SEARCH FOR GAMMA-RAY EMISSION FROM X-RAY-SELECTED SEYFERT GALAXIES WITH FERMI-LAT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ackermann, M.; Ajello, M.; Allafort, A.

We report on a systematic investigation of the {gamma}-ray properties of 120 hard X-ray-selected Seyfert galaxies classified as 'radio-quiet' objects, utilizing the three-year accumulation of Fermi Large Area Telescope (LAT) data. Our sample of Seyfert galaxies is selected using the Swift Burst Alert Telescope 58 month catalog, restricting the analysis to the bright sources with average hard X-ray fluxes F{sub 14-195keV} {>=} 2.5 Multiplication-Sign 10{sup -11} erg cm{sup -2} s{sup -1} at high Galactic latitudes (|b| > 10 Degree-Sign ). In order to remove 'radio-loud' objects from the sample, we use the 'hard X-ray radio loudness parameter', R{sub rX}, definedmore » as the ratio of the total 1.4 GHz radio to 14-195 keV hard X-ray energy fluxes. Among 120 X-ray bright Seyfert galaxies with R{sub rX} <10{sup -4}, we did not find a statistically significant {gamma}-ray excess (TS > 25) positionally coincident with any target Seyferts, with possible exceptions of ESO 323-G077 and NGC 6814. The mean value of the 95% confidence level {gamma}-ray upper limit for the integrated photon flux above 100 MeV from the analyzed Seyferts is {approx_equal} 4 Multiplication-Sign 10{sup -9} photons cm{sup -2} s{sup -1} , and the upper limits derived for several objects reach {approx_equal} 1 Multiplication-Sign 10{sup -9} photons cm{sup -2} s{sup -1} . Our results indicate that no prominent {gamma}-ray emission component related to active galactic nucleus activity is present in the spectra of Seyferts around GeV energies. The Fermi-LAT upper limits derived for our sample probe the ratio of {gamma}-ray to X-ray luminosities L{sub {gamma}}/L{sub X} < 0.1, and even <0.01 in some cases. The obtained results impose novel constraints on the models for high-energy radiation of 'radio-quiet' Seyfert galaxies.« less

CHANDRA OBSERVATIONS OF GALAXY ZOO MERGERS: FREQUENCY OF BINARY ACTIVE NUCLEI IN MASSIVE MERGERS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Teng, Stacy H.; Schawinski, Kevin; Urry, C. Megan

We present the results from a Chandra pilot study of 12 massive galaxy mergers selected from Galaxy Zoo. The sample includes major mergers down to a host galaxy mass of 10{sup 11} M{sub Sun} that already have optical active galactic nucleus (AGN) signatures in at least one of the progenitors. We find that the coincidences of optically selected active nuclei with mildly obscured (N{sub H} {approx}< 1.1 Multiplication-Sign 10{sup 22} cm{sup -2}) X-ray nuclei are relatively common (8/12), but the detections are too faint (<40 counts per nucleus; f{sub 2-10keV} {approx}< 1.2 Multiplication-Sign 10{sup -13} erg s{sup -1} cm{sup -2})more » to reliably separate starburst and nuclear activity as the origin of the X-ray emission. Only one merger is found to have confirmed binary X-ray nuclei, though the X-ray emission from its southern nucleus could be due solely to star formation. Thus, the occurrences of binary AGNs in these mergers are rare (0%-8%), unless most merger-induced active nuclei are very heavily obscured or Compton thick.« less

An investigation of coronal active region loop structures using AS&E rocket X-ray images

NASA Technical Reports Server (NTRS)

Webb, D. F.

1983-01-01

Simultaneous high spatial resolution observations at 6 cm in soft X-rays, in photospheric magnetograms, and in optical filtergrams were used to compare the most intense sources of centimetric emission in two active regions to coronal loops, sunspots, chromospheric structures, and photospheric magnetic fields. Results show that the majority of the bright microwave components are not associated with sunspots or X-ray emission. A nonthermal mechanism appears necessary to explain the brightest microwave components, discrete regions of continuous particle acceleration may be common in active regions. Studies of the plasma parameters of selected loops imply that the radio emission is consistent with gyro-resonance absorption at the third and fourth harmonic, at least from part of each loop. Results are presented for: (1) X-ray and microwave observations of active regions; (2) comparison of coronal holes observed in soft X-rays and Hel 10830 A spectrosheliograms; and (3) the reappearance of polar coronal holes and the evolution of the solar magnetic field.

Atomic-scale distortion of optically activated Sm dopants identified with site-selective X-ray absorption spectroscopy

NASA Astrophysics Data System (ADS)

Ishii, Masashi; Crowe, Iain F.; Halsall, Matthew P.; Hamilton, Bruce; Hu, Yongfeng; Sham, Tsun-Kong; Harako, Susumu; Zhao, Xin-Wei; Komuro, Shuji

2013-10-01

The local structure of luminescent Sm dopants was investigated using an X-ray absorption fine-structure technique with X-ray-excited optical luminescence. Because this technique evaluates X-ray absorption from luminescence, only optically active sites are analyzed. The Sm L3 near-edge spectrum contains split 5d states and a shake-up transition that are specific to luminescent Sm. Theoretical calculations using cluster models identified an atomic-scale distortion that can reproduce the split 5d states. The model with C4v local symmetry and compressive bond length of Sm-O of a six-fold oxygen (SmO6) cluster is most consistent with the experimental results.

An astrophysics data program investigation of a synoptic study of quasar continua

NASA Technical Reports Server (NTRS)

Elvis, Martin

1991-01-01

A summary of the program is presented. The major product of the program, an atlas of quasar energy distributions, is presented in the appendices along with papers written as a result of this research. The topics covered in the papers include: (1) accurate galactic N(sub h) values toward quasars and active galactic nuclei (AGN); (2) weak bump quasars; (3) millimeter measurements of hard x ray selected active galaxies- implications for the nature of the continuous spectrum; (3) persistence and change in the soft x ray spectrum of the quasar PG1211+143; (4) the soft x ray excess in einstein quasar spectra; and (5) EXOSAT x ray spectra of quasars.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trouille, L.; Barger, A. J.; Tremonti, C.

The Baldwin, Phillips, and Terlevich emission-line ratio diagnostic ([O III]/H{beta} versus [N II]/H{alpha}, hereafter BPT diagram) efficiently separates galaxies whose signal is dominated by star formation (BPT-SF) from those dominated by active galactic nucleus (AGN) activity (BPT-AGN). Yet this BPT diagram is limited to z < 0.5, the redshift at which [N II]{lambda}6584 leaves the optical spectral window. Using the Sloan Digital Sky Survey (SDSS), we construct a new diagnostic, or TBT diagram, that is based on rest-frame g - z color, [Ne III]{lambda}3869, and [O II]{lambda}{lambda}3726 + 3729 and can be used for galaxies out to z < 1.4.more » The TBT diagram identifies 98.7% of the SDSS BPT-AGN as TBT-AGN and 97% of the SDSS BPT-SF as TBT-SF. Furthermore, it identifies 97% of the OPTX Chandra X-ray-selected AGNs as TBT-AGN. This is in contrast to the BPT diagram, which misidentifies 20% of X-ray-selected AGNs as BPT-SF. We use the Great Observatories Origins Deep Survey North and Lockman Hole galaxy samples, with their accompanying deep Chandra imaging, to perform X-ray and infrared stacking analyses to further validate our TBT-AGN and TBT-SF selections; that is, we verify the dominance of AGN activity in the former and star formation activity in the latter. Finally, we address the inclusion of the majority of the BPT-comp (sources lying between the BPT-SF and BPT-AGN regimes) in our TBT-AGN regime. We find that the stacked BPT-comp source is X-ray hard (({Gamma}{sub eff}) = 1.0{sup +0.4}{sub -0.4}) and has a high X-ray luminosity to total infrared luminosity ratio. This suggests that, on average, the X-ray signal in BPT-comp is dominated by obscured or low accretion rate AGN activity rather than by star formation, supporting their inclusion in the TBT-AGN regime.« less

Systematic and Performance Tests of the Hard X-ray Polarimeter X-Calibur

NASA Astrophysics Data System (ADS)

Endsley, Ryan; Beilicke, Matthias; Kislat, Fabian; Krawczynski, Henric; X-Calibur/InFOCuS

2015-01-01

X-ray polarimetry has great potential to reveal new astrophysical information about the emission processes of high energy sources such as black hole environments, X-ray binary systems, and active galactic nuclei. Here we present the results and conclusions of systematic and performance measurements of the hard X-ray polarimeter, X-Calibur. Designed to be flown on a balloon-borne X-ray telescope, X-Calibur will achieve unprecedented sensitivity and makes use of the fact that polarized X-rays preferentially Compton-scatter perpendicular to their E-field vector. Extensive laboratory measurements taken at Washington University and the Cornell High-Energy Synchrotron Source (CHESS) indicate that X-Calibur combines a detection efficiency on the order of unity with a high modulation factor of µ ≈ 0.5 averaged over the whole detector assembly, and with values up to µ ≈ 0.7 for select subsections of the polarimeter. Additionally, we are able to suppress background flux by more than two orders of magnitude by utilizing an active shield and scintillator coincidence. Comparing laboratory data with Monte Carlo simulations of both polarized and unpolarized hard X-ray beams illustrate that we have an exceptional understanding of the detector response.

Analysis of selected microflares observed by SphinX over the last minimum of solar activity

NASA Astrophysics Data System (ADS)

Siarkowski, Marek; Sylwester, Janusz; Sylwester, Barbara; Gryciuk, Magdalena

The Solar Photometer in X-rays (SphinX) was designed to observe soft X-ray solar emission in the energy range between 1 keV and 15 keV with the resolution better than 0.5 keV. The instrument operated from February until November 2009 aboard CORONAS-Photon satellite, during the phase of exceptionally low minimum of solar activity. Here we use SphinX data for analysis of selected microflare-class events. We selected events of unusual lightcurves or location. Our study involves determination of temporal characteristics (times of start, maximum and end of flares) and analysis of physical conditions in flaring plasma (temperature, emission measure). Dedicated method has been used in order to remove emission not related to flare. Supplementary information about morphology and evolution of investigated events has been derived from the analysis of XRT/Hinode and SECCHI /STEREO images.

ROSAT x ray survey observations of active chromospheric binary systems and other selected sources

NASA Technical Reports Server (NTRS)

Ramsey, Lawrence W.

1993-01-01

The connection between processes that produce optical chromospheric activity indicators and those that produce x-rays in RS CVn binary systems by taking advantage of the ROSAT All-Sky Survey (RASS) results and our unique ground-based data set was investigated. In RS CVn systems, excess emission in the Ca 2 resonance (K & H) and infrared triplet (IRT) lines and in the Balmer lines of hydrogen is generally cited as evidence for chromospheric activity, which is usually modeled as scaled up solar-type activity. X-ray emission in RS CVn systems is believed to arise from coronal loop structures. Results from spectra data obtained from RASS observations are discussed and presented.

Black hole growth and starburst activity at z = 0.6-4 in the Chandra Deep Field South. Host galaxies properties of obscured AGN

NASA Astrophysics Data System (ADS)

Brusa, M.; Fiore, F.; Santini, P.; Grazian, A.; Comastri, A.; Zamorani, G.; Hasinger, G.; Merloni, A.; Civano, F.; Fontana, A.; Mainieri, V.

2009-12-01

Aims: The co-evolution of host galaxies and the active black holes which reside in their centre is one of the most important topics in modern observational cosmology. Here we present a study of the properties of obscured active galactic nuclei (AGN) detected in the CDFS 1 Ms observation and their host galaxies. Methods: We limited the analysis to the MUSIC area, for which deep K-band observations obtained with ISAAC@VLT are available, ensuring accurate identifications of the counterparts of the X-ray sources as well as reliable determination of photometric redshifts and galaxy parameters, such as stellar masses and star formation rates. In particular, we: 1) refined the X-ray/infrared/optical association of 179 sources in the MUSIC area detected in the Chandra observation; 2) studied the host galaxies observed and rest frame colors and properties. Results: We found that X-ray selected (LX ⪆ 1042 erg s-1) AGN show Spitzer colors consistent with both AGN and starburst dominated infrared continuum; the latter would not have been selected as AGN from infrared diagnostics. The host galaxies of X-ray selected obscured AGN are all massive (Mast > 1010 M_⊙) and, in 50% of the cases, are also actively forming stars (1/SSFR < tHubble) in dusty environments. The median L/LEdd value of the active nucleus is between 2% and 10% depending on the assumed MBH/Mast ratio. Finally, we found that the X-ray selected AGN fraction increases with the stellar mass up to a value of 30% at z > 1 and Mast > 3 × 1011 M_⊙, a fraction significantly higher than in the local Universe for AGN of similar luminosities. Tables [see full textsee full textsee full text] and [see full textsee full textsee full text] are only available in electronic form at http://www.aanda.org

Solution XAS Analysis for Exploring the Active Species in Homogeneous Vanadium Complex Catalysis

NASA Astrophysics Data System (ADS)

Nomura, Kotohiro; Mitsudome, Takato; Tsutsumi, Ken; Yamazoe, Seiji

2018-06-01

Selected examples in V K-edge X-ray Absorption Near Edge Structure (XANES) analysis of a series of vanadium complexes containing imido ligands (possessing metal-nitrogen double bond) in toluene solution have been introduced, and their pre-edge and the edge were affected by their structures and nature of ligands. Selected results in exploring the oxidation states of the active species in ethylene dimerization/polymerization using homogeneous vanadium catalysts [consisting of (imido)vanadium(V) complexes and Al cocatalysts] by X-ray absorption spectroscopy (XAS) analyses have been introduced. It has been demonstrated that the method should provide more clear information concerning the active species in situ, especially by combination with the other methods (NMR and ESR spectra, X-ray crystallographic analysis, and reaction chemistry), and should be powerful tool for study of catalysis mechanism as well as for the structural analysis in solution.

The Complete Local Volume Groups Sample - I. Sample selection and X-ray properties of the high-richness subsample

NASA Astrophysics Data System (ADS)

O'Sullivan, Ewan; Ponman, Trevor J.; Kolokythas, Konstantinos; Raychaudhury, Somak; Babul, Arif; Vrtilek, Jan M.; David, Laurence P.; Giacintucci, Simona; Gitti, Myriam; Haines, Chris P.

2017-12-01

We present the Complete Local-Volume Groups Sample (CLoGS), a statistically complete optically selected sample of 53 groups within 80 Mpc. Our goal is to combine X-ray, radio and optical data to investigate the relationship between member galaxies, their active nuclei and the hot intra-group medium (IGM). We describe sample selection, define a 26-group high-richness subsample of groups containing at least four optically bright (log LB ≥ 10.2 LB⊙) galaxies, and report the results of XMM-Newton and Chandra observations of these systems. We find that 14 of the 26 groups are X-ray bright, possessing a group-scale IGM extending at least 65 kpc and with luminosity >1041 erg s-1, while a further three groups host smaller galaxy-scale gas haloes. The X-ray bright groups have masses in the range M500 ≃ 0.5-5 × 1013 M⊙, based on system temperatures of 0.4-1.4 keV, and X-ray luminosities in the range 2-200 × 1041 erg s-1. We find that ∼53-65 per cent of the X-ray bright groups have cool cores, a somewhat lower fraction than found by previous archival surveys. Approximately 30 per cent of the X-ray bright groups show evidence of recent dynamical interactions (mergers or sloshing), and ∼35 per cent of their dominant early-type galaxies host active galactic nuclei with radio jets. We find no groups with unusually high central entropies, as predicted by some simulations, and confirm that CLoGS is in principle capable of detecting such systems. We identify three previously unrecognized groups, and find that they are either faint (LX, R500 < 1042 erg s-1) with no concentrated cool core, or highly disturbed. This leads us to suggest that ∼20 per cent of X-ray bright groups in the local universe may still be unidentified.

X-Ray Temperatures, Luminosities, and Masses from XMM-Newton Follow-up of the First Shear-selected Galaxy Cluster Sample

DOE Office of Scientific and Technical Information (OSTI.GOV)

Deshpande, Amruta J.; Hughes, John P.; Wittman, David, E-mail: amrejd@physics.rutgers.edu, E-mail: jph@physics.rutgers.edu, E-mail: dwittman@physics.ucdavis.edu

We continue the study of the first sample of shear-selected clusters from the initial 8.6 square degrees of the Deep Lens Survey (DLS); a sample with well-defined selection criteria corresponding to the highest ranked shear peaks in the survey area. We aim to characterize the weak lensing selection by examining the sample’s X-ray properties. There are multiple X-ray clusters associated with nearly all the shear peaks: 14 X-ray clusters corresponding to seven DLS shear peaks. An additional three X-ray clusters cannot be definitively associated with shear peaks, mainly due to large positional offsets between the X-ray centroid and the shearmore » peak. Here we report on the XMM-Newton properties of the 17 X-ray clusters. The X-ray clusters display a wide range of luminosities and temperatures; the L {sub X} − T {sub X} relation we determine for the shear-associated X-ray clusters is consistent with X-ray cluster samples selected without regard to dynamical state, while it is inconsistent with self-similarity. For a subset of the sample, we measure X-ray masses using temperature as a proxy, and compare to weak lensing masses determined by the DLS team. The resulting mass comparison is consistent with equality. The X-ray and weak lensing masses show considerable intrinsic scatter (∼48%), which is consistent with X-ray selected samples when their X-ray and weak lensing masses are independently determined.« less

The dependence of the soft X ray spectral slope with radio property, luminosity, and redshift, for a large sample of AGN from the Einstein IPC data base

NASA Technical Reports Server (NTRS)

Brunner, H.; Worrall, D. M.; Wilkes, Belinda J.; Elvis, Martin

1989-01-01

The dependence of the soft X-ray spectral slope on radio, optical and X-ray properties, and on redshift are reported for a large sample of Active Galactic Nuclei (AGN). The sample includes 317 optically and radio-selected AGN from a preliminary version of the Einstein Imaging Proportional Counter (IPC) quasar and AGN data base. The main results are: the difference in X-ray slope between radio-loud and radio-quiet AGN were confirmed for an independent and much larger sample of sources; a difference in X-ray slope between flat and steep radio spectrum AGN is observed only in high luminosity sub-sample; in flat radio spectrum AGNs there is an indication for a dependence of the X-ray spectral index on X-ray luminosity redshift and alpha sub 0x.

X-Ray Temperatures, Luminosities, and Masses from XMM-Newton Follow-upof the First Shear-selected Galaxy Cluster Sample

NASA Astrophysics Data System (ADS)

Deshpande, Amruta J.; Hughes, John P.; Wittman, David

2017-04-01

We continue the study of the first sample of shear-selected clusters from the initial 8.6 square degrees of the Deep Lens Survey (DLS); a sample with well-defined selection criteria corresponding to the highest ranked shear peaks in the survey area. We aim to characterize the weak lensing selection by examining the sample’s X-ray properties. There are multiple X-ray clusters associated with nearly all the shear peaks: 14 X-ray clusters corresponding to seven DLS shear peaks. An additional three X-ray clusters cannot be definitively associated with shear peaks, mainly due to large positional offsets between the X-ray centroid and the shear peak. Here we report on the XMM-Newton properties of the 17 X-ray clusters. The X-ray clusters display a wide range of luminosities and temperatures; the L X -T X relation we determine for the shear-associated X-ray clusters is consistent with X-ray cluster samples selected without regard to dynamical state, while it is inconsistent with self-similarity. For a subset of the sample, we measure X-ray masses using temperature as a proxy, and compare to weak lensing masses determined by the DLS team. The resulting mass comparison is consistent with equality. The X-ray and weak lensing masses show considerable intrinsic scatter (˜48%), which is consistent with X-ray selected samples when their X-ray and weak lensing masses are independently determined. Some of the data presented herein were obtained at the W.M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration. The Observatory was made possible by the generous financial support of the W. M. Keck Foundation.

Common observations of solar X-rays from SPHINX/CORONAS-PHOTON and XRS/MESSENGER

NASA Astrophysics Data System (ADS)

Kepa, Anna; Sylwester, Janusz; Sylwester, Barbara; Siarkowski, Marek; Mrozek, Tomasz; Gryciuk, Magdalena; Phillips, Kenneth

SphinX was a soft X-ray spectrophotometer constructed in the Space Research Centre of Polish Academy of Sciences. The instrument was launched on 30 January 2009 aboard CORONAS-PHOTON satellite as a part of TESIS instrument package. SphinX measured total solar X-ray flux in the energy range from 1 to 15 keV during the period of very low solar activity from 20 February to 29 November 2009. For these times the solar detector (X-ray Spectrometer - XRS) onboard MESSENGER also observed the solar X-rays from a different vantage point. XRS measured the radiation in similar energy range. We present results of the comparison of observations from both instruments and show the preliminary results of physical analysis of spectra for selected flares.

Chandra stacking analysis of CANDELS galaxies at z>1.5

NASA Astrophysics Data System (ADS)

Civano, Francesca

2016-09-01

The goal of this proposal is to study the X-ray emission of non-X-ray detected galaxies at z>1.5, beyond the peak of stellar and nuclear activity, in combination with galaxy global properties, such as stellar mass and star formation activity and their morphological classification. To achieve this goal, we will select galaxies in CANDELS. Making use of the 5 X-ray surveys with different depths (160 ks for COSMOS, 800 ks for AEGIS-XD and X-UDS, 2 Ms for GOODS-N and 4 (8) Ms GOODS-S) available in these famous fields, we will be able to reach X-ray luminosities where stellar emission dominate the nuclear one. This analysis will extend to z>1.5, the results obtained performing stacking analysis solely using the Chandra COSMOS Legacy Survey at lower redshift.

Tetrahedral hydrocarbon nanoparticles in space: X-ray spectra

NASA Astrophysics Data System (ADS)

Bilalbegović, G.; Maksimović, A.; Valencic, L. A.

2018-06-01

It has been proposed, or confirmed, that diamond nanoparticles exist in various environments in space: close to active galactic nuclei, in the vicinity of supernovae and pulsars, in the interior of several planets in the Solar system, in carbon planets, and other exoplanets, carbon-rich stars, meteorites, in X-ray active Herbig Ae/Be stars, and in the interstellar medium. Using density functional theory methods, we calculate the carbon K-edge X-ray absorption spectrum of two large tetrahedral nanodiamonds: C26H32 and C51H52. We also study and test our methods on the astrophysical molecule CH4, the smallest C-H tetrahedral structure. A possible detection of nanodiamonds from X-ray spectra by future telescopes, such as the project Arcus, is proposed. Simulated spectra of the diffuse interstellar medium using Cyg X-2 as a source show that nanodiamonds studied in this work can be detected by Arcus, a high-resolution X-ray spectrometer mission selected by NASA for a Phase A concept study.

Searching for Dual AGNs in Galaxy Mergers: Understanding Double-Peaked [O III] and Ultra Hard X-rays as Selection Method

NASA Astrophysics Data System (ADS)

McGurk, Rosalie C.; Max, Claire E.; Medling, Anne; Shields, Gregory A.

2015-01-01

When galaxies merge, gas accretes onto both central supermassive black holes. Thus, one expects to see close pairs of active galactic nuclei (AGNs), or dual AGNs, in a fraction of galaxy mergers. However, finding them remains a challenge. The presence of double-peaked [O III] or of ultra hard X-rays have been proposed as techniques to select dual AGNs efficiently. We studied a sample of double-peaked narrow [O III] emitting AGNs from SDSS DR7. By obtaining new and archival high spatial resolution images taken with the Keck 2 Laser Guide Star Adaptive Optics system and the near-infrared (IR) camera NIRC2, we showed that 30% of double-peaked [O III] emission line SDSS AGNs have two spatial components within a 3' radius. However, spatially resolved spectroscopy or X-ray observations are needed to confirm these galaxy pairs as systems containing two AGNs. We followed up these spatially-double candidate dual AGNs with integral field spectroscopy from Keck OSIRIS and Gemini GMOS and with long-slit spectroscopy from Keck NIRSPEC and Shane Kast Double Spectrograph. We find double-peaked emitters are caused sometimes by dual AGN and sometimes by outflows or narrow line kinematics. We also performed Chandra X-ray ACIS-S observations on 12 double-peaked candidate dual AGNs. Using our observations and 8 archival observations, we compare the distribution of X-ray photons to our spatially double near-IR images, measure X-ray luminosities and hardness ratios, and estimate column densities. By assessing what fraction of double-peaked emission line SDSS AGNs are true dual AGNs, we can better determine whether double-peaked [O III] is an efficient dual AGN indicator and constrain the statistics of dual AGNs. A second technique to find dual AGN is the detection of ultra hard X-rays by the Swift Burst Alert Telescope. We use CARMA observations to measure and map the CO(1-0) present in nearby ultra-hard X-ray Active Galactic Nuclei (AGNs) merging with either a quiescent companion galaxy or a companion galaxy hosting a second AGN, in order to understand the role molecular gas plays in feeding this unusual population of ultra-hard X-ray AGNs and to understand ultra-hard X-rays as a dual AGN selection method.

The clustering amplitude of X-ray-selected AGN at z ˜ 0.8: evidence for a negative dependence on accretion luminosity

NASA Astrophysics Data System (ADS)

Mountrichas, G.; Georgakakis, A.; Menzel, M.-L.; Fanidakis, N.; Merloni, A.; Liu, Z.; Salvato, M.; Nandra, K.

2016-04-01

The northern tile of the wide-area and shallow XMM-XXL X-ray survey field is used to estimate the average dark matter halo mass of relatively luminous X-ray-selected active galactic nucleus (AGN) [log {L}_X (2-10 keV)= 43.6^{+0.4}_{-0.4} erg s^{-1}] in the redshift interval z = 0.5-1.2. Spectroscopic follow-up observations of X-ray sources in the XMM-XXL field by the Sloan telescope are combined with the VIMOS Public Extragalactic Redshift Survey spectroscopic galaxy survey to determine the cross-correlation signal between X-ray-selected AGN (total of 318) and galaxies (about 20 000). We model the large scales (2-25 Mpc) of the correlation function to infer a mean dark matter halo mass of log M / (M_{{⊙}} h^{-1}) = 12.50 ^{+0.22} _{-0.30} for the X-ray-selected AGN sample. This measurement is about 0.5 dex lower compared to estimates in the literature of the mean dark matter halo masses of moderate-luminosity X-ray AGN [LX(2-10 keV) ≈ 1042-1043 erg s- 1] at similar redshifts. Our analysis also links the mean clustering properties of moderate-luminosity AGN with those of powerful ultraviolet/optically selected QSOs, which are typically found in haloes with masses few times 1012 M⊙. There is therefore evidence for a negative luminosity dependence of the AGN clustering. This is consistent with suggestions that AGN have a broad dark matter halo mass distribution with a high mass tail that becomes subdominant at high accretion luminosities. We further show that our results are in qualitative agreement with semi-analytic models of galaxy and AGN evolution, which attribute the wide range of dark matter halo masses among the AGN population to different triggering mechanisms and/or black hole fuelling modes.

Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kunnus, Kristjan; Josefsson, Ida; Rajkovic, Ivan

Here, ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbitalmore » and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)5 in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given—which will be covered experimentally by upcoming transform-limited x-ray sources.« less

Anti-Stokes resonant x-ray Raman scattering for atom specific and excited state selective dynamics

DOE PAGES

Kunnus, Kristjan; Josefsson, Ida; Rajkovic, Ivan; ...

2016-10-07

Here, ultrafast electronic and structural dynamics of matter govern rate and selectivity of chemical reactions, as well as phase transitions and efficient switching in functional materials. Since x-rays determine electronic and structural properties with elemental, chemical, orbital and magnetic selectivity, short pulse x-ray sources have become central enablers of ultrafast science. Despite of these strengths, ultrafast x-rays have been poor at picking up excited state moieties from the unexcited ones. With time-resolved anti-Stokes resonant x-ray Raman scattering (AS-RXRS) performed at the LCLS, and ab initio theory we establish background free excited state selectivity in addition to the elemental, chemical, orbitalmore » and magnetic selectivity of x-rays. This unparalleled selectivity extracts low concentration excited state species along the pathway of photo induced ligand exchange of Fe(CO)5 in ethanol. Conceptually a full theoretical treatment of all accessible insights to excited state dynamics with AS-RXRS with transform-limited x-ray pulses is given—which will be covered experimentally by upcoming transform-limited x-ray sources.« less

X-ray versus infrared selection of distant galaxy clusters: A case study using the XMM-LSS and SpARCS cluster samples

NASA Astrophysics Data System (ADS)

Willis, J. P.; Ramos-Ceja, M. E.; Muzzin, A.; Pacaud, F.; Yee, H. K. C.; Wilson, G.

2018-04-01

We present a comparison of two samples of z > 0.8 galaxy clusters selected using different wavelength-dependent techniques and examine the physical differences between them. We consider 18 clusters from the X-ray selected XMM-LSS distant cluster survey and 92 clusters from the optical-MIR selected SpARCS cluster survey. Both samples are selected from the same approximately 9 square degree sky area and we examine them using common XMM-Newton, Spitzer-SWIRE and CFHT Legacy Survey data. Clusters from each sample are compared employing aperture measures of X-ray and MIR emission. We divide the SpARCS distant cluster sample into three sub-samples: a) X-ray bright, b) X-ray faint, MIR bright, and c) X-ray faint, MIR faint clusters. We determine that X-ray and MIR selected clusters display very similar surface brightness distributions of galaxy MIR light. In addition, the average location and amplitude of the galaxy red sequence as measured from stacked colour histograms is very similar in the X-ray and MIR-selected samples. The sub-sample of X-ray faint, MIR bright clusters displays a distribution of BCG-barycentre position offsets which extends to higher values than all other samples. This observation indicates that such clusters may exist in a more disturbed state compared to the majority of the distant cluster population sampled by XMM-LSS and SpARCS. This conclusion is supported by stacked X-ray images for the X-ray faint, MIR bright cluster sub-sample that display weak, centrally-concentrated X-ray emission, consistent with a population of growing clusters accreting from an extended envelope of material.

X-ray lithography using holographic images

DOEpatents

Howells, Malcolm R.; Jacobsen, Chris

1995-01-01

A non-contact X-ray projection lithography method for producing a desired X-ray image on a selected surface of an X-ray-sensitive material, such as photoresist material on a wafer, the desired X-ray image having image minimum linewidths as small as 0.063 .mu.m, or even smaller. A hologram and its position are determined that will produce the desired image on the selected surface when the hologram is irradiated with X-rays from a suitably monochromatic X-ray source of a selected wavelength .lambda.. On-axis X-ray transmission through, or off-axis X-ray reflection from, a hologram may be used here, with very different requirements for monochromaticity, flux and brightness of the X-ray source. For reasonable penetration of photoresist materials by X-rays produced by the X-ray source, the wavelength X, is preferably chosen to be no more than 13.5 nm in one embodiment and more preferably is chosen in the range 1-5 nm in the other embodiment. A lower limit on linewidth is set by the linewidth of available microstructure writing devices, such as an electron beam.

EVIDENCE FOR ELEVATED X-RAY EMISSION IN LOCAL LYMAN BREAK GALAXY ANALOGS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Basu-Zych, Antara R.; Lehmer, Bret D.; Hornschemeier, Ann E.

2013-09-10

Our knowledge of how X-ray emission scales with star formation at the earliest times in the universe relies on studies of very distant Lyman break galaxies (LBGs). In this paper, we study the relationship between the 2-10 keV X-ray luminosity (L{sub X}), assumed to originate from X-ray binaries (XRBs), and star formation rate (SFR) in ultraviolet (UV) selected z < 0.1 Lyman break analogs (LBAs). We present Chandra observations for four new Galaxy Evolution Explorer selected LBAs. Including previously studied LBAs, Haro 11 and VV 114, we find that LBAs demonstrate L{sub X}/SFR ratios that are elevated by {approx}1.5{sigma} comparedmore » to local galaxies, similar to the ratios found for stacked LBGs in the early universe (z > 2). Unlike some of the composite LBAs studied previously, we show that these LBAs are unlikely to harbor active galactic nuclei, based on their optical and X-ray spectra and the spatial distribution of the X-rays in three spatially extended cases. Instead, we expect that high-mass X-ray binaries (HMXBs) dominate the X-ray emission in these galaxies, based on their high specific SFRs (sSFRs {identical_to} SFR/M{sub *} {>=} 10{sup -9} yr{sup -1}), which suggest the prevalence of young stellar populations. Since both UV-selected populations (LBGs and LBAs) have lower dust attenuations and metallicities compared to similar samples of more typical local galaxies, we investigate the effects of dust extinction and metallicity on the L{sub X}/SFR for the broader population of galaxies with high sSFRs (>10{sup -10} yr{sup -1}). The estimated dust extinctions (corresponding to column densities of N{sub H} < 10{sup 22} cm{sup -2}) are expected to have insignificant effects on observed L{sub X}/SFR ratio for the majority of galaxy samples. We find that the observed relationship between L{sub X}/SFR and metallicity appears consistent with theoretical expectations from XRB population synthesis models. Therefore, we conclude that lower metallicities, related to more luminous HMXBs such as ultraluminous X-ray sources, drive the elevated L{sub X}/SFR observed in our sample of z < 0.1 LBAs. The relatively metal-poor, active mode of star formation in LBAs and distant z > 2 LBGs may yield higher total HMXB luminosity than found in typical galaxies in the local universe.« less

Determination of Differential Emission Measure Distribution of Coronal Structures Observed by SphinX During Recent Minimum of Solar Activity

NASA Astrophysics Data System (ADS)

Kepa, Anna; Gburek, Szymon; Siarkowski, Marek; Sylwester, Barbara; Sylwester, Janusz; Kowalinski, Miroslaw

SphinX is a high-sensitivity soft X-ray spectrophotometer which measures soft X-ray spectra in the energy range between 0.8 keV and 15 keV. From February to November 2009 the instrument has observed unusually quiet solar coronal emission as well as a number of weak solar flares. Based on SphinX spectra it is possible to study the differential emission measure distributions (DEM) in the temperature range roughly between 1 MK and 10 MK. The aim of the present study is to unveil DEM plasma distributions for selected activity conditions and analyze their variability.

Correlations of the IR Luminosity and Eddington Ratio with a Hard X-ray Selected Sample of AGN

NASA Technical Reports Server (NTRS)

Mushotzy, Richard F.; Winter, Lisa M.; McIntosh, Daniel H.; Tueller, Jack

2008-01-01

We use the SWIFT Burst Alert Telescope (BAT) sample of hard x-ray selected active galactic nuclei (AGN) with a median redshift of 0.03 and the 2MASS J and K band photometry to examine the correlation of hard x-ray emission to Eddington ratio as well as the relationship of the J and K band nuclear luminosity to the hard x-ray luminosity. The BAT sample is almost unbiased by the effects of obscuration and thus offers the first large unbiased sample for the examination of correlations between different wavelength bands. We find that the near-IR nuclear J and K band luminosity is related to the BAT (14 - 195 keV) luminosity over a factor of 10(exp 3) in luminosity (L(sub IR) approx.equals L(sub BAT)(sup 1.25) and thus is unlikely to be due to dust. We also find that the Eddington ratio is proportional to the x-ray luminosity. This new result should be a strong constraint on models of the formation of the broad band continuum.

X-Ray Processing of ChaMPlane Fields: Methods and Initial Results for Selected Anti-Galactic Center Fields

NASA Astrophysics Data System (ADS)

Hong, JaeSub; van den Berg, Maureen; Schlegel, Eric M.; Grindlay, Jonathan E.; Koenig, Xavier; Laycock, Silas; Zhao, Ping

2005-12-01

We describe the X-ray analysis procedure of the ongoing Chandra Multiwavelength Plane (ChaMPlane) Survey and report the initial results from the analysis of 15 selected anti-Galactic center observations (90deg

Do X-ray dark or underluminous galaxy clusters exist?

NASA Astrophysics Data System (ADS)

Andreon, S.; Moretti, A.

2011-12-01

We study the X-ray properties of a color-selected sample of clusters at 0.1 < z < 0.3, to quantify the real aboundance of the population of X-ray dark or underluminous clusters and at the same time the spurious detection contamination level of color-selected cluster catalogs. Starting from a local sample of color-selected clusters, we restrict our attention to those with sufficiently deep X-ray observations to probe their X-ray luminosity down to very faint values and without introducing any X-ray bias. This allowed us to have an X-ray- unbiased sample of 33 clusters to measure the LX-richness relation. Swift 1.4 Ms X-ray observations show that at least 89% of the color-detected clusters are real objects with a potential well deep enough to heat and retain an intracluster medium. The percentage rises to 94% when one includes the single spectroscopically confirmed color-selected cluster whose X-ray emission is not secured. Looking at our results from the opposite perspective, the percentage of X-ray dark clusters among color-selected clusters is very low: at most about 11 per cent (at 90% confidence). Supplementing our data with those from literature, we conclude that X-ray- and color- cluster surveys sample the same population and consequently that in this regard we can safely use clusters selected with any of the two methods for cosmological purposes. This is an essential and promising piece of information for upcoming surveys in both the optical/IR (DES, EUCLID) and X-ray (eRosita). Richness correlates with X-ray luminosity with a large scatter, 0.51 ± 0.08 (0.44 ± 0.07) dex in lgLX at a given richness, when Lx is measured in a 500 (1070) kpc aperture. We release data and software to estimate the X-ray flux, or its upper limit, of a source with over-Poisson background fluctuations (found in this work to be ~20% on cluster angular scales) and to fit X-ray luminosity vs richness if there is an intrinsic scatter. These Bayesian applications rigorously account for boundaries (e.g., the X-ray luminosity and the richness cannot be negative).

The OPTX Project. V. Identifying Distant Active Galactic Nuclei

NASA Astrophysics Data System (ADS)

Trouille, L.; Barger, A. J.; Tremonti, C.

2011-11-01

The Baldwin, Phillips, and Terlevich emission-line ratio diagnostic ([O III]/Hβ versus [N II]/Hα, hereafter BPT diagram) efficiently separates galaxies whose signal is dominated by star formation (BPT-SF) from those dominated by active galactic nucleus (AGN) activity (BPT-AGN). Yet this BPT diagram is limited to z < 0.5, the redshift at which [N II]λ6584 leaves the optical spectral window. Using the Sloan Digital Sky Survey (SDSS), we construct a new diagnostic, or TBT diagram, that is based on rest-frame g - z color, [Ne III]λ3869, and [O II]λλ3726 + 3729 and can be used for galaxies out to z < 1.4. The TBT diagram identifies 98.7% of the SDSS BPT-AGN as TBT-AGN and 97% of the SDSS BPT-SF as TBT-SF. Furthermore, it identifies 97% of the OPTX Chandra X-ray-selected AGNs as TBT-AGN. This is in contrast to the BPT diagram, which misidentifies 20% of X-ray-selected AGNs as BPT-SF. We use the Great Observatories Origins Deep Survey North and Lockman Hole galaxy samples, with their accompanying deep Chandra imaging, to perform X-ray and infrared stacking analyses to further validate our TBT-AGN and TBT-SF selections; that is, we verify the dominance of AGN activity in the former and star formation activity in the latter. Finally, we address the inclusion of the majority of the BPT-comp (sources lying between the BPT-SF and BPT-AGN regimes) in our TBT-AGN regime. We find that the stacked BPT-comp source is X-ray hard (langΓeffrang = 1.0+0.4 -0.4) and has a high X-ray luminosity to total infrared luminosity ratio. This suggests that, on average, the X-ray signal in BPT-comp is dominated by obscured or low accretion rate AGN activity rather than by star formation, supporting their inclusion in the TBT-AGN regime. Some of the data presented herein were obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California, and the National Aeronautics and Space Administration. The observatory was made possible by the generous financial support of the W. M. Keck Foundation.

SPIDERS: selection of spectroscopic targets using AGN candidates detected in all-sky X-ray surveys

NASA Astrophysics Data System (ADS)

Dwelly, T.; Salvato, M.; Merloni, A.; Brusa, M.; Buchner, J.; Anderson, S. F.; Boller, Th.; Brandt, W. N.; Budavári, T.; Clerc, N.; Coffey, D.; Del Moro, A.; Georgakakis, A.; Green, P. J.; Jin, C.; Menzel, M.-L.; Myers, A. D.; Nandra, K.; Nichol, R. C.; Ridl, J.; Schwope, A. D.; Simm, T.

2017-07-01

SPIDERS (SPectroscopic IDentification of eROSITA Sources) is a Sloan Digital Sky Survey IV (SDSS-IV) survey running in parallel to the Extended Baryon Oscillation Spectroscopic Survey (eBOSS) cosmology project. SPIDERS will obtain optical spectroscopy for large numbers of X-ray-selected active galactic nuclei (AGN) and galaxy cluster members detected in wide-area eROSITA, XMM-Newton and ROSAT surveys. We describe the methods used to choose spectroscopic targets for two sub-programmes of SPIDERS X-ray selected AGN candidates detected in the ROSAT All Sky and the XMM-Newton Slew surveys. We have exploited a Bayesian cross-matching algorithm, guided by priors based on mid-IR colour-magnitude information from the Wide-field Infrared Survey Explorer survey, to select the most probable optical counterpart to each X-ray detection. We empirically demonstrate the high fidelity of our counterpart selection method using a reference sample of bright well-localized X-ray sources collated from XMM-Newton, Chandra and Swift-XRT serendipitous catalogues, and also by examining blank-sky locations. We describe the down-selection steps which resulted in the final set of SPIDERS-AGN targets put forward for spectroscopy within the eBOSS/TDSS/SPIDERS survey, and present catalogues of these targets. We also present catalogues of ˜12 000 ROSAT and ˜1500 XMM-Newton Slew survey sources that have existing optical spectroscopy from SDSS-DR12, including the results of our visual inspections. On completion of the SPIDERS programme, we expect to have collected homogeneous spectroscopic redshift information over a footprint of ˜7500 deg2 for >85 per cent of the ROSAT and XMM-Newton Slew survey sources having optical counterparts in the magnitude range 17 < r < 22.5, producing a large and highly complete sample of bright X-ray-selected AGN suitable for statistical studies of AGN evolution and clustering.

A Period-Activity Relation for Active RS CVN Stars

NASA Astrophysics Data System (ADS)

Simon, Theodore

Soft X ray observations of RS CVn binaries point to a correlation between L x /Lbol (the X ray to bolometric luminosity ratio that measures the coronal heating rate) and Omega (the stellar angular velocity). This correlation is almost certainly caused by a stellar dynamo, operating in rapidly-rotating late-type stars with deep convection zones. We are proposing to extend the X ray "rotation-activity relation" to the uv transition region and chromospheric emission lines observable with IUE. If the non-radiative heating rates of stellar transition regions and chromospheres are determined largely by magnetic processes associated with a stellar dynamo, then a similar correlation may be found. We have selected a group of recently discovered active long-period systems, which we believe will be very bright at uv wavelengths. One important goal of this program is to determine whether past studies of the "rotation-activity connection" have been compromised by the omission of active long-period RS CVn systems.

The Complete Local-Volume Groups Sample (CLoGS): Early results from X-ray and radio observations

NASA Astrophysics Data System (ADS)

Vrtilek, Jan M.; O'Sullivan, Ewan; David, Laurence P.; Giacintucci, Simona; Kolokythas, Konstantinos

2017-08-01

Although the group environment is the dominant locus of galaxy evolution (in contrast to rich clusters, which contain only a few percent of galaxies), there has been a lack of reliable, representative group samples in the local Universe. In particular, X-ray selected samples are strongly biased in favor of the X-ray bright, centrally-concentrated cool-core systems. In response, we have designed the Complete Local-Volume Groups Sample (CLoGS), an optically-selected statistically-complete sample of 53 groups within 80 Mpc which is intended to overcome the limitations of X-ray selected samples and serve as a representative survey of groups in the local Universe. We have supplemented X-ray data from Chandra and XMM (70% complete to date, using both archival and new observations, with a 26-group high richness subsample 100% complete) with GMRT radio continuum observations (at 235 and 610 MHz, complete for the entire sample). CLoGS includes groups with a wide variety of properties in terms of galaxy population, hot gas content, and AGN power. We here describe early results from the survey, including the range of AGN activity observed in the dominant galaxies, the relative fraction of cool-core and non-cool-core groups in our sample, and the degree of disturbance observed in the IGM.

Two-dimensional gold nanostructures with high activity for selective oxidation of carbon–hydrogen bonds

PubMed Central

Wang, Liang; Zhu, Yihan; Wang, Jian-Qiang; Liu, Fudong; Huang, Jianfeng; Meng, Xiangju; Basset, Jean-Marie; Han, Yu; Xiao, Feng-Shou

2015-01-01

Efficient synthesis of stable two-dimensional (2D) noble metal catalysts is a challenging topic. Here we report the facile synthesis of 2D gold nanosheets via a wet chemistry method, by using layered double hydroxide as the template. Detailed characterization with electron microscopy and X-ray photoelectron spectroscopy demonstrates that the nanosheets are negatively charged and [001] oriented with thicknesses varying from single to a few atomic layers. X-ray absorption spectroscopy reveals unusually low gold–gold coordination numbers. These gold nanosheets exhibit high catalytic activity and stability in the solvent-free selective oxidation of carbon–hydrogen bonds with molecular oxygen. PMID:25902034

Two-dimensional gold nanostructures with high activity for selective oxidation of carbon-hydrogen bonds.

PubMed

Wang, Liang; Zhu, Yihan; Wang, Jian-Qiang; Liu, Fudong; Huang, Jianfeng; Meng, Xiangju; Basset, Jean-Marie; Han, Yu; Xiao, Feng-Shou

2015-04-22

Efficient synthesis of stable two-dimensional (2D) noble metal catalysts is a challenging topic. Here we report the facile synthesis of 2D gold nanosheets via a wet chemistry method, by using layered double hydroxide as the template. Detailed characterization with electron microscopy and X-ray photoelectron spectroscopy demonstrates that the nanosheets are negatively charged and [001] oriented with thicknesses varying from single to a few atomic layers. X-ray absorption spectroscopy reveals unusually low gold-gold coordination numbers. These gold nanosheets exhibit high catalytic activity and stability in the solvent-free selective oxidation of carbon-hydrogen bonds with molecular oxygen.

Two-dimensional gold nanostructures with high activity for selective oxidation of carbon-hydrogen bonds

NASA Astrophysics Data System (ADS)

Wang, Liang; Zhu, Yihan; Wang, Jian-Qiang; Liu, Fudong; Huang, Jianfeng; Meng, Xiangju; Basset, Jean-Marie; Han, Yu; Xiao, Feng-Shou

2015-04-01

Efficient synthesis of stable two-dimensional (2D) noble metal catalysts is a challenging topic. Here we report the facile synthesis of 2D gold nanosheets via a wet chemistry method, by using layered double hydroxide as the template. Detailed characterization with electron microscopy and X-ray photoelectron spectroscopy demonstrates that the nanosheets are negatively charged and [001] oriented with thicknesses varying from single to a few atomic layers. X-ray absorption spectroscopy reveals unusually low gold-gold coordination numbers. These gold nanosheets exhibit high catalytic activity and stability in the solvent-free selective oxidation of carbon-hydrogen bonds with molecular oxygen.

X-ray versus infrared selection of distant galaxy clusters: a case study using the XMM-LSS and SpARCS cluster samples

NASA Astrophysics Data System (ADS)

Willis, J. P.; Ramos-Ceja, M. E.; Muzzin, A.; Pacaud, F.; Yee, H. K. C.; Wilson, G.

2018-07-01

We present a comparison of two samples of z> 0.8 galaxy clusters selected using different wavelength-dependent techniques and examine the physical differences between them. We consider 18 clusters from the X-ray-selected XMM Large Scale Structure (LSS) distant cluster survey and 92 clusters from the optical-mid-infrared (MIR)-selected Spitzer Adaptation of the Red Sequence Cluster survey (SpARCS) cluster survey. Both samples are selected from the same approximately 9 sq deg sky area and we examine them using common XMM-Newton, Spitizer Wide-Area Infrared Extra-galactic (SWIRE) survey, and Canada-France-Hawaii Telescope Legacy Survey data. Clusters from each sample are compared employing aperture measures of X-ray and MIR emission. We divide the SpARCS distant cluster sample into three sub-samples: (i) X-ray bright, (ii) X-ray faint, MIR bright, and (iii) X-ray faint, MIR faint clusters. We determine that X-ray- and MIR-selected clusters display very similar surface brightness distributions of galaxy MIR light. In addition, the average location and amplitude of the galaxy red sequence as measured from stacked colour histograms is very similar in the X-ray- and MIR-selected samples. The sub-sample of X-ray faint, MIR bright clusters displays a distribution of brightest cluster galaxy-barycentre position offsets which extends to higher values than all other samples. This observation indicates that such clusters may exist in a more disturbed state compared to the majority of the distant cluster population sampled by XMM-LSS and SpARCS. This conclusion is supported by stacked X-ray images for the X-ray faint, MIR bright cluster sub-sample that display weak, centrally concentrated X-ray emission, consistent with a population of growing clusters accreting from an extended envelope of material.

The X-ray properties of high redshift, optically selected QSOs. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Anderson, S. F.

1985-01-01

In order to study the X-ray properties of high redshift QSOs, grism/grens plates covering 17 deg. of sky previously imaged to very sensitive X-ray flux levels with the Einstein Observatory were taken. Following optical selection of the QSO, the archived X-ray image is examined to extract an X-ray flux detection or a sensitive upper limit.

X-ray-bright optically faint active galactic nuclei in the Subaru Hyper Suprime-Cam wide survey

NASA Astrophysics Data System (ADS)

Terashima, Yuichi; Suganuma, Makoto; Akiyama, Masayuki; Greene, Jenny E.; Kawaguchi, Toshihiro; Iwasawa, Kazushi; Nagao, Tohru; Noda, Hirofumi; Toba, Yoshiki; Ueda, Yoshihiro; Yamashita, Takuji

2018-01-01

We construct a sample of X-ray-bright optically faint active galactic nuclei by combining Subaru Hyper Suprime-Cam, XMM-Newton, and infrared source catalogs. Fifty-three X-ray sources satisfying i-band magnitude fainter than 23.5 mag and X-ray counts with the EPIC-PN detector larger than 70 are selected from 9.1 deg2, and their spectral energy distributions (SEDs) and X-ray spectra are analyzed. Forty-four objects with an X-ray to i-band flux ratio FX/Fi > 10 are classified as extreme X-ray-to-optical flux sources. Spectral energy distributions of 48 among 53 are represented by templates of type 2 AGNs or star-forming galaxies and show the optical signature of stellar emission from host galaxies in the source rest frame. Infrared/optical SEDs indicate a significant contribution of emission from dust to the infrared fluxes, and that the central AGN is dust obscured. The photometric redshifts determined from the SEDs are in the range of 0.6-2.5. The X-ray spectra are fitted by an absorbed power-law model, and the intrinsic absorption column densities are modest (best-fit log NH = 20.5-23.5 cm-2 in most cases). The absorption-corrected X-ray luminosities are in the range of 6 × 1042-2 × 1045 erg s-1. Twenty objects are classified as type 2 quasars based on X-ray luminsosity and NH. The optical faintness is explained by a combination of redshifts (mostly z > 1.0), strong dust extinction, and in part a large ratio of dust/gas.

Early-type galaxies in the Chandra cosmos survey

DOE Office of Scientific and Technical Information (OSTI.GOV)

Civano, F.; Fabbiano, G.; Kim, D.-W.

2014-07-20

We study a sample of 69 X-ray detected early-type galaxies (ETGs), selected from the Chandra COSMOS survey, to explore the relation between the X-ray luminosity of hot gaseous halos (L{sub X,{sub gas}}) and the integrated stellar luminosity (L{sub K} ) of the galaxies, in a range of redshift extending out to z = 1.5. In the local universe, a tight, steep relationship has been established between these two quantities (L{sub X,gas}∼L{sub K}{sup 4.5}), suggesting the presence of largely virialized halos in X-ray luminous systems. We use well-established relations from the study of local universe ETGs, together with the expected evolutionmore » of the X-ray emission, to subtract the contribution of low-mass X-ray binary populations from the X-ray luminosity of our sample. Our selection minimizes the presence of active galactic nuclei (AGNs), yielding a sample representative of normal passive COSMOS ETGs; therefore, the resulting luminosity should be representative of gaseous halos, although we cannot exclude other sources such as obscured AGNs or enhanced X-ray emission connected with embedded star formation in the higher-z galaxies. We find that most of the galaxies with estimated L{sub X} < 10{sup 42} erg s{sup –1} and z < 0.55 follow the L{sub X,{sub gas}}-L{sub K} relation of local universe ETGs. For these galaxies, the gravitational mass can be estimated with a certain degree of confidence from the local virial relation. However, the more luminous (10{sup 42} erg s{sup –1}« less

Host Galaxy Properties Of The Swift Bat Hard X-ray Survey Of Agn

NASA Astrophysics Data System (ADS)

Koss, Michael; Mushotzky, R.; Veilleux, S.; Winter, L.

2010-03-01

Surveys of AGN taken in the optical, UV, and soft X-rays miss an important population of obscured AGN only visible in the hard X-rays and mid-IR wavelengths. The SWIFT BAT survey in the hard X-ray range (14-195 keV) has provided a uniquely unbiased sample of AGN unaffected by galactic or circumnuclear absorption. Optical imaging of this unbiased sample provides a new opportunity to understand how the environments of the host galaxies are linked to AGN. In 2008, we observed 90 of these targets at Kitt Peak with the 2.1m in the SDSS ugriz bands over 17 nights. Using these observations and SDSS data we review the relationships between color, morphology, merger activity, stellar mass, star formation, and AGN luminosity for a sample of 145 AGN Hard X-ray Selected AGN.

A computer controlled television detector for light, X-rays and particles

NASA Technical Reports Server (NTRS)

Kalata, K.

1981-01-01

A versatile, high resolution, software configurable, two-dimensional intensified vidicon quantum detector system has been developed for multiple research applications. A thin phosphor convertor allows the detection of X-rays below 20 keV and non-relativistic particles in addition to visible light, and a thicker scintillator can be used to detect X-rays up to 100 keV and relativistic particles. Faceplates may be changed to allow any active area from 1 to 40 mm square, and active areas up to 200 mm square are possible. The image is integrated in a digital memory on any software specified array size up to 4000 x 4000. The array size is selected to match the spatial resolution, which ranges from 10 to 100 microns depending on the operating mode, the active area, and the photon or particle energy. All scan and data acquisition parameters are under software control to allow optimal data collection for each application.

The Cosmic History of Hot Gas Cooling and Radio AGN Activity in Massive Early-Type Galaxies

NASA Technical Reports Server (NTRS)

Danielson, A. L. R.; Lehmer, B. D.; Alexander, D. M.; Brandt, W. M.; Luo, B.; Miller, N.; Xue, Y. Q.; Stott, J. P.

2012-01-01

We study the X-ray properties of 393 optically selected early-type galaxies (ETGs) over the redshift range of z approx equals 0.0-1.2 in the Chandra Deep Fields. To measure the average X-ray properties of the ETG population, we use X-ray stacking analyses with a subset of 158 passive ETGs (148 of which were individually undetected in X-ray). This ETG subset was constructed to span the redshift ranges of z = 0.1-1.2 in the approx equals 4 Ms CDF-S and approx equals 2 Ms CDF-N and z = 0.1-0.6 in the approx equals 250 ks E-CDF-S where the contribution from individually undetected AGNs is expected to be negligible in our stacking. We find that 55 of the ETGs are detected individually in the X-rays, and 12 of these galaxies have properties consistent with being passive hot-gas dominated systems (i.e., systems not dominated by an X-ray bright Active Galactic Nucleus; AGN). On the basis of our analyses, we find little evolution in the mean 0.5-2 keY to B-band luminosity ratio (L(sub x) /L(sub Beta) varies as [1 +z]) since z approx equals 1.2, implying that some heating mechanism prevents the gas from cooling in these systems. We consider that feedback from radio-mode AGN activity could be responsible for heating the gas. We select radio AGNs in the ETG population using their far-infrared/radio flux ratio. Our radio observations allow us to constrain the duty cycle history of radio AGN activity in our ETG sample. We estimate that if scaling relations between radio and mechanical power hold out to z approx equals 1.2 for the ETG population being studied here, the average mechanical power from AGN activity is a factor of approx equals1.4 -- 2.6 times larger than the average radiative cooling power from hot gas over the redshift range z approx equals 0-1.2. The excess of inferred AGN mechanical power from these ETGs is consistent with that found in the local Universe for similar types of galaxies.

Narrow-line Seyfert 1 galaxies at hard X-rays

NASA Astrophysics Data System (ADS)

Panessa, F.; de Rosa, A.; Bassani, L.; Bazzano, A.; Bird, A.; Landi, R.; Malizia, A.; Miniutti, G.; Molina, M.; Ubertini, P.

2011-11-01

Narrow-line Seyfert 1 (NLSy1) galaxies are a peculiar class of type 1 active galactic nuclei (broad-line Seyfert 1 galaxies, hereinafter BLSy1). The X-ray properties of individual objects belonging to this class are often extreme and associated with accretion at high Eddington ratios. Here, we present a study on a sample of 14 NLSy1 galaxies selected at hard X-rays (>20 keV) from the fourth INTEGRAL/IBIS catalogue. The 20-100 keV IBIS spectra show hard-X-ray photon indices flatly distributed (Γ20-100 keV ranging from ˜1.3 to ˜3.6) with an average value of <Γ20-100 keV>= 2.3 ± 0.7, compatible with a sample of hard-X-ray BLSy1 average slopes. Instead, NLSy1 galaxies show steeper spectral indices with respect to BLSy1 galaxies when broad-band spectra are considered. Indeed, we combine XMM-Newton and Swift/XRT with INTEGRAL/IBIS data sets to obtain a wide energy spectral coverage (0.3-100 keV). A constraint on the high energy cut-off and on the reflection component is achieved only in one source, SWIFT J2127.4+5654 (Ecut-off˜ 50 keV, R= 1.0+0.5- 0.4). Hard-X-ray-selected NLSy1 galaxies do not display particularly strong soft excess emission, while absorption fully or partially covering the continuum is often measured as well as Fe line emission features. Variability is a common trait in this sample, both at X-rays and at hard X-rays. The fraction of NLSy1 galaxies in the hard-X-ray sky is likely to be ˜15 per cent, in agreement with estimates derived in optically selected NLSy1 samples. We confirm the association of NLSy1 galaxies with small black hole masses with a peak at 107 M⊙ in the distribution; however, hard-X-ray NLSy1 galaxies seem to occupy the lower tail of the Eddington ratio distribution of classical NLSy1 galaxies. Based on observations obtained with the INTEGRAL/IBIS, XMM-Newton and Swift/XRT.

Search for X-ray Emission from AGB Stars in the Coronal Graveyard

NASA Astrophysics Data System (ADS)

Montez, Rodolfo

2013-10-01

Maser observations demonstrate the existence of magnetic fields in the circumstellar envelopes of AGB stars. However, thus far, only 2-3 AGB stars have exhibited evidence for coronal X-ray emission. We have demonstrated that only the sensitivity of modern X-ray telescopes can detect magnetically-induced coronal emission and have identified a sample of AGB stars which are ideal candidates to search for such emission. Specifically, we have selected a sample of AGB stars with SiO maser emission, UV emission in at least one of the GALEX bandpasses, and low mass loss rates. The four selected AGB stars provide a pilot sample that optimally probes for coronal activity beyond the giant phase and that provides valuable tests for the launching and shaping of AGB mass loss.

Amuse-Virgo: Downsizing In Black Hole Accretion

NASA Astrophysics Data System (ADS)

Gallo, Elena

2010-03-01

An issue of fundamental importance in understanding the galaxy-black hole connection is the duty cycle of accretion. If black holes are indeed ubiquitous in galactic nuclei, little is known about the frequency and intensity of their activity, the more so at the low-mass/low-luminosity end. I will present new results from AMUSE-Virgo, a Chandra survey of (formally) inactive early type galaxies in the Virgo cluster. Out of 100 objects, 32 show a nuclear X-ray source, including 6 hybrid nuclei which also host a massive nuclear cluster as visible from archival HST images. After carefully accounting for contamination from nuclear low mass X-ray binaries based on the shape and normalization of their X-ray luminosity function, we conclude that between 24-34% of the galaxies in our sample host a X-ray active super-massive black hole. This sets a firm lower limit to the black hole occupation fraction in nearby bulges within a cluster environment. At face value, the active fraction is found to increase with host stellar mass. However, taking into account selection effects, we find that the average Eddington-scaled X-ray luminosity scales with black hole mass to the power -0.62, with an intrinsic scatter of 0.46 dex. This represents the first observational evidence for down-sizing of black hole accretion in local early types, that is, the fraction of active galaxies, defined as those above a fixed X-ray Eddington ratio, decreases with increasing host galaxy mass.

Testing for X-Ray–SZ Differences and Redshift Evolution in the X-Ray Morphology of Galaxy Clusters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nurgaliev, D.; McDonald, M.; Benson, B. A.

We present a quantitative study of the X-ray morphology of galaxy clusters, as a function of their detection method and redshift. We analyze two separate samples of galaxy clusters: a sample of 36 clusters atmore » $$0.35\\lt z\\lt 0.9$$ selected in the X-ray with the ROSAT PSPC 400 deg(2) survey, and a sample of 90 clusters at $$0.25\\lt z\\lt 1.2$$ selected via the Sunyaev–Zel’dovich (SZ) effect with the South Pole Telescope. Clusters from both samples have similar-quality Chandra observations, which allow us to quantify their X-ray morphologies via two distinct methods: centroid shifts (w) and photon asymmetry ($${A}_{\\mathrm{phot}}$$). The latter technique provides nearly unbiased morphology estimates for clusters spanning a broad range of redshift and data quality. We further compare the X-ray morphologies of X-ray- and SZ-selected clusters with those of simulated clusters. We do not find a statistically significant difference in the measured X-ray morphology of X-ray and SZ-selected clusters over the redshift range probed by these samples, suggesting that the two are probing similar populations of clusters. We find that the X-ray morphologies of simulated clusters are statistically indistinguishable from those of X-ray- or SZ-selected clusters, implying that the most important physics for dictating the large-scale gas morphology (outside of the core) is well-approximated in these simulations. Finally, we find no statistically significant redshift evolution in the X-ray morphology (both for observed and simulated clusters), over the range of $$z\\sim 0.3$$ to $$z\\sim 1$$, seemingly in contradiction with the redshift-dependent halo merger rate predicted by simulations.« less

Testing for X-Ray–SZ Differences and Redshift Evolution in the X-Ray Morphology of Galaxy Clusters

DOE PAGES

Nurgaliev, D.; McDonald, M.; Benson, B. A.; ...

2017-05-16

We present a quantitative study of the X-ray morphology of galaxy clusters, as a function of their detection method and redshift. We analyze two separate samples of galaxy clusters: a sample of 36 clusters atmore » $$0.35\\lt z\\lt 0.9$$ selected in the X-ray with the ROSAT PSPC 400 deg(2) survey, and a sample of 90 clusters at $$0.25\\lt z\\lt 1.2$$ selected via the Sunyaev–Zel’dovich (SZ) effect with the South Pole Telescope. Clusters from both samples have similar-quality Chandra observations, which allow us to quantify their X-ray morphologies via two distinct methods: centroid shifts (w) and photon asymmetry ($${A}_{\\mathrm{phot}}$$). The latter technique provides nearly unbiased morphology estimates for clusters spanning a broad range of redshift and data quality. We further compare the X-ray morphologies of X-ray- and SZ-selected clusters with those of simulated clusters. We do not find a statistically significant difference in the measured X-ray morphology of X-ray and SZ-selected clusters over the redshift range probed by these samples, suggesting that the two are probing similar populations of clusters. We find that the X-ray morphologies of simulated clusters are statistically indistinguishable from those of X-ray- or SZ-selected clusters, implying that the most important physics for dictating the large-scale gas morphology (outside of the core) is well-approximated in these simulations. Finally, we find no statistically significant redshift evolution in the X-ray morphology (both for observed and simulated clusters), over the range of $$z\\sim 0.3$$ to $$z\\sim 1$$, seemingly in contradiction with the redshift-dependent halo merger rate predicted by simulations.« less

BAT AGN Spectroscopic Survey. VIII. Type 1 AGN with Massive Absorbing Columns

NASA Astrophysics Data System (ADS)

Shimizu, T. Taro; Davies, Richard I.; Koss, Michael; Ricci, Claudio; Lamperti, Isabella; Oh, Kyuseok; Schawinski, Kevin; Trakhtenbrot, Benny; Burtscher, Leonard; Genzel, Reinhard; Lin, Ming-yi; Lutz, Dieter; Rosario, David; Sturm, Eckhard; Tacconi, Linda

2018-04-01

We explore the relationship between X-ray absorption and optical obscuration within the BAT AGN Spectroscopic Survey (BASS), which has been collecting and analyzing the optical and X-ray spectra for 641 hard X-ray selected (E > 14 keV) active galactic nuclei (AGNs). We use the deviation from a linear broad Hα-to-X-ray relationship as an estimate of the maximum optical obscuration toward the broad line region (BLR) and compare the A V to the hydrogen column densities ({N}{{H}}) found through systematic modeling of their X-ray spectra. We find that the inferred columns implied by A V toward the BLR are often orders of magnitude less than the columns measured toward the X-ray emitting region, indicating a small-scale origin for the X-ray absorbing gas. After removing 30% of Sy 1.9s that potentially have been misclassified due to outflows, we find that 86% (164/190) of the Type 1 population (Sy 1–1.9) are X-ray unabsorbed as expected based on a single obscuring structure. However, 14% (26/190), of which 70% (18/26) are classified as Sy 1.9, are X-ray absorbed, suggesting that the BLR itself is providing extra obscuration toward the X-ray corona. The fraction of X-ray absorbed Type 1 AGNs remains relatively constant with AGN luminosity and Eddington ratio, indicating a stable BLR covering fraction.

