s, an extended, severe drought impacted the area that resulted in significant declines in Lake Merced lake levels that raised concerns about the long-term health of the lake. In response to these concerns, the Lake Merced Water Level Restoration Project was developed to evaluate an engineered solution to increase and maintain Lake Merced lake levels. The Lake Merced Lake-Level Model was developed to support the conceptual engineering design to restore lake levels. It is a spreadsheet-based water-balance model that performs monthly water-balance calculations based on the hydrological conceptual model. The model independently calculates each water-balance component based on available climate and hydrological data. The model objective was to develop a practical, rule-based approach for the water balance and to calibrate the model results to measured lake levels. The advantage of a rule-based approach is that once the rules are defined, they enhance the ability to then adapt the model for use in future-case simulations. The model was calibrated to historical lake levels over a 70-year period from 1939 to 2009. Calibrating the model over this long historical range tested the model over a variety of hydrological conditions including wet, normal and dry precipitation years, flood events, and periods of high and low lake levels. The historical lake level range was over 16 feet. The model calibration of historical to simulated lake levels had a residual mean of 0.02 feet and an absolute residual mean of 0.42 feet. More importantly, the model demonstrated the ability to simulate both long-term and short-term trends with a strong correlation of the magnitude for both annual and seasonal fluctuations in lake levels. The calibration results demonstrate an improved conceptual understanding of the key hydrological factors that control lake levels, reduce uncertainty
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NASA Astrophysics Data System (ADS)
Odabasi, Mustafa; Cetin, Eylem; Sofuoglu, Aysun
Octanol-air partition coefficients ( KOA) for 14 polycyclic aromatic hydrocarbons (PAHs) were determined as a function of temperature using the gas chromatographic retention time method. log KOA values at 25° ranged over six orders of magnitude, between 6.34 (acenaphthylene) and 12.59 (dibenz[ a,h]anthracene). The determined KOA values were within factor of 0.7 (dibenz[ a,h]anthracene) to 15.1 (benz[ a]anthracene) of values calculated as the ratio of octanol-water partition coefficient to dimensionless Henry's law constant. Supercooled liquid vapor pressures ( PL) of 13 PAHs were also determined using the gas chromatographic retention time technique. Activity coefficients in octanol calculated using KOA and PL ranged between 3.2 and 6.2 indicating near-ideal solution behavior. Atmospheric concentrations measured in this study in Izmir, Turkey were used to investigate the partitioning of PAHs between particle and gas-phases. Experimental gas-particle partition coefficients ( Kp) were compared to the predictions of KOA absorption and KSA (soot-air partition coefficient) models. Octanol-based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. Ratios of measured/modeled partition coefficients ranged between 1.1 and 15.5 (4.5±6.0, average±SD) for KOA model. KSA model predictions were relatively better and measured to modeled ratios ranged between 0.6 and 5.6 (2.3±2.7, average±SD).
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NASA Astrophysics Data System (ADS)
Torregrosa, A.; Flint, L. E.; Flint, A. L.; Peters, J.; Combs, C.
2014-12-01
Coastal fog modifies the hydrodynamic and thermodynamic properties of California watersheds with the greatest impact to ecosystem functioning during arid summer months. Lowered maximum temperatures resulting from inland penetration of marine fog are probably adequate to capture fog effects on thermal land surface characteristics however the hydrologic impact from lowered rates of evapotranspiration due to shade, fog drip, increased relative humidity, and other factors associated with fog events are more difficult to gauge. Fog products, such as those derived from National Weather Service Geostationary Operational Environmental Satellite (GOES) imagery, provide high frequency (up to 15 min) views of fog and low cloud cover and can potentially improve water balance models. Even slight improvements in water balance calculations can benefit urban water managers and agricultural irrigation. The high frequency of GOES output provides the opportunity to explore options for integrating fog frequency data into water balance models. This pilot project compares GOES-derived fog frequency intervals (6, 12 and 24 hour) to explore the most useful for water balance models and to develop model-relevant relationships between climatic and water balance variables. Seasonal diurnal thermal differences, plant ecophysiological processes, and phenology suggest that a day/night differentiation on a monthly basis may be adequate. To explore this hypothesis, we examined discharge data from stream gages and outputs from the USGS Basin Characterization Model for runoff, recharge, potential evapotranspiration, and actual evapotranspiration for the Russian River Watershed under low, medium, and high fog event conditions derived from hourly GOES imagery (1999-2009). We also differentiated fog events into daytime and nighttime versus a 24-hour compilation on a daily, monthly, and seasonal basis. Our data suggest that a daily time-step is required to adequately incorporate the hydrologic effect of
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This document describes procedures to determine the concentrations of nonionic organic chemicals in sediment interstitial waters. In previous ESB documents, the general equilibrium partitioning (EqP) approach was chosen for the derivation of sediment benchmarks because it account...
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Sun, Jianlei; Yuen, Samuel T S; Fourie, Andy B
2010-11-01
This paper examines the potential effects of a geotextile layer used in a lysimeter pan experiment conducted in a monolithic (evapotranspiration) soil cover trial on its resulting water balance performance. The geotextile was added to the base of the lysimeter to serve as a plant root barrier in order to delineate the root zone depth. Both laboratory data and numerical modelling results indicated that the geotextile creates a capillary barrier under certain conditions and retains more water in the soil above the soil/geotextile interface than occurs without a geotextile. The numerical modelling results also suggested that the water balance of the soil cover could be affected by an increase in plant transpiration taking up this extra water retained above the soil/geotextile interface. This finding has a practical implication on the full-scale monolithic cover design, as the absence of the geotextile in the full-scale cover may affect the associated water balance and hence cover performance. Proper consideration is therefore required to assess the final monolithic cover water balance performance if its design is based on the lysimeter results. Copyright © 2010 Elsevier Ltd. All rights reserved.
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NASA Astrophysics Data System (ADS)
Gomez, Jose Alfonso; Guzman, Gema; Lorite, Ignacio
2016-04-01
Vines are one of the most extended tree crops in Europe covering a wide range of environmental and management conditions. Soil management is a key element in maintaining vines in adequate agronomic conditions, as well as in determining not only yield but also grape quality. The soil management practices adopted in vineyards could favor accelerated erosion. Particularly, cultivation with rows running up-and-down the slope on sloping vineyards, maintenance of bare soil, compaction due to high traffic of machinery are some of the vineyard's management practices that expose soil to degradation, favoring runoff and soil erosion processes. In fact high erosion rates in vines have been recently reported by Gomez et al., (2011). The adoption of grass cover in vineyards as a soil management technique has a fundamental role in soil protection against erosion, but it can have a major impact on water balance and then in grape yield and quality. This effect, the possibility of competition for soil water with the vine, is in fact mentioned by vine growers as a limiting factor for use of cover crops in vineyards under semiarid conditions or during dry periods even in sub-humid climates. To evaluate the interaction between the use of cover crops and soil management adjustments (eg. spatial extension in the vineyard and time for seeding and mowing) In order to achieve an optimum equilibrium between soil protection and grape production we developed a conceptual water balance model that reproduces the major processes in vineyards, WABYN. This model simulates the effect of different soil management alternatives, as for instance conventional tillage or cover crop, on soil water balance components. It has been implemented in a user friendly interface in order to allow its use by technicians and other stakeholders in the vine sector. It follows the methodology of a previous model specific for olive orchards (Abazi et al., 2012) using a model called WABOL. In spite of this simplified
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Intra-storm variability in microbial partitioning and microbial loading rates.
Krometis, Leigh-Anne H; Characklis, Gregory W; Simmons, Otto D; Dilts, Mackenzie J; Likirdopulos, Christina A; Sobsey, Mark D
2007-01-01
Association with particles in the water column can have a significant impact on microbial fate and transport. This study analyzed multiple stormwater samples taken throughout the duration of three separate storms (at two different sites) to evaluate the fraction of microbes partitioning to denser "settleable" particles and to examine how partitioning behavior varied over the course of a storm. Intra-storm sampling also allowed for estimates of microbial loading rates (both total and particle-associated) and cumulative storm-induced microbial load. Five different indicator organisms were examined, with the fraction of microbes associated with settleable particles assessed via a calibrated centrifugation method. Partitioning behavior varied across microorganism type, with an average of 40% of fecal coliforms, Escherichia coli, and enterococci associating with settleable particles, compared to approximately 65% of Clostridium perfringens spores and only 13% of total coliphage. Partitioning remained fairly constant for each type of organism throughout storm events. Nonetheless, higher concentrations of both settleable particles and microbes entering the water column soon after the onset of a storm led to higher loading rates of settleable microbes in the storm's earliest stages, a trend that could have important implications for the design of stormwater management structures (e.g., detention basins). Estimates of cumulative storm-induced microbial loading suggested that one day's worth of storm loading can be the equivalent of months, or even years, of dry-weather loading.
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NASA Astrophysics Data System (ADS)
Liu, Bin; Gan, Hong
2018-06-01
Rapid social and economic development results in increased demand for water resources. This can lead to the unsustainable development and exploitation of water resources which in turn causes significant environmental problems. Conventional water resource management approaches, such as supply and demand management strategies, frequently fail to restore regional water balance. This paper introduces the concept of water consumption balance, the balance between actual evapotranspiration (ET) and target ET, and establishes a framework to realize regional water balance. The framework consists of three stages: (1) determination of target ET and actual ET; (2) quantification of the water-saving requirements for the region; and (3) reduction of actual ET by implementing various water saving management strategies. Using this framework, a case study was conducted for Guantao County, China. The SWAT model was utilized to aid in the selection of the best water saving management strategy by comparing the ET of different irrigation methods and crop pattern adjustments. Simulation results revealed that determination of SWAT model parameters using remote sensing ET is feasible and that the model is a valuable tool for ET management. Irrigation was found to have a greater influence on the ET of winter wheat as compared to that of maize, indicating that reduction in winter wheat cultivation is the most effective way to reduce regional ET. However, the effect of water-saving irrigation methods on the reduction of ET was not obvious. This indicates that it would be difficult to achieve regional ET reduction using water-saving irrigation methods only. Furthermore, selecting the best water saving management strategy by relying solely on the amount of reduced ET was insufficient, because it ignored the impact of water conservation measures on the livelihood of the agricultural community. Incorporating these considerations with our findings, we recommend changing the current irrigation
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Senay, Gabriel B.
2008-01-01
The main objective of this study is to present an improved modeling technique called Vegetation ET (VegET) that integrates commonly used water balance algorithms with remotely sensed Land Surface Phenology (LSP) parameter to conduct operational vegetation water balance modeling of rainfed systems at the LSP’s spatial scale using readily available global data sets. Evaluation of the VegET model was conducted using Flux Tower data and two-year simulation for the conterminous US. The VegET model is capable of estimating actual evapotranspiration (ETa) of rainfed crops and other vegetation types at the spatial resolution of the LSP on a daily basis, replacing the need to estimate crop- and region-specific crop coefficients.
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Estimating ground-water inflow to lakes in central Florida using the isotope mass-balance approach
Sacks, Laura A.
2002-01-01
The isotope mass-balance approach was used to estimate ground-water inflow to 81 lakes in the central highlands and coastal lowlands of central Florida. The study area is characterized by a subtropical climate and numerous lakes in a mantled karst terrain. Ground-water inflow was computed using both steady-state and transient formulations of the isotope mass-balance equation. More detailed data were collected from two study lakes, including climatic, hydrologic, and isotopic (hydrogen and oxygen isotope ratio) data. For one of these lakes (Lake Starr), ground-water inflow was independently computed from a water-budget study. Climatic and isotopic data collected from the two lakes were similar even though they were in different physiographic settings about 60 miles apart. Isotopic data from all of the study lakes plotted on an evaporation trend line, which had a very similar slope to the theoretical slope computed for Lake Starr. These similarities suggest that data collected from the detailed study lakes can be extrapolated to the rest of the study area. Ground-water inflow computed using the isotope mass-balance approach ranged from 0 to more than 260 inches per year (or 0 to more than 80 percent of total inflows). Steady-state and transient estimates of ground-water inflow were very similar. Computed ground-water inflow was most sensitive to uncertainty in variables used to calculate the isotopic composition of lake evaporate (isotopic compositions of lake water and atmospheric moisture and climatic variables). Transient results were particularly sensitive to changes in the isotopic composition of lake water. Uncertainty in ground-water inflow results is considerably less for lakes with higher ground-water inflow than for lakes with lower ground-water inflow. Because of these uncertainties, the isotope mass-balance approach is better used to distinguish whether ground-water inflow quantities fall within certain ranges of values, rather than for precise
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Partitioning evapotranspiration into evaporation and transpiration in a corn field
USDA-ARS?s Scientific Manuscript database
Evapotranspiration (ET) is a main component of the hydrology cycle. It consists of soil water evaporation (E) and plant transpiration (T). Accurate partitioning of ET into E and T is challenging. We measured soil water E using heat pulse sensors and a micro-Bowen ratio system, T using stem flow gaug...