Luminosity function and cosmological evolution of X-ray selected quasars

NASA Technical Reports Server (NTRS)

Maccacaro, T.; Gioia, I. M.

1983-01-01

The preliminary analysis of a complete sample of 55 X-ray sources is presented as part of the Medium Sensitivity Survey of the Einstein Observatory. A pure luminosity evolutionary law is derived in order to determine the uniform distribution of the sources and the rates of evolution for Active Galactic Nuclei (AGNs) observed by X-ray and optical techniques are compared. A nonparametric representation of the luminosity function is fitted to the observational data. On the basis of the reduced data, it is determined that: (1) AGNs evolve cosmologically; (2) less evolution is required to explain the X-ray data than the optical data; (3) the high-luminosity portion of the X-ray luminosity can be described by a power-law with a slope of gamma = 3.6; and (4) the X-ray luminosity function flattens at low luminosities. Some of the implications of the results for conventional theoretical models of the evolution of quasars and Seyfert galaxies are discussed.

X-ray crystallography

NASA Technical Reports Server (NTRS)

2001-01-01

X-rays diffracted from a well-ordered protein crystal create sharp patterns of scattered light on film. A computer can use these patterns to generate a model of a protein molecule. To analyze the selected crystal, an X-ray crystallographer shines X-rays through the crystal. Unlike a single dental X-ray, which produces a shadow image of a tooth, these X-rays have to be taken many times from different angles to produce a pattern from the scattered light, a map of the intensity of the X-rays after they diffract through the crystal. The X-rays bounce off the electron clouds that form the outer structure of each atom. A flawed crystal will yield a blurry pattern; a well-ordered protein crystal yields a series of sharp diffraction patterns. From these patterns, researchers build an electron density map. With powerful computers and a lot of calculations, scientists can use the electron density patterns to determine the structure of the protein and make a computer-generated model of the structure. The models let researchers improve their understanding of how the protein functions. They also allow scientists to look for receptor sites and active areas that control a protein's function and role in the progress of diseases. From there, pharmaceutical researchers can design molecules that fit the active site, much like a key and lock, so that the protein is locked without affecting the rest of the body. This is called structure-based drug design.

THE GLOBAL IMPLICATIONS OF THE HARD EXCESS. II. ANALYSIS OF THE LOCAL POPULATION OF RADIO-QUIET AGNs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tatum, M. M.; Turner, T. J.; Reeves, J. N.

2016-02-10

Active galactic nuclei (AGNs) show evidence for reprocessing gas, outflowing from the accreting black hole. The combined effects of absorption and scattering from the circumnuclear material likely explain the “hard excess” of X-ray emission above 20 keV, compared with the extrapolation of spectra from lower X-ray energies. In a recent Suzaku study, we established that the ubiquitous hard excess in hard, X-ray-selected, radio-quiet type 1 AGNs is consistent with a reprocessing of the X-ray continuum in an ensemble of clouds, located tens to hundreds of gravitational radii from the nuclear black hole. Here we add hard X-ray-selected, type 2 AGNsmore » to extend our original study and show that the gross X-ray spectral properties of the entire local population of radio-quiet AGNs may be described by a simple unified scheme. We find a broad, continuous distribution of spectral hardness ratio and Fe Kα equivalent width across all AGN types, which can be reproduced by varying the observer's sightline through a single, simple model cloud ensemble, provided that the radiative transfer through the model cloud distribution includes not only photoelectric absorption but also three-dimensional (3D) Compton scattering. Variation in other parameters of the cloud distribution, such as column density or ionization, should be expected between AGNs, but such variation is not required to explain the gross X-ray spectral properties.« less

Microgravity

NASA Image and Video Library

2001-06-06

X-rays diffracted from a well-ordered protein crystal create sharp patterns of scattered light on film. A computer can use these patterns to generate a model of a protein molecule. To analyze the selected crystal, an X-ray crystallographer shines X-rays through the crystal. Unlike a single dental X-ray, which produces a shadow image of a tooth, these X-rays have to be taken many times from different angles to produce a pattern from the scattered light, a map of the intensity of the X-rays after they diffract through the crystal. The X-rays bounce off the electron clouds that form the outer structure of each atom. A flawed crystal will yield a blurry pattern; a well-ordered protein crystal yields a series of sharp diffraction patterns. From these patterns, researchers build an electron density map. With powerful computers and a lot of calculations, scientists can use the electron density patterns to determine the structure of the protein and make a computer-generated model of the structure. The models let researchers improve their understanding of how the protein functions. They also allow scientists to look for receptor sites and active areas that control a protein's function and role in the progress of diseases. From there, pharmaceutical researchers can design molecules that fit the active site, much like a key and lock, so that the protein is locked without affecting the rest of the body. This is called structure-based drug design.

Time-resolved soft-x-ray studies of energy transport in layered and planar laser-driven targets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stradling, G.L.

New low-energy x-ray diagnostic techniques are used to explore energy-transport processes in laser heated plasmas. Streak cameras are used to provide 15-psec time-resolution measurements of subkeV x-ray emission. A very thin (50 ..mu..g/cm/sup 2/) carbon substrate provides a low-energy x-ray transparent window to the transmission photocathode of this soft x-ray streak camera. Active differential vacuum pumping of the instrument is required. The use of high-sensitivity, low secondary-electron energy-spread CsI photocathodes in x-ray streak cameras is also described. Significant increases in sensitivity with only a small and intermittant decrease in dynamic range were observed. These coherent, complementary advances in subkeV, time-resolvedmore » x-ray diagnostic capability are applied to energy-transport investigations of 1.06-..mu..m laser plasmas. Both solid disk targets of a variety of Z's as well as Be-on-Al layered-disk targets were irradiated with 700-psec laser pulses of selected intensity between 3 x 10/sup 14/ W/cm/sup 2/ and 1 x 10/sup 15/ W/cm/sup 2/.« less

HOST GALAXY PROPERTIES OF THE SWIFT BAT ULTRA HARD X-RAY SELECTED ACTIVE GALACTIC NUCLEUS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koss, Michael; Mushotzky, Richard; Veilleux, Sylvain

We have assembled the largest sample of ultra hard X-ray selected (14-195 keV) active galactic nucleus (AGN) with host galaxy optical data to date, with 185 nearby (z < 0.05), moderate luminosity AGNs from the Swift BAT sample. The BAT AGN host galaxies have intermediate optical colors (u - r and g - r) that are bluer than a comparison sample of inactive galaxies and optically selected AGNs from the Sloan Digital Sky Survey (SDSS) which are chosen to have the same stellar mass. Based on morphological classifications from the RC3 and the Galaxy Zoo, the bluer colors of BATmore » AGNs are mainly due to a higher fraction of mergers and massive spirals than in the comparison samples. BAT AGNs in massive galaxies (log M{sub *} >10.5) have a 5-10 times higher rate of spiral morphologies than in SDSS AGNs or inactive galaxies. We also see enhanced far-infrared emission in BAT AGN suggestive of higher levels of star formation compared to the comparison samples. BAT AGNs are preferentially found in the most massive host galaxies with high concentration indexes indicative of large bulge-to-disk ratios and large supermassive black holes. The narrow-line (NL) BAT AGNs have similar intrinsic luminosities as the SDSS NL Seyferts based on measurements of [O III] {lambda}5007. There is also a correlation between the stellar mass and X-ray emission. The BAT AGNs in mergers have bluer colors and greater ultra hard X-ray emission compared to the BAT sample as a whole. In agreement with the unified model of AGNs, and the relatively unbiased nature of the BAT sources, the host galaxy colors and morphologies are independent of measures of obscuration such as X-ray column density or Seyfert type. The high fraction of massive spiral galaxies and galaxy mergers in BAT AGNs suggest that host galaxy morphology is related to the activation and fueling of local AGN.« less

Skylab

NASA Image and Video Library

1973-01-01

This chart describes the Skylab student experiment X-Rays from Jupiter, proposed by Jearne Leventhal of Berkeley, California. This experiment was an investigation to detect x-rays from the planet Jupiter and determine any correlation with solar flare activity. In March 1972, NASA and the National Science Teachers Association selected 25 experiment proposals for flight on Skylab. Science advisors from the Marshall Space Flight Center aided and assisted the students in developing the proposals for flight on Skylab.

Discovery of a dual active galactic nucleus with ˜8 kpc separation

NASA Astrophysics Data System (ADS)

Ellison, Sara L.; Secrest, Nathan J.; Mendel, J. Trevor; Satyapal, Shobita; Simard, Luc

2017-09-01

Targeted searches for dual active galactic nuclei (AGNs), with separations 1-10 kpc, have yielded relatively few successes. A recent pilot survey by Satyapal et al. has demonstrated that mid-infrared (mid-IR) pre-selection has the potential to significantly improve the success rate for dual AGN confirmation in late stage galaxy mergers. In this Letter, we combine mid-IR selection with spatially resolved optical AGN diagnostics from the Mapping Nearby Galaxies at Apache Point Observatory survey to identify a candidate dual AGN in the late stage major galaxy merger SDSS J140737.17+442856.2 at z = 0.143. The nature of the dual AGN is confirmed with Chandra X-ray observations that identify two hard X-ray point sources with intrinsic (corrected for absorption) 2-10 keV luminosities of 4 × 1041 and 3.5 × 1043 erg s-1 separated by 8.3 kpc. The neutral hydrogen absorption (˜1022 cm-2) towards the two AGNs is lower than in duals selected solely on their mid-IR colours, indicating that strategies that combine optical and mid-IR diagnostics may complement techniques that identify the highly obscured dual phase, such as at high X-ray energies or mid-IR only.

Host Galaxy Properties of SWIFT Hard X-ray Selected AGN

NASA Astrophysics Data System (ADS)

Koss, Michael; Mushotzky, R.; Veilleux, S.; Winter, L.

2010-01-01

Surveys of AGN taken in the optical, UV, and soft X-rays miss an important population of obscured AGN only visible in the hard X-rays and mid-IR wavelengths. The SWIFT BAT survey in the hard X-ray range (14-195 keV) has provided a uniquely unbiased sample of 258 AGN unaffected by galactic or circumnuclear absorption. Optical imaging of this unbiased sample provides a new opportunity to understand how the environments of the host galaxies are linked to AGN. In 2008, we observed 110 of these targets at Kitt Peak with the 2.1m in the SDSS ugriz bands over 17 nights. Using these observations and SDSS data we review the relationships between color, morphology, merger activity, star formation, and AGN luminosity.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shin, Jaejin; Woo, Jong-Hak; Mulchaey, John S.

We perform a comprehensive study of X-ray cavities using a large sample of X-ray targets selected from the Chandra archive. The sample is selected to cover a large dynamic range including galaxy clusters, groups, and individual galaxies. Using β -modeling and unsharp masking techniques, we investigate the presence of X-ray cavities for 133 targets that have sufficient X-ray photons for analysis. We detect 148 X-ray cavities from 69 targets and measure their properties, including cavity size, angle, and distance from the center of the diffuse X-ray gas. We confirm the strong correlation between cavity size and distance from the X-raymore » center similar to previous studies. We find that the detection rates of X-ray cavities are similar among galaxy clusters, groups and individual galaxies, suggesting that the formation mechanism of X-ray cavities is independent of environment.« less

X-ray data booklet. Revision

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vaughan, D.

A compilation of data is presented. Included are properties of the elements, electron binding energies, characteristic x-ray energies, fluorescence yields for K and L shells, Auger energies, energy levels for hydrogen-, helium-, and neonlike ions, scattering factors and mass absorption coefficients, and transmission bands of selected filters. Also included are selected reprints on scattering processes, x-ray sources, optics, x-ray detectors, and synchrotron radiation facilities. (WRF)

Synthesis and x-ray characterization of cobalt phosphide (Co₂P) nanorods for the oxygen reduction reaction

DOE PAGES

Doan-Nguyen, Vicky V.T.; Su, Dong; Zhang, Sen; ...

2015-07-14

Low temperature fuel cells are clean, effective alternative fuel conversion technology. Oxygen reduction reaction (ORR) at the fuel cell cathode has required Pt as the electrocatalyst for high activity and selectivity of the four-electron reaction pathway. Targeting a less expensive, earth abundant alternative, we have developed the synthesis of cobalt phosphide (Co₂P) nanorods for ORR. Characterization techniques that include total X-ray scattering and extended X-ray absorption fine structure revealed a deviation of the nanorods from bulk crystal structure with a contraction along the b orthorhombic lattice parameter. The carbon supported nanorods have comparable activity but are remarkably more stable thanmore » conventional Pt catalysts for the oxygen reduction reaction in alkaline environments.« less

Hydrogen line ratios in Seyfert galaxies and low redshift quasars

NASA Technical Reports Server (NTRS)

Kriss, G. R.

1984-01-01

New observations of the Lymal alpha radiation/hydrogen alpha radiation ratio in a set of X-ray selected active galactic nuclei and an archival study of International Ultraviolet Explorer (IUE) observations of Lymal alpha low redshift quasars and Seyfert galaxies have been used to form a large sample for studying the influence of soft X-rays on the enhancement of Balmer emission in the broad line region. In common models of broad line clouds, the Balmer lines are formed deep in the interior, largely by collisional excitation. Heating within the clouds is provided by soft X-ray radiation, while Lymal alpha is formed mainly by recombination after photoionization. The ratio Lymal alpha/Halpha is expected to depend weakly on the ratio of ionizing ultraviolet luminosity to X-ray luminosity (L sub UV/l sub x). If the Lymal alpha luminosity is used as a measure of L sub UV' a weak dependence of Lymal/H alpha on the X-ray luminosity is found similar to previous results.

"A Richness Study of 14 Distant X-Ray Clusters from the 160 Square Degree Survey"

NASA Technical Reports Server (NTRS)

Jones, Christine; West, Donald (Technical Monitor)

2001-01-01

We have measured the surface density of galaxies toward 14 X-ray-selected cluster candidates at redshifts z(sub i) 0.46, and we show that they are associated with rich galaxy concentrations. These clusters, having X-ray luminosities of Lx(0.5-2 keV) approx. (0.5 - 2.6) x 10(exp 44) ergs/ sec are among the most distant and luminous in our 160 deg(exp 2) ROSAT Position Sensitive Proportional Counter cluster survey. We find that the clusters range between Abell richness classes 0 and 2 and have a most probable richness class of 1. We compare the richness distribution of our distant clusters to those for three samples of nearby clusters with similar X-ray luminosities. We find that the nearby and distant samples have similar richness distributions, which shows that clusters have apparently not evolved substantially in richness since redshift z=0.5. There is, however, a marginal tendency for the distant clusters to be slightly poorer than nearby clusters, although deeper multicolor data for a large sample would be required to confirm this trend. We compare the distribution of distant X-ray clusters in the L(sub X)-richness plane to the distribution of optically selected clusters from the Palomar Distant Cluster Survey. The optically selected clusters appear overly rich for their X-ray luminosities, when compared to X-ray-selected clusters. Apparently, X-ray and optical surveys do not necessarily sample identical mass concentrations at large redshifts. This may indicate the existence of a population of optically rich clusters with anomalously low X-ray emission, More likely, however, it reflects the tendency for optical surveys to select unvirialized mass concentrations, as might be expected when peering along large-scale filaments.

The selection criteria elements of X-ray optics system

NASA Astrophysics Data System (ADS)

Plotnikova, I. V.; Chicherina, N. V.; Bays, S. S.; Bildanov, R. G.; Stary, O.

2018-01-01

At the design of new modifications of x-ray tomography there are difficulties in the right choice of elements of X-ray optical system. Now this problem is solved by practical consideration, selection of values of the corresponding parameters - tension on an x-ray tube taking into account the thickness and type of the studied material. For reduction of time and labor input of design it is necessary to create the criteria of the choice, to determine key parameters and characteristics of elements. In the article two main elements of X-ray optical system - an x-ray tube and the detector of x-ray radiation - are considered. Criteria of the choice of elements, their key characteristics, the main dependences of parameters, quality indicators and also recommendations according to the choice of elements of x-ray systems are received.

A pulse shape discriminator and an online system for the balloon-borne hard X-ray/gamma-ray detector

NASA Astrophysics Data System (ADS)

Takahashi, T.; Kamae, T.; Tanaka, M.; Gunji, S.; Miyazuki, S.; Tamura, T.; Sekimoto, Y.; Yamaoka, N.; Nishimura, J.; Yajima, N.

Attention is given to a new kind of phoswich counters (the well-type phoswich counter) that will be capable of detecting very low flux hard X-rays/gamma-rays (40-1000 keV) from astronomical objects. A specially designed pulse-shape discriminator (PSD) selects hard X-rays/gamma-rays that has deposited energy only in the detection part. Sixty-four such counters are assembled into an array where each phoswich element acts as an active shield to the neighboring elements too. The ADCs, the TDCs, the hit-pattern latches, and the precision clock are read out by a VME-based online system, stored on an 8-mm video tape, and transmitted to the ground station. The design and performance of the pulse shape discriminator and the online system are described.

Soft X-ray observations of pre-main sequence stars in the chamaeleon dark cloud

NASA Technical Reports Server (NTRS)

Feigelson, Eric D.; Kriss, Gerard A.

1987-01-01

Einstein IPC observations of the nearby Chamaeleon I star forming cloud show 22 well-resolved soft X-ray sources in a 1x2 deg region. Twelve are associated with H-alpha emission line pre-main sequence (PMS) stars, and four with optically selected PMS stars. Several X-ray sources have two or more PMS stars in their error circles. Optical spectra were obtained at CTIO of possible stellar counterparts of the remaining X-ray sources. They reveal 5 probable new cloud members, K7-MO stars with weak or absent emission lines. These naked X-ray selected PMS stars are similar to those found in the Taurus-Auriga cloud. The spatial distributions and H-R diagrams of the X-ray and optically selected PMS stars in the cloud are very similar. Luminosity functions indicate the Chamaeleon stars are on average approximately 5 times more X-ray luminous than Pleiad dwarfs. A significant correlation between L sub x and optical magnitude suggests this trend may continue within the PMS phase of stellar evolution. The relation of increasing X-ray luminosity with decreasing stellar ages is thus extended to stellar ages as young as 1 million years.

The column density distribution of hard X-ray radio galaxies

NASA Astrophysics Data System (ADS)

Panessa, F.; Bassani, L.; Landi, R.; Bazzano, A.; Dallacasa, D.; La Franca, F.; Malizia, A.; Venturi, T.; Ubertini, P.

2016-09-01

In order to investigate the role of absorption in active galactic nuclei (AGN) with jets, we have studied the column density distribution of a hard X-ray selected sample of radio galaxies, derived from the INTEGRAL/Imager on Board the Integral Satellite (IBIS) and Swift/The Burst Alert Telescope (BAT) AGN catalogues (˜7-10 per cent of the total AGN population). The 64 radio galaxies have a typical FR II radio morphology and are characterized by high 20-100 keV luminosities (from 1042 to 1046 erg s-1) and high Eddington ratios (log LBol/LEdd typically larger than ˜0.01). The observed fraction of absorbed AGN (NH > 1022 cm-2) is around 40 per cent among the total sample, and ˜75 per cent among type 2 AGN. The majority of obscured AGN are narrow-line objects, while unobscured AGN are broad-line objects, obeying to the zeroth-order predictions of unified models. A significant anti-correlation between the radio core dominance parameter and the X-ray column density is found. The observed fraction of Compton thick AGN is ˜2-3 per cent, in comparison with the 5-7 per cent found in radio-quiet hard X-ray selected AGN. We have estimated the absorption and Compton thick fractions in a hard X-ray sample containing both radio galaxies and non-radio galaxies and therefore affected by the same selection biases. No statistical significant difference was found in the absorption properties of radio galaxies and non-radio galaxies sample. In particular, the Compton thick objects are likely missing in both samples and the fraction of obscured radio galaxies appears to decrease with luminosity as observed in hard X-ray non-radio galaxies.

Accretion Properties of a Sample of Hard X-Ray (<60 keV) Selected Seyfert 1 Galaxies

NASA Astrophysics Data System (ADS)

Wang, J.; Mao, Y. F.; Wei, J. Y.

2009-02-01

We examine the accretion properties in a sample of 42 hard (3-60 keV) X-ray selected nearby broad-line active galactic nuclei (AGNs). The energy range in the sample is harder than that usually used in similar previous studies. These AGNs are mainly complied from the RXTE All Sky Survey, and complemented by the released INTEGRAL AGN catalog. The black hole masses, bolometric luminosities of AGN, and Eddington ratios are derived from their optical spectra in terms of the broad Hβ emission line. The tight correlation between the hard X-ray (3-20 keV) and bolometric/line luminosity is well identified in our sample. Also identified is a strong inverse Baldwin relationship of the Hβ emission line. In addition, all of these hard X-ray AGNs are biased toward luminous objects with a high Eddington ratio (mostly between 0.01 and 0.1) and a low column density (<1022 cm-2), which is most likely due to the selection effect of the surveys. The hard X-ray luminosity is consequently found to be strongly correlated with the black hole mass. We believe the sample completeness will be improved in the next few years by the ongoing Swift and the International Gamma-Ray Astrophysics Laboratory missions, and by the next advanced missions, such as NuSTAR, Simbol-X, and NeXT. Finally, the correlation between RFe (= optical Fe II/Hβ) and disk temperature as assessed by T vprop (L/L Edd)M -1 BH leads us to suggest that the strength of the Fe II emission is mainly determined by the shape of the ionizing spectrum.

Variability-selected active galactic nuclei from supernova search in the Chandra deep field south

NASA Astrophysics Data System (ADS)

Trevese, D.; Boutsia, K.; Vagnetti, F.; Cappellaro, E.; Puccetti, S.

2008-09-01

Context: Variability is a property shared by virtually all active galactic nuclei (AGNs), and was adopted as a criterion for their selection using data from multi epoch surveys. Low Luminosity AGNs (LLAGNs) are contaminated by the light of their host galaxies, and cannot therefore be detected by the usual colour techniques. For this reason, their evolution in cosmic time is poorly known. Consistency with the evolution derived from X-ray detected samples has not been clearly established so far, also because the low luminosity population consists of a mixture of different object types. LLAGNs can be detected by the nuclear optical variability of extended objects. Aims: Several variability surveys have been, or are being, conducted for the detection of supernovae (SNe). We propose to re-analyse these SNe data using a variability criterion optimised for AGN detection, to select a new AGN sample and study its properties. Methods: We analysed images acquired with the wide field imager at the 2.2 m ESO/MPI telescope, in the framework of the STRESS supernova survey. We selected the AXAF field centred on the Chandra Deep Field South where, besides the deep X-ray survey, various optical data exist, originating in the EIS and COMBO-17 photometric surveys and the spectroscopic database of GOODS. Results: We obtained a catalogue of 132 variable AGN candidates. Several of the candidates are X-ray sources. We compare our results with an HST variability study of X-ray and IR detected AGNs, finding consistent results. The relatively high fraction of confirmed AGNs in our sample (60%) allowed us to extract a list of reliable AGN candidates for spectroscopic follow-up observations. Table [see full text] is only available in electronic form at http://www.aanda.org

Testing the Pairs-Reflection Model with X-Ray Spectral Variability and X-Ray Properties of Complete Samples of Radio-Selected BL Lacertae Objects

NASA Astrophysics Data System (ADS)

Urry, C. Megan

1997-01-01

This grant was awarded to Dr. C. Megan Urry of the Space Telescope Science Institute in response to two successful ADP proposals to use archival Ginga and Rosat X-ray data for 'Testing the Pairs-Reflection model with X-Ray Spectral Variability' (in collaboration with Paola Grandi, now at the University of Rome) and 'X-Ray Properties of Complete Samples of Radio-Selected BL Lacertae Objects' (in collaboration with then-graduate student Rita Sambruna, now a post-doc at Goddard Space Flight Center). In addition, post-docs Joseph Pesce and Elena Pian, and graduate student Matthew O'Dowd, have worked on several aspects of these projects. The grant was originally awarded on 3/01/94; this report covers the full period, through May 1997. We have completed our project on the X-ray properties of radio-selected BL Lacs.

The Imaging X-Ray Polarimetry Explorer (IXPE): Overview

NASA Technical Reports Server (NTRS)

O'Dell, Steve; Weisskopf, M.; Soffitta, P.; Baldini, L.; Bellazzini, R.; Costa, E.; Elsner, R.; Kaspi, V.; Kolodziejczak, J.; Latronico, L.;

X-ray bright points and He I lambda 10830 dark points

NASA Technical Reports Server (NTRS)

Golub, L.; Harvey, K. L.; Herant, M.; Webb, D. F.

1989-01-01

Using near-simultaneous full disk Solar X-ray images and He I 10830 lambda, spectroheliograms from three recent rocket flights, dark points identified on the He I maps were compared with X-ray bright points identified on the X-ray images. It was found that for the largest and most obvious features there is a strong correlation: most He I dark points correspond to X-ray bright points. However, about 2/3 of the X-ray bright points were not identified on the basis of the helium data alone. Once an X-ray feature is identified it is almost always possible to find an underlying dark patch of enhanced He I absorption which, however, would not a priori have been selected as a dark point. Therefore, the He I dark points, using current selection criteria, cannot be used as a one-to-one proxy for the X-ray data. He I dark points do, however, identify the locations of the stronger X-ray bright points.

X-ray bright points and He I lambda 10830 dark points

NASA Technical Reports Server (NTRS)

Golub, L.; Harvey, K. L.; Herant, M.; Webb, D. F.

1989-01-01

Using near-simultaneous full disk Solar X-ray images and He I 10830 lambda, spectroheliograms from three recent rocket flights, dark points identified on the He I maps were compared with x-ray bright points identified on the X-ray images. It was found that for the largest and most obvious features there is a strong correlation: most He I dark points correspond to X-ray bright points. However, about 2/3 of the X-ray bright points were not identified on the basis of the helium data alone. Once an X-ray feature is identified it is almost always possible to find an underlying dark patch of enhanced He I absorption which, however, would not a priori have been selected as a dark point. Therefore, the He I dark points, using current selection criteria, cannot be used as a one-to-one proxy for the X-ray data. He I dark points do, however, identify the locations of the stronger X-ray bright points.

Discovery of low-redshift X-ray selected quasars - New clues to the QSO phenomenon

NASA Technical Reports Server (NTRS)

Grindlay, J. E.; Forman, W. R.; Steiner, J. E.; Canizares, C. R.; Mcclintock, J. E.

1980-01-01

The identification of six X-ray sources discovered by the Einstein Observatory with X-ray quasars is reported, and the properties of these X-ray selected quasars are discussed. The four high-latitude fields of 1 sq deg each in which the Einstein imaging proportional counter detected serendipitous X-ray sources at intermediate exposures of 10,000 sec were observed by 4-m and 1.5-m telescopes, and optical sources with uv excesses and emission line spectra typical of many low-redshift quasars and Seyfert 1 galaxies were found within the 1-arcsec error boxes of the X-ray sources. All six quasars identified were found to be radio quiet, with low redshift and relatively faint optical magnitudes, and to be similar in space density, colors and magnitude versus redshift relation to an optically selected sample at the same mean magnitude. X-ray luminosity was found to be well correlated with both continuum and broad-line emission luminosities for the known radio-quiet quasars and Seyfert 1 galaxies, and it was observed that the five objects with the lowest redshifts have very similar X-ray/optical luminosity ratios despite tenfold variations in X-ray luminosity. It is concluded that photoionization by a continuum extending to X-ray energies is the dominant excitation mechanism in radio-quiet quasars.

SPECTRAL SURVEY OF X-RAY BRIGHT ACTIVE GALACTIC NUCLEI FROM THE ROSSI X-RAY TIMING EXPLORER

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rivers, Elizabeth; Markowitz, Alex; Rothschild, Richard, E-mail: erivers@ucsd.edu

2011-03-15

Using long-term monitoring data from the Rossi X-ray Timing Explorer (RXTE), we have selected 23 active galactic nuclei (AGNs) with sufficient brightness and overall observation time to derive broadband X-ray spectra from 3 to {approx}>100 keV. Our sample includes mainly radio-quiet Seyferts, as well as seven radio-loud sources. Given the longevity of the RXTE mission, the greater part of our data is spread out over more than a decade, providing truly long-term average spectra and eliminating inconsistencies arising from variability. We present long-term average values of absorption, Fe line parameters, Compton reflection strengths, and photon indices, as well as fluxesmore » and luminosities for the hard and very hard energy bands, 2-10 keV and 20-100 keV, respectively. We find tentative evidence for high-energy rollovers in three of our objects. We improve upon previous surveys of the very hard X-ray energy band in terms of accuracy and sensitivity, particularly with respect to confirming and quantifying the Compton reflection component. This survey is meant to provide a baseline for future analysis with respect to the long-term averages for these sources and to cement the legacy of RXTE, and especially its High Energy X-ray Timing Experiment, as a contributor to AGN spectral science.« less

Simultaneous Planck , Swift , and Fermi observations of X-ray and γ -ray selected blazars

DOE PAGES

Giommi, P.; Polenta, G.; Lähteenmäki, A.; ...

2012-05-22

We present simultaneous Planck, Swift, Fermi, and ground-based data for 105 blazars belonging to three samples with flux limits in the soft X-ray, hard X-ray, and γ-ray bands, with additional 5GHz flux-density limits to ensure a good probability of a Planck detection. We compare our results to those of a companion paper presenting simultaneous Planck and multi-frequency observations of 104 radio-loud northern active galactic nuclei selected at radio frequencies. While we confirm several previous results, our unique data set allows us to demonstrate that the selection method strongly influences the results, producing biases that cannot be ignored. Almost all themore » BL Lac objects have been detected by the Fermi Large AreaTelescope (LAT), whereas 30% to 40% of the flat-spectrum radio quasars (FSRQs) in the radio, soft X-ray, and hard X-ray selected samples are still below the γ-ray detection limit even after integrating 27 months of Fermi-LAT data. The radio to sub-millimetre spectral slope of blazars is quite flat, with >α> ~ 0 up to about 70GHz, above which it steepens to ~ -0.65. The BL Lacs have significantly flatter spectra than FSRQs at higher frequencies. The distribution of the rest-frame synchrotron peak frequency (ν peak S) in the spectral energy distribution (SED) of FSRQs is the same in all the blazar samples with peak S> = 10 13.1 ± 0.1 Hz, while the mean inverse Compton peak frequency, >ν peak IC>, ranges from 1021 to 1022 Hz. The distributions of ν peak S and ν peak IC of BL Lacs are much broader and are shifted to higher energies than those of FSRQs; their shapes strongly depend on the selection method. The Compton dominance of blazars, defined as the ratio of the inverse Compton to synchrotron peak luminosities, ranges from less than 0.2 to nearly 100, with only FSRQs reaching values larger than about 3. Its distribution is broad and depends strongly on the selection method, with γ-ray selected blazars peaking at ~7 or more, and radio-selected blazars at values close to 1, thus implying that the common assumption that the blazar power budget is largely dominated by high-energy emission is a selection effect. A comparison of our multi-frequency data with theoretical predictions shows that simple homogeneous SSC models cannot explain the simultaneous SEDs of most of the γ-ray detected blazars in all samples. The SED of the blazars that were not detected by Fermi-LAT may instead be consistent with SSC emission. Our data challenge the correlation between bolometric luminosity and ν peak S predicted by the blazar sequence.« less

X-ray and Ultraviolet Properties of AGNs in Nearby Dwarf Galaxies

NASA Astrophysics Data System (ADS)

Baldassare, Vivienne F.; Reines, Amy E.; Gallo, Elena; Greene, Jenny E.

2017-02-01

We present new Chandra X-ray Observatory and Hubble Space Telescope observations of eight optically selected broad-line active galactic nucleus (AGN) candidates in nearby dwarf galaxies (z < 0.055). Including archival Chandra observations of three additional sources, our sample contains all 10 galaxies from Reines et al. (2013) with both broad Hα emission and narrow-line AGN ratios (six AGNs, four composites), as well as one low-metallicity dwarf galaxy with broad Hα and narrow-line ratios characteristic of star formation. All 11 galaxies are detected in X-rays. Nuclear X-ray luminosities range from L 0.5-7keV ≈ 5 × 1039 to 1 × 1042 ergs-1. In all cases except for the star-forming galaxy, the nuclear X-ray luminosities are significantly higher than would be expected from X-ray binaries, providing strong confirmation that AGNs and composite dwarf galaxies do indeed host actively accreting black holes (BHs). Using our estimated BH masses (which range from ˜7 × 104 to 1 × 106 M ⊙), we find inferred Eddington fractions ranging from ˜0.1% to 50%, I.e., comparable to massive broad-line quasars at higher redshift. We use the HST imaging to determine the ratio of UV to X-ray emission for these AGNs, finding that they appear to be less X-ray luminous with respect to their UV emission than more massive quasars (I.e., α OX values an average of 0.36 lower than expected based on the relation between α OX and 2500 Å luminosity). Finally, we discuss our results in the context of different accretion models onto nuclear BHs.

X-Ray and Ultraviolet Properties of AGNs in Nearby Dwarf Galaxies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baldassare, Vivienne F.; Gallo, Elena; Reines, Amy E.

2017-02-10

We present new Chandra X-ray Observatory and Hubble Space Telescope observations of eight optically selected broad-line active galactic nucleus (AGN) candidates in nearby dwarf galaxies ( z < 0.055). Including archival Chandra observations of three additional sources, our sample contains all 10 galaxies from Reines et al. (2013) with both broad H α emission and narrow-line AGN ratios (six AGNs, four composites), as well as one low-metallicity dwarf galaxy with broad H α and narrow-line ratios characteristic of star formation. All 11 galaxies are detected in X-rays. Nuclear X-ray luminosities range from L {sub 0.5–7keV} ≈ 5 × 10{sup 39}more » to 1 × 10{sup 42} ergs{sup −1}. In all cases except for the star-forming galaxy, the nuclear X-ray luminosities are significantly higher than would be expected from X-ray binaries, providing strong confirmation that AGNs and composite dwarf galaxies do indeed host actively accreting black holes (BHs). Using our estimated BH masses (which range from ∼7 × 10{sup 4} to 1 × 10{sup 6} M {sub ⊙}), we find inferred Eddington fractions ranging from ∼0.1% to 50%, i.e., comparable to massive broad-line quasars at higher redshift. We use the HST imaging to determine the ratio of UV to X-ray emission for these AGNs, finding that they appear to be less X-ray luminous with respect to their UV emission than more massive quasars (i.e., α {sub OX} values an average of 0.36 lower than expected based on the relation between α {sub OX} and 2500 Å luminosity). Finally, we discuss our results in the context of different accretion models onto nuclear BHs.« less

A Fresnel zone plate collimator: potential and aberrations

NASA Astrophysics Data System (ADS)

Menz, Benedikt; Bräuninger, Heinrich; Burwitz, Vadim; Hartner, Gisela; Predehl, Peter

2015-09-01

A collimator, that parallelizes an X-ray beam, provides a significant improvement of the metrology to characterize X-ray optics for space instruments at MPE's PANTER X-ray test facility. A Fresnel zone plate was selected as a collimating optic, as it meets a good angular resolution < 0.1n combined with a large active area > 10 cm2. Such an optic is ideally suited to illuminate Silicon Pore Optic (SPO) modules as proposed for ATHENA. This paper provides the theoretic description of such a Fresnel zone plate especially considering resolution and efficiency. Based on the theoretic results the collimator setup performance is analyzed and requirements for fabrication and alignment are calculated.

Wide Field X-Ray Telescope Mission Concept Study Results

NASA Technical Reports Server (NTRS)

Hopkins, R. C.; Thomas, H. D.; Fabisinski, L. L.; Baysinger, M.; Hornsby, L. S.; Maples, C. D.; Purlee, T. E.; Capizzo, P. D.; Percy, T. K.

2014-01-01

The Wide Field X-Ray Telescope (WFXT) is an astrophysics mission concept for detecting and studying extra-galactic x-ray sources, including active galactic nuclei and clusters of galaxies, in an effort to further understand cosmic evolution and structure. This Technical Memorandum details the results of a mission concept study completed by the Advanced Concepts Office at NASA Marshall Space Flight Center in 2012. The design team analyzed the mission and instrument requirements, and designed a spacecraft that enables the WFXT mission while using high heritage components. Design work included selecting components and sizing subsystems for power, avionics, guidance, navigation and control, propulsion, structures, command and data handling, communications, and thermal control.

High resolution x-ray fluorescence spectroscopy - a new technique for site- and spin-selectivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Xin

1996-12-01

X-ray spectroscopy has long been used to elucidate electronic and structural information of molecules. One of the weaknesses of x-ray absorption is its sensitivity to all of the atoms of a particular element in a sample. Through out this thesis, a new technique for enhancing the site- and spin-selectivity of the x-ray absorption has been developed. By high resolution fluorescence detection, the chemical sensitivity of K emission spectra can be used to identify oxidation and spin states; it can also be used to facilitate site-selective X-ray Absorption Near Edge Structure (XANES) and site-selective Extended X-ray Absorption Fine Structure (EXAFS). Themore » spin polarization in K fluorescence could be used to generate spin selective XANES or spin-polarized EXAFS, which provides a new measure of the spin density, or the nature of magnetic neighboring atoms. Finally, dramatic line-sharpening effects by the combination of absorption and emission processes allow observation of structure that is normally unobservable. All these unique characters can enormously simplify a complex x-ray spectrum. Applications of this novel technique have generated information from various transition-metal model compounds to metalloproteins. The absorption and emission spectra by high resolution fluorescence detection are interdependent. The ligand field multiplet model has been used for the analysis of K{alpha} and K{beta} emission spectra. First demonstration on different chemical states of Fe compounds has shown the applicability of site selectivity and spin polarization. Different interatomic distances of the same element in different chemical forms have been detected using site-selective EXAFS.« less

Suzaku  Observations of Heavily Obscured (Compton-thick) Active Galactic Nuclei Selected by the Swift/BAT Hard X-Ray Survey

NASA Astrophysics Data System (ADS)

Tanimoto, Atsushi; Ueda, Yoshihiro; Kawamuro, Taiki; Ricci, Claudio; Awaki, Hisamitsu; Terashima, Yuichi

2018-02-01

We present a uniform broadband X-ray (0.5–100.0 keV) spectral analysis of 12 Swift/Burst Alert Telescope selected Compton-thick ({log}{N}{{H}}/{{cm}}-2≥slant 24) active galactic nuclei (CTAGNs) observed with Suzaku. The Suzaku data of three objects are published here for the first time. We fit the Suzaku and Swift spectra with models utilizing an analytic reflection code and those utilizing the Monte-Carlo-based model from an AGN torus by Ikeda et al. The main results are as follows: (1) The estimated intrinsic luminosity of a CTAGN strongly depends on the model; applying Compton scattering to the transmitted component in an analytic model may largely overestimate the intrinsic luminosity at large column densities. (2) Unabsorbed reflection components are commonly observed, suggesting that the tori are clumpy. (3) Most of CTAGNs show small scattering fractions (<0.5%), implying a buried AGN nature. (4) Comparison with the results obtained for Compton-thin AGNs suggests that the properties of these CTAGNs can be understood as a smooth extension from Compton-thin AGNs with heavier obscuration; we find no evidence that the bulk of the population of hard-X-ray-selected CTAGNs are different from less obscured objects.

Neutron diffraction reveals hydrogen bonds critical for cGMP-selective activation: Insights for cGMP-dependent protein kinase agonist design

DOE PAGES

Huang, Gilbert Y.; Gerlits, Oksana O.; Blakeley, Matthew P.; ...

2014-10-01

High selectivity of cyclic-nucleotide binding (CNB) domains for cAMP and cGMP are required for segregating signaling pathways; however, the mechanism of selectivity remains unclear. To investigate the mechanism of high selectivity in cGMP-dependent protein kinase (PKG), we determined a room-temperature joint X-ray/neutron (XN) structure of PKG Iβ CNB-B, a domain 200-fold selective for cGMP over cAMP, bound to cGMP (2.2 Å), and a low-temperature X-ray structure of CNB-B with cAMP (1.3 Å). Finally, the XN structure directly describes the hydrogen bonding interactions that modulate high selectivity for cGMP, while the structure with cAMP reveals that all these contacts are disrupted,more » explaining its low affinity for cAMP.« less

X-Ray Diffraction Apparatus

NASA Technical Reports Server (NTRS)

Blake, David F. (Inventor); Bryson, Charles (Inventor); Freund, Friedmann (Inventor)

1996-01-01

An x-ray diffraction apparatus for use in analyzing the x-ray diffraction pattern of a sample is introduced. The apparatus includes a beam source for generating a collimated x-ray beam having one or more discrete x-ray energies, a holder for holding the sample to be analyzed in the path of the beam, and a charge-coupled device having an array of pixels for detecting, in one or more selected photon energy ranges, x-ray diffraction photons produced by irradiating such a sample with said beam. The CCD is coupled to an output unit which receives input information relating to the energies of photons striking each pixel in the CCD, and constructs the diffraction pattern of photons within a selected energy range striking the CCD.

Hunting for Intrinsically X-ray Weak Quasars: The Case of PHL 1811 Analogs

NASA Astrophysics Data System (ADS)

Brandt, William

2009-09-01

A central dogma of X-ray astronomy is that luminous X-ray emission is a universal property of efficiently accreting supermassive black holes. One interesting challenge to this idea has come from the quasar PHL 1811 which appears to be intrinsically X-ray weak and also has distinctive emission-line properties. We propose to observe a sample of eight SDSS quasars, selected to have similar UV emission-line properties to that of PHL 1811, to test if they are also X-ray weak. Our analyses of the currently available X-ray data appear to support this hypothesis but do not provide a proper test. Our results will have implications for the nature of accretion-disk coronae, emission-line formation, and AGN selection.

Mini-Survey on SDSS OIII AGN with Swift

NASA Technical Reports Server (NTRS)

Angelini, Lorella

2008-01-01

The number of AGN and their luminosity distribution are crucial parameters for our understanding of the AGN phenomenon. There is a common wisdom that every massive galaxy has a massive black hole. However, most of these objects either are not radiating or until recently have been very difficult to detect. The Sloan Digital Sky Survey (SDSS) data, based on the [OIII] line indicate that perhaps up to 20% of all galaxies may be classified as AGN a surprising result that must be checked with independent data. X-ray surveys have revealed that hard X-ray selected AGN show a strong luminosity dependent evolution and their luminosity function (LF) shows a dramatic break towards low $L_X$ (at all $z$). This is seen for all types of AGN, but is stronger for the broad-line objects. In sharp contrast, the local LF of {it optically-selected samples} shows no such break and no differences between narrow and broad-line objects. Assuming both hard X-ray and [O{\\sc iii}] emission are fair indicators of AGN activity, it is important to understand this discrepancy. We present here the results of a min-survey done with Swift on a selected sample of SDSS selected AGN. The objects have been sampled at different L([O{\\sc iii}]) to check the relation with the $L_X$ observed with Swift.

A Full Year's Chandra Exposure on Sloan Digital Sky Survey Quasars from the Chandra Multiwavelength Project

NASA Astrophysics Data System (ADS)

Green, Paul J.; Aldcroft, T. L.; Richards, G. T.; Barkhouse, W. A.; Constantin, A.; Haggard, D.; Karovska, M.; Kim, D.-W.; Kim, M.; Vikhlinin, A.; Anderson, S. F.; Mossman, A.; Kashyap, V.; Myers, A. D.; Silverman, J. D.; Wilkes, B. J.; Tananbaum, H.

2009-01-01

We study the spectral energy distributions and evolution of a large sample of optically selected quasars from the Sloan Digital Sky Survey that were observed in 323 Chandra images analyzed by the Chandra Multiwavelength Project. Our highest-confidence matched sample includes 1135 X-ray detected quasars in the redshift range 0.2 < z < 5.4, representing some 36 Msec of effective exposure. We provide catalogs of QSO properties, and describe our novel method of calculating X-ray flux upper limits and effective sky coverage. Spectroscopic redshifts are available for about 1/3 of the detected sample; elsewhere, redshifts are estimated photometrically. We detect 56 QSOs with redshift z > 3, substantially expanding the known sample. We find no evidence for evolution out to z ~ 5 for either the X-ray photon index Γ or for the ratio of optical/UV to X-ray flux αox. About 10% of detected QSOs show best-fit intrinsic absorbing columns greater than 1022 cm-2, but the fraction might reach ~1/3 if most nondetections are absorbed. We confirm a significant correlation between αox and optical luminosity, but it flattens or disappears for fainter (MB gsim -23) active galactic nucleus (AGN) alone. We report significant hardening of Γ both toward higher X-ray luminosity, and for relatively X-ray loud quasars. These trends may represent a relative increase in nonthermal X-ray emission, and our findings thereby strengthen analogies between Galactic black hole binaries and AGN. For uniformly selected subsamples of narrow-line Seyfert 1s and narrow absorption line QSOs, we find no evidence for unusual distributions of either αox or Γ.

X-ray backscatter imaging of nuclear materials

DOEpatents

Chapman, Jeffrey Allen; Gunning, John E; Hollenbach, Daniel F; Ott, Larry J; Shedlock, Daniel

2014-09-30

The energy of an X-ray beam and critical depth are selected to detect structural discontinuities in a material having an atomic number Z of 57 or greater. The critical depth is selected by adjusting the geometry of a collimator that blocks backscattered radiation so that backscattered X-ray originating from a depth less than the critical depth is not detected. Structures of Lanthanides and Actinides, including nuclear fuel rod materials, can be inspected for structural discontinuities such as gaps, cracks, and chipping employing the backscattered X-ray.

Studies of an x ray selected sample of cataclysmic variables. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Silber, Andrew D.

1986-01-01

Just prior to the thesis research, an all-sky survey in hard x rays with the HEAO-1 satellite and further observations in the optical resulted in a catalog of about 700 x-ray sources with known optical counterparts. This sample includes 43 cataclysmic variables, which are binaries consisting of a detached white-dwarf and a Roche lobe filling companion star. This thesis consists of studies of the x-ray selected sample of catalcysmic variables.

Short time variability of solar corona during recent solar cycle minimum

NASA Astrophysics Data System (ADS)

Siarkowski, Marek; Gryciuk, Magdalena; Gburek, Szymon; Sylwester, Janusz; Sylwester, Barbara; Kepa, Anna; Buczkowska, Agnieszka; Kowalinski, Miroslaw

Sphinx is the X-ray spectrophotometer designed to measure X-ray emission from the Sun in the energy range between 0.8 keV and 15 keV. The instrument is placed onboard Russian KORONAS-PHOTON satellite launched on January 30, 2009. In this paper we present the observations of coronal emission obtained between March-April and August-September 2009, i.e. the times towards the end of the last, very prolonged and deep minimum of solar activity. Prompt analysis of SphinX spectra reveal the variability of the average coronal plasma charac-teristics like the temperature and emission measure. These data are used to compare SphinX and GOES measurements, for selected times. Examples of many sub/microflare events with maxima of the X-ray flux, observed much below the GOES sensitivity threshold level will be presented.

Infrared properties of serendipitous X-ray quasars

NASA Technical Reports Server (NTRS)

Neugebauer, G.; Soifer, B. T.; Matthews, K.; Margon, B.; Chanan, G. A.

1982-01-01

Near infrared measurements were obtained of 30 quasars originally found serendipitously as X-ray sources in fields of other objects. The observations show that the infrared characteristics of these quasars do not differ significantly from those of quasars selected by other criteria. Because this X-ray selected sample is subject to different selection biases than previous radio and optical surveys, this conclusion is useful in validating previous inferences regarding the infrared colors of 'typical' quasars.

Compton thick AGN in Chandra sureys

NASA Astrophysics Data System (ADS)

Brightman, Murray; Nandra, Kirpal

2014-07-01

We present the results from the X-ray spectral analysis of active galactic nuclei (AGN) in the Chandra Deep Field-South, AEGIS-XD and Chandra-COSMOS surveys, focussing on the identification and characterisation of the most heavily obscured, Compton thick (CT, N H > 104 cm-2) sources. Our sample is comprised of 3088 X-ray selected sources, which has a high rate of redshift completeness (97%). The aim is to produce the largest and cleanest uniform sample of these sources from the data as possible. We identify these sources through X-ray spectral fitting, utilising torus spectral models designed for heavily obscured AGN which self consistently include the spectral signatures of heavy absorption, being Compton scattering, photoelectric absorption and iron Kα fluorescence. We identify a total of 163 CT AGN covering an intrinsic 2-10 keV X-ray luminosity range of 102 -3 × 105 erg s-1 and from z = 0.1-7.

Host Galaxy Morphologies Of Hard X-ray Selected AGN From The Swift BAT Survey

NASA Astrophysics Data System (ADS)

Koss, Michael; Mushotzky, R.; Veilleux, S.

2009-01-01

Surveys of AGN taken in the optical, UV, and soft X-rays miss an important population of obscured AGN only visible in the hard X-rays and mid-IR wavelengths. The SWIFT BAT survey in the hard X-ray range (14-195 keV) has provided a uniquely unbiased sample of 258 AGN unaffected by galactic or circumnuclear absorption. Optical imaging of this unbiased sample provides a new opportunity to understand how the environments of the host galaxies are linked to AGN. For these host galaxies, only a fraction, 29%, have high quality optical images, predominately from the SDSS. In addition, about 33% show peculiar morphologies and interaction. In 2008, we observed 110 of these targets at Kitt Peak with the 2.1m in the SDSS bands over 17 nights. Using these observations and SDSS data we review the relationships between color, morphology, merger activity, star formation, and AGN luminosity.

Potassium-Promoted Molybdenum Carbide as a Highly Active and Selective Catalyst for CO2 Conversion to CO.

PubMed

Porosoff, Marc D; Baldwin, Jeffrey W; Peng, Xi; Mpourmpakis, Giannis; Willauer, Heather D

2017-06-09

The high concentration of CO 2 bound in seawater represents a significant opportunity to extract and use this CO 2 as a C 1 feedstock for synthetic fuels. Using an existing process, CO 2 and H 2 can be concurrently extracted from seawater and then catalytically reacted to produce synthetic fuel. Hydrogenating CO 2 directly into liquid hydrocarbons is exceptionally difficult, but by first identifying a catalyst for selective CO production through the reverse water-gas shift (RWGS) reaction, CO can then be hydrogenated to fuel through Fischer-Tropsch (FT) synthesis. Results of this study demonstrate that potassium-promoted molybdenum carbide supported on γ-Al 2 O 3 (K-Mo 2 C/γ-Al 2 O 3 ) is a low-cost, stable, and highly selective catalyst for RWGS over a wide range of conversions. These findings are supported by X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and density functional theory calculations. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Broad Band Properties of the BAT Selected AGN

NASA Technical Reports Server (NTRS)

Mushotzky, Richard; Winter, Lisa; Tueller, Jack

2008-01-01

I will present the x-ray spectral properties of approx.150 BAT selected ACN focusing on the issues of spectral complexity, x-ray absorption and its distribution and that contribution of sources to the x-ray background. If time permits we will also present the nature of the host galaxies of the ACN and their relationship to merger candidates.

X-Ray Characteristics of Megamaser Galaxies

NASA Astrophysics Data System (ADS)

Leiter, K.; Kadler, M.; Wilms, J.; Braatz, J.; Grossberger, C.; Krauss, F.; Kreikenbohm, A.; Langejahn, M.; Litzinger, E.; Markowitz, A.

2017-10-01

Water megamaser galaxies are a rare subclass of Active Galactic Nuclei (AGN). They play a key role in modern cosmology, providing a significant improvement for measuring geometrical distances with high precision. Megamaser studies presently measure H_{0} to about 5%. The goal of modern programs is to reach 3%, which strongly constrains the equation of state of dark energy. An increasing number of independent measurements of suitable water masers is providing the statistics necessary to decrease the uncertainties. X-ray studies of maser galaxies yield important constraints on target-selection criteria for future surveys, increasing their detection rate. We studied the X-ray properties of a homogeneous sample of Type 2 AGN with water maser activity observed by XMM-Newton to investigate the properties of megamaser-hosting galaxies compared to a control sample of non-maser galaxies. Comparing the luminosity distributions confirm previous results that water maser galaxies appear more luminous than non-maser sources. The maser phenomenon goes along with more complex X-ray spectra, higher column densities and higher equivalent widths of the Fe Kα line. Both a sufficiently luminous X-ray source and a high absorbing column density in the line of sight are necessary prerequisites to favour the appearance of the water megamaser phenomenon in AGN.

NuSTAR Observations of WISE J1036+0449, A Galaxy at Z Approx. 1 Obscured by Hot Dust

NASA Technical Reports Server (NTRS)

Ricci, C.; Assef, R. J.; Stern, D.; Nikutta, R.; Alexander, D. M.; Asmus, D.; Ballantyne, D. R.; Bauer, F. E.; Blain, A. W.; Boggs, S.;

NuSTAR Observations of WISE J1036+0449, A Galaxy at zeta approx 1 Obscured by Hot Dust

NASA Technical Reports Server (NTRS)

Ricci, C.; Assef, R. J.; Stern, Daniel K.; Nikutta, R.; Alexander, D. M.; Asmus, D.; Ballantyne, D. R.; Bauer, F. E.; Blain, A.W.; Zhang, William W.;

Mini-Survey of SDSS OIII AGN with Swift

NASA Technical Reports Server (NTRS)

Angelina, Lorella; George, Ian

2007-01-01

There is a common wisdom that every massive galaxy has a massive block hole. However, most of these objects either are not radiating or until recently have been very difficult to detect. The Sloan Digital Sky Survey (SDSS) data, based on the [OIII] line indicate that perhaps up to 20% of all galaxies may be classified as AGN a surprising result that must be checked with independent data. X-ray surveys have revealed that hard X-ray selected AGN show a strong luminosity dependent evolution and their luminosity function (LF) shows a dramatic break towards low Lx (at all z). This is seen for all types of AGN, but is stronger for the broad-line objects. In sharp contrast, the local LF of (optically-selected samples) shows no such break and no differences between narrow and broad-line objects. Assuming both hard X-ray and [OIII] emission are fair indicators of AGN activity, it is important to understand this discrepancy. We present here the results of a mini-survey done with Swift on a selected sample of SDSS selected AGN. The objects have been sampled at different L([OIII]) to check the relation with the Lx observed with Swift.

Physics and evolution of obscured X-ray sources: a multiwavelength approach

NASA Astrophysics Data System (ADS)

Brusa, Marcella

2004-06-01

Observations at high energies yield important information on the structure and nature of AGN; when coupled with deep optical and near-infrared (photometric and spectroscopic) follow-up, they provide constraints on the mass of the growing black holes and, therefore, are essential to better understand the nature of the various components of the X-ray background light and can be used as test for the accretion paradigm. Conversely, optical and near-infrared surveys of galaxies are crucial to discriminate between different cosmological scenarios (e.g. hierarchical or monolithic growth of the structures) and, thus, to recover the galaxy evolution path. In this framework, in the first part of the thesis, I will discuss the main results from an extensive program of multiwavelength observations of hard X-ray selected sources serendipitously discovered in XMM-Newton fields over ~1 deg^2 (the HELLAS2XMM survey). With a complementary approach to that of hard X-ray surveys, in order to investigate the link between nuclear activity and the galaxy formation, in the second part of the thesis I will present XMM-Newton and Chandra observations of photometric and spectroscopically selected Extremely Red Objects (EROs).

X-ray astronomical spectroscopy

NASA Technical Reports Server (NTRS)

Holt, Stephen S.

1987-01-01

The contributions of the Goddard group to the history of X-ray astronomy are numerous and varied. One role that the group has continued to play involves the pursuit of techniques for the measurement and interpretation of the X-ray spectra of cosmic sources. The latest development is the selection of the X-ray microcalorimeter for the Advanced X-ray Astrophysics Facility (AXAF) study payload. This technology is likely to revolutionize the study of cosmic X-ray spectra.

X-Ray Properties of K-Selected Galaxies at 0.5 Less than z Less than 2.0: Investigating Trends with Stellar Mass, Redshift and Spectral Type

NASA Technical Reports Server (NTRS)

Jones, Therese M.; Kriek, Mariska; vanDokkum, Peter G.; Brammer, Gabriel; Franx, Marijn; Greene, Jenny E.; Labbe, Ivo; Whitaker, Katherine E.

2014-01-01

We examine how the total X-ray luminosity correlates with stellar mass, stellar population, and redshift for a K-band limited sample of approximately 3500 galaxies at 0.5 < z < 2.0 from the NEWFIRM Medium Band Survey in the COSMOS field. The galaxy sample is divided into 32 different galaxy types, based on similarities between the spectral energy distributions. For each galaxy type, we further divide the sample into bins of redshift and stellar mass, and perform an X-ray stacking analysis using the Chandra COSMOS data. We find that full band X-ray luminosity is primarily increasing with stellar mass, and at similar mass and spectral type is higher at larger redshifts. When comparing at the same stellar mass, we find that the X-ray luminosity is slightly higher for younger galaxies (i.e., weaker 4000 angstrom breaks), but the scatter in this relation is large. We compare the observed X-ray luminosities to those expected from low- and high-mass X-ray binaries (XRBs). For blue galaxies, XRBs can almost fully account for the observed emission, while for older galaxies with larger 4000 angstrom breaks, active galactic nuclei (AGN) or hot gas dominate the measured X-ray flux. After correcting for XRBs, the X-ray luminosity is still slightly higher in younger galaxies, although this correlation is not significant. AGN appear to be a larger component of galaxy X-ray luminosity at earlier times, as the hardness ratio increases with redshift. Together with the slight increase in X-ray luminosity this may indicate more obscured AGNs or higher accretion rates at earlier times.

Hard and soft X-ray microscopy and tomography in catalysis: bridging the different time and length scales.

PubMed

Grunwaldt, Jan-Dierk; Schroer, Christian G

2010-12-01

X-ray microscopic techniques are excellent and presently emerging techniques for chemical imaging of heterogeneous catalysts. Spatially resolved studies in heterogeneous catalysis require the understanding of both the macro and the microstructure, since both have decisive influence on the final performance of the industrially applied catalysts. A particularly important aspect is the study of the catalysts during their preparation, activation and under operating conditions, where X-rays have an inherent advantage due to their good penetration length especially in the hard X-ray regime. Whereas reaction cell design for hard X-rays is straightforward, recently smart in situ cells have also been reported for the soft X-ray regime. In the first part of the tutorial review, the constraints from a catalysis view are outlined, then the scanning and full-field X-ray microscopy as well as coherent X-ray diffraction imaging techniques are described together with the challenging design of suitable environmental cells. Selected examples demonstrate the application of X-ray microscopy and tomography to monitor structural gradients in catalytic reactors and catalyst preparation with micrometre resolution but also the possibility to follow structural changes in the sub-100 nm regime. Moreover, the potential of the new synchrotron radiation sources with higher brilliance, recent milestones in focusing of hard X-rays as well as spatiotemporal studies are highlighted. The tutorial review concludes with a view on future developments in the field of X-ray microscopy that will have strong impact on the understanding of catalysts in the future and should be combined with in situ electron microscopic studies on the nanoscale and other spectroscopic studies like microRaman, microIR and microUV-vis on the macroscale.

A recyclable Au(I) catalyst for selective homocoupling of arylboronic acids: significant enhancement of nano-surface binding for stability and catalytic activity.

PubMed

Zhang, Xin; Zhao, Haitao; Wang, Jianhui

2010-08-01

Au nanoparticles stabilized by polystyrene-co-polymethacrylic acid microspheres (PS-co-PMAA) were prepared and characterized via X-ray diffraction (XRD), and transmission electron microscope (TEM). The Au nanoparticles supported on the microspheres showed highly selective catalytic activity for homo-coupling reactions of arylboronic acids in a system of aryl-halides and arylboronic acids. X-ray photoelectron spectroscopy (XPS) spectra of the catalyst shows large amounts of Au(I) complexes band to the surface of the Au nanoparticles, which contributes to the selective homocoupling of the arylboronic acids. More importantly, this supported Au complex is a highly recyclable catalyst. The supported Au catalyst can be recycled and reused at least 6 times for a phenylboronic acid reactant, whereas the parent complex shows very low catalytic activity for this compound. The high catalytic activity of this material is attributed to: (1) the high surface to volume ratio which leads to more active sites being exposed to reactants; (2) the strong surface binding of the Au nanoparticle to the Au(I) complexes, which enhances both the stability and the catalytic activity of these complexes.

New carbocyclic nucleoside analogues with a bicyclo[2.2.1]heptane fragment as sugar moiety; synthesis, X-ray crystallography and anticancer activity.

PubMed

Tănase, Constantin I; Drăghici, Constantin; Căproiu, Miron Teodor; Shova, Sergiu; Mathe, Christophe; Cocu, Florea G; Enache, Cristian; Maganu, Maria

2014-01-01

An amine group was synthesized starting from an optically active bicyclo[2.2.1]heptane compound, which was then used to build the 5 atoms ring of a key 6-chloropurine intermediate. This was then reacted with ammonia and selected amines obtaining new adenine- and 6-substituted adenine conformationally constrained carbocyclic nucleoside analogues with a bicyclo[2.2.1]heptane skeleton in the sugar moiety. X-ray crystallography confirmed an exo-coupling of base to the ring and a L configuration of the nucleoside analogues. The compounds were tested for anticancer activity. Copyright © 2013 Elsevier Ltd. All rights reserved.

The intraday variability in the radio-selected and X-ray-selected BL Lacertae objects

NASA Astrophysics Data System (ADS)

Bai, J. M.; Xie, G. Z.; Li, K. H.; Zhang, X.; Liu, W. W.

1998-10-01

Seven BL Lac objects have been photometrically observed in an effort to study the difference of optical intraday variability between the radio-selected BL Lac objects (RBLs) and X-ray-selected BL Lac objects (XBLs). The objects we observed are selected arbitrarily. They are four RBLs, PKS 0735+178, PKS 0754+101, OJ 287 and BL Lac, and three XBLs, H 0323+022, H 0548-322 and H 2154-304. During the observation all of them exhibited microvariation, and H 0323+022 and H 0548-322 sometimes showed brightness oscillation. PKS 0735+178 and BL Lac were in their faint states and not very active. It seems that RBLs do not show microvariability more frequently than XBLs. Table 2 is only available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5)

X-ray study of a sample of FR0 radio galaxies: unveiling the nature of the central engine

NASA Astrophysics Data System (ADS)

Torresi, E.; Grandi, P.; Capetti, A.; Baldi, R. D.; Giovannini, G.

2018-06-01

Fanaroff-Riley type 0 radio galaxies (FR0s) are compact radio sources that represent the bulk of the radio-loud active galactic nuclei (AGN) population, but they are still poorly understood. Pilot studies on these sources have been already performed at radio and optical wavelengths: here we present the first X-ray study of a sample of 19 FR0 radio galaxies selected from the Sloan Digital Sky Survey/NRAO VLA Sky Survey/Faint Images of the Radio Sky at Twenty-cm sample of Best & Heckman, with redshift ≤0.15, radio size ≤10 kpc, and optically classified as low-excitation galaxies. The X-ray spectra are modelled with a power-law component absorbed by Galactic column density with, in some cases, a contribution from thermal extended gas. The X-ray photons are likely produced by the jet as attested by the observed correlation between X-ray (2-10 keV) and radio (5 GHz) luminosities, similar to Fanaroff-Riley type I radio galaxies (FRIs). The estimated Eddington-scaled luminosities indicate a low accretion rate. Overall, we find that the X-ray properties of FR0s are indistinguishable from those of FRIs, thus adding another similarity between AGN associated with compact and extended radio sources. A comparison between FR0s and low-luminosity BL Lacs rules out important beaming effects in the X-ray emission of the compact radio galaxies. FR0s have different X-ray properties with respect to young radio sources (e.g. gigahertz-peaked spectrum/compact steep spectrum sources), generally characterized by higher X-ray luminosities and more complex spectra. In conclusion, the paucity of extended radio emission in FR0s is probably related to the intrinsic properties of their jets that prevent the formation of extended structures, and/or to intermittent activity of their engines.

Identifying Luminous AGN in Deep Surveys: Revised IRAC Selection Criteria

NASA Astrophysics Data System (ADS)

Donley, Jennifer; Koekemoer, A. M.; Brusa, M.; Capak, P.; Cardamone, C. N.; Civano, F.; Ilbert, O.; Impey, C. D.; Kartaltepe, J.; Miyaji, T.; Salvato, M.; Sanders, D. B.; Trump, J. R.; Zamorani, G.