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Singh, Jasmeet; Lai, Amy Jo; Alaee, Yasmin; Ranganathan, Radha
2014-01-01
Distributions of lysopalmitoylphosphatidylcholine (LPPC), palmitic acid (PA) and their 1:1 mixtures between water and dipalmitoylphosphatidylcholine (DPPC) bilayer were determined using a fluorescence probe that selectively detects only the solutes in water. Water solute concentrations were obtained at each of several lipid concentrations. Dynamic Light Scattering experiments confirmed that the lipid/solute aggregates were vesicles in the concentration range investigated. Lipid concentration dependence of the solute component in water was fit to a thermodynamic model of solute distribution between two coexisting solvents. Water/bilayer partition coefficient and the free energy of transfer, for each of these solutes were determined from the fit. Main findings are: (1) Water/bilayer partition coefficient of solute is greater for 2 to 10% solute mole fraction than for 0 to 2%, signaling solute induced bilayer perturbation that increases bilayer solubility, beginning at 2% solute mole fraction. (2) Partition coefficients are in the order LPPC
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Singh, Jasmeet; Lai, Amy Jo; Alaee, Yasmin; Ranganathan, Radha
2013-01-01
Distribution of lysopalmitoylphosphatidylcholine (LPPC), Palmitic acid (PA) and their 1:1 mixtures between water and dipalmitoylphosphatidylcholine (DPPC) bilayer were determined using a fluorescence probe that selectively detects only the solutes in water. Water solute concentrations were obtained at each of several lipid concentrations. Dynamic Light Scattering experiments confirmed that the lipid/solute aggregates were vesicles in the concentration range investigated. Lipid concentration dependence of the solute component in water was fit to a thermodynamic model of solute distribution between two coexisting solvents. Water/bilayer partition coefficient and the free energy of transfer, for each of these solutes were determined from the fit. Main findings are: (1) Water/bilayer partition coefficient of solute is greater for 2 to 10 % solute mole fraction than for 0 to 2 %, signaling solute induced bilayer perturbation that increases bilayer solubility, beginning at 2 % solute mole fraction. (2) Partition coefficients are in the order LPPC
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Wong, Fiona; Wania, Frank
2011-06-01
Assessing the behaviour of organic chemicals in soil is a complex task as it is governed by the physical chemical properties of the chemicals, the characteristics of the soil as well as the ambient conditions of the environment. The chemical partitioning space, defined by the air-water partition coefficient (K(AW)) and the soil organic carbon-water partition coefficient (K(OC)), was employed to visualize the equilibrium distribution of organic contaminants between the air-filled pores, the pore water and the solid phases of the bulk soil and the relative importance of the three transport processes removing contaminants from soil (evaporation, leaching and particle erosion). The partitioning properties of twenty neutral organic chemicals (i.e. herbicides, pharmaceuticals, polychlorinated biphenyls and volatile chemicals) were estimated using poly-parameter linear free energy relationships and superimposed onto these maps. This allows instantaneous estimation of the equilibrium phase distribution and mobility of neutral organic chemicals in soil. Although there is a link between the major phase and the dominant transport process, such that chemicals found in air-filled pore space are subject to evaporation, those in water-filled pore space undergo leaching and those in the sorbed phase are associated with particle erosion, the partitioning coefficient thresholds for distribution and mobility can often deviate by many orders of magnitude. In particular, even a small fraction of chemical in pore water or pore air allows for evaporation and leaching to dominate over solid phase transport. Multiple maps that represent soils that differ in the amount and type of soil organic matter, water saturation, temperature, depth of surface soil horizon, and mineral matters were evaluated.
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Li, Yuntao; Adams, Jonathan; Shi, Yu; Wang, Hao; He, Jin-Sheng; Chu, Haiyan
2017-01-01
Global change may be a severe threat to natural and agricultural systems, partly through its effects in altering soil biota and processes, due to changes in water balance. We studied the potential influence of changing soil water balance on soil biota by comparing existing sites along a natural water balance gradient in the Qinghai-Tibetan Plateau. In this study, the community structure of bacteria, archaea and eukaryotes differed between the different soil water conditions. Soil moisture was the strongest predictor of bacterial and eukaryotic community structure, whereas C/N ratio was the key factor predicting variation in the archaeal community. Bacterial and eukaryotic diversity was quite stable among different soil water availability, but archaeal diversity was dramatically different between the habitats. The auxotype of methanogens also varied significantly among different habitats. The co-varying soil properties among habitats shaped the community structure of soil microbes, with archaea being particularly sensitive in terms of community composition, diversity and functional groups. Bacterial and archaeal phylogenetic community turnover was mainly driven by deterministic processes while stochastic processes had stronger effects on eukaryotic phylogenetic community turnover. Our work provides insight into microbial community, functional group and phylogenetic turnover under different soil conditions in low-latitude alpine ecosystem. PMID:28401921
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NASA Astrophysics Data System (ADS)
Li, Yuntao; Adams, Jonathan; Shi, Yu; Wang, Hao; He, Jin-Sheng; Chu, Haiyan
2017-04-01
Global change may be a severe threat to natural and agricultural systems, partly through its effects in altering soil biota and processes, due to changes in water balance. We studied the potential influence of changing soil water balance on soil biota by comparing existing sites along a natural water balance gradient in the Qinghai-Tibetan Plateau. In this study, the community structure of bacteria, archaea and eukaryotes differed between the different soil water conditions. Soil moisture was the strongest predictor of bacterial and eukaryotic community structure, whereas C/N ratio was the key factor predicting variation in the archaeal community. Bacterial and eukaryotic diversity was quite stable among different soil water availability, but archaeal diversity was dramatically different between the habitats. The auxotype of methanogens also varied significantly among different habitats. The co-varying soil properties among habitats shaped the community structure of soil microbes, with archaea being particularly sensitive in terms of community composition, diversity and functional groups. Bacterial and archaeal phylogenetic community turnover was mainly driven by deterministic processes while stochastic processes had stronger effects on eukaryotic phylogenetic community turnover. Our work provides insight into microbial community, functional group and phylogenetic turnover under different soil conditions in low-latitude alpine ecosystem.
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On delay adjustment for dynamic load balancing in distributed virtual environments.
Deng, Yunhua; Lau, Rynson W H
2012-04-01
Distributed virtual environments (DVEs) are becoming very popular in recent years, due to the rapid growing of applications, such as massive multiplayer online games (MMOGs). As the number of concurrent users increases, scalability becomes one of the major challenges in designing an interactive DVE system. One solution to address this scalability problem is to adopt a multi-server architecture. While some methods focus on the quality of partitioning the load among the servers, others focus on the efficiency of the partitioning process itself. However, all these methods neglect the effect of network delay among the servers on the accuracy of the load balancing solutions. As we show in this paper, the change in the load of the servers due to network delay would affect the performance of the load balancing algorithm. In this work, we conduct a formal analysis of this problem and discuss two efficient delay adjustment schemes to address the problem. Our experimental results show that our proposed schemes can significantly improve the performance of the load balancing algorithm with neglectable computation overhead.
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Kim, Eun-Ah; Luthy, Richard G
2011-11-01
This study investigated the role of dissolved organic matter on mercury partitioning between a hydrophobic surface (polyethylene, PE) and a reduced sulfur-rich surface (polysulfide rubber, PSR). Comparative sorption studies employed polyethylene and polyethylene coated with PSR for reactions with DOM-bound mercuric ions. These studies revealed that PSR enhanced the Hg-DOM removal from water when DOM was Suwannee River natural organic matter (NOM), fulvic acid (FA), or humic acid (HA), while the same amount of 1,3-propanedithiol-bound mercuric ion was removed by both PE and PSR-PE. The differences for Hg-DOM removal efficiencies between PE and PSR-PE varied depending on which DOM was bound to mercuric ion as suggested by the PE/water and PSR-PE/water partition coefficients for mercury. The surface concentrations of mercury on PE and PSR-PE with the same DOM measured by x-ray photoelectron spectroscopy were similar, which indicated the comparable amounts of immobilized mercury on PE and PSR-PE being exposed to the aqueous phase. With these observations, two major pathways for the immobilization reactions between PSR-PE and Hg-DOM were examined: 1) adsorption of Hg-DOM on PE by hydrophobic interactions between DOM and PE, and 2) addition reaction of Hg-DOM onto PSR by a complexation reaction between Hg and PSR. The percent contribution of each pathway was derived from a mass balance and the ratios among aqueous mercury, PE-bound Hg-DOM, and PSR-bound Hg-DOM concentrations. The results indicate strong binding of mercuric ion with both dissolved organic matter and PSR polymer. The FT-IR examination of Hg-preloaded-PSR-PEs after the reaction with DOM corroborated a strong interaction between mercuric ion and 1,3-propanedithiol compared to Hg-HA, Hg-FA, or Hg-NOM interactions. Copyright © 2011 Elsevier Ltd. All rights reserved.
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Kim, Eun-Ah
2011-01-01
This study investigated the role of dissolved organic matter on mercury partitioning between a hydrophobic surface (polyethylene, PE) and a reduced sulfur-rich surface (polysulfide rubber, PSR). Comparative sorption studies employed polyethylene and polyethylene coated with PSR for reactions with DOM-bound mercuric ions. These studies revealed that PSR enhanced the Hg-DOM removal from water when DOM was Suwannee River natural organic matter (NOM), fulvic acid (FA), or humic acid (HA), while the same amount of 1,3-propanedithiol-bound mercuric ion was removed by both PE and PSR-PE. The differences for Hg-DOM removal efficiencies between PE and PSR-PE varied depending on which DOM was bound to mercuric ion as suggested by the PE/water and PSR-PE/water partition coefficients for mercury. The surface concentrations of mercury on PE and PSR-PE with the same DOM measured by x-ray – photoelectron spectroscopy were similar, which indicated the comparable amounts of immobilized mercury on PE and PSR-PE being exposed to the aqueous phase. With these observations, two major pathways for the immobilization reactions between PSR-PE and Hg- DOM were examined: 1) adsorption of Hg-DOM on PE by hydrophobic interactions between DOM and PE, and 2) addition reaction of Hg-DOM onto PSR by a complexation reaction between Hg and PSR. The percent contribution of each pathway was derived from a mass balance and the ratios among aqueous mercury, PE-bound Hg-DOM, and PSR-bound Hg-DOM concentrations. The results indicate strong binding of mercuric ion with both dissolved organic matter and PSR polymer. The FT-IR examination of Hg-preloaded-PSR-PEs after the reaction with DOM corroborated a strong interaction between mercuric ion and 1,3-propanedithiol compared to Hg-HA, Hg-FA, or Hg-NOM interactions. PMID:21872900
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Assessment of the water balance over France using regionalized Turc-Pike formula
NASA Astrophysics Data System (ADS)
Le Lay, Matthieu; Garçon, Rémy; Gailhard, Joël; Garavaglia, Federico
2016-04-01
With extensive use of hydrological models over a wide range of hydro-climatic contexts, bias in hydro-climatic data may lead to unreliable models and thus hydrological forecasts and projections. This issue is particularly pregnant when considering mountainous areas with great uncertainties on precipitations, or when considering complex unconservative catchments (e.g. karstic systems). The Turc-Pike water balance formula, analogous to the classical Budyko formula, is a simple and efficient mathematical formulation relating long-term average streamflow to long-term average precipitation and potential evaporation. In this study, we propose to apply this framework to assess and eventually adjust the water-balance before calibrating an operational hydrologic model (MORDOR model). Considering a large set of 350 french catchments, the Turc-Pike formula is regionalized based on ecohydrologic criterions to handle various hydro-climatic contexts. This interannual regional model is then applied to assess the water-balance over numerous catchments and various conditions, such as karstic, snow-driven or glaciarized and even anthropized catchments. Results show that it is possible to obtain pretty realistic corrections of meteorological inputs (precipitations, temperature or potential evaporation) or hydrologic surface (or runoff). These corrections can often be confirmed a posteriori by exogenous information. Positive impacts on hydrologic model's calibration are also demonstrated. This methodology is now operational for hydrologic applications at EDF (Electricité de France, French electric utility company), and therefore applied on hundreds of catchments.
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NASA Astrophysics Data System (ADS)
Bowen, Gabriel J.; Kennedy, Casey D.; Liu, Zhongfang; Stalker, Jeremy
2011-12-01
The stable H and O isotope composition of river and stream water records information on runoff sources and land-atmosphere water fluxes within the catchment and is a potentially powerful tool for network-based monitoring of ecohydrological systems. Process-based hydrological models, however, have thus far shown limited power to replicate observed large-scale variation in U.S. surface water isotope ratios. Here we develop a geographic information system-based model to predict long-term annual average surface water isotope ratios across the contiguous United States. We use elevation-explicit, gridded precipitation isotope maps as model input and data from a U.S. Geological Survey monitoring program for validation. We find that models incorporating monthly variation in precipitation-evapotranspiration (P-E) amounts account for the majority (>89%) of isotopic variation and have reduced regional bias relative to models that do not consider intra-annual P-E effects on catchment water balance. Residuals from the water balance model exhibit strong spatial patterning and correlations that suggest model residuals isolate additional hydrological signal. We use interpolated model residuals to generate optimized prediction maps for U.S. surface water δ2H and δ18O values. We show that the modeled surface water values represent a relatively accurate and unbiased proxy for drinking water isotope ratios across the United States, making these data products useful in ecological and criminal forensics applications that require estimates of the local environmental water isotope variation across large geographic regions.
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NASA Astrophysics Data System (ADS)
Garcia-Estringana, P.; Latron, J.; Molina, A. J.; Llorens, P.
2012-04-01
Rainfall partitioning fluxes (throughfall and stemflow) have a large degree of temporal and spatial variability and may consequently lead to significant changes in the volume and composition of water that reach the understory and the soil. The objective of this work is to study the effect of rainfall partitioning on the seasonal and spatial variability of the soil water content in a Mediterranean downy oak forest (Quercus pubescens), located in the Vallcebre research catchments (42° 12'N, 1° 49'E). The monitoring design, started on July 2011, consists of a set of 20 automatic rain recorders and 40 automatic soil moisture probes located below the canopy. One hundred hemispheric photographs of the canopy were used to place the instruments at representative locations (in terms of canopy cover) within the plot. Bulk rainfall, stemflow and meteorological conditions above the forest cover are also automatically recorded. Canopy cover, in leaf and leafless periods, as well as biometric characteristics of the plot, are also regularly measured. This work presents the first results describing throughfall and soil moisture spatial variability during both the leaf and leafless periods. The main drivers of throughfall variability, as canopy structure and meteorological conditions are also analysed.
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NASA Astrophysics Data System (ADS)
Tseng, H.; Giambelluca, T. W.; DeLay, J. K.; Nullet, M.
2017-12-01
Steep climate gradients and diverse ecosystems make the Hawaiian Islands an ideal laboratory for ecohydrological experiments. Researchers are able to control physical and ecological variables, which is difficult for most environmental studies, by selecting sites along these gradients. Tropical montane forests, especially those situated in the cloud zone, are known to improve recharge and sustain baseflow. This is probably the result of frequent and persistent fog characteristic to these systems. During fog events, evapotranspiration is suppressed due to high humidity and reduced solar radiation. Moreover, cloud water interception by the forest canopy can produce fog drip and contribute significantly to the local water budget. Because the interception process is a complex interaction between the atmosphere and the vegetation, the effects of the meteorological conditions and canopy characteristics are equally important and sometimes hard to separate. This study aims to examine patterns in cloud water interception and canopy water balance across five tropical montane forest sites on three of the main islands of Hawaii. The sites cover a range of elevations between 1100- 2114 m, annual rainfall between 1155-3375 mm, and different dominant plant species with canopy heights ranging from 1.5 m to 30 m. We investigate the effect of climatic factors by comparing passive fog gauge measurements and other meteorological variables, then examine the differences in canopy water balance by comparing throughfall and stemflow measurements at these sites. While this study is ongoing, we present the first few months of field observations and the results of preliminary analyses. This study will improve understanding of how large-scale climate and vegetation factors interact to control cloud water interception and will inform ongoing watershed management. This is particularly important for oceanic islands such as Hawaii because they rely on precipitation entirely for water supply and
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Chemical amplification based on fluid partitioning
Anderson, Brian L [Lodi, CA; Colston, Jr., Billy W.; Elkin, Chris [San Ramon, CA
2006-05-09
A system for nucleic acid amplification of a sample comprises partitioning the sample into partitioned sections and performing PCR on the partitioned sections of the sample. Another embodiment of the invention provides a system for nucleic acid amplification and detection of a sample comprising partitioning the sample into partitioned sections, performing PCR on the partitioned sections of the sample, and detecting and analyzing the partitioned sections of the sample.
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Sacks, L.A.; Swancar, Amy; Lee, T.M.
1998-01-01
Water budget and chemical mass-balance approaches were used to estimate ground-water exchange with 10 lakes in ridge areas of Polk and Highlands Counties, Florida. At each lake, heads were monitored in the surficial aquifer system and deeper Upper Floridan aquifer, lake stage and rainfall were measured continuously, and lakes and wells were sampled three times between October 1995 and December 1996. The water-budget approach computes net ground-water flow (ground-water inflow minus outflow) as the residual of the monthly waterbudget equation. Net ground-water flow varied seasonally at each of the 10 lakes, and was notably different between lakes, illustrating short-term differences in ground-water fluxes. Monthly patterns in net ground-water flow were related to monthly patterns of other hydrologic variables such as rainfall, ground-water flow patterns, and head differences between the lake and the Upper Floridan aquifer. The chemical mass-balance approach combines the water budget and solute or isotope mass-balance equations, and assumes steady-state conditions. Naturally occurring tracers that were analyzed for include calcium, magnesium, sodium, potassium, chloride, and bromide, the isotopes deuterium and oxygen-18. Chloride and sodium were the most successful solute tracers; however, their concentrations in ground water typically varied spatially, and in places were similar to that in lake water, limiting their sensitivity as tracers. In contrast, the isotopes were more robust tracers because the isotopic composition of ground water was relatively uniform and was distinctly different from the lake water. Groundwater inflow computed using the chemical massbalance method varied significantly between lakes, and ranged from less than 10 to more than 150 inches per year. Both water-budget and chemical mass-balance approaches had limitations, but the multiple lines of evidence gained using both approaches improved the understanding of the role of ground water in the
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NASA Technical Reports Server (NTRS)
Moran, M. Susan; Scott, Russell L.; Keefer, Timothy O.; Paige, Ginger B.; Emmerich, William E.; Cosh, Michael H.; O'Neill, Peggy E.
2007-01-01
The encroachment of woody plants in grasslands across the Western U.S. will affect soil water availability by altering the contributions of evaporation (E) and transpiration (T) to total evapotranspiration (ET). To study this phenomenon, a network of flux stations is in place to measure ET in grass- and shrub-dominated ecosystems throughout the Western U.S. A method is described and tested here to partition the daily measurements of ET into E and T based on diurnal surface temperature variations of the soil and standard energy balance theory. The difference between the mid-afternoon and pre-dawn soil surface temperature, termed Apparent Thermal Inertia (I(sub A)), was used to identify days when E was negligible, and thus, ET=T. For other days, a three-step procedure based on energy balance equations was used to estimate Qe contributions of daily E and T to total daily ET. The method was tested at Walnut Gulch Experimental Watershed in southeast Arizona based on Bowen ratio estimates of ET and continuous measurements of surface temperature with an infrared thermometer (IRT) from 2004- 2005, and a second dataset of Bowen ratio, IRT and stem-flow gage measurements in 2003. Results showed that reasonable estimates of daily T were obtained for a multi-year period with ease of operation and minimal cost. With known season-long daily T, E and ET, it is possible to determine the soil water availability associated with grass- and shrub-dominated sites and better understand the hydrologic impact of regional woody plant encroachment.
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Regional estimation of base recharge to ground water using water balance and a base-flow index.
Szilagyi, Jozsef; Harvey, F Edwin; Ayers, Jerry F
2003-01-01
Naturally occurring long-term mean annual base recharge to ground water in Nebraska was estimated with the help of a water-balance approach and an objective automated technique for base-flow separation involving minimal parameter-optimization requirements. Base recharge is equal to total recharge minus the amount of evapotranspiration coming directly from ground water. The estimation of evapotranspiration in the water-balance equation avoids the need to specify a contributing drainage area for ground water, which in certain cases may be considerably different from the drainage area for surface runoff. Evapotranspiration was calculated by the WREVAP model at the Solar and Meteorological Surface Observation Network (SAMSON) sites. Long-term mean annual base recharge was derived by determining the product of estimated long-term mean annual runoff (the difference between precipitation and evapotranspiration) and the base-flow index (BFI). The BFI was calculated from discharge data obtained from the U.S. Geological Survey's gauging stations in Nebraska. Mapping was achieved by using geographic information systems (GIS) and geostatistics. This approach is best suited for regional-scale applications. It does not require complex hydrogeologic modeling nor detailed knowledge of soil characteristics, vegetation cover, or land-use practices. Long-term mean annual base recharge rates in excess of 110 mm/year resulted in the extreme eastern part of Nebraska. The western portion of the state expressed rates of only 15 to 20 mm annually, while the Sandhills region of north-central Nebraska was estimated to receive twice as much base recharge (40 to 50 mm/year) as areas south of it.
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Hierarchically partitioned nonlinear equation solvers
NASA Technical Reports Server (NTRS)
Padovan, Joseph
1987-01-01
By partitioning solution space into a number of subspaces, a new multiply constrained partitioned Newton-Raphson nonlinear equation solver is developed. Specifically, for a given iteration, each of the various separate partitions are individually and simultaneously controlled. Due to the generality of the scheme, a hierarchy of partition levels can be employed. For finite-element-type applications, this includes the possibility of degree-of-freedom, nodal, elemental, geometric substructural, material and kinematically nonlinear group controls. It is noted that such partitioning can be continuously updated, depending on solution conditioning. In this context, convergence is ascertained at the individual partition level.
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Drinking and water balance during exercise and heat acclimation
NASA Technical Reports Server (NTRS)
Greenleaf, J. E.; Brock, P. J.; Keil, L. C.; Morse, J. T.
1983-01-01
The interactions between fluid intake and balance, and plasma ion, osmotic, and endocrine responses during dehydration produced by exercise in cool and warm environments during acclimation are explored. Two groups of five male subjects performed 8 days of ergometer exercise in hot and thermoneutral conditions, respectively. The exercise trials lasted 2 hr each. Monitoring was carried out on the PV, osmotic, sodium, and endocrine concentrations, voluntary fluid intake, fluid balances, and fluid deficits. A negative correlation was observed between the plasma sodium and osmolality during acclimation. The presence of hypervolemia during acclimation is suggested as a cause of drinking, while the vasopressin concentration was not found to be a significant factor stimulating drinking. Finally, the predominant mechanism in fluid intake during exercise and heat exposure is concluded to be the renin-angiotensin II system in the presence of reductions in total body water and extracellular plasma volumes.
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Krogseth, Ingjerd Sunde; Whelan, Michael John; Christensen, Guttorm Normann; Breivik, Knut; Evenset, Anita; Warner, Nicholas Alexander
2017-01-03
Cyclic volatile methyl siloxanes (cVMS) are emitted to aquatic environments with wastewater effluents. Here, we evaluate the environmental behavior of three cVMS compounds (octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6)) in a high latitude lake (Storvannet, 70°N 23°E), experiencing intermittent wastewater emissions and high latitude environmental conditions (low temperatures and seasonal ice cover). Measured cVMS concentrations in lake water were below detection limits in both March and June 2014. However, mean concentrations in sediments were 207 ± 30, 3775 ± 973 and 848 ± 211 ng g -1 organic carbon for D4, D5 and D6, respectively. To rationalize measurements, a fugacity-based model for lakes (QWASI) was parametrized for Storvannet. The key removal process for cVMS from the lake was predicted to be advection due to the low hydraulic retention time of the lake, followed by volatilization. Predicted cVMS behavior was highly sensitive to the partition coefficient between organic carbon and water (K OC ) and its temperature dependence. Predictions indicated lower overall persistence with decreasing temperature due to enhanced partitioning from sediments to water. Inverse modeling to predict steady-state emissions from cVMS concentrations in sediment provided unrealistically high emissions, when evaluated against measured concentrations in sewage. However, high concentrations of cVMS in sediment and low concentrations in water could be explained via a hypothetical dynamic emission scenario consistent with combined sewer overflows. The study illustrates the importance of considering compound-specific behavior of emerging contaminants that may differ from legacy organic contaminants.
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Partitioning of etofenprox under simulated California rice-growing conditions.
Vasquez, Martice E; Gunasekara, Amrith S; Cahill, Thomas M; Tjeerdema, Ronald S
2010-01-01
The pyrethroid insecticide etofenprox is of current interest to rice farmers in the Sacramento Valley owing to its effectiveness against the rice water weevil, Lissorhoptrus oryzophilus Kuschel. This study aimed to describe the partitioning of etofenprox under simulated rice field conditions by determining its Henry's law constant (H) (an estimate of volatilization) and organic carbon-normalized soil-water distribution coefficient (K(oc)) at representative field temperatures. A comparison of etofenprox and lambda-cyhalothrin is presented using a level-1 fugacity model. Experimental determination of H revealed that etofenprox partitioned onto the apparatus walls and did not significantly volatilize; the maximum value of H was estimated to be 6.81 x 10(-1) Pa m(3) mol(-1) at 25 degrees C, based on its air and water method detection limits. Calculated values for H ranged from 5.6 x 10(-3) Pa m(3) mol(-1) at 5 degrees C to 2.9 x 10(-1) Pa m(3) mol(-1) at 40 degrees C, based on estimated solubility and vapor pressure values at various temperatures. Log K(oc) values (at 25 degrees C) were experimentally determined to be 6.0 and 6.4 for Princeton and Richvale rice field soils, respectively, and were very similar to the values for other pyrethroids. Finally, temperature appears to have little influence on etofenprox sorption, as the log K(oc) for the Princeton soil at 35 degrees C was 6.1. High sorption coefficients and relatively insignificant desorption and volatilization of etofenprox suggest that its insolubility drives it to partition from water by sorbing to soils with high affinity. Offsite movement is unlikely unless transported in a bound state on suspended sediments.
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NASA Astrophysics Data System (ADS)
Liu, Qiang; McVicar, Tim R.; Yang, Zhifeng; Donohue, Randall J.; Liang, Liqiao; Yang, Yuting
2016-12-01
Vegetation patterns are affected by water availability, which, in turn, influences the hydrological partitioning and regional water balance, especially in water-limited regions. Considering the important role of vegetation in partitioning the catchment water yield, the recently developed Budyko-Choudhury-Porporato (or BCP) model incorporated Porporato's model of key ecohydrological processes into Choudury's form of the Budyko hydroclimatic framework. Here we extend the steady state BCP model by incorporating dynamic ecohydrological processes into it and combining it with a typical bucket soil water balance model (resulting in the dynamic BCP, or dBCP, model). The dBCP model is used here to assess the impacts of vegetation on the water balance in a temperate water-limited basin (i.e., the Yellow River Basin (YRB) in north China), where growing season phenology is primarily constrained by low temperatures. The results show that: (i) the incorporation of dynamic growing season (fs) and dynamic effective rooting depth (Ze) conditions into the dBCP model improves results when compared to the original BCP model; (ii) dBCP model's results vary depending on time-step used (i.e., we tested mean-annual to monthly), which reflected the influence of catchment variables, e.g., catchment area, catchment-average air temperature, dryness index and Ze; and (iii) actual evapotranspiration (E) is more sensitive to changes in mean storm depth (α), followed by P, Ze, and Ep. When taking into account observed variability of each of four ecohydrological variables, changes in Ze cause the greatest variability in E, generally followed by variability in P and α, and then Ep. The dBCP results indicate that incorporating dynamic ecohydrological processes into the Budyko framework can improve the estimation of inter-annual variability of the regional water balance. This can help to understand the water requirement and to establish suitable water management strategies to adapt to climate
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Lawton, Timothy J; Uzarski, Joshua R; Filocamo, Shaun F
2016-08-16
The compatibility of multiple functions at a single interface is difficult to achieve, but is even more challenging when the functions directly counteract one another. This study provides insight into the creation of a simultaneously multifunctional surface formed by balancing two orthogonal functions; water repellency and enzyme catalysis. A partially fluorinated thiol is used to impart bulk hydrophobicity on the surface, and an N-hydroxysuccinimide ester-terminated thiol provides a specific anchoring sites for the covalent enzyme attachment. Different ratios of the two thiols are mixed together to form amphiphilic self-assembled monolayers, which are characterized with polarization-modulation infrared reflection-absorption spectroscopy and contact angle goniometry. The enzyme activity is measured by a fluorescence assay. With the results collected here, specific surface compositions are identified at which the orthogonal functions of water repellency and enzyme catalysis are balanced and exist simultaneously. An understanding of how to effectively balance orthogonal functions at surfaces can be extended to a number of higher-scale applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Resource partitioning by evergreen and deciduous species in a tropical dry forest.