2012-01-01

Spitzer IRAC selection is a powerful tool for identifying luminous AGN. The AGN selection wedges currently in use, however, are heavily contaminated by star-forming galaxies, especially at high redshift. Using the large samples of luminous AGN and high-redshift star-forming galaxies in COSMOS, we redefine the AGN selection criteria for use in deep IRAC surveys. The new IRAC criteria are designed to be both highly complete and reliable, and incorporate the best aspects of the current AGN selection wedges and of infrared power-law selection while excluding high redshift star-forming galaxies selected via the BzK, DRG, LBG, and SMG criteria. At QSO-luminosities of log L(2-10 keV)>44, the new IRAC criteria recover 75% of the hard X-ray and IRAC-detected XMM-COSMOS sample, yet only 37% of the IRAC AGN candidates have X-ray counterparts, a fraction that rises to 51% in regions with Chandra exposures of 50-160 ks. X-ray stacking of the individually X-ray non-detected AGN candidates leads to a hard X-ray signal indicative of heavily obscured to mildly Compton-thick obscuration (log NH >= 23.7). While IRAC selection recovers a substantial fraction of luminous unobscured and obscured AGN, it is incomplete to low-luminosity and host-dominated AGN.

An X-Ray Survey of the Open Cluster NGC 6475 (M7) with ROSAT

NASA Technical Reports Server (NTRS)

Prosser, Charles F.; Stauffer, John R.; Caillault, J.-P.; Balachandran, Suchitra; Stern, Robert A.; Randich, Sofia

1995-01-01

A ROSAT x-ray survey, with complimentary optical photometry, of the open cluster NGC 6475 has enabled the detection of approx. 50 late-F to K0 and approx. 70 K/M dwarf new candidate members, providing the first reliable detection of low-mass stars in this low. galactic latitude, 220 Myr old cluster. The x-ray observations reported here have a typical limiting sensitivity of L(sub x) approx. equal to 10(exp 29) erg/s. The detection frequency of early type cluster members is consistent with the hypothesis that the x-ray emitting early type stars are binary systems with an unseen, low-mass secondary producing the x rays. The ratio between x-ray and bolometric luminosity among NGC 6475 members saturates at a spectral-type/color which is intermediate between that in much younger and in much older clusters, consistent with rotational spindown of solar-type stars upon their arrival on the ZAMS. The upper envelope of x-ray luminosity as a function of spectral type is comparable to that of the Pleiades, with the observed spread in x-ray luminosity among low-mass members being likely due to the presence of binaries and relatively rapid rotators. However, the list of x-ray selected candidate members is likely biased against low-mass, slowly rotating single stars. While some preliminary spectroscopic information is given in an appendix, further spectroscopic observations of the new candidate members will aid in interpreting the coronal activity among solar-type NGC 6475 members and their relation to similar stars in older and younger open clusters.

X-Ray Properties of Lensing-Selected Clusters

NASA Astrophysics Data System (ADS)

Paterno-Mahler, Rachel; Sharon, Keren; Bayliss, Matthew; McDonald, Michael; Gladders, Michael; Johnson, Traci; Dahle, Hakon; Rigby, Jane R.; Whitaker, Katherine E.; Florian, Michael; Wuyts, Eva

2017-08-01

I will present preliminary results from the Michigan Swift X-ray observations of clusters from the Sloan Giant Arcs Survey (SGAS). These clusters were lensing selected based on the presence of a giant arc visible from SDSS. I will characterize the morphology of the intracluster medium (ICM) of the clusters in the sample, and discuss the offset between the X-ray centroid, the mass centroid as determined by strong lensing analysis, and the BCG position. I will also present early-stage work on the scaling relation between the lensing mass and the X-ray luminosity.

Tending the Fire, A Legacy Survey of Molecular Gas Fueling in Powerful Nearby AGN

NASA Astrophysics Data System (ADS)

Koss, Michael; BASS Team

2018-01-01

Over the last 30 years the importance of host galaxy molecular gas for growing black holes has been intensely debated. We have observed a a volume-limited sample of over 200 nearby powerful AGN (0.01 < z < 0.05, Lbol;AGN > 10^44 erg/s) using the CO 2-1 line with the JCMT and APEX telescopes to definitively address this issue. The AGN are selected from the Swift-BAT all sky hard X-ray survey which is superior to optical or IR selection since high energy X-rays (14-195 keV) are almost independent of host galaxy properties and obscuration. We compare our samples molecular gas properties to inactive galaxies selected with the IRAM 30m COLD GASS survey to understand the general trends with AGN activity.

Facile preparation of highly-dispersed cobalt-silicon mixed oxide nanosphere and its catalytic application in cyclohexane selective oxidation

PubMed Central

2011-01-01

Highly dispersed cobalt-silicon mixed oxide [Co-SiO2] nanosphere was successfully prepared with a modified reverse-phase microemulsion method. This material was characterized in detail by X-ray diffraction, transmission electron microscopy, Fourier transform infrared, ultraviolet-visible diffuse reflectance spectra, X-ray absorption spectroscopy near-edge structure, and N2 adsorption-desorption measurements. High valence state cobalt could be easily obtained without calcination, which is fascinating for the catalytic application for its strong oxidation ability. In the selective oxidation of cyclohexane, Co-SiO2 acted as an efficient catalyst, and good activity could be obtained under mild conditions. PMID:22067075

Variability Selected Low-Luminosity Active Galactic Nuclei in the 4 Ms Chandra Deep Field-South

NASA Technical Reports Server (NTRS)

Young, M.; Brandt, W. N.; Xue, Y. Q.; Paolillo, D. M.; Alexander, F. E.; Bauer, F. E.; Lehmer, B. D.; Luo, B.; Shemmer, O.; Schneider, D. P.;

NuSTAR constraints on coronal cutoffs in Swift-BAT selected Seyfert 1 AGN

NASA Astrophysics Data System (ADS)

Kamraj, Nikita; Harrison, Fiona; Balokovic, Mislav; Brightman, Murray; Stern, Daniel

2017-08-01

The continuum X-ray emission from Active Galactic Nuclei (AGN) is believed to originate in a hot, compact corona above the accretion disk. Compton upscattering of UV photons from the inner accretion disk by coronal electrons produces a power law X-ray continuum with a cutoff at energies determined by the electron temperature. The NuSTAR observatory, with its high sensitivity in hard X-rays, has enabled detailed broadband modeling of the X-ray spectra of AGN, thereby allowing tight constraints to be placed on the high-energy cutoff of the X-ray continuum. Recent detections of low cutoff energies in Seyfert 1 AGN in the NuSTAR band have motivated us to pursue a systematic search for low cutoff candidates in Swift-BAT detected Seyfert 1 AGN that have been observed with NuSTAR. We use our constraints on the cutoff energy to map out the location of these sources on the compactness - temperature diagram for AGN coronae, and discuss the implications of low cutoff energies for the cooling and thermalization mechanisms in the corona.

Black Hole growth and star formation activity in the CDFS

NASA Astrophysics Data System (ADS)

Brusa, Marcella; Fiore, Fabrizio

2010-07-01

We present a study of the properties of obscured Active Galactic Nuclei (AGN) detected in the CDFS 1Ms observation and their host galaxies. We limited the analysis to the MUSIC area, for which deep K-band observations obtained with ISAACatVLT are available, ensuring accurate identifications of the counterparts of the X-ray sources as well as reliable determination of photometric redshifts and galaxy parameters, such as stellar masses and star formation rates. Among other findings, we found that the X-ray selected AGN fraction increases with the stellar mass up to a value of 30% at z>1 and M*>3×1011 M.

The space density of Compton-thick AGN at z ≈ 0.8 in the zCOSMOS-Bright Survey

NASA Astrophysics Data System (ADS)

Vignali, C.; Mignoli, M.; Gilli, R.; Comastri, A.; Iwasawa, K.; Zamorani, G.; Mainieri, V.; Bongiorno, A.

2014-11-01

Context. The obscured accretion phase in black hole growth is a crucial ingredient in many models linking the active galactic nuclei (AGN) activity with the evolution of their host galaxy. At present, a complete census of obscured AGN is still missing, although several attempts in this direction have been carried out recently, mostly in the hard X-rays and at mid-infrared wavelengths. Aims: The purpose of this work is to assess whether the [Ne v] emission line at 3426 Å can reliably pick up obscured AGN up to z ≈ 1 by assuming that it is a reliable proxy of the intrinsic AGN luminosity and using moderately deep X-ray data to characterize the amount of obscuration. Methods: A sample of 69 narrow-line (Type 2) AGN at z ≈ 0.65-1.20 were selected from the 20k-zCOSMOS Bright galaxy sample on the basis of the presence of the [Ne v]3426 Å emission. The X-ray properties of these galaxies were then derived using the Chandra-COSMOS coverage of the field; the X-ray-to-[Ne v] flux ratio, coupled with X-ray spectral and stacking analyses, was then used to infer whether Compton-thin or Compton-thick absorption is present in these sources. Then the [Ne v] luminosity function was computed to estimate the space density of Compton-thick AGN at z ≈ 0.8. Results: Twenty-three sources were detected by Chandra, and their properties are consistent with moderate obscuration (on average, ≈a few × 1022 cm-2). The X-ray properties of the remaining 46 X-ray undetected Type 2 AGN (among which we expect to find the most heavily obscured objects) were derived using X-ray stacking analysis. Current data, supported by Monte Carlo simulations, indicate that a fraction as high as ≈40% of the present sample is likely to be Compton thick. The space density of Compton-thick AGN with logL2-10 keV> 43.5 at z = 0.83 is ΦThick = (9.1 ± 2.1) × 10-6 Mpc-3, in good agreement with both X-ray background model expectations and the previously measured space density for objects in a similar redshift and luminosity range. We regard our selection technique for Compton-thick AGN as clean but not complete, since even a mild extinction in the narrow-line region can suppress [Ne v] emission. Therefore, our estimate of their space density should be considered as a lower limit.

Rapid X-Ray Variability of Active Galaxies. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Tennant, A. F., Jr.

1983-01-01

Active galactic nuclei are luminous sources of X-rays. The thesis that the X-rays are generated within 10 gravitational radii from the central object is tested. A very sensitive search for rapid ( 1 day) X-ray variability from active galaxies was made.

Simultaneous Planck, Swift, and Fermi Observations of X-ray and Gamma-ray Selected Blazars

NASA Technical Reports Server (NTRS)

Giommi, P.; Polenta, G.; Laehteenmaeki, A.; Thompson, D. J.; Capalbi, M.; Cutini, S.; Gasparrini, D.; Gonzalez, Nuevo, J.; Leon-Tavares, J.; Lopez-Caniego, M.;

Simultaneous Planck, Swift, and Fermi Observations of X-Ray and gamma-Ray Selected Blazars

NASA Technical Reports Server (NTRS)

Giommi, P.; Polenta, G.; Laehteenmaeki, A.; Thompson, D. J.; Capalbi, M.; Cutini, S.; Gasparrini, D.; Gonzalez-Nuevo, J.; Leon-Tavares, J.; Lopez-Caniego, M.;

Multiwavelength observations of Active Galactic Nuclei from the radio to the hard X-rays

NASA Astrophysics Data System (ADS)

Beuchert, Tobias

2017-07-01

Active Galaxies form a peculiar type of galaxies. Their cores, the so-called "Active Galactic Nuclei" (AGN), are the most persistent luminous objects in the universe. Accretion of several solar masses per year onto black holes of Millions to Billions of solar masses drive the immense energy output of these systems, which can exceed that of the entire galaxy. The compact energy source, however, only measures about one over a Billion times that of the entire galaxy. Subject of my thesis are observations of the two main channels of energy release of selected AGN systems, both of which are encompassed by profound and yet unanswered questions. These channels are on the one hand the pronounced X-ray emission of the hot and compact accreting environment in close vicinity of the black hole, and on the other hand the radio synchrotron emission of magnetically collimated jets that are fed by portions of the accreted matter. These jets also function as effective accelerators and drive the injected matter deep into the intergalactic medium. As the circumnuclear environment of AGN is too compact to be spatially resolved in the X-rays, I show how X-ray spectroscopy can be used to: (1) understand the effects of strong gravity to trace the geometry and physics of the X-ray source and (2) more consistently quantify matter that surrounds and dynamically absorbs our direct line of sight towards the X-ray source. Second, I unveil the valuable information contained in the polarized radio light being emitted from magnetized jet outflows. In contrast to the X-ray emitting region, I am able to spatially resolve the inner parts of the jet of a prominent galaxy with help of the Very Long Baseline Array, a large network of radio telescopes. The resulting polarization maps turn out to be exceptionally promising in answering fundamental questions related to jet physics.

Very low luminosity active galaxies and the X-ray background

NASA Technical Reports Server (NTRS)

Elvis, M.; Soltan, A.; Keel, W. C.

1984-01-01

The properties of very low luminosity active galactic nuclei are not well studied, and, in particular, their possible contribution to the diffuse X-ray background is not known. In the present investigation, an X-ray luminosity function for the range from 10 to the 39th to 10 to the 42.5th ergs/s is constructed. The obtained X-ray luminosity function is integrated to estimate the contribution of these very low luminosity active galaxies to the diffuse X-ray background. The construction of the X-ray luminosity function is based on data obtained by Keel (1983) and some simple assumptions about optical and X-ray properties.

Energy-discrimination x-ray computed tomography system utilizing a scanning cadmium-telluride detector

NASA Astrophysics Data System (ADS)

Sato, Eiichi; Abduraxit, Ablajan; Enomoto, Toshiyuki; Watanabe, Manabu; Hitomi, Keitaro; Takahashi, Kiyomi; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2010-04-01

An energy-discrimination K-edge x-ray computed tomography (CT) system is useful for controlling the image contrast of a target region by selecting both the photon energy and the energy width. The CT system has an oscillation-type linear cadmium telluride (CdTe) detectror. CT is performed by repeated linear scans and rotations of an object. Penetrating x-ray photons from the object are detected by a CdTe detector, and event signals of x-ray photons are produced using charge-sensitive and shaping amplifiers. Both photon energy and energy width are selected out using a multichannel analyzer, and the number of photons is counted by a counter card. In energy-discrimination CT, the tube voltage and tube current were 80 kV and 20 μA, respectively, and the x-ray intensity was 1.92 μGy/s at a distance of 1.0 m from the source and a tube voltage of 80 kV. The energy-discrimination CT was carried out by selecting x-ray photon energies.

TS-1 supported highly dispersed sub-5 nm gold nanoparticles toward direct propylene epoxidation using H2 and O2

NASA Astrophysics Data System (ADS)

Li, Naixu; Chen, Yong; Shen, Quanhao; Yang, Bin; Liu, Ming; Wei, Lingfei; Tian, Wei; Zhou, Jiancheng

2018-05-01

We report a simple and efficient method for the preparation of highly dispersed Au nanoparticles (< 5 nm) on TS-1 substrate. The synthesis relies on the use of NaBH4 as a reductant for rapid Au atom generation, as well as PVA as a capping agent confining the particle size and dispersion. The samples were characterized by N2 physisorption, inductively coupled plasma mass spectrometry, power X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, CO pulse chemisorption and thermogravimetric analysis. The size of Au particles can be controlled in the range of 3-5 nm. The supported catalyst shows both good activity and selectivity for propylene oxide (PO) generation from direct propylene epoxidation. An optimal performance with PO formation rate of 102.94 gPO h-1 kg-1cat and selectivity of 84.83% is achieved over 2.0 wt% Au/TS-1 catalyst, which is prepared by controlling PVA/Au3+ mass ratio of 1.5/1 and NaBH4/Au3+ mole ratio of 5/1. After 50 h test at 200 °C, no significant decrement of both catalytic activity and PO selectivity can be observed, indicating the excellent thermally stability of the catalyst. Furthermore, a possible reaction mechanism is described on basis of the previous researches and our experimental results.

Identification of high-mass X-ray binaries selected from XMM-Newton observations of the LMC★

NASA Astrophysics Data System (ADS)

van Jaarsveld, N.; Buckley, D. A. H.; McBride, V. A.; Haberl, F.; Vasilopoulos, G.; Maitra, C.; Udalski, A.; Miszalski, B.

2018-04-01

The Large Magellanic Cloud (LMC) currently hosts around 23 high-mass X-ray binaries (HMXBs) of which most are Be/X-ray binaries. The LMC XMM-Newton survey provided follow-up observations of previously known X-ray sources that were likely HMXBs, as well as identifying new HMXB candidates. In total, 19 candidate HMXBs were selected based on their X-ray hardness ratios. In this paper we present red and blue optical spectroscopy, obtained with Southern African Large Telescope and the South African Astronomical Observatory 1.9-m telescope, plus a timing analysis of the long-term optical light curves from OGLE to confirm the nature of these candidates. We find that nine of the candidates are new Be/X-ray binaries, substantially increasing the LMC Be/X-ray binary population. Furthermore, we present the optical properties of these new systems, both individually and as a group of all the BeXBs identified by the XMM-Newton survey of the LMC.

Analysis and Interpretation of Hard X-ray Emission fromthe Bullet Cluster (1E0657-56), the Most Distant Cluster of Galaxies Observed by the RXTE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Petrosian, Vahe; /Stanford U., Phys. Dept. /SLAC /Stanford U., Appl. Phys. Dept.; Madejski, Greg

2006-08-16

Evidence for non-thermal activity in clusters of galaxies is well established from radio observations of synchrotron emission by relativistic electrons. New windows in the Extreme Ultraviolet and Hard X-ray ranges have provided for more powerful tools for the investigation of this phenomenon. Detection of hard X-rays in the 20 to 100 keV range have been reported from several clusters of galaxies, notably from Coma and others. Based on these earlier observations we identified the relatively high redshift cluster 1E0657-56 (also known as RX J0658-5557) as a good candidate for hard X-ray observations. This cluster, also known as the bullet cluster,more » has many other interesting and unusual features, most notably that it is undergoing a merger, clearly visible in the X-ray images. Here we present results from a successful RXTE observations of this cluster. We summarize past observations and their theoretical interpretation which guided us in the selection process. We describe the new observations and present the constraints we can set on the flux and spectrum of the hard X-rays. Finally we discuss the constraints one can set on the characteristics of accelerated electrons which produce the hard X-rays and the radio radiation.« less

Surface engineering on mesoporous silica chips for enriching low molecular weight phosphorylated proteins

NASA Astrophysics Data System (ADS)

Hu, Ye; Peng, Yang; Lin, Kevin; Shen, Haifa; Brousseau, Louis C., III; Sakamoto, Jason; Sun, Tong; Ferrari, Mauro

2011-02-01

Phosphorylated peptides and proteins play an important role in normal cellular activities, e.g., gene expression, mitosis, differentiation, proliferation, and apoptosis, as well as tumor initiation, progression and metastasis. However, technical hurdles hinder the use of common fractionation methods to capture phosphopeptides from complex biological fluids such as human sera. Herein, we present the development of a dual strategy material that offers enhanced capture of low molecular weight phosphoproteins: mesoporous silica thin films with precisely engineered pore sizes that sterically select for molecular size combined with chemically selective surface modifications (i.e. Ga3+, Ti4+ and Zr4+) that target phosphoroproteins. These materials provide high reproducibility (CV = 18%) and increase the stability of the captured proteins by excluding degrading enzymes, such as trypsin. The chemical and physical properties of the composite mesoporous thin films were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy and ellipsometry. Using mass spectroscopy and biostatistics analysis, the enrichment efficiency of different metal ions immobilized on mesoporous silica chips was investigated. The novel technology reported provides a platform capable of efficiently profiling the serum proteome for biomarker discovery, forensic sampling, and routine diagnostic applications.Phosphorylated peptides and proteins play an important role in normal cellular activities, e.g., gene expression, mitosis, differentiation, proliferation, and apoptosis, as well as tumor initiation, progression and metastasis. However, technical hurdles hinder the use of common fractionation methods to capture phosphopeptides from complex biological fluids such as human sera. Herein, we present the development of a dual strategy material that offers enhanced capture of low molecular weight phosphoproteins: mesoporous silica thin films with precisely engineered pore sizes that sterically select for molecular size combined with chemically selective surface modifications (i.e. Ga3+, Ti4+ and Zr4+) that target phosphoroproteins. These materials provide high reproducibility (CV = 18%) and increase the stability of the captured proteins by excluding degrading enzymes, such as trypsin. The chemical and physical properties of the composite mesoporous thin films were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy and ellipsometry. Using mass spectroscopy and biostatistics analysis, the enrichment efficiency of different metal ions immobilized on mesoporous silica chips was investigated. The novel technology reported provides a platform capable of efficiently profiling the serum proteome for biomarker discovery, forensic sampling, and routine diagnostic applications. Electronic supplementary information (ESI) available. See DOI: 10.1039/c0nr00720j

X-ray transmission microscope development

NASA Astrophysics Data System (ADS)

Kaukler, William F.; Rosenberger, Franz E.

1995-08-01

This report covers the third 6 month period, from February 28, 1995 to August 31, 1995, under this contract. The main efforts during this period were the construction of the X-ray furnace, evaluation and selection of the CCD technology for the X-ray camera, solidification experiments with Al alloys and Al-zirconia composites in the prototype furnace, evaluation of specimens for the particle pushing flight experiment - PEPSI, measurements of emitted spectra from X-ray source, testing of the high resolution X-ray test targets, and the establishment of criteria for and selection of peripheral equipment. In addition to these tasks, two presentations were prepared in this period; one for the AIAA Microgravity Symposium and another for the Gordon Conference on Gravitational Effects in Pyisico-Chemical Systems.

X-ray transmission microscope development

NASA Technical Reports Server (NTRS)

Kaukler, William F.; Rosenberger, Franz E.

1995-01-01

This report covers the third 6 month period, from February 28, 1995 to August 31, 1995, under this contract. The main efforts during this period were the construction of the X-ray furnace, evaluation and selection of the CCD technology for the X-ray camera, solidification experiments with Al alloys and Al-zirconia composites in the prototype furnace, evaluation of specimens for the particle pushing flight experiment - PEPSI, measurements of emitted spectra from X-ray source, testing of the high resolution X-ray test targets, and the establishment of criteria for and selection of peripheral equipment. In addition to these tasks, two presentations were prepared in this period; one for the AIAA Microgravity Symposium and another for the Gordon Conference on Gravitational Effects in Pyisico-Chemical Systems.

Toward active x-ray telescopes

NASA Astrophysics Data System (ADS)

O'Dell, Stephen L.; Atkins, Carolyn; Button, Timothy W.; Cotroneo, Vincenzo; Davis, William N.; Doel, Peter; Feldman, Charlotte H.; Freeman, Mark D.; Gubarev, Mikhail V.; Kolodziejczak, Jeffery J.; Michette, Alan G.; Ramsey, Brian D.; Reid, Paul B.; Rodriguez Sanmartin, Daniel; Saha, Timo T.; Schwartz, Daniel A.; Trolier-McKinstry, Susan; Wilke, Rudeger H. T.; Willingale, Richard; Zhang, William W.

2011-09-01

Future x-ray observatories will require high-resolution (< 1") optics with very-large-aperture (> 25 m2) areas. Even with the next generation of heavy-lift launch vehicles, launch-mass constraints and aperture-area requirements will limit the areal density of the grazing-incidence mirrors to about 1 kg/m2 or less. Achieving sub-arcsecond x-ray imaging with such lightweight mirrors will require excellent mirror surfaces, precise and stable alignment, and exceptional stiffness or deformation compensation. Attaining and maintaining alignment and figure control will likely involve active (in-space adjustable) x-ray optics. In contrast with infrared and visible astronomy, active optics for x-ray astronomy is in its infancy. In the middle of the past decade, two efforts began to advance technologies for adaptive x-ray telescopes: The Smart X-ray Optics (SXO) Basic Technology project in the United Kingdom (UK) and the Generation-X (Gen-X) concept studies in the United States (US). This paper discusses relevant technological issues and summarizes progress toward active x-ray telescopes.

Automatic tool alignment in a backscatter X-ray scanning system

DOEpatents

Garretson, Justin; Hobart, Clinton G.; Gladwell, Thomas S.; Monda, Mark J.

2015-11-17

Technologies pertaining to backscatter x-ray scanning systems are described herein. The backscatter x-ray scanning system includes an x-ray source, which directs collimated x-rays along a plurality of output vectors towards a target. A detector detects diffusely reflected x-rays subsequent to respective collimated x-rays impacting the target, and outputs signals indicative of parameters of the detected x-rays. An image processing system generates an x-ray image based upon parameters of the detected x-rays, wherein each pixel in the image corresponds to a respective output vector. A user selects a particular portion of the image, and a medical device is positioned such that its directional axis is coincident with the output vector corresponding to at least one pixel in the portion of the image.

Automatic tool alignment in a backscatter x-ray scanning system

DOEpatents

Garretson, Justin; Hobart, Clinton G.; Gladwell, Thomas S.; Monda, Mark J.

2015-06-16

Technologies pertaining to backscatter x-ray scanning systems are described herein. The backscatter x-ray scanning system includes an x-ray source, which directs collimated x-rays along a plurality of output vectors towards a target. A detector detects diffusely reflected x-rays subsequent to respective collimated x-rays impacting the target, and outputs signals indicative of parameters of the detected x-rays. An image processing system generates an x-ray image based upon parameters of the detected x-rays, wherein each pixel in the image corresponds to a respective output vector. A user selects a particular portion of the image, and a tool is positioned such that its directional axis is coincident with the output vector corresponding to at least one pixel in the portion of the image.

Multilayer and grazing incidence X-ray/EUV optics; Proceedings of the Meeting, San Diego, CA, July 22-24, 1991

NASA Technical Reports Server (NTRS)

Hoover, Richard B. (Editor)

1992-01-01

The present conference discusses the Advanced X-ray Astrophysics Facility (AXAF) calibration by means of synchrotron radiation and its X-ray reflectivity, X-ray scattering measurements from thin-foil X-ray mirrors, lobster-eye X-ray optics using microchannel plates, space-based interferometry at EUV and soft X-ray wavelengths, a water-window imaging X-ray telescope, a graded d-spacing multilayer telescope for high energy X-ray astronomy, photographic films for the multispectral solar telescope array, a soft X-ray ion chamber, and the development of hard X-ray optics. Also discussed are X-ray spectroscopy with multilayered optics, a slit aperture for monitoring X-ray experiments, an objective double-crystal spectrometer, a Ly-alpha coronagraph/polarimeter, tungsten/boron nitride multilayers for XUV optical applications, the evaluation of reflectors for soft X-ray optics, the manufacture of elastically bent crystals and multilayer mirrors, and selective photodevices for the VUV.

In situ spectroscopic characterization of Ni 1-xZn x/ZnO catalysts and their selectivity for acetylene semihydrogenation in excess ethylene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spanjers, Charles S.; Sim, Richard S.; Sturgis, Nicholas P.

2015-10-30

The structures of ZnO-supported Ni catalysts were explored with in situ X-ray absorption spectroscopy, temperature-programmed reduction, X-ray diffraction, high-resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy, and electron energy loss spectroscopy. Calcination of nickel nitrate on a nanoparticulate ZnO support at 450 °C results in the formation of Zn-doped NiO (ca. N₀̣̣₈₅ Zn₀̣̣₁₅O) nanoparticles with the rock salt crystal structure. Subsequent in situ reduction monitored by X-ray absorption near-edge structure (XANES) at the Ni K edge reveals a direct transformation of the Zn-doped NiO nanoparticles to a face-centered cubic alloy, Ni 1-xZn x, at ~400 °C with x increasingmore » with increasing temperature. Both in situ XANES and ex situ HRTEM provide evidence for intermetallic β₁-NiZn formation at ~550 °C. In comparison to a Ni/SiO₂ catalyst, Ni/ZnO necessitates a higher temperature for the reduction of Ni II to Ni⁰, which highlights the strong interaction between Ni and the ZnO support. The catalytic activity for acetylene removal from an ethylene feed stream is decreased by a factor of 20 on Ni/ZnO in comparison to Ni/SiO₂. The decrease in catalytic activity of Ni/ZnO is accompanied by a reduced absolute selectivity to ethylene. H–D exchange measurements demonstrate a reduced ability of Ni/ZnO to dissociate hydrogen in comparison to Ni/SiO₂.These results of the catalytic experiments suggest that the catalytic properties are controlled, in part, by the zinc oxide support and stress the importance of reporting absolute ethylene selectivity for the catalytic semihydrogenation of acetylene in excess ethylene.« less

High efficient photocatalytic selective oxidation of benzyl alcohol to benzaldehyde by solvothermal-synthesized ZnIn2S4 microspheres under visible light irradiation

NASA Astrophysics Data System (ADS)

Chen, Zhixin; Xu, Jingjing; Ren, Zhuyun; He, Yunhui; Xiao, Guangcan

2013-09-01

Hexagonal ZnIn2S4 samples have been synthesized by a solvothermal method. Their properties have been determined by X-ray diffraction, ultraviolet-visible-light diffuse reflectance spectra, field emission scanning electron microscopy, nitrogen adsorption-desorption and X-ray photoelectron spectra. These results demonstrate that ethanol solvent has significant influence on the morphology, optical and electronic nature for such marigold-like ZnIn2S4 microspheres. The visible light photocatalytic activities of the ZnIn2S4 have been evaluated by selective oxidation of benzyl alcohol to benzaldehyde using molecular oxygen as oxidant. The results show that 100% conversion along with >99% selectivity are reached over ZnIn2S4 prepared in ethanol solvent under visible light irradiation (λ>420 nm) of 2 h, but only 58% conversion and 57% yield are reached over ZnIn2S4 prepared in aqueous solvent. A possible mechanism of the high photocatalytic activity for selective oxidation of benzyl alcohol over ZnIn2S4 is proposed and discussed.

Chandra and ALMA observations of the nuclear activity in two strongly lensed star-forming galaxies

NASA Astrophysics Data System (ADS)

Massardi, M.; Enia, A. F. M.; Negrello, M.; Mancuso, C.; Lapi, A.; Vignali, C.; Gilli, R.; Burkutean, S.; Danese, L.; Zotti, G. De

2018-02-01

Aim. According to coevolutionary scenarios, nuclear activity and star formation play relevant roles in the early stages of galaxy formation. We aim at identifying them in high-redshift galaxies by exploiting high-resolution and high-sensitivity X-ray and millimeter-wavelength data to confirm the presence or absence of star formation and nuclear activity and describe their relative roles in shaping the spectral energy distributions and in contributing to the energy budgets of the galaxies. Methods: We present the data, model, and analysis in the X-ray and millimeter (mm) bands for two strongly lensed galaxies, SDP.9 (HATLAS J090740.0-004200) and SDP.11 (HATLAS J091043.1-000322), which we selected in the Herschel-ATLAS catalogs for their excess emission in the mid-IR regime at redshift ≳1.5. This emission suggests nuclear activity in the early stages of galaxy formation. We observed both of them with Chandra ACIS-S in the X-ray regime and analyzed the high-resolution mm data that are available in the ALMA Science Archive for SDP.9. By combining the information available in mm, optical, and X-ray bands, we reconstructed the source morphology. Results: Both targets were detected in the X-ray, which strongly indicates highly obscured nuclear activity. ALMA observations for SDP.9 for the continuum and CO(6-5) spectral line with high resolution (0.02 arcsec corresponding to 65 pc at the distance of the galaxy) allowed us to estimate the lensed galaxy redshift to a better accuracy than pre-ALMA estimates (1.5753 ± 0.0003) and to model the emission of the optical, millimetric, and X-ray band for this galaxy. We demonstrate that the X-ray emission is generated in the nuclear environment, which strongly supports that this object has nuclear activity. On the basis of the X-ray data, we attempt an estimate of the black hole properties in these galaxies. Conclusions: By taking advantage of the lensing magnification, we identify weak nuclear activity associated with high-z galaxies with high star formation rates. This is useful to extend the investigation of the relationship between star formation and nuclear activity to two intrinsically less luminous high-z star-forming galaxies than was possible so far. Given our results for only two objects, they alone cannot constrain the evolutionary models, but provide us with interesting hints and set an observational path toward addressing the role of star formation and nuclear activity in forming galaxies. The reduced images and data cubes as FITS files are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/610/A53

High levels of absorption in orientation-unbiased, radio-selected 3CR Active Galaxies

NASA Astrophysics Data System (ADS)

Wilkes, Belinda J.; Haas, Martin; Barthel, Peter; Leipski, Christian; Kuraszkiewicz, Joanna; Worrall, Diana; Birkinshaw, Mark; Willner, Steven P.

2014-08-01

A critical problem in understanding active galaxies (AGN) is the separation of intrinsic physical differences from observed differences that are due to orientation. Obscuration of the active nucleus is anisotropic and strongly frequency dependent leading to complex selection effects for observations in most wavebands. These can only be quantified using a sample that is sufficiently unbiased to test orientation effects. Low-frequency radio emission is one way to select a close-to orientation-unbiased sample, albeit limited to the minority of AGN with strong radio emission.Recent Chandra, Spitzer and Herschel observations combined with multi-wavelength data for a complete sample of high-redshift (1 24.2) = 2.5:1.4:1 in these high-luminosity (log L(0.3-8keV) ~ 44-46) sources. These ratios are consistent with current expectations based on modelingthe Cosmic X-ray Background. A strong correlation with radio orientation constrains the geometry of the obscuring disk/torus to have a ~60 degree opening angle and ~12 degree Compton-thick cross-section. The deduced ~50% obscured fraction of the population contrasts with typical estimates of ~20% obscured in optically- and X-ray-selected high-luminosity samples. Once the primary nuclear emission is obscured, AGN X-ray spectra are frequently dominated by unobscured non-nuclear or scattered nuclear emission which cannot be distinguished from direct nuclear emission with a lower obscuration level unless high quality data is available. As a result, both the level of obscuration and the estimated instrinsic luminosities of highly-obscured AGN are likely to be significantly (*10-1000) underestimated for 25-50% of the population. This may explain the lower obscured fractions reported for optical and X-ray samples which have no independent measure of the AGN luminosity. Correcting AGN samples for these underestimated luminosities would result in flatter derived luminosity functions and potentially change their evolution.

High Resolution X-Ray Phase Contrast Imaging with Acoustic Tissue-Selective Contrast Enhancement

DTIC Science & Technology

2005-06-01

Ultrasonics Symp 1319 (1999). 17. Sarvazyan, A. P. Shear Wave Elasticity Imaging: A New Ultrasonic Technology of Medical Diagnostics. Ultrasound in...samples using acoustically modulated X-ray phase contrast imaging. 15. SUBJECT TERMS x-ray, ultrasound, phase contrast, imaging, elastography 16...x-rays, phase contrast imaging is based on phase changes as x-rays traverse a body resulting in wave interference that result in intensity changes in

CHANDRA X-RAY AND HUBBLE SPACE TELESCOPE IMAGING OF OPTICALLY SELECTED KILOPARSEC-SCALE BINARY ACTIVE GALACTIC NUCLEI. II. HOST GALAXY MORPHOLOGY AND AGN ACTIVITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shangguan, Jinyi; Ho, Luis C.; Liu, Xin

Binary active galactic nuclei (AGNs) provide clues to how gas-rich mergers trigger and fuel AGNs and how supermassive black hole (SMBH) pairs evolve in a gas-rich environment. While significant effort has been invested in their identification, the detailed properties of binary AGNs and their host galaxies are still poorly constrained. In a companion paper, we examined the nature of ionizing sources in the double nuclei of four kiloparsec-scale binary AGNs with redshifts between 0.1 and 0.2. Here, we present their host galaxy morphology based on F336W ( U -band) and F105W ( Y -band) images taken by the Wide Fieldmore » Camera 3 on board the Hubble Space Telescope . Our targets have double-peaked narrow emission lines and were confirmed to host binary AGNs with follow-up observations. We find that kiloparsec-scale binary AGNs occur in galaxy mergers with diverse morphological types. There are three major mergers with intermediate morphologies and a minor merger with a dominant disk component. We estimate the masses of the SMBHs from their host bulge stellar masses and obtain Eddington ratios for each AGN. Compared with a representative control sample drawn at the same redshift and stellar mass, the AGN luminosities and Eddington ratios of our binary AGNs are similar to those of single AGNs. The U − Y color maps indicate that clumpy star-forming regions could significantly affect the X-ray detection of binary AGNs, e.g., the hardness ratio. Considering the weak X-ray emission in AGNs triggered in merger systems, we suggest that samples of X-ray-selected AGNs may be biased against gas-rich mergers.« less

Obscured AGN at z ~ 1 from the zCOSMOS-Bright Survey. I. Selection and optical properties of a [Ne v]-selected sample

NASA Astrophysics Data System (ADS)

Mignoli, M.; Vignali, C.; Gilli, R.; Comastri, A.; Zamorani, G.; Bolzonella, M.; Bongiorno, A.; Lamareille, F.; Nair, P.; Pozzetti, L.; Lilly, S. J.; Carollo, C. M.; Contini, T.; Kneib, J.-P.; Le Fèvre, O.; Mainieri, V.; Renzini, A.; Scodeggio, M.; Bardelli, S.; Caputi, K.; Cucciati, O.; de la Torre, S.; de Ravel, L.; Franzetti, P.; Garilli, B.; Iovino, A.; Kampczyk, P.; Knobel, C.; Kovač, K.; Le Borgne, J.-F.; Le Brun, V.; Maier, C.; Pellò, R.; Peng, Y.; Perez Montero, E.; Presotto, V.; Silverman, J. D.; Tanaka, M.; Tasca, L.; Tresse, L.; Vergani, D.; Zucca, E.; Bordoloi, R.; Cappi, A.; Cimatti, A.; Koekemoer, A. M.; McCracken, H. J.; Moresco, M.; Welikala, N.

2013-08-01

Aims: The application of multi-wavelength selection techniques is essential for obtaining a complete and unbiased census of active galactic nuclei (AGN). We present here a method for selecting z ~ 1 obscured AGN from optical spectroscopic surveys. Methods: A sample of 94 narrow-line AGN with 0.65 < z < 1.20 was selected from the 20k-Bright zCOSMOS galaxy sample by detection of the high-ionization [Ne v] λ3426 line. The presence of this emission line in a galaxy spectrum is indicative of nuclear activity, although the selection is biased toward low absorbing column densities on narrow-line region or galactic scales. A similar sample of unobscured (type 1 AGN) was collected applying the same analysis to zCOSMOS broad-line objects. This paper presents and compares the optical spectral properties of the two AGN samples. Taking advantage of the large amount of data available in the COSMOS field, the properties of the [Ne v]-selected type 2 AGN were investigated, focusing on their host galaxies, X-ray emission, and optical line-flux ratios. Finally, a previously developed diagnostic, based on the X-ray-to-[Ne v] luminosity ratio, was exploited to search for the more heavily obscured AGN. Results: We found that [Ne v]-selected narrow-line AGN have Seyfert 2-like optical spectra, although their emission line ratios are diluted by a star-forming component. The ACS morphologies and stellar component in the optical spectra indicate a preference for our type 2 AGN to be hosted in early-type spirals with stellar masses greater than 109.5 - 10 M⊙, on average higher than those of the galaxy parent sample. The fraction of galaxies hosting [Ne v]-selected obscured AGN increases with the stellar mass, reaching a maximum of about 3% at ≈2 × 1011 M⊙. A comparison with other selection techniques at z ~ 1, namely the line-ratio diagnostics and X-ray detections, shows that the detection of the [Ne v] λ3426 line is an effective method for selecting AGN in the optical band, in particular the most heavily obscured ones, but cannot provide a complete census of type 2 AGN by itself. Finally, the high fraction of [Ne v]-selected type 2 AGN not detected in medium-deep (≈100-200 ks) Chandra observations (67%) is suggestive of the inclusion of Compton-thick (i.e., with NH > 1024 cm-2) sources in our sample. The presence of a population of heavily obscured AGN is corroborated by the X-ray-to-[Ne v] ratio; we estimated, by means of an X-ray stacking technique and simulations, that the Compton-thick fraction in our sample of type 2 AGN is 43 ± 4% (statistical errors only), which agrees well with standard assumptions by XRB synthesis models.

The NuSTAR Serendipitous Survey: The 40-month Catalog and the Properties of the Distant High-energy X-Ray Source Population

NASA Astrophysics Data System (ADS)

Lansbury, G. B.; Stern, D.; Aird, J.; Alexander, D. M.; Fuentes, C.; Harrison, F. A.; Treister, E.; Bauer, F. E.; Tomsick, J. A.; Baloković, M.; Del Moro, A.; Gandhi, P.; Ajello, M.; Annuar, A.; Ballantyne, D. R.; Boggs, S. E.; Brandt, W. N.; Brightman, M.; Chen, C.-T. J.; Christensen, F. E.; Civano, F.; Comastri, A.; Craig, W. W.; Forster, K.; Grefenstette, B. W.; Hailey, C. J.; Hickox, R. C.; Jiang, B.; Jun, H. D.; Koss, M.; Marchesi, S.; Melo, A. D.; Mullaney, J. R.; Noirot, G.; Schulze, S.; Walton, D. J.; Zappacosta, L.; Zhang, W. W.

2017-02-01

We present the first full catalog and science results for the Nuclear Spectroscopic Telescope Array (NuSTAR) serendipitous survey. The catalog incorporates data taken during the first 40 months of NuSTAR operation, which provide ≈20 Ms of effective exposure time over 331 fields, with an areal coverage of 13 deg2, and 497 sources detected in total over the 3-24 keV energy range. There are 276 sources with spectroscopic redshifts and classifications, largely resulting from our extensive campaign of ground-based spectroscopic follow-up. We characterize the overall sample in terms of the X-ray, optical, and infrared source properties. The sample is primarily composed of active galactic nuclei (AGNs), detected over a large range in redshift from z = 0.002 to 3.4 (median of < z> =0.56), but also includes 16 spectroscopically confirmed Galactic sources. There is a large range in X-ray flux, from {log}({f}3-24{keV}/{erg} {{{s}}}-1 {{cm}}-2)≈ -14 to -11, and in rest-frame 10-40 keV luminosity, from {log}({L}10-40{keV}/{erg} {{{s}}}-1)≈ 39 to 46, with a median of 44.1. Approximately 79% of the NuSTAR sources have lower-energy (<10 keV) X-ray counterparts from XMM-Newton, Chandra, and Swift XRT. The mid-infrared (MIR) analysis, using WISE all-sky survey data, shows that MIR AGN color selections miss a large fraction of the NuSTAR-selected AGN population, from ≈15% at the highest luminosities ({L}{{X}}> {10}44 erg s-1) to ≈80% at the lowest luminosities ({L}{{X}}< {10}43 erg s-1). Our optical spectroscopic analysis finds that the observed fraction of optically obscured AGNs (I.e., the type 2 fraction) is {F}{Type2}={53}-15+14 % , for a well-defined subset of the 8-24 keV selected sample. This is higher, albeit at a low significance level, than the type 2 fraction measured for redshift- and luminosity-matched AGNs selected by <10 keV X-ray missions.

The HELLAS2XMM survey. XI. Unveiling the nature of X-ray bright optically normal galaxies

NASA Astrophysics Data System (ADS)

Civano, F.; Mignoli, M.; Comastri, A.; Vignali, C.; Fiore, F.; Pozzetti, L.; Brusa, M.; La Franca, F.; Matt, G.; Puccetti, S.; Cocchia, F.

2007-12-01

Aims:X-ray bright optically normal galaxies (XBONGs) constitute a small but significant fraction of hard X-ray selected sources in recent Chandra and XMM-Newton surveys. Even though several possibilities were proposed to explain why a relatively luminous hard X-ray source does not leave any significant signature of its presence in terms of optical emission lines, the nature of XBONGs is still subject of debate. We aim to better understand their nature by means of a multiwavelength and morphological analysis of a small sample of these sources. Methods: Good-quality photometric near-infrared data (ISAAC/VLT) of four low-redshift (z = 0.1{-}0.3) XBONGs, selected from the HELLAS2XMM survey, have been used to search for the presence of the putative nucleus, applying the surface-brightness decomposition technique through the least-squares fitting program GALFIT. Results: The surface brightness decomposition allows us to reveal a nuclear point-like source, likely to be responsible for the X-ray emission, in two out of the four sources. The results indicate that moderate amounts of gas and dust, covering a large solid angle (possibly 4π) at the nuclear source, combined with the low nuclear activity, may explain the lack of optical emission lines. The third XBONG is associated with an X-ray extended source and no nuclear excess is detected in the near infrared at the limits of our observations. The last source is associated to a close (d≤ 1 arcsec) double system and the fitting procedure cannot achieve a firm conclusion. Based on observations made at the European Southern Observatory, Paranal, Chile (ESO Programme ID 69.A-0554).

The Nuclear Spectroscopic Telescope Array (NuSTAR) High-Energy X-ray Mission

NASA Technical Reports Server (NTRS)

Harrison, Fiona A.; Craig, Willliam W.; Christensen, Finn E.; Hailey, Charles J.; Zhang, William W.; Boggs, Steven E.; Stern, Daniel; Cook, W. Rick; Forster, Karl; Giommi, Paolo;

Be/X-ray Binary Science for Future X-ray Timing Missions

NASA Technical Reports Server (NTRS)

Wilson-Hodge, Colleen A.

2011-01-01

For future missions, the Be/X-ray binary community needs to clearly define our science priorities for the future to advocate for their inclusion in future missions. In this talk, I will describe current designs for two potential future missions and Be X-ray binary science enabled by these designs. The Large Observatory For X-ray Timing (LOFT) is an X-ray timing mission selected in February 2011 for the assessment phase from the 2010 ESA M3 call for proposals. The Advanced X-ray Timing ARray (AXTAR) is a NASA explorer concept X-ray timing mission. This talk is intended to initiate discussions of our science priorities for the future.

A Search for Hyperluminous X-Ray Sources in the XMM-Newton Source Catalog

NASA Astrophysics Data System (ADS)

Zolotukhin, I.; Webb, N. A.; Godet, O.; Bachetti, M.; Barret, D.

2016-02-01

We present a new method to identify luminous off-nuclear X-ray sources in the outskirts of galaxies from large public redshift surveys, distinguishing them from foreground and background interlopers. Using the 3XMM-DR5 catalog of X-ray sources and the SDSS DR12 spectroscopic sample of galaxies, with the help of this off-nuclear cross-matching technique, we selected 98 sources with inferred X-ray luminosities in the range 1041 < LX < 1044 erg s-1, compatible with hyperluminous X-ray objects (HLX). To validate the method, we verify that it allowed us to recover known HLX candidates such as ESO 243-49 HLX-1 and M82 X-1. From a statistical study, we conservatively estimate that up to 71 ± 11 of these sources may be foreground- or background sources, statistically leaving at least 16 that are likely to be HLXs, thus providing support for the existence of the HLX population. We identify two good HLX candidates and using other publicly available data sets, in particular the VLA FIRST in radio, UKIRT Infrared Deep Sky Survey in the near-infrared, GALEX in the ultraviolet and Canada-France-Hawaii Telescope Megacam archive in the optical, we present evidence that these objects are unlikely to be foreground or background X-ray objects of conventional types, e.g., active galactic nuclei, BL Lac objects, Galactic X-ray binaries, or nearby stars. However, additional dedicated X-ray and optical observations are needed to confirm their association with the assumed host galaxies and thus secure their HLX classification.

Variable magnification glancing incidence x ray telescope

NASA Technical Reports Server (NTRS)

Hoover, Richard (Inventor)

1990-01-01

A multispectral glancing incidence x ray telescope is disclosed, which capable of broadband, high resolution imaging of solar and stellar x ray and extreme ultraviolet radiation sources includes a primary optical system which focuses the incoming radiation to a primary focus. Two or more ellipsoidal mirrors are positioned behind the primary focus at an inclination to the optical axis, each mirror having a concave surface coated with a multilayer synthetic microstructure coating to reflect a desired wavelength. The ellipsoidal mirrors are segments of respective ellipsoids having a common first focus coincident with the primary focus. A detector such as an x ray sensitive photographic film is positioned at the second focus of each of the ellipsoids so that each of the ellipsoidal mirrors may reflect the image at the first focus to the detector. In one embodiment the mirrors are inclined at different angles and has its respective second focus at a different location, separate detectors being located at the respective second focus. The mirrors are arranged so that the magnification and field of view differ, and a solenoid activated arm may withdraw at least one mirror from the beam to select the mirror upon which the beam is to impinge so that selected magnifications and fields of view may be detected.

The X-CLASS-redMaPPer galaxy cluster comparison. I. Identification procedures

NASA Astrophysics Data System (ADS)

Sadibekova, T.; Pierre, M.; Clerc, N.; Faccioli, L.; Gastaud, R.; Le Fevre, J.-P.; Rozo, E.; Rykoff, E.

2014-11-01

Context. This paper is the first in a series undertaking a comprehensive correlation analysis between optically selected and X-ray-selected cluster catalogues. The rationale of the project is to develop a holistic picture of galaxy clusters utilising optical and X-ray-cluster-selected catalogues with well-understood selection functions. Aims: Unlike most of the X-ray/optical cluster correlations to date, the present paper focuses on the non-matching objects in either waveband. We investigate how the differences observed between the optical and X-ray catalogues may stem from (1) a shortcoming of the detection algorithms; (2) dispersion in the X-ray/optical scaling relations; or (3) substantial intrinsic differences between the cluster populations probed in the X-ray and optical bands. The aim is to inventory and elucidate these effects in order to account for selection biases in the further determination of X-ray/optical cluster scaling relations. Methods: We correlated the X-CLASS serendipitous cluster catalogue extracted from the XMM archive with the redMaPPer optical cluster catalogue derived from the Sloan Digital Sky Survey (DR8). We performed a detailed and, in large part, interactive analysis of the matching output from the correlation. The overlap between the two catalogues has been accurately determined and possible cluster positional errors were manually recovered. The final samples comprise 270 and 355 redMaPPer and X-CLASS clusters, respectively. X-ray cluster matching rates were analysed as a function of optical richness. In the second step, the redMaPPer clusters were correlated with the entire X-ray catalogue, containing point and uncharacterised sources (down to a few 10-15 erg s-1 cm-2 in the [0.5-2] keV band). A stacking analysis was performed for the remaining undetected optical clusters. Results: We find that all rich (λ ≥ 80) clusters are detected in X-rays out to z = 0.6. Below this redshift, the richness threshold for X-ray detection steadily decreases with redshift. Likewise, all X-ray bright clusters are detected by redMaPPer. After correcting for obvious pipeline shortcomings (about 10% of the cases both in optical and X-ray), ~50% of the redMaPPer (down to a richness of 20) are found to coincide with an X-CLASS cluster; when considering X-ray sources of any type, this fraction increases to ~80%; for the remaining objects, the stacking analysis finds a weak signal within 0.5 Mpc around the cluster optical centres. The fraction of clusters totally dominated by AGN-type emission appears to be a few percent. Conversely, ~40% of the X-CLASS clusters are identified with a redMaPPer (down to a richness of 20) - part of the non-matches being due to the X-CLASS sample extending further out than redMaPPer (z< 1.5 vs. z< 0.6), but extending the correlation down to a richness of 5 raises the matching rate to ~65%. Conclusions: This state-of-the-art study involving two well-validated cluster catalogues has shown itself to be complex, and it points to a number of issues inherent to blind cross-matching, owing both to pipeline shortcomings and cluster peculiar properties. These can only been accounted for after a manual check. The combined X-ray and optical scaling relations will be presented in a subsequent article.

In vivo demonstration of enhanced radiotherapy using rare earth doped titania nanoparticles.

PubMed

Townley, Helen E; Kim, Jeewon; Dobson, Peter J

2012-08-21

Radiation therapy is often limited by damage to healthy tissue and associated side-effects; restricting radiation to ineffective doses. Preferential incorporation of materials into tumour tissue can enhance the effect of radiation. Titania has precedent for use in photodynamic therapy (PDT), generating reactive oxygen species (ROS) upon photoexcitation, but is limited by the penetration depth of UV light. Optimization of a nanomaterial for interaction with X-rays could be used for deep tumour treatment. As such, titania nanoparticles were doped with gadolinium to optimize the localized energy absorption from a conventional medical X-ray, and further optimized by the addition of other rare earth (RE) elements. These elements were selected due to their large X-ray photon interaction cross-section, and potential for integration into the titania crystal structure. Specific activation of the nanoparticles by X-ray can result in generation of ROS leading to cell death in a tumour-localized manner. We show here that intratumoural injection of RE doped titania nanoparticles can enhance the efficacy of radiotherapy in vivo.

Active galactic nuclei as cosmological probes.

NASA Astrophysics Data System (ADS)

Lusso, Elisabeta; Risaliti, Guido

2018-01-01

I will present the latest results on our analysis of the non-linear X-ray to UV relation in a sample of optically selected quasars from the Sloan Digital Sky Survey, cross-matched with the most recent XMM-Newton and Chandra catalogues. I will show that this correlation is not only very tight, but can be potentially even tighter by including a further dependence on the emission line full-width half maximum. This result imply that the non-linear X-ray to optical-ultraviolet luminosity relation is the manifestation of an ubiquitous physical mechanism, whose details are still unknown, that regulates the energy transfer from the accretion disc to the X-ray emitting corona in quasars. I will discuss what the perspectives of AGN in the context of observational cosmology are. I will introduce a novel technique to test the cosmological model using quasars as “standard candles” by employing the non-linear X-ray to UV relation as an absolute distance indicator.

Searching for New γ-Ray Blazar Candidates in the Third Palermo BAT Hard X-Ray Catalog with WISE

NASA Astrophysics Data System (ADS)

Maselli, A.; Massaro, F.; Cusumano, G.; D'Abrusco, R.; La Parola, V.; Paggi, A.; Segreto, A.; Smith, Howard A.; Tosti, G.

2013-06-01

We searched for γ-ray blazar candidates among the 382 unidentified hard X-ray sources of the third Palermo BAT Catalog (3PBC) obtained from the analysis of 66 months of Swift Burst Alert Telescope (BAT) survey data and listing 1586 sources. We adopted a recently developed association method based on the peculiar infrared colors that characterize the γ-ray blazars included in the second catalog of active galactic nuclei detected by the Fermi Large Area Telescope. We used this method exploiting the data of the all-sky survey performed by the Wide-field Infrared Survey Explorer (WISE) to establish correspondences between unidentified 3PBC sources and WISE γ-ray blazar candidates located within the BAT positional uncertainty region at a 99% confidence level. We obtained a preliminary list of candidates for which we analyzed all the available data in the Swift archive to complement the information in the literature and in the radio, infrared, and optical catalogs with the information on their optical-UV and soft X-ray emission. Requiring the presence of radio and soft X-ray counterparts consistent with the infrared positions of the selected WISE sources, as well as a blazar-like radio morphology, we finally obtained a list of 24 γ-ray blazar candidates.

High-z X-ray Obscured Quasars in Galaxies with Extreme Mid-IR/Optical Colors

NASA Astrophysics Data System (ADS)

Piconcelli, E.; Lanzuisi, G.; Fiore, F.; Feruglio, C.; Vignali, C.; Salvato, M.; Grappioni, C.

2009-05-01

Extreme Optical/Mid-IR color cuts have been used to uncover a population of dust-enshrouded, mid-IR luminous galaxies at high redshifts. Several lines of evidence point towards the presence of an heavily absorbed, possibly Compton-thick quasar at the heart of these systems. Nonetheless, the X-ray spectral properties of these intriguing sources still remain largely unexplored. Here we present an X-ray spectroscopic study of a large sample of 44 extreme dust-obscured galaxies (EDOGs) with F24 μm/FR>2000 and F24 μm>1.3 mJy selected from a 6 deg2 region in the SWIRE fields. The application of our selection criteria to a wide area survey has been capable of unveiling a population of X-ray luminous, absorbed z>1 quasars which is mostly missed in the traditional optical/X-ray surveys performed so far. Advances in the understanding of the X-ray properties of these recently-discovered sources by Simbol-X observations will be also discussed.

Element Selectivity in Second-Harmonic Generation of GaFeO3 by a Soft-X-Ray Free-Electron Laser

NASA Astrophysics Data System (ADS)

Yamamoto, Sh.; Omi, T.; Akai, H.; Kubota, Y.; Takahashi, Y.; Suzuki, Y.; Hirata, Y.; Yamamoto, K.; Yukawa, R.; Horiba, K.; Yumoto, H.; Koyama, T.; Ohashi, H.; Owada, S.; Tono, K.; Yabashi, M.; Shigemasa, E.; Yamamoto, S.; Kotsugi, M.; Wadati, H.; Kumigashira, H.; Arima, T.; Shin, S.; Matsuda, I.

2018-06-01

Nonlinear optical frequency conversion has been challenged to move down to the extreme ultraviolet and x-ray region. However, the extremely low signals have allowed researchers to only perform transmission experiments of the gas phase or ultrathin films. Here, we report second harmonic generation (SHG) of the reflected beam of a soft x-ray free-electron laser from a solid, which is enhanced by the resonant effect. The observation revealed that the double resonance condition can be met by absorption edges for transition metal oxides in the soft x-ray range, and this suggests that the resonant SHG technique can be applicable to a wide range of materials. We discuss the possibility of element-selective SHG spectroscopy measurements in the soft x-ray range.

Direct measurement of 235U in spent fuel rods with Gamma-ray mirrors

NASA Astrophysics Data System (ADS)

Ruz, J.; Brejnholt, N. F.; Alameda, J. B.; Decker, T. A.; Descalle, M. A.; Fernandez-Perea, M.; Hill, R. M.; Kisner, R. A.; Melin, A. M.; Patton, B. W.; Soufli, R.; Ziock, K.; Pivovaroff, M. J.

2015-03-01

Direct measurement of plutonium and uranium X-rays and gamma-rays is a highly desirable non-destructive analysis method for the use in reprocessing fuel environments. The high background and intense radiation from spent fuel make direct measurements difficult to implement since the relatively low activity of uranium and plutonium is masked by the high activity from fission products. To overcome this problem, we make use of a grazing incidence optic to selectively reflect Kα and Kβ fluorescence of Special Nuclear Materials (SNM) into a high-purity position-sensitive germanium detector and obtain their relative ratios.

Monitoring X-Ray Emission from X-Ray Bursters

NASA Technical Reports Server (NTRS)

Halpern, Jules P.; Kaaret, Philip

1999-01-01

The scientific goal of this project was to monitor a selected sample of x-ray bursters using data from the All-Sky Monitor (ASM) on the Rossi X-Ray Timing Explorer together with data from the Burst and Transient Source Experiment (BATSE) on the Compton Gamma-Ray Observatory to study the long-term temporal evolution of these sources in the x-ray and hard x-ray bands. The project was closely related to "Long-Term Hard X-Ray Monitoring of X-Ray Bursters", NASA project NAG5-3891, and and "Hard x-ray emission of x-ray bursters", NASA project NAG5-4633, and shares publications in common with both of these. The project involved preparation of software for use in monitoring and then the actual monitoring itself. These efforts have lead to results directly from the ASM data and also from Target of Opportunity Observations (TOO) made with the Rossi X-Ray Timing Explorer based on detection of transient hard x-ray outbursts with the ASM and BATSE.

THE XMM-NEWTON WIDE FIELD SURVEY IN THE COSMOS FIELD: REDSHIFT EVOLUTION OF AGN BIAS AND SUBDOMINANT ROLE OF MERGERS IN TRIGGERING MODERATE-LUMINOSITY AGNs AT REDSHIFTS UP TO 2.2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allevato, V.; Hasinger, G.; Salvato, M.

2011-08-01

We present a study of the redshift evolution of the projected correlation function of 593 X-ray selected active galactic nuclei (AGNs) with I{sub AB} < 23 and spectroscopic redshifts z < 4, extracted from the 0.5-2 keV X-ray mosaic of the 2.13 deg{sup 2} XMM- Cosmic Evolution Survey (COSMOS). We introduce a method to estimate the average bias of the AGN sample and the mass of AGN hosting halos, solving the sample variance using the halo model and taking into account the growth of the structure over time. We find evidence of a redshift evolution of the bias factor formore » the total population of XMM-COSMOS AGNs from b-bar (z-bar =0.92)=2.30{+-}0.11 to b-bar (z-bar =1.94)=4.37{+-}0.27 with an average mass of the hosting dark matter (DM) halos log M{sub 0}(h{sup -1} M{sub sun}) {approx} 13.12 {+-} 0.12 that remains constant at all z < 2. Splitting our sample into broad optical line AGNs (BL), AGNs without broad optical lines (NL), and X-ray unobscured and obscured AGNs, we observe an increase of the bias with redshift in the range z-bar = 0.7-2.25 and z-bar = 0.6-1.5 which corresponds to a constant halo mass of log M{sub 0}(h{sup -1} M{sub sun}) {approx} 13.28 {+-} 0.07 and log M{sub 0}(h{sup -1} M{sub sun}) {approx} 13.00 {+-} 0.06 for BL/X-ray unobscured AGNs and NL/X-ray obscured AGNs, respectively. The theoretical models, which assume a quasar phase triggered by major mergers, cannot reproduce the high bias factors and DM halo masses found for X-ray selected BL AGNs with L{sub BOL} {approx} 2 x 10{sup 45} erg s{sup -1}. Our work extends up to z {approx} 2.2 the z {approx}< 1 statement that, for moderate-luminosity X-ray selected BL AGNs, the contribution from major mergers is outnumbered by other processes, possibly secular ones such as tidal disruptions or disk instabilities.« less

Chandra-SDSS Normal and Star-Forming Galaxies. I. X-Ray Source Properties of Galaxies Detected by the Chandra X-Ray Observatory in SDSS DR2

NASA Astrophysics Data System (ADS)

Hornschemeier, A. E.; Heckman, T. M.; Ptak, A. F.; Tremonti, C. A.; Colbert, E. J. M.

2005-01-01

We have cross-correlated X-ray catalogs derived from archival Chandra X-Ray Observatory ACIS observations with a Sloan Digital Sky Survey Data Release 2 (DR2) galaxy catalog to form a sample of 42 serendipitously X-ray-detected galaxies over the redshift interval 0.03

X-ray Spectrometry.

ERIC Educational Resources Information Center

Markowicz, Andrzej A.; Van Grieken, Rene E.

1984-01-01

Provided is a selective literature survey of X-ray spectrometry from late 1981 to late 1983. Literature examined focuses on: excitation (photon and electron excitation and particle-induced X-ray emission; detection (wavelength-dispersive and energy-dispersive spectrometry); instrumentation and techniques; and on such quantitative analytical…

Starburst Galaxies: Hard X-ray spectra and contribution to the diffuse background

NASA Technical Reports Server (NTRS)

Gruber, Duane E.

1993-01-01

During the period of this grant two main tasks were performed: a determination of a selection criterion for starburst galaxies most likely to emit X-rays, and performance of a pilot study of the X-ray emission from nine such systems. Starburst galaxies may be expected to emit flat-spectrum X-ray at energies above 10 keV resulting from the various remnants of the short-lived massive stars which characterize the starburst. The investigation to determine the optimum sample resulted in a change from an X-ray selected (HEAO-2) sample to infrared selection based on the IRAS catalogue. A much broader sample thereby available for study, and selection could be limited to only the nearest objects and still obtain a reasonably large sample. A sample of 99 of the brightest infrared starburst galaxies was settled on for the X-ray survey. For a set of practical size, this was then reduced to a subset of 53, based on luminosity and nearness. X-ray emission from these objects was individually measured from the UCSD HEAO-1 all-sky survey in four energy bands between 13 keV to 160 keV. This data base consists of about 20 optical disk volumes. Net significance for the result was roughly two sigma, and a very hard spectral shape is indicated for the net spectrum of the surveyed galaxies. With the possibility of detection of the class, it was then felt worthwhile to examine fluxes from these sources in other archival data. This was performed with the HEAO-1 A2 data and the HEAO-2 (EINSTEIN) main archive and slew survey. Positive results were also obtained for the sample, but again at weak significance. With three independent measures of weak X-ray fluxes from nearby starburst galaxies, we wrote a letter to the Astrophysical Journal (enclosed) discussing these results and their likely significance, in particular, for the contribution to the cosmic diffuse x-ray background, perhaps as much as 25 percent.

Highly Efficient Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over Gold Supported on Zinc Oxide Materials

DOE PAGES

Chen, Hangning; Cullen, David A.; Larese, J. Z.

2015-11-30

We used Au/ZnO catalysts for liquid-phase selective hydrogenation of cinnamaldehyde to cinnamyl alcohol and compared with Au/Fe 2O 3 catalysts. To investigate the influence of the support on the hydrogenation activity and selectivity, three different Au/ZnO catalysts were synthesized, including Au/rod-tetrapod ZnO, Au/porous ZnO, and Au/ZnO-CP prepared using a coprecipitation method. Moreover, the influence of calcination temperature was also systematically investigated in this study. The characterization of Au/ZnO catalysts was performed using ICP, N 2 adsorption/desorption isotherms, X-ray diffraction, scanning transmission electron microscopy, and X-ray photoelectron spectroscopy. Among all the supported Au catalysts prepared in this study, Au/ZnO-CP exhibits bothmore » the highest hydrogenation activity and selectivity. Using a 1.5% Au/ZnO-CP catalyst, 100% selectivity could be achieved with 94.9% conversion. Finally, we find that the Au particle (size and shape), the ZnO support (size and surface texture) and the interaction between Au and ZnO are three important parameters for achieving a highly efficient Au/ZnO catalyst.« less

BEaTriX, expanded x-ray beam facility for testing modular elements of telescope optics: an update

NASA Astrophysics Data System (ADS)

Pelliciari, C.; Spiga, D.; Bonnini, E.; Buffagni, E.; Ferrari, C.; Pareschi, G.; Tagliaferri, G.