Álvarez-Yépiz, Juan C; Búrquez, Alberto; Martínez-Yrízar, Angelina; Teece, Mark; Yépez, Enrico A; Dovciak, Martin
2017-02-01
Niche differentiation can lead to coexistence of plant species by partitioning limiting resources. Light partitioning promotes niche differentiation in tropical humid forests, but it is unclear how niche partitioning occurs in tropical dry forests where both light and soil resources can be limiting. We studied the adult niche of four dominant evergreen (cycad, palm) and drought-deciduous (legume, oak) species co-occurring along environmental gradients. We analyzed light intensity and soil fertility effects on key functional traits related to plant carbon and water economy, how these traits determine species' functional strategies, and how these strategies relate to relative species abundance and spatial patterns. Light intensity was negatively associated with a key trait linked to plant water economy (leaf δ 13 C, a proxy for long-term water-use efficiency-WUE), while soil fertility was negatively associated with a key trait for plant carbon economy (LNC, leaf nitrogen content). Evergreens were highly sclerophyllous and displayed an efficient water economy but poor carbon economy, in agreement with a conservative resource-use strategy (i.e., high WUE but low LNC, photosynthetic rates and stature). Conversely, deciduous species, with an efficient carbon economy but poor water economy, exhibited an exploitative resource-use strategy (i.e., high LNC, photosynthetic rates and stature, but low WUE). Evergreen and deciduous species segregated spatially, particularly at fine-scales, as expected for species with different resource-use strategies. The efficient water economy of evergreens was related to their higher relative abundance, suggesting a functional advantage against drought-deciduous species in water-limited environments within seasonally dry tropical forests.
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NASA Technical Reports Server (NTRS)
Farhat, Charbel; Lesoinne, Michel
1993-01-01
Most of the recently proposed computational methods for solving partial differential equations on multiprocessor architectures stem from the 'divide and conquer' paradigm and involve some form of domain decomposition. For those methods which also require grids of points or patches of elements, it is often necessary to explicitly partition the underlying mesh, especially when working with local memory parallel processors. In this paper, a family of cost-effective algorithms for the automatic partitioning of arbitrary two- and three-dimensional finite element and finite difference meshes is presented and discussed in view of a domain decomposed solution procedure and parallel processing. The influence of the algorithmic aspects of a solution method (implicit/explicit computations), and the architectural specifics of a multiprocessor (SIMD/MIMD, startup/transmission time), on the design of a mesh partitioning algorithm are discussed. The impact of the partitioning strategy on load balancing, operation count, operator conditioning, rate of convergence and processor mapping is also addressed. Finally, the proposed mesh decomposition algorithms are demonstrated with realistic examples of finite element, finite volume, and finite difference meshes associated with the parallel solution of solid and fluid mechanics problems on the iPSC/2 and iPSC/860 multiprocessors.
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Warr, Oliver; Rochelle, Christopher A; Masters, Andrew J; Ballentine, Christopher J
2016-01-01
An experimental approach is presented which can be used to determine partitioning of trace gases within CO2-water systems. The key advantages of this system are (1) The system can be isolated with no external exchange, making it ideal for experiments with conservative tracers. (2) Both phases can be sampled concurrently to give an accurate composition at each phase at any given time. (3) Use of a lower temperature flow loop outside of the reactor removes contamination and facilitates sampling. (4) Rapid equilibration at given pressure/temperature conditions is significantly aided by stirring and circulating the water phase using a magnetic stirrer and high-pressure liquid chromatography pump, respectively.
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NASA Astrophysics Data System (ADS)
Luo, Xin; Jiao, Jiu Jimmy; Wang, Xu-sheng; Liu, Kun; Lian, Ergang; Yang, Shouye
2017-03-01
Studies of isotope characteristics of lake water in a desert can provide important information on groundwater discharge and hydrologic partition of the lakes in the desert. This paper presents the investigation of 18O and 2H stable isotopes and radiogenic radium of different water endmembers in three representative lakes of Badain-E, Badain-W and Sumujilin-S in the Badain Jaran Desert (BJD), the fourth largest desert in the world. A stable 18O and 2H isotopic buildup model is constructed to classify the hydrologic conditions of the desert lakes by estimating the ratio between groundwater discharge rate (Fin) and lake surface evaporation (E). Then the radium mass balance models are developed to quantify Fin. Based on the obtained Fin/E and Fin, Badain-E, Badain-W and Sumujilin-S are classified as flowing through, terminal and desiccating lakes, respectively, and their hydrologic partition is obtained. The groundwater discharge rate of Badain-E, Badain-W and Sumujilin-S, is estimated to be 8-10 mm d-1, 4-5 mm d-1, and 7-8 mm d-1, respectively. The total groundwater discharge to the lake areas in the BJD is about 1.68 × 105 m3 d-1. The flow-through condition explains the existence of the fresh lakes, while the terminal and desiccating conditions lead to the lake salinization over time. This study represents the first attempt to couple both stable and radium isotopic approaches to investigate the groundwater discharge and hydrologic partition of desert lakes in the BJD and is instructional to lake studies in other deserts in the world.
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Balancing water resource conservation and food security in China
Dalin, Carole; Qiu, Huanguang; Hanasaki, Naota; Mauzerall, Denise L.; Rodriguez-Iturbe, Ignacio
2015-01-01
China’s economic growth is expected to continue into the next decades, accompanied by sustained urbanization and industrialization. The associated increase in demand for land, water resources, and rich foods will deepen the challenge of sustainably feeding the population and balancing agricultural and environmental policies. We combine a hydrologic model with an economic model to project China’s future food trade patterns and embedded water resources by 2030 and to analyze the effects of targeted irrigation reductions on this system, notably on national agricultural water consumption and food self-sufficiency. We simulate interprovincial and international food trade with a general equilibrium welfare model and a linear programming optimization, and we obtain province-level estimates of commodities’ virtual water content with a hydrologic model. We find that reducing irrigated land in regions highly dependent on scarce river flow and nonrenewable groundwater resources, such as Inner Mongolia and the greater Beijing area, can improve the efficiency of agriculture and trade regarding water resources. It can also avoid significant consumption of irrigation water across China (up to 14.8 km3/y, reduction by 14%), while incurring relatively small decreases in national food self-sufficiency (e.g., by 3% for wheat). Other researchers found that a national, rather than local, water policy would have similar effects on food production but would only reduce irrigation water consumption by 5%. PMID:25825748
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Balancing water resource conservation and food security in China.
Dalin, Carole; Qiu, Huanguang; Hanasaki, Naota; Mauzerall, Denise L; Rodriguez-Iturbe, Ignacio
2015-04-14
China's economic growth is expected to continue into the next decades, accompanied by sustained urbanization and industrialization. The associated increase in demand for land, water resources, and rich foods will deepen the challenge of sustainably feeding the population and balancing agricultural and environmental policies. We combine a hydrologic model with an economic model to project China's future food trade patterns and embedded water resources by 2030 and to analyze the effects of targeted irrigation reductions on this system, notably on national agricultural water consumption and food self-sufficiency. We simulate interprovincial and international food trade with a general equilibrium welfare model and a linear programming optimization, and we obtain province-level estimates of commodities' virtual water content with a hydrologic model. We find that reducing irrigated land in regions highly dependent on scarce river flow and nonrenewable groundwater resources, such as Inner Mongolia and the greater Beijing area, can improve the efficiency of agriculture and trade regarding water resources. It can also avoid significant consumption of irrigation water across China (up to 14.8 km(3)/y, reduction by 14%), while incurring relatively small decreases in national food self-sufficiency (e.g., by 3% for wheat). Other researchers found that a national, rather than local, water policy would have similar effects on food production but would only reduce irrigation water consumption by 5%.
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NASA Astrophysics Data System (ADS)
Komacek, T. D.; Abbot, D. S.
2016-12-01
Terrestrial exoplanets in the canonical habitable zone may have a variety of initial water fractions due to their volatile delivery rate via planetesimals. If the total planetary water complement is high, the entire surface may be covered in water, forming a "waterworld". The habitable zone for waterworlds is likely smaller than that for planets with partial land coverage because waterworlds lack the stabilizing silicate-weathering feedback. On a planet with active tectonics, competing mechanisms act to regulate the abundance of water on the surface by determining the partitioning of water between interior and surface. We have explored how the incorporation of different mechanisms for the outgassing and regassing of water changes the volatile evolution of a planet. Specifically, we have examined three models for volatile cycling: a model with degassing and regassing both determined by the seafloor pressure, one with mantle temperature-dependent degassing and regassing rates, and a hybrid model that has the degassing rate driven by seafloor pressure and the regassing rate determined by the mantle temperature. We find that the volatile cycling in all three of these scenarios reaches a steady-state after a few billion years. Using these steady-states, we can make predictions from each model for how much water is needed to flood the surface and make a waterworld. We find that if volatile cycling is either solely temperature-dependent or pressure-dependent, exoplanets require a high abundance (more than 0.3% by mass) of water to have fully inundated surfaces. This is because the waterworld boundary for these models is regulated by how much water can be stuffed into the mantle. However, if degassing is more dependent on the seafloor pressure and regassing mainly dependent on mantle temperature, super-Earth mass planets with a total water fraction similar to that of the Earth (approximately 0.05% by mass) can become waterworlds. As a result, further understanding of the
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Gauging leaf-level contributions to landscape-level water loss within a Western US dryland fores
NASA Astrophysics Data System (ADS)
Murphy, P.; Potts, D. L.; Minor, R. L.; Hamerlynck, E. P.; Sutter, L., Jr.; Barron-Gafford, G.
2017-12-01
Western US forests represent a large constituent of the North American water and carbon cycles, yet the primary controls on water loss from these ecosystems remains unknown. In dryland forests, such as those found in the Southwestern US, water availability is key to ecosystem function, and the timing and magnitude of water loss can have lasting effects on the health of these communities. One poorly defined part of the water balance in these forests is the partitioning of evapotranspiration (ET) into evaporation (E; blue flow) to transpiration (T; green flow). A study of water fluxes at multiple scales in a semiarid montane forest in Southern Arizona speaks to the partitioning of these two water flows. Within the footprint of an eddy covariance system, which estimates ecosystem ET, we have examined the impacts of variation in climate, species makeup, and topographic position on E and T. This was done using leaf-level measures of T, pedon-scale measures of E, and whole-tree water loss by way of sap flux sensors. Where available, we have examined E, T, and ET fluxes across multiple seasons and years of highly variable precipitation records. Understanding the partitioning of ET is crucial, considering that projected changes to dryland ecosystems include longer periods of drought separated by heavier precipitation events. At a moment when potential impacts of changing climate on dryland structure and function are poorly understood, a stronger comprehension of these blue and green water flows is necessary to forecast the productivity of Western US forests into the future.
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NASA Astrophysics Data System (ADS)
Hao, L.; Sun, G.; Liu, Y.; Qin, M.; Huang, X.; Fang, D.
2017-12-01
Paddy rice wetlands are the main land use type across southern China, which impact the regional environments by affecting evapotranspiration (ET) and other water and energy related processes. Our study focuses on the effects of land-cover change on water and energy processes in the Qinhuai River Basin, a typical subtropical humid region that is under rapid ecological and economical transformations. This study integrates multiple methods and techniques including remote sensing, water and energy balance model (i.e., Surface Energy Balance Algorithm for Land, SEBAL), ecohydrological model (i.e., Soil and Water Assessment Tool, SWAT), and ground observation (Eddy Covariance measurement, etc.). We found that conversion of paddy rice field to urban use led to rise in vapor pressure deficit (VPD) and reduction in ET, and thus resulted in changes in local and regional water and heat balance. The effects of the land-use change on ET and VPD overwhelmed the effects of regional climate warming and climate variability. We conclude that the ongoing large-scale urbanization of the rice paddy-dominated regions in humid southern China and East Asia will likely exacerbate environmental consequences (e.g., elevated storm-flow volume, aggravated flood risks, and intensified urban heat island and urban dry island effects). The potential role of vegetated land cover in moderating water and energy balances and maintaining a stable climate should be considered in massive urban planning and global change impact assessment in southern China.
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Partitioning Behavior of Organic Contaminants in Carbon Storage Environments: A Critical Review
DOE Office of Scientific and Technical Information (OSTI.GOV)
Burant, Aniela; Lowry, Gregory V; Karamalidis, Athanasios K
2012-12-04
Carbon capture and storage is a promising strategy for mitigating the CO{sub 2} contribution to global climate change. The large scale implementation of the technology mandates better understanding of the risks associated with CO{sub 2} injection into geologic formations and the subsequent interactions with groundwater resources. The injected supercritical CO{sub 2} (sc-CO{sub 2}) is a nonpolar solvent that can potentially mobilize organic compounds that exist at residual saturation in the formation. Here, we review the partitioning behavior of selected organic compounds typically found in depleted oil reservoirs in the residual oil–brine–sc-CO{sub 2} system under carbon storage conditions. The solubility ofmore » pure phase organic compounds in sc-CO{sub 2} and partitioning of organic compounds between water and sc-CO{sub 2} follow trends predicted based on thermodynamics. Compounds with high volatility and low aqueous solubility have the highest potential to partition to sc-CO{sub 2}. The partitioning of low volatility compounds to sc-CO{sub 2} can be enhanced by co-solvency due to the presence of higher volatility compounds in the sc-CO{sub 2}. The effect of temperature, pressure, salinity, pH, and dissolution of water molecules into sc-CO{sub 2} on the partitioning behavior of organic compounds in the residual oil-brine-sc-CO{sub 2} system is discussed. Data gaps and research needs for models to predict the partitioning of organic compounds in brines and from complex mixtures of oils are presented. Models need to be able to better incorporate the effect of salinity and co-solvency, which will require more experimental data from key classes of organic compounds.« less
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The force balance of sea ice in a numerical model of the Arctic Ocean
NASA Astrophysics Data System (ADS)
Steele, Michael; Zhang, Jinlun; Rothrock, Drew; Stern, Harry
1997-09-01
The balance of forces in the sea ice model of Hibler [1979] is examined. The model predicts that internal stress gradients are an important force in much of the Arctic Ocean except in summer, when they are significant only off the northern coasts of Greenland and the Canadian Archipelago. A partition of the internal stress gradient between the pressure gradient and the viscous terms reveals that both are significant, although they operate on very different timescales. The acceleration term is generally negligible, while the sum of Coriolis plus sea surface tilt is small. Thus the seasonal average force balance in fall, winter, and spring is mostly between three terms of roughly equal magnitudes: air drag, water drag, and internal stress gradients. This is also true for the monthly average force balance. However, we find that there is a transition around the weekly timescale and that on a daily basis the force balance at a particular location and time is often between only two terms: either between air drag and water drag or between air drag and internal stress gradients. The model is in agreement with the observations of Thorndike and Colony [1982] in that the correlation between geostrophic wind forcing and the model's ice velocity field is high. This result is discussed in the context of the force balance; we show that the presence of significant internal stress gradients does not preclude high wind-ice correlation. A breakdown of the internal stress gradient into component parts reveals that the shear viscous force is far from negligible, which casts strong doubt on the theoretical validity of the cavitating fluid approximation (in which this component is neglected). Finally, the role of ice pressure is examined by varying the parameter P*. We find a strong sensitivity in terms of the force balance, as well as ice thickness and velocity.
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Andrić, Filip; Šegan, Sandra; Dramićanin, Aleksandra; Majstorović, Helena; Milojković-Opsenica, Dušanka
2016-08-05
Soil-water partition coefficient normalized to the organic carbon content (KOC) is one of the crucial properties influencing the fate of organic compounds in the environment. Chromatographic methods are well established alternative for direct sorption techniques used for KOC determination. The present work proposes reversed-phase thin-layer chromatography (RP-TLC) as a simpler, yet equally accurate method as officially recommended HPLC technique. Several TLC systems were studied including octadecyl-(RP18) and cyano-(CN) modified silica layers in combination with methanol-water and acetonitrile-water mixtures as mobile phases. In total 50 compounds of different molecular shape, size, and various ability to establish specific interactions were selected (phenols, beznodiazepines, triazine herbicides, and polyaromatic hydrocarbons). Calibration set of 29 compounds with known logKOC values determined by sorption experiments was used to build simple univariate calibrations, Principal Component Regression (PCR) and Partial Least Squares (PLS) models between logKOC and TLC retention parameters. Models exhibit good statistical performance, indicating that CN-layers contribute better to logKOC modeling than RP18-silica. The most promising TLC methods, officially recommended HPLC method, and four in silico estimation approaches have been compared by non-parametric Sum of Ranking Differences approach (SRD). The best estimations of logKOC values were achieved by simple univariate calibration of TLC retention data involving CN-silica layers and moderate content of methanol (40-50%v/v). They were ranked far well compared to the officially recommended HPLC method which was ranked in the middle. The worst estimates have been obtained from in silico computations based on octanol-water partition coefficient. Linear Solvation Energy Relationship study revealed that increased polarity of CN-layers over RP18 in combination with methanol-water mixtures is the key to better modeling of
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NASA Astrophysics Data System (ADS)
Admajaya, F. T.; Onodera, S. I.; Shimizu, Y.; Saito, M.
2017-12-01
To estimate hydrological responses under various meteorological conditions in forests dominated, steep catchments, it is necessary to apply the model approach. The purpose of this study is to estimate water balance in Ota river and Gonokawa river watersheds, using SWAT Model. SWAT-CUP SUFI2 was used for model calibration for five years (2006-2010) and validation periods of four years (2011-2014). Evapotranspiration was estimated by the Penman-Monteith method. The water balance of the Ota river and Gonokawa river have been analyzed for last nine years. The results of the daily calibration period were ranging between satisfactory to very good. The mean annual water balance for long-term period and monthly seasonal variation in two catchments were similar as follows, precipitation, evapotranspiration, discharge, and groundwater recharge were 1,852.7 mm, 718.8 mm (38.8% of the precipitation), 776.3 mm (41.9%), and 358.2 mm (19.2%), and seasonal variation pattern of water balance which summer season was high, respectively. The difference of seasonal variations and annual variation between a flood and a drought year of Ota river and Gono river was slightly big. Decreasing rates of precipitation during a drought year was 23% in Ota river as compared with 18% in Gono river catchments. In addition, the decreasing rate in river discharge was 43% in Ota river, but 36% in Gono river
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NASA Astrophysics Data System (ADS)
Carmona, Alejandra M.; Sivapalan, Murugesu; Yaeger, Mary A.; Poveda, Germán.
2014-12-01
Patterns of interannual variability of the annual water balance are explored using data from 190 MOPEX catchments across the continental U.S. This analysis has led to the derivation of a quantitative, dimensionless, Budyko-type framework to characterize the observed interannual variability of annual water balances. The resulting model is expressed in terms of a humidity index that measures the competition between water and energy availability at the annual time scale, and a similarity parameter (α) that captures the net effects of other short-term climate features and local landscape characteristics. This application of the model to the 190 study catchments revealed the existence of space-time symmetry between spatial (between-catchment) variability and general trends in the temporal (between-year) variability of the annual water balances. The MOPEX study catchments were classified into eight similar catchment groups on the basis of magnitudes of the similarity parameter α. Interesting regional trends of α across the continental U.S. were brought out through identification of similarities between the spatial positions of the catchment groups with the mapping of distinctive ecoregions that implicitly take into account common climatic and vegetation characteristics. In this context, this study has introduced a deep sense of similarity that is evident in observed space-time variability of water balances that also reflect the codependence and coevolution of climate and landscape properties.
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The water balance components of undisturbed tropical woodlands in the Brazilian cerrado
USDA-ARS?s Scientific Manuscript database
Deforestation of the Brazilian cerrado region has caused major changes in hydrological processes. These changes in water balance components are still poorly understood but are important for making land management decisions in this region. To better understand pre-deforestation conditions, we determi...
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Souza, Erica Silva; Zaramello, Laize; Kuhnen, Carlos Alberto; Junkes, Berenice da Silva; Yunes, Rosendo Augusto; Heinzen, Vilma Edite Fonseca
2011-01-01
A new possibility for estimating the octanol/water coefficient (log P) was investigated using only one descriptor, the semi-empirical electrotopological index (ISET). The predictability of four octanol/water partition coefficient (log P) calculation models was compared using a set of 131 aliphatic organic compounds from five different classes. Log P values were calculated employing atomic-contribution methods, as in the Ghose/Crippen approach and its later refinement, AlogP; using fragmental methods through the ClogP method; and employing an approach considering the whole molecule using topological indices with the MlogP method. The efficiency and the applicability of the ISET in terms of calculating log P were demonstrated through good statistical quality (r > 0.99; s < 0.18), high internal stability and good predictive ability for an external group of compounds in the same order as the widely used models based on the fragmental method, ClogP, and the atomic contribution method, AlogP, which are among the most used methods of predicting log P. PMID:22072945
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Souza, Erica Silva; Zaramello, Laize; Kuhnen, Carlos Alberto; Junkes, Berenice da Silva; Yunes, Rosendo Augusto; Heinzen, Vilma Edite Fonseca
2011-01-01
A new possibility for estimating the octanol/water coefficient (log P) was investigated using only one descriptor, the semi-empirical electrotopological index (I(SET)). The predictability of four octanol/water partition coefficient (log P) calculation models was compared using a set of 131 aliphatic organic compounds from five different classes. Log P values were calculated employing atomic-contribution methods, as in the Ghose/Crippen approach and its later refinement, AlogP; using fragmental methods through the ClogP method; and employing an approach considering the whole molecule using topological indices with the MlogP method. The efficiency and the applicability of the I(SET) in terms of calculating log P were demonstrated through good statistical quality (r > 0.99; s < 0.18), high internal stability and good predictive ability for an external group of compounds in the same order as the widely used models based on the fragmental method, ClogP, and the atomic contribution method, AlogP, which are among the most used methods of predicting log P.
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Insights into the effects of patchy ice layers on water balance heterogeneity in peatlands
NASA Astrophysics Data System (ADS)
Dixon, Simon; Kettridge, Nicholas; Devito, Kevin; Petrone, Rich; Mendoza, Carl; Waddington, Mike
2017-04-01
Peatlands in boreal and sub-arctic settings are characterised by a high degree of seasonality. During winter soils are frozen and snow covers the surface preventing peat moss growth. Conversely, in summer, soils unfreeze and rain and evapotranspiration drive moss productivity. Although advances have been made in understanding growing season water balance and moss dynamics in northern peatlands, there remains a gap in knowledge of inter-seasonal water balance as layers of ice break up during the spring thaw. Understanding the effects of ice layers on spring water balance is important as this coincides with periods of high wildfire risk, such as the devastating Fort McMurrary wildfire of May, 2016. We hypothesise that shallow layers of ice disconnect the growing surface of moss from a falling water table, and prevent water from being supplied from depth. A disconnect between the evaporating surface and deeper water storage will lead to the drying out of the surface layer of moss and a greater risk of severe spring wildfires. We utilise the unsaturated flow model Hydrus 2D to explore water balance in peat layers with an impermeable layer representing ice. Additionally we create models to represent the heterogeneous break up of ice layers observed in Canadian boreal peatlands; these models explore the ability of breaks in an ice layer to connect the evaporating surface to a deeper water table. Results show that peatlands with slower rates of moss growth respond to dry periods by limiting evapotranspiration and thus maintain moist conditions in the sub-surface and a water table above the ice layer. Peatlands which are more productive continue to grow moss and evaporate during dry periods; this results in the near surface mosses drying out and the water table dropping below the level of the ice. Where there are breaks in the ice layer the evaporating surface is able to maintain contact with a falling water table, but connectivity is limited to above the breaks, with
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Iyer, Bharat Ramasubramanian; Zadafiya, Punit; Vetal, Pallavi Vijay
2017-01-01
The free energy of water-to-interface amino acid partitioning is a major contributing factor in membrane protein folding and stability. The interface residues at the C terminus of transmembrane β-barrels form the β-signal motif required for assisted β-barrel assembly in vivo but are believed to be less important for β-barrel assembly in vitro. Here, we experimentally measured the thermodynamic contribution of all 20 amino acids at the β-signal motif to the unassisted folding of the model β-barrel protein PagP. We obtained the partitioning free energy for all 20 amino acids at the lipid-facing interface (ΔΔG0w,i(φ)) and the protein-facing interface (ΔΔG0w,i(π)) residues and found that hydrophobic amino acids are most favorably transferred to the lipid-facing interface, whereas charged and polar groups display the highest partitioning energy. Furthermore, the change in non-polar surface area correlated directly with the partitioning free energy for the lipid-facing residue and inversely with the protein-facing residue. We also demonstrate that the interface residues of the β-signal motif are vital for in vitro barrel assembly, because they exhibit a side chain–specific energetic contribution determined by the change in nonpolar accessible surface. We further establish that folding cooperativity and hydrophobic collapse are balanced at the membrane interface for optimal stability of the PagP β-barrel scaffold. We conclude that the PagP C-terminal β-signal motif influences the folding cooperativity and stability of the folded β-barrel and that the thermodynamic contributions of the lipid- and protein-facing residues in the transmembrane protein β-signal motif depend on the nature of the amino acid side chain. PMID:28592485
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USDA-ARS?s Scientific Manuscript database
Studies of global hydrologic cycles, carbon cycles and climate change are greatly facilitated when global estimates of evapotranspiration (E) are available. We have developed an air-relative-humidity-based two-source (ARTS) E model that simulates the surface energy balance, soil water balance, and e...
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Luo, Hanjiang; Guo, Zhongwen; Wu, Kaishun; Hong, Feng; Feng, Yuan
2009-01-01
Underwater acoustic sensor networks (UWA-SNs) are envisioned to perform monitoring tasks over the large portion of the world covered by oceans. Due to economics and the large area of the ocean, UWA-SNs are mainly sparsely deployed networks nowadays. The limited battery resources is a big challenge for the deployment of such long-term sensor networks. Unbalanced battery energy consumption will lead to early energy depletion of nodes, which partitions the whole networks and impairs the integrity of the monitoring datasets or even results in the collapse of the entire networks. On the contrary, balanced energy dissipation of nodes can prolong the lifetime of such networks. In this paper, we focus on the energy balance dissipation problem of two types of sparsely deployed UWA-SNs: underwater moored monitoring systems and sparsely deployed two-dimensional UWA-SNs. We first analyze the reasons of unbalanced energy consumption in such networks, then we propose two energy balanced strategies to maximize the lifetime of networks both in shallow and deep water. Finally, we evaluate our methods by simulations and the results show that the two strategies can achieve balanced energy consumption per node while at the same time prolong the networks lifetime. PMID:22399970
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Canopy water balance of windward and leeward Hawaiian cloud forests on Haleakalā, Maui, Hawai'i
Giambelluca, Thomas W.; DeLay, John K.; Nullet, Michael A.; Scholl, Martha A.; Gingerich, Stephen B.
2011-01-01
The contribution of intercepted cloud water to precipitation at windward and leeward cloud forest sites on the slopes of Haleakalā, Maui was assessed using two approaches. Canopy water balance estimates based on meteorological monitoring were compared with interpretations of fog screen measurements collected over a 2-year period at each location. The annual incident rainfall was 973 mm at the leeward site (Auwahi) and 2550 mm at the windward site (Waikamoi). At the leeward, dry forest site, throughfall was less than rainfall (87%), and, at the windward, wet forest site, throughfall exceeded rainfall (122%). Cloud water interception estimated from canopy water balance was 166 mm year−1 at Auwahi and 1212 mm year−1 at Waikamoi. Annual fog screen measurements of cloud water flux, corrected for wind-blown rainfall, were 132 and 3017 mm for the dry and wet sites respectively. Event totals of cloud water flux based on fog screen measurements were poorly correlated with event cloud water interception totals derived from the canopy water balance. Hence, the use of fixed planar fog screens to estimate cloud water interception is not recommended. At the wet windward site, cloud water interception made up 32% of the total precipitation, adding to the already substantial amount of rainfall. At the leeward dry site, cloud water interception was 15% of the total precipitation. Vegetation at the dry site, where trees are more exposed and isolated, was more efficient at intercepting the available cloud water than at the rainy site, but events were less frequent, shorter in duration and lower in intensity. A large proportion of intercepted cloud water, 74% and 83%, respectively for the two sites, was estimated to become throughfall, thus adding significantly to soil water at both sites
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Ultraendurance cycling in a hot environment: thirst, fluid consumption, and water balance.