2015-09-01

We present in this paper an update on the design of BEaTriX (Beam Expander Testing X-ray facility), an X-ray apparatus to be realized at INAF/OAB and that will generate an expanded, uniform and parallel beam of soft X-rays. BEaTriX will be used to perform the functional tests of X-ray focusing modules of large X-ray optics such as those for the ATHENA X-ray observatory, using the Silicon Pore Optics (SPO) as a baseline technology, and Slumped Glass Optics (SGO) as a possible alternative. Performing the tests in X-rays provides the advantage of an in-situ, at-wavelength quality control of the optical modules produced in series by the industry, performing a selection of the modules with the best angular resolution, and, in the case of SPOs, there is also the interesting possibility to align the parabolic and the hyperbolic stacks directly under X-rays, to minimize the aberrations. However, a parallel beam with divergence below 2 arcsec is necessary in order to measure mirror elements that are expected to reach an angular resolution of about 4 arcsec, since the ATHENA requirement for the entire telescope is 5 arcsec. Such a low divergence over the typical aperture of modular optics would require an X-ray source to be located in a several kilometers long vacuum tube. In contrast, BEaTriX will be compact enough (5 m x 14 m) to be housed in a small laboratory, will produce an expanded X-ray beam 60 mm x 200 mm broad, characterized by a very low divergence (1.5 arcsec HEW), strong polarization, high uniformity, and X-ray energy selectable between 1.5 keV and 4.5 keV. In this work we describe the BEaTriX layout and show a performance simulation for the X-ray energy of 4.5 keV.

Apollo 15 X-ray fluorescence experiment

NASA Technical Reports Server (NTRS)

Adler, I.; Trombka, J.; Gerard, J.; Schmadebeck, R.; Lowman, P.; Blodgett, H.; Yin, L.; Eller, E.; Lamothe, R.; Gorenstein, P.

1971-01-01

The X-ray fluorescence spectrometer, carried in the SIM bay of the command service module was employed principally for compositional mapping of the lunar surface while in lunar orbit, and secondarily, for X-ray astronomical observations during the trans-earth coast. The lunar surface measurements involved observations of the intensity and characteristics energy distribution of the secondary or fluorescent X-rays produced by the interaction of solar X-rays with the lunar surface. The astronomical observations consisted of relatively long periods of measurements of X-rays from pre-selected galactic sources such as Cyg-X-1 and Sco X-1 as well as from the galactic poles.

Study on the influence of X-ray tube spectral distribution on the analysis of bulk samples and thin films: Fundamental parameters method and theoretical coefficient algorithms

NASA Astrophysics Data System (ADS)

Sitko, Rafał

2008-11-01

Knowledge of X-ray tube spectral distribution is necessary in theoretical methods of matrix correction, i.e. in both fundamental parameter (FP) methods and theoretical influence coefficient algorithms. Thus, the influence of X-ray tube distribution on the accuracy of the analysis of thin films and bulk samples is presented. The calculations are performed using experimental X-ray tube spectra taken from the literature and theoretical X-ray tube spectra evaluated by three different algorithms proposed by Pella et al. (X-Ray Spectrom. 14 (1985) 125-135), Ebel (X-Ray Spectrom. 28 (1999) 255-266), and Finkelshtein and Pavlova (X-Ray Spectrom. 28 (1999) 27-32). In this study, Fe-Cr-Ni system is selected as an example and the calculations are performed for X-ray tubes commonly applied in X-ray fluorescence analysis (XRF), i.e., Cr, Mo, Rh and W. The influence of X-ray tube spectra on FP analysis is evaluated when quantification is performed using various types of calibration samples. FP analysis of bulk samples is performed using pure-element bulk standards and multielement bulk standards similar to the analyzed material, whereas for FP analysis of thin films, the bulk and thin pure-element standards are used. For the evaluation of the influence of X-ray tube spectra on XRF analysis performed by theoretical influence coefficient methods, two algorithms for bulk samples are selected, i.e. Claisse-Quintin (Can. Spectrosc. 12 (1967) 129-134) and COLA algorithms (G.R. Lachance, Paper Presented at the International Conference on Industrial Inorganic Elemental Analysis, Metz, France, June 3, 1981) and two algorithms (constant and linear coefficients) for thin films recently proposed by Sitko (X-Ray Spectrom. 37 (2008) 265-272).

GSFC Contributions to the NATO X-ray Astronomy Institute, Erice, July 1979. [X-ray spectra of supernova remants, galactic X-ray sources, active galactic nuclei, and clusters of galaxies

NASA Technical Reports Server (NTRS)

Holt, S. S.; Mushotzky, R. F.

1979-01-01

An overview of X-ray astronomical spectroscopy in general is presented and results obtained by HEAO 1 and 2 as well as earlier spacecraft are examined. Particular emphasis is given to the spectra of supernova remnants; galactic binary X-ray sources, cataclysmic variables, bulges, pulsars, and stars; the active nuclei of Seyfert 1 galaxy, BL Lac, and quasars; the diffuse X-ray background; and galactic clusters.

Unveiling the physics of AGN through X-ray variability

NASA Astrophysics Data System (ADS)

Hernández-García, L.; González-Martín, O.; Masegosa, J.; Márquez, I.

2017-03-01

Although variability is a general property characterizing active galactic nuclei (AGN), it is not well established whether the changes occur in the same way in every nuclei. The main purpose of this work is to study the X-ray variability pattern(s) in AGN selected at optical wavelengths in a large sample, including low ionization nuclear emission line regions (LINERs) and type 1.8, 1.9, and 2 Seyferts, using the public archives in Chandra and/or XMM-Newton. Spectra of the same source gathered at different epochs were simultaneously fitted to study long term variations; the variability patterns were studied allowing different parameters to vary during the spectral fit. Whenever possible, short term variations from the analysis of the light curves and long term UV flux variability were studied. Variations at X-rays in timescales of months/years are very common in all AGN families but short term variations are only found in type 1.8 and 1.9 Seyferts. The main driver of the long term X-ray variations seems to be related to changes in the nuclear power. Other variability patterns cannot be discarded in a few cases. We discuss the geometry and physics of AGN through the X-ray variability analysis.

X-ray Fluorescence Holography: Principles, Apparatus, and Applications

NASA Astrophysics Data System (ADS)

Hayashi, Kouichi; Korecki, Pawel

2018-06-01

X-ray fluorescence holography (XFH) is an atomic structure determination technique that combines the capabilities of X-ray diffraction and X-ray fluorescence spectroscopy. It provides a unique means of gaining fully three-dimensional information about the local atomic structure and lattice site positions of selected elements inside compound samples. In this work, we discuss experimental and theoretical aspects that are essential for the efficient recording and analysis of X-ray fluorescence holograms and review the most recent advances in XFH. We describe experiments performed with brilliant synchrotron radiation as well as with tabletop setups that employ conventional X-ray tubes.

Toward Active X-ray Telescopes II

NASA Technical Reports Server (NTRS)

O'Dell, Stephen L.; Aldroft, Thomas L.; Atkins, Carolyn; Button, Timothy W.; Cotroneo, Vincenzo; Davis, William N.; Doel, Peter; Feldman, Charlotte H.; Freeman, Mark D.; Gubarev, Mikhail V.;

Early evolution of an X-ray emitting solar active region

NASA Technical Reports Server (NTRS)

Wolfson, C. J.; Acton, L. W.; Leibacher, J. W.; Roethig, D. T.

1977-01-01

The birth and early evolution of a solar active region has been investigated using X-ray observations from the mapping X-ray heliometer on board the OSO-8 spacecraft. X-ray emission is observed within three hours of the first detection of H-alpha plage. At that time, a plasma temperature of four million K in a region having a density on the order of 10 to the 10th power per cu cm is inferred. During the fifty hours following birth almost continuous flares or flare-like X-ray bursts are superimposed on a monotonically increasing base level of X-ray emission produced by the plasma. If the X-rays are assumed to result from heating due to dissipation of current systems or magnetic field reconnection, it may be concluded that flare-like X-ray emission soon after active region birth implies that the magnetic field probably emerges in a stressed or complex configuration.

Atomically Precise Growth of Catalytically Active Cobalt Sulfide on Flat Surfaces and within a Metal–Organic Framework via Atomic Layer Deposition

DOE PAGES

Peters, Aaron W.; Li, Zhanyong; Farha, Omar K.; ...

2015-08-04

Atomic layer deposition (ALD) has been employed as a new synthetic route to thin films of cobalt sulfide on silicon and fluorine-doped tin oxide platforms. The self-limiting nature of the stepwise synthesis is established through growth rate studies at different pulse times and temperatures. Additionally, characterization of the materials by X-ray diffraction and X-ray photoelectron spectroscopy indicates that the crystalline phase of these films has the composition Co 9S 8. The nodes of the metal–organic framework (MOF) NU-1000 were then selectively functionalized with cobalt sulfide via ALD in MOFs (AIM). Spectroscopic techniques confirm uniform deposition of cobalt sulfide throughout themore » crystallites, with no loss in crystallinity or porosity. The resulting material, CoS-AIM, is catalytically active for selective hydrogenation of m-nitrophenol to m-aminophenol, and outperforms the analogous oxide AIM material (CoO-AIM) as well as an amorphous CoS x reference material. Here, these results reveal AIM to be an effective method of incorporating high surface area and catalytically active cobalt sulfide in metal–organic frameworks.« less

Mini Survey of SDSS [OIII] AGN with Swift: Testing the Hypothesis that L(sub [OIII]) Traces AGN Luminosity

NASA Technical Reports Server (NTRS)

2007-01-01

The number of AGN and their luminosity distribution are crucial parameters for our understanding of the AGN phenomenon. Recent work strongly suggests every massive galaxy has a central black hole. However most of these objects either are not radiating or have been very difficult to detect We are now in the era of large surveys, and the luminosity function (LF] of AGN has been estimated in various ways. In the X-ray band. Chandra and XMM surveys have revealed that the LF of hard X-ray selected AGN shows a strong luminosity-dependent evolution with a dramatic break towards low L(sub x) (at all z). This is seen for all types of AGN, but is stronger for the broad-line objects. In sharp contrast, the local LF of optically-selected samples shows no such break and no differences between narrow and broad-line objects. If as been suggested, hard X ray and optical emission line can both can be fair indicators of AGN activity, it is important to first understand how reliable these characteristics are if we hope to understand the apparent discrepancy in the LFs.

Support effects in catalysis studied by in-situ sum frequency generation vibrational spectroscopy and in-situ x-ray spectroscopies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kennedy, Griffin John

Here, kinetic measurements are paired with in-situ spectroscopic characterization tools to investigate colloidally based, supported Pt catalytic model systems in order to elucidate the mechanisms by which metal and support work in tandem to dictate activity and selectivity. The results demonstrate oxide support materials, while inactive in absence of Pt nanoparticles, possess unique active sites for the selective conversion of gas phase molecules when paired with an active metal catalyst.

Extreme ultraviolet and X-ray spectroheliograph for OSO-H

NASA Technical Reports Server (NTRS)

Sterk, A. A.; Kieser, F.; Peck, S.; Knox, E.

1972-01-01

A complex scientific instrument was designed, fabricated, tested, and calibrated for launch onboard OSO-H. This instrument consisted of four spectroheliographs and an X-ray polarimeter. The instrument is designed to study solar radiation at selected wavelengths in the X-ray and the extreme ultraviolet ranges, make observations at the H-alpha wavelength, and measure the degree of polarization of X-ray emissions.

SPIDERS: the spectroscopic follow-up of X-ray-selected clusters of galaxies in SDSS-IV

DOE PAGES

Clerc, N.; Merloni, A.; Zhang, Y. -Y.; ...

2016-09-05

SPIDERS (The SPectroscopic IDentification of ERosita Sources) is a programme dedicated to the homogeneous and complete spectroscopic follow-up of X-ray active galactic nuclei and galaxy clusters over a large area (~7500 deg 2) of the extragalactic sky. SPIDERS is part of the Sloan Digital Sky Survey (SDSS)-IV project, together with the Extended Baryon Oscillation Spectroscopic Survey and the Time-Domain Spectroscopic Survey. This study describes the largest project within SPIDERS before the launch of eROSITA: an optical spectroscopic survey of X-ray-selected, massive (~10 14–10 15 M⊙) galaxy clusters discovered in ROSAT and XMM–Newton imaging. The immediate aim is to determine precisemore » (Δz ~ 0.001) redshifts for 4000–5000 of these systems out to z ~ 0.6. The scientific goal of the program is precision cosmology, using clusters as probes of large-scale structure in the expanding Universe. We present the cluster samples, target selection algorithms and observation strategies. We demonstrate the efficiency of selecting targets using a combination of SDSS imaging data, a robust red-sequence finder and a dedicated prioritization scheme. We describe a set of algorithms and work-flow developed to collate spectra and assign cluster membership, and to deliver catalogues of spectroscopically confirmed clusters. We discuss the relevance of line-of-sight velocity dispersion estimators for the richer systems. We illustrate our techniques by constructing a catalogue of 230 spectroscopically validated clusters (0.031 < z < 0.658), found in pilot observations. Finally, we discuss two potential science applications of the SPIDERS sample: the study of the X-ray luminosity-velocity dispersion (LX–σ) relation and the building of stacked phase-space diagrams.« less

SPIDERS: the spectroscopic follow-up of X-ray selected clusters of galaxies in SDSS-IV

NASA Astrophysics Data System (ADS)

Clerc, N.; Merloni, A.; Zhang, Y.-Y.; Finoguenov, A.; Dwelly, T.; Nandra, K.; Collins, C.; Dawson, K.; Kneib, J.-P.; Rozo, E.; Rykoff, E.; Sadibekova, T.; Brownstein, J.; Lin, Y.-T.; Ridl, J.; Salvato, M.; Schwope, A.; Steinmetz, M.; Seo, H.-J.; Tinker, J.

2016-12-01

SPIDERS (The SPectroscopic IDentification of eROSITA Sources) is a programme dedicated to the homogeneous and complete spectroscopic follow-up of X-ray active galactic nuclei and galaxy clusters over a large area (˜7500 deg2) of the extragalactic sky. SPIDERS is part of the Sloan Digital Sky Survey (SDSS)-IV project, together with the Extended Baryon Oscillation Spectroscopic Survey and the Time-Domain Spectroscopic Survey. This paper describes the largest project within SPIDERS before the launch of eROSITA: an optical spectroscopic survey of X-ray-selected, massive (˜1014-1015 M⊙) galaxy clusters discovered in ROSAT and XMM-Newton imaging. The immediate aim is to determine precise (Δz ˜ 0.001) redshifts for 4000-5000 of these systems out to z ˜ 0.6. The scientific goal of the program is precision cosmology, using clusters as probes of large-scale structure in the expanding Universe. We present the cluster samples, target selection algorithms and observation strategies. We demonstrate the efficiency of selecting targets using a combination of SDSS imaging data, a robust red-sequence finder and a dedicated prioritization scheme. We describe a set of algorithms and work-flow developed to collate spectra and assign cluster membership, and to deliver catalogues of spectroscopically confirmed clusters. We discuss the relevance of line-of-sight velocity dispersion estimators for the richer systems. We illustrate our techniques by constructing a catalogue of 230 spectroscopically validated clusters (0.031 < z < 0.658), found in pilot observations. We discuss two potential science applications of the SPIDERS sample: the study of the X-ray luminosity-velocity dispersion (LX-σ) relation and the building of stacked phase-space diagrams.

The mm-wave compact component of an AGN

NASA Astrophysics Data System (ADS)

Behar, Ehud; Vogel, Stuart; Baldi, Ranieri D.; Smith, Krista L.; Mushotzky, Richard F.

2018-07-01

mm-wave emission from active galactic nuclei (AGNs) may hold the key to understanding the physical origin of their radio cores. The correlation between radio/mm and X-ray luminosity may suggest a similar physical origin of the two sources. Since synchrotron self-absorption decreases with frequency, mm-waves probe smaller length-scales than cm-waves. We report on 100 GHz (3 mm) observations with the Combined Array for Research in Millimeter-wave Astronomy of 26 AGNs selected from the hard X-ray Swift/Burst Alert Telescope survey. 20/26 targets were detected at 100 GHz down to the 1 mJy (3σ) sensitivity, which corresponds to optically thick synchrotron source sizes of 10-4-10-3 pc. Most sources show a 100 GHz flux excess with respect to the spectral slope extrapolated from low frequencies. This mm spectral component likely originates from smaller scales than the few-GHz emission. The measured mm sources lie roughly around the Lmm (100 GHz) ˜10-4LX (2-10 keV) relation, similar to a few previously published X-ray selected sources, and hinting perhaps at a common coronal origin.

The mm-wave compact component of AGN

NASA Astrophysics Data System (ADS)

Behar, Ehud; Vogel, Stuart; Baldi, Ranieri D.; Smith, Krista L.; Mushotzky, Richard F.

2018-05-01

mm-wave emission from Active Galactic Nuclei (AGN) may hold the key to understanding the physical origin of their radio cores. The correlation between radio/mm and X-ray luminosity may suggest a similar physical origin of the two sources. Since synchrotron self absorption decreases with frequency, mm-waves probe smaller length scales than cm-waves. We report on 100 GHz (3 mm) observations with CARMA of 26 AGNs selected from the hard X-ray Swift/BAT survey. 20/26 targets were detected at 100 GHz down to the 1 mJy (3σ) sensitivity, which corresponds to optically thick synchrotron source sizes of 10-4 - 10-3 pc. Most sources show a 100 GHz flux excess with respect to the spectral slope extrapolated from low frequencies. This mm spectral component likely originates from smaller scales than the few-GHz emission. The measured mm sources lie roughly around the Lmm (100 GHz) ˜10-4LX (2-10 keV) relation, similar to a few previously published X-ray selected sources, and hinting perhaps at a common coronal origin.

In situ hydrogenation and decarboxylation of oleic acid into heptadecane over a Cu–Ni alloy catalyst using methanol as a hydrogen carrier

DOE PAGES

Zhang, Zihao; Yang, Qiwei; Chen, Hao; ...

2017-10-13

In this paper, supported Cu–Ni bimetallic catalysts were synthesized and evaluated for the in situ hydrogenation and decarboxylation of oleic acid using methanol as a hydrogen donor. The supported Cu–Ni alloy exhibited a significant improvement in both activity and selectivity towards the production of heptadecane in comparison with monometallic Cu and Ni based catalysts. The formation of the Cu–Ni alloy is demonstrated by high-angle annular dark-field scanning transmission electron microscopy (HADDF-STEM), energy dispersive X-ray spectroscopy (EDS-mapping), X-ray diffraction (XRD) and temperature programmed reduction (TPR). A partially oxidized Cu in the Cu–Ni alloy is revealed by diffuse reflectance infrared Fourier transformmore » spectroscopy (DRIFTS) following CO adsorption and X-ray photoelectron spectroscopy (XPS). The temperature programmed desorption of ethylene and propane (ethylene/propane-TPD) suggested that the formation of the Cu–Ni alloy inhibited the cracking of C–C bonds compared to Ni, and remarkably increased the selectivity to heptadecane. The temperature programmed desorption of acetic acid (acetic acid-TPD) indicated that the bimetallic Cu–Ni alloy and Ni catalysts had a stronger adsorption of acetic acid than that of the Cu catalyst. Finally, the formation of the Cu–Ni alloy and a partially oxidized Cu facilitates the decarboxylation reaction and inhibits the cracking reaction of C–C bonds, leading to enhanced catalytic activity and selectivity.« less

In situ hydrogenation and decarboxylation of oleic acid into heptadecane over a Cu–Ni alloy catalyst using methanol as a hydrogen carrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Zihao; Yang, Qiwei; Chen, Hao

In this paper, supported Cu–Ni bimetallic catalysts were synthesized and evaluated for the in situ hydrogenation and decarboxylation of oleic acid using methanol as a hydrogen donor. The supported Cu–Ni alloy exhibited a significant improvement in both activity and selectivity towards the production of heptadecane in comparison with monometallic Cu and Ni based catalysts. The formation of the Cu–Ni alloy is demonstrated by high-angle annular dark-field scanning transmission electron microscopy (HADDF-STEM), energy dispersive X-ray spectroscopy (EDS-mapping), X-ray diffraction (XRD) and temperature programmed reduction (TPR). A partially oxidized Cu in the Cu–Ni alloy is revealed by diffuse reflectance infrared Fourier transformmore » spectroscopy (DRIFTS) following CO adsorption and X-ray photoelectron spectroscopy (XPS). The temperature programmed desorption of ethylene and propane (ethylene/propane-TPD) suggested that the formation of the Cu–Ni alloy inhibited the cracking of C–C bonds compared to Ni, and remarkably increased the selectivity to heptadecane. The temperature programmed desorption of acetic acid (acetic acid-TPD) indicated that the bimetallic Cu–Ni alloy and Ni catalysts had a stronger adsorption of acetic acid than that of the Cu catalyst. Finally, the formation of the Cu–Ni alloy and a partially oxidized Cu facilitates the decarboxylation reaction and inhibits the cracking reaction of C–C bonds, leading to enhanced catalytic activity and selectivity.« less

X-Rays and Infrared Selected AGN

NASA Astrophysics Data System (ADS)

Kirhakos, S. D.; Steiner, J. E.

1990-11-01

RESUMEN. En la busqueda de nucleos activos galacticos (NAG) oscurecidos, seleccionamos una tnuestra de galaxias ernisoras de rayos S infrarrojos, Ia mayoria de las cuales son vistas de perf ii. La 6ptica de la regi6n nuclear de las galaxias seleccionadas revelan que el 76% de ellas muestran lineas de emisi5n La clasificaci6n de los es- pectros de acuerdo a los anchos y a la intensidad de cocientes de lineas muestran que existen 34 NAG, 34 objetos de tipo de transici6n y 34 galaxias de la regi6n con nucleos de tipo regi6n H II. Entre los NAG, 3 son del tipo Seyfert I y las otras son del tipo 2. Sugerimos que los objetos identificados como NAG de llneas angostas son objetos tipo Seyfert I oscurecidos ABSTRACT. Looking for obscured active galactic nuclei (AGN), we selected a sample of infrarediX-rays emitting galaxies, mos"t of which are seen as edge-on. Optical spectroscopy of the nuclear region of the selected galaxies revealed that 76 % of them show emission l 'nes. Classification of the spectra according to the widths and line intensity ratios shows that there are 34 AGN, 34 transition type objects and 43 nuclear HIl-like region galaxies. Among the AGN, three are Seyfert type 1 and the others are type 2 objects. We suggest that the objects identified as narrow line AGN are obscured Seyfert 1. o'L : GALAXIES-ACTIVE - X-RAY S-GENERAL

Methanol steam reforming over Ni-CeO 2 model and powder catalysts: Pathways to high stability and selectivity for H 2/CO 2 production

DOE PAGES

Liu, Zongyuan; Yao, Siyu; Johnston-Peck, Aaron; ...

2017-08-25

Here, nickel-ceria has been reported as a very good catalysts for the reforming of methane. Here, the methanol steam reforming reaction on both powder (Ni-CeO 2) and model (Ni-CeO 2-x(111)) catalysts was investigated. The active phase evolution and surface species transformation on powder catalysts were studied via in situ X-ray diffraction (XRD) and diffuse reflectance infrared transform spectroscopy (DRIFTS). Phase transitions of NiO → NiC → Ni and CeO 2 → CeO 2-x were observed during the reaction. The simultaneous production of H 2/CO 2 demonstrates that the active phase of the catalysts contains metallic Ni supported over partially reducedmore » ceria. The DRIFTS experiments indicate that a methoxy to formate transition is associated with the reduction of ceria whereas the formation of carbonate species results from the presence of metallic Ni. A study of the reaction of methanol with Ni-CeO 2-x(111) by X-ray photoelectron spectroscopy (XPS) points to the essential role of metal-support interactions in an oxygen transfer from ceria to Ni that contributes to the high selectivity of the catalysts.« less

Methanol steam reforming over Ni-CeO 2 model and powder catalysts: Pathways to high stability and selectivity for H 2/CO 2 production

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Zongyuan; Yao, Siyu; Johnston-Peck, Aaron

Here, nickel-ceria has been reported as a very good catalysts for the reforming of methane. Here, the methanol steam reforming reaction on both powder (Ni-CeO 2) and model (Ni-CeO 2-x(111)) catalysts was investigated. The active phase evolution and surface species transformation on powder catalysts were studied via in situ X-ray diffraction (XRD) and diffuse reflectance infrared transform spectroscopy (DRIFTS). Phase transitions of NiO → NiC → Ni and CeO 2 → CeO 2-x were observed during the reaction. The simultaneous production of H 2/CO 2 demonstrates that the active phase of the catalysts contains metallic Ni supported over partially reducedmore » ceria. The DRIFTS experiments indicate that a methoxy to formate transition is associated with the reduction of ceria whereas the formation of carbonate species results from the presence of metallic Ni. A study of the reaction of methanol with Ni-CeO 2-x(111) by X-ray photoelectron spectroscopy (XPS) points to the essential role of metal-support interactions in an oxygen transfer from ceria to Ni that contributes to the high selectivity of the catalysts.« less

The quasar luminosity function at redshift 4 with the Hyper Suprime-Cam Wide Survey

NASA Astrophysics Data System (ADS)

Akiyama, Masayuki; He, Wanqiu; Ikeda, Hiroyuki; Niida, Mana; Nagao, Tohru; Bosch, James; Coupon, Jean; Enoki, Motohiro; Imanishi, Masatoshi; Kashikawa, Nobunari; Kawaguchi, Toshihiro; Komiyama, Yutaka; Lee, Chien-Hsiu; Matsuoka, Yoshiki; Miyazaki, Satoshi; Nishizawa, Atsushi J.; Oguri, Masamune; Ono, Yoshiaki; Onoue, Masafusa; Ouchi, Masami; Schulze, Andreas; Silverman, John D.; Tanaka, Manobu M.; Tanaka, Masayuki; Terashima, Yuichi; Toba, Yoshiki; Ueda, Yoshihiro

2018-01-01

We present the luminosity function of z ˜ 4 quasars based on the Hyper Suprime-Cam Subaru Strategic Program Wide layer imaging data in the g, r, i, z, and y bands covering 339.8 deg2. From stellar objects, 1666 z ˜ 4 quasar candidates are selected via the g-dropout selection down to i = 24.0 mag. Their photometric redshifts cover the redshift range between 3.6 and 4.3, with an average of 3.9. In combination with the quasar sample from the Sloan Digital Sky Survey in the same redshift range, a quasar luminosity function covering the wide luminosity range of M1450 = -22 to -29 mag is constructed. The quasar luminosity function is well described by a double power-law model with a knee at M1450 = -25.36 ± 0.13 mag and a flat faint-end slope with a power-law index of -1.30 ± 0.05. The knee and faint-end slope show no clear evidence of redshift evolution from those seen at z ˜ 2. The flat slope implies that the UV luminosity density of the quasar population is dominated by the quasars around the knee, and does not support the steeper faint-end slope at higher redshifts reported at z > 5. If we convert the M1450 luminosity function to the hard X-ray 2-10 keV luminosity function using the relation between the UV and X-ray luminosity of quasars and its scatter, the number density of UV-selected quasars matches well with that of the X-ray-selected active galactic nuclei (AGNs) above the knee of the luminosity function. Below the knee, the UV-selected quasars show a deficiency compared to the hard X-ray luminosity function. The deficiency can be explained by the lack of obscured AGNs among the UV-selected quasars.

An Ultraviolet Investigation of Activity on Exoplanet Host Stars

NASA Astrophysics Data System (ADS)

Shkolnik, Evgenya L.

2013-03-01

Using the far-UV (FUV) and near-UV (NUV) photometry from the NASA Galaxy Evolution Explorer (GALEX), we searched for evidence of increased stellar activity due to tidal and/or magnetic star-planet interactions (SPI) in the 272 known FGK planetary hosts observed by GALEX. With the increased sensitivity of GALEX, we are able probe systems with lower activity levels and at larger distances than what has been done to date with X-ray satellites. We compared samples of stars with close-in planets (a < 0.1 AU) to those with far-out planets (a > 0.5 AU) and looked for correlations of excess activity with other system parameters. This statistical investigation found no clear correlations with a, Mp , or Mp /a, in contrast to some X-ray and Ca II studies. However, there is tentative evidence (at a level of 1.8σ) that stars with radial-velocity-(RV)-detected close-in planets are more FUV-active than stars with far-out planets, in agreement with several published X-ray and Ca II results. The case is strengthened to a level of significance to 2.3σ when transit-detected close-in planets are included. This is most likely because the RV-selected sample of stars is significantly less active than the field population of comparable stars, while the transit-selected sample is similarly active. Given the factor of 2-3 scatter in fractional FUV luminosity for a given stellar effective temperature, it is necessary to conduct a time-resolved study of the planet hosts in order to better characterize their UV variability and generate a firmer statistical result. Based on observations made with the NASA Galaxy Evolution Explorer. GALEX is operated for NASA by the California Institute of Technology under NASA contract NAS5-98034.

Automated selection of trabecular bone regions in knee radiographs.

PubMed

Podsiadlo, P; Wolski, M; Stachowiak, G W

2008-05-01

Osteoarthritic (OA) changes in knee joints can be assessed by analyzing the structure of trabecular bone (TB) in the tibia. This analysis is performed on TB regions selected manually by a human operator on x-ray images. Manual selection is time-consuming, tedious, and expensive. Even if a radiologist expert or highly trained person is available to select regions, high inter- and intraobserver variabilities are still possible. A fully automated image segmentation method was, therefore, developed to select the bone regions for numerical analyses of changes in bone structures. The newly developed method consists of image preprocessing, delineation of cortical bone plates (active shape model), and location of regions of interest (ROI). The method was trained on an independent set of 40 x-ray images. Automatically selected regions were compared to the "gold standard" that contains ROIs selected manually by a radiologist expert on 132 x-ray images. All images were acquired from subjects locked in a standardized standing position using a radiography rig. The size of each ROI is 12.8 x 12.8 mm. The automated method results showed a good agreement with the gold standard [similarity index (SI) = 0.83 (medial) and 0.81 (lateral) and the offset =[-1.78, 1.27]x[-0.65,0.26] mm (medial) and [-2.15, 1.59]x[-0.58, 0.52] mm (lateral)]. Bland and Altman plots were constructed for fractal signatures, and changes of fractal dimensions (FD) to region offsets calculated between the gold standard and automatically selected regions were calculated. The plots showed a random scatter and the 95% confidence intervals were (-0.006, 0.008) and (-0.001, 0.011). The changes of FDs to region offsets were less than 0.035. Previous studies showed that differences in FDs between non-OA and OA bone regions were greater than 0.05. ROIs were also selected by a second radiologist and then evaluated. Results indicated that the newly developed method could replace a human operator and produces bone regions with an accuracy that is sufficient for fractal analyses of bone texture.

X-ray Selected Symbiotic Candidates in the Galactic Bulge Survey

NASA Astrophysics Data System (ADS)

Hynes, Robert I.; Wetuski, Joshua` D.; Jonker, Peter; Torres, Manuel; Heinke, Craig O.; Maccarone, Tom; Steeghs, Danny; Britt, Christopher; Johnson, Christopher; Nelemans, Gijs

2017-06-01

The Galactic Bulge Survey (GBS) is a broad, shallow survey of Bulge X-ray sources with extensive multiwavelength support. The limiting sensitivity, about 2×1032 erg/s at the Bulge distance, is well suited to finding symbiotic X-ray binaries (SyXBs) containing neutron stars accreting from a cool giant wind, as well as X-ray bright white dwarf systems. Giant counterparts can be securely detected in IR photometry, allowing us to estimate the total number of symbiotics detected by the GBS, and identify a good number of promising candidates. Such an X-ray selected symbiotic sample may be quite different to the traditional symbiotic star population which is usually selected by optical spectroscopy, and consequently biased towards systems with rich line emission. Of the 1640 unique X-ray sources identified by the GBS we find 91 significant matches with candidate Bulge giants. We expect 68 coincidences, so estimate a total sample of about 23 X-ray emitting cool giants detected by the GBS. Most of these are likely to be SyXBs or symbiotics of some type. Narrowing our search to sources coincident to 1", we find 23 matches, with only 8 coincidences expected, so this subsample has a relatively high purity, and likely includes most of the GBS symbiotics. The properties of this subsample are mostly consistent with cool giants, with typical SEDs, long-term lightcurves, and spectra. The sources are inconsistent in color with nearby M dwarfs and show small proper motions, so the foreground contamination is likely small. We present a selection of the best studied objects, focusing on one extremely variable X-ray source coincident with a carbon giant. This is quite an unusual object as carbon stars are rare in the Bulge. The scientific results reported in this article are based on observations made by the Chandra X-ray Observatory and data obtained from the Chandra Data Archive. Support for this work was provided by the National Aeronautics and Space Administration through Chandra Award Numbers GO4-15047X and AR5-16004X issued by the Chandra X-ray Observatory Center, which is operated by the Smithsonian Astrophysical Observatory for and on behalf of the National Aeronautics Space Administration under contract NAS8-03060.

X-ray stars observed in LAMOST spectral survey

NASA Astrophysics Data System (ADS)

Lu, Hong-peng; Zhang, Li-yun; Han, Xianming L.; Shi, Jianrong

2018-05-01

X-ray stars have been studied since the beginning of X-ray astronomy. Investigating and studying the chromospheric activity from X-ray stellar optical spectra is highly significant in providing insights into stellar magnetic activity. The big data of LAMOST survey provides an opportunity for researching stellar optical spectroscopic properties of X-ray stars. We inferred the physical properties of X-ray stellar sources from the analysis of LAMOST spectra. First, we cross-matched the X-ray stellar catalogue (12254 X-ray stars) from ARXA with LAMOST data release 3 (DR3), and obtained 984 good spectra from 713 X-ray sources. We then visually inspected and assigned spectral type to each spectrum and calculated the equivalent width (EW) of Hα line using the Hammer spectral typing facility. Based on the EW of Hα line, we found 203 spectra of 145 X-ray sources with Hα emission above the continuum. For these spectra we also measured the EWs of Hβ, Hγ, Hδ and Ca ii IRT lines of these spectra. After removing novae, planetary nebulae and OB-type stars, we found there are 127 X-ray late-type stars with Hα line emission. By using our spectra and results from the literature, we found 53 X-ray stars showing Hα variability; these objects are Classical T Tauri stars (CTTs), cataclysmic variables (CVs) or chromospheric activity stars. We also found 18 X-ray stars showing obvious emissions in the Ca ii IRT lines. Of the 18 X-ray stars, 16 are CTTs and 2 are CVs. Finally, we discussed the relationships between the EW of Hα line and X-ray flux.

Formation of Copper Catalysts for CO 2 Reduction with High Ethylene/Methane Product Ratio Investigated with In Situ X-ray Absorption Spectroscopy

DOE PAGES

Eilert, André; Roberts, F. Sloan; Friebel, Daniel; ...

2016-04-04

Nanostructured copper cathodes are among the most efficient and selective catalysts to date for making multicarbon products from the electrochemical carbon dioxide reduction reaction (CO 2RR). We report an in situ X-ray absorption spectroscopy investigation of the formation of a copper nanocube CO 2RR catalyst with high activity that highly favors ethylene over methane production. The results show that the precursor for the copper nanocube formation is copper(I)-oxide, not copper(I)-chloride as previously assumed. A second route to an electrochemically similar material via a copper(II)–carbonate/hydroxide is also reported. In conclusion, this study highlights the importance of using oxidized copper precursors formore » constructing selective CO 2 reduction catalysts and shows the precursor oxidation state does not affect the electrocatalyst selectivity toward ethylene formation.« less

Site-selective XAFS spectroscopy tuned to surface active sites of Cu/ZnO and Cr/SiO2 catalysts.

PubMed

Izumi, Y; Nagamori, H; Kiyotaki, F; Minato, T

2001-03-01

XAFS (X-ray absorption fine structure) spectra were measured by using the fluorescence spectrometer for the emitted X-ray from sample. The chemical shifts between Cu0 and Cu1 and between CrIII and CrVI were evaluated. Tuning the fluorescence spectrometer to each energy, the Cu0 and CuI site-selective XANES for Cu/ZnO catalyst were measured. The first one was similar to the XANES of Cu metal and the second one was the 5 : 5 average of XANES for CuI sites + Cu metal. The population ratio of copper site of the Cu/ZnO catalyst was found to be Cu metal: Cu2O : CuI atomically dispersed on surface = 70(+/-23) : 22(+/-14) : 8(+/-5). Site-selective XANES for CrIII site of Cr/SiO2 catalyst was also studied.

Current and Future X-ray Studies of High-Redshift AGNs and the First Supermassive Black Holes

NASA Astrophysics Data System (ADS)

Brandt, Niel

2016-01-01

X-ray observations of high-redshift AGNs at z = 4-7 have played a critical role in understanding the physical processes at work inthese objects as well as their basic demographics. Since 2000, Chandra and XMM-Newton have provided new X-ray detections for more than 120 such objects, and well-defined samples of z > 4 AGNs now allow reliable X-ray population studies. Once luminosity effectsare considered, the basic X-ray continuum properties of most high-redshift AGNs appear remarkably similar to those of local AGNs, although there are some notable apparent exceptions (e.g., highly radio-loud quasars). Furthermore, the X-ray absorption found in some objects has been used as a diagnostic of outflowing winds and circumnuclear material. Demographically, the X-ray data now support an exponential decline in the number density of luminous AGNs above z ~ 3, and quantitative space-density comparisons for optically selected and X-ray selected quasars indicate basic statistical agreement.The current X-ray discoveries point the way toward the future breakthroughs that will be possible with, e.g., Athena and the X-raySurveyor. These missions will execute powerful blank-field surveys to elucidate the demographics of the first growing supermassive black holes (SMBHs), including highly obscured systems, up to z ~ 10. They will also carry out complementary X-ray spectroscopic and variability investigations of high-redshift AGNs by targeting the most-luminous z = 7-10 quasars found in wide-field surveys by, e.g., Euclid, LSST, and WFIRST. X-ray spectroscopic and variability studies of the X-ray continuum and reflection signatures will help determine Eddington ratios and disk/corona properties; measuring these will clarify how the first quasars grew so quickly. Furthermore, absorption line/edge studies will reveal how outflows from the first SMBHs influenced the growth of the first galaxies. I will suggest some efficient observational strategies for Athena and the X-ray Surveyor.

An unbiased view of X-ray obscuration amongst active galactic nuclei with NuLANDS

NASA Astrophysics Data System (ADS)

Boorman, Peter Gregory; Gandhi, Poshak; Stern, Daniel; Harrison, Fiona; NuSTAR Obscured AGN Team

2018-01-01

Nearly all active galactic nuclei (AGN) are obscured in X-rays behind column densities of NH ≥ 1022 cm-2. Hard X-ray studies have proven very effective to quanitfy the levels of obscuration amongst AGN, up to and just above the Compton-thick limit (NH ˜ 1.5 × 1024 cm-2). However, Compton-thick sources with NH values beyond this limit are typically missed in hard X-ray all-sky surveys such as Swift/BAT, requiring many studies to apply considerable bias corrections to account for the loss. Incorrectly quanitfying the heavily obscured AGN population can have a dramatic effect on synthesis models designed to fit the Cosmic X-ray Background spectrum, due to their significant contribution to the peak flux of the background at ~30 keV. This is what motivated the NuSTAR Local AGN NH Distribution Survey (NuLANDS) - a NuSTAR 1 Ms legacy survey of an obscuration-independent, infrared selected sample of AGN, undetected by BAT and unobserved by NuSTAR before - a considerable number of which are predicted to be heavily obscured. NuSTAR is the first true X-ray focusing instrument capable of spectral analysis > 10 keV, and as such can and will place robust constraints on the NH values of these elusive AGN. In this poster, I will present the first results from NuLANDS, including multiple newly identified Compton-thick AGN, previously undetected in the Swift/BAT 70-month catalog. I will further highlight the exciting prospects for the complete NuLANDS sample, with the ultimate goal of constructing a representative NH distribution of AGN in the local Universe, requiring minimal bias corrections.

Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hong, Yongchun; Zhang, He; Sun, Junming

2014-10-31

In this work, a series of Pd/Fe2O3 catalysts were synthesized, characterized, and evaluated for the hydrodeoxygenation (HDO) of m-cresol. It was found that the addition of Pd remarkably promotes the catalytic activity of Fe while the product distributions resemble that of monometallic Fe catalyst, showing high selectivity towards the production of toluene (C-O cleavage without saturation of aromatic ring and C-C cleavage). Reduced catalysts featured with Pd patches on the top of reduced Fe nanoparticle surface, and the interaction between Pd and Fe was further confirmed using X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray absorption nearmore » edge fine structure (XANES). A possible mechanism, including Pd assisted H2 dissociation and Pd facilitated stabilization of metallic Fe surface as well as Pd enhanced product desorption, is proposed to be responsible for the high activity and HDO selectivity in Pd-Fe catalysts. The synergic catalysis derived from Pd-Fe interaction found in this work was proved to be applicable to other precious metal promoted Fe catalysts, providing a promising strategy for future design of highly active and selective HDO catalysts.« less

Dual energy scanning beam laminographic x-radiography

DOEpatents

Majewski, Stanislaw; Wojcik, Randolph F.

1998-01-01

A multiple x-ray energy level imaging system includes a scanning x-ray beam and two detector design having a first low x-ray energy sensitive detector and a second high x-ray energy sensitive detector. The low x-ray energy detector is placed next to or in front of the high x-ray energy detector. The low energy sensitive detector has small stopping power for x-rays. The lower energy x-rays are absorbed and converted into electrical signals while the majority of the higher energy x-rays pass through undetected. The high energy sensitive detector has a large stopping power for x-rays as well as it having a filter placed between it and the object to absorb the lower energy x-rays. In a second embodiment; a single energy sensitive detector is provided which provides an output signal proportional to the amount of energy in each individual x-ray it absorbed. It can then have an electronic threshold or thresholds set to select two or more energy ranges for the images. By having multiple detectors located at different positions, a dual energy laminography system is possible.

Dual energy scanning beam laminographic x-radiography

DOEpatents

Majewski, S.; Wojcik, R.F.

1998-04-21

A multiple x-ray energy level imaging system includes a scanning x-ray beam and two detector design having a first low x-ray energy sensitive detector and a second high x-ray energy sensitive detector. The low x-ray energy detector is placed next to or in front of the high x-ray energy detector. The low energy sensitive detector has small stopping power for x-rays. The lower energy x-rays are absorbed and converted into electrical signals while the majority of the higher energy x-rays pass through undetected. The high energy sensitive detector has a large stopping power for x-rays as well as it having a filter placed between it and the object to absorb the lower energy x-rays. In a second embodiment; a single energy sensitive detector is provided which provides an output signal proportional to the amount of energy in each individual x-ray it absorbed. It can then have an electronic threshold or thresholds set to select two or more energy ranges for the images. By having multiple detectors located at different positions, a dual energy laminography system is possible. 6 figs.

Observation of hohlraum-wall motion with spectrally selective x-ray imaging at the National Ignition Facility

NASA Astrophysics Data System (ADS)

Izumi, N.; Meezan, N. B.; Divol, L.; Hall, G. N.; Barrios, M. A.; Jones, O.; Landen, O. L.; Kroll, J. J.; Vonhof, S. A.; Nikroo, A.; Jaquez, J.; Bailey, C. G.; Hardy, C. M.; Ehrlich, R. B.; Town, R. P. J.; Bradley, D. K.; Hinkel, D. E.; Moody, J. D.

2016-11-01

The high fuel capsule compression required for indirect drive inertial confinement fusion requires careful control of the X-ray drive symmetry throughout the laser pulse. When the outer cone beams strike the hohlraum wall, the plasma ablated off the hohlraum wall expands into the hohlraum and can alter both the outer and inner cone beam propagations and hence the X-ray drive symmetry especially at the final stage of the drive pulse. To quantitatively understand the wall motion, we developed a new experimental technique which visualizes the expansion and stagnation of the hohlraum wall plasma. Details of the experiment and the technique of spectrally selective x-ray imaging are discussed.

Observation of hohlraum-wall motion with spectrally selective x-ray imaging at the National Ignition Facility.

PubMed

Izumi, N; Meezan, N B; Divol, L; Hall, G N; Barrios, M A; Jones, O; Landen, O L; Kroll, J J; Vonhof, S A; Nikroo, A; Jaquez, J; Bailey, C G; Hardy, C M; Ehrlich, R B; Town, R P J; Bradley, D K; Hinkel, D E; Moody, J D

2016-11-01

The high fuel capsule compression required for indirect drive inertial confinement fusion requires careful control of the X-ray drive symmetry throughout the laser pulse. When the outer cone beams strike the hohlraum wall, the plasma ablated off the hohlraum wall expands into the hohlraum and can alter both the outer and inner cone beam propagations and hence the X-ray drive symmetry especially at the final stage of the drive pulse. To quantitatively understand the wall motion, we developed a new experimental technique which visualizes the expansion and stagnation of the hohlraum wall plasma. Details of the experiment and the technique of spectrally selective x-ray imaging are discussed.

Silica-supported isolated gallium sites as highly active, selective and stable propane dehydrogenation catalysts† †Electronic supplementary information (ESI) available: Experimental details, material characterization data, catalytic measurement details and crystallographic details. CCDC 1499756. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc05178b Click here for additional data file. Click here for additional data file.

PubMed Central

Searles, Keith; Siddiqi, Georges; Safonova, Olga V.

2017-01-01

Single-site gallium centers on the surface of silica are prepared via grafting of [Ga(OSi(OtBu)3)3(THF)] on SiO2–700 followed by a thermolysis step. The resulting surface species corresponds to well-defined tetra-coordinate gallium single-sites, [( 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 SiO)3Ga(XOSi)] (X = –H or Si) according to IR, X-ray absorption near-edge structure and extended X-ray absorption fine structure analysis. These gallium sites show high activity, selectivity and stability for propane dehydrogenation with an initial turnover frequency of 20 per h per gallium center, propylene selectivity of ≥93% and remarkable stability over 20 h. The stability of the catalyst probably results from site-isolation of the active site on a non-reducible support such as silica, diminishing facile reduction typical of Ga2O3-based catalysts. PMID:28553501

Accreting Binary Populations in the Earlier Universe

NASA Technical Reports Server (NTRS)

Hornschemeier, Ann

2010-01-01

It is now understood that X-ray binaries dominate the hard X-ray emission from normal star-forming galaxies. Thanks to the deepest (2-4 Ms) Chandra surveys, such galaxies are now being studied in X-rays out to z approximates 4. Interesting X-ray stacking results (based on 30+ galaxies per redshift bin) suggest that the mean rest-frame 2-10 keV luminosity from z=3-4 Lyman break galaxies (LBGs), is comparable to the most powerful starburst galaxies in the local Universe. This result possibly indicates a similar production mechanism for accreting binaries over large cosmological timescales. To understand and constrain better the production of X-ray binaries in high-redshift LBGs, we have utilized XMM-Newton observations of a small sample of z approximates 0.1 GALEX-selected Ultraviolet-Luminous Galaxies (UVLGs); local analogs to high-redshift LBGs. Our observations enable us to study the X-ray emission from LBG-like galaxies on an individual basis, thus allowing us to constrain object-to-object variances in this population. We supplement these results with X-ray stacking constraints using the new 3.2 Ms Chandra Deep Field-South (completed spring 2010) and LBG candidates selected from HST, Swift UVOT, and ground-based data. These measurements provide new X-ray constraints that sample well the entire z=0-4 baseline

Microstructural and mineralogical characterization of selected shales in support of nuclear waste repository studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, S.Y.; Hyder, L.K.; Alley, P.D.

1988-01-01

Five shales were examined as part of the Sedimentary Rock Program evaluation of this medium as a potential host for a US civilian nuclear waste repository. The units selected for characterization were the Chattanooga Shale from Fentress County, Tennessee; the Pierre Shale from Gregory County, South Dakota; the Green River Formation from Garfield County, Colorado; and the Nolichucky Shale and Pumpkin Valley Shale from Roane County, Tennessee. The micromorphology and structure of the shales were examined by petrographic, scanning electron, and high-resolution transmission electron microscopy. Chemical and mineralogical compositions were studied through the use of energy-dispersive x-ray, neutron activation, atomicmore » absorption, thermal, and x-ray diffraction analysis techniques. 18 refs., 12 figs., 2 tabs.« less

X-ray beamsplitter

DOEpatents

Ceglio, N.M.; Stearns, D.G.; Hawryluk, A.M.; Barbee, T.W. Jr.

1987-08-07

An x-ray beamsplitter which splits an x-ray beam into two coherent parts by reflecting and transmitting some fraction of an incident beam has applications for x-ray interferometry, x-ray holography, x-ray beam manipulation, and x-ray laser cavity output couplers. The beamsplitter is formed of a wavelength selective multilayer thin film supported by a very thin x-ray transparent membrane. The beamsplitter resonantly transmits and reflects x-rays through thin film interference effects. A thin film is formed of 5--50 pairs of alternate Mo/Si layers with a period of 20--250 A. The support membrane is 10--200 nm of silicon nitride or boron nitride. The multilayer/support membrane structure is formed across a window in a substrate by first forming the structure on a solid substrate and then forming a window in the substrate to leave a free-standing structure over the window. 6 figs.

X-ray beamsplitter

DOEpatents

Ceglio, Natale M.; Stearns, Daniel S.; Hawryluk, Andrew M.; Barbee, Jr., Troy W.

1989-01-01

An x-ray beamsplitter which splits an x-ray beam into two coherent parts by reflecting and transmitting some fraction of an incident beam has applications for x-ray interferometry, x-ray holography, x-ray beam manipulation, and x-ray laser cavity output couplers. The beamsplitter is formed of a wavelength selective multilayer thin film supported by a very thin x-ray transparent membrane. The beamsplitter resonantly transmits and reflects x-rays through thin film interference effects. A thin film is formed of 5-50 pairs of alternate Mo/Si layers with a period of 20-250 A. The support membrane is 10-200 nm of silicon nitride or boron nitride. The multilayer/support membrane structure is formed across a window in a substrate by first forming the structure on a solid substrate and then forming a window in the substrate to leave a free-standing structure over the window.

SEARCHING FOR NEW {gamma}-RAY BLAZAR CANDIDATES IN THE THIRD PALERMO BAT HARD X-RAY CATALOG WITH WISE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Maselli, A.; Cusumano, G.; La Parola, V.

We searched for {gamma}-ray blazar candidates among the 382 unidentified hard X-ray sources of the third Palermo BAT Catalog (3PBC) obtained from the analysis of 66 months of Swift Burst Alert Telescope (BAT) survey data and listing 1586 sources. We adopted a recently developed association method based on the peculiar infrared colors that characterize the {gamma}-ray blazars included in the second catalog of active galactic nuclei detected by the Fermi Large Area Telescope. We used this method exploiting the data of the all-sky survey performed by the Wide-field Infrared Survey Explorer (WISE) to establish correspondences between unidentified 3PBC sources andmore » WISE {gamma}-ray blazar candidates located within the BAT positional uncertainty region at a 99% confidence level. We obtained a preliminary list of candidates for which we analyzed all the available data in the Swift archive to complement the information in the literature and in the radio, infrared, and optical catalogs with the information on their optical-UV and soft X-ray emission. Requiring the presence of radio and soft X-ray counterparts consistent with the infrared positions of the selected WISE sources, as well as a blazar-like radio morphology, we finally obtained a list of 24 {gamma}-ray blazar candidates.« less

A Long Decay of X-Ray Flux and Spectral Evolution in the Supersoft Active Galactic Nucleus GSN 069

NASA Astrophysics Data System (ADS)

Shu, X. W.; Wang, S. S.; Dou, L. M.; Jiang, N.; Wang, J. X.; Wang, T. G.

2018-04-01

GSN 069 is an optically identified very low-mass active galactic nuclei (AGN) that shows supersoft X-ray emission. The source is known to exhibit a huge X-ray outburst, with flux increased by more than a factor of ∼240 compared to the quiescence state. We report its long-term evolution in the X-ray flux and spectral variations over a timescale of ∼decade, using both new and archival X-ray observations from the XMM-Newton and Swift. The new Swift observations detected the source in its lowest level of X-ray activity since the outburst, a factor of ∼4 lower in the 0.2–2 keV flux than that obtained with the XMM-Newton observations nearly eight years ago. Combining with the historical X-ray measurements, we find that the X-ray flux is decreasing slowly. There seemed to be spectral softening associated with the drop of X-ray flux. In addition, we find evidence for the presence of a weak, variable, hard X-ray component, in addition to the dominant thermal blackbody emission reported before. The long decay of X-ray flux and spectral evolution, as well as the supersoft X-ray spectra, suggest that the source could be a tidal disruption event (TDE), though a highly variable AGN cannot be fully ruled out. Further continued X-ray monitoring would be required to test the TDE interpretation, by better determining the flux evolution in the decay phase.

Enhancement of the ETS-10 titanosilicate activity in the shape-selective photocatalytic degradation of large aromatic molecules by controlled defect production.

PubMed

Llabrés I Xamena, Francesc X; Calza, Paola; Lamberti, Carlo; Prestipino, Carmelo; Damin, Alessandro; Bordiga, Silvia; Pelizzetti, Ezio; Zecchina, Adriano

2003-02-26

In recent times, it has been shown that the microporous ETS-10 titanosilicate can be used as a shape-selective photocatalyst for the decomposition of aromatic molecules (Chem. Commun. 2001, 2131). Its actual use on practical grounds is however discouraged by its too low activity, when compared with that of TiO(2) photocatalysts. In the present work, we show how an ad hoc mild treatment with HF enhances the activity of ETS-10 toward the photodegradation of large aromatic molecules that are unable to penetrate inside the zeolitic pores, such as 2,5-dichlorophenol, 2,4,5-trichlorophenol, 1,3,5-trihydroxybenzene, and 2,3-dihydroxynaphthalene (DHN). The photoactivity of the acid-treated materials is comparable or even greater than that of the nonselective TiO(2) catalyst. Moreover, the enhancement of the photoactivity is accompanied by a remarkable parallel increase of the shape selectivity, particularly toward DHN (k(DHN)/k(P) = 127, where P = phenol). A complete characterization (by means of X-ray diffraction, scanning electron microscopy, transmission electron microscopy, ultraviolet-visible spectroscopy, and X-ray aborption spectroscopy techniques) of a set of ETS-10 samples which have undergone a progressively severe HF treatment allows us to propose an explanation of the photocatalytic activity and selectivity of the modified materials.

Method for dose-reduced 3D catheter tracking on a scanning-beam digital x-ray system using dynamic electronic collimation

NASA Astrophysics Data System (ADS)

Dunkerley, David A. P.; Funk, Tobias; Speidel, Michael A.

2016-03-01

Scanning-beam digital x-ray (SBDX) is an inverse geometry x-ray fluoroscopy system capable of tomosynthesis-based 3D catheter tracking. This work proposes a method of dose-reduced 3D tracking using dynamic electronic collimation (DEC) of the SBDX scanning x-ray tube. Positions in the 2D focal spot array are selectively activated to create a regionof- interest (ROI) x-ray field around the tracked catheter. The ROI position is updated for each frame based on a motion vector calculated from the two most recent 3D tracking results. The technique was evaluated with SBDX data acquired as a catheter tip inside a chest phantom was pulled along a 3D trajectory. DEC scans were retrospectively generated from the detector images stored for each focal spot position. DEC imaging of a catheter tip in a volume measuring 11.4 cm across at isocenter required 340 active focal spots per frame, versus 4473 spots in full-FOV mode. The dose-area-product (DAP) and peak skin dose (PSD) for DEC versus full field-of-view (FOV) scanning were calculated using an SBDX Monte Carlo simulation code. DAP was reduced to 7.4% to 8.4% of the full-FOV value, consistent with the relative number of active focal spots (7.6%). For image sequences with a moving catheter, PSD was 33.6% to 34.8% of the full-FOV value. The root-mean-squared-deviation between DEC-based 3D tracking coordinates and full-FOV 3D tracking coordinates was less than 0.1 mm. The 3D distance between the tracked tip and the sheath centerline averaged 0.75 mm. Dynamic electronic collimation can reduce dose with minimal change in tracking performance.

The Frequency of Intrinsic X-Ray Weakness among Broad Absorption Line Quasars

NASA Astrophysics Data System (ADS)

Liu, Hezhen; Luo, B.; Brandt, W. N.; Gallagher, S. C.; Garmire, G. P.

2018-06-01

We present combined ≈14–37 ks Chandra observations of seven z = 1.6–2.7 broad absorption line (BAL) quasars selected from the Large Bright Quasar Survey (LBQS). These seven objects are high-ionization BAL (HiBAL) quasars, and they were undetected in the Chandra hard band (2–8 keV) in previous observations. The stacking analyses of previous Chandra observations suggested that these seven objects likely contain some candidates for intrinsically X-ray weak BAL quasars. With the new Chandra observations, six targets are detected. We calculate their effective power-law photon indices and hard-band flux weakness, and find that two objects, LBQS 1203+1530 and LBQS 1442–0011, show soft/steep spectral shapes ({{{Γ }}}eff}={2.2}-0.9+0.9 and {1.9}-0.8+0.9) and significant X-ray weakness in the hard band (by factors of ≈15 and 12). We conclude that the two HiBAL quasars are good candidates for intrinsically X-ray weak BAL quasars. The mid-infrared-to-ultraviolet spectral energy distributions of the two candidates are consistent with those of typical quasars. We constrain the fraction of intrinsically X-ray weak active galactic nuclei (AGNs) among HiBAL quasars to be ≈7%–10% (2/29–3/29), and we estimate it is ≈6%–23% (2/35–8/35) among the general BAL quasar population. Such a fraction is considerably larger than that among non-BAL quasars, and we suggest that intrinsically X-ray weak quasars are preferentially observed as BAL quasars. Intrinsically X-ray weak AGNs likely comprise a small minority of the luminous type 1 AGN population, and they should not affect significantly the completeness of these AGNs found in deep X-ray surveys.

X-ray energy selected imaging with Medipix II

NASA Astrophysics Data System (ADS)

Ludwig, J.; Zwerger, A.; Benz, K.-W.; Fiederle, M.; Braml, H.; Fauler, A.; Konrath, J.-P.

2004-09-01

Two different X-ray tube accelerating voltages (60 and 70kV) are used for diagnosis of front teeth and molars. Different energy ranges are necessary as function of tooth thickness to obtain similar contrast for imaging. This technique drives the costs for the X-ray tube up and allows for just two optimized settings. Energy range selection for the detection of the penetrating X-rays would overcome these severe setbacks. The single photon counting chip MEDIPIX2 http://www.cern.ch/medipix exhibits exactly this feature.First simulations and measurements have been carried out using a dental X-ray source. As a demonstrator a real tooth has been used with different cavities and filling materials. Simulations showed in general larger improvements as compared to measurements regarding SNR and contrast: A beneficial factor of 4% wrt SNR and 25% for contrast, measurements showed factors of 2.5 and up to 10%, respectively.

Anticancer and enhanced antimicrobial activity of biosynthesizd silver nanoparticles against clinical pathogens

NASA Astrophysics Data System (ADS)

Rajeshkumar, Shanmugam; Malarkodi, Chelladurai; Vanaja, Mahendran; Annadurai, Gurusamy

2016-07-01

The present investigation shows the biosynthesis of eco-friendly silver nanoparticles using culture supernatant of Enterococcus sp. and study the effect of enhanced antimicrobial activity, anticancer activity against pathogenic bacteria, fungi and cancer cell lines. Silver nanoparticles was synthesized by adding 1 mM silver nitrate into the 100 ml of 24 h freshly prepared culture supernatant of Enterococcus sp. and were characterized by UV-vis spectroscopy, X-ray diffraction (XRD), Transmission Electron Microscope (TEM), Selected Area Diffraction X-Ray (SAED), Energy Dispersive X Ray (EDX) and Fourier Transform Infra red Spectroscopy (FT-IR). The synthesized silver nanoparticles were impregnated with commercial antibiotics for evaluation of enhanced antimicrobial activity. Further these synthesized silver nanoparticles were assessed for its anticancer activity against cancer cell lines. In this study crystalline structured nanoparticles with spherical in the size ranges from 10 to 80 nm and it shows excellent enhanced antimicrobial activity than the commercial antibiotics. The in vitro assay of silver nanoparticles on anticancer have great potential to inhibit the cell viability. Amide linkages and carboxylate groups of proteins from Enterococcus sp. may bind with silver ions and convert into nanoparticles. The activities of commercial antibiotics were enhanced by coating silver nanoparticles shows significant improved antimicrobial activity. Silver nanoparticles have the great potential to inhibit the cell viability of liver cancer cells lines (HepG2) and lung cancer cell lines (A549).

Cobalt Oxide on N-Doped Carbon for 1-Butene Oligomerization to Produce Linear Octenes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhao, Dongting; Xu, Zhuoran; Chada, Joseph P.

Cobalt oxide supported on N-doped carbon catalysts were investigated for 1-butene oligomerization. The materials were synthesized by treating activated carbon with nitric acid and subsequently with NH3 at 200, 400, 600, and 800 °C, followed by impregnation with cobalt. The 1-butene oligomerization selectivity increased with ammonia treatment temperature of the carbon support. The oligomerization selectivity of cobalt oxide on N-doped carbon synthesized at 800 °C (800A-CoOx/N-C) is 2.6 times higher than previously reported cobalt oxide on N-doped carbon synthesized with NH4OH (2A-CoOx/N-C). Over 70% of the butene dimers were linear C8 olefins for all catalysts. The oligomerization selectivity increased withmore » 1-butene conversion. The catalysts were characterized by elemental analysis, N2 adsorption, X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), and X-ray photoelectron spectroscopy (XPS). The nitrogen content of the catalysts increases with ammonia treatment temperature as confirmed by elemental analysis. The surface content of pyridinic nitrogen with a binding energy of 398.4 ± 0.1 eV increased with ammonia treatment temperature as evidenced by deconvolution of N 1s XPS spectra.« less

A giant radio flare from Cygnus X-3 with associated γ-ray emission: The 2011 radio and γ-ray flare of Cyg X-3

DOE PAGES

Corbel, S.; Dubus, G.; Tomsick, J. A.; ...

2012-04-10

With frequent flaring activity of its relativistic jets, Cygnus X-3 (Cyg X-3) is one of the most active microquasars and is the only Galactic black hole candidate with confirmed high-energy γ-ray emission, thanks to detections by Fermi Large Area Telescope (Fermi/LAT) and AGILE. In 2011, we observed Cyg X-3 in order to transit to a soft X-ray state, which is known to be associated with high-energy γ-ray emission. We present the results of a multiwavelength campaign covering a quenched state, when radio emission from Cyg X-3 is at its weakest and the X-ray spectrum is very soft. A giant (~20more » Jy) optically thin radio flare marks the end of the quenched state, accompanied by rising non-thermal hard X-rays. Fermi/LAT observations (E≥ 100 MeV) reveal renewed γ-ray activity associated with this giant radio flare, suggesting a common origin for all non-thermal components. In addition, current observations unambiguously show that the γ-ray emission is not exclusively related to the rare giant radio flares. A three-week period of γ-ray emission is also detected when Cyg X-3 was weakly flaring in radio, right before transition to the radio quenched state. There were no γ-rays observed during the ~1-month long quenched state, when the radio flux is weakest. These results suggest transitions into and out of the ultrasoft X-ray (radio-quenched) state trigger γ-ray emission, implying a connection to the accretion process, and also that the γ-ray activity is related to the level of radio flux (and possibly shock formation), strengthening the connection to the relativistic jets.« less

A Correlation Between the Intrinsic Brightness and Average Decay Rate of Gamma-Ray Burst X-Ray Afterglow Light Curves

NASA Technical Reports Server (NTRS)

Racusin, J. L.; Oates, S. R.; De Pasquale, M.; Kocevski, D.

2016-01-01

We present a correlation between the average temporal decay (alpha X,avg, greater than 200 s) and early-time luminosity (LX,200 s) of X-ray afterglows of gamma-ray bursts as observed by the Swift X-ray Telescope. Both quantities are measured relative to a rest-frame time of 200 s after the gamma-ray trigger. The luminosity â€" average decay correlation does not depend on specific temporal behavior and contains one scale-independent quantity minimizing the role of selection effects. This is a complementary correlation to that discovered by Oates et al. in the optical light curves observed by the Swift Ultraviolet Optical Telescope. The correlation indicates that, on average, more luminous X-ray afterglows decay faster than less luminous ones, indicating some relative mechanism for energy dissipation. The X-ray and optical correlations are entirely consistent once corrections are applied and contamination is removed. We explore the possible biases introduced by different light-curve morphologies and observational selection effects, and how either geometrical effects or intrinsic properties of the central engine and jet could explain the observed correlation.

The X-ray luminous galaxy cluster XMMU J1007.4+1237 at z = 1.56. The dawn of starburst activity in cluster cores

NASA Astrophysics Data System (ADS)

Fassbender, R.; Nastasi, A.; Böhringer, H.; Šuhada, R.; Santos, J. S.; Rosati, P.; Pierini, D.; Mühlegger, M.; Quintana, H.; Schwope, A. D.; Lamer, G.; de Hoon, A.; Kohnert, J.; Pratt, G. W.; Mohr, J. J.

2011-03-01

Context. Observational galaxy cluster studies at z > 1.5 probe the formation of the first massive M > 1014 M⊙ dark matter halos, the early thermal history of the hot ICM, and the emergence of the red-sequence population of quenched early-type galaxies. Aims: We present first results for the newly discovered X-ray luminous galaxy cluster XMMU J1007.4+1237 at z = 1.555, detected and confirmed by the XMM-Newton Distant Cluster Project (XDCP) survey. Methods: We selected the system as a serendipitous weak extended X-ray source in XMM-Newton archival data and followed it up with two-band near-infrared imaging and deep optical spectroscopy. Results: We can establish XMMU J1007.4+1237 as a spectroscopically confirmed, massive,bona fide galaxy cluster with a bolometric X-ray luminosity of Lbol_X,500≃(2.1 ± 0.4)× 10^{44} erg/s, a red galaxy population centered on the X-ray emission, and a central radio-loud brightest cluster galaxy. However, we see evidence for the first time that the massive end of the galaxy population and the cluster red-sequence are not yet fully in place. In particular, we find ongoing starburst activity for the third ranked galaxy close to the center and another slightly fainter object. Conclusions: At a lookback time of 9.4 Gyr, the cluster galaxy population appears to be caught in an important evolutionary phase, prior to full star-formation quenching and mass assembly in the core region. X-ray selection techniques are an efficient means of identifying and probing the most distant clusters without any prior assumptions about their galaxy content. Based on observations under programme ID 081.A-0312 collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, and observations collected at the Centro Astronómico Hispano Alemán (CAHA) at Calar Alto, operated jointly by the Max-Planck Institut für Astronomie and the Instituto de Astrofísica de Andalucía (CSIC).Figure 2 and Tables 1 and 2 are only available in electronic form at http://www.aanda.org

The optical blocking filter for the ATHENA wide field imager: ongoing activities towards the conceptual design

NASA Astrophysics Data System (ADS)

Barbera, M.; Branduardi-Raymont, G.; Collura, A.; Comastri, A.; Eder, J.; Kamisiński, T.; Lo Cicero, U.; Meidinger, N.; Mineo, T.; Molendi, S.; Parodi, G.; Pilch, A.; Piro, L.; Rataj, M.; Rauw, G.; Sciortino, L.; Sciortino, S.; Wawer, P.

2015-08-01

ATHENA is the L2 mission selected by ESA to pursue the science theme "Hot and Energetic Universe" (launch scheduled in 2028). One of the key instruments of ATHENA is the Wide Field Imager (WFI) which will provide imaging in the 0.1-15 keV band over a 40'x40' large field of view, together with spectrally and time-resolved photon counting. The WFI camera, based on arrays of DEPFET active pixel sensors, is also sensitive to UV/Vis photons. Optically generated electron-hole pairs may degrade the spectral resolution as well as change the energy scale by introducing a signal offset. For this reason, the use of an X-ray transparent optical blocking filter is needed to allow the observation of all type of X-ray sources that present a UV/Visible bright counterpart. In this paper, we describe the main activities that we are carrying on for the conceptual design of the optical blocking filter, that will be mounted on the filter wheel, in order to satisfy the scientific requirements on optical load from bright UV/Vis astrophysical source, to maximize the X-ray transmission, and to withstand the severe acoustic and vibration loads foreseen during launch.

Evidence of plasma heating in solar microflares during the minimum of solar activity

NASA Astrophysics Data System (ADS)

Kirichenko, Alexey; Bogachev, Sergey

We present a statistical study of 80 solar microflares observed during the deep minimum of solar activity between 23 and 24 solar cycles. Our analysis covers the following characteristics of the flares: thermal energy of flaring plasma, its temperature and its emission measure in soft X-rays. The data were obtained during the period from April to July of 2009, which was favorable for observations of weak events because of very low level of solar activity. The most important part of our analysis was an investigation of extremely weak microflares corresponding to X-ray class below A1.0. We found direct evidence of plasma heating in more than 90% of such events. Temperature of flaring plasma was determined under the isothermal approximation using the data of two solar instruments: imaging spectroheliometer MISH onboard Coronas-Photon spacecraft and X-ray spectrophotometer SphinX operating in energy range 0.8 - 15 keV. The main advantage of MISH is the ability to image high temperature plasma (T above 4 MK) without a low-temperature background. The SphinX data was selected due to its high sensitivity, which makes available the registration of X-ray emission from extremely weak microflares corresponding GOES A0.1 - A0.01 classes. The temperature we obtained lies in the range from 2.6 to 13.6 MK, emission measure, integrated over the range 1 - 8 Å - 2.7times10(43) - 4.9times10(47) cm (-3) , thermal energy of flaring region - 5times10(26) - 1.6times10(29) erg. We compared our results with the data obtained by Feldman et. al. 1996 and Ryan et. al. 2012 for solar flares with X-ray classes above A2.0 and conclude that the relation between X-ray class of solar flare and its temperature is strongly different for ordinary flares (above A2.0) and for weak microflares (A0.01 - A2.0). Our result supports the idea that weak solar events (microflares and nanoflares) may play significant a role in plasma heating in solar corona.

Note: application of a pixel-array area detector to simultaneous single crystal X-ray diffraction and X-ray absorption spectroscopy measurements.

PubMed

Sun, Cheng-Jun; Zhang, Bangmin; Brewe, Dale L; Chen, Jing-Sheng; Chow, G M; Venkatesan, T; Heald, Steve M

2014-04-01

X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorption near edge structure for Pr0.67Sr0.33MnO3 film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.

X-ray insights into star and planet formation.

PubMed

Feigelson, Eric D

2010-04-20

Although stars and planets form in cold environments, X-rays are produced in abundance by young stars. This review examines the implications of stellar X-rays for star and planet formation studies, highlighting the contributions of NASA's (National Aeronautics and Space Administration) Chandra X-ray Observatory. Seven topics are covered: X-rays from protostellar outflow shocks, X-rays from the youngest protostars, the stellar initial mass function, the structure of young stellar clusters, the fate of massive stellar winds, X-ray irradiation of protoplanetary disks, and X-ray flare effects on ancient meteorites. Chandra observations of star-forming regions often show dramatic star clusters, powerful magnetic reconnection flares, and parsec-scale diffuse plasma. X-ray selected samples of premain sequence stars significantly advance studies of star cluster formation, the stellar initial mass function, triggered star-formation processes, and protoplanetary disk evolution. Although X-rays themselves may not play a critical role in the physics of star formation, they likely have important effects on protoplanetary disks by heating and ionizing disk gases.

X-ray insights into star and planet formation

PubMed Central

Feigelson, Eric D.

2010-01-01

Although stars and planets form in cold environments, X-rays are produced in abundance by young stars. This review examines the implications of stellar X-rays for star and planet formation studies, highlighting the contributions of NASA’s (National Aeronautics and Space Administration) Chandra X-ray Observatory. Seven topics are covered: X-rays from protostellar outflow shocks, X-rays from the youngest protostars, the stellar initial mass function, the structure of young stellar clusters, the fate of massive stellar winds, X-ray irradiation of protoplanetary disks, and X-ray flare effects on ancient meteorites. Chandra observations of star-forming regions often show dramatic star clusters, powerful magnetic reconnection flares, and parsec-scale diffuse plasma. X-ray selected samples of premain sequence stars significantly advance studies of star cluster formation, the stellar initial mass function, triggered star-formation processes, and protoplanetary disk evolution. Although X-rays themselves may not play a critical role in the physics of star formation, they likely have important effects on protoplanetary disks by heating and ionizing disk gases. PMID:20404197

Host Galaxy Properties of the Swift BAT Ultra Hard X-Ray Selected AGN

NASA Technical Reports Server (NTRS)

Koss, Michael; Mushotzky, Richard; Veilleux, Sylvain; Winter, Lisa M.; Baumgartner, Wayne; Tueller, Jack; Gehrels, Neil; Valencic, Lynne

2011-01-01

We have assembled the largest sample of ultra hard X-ray selected (14-195 keV) AGN with host galaxy optical data to date, with 185 nearby (z<0.05), moderate luminosity AGN from the Swift Burst Alert Telescope (BAT) sample. The BAT AGN host galaxies have intermediate optical colors (u -- r and g -- r) that are bluer than a comparison sample of inactive galaxies and optically selected AGN from the Sloan Digital Sky Survey (SDSS) which are chosen to have the same stellar mass. Based on morphological classifications from the RC3 and the Galaxy Zoo, the bluer colors of BAT AGN are mainly due to a higher fraction of mergers and massive spirals than in the comparison samples. BAT AGN in massive galaxies (log Stellar Mass >10.5) have a 5 to 10 times higher rate of spiral morphologies than in SDSS AGN or inactive galaxies. We also see enhanced far-IR emission in BAT AGN suggestive of higher levels of star formation compared to the comparison samples. BAT AGN are preferentially found in the most massive host galaxies with high concentration indexes indicative of large bulge-to-disk ratios and large supermassive black holes. The narrow-line (NL) BAT AGN have similar intrinsic luminosities as the SDSS NL Seyferts based on measurements of [O III] Lambda 5007. There is also a correlation between the stellar mass and X-ray emission. The BAT AGN in mergers have bluer colors and greater ultra hard X-ray emission compared to the BAT sample as whole. In agreement with the Unified Model of AGN, and the relatively unbiased nature of the BAT sources, the host galaxy colors and morphologies are independent of measures of obscuration such as X-ray column density or Seyfert type. The high fraction of massive spiral galaxies and galaxy mergers in BAT AGN suggest that host galaxy morphology is related to the activation and fueling of local AGN.

Large-scale clustering measurements with photometric redshifts: comparing the dark matter haloes of X-ray AGN, star-forming and passive galaxies at z ≈ 1

NASA Astrophysics Data System (ADS)

Georgakakis, A.; Mountrichas, G.; Salvato, M.; Rosario, D.; Pérez-González, P. G.; Lutz, D.; Nandra, K.; Coil, A.; Cooper, M. C.; Newman, J. A.; Berta, S.; Magnelli, B.; Popesso, P.; Pozzi, F.

2014-10-01

We combine multi-wavelength data in the AEGIS-XD and C-COSMOS surveys to measure the typical dark matter halo mass of X-ray selected active galactic nuclei (AGN) [LX(2-10 keV) > 1042 erg s- 1] in comparison with far-infrared selected star-forming galaxies detected in the Herschel/PEP survey (PACS Evolutionary Probe; LIR > 1011 L⊙) and quiescent systems at z ≈ 1. We develop a novel method to measure the clustering of extragalactic populations that uses photometric redshift probability distribution functions in addition to any spectroscopy. This is advantageous in that all sources in the sample are used in the clustering analysis, not just the subset with secure spectroscopy. The method works best for large samples. The loss of accuracy because of the lack of spectroscopy is balanced by increasing the number of sources used to measure the clustering. We find that X-ray AGN, far-infrared selected star-forming galaxies and passive systems in the redshift interval 0.6 < z < 1.4 are found in haloes of similar mass, log MDMH/(M⊙ h-1) ≈ 13.0. We argue that this is because the galaxies in all three samples (AGN, star-forming, passive) have similar stellar mass distributions, approximated by the J-band luminosity. Therefore, all galaxies that can potentially host X-ray AGN, because they have stellar masses in the appropriate range, live in dark matter haloes of log MDMH/(M⊙ h-1) ≈ 13.0 independent of their star formation rates. This suggests that the stellar mass of X-ray AGN hosts is driving the observed clustering properties of this population. We also speculate that trends between AGN properties (e.g. luminosity, level of obscuration) and large-scale environment may be related to differences in the stellar mass of the host galaxies.

NuSTAR Observations of WISE J1036+0449, a Galaxy at z~1 Obscured by Hot Dust

NASA Astrophysics Data System (ADS)

Ricci, C.; Assef, R. J.; Stern, D.; Nikutta, R.; Alexander, D. M.; Asmus, D.; Ballantyne, D. R.; Bauer, F. E.; Blain, A. W.; Boggs, S.; Boorman, P. G.; Brandt, W. N.; Brightman, M.; Chang, C. S.; Chen, C.-T. J.; Christensen, F. E.; Comastri, A.; Craig, W. W.; Díaz-Santos, T.; Eisenhardt, P. R.; Farrah, D.; Gandhi, P.; Hailey, C. J.; Harrison, F. A.; Jun, H. D.; Koss, M. J.; LaMassa, S.; Lansbury, G. B.; Markwardt, C. B.; Stalevski, M.; Stanley, F.; Treister, E.; Tsai, C.-W.; Walton, D. J.; Wu, J. W.; Zappacosta, L.; Zhang, W. W.

2017-01-01

Hot dust-obscured galaxies (hot DOGs), selected from Wide-Field Infrared Survey Explorer’s all-sky infrared survey, host some of the most powerful active galactic nuclei known and may represent an important stage in the evolution of galaxies. Most known hot DOGs are located at z> 1.5, due in part to a strong bias against identifying them at lower redshift related to the selection criteria. We present a new selection method that identifies 153 hot DOG candidates at z˜ 1, where they are significantly brighter and easier to study. We validate this approach by measuring a redshift z = 1.009 and finding a spectral energy distribution similar to that of higher-redshift hot DOGs for one of these objects, WISE J1036+0449 ({L}{Bol}≃ 8× {10}46 {erg} {{{s}}}-1). We find evidence of a broadened component in Mg II, which would imply a black hole mass of {M}{BH}≃ 2× {10}8 {M}⊙ and an Eddington ratio of {λ }{Edd}≃ 2.7. WISE J1036+0449 is the first hot DOG detected by the Nuclear Spectroscopic Telescope Array, and observations show that the source is heavily obscured, with a column density of {N}{{H}}≃ (2{--}15)× {10}23 {{cm}}-2. The source has an intrinsic 2-10 keV luminosity of ˜ 6× {10}44 {erg} {{{s}}}-1, a value significantly lower than that expected from the mid-infrared/X-ray correlation. We also find that other hot DOGs observed by X-ray facilities show a similar deficiency of X-ray flux. We discuss the origin of the X-ray weakness and the absorption properties of hot DOGs. Hot DOGs at z≲ 1 could be excellent laboratories to probe the characteristics of the accretion flow and of the X-ray emitting plasma at extreme values of the Eddington ratio.

In vivo demonstration of enhanced radiotherapy using rare earth doped titania nanoparticles†

PubMed Central

Townley, Helen E.; Kim, Jeewon; Dobson, Peter J.

2017-01-01

Radiation therapy is often limited by damage to healthy tissue and associated side-effects; restricting radiation to ineffective doses. Preferential incorporation of materials into tumour tissue can enhance the effect of radiation. Titania has precedent for use in photodynamic therapy (PDT), generating reactive oxygen species (ROS) upon photoexcitation, but is limited by the penetration depth of UV light. Optimization of a nanomaterial for interaction with X-rays could be used for deep tumour treatment. As such, titania nanoparticles were doped with gadolinium to optimize the localized energy absorption from a conventional medical X-ray, and further optimized by the addition of other rare earth (RE) elements. These elements were selected due to their large X-ray photon interaction cross-section, and potential for integration into the titania crystal structure. Specific activation of the nanoparticles by X-ray can result in generation of ROS leading to cell death in a tumour-localized manner. We show here that intratumoural injection of RE doped titania nanoparticles can enhance the efficacy of radiotherapy in vivo. PMID:22767269

Disentangling Transient Charge Density and Metal–Ligand Covalency in Photoexcited Ferricyanide with Femtosecond Resonant Inelastic Soft X-ray Scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jay, Raphael M.; Norell, Jesper; Eckert, Sebastian

Soft X-ray spectroscopies are ideal probes of the local valence electronic structure of photocatalytically active metal sites. Here, we apply the selectivity of time-resolved resonant inelastic X-ray scattering at the iron L-edge to the transient charge distribution of an optically excited charge-transfer state in aqueous ferricyanide. Through comparison to steady-state spectra and quantum chemical calculations, the coupled effects of valence-shell closing and ligand-hole creation are experimentally and theoretically disentangled and described in terms of orbital occupancy, metal–ligand covalency, and ligand field splitting, thereby extending established steady-state concepts to the excited-state domain. π-Back-donation is found to be mainly determined by themore » metal site occupation, whereas the ligand hole instead influences σ-donation. Here, our results demonstrate how ultrafast resonant inelastic X-ray scattering can help characterize local charge distributions around catalytic metal centers in short-lived charge-transfer excited states, as a step toward future rationalization and tailoring of photocatalytic capabilities of transition-metal complexes.« less

Disentangling Transient Charge Density and Metal–Ligand Covalency in Photoexcited Ferricyanide with Femtosecond Resonant Inelastic Soft X-ray Scattering

DOE PAGES

Jay, Raphael M.; Norell, Jesper; Eckert, Sebastian; ...

2018-06-11

Soft X-ray spectroscopies are ideal probes of the local valence electronic structure of photocatalytically active metal sites. Here, we apply the selectivity of time-resolved resonant inelastic X-ray scattering at the iron L-edge to the transient charge distribution of an optically excited charge-transfer state in aqueous ferricyanide. Through comparison to steady-state spectra and quantum chemical calculations, the coupled effects of valence-shell closing and ligand-hole creation are experimentally and theoretically disentangled and described in terms of orbital occupancy, metal–ligand covalency, and ligand field splitting, thereby extending established steady-state concepts to the excited-state domain. π-Back-donation is found to be mainly determined by themore » metal site occupation, whereas the ligand hole instead influences σ-donation. Here, our results demonstrate how ultrafast resonant inelastic X-ray scattering can help characterize local charge distributions around catalytic metal centers in short-lived charge-transfer excited states, as a step toward future rationalization and tailoring of photocatalytic capabilities of transition-metal complexes.« less

Evolution of X-ray activity of 1-3 Msun late-type stars in early post-main-sequence phases

NASA Astrophysics Data System (ADS)

Pizzolato, N.; Maggio, A.; Sciortino, S.

2000-09-01

We have investigated the variation of coronal X-ray emission during early post-main-sequence phases for a sample of 120 late-type stars within 100 pc, and with estimated masses in the range 1-3 Msun, based on Hipparcos parallaxes and recent evolutionary models. These stars were observed with the ROSAT/PSPC, and the data processed with the Palermo-CfA pipeline, including detection and evaluation of X-ray fluxes (or upper limits) by means of a wavelet transform algorithm. We have studied the evolutionary history of X-ray luminosity and surface flux for stars in selected mass ranges, including stars with inactive A-type progenitors on the main sequence and lower mass solar-type stars. Our stellar sample suggests a trend of increasing X-ray emission level with age for stars with masses M > 1.5 Msun, and a decline for lower-mass stars. A similar behavior holds for the average coronal temperature, which follows a power-law correlation with the X-ray luminosity, independently of their mass and evolutionary state. We have also studied the relationship between X-ray luminosity and surface rotation rate for stars in the same mass ranges, and how this relationships departs from the Lx ~ vrot2 law followed by main-sequence stars. Our results are interpreted in terms of a magnetic dynamo whose efficiency depends on the stellar evolutionary state through the mass-dependent changes of the stellar internal structure, including the properties of envelope convection and the internal rotation profile.

Optical Substructure and BCG Offsets of Sunyaev-Zel'dovich and X-ray Selected Galaxy Clusters

NASA Astrophysics Data System (ADS)

Lopes, Paulo AA; Trevisan, M.; Laganá, T. F.; Durret, F.; Ribeiro, A. LB; Rembold, S. B.

2018-05-01

We used optical imaging and spectroscopic data to derive substructure estimates for local Universe (z < 0.11) galaxy clusters from two different samples. The first was selected through the Sunyaev-Zel'dovich (SZ) effect by the Planck satellite and the second is an X-ray selected sample. In agreement to X-ray substructure estimates we found that the SZ systems have a larger fraction of substructure than the X-ray clusters. We have also found evidence that the higher mass regime of the SZ clusters, compared to the X-ray sample, explains the larger fraction of disturbed objects in the Planck data. Although we detect a redshift evolution in the substructure fraction, it is not sufficient to explain the different results between the higher-z SZ sample and the X-ray one. We have also verified a good agreement (˜60%) between the optical and X-ray substructure estimates. However, the best level of agreement is given by the substructure classification given by measures based on the brightest cluster galaxy (BCG), either the BCG-X-ray centroid offset, or the magnitude gap between the first and second BCGs. We advocate the use of those two parameters as the most reliable and cheap way to assess cluster dynamical state. We recommend an offset cut of ˜0.01 ×R500 to separate relaxed and disturbed clusters. Regarding the magnitude gap the separation can be done at Δm12 = 1.0. The central galaxy paradigm (CGP) may not be valid for ˜20% of relaxed massive clusters. This fraction increases to ˜60% for disturbed systems.

Simultaneous SMM flat crystal spectrometer and Very Large Array observations of solar active regions

NASA Technical Reports Server (NTRS)

Lang, Kenneth R.; Willson, Robert F.; Smith, Kermit L.; Strong, Keith T.

1987-01-01

High-resolution images of the quiescent emission from two solar active regions at 20 cm (VLA) and soft X-ray (SMM FCS) wavelengths are compared. There are regions where the X-ray coronal loops have been completely imaged at 20 cm wavelength. In other regions, the X-ray radiation was detected without detectable 20 cm radiation, and vice versa. The X-ray data were used to infer average electron temperatures of about 3-million K and average electron densities of about 2.5 x 10 to the 9th/cu cm for the X-ray emitting plasma in the two active regions. The thermal bremsstrahlung of the X-ray emitting plasma is optically thin at 20 cm wavelength. The 20 cm brightness temperatures were always less than T(e), which is consistent with optically thin bremsstrahlung. The low T(B) can be explained if a higher, cooler plasma covers the hotter X-ray emitting plasma. Thermal gyroresonance radiation must account for the intense 20 cm radiation near and above sunspots where no X-ray radiation is detected.

Supergiant fast X-ray transients with Swift: Spectroscopic and temporal properties

NASA Astrophysics Data System (ADS)

Romano, P.; Mangano, V.; Ducci, L.; Esposito, P.; Farinelli, R.; Ceccobello, C.; Vercellone, S.; Burrows, D. N.; Kennea, J. A.; Krimm, H. A.; Gehrels, N.

2012-12-01

Supergiant fast X-ray transients (SFXTs) are a class of high-mass X-ray binaries with possible counterparts in the high energy gamma rays. The Swift SFXT Project1 has conducted a systematic investigation of the properties of SFTXs on timescales ranging from minutes to years and in several intensity states (from bright flares, to intermediate intensity states, and down to almost quiescence). We also performed broad-band spectroscopy of outbursts, and intensity-selected spectroscopy outside of outbursts. We demonstrated that while the brightest phase of the outburst only lasts a few hours, further activity is observed at lower fluxes for a remarkably longer time, up to weeks. Furthermore, we assessed the fraction of the time these sources spend in each phase, and their duty cycle of inactivity. We present the most recent results from our investigation. The spectroscopic and, most importantly, timing properties of SFXTs we have uncovered with Swift will serve as a guide in search for the high energy emission from these enigmatic objects.

Evidence for magnetic energy storage in coronal active regions

NASA Technical Reports Server (NTRS)

Krieger, A. S.; De Feiter, L. D.; Vaiana, G. S.

1976-01-01

Examination of X-ray images obtained by the S-054 X-ray spectrographic telescope on Skylab shows the presence of some atypical X-ray-emitting coronal structures in active regions which are not consistent with potential extrapolations of photospheric magnetic fields. Analysis of the observed temporal changes in the X-ray-emitting active-region structures demonstrates that the majority of these consist of brightness changes representing temperature (and perhaps density) variations of the material in the loops.

Observation of hohlraum-wall motion with spectrally selective x-ray imaging at the National Ignition Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Izumi, N., E-mail: izumi2@llnl.gov; Meezan, N. B.; Divol, L.

The high fuel capsule compression required for indirect drive inertial confinement fusion requires careful control of the X-ray drive symmetry throughout the laser pulse. When the outer cone beams strike the hohlraum wall, the plasma ablated off the hohlraum wall expands into the hohlraum and can alter both the outer and inner cone beam propagations and hence the X-ray drive symmetry especially at the final stage of the drive pulse. To quantitatively understand the wall motion, we developed a new experimental technique which visualizes the expansion and stagnation of the hohlraum wall plasma. Details of the experiment and the techniquemore » of spectrally selective x-ray imaging are discussed.« less

Imagery and spectroscopy of supernova remnants and H-2 regions

NASA Technical Reports Server (NTRS)

Dufour, R. J.

1984-01-01

Research activities relating to supernova remnants were summarized. The topics reviewed include: progenitor stars of supernova remnants, UV/optical/radio/X-ray imagery of selected regions in the Cygnus Loop, UV/optical spectroscopy of the Cygnus Loop spur, and extragalactic supernova remnant spectra.

The Sun's X-ray Emission During the Recent Solar Minimum

NASA Astrophysics Data System (ADS)

Sylwester, Janusz; Kowalinski, Mirek; Gburek, Szymon; Siarkowski, Marek; Kuzin, Sergey; Farnik, Frantisek; Reale, Fabio; Phillips, Kenneth J. H.

2010-02-01

The Sun recently underwent a period of a remarkable lack of major activity such as large flares and sunspots, without equal since the advent of the space age a half century ago. A widely used measure of solar activity is the amount of solar soft X-ray emission, but until recently this has been below the threshold of the X-ray-monitoring Geostationary Operational Environmental Satellites (GOES). There is thus an urgent need for more sensitive instrumentation to record solar X-ray emission in this range. Anticipating this need, a highly sensitive spectrophotometer called Solar Photometer in X-rays (SphinX) was included in the solar telescope/spectrometer TESIS instrument package on the third spacecraft in Russia's Complex Orbital Observations Near-Earth of Activity of the Sun (CORONAS-PHOTON) program, launched 30 January 2009 into a near-polar orbit. SphinX measures X-rays in a band similar to the GOES longer-wavelength channel.

Co-Pt core-shell nanostructured catalyst prepared by selective chemical vapor pulse deposition of Pt on Co as a cathode in polymer electrolyte fuel cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seo, Sang-Joon; Chung, Ho-Kyoon; Yoo, Ji-Beom

2014-01-15

A new type of PtCo/C catalyst for use as a cathode in polymer electrolyte fuel cells was prepared by selective chemical vapor pulse deposition (CVPD) of Pt on the surface of Co. The activity of the prepared catalyst for oxygen reduction was higher than that of a catalyst prepared by sequential impregnation (IMP) with the two metallic components. This catalytic activity difference occurs because the former catalyst has smaller Pt crystallites that produce stronger Pt-Co interactions and have a larger Pt surface area. Consequently, the CVPD catalyst has a great number of Co particles that are in close contact withmore » the added Pt. The Pt surface was also electronically modified by interactions with Co, which were stronger in the CVPD catalyst than in the IMP catalyst, as indicated by X-ray diffraction, X-ray photoemission spectroscopy, and cyclic voltammetry measurements of the catalysts.« less

Normal incidence X-ray telescope power spectra of X-ray emission from solar active regions. I - Observations. II - Theory

NASA Technical Reports Server (NTRS)

Gomez, Daniel O.; Martens, Petrus C. H.; Golub, Leon

1993-01-01

Fourier analysis is applied to very high resolution image of coronal active regions obtained by the Normal Incidence X-Ray Telescope is used to find a broad isotropic power-law spectrum of the spatial distribution of soft X-ray intensities. Magnetic structures of all sizes are present down to the resolution limit of the instrument. Power spectra for the X-ray intensities of a sample of topologically different active regions are found which fall off with increasing wavenumber as 1/k-cubed. A model is presented that relates the basic features of coronal magnetic fluctuations to the subphotospheric hydrodynamic turbulence that generates them. The model is used to find a theoretical power spectrum for the X-ray intensity which falls off with increasing wavenumber as 1/k-cubed. The implications of a turbulent regime in active regions are discussed.

Structural and surface changes of cobalt modified manganese oxide during activation and ethanol steam reforming reaction

NASA Astrophysics Data System (ADS)

Gac, Wojciech; Greluk, Magdalena; Słowik, Grzegorz; Turczyniak-Surdacka, Sylwia

2018-05-01

Surface and structural changes of unmodified manganese and cobalt-manganese oxide during activation and ethanol steam reforming reaction conditions (ESR) were studied by means of X-ray diffraction, X-ray photoelectron spectroscopy, temperature-programmed reduction/oxidation (TPR/TPO) and transmission electron microscopy. It was shown that synthesis of cobalt manganese oxide by the redox precipitation method led to the formation of strongly dispersed cobalt ionic species within cryptomelane-based manganese oxide structure. Development of large cube-like MnO nanoparticles with spherical cobalt metallic crystallites decorated by manganese oxide on the high oxidation state and potassium species was observed during reduction. Cobalt manganese catalyst showed high initial activity and selectivity to H2 and CO2 in ethanol stem reforming reaction in the range of 390-480 °C. The drop of ethanol conversion and changes of selectivity with the time-on-stream were observed. An increase of reaction temperature led to intensification of deactivation phenomena. TEM studies evidenced coexistence of Co and CoOx nanoparticles formed under ethanol steam reforming conditions, partially covered by filamentous and encapsulating carbonaceous deposits.

Thin-film-based scintillators for hard x-ray microimaging detectors: the ScinTAX Project

NASA Astrophysics Data System (ADS)

Rack, A.; Cecilia, A.; Douissard, P.-A.; Dupré, K.; Wesemann, V.; Baumbach, T.; Couchaud, M.; Rochet, X.; Riesemeier, H.; Radtke, M.; Martin, T.

2014-09-01

The project ScinTAX developed novel thin scintillating films for the application in high performance X-ray imaging and subsequent introduced new X-ray detectors to the market. To achieve this aim lutetium orthosilicate (LSO) scintillators doped with different activators were grown successfully by liquid phase epitaxy. The high density of LSO (7.4 g/cm3), the effective atomic number (65.2) and the high light yield make this scintillator highly applicable for indirect X-ray detection in which the ionizing radiation is converted into visible light and then registered by a digital detector. A modular indirect detection system has been developed to fully exploit the potential of this thin film scintillator for radiographic and tomographic imaging. The system is compatible for high-resolution imaging with moderate dose as well as adaptable to intense high-dose applications where radiation hard microimaging detectors are required. This proceedings article shall review the achieved performances and technical details on this high-resolution detector system which is now available. A selected example application demonstrates the great potential of the optimized detector system for hard X-ray microimaging, i.e. either to improve image contrast due to the availability of efficient thin crystal films or to reduce the dose to the sample.

Polarimeter for Low Energy X-ray Astrophysical Sources (PLEXAS)

NASA Technical Reports Server (NTRS)

Murray, Stephen S.; Pierce, David L. (Technical Monitor)

2002-01-01

The Polarimeter for Low Energy X-ray Astrophysical Sources (PLEXAS) is an astrophysics mission concept for measuring the polarization of X-ray sources at low energies below the C-K band (less than 277 eV). PLEXAS uses the concept of variations in the reflectivity of a multilayered X-ray telescope as a function of the orientation of an X-rays polarization vector with respect to the reflecting surface of the optic. By selecting an appropriate multilayer, and rotating the X-ray telescope while pointing to a source, there will be a modulation in the source intensity, as measured at the focus of the telescope, which is proportional to the degree of polarization in the source.

PAL-XFEL soft X-ray scientific instruments and X-ray optics: First commissioning results

NASA Astrophysics Data System (ADS)

Park, Sang Han; Kim, Minseok; Min, Changi-Ki; Eom, Intae; Nam, Inhyuk; Lee, Heung-Soo; Kang, Heung-Sik; Kim, Hyeong-Do; Jang, Ho Young; Kim, Seonghan; Hwang, Sun-min; Park, Gi-Soo; Park, Jaehun; Koo, Tae-Yeong; Kwon, Soonnam

2018-05-01

We report an overview of soft X-ray scientific instruments and X-ray optics at the free electron laser (FEL) of the Pohang Accelerator Laboratory, with selected first-commissioning results. The FEL exhibited a pulse energy of 200 μJ/pulse, a pulse width of <50 fs full width at half maximum, and an energy bandwidth of 0.44% at a photon energy of 850 eV. Monochromator resolving power of 10 500 was achieved. The estimated total time resolution between optical laser and X-ray pulses was <270 fs. A resonant inelastic X-ray scattering spectrometer was set up; its commissioning results are also reported.

Applications of phase-contrast x-ray imaging to medicine using an x-ray interferometer

NASA Astrophysics Data System (ADS)

Momose, Atsushi; Yoneyama, Akio; Takeda, Tohoru; Itai, Yuji; Tu, Jinhong; Hirano, Keiichi

1999-10-01

We are investigating possible medical applications of phase- contrast X-ray imaging using an X-ray interferometer. This paper introduces the strategy of the research project and the present status. The main subject is to broaden the observation area to enable in vivo observation. For this purpose, large X-ray interferometers were developed, and 2.5 cm X 1.5 cm interference patterns were generated using synchrotron X-rays. An improvement of the spatial resolution is also included in the project, and an X-ray interferometer designed for high-resolution phase-contrast X-ray imaging was fabricated and tested. In parallel with the instrumental developments, various soft tissues are observed by phase- contrast X-ray CT to find correspondence between the generated contrast and our histological knowledge. The observation done so far suggests that cancerous tissues are differentiated from normal tissues and that blood can produce phase contrast. Furthermore, this project includes exploring materials that modulate phase contrast for selective imaging.

Modified multiple drug resistance phenotype of Chinese hamster ovary cells selected with X-rays and vincristine versus X-rays only.

PubMed Central

McClean, S.; Hill, B. T.

1994-01-01

Exposure of Chinese hamster ovary (CHO) cells to fractionated X-irradiation [ten fractions of 9 Gray (Gy)] resulted in the expression of a multiple drug resistance phenotype which was distinct from that of drug-selected cells in two features: (i) resistance to vinca alkaloids and epipodophyllotoxins but sensitivity to anthracyclines was retained; (ii) overexpression of P-glycoprotein (Pgp) but regulated by post-translational stability rather than by any elevation in Pgp mRNA (Hill et al., 1990). It was also reported that when these cells (designated DXR-10) were subsequently exposed to another ten fractions of 9 Gy (20 x 9 Gy in total), no further increases in drug resistance or in the extent of Pgp expression were observed. To examine this apparent plateauing of the drug resistance phenotype following X-ray pretreatment, DXR-10 cells were instead treated with ten pulsed vincristine exposures. The resultant cell line, designated DXR-10/VCR-10, proved to be more resistant to vincristine, implying that the effect of further drug selection was additive to that of X-ray pretreatment. In addition, these cells showed resistance to doxorubicin and increased Pgp expression which was matched by a concomitant elevation in Pgp mRNA. These findings appear to confirm that Pgp expression is differentially regulated in tumour cells showing drug resistance after drug as opposed to X-ray selection. Images Figure 2 Figure 3 Figure 5 PMID:7908216

New insights into the X-ray properties of nearby barred spiral galaxy NGC 1672

NASA Astrophysics Data System (ADS)

Jenkins, L. P.; Brnadt, W. N.; Colbert, E. J. M.; Levan, A. J.; Roberts, T. P.; Ward, M. J.; Zezas, A.

2008-02-01

We present some preliminary results from new Chandra and XMM-Newton X-ray observations of the nearby barred spiral galaxy NGC1672. It shows dramatic nuclear and extra-nuclear star formation activity, including starburst regions located near each end of its strong bar, both of which host ultraluminous X-ray sources (ULXs). With the new high-spatial-resolution Chandra imaging, we show for the first time that NGC1672 possesses a faint ($L(X)~10^39 erg/s), hard central X-ray source surrounded by an X-ray bright circumnuclear starburst ring that dominates the X-ray emission in the region. The central source may represent low-level AGN activity, or alternatively the emission from X-ray binaries associated with star-formation in the nucleus.

A large sample of shear-selected clusters from the Hyper Suprime-Cam Subaru Strategic Program S16A Wide field mass maps

NASA Astrophysics Data System (ADS)

Miyazaki, Satoshi; Oguri, Masamune; Hamana, Takashi; Shirasaki, Masato; Koike, Michitaro; Komiyama, Yutaka; Umetsu, Keiichi; Utsumi, Yousuke; Okabe, Nobuhiro; More, Surhud; Medezinski, Elinor; Lin, Yen-Ting; Miyatake, Hironao; Murayama, Hitoshi; Ota, Naomi; Mitsuishi, Ikuyuki

2018-01-01

We present the result of searching for clusters of galaxies based on weak gravitational lensing analysis of the ˜160 deg2 area surveyed by Hyper Suprime-Cam (HSC) as a Subaru Strategic Program. HSC is a new prime focus optical imager with a 1.5°-diameter field of view on the 8.2 m Subaru telescope. The superb median seeing on the HSC i-band images of 0.56" allows the reconstruction of high angular resolution mass maps via weak lensing, which is crucial for the weak lensing cluster search. We identify 65 mass map peaks with a signal-to-noise (S/N) ratio larger than 4.7, and carefully examine their properties by cross-matching the clusters with optical and X-ray cluster catalogs. We find that all the 39 peaks with S/N > 5.1 have counterparts in the optical cluster catalogs, and only 2 out of the 65 peaks are probably false positives. The upper limits of X-ray luminosities from the ROSAT All Sky Survey (RASS) imply the existence of an X-ray underluminous cluster population. We show that the X-rays from the shear-selected clusters can be statistically detected by stacking the RASS images. The inferred average X-ray luminosity is about half that of the X-ray-selected clusters of the same mass. The radial profile of the dark matter distribution derived from the stacking analysis is well modeled by the Navarro-Frenk-White profile with a small concentration parameter value of c500 ˜ 2.5, which suggests that the selection bias on the orientation or the internal structure for our shear-selected cluster sample is not strong.

Xray cavities in a sample of 83 SPT-selected clusters galaxies. Tracing the evolution of AGN feedback in clusters of galaxies out to z=1.2

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hlavacek-Larrondo, J.; McDonald, M.; Benson, B. A.

2015-05-18

X-ray cavities are key tracers of mechanical (or radio mode) heating arising from the active galactic nuclei (AGNs) in brightest cluster galaxies (BCGs). We report on a survey for X-ray cavities in 83 massive, high-redshift (more » $$0.4\\lt z\\lt 1.2$$) clusters of galaxies selected by their Sunyaev-Zel’dovich signature in the South Pole Telescope data. Based on Chandra X-ray images, we find a total of six clusters having symmetric pairs of surface brightness depressions consistent with the picture of radio jets inflating X-ray cavities in the intracluster medium (ICM). The majority of these detections are of relatively low significance and require deeper follow-up data in order to be confirmed. Further, this search will miss small (<10 kpc) X-ray cavities that are unresolved by Chandra at high ($$z\\gtrsim 0.5$$) redshift. Despite these limitations, our results suggest that the power generated by AGN feedback in BCGs has remained unchanged for over half of the age of the universe ($$\\gt 7$$ Gyr at $$z\\sim 0.8$$). On average, the detected X-ray cavities have powers of $$(0.8-5)\\times {{10}^{45}}\\ {\\rm erg}\\ {{{\\rm s}}^{-1}}$$, enthalpies of $$(3-6)\\times {{10}^{59}}\\ {\\rm erg}$$, and radii of ~17 kpc. Integrating over 7 Gyr, we find that the supermassive black holes in BCGs may have accreted 10(8) to several $${{10}^{9}}\\,{{M}_{\\odot }}$$ of material to power these outflows. This level of accretion indicates that significant supermassive black hole growth may occur not only at early times, in the quasar era, but at late times as well. We also find that X-ray cavities at high redshift may inject an excess heat of 0.1–1.0 keV per particle into the hot ICM above and beyond the energy needed to offset cooling. Although this result needs to be confirmed, we note that the magnitude of excess heating is similar to the energy needed to preheat clusters, break self-similarity, and explain the excess entropy in hot atmospheres.« less

Probing buried layers by photoelectron spectromicroscopy with hard x-ray excitation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wiemann, C.; Patt, M.; Cramm, S.

We report about a proof-of-principle experiment which explores the perspectives of performing hard x-ray photoemission spectromicroscopy with high lateral resolution. Our results obtained with an energy-filtered photoemission microscope at the PETRA III storage ring facility using hard x-ray excitation up to 6.5 keV photon energy demonstrate that it is possible to obtain selected-area x-ray photoemission spectra from regions less than 500 nm in diameter.

[Development of X-ray excited fluorescence spectrometer].

PubMed

Ni, Chen; Gu, Mu; Di, Wang; Cao, Dun-Hua; Liu, Xiao-Lin; Huang, Shi-Ming

2009-08-01

An X-ray excited fluorescence spectrometer was developed with an X-ray tube and a spectrometer. The X-ray tube, spectrometer, autocontrol method and data processing selected were roundly evaluated. The wavelength and detecting efficiency of the apparatus were calibrated with the mercury and tungsten bromine standard lamps, and the X-ray excited emission spectra of BaF2, Cs I (Tl) crystals were measured. The results indicate that the apparatus has advantages of good wavelength resolution, high stability, easy to operation and good radioprotection. It is a wery effective tool for exploration of new scintillation materials.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov; Brewe, Dale L.; Heald, Steve M.

X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) are two main x-ray techniques in synchrotron radiation facilities. In this Note, we present an experimental setup capable of performing simultaneous XRD and XAS measurements by the application of a pixel-array area detector. For XRD, the momentum transfer in specular diffraction was measured by scanning the X-ray energy with fixed incoming and outgoing x-ray angles. By selecting a small fixed region of the detector to collect the XRD signal, the rest of the area was available for collecting the x-ray fluorescence for XAS measurements. The simultaneous measurement of XRD and X-ray absorptionmore » near edge structure for Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film was demonstrated as a proof of principle for future time-resolved pump-probe measurements. A static sample makes it easy to maintain an accurate overlap of the X-ray spot and laser pump beam.« less

Monochromatic x-ray radiography for areal-density measurement of inertial fusion energy fuel in fast ignition experiment.

PubMed

Fujioka, Shinsuke; Fujiwara, Takashi; Tanabe, Minoru; Nishimura, Hiroaki; Nagatomo, Hideo; Ohira, Shinji; Inubushi, Yuichi; Shiraga, Hiroyuki; Azechi, Hiroshi

2010-10-01

Ultrafast, two-dimensional x-ray imaging is an important diagnostics for the inertial fusion energy research, especially in investigating implosion dynamics at the final stage of the fuel compression. Although x-ray radiography was applied to observing the implosion dynamics, intense x-rays emitted from the high temperature and dense fuel core itself are often superimposed on the radiograph. This problem can be solved by coupling the x-ray radiography with monochromatic x-ray imaging technique. In the experiment, 2.8 or 5.2 keV backlight x-rays emitted from laser-irradiated polyvinyl chloride or vanadium foils were selectively imaged by spherically bent quartz crystals with discriminating the out-of-band emission from the fuel core. This x-ray radiography system achieved 24 μm and 100 ps of spatial and temporal resolutions, respectively.

Simple solution-combustion synthesis of Ni-NiO@C nanocomposites with highly electrocatalytic activity for methanol oxidation

NASA Astrophysics Data System (ADS)

Yu, Jie; Ni, Yonghong; Zhai, Muheng

2018-01-01

Transition metal and its oxide composite nanomaterials are attracting increasing research interest due to their superior properties and extensive applications in many fields. In this paper, Ni-NiO@C nanocomposites were successfully synthesized in one step via a simple solution-combustion route, employing NiCl2 as the Ni source, oxygen in the atmosphere as the oxygen source, and ethanol as the solvent. The final product was characterized by powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), (high resolution) transmission electron microscopy (TEM/HRTEM), and Raman spectra. N2 gas sorption-desorption experiments uncovered that the BET surface area of Ni-NiO@C nanocomposites reached 161.9 m2 g-1, far higher than 34.2 m2 g-1 of Ni-NiO. The electrochemical measurement showed that the as-produced Ni-NiO@C nanocomposites presented better catalytic activity for the electro-oxidation of methanol than Ni-NiO and NiO, which provides a new catalyst selection for the electro-oxidation of methanol.

Cellulose aerogels functionalized with polypyrrole and silver nanoparticles: In-situ synthesis, characterization and antibacterial activity.

PubMed

Wan, Caichao; Li, Jian

2016-08-01

Green porous and lightweight cellulose aerogels have been considered as promising candidates to substitute some petrochemical host materials to support various nanomaterials. In this work, waste wheat straw was collected as feedstock to fabricate cellulose hydrogels, and a green inexpensive NaOH/polyethylene glycol solution was used as cellulose solvent. Prior to freeze-drying treatment, the cellulose hydrogels were integrated with polypyrrole and silver nanoparticles by easily-operated in-situ oxidative polymerization of pyrrole using silver ions as oxidizing agent. The tri-component hybrid aerogels were characterized by scanning electron microscope, transmission electron microscope, energy dispersive X-ray spectroscopy, selected area electron diffraction, X-ray photoelectron spectroscopy, and X-ray diffraction. Moreover, the antibacterial activity of the hybrid aerogels against Escherichia coli (Gram-negative), Staphylococcus aureus (Gram-positive) and Listeria monocytogenes (intracellular bacteria) was qualitatively and quantitatively investigated by parallel streak method and determination of minimal inhibitory concentration, respectively. This work provides an example of combining cellulose aerogels with nanomaterials, and helps to develop novel forms of cellulose-based functional materials. Copyright © 2016 Elsevier Ltd. All rights reserved.

The XXL Survey I. Scientific Motivations - Xmm-Newton Observing Plan - Follow-up Observations and Simulation Programme

NASA Technical Reports Server (NTRS)

Pierre, M.; Pacaud, F.; Adami, C.; Alis, S.; Altieri, B.; Baran, N.; Benoist, C.; Birkinshaw, M.; Bongiorno, A.; Bremer, M. N.;

The MYStIX Infrared-Excess Source Catalog

NASA Astrophysics Data System (ADS)

Povich, Matthew S.; Kuhn, Michael A.; Getman, Konstantin V.; Busk, Heather A.; Feigelson, Eric D.; Broos, Patrick S.; Townsley, Leisa K.; King, Robert R.; Naylor, Tim

2013-12-01

The Massive Young Star-Forming Complex Study in Infrared and X-rays (MYStIX) project provides a comparative study of 20 Galactic massive star-forming complexes (d = 0.4-3.6 kpc). Probable stellar members in each target complex are identified using X-ray and/or infrared data via two pathways: (1) X-ray detections of young/massive stars with coronal activity/strong winds or (2) infrared excess (IRE) selection of young stellar objects (YSOs) with circumstellar disks and/or protostellar envelopes. We present the methodology for the second pathway using Spitzer/IRAC, 2MASS, and UKIRT imaging and photometry. Although IRE selection of YSOs is well-trodden territory, MYStIX presents unique challenges. The target complexes range from relatively nearby clouds in uncrowded fields located toward the outer Galaxy (e.g., NGC 2264, the Flame Nebula) to more distant, massive complexes situated along complicated, inner Galaxy sightlines (e.g., NGC 6357, M17). We combine IR spectral energy distribution (SED) fitting with IR color cuts and spatial clustering analysis to identify IRE sources and isolate probable YSO members in each MYStIX target field from the myriad types of contaminating sources that can resemble YSOs: extragalactic sources, evolved stars, nebular knots, and even unassociated foreground/background YSOs. Applying our methodology consistently across 18 of the target complexes, we produce the MYStIX IRE Source (MIRES) Catalog comprising 20,719 sources, including 8686 probable stellar members of the MYStIX target complexes. We also classify the SEDs of 9365 IR counterparts to MYStIX X-ray sources to assist the first pathway, the identification of X-ray-detected stellar members. The MIRES Catalog provides a foundation for follow-up studies of diverse phenomena related to massive star cluster formation, including protostellar outflows, circumstellar disks, and sequential star formation triggered by massive star feedback processes.

Fast transient X-rays and gamma ray bursts - Are they stellar flares?

NASA Astrophysics Data System (ADS)

Rao, A. R.; Vahia, M. N.

Short period transient X-ray emissions (FTX) have been observed from several sources in the sky and the largest single group of objects identified with such sources are active stars: flare stars, and RS CVn binaries. The study of the number, source and flux distribution of the fast transient X-ray sources shows that all the FTX emission can be treated as flares in the interbinary regions of active stars. It is suggested that the FTX emission is a common feature of the gamma ray bursts (GRBs). The evidence for the similarity between the hard X-ray flares and GRBs is discussed, and the possibility that the gamma ray bursts are the impulsive precursors of FTX originating from active stars with large scale magnetic activity is examined.

Chandra X-Ray and Hubble Space Telescope Imaging of Optically Selected Kiloparsec-scale Binary Active Galactic Nuclei. II. Host Galaxy Morphology and AGN Activity

NASA Astrophysics Data System (ADS)

Shangguan, Jinyi; Liu, Xin; Ho, Luis C.; Shen, Yue; Peng, Chien Y.; Greene, Jenny E.; Strauss, Michael A.

2016-05-01

Binary active galactic nuclei (AGNs) provide clues to how gas-rich mergers trigger and fuel AGNs and how supermassive black hole (SMBH) pairs evolve in a gas-rich environment. While significant effort has been invested in their identification, the detailed properties of binary AGNs and their host galaxies are still poorly constrained. In a companion paper, we examined the nature of ionizing sources in the double nuclei of four kiloparsec-scale binary AGNs with redshifts between 0.1 and 0.2. Here, we present their host galaxy morphology based on F336W (U-band) and F105W (Y-band) images taken by the Wide Field Camera 3 on board the Hubble Space Telescope. Our targets have double-peaked narrow emission lines and were confirmed to host binary AGNs with follow-up observations. We find that kiloparsec-scale binary AGNs occur in galaxy mergers with diverse morphological types. There are three major mergers with intermediate morphologies and a minor merger with a dominant disk component. We estimate the masses of the SMBHs from their host bulge stellar masses and obtain Eddington ratios for each AGN. Compared with a representative control sample drawn at the same redshift and stellar mass, the AGN luminosities and Eddington ratios of our binary AGNs are similar to those of single AGNs. The U - Y color maps indicate that clumpy star-forming regions could significantly affect the X-ray detection of binary AGNs, e.g., the hardness ratio. Considering the weak X-ray emission in AGNs triggered in merger systems, we suggest that samples of X-ray-selected AGNs may be biased against gas-rich mergers. Based, in part, on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with program number GO 12363.

A giant radio flare from Cygnus X-3 with associated γ-ray emission

NASA Astrophysics Data System (ADS)

Corbel, S.; Dubus, G.; Tomsick, J. A.; Szostek, A.; Corbet, R. H. D.; Miller-Jones, J. C. A.; Richards, J. L.; Pooley, G.; Trushkin, S.; Dubois, R.; Hill, A. B.; Kerr, M.; Max-Moerbeck, W.; Readhead, A. C. S.; Bodaghee, A.; Tudose, V.; Parent, D.; Wilms, J.; Pottschmidt, K.

2012-04-01

With frequent flaring activity of its relativistic jets, Cygnus X-3 (Cyg X-3) is one of the most active microquasars and is the only Galactic black hole candidate with confirmed high-energy γ-ray emission, thanks to detections by Fermi Large Area Telescope (Fermi/LAT) and AGILE. In 2011, Cyg X-3 was observed to transit to a soft X-ray state, which is known to be associated with high-energy γ-ray emission. We present the results of a multiwavelength campaign covering a quenched state, when radio emission from Cyg X-3 is at its weakest and the X-ray spectrum is very soft. A giant (˜20 Jy) optically thin radio flare marks the end of the quenched state, accompanied by rising non-thermal hard X-rays. Fermi/LAT observations (E≥ 100 MeV) reveal renewed γ-ray activity associated with this giant radio flare, suggesting a common origin for all non-thermal components. In addition, current observations unambiguously show that the γ-ray emission is not exclusively related to the rare giant radio flares. A three-week period of γ-ray emission is also detected when Cyg X-3 was weakly flaring in radio, right before transition to the radio quenched state. No γ-rays are observed during the ˜1-month long quenched state, when the radio flux is weakest. Our results suggest transitions into and out of the ultrasoft X-ray (radio-quenched) state trigger γ-ray emission, implying a connection to the accretion process, and also that the γ-ray activity is related to the level of radio flux (and possibly shock formation), strengthening the connection to the relativistic jets.

A Giant Radio Flare from Cygnus X-3 with Associated Gamma-Ray Emission

NASA Technical Reports Server (NTRS)

Corbel, S.; Dubus, G.; Tomsick, J. A.; Szostek, A.; Corbet, R. H. D.; Miller-Jones, J. C. A.; Richards, J. L.; Pooley, G.; Trushkin, S.; Dubois, R.;

Mini-Survey Of SDSS of [OIII] AGN With Swift

NASA Technical Reports Server (NTRS)

Angelini, L.; George, I. M.; Hill, J.; Padgett, C. A.; Mushotzky, R. F.

2008-01-01

The number of AGN and their luminosity distribution are crucial parameters for our understanding of the AGN phenomenon. Recent work (e.g. Ferrarese and Merritt 2000) strongly suggests every massive galaxy has a central black hole. However, most of these objects either are not radiating or have been very difficult to detect. We are now in the era of large surveys, and the luminosity function (LF) of AGN has been estimated in various ways. In the X-ray band, Chandra and XMM surveys (e.g., Barger et al. 2005; Hasinger, et al. 2005) have revealed that the LF of Hard X-ray selected AGN shows a strong luminosity-dependent evolution with a dramatic break towards low L(x) (at al z). This is seen for all types of AGN, but is stronger for the broad-line objects (e.g., Steffen et al. 2004). In sharp contrast, the local LF of optically-selected samples shows no such break and no differences between narrow and broad-line objects (Hao et al. 2005). If, as been suggested, hard X-ray and optical emission line can both be fair indicators of AGN activity, it is important to first understand how reliable these characteristics are if we hope to understand the apparent discrepancy in the LFs.

Energy discriminating x-ray camera utilizing a cadmium telluride detector

NASA Astrophysics Data System (ADS)

Sato, Eiichi; Purkhet, Abderyim; Matsukiyo, Hiroshi; Osawa, Akihiro; Enomoto, Toshiyuki; Wantanabe, Manabu; Nagao, Jiro; Nomiya, Seiichiro; Hitomi, Keitaro; Tanaka, Etsuro; Kawai, Toshiaki; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2009-07-01

An energy-discriminating x-ray camera is useful for performing monochromatic radiography using polychromatic x rays. This x-ray camera was developed to carry out K-edge radiography using iodine-based contrast media. In this camera, objects are exposed by a cone beam from a cerium x-ray generator, and penetrating x-ray photons are detected by a cadmium telluride detector with an amplifier unit. The optimal x-ray photon energy and the energy width are selected out using a multichannel analyzer, and the photon number is counted by a counter card. Radiography was performed by the detector scanning using an x-y stage driven by a two-stage controller, and radiograms obtained by energy discriminating are shown on a personal computer monitor. In radiography, the tube voltage and current were 60 kV and 36 μA, respectively, and the x-ray intensity was 4.7 μGy/s. Cerium K-series characteristic x rays are absorbed effectively by iodine-based contrast media, and iodine K-edge radiography was performed using x rays with energies just beyond iodine K-edge energy 33.2 keV.

The use of C-near edge X-ray absorption fine structure spectroscopy for the elaboration of chemistry in lignocellulosics

Treesearch

Lucian A. Lucia; Hiroki Nanko; Alan W. Rudie; Doug G. Mancosky; Sue Wirick

2006-01-01

The research presented elucidates the oxidation chemistry occurring in hydrogen peroxide bleached kraft pulp fibers by employing carbon near edge x-ray absorption fine structure spectroscopy (C-NEXAFS). C-NEXAFS is a soft x-ray technique that selectively interrogates atomic moieties using photoelectrons (Xrays) of variable energies. The X1A beam line at the National...

X-ray cavities in a sample of 83 SPT-selected clusters of galaxies: Tracing the evolution of AGN feedback in clusters of galaxies out to z = 1.2

DOE PAGES

Hlavacek-Larrondo, J.; McDonald, M.; Benson, B. A.; ...

2015-05-18

X-ray cavities are key tracers of mechanical (or radio mode) heating arising from the active galactic nuclei (AGNs) in brightest cluster galaxies (BCGs). Here, we report on a survey for X-ray cavities in 83 massive, high-redshift (more » $$0.4\\lt z\\lt 1.2$$) clusters of galaxies selected by their Sunyaev-Zel'dovich signature in the South Pole Telescope data. Based on Chandra X-ray images, we find a total of six clusters having symmetric pairs of surface brightness depressions consistent with the picture of radio jets inflating X-ray cavities in the intracluster medium (ICM). Furthermore, the majority of these detections are of relatively low significance and require deeper follow-up data in order to be confirmed. Further, this search will miss small (<10 kpc) X-ray cavities that are unresolved by Chandra at high ($$z\\gtrsim 0.5$$) redshift. Despite these limitations, our results suggest that the power generated by AGN feedback in BCGs has remained unchanged for over half of the age of the universe ($$\\gt 7$$ Gyr at $$z\\sim 0.8$$). On average, the detected X-ray cavities have powers of $$(0.8-5)\\times {{10}^{45}}\\ {\\rm erg}\\ {{{\\rm s}}^{-1}}$$, enthalpies of $$(3-6)\\times {{10}^{59}}\\ {\\rm erg}$$, and radii of ~17 kpc. Integrating over 7 Gyr, we find that the supermassive black holes in BCGs may have accreted 108 to several $${{10}^{9}}\\;{{M}_{\\odot }}$$ of material to power these outflows. This level of accretion indicates that significant supermassive black hole growth may occur not only at early times, in the quasar era, but at late times as well. We also find that X-ray cavities at high redshift may inject an excess heat of 0.1–1.0 keV per particle into the hot ICM above and beyond the energy needed to offset cooling. Though our result needs to be confirmed, we note that the magnitude of excess heating is similar to the energy needed to preheat clusters, break self-similarity, and explain the excess entropy in hot atmospheres.« less

Use of Phage Display to Identify Novel Mineralocorticoid Receptor-Interacting Proteins

PubMed Central

Yang, Jun; Fuller, Peter J.; Morgan, James; Shibata, Hirotaka; McDonnell, Donald P.; Clyne, Colin D.

2014-01-01

The mineralocorticoid receptor (MR) plays a central role in salt and water homeostasis via the kidney; however, inappropriate activation of the MR in the heart can lead to heart failure. A selective MR modulator that antagonizes MR signaling in the heart but not the kidney would provide the cardiovascular protection of current MR antagonists but allow for normal electrolyte balance. The development of such a pharmaceutical requires an understanding of coregulators and their tissue-selective interactions with the MR, which is currently limited by the small repertoire of MR coregulators described in the literature. To identify potential novel MR coregulators, we used T7 phage display to screen tissue-selective cDNA libraries for MR-interacting proteins. Thirty MR binding peptides were identified, from which three were chosen for further characterization based on their nuclear localization and their interaction with other MR-interacting proteins or, in the case of x-ray repair cross-complementing protein 6, its known status as an androgen receptor coregulator. Eukaryotic elongation factor 1A1, structure-specific recognition protein 1, and x-ray repair cross-complementing protein 6 modulated MR-mediated transcription in a ligand-, cell- and/or promoter-specific manner and colocalized with the MR upon agonist treatment when imaged using immunofluorescence microscopy. These results highlight the utility of phage display for rapid and sensitive screening of MR binding proteins and suggest that eukaryotic elongation factor 1A1, structure-specific recognition protein 1, and x-ray repair cross-complementing protein 6 may be potential MR coactivators whose activity is dependent on the ligand, cellular context, and target gene promoter. PMID:25000480

Galaxy-scale Bars in Late-type Sloan Digital Sky Survey Galaxies Do Not Influence the Average Accretion Rates of Supermassive Black Holes

NASA Astrophysics Data System (ADS)

Goulding, A. D.; Matthaey, E.; Greene, J. E.; Hickox, R. C.; Alexander, D. M.; Forman, W. R.; Jones, C.; Lehmer, B. D.; Griffis, S.; Kanek, S.; Oulmakki, M.

2017-07-01

Galaxy-scale bars are expected to provide an effective means for driving material toward the central region in spiral galaxies, and possibly feeding supermassive black holes (BHs). Here we present a statistically complete study of the effect of bars on average BH accretion. From a well-selected sample of 50,794 spiral galaxies (with {M}* ˜ 0.2{--}30× {10}10 {M}⊙ ) extracted from the Sloan Digital Sky Survey Galaxy Zoo 2 project, we separate those sources considered to contain galaxy-scale bars from those that do not. Using archival data taken by the Chandra X-ray Observatory, we identify X-ray luminous ({L}{{X}}≳ {10}41 {erg} {{{s}}}-1) active galactic nuclei and perform an X-ray stacking analysis on the remaining X-ray undetected sources. Through X-ray stacking, we derive a time-averaged look at accretion for galaxies at fixed stellar mass and star-formation rate, finding that the average nuclear accretion rates of galaxies with bar structures are fully consistent with those lacking bars ({\\dot{M}}{acc}≈ 3× {10}-5 {M}⊙ yr-1). Hence, we robustly conclude that large-scale bars have little or no effect on the average growth of BHs in nearby (z< 0.15) galaxies over gigayear timescales.

Projection x-ray topography system at 1-BM x-ray optics test beamline at the advanced photon source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stoupin, Stanislav, E-mail: sstoupin@aps.anl.gov; Liu, Zunping; Trakhtenberg, Emil

2016-07-27

Projection X-ray topography of single crystals is a classic technique for the evaluation of intrinsic crystal quality of large crystals. In this technique a crystal sample and an area detector (e.g., X-ray film) collecting intensity of a chosen crystallographic reflection are translated simultaneously across an X-ray beam collimated in the diffraction scattering plane (e.g., [1, 2]). A bending magnet beamline of a third-generation synchrotron source delivering x-ray beam with a large horizontal divergence, and therefore, a large horizontal beam size at a crystal sample position offers an opportunity to obtain X-ray topographs of large crystalline samples (e.g., 6-inch wafers) inmore » just a few exposures. Here we report projection X-ray topography system implemented recently at 1-BM beamline of the Advanced Photon Source. A selected X-ray topograph of a 6-inch wafer of 4H-SiC illustrates capabilities and limitations of the technique.« less

Bimetal-organic frameworks for functionality optimization: MnFe-MOF-74 as a stable and efficient catalyst for the epoxidation of alkenes with H2O2.

PubMed

Yuan, Kuo; Song, Tianqun; Wang, Dawei; Zou, Ye; Li, Jinfeng; Zhang, Xiaotao; Tang, Zhiyong; Hu, Wenping

2018-01-25

In this work, we synthesized a series of microcrystalline Mn x N 100-x -MOF-74 (N = Fe, Co and Ni) materials by a one-pot reaction. Powder X-ray diffraction (PXRD) patterns of Mn x N 100-x -MOF-74 matched well with those of single-metal MOF-74, and the scanning electron microscopy (SEM) images exhibited homogeneous nanocrystallites aggregated together. The amounts and dispersion of metals were analyzed by using inductively coupled plasma (ICP) and energy-dispersive X-ray spectroscopy (EDS), separately. Mn x N 100-x -MOF-74 could remain crystalline and efficiently catalyze the epoxidation of alkenes in DMF with NaHCO 3 and 30% H 2 O 2 . In particular, Mn 29.39 Fe 70.61 -MOF-74 can achieve almost 100% conversion for styrene with 95.0% selectivity towards styrene oxide and be reused at least five times without loss of activity.

The complete Einstein Observatory X-ray survey of the Orion Nebula region.

NASA Technical Reports Server (NTRS)

Gagne, Marc; Caillault, Jean-Pierre

1994-01-01

We have analyzed archival Einstein Observatory images of a roughly 4.5 square degree region centered on the Orion Nebula. In all, 245 distinct X-ray sources have been detected in six High Resolution Imager (HRI) and 17 Imaging Proportional Counter (IPC) observations. An optical database of over 2700 stars has been assembled to search for candidate counterparts to the X-ray sources. Roughly half the X-ray sources are identified with a single Orion Nebula cluster member. The 10 main-sequence O6-B5 cluster stars detected in Orion have X-ray activity levels comparable to field O and B stars. X-ray emission has also been detected in the direction of four main-sequence late-B and early-A type stars. Since the mechanisms producing X-rays in late-type coronae and early-type winds cannot operate in the late-B and early-A type atmospheres, we argue that the observed X-rays, with L(sub X) approximately = 3 x 10(exp 30) ergs/s, are probably produced in the coronae of unseen late-type binary companions. Over 100 X-ray sources have been associated with late-type pre-main sequence stars. The upper envelope of X-ray activity rises sharply from mid-F to late-G, with L(sub x)/L(sub bol) in the range 10(exp -4) to 2 x 10(exp -3) for stars later than approximately G7. We have looked for variability of the late-type cluster members on timescales of a day to a year and find that 1/4 of the stars show significantly variable X-ray emission. A handful of the late-type stars have published rotational periods and spectroscopic rotational velocities; however, we see no correlation between X-ray activity and rotation. Thus, for this sample of pre-main-sequence stars, the large dispersion in X-ray activity does not appear to be caused by the dispersion in rotation, in contrast with results obtained for low-mass main-sequence stars in the Pleiades and pre-main-sequence stars in Taurus-Auriga.

Exploring the X-Ray Universe

NASA Astrophysics Data System (ADS)

Seward, Frederick D.; Charles, Philip A.

1995-11-01

Exploring the X-Ray Universe describes the view of the stars and galaxies that is obtained through X-ray telescopes. X-rays, which are invisible to human sight, are created in the cores of active galaxies, in cataclysmic stellar explosions, and in streams of gas expelled by the Sun and stars. The window on the heavens used by the X-ray astronomers shows the great drama of cosmic violence on the grandest scale.

Preparation of K-doped TiO2 nanostructures by wet corrosion and their sunlight-driven photocatalytic performance

NASA Astrophysics Data System (ADS)

Shin, Eunhye; Jin, Saera; Kim, Jiyoon; Chang, Sung-Jin; Jun, Byung-Hyuk; Park, Kwang-Won; Hong, Jongin

2016-08-01

K-doped TiO2 nanowire networks were prepared by the corrosion reaction of Ti nanoparticles in an alkaline (potassium hydroxide: KOH) solution. The prepared nanostructures were characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) analysis, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, X-ray diffraction (XRD) and photoluminescence (PL) spectra. Their sunlight-driven photocatalytic activity was also investigated with differently charged dye molecules, such as methylene blue, rhodamine B and methyl orange. The adsorption of the dye molecules on the photocatalyst surface would play a critical role in their selective photodegradation under sunlight illumination.

High-Resolution Spectroscopy with the Chandra X-ray Observatory

ScienceCinema

Canizares, Claude R. [MIT, Cambridge, Massachusetts, United States

2017-12-09

The capabilities of the Chandra X-ray Observatory and XMM-Newton for high-resolution spectroscopy have brought tradition plasma diagnostic techniques to the study of cosmic plasma. Observations have probed nearly every class of astronomical object, from young proto-starts through massive O starts and black hole binaries, supernova remnants, active galactic nuclei, and the intergalactic medium. Many of these sources show remarkable rich spectra that reveal new physical information, such as emission measure distributions, elemental abundances, accretion disk and wind signatures, and time variability. This talk will present an overview of the Chandra instrumentaton and selected examples of spectral observations of astrophysical and cosmological importance.

A Study of the Structure-Activity Relationship of GABAA-Benzodiazepine Receptor Bivalent Ligands by Conformational Analysis with Low Temperature NMR and X-ray Analysis

PubMed Central

Han, Dongmei; Försterling, F. Holger; Li, Xiaoyan; Deschamps, Jeffrey R.; Parrish, Damon; Cao, Hui; Rallapalli, Sundari; Clayton, Terry; Teng, Yun; Majumder, Samarpan; Sankar, Subramaniam; Roth, Bryan L.; Sieghart, Werner; Furtmuller, Roman; Rowlett, James; Weed, Mike R.; Cook, James M.

2013-01-01

The stable conformations of GABAA-benzodiazepine receptor bivalent ligands were determined by low temperature NMR spectroscopy and confirmed by single crystal X-ray analysis. The stable conformations in solution correlated well with those in the solid state. The linear conformation was important for these dimers to access the binding site and exhibit potent in vitro affinity and was illustrated for α5 subtype selective ligands. Bivalent ligands with an oxygen-containing linker folded back upon themselves both in solution and the solid state. Dimers which are folded do not bind to Bz receptors. PMID:18790643

Fabrication and testing of a newly designed slit system for depth-resolved X-ray diffraction measurements

DOE PAGES

Sinsheimer, John; Bouet, Nathalie; Ghose, Sanjit; ...

2016-10-06

A new system of slits called `spiderweb slits' have been developed for depth-resolved powder or polycrystalline X-ray diffraction measurements. The slits act on diffracted X-rays to select a particular gauge volume of sample, while absorbing diffracted X-rays from outside of this volume. Although the slit geometry is to some extent similar to that of previously developed conical slits or spiral slits, this new design has advantages over the previous ones in use for complex heterogeneous materials and in situ and operando diffraction measurements. For example, the slits can measure a majority of any diffraction cone for any polycrystalline material, overmore » a continuous range of diffraction angles, and work for X-ray energies of tens to hundreds of kiloelectronvolts. In addition, the design is generated and optimized using ray-tracing simulations, and fabricated through laser micromachining. The first prototype was successfully tested at the X17A beamline at the National Synchrotron Light Source, and shows similar performance to simulations, demonstrating gauge volume selection for standard powders, for all diffraction peaks over angles of 2–10°. A similar, but improved, design will be implemented at the X-ray Powder Diffraction beamline at the National Synchrotron Light Source II.« less

Fabrication and testing of a newly designed slit system for depth-resolved X-ray diffraction measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sinsheimer, John; Bouet, Nathalie; Ghose, Sanjit

2016-10-06

A new system of slits called `spiderweb slits' have been developed for depth-resolved powder or polycrystalline X-ray diffraction measurements. The slits act on diffracted X-rays to select a particular gauge volume of sample, while absorbing diffracted X-rays from outside of this volume. Although the slit geometry is to some extent similar to that of previously developed conical slits or spiral slits, this new design has advantages over the previous ones in use for complex heterogeneous materials andin situandoperandodiffraction measurements. For example, the slits can measure a majority of any diffraction cone for any polycrystalline material, over a continuous range ofmore » diffraction angles, and work for X-ray energies of tens to hundreds of kiloelectronvolts. The design is generated and optimized using ray-tracing simulations, and fabricated through laser micromachining. The first prototype was successfully tested at the X17A beamline at the National Synchrotron Light Source, and shows similar performance to simulations, demonstrating gauge volume selection for standard powders, for all diffraction peaks over angles of 2–10°. A similar, but improved, design will be implemented at the X-ray Powder Diffraction beamline at the National Synchrotron Light Source II.« less

NuSTAR Observations of Heavily Obscured Quasars Selected by WISE

NASA Astrophysics Data System (ADS)

Yan, Wei

2017-08-01

A key goal of the Nuclear Spectroscopic Telescope Array (NuSTAR) program is to find and characterize heavily obscured quasars, luminous accreting supermassive black holes hidden by gas and dust. Based on mid-infrared (IR) photometry from Wide-Field Infrared Survey Explorer (WISE) and optical photometry from the Sloan Digital Sky Surveys, we have selected a large population of obscured quasars; here we report the NuSTAR observations of four WISE-selected heavily obscured quasars for which we have optical spectroscopy from the Southern African Large Telescope and KECK Telescope. Three of four objects are undetected with NuSTAR, while the fourth has only a marginal detection. We confirm our objects have observed hard X-ray (10-40 keV) luminosities at or below ~1043 erg s-1. We compare IR and X-ray luminosities to obtain estimates of hydrogen column NH based on the suppression of the hard X-ray emission. We estimate NH to be at or greater than 1025 cm-2, confirming that WISE and optical selection can identify very heavily obscured quasars that may be missed in X-ray surveys.

X-ray astronomy from Uhuru to HEAO-1

NASA Technical Reports Server (NTRS)

Clark, G. W.

1981-01-01

The nature of galactic and extragalactic X-ray sources is investigated using observations made with nine satellites and several rockets. The question of X-ray pulsars being neutron stars or white dwarfs is considered, as is the nature of Population II and low-luminosity X-ray stars, the diffuse X-ray emission from clusters of galaxies, the unidentified high-galactic-latitude (UHGL) sources, and the unresolved soft X-ray background. The types of sources examined include binary pulsars, Population II X-ray stars (both nonbursters and bursters) inside and outside globular clusters, coronal X-ray emitters, and active galactic nuclei. It is concluded that: (1) X-ray pulsars are strongly magnetized neutron stars formed in the evolution of massive close binaries; (2) all Population II X-ray stars are weakly magnetized or nonmagnetic neutron stars accreting from low-mass companions in close binary systems; (3) the diffuse emission from clusters is thermal bremsstrahlung of hot matter processed in stars and swept out by ram pressure exerted by the intergalactic gas; (4) most or all of the UHGL sources are active galactic nuclei; and (5) the soft X-ray background is emission from a hot component of the interstellar medium.

Spatially resolved quantification of agrochemicals on plant surfaces using energy dispersive X-ray microanalysis.

PubMed

Hunsche, Mauricio; Noga, Georg

2009-12-01

In the present study the principle of energy dispersive X-ray microanalysis (EDX), i.e. the detection of elements based on their characteristic X-rays, was used to localise and quantify organic and inorganic pesticides on enzymatically isolated fruit cuticles. Pesticides could be discriminated from the plant surface because of their distinctive elemental composition. Findings confirm the close relation between net intensity (NI) and area covered by the active ingredient (AI area). Using wide and narrow concentration ranges of glyphosate and glufosinate, respectively, results showed that quantification of AI requires the selection of appropriate regression equations while considering NI, peak-to-background (P/B) ratio, and AI area. The use of selected internal standards (ISs) such as Ca(NO(3))(2) improved the accuracy of the quantification slightly but led to the formation of particular, non-typical microstructured deposits. The suitability of SEM-EDX as a general technique to quantify pesticides was evaluated additionally on 14 agrochemicals applied at diluted or regular concentration. Among the pesticides tested, spatial localisation and quantification of AI amount could be done for inorganic copper and sulfur as well for the organic agrochemicals glyphosate, glufosinate, bromoxynil and mancozeb. (c) 2009 Society of Chemical Industry.

VizieR Online Data Catalog: New gamma-ray blazar candidates in the 3PBC (Maselli+, 2013)

NASA Astrophysics Data System (ADS)

Maselli, A.; Massaro, F.; Cusumano, G.; D'Abrusco, R.; La Parola, V.; Paggi, A.; Segreto, A.; Smith, H. A.; Tosti, G.

2013-06-01

We searched for γ-ray blazar candidates among the 382 unidentified hard X-ray sources of the third Palermo BAT Catalog (3PBC) obtained from the analysis of 66 months of Swift Burst Alert Telescope (BAT) survey data and listing 1586 sources. We adopted a recently developed association method based on the peculiar infrared colors that characterize the γ-ray blazars included in the second catalog of active galactic nuclei detected by the Fermi Large Area Telescope. We used this method exploiting the data of the all-sky survey performed by the Wide-field Infrared Survey Explorer (WISE) to establish correspondences between unidentified 3PBC sources and WISE γ-ray blazar candidates located within the BAT positional uncertainty region at a 99% confidence level. We obtained a preliminary list of candidates for which we analyzed all the available data in the Swift archive to complement the information in the literature and in the radio, infrared, and optical catalogs with the information on their optical-UV and soft X-ray emission. Requiring the presence of radio and soft X-ray counterparts consistent with the infrared positions of the selected WISE sources, as well as a blazar-like radio morphology, we finally obtained a list of 24 γ-ray blazar candidates. (2 data files).

The ROSAT Brightest Cluster Sample - I. The compilation of the sample and the cluster log N-log S distribution

NASA Astrophysics Data System (ADS)

Ebeling, H.; Edge, A. C.; Bohringer, H.; Allen, S. W.; Crawford, C. S.; Fabian, A. C.; Voges, W.; Huchra, J. P.

1998-12-01

We present a 90 per cent flux-complete sample of the 201 X-ray-brightest clusters of galaxies in the northern hemisphere (delta>=0 deg), at high Galactic latitudes (|b|>=20 deg), with measured redshifts z<=0.3 and fluxes higher than 4.4x10^-12 erg cm^-2 s^-1 in the 0.1-2.4 keV band. The sample, called the ROSAT Brightest Cluster Sample (BCS), is selected from ROSAT All-Sky Survey data and is the largest X-ray-selected cluster sample compiled to date. In addition to Abell clusters, which form the bulk of the sample, the BCS also contains the X-ray-brightest Zwicky clusters and other clusters selected from their X-ray properties alone. Effort has been made to ensure the highest possible completeness of the sample and the smallest possible contamination by non-cluster X-ray sources. X-ray fluxes are computed using an algorithm tailored for the detection and characterization of X-ray emission from galaxy clusters. These fluxes are accurate to better than 15 per cent (mean 1sigma error). We find the cumulative logN-logS distribution of clusters to follow a power law kappa S^alpha with alpha=1.31^+0.06_-0.03 (errors are the 10th and 90th percentiles) down to fluxes of 2x10^-12 erg cm^-2 s^-1, i.e. considerably below the BCS flux limit. Although our best-fitting slope disagrees formally with the canonical value of -1.5 for a Euclidean distribution, the BCS logN-logS distribution is consistent with a non-evolving cluster population if cosmological effects are taken into account. Our sample will allow us to examine large-scale structure in the northern hemisphere, determine the spatial cluster-cluster correlation function, investigate correlations between the X-ray and optical properties of the clusters, establish the X-ray luminosity function for galaxy clusters, and discuss the implications of the results for cluster evolution.

The Evolution of Swift/BAT blazars and the origin of the MeV background

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ajello, M.; /SLAC /KIPAC, Menlo Park; Costamante, L.

2009-10-17

We use 3 years of data from the Swift/BAT survey to select a complete sample of X-ray blazars above 15 keV. This sample comprises 26 Flat-Spectrum Radio Quasars (FSRQs) and 12 BL Lac objects detected over a redshift range of 0.03 < z < 4.0. We use this sample to determine, for the first time in the 15-55 keV band, the evolution of blazars. We find that, contrary to the Seyfert-like AGNs detected by BAT, the population of blazars shows strong positive evolution. This evolution is comparable to the evolution of luminous optical QSOs and luminous X-ray selected AGNs. Wemore » also find evidence for an epoch-dependence of the evolution as determined previously for radio-quiet AGNs. We interpret both these findings as a strong link between accretion and jet activity. In our sample, the FSRQs evolve strongly, while our best-fit shows that BL Lacs might not evolve at all. The blazar population accounts for 10-20% (depending on the evolution of the BL Lacs) of the Cosmic X-ray background (CXB) in the 15-55 keV band. We find that FSRQs can explain the entire CXB emission for energies above 500 keV solving the mystery of the generation of the MeV background. The evolution of luminous FSRQs shows a peak in redshift (z{sub c} = 4.3 {+-} 0.5) which is larger than the one observed in QSOs and X-ray selected AGNs. We argue that FSRQs can be used as tracers of massive elliptical galaxies in the early Universe.« less

Cosmological hydrodynamical simulations of galaxy clusters: X-ray scaling relations and their evolution

NASA Astrophysics Data System (ADS)

Truong, N.; Rasia, E.; Mazzotta, P.; Planelles, S.; Biffi, V.; Fabjan, D.; Beck, A. M.; Borgani, S.; Dolag, K.; Gaspari, M.; Granato, G. L.; Murante, G.; Ragone-Figueroa, C.; Steinborn, L. K.

2018-03-01

We analyse cosmological hydrodynamical simulations of galaxy clusters to study the X-ray scaling relations between total masses and observable quantities such as X-ray luminosity, gas mass, X-ray temperature, and YX. Three sets of simulations are performed with an improved version of the smoothed particle hydrodynamics GADGET-3 code. These consider the following: non-radiative gas, star formation and stellar feedback, and the addition of feedback by active galactic nuclei (AGN). We select clusters with M500 > 1014 M⊙E(z)-1, mimicking the typical selection of Sunyaev-Zeldovich samples. This permits to have a mass range large enough to enable robust fitting of the relations even at z ˜ 2. The results of the analysis show a general agreement with observations. The values of the slope of the mass-gas mass and mass-temperature relations at z = 2 are 10 per cent lower with respect to z = 0 due to the applied mass selection, in the former case, and to the effect of early merger in the latter. We investigate the impact of the slope variation on the study of the evolution of the normalization. We conclude that cosmological studies through scaling relations should be limited to the redshift range z = 0-1, where we find that the slope, the scatter, and the covariance matrix of the relations are stable. The scaling between mass and YX is confirmed to be the most robust relation, being almost independent of the gas physics. At higher redshifts, the scaling relations are sensitive to the inclusion of AGNs which influences low-mass systems. The detailed study of these objects will be crucial to evaluate the AGN effect on the ICM.

X-Ray Emission from Ultraviolet Luminous Galaxies and Lyman Break Galaxies

NASA Technical Reports Server (NTRS)

Hornschemeier, Ann; Ptak, A. F.; Salim, S.; Heckman, T. P.; Overzier, R.; Mallery, R.; Rich, M.; Strickland, D.; Grimes, J.

2009-01-01

We present results from an XMM mini-survey of GALEX-selected Ultraviolet-Luminous Galaxies (UVLGs) that appear to include an interesting subset that are analogs to the distant (3

The TESIS Project: Are Type 2 QSO Hidden in X-Ray Emitting EROs?

NASA Astrophysics Data System (ADS)

Severgnini, P.; Della Ceca, R.; Braito, V.; Saracco, P.; Longhetti, M.; Bender, R.; Drory, N.; Feulner, G.; Hopp, U.; Mannucci, F.; Maraston, C.

X-ray selected EROs are, on average, the hardest X-ray sources in medium and deep X-ray fields. This coupled with their extremely red colors (R-K > 5) suggest that they represent one of the most promising population where looking for high-luminosity (LX > 1044 erg s-1) and X-ray obscured (NH > 1022 cm-2) type2 AGNs, the so called QSO2 (e.g., [5]; [4]; Mignoli et al. submitted to A&A). These latter are predicted in large density by the synthesis model of the Cosmic X-ray background [9] even if only few observational evidences have been found so far (e.g., [1] and references therein; Caccianiga et al. A&A accepted).

Multiwavelength study of the flaring activity of Sagittarius A* in 2014 February-April

NASA Astrophysics Data System (ADS)

Mossoux, E.; Grosso, N.; Bushouse, H.; Eckart, A.; Yusef-Zadeh, F.; Plambeck, D.; Peissker, F.; Valencia-S., M.; Porquet, D.; Roberts, D.

2017-10-01

We studied the flaring activity of the Galactic Center supermassive black hole Sgr A* close to the DSO/G2 pericenter passage with XMM-Newton, HST/WFC3, VLT/SINFONI, VLA and CARMA. We detected 3 and 2 NIR and 2 X-ray flares with HST, VLT and XMM-Newton, respectively. The Mar. 10 X-ray flare has a long rise and a rapid decay. Its NIR counterpart peaked before the X-ray peak implying a variation in the X-ray-to-NIR flux ratio. This flare may be one flare created by the adiabatic compression of a plasmon or 2 close flares with simultaneous X-ray/NIR peaks. The rising radio flux-density observed on Mar. 10 with the VLA could be the delayed emission from a NIR/X-ray flare preceding our observations. On Apr. 2, we observed the start of the NIR counterpart of the X-ray flare and the end of a bright NIR flare without X-ray counterpart. We studied the physical parameters of the flaring region for each NIR flare but none of the radiative processes can be ruled out for the X-ray flares creation. Our X-ray flaring rate is consistent with those observed in the 2012 Chandra/XVP campaign. No increase in the flaring activity was thus triggered close to the DSO/G2 pericenter passage.

Novel visualization studies of lignocellulosic oxidation chemistry by application of C-near edge X-ray absorption fine structure spectroscopy

Treesearch

Douglas G. Mancosky; Lucian A. Lucia; Hiroki Nanko; Sue Wirick; Alan W. Rudie; Robert Braun

2005-01-01

The research presented herein is the first attempt to probe the chemical nature of lignocellulosic samples by the application of carbon near edge X-ray absorption fine structure spectroscopy (C-NEXAFS). C-NEXAFS is a soft X-ray technique that principally provides selective interrogation of discrete atomic moieties using photoelectrons of variable energies. The X1A beam...

An Einstein Observatory SAO-based catalog of B-type stars

NASA Technical Reports Server (NTRS)

Grillo, F.; Sciortino, S.; Micela, G.; Vaiana, G. S.; Harnden, F. R., Jr.

1992-01-01

About 4000 X-ray images obtained with the Einstein Observatory are used to measure the 0.16-4.0 keV emission from 1545 B-type SAO stars falling in the about 10 percent of the sky surveyed with the IPC. Seventy-four detected X-ray sources with B-type stars are identified, and it is estimated that no more than 15 can be misidentified. Upper limits to the X-ray emission of the remaining stars are presented. In addition to summarizing the X-ray measurements and giving other relevant optical data, the present extensive catalog discusses the reduction process and analyzes selection effects associated with both SAO catalog completeness and IPC target selection procedures. It is concluded that X-ray emission, at the level of Lx not less than 10 exp 30 ergs/s, is quite common in B stars of early spectral types (B0-B3), regardless of luminosity class, but that emission, at the same level, becomes less common, or nonexistent, in later B-type stars.

X-ray lithography masking

NASA Technical Reports Server (NTRS)

Smith, Henry I. (Inventor); Lim, Michael (Inventor); Carter, James (Inventor); Schattenburg, Mark (Inventor)

1998-01-01

X-ray masking apparatus includes a frame having a supporting rim surrounding an x-ray transparent region, a thin membrane of hard inorganic x-ray transparent material attached at its periphery to the supporting rim covering the x-ray transparent region and a layer of x-ray opaque material on the thin membrane inside the x-ray transparent region arranged in a pattern to selectively transmit x-ray energy entering the x-ray transparent region through the membrane to a predetermined image plane separated from the layer by the thin membrane. A method of making the masking apparatus includes depositing back and front layers of hard inorganic x-ray transparent material on front and back surfaces of a substrate, depositing back and front layers of reinforcing material on the back and front layers, respectively, of the hard inorganic x-ray transparent material, removing the material including at least a portion of the substrate and the back layers of an inside region adjacent to the front layer of hard inorganic x-ray transparent material, removing a portion of the front layer of reinforcing material opposite the inside region to expose the surface of the front layer of hard inorganic x-ray transparent material separated from the inside region by the latter front layer, and depositing a layer of x-ray opaque material on the surface of the latter front layer adjacent to the inside region.

Towards A Complete Census of the Compton-thick AGN population and the NH Distribution of AGN in the Local Universe.

NASA Astrophysics Data System (ADS)

Annuar, A.

2015-09-01

We present updated results from an ongoing project to establish the most unbiased census of the Compton- thick active galactic nucleus (CTAGN) population and the intrinsic column density (NH) distribution of the overall AGN population in the local universe, using a sample of mid-infrared (mid-IR) selected AGN within 15 Mpc. We find that 20% of the AGN in the sample are bona-fide CTAGN based upon hard X-ray studies (E > 10 keV). More candidates are then selected using multiwavelength techniques, i.e. mid-IR:X-ray and optical [OIII]5007:X-ray flux ratios. Based on these analyses along with evidence from previous literature, we initially find a further 25% of potential candidates. We then observed two of these candidates, NGC 5643 and NGC 3486, using NuSTAR and is able to confirm the former as a CTAGN and rule out the latter as an obscured AGN. This constrains the total CTAGN population in the sample to 25-40%, though it could potentially be as high as 65% accounting for those that still lack data. Finally, we use these results to estimate the intrinsic NH distribution of the local AGN population. Two more of our CTAGN candidates are scheduled to be observed by NuSTAR, bringing the completeness of hard X-ray energy data of the sample to 65%. This work provides a well-defined local benchmark for AGN unification studies.

The Generation-X X-ray Observatory Vision Mission and Technology Study

NASA Technical Reports Server (NTRS)

Figueroa-Feliciano, Enectali

2004-01-01

The new frontier in astrophysics is the study of the birth and evolution of the first stars, galaxies and black holes in the early Universe. X-ray astronomy opens a window into these objects by studying the emission from black holes, supernova explosions and the gamma-ray burst afterglows of massive stars. However, such objects are beyond the grasp of current or near-future observatories. X-ray imaging and spectroscopy of such distant objects will require an X-ray telescope with large collecting area and high angular resolution. Our team has conceived the Generation-X Vision Mission based on an X-ray observatory with 100 sq m collecting area at 1 keV (1000 times larger than Chandra) and 0.1 arcsecond angular resolution (several times better than Chandra and 50 times better than the Constellation-X resolution goal). Such an observatory would be capable of detecting the earliest black holes and galaxies in the Universe, and will also study extremes of density, gravity, magnetic fields, and kinetic energy which cannot be created in laboratories. NASA has selected the Generation-X mission for study under its Vision Mission Program. We describe the studies being performed to develop the mission concept and define candidate technologies and performance requirements for Generation-X. The baseline Generation-X mission involves four 8m diameter X-ray telescopes operating at Sun-Earth L2. We trade against an alternate concept of a single 26m diameter telescope with focal plane instruments on a separate spacecraft. A telescope of this size will require either robotic or human-assisted in-flight assembly. The required effective area implies that extremely lightweight grazing incidence X-ray optics must be developed. To achieve the required aerial density of at least 100 times lower than in Chandra, we will study 0.1mm thick mirrors which have active on-orbit figure control. We discuss the suite of required detectors, including a large FOV high angular resolution imager, a cryogenic imaging spectrometer and a grating spectrometer. We outline the development roadmap to confront the many technological challenges far implementing the Generation-X mission.

Disentangling Dominance: Obscured AGN Activity versus Star Formation in BPT-Composites

NASA Astrophysics Data System (ADS)

Trouille, Laura

2011-11-01

Approximately 20% of SDSS emission-line galaxies (ELG) lie in the BPT-comp regime, between the Kauffmann et al. (2003) empirically determined SF-dominated regime and the Kewley et al. (2001) theoretically predicted AGN-dominated regime. BPT-AGN, on the other hand, make up only 11% of the ELG population. Whether to include the significant number of BPT-comp in samples of AGN or samples of star-forming galaxies is an open question and has important implications for galaxy evolution studies, metallicity studies, etc. Using a large pectroscopic sample of GOODS-N and LH galaxies with deep Chandra imaging, we perform an X-ray stacking analysis of BPT-comp. We find the stacked signal to be X-ray hard. This X-ray hardness can be indicative of obscured AGN activity or the presence of HMXBs associated with ongoing star formation. In order to distinguish between these scenarios, we perform an IR stacking analysis using Spitzer 24 micron data. The stacked BPT-comp lies well above the expected value for L_x/L_IR for pure star-forming galaxies; similarly for the X-ray detected BPT-comp. We also find that the BPT-comp lie in the AGN-dominated regime of our new TBT diagnostic, which uses [NeIII]/[OII] versus rest-frame g-z colour to identify AGN and star forming galaxies out to z=1.4. [NeIII], which has a higher ionisation potential than other commonly used forbidden emission lines, appears to foster a more reliable selection of AGN-dominated galaxies. These findings suggest that both the X-ray and optical signal in BPT-comp are dominated by obscured or low accretion rate AGN activity rather than star formation. This is in contrast to claims by previous optical emission-line studies that the signal in BPT-comp is dominated by star-formation activity. Therefore, we recommend that groups carefully consider the impact of excluding or including BPT-comp on the interpretation of their results. For example, for studies involving determining the bolometric contribution from AGN activity or the role of AGN activity in galaxy evolution, we advise maximal inclusiveness. Since BPT-comp comprise a significant percentage of the overall emission-line galaxy population, inclusion of the BPT-comp would provide a more comprehensive picture of the true impact of AGN activity in these studies.

Rocket studies of solar corona and transition region. [X-Ray spectrometer/spectrograph telescope

NASA Technical Reports Server (NTRS)

Acton, L. W.; Bruner, E. C., Jr.; Brown, W. A.; Nobles, R. A.

1979-01-01

The XSST (X-Ray Spectrometer/Spectrograph Telescope) rocket payload launched by a Nike Boosted Black Brant was designed to provide high spectral resolution coronal soft X-ray line information on a spectrographic plate, as well as time resolved photo-electric records of pre-selected lines and spectral regions. This spectral data is obtained from a 1 x 10 arc second solar region defined by the paraboloidal telescope of the XSST. The transition region camera provided full disc images in selected spectral intervals originating in lower temperature zones than the emitting regions accessible to the XSST. A H-alpha camera system allowed referencing the measurements to the chromospheric temperatures and altitudes. Payload flight and recovery information is provided along with X-ray photoelectric and UV flight data, transition camera results and a summary of the anomalies encountered. Instrument mechanical stability and spectrometer pointing direction are also examined.

Studies of the evolution of the x ray emission of clusters of galaxies

NASA Technical Reports Server (NTRS)

Henry, J. Patrick

1990-01-01

The x ray luminosity function of clusters of galaxies was determined at different cosmic epoches using data from the Einstein Observatory Extended Medium Survey. The sample consisted of 67 x ray selected clusters that were grouped into three redshift shells. Evolution was detected in the x ray properties of clusters. The present volume density of high luminosity clusters was found to be greater than it was in the past. This result is the first convincing evidence for evolution in the x ray properties of clusters. Investigations into the constraints provided by these data on various Cold Dark Matter models are underway.

Patient doses in the healing arts

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Determinations of radiation doses to patients from x-ray procedures and radiopharmaceuticals are detailed in this chapter. Instructions are given for estimating doses from x-ray procedures. For selected pediatric procedures, the methodology developed by the Food and Drug Administration is presented. The effect of testicular and ovarian shielding is illustrated in tabular form. Estimates of the Genetically Significant Dose (GSD) and mean annual bone marrow dose from diagnostic x-ray examinations are presented for the US populations (1990). This chapter also provides tables of patient doses from selected nuclear medicine procedures and estimates of fetal doses from {sup 131}I.

The XMM-Newton Extended Survey of the Taurus Molecular Cloud (XEST)

NASA Technical Reports Server (NTRS)

Guedel, M.; Briggs, K. R.; Arzner, K.; Audard, M.; Bouvier, J.; Feigelson, E. D.; Franciosini, E.; Glauser, A.; Grosso, N.; Micela, G.;

Lifetime-vibrational interference effects in resonantly excited x-ray emission spectra of CO

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skytt, P.; Glans, P.; Gunnelin, K.

1997-04-01

The parity selection rule for resonant X-ray emission as demonstrated for O{sub 2} and N{sub 2} can be seen as an effect of interference between coherently excited degenerate localized core states. One system where the core state degeneracy is not exact but somewhat lifted was previously studied at ALS, namely the resonant X-ray emission of amino-substituted benzene (aniline). It was shown that the X-ray fluorescence spectrum resulting from excitation of the C1s at the site of the {open_quotes}aminocarbon{close_quotes} could be described in a picture separating the excitation and the emission processes, whereas the spectrum corresponding to the quasi-degenerate carbons couldmore » not. Thus, in this case it was necessary to take interference effects between the quasi-degenerate intermediate core excited states into account in order to obtain agreement between calculations and experiment. The different vibrational levels of core excited states in molecules have energy splittings which are of the same order of magnitude as the natural lifetime broadening of core excitations in the soft X-ray range. Therefore, lifetime-vibrational interference effects are likely to appear and influence the band shapes in resonant X-ray emission spectra. Lifetime-vibrational interference has been studied in non-resonant X-ray emission, and in Auger spectra. In this report the authors discuss results of selectively excited soft X-ray fluorescence spectra of molecules, where they focus on lifetime-interference effects appearing in the band shapes.« less

Probing the Complex Architecture of Multimodular Carbohydrate-Active Enzymes Using a Combination of Small Angle X-Ray Scattering and X-Ray Crystallography.

PubMed

Czjzek, Mirjam; Ficko-Blean, Elizabeth

2017-01-01

The various modules in multimodular carbohydrate-active enzymes (CAZymes) may function in catalysis, carbohydrate binding, protein-protein interactions or as linkers. Here, we describe how combining the biophysical techniques of Small Angle X-ray Scattering (SAXS) and macromolecular X-ray crystallography (XRC) provides a powerful tool for examination into questions related to overall structural organization of ultra multimodular CAZymes.

From EXOSAT to the High Energy Astrophysics Science Archive (HEASARC): X-ray Astronomy Comes of Age

NASA Technical Reports Server (NTRS)

White, Nicholas E.

2012-01-01

In May 1983 the European Space Agency launched EXOSAT, its first X-ray astronomy observatory. Even though it lasted only 3 short years, this mission brought not only new capabilities that resulted in unexpected discoveries, but also a pioneering approach to operations and archiving that changed X-ray astronomy from observations led by small instrument teams, to an observatory approach open to the entire community through a guest observer program. The community use of the observatory was supported by a small dedicated team of scientists, the precursor to the data center activities created to support e.g. Chandra and XMM-Newton. The new science capabilities of EX OS AT included a 90 hr highly eccentric high earth orbit that allow unprecedented continuous coverage of sources as well as direct communication with the satellite that allowed real time decisions to respond to unexpected events through targets of opportunity. The advantages of this orbit demonstrated by EXOSAT resulted in Chandra and XMM-Newton selecting similar orbits. The three instruments on board the EXOSAT observatory were complementary, designed to give complete coverage over a wide energy band pass of 0.05-50 keY. An onboard processor could be programmed to give multiple data modes that could be optimized in response to science discoveries: These new capabilities resulted in many new discoveries including the first comprehensive study of AGN variability, new orbital periods in X-ray binaries and cataclysmic variables, new black holes, quasi-periodic oscillations from neutron stars and black holes and broad band X-ray spectroscopy. The EXOSAT team generated a well-organized database accessible worldwide over the nascent internet, allowing remote selection of data products, making samples and undertaking surveys from the data. The HEASARC was established by NASA at Goddard Space Flight Center in 1990 as the repository of NASA X-ray and Gamma-ray data. The proven EXOSAT database system became the core of the HEASARC infrastructure. The HEASARC pioneered many concepts now taken for granted including standardized formats using FITS files, restoring data from earlier missions, multi-mission analysis tools and a searchable archive over the world wide web.

Energy-discriminating X-ray computed tomography system utilizing a cadmium telluride detector

NASA Astrophysics Data System (ADS)

Sato, Eiichi; Abderyim, Purkhet; Enomoto, Toshiyuki; Watanabe, Manabu; Hitomi, Keitaro; Takahasi, Kiyomi; Sato, Shigehiro; Ogawae, Akira; Onagawa, Jun

2010-07-01

An energy-discriminating K-edge X-ray computed tomography (CT) system is useful for increasing contrast resolution of a target region utilizing contrast media and for reducing the absorbed dose for patients. The CT system is of the first-generation type with a cadmium telluride (CdTe) detector, and a projection curve is obtained by translation scanning using the CdTe detector in conjunction with an x-stage. An object is rotated by the rotation step angle using a turntable between the translation scans. Thus, CT is carried out by repeating the translation scanning and the rotation of an object. Penetrating X-ray photons from the object are detected by the CdTe detector, and event signals of X-ray photons are produced using charge-sensitive and shaping amplifiers. Both the photon energy and the energy width are selected by use of a multi-channel analyzer, and the number of photons is counted by a counter card. Demonstration of enhanced iodine K-edge X-ray CT was carried out by selecting photons with energies just beyond the iodine K-edge energy of 33.2 keV.

Extragalactic Hard X-ray Surveys: From INTEGRAL to Simbol-X

NASA Astrophysics Data System (ADS)

Paltani, S.; Dwelly, T.; Walter, R.; McHardy, I. M.; Courvoisier, T. J.-L.

2009-05-01

We present some results of the deepest extragalactic survey performed by the INTEGRAL satellite. The fraction of very absorbed AGN is quite large. The sharp decrease in the absorption fraction with X-ray luminosity observed at lower-energy X-rays is not observed. The current lack of truly Compton-thick objects, with an upper limit of 14% to the size of this population, is just compatible with recent modeling of the cosmic X-ray background. We also study the prospects for a future hard X-ray serendipitous survey with Simbol-X. We show that Simbol-X will easily detect a large number of serendipitous AGN, allowing us to study the evolution of AGN up to redshifts about 2, opening the door to the cosmological study of hard X-ray selected AGN, which is barely possible with existing satellites like Swift and INTEGRAL.

The development of efficient X-ray conversion material for digital mammography

NASA Astrophysics Data System (ADS)

Oh, K.; Shin, J.; Kim, S.; Lee, Y.; Jeon, S.; Kim, J.; Nam, S.

2012-02-01

In this study, an experimental method based on theory is used to develop photoconductor that can replace the a-Se currently used as X-ray conversion layer in digital mammography. This is necessary because a-Se produced by the commercial fabrication method, of physical vapor deposition, has exhibited several problems when applied to digital mammography: instability due to crystallization and defect expansion due to high operating voltages, which is called the aging effect. Therefore, our work focused on developing a method of fabricating X-ray conversion films that do not suffer from crystallization and X-ray damage and optimizing the factors affecting the properties of the candidate photoconductors in order to acquire sufficient electrical signals to detect minute calcifications. The photoconductors were initially selected after the requirements for X-ray conversion materials, such as high atomic absorption, density, band-gap energy, work function, and resistivity, were examined. We selected HgI2, PbI2, and PbO because of their basic properties. Next, we experimentally investigated the performance of film samples fabricated by sedimentation and screen printing instead of physical vapor deposition. The structure of the X-ray conversion films (e.g., the thickness, electrodes, and blocking layer) were optimized for the application of a relatively low voltage to the X-ray conversion layer. The performance of the films were morphologically and electrically evaluated under mammography X-ray exposure conditions, and compared with those of a-Se films produced by physical vapor deposition. PbO appeared to be the most suitable alternative material because its electrical properties, such as the dark current, sensitivity, and signal-to-noise ratio (SNR), did not reveal the X-ray damage problem, and thus were maintained after repeated exposure to X-rays. Although PbO showed low sensitivity to X-ray exposure, its SNR was superior to that of the other materials, which is expected to improve its detective quantum efficiency, one of the factors used in evaluating images acquired by digital mammography.

The UV and X-ray activity of the M dwarfs within 10 pc of the Sun

NASA Astrophysics Data System (ADS)

Stelzer, B.; Marino, A.; Micela, G.; López-Santiago, J.; Liefke, C.

2013-05-01

M dwarfs are the most numerous stars in the Galaxy. They are characterized by strong magnetic activity. The ensuing high-energy emission is crucial for the evolution of their planets and the eventual presence of life on them. We systematically study the X-ray and ultraviolet emission of a subsample of M dwarfs from a recent proper-motion survey, selecting all M dwarfs within 10 pc to obtain a nearly volume-limited sample (˜90 per cent completeness). Archival ROSAT, XMM-Newton and GALEX data are combined with published spectroscopic studies of Hα emission and rotation to obtain a broad picture of stellar activity on M dwarfs. We make use of synthetic model spectra to determine the relative contributions of photospheric and chromospheric emission to the ultraviolet flux. We also analyse the same diagnostics for a comparison sample of young M dwarfs in the TW Hya association (˜10 Myr). We find that generally the emission in the GALEX bands is dominated by the chromosphere but the photospheric component is not negligible in early-M field dwarfs. The surface fluxes for the Hα, near-ultraviolet, far-ultraviolet and X-ray emission are connected via a power-law dependence. We present here for the first time such flux-flux relations involving broad-band ultraviolet emission for M dwarfs. Activity indices are defined as flux ratio between the activity diagnostic and the bolometric flux of the star in analogy to the Ca IIR'HK index. For given spectral type, these indices display a spread of 2-3 dex which is largest for M4 stars. Strikingly, at mid-M spectral types, the spread of rotation rates is also at its highest level. The mean activity index for fast rotators, likely representing the saturation level, decreases from X-rays over the FUV to the NUV band and Hα, i.e. the fractional radiation output increases with atmospheric height. The comparison to the ultraviolet and X-ray properties of TW Hya members shows a drop of nearly three orders of magnitude for the luminosity in these bands between ˜10 Myr and few Gyr age. A few young field dwarfs (<1 Gyr) in the 10-pc sample bridge the gap indicating that the drop in magnetic activity with age is a continuous process. The slope of the age decay is steeper for the X-ray than for the UV luminosity.

The AGN activity in a sample of IR Luminous Major Mergers

NASA Astrophysics Data System (ADS)

Loiseau, N.; de Rosa, A.; Bianchi, S.; Bogdanovich, T.

2017-10-01

As part of our study of the nuclear activity in a sample of 70 IR luminous major mergers we obtained XMM-Newton data of 4 more pairs of these galaxies. This is part of our multiwavelength study of the nuclear activity in mergers and groups of galaxies (MAGNA collaboration). Our purpose is to understand in which cases one or both of the galaxies of the major merger would have a massive black hole, and if the interaction stage, or the mass/type of the galaxies have role in the enhanced AGN and/or Starburst activity. X-rays can be the best tool to detect hidden AGN. At present very few mergers of AGN simultaneously active have been detected, most of them serendipitously. We present here the X-ray data of these 4 pairs, which have been selected using their WISE colors as a diagnostic tool. We compare the results for these 8 galaxies with the data of the 33 merging galaxies of this sample previously detected with XMM-Newton or Chandra.

THE XMM-NEWTON WIDE-FIELD SURVEY IN THE COSMOS FIELD (XMM-COSMOS): DEMOGRAPHY AND MULTIWAVELENGTH PROPERTIES OF OBSCURED AND UNOBSCURED LUMINOUS ACTIVE GALACTIC NUCLEI

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brusa, M.; Cappelluti, N.; Merloni, A.

2010-06-10

We report the final optical identifications of the medium-depth ({approx}60 ks), contiguous (2 deg{sup 2}) XMM-Newton survey of the COSMOS field. XMM-Newton has detected {approx}1800 X-ray sources down to limiting fluxes of {approx}5 x 10{sup -16}, {approx}3 x 10{sup -15}, and {approx}7 x 10{sup -15} erg cm{sup -2} s{sup -1} in the 0.5-2 keV, 2-10 keV, and 5-10 keV bands, respectively ({approx}1 x 10{sup -15}, {approx}6 x 10{sup -15}, and {approx}1 x 10{sup -14} erg cm{sup -2} s{sup -1}, in the three bands, respectively, over 50% of the area). The work is complemented by an extensive collection of multiwavelength datamore » from 24 {mu}m to UV, available from the COSMOS survey, for each of the X-ray sources, including spectroscopic redshifts for {approx}>50% of the sample, and high-quality photometric redshifts for the rest. The XMM and multiwavelength flux limits are well matched: 1760 (98%) of the X-ray sources have optical counterparts, 1711 ({approx}95%) have IRAC counterparts, and 1394 ({approx}78%) have MIPS 24 {mu}m detections. Thanks to the redshift completeness (almost 100%) we were able to constrain the high-luminosity tail of the X-ray luminosity function confirming that the peak of the number density of log L{sub X} > 44.5 active galactic nuclei (AGNs) is at z {approx} 2. Spectroscopically identified obscured and unobscured AGNs, as well as normal and star-forming galaxies, present well-defined optical and infrared properties. We devised a robust method to identify a sample of {approx}150 high-redshift (z > 1), obscured AGN candidates for which optical spectroscopy is not available. We were able to determine that the fraction of the obscured AGN population at the highest (L{sub X} > 10{sup 44} erg s{sup -1}) X-ray luminosity is {approx}15%-30% when selection effects are taken into account, providing an important observational constraint for X-ray background synthesis. We studied in detail the optical spectrum and the overall spectral energy distribution of a prototypical Type 2 QSO, caught in a stage transitioning from being starburst dominated to AGN dominated, which was possible to isolate only thanks to the combination of X-ray and infrared observations.« less

Should plain X-rays be routinely performed after blunt knee trauma? A prospective analysis.

PubMed

Jenny, Jean-Yves; Boeri, Cyril; El Amrani, Hakima; Dosch, Jean-Claude; Dupuis, Michel; Moussaoui, Akli; Mairot, Fabrice

2005-06-01

We tested the hypothesis that it was possible to decrease the number of performed x-rays after a knee trauma without delayed fracture diagnosis by using the Ottawa knee rules. Patients had routine x-rays of the injured knee during the first stage of the study and selective x-rays during the second stage. All patients were followed up to 6 months after the trauma. 138 patients were included in the first stage; 57 had negative Ottawa criteria: no fracture was observed; following the Ottawa rules, 41% of the x-rays could have been avoided. 178 patients were included in the second stage; 63 patients had negative Ottawa criteria: no fracture was diagnosed during the whole follow-up; 35% of the x-rays have been avoided. Ottawa rules allowed decreasing the number of x-rays performed after a knee trauma by 35% with a sensitivity for a knee fracture detection of 100%.

On the surface density of X-ray selected BL Lacertae objects

NASA Technical Reports Server (NTRS)

Maccacaro, T.; Gioia, I. M.; Maccagni, D.; Stocke, J. T.

1984-01-01

Only a handful of BL Lac objects have been found as a result of systematic optical identification of serendipitous Einstein X-ray sources. By combining the data from two flux-limited complete X-ray surveys (the HEAO 1 A-2 and the Einstein Observatory Medium Sensitivity Survey) the surface density of X-ray emitting BL Lac objects is evaluated as a function of their X-ray flux. It is found that a single power law is not an acceptable representation of the BL Lac objects' X-ray log N-log S. The number-flux relationship is consistent with the Euclidean slope at 'high' flux levels but shows a drastic flattnring below fluxes of the order of 10 to the -12th ergs per sq cm/s. The implications of this result are briefly discussed with respect to the luminosity function, the cosmological evolution, and the X-ray to optical flux ratio in BL Lac objects.

Toward Large-Area Sub-Arcsecond X-Ray Telescopes

NASA Technical Reports Server (NTRS)

O'Dell, Stephen L.; Aldcroft, Thomas L.; Allured, Ryan; Atkins, Carolyn; Burrows, David N.; Cao, Jian; Chalifoux, Brandon D.; Chan, Kai-Wing; Cotroneo, Vincenzo; Elsner, Ronald F.;

Spatially resolved single crystal x-ray spectropolarimetry of wire array z-pinch plasmas

NASA Astrophysics Data System (ADS)

Wallace, M. S.; Haque, S.; Neill, P.; Pereira, N. R.; Presura, R.

2018-01-01

A recently developed single-crystal x-ray spectropolarimeter has been used to record paired sets of polarization-dependent and axially resolved x-ray spectra emitted by wire array z-pinches. In this measurement, two internal planes inside a suitable crystal diffract the x-rays into two perpendicular directions that are normal to each other, thereby separating incident x-rays into their linearly polarized components. This paper gives considerations for fielding the instrument on extended sources. Results from extended sources are difficult to interpret because generally the incident x-rays are not separated properly by the crystal. This difficulty is mitigated by using a series of collimating slits to select incident x-rays that propagate in a plane of symmetry between the polarization-splitting planes. The resulting instrument and some of the spatially resolved polarized x-ray spectra recorded for a 1-MA aluminum wire array z-pinch at the Nevada Terawatt Facility at the University of Nevada, Reno will be presented.

X-ray studies of coeval star samples. II - The Pleiades cluster as observed with the Einstein Observatory

NASA Technical Reports Server (NTRS)

Micela, G.; Sciortino, S.; Vaiana, G. S.; Harnden, F. R., Jr.; Rosner, R.

1990-01-01

Coronal X-ray emission of the Pleiades stars is investigated, and maximum likelihood, integral X-ray luminosity functions are computed for Pleiades members in selected color-index ranges. A detailed search is conducted for long-term variability in the X-ray emission of those stars observed more than once. An overall comparison of the survey results with those of previous surveys confirms the ubiquity of X-ray emission in the Pleiades cluster stars and its higher rate of emission with respect to older stars. It is found that the X-ray emission from dA and early dF stars cannot be proven to be dissimilar to that of Hyades and field stars of the same spectral type. The Pleiades cluster members show a real rise of the X-ray luminosity from dA stars to early dF stars. X-ray emission for the young, solarlike Pleiades stars is about two orders of magnitude more intense than for the nearby solarlike stars.

Spatially resolved single crystal x-ray spectropolarimetry of wire array z-pinch plasmas.

PubMed

Wallace, M S; Haque, S; Neill, P; Pereira, N R; Presura, R

2018-01-01

A recently developed single-crystal x-ray spectropolarimeter has been used to record paired sets of polarization-dependent and axially resolved x-ray spectra emitted by wire array z-pinches. In this measurement, two internal planes inside a suitable crystal diffract the x-rays into two perpendicular directions that are normal to each other, thereby separating incident x-rays into their linearly polarized components. This paper gives considerations for fielding the instrument on extended sources. Results from extended sources are difficult to interpret because generally the incident x-rays are not separated properly by the crystal. This difficulty is mitigated by using a series of collimating slits to select incident x-rays that propagate in a plane of symmetry between the polarization-splitting planes. The resulting instrument and some of the spatially resolved polarized x-ray spectra recorded for a 1-MA aluminum wire array z-pinch at the Nevada Terawatt Facility at the University of Nevada, Reno will be presented.

The Massive Star-Forming Regions Omnibus X-Ray Catalog

NASA Astrophysics Data System (ADS)

Townsley, Leisa K.; Broos, Patrick S.; Garmire, Gordon P.; Bouwman, Jeroen; Povich, Matthew S.; Feigelson, Eric D.; Getman, Konstantin V.; Kuhn, Michael A.

2014-07-01

We present the Massive Star-forming Regions (MSFRs) Omnibus X-ray Catalog (MOXC), a compendium of X-ray point sources from Chandra/ACIS observations of a selection of MSFRs across the Galaxy, plus 30 Doradus in the Large Magellanic Cloud. MOXC consists of 20,623 X-ray point sources from 12 MSFRs with distances ranging from 1.7 kpc to 50 kpc. Additionally, we show the morphology of the unresolved X-ray emission that remains after the cataloged X-ray point sources are excised from the ACIS data, in the context of Spitzer and WISE observations that trace the bubbles, ionization fronts, and photon-dominated regions that characterize MSFRs. In previous work, we have found that this unresolved X-ray emission is dominated by hot plasma from massive star wind shocks. This diffuse X-ray emission is found in every MOXC MSFR, clearly demonstrating that massive star feedback (and the several-million-degree plasmas that it generates) is an integral component of MSFR physics.

Discovery of very high energy gamma rays associated with an x-ray binary.

PubMed

Aharonian, F; Akhperjanian, A G; Aye, K-M; Bazer-Bachi, A R; Beilicke, M; Benbow, W; Berge, D; Berghaus, P; Bernlöhr, K; Boisson, C; Bolz, O; Borrel, V; Braun, I; Breitling, F; Brown, A M; Bussons Gordo, J; Chadwick, P M; Chounet, L-M; Cornils, R; Costamante, L; Degrange, B; Dickinson, H J; Djannati-Ataï, A; Drury, L O'c; Dubus, G; Emmanoulopoulos, D; Espigat, P; Feinstein, F; Fleury, P; Fontaine, G; Fuchs, Y; Funk, S; Gallant, Y A; Giebels, B; Gillessen, S; Glicenstein, J F; Goret, P; Hadjichristidis, C; Hauser, M; Heinzelmann, G; Henri, G; Hermann, G; Hinton, J A; Hofmann, W; Holleran, M; Horns, D; Jacholkowska, A; de Jager, O C; Khélifi, B; Komin, Nu; Konopelko, A; Latham, I J; Le Gallou, R; Lemière, A; Lemoine-Goumard, M; Leroy, N; Lohse, T; Marcowith, A; Martin, J-M; Martineau-Huynh, O; Masterson, C; McComb, T J L; de Naurois, M; Nolan, S J; Noutsos, A; Orford, K J; Osborne, J L; Ouchrif, M; Panter, M; Pelletier, G; Pita, S; Pühlhofer, G; Punch, M; Raubenheimer, B C; Raue, M; Raux, J; Rayner, S M; Reimer, A; Reimer, O; Ripken, J; Rob, L; Rolland, L; Rowell, G; Sahakian, V; Saugé, L; Schlenker, S; Schlickeiser, R; Schuster, C; Schwanke, U; Siewert, M; Sol, H; Spangler, D; Steenkamp, R; Stegmann, C; Tavernet, J-P; Terrier, R; Théoret, C G; Tluczykont, M; Vasileiadis, G; Venter, C; Vincent, P; Völk, H J; Wagner, S J

2005-07-29

X-ray binaries are composed of a normal star in orbit around a neutron star or stellar-mass black hole. Radio and x-ray observations have led to the presumption that some x-ray binaries called microquasars behave as scaled-down active galactic nuclei. Microquasars have resolved radio emission that is thought to arise from a relativistic outflow akin to active galactic nuclei jets, in which particles can be accelerated to large energies. Very high energy gamma-rays produced by the interactions of these particles have been observed from several active galactic nuclei. Using the High Energy Stereoscopic System, we find evidence for gamma-ray emission of >100 gigaelectron volts from a candidate microquasar, LS 5039, showing that particles are also accelerated to very high energies in these systems.

Fixture for supporting and aligning a sample to be analyzed in an x-ray diffraction apparatus

DOEpatents

Green, L.A.; Heck, J.L. Jr.

1985-04-23

A fixture is provided for supporting and aligning small samples of material on a goniometer for x-ray diffraction analysis. A sample-containing capillary is accurately positioned for rotation in the x-ray beam by selectively adjusting the fixture to position the capillary relative to the x and y axes thereof to prevent wobble and position the sample along the z axis or the axis of rotation. By employing the subject fixture relatively small samples of materials can be analyzed in an x-ray diffraction apparatus previously limited to the analysis of much larger samples.

Fixture for supporting and aligning a sample to be analyzed in an X-ray diffraction apparatus

DOEpatents

Green, Lanny A.; Heck, Jr., Joaquim L.

1987-01-01

A fixture is provided for supporting and aligning small samples of material on a goniometer for X-ray diffraction analysis. A sample-containing capillary is accurately positioned for rotation in the X-ray beam by selectively adjusting the fixture to position the capillary relative to the x and y axes thereof to prevent wobble and position the sample along the z axis or the axis of rotation. By employing the subject fixture relatively small samples of materials can be analyzed in an X-ray diffraction apparatus previously limited to the analysis of much larger samples.

Variable spectra of active galaxies

NASA Technical Reports Server (NTRS)

Halpern, Jules P.

1988-01-01

The analysis of EXOSAT spectra of active galaxies are presented. The objects examined for X-ray spectral variability were MR 2251-178 and 3C 120. The results of these investigations are described, as well as additional results on X-ray spectral variability related to EXOSAT observations of active galaxies. Additionally, the dipping X-ray source 4U1624-49 was also investigated.

MOF-74 as an Efficient Catalyst for the Low-Temperature Selective Catalytic Reduction of NOx with NH3.

PubMed

Jiang, Haoxi; Wang, Qianyun; Wang, Huiqin; Chen, Yifei; Zhang, Minhua

2016-10-12

In this work, Mn-MOF-74 with hollow spherical structure and Co-MOF-74 with petal-like shape have been prepared successfully via the hydrothermal method. The catalysts were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetry-mass spectrum analysis (TG-MS), N 2 adsorption/desorption, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). It is found that MOF-74(Mn, Co) exhibits the capability for selective catalytic reduction (SCR) of NO x at low temperatures. Both experimental (temperature-programmed desorption, TPD) and computational methods have shown that Co-MOF-74 and Mn-MOF-74 owned high adsorption and activation abilities for NO and NH 3 . The catalytic activities of Mn-MOF-74 and Co-MOF-74 for low-temperature denitrification (deNO x ) in the presence of NH 3 were 99% at 220 °C and 70% at 210 °C, respectively. It is found that the coordinatively unsaturated metal sites (CUSs) in M-MOF-74 (M = Mn and Co) played important roles in SCR reaction. M-MOF-74 (M = Mn and Co), especially Mn-MOF-74, showed excellent catalytic performance for low-temperature SCR. In addition, in the reaction process, NO conversion on Mn-MOF-74 decreased with the introduction of H 2 O and SO 2 and almost recovered when gas was cut off. However, for Co-MOF-74, SO 2 almost has no effect on the catalytic activity. This work showed that MOF-74 could be used prospectively as deNO x catalyst.

Luminosity correlations in quasars

NASA Technical Reports Server (NTRS)

Chanan, G. A.

1983-01-01

Simulations are conducted with and without flux thresholds in an investigation of quasar luminosity correlations by means of a Monte Carlo analysis, for various model distributions of quasars in X-rays and optical luminosity. For the case where the X-ray photons are primary, an anticorrelation between X-ray-to-optical luminosity ratio and optical luminosity arises as a natural consequence which resembles observations. The low optical luminosities of X-ray selected quasars can be understood as a consequence of the same effect, and similar conclusions may hold if the X-ray and optical luminosities are determined independently by a third parameter, although they do not hold if the optical photons are primary. The importance of such considerations is demonstrated through a reanalysis of the published X-ray-to-optical flux ratios for the 3CR sample.

X-ray phase imaging-From static observation to dynamic observation-

DOE Office of Scientific and Technical Information (OSTI.GOV)

Momose, A.; Yashiro, W.; Olbinado, M. P.

2012-07-31

We are attempting to expand the technology of X-ray grating phase imaging/tomography to enable dynamic observation. X-ray phase imaging has been performed mainly for static cases, and this challenge is significant since properties of materials (and hopefully their functions) would be understood by observing their dynamics in addition to their structure, which is an inherent advantage of X-ray imaging. Our recent activities in combination with white synchrotron radiation for this purpose are described. Taking advantage of the fact that an X-ray grating interferometer functions with X-rays of a broad energy bandwidth (and therefore high flux), movies of differential phase imagesmore » and visibility images are obtained with a time resolution of a millisecond. The time resolution of X-ray phase tomography can therefore be a second. This study is performed as a part of a project to explore X-ray grating interferometry, and our other current activities are also briefly outlined.« less

Time-dependent nonequilibrium soft x-ray response during a spin crossover

DOE Office of Scientific and Technical Information (OSTI.GOV)

van Veenendaal, Michel

The rapid development of high-brilliance pulsed X-ray sources with femtosecond time resolution has created a need for a better theoretical understanding of the time-dependent soft-X-ray response of dissipative many-body quantum systems. It is demonstrated how soft-X-ray spectroscopies, such as X-ray absorption and resonant inelastic X-ray scattering at transition-metal L-edges, can provide insight into intersystem crossings, such as a spin crossover. The photoinduced doublet-to-quartet spin crossover on cobalt in Fe-Co Prussian blue analogues is used as an example to demonstrate how the X-ray response is affected by the dissipative nonequilibrium dynamics. The time-dependent soft-X-ray spectra provide a wealth of information thatmore » reflect the changes in the nonequilibrium initial state via continuously changing spectral lineshapes that cannot be decomposed into initial photoexcited and final metastable spectra, strong broadenings, a collapse of clear selection rules during the intersystem crossing, strong fluctuations in the isotropic branching ratio in X-ray absorption, and crystal-field collapse/oscillations and strongly time-dependent anti-Stokes processes in RIXS.« less

Highly variable AGN from the XMM-Newton slew survey

NASA Astrophysics Data System (ADS)

Strotjohann, N. L.; Saxton, R. D.; Starling, R. L. C.; Esquej, P.; Read, A. M.; Evans, P. A.; Miniutti, G.

2016-07-01

Aims: We investigate the properties of a variability-selected complete sample of active galactic nuclei (AGN) in order to identify the mechanisms which cause large amplitude X-ray variability on timescales of years. Methods: A complete sample of 24 sources was constructed, from AGN which changed their soft X-ray luminosity by more than one order of magnitude over 5-20 years between ROSAT observations and the XMM-Newton slew survey. Follow-up observations were obtained with the Swift satellite. We analysed the spectra of these AGN at the Swift and XMM observation epochs, where six sources had continued to display extreme variability. Multiwavelength data are used to calculate black hole masses and the relative X-ray brightness αOX. Results: After removal of two probable spurious sources, we find that the sample has global properties which differ little from a non-varying control sample drawn from the wider XMM-slew/ROSAT/Veron sample of all secure AGN detections. A wide range of AGN types are represented in the varying sample. The black hole mass distributions for the varying and non-varying sample are not significantly different. This suggests that long timescale variability is not strongly affected by black hole mass. There is marginal evidence that the variable sources have a lower redshift (2σ) and X-ray luminosity (1.7σ). Apart from two radio-loud sources, the sample sources have normal optical-X-ray ratios (αOX) when at their peak but are X-ray weak during their lowest flux measurements. Conclusions: Drawing on our results and other studies, we are able to identify a variety of variability mechanisms at play: tidal disruption events, jet activity, changes in absorption, thermal emission from the inner accretion disc, and variable accretion disc reflection. Little evidence for strong absorption is seen in the majority of the sample and single-component absorption can be excluded as the mechanism for most sources.

Active galactic nucleus X-ray variability in the XMM-COSMOS survey

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lanzuisi, G.; Ponti, G.; Salvato, M.

2014-02-01

We used the observations carried out by XMM in the COSMOS field over 3.5 yr to study the long term variability of a large sample of active galactic nuclei (AGNs) (638 sources) in a wide range of redshifts (0.1 < z < 3.5) and X-ray luminosities (10{sup 41} < L {sub 0.5-10} <10{sup 45.5}). Both a simple statistical method to assess the significance of variability and the Normalized Excess Variance (σ{sub rms}{sup 2}) parameter were used to obtain a quantitative measurement of the variability. Variability is found to be prevalent in most AGNs, whenever we have good statistics to measuremore » it, and no significant differences between type 1 and type 2 AGNs were found. A flat (slope –0.23 ± 0.03) anti-correlation between σ{sub rms}{sup 2} and X-ray luminosity is found when all significantly variable sources are considered together. When divided into three redshift bins, the anti-correlation becomes stronger and evolving with z, with higher redshift AGNs being more variable. We prove, however, that this effect is due to the pre-selection of variable sources: when considering all of the sources with an available σ{sub rms}{sup 2} measurement, the evolution in redshift disappears. For the first time, we were also able to study long term X-ray variability as a function of M {sub BH} and Eddington ratio for a large sample of AGNs spanning a wide range of redshifts. An anti-correlation between σ{sub rms}{sup 2} and M {sub BH} is found, with the same slope of anti-correlation between σ{sub rms}{sup 2} and X-ray luminosity, suggesting that the latter may be a by-product of the former. No clear correlation is found between σ{sub rms}{sup 2} and the Eddington ratio in our sample. Finally, no correlation is found between the X-ray σ{sub rms}{sup 2} and optical variability.« less

Coronal Properties of X-ray bright stars in young associations: abundances, temperatures and variability

NASA Astrophysics Data System (ADS)

Argiroffi, Costanza

2006-03-01

In this work I have investigated open issues related to the X-ray radiation from young stars, including heating mechanisms of the emitting plasma, its chemical composition, and possible effects due to circumstellar accretion disks. To this aim, I have analyzed observations of young nearby stars taken with the X-ray observatories XMM-Newton and Chandra. For a detailed study of the characteristics of the X-ray emitting plasma, I have selected two X-ray bright young stars, TWA 5 and PZ Tel, for which high-resolution X-ray spectroscopy was achievable, and two regions of the young stellar association Upper Scorpius (USco), for which X-ray images and medium-resolution spectra of individual sources were obtained. TWA 5 is a 10 Myr old star in the TW Hydrae association, which is still accreting material from its circumstellar envelope, while PZ Tel is a ? 12 Myr star in the beta Pictoris moving group, which already dissipated its circumstellar disk. The different evolutionary stages of these two stars allow to probe whether X-ray emission is produced, or affected, by accretion processes. High-resolution X-ray spectra of TWA 5 and PZ Tel were gathered with the grating spectrometers on board XMM-Newton and Chandra, respectively. From the measurements of individual emission line fluxes in their X-ray spectra, I have derived emission measure distributions vs. temperature, abundances, and electron densities of the X-ray emitting plasma. I have found that, in spite of their different evolutionary status, hot (T ? 10 MK) plasma is the main responsible for the observed X-ray emission of both stars. The hot plasma on TWA 5 displays peculiar element abundances with respect to the solar photospheric composition with Ne/Fe ? 10(Ne/Fe), while the coronal plasma on PZ Tel shows Ne/Fe ? 3(Ne/Fe). To explain the strong Fe underabundance (? 0.1 Fe) and the extremely high Ne/Fe ratio of TWA 5 I have considered three different scenarios: (1) coronal plasma may be affected by selective element depletion dependent on the first ionization potential (FIP), similar to the inverse FIP effect usually observed in the coronae of very active stars; (2) the X-ray emitting plasma on TWA 5 may be partially heated by the shock produced by the infall accretion streams onto the stellar photosphere, and hence it may originate from the circumstellar disk, where grain depletion is a possible cause of the metal deficiency; (3) the peculiar abundances on TWA 5 are due to the local chemical composition of the original cloud from which the star formed, and this explains why TWA 5 shares the same abundances with TW Hydrae, another young star located in the same stellar association. The 5 Myr old USco association, due to its vicinity (145 pc) and low circumstellar extinction, is a good laboratory to perform a detailed study of PMS stars of this age. Here I present the results of the analysis of deep XMM-Newton observations of two USco regions covering an area of ?0.4 deg^2 . I have detected 224 X-ray sources among which 22 have been identified with probable USco members on the basis of near infrared and optical photometry. Among these 22 sources, I have recognized 13 sources as USco members for the first time. Except for the intermediate mass star HD 142578, all the detected USco sources are low mass stars of spectral type ranging from G to late M, and including at least one brown dwarf. The X-ray spectral analysis of the most intense USco sources indicates metal depleted plasma with temperature of ? 10 MK, resembling the typical case of active main sequence stars, as already found for TWA 5 and PZ Tel. Strong flares detected from 4 USco members have allowed me to derive coronal lengths of the flaring structures by performing time resolved spectroscopy during the flare decay phases. In all cases the flaring loops have sizes of 10^10 - 10^11 cm, hence smaller than the corresponding stellar radii. These results suggest that, in these very young stars coronal plasma is confined in compact loops. The coronal properties of PZ Tel, TWA 5, and of the USco members indicate that the coronae of pre-main sequence stars become similar to those of older active main-sequence stars on short time scales (? 5 Myr), in terms of average temperature, density, elemental abundances, and loop lengths, even if accretion processes from circumstellar disks are still at work.

Cygnus X-3 Returns to an Active State

NASA Astrophysics Data System (ADS)

McCollough, Michael L.; Koljonen, Karri; Gurwell, Mark A.; Trushkin, Sergei; Pooley, Guy G.

2017-08-01

Cygnus X-3 is a well-known microquasar composed of a mass-donating Wolf-Rayet star and a compact object. Recently, Cygnus X-3 has been in a quiescent state for an extended period of time (2011-2016) but returned to an active state on two occasions during 2016/2017 including quenched/hypersoft states, gamma-ray emission, and major radio flares. During these two periods of activity, we undertook multi-wavelength observing campaigns with observations in the radio (RATAN-600, AMI-LA, Metsähovi), submillimeter (SMA, EHT), X-ray (Swift/XRT, MAXI), hard X-ray (Swift/BAT, NuSTAR), and gamma-ray (AGILE, Fermi, VERITAS). At the peak of the major radio flare in April 2017 observations were made with VERITAS (TeV), NuSTAR (hard X-ray), and the Event Horizon Telescope (submillimeter). In this presentation, I will review these observing campaigns and the insights they provide about Cygnus X-3.

X-ray/EUV optics for astronomy, microscopy, polarimetry, and projection lithography; Proceedings of the Meeting, San Diego, CA, July 9-13, 1990

NASA Technical Reports Server (NTRS)

Hoover, Richard B. (Editor); Walker, Arthur B. C., Jr. (Editor)

1991-01-01

Topics discussed in this issue include the fabrication of multilayer X-ray/EUV coatings; the design, characterization, and test of multilayer X-ray/EUV coatings; multilayer X-ray/EUV monochromators and imaging microscopes; X-ray/EUV telescopes; the test and calibration performance of X-ray/EUV instruments; XUV/soft X-ray projection lithography; X-ray/EUV space observatories and missions; X-ray/EUV telescopes for solar research; X-ray/EUV polarimetry; X-ray/EUV spectrographs; and X-ray/EUV filters and gratings. Papers are presented on the deposition-controlled uniformity of multilayer mirrors, interfaces in Mo/Si multilayers, the design and analysis of an aspherical multilayer imaging X-ray microscope, recent developments in the production of thin X-ray reflecting foils, and the ultraprecise scanning technology. Consideration is also given to an active sun telescope array, the fabrication and performance at 1.33 nm of a 0.24-micron-period multilayer grating, a cylindrical proportional counter for X-ray polarimetry, and the design and analysis of the reflection grating arrays for the X-Ray Multi-Mirror Mission.

Luminous Obscured AGN Unveiled in the Stripe 82 X-ray Survey

NASA Astrophysics Data System (ADS)

LaMassa, Stephanie; Glikman, Eilat; Brusa, Marcella; Rigby, Jane; Tasnim Ananna, Tonima; Stern, Daniel; Lira, Paulina; Urry, Meg; Salvato, Mara; Alexandroff, Rachael; Allevato, Viola; Cardamone, Carolin; Civano, Francesca Maria; Coppi, Paolo; Farrah, Duncan; Komossa, S.; Lanzuisi, Giorgio; Marchesi, Stefano; Richards, Gordon; Trakhtenbrot, Benny; Treister, Ezequiel

2018-01-01

Stripe 82X is a wide-area (30 deg2) X-ray survey overlapping the legacy Sloan Digital Sky Survey (SDSS) Stripe 82 field, designed to uncover rare, high luminosity active galactic nuclei (AGN). We report on the results of an on-going near-infrared (NIR) spectroscopic campaign to follow-up reddened AGN candidates with Palomar TripleSpec, Keck NIRSPEC, and Gemini GNIRS. We identified 8 AGN in our bright NIR sample (K < 16, Vega), selected to have red R-K colors (> 4, Vega); four of these sources had existing optical spectra in SDSS. We targeted four out of 34 obscured AGN candidates in our faint NIR sample (K > 17, Vega), all of which are undetected in the single-epoch SDSS imaging, making them the best candidates for the most obscured and/or the most distant reddend AGN in Stripe 82X. All twelve sources are Type 1 AGN, with the FWHM of at least one permitted emission line exceeding 1300 km/s. We find that our nearly complete bright NIR sample (12/13 obscured AGN candidates have spectroscopic redshifts) is more distant (z > 0.5) than a matched sample of blue Type 1 AGN from Stripe 82X; these AGN tend to be more luminous than their blue, unobscured counterparts. Results from our pilot program of faint NIR-selected obscured AGN candidates demonstrate that our selection recovers reddened quasars missed by SDSS.

Tuning the Selectivity of Single-Site Supported Metal Catalysts with Ionic Liquids

DOE PAGES

Babucci, Melike; Fang, Chia -Yu; Hoffman, Adam S.; ...

2017-09-11

1,3-Dialkylimidazolium ionic liquid coatings act as electron donors, increasing the selectivity for partial hydrogenation of 1,3-butadiene catalyzed by iridium complexes supported on high-surface-area γ-Al 2O 3. High-energy-resolution fluorescence detection X-ray absorption near-edge structure (HERFD XANES) measurements quantify the electron donation and are correlated with the catalytic activity and selectivity. Furthermore, the results demonstrate broad opportunities to tune electronic environments and catalytic properties of atomically dispersed supported metal catalysts.

X-ray superbubbles

NASA Technical Reports Server (NTRS)

Cash, W.

1983-01-01

Four regions of the galaxy, the Cygnus Superbubble, the Eta Carina complex, the Orion/Eridanus complex, and the Gum Nebula, are discussed as examples of collective effects in the interstellar medium. All four regions share certain features, indicating a common structure. The selection effects which determine the observable X-ray properties of the superbubbles are discussed, and it is demonstrated that only a very few more in our Galaxy can be detected in X rays. X-ray observation of extragalactic superbubbles is shown to be possible but requires the capabilities of a large, high quality, AXAF class observatory.

Ultrafast Independent N-H and N-C Bond Deformation Investigated with Resonant Inelastic X-Ray Scattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eckert, Sebastian; Norell, Jesper; Miedema, Piter S.

Here, the femtosecond excited-state dynamics following resonant photoexcitation enable the selective deformation of N-H and N-C chemical bonds in 2-thiopyridone in aqueous solution with optical or X-ray pulses. In combination with multiconfigurational quantum-chemical calculations, the orbital-specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X-ray scattering at the N 1s level using synchrotron radiation and the soft X-ray free-electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort timescale.

Ultrafast Independent N-H and N-C Bond Deformation Investigated with Resonant Inelastic X-Ray Scattering

DOE PAGES

Eckert, Sebastian; Norell, Jesper; Miedema, Piter S.; ...

2017-04-04

Here, the femtosecond excited-state dynamics following resonant photoexcitation enable the selective deformation of N-H and N-C chemical bonds in 2-thiopyridone in aqueous solution with optical or X-ray pulses. In combination with multiconfigurational quantum-chemical calculations, the orbital-specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X-ray scattering at the N 1s level using synchrotron radiation and the soft X-ray free-electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort timescale.

Influence of Cu-Ti thin film surface properties on antimicrobial activity and viability of living cells.

PubMed

Wojcieszak, Damian; Kaczmarek, Danuta; Antosiak, Aleksandra; Mazur, Michal; Rybak, Zbigniew; Rusak, Agnieszka; Osekowska, Malgorzata; Poniedzialek, Agata; Gamian, Andrzej; Szponar, Bogumila

2015-11-01

The paper describes properties of thin-film coatings based on copper and titanium. Thin films were prepared by co-sputtering of Cu and Ti targets in argon plasma. Deposited coatings consist of 90at.% of Cu and 10at.% of Ti. Characterization of the film was made on the basis of investigations of microstructure and physicochemical properties of the surface. Methods such as scanning electron microscopy, x-ray microanalysis, x-ray diffraction, x-ray photoelectron spectroscopy, atomic force microscopy, optical profilometry and wettability measurements were used to assess the properties of deposited thin films. An impact of Cu-Ti coating on the growth of selected bacteria and viability of the living cells (line L929, NCTC clone 929) was described in relation to the structure, surface state and wettability of the film. It was found that as-deposited films were amorphous. However, in such surroundings the nanocrystalline grains of 10-15nm and 25-35nm size were present. High surface active area with a roughness of 8.9nm, had an effect on receiving relatively high water contact angle value (74.1°). Such wettability may promote cell adhesion and result in an increase of the probability of copper ion transfer from the film surface into the cell. Thin films revealed bactericidal and fungicidal effects even in short term-contact. High activity of prepared films was directly related to high amount (ca. 51 %) of copper ions at 1+ state as x-ray photoelectron spectroscopy results have shown. Copyright © 2015 Elsevier B.V. All rights reserved.

How long does a burst burst?

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Bin-Bin; Connaughton, Valerie; Briggs, Michael S.

2014-05-20

Several gamma-ray bursts (GRBs) last much longer (∼hours) in γ-rays than typical long GRBs (∼minutes), and it has recently been proposed that these 'ultra-long GRBs' may form a distinct population, probably with a different (e.g., blue supergiant) progenitor than typical GRBs. However, Swift observations suggest that many GRBs have extended central engine activities manifested as flares and internal plateaus in X-rays. We perform a comprehensive study on a large sample of Swift GRBs with X-Ray Telescope observations to investigate GRB central engine activity duration and to determine whether ultra-long GRBs are unusual events. We define burst duration t {sub burst}more » based on both γ-ray and X-ray light curves rather than using γ-ray observations alone. We find that t {sub burst} can be reliably measured in 343 GRBs. Within this 'good' sample, 21.9% GRBs have t {sub burst} ≳ 10{sup 3} s and 11.5% GRBs have t {sub burst} ≳ 10{sup 4} s. There is an apparent bimodal distribution of t {sub burst} in this sample. However, when we consider an 'undetermined' sample (304 GRBs) with t {sub burst} possibly falling in the gap between GRB duration T {sub 90} and the first X-ray observational time, as well as a selection effect against t {sub burst} falling into the first Swift orbital 'dead zone' due to observation constraints, the intrinsic underlying t {sub burst} distribution is consistent with being a single component distribution. We found that the existing evidence for a separate ultra-long GRB population is inconclusive, and further multi-wavelength observations are needed to draw a firmer conclusion. We also discuss the theoretical implications of our results. In particular, the central engine activity duration of GRBs is generally much longer than the γ-ray T {sub 90} duration and it does not even correlate with T {sub 90}. It would be premature to make a direct connection between T {sub 90} and the size of the progenitor star.« less

Application of MEMS-based x-ray optics as tuneable nanosecond choppers

NASA Astrophysics Data System (ADS)

Chen, Pice; Walko, Donald A.; Jung, Il Woong; Li, Zhilong; Gao, Ya; Shenoy, Gopal K.; Lopez, Daniel; Wang, Jin

2017-08-01

Time-resolved synchrotron x-ray measurements often rely on using a mechanical chopper to isolate a set of x-ray pulses. We have started the development of micro electromechanical systems (MEMS)-based x-ray optics, as an alternate method to manipulate x-ray beams. In the application of x-ray pulse isolation, we recently achieved a pulse-picking time window of half a nanosecond, which is more than 100 times faster than mechanical choppers can achieve. The MEMS device consists of a comb-drive silicon micromirror, designed for efficiently diffracting an x-ray beam during oscillation. The MEMS devices were operated in Bragg geometry and their oscillation was synchronized to x-ray pulses, with a frequency matching subharmonics of the cycling frequency of x-ray pulses. The microscale structure of the silicon mirror in terms of the curvature and the quality of crystallinity ensures a narrow angular spread of the Bragg reflection. With the discussion of factors determining the diffractive time window, this report showed our approaches to narrow down the time window to half a nanosecond. The short diffractive time window will allow us to select single x-ray pulse out of a train of pulses from synchrotron radiation facilities.

A vacuum-sealed compact x-ray tube based on focused carbon nanotube field-emission electrons

NASA Astrophysics Data System (ADS)

Jeong, Jin-Woo; Kim, Jae-Woo; Kang, Jun-Tae; Choi, Sungyoul; Ahn, Seungjoon; Song, Yoon-Ho

2013-03-01

We report on a fully vacuum-sealed compact x-ray tube based on focused carbon nanotube (CNT) field-emission electrons for various radiography applications. The specially designed two-step brazing process enabled us to accomplish a good vacuum level for the stable and reliable operation of the x-ray tube without any active vacuum pump. Also, the integrated focusing electrodes in the field-emission electron gun focused electron beams from the CNT emitters onto the anode target effectively, giving a small focal spot of around 0.3 mm with a large current of above 50 mA. The active-current control through the cathode electrode of the x-ray tube led a fast digital modulation of x-ray dose with a low voltage of below 5 V. The fabricated compact x-ray tube showed a stable and reliable operation, indicating good maintenance of a vacuum level of below 5 × 10-6 Torr and the possibility of field-emission x-ray tubes in a stand-alone device without an active pumping system.

Soft X-ray Focusing Telescope Aboard AstroSat: Design, Characteristics and Performance

NASA Astrophysics Data System (ADS)

Singh, K. P.; Stewart, G. C.; Westergaard, N. J.; Bhattacharayya, S.; Chandra, S.; Chitnis, V. R.; Dewangan, G. C.; Kothare, A. T.; Mirza, I. M.; Mukerjee, K.; Navalkar, V.; Shah, H.; Abbey, A. F.; Beardmore, A. P.; Kotak, S.; Kamble, N.; Vishwakarama, S.; Pathare, D. P.; Risbud, V. M.; Koyande, J. P.; Stevenson, T.; Bicknell, C.; Crawford, T.; Hansford, G.; Peters, G.; Sykes, J.; Agarwal, P.; Sebastian, M.; Rajarajan, A.; Nagesh, G.; Narendra, S.; Ramesh, M.; Rai, R.; Navalgund, K. H.; Sarma, K. S.; Pandiyan, R.; Subbarao, K.; Gupta, T.; Thakkar, N.; Singh, A. K.; Bajpai, A.

2017-06-01

The Soft X-ray focusing Telescope (SXT), India's first X-ray telescope based on the principle of grazing incidence, was launched aboard the AstroSat and made operational on October 26, 2015. X-rays in the energy band of 0.3-8.0 keV are focussed on to a cooled charge coupled device thus providing medium resolution X-ray spectroscopy of cosmic X-ray sources of various types. It is the most sensitive X-ray instrument aboard the AstroSat. In its first year of operation, SXT has been used to observe objects ranging from active stars, compact binaries, supernova remnants, active galactic nuclei and clusters of galaxies in order to study its performance and quantify its characteriztics. Here, we present an overview of its design, mechanical hardware, electronics, data modes, observational constraints, pipeline processing and its in-orbit performance based on preliminary results from its characterization during the performance verification phase.

Cosmic X-ray physics

NASA Technical Reports Server (NTRS)

Mccammon, D.; Cox, D. P.; Kraushaar, W. L.; Sanders, W. T.

1985-01-01

A progress report of research activities carried out in the area of cosmic X-ray physics is presented. The Diffuse X-ray Spectrometer DXS which has been flown twice as a rocket payload is described. The observation times proved to be too small for meaningful X-ray data to be obtained. Data collection and reduction activities from the Ultra-Soft X-ray background (UXT) instrument are described. UXT consists of three mechanically-collimated X-ray gas proportional counters with window/filter combinations which allow measurements in three energy bands, Be (80-110 eV), B (90-187 eV), and O (e84-532 eV). The Be band measurements provide an important constraint on local absorption of X-rays from the hot component of the local interstellar medium. Work has also continued on the development of a calorimetric detector for high-resolution spectroscopy in the 0.1 keV - 8keV energy range.

Identifying Distant AGNs

NASA Astrophysics Data System (ADS)

Trouille, Laura; Barger, Amy; Tremonti, Christy

2014-07-01

The Baldwin, Phillips, and Terlevich emission-line ratio diagnostic ([OIII]/Hβ versus [NII]/Hα, hereafter BPT diagram) efficiently separates galaxies whose signal is dominated by star formation (BPT-SF) from those dominated by AGN activity (BPT-AGN). Yet the BPT diagram is limited to z<0.5, the redshift at which [NII]λ6584 leaves the optical spectral window. Using the Sloan Digital Sky Survey (SDSS), we construct a new diagnostic, or TBT diagram, that is based on rest-frame g-z color, [NeIII]λ3869, and [OII]λλ3726+3729 and can be used for galaxies out to z<1.4. The TBT diagram identifies 98.7% of the SDSS BPT-AGN as TBT-AGN and 97% of the SDSS BPT-SF as TBT-SF. Furthermore, it identifies 97% of the OPTX Chandra X-ray selected AGNs as TBT-AGN. This is in contrast to the BPT diagram, which misidentifies 20% of X-ray selected AGNs as BPT-SF.

Radio-loud AGN through the eyes of 3XMM, WISE and FIRST/NVSS

NASA Astrophysics Data System (ADS)

Mingo, B.

2014-07-01

We present the results from a new radio-loud AGN sample, obtained through the cross-correlation between the 3XMM, WISE and FIRST/NVSS catalogues. The radio selection allows us to eliminate the restrictions traditionally associated with mid-IR and X-ray sample selections, and to explore the population of lower luminosity AGN, in which the host galaxy contribution is substantial. We investigate the correlations between radio, mid-IR and X-ray emission associated to both stellar and AGN activity, and whether they can be disentangled. This work has been carried out as part of the ARCHES project. ARCHES (Astronomical Resource Cross-matching for High Energy Studies), funded within the EU/FP7-Cooperation Space framework, is a project which aims to produce well-characterised multi-wavelength data for large samples of sources drawn from the 3XMM serendipitous source catalogue.

Distinct regions that control ion selectivity and calcium-dependent activation in the bestrophin ion channel.

PubMed

Vaisey, George; Miller, Alexandria N; Long, Stephen B

2016-11-22

Cytoplasmic calcium (Ca 2+ ) activates the bestrophin anion channel, allowing chloride ions to flow down their electrochemical gradient. Mutations in bestrophin 1 (BEST1) cause macular degenerative disorders. Previously, we determined an X-ray structure of chicken BEST1 that revealed the architecture of the channel. Here, we present electrophysiological studies of purified wild-type and mutant BEST1 channels and an X-ray structure of a Ca 2+ -independent mutant. From these experiments, we identify regions of BEST1 responsible for Ca 2+ activation and ion selectivity. A "Ca 2+ clasp" within the channel's intracellular region acts as a sensor of cytoplasmic Ca 2+ . Alanine substitutions within a hydrophobic "neck" of the pore, which widen it, cause the channel to be constitutively active, irrespective of Ca 2+ . We conclude that the primary function of the neck is as a "gate" that controls chloride permeation in a Ca 2+ -dependent manner. In contrast to what others have proposed, we find that the neck is not a major contributor to the channel's ion selectivity. We find that mutation of a cytosolic "aperture" of the pore does not perturb the Ca 2+ dependence of the channel or its preference for anions over cations, but its mutation dramatically alters relative permeabilities among anions. The data suggest that the aperture functions as a size-selective filter that permits the passage of small entities such as partially dehydrated chloride ions while excluding larger molecules such as amino acids. Thus, unlike ion channels that have a single "selectivity filter," in bestrophin, distinct regions of the pore govern anion-vs.-cation selectivity and the relative permeabilities among anions.

Searching for faint AGN in the CDFS: an X-ray (Chandra) vs optical variability (HST) comparison.

NASA Astrophysics Data System (ADS)

Georgantopoulos, I.; Pouliasis, E.; Bonanos, A.; Sokolovsky, K.; Yang, M.; Hatzidimitriou, D.; Bellas, I.; Gavras, P.; Spetsieri, Z.

2017-10-01

X-ray surveys are believed to be the most efficient way to detect AGN. Recently though, optical variability studies are claimed to probe even fainter AGN. We are presenting results from an HST study aimed to identify Active Galactic Nuclei (AGN) through optical variability selection in the CDFS.. This work is part of the 'Hubble Catalogue of Variables'project of ESA that aims to identify variable sources in the Hubble Source Catalogue.' In particular, we used Hubble Space Telescope (HST) z-band images taken over 5 epochs and performed aperture photometry to derive the lightcurves of the sources. Two statistical methods (standard deviation & interquartile range) resulting in a final sample of 175 variable AGN candidates, having removed the artifacts by visual inspection and known stars and supernovae. The fact that the majority of the sources are extended and variable indicates AGN activity. We compare the efficiency of the method by comparing with the 7Ms Chandra detections. Our work shows that the optical variability probes AGN at comparable redshifts but at deeper optical magnitudes. Our candidate AGN (non detected in X-rays) have luminosities of L_x<6×10^{40} erg/sec at z˜0.7 suggesting that these are associated with low luminosity Seyferts and LINERS.

Broad-band characteristics of seven new hard X-ray selected cataclysmic variables

NASA Astrophysics Data System (ADS)

Bernardini, F.; de Martino, D.; Mukai, K.; Russell, D. M.; Falanga, M.; Masetti, N.; Ferrigno, C.; Israel, G.

2017-10-01

We present timing and spectral analysis of a sample of seven hard X-ray selected cataclysmic variable candidates based on simultaneous X-ray and optical observations collected with XMM-Newton, complemented with Swift/BAT and INTEGRAL /IBIS hard X-ray data and ground-based optical photometry. For six sources, X-ray pulsations are detected for the first time in the range of ˜296-6098 s, identifying them as members of the magnetic class. Swift J0927.7-6945, Swift J0958.0-4208, Swift J1701.3-4304, Swift J2113.5+5422 and possibly PBC J0801.2-4625 are intermediate polars (IPs), while Swift J0706.8+0325 is a short (1.7 h) orbital period polar, the 11th hard X-ray-selected identified so far. X-ray orbital modulation is also observed in Swift J0927.7-6945 (5.2 h) and Swift J2113.5+5422 (4.1 h). Swift J1701.3-4304 is discovered as the longest orbital period (12.8 h) deep eclipsing IP. The spectra of the magnetic systems reveal optically thin multitemperature emission between 0.2 and 60 keV. Energy-dependent spin pulses and the orbital modulation in Swift J0927.7-6945 and Swift J2113.5+5422 are due to intervening local high-density absorbing material (NH ˜ 1022 - 23 cm-2). In Swift J0958.0-4208 and Swift J1701.3-4304, a soft X-ray blackbody (kT ˜ 50 and ˜80 eV) is detected, adding them to the growing group of `soft' IPs. White dwarf masses are determined in the range of ˜ 0.58-1.18 M⊙, indicating massive accreting primaries in five of them. Most sources accrete at rates lower than the expected secular value for their orbital period. Formerly proposed as a long-period (9.4 h) nova-like CV, Swift J0746.3-1608 shows peculiar spectrum and light curves suggesting either an atypical low-luminosity CV or a low-mass X-ray binary.

The BL LAC phenomenon: X-ray observations of transition objects and determination of the x-ray spectrum of a complete sample of flat-spectrum radio sources

NASA Technical Reports Server (NTRS)

Worrall, Diana M.

1994-01-01

This report summarizes the activities related to two ROSAT investigations: (1) x-ray properties of radio galaxies thought to contain BL Lac type nuclei; and (2) x-ray spectra of a complete sample of flat-spectrum radio sources. The following papers describing the research are provided as attachments: Multiple X-ray Emission Components in Low Power Radio Galaxies; New X-ray Results on Radio Galaxies; Analysis Techniques for a Multiwavelength Study of Radio Galaxies; Separation of X-ray Emission Components in Radio Galaxies; X-ray Emission in Powerful Radio Galaxies and Quasars; Extended and Compact X-ray Emission in Powerful Radio Galaxies; and X-ray Spectra of a Complete Sample of Extragalactic Core-dominated Radio Sources.

Coherent X-ray imaging across length scales

NASA Astrophysics Data System (ADS)

Munro, P. R. T.

2017-04-01

Contemporary X-ray imaging techniques span a uniquely wide range of spatial resolutions, covering five orders of magnitude. The evolution of X-ray sources, from the earliest laboratory sources through to highly brilliant and coherent free-electron lasers, has been key to the development of these imaging techniques. This review surveys the predominant coherent X-ray imaging techniques with fields of view ranging from that of entire biological organs, down to that of biomolecules. We introduce the fundamental principles necessary to understand the image formation for each technique as well as briefly reviewing coherent X-ray source development. We present example images acquired using a selection of techniques, by leaders in the field.

X-Ray Instrument for Mars 2020 Rover is PIXL

NASA Image and Video Library

2014-07-31

This diagram depicts the sensor head of the Planetary Instrument for X-RAY Lithochemistry, or PIXL, which has been selected as one of seven investigations for the payload of NASA Mars 2020 rover mission.

Zirconium and silver co-doped TiO2 nanoparticles as visible light catalyst for reduction of 4-nitrophenol, degradation of methyl orange and methylene blue

NASA Astrophysics Data System (ADS)

Naraginti, Saraschandra; Stephen, Finian Bernard; Radhakrishnan, Adhithya; Sivakumar, A.

2015-01-01

Catalytic activity of Zr and Ag co-doped TiO2 nanoparticles on the reduction of 4-nitrophenol, degradation of methylene blue and methyl orange was studied using sodium borohydride as reducing agent. The nanoparticles were characterized using X-ray diffraction, energy dispersive X-ray, high resolution transmission electron microscopy, selected area electron diffraction and UV-Vis spectroscopy. The rate of the reduction/degradation was found to increase with increasing amount of the photocatalyst which could be attributed to higher dispersity and small size of the nanoparticles. The catalytic activity of Zr and Ag co-doped TiO2 nanoparticles showed no significant difference even after recycling the catalyst four times indicating a promising potential for industrial application of the prepared photocatalyst.

Mesoporous silica nanoparticle supported PdIr bimetal catalyst for selective hydrogenation, and the significant promotional effect of Ir

NASA Astrophysics Data System (ADS)

Yang, Hui; Huang, Chao; Yang, Fan; Yang, Xu; Du, Li; Liao, Shijun

2015-12-01

A mesoporous silica nanoparticle (MSN) supported bimetal catalyst, PdIr/MSN, was prepared by a facile impregnation and hydrogen reduction method. The strong promotional effect of Ir was observed and thoroughly investigated. At the optimal molar ratio of Ir to Pd (NIr/NPd = 0.1), the activity of PdIr0.1/MSN was up to eight times and 28 times higher than that of monometallic Pd/MSN and Ir/MSN, respectively. The catalysts were characterized comprehensively by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and hydrogen temperature programmed reduction, which revealed that the promotional effect of Ir may be due to the enhanced dispersion of active components on the MSN, and to the intensified Pd-Ir electronic interaction caused by the addition of Ir.

General equations for optimal selection of diagnostic image acquisition parameters in clinical X-ray imaging.

PubMed

Zheng, Xiaoming

2017-12-01

The purpose of this work was to examine the effects of relationship functions between diagnostic image quality and radiation dose on the governing equations for image acquisition parameter variations in X-ray imaging. Various equations were derived for the optimal selection of peak kilovoltage (kVp) and exposure parameter (milliAmpere second, mAs) in computed tomography (CT), computed radiography (CR), and direct digital radiography. Logistic, logarithmic, and linear functions were employed to establish the relationship between radiation dose and diagnostic image quality. The radiation dose to the patient, as a function of image acquisition parameters (kVp, mAs) and patient size (d), was used in radiation dose and image quality optimization. Both logistic and logarithmic functions resulted in the same governing equation for optimal selection of image acquisition parameters using a dose efficiency index. For image quality as a linear function of radiation dose, the same governing equation was derived from the linear relationship. The general equations should be used in guiding clinical X-ray imaging through optimal selection of image acquisition parameters. The radiation dose to the patient could be reduced from current levels in medical X-ray imaging.

Preparing the optics technology to observe the hot universe

NASA Astrophysics Data System (ADS)

Bavdaz, Marcos; Wille, Eric; Wallace, Kotska; Shortt, Brian; Fransen, Sebastiaan; Collon, Maximilien; Ackermann, Marcelo; Vacanti, Giuseppe; Guenther, Ramses; Haneveld, Jeroen; Riekerink, Mark Olde; van Baren, Coen; Kampf, Dirk; Zuknik, Karl-Heinz; Christensen, Finn; Della Monica Ferreira, Desiree; Jakobsen, Anders Clemen; Krumrey, Michael; Müller, Peter; Burwitz, Vadim; Pareschi, Giovanni; Ghigo, Mauro

2014-07-01

With the selection of "The hot and energetic Universe" as science theme for ESA's second large class mission (L2) in the Cosmic Vision programme, work is focusing on the technology preparation for an advanced X-ray observatory. The core enabling technology for the high performance mirror is the Silicon Pore Optics (SPO) [1 to 23], a modular X-ray optics technology, which utilises processes and equipment developed for the semiconductor industry. The paper provides an overview of the programmatic background, the status of SPO technology and gives an outline of the development roadmap and activities undertaken and planned by ESA on optics, coatings [24 to 30] and test facilities [31, 33].

Electronic structure of transition metal-cysteine complexes from X-ray absorption spectroscopy.

PubMed

Leung, Bonnie O; Jalilehvand, Farideh; Szilagyi, Robert K

2008-04-17

The electronic structures of HgII, NiII, CrIII, and MoV complexes with cysteine were investigated by sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy and density functional theory. The covalency in the metal-sulfur bond was determined by analyzing the intensities of the electric-dipole allowed pre-edge features appearing in the XANES spectra below the ionization threshold. Because of the well-defined structures of the selected cysteine complexes, the current work provides a reference set for further sulfur K-edge XAS studies of bioinorganic active sites with transition metal-sulfur bonds from cysteine residues as well as more complex coordination compounds with thiolate ligands.

Fischer–Tropsch Synthesis at a Low Pressure on Subnanometer Cobalt Oxide Clusters: The Effect of Cluster Size and Support on Activity and Selectivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Sungsik; Lee, Byeongdu; Seifert, Sönke

2015-05-21

In this study, the catalytic activity and changes in the oxidation state during the Fischer Tropsch (FT) reaction was investigated on subnanometer size-selected cobalt clusters deposited on oxide (Al2O3, MgO) and carbon-based (ultrananocrystalline diamond UNCD) supports by temperature programmed reaction (TPRx) combined with in-situ grazing-incidence X-ray absorption characterization (GIXAS). The activity and selectivity of ultrasmall cobalt clusters exhibits a very strong dependence on cluster size and support. The evolution of the oxidation state of metal cluster during the reaction reveals that metal-support interaction plays a key role in the reaction.

Energetic electrons, hard x-ray emission and MHD activity studies in the IR-T1 tokamak.

PubMed

Agah, K Mikaili; Ghoranneviss, M; Elahi, A Salar

2015-01-01

Determinations of plasma parameters as well as the Magnetohydrodynamics (MHD) activity, energetic electrons energy and energy confinement time are essential for future fusion reactors experiments and optimized operation. Also some of the plasma information can be deduced from these parameters, such as plasma equilibrium, stability, and MHD instabilities. In this contribution we investigated the relation between energetic electrons, hard x-ray emission and MHD activity in the IR-T1 Tokamak. For this purpose we used the magnetic diagnostics and a hard x-ray spectroscopy in IR-T1 tokamak. A hard x-ray emission is produced by collision of the runaway electrons with the plasma particles or limiters. The mean energy was calculated from the slope of the energy spectrum of hard x-ray photons.

Active x-ray optics for high resolution space telescopes

NASA Astrophysics Data System (ADS)

Doel, Peter; Atkins, Carolyn; Brooks, D.; Feldman, Charlotte; Willingale, Richard; Button, Tim; Rodriguez Sanmartin, Daniel; Meggs, Carl; James, Ady; Willis, Graham; Smith, Andy

2017-11-01

The Smart X-ray Optics (SXO) Basic Technology project started in April 2006 and will end in October 2010. The aim is to develop new technologies in the field of X-ray focusing, in particular the application of active and adaptive optics. While very major advances have been made in active/adaptive astronomical optics for visible light, little was previously achieved for X-ray optics where the technological challenges differ because of the much shorter wavelengths involved. The field of X-ray astronomy has been characterized by the development and launch of ever larger observatories with the culmination in the European Space Agency's XMM-Newton and NASA's Chandra missions which are currently operational. XMM-Newton uses a multi-nested structure to provide modest angular resolution ( 10 arcsec) but large effective area, while Chandra sacrifices effective area to achieve the optical stability necessary to provide sub-arc second resolution. Currently the European Space Agency (ESA) is engaged in studies of the next generation of X-ray space observatories, with the aim of producing telescopes with increased sensitivity and resolution. To achieve these aims several telescopes have been proposed, for example ESA and NASA's combined International X-ray Observatory (IXO), aimed at spectroscopy, and NASA's Generation-X. In the field of X-ray astronomy sub 0.2 arcsecond resolution with high efficiency would be very exciting. Such resolution is unlikely to be achieved by anything other than an active system. The benefits of a such a high resolution would be important for a range of astrophysics subjects, for example the potential angular resolution offered by active X-ray optics could provide unprecedented structural imaging detail of the Solar Wind bowshock interaction of comets, planets and similar objects and auroral phenomena throughout the Solar system using an observing platform in low Earth orbit. A major aim of the SXO project was to investigate the production of thin actively controlled grazing incident optics for the next generation of X-ray space telescopes. Currently telescope systems are limited in the resolution and sensitivity by the optical quality of the thin shell optics used. As part of its research programme an actively controlled prototype X-ray thin shell telescope optic of dimensions 30x10cm has been developed to bench test the technology. The design is based on thin nickel shells bonded to shaped piezo-electric unimorph actuators made from lead zirconate titanate (PZT).

Micromirror-based manipulation of synchrotron x-ray beams

NASA Astrophysics Data System (ADS)

Walko, D. A.; Chen, Pice; Jung, I. W.; Lopez, D.; Schwartz, C. P.; Shenoy, G. K.; Wang, Jin

2017-08-01

Synchrotron beamlines typically use macroscopic, quasi-static optics to manipulate x-ray beams. We present the use of dynamic microelectromechanical systems-based optics (MEMS) to temporally modulate synchrotron x-ray beams. We demonstrate this concept using single-crystal torsional MEMS micromirrors oscillating at frequencies of 75 kHz. Such a MEMS micromirror, with lateral dimensions of a few hundred micrometers, can interact with x rays by operating in grazing-incidence reflection geometry; x rays are deflected only when an x-ray pulse is incident on the rotating micromirror under appropriate conditions, i.e., at an angle less than the critical angle for reflectivity. The time window for such deflections depends on the frequency and amplitude of the MEMS rotation. We demonstrate that reflection geometry can produce a time window of a few microseconds. We further demonstrate that MEMS optics can isolate x rays from a selected synchrotron bunch or group of bunches. With ray-trace simulations we explain the currently achievable time windows and suggest a path toward improvements.

Novel Tacrine-Benzofuran Hybrids as Potent Multitarget-Directed Ligands for the Treatment of Alzheimer's Disease: Design, Synthesis, Biological Evaluation, and X-ray Crystallography.

PubMed

Zha, Xiaoming; Lamba, Doriano; Zhang, Lili; Lou, Yinghan; Xu, Changxu; Kang, Di; Chen, Li; Xu, Yungen; Zhang, Luyong; De Simone, Angela; Samez, Sarah; Pesaresi, Alessandro; Stojan, Jure; Lopez, Manuela G; Egea, Javier; Andrisano, Vincenza; Bartolini, Manuela

2016-01-14

Twenty-six new tacrine-benzofuran hybrids were designed, synthesized, and evaluated in vitro on key molecular targets for Alzheimer's disease. Most hybrids exhibited good inhibitory activities on cholinesterases and β-amyloid self-aggregation. Selected compounds displayed significant inhibition of human β-secretase-1 (hBACE-1). Among the 26 hybrids, 2e showed the most interesting profile as a subnanomolar selective inhibitor of human acetylcholinesterase (hAChE) (IC50 = 0.86 nM) and a good inhibitor of both β-amyloid aggregation (hAChE- and self-induced, 61.3% and 58.4%, respectively) and hBACE-1 activity (IC50 = 1.35 μM). Kinetic studies showed that 2e acted as a slow, tight-binding, mixed-type inhibitor, while X-ray crystallographic studies highlighted the ability of 2e to induce large-scale structural changes in the active-site gorge of Torpedo californica AChE (TcAChE), with significant implications for structure-based drug design. In vivo studies confirmed that 2e significantly ameliorates performances of scopolamine-treated ICR mice. Finally, 2e administration did not exhibit significant hepatotoxicity.

Carbon Dioxide Electroreduction using a Silver-Zinc Alloy [CO 2 Electroreduction on a Ag-Zn Alloy

DOE PAGES

Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R.; ...

2017-02-20

We report on CO 2 electroreduction activity and selectivity of a polycrystalline AgZn foil in aqueous bicarbonate electrolyte. X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) measurements show that the alloy foil was slightly enriched in zinc both at the surface and in the bulk, with a surface alloy composition of 61.3±5.4 at % zinc and with Ag 5Zn 8 as the most prominent bulk phase. AgZn is active for CO 2 reduction; CO is the main product, likely due to the weak CO binding energy of the surface, with methane and methanol emerging as minor products. Compared to puremore » silver and pure zinc foils, enhancements in activity and selectivity for methane and methanol are observed. A five-fold increase is observed in the combined partial current densities for methane and methanol at –1.43 V vs. the reversible hydrogen electrode (RHE), representing a four- to six-fold increase in faradaic efficiency. Here, such enhancements indicate the existence of a synergistic effect between silver and zinc at the surface of the alloy that contributes to the enhanced formation of further reduced products.« less

The 5-10 keV AGN luminosity function at 0.01 < z < 4.0

NASA Astrophysics Data System (ADS)

Fotopoulou, S.; Buchner, J.; Georgantopoulos, I.; Hasinger, G.; Salvato, M.; Georgakakis, A.; Cappelluti, N.; Ranalli, P.; Hsu, L. T.; Brusa, M.; Comastri, A.; Miyaji, T.; Nandra, K.; Aird, J.; Paltani, S.

2016-03-01

The active galactic nuclei (AGN) X-ray luminosity function traces actively accreting supermassive black holes and is essential for the study of the properties of the AGN population, black hole evolution, and galaxy-black hole coevolution. Up to now, the AGN luminosity function has been estimated several times in soft (0.5-2 keV) and hard X-rays (2-10 keV). AGN selection in these energy ranges often suffers from identification and redshift incompleteness and, at the same time, photoelectric absorption can obscure a significant amount of the X-ray radiation. We estimate the evolution of the luminosity function in the 5-10 keV band, where we effectively avoid the absorbed part of the spectrum, rendering absorption corrections unnecessary up to NH ~ 1023 cm-2. Our dataset is a compilation of six wide, and deep fields: MAXI, HBSS, XMM-COSMOS, Lockman Hole, XMM-CDFS, AEGIS-XD, Chandra-COSMOS, and Chandra-CDFS. This extensive sample of ~1110 AGN (0.01 < z < 4.0, 41 < log Lx < 46) is 98% redshift complete with 68% spectroscopic redshifts. For sources lacking a spectroscopic redshift estimation we use the probability distribution function of photometric redshift estimation specifically tuned for AGN, and a flat probability distribution function for sources with no redshift information. We use Bayesian analysis to select the best parametric model from simple pure luminosity and pure density evolution to more complicated luminosity and density evolution and luminosity-dependent density evolution (LDDE). We estimate the model parameters that describe best our dataset separately for each survey and for the combined sample. We show that, according to Bayesian model selection, the preferred model for our dataset is the LDDE. Our estimation of the AGN luminosity function does not require any assumption on the AGN absorption and is in good agreement with previous works in the 2-10 keV energy band based on X-ray hardness ratios to model the absorption in AGN up to redshift three. Our sample does not show evidence of a rapid decline of the AGN luminosity function up to redshift four.

Upper limits for X-ray emission from Jupiter as measured from the Copernicus satellite

NASA Technical Reports Server (NTRS)

Vesecky, J. F.; Culhane, J. L.; Hawkins, F. J.

1975-01-01

X-ray telescopic observations are made by the Copernicus satellite for detecting X-ray emission from Jupiter analogous to X-rays from terrestrial aurorae. Values of X-ray fluxes recorded by three Copernicus detectors covering the 0.6 to 7.5 keV energy range are reported. The detectors employed are described and the times at which the observations were made are given. Resulting upper-limit spectra are compared with previous X-ray observations of Jupiter. The upper-limit X-ray fluxes are discussed in terms of magnetospheric activity on Jupiter.

The Hunt for Red Quasars: Luminous Obscured Black Hole Growth Unveiled in the Stripe 82 X-Ray Survey

NASA Astrophysics Data System (ADS)

LaMassa, Stephanie M.; Glikman, Eilat; Brusa, Marcella; Rigby, Jane R.; Tasnim Ananna, Tonima; Stern, Daniel; Lira, Paulina; Urry, C. Megan; Salvato, Mara; Alexandroff, Rachael; Allevato, Viola; Cardamone, Carolin; Civano, Francesca; Coppi, Paolo; Farrah, Duncan; Komossa, S.; Lanzuisi, Giorgio; Marchesi, Stefano; Richards, Gordon; Trakhtenbrot, Benny; Treister, Ezequiel

2017-10-01

We present results of a ground-based near-infrared campaign with Palomar TripleSpec, Keck NIRSPEC, and Gemini GNIRS to target two samples of reddened active galactic nucleus (AGN) candidates from the 31 deg2 Stripe 82 X-ray survey. One sample, which is ˜89% complete to K< 16 (Vega), consists of eight confirmed AGNs, four of which were identified with our follow-up program, and is selected to have red R - K colors (> 4, Vega). The fainter sample (K> 17, Vega) represents a pilot program to follow-up four sources from a parent sample of 34 that are not detected in the single-epoch SDSS catalog and have WISE quasar colors. All 12 sources are broad-line AGNs (at least one permitted emission line has an FWHM exceeding 1300 km s-1) and span a redshift range 0.59< z< 2.5. Half the (R - K)-selected AGNs have features in their spectra suggestive of outflows. When comparing these sources to a matched sample of blue Type 1 AGNs, we find that the reddened AGNs are more distant (z> 0.5), and a greater percentage have high X-ray luminosities ({L}{{X},{full}}> {10}44 erg s-1). Such outflows and high luminosities may be consistent with the paradigm that reddened broad-line AGNs represent a transitory phase in AGN evolution as described by the major merger model for black hole growth. Results from our pilot program demonstrate proof of concept that our selection technique is successful in discovering reddened quasars at z> 1 missed by optical surveys.

Serotonergic and dopaminergic activities of rigidified (R)-aporphine derivatives.

PubMed

Linnanen, T; Brisander, M; Mohell, N; Johansson, A M

2001-02-12

Novel rigidified (R)-aporphine derivatives were synthesized from (R)-1,11-carbonylaporphine by ring expansion reactions. The structures of the novel analogues were assigned by NMR spectroscopy and X-ray crystallography. The compounds showed moderate affinities and selectivities at serotonin S-HT1A and 5-HT7 and dopamine D2A receptors.

Association between leukaemia and X-ray in children: a nationwide study.

PubMed

Shih, Tian-Yu; Wu, Jay; Muo, Chin-Shin; Kao, Chia-Hung

2014-08-01

The frequency of employing radiography is increasing. Long-term risks of performing X-ray procedures on children and adolescents for medical diagnosis have raised significant concerns. In this study, we adopt the case-control methodology to evaluate the relationship between the incidence rate of acute leukaemia and exposure to radiation during diagnostic X-ray examinations for children. Based on 1998-2010 data obtained from the Taiwan Bureau of National Health Insurance database, we selected 58 children with leukaemia and randomly selected an additional 232 children as the control group. The mean age of children with leukaemia is 8.92 ± 5.24 years. The risk of leukaemia in children who underwent X-ray examinations increased 2.14-fold (95% CI, 1.18-3.87). In this study, we identified that, when undergoing X-ray examinations, the risk of leukaemia in children increased for both sex and age groups. Specifically, the relationship between leukaemia and X-ray in boys (OR = 3.28, 95%CI, 1.33-8.07) and in ages of 6 to 11 years (OR = 2.58, 95%CI, 1.09-6.10) was significant. Overall, the risk of leukaemia in children who underwent X-ray examinations progressively increased from a ratio of 1.65 to 3.14. Moreover, an identical trend was observed for boys (1.85 to 6.42). Exposure to X-ray increased the risk of leukaemia in children. © 2014 The Authors. Journal of Paediatrics and Child Health © 2014 Paediatrics and Child Health Division (Royal Australasian College of Physicians).

X-Ray Crystallography as a Tool to Determine Three-Dimensional Structures of Commercial Enzymes Subjected to Treatment in Pressurized Fluids.

PubMed

Feiten, Mirian Cristina; Di Luccio, Marco; Santos, Karine F; de Oliveira, Débora; Oliveira, J Vladimir

2017-06-01

The study of enzyme function often involves a multi-disciplinary approach. Several techniques are documented in the literature towards determining secondary and tertiary structures of enzymes, and X-ray crystallography is the most explored technique for obtaining three-dimensional structures of proteins. Knowledge of three-dimensional structures is essential to understand reaction mechanisms at the atomic level. Additionally, structures can be used to modulate or improve functional activity of enzymes by the production of small molecules that act as substrates/cofactors or by engineering selected mutants with enhanced biological activity. This paper presentes a short overview on how to streamline sample preparation for crystallographic studies of treated enzymes. We additionally revise recent developments on the effects of pressurized fluid treatment on activity and stability of commercial enzymes. Future directions and perspectives on the the role of crystallography as a tool to access the molecular mechanisms underlying enzymatic activity modulation upon treatment in pressurized fluids are also addressed.

Evolution of X-ray astronomy

NASA Technical Reports Server (NTRS)

Rossj, B.

1981-01-01

The evolution of X-ray astronomy up to the launching of the Einstein observatory is presented. The evaluation proceeded through the following major steps: (1) discovery of an extrasolar X-ray source, Sco X-1, orders of magnitude stronger than astronomers believed might exist; (2) identification of a strong X-ray source with the Crab Nebula; (3) identification of Sco X-1 with a faint, peculiar optical object; (4) demonstration that X-ray stars are binary systems, each consisting of a collapsed object accreting matter from an ordinary star; (5) discovery of X-ray bursts; (6) discovery of exceedingly strong X-ray emission from active galaxies, quasars and clusters of galaxies; (7) demonstration that the principal X-ray source is a hot gas filling the space between galaxies.

Glass sample preparation and performance investigations. [solar x-ray imager

NASA Technical Reports Server (NTRS)

Johnson, R. Barry

1992-01-01

This final report details the work performed under this delivery order from April 1991 through April 1992. The currently available capabilities for integrated optical performance modeling at MSFC for large and complex systems such as AXAF were investigated. The Integrated Structural Modeling (ISM) program developed by Boeing for the U.S. Air Force was obtained and installed on two DECstations 5000 at MSFC. The structural, thermal and optical analysis programs available in ISM were evaluated. As part of the optomechanical engineering activities, technical support was provided in the design of support structure, mirror assembly, filter wheel assembly and material selection for the Solar X-ray Imager (SXI) program. As part of the fabrication activities, a large number of zerodur glass samples were prepared in different sizes and shapes for acid etching, coating and polishing experiments to characterize the subsurface damage and stresses produced by the grinding and polishing operations. Various optical components for AXAF video microscope and the x-ray test facility were also fabricated. A number of glass fabrication and test instruments such as a scatter plate interferometer, a gravity feed saw and some phenolic cutting blades were fabricated, integrated and tested.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Babucci, Melike; Fang, Chia -Yu; Hoffman, Adam S.

1,3-Dialkylimidazolium ionic liquid coatings act as electron donors, increasing the selectivity for partial hydrogenation of 1,3-butadiene catalyzed by iridium complexes supported on high-surface-area γ-Al 2O 3. High-energy-resolution fluorescence detection X-ray absorption near-edge structure (HERFD XANES) measurements quantify the electron donation and are correlated with the catalytic activity and selectivity. Furthermore, the results demonstrate broad opportunities to tune electronic environments and catalytic properties of atomically dispersed supported metal catalysts.

Study of novel mechano-chemical activation process of red mud to optimize nitrate removal from water.

PubMed

Alighardashi, A; Gharibi, H R; Raygan, Sh; Akbarzadeh, A

2016-01-01

Red mud (RM) is the industrial waste of alumina production and causes serious environmental risks. In this paper, a novel activation procedure for RM (mechano-chemical processing) is proposed in order to improve the nitrate adsorption from water. High-energy milling and acidification were selected as mechanical and chemical activation methods, respectively. Synthesized samples of adsorbent were produced considering two parameters of activation: acid concentrations and acidification time in two selected milling times. Optimization of the activation process was based on nitrate removal from a stock solution. Experimental data were analyzed with two-way analysis of variance and Kruskal-Wallis methods to verify and discover the accuracy and probable errors. Best conditions (acceptable removal percentage > 75) were 17.6% w/w for acid concentrate and 19.9 minutes for acidification time in 8 hours for milling time. A direct relationship between increase in nitrate removal and increasing the acid concentration and acidification time was observed. The adsorption isotherms were studied and compared with other nitrate adsorbents. Characterization tests (X-ray fluorescence, X-ray diffraction, Fourier transform infrared spectrophotometry, dynamic light scattering, surface area analysis and scanning electron microscopy) were conducted for both raw and activated adsorbents. Results showed noticeable superiority in characteristics after activation: higher specific area and porosity, lower particle size and lower agglomeration in structure.

Differences in responses to X-ray exposure between osteoclast and osteoblast cells

PubMed Central

Zhang, Jian; Wang, Ziyang; Wu, Anqing; Nie, Jing; Pei, Hailong; Hu, Wentao; Wang, Bing; Shang, Peng; Li, Bingyan

2017-01-01

Abstract Radiation-induced bone loss is a potential health concern for cancer patients undergoing radiotherapy. Enhanced bone resorption by osteoclasts and decreased bone formation by osteoblasts were thought to be the main reasons. In this study, we showed that both pre-differentiating and differentiating osteoclasts were relatively sensitive to X-rays compared with osteoblasts. X-rays decreased cell viability to a greater degree in RAW264.7 cells and in differentiating cells than than in osteoblastic MC3T3-E1 cells. X-rays at up to 8 Gy had little effects on osteoblast mineralization. In contrast, X-rays at 1 Gy induced enhanced osteoclastogenesis by enhanced cell fusion, but had no effects on bone resorption. A higher dose of X-rays at 8 Gy, however, had an inhibitory effect on bone resorption. In addition, actin ring formation was disrupted by 8 Gy of X-rays and reorganized into clusters. An increased activity of Caspase 3 was found after X-ray exposure. Actin disorganization and increased apoptosis may be the potential effects of X-rays at high doses, by inhibiting osteoclast differentiation. Taken together, our data indicate high radiosensitivity of osteoclasts. X-ray irradiation at relatively low doses can activate osteoclastogenesis, but not osteogenic differentiation. The radiosensitive osteoclasts are the potentially responsive cells for X-ray-induced bone loss. PMID:28541506

Dose-rate plays a significant role in synchrotron radiation X-ray-induced damage of rodent testes.

PubMed

Chen, Heyu; Wang, Ban; Wang, Caixia; Cao, Wei; Zhang, Jie; Ma, Yingxin; Hong, Yunyi; Fu, Shen; Wu, Fan; Ying, Weihai

2016-01-01

Synchrotron radiation (SR) X-ray has significant potential for applications in medical imaging and cancer treatment. However, the mechanisms underlying SR X-ray-induced tissue damage remain unclear. Previous studies on regular X-ray-induced tissue damage have suggested that dose-rate could affect radiation damage. Because SR X-ray has exceedingly high dose-rate compared to regular X-ray, it remains to be determined if dose-rate may affect SR X-ray-induced tissue damage. We used rodent testes as a model to investigate the role of dose-rate in SR X-ray-induced tissue damage. One day after SR X-ray irradiation, we determined the effects of the irradiation of the same dosage at two different dose-rates, 0.11 Gy/s and 1.1 Gy/s, on TUNEL signals, caspase-3 activation and DNA double-strand breaks (DSBs) of the testes. Compared to those produced by the irradiation at 0.11 Gy/s, irradiation at 1.1 Gy/s produced higher levels of DSBs, TUNEL signals, and caspase-3 activation in the testes. Our study has provided the first evidence suggesting that dose-rate could be a significant factor in SR X-ray-induced tissue damage, which may establish a valuable base for utilizing this factor to manipulate the tissue damage in SR X-ray-based medical applications.

Dose-rate plays a significant role in synchrotron radiation X-ray-induced damage of rodent testes

PubMed Central

Chen, Heyu; Wang, Ban; Wang, Caixia; Cao, Wei; Zhang, Jie; Ma, Yingxin; Hong, Yunyi; Fu, Shen; Wu, Fan; Ying, Weihai

2016-01-01

Synchrotron radiation (SR) X-ray has significant potential for applications in medical imaging and cancer treatment. However, the mechanisms underlying SR X-ray-induced tissue damage remain unclear. Previous studies on regular X-ray-induced tissue damage have suggested that dose-rate could affect radiation damage. Because SR X-ray has exceedingly high dose-rate compared to regular X-ray, it remains to be determined if dose-rate may affect SR X-ray-induced tissue damage. We used rodent testes as a model to investigate the role of dose-rate in SR X-ray-induced tissue damage. One day after SR X-ray irradiation, we determined the effects of the irradiation of the same dosage at two different dose-rates, 0.11 Gy/s and 1.1 Gy/s, on TUNEL signals, caspase-3 activation and DNA double-strand breaks (DSBs) of the testes. Compared to those produced by the irradiation at 0.11 Gy/s, irradiation at 1.1 Gy/s produced higher levels of DSBs, TUNEL signals, and caspase-3 activation in the testes. Our study has provided the first evidence suggesting that dose-rate could be a significant factor in SR X-ray-induced tissue damage, which may establish a valuable base for utilizing this factor to manipulate the tissue damage in SR X-ray-based medical applications. PMID:28078052

The ever-surprising blazar OJ 287: multi-wavelength study and appearance of a new component in X-rays

NASA Astrophysics Data System (ADS)

Kushwaha, Pankaj; Gupta, Alok C.; Wiita, Paul J.; Pal, Main; Gaur, Haritma; de Gouveia Dal Pino, E. M.; Kurtanidze, O. M.; Semkov, E.; Damljanovic, G.; Hu, S. M.; Uemura, M.; Vince, O.; Darriba, A.; Gu, M. F.; Bachev, R.; Chen, Xu; Itoh, R.; Kawabata, M.; Kurtanidze, S. O.; Nakaoka, T.; Nikolashvili, M. G.; Sigua, L. A.; Strigachev, A.; Zhang, Z.

2018-06-01

We present a multi-wavelength spectral and temporal investigation of OJ 287 emission during its strong optical-to-X-ray activity between July 2016 - July 2017. The daily γ-ray fluxes from Fermi-LAT are consistent with no variability. The strong optical-to-X-ray variability is accompanied by a change in power-law spectral index of the X-ray spectrum from <2 to >2, with variations often associated with changes in optical polarization properties. Cross-correlations between optical-to-X-ray emission during four continuous segments show simultaneous optical-ultraviolet (UV) variations while the X-ray and UV/optical are simultaneous only during the middle two segments. In the first segment, the results suggest X-rays lag the optical/UV, while in the last segment X-rays lead by ˜ 5-6 days. The last segment also shows a systematic trend with variations appearing first at higher energies followed by lower energy ones. The LAT spectrum before the VHE activity is similar to preceding quiescent state spectrum while it hardens during VHE activity period and is consistent with the extrapolated VHE spectrum during the latter. Overall, the broadband spectral energy distributions (SEDs) during high activity periods are a combination of a typical OJ 287 SED and an HBL SED, and can be explained in a two-zone leptonic model, with the second zone located at parsec scales, beyond the broad line region, being responsible for the HBL-like spectrum. The change of polarization properties from systematic to chaotic and back to systematic, before, during and after the VHE activity, suggest dynamic roles for magnetic fields and turbulence.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jay, Raphael M.; Norell, Jesper; Eckert, Sebastian

Soft X-ray spectroscopies are ideal probes of the local valence electronic structure of photocatalytically active metal sites. Here, we apply the selectivity of time-resolved resonant inelastic X-ray scattering at the iron L-edge to the transient charge distribution of an optically excited charge-transfer state in aqueous ferricyanide. Through comparison to steady-state spectra and quantum chemical calculations, the coupled effects of valence-shell closing and ligand-hole creation are experimentally and theoretically disentangled and described in terms of orbital occupancy, metal–ligand covalency, and ligand field splitting, thereby extending established steady-state concepts to the excited-state domain. π-Back-donation is found to be mainly determined by themore » metal site occupation, whereas the ligand hole instead influences σ-donation. Here, our results demonstrate how ultrafast resonant inelastic X-ray scattering can help characterize local charge distributions around catalytic metal centers in short-lived charge-transfer excited states, as a step toward future rationalization and tailoring of photocatalytic capabilities of transition-metal complexes.« less

Room-temperature H2S Gas Sensor Based on Au-doped ZnFe2O4 Yolk-shell Microspheres.

PubMed

Yan, Yin; Nizamidin, Patima; Turdi, Gulmira; Kari, Nuerguli; Yimit, Abliz

2017-01-01

Room-temperature type H 2 S sensing devices that use Au-doped ZnFe 2 O 4 yolk-shell microspheres as the active material have been fabricated using a solvothermal method as well as subsequent annealing and a chemical etching process. The samples are characterized using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), field-emission scanning electron microscopy (FESEM), and X-ray photoelectron spectroscopy (XPS). The results demonstrate that the doping of Au does not change the spinel structure of the products, which were yolk-shell microspheres, while the particle size varied with the Au doping concentration. Also, the as-fabricated sensor device exhibited excellent selectivity toward H 2 S gas at the room temperature; the gas-sensing property of 2 wt% Au-doped ZnFe 2 O 4 microspheres was the best. The Au-doped ZnFe 2 O 4 yolk-shell microspheres can be promising as a sensing material for H 2 S gas detecting at room temperature.

X-Ray Astronomy Research at the Marshall Space Flight Center

NASA Technical Reports Server (NTRS)

Austin, Robert A.

1999-01-01

For at least twenty years, NASA's Marshall Space Flight Center (MSFC) has played a major role in the development of X-ray astronomy in the United States. MSFC scientists and engineers are currently involved in a wide range of programs which will contribute to the growth of X-ray astronomy well into the next century. Areas of activity include calibration of X-ray astronomy instrumentation using Marshall's world-class X-ray Calibration Facility (XRCF), development of high-throughput, replicated X-ray optics, X-ray detector development, balloon-based X-ray astronomy, and analysis of Active Galactic Nuclei (AGNs) and clusters of galaxies. Recent milestones include the successful calibration of NASA's premier X-ray Astronomy Satellite - AXAF (recently renamed Chandra), a balloon flight of a large area (1000 sq cm) micro-strip proportional counter, and work on a hard X-ray (30-100 keV) telescope called HERO, capable of high quality spectroscopy and imaging through the use of grazing incidence optics and an Imaging Gas Scintillation Proportional Counter (IGSPC). In my presentation, I will provide a general overview of our research and facilities. I will conclude with a more detailed discussion of our High Energy Replicated Optics (HERO) program and plans for long duration (>100 days) balloon flights which will take place in the near future.

First demonstration of iodine mapping in nonliving phantoms using an X-ray fluorescence computed tomography system with a cadmium telluride detector and a tungsten-target tube

NASA Astrophysics Data System (ADS)

Sato, Eiichi; Sato, Yuichi; Ehara, Shigeru; Abudurexiti, Abulajiang; Hagiwara, Osahiko; Matsukiyo, Hiroshi; Osawa, Akihiro; Enomoto, Toshiyuki; Watanabe, Manabu; Nagao, Jiro; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2011-05-01

X-ray fluorescence (XRF) analysis is useful for mapping various atoms in objects, and XRF is emitted by absorbing X-ray photons with energies beyond the K-edge energy of the target atom. Narrow-energy-width bremsstrahlung X-rays are selected using a 3.0-mm-thick aluminum filter. These rays are absorbed by iodine media in objects, and iodine XRF is produced from the iodine atoms. Next, iodine Kα photons are discriminated by a multichannel analyzer and the number of photons is counted by a counter card. CT is performed by repeated linear scans and rotations of an object. The X-ray generator has a 100 μm focus tube with a 0.5-mm-thick beryllium window, and the tube voltage and the current for XRF were 80 kV and 0.50 mA, respectively. The demonstration of XRF-CT for mapping iodine atoms was carried out by selection of photons in an energy range from 27.5 to 29.5 keV with a photon-energy resolution of 1.2 keV.

Results from OSO-IV - The long term behavior of X-ray emitting regions.

NASA Technical Reports Server (NTRS)

Krieger, A.; Paolini, F.; Vaiana, G. S.; Webb, D.

1972-01-01

Analysis of images of the sun obtained with the aid of a grazing incidence X-ray telescope on board the OSO IV spacecraft in the 2.5 to 12-A waveband nearly continuously from Oct. 27, 1967, to May 12, 1968. The instrument had sufficient spatial resolution (one and four arc minutes) and temporal resolution (5 to 20 min) to estimate the spatial characteristics of X-ray emitting regions and to monitor the temporal behavior of individual active regions. Variations in the absence of flares of as much as a factor of 10 in the X-ray output of individual regions were observed, with typical durations ranging from several hours to several days. The X-ray time variations are related to observations at optical and radio wavelengths. The results are interpreted under the assumption that the X-ray time variations are caused by temperature changes in the coronal portions of active regions. The contribution of radiative losses to the energy budget of the coronal active region is estimated.

X-ray emission processes in stars and their immediate environment

PubMed Central

Testa, Paola

2010-01-01

A decade of X-ray stellar observations with Chandra and XMM-Newton has led to significant advances in our understanding of the physical processes at work in hot (magnetized) plasmas in stars and their immediate environment, providing new perspectives and challenges, and in turn the need for improved models. The wealth of high-quality stellar spectra has allowed us to investigate, in detail, the characteristics of the X-ray emission across the Hertzsprung-Russell (HR) diagram. Progress has been made in addressing issues ranging from classical stellar activity in stars with solar-like dynamos (such as flares, activity cycles, spatial and thermal structuring of the X-ray emitting plasma, and evolution of X-ray activity with age), to X-ray generating processes (e.g., accretion, jets, magnetically confined winds) that were poorly understood in the preChandra/XMM-Newton era. I will discuss the progress made in the study of high energy stellar physics and its impact in a wider astrophysical context, focusing on the role of spectral diagnostics now accessible. PMID:20360562

Three-energy focusing Laue monochromator for the diamond light source x-ray pair distribution function beamline I15-1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sutter, John P., E-mail: john.sutter@diamond.ac.uk; Chater, Philip A.; Hillman, Michael R.

2016-07-27

The I15-1 beamline, the new side station to I15 at the Diamond Light Source, will be dedicated to the collection of atomic pair distribution function data. A Laue monochromator will be used consisting of three silicon crystals diffracting X-rays at a common Bragg angle of 2.83°. The crystals use the (1 1 1), (2 2 0), and (3 1 1) planes to select 40, 65, and 76 keV X-rays, respectively, and will be bent meridionally to horizontally focus the selected X-rays onto the sample. All crystals will be cut to the same optimized asymmetry angle in order to eliminate imagemore » broadening from the crystal thickness. Finite element calculations show that the thermal distortion of the crystals will affect the image size and bandpass.« less

Image processing for x-ray inspection of pistachio nuts

NASA Astrophysics Data System (ADS)

Casasent, David P.

2001-03-01

A review is provided of image processing techniques that have been applied to the inspection of pistachio nuts using X-ray images. X-ray sensors provide non-destructive internal product detail not available from other sensors. The primary concern in this data is detecting the presence of worm infestations in nuts, since they have been linked to the presence of aflatoxin. We describe new techniques for segmentation, feature selection, selection of product categories (clusters), classifier design, etc. Specific novel results include: a new segmentation algorithm to produce images of isolated product items; preferable classifier operation (the classifier with the best probability of correct recognition Pc is not best); higher-order discrimination information is present in standard features (thus, high-order features appear useful); classifiers that use new cluster categories of samples achieve improved performance. Results are presented for X-ray images of pistachio nuts; however, all techniques have use in other product inspection applications.

Analysis of solar X-ray data

NASA Technical Reports Server (NTRS)

Teske, R. G.

1972-01-01

Type III solar bursts occurring in the absence of solar flares were observed to be accompanied by weak X-radiation. The energy scale of an OSO-3 soft X-ray ion chamber was assessed using realistic theoretical X-ray spectra. Relationships between soft solar X-rays and solar activity were investigated. These included optical studies, the role of the Type III acceleration mechanism in establishing the soft X-ray source volume, H alpha flare intensity variations, and gross magnetic field structure.

The Hard X-ray Imager (HXI) for the ASTRO-H Mission

NASA Astrophysics Data System (ADS)

Sato, Goro; Kokubun, Motohide; Nakazawa, Kazuhiro; Enoto, Teruaki; Fukazawa, Yasushi; Harayama, Atsushi; Hayashi, Katsuhiro; Kataoka, Jun; Katsuta, Junichiro; Kawaharada, Madoka; Laurent, Philippe; Lebrun, François; Limousin, Olivier; Makishima, Kazuo; Mizuno, Tsunefumi; Mori, Kunishiro; Nakamori, Takeshi; Noda, Hirofumi; Odaka, Hirokazu; Ohno, Masanori; Ohta, Masayuki; Saito, Shinya; Sato, Rie; Tajima, Hiroyasu; Takahashi, Hiromitsu; Takahashi, Tadayuki; Takeda, Shinichiro; Terada, Yukikatsu; Uchiyama, Hideki; Uchiyama, Yasunobu; Watanabe, Shin; Yamaoka, Kazutaka; Yatsu, Yoichi; Yuasa, Takayuki

2014-07-01

The 6th Japanese X-ray satellite, ASTRO-H, is scheduled for launch in 2015. The hard X-ray focusing imaging system will observe astronomical objects with the sensitivity for detecting point sources with a brightness of 1/100,000 times fainter than the Crab nebula at > 10 keV. The Hard X-ray Imager (HXI) is a focal plane detector 12 m below the hard X-ray telescope (HXT) covering the energy range from 5 to 80 keV. The HXI is composed of a stacked Si/CdTe semiconductor detector module and surrounding BGO scintillators. The latter work as active shields for efficient reduction of background events caused by cosmic-ray particles, cosmic X-ray background, and in-orbit radiation activation. In this paper, we describe the detector system, and present current status of flight model development, and performance of HXI using an engineering model of HXI.

Cosmological constraints from X-ray all sky surveys, from CODEX to eROSITA

NASA Astrophysics Data System (ADS)

Finoguenov, A.

2017-10-01

Large area cluster cosmology has long become a multiwavelength discipline. Understanding the effect of various selections is currently the main path to improving on the validity of cluster cosmological results. Many of these results are based on the large area sample derived from RASS data. We perform wavelet detection of X-ray sources and make extensive simulations of the detection of clusters in the RASS data. We assign an optical richness to each of the 25,000 detected X-ray sources in the 10,000 square degrees of SDSS BOSS area. We show that there is no obvious separation of sources on galaxy clusters and AGN, based on distribution of systems on their richness. We conclude that previous catalogs, such as MACS, REFLEX are all subject to a complex optical selection function, in addition to an X-ray selection. We provide a complete model of identification of cluster counts are galaxy clusters, which includes chance identification, effect of AGN halo occupation distribution and the thermal emission of ICM. Finally we present the cosmological results obtained using this sample.

Dynamic electronic collimation method for 3-D catheter tracking on a scanning-beam digital x-ray system

PubMed Central

Dunkerley, David A. P.; Slagowski, Jordan M.; Funk, Tobias; Speidel, Michael A.

2017-01-01

Abstract. Scanning-beam digital x-ray (SBDX) is an inverse geometry x-ray fluoroscopy system capable of tomosynthesis-based 3-D catheter tracking. This work proposes a method of dose-reduced 3-D catheter tracking using dynamic electronic collimation (DEC) of the SBDX scanning x-ray tube. This is achieved through the selective deactivation of focal spot positions not needed for the catheter tracking task. The technique was retrospectively evaluated with SBDX detector data recorded during a phantom study. DEC imaging of a catheter tip at isocenter required 340 active focal spots per frame versus 4473 spots in full field-of-view (FOV) mode. The dose-area product (DAP) and peak skin dose (PSD) for DEC versus full FOV scanning were calculated using an SBDX Monte Carlo simulation code. The average DAP was reduced to 7.8% of the full FOV value, consistent with the relative number of active focal spots (7.6%). For image sequences with a moving catheter, PSD was 33.6% to 34.8% of the full FOV value. The root-mean-squared-deviation between DEC-based 3-D tracking coordinates and full FOV 3-D tracking coordinates was less than 0.1 mm. The 3-D distance between the tracked tip and the sheath centerline averaged 0.75 mm. DEC is a feasible method for dose reduction during SBDX 3-D catheter tracking. PMID:28439521

The NASA X-Ray Mission Concepts Study

NASA Technical Reports Server (NTRS)

Petre, Robert; Ptak, A.; Bookbinder, J.; Garcia, M.; Smith, R.; Bautz, M.; Bregman, J.; Burrows, D.; Cash, W.; Jones-Forman, C.;

Synthesis and preliminary biological evaluation of potent and selective 2-(3-alkoxy-1-azetidinyl) quinolines as novel PDE10A inhibitors with improved solubility.

PubMed

Rzasa, Robert M; Frohn, Michael J; Andrews, Kristin L; Chmait, Samer; Chen, Ning; Clarine, Jeffrey G; Davis, Carl; Eastwood, Heather A; Horne, Daniel B; Hu, Essa; Jones, Adrie D; Kaller, Matthew R; Kunz, Roxanne K; Miller, Silke; Monenschein, Holger; Nguyen, Thomas; Pickrell, Alexander J; Porter, Amy; Reichelt, Andreas; Zhao, Xiaoning; Treanor, James J S; Allen, Jennifer R

2014-12-01

We report the discovery of a novel series of 2-(3-alkoxy-1-azetidinyl) quinolines as potent and selective PDE10A inhibitors. Structure-activity studies improved the solubility (pH 7.4) and maintained high PDE10A activity compared to initial lead compound 3, with select compounds demonstrating good oral bioavailability. X-ray crystallographic studies revealed two distinct binding modes to the catalytic site of the PDE10A enzyme. An ex vivo receptor occupancy assay in rats demonstrated that this series of compounds covered the target within the striatum.

Near-infrared Variability of Obscured and Unobscured X-Ray-selected AGNs in the COSMOS Field

NASA Astrophysics Data System (ADS)

Sánchez, P.; Lira, P.; Cartier, R.; Pérez, V.; Miranda, N.; Yovaniniz, C.; Arévalo, P.; Milvang-Jensen, B.; Fynbo, J.; Dunlop, J.; Coppi, P.; Marchesi, S.

2017-11-01

We present our statistical study of near-infrared (NIR) variability of X-ray-selected active galactic nuclei (AGNs) in the COSMOS field, using UltraVISTA data. This is the largest sample of AGN light curves in YJHKs bands, making it possible to have a global description of the nature of AGNs for a large range of redshifts and for different levels of obscuration. To characterize the variability properties of the sources, we computed the structure function. Our results show that there is an anticorrelation between the structure function A parameter (variability amplitude) and the wavelength of emission and a weak anticorrelation between A and the bolometric luminosity. We find that broad-line (BL) AGNs have a considerably larger fraction of variable sources than narrow-line (NL) AGNs and that they have different distributions of the A parameter. We find evidence that suggests that most of the low-luminosity variable NL sources correspond to BL AGNs, where the host galaxy could be damping the variability signal. For high-luminosity variable NL sources, we propose that they can be examples of “true type II” AGNs or BL AGNs with limited spectral coverage, which results in missing the BL emission. We also find that the fraction of variable sources classified as unobscured in the X-ray is smaller than the fraction of variable sources unobscured in the optical range. We present evidence that this is related to the differences in the origin of the obscuration in the optical and X-ray regimes.

Deep ALMA photometry of distant X-ray AGN: improvements in star formation rate constraints, and AGN identification

NASA Astrophysics Data System (ADS)

Stanley, F.; Harrison, C. M.; Alexander, D. M.; Simpson, J.; Knudsen, K. K.; Mullaney, J. R.; Rosario, D. J.; Scholtz, J.

2018-05-01

We present the star formation rates (SFRs) of a sample of 109 galaxies with X-ray selected active galactic nuclei (AGN) with moderate to high X-ray luminosities (\\mathrel {L_2-8{keV}}= 10^{42} - 10^{45} \\mathrel {erg {} s^{-1}}), at redshifts 1 < z < 4.7, that were selected to be faint or undetected in the Herschel bands. We combine our deep ALMA continuum observations with deblended 8-500\\mathrel {μ m} photometry from Spitzer and Herschel, and use infrared (IR) SED fitting and AGN - star formation decomposition methods. The addition of the ALMA photometry results in an order of magnitude more X-ray AGN in our sample with a measured SFR (now 37 per cent). The remaining 63 per cent of the sources have SFR upper limits that are typically a factor of 2-10 times lower than the pre-ALMA constraints. With the improved constraints on the IR SEDs, we can now identify a mid-IR (MIR) AGN component in 50 per cent of our sample, compared to only ˜1 per cent previously. We further explore the F_{870\\mathrel {μ m}}/F_{24\\mathrel {μ m}}-redshift plane as a tool for the identification of MIR emitting AGN, for three different samples representing AGN dominated, star formation dominated, and composite sources. We demonstrate that the F_{870\\mathrel {μ m}}/F_{24\\mathrel {μ m}}-redshift plane can successfully split between AGN and star formation dominated sources, and can be used as an AGN identification method.

Merger-driven fueling of active galactic nuclei: Six dual and of AGNs discovered with Chandra and Hubble Space Telescope observations

DOE PAGES

Comerford, Julia M.; Pooley, David; Barrows, R. Scott; ...

2015-06-19

Dual active galactic nuclei (AGNs) and offset AGNs are kpc-scale separation supermassive black holes pairs created during galaxy mergers, where both or one of the black holes are AGNs, respectively. These dual and offset AGNs are valuable probes of the link between mergers and AGNs but are challenging to identify. Here we present Chandra/ACIS observations of 12 optically selected dual AGN candidates atmore » $$z\\lt 0.34$$, where we use the X-rays to identify AGNs. We also present Hubble Space Telescope/Wide Field Camera 3 observations of 10 of these candidates, which reveal any stellar bulges accompanying the AGNs. We discover a dual AGN system with separation $${\\rm \\Delta }x=2.2$$ kpc, where the two stellar bulges have coincident [O iii] λ5007 and X-ray sources. This system is an extremely minor merger (460:1) that may include a dwarf galaxy hosting an intermediate mass black hole. We also find six single AGNs, and five systems that are either dual or offset AGNs with separations $${\\rm \\Delta }x\\lt 10$$ kpc. Four of the six dual AGNs and dual/offset AGNs are in ongoing major mergers, and these AGNs are 10 times more luminous, on average, than the single AGNs in our sample. This hints that major mergers may preferentially trigger higher luminosity AGNs. Further, we find that confirmed dual AGNs have hard X-ray luminosities that are half of those of single AGNs at fixed [O III] λ5007 luminosity, on average. Lastly, this could be explained by high densities of gas funneled to galaxy centers during mergers, and emphasizes the need for deeper X-ray observations of dual AGN candidates.« less

Effect of Ce/Zr molar ratio on the performance of Cu–Ce{sub x}–Zr{sub 1−x}/TiO{sub 2} catalyst for selective catalytic reduction of NO{sub x} with NH{sub 3} in diesel exhaust

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Xiaoliang; Gong, Cairong, E-mail: gcr@tju.edu.cn; Lv, Gang

2014-12-15

Graphical abstract: The Cu–Ce{sub 0.25}–Zr{sub 0.75}/TiO{sub 2} catalyst exhibited excellent SCR activity at 165–450 °C within the range of exhaust temperatures of diesel engines. - Highlights: • Cu–Ce{sub x}–Zr{sub 1−x}/TiO{sub 2} catalysts were prepared by a wet impregnation method. • The property for NH{sub 3}-selective catalytic reduction of NO{sub x} were investigated. • The Ce/Zr molar ratio had effects on the performance of Cu–Ce–Zr/TiO{sub 2} catalysts. • The Cu–Ce{sub 0.25}–Zr{sub 0.75}/TiO{sub 2} sample exhibited 100% NO{sub x} conversion between 165 °C and 450 °C. • The factors that govern the activity enhancement were extensively investigated. - Abstract: Copper–cerium–zirconium catalysts loadedmore » on TiO{sub 2} prepared by a wet impregnation method were investigated for NH{sub 3}-selective catalytic reduction of NO{sub x}, aiming to study the effects of the Ce/Zr molar ratio on the performance of Cu–Ce–Zr/TiO{sub 2} catalysts. The Cu–Ce{sub 0.25}–Zr{sub 0.75}/TiO{sub 2} sample exhibited nearly 100% NO{sub x} conversion over a wide temperature range (165–450 °C), which is strikingly superior to that of Cu/TiO{sub 2} (210–389 °C) within the range of exhaust temperatures of diesel engines. The factors that govern the activity enhancement were extensively investigated by using a series of characterization techniques, namely X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction by hydrogen (H{sub 2}-TPR). The results showed that the addition of zirconium and/or cerium refined the copper dispersion, prevented copper crystallization and partially incorporated the copper ions into the zirconia (ceira) lattice, which led to enhance the redox abilities of Cu–Ce–Zr/TiO{sub 2} catalysts.« less

VizieR Online Data Catalog: Properties of giant arcs behind CLASH clusters (Xu+, 2016)

NASA Astrophysics Data System (ADS)

Xu, B.; Postman, M.; Meneghetti, M.; Seitz, S.; Zitrin, A.; Merten, J.; Maoz, D.; Frye, B.; Umetsu, K.; Zheng, W.; Bradley, L.; Vega, J.; Koekemoer, A.

2018-01-01

Giant arcs are found in the CLASH images and in simulated images that mimic the CLASH data, using an efficient automated arc-finding algorithm whose selection function has been carefully quantified. CLASH is a 524-orbit multicycle treasury program that targeted 25 massive clusters with 0.18=6.5 in 20 X-ray-selected CLASH clusters. After applying our minimum arc length criterion l>=6", the arc count drops to 81 giant arcs selected from the 20 X-ray-selected CLASH clusters. (2 data files).

Improving X-Ray Optics via Differential Deposition

NASA Technical Reports Server (NTRS)

Kilaru, Kiranmayee; Ramsey, Brian D.; Atkins, Carolyn

2017-01-01

Differential deposition, a post-fabrication figure correction technique, has the potential to significantly improve the imaging quality of grazing-incidence X-ray optics. DC magnetron sputtering is used to selectively coat the mirror in order to minimize the figure deviations. Custom vacuum chambers have been developed at NASA MSFC that will enable the implementation of the deposition on X-ray optics. A factor of two improvement has been achieved in the angular resolution of the full-shell X-ray optics with first stage correction of differential deposition. Current efforts are focused on achieving higher improvements through efficient implementation of differential deposition.

X-ray atlas of rheumatic diseases

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dihlmann, W.

1986-01-01

This atlas comprises instructive X-rays of the various inflammatory rheumatic joint diseases in all stages at the extremities and the spinal column. In addition, the complex pattern of the wide range of arthroses, also known as degenerative rheumatic disease is included. Besides the instructive pointers to X-ray diagnosis, the book is also a guide to differential diagnosis. Hence, this book is actually an X-ray atlas of joint diseases in general. Selected Contents: Introduction: What Does ''Rheumatism'' Actually Mean./Radiographic Methodology in Rheumatic Diseases of the Locomotor System/The Mosaic of Arthritis/Adult Rheumatoid Arthritis/Seronegative Spondylarthritis/Classic Collagen Diseases/Enthesiopathies/Gout-Pseudogout

X-ray studies of coeval star samples. II. The Pleiades cluster as observed with the Einstein Observatory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Micela, G.; Sciortino, S.; Vaiana, G.S.

1990-01-01

Coronal X-ray emission of the Pleiades stars is investigated, and maximum likelihood, integral X-ray luminosity functions are computed for Pleiades members in selected color-index ranges. A detailed search is conducted for long-term variability in the X-ray emission of those stars observed more than once. An overall comparison of the survey results with those of previous surveys confirms the ubiquity of X-ray emission in the Pleiades cluster stars and its higher rate of emission with respect to older stars. It is found that the X-ray emission from dA and early dF stars cannot be proven to be dissimilar to that ofmore » Hyades and field stars of the same spectral type. The Pleiades cluster members show a real rise of the X-ray luminosity from dA stars to early dF stars. X-ray emission for the young, solarlike Pleiades stars is about two orders of magnitude more intense than for the nearby solarlike stars. 77 refs.« less

Real-time X-ray Diffraction: Applications to Materials Characterization

NASA Technical Reports Server (NTRS)

Rosemeier, R. G.

1984-01-01

With the high speed growth of materials it becomes necessary to develop measuring systems which also have the capabilities of characterizing these materials at high speeds. One of the conventional techniques of characterizing materials was X-ray diffraction. Film, which is the oldest method of recording the X-ray diffraction phenomenon, is not quite adequate in most circumstances to record fast changing events. Even though conventional proportional counters and scintillation counters can provide the speed necessary to record these changing events, they lack the ability to provide image information which may be important in some types of experiment or production arrangements. A selected number of novel applications of using X-ray diffraction to characterize materials in real-time are discussed. Also, device characteristics of some X-ray intensifiers useful in instantaneous X-ray diffraction applications briefly presented. Real-time X-ray diffraction experiments with the incorporation of image X-ray intensification add a new dimension in the characterization of materials. The uses of real-time image intensification in laboratory and production arrangements are quite unlimited and their application depends more upon the ingenuity of the scientist or engineer.

Gamma rays of energy or = 10(15) eV from Cyg X-3

NASA Technical Reports Server (NTRS)

Kifune, T.; Nishijima, K.; Hara, T.; Hatano, Y.; Hayashida, N.; Honda, M.; Kamata, K.; Matsubara, Y.; Mori, M.; Nagano, M.

1985-01-01

The experimental data of extensive air showers observed at Akeno have been analyzed to detect the gamma ray signal from Cyg X-3. After muon poor air showers are selected, the correlation of data acquisition time with 4.8 hours X-ray period is studied, giving the data concentration near the phase 0.6, the time of X-ray maximum. The probability that uniform backgrounds create the distribution is 0.2%. The time averaged integral gamma ray flux is estimated as (1.1 + or - 0.4)x 10 to the -14th power cm(-2) sec(-1) for Eo 10 to the 15th power eV and (8.8 + or - 5.0)x 10 to the 14th power cm(-2) sec(-1) for Eo 6 x 10 to the 14th power eV.

A comparison of coronal X-ray structures of active regions with magnetic fields computed from photospheric observations

NASA Technical Reports Server (NTRS)

Poletto, G.; Vaiana, G. S.; Zombeck, M. V.; Krieger, A. S.; Timothy, A. F.

1975-01-01

The appearances of several X-ray active regions observed on March 7, 1970 and June 15, 1973 are compared with the corresponding coronal magnetic-field topology. Coronal fields have been computed from measurements of the longitudinal component of the underlying magnetic fields, based on the current-free hypothesis. An overall correspondence between X-ray structures and calculated field lines is established, and the magnetic counterparts of different X-ray features are also examined. A correspondence between enhanced X-ray emission and the location of compact closed field lines is suggested. Representative magnetic-field values calculated under the assumption of current-free fields are given for heights up to 200 sec.

A long-term space astrophysics research program: An x-ray perspective of the components and structure of galaxies

NASA Technical Reports Server (NTRS)

Fabbiano, G.

1995-01-01

X-ray studies of galaxies by the Smithsonian Astrophysical Observatory (SAO) and MIT are described. Activities at SAO include ROSAT PSPC x-ray data reduction and analysis pipeline; x-ray sources in nearby Sc galaxies; optical, x-ray, and radio study of ongoing galactic merger; a radio, far infrared, optical, and x-ray study of the Sc galaxy NGC247; and a multiparametric analysis of the Einstein sample of early-type galaxies. Activities at MIT included continued analysis of observations with ROSAT and ASCA, and continued development of new approaches to spectral analysis with ASCA and AXAF. Also, a new method for characterizing structure in galactic clusters was developed and applied to ROSAT images of a large sample of clusters. An appendix contains preprints generated by the research.

Search for X rays from the planet Jupiter.

NASA Technical Reports Server (NTRS)

Hurley, K. C.

1972-01-01

Actively collimated balloon-borne scintillation counters employing a special phoswich anticoincidence technique were flown a total of 5 times from Palestine, Texas. Jupiter was observed for a total of 133 min, and an upper limit to the flux of X rays present at the observation time is .016 X rays/sq cm sec in the energy range 30-100 keV. Three separate calculations are made to estimate the flux of Jovian X rays at the earth. These estimates range from .000000001 to .1 X rays/sq cm sec in the energy range 30-100 keV. It is concluded that, since there was no decametric emission at the time of the flight and there had been no significant solar activity for several days prior to the flight, no X rays were being generated at the time of the observation.

The 2001 April Burst Activation of SGR 1900-14: Pulse Properties and Torque

NASA Technical Reports Server (NTRS)

Woods, P. M.; Kouveliotou, C.; Goegues, E.; Finger, M. H.; Feroci, M.; Mereghetti, S.; Swank, J. H.; Hurley, K.; Heise, J.; Smith D.

2003-01-01

We report on observations of SGR 1900+14 made with the Rossi X-Ray Timing Explorer (RXTE) and BeppoSAXduring the 2001 April burst activation of the source. Using these data, we measure the spin-down torque on the star and confirm earlier findings that the torque and burst activity are not directly correlated. We compare the X-ray pulse profile to the gamma-ray profile during the April 18 intermediate flare and show that (1) their shapes are similar and (1) the gamma-ray profile aligns closely in phase with the X-ray pulsations. The good phase alignment of the gamma-ray and X-ray profiles suggests that there was no rapid spin-down following this flare of the magnitude inferred for the August 27 giant flare. We discuss how these observations further constrain magnetic field reconfiguration models for the large flares of SGRs.

Taguchi's technique: an effective method for improving X-ray medical radiographic screen performance.

PubMed

Vlachogiannis, J G

2003-01-01

Taguchi's technique is a helpful tool to achieve experimental optimization of a large number of decision variables with a small number of off-line experiments. The technique appears to be an ideal tool for improving the performance of X-ray medical radiographic screens under a noise source. Currently there are very many guides available for improving the efficiency of X-ray medical radiographic screens. These guides can be refined using a second-stage parameter optimization. based on Taguchi's technique, selecting the optimum levels of controllable X-ray radiographic screen factors. A real example of the proposed technique is presented giving certain performance criteria. The present research proposes the reinforcement of X-ray radiography by Taguchi's technique as a novel hardware mechanism.

Detailed Calibration of SphinX instrument at the Palermo XACT facility of INAF-OAPA

NASA Astrophysics Data System (ADS)

Szymon, Gburek; Collura, Alfonso; Barbera, Marco; Reale, Fabio; Sylwester, Janusz; Kowalinski, Miroslaw; Bakala, Jaroslaw; Kordylewski, Zbigniew; Plocieniak, Stefan; Podgorski, Piotr; Trzebinski, Witold; Varisco, Salvatore

The Solar photometer in X-rays (SphinX) experiment is scheduled for launch late summer 2008 on-board the Russian CORONAS-Photon satellite. SphinX will use three silicon PIN diode detectors with selected effective areas in order to record solar spectra in the X-ray energy range 0.3-15 keV with unprecedented temporal and medium energy resolution. High sensitivity and large dynamic range of the SphinX instrument will give for the first time possibility of observing solar soft X-ray variability from the weakest levels, ten times below present thresholds, to the largest X20+ flares. We present the results of the ground X-ray calibrations of the SphinX instrument performed at the X-ray Astronomy Calibration and Testing (XACT) facility of INAF-OAPA. The calibrations were essential for determination of SphinX detector energy resolution and efficiency. We describe the ground tests instrumental set-up, adopted measurement techniques and present results of the calibration data analysis.

Joint reconstruction of x-ray fluorescence and transmission tomography

PubMed Central

Di, Zichao Wendy; Chen, Si; Hong, Young Pyo; Jacobsen, Chris; Leyffer, Sven; Wild, Stefan M.

2017-01-01

X-ray fluorescence tomography is based on the detection of fluorescence x-ray photons produced following x-ray absorption while a specimen is rotated; it provides information on the 3D distribution of selected elements within a sample. One limitation in the quality of sample recovery is the separation of elemental signals due to the finite energy resolution of the detector. Another limitation is the effect of self-absorption, which can lead to inaccurate results with dense samples. To recover a higher quality elemental map, we combine x-ray fluorescence detection with a second data modality: conventional x-ray transmission tomography using absorption. By using these combined signals in a nonlinear optimization-based approach, we demonstrate the benefit of our algorithm on real experimental data and obtain an improved quantitative reconstruction of the spatial distribution of dominant elements in the sample. Compared with single-modality inversion based on x-ray fluorescence alone, this joint inversion approach reduces ill-posedness and should result in improved elemental quantification and better correction of self-absorption. PMID:28788848

New consistency tests for high-accuracy measurements of X-ray mass attenuation coefficients by the X-ray extended-range technique.

PubMed

Chantler, C T; Islam, M T; Rae, N A; Tran, C Q; Glover, J L; Barnea, Z

2012-03-01

An extension of the X-ray extended-range technique is described for measuring X-ray mass attenuation coefficients by introducing absolute measurement of a number of foils - the multiple independent foil technique. Illustrating the technique with the results of measurements for gold in the 38-50 keV energy range, it is shown that its use enables selection of the most uniform and well defined of available foils, leading to more accurate measurements; it allows one to test the consistency of independently measured absolute values of the mass attenuation coefficient with those obtained by the thickness transfer method; and it tests the linearity of the response of the counter and counting chain throughout the range of X-ray intensities encountered in a given experiment. In light of the results for gold, the strategy to be ideally employed in measuring absolute X-ray mass attenuation coefficients, X-ray absorption fine structure and related quantities is discussed.

Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode

DOE PAGES

Alonso-Mori, Roberto; Kern, Jan; Gildea, Richard J.; ...

2012-11-05

The ultrabright femtosecond X-ray pulses provided by X-ray free-electron lasers open capabilities for studying the structure and dynamics of a wide variety of systems beyond what is possible with synchrotron sources. Recently, this “probe-before-destroy” approach has been demonstrated for atomic structure determination by serial X-ray diffraction of microcrystals. There has been the question whether a similar approach can be extended to probe the local electronic structure by X-ray spectroscopy. To address this, we have carried out femtosecond X-ray emission spectroscopy (XES) at the Linac Coherent Light Source using redox-active Mn complexes. XES probes the charge and spin states as wellmore » as the ligand environment, critical for understanding the functional role of redox-active metal sites. Kβ 1,3 XES spectra of Mn II and Mn 2 III,IV complexes at room temperature were collected using a wavelength dispersive spectrometer and femtosecond X-ray pulses with an individual dose of up to >100 MGy. The spectra were found in agreement with undamaged spectra collected at low dose using synchrotron radiation. Our results demonstrate that the intact electronic structure of redox active transition metal compounds in different oxidation states can be characterized with this shot-by-shot method. This opens the door for studying the chemical dynamics of metal catalytic sites by following reactions under functional conditions. Furthermore, the technique can be combined with X-ray diffraction to simultaneously obtain the geometric structure of the overall protein and the local chemistry of active metal sites and is expected to prove valuable for understanding the mechanism of important metalloproteins, such as photosystem II.« less

Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode

PubMed Central

Alonso-Mori, Roberto; Kern, Jan; Gildea, Richard J.; Sokaras, Dimosthenis; Weng, Tsu-Chien; Lassalle-Kaiser, Benedikt; Tran, Rosalie; Hattne, Johan; Laksmono, Hartawan; Hellmich, Julia; Glöckner, Carina; Echols, Nathaniel; Sierra, Raymond G.; Schafer, Donald W.; Sellberg, Jonas; Kenney, Christopher; Herbst, Ryan; Pines, Jack; Hart, Philip; Herrmann, Sven; Grosse-Kunstleve, Ralf W.; Latimer, Matthew J.; Fry, Alan R.; Messerschmidt, Marc M.; Miahnahri, Alan; Seibert, M. Marvin; Zwart, Petrus H.; White, William E.; Adams, Paul D.; Bogan, Michael J.; Boutet, Sébastien; Williams, Garth J.; Zouni, Athina; Messinger, Johannes; Glatzel, Pieter; Sauter, Nicholas K.; Yachandra, Vittal K.; Yano, Junko; Bergmann, Uwe

2012-01-01

The ultrabright femtosecond X-ray pulses provided by X-ray free-electron lasers open capabilities for studying the structure and dynamics of a wide variety of systems beyond what is possible with synchrotron sources. Recently, this “probe-before-destroy” approach has been demonstrated for atomic structure determination by serial X-ray diffraction of microcrystals. There has been the question whether a similar approach can be extended to probe the local electronic structure by X-ray spectroscopy. To address this, we have carried out femtosecond X-ray emission spectroscopy (XES) at the Linac Coherent Light Source using redox-active Mn complexes. XES probes the charge and spin states as well as the ligand environment, critical for understanding the functional role of redox-active metal sites. Kβ1,3 XES spectra of MnII and Mn2III,IV complexes at room temperature were collected using a wavelength dispersive spectrometer and femtosecond X-ray pulses with an individual dose of up to >100 MGy. The spectra were found in agreement with undamaged spectra collected at low dose using synchrotron radiation. Our results demonstrate that the intact electronic structure of redox active transition metal compounds in different oxidation states can be characterized with this shot-by-shot method. This opens the door for studying the chemical dynamics of metal catalytic sites by following reactions under functional conditions. The technique can be combined with X-ray diffraction to simultaneously obtain the geometric structure of the overall protein and the local chemistry of active metal sites and is expected to prove valuable for understanding the mechanism of important metalloproteins, such as photosystem II. PMID:23129631

BLACK HOLE MASS AND EDDINGTON RATIO DISTRIBUTION FUNCTIONS OF X-RAY-SELECTED BROAD-LINE AGNs AT z {approx} 1.4 IN THE SUBARU XMM-NEWTON DEEP FIELD

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nobuta, K.; Akiyama, M.; Ueda, Y.

2012-12-20

In order to investigate the growth of supermassive black holes (SMBHs), we construct the black hole mass function (BHMF) and Eddington ratio distribution function (ERDF) of X-ray-selected broad-line active galactic nuclei (AGNs) at z {approx} 1.4 in the Subaru XMM-Newton Deep Survey (SXDS) field. A significant part of the accretion growth of SMBHs is thought to take place in this redshift range. Black hole masses of X-ray-selected broad-line AGNs are estimated using the width of the broad Mg II line and 3000 A monochromatic luminosity. We supplement the Mg II FWHM values with the H{alpha} FWHM obtained from our NIRmore » spectroscopic survey. Using the black hole masses of broad-line AGNs at redshifts between 1.18 and 1.68, the binned broad-line AGN BHMFs and ERDFs are calculated using the V{sub max} method. To properly account for selection effects that impact the binned estimates, we derive the corrected broad-line AGN BHMFs and ERDFs by applying the maximum likelihood method, assuming that the ERDF is constant regardless of the black hole mass. We do not correct for the non-negligible uncertainties in virial BH mass estimates. If we compare the corrected broad-line AGN BHMF with that in the local universe, then the corrected BHMF at z = 1.4 has a higher number density above 10{sup 8} M{sub Sun} but a lower number density below that mass range. The evolution may be indicative of a downsizing trend of accretion activity among the SMBH population. The evolution of broad-line AGN ERDFs from z = 1.4 to 0 indicates that the fraction of broad-line AGNs with accretion rates close to the Eddington limit is higher at higher redshifts.« less

Synthesis, characterization, X-ray crystal structures of heterocyclic Schiff base compounds and in vitro cholinesterase inhibition and anticancer activity

NASA Astrophysics Data System (ADS)

Arafath, Md. Azharul; Adam, Farook; Al-Suede, Fouad Saleih R.; Razali, Mohd R.; Ahamed, Mohamed B. Khadeer; Abdul Majid, Amin Malik Shah; Hassan, Mohd Zaheen; Osman, Hasnah; Abubakar, Saifullah

2017-12-01

Four heterocyclic embedded Schiff base derivatives (1-4) were synthesized and characterized by melting point, elemental analysis, FTIR, 1H, 13C NMR, UV-Visible spectral data. The structures of compounds 1, 2 and 4 were successfully established through single crystal X-ray diffraction analysis. In vitro cholinesterase inhibition assays showed that the cyclized derivative 1 displayed higher BuChE enzyme inhibitory activity with IC50 value of 1.45 ± 0.09 μM. The anti-proliferative efficacies of the compounds were also evaluated using human colorectal HCT 116 and breast MCF-7 adenocarcinoma cell lines. In addition, a human normal endothelial cell line (Ea.hy926) was also tested to assess the safety and selectivity of the compounds towards normal and cancer cells, respectively. Among the compounds tested, compound 2 displayed potent cytotoxic effect (IC50 = 34 μM) against HCT 116 cells with highest selectivity index of 3.1 with respect to the normal endothelial cells. Whereas, compound 4 exhibited significant anti-proliferative effect (IC50 = 21.1 μM) against MCF-7 cells with highest selectivity index of 3.3 with respect to the normal endothelial cells. The docking result of these compounds against hAChE showed potent activities with different binding modes. These compounds could be a promising pharmacological agent to treat cancer and Alzheimer's disease.

Discovery of the X-ray selected galaxy cluster XMMU J0338.8+0021 at z = 1.49. Indications of a young system with a brightest galaxy in formation

NASA Astrophysics Data System (ADS)

Nastasi, A.; Fassbender, R.; Böhringer, H.; Šuhada, R.; Rosati, P.; Pierini, D.; Verdugo, M.; Santos, J. S.; Schwope, A. D.; de Hoon, A.; Kohnert, J.; Lamer, G.; Mühlegger, M.; Quintana, H.

2011-08-01

We report the discovery of a galaxy cluster at z = 1.490 originally selected as an extended X-ray source in the XMM-Newton Distant Cluster Project. Further observations carried out with the VLT-FORS2 spectrograph allowed the spectroscopic confirmation of seven secure cluster members, providing a median system redshift of z = 1.490 ± 0.009. The color-magnitude diagram of XMMU J0338.8+0021 reveals the presence of a well-populated red sequence with z - H ≈ 3, albeit with an apparent significant scatter in color. Since we do not detect indications of any strong star formation activity in these objects, the color spread could represent the different stellar ages of the member galaxies. In addition, we found the brightest cluster galaxy in a very active dynamical state, with an interacting, merging companion located at a physical projected distance of d ≈ 20 kpc. From the X-ray luminosity, we estimate a cluster mass of M200 ~ 1.2 × 1014 M⊙. The data appear to be consistent with a scenario in which XMMU J0338.8+0021 is a young system, possibly caught in a moment of active ongoing mass assembly. Based on observations under programme ID 084.A-0844 collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile, and observations collected at the Centro Astronómico Hispano Alemán at Calar Alto, operated jointly by the Max-Planck Institut für Astronomie and the Instituto de Astrofísica de Andalucía (CSIC).Tables 1, 2 and Figs. 3-6 are available in electronic form at http://www.aanda.org

Advances in X-ray optics: From metrology characterization to wavefront sensing-based optimization of active optics

DOE PAGES

Cocco, Daniele; Idir, Mourad; Morton, Daniel; ...

2018-03-20

Experiments using high brightness X-rays are on the forefront of science due to the vast variety of knowledge they can provide. New Synchrotron Radiation (SR) and Free Electron Laser (FEL) light sources provide unique tools for advanced studies using X-rays. Top-level scientists from around the world are attracted to these beamlines to perform unprecedented experiments. High brightness, low emittance light sources allow beamline scientists the possibility to dream up cutting-edge experimental stations. X-ray optics play a key role in bringing the beam from the source to the experimental stations. This paper explores the recent developments in X-ray optics. It touchesmore » on simulations, diagnostics, metrology and adaptive optics, giving an overview of the role X-ray optics have played in the recent past. It will also touch on future developments for one of the most active field in the X-ray science.« less

Advances in X-ray optics: From metrology characterization to wavefront sensing-based optimization of active optics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cocco, Daniele; Idir, Mourad; Morton, Daniel

Experiments using high brightness X-rays are on the forefront of science due to the vast variety of knowledge they can provide. New Synchrotron Radiation (SR) and Free Electron Laser (FEL) light sources provide unique tools for advanced studies using X-rays. Top-level scientists from around the world are attracted to these beamlines to perform unprecedented experiments. High brightness, low emittance light sources allow beamline scientists the possibility to dream up cutting-edge experimental stations. X-ray optics play a key role in bringing the beam from the source to the experimental stations. This paper explores the recent developments in X-ray optics. It touchesmore » on simulations, diagnostics, metrology and adaptive optics, giving an overview of the role X-ray optics have played in the recent past. It will also touch on future developments for one of the most active field in the X-ray science.« less

Compton thick active galactic nuclei in Chandra surveys

NASA Astrophysics Data System (ADS)

Brightman, Murray; Nandra, Kirpal; Salvato, Mara; Hsu, Li-Ting; Aird, James; Rangel, Cyprian

2014-09-01

We present the results from an X-ray spectral analysis of active galactic nuclei (AGN) in the ChandraDeep Field-South, All-wavelength Extended Groth-strip International Survey (AEGIS)-Deep X-ray survey (XD) and Chandra-Cosmic Evolution Surveys (COSMOS), focusing on the identification and characterization of the most heavily obscured, Compton thick (CT, NH > 1024 cm-2) sources. Our sample is comprised of 3184 X-ray selected extragalactic sources, which has a high rate of redshift completeness (96.6 per cent), and includes additional spectroscopic redshifts and improved photometric redshifts over previous studies. We use spectral models designed for heavily obscured AGN which self-consistently include all major spectral signatures of heavy absorption. We validate our spectral fitting method through simulations, identify CT sources not selected through this method using X-ray colours and take considerations for the constraints on NH given the low count nature of many of our sources. After these considerations, we identify a total of 100 CT AGN with best-fitting NH > 1024 cm-2 and NH constrained to be above 1023.5 cm-2 at 90 per cent confidence. These sources cover an intrinsic 2-10 keV X-ray luminosity range of 1042-3 × 1045 erg s-1 and a redshift range of z = 0.1-4. This sample will enable characterization of these heavily obscured AGN across cosmic time and to ascertain their cosmological significance. These survey fields are sites of extensive multiwavelength coverage, including near-infrared Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey (CANDELS) data and far-infrared Herschel data, enabling forthcoming investigations into the host properties of CT AGN. Furthermore, by using the torus models to test different covering factor scenarios, and by investigating the inclusion of the soft scattered emission, we find evidence that the covering factor of the obscuring material decreases with LX for all redshifts, consistent with the receding torus model, and that this factor increases with redshift, consistent with an increase in the obscured fraction towards higher redshifts. The strong relationship between the parameters of obscuration and LX points towards an origin intrinsic to the AGN; however, the increase of the covering factor with redshift may point towards contributions to the obscuration by the host galaxy. We make NH, Γ (with uncertainties), observed X-ray fluxes and intrinsic 2-10 keV luminosities for all sources analysed in this work publicly available in an online catalogue.

Internal absorption of gamma-rays in relativistic blobs of active galactic nuclei

NASA Astrophysics Data System (ADS)

Sitarek, Julian; Bednarek, Wlodek

2007-06-01

We investigate the production of gamma-rays in the inverse Compton (IC) scattering process by leptons accelerated inside relativistic blobs in jets of active galactic nuclei. Leptons are injected homogeneously inside the spherical blob and initiate IC e ± pair cascade in the synchrotron radiation (produced by the same population of leptons, SSC model), provided that the optical depth for gamma-rays is larger than unity. It is shown that for likely parameters internal absorption of gamma-rays has to be important. We suggest that new type of blazars might be discovered by the future simultaneous X-ray and γ-ray observations, showing peak emissions in the hard X-rays, and in the GeV γ-rays. Moreover, the considered scenario might be also responsible for the orphan X-ray flares recently reported from BL Lac type active galaxies.

Multilayer X-ray imaging systems

NASA Astrophysics Data System (ADS)

Shealy, D. L.; Hoover, R. B.; Gabardi, D. R.

1986-01-01

An assessment of the imaging properties of multilayer X-ray imaging systems with spherical surfaces has been made. A ray trace analysis was performed to investigate the effects of using spherical substrates (rather than the conventional paraboloidal/hyperboloidal contours) for doubly reflecting Cassegrain telescopes. These investigations were carried out for mirrors designed to operate at selected soft X-ray/XUV wavelengths that are of significance for studies of the solar corona/transition region from the Stanford/MSFC Rocket X-Ray Telescope. The effects of changes in separation of the primary and secondary elements were also investigated. These theoretical results are presented as well as the results of ray trace studies to establish the resolution and vignetting effects as a function of field angle and system parameters.

NuSTAR Reveals Extreme Absorption in z < 0.5 Type 2 Quasars

NASA Astrophysics Data System (ADS)

Lansbury, G. B.; Gandhi, P.; Alexander, D. M.; Assef, R. J.; Aird, J.; Annuar, A.; Ballantyne, D. R.; Baloković, M.; Bauer, F. E.; Boggs, S. E.; Brandt, W. N.; Brightman, M.; Christensen, F. E.; Civano, F.; Comastri, A.; Craig, W. W.; Del Moro, A.; Grefenstette, B. W.; Hailey, C. J.; Harrison, F. A.; Hickox, R. C.; Koss, M.; LaMassa, S. M.; Luo, B.; Puccetti, S.; Stern, D.; Treister, E.; Vignali, C.; Zappacosta, L.; Zhang, W. W.

2015-08-01

The intrinsic column density (NH) distribution of quasars is poorly known. At the high obscuration end of the quasar population and for redshifts z < 1, the X-ray spectra can only be reliably characterized using broad-band measurements that extend to energies above 10 keV. Using the hard X-ray observatory NuSTAR, along with archival Chandra and XMM-Newton data, we study the broad-band X-ray spectra of nine optically selected (from the SDSS), candidate Compton-thick (NH > 1.5 × 1024 cm-2) type 2 quasars (CTQSO2s); five new NuSTAR observations are reported herein, and four have been previously published. The candidate CTQSO2s lie at z < 0.5, have observed [O iii] luminosities in the range 8.4\\lt {log}({L}[{{O} {{III}}]}/{L}⊙ )\\lt 9.6, and show evidence for extreme, Compton-thick absorption when indirect absorption diagnostics are considered. Among the nine candidate CTQSO2s, five are detected by NuSTAR in the high-energy (8-24 keV) band: two are weakly detected at the ≈3σ confidence level and three are strongly detected with sufficient counts for spectral modeling (≳90 net source counts at 8-24 keV). For these NuSTAR-detected sources direct (i.e., X-ray spectral) constraints on the intrinsic active galactic nucleus properties are feasible, and we measure column densities ≈2.5-1600 times higher and intrinsic (unabsorbed) X-ray luminosities ≈10-70 times higher than pre-NuSTAR constraints from Chandra and XMM-Newton. Assuming the NuSTAR-detected type 2 quasars are representative of other Compton-thick candidates, we make a correction to the NH distribution for optically selected type 2 quasars as measured by Chandra and XMM-Newton for 39 objects. With this approach, we predict a Compton-thick fraction of {f}{CT}={36}-12+14 %, although higher fractions (up to 76%) are possible if indirect absorption diagnostics are assumed to be reliable.

An Archival Chandra and XMM-Newton Survey of Type 2 Quasars

NASA Technical Reports Server (NTRS)

Jia, Jianjun; Ptak, Andrew Francis; Heckman, Timothy; Zakamska, Nadia L.

2013-01-01

In order to investigate obscuration in high-luminosity type 2 active galactic nuclei (AGNs), we analyzed Chandra and XMM-Newton archival observations for 71 type 2 quasars detected at 0.05 < z < 0.73, which were selected based on their [O III] lambda5007 emission lines. For 54 objects with good spectral fits, the observed hard X-ray luminosity ranges from 2 × 10(exp 41) to 5.3 × 10(exp 44) erg s(exp -1), with a median of 1.1 × 10(exp 43) erg s(exp -1). We find that the means of the column density and photon index of our sample are log N(sub H) = 22.9 cm(exp -2) and gamma = 1.87, respectively. From simulations using a more physically realistic model, we find that the absorbing column density estimates based on simple power-law models significantly underestimate the actual absorption in approximately half of the sources. Eleven sources show a prominent Fe K alpha emission line (EW>100 eV in the rest frame) and we detect this line in the other sources through a joint fit (spectral stacking). The correlation between the Fe K alpha and [O III] fluxes and the inverse correlation of the equivalent width of the Fe Ka line with the ratio of hard X-ray and [O III] fluxes is consistent with previous results for lower luminosity Seyfert 2 galaxies. We conclude that obscuration is the cause of the weak hard X-ray emission rather than intrinsically low X-ray luminosities. We find that about half of the population of optically selected type 2 quasars are likely to be Compton thick. We also find no evidence that the amount of X-ray obscuration depends on the AGN luminosity (over a range of more than three orders of magnitude in luminosity).

Does the obscured AGN fraction really depend on luminosity?

NASA Astrophysics Data System (ADS)

Sazonov, S.; Churazov, E.; Krivonos, R.

2015-12-01

We use a sample of 151 local non-blazar active galactic nuclei (AGN) selected from the INTEGRAL all-sky hard X-ray survey to investigate if the observed declining trend of the fraction of obscured (i.e. showing X-ray absorption) AGN with increasing luminosity is mostly an intrinsic or selection effect. Using a torus-obscuration model, we demonstrate that in addition to negative bias, due to absorption in the torus, in finding obscured AGN in hard X-ray flux-limited surveys, there is also positive bias in finding unobscured AGN, due to Compton reflection in the torus. These biases can be even stronger taking into account plausible intrinsic collimation of hard X-ray emission along the axis of the obscuring torus. Given the AGN luminosity function, which steepens at high luminosities, these observational biases lead to a decreasing observed fraction of obscured AGN with increasing luminosity even if this fraction has no intrinsic luminosity dependence. We find that if the central hard X-ray source in AGN is isotropic, the intrinsic (i.e. corrected for biases) obscured AGN fraction still shows a declining trend with luminosity, although the intrinsic obscured fraction is significantly larger than the observed one: the actual fraction is larger than ˜85 per cent at L ≲ 1042.5 erg s-1 (17-60 keV), and decreases to ≲60 per cent at L ≳ 1044 erg s-1. In terms of the half-opening angle θ of an obscuring torus, this implies that θ ≲ 30° in lower luminosity AGN, and θ ≳ 45° in higher luminosity ones. If, however, the emission from the central supermassive black hole is collimated as dL/dΩ ∝ cos α, the intrinsic dependence of the obscured AGN fraction is consistent with a luminosity-independent torus half-opening angle θ ˜ 30°.

The ΓX-L/LEdd relation in BAT AGN Spectroscopic Survey (BASS)

NASA Astrophysics Data System (ADS)

Trakhtenbrot, Benny; Ricci, Claudio; Koss, Michael; Schawinski, Kevin; Mushotzky, Richard; Ueda, Yoshihiro; Veilleux, Sylvain; Lamperti, Isabella; Oh, Kyuseok; Treister, Ezequiel; Stern, Daniel; Harrison, Fiona; Balokovic, Mislav

2018-01-01

We present a study of the relation between accretion rate (in terms of L/LEdd) and shape of the hard X-ray spectral energy distribution (namely the photon index Γx) for a large sample of over 200 hard X-ray-selected, low-redshift active galactic nuclei (AGNs), drawn from the Swift/BAT AGN Spectroscopic Survey (BASS). This includes 30 AGNs for which black hole mass (and therefore L/LEdd) is measured directly through masers, spatially resolved gas or stellar dynamics, or reverberation mapping. The high-quality and broad energy coverage of the data provided through BASS allow us to examine several alternative determinations of both Γx and L/LEdd. We find very weak correlation between Γx and L/LEdd for the BASS sample as a whole, with best-fitting relations that are considerably shallower than those reported in previous studies. Moreover, we find no corresponding correlations among the subsets of AGN with different MBH determination methodology, and in particular those AGN with direct or single-epoch MBH estimates. This latter finding is in contrast to several previous studies which focused on z > 0.5 broad-line AGN. We conclude that this tension can be partially accounted for if one adopts a simplified, power-law X-ray spectral model, combined with L/LEdd estimates that are based on the continuum emission and on single-epoch broad-line spectroscopy in the optical regime. Given these findings, we highlight the limitations of using Γx as a probe of supermassive black hole evolution in deep extragalactic X-ray surveys.

The x ray properties of a large, uniform QSO sample: Einstein observations of the LBQS

NASA Technical Reports Server (NTRS)

Margon, B.; Anderson, S. F.; Xu, X.; Green, P. J.; Foltz, C. B.

1992-01-01

Although there are large numbers of Quasi Stellar Objects (QSO's) now observed in X rays, extensive X-ray observations of uniformly selected, 'complete' QSO samples are more rare. The Large Bright QSO Survey (LBQS) consists of about 1000 objects with well understood properties, most brighter than B = 18.8 and thus amenable to X-ray detections in relatively brief exposures. The sample is thought to be highly complete in the range 0.2 less than z less than 3.3, a significantly broader interval than many other surveys. The Einstein IPC observed 150 of these objects, mostly serendipitously, during its lifetime. We report the results of an analysis of these IPC data, considering not only the 20 percent of the objects we find to have positive X-ray detections, but also the ensemble X-ray properties derived by 'image stacking'.

X-ray modeling for SMILE

NASA Astrophysics Data System (ADS)

Sun, T.; Wang, C.; Wei, F.; Liu, Z. Q.; Zheng, J.; Yu, X. Z.; Sembay, S.; Branduardi-Raymont, G.

2016-12-01

SMILE (Solar wind Magnetosphere Ionosphere Link Explorer) is a novel mission to explore the coupling of the solar wind-magnetosphere-ionosphere system via providing global images of the magnetosphere and aurora. As the X-ray imaging is a brand new technique applied to study the large scale magnetopause, modeling of the solar wind charge exchange (SWCX) X-ray emissions in the magnetosheath and cusps is vital in various aspects: it helps the design of the Soft X-ray Imager (SXI) on SMILE, selection of satellite orbits, as well as the analysis of expected scientific outcomes. Based on the PPMLR-MHD code, we present the simulation results of the X-ray emissions in geospace during storm time. Both the polar orbit and the Molniya orbit are used. From the X-ray images of the magnetosheath and cusps, the magnetospheric responses to an interplanetary shock and IMF southward turning are analyzed.

Time-dependent nonequilibrium soft x-ray response during a spin crossover

NASA Astrophysics Data System (ADS)

van Veenendaal, Michel

2018-03-01

A theoretical framework is developed for better understanding the time-dependent soft-x-ray response of dissipative quantum many-body systems. It is shown how x-ray absorption and resonant inelastic x-ray scattering (RIXS) at transition-metal L edges can provide insight into ultrafast intersystem crossings of importance for energy conversion, ultrafast magnetism, and catalysis. The photoinduced doublet-to-quartet spin crossover on cobalt in Fe-Co Prussian blue analogs is used as a model system to demonstrate how the x-ray response is affected by the nonequilibrium dynamics on a femtosecond time scale. Changes in local spin and symmetry and the underlying mechanism are reflected in strong broadenings, a collapse of clear selection rules during the intersystem crossing, fluctuations in the isotropic branching ratio in x-ray absorption, crystal-field collapse and/or oscillations, and time-dependent anti-Stokes processes in RIXS.

ROSAT - A German X-ray satellite searches for the big bang

NASA Astrophysics Data System (ADS)

The scientific aims, design, development history, launch, and initial performance of the NASA/FRG orbiting X-ray observatory Rosat are reviewed and illustrated with extensive drawings, diagrams, photographs, and sample images. The main Rosat instrument is a 120-cm-long 83-cm-aperture Wolter X-ray telescope with optical surfaces ground to achieve mean microroughness of less than 1 nm and image resolution 2.5 arcsec. The Rosat mission began with a Delta II launch on June 1, 1990; its first objective is an all-sky X-ray survey which should increase the number of known X-ray sources from about 5000 to over 100,000. The second phase involves detailed observations of selected objects, including nearby normal stars, SN clouds, binary systems, hot neutron stars, and extremely distant QSOs. The first images obtained by Rosat were of the Galactic SNR Cas A, revealing the structure of the shock front and a weak X-ray halo.

Skylab

NASA Image and Video Library

1973-01-01

This chart describes the Skylab student experiment X-Ray Stellar Classes, proposed by Joe Reihs of Baton Rouge, Louisiana. This experiment utilized Skylab's X-Ray Spectrographic Telescope to observe and determine the general characteristics and location of x-ray sources. In March 1972, NASA and the National Science Teachers Association selected 25 experiment proposals for flight on Skylab. Science advisors from the Marshall Space Flight Center aided and assisted the students in developing the proposals for flight on Skylab.

A review of recent work in sub-nanometre displacement measurement using optical and X-ray interferometry.

PubMed

Peggs, G N; Yacoot, A

2002-05-15

This paper reviews recent work in the field of displacement measurement using optical and X-ray interferometry at the sub-nanometre level of accuracy. The major sources of uncertainty in optical interferometry are discussed and a selection of recent designs of ultra-precise, optical-interferometer-based, displacement measuring transducers presented. The use of X-ray interferometry and its combination with optical interferometry is discussed.

Continuous Shape Estimation of Continuum Robots Using X-ray Images

PubMed Central

Lobaton, Edgar J.; Fu, Jinghua; Torres, Luis G.; Alterovitz, Ron

2015-01-01

We present a new method for continuously and accurately estimating the shape of a continuum robot during a medical procedure using a small number of X-ray projection images (e.g., radiographs or fluoroscopy images). Continuum robots have curvilinear structure, enabling them to maneuver through constrained spaces by bending around obstacles. Accurately estimating the robot’s shape continuously over time is crucial for the success of procedures that require avoidance of anatomical obstacles and sensitive tissues. Online shape estimation of a continuum robot is complicated by uncertainty in its kinematic model, movement of the robot during the procedure, noise in X-ray images, and the clinical need to minimize the number of X-ray images acquired. Our new method integrates kinematics models of the robot with data extracted from an optimally selected set of X-ray projection images. Our method represents the shape of the continuum robot over time as a deformable surface which can be described as a linear combination of time and space basis functions. We take advantage of probabilistic priors and numeric optimization to select optimal camera configurations, thus minimizing the expected shape estimation error. We evaluate our method using simulated concentric tube robot procedures and demonstrate that obtaining between 3 and 10 images from viewpoints selected by our method enables online shape estimation with errors significantly lower than using the kinematic model alone or using randomly spaced viewpoints. PMID:26279960

Continuous Shape Estimation of Continuum Robots Using X-ray Images.

PubMed

Lobaton, Edgar J; Fu, Jinghua; Torres, Luis G; Alterovitz, Ron

2013-05-06

We present a new method for continuously and accurately estimating the shape of a continuum robot during a medical procedure using a small number of X-ray projection images (e.g., radiographs or fluoroscopy images). Continuum robots have curvilinear structure, enabling them to maneuver through constrained spaces by bending around obstacles. Accurately estimating the robot's shape continuously over time is crucial for the success of procedures that require avoidance of anatomical obstacles and sensitive tissues. Online shape estimation of a continuum robot is complicated by uncertainty in its kinematic model, movement of the robot during the procedure, noise in X-ray images, and the clinical need to minimize the number of X-ray images acquired. Our new method integrates kinematics models of the robot with data extracted from an optimally selected set of X-ray projection images. Our method represents the shape of the continuum robot over time as a deformable surface which can be described as a linear combination of time and space basis functions. We take advantage of probabilistic priors and numeric optimization to select optimal camera configurations, thus minimizing the expected shape estimation error. We evaluate our method using simulated concentric tube robot procedures and demonstrate that obtaining between 3 and 10 images from viewpoints selected by our method enables online shape estimation with errors significantly lower than using the kinematic model alone or using randomly spaced viewpoints.

Optical spectroscopy of the Be/X-ray binary V850 Centauri/GX 304-1 during faint X-ray periodical activity

NASA Astrophysics Data System (ADS)

Malacaria, C.; Kollatschny, W.; Whelan, E.; Santangelo, A.; Klochkov, D.; McBride, V.; Ducci, L.

2017-07-01

Context. Be/X-ray binaries (BeXRBs) are the most populous class of high-mass X-ray binaries. Their X-ray duty cycle is tightly related to the optical companion wind activity, which in turn can be studied through dedicated optical spectroscopic observations. Aims: We study optical spectral features of the Be circumstellar disk to test their long-term variability and their relation with the X-ray activity. Special attention has been given to the Hα emission line, one of the best tracers of the disk conditions. Methods: We obtained optical broadband medium resolution spectra from a dedicated campaign with the Anglo-Australian Telescope and the Southern African Large Telescope in 2014-2015. Data span over one entire binary orbit, and cover both X-ray quiescent and moderately active periods. We used Balmer emission lines to follow the evolution of the circumstellar disk. Results: We observe prominent spectral features, like double-peaked Hα and Hβ emission lines. The HαV/R ratio significantly changes over a timescale of about one year. Our observations are consistent with a system observed at a large inclination angle (I ≳ 60°). The derived circumstellar disk size shows that the disk evolves from a configuration that prevents accretion onto the neutron star, to one that allows only moderate accretion. This is in agreement with the contemporary observed X-ray activity. Our results are interpreted within the context of inefficient tidal truncation of the circumstellar disk, as expected for this source's binary configuration. We derived the Hβ-emitting region size, which is equal to about half of the corresponding Hα-emitting disk, and constrain the luminosity class of V850 Cen as III-V, consistent with the previously proposed class.

X-ray structures define human P2X3 receptor gating cycle and antagonist action

PubMed Central

Mansoor, Steven E.; Lü, Wei; Oosterheert, Wout; Shekhar, Mrinal; Tajkhorshid, Emad; Gouaux, Eric

2016-01-01

Summary P2X receptors are trimeric, non-selective cation channels activated by ATP that play important roles in cardiovascular, neuronal and immune systems. Despite their central function in human physiology and as potential targets of therapeutic agents, there are no structures of human P2X receptors. Mechanisms of receptor desensitization and ion permeation, principles of antagonism, and complete structure of the pore-forming transmembrane domains remain unclear. We report x-ray crystal structures of human P2X3 receptor in apo/resting, agonist-bound/open-pore, agonist-bound/desensitized and antagonist-bound closed states. The open state structure harbors an intracellular motif we term the “cytoplasmic cap”, that stabilizes the open state of the ion channel pore and creates lateral, phospholipid-lined cytoplasmic fenestrations for water and ion egress. Competitive antagonists TNP-ATP and A-317491 stabilize the apo/resting state and reveal the interactions responsible for competitive inhibition. These structures illuminate the conformational rearrangements underpinning P2X receptor gating and provide a foundation for development of new pharmacologic agents. PMID:27626375

Mutagenic interactions between X-rays and two promutagens, o-phenylenediamine and N-nitrosodimethylamine, in the stamen hairs of Tradescantia clone BNL 4430.

PubMed

Xiao, L Z; Ichikawa, S

1998-03-16

Mutagenic interactions between X-rays and two promutagens, o-phenylenediamine (PDA) and N-nitrosodimethylamine (DMN), were studied in the stamen hairs of Tradescantia clone BNL 4430, a blue/pink heterozygote. The young inflorescence-bearing shoots with roots of this clone cultivated in a nutrient solution circulating growth chamber were used as tester plants. After determining dose-response curves for X-rays. PDA and DMN, combined treatments with PDA or DMN and X-rays were conducted, exposing acutely to X-rays 20 h before starting, at the midpoint of, or 20 h after completing the PDA or DMN treatments for 4 h. Clear synergistic effects in inducing somatic pink mutations were detected when X-rays were irradiated before the PDA or DMN treatments, resembling those confirmed earlier between maleic hydrazide (MH) and X-rays. On the contrary, clear antagonistic effects were observed when X-rays were given after the PDA or DMN treatments, also resembling those between MH and X-rays. When X-rayed at the midpoint of the PDA or DMN treatments, merely additive and synergistic effects were observed, respectively, differing from the antagonistic effects between MH and X-rays. The mutagenic synergisms detected were considered to be the results of interactions between DNA strand breaks (and the resultant chromosome breaks) induced by X-rays and those by PDA or DMN, whereas the mutagenic antagonisms observed were presumed to be due to X-ray-caused inhibition of the activation of PDA and DMN in the stamen-hair cells. The time periods required for penetrations into floral tissues and/or activations into mutagens seem different among PDA, DMN and MH. Copyright 1998 Elsevier Science B.V.

Shedding a New Light on the Universe: An Information and Activity Booklet. Grades 9-12.

ERIC Educational Resources Information Center

Masetti, Maggie

This activity booklet is divided into two parts. Part One presents basic information about the electromagnetic spectrum and multiwavelength astronomy with an emphasis on X-ray astronomy. Part Two describes X-ray detectors at a more advanced level. An introduction to the Rossi X-ray Timing Explorer (RXTE) and its contributions to science is…

Towards protein-crystal centering using second-harmonic generation (SHG) microscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kissick, David J.; Dettmar, Christopher M.; Becker, Michael

2013-05-01

The potential of second-harmonic generation (SHG) microscopy for automated crystal centering to guide synchrotron X-ray diffraction of protein crystals has been explored. The potential of second-harmonic generation (SHG) microscopy for automated crystal centering to guide synchrotron X-ray diffraction of protein crystals was explored. These studies included (i) comparison of microcrystal positions in cryoloops as determined by SHG imaging and by X-ray diffraction rastering and (ii) X-ray structure determinations of selected proteins to investigate the potential for laser-induced damage from SHG imaging. In studies using β{sub 2} adrenergic receptor membrane-protein crystals prepared in lipidic mesophase, the crystal locations identified by SHGmore » images obtained in transmission mode were found to correlate well with the crystal locations identified by raster scanning using an X-ray minibeam. SHG imaging was found to provide about 2 µm spatial resolution and shorter image-acquisition times. The general insensitivity of SHG images to optical scatter enabled the reliable identification of microcrystals within opaque cryocooled lipidic mesophases that were not identified by conventional bright-field imaging. The potential impact of extended exposure of protein crystals to five times a typical imaging dose from an ultrafast laser source was also assessed. Measurements of myoglobin and thaumatin crystals resulted in no statistically significant differences between structures obtained from diffraction data acquired from exposed and unexposed regions of single crystals. Practical constraints for integrating SHG imaging into an active beamline for routine automated crystal centering are discussed.« less

A compact and high efficiency GAGG well counter for radiocesium concentration measurements

NASA Astrophysics Data System (ADS)

Yamamoto, Seiichi; Ogata, Yoshimune

2014-07-01

After the Fukushima nuclear disaster, social concern about radiocesium (137Cs and 134Cs) contamination in food increased. However, highly efficient instruments that can measure low level radioactivity are quite expensive and heavy. A compact, lightweight, and reliable radiation detector that can inexpensively monitor low level radiocesium is highly desired. We developed a compact and highly efficient radiocesium detector to detect ~32 keV X-rays from radiocesium instead of high energy gamma photons. A 1-mm thick GAGG scintillator was selected to effectively detect ~32 keV X-rays from 137Cs to reduce the influence of ambient radiation. Four sets of 25 mm×25 mm×1 mm GAGG plates, each of which was optically coupled to a triangular-shaped light guide, were optically coupled to a photomultiplier tube (PMT) to form a square-shaped well counter. Another GAGG plate was directly optically coupled to the PMT to form its bottom detector. The energy resolution of the GAGG well counter was 22.3% FWHM for 122 keV gamma rays and 32% FWHM for ~32 keV X-rays. The counting efficiency for the X-rays from radiocesium (mixture of 137Cs and 134Cs) was 4.5%. In measurements of the low level radiocesium mixture, a photo-peak of ~32 keV X-rays can clearly be distinguished from the background. The minimum detectable activity (MDA) was estimated to be ~100 Bq/kg for 1000 s measurement. The results show that our developed GAGG well counter is promising for the detection of radiocesium in food.

FRESH ACTIVITY IN OLD SYSTEMS: RADIO AGNs IN FOSSIL GROUPS OF GALAXIES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hess, Kelley M.; Wilcots, Eric M.; Hartwick, Victoria L., E-mail: hess@ast.uct.ac.za, E-mail: ewilcots@astro.wisc.edu, E-mail: vhartwick@wisc.edu

2012-08-15

We present the first systematic 1.4 GHz Very Large Array radio continuum survey of fossil galaxy group candidates. These are virialized systems believed to have assembled over a gigayear in the past through the merging of galaxy group members into a single, isolated, massive elliptical galaxy and featuring an extended hot X-ray halo. We use new photometric and spectroscopic data from Sloan Digital Sky Survey Data Release 7 to determine that three of the candidates are clearly not fossil groups. Of the remaining 30 candidates, 67% contain a radio-loud (L{sub 1.4GHz} > 10{sup 23} W Hz{sup -1}) active galactic nucleusmore » (AGN) at the center of their dominant elliptical galaxy. We find a weak correlation between the radio luminosity of the AGN and the X-ray luminosity of the halo suggesting that the AGN contributes to energy deposition into the intragroup medium. We only find a correlation between the radio and optical luminosity of the central elliptical galaxy when we include X-ray-selected, elliptically dominated non-fossil groups, indicating a weak relationship between AGN strength and the mass assembly history of the groups. The dominant elliptical galaxy of fossil groups is on average roughly an order of magnitude more luminous than normal group elliptical galaxies in optical, X-ray, and radio luminosities and our findings are consistent with previous results that the radio-loud fraction in elliptical galaxies is linked to the stellar mass of a population. The current level of activity in fossil groups suggests that AGN fueling continues long after the last major merger. We discuss several possibilities for fueling the AGN at the present epoch.« less

The SWIFT AGN and Cluster Survey. I. Number Counts of AGNs and Galaxy Clusters

NASA Astrophysics Data System (ADS)

Dai, Xinyu; Griffin, Rhiannon D.; Kochanek, Christopher S.; Nugent, Jenna M.; Bregman, Joel N.

2015-05-01

The Swift active galactic nucleus (AGN) and Cluster Survey (SACS) uses 125 deg2 of Swift X-ray Telescope serendipitous fields with variable depths surrounding γ-ray bursts to provide a medium depth (4× {{10}-15} erg cm-2 s-1) and area survey filling the gap between deep, narrow