Armstrong, Lawrence E; Johnson, Evan C; McKenzie, Amy L; Ellis, Lindsay A; Williamson, Keith H
2015-04-01
The purpose of this field investigation was to identify and clarify factors that may be used by strength and conditioning professionals to help athletes drink adequately but not excessively during endurance exercise. A universal method to accomplish this goal does not exist because the components of water balance (i.e., sweat rate, fluid consumed) are different for each athlete and endurance events differ greatly. Twenty-six male cyclists (mean ± SD; age, 41 ± 8 years; height, 177 ± 7 cm; body mass, 81.85 ± 8.95 kg) completed a summer 164-km road cycling event in 7.0 ± 2.1 hours (range, 4.5-10.4 hours). Thirst ratings, fluid consumed, indices of hydration status, and body water balance (ingested fluid volume - [urine excreted + sweat loss]) were the primary outcome variables. Measurements were taken before the event, at designated aid stations on the course (52, 97, and 136 km), and at the finish line. Body water balance during exercise was not significantly correlated with exercise time on the course, height, body mass, or body mass index. Thirst ratings were not significantly correlated with any variable. We also observed a wide range of total sweat losses (4.9-12.7 L) and total fluid intakes (2.1-10.5 L) during this ultraendurance event. Therefore, we recommend that strength and conditioning professionals develop an individualized drinking plan for each athlete, by calculating sweat rate (milliliter per hour) on the basis of body mass change (in kilograms), during field simulations of competition.
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Barlow, Paul M.; Dickerman, David C.
2001-01-01
Ground water withdrawn for water supply reduces streamflow in the Hunt-Annaquatucket-Pettaquamscutt Basin in Rhode Island. These reductions may adversely affect aquatic habitats. A hydrologic model was prepared by the U.S. Geological Survey in cooperation with the Rhode Island Water Resources Board, Town of North Kingstown, Rhode Island Department of Environmental Management, and Rhode Island Economic Development Corporation to aid water-resource planning in the basin. Results of the model provide information that helps water suppliers and natural-resource managers evaluate strategies for balancing ground-water development and streamflow reductions in the basin.
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Takahashi, Yoshio; Fan, Qiaohui; Suga, Hiroki; Tanaka, Kazuya; Sakaguchi, Aya; Takeichi, Yasuo; Ono, Kanta; Mase, Kazuhiko; Kato, Kenji; Kanivets, Vladimir V
2017-09-29
Adsorption of radiocesium (RCs) on particulate matters in aquatic environment is important to understand its mobility and bioavailability. We here focused on factors controlling partition of RCs on particulate matters and sediments in Kuchibuto (Fukushima) and Pripyat (Chernobyl) Rivers, though RCs level in water was much smaller than WHO guideline. Moreover, Cs speciation and organic matter-clay mineral interaction were studied: (i) extended X-ray absorption fine structure showed that the contribution of outer-sphere complex of Cs on particulate matters is larger in Chernobyl than in Fukushima and (ii) scanning transmission X-ray microscope revealed larger association of humic substances and clay minerals in Chernobyl partly due to high [Ca 2+ ] in the Pripyat River. Consequently, RCs is more soluble in the Pripyat River due to weaker interaction of RCs with clay minerals caused by the inhibition effect of the adsorbed humic substances. In contrast, particulate matters and sediments in the Kuchibuto River display high adsorption affinity with lesser inhibition effect of adsorbed humic substances. This difference is possibly governed by the geology and soil type of provenances surrounding both catchments (Fukushima: weathered granite; Chernobyl: peat wetland and carbonate platform) which leads to high concentrations of organic matter and Ca 2+ in the Pripyat River.
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Huhn, Carolin; Pyell, Ute
2008-07-11
It is investigated whether those relationships derived within an optimization scheme developed previously to optimize separations in micellar electrokinetic chromatography can be used to model effective electrophoretic mobilities of analytes strongly differing in their properties (polarity and type of interaction with the pseudostationary phase). The modeling is based on two parameter sets: (i) carbon number equivalents or octanol-water partition coefficients as analyte descriptors and (ii) four coefficients describing properties of the separation electrolyte (based on retention data for a homologous series of alkyl phenyl ketones used as reference analytes). The applicability of the proposed model is validated comparing experimental and calculated effective electrophoretic mobilities. The results demonstrate that the model can effectively be used to predict effective electrophoretic mobilities of neutral analytes from the determined carbon number equivalents or from octanol-water partition coefficients provided that the solvation parameters of the analytes of interest are similar to those of the reference analytes.
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Method of up-front load balancing for local memory parallel processors
NASA Technical Reports Server (NTRS)
Baffes, Paul Thomas (Inventor)
1990-01-01
In a parallel processing computer system with multiple processing units and shared memory, a method is disclosed for uniformly balancing the aggregate computational load in, and utilizing minimal memory by, a network having identical computations to be executed at each connection therein. Read-only and read-write memory are subdivided into a plurality of process sets, which function like artificial processing units. Said plurality of process sets is iteratively merged and reduced to the number of processing units without exceeding the balance load. Said merger is based upon the value of a partition threshold, which is a measure of the memory utilization. The turnaround time and memory savings of the instant method are functions of the number of processing units available and the number of partitions into which the memory is subdivided. Typical results of the preferred embodiment yielded memory savings of from sixty to seventy five percent.
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Diurnal Variation in Gas Exchange: The Balance between Carbon Fixation and Water Loss.
Matthews, Jack S A; Vialet-Chabrand, Silvere R M; Lawson, Tracy
2017-06-01
Stomatal control of transpiration is critical for maintaining important processes, such as plant water status, leaf temperature, as well as permitting sufficient CO 2 diffusion into the leaf to maintain photosynthetic rates ( A ). Stomatal conductance often closely correlates with A and is thought to control the balance between water loss and carbon gain. It has been suggested that a mesophyll-driven signal coordinates A and stomatal conductance responses to maintain this relationship; however, the signal has yet to be fully elucidated. Despite this correlation under stable environmental conditions, the responses of both parameters vary spatially and temporally and are dependent on species, environment, and plant water status. Most current models neglect these aspects of gas exchange, although it is clear that they play a vital role in the balance of carbon fixation and water loss. Future efforts should consider the dynamic nature of whole-plant gas exchange and how it represents much more than the sum of its individual leaf-level components, and they should take into consideration the long-term effect on gas exchange over time. © 2017 American Society of Plant Biologists. All Rights Reserved.
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A Well-Balanced Central-Upwind Scheme for the 2D Shallow Water Equations on Triangular Meshes
NASA Technical Reports Server (NTRS)
Bryson, Steve; Levy, Doron
2004-01-01
We are interested in approximating solutions of the two-dimensional shallow water equations with a bottom topography on triangular meshes. We show that there is a certain flexibility in choosing the numerical fluxes in the design of semi-discrete Godunov-type central schemes. We take advantage of this fact to generate a new second-order, central-upwind method for the two-dimensional shallow water equations that is well-balanced. We demonstrate the accuracy of our method as well as its balance properties in a variety of examples.
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New polymers for low-gravity purification of cells by phase partitioning
NASA Technical Reports Server (NTRS)
Harris, J. M.
1983-01-01
A potentially powerful technique for separating different biological cell types is based on the partitioning of these cells between the immiscible aqueous phases formed by solution of certain polymers in water. This process is gravity-limited because cells sediment rather than associate with the phase most favored on the basis of cell-phase interactions. In the present contract we have been involved in the synthesis of new polymers both to aid in understanding the partitioning process and to improve the quality of separations. The prime driving force behind the design of these polymers is to produce materials which will aid in space experiments to separate important cell types and to study the partitioning process in the absence of gravity (i.e., in an equilibrium state).
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Hong, Lei; Ghosh, Upal; Mahajan, Tania; Zare, Richard N; Luthy, Richard G
2003-08-15
This study assessed polycyclic aromatic hydrocarbon (PAH) association and aqueous partitioning in lampblack-impacted field soils from five sites in California that formerly housed oil-gas process operations. Lampblack is the solid residue resulting from the decomposition of crude oil at high temperatures in the gas-making operation and is coated or impregnated with oil gasification byproducts, among which PAHs are the compounds of the greatest regulatory concern. A suite of complementary measurements investigated the character of lampblack particles and PAH location and the associated effects on PAH partitioning between lampblack and water. PAH analyses on both whole samples and density-separated components demonstrated that 81-100% of PAHs in the lampblack-impacted soils was associated with lampblack particles. FTIR, 13C NMR, and SEM analyses showed that oil-gas lampblack solids comprise primarily aromatic carbon with soot-like structures. A free-phase aromatic oil may be present in some of the lampblack soils containing high PAH concentrations. Comparable long-term aqueous partitioning measurements were obtained with an air-bridge technique and with a centrifugation/alum flocculation procedure. Large solid/water partition coefficient (Kd) values were observed in samples exhibiting lower PAH and oil levels, whereas smaller Kd values were measured in lampblack samples containing high PAH levels. The former result is in agreement with an oil-soot partitioning model, and the latter is in agreement with a coal tar-water partitioning model. Lampblack containing high PAH levels appears to exhaust the sorption capacity of the soot-carbon, creating a free aromatic oil phase that exhibits partitioning behavior similar to PAHs in coal tar. This study improves mechanistic understanding of PAH sorption on aged lampblack residuals at former oil-gas sites and provides a framework for mechanistic assessment of PAH leaching potential and risk from such site materials.
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Variations in water balance and recharge potential at three western desert sites
Gee, G.W.; Wierenga, P.J.; Andraski, Brian J.; Young, M.H.; Fayer, M.J.; Rockhold, M.L.
1994-01-01
Radioactive and hazardous waste landfills exist at numerous desert locations in the USA. At these locations, annual precipitation is low and soils are generally dry, yet little is known about recharge of water and transport of contaminants to the water table. Recent water balance measurements made at three desert locations, Las Cruces, NM, Beatty, NV, and the U.S. Department of Energy's Hanford Site in the state of Washington, provide information on recharge potential under three distinctly different climate and soil conditions. All three sites show water storage increases with time when soils are coarse textured and plants are removed from the surface, the rate of increase being influenced by climatic variables such as precipitation, radiation, temperature, and wind. Lysimeter data from Hanford and Las Cruces indicate that deep drainage (recharge) from bare, sandy soils can range from 10 to >50% of the annual precipitation. At Hanford, when desert plants are present on sandy or gravelly surface soils, deep drainage is reduced but not eliminated. When surface soils are silt loams, deep drainage is eliminated whether plants are present or not. At Las Cruces and Beatty, the presence of plants eliminated deep drainage at the measurement sites. Differences in water balance between sites are attributed to precipitation quantity and distribution and to soil and vegetation types. The implication for waste management at desert locations is that surface soil properties and plant characteristics must be considered in waste site design in order to minimize recharge potential.
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Development of a multicomponent force and moment balance for water tunnel applications, volume 2
NASA Technical Reports Server (NTRS)
Suarez, Carlos J.; Malcolm, Gerald N.; Kramer, Brian R.; Smith, Brooke C.; Ayers, Bert F.
1994-01-01
The principal objective of this research effort was to develop a multicomponent strain gauge balance to measure forces and moments on models tested in flow visualization water tunnels. Static experiments (which are discussed in Volume 1 of this report) were conducted, and the results showed good agreement with wind tunnel data on similar configurations. Dynamic experiments, which are the main topic of this Volume, were also performed using the balance. Delta wing models and two F/A-18 models were utilized in a variety of dynamic tests. This investigation showed that, as expected, the values of the inertial tares are very small due to the low rotating rates required in a low-speed water tunnel and can, therefore, be ignored. Oscillations in pitch, yaw and roll showed hysteresis loops that compared favorably to data from dynamic wind tunnel experiments. Pitch-up and hold maneuvers revealed the long persistence, or time-lags, of some of the force components in response to the motion. Rotary-balance experiments were also successfully performed. The good results obtained in these dynamic experiments bring a whole new dimension to water tunnel testing and emphasize the importance of having the capability to perform simultaneous flow visualization and force/moment measurements during dynamic situations.
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Payn, R.A.; Gooseff, M.N.; McGlynn, B.L.; Bencala, K.E.; Wondzell, S.M.
2009-01-01
Channel water balances of contiguous reaches along streams represent a poorly understood scale of stream-subsurface interaction. We measured reach water balances along a headwater stream in Montana, United States, during summer base flow recessions. Reach water balances were estimated from series of tracer tests in 13 consecutive reaches delineated evenly along a 2.6 km valley segment. For each reach, we estimated net change in discharge, gross hydrologic loss, and gross hydrologic gain from tracer dilution and mass recovery. Four series of tracer tests were performed during relatively high, intermediate, and low base flow conditions. The relative distribution of channel water along the stream was strongly related to a transition in valley structure, with a general increase in gross losses through the recession. During tracer tests at intermediate and low flows, there were frequent substantial losses of tracer mass (>10%) that could not be explained by net loss in flow over the reach, indicating that many of the study reaches were concurrently losing and gaining water. For example, one reach with little net change in discharge exchanged nearly 20% of upstream flow with gains and losses along the reach. These substantial bidirectional exchanges suggest that some channel interactions with subsurface flow paths were not measurable by net change in flow or transient storage of recovered tracer. Understanding bidirectional channel water balances in stream reaches along valleys is critical to an accurate assessment of stream solute fate and transport and to a full assessment of exchanges between the stream channel and surrounding subsurface.
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Payn, R.A.; Gooseff, M.N.; McGlynn, B.L.; Bencala, K.E.; Wondzell, S.M.
2009-01-01
Channel water balances of contiguous reaches along streams represent a poorly understood scale of stream-subsurface interaction. We measured reach water balances along a headwater stream in Montana, United States, during summer base flow recessions. Reach water balances were estimated from series of tracer tests in 13 consecutive reaches delineated evenly along a 2.6 km valley segment. For each reach, we estimated net change in discharge, gross hydrologic loss, and gross hydrologic gain from tracer dilution and mass recovery. Four series of tracer tests were performed during relatively high, intermediate, and low base flow conditions. The relative distribution of channel water along the stream was strongly related to a transition in valley structure, with a general increase in gross losses through the recession. During tracer tests at intermediate and low flows, there were frequent substantial losses of tracer mass (>10%) that could not be explained by net loss in flow over the reach, indicating that many of the study reaches were concurrently losing and gaining water. For example, one reach with little net change in discharge exchanged nearly 20% of upstream flow with gains and losses along the reach. These substantial bidirectional exchanges suggest that some channel interactions with subsurface flow paths were not measurable by net change in flow or transient storage of recovered tracer. Understanding bidirectional channel water balances in stream reaches along valleys is critical to an accurate assessment of stream solute fate and transport and to a full assessment of exchanges between the stream channel and surrounding subsurface. Copyright 2009 by the American Geophysical Union.
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NASA Astrophysics Data System (ADS)
Dubbert, M.; Piayda, A.; Costa e Silva, F.; Correia, A.; Pereira, J. S.; Cuntz, M.; Werner, C.
2013-12-01
Water is one of the key factors driving ecosystem productivity, especially in water-limited ecosystems, where global climate change is expected to intensify drought and alter precipitation patterns. One such ecosystem is the ';Montado', where two vegetation layers respond differently to drought: oak trees avoid drought due to their access to deeper soil layers and ground water while herbaceous plants, surviving the summer in the form of seeds. We aimed at 1) quantifying the impact of the understory herbaceous vegetation on ecosystem carbon and water fluxes throughout the year, 2) determining the driving environmental factors for evapotranspiration (ET) and net ecosystem exchange (NEE) and 3) disentangling how ET components of the ecosystem relate to carbon dioxide exchange. We present one year data set comparing modeled and measured stable oxygen isotope signatures (δ18O) of soil evaporation, confirming that the Craig and Gordon equation leads to good agreement with measured δ18O of evaporation (Dubbert et al. 2013). Partitioning ecosystem ET and NEE into its three sources revealed a strong contribution of soil evaporation (E) and herbaceous transpiration (T) to ecosystem ET during spring and fall. In contrast, soil respiration (R) and herbaceous net carbon gain contributed to a lesser amount to ecosystem NEE during spring and fall, leading to consistently smaller water use efficiencies (WUE) of the herbaceous understory compared to the cork-oaks. Here, we demonstrate that the ability to assess ET, NEE and WUE independent of soil evaporation dynamics enables the understanding of the mechanisms of the coupling between water and carbon fluxes and their responses to drought. Dubbert, M., Cuntz, M., Piayda, A., Maguas, C., Werner, C., 2013: Partitioning evapotranspiration - Testing the Craig and Gordon model with field measurements of oxygen isotope ratios of evaporative fluxes. J Hydrol. a) Oxygen isotope signatures of soil evaporation on bare soil plots calculated
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NASA Astrophysics Data System (ADS)
Xu, Bingcheng; Deng, Xiping; Zhang, Suiqi; Shan, Lun
2010-10-01
Seedling biomass and allocation, transpiration water use efficiency (TWUE), and species competition between switchgrass ( Panicum virgatum L.) and milkvetch ( Astragalus adsurgens Pall.) were investigated in a pot-cultivated experiment under different levels of water availability. The experiment was conducted using a simple replacement design in which switchgrass and milkvetch were grown in growth chamber with ten seedlings per pot, in three combinations of the two species (0:10, 5:5 and 10:0). Five water treatments included sufficient water supply (HW), gradual soil drying from HW (DHW), moderate water stress (LW), gradual soil drying from LW (DLW), and re-establishment of LW conditions after 12 days of drying from LW (RLW). Water treatments were applied over a 15-day period. Biomass production and its partitioning, and TWUE were determined at the end of the experiment. Species competitive indices (competitive ratio (CR), aggressivity (A) and relative yield total (RYT)) were calculated from the biomass dry weight data for shoots, roots and total biomass. Water stress significantly reduced seedling biomass production but increased root:shoot ratios in both monocultures and mixtures. In the RLW treatment, only switchgrass monocultures displayed compensatory biomass production and TWUE, while both species demonstrated compensatory growth in the mixture. Switchgrass was the dominant species and much more aggressive than milkvetch in the LW treatment, while in the other four treatments milkvetch was the dominant species as measured by the positive value of aggressivity and higher values of CR. The total biomass RYT values of the two species were higher than 1.0, indicating some degree of resource complimentarity. In the two-species mixture, although the biomass production was lower than that of milkvetch in the monoculture, there was better TWUE, especially under low and fluctuating water availability.
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Ecological partitioning and diversity in tropical planktonic foraminifera
2012-01-01
Background Ecological processes are increasingly being viewed as an important mode of diversification in the marine environment, where the high dispersal potential of pelagic organisms, and a lack of absolute barriers to gene flow may limit the occurrence of allopatric speciation through vicariance. Here we focus on the potential role of ecological partitioning in the diversification of a widely distributed group of marine protists, the planktonic foraminifera. Sampling was conducted in the tropical Arabian Sea, during the southwest (summer) monsoon, when pronounced environmental conditions result in a strong disparity in temperature, salinity and productivity between distinct northern and southern water masses. Results We uncovered extensive genetic diversity within the Arabian Sea planktonic foraminifera, identifying 13 morphospecies, represented by 20 distinct SSU rRNA genetic types. Several morphospecies/genetic types displayed non-random biogeographical distributions, partitioning between the northern and southern water masses, giving a strong indication of independent ecological adaptations. Conclusions We propose sea-surface primary productivity as the main factor driving the geographical segregation of Arabian Sea planktonic foraminifera, during the SW monsoon, with variations in symbiotic associations possibly playing a role in the specific ecological adaptations observed. Our findings suggest that ecological partitioning could be contributing to the high levels of 'cryptic' genetic diversity observed within the planktonic foraminifera, and support the view that ecological processes may play a key role in the diversification of marine pelagic organisms. PMID:22507289
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Partitioning of mercury onto suspended sediments in estuaries.
Le Roux, S M; Turner, A; Millward, G E; Ebdon, L; Appriou, P
2001-02-01
Radiochemical partitioning experiments using 203Hg have been undertaken with mixtures of river, seawater and sediment samples taken from three geochemically contrasting UK estuaries: the Plym, Beaulieu and Mersey. Species of dissolved Hg were determined using reversed-phase C18 chelating columns and particulate species were determined by sequential leaching with 1 M NH4OAc and 1 M HCl. Mercury had a high particle reactivity with partition coefficients, KDs, ranging from 10(4) to 5 x 10(5) ml g(-1), depending on salinity, the chemical composition of the end-member waters, and on the physico-chemical characteristics of the sediment. Dissolved organic matter present in the waters (humic substances and/or anthropogenic compounds) was found to be the main factor governing the forms of dissolved Hg and their reactivity. From the spiked 203Hg, up to 95% of the dissolved metal was retained on the C18 columns for the Mersey waters, whereas this fraction was < 60% in the Plym and Beaulieu waters. Quasi-irreversible adsorption of Hg onto particles from each estuary was observed over a time-scale of a few hours and < 20% of total particulate Hg was released by the sequential leach. In this paper, physico-chemical processes are proposed to explain the estuarine behaviour of Hg and the results are discussed in terms of Hg availability in estuarine systems.
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Surface melt dominates Alaska glacier mass balance
Larsen Chris F,; Burgess, E; Arendt, A.A.; O'Neel, Shad; Johnson, A.J.; Kienholz, C.
2015-01-01
Mountain glaciers comprise a small and widely distributed fraction of the world's terrestrial ice, yet their rapid losses presently drive a large percentage of the cryosphere's contribution to sea level rise. Regional mass balance assessments are challenging over large glacier populations due to remote and rugged geography, variable response of individual glaciers to climate change, and episodic calving losses from tidewater glaciers. In Alaska, we use airborne altimetry from 116 glaciers to estimate a regional mass balance of −75 ± 11 Gt yr−1 (1994–2013). Our glacier sample is spatially well distributed, yet pervasive variability in mass balances obscures geospatial and climatic relationships. However, for the first time, these data allow the partitioning of regional mass balance by glacier type. We find that tidewater glaciers are losing mass at substantially slower rates than other glaciers in Alaska and collectively contribute to only 6% of the regional mass loss.
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Water balance-based estimation of groundwater recharge in the Lake Chad Basin
NASA Astrophysics Data System (ADS)
Babamaaji, R. A.; Lee, J.
2012-12-01
Lake Chad Basin (LCB) has experienced drastic changes of land cover and poor water management practices during the last 50 years. The successive droughts in the 1970s and 1980s resulted in the shortage of surface water and groundwater resources. This problem of drought and shortage of water has a devastating implication on the natural resources of the Basin with great consequence on food security, poverty reduction and quality of life of the inhabitants in the LCB. Therefore, understanding the change of land use and its characteristics must be a first step to find how such changes disturb the water cycle especially the groundwater in the LCB. The abundance of groundwater is affected by the climate change through the interaction with surface water, such as lakes and rivers, and vertical recharge through an infiltration process. Quantifying the impact of climate change on the groundwater resource requires not only reliable forecasting of changes in the major climatic variables, but also accurate estimation of groundwater recharge. Spatial variations in the land use/land cover, soil texture, topographic slope, and meteorological conditions should be accounted for in the recharge estimation. In this study, we employed a spatially distributed water balance model WetSpass to simulate a long-term average change of groundwater recharge in the LCB of Africa. WetSpass is a water balance-based model to estimate seasonal average spatial distribution of surface runoff, evapotranspiration, and groundwater recharge. The model is especially suitable for studying the effect of land use/land cover change on the water regime in the LCB. The present study describes the concept of the model and its application to the development of recharge map of the LCB.
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Intra-basin variability of snowmelt water balance calculations in a subarctic catchment
NASA Astrophysics Data System (ADS)
McCartney, Stephen E.; Carey, Sean K.; Pomeroy, John W.
2006-03-01
The intra-basin variability of snowmelt and melt-water runoff hydrology in an 8 km2 subarctic alpine tundra catchment was examined for the 2003 melt period. The catchment, Granger Creek, is within the Wolf Creek Research Basin, Yukon, which is typical of mountain subarctic landscapes in northwestern Canada. The study catchment was segmented into nine internally uniform zones termed hydrological response units (HRUs) based on their similar hydrological, physiographic, vegetation and soil properties. Snow accumulation exhibited significant variability among the HRUs, with greatest snow water equivalent in areas of tall shrub vegetation. Melt began first on southerly exposures and at lower elevations, yet average melt rates for the study period varied little among HRUs with the exception of those with steep aspects. In HRUs with capping organic soils, melt water first infiltrated this surface horizon, satisfying its storage capacity, and then percolated into the frozen mineral substrate. Infiltration and percolation into frozen mineral soils was restricted where melt occurred rapidly and organic soils were thin; in this case, melt-water delivery rates exceeded the frozen mineral soil infiltration rate, resulting in high runoff rates. In contrast, where there were slower melt rates and thick organic soils, infiltration was unlimited and runoff was suppressed. The snow water equivalent had a large impact on runoff volume, as soil storage capacity was quickly surpassed in areas of deep snow, diverting the bulk of melt water laterally to the drainage network. A spatially distributed water balance indicated that the snowmelt freshet was primarily controlled by areas with tall shrub vegetation that accumulate large quantities of snow and by alpine areas with no capping organic soils. The intra-basin water balance variability has important implications for modelling freshet in hydrological models.
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The water balance of the urban Salt Lake Valley: a multiple-box model validated by observations
NASA Astrophysics Data System (ADS)
Stwertka, C.; Strong, C.
2012-12-01
A main focus of the recently awarded National Science Foundation (NSF) EPSCoR Track-1 research project "innovative Urban Transitions and Arid-region Hydro-sustainability (iUTAH)" is to quantify the primary components of the water balance for the Wasatch region, and to evaluate their sensitivity to climate change and projected urban development. Building on the multiple-box model that we developed and validated for carbon dioxide (Strong et al 2011), mass balance equations for water in the atmosphere and surface are incorporated into the modeling framework. The model is used to determine how surface fluxes, ground-water transport, biological fluxes, and meteorological processes regulate water cycling within and around the urban Salt Lake Valley. The model is used to evaluate the hypotheses that increased water demand associated with urban growth in Salt Lake Valley will (1) elevate sensitivity to projected climate variability and (2) motivate more attentive management of urban water use and evaporative fluxes.
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Wendland, Edson; Gomes, Luis H; Troeger, Uwe
2015-01-01
The contribution of recharge to regional groundwater flow systems is essential information required to establish sustainable water resources management. The objective of this work was to determine the groundwater outflow in the Ribeirão da Onça Basin using a water balance model of the saturated soil zone. The basin is located in the outcrop region of the Guarani Aquifer System (GAS). The water balance method involved the determination of direct recharge values, groundwater storage variation and base flow. The direct recharge was determined by the water table fluctuation method (WTF). The base flow was calculated by the hydrograph separation method, which was generated by a rain-flow model supported by biweekly streamflow measurements in the control section. Undisturbed soil samples were collected at depths corresponding to the variation zone of the groundwater level to determine the specific yield of the soil (drainable porosity). Water balances were performed in the saturated zone for the hydrological years from February 2004 to January 2007. The direct recharge ranged from 14.0% to 38.0%, and groundwater outflow from 0.4% to 2.4% of the respective rainfall during the same period.
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USDA-ARS?s Scientific Manuscript database
Understanding the role of ecosystems in modulating energy, water and carbon fluxes is critical to quantifying the variability in energy, carbon, and water balances across landscapes. This study compares and contrasts the seasonal surface fluxes of sensible heat, latent heat and carbon fluxes measur...
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NASA Astrophysics Data System (ADS)
Speich, Matthias; Zappa, Massimiliano; Lischke, Heike
2017-04-01
Evaporation and transpiration affect both catchment water yield and the growing conditions for vegetation. They are driven by climate, but also depend on vegetation, soil and land surface properties. In hydrological and land surface models, these properties may be included as constant parameters, or as state variables. Often, little is known about the effect of these variables on model outputs. In the present study, the effect of surface properties on evaporation was assessed in a global sensitivity analysis. To this effect, we developed a simple local water balance model combining state-of-the-art process formulations for evaporation, transpiration and soil water balance. The model is vertically one-dimensional, and the relative simplicity of its process formulations makes it suitable for integration in a spatially distributed model at regional scale. The main model outputs are annual total evaporation (TE, i.e. the sum of transpiration, soil evaporation and interception), and a drought index (DI), which is based on the ratio of actual and potential transpiration. This index represents the growing conditions for forest trees. The sensitivity analysis was conducted in two steps. First, a screening analysis was applied to identify unimportant parameters out of an initial set of 19 parameters. In a second step, a statistical meta-model was applied to a sample of 800 model runs, in which the values of the important parameters were varied. Parameter effect and interactions were analyzed with effects plots. The model was driven with forcing data from ten meteorological stations in Switzerland, representing a wide range of precipitation regimes across a strong temperature gradient. Of the 19 original parameters, eight were identified as important in the screening analysis. Both steps highlighted the importance of Plant Available Water Capacity (AWC) and Leaf Area Index (LAI). However, their effect varies greatly across stations. For example, while a transition from a
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Musaeva, T S; Karipidi, M K; Zabolotskikh, I B
2016-11-01
a comprehensive assessment of the water balance on the basis of daily, cumulative balance and 10% of the body weight gain and their role in the development of early complications after major abdominal surgery. A retrospective study of the perioperative period in 150 patients who underwent major abdomi- nal surgery was performed. The physical condition of the patients corresponded to ASA 3 class. The average age was 46 (38-62) years. The following stages ofresearch: an analysis of daily balance and cumulative balance in complicated and uncomplicated group and their role in the development of complications; the timing of development ofcomplications and possible relationship with fluid overload and the development of complications; changes in the level of albumin within 10 days of the postoperative period. The analysis of complications didn't show significant differences between complicated and uncomplicated groups according to the water balance during the surgery and by the end of the first day. When constructing the area under the ROC curve (A UROC) low resolution ofthe balance in intraoperative period and the first day and the balance on the second day to predict complications was shown. Significant diferences according to the cumulative balance was observed from the third day of the postoperative period Also with the third day of the postoperative period there is a good resolution for prediction ofpostoperative complications according to the cumulative balance with the cut-offpoint > of 50,7 ml/kg. the excessive infusion therapy is a predictor of adverse outcome in patients after major abdominal surgery. Therefore, after 3 days of postoperative period it is important to maintain mechanisms for the excretion of excess fluid or limitations of infusion therapy.
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NASA Astrophysics Data System (ADS)
García-Arias, Alicia; Ruiz-Pérez, Guiomar; Francés, Félix
2017-04-01
Vegetation plays a main role in the water balance of most hydrological systems. However, in the past it has been barely considered the effect of the interception and evapotranspiration for hydrological modelling purposes. During the last years many authors have recognised and supported ecohydrological approaches instead of traditional strategies. This contribution is aimed to demonstrate the pivotal role of the vegetation in ecohydrological models and that a better understanding of the hydrological systems can be achieved by considering the appropriate processes related to plants. The study is performed in two scales: the plot scale and the reach scale. At plot scale, only zonal vegetation was considered while at reach scale both zonal and riparian were taken into account. In order to assure the main role of the water on the vegetation development, semiarid environments have been selected for the case studies. Results show an increase of the capabilities to predict plant behaviour and water balance when interception and evapotranspiration are taken into account in the soil water balance
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Spatial variability of hillslope water balance, wolf creek basin, subarctic yukon
NASA Astrophysics Data System (ADS)
Carey, Sean K.; Woo, Ming-Ko
2001-11-01
A hydrological study was conducted between 1997 and 1999 in the subalpine open woodland of the Wolf Creek Basin, Yukon, to assess the interslope water balance variability. The water balance during the snowmelt and summer periods on four hillslopes revealed strong contrasts in process magnitudes and highlighted important factors including frost, vegetation, soils and microclimate that controlled vertical and lateral fluxes of water. Snow accounted for approximately half the annual water input, while differences in accumulation among hillslopes were related to interception properties of vegetation. Available energy at the snow surface controlled the melt sequence and the snow on some slopes disappeared up to two months earlier than others. Snowmelt runoff was confined to slopes with ice-rich substrates that inhibited deep percolation, with the runoff magnitude governed by the snow storage and the antecedent moisture of the desiccated organic soils prior to melt. During summer, evapotranspiration exceeded rainfall, largely sustained by water from the soil moisture reservoir recharged during the melt period. Differences in net radiation on slopes controlled the potential evapotranspiration, with the actual rates limited by the phenology of the deciduous forests and shrubs. Evapotranspiration was further suppressed on slopes where the organic soils became dry in late summer. Summer runoff was confined to slopes with porous organic layers overlying mineral soils to form a two-layer flow system: (1) quickflow in the surface organic layer and (2) slowflow in the mineral soil. Differences in the rates of flow were related to the position of the water table which may rise into the organic layer to activate quickflow. The presence of ice-rich frost and permafrost impeded vertical drainage and indirectly regulated the position of the water table. The location of the hillslope within a basin influenced recharge and discharge dynamics. Slope segments with large inflows sustained
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NASA Astrophysics Data System (ADS)
Bouteffeha, Maroua; Dagès, Cécile; Bouhlila, Rachida; Raclot, Damien; Molénat, Jérôme
2013-04-01
In Mediterranean regions, food and water demand increase with population growth leading to considerable changes of the land use and agricultural practices. In North Africa, particularly in the Mediterranean zones, hill reservoirs are water harvesting infrastructures that have been increasingly adopted to mobilize runoff and create alternative water resource that can be used to develop agriculture. Hill reservoirs are also used to prevent from silting of downstream dams. Management of water resources collected in these infrastructures requires a good knowledge of their hydrological functioning. In particular, the rate of water exchanges between the reservoir and the underlying aquifer, called surface-subsurface exchange hereafter, is still an open question. The main purpose of the study is to better know the hydrological functioning of hill reservoirs in quantifying at the annual and intra-annual time scales the flux of surface-subsurface exchange and the uncertainty associated to the flux. The approach is based on the hydrological water balance of the hill reservoir. It was applied to the hill reservoir of the 2.6 km² Kamech catchment (Tunisia), which belongs to the long term Mediterranean hydrological observatory OMERE (Voltz and Albergel, 2002). The dense monitoring of the observation catchment allowed quantifying the fluxes of all hydrological processes governing the reservoir hydrology, and their associated uncertainties. The water balance was established by considering water inputs (direct rainfall, waddy and hillslope runoff, surface-subsurface exchange), water outputs (evaporation, spillway discharge) and hill reservoir water volume changes. The surface-subsurface exchange component was deduced as the default closure term in the water balance. The results first demonstrate the ability of the proposed approach to estimate the net surface-subsurface exchange flux and its uncertainty at various time scales. Its application on the Kamech catchment for two
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Trace element partitioning during the retorting of Julia Creek oil shale
DOE Office of Scientific and Technical Information (OSTI.GOV)
Patterson, J.H.; Dale, L.S.; Chapman, J.f.
1987-05-01
A bulk sample of oil shale from the Julia Creek deposit in Queensland was retorted under Fischer assay conditions at temperatures ranging from 250 to 550 /sup 0/C. The distributions of the trace elements detected in the shale oil and retort water were determined at each temperature. Oil distillation commenced at 300 /sup 0/C and was essentially complete at 500 /sup 0/C. A number of trace elements were progressively mobilized with increasing retort temperature up to 450 /sup 0/C. The following trace elements partitioned mainly to the oil: vanadium, arsenic, selenium, iron, nickel, titanium, copper, cobalt, and aluminum. Elements thatmore » also partitioned to the retort waters included arsenic, selenium, chlorine, and bromine. Element mobilization is considered to be caused by the volatilization of organometallic compounds, sulfide minerals, and sodium halides present in the oil shale. The results have important implications for shale oil refining and for the disposal of retort waters. 22 references, 5 tables.« less
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NASA Astrophysics Data System (ADS)
Abadzadesahraei, S.; Déry, S.; Rex, J. F.
2016-12-01
Northeastern British Columbia (BC) is undergoing rapid development for oil and gas extraction, largely depending on subsurface hydraulic fracturing (fracking), which relies on available freshwater. Even though this industrial activity has made substantial contributions to regional and provincial economies, it is important to ensure that sufficient and sustainable water supplies are available for all those dependent on the resource, including ecological systems. Further, BC statistics predict that the northeastern region's population will increase by 30% over the next 25 years, thereby amplifying the demands of domestic and industrial water usage. Hence, given the increasing demands for surface water in the complex wetlands of northeastern BC, obtaining accurate long-term water balance information is of vital importance. Thus, this study aims to simulate the 1979-2014 water balance at two boreal watersheds using the MIKE SHE model. More specifically, this research intends to quantify the historical, and regional, water budgets and their associated hydrological processes at two boreal watersheds—the Coles Lake and Tsea Lake watersheds—in northeastern BC. The development of coupled groundwater and surface water model of these watersheds are discussed. The model setup, calibration process, and results are presented, focusing on the water balance of boreal watersheds. Hydrological components within these watersheds are quantified through a combination of intensive fieldwork, observational data, analysis and numerical modeling. The output from the model provides important information for decision makers to manage water resources in northeastern BC. Keywords: Northeastern BC; boreal watershed; water balance; MIKE SHE hydrological model.
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Instantons on ALE spaces and orbifold partitions
NASA Astrophysics Data System (ADS)
Dijkgraaf, Robbert; Sułkowski, Piotr
2008-03-01
We consider Script N = 4 theories on ALE spaces of Ak-1 type. As is well known, their partition functions coincide with Ak-1 affine characters. We show that these partition functions are equal to the generating functions of some peculiar classes of partitions which we introduce under the name 'orbifold partitions'. These orbifold partitions turn out to be related to the generalized Frobenius partitions introduced by G. E. Andrews some years ago. We relate the orbifold partitions to the blended partitions and interpret explicitly in terms of a free fermion system.
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Sayed, M A M; Downing, J
2015-04-01
The effects of dietary electrolyte balance (DEB) and electrolyte-betaine (El-Be) supplements on heat-stressed broiler performance, acid-base balance and water retention were evaluated during the period 31-40 d of age in a 2 × 3 factorial arrangement of treatments. A total of 240 broilers were assigned to 6 treatment groups each with 8 replicates of 5 birds per cage and were exposed to cyclic high temperature (32 - 24 ± 1°C). Birds were provided with diets having DEB of either 180 or 220 mEq/kg. El-Be supplements were either added to the diet, water or not added to either of them to complete the array of 6 treatment groups. An additional 80 birds were kept at thermoneutral temperature (20 ± 1°C) and were provided with tap water and diets with DEB of either 180 or 220 mEq/kg to serve as negative controls. Exposure to high temperature depressed growth performance, increased rectal temperature and decreased potassium (K(+)) retention. In high-temperature room, birds fed on diets with DEB of 220 mEq/kg tended to increase BW from 35-40 d of age. However, at thermoneutral temperature, broilers fed on diets with DEB of 220 mEq/kg increased K(+) retention. Adding El-Be supplements in feed or water improved feed conversion ratio (FCR), enhanced water consumption and increased K(+) and sodium (Na(+)) retention. Interactions between DEB and El-Be supplements tended to affect body weight gain and FCR during the periods 35-40 and 31-40 d of age, respectively. It is suggested that when using a diet with DEB of 180 mEq/kg, adding the El-Be supplements in drinking water was more beneficial than in feed. Adding the supplements in feed or water was equally useful when using DEB of 220 mEq/kg.
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Meeting the challenges of on-host and off-host water balance in blood-feeding arthropods
Benoit, Joshua B.; Denlinger, David L.
2010-01-01
In this review, we describe water balance requirements of blood-feeding arthropods, particularly contrasting dehydration tolerance during the unfed, off-host state and the challenges of excess water that accompany receipt of the bloodmeal. Most basic water balance characteristics during the off-host stage are applicable to other terrestrial arthropods, as well. A well-coordinated suite of responses enable arthropods to conserve water resources, enhance their desiccation tolerance, and increase their water supplies by employing a diverse array of molecular, structural and behavioral responses. Water loss rates during the off-host phase are particularly useful for generating a scheme to classify vectors according to their habitat requirements for water, thus providing a convenient tool with potential predictive power for defining suitable current and future vector habitats. Blood feeding elicits an entirely different set of challenges as the vector responds to overhydration by quickly increasing its rate of cuticular water loss and elevating the rate of diuresis to void excess water and condense the bloodmeal. Immature stages that feed on blood normally have a net increase in water content at the end of a blood-feeding cycle, but in adults the water content reverts to the prefeeding level when the cycle is completed. Common themes are evident in diverse arthropods that feed on blood, particularly the physiological mechanisms used to respond to the sudden influx of water as well as the mechanisms used to counter water shortfalls that are encountered during the nonfeeding, off-host state. PMID:20206630
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Climatic change impacts on water balance of the Upper Jordan River
NASA Astrophysics Data System (ADS)
Heckl, A.; Kunstmann, H.
2009-04-01
The Eastern Mediterranean and Near East (EM/NE) is an extremely water scarce environment. It is expected that problems will increase due to climate change and population growth. The impact of climate change on water availability in EM/NE and in particular the Jordan River catchment is investigated in this study. Focus is set on the Upper Jordan River catchment (UJC) as it provides 1/3rd of freshwater resources in Israel and Palestine. It is a hydro-geologically extremely complex region with karstic groundwater flow and an orography with steep gradients. The methods used are high resolution coupled regional climate - hydrology simulations. Two IPCC scenarios (A2 and B2) of the global climate model ECHAM4 have been dynamically downscaled using the non-hydrostatic meteorological model MM5 in two nesting steps with resolutions of 54x54 km2 and 18x18 km2 for the period 1961-2099, whereby the time slice 1961-1989 represents the current climate. The meteorological fields are used to drive the physically based hydrological model WaSiM applied to the UJC. The hydrological model computes in detail the surface and subsurface water flow and water balance in a horizontal resolution of 450 x 450 m2 and dynamically couples to a 2-dim numerical groundwater model. Parameters like surface runoff, groundwater recharge, soil moisture and evapotranspiration can be extracted. Results show in both scenarios increasing yearly mean temperatures up to 4-5 K until 2099 and decreasing yearly precipitation amounts up to 25% (scenario A2). The effect on the water balance of the UJC are reduced discharge and groundwater recharge, increased evaporation and reduction of snow cover in the mountains which usually serves as an important freshwater reservoir for the summer discharge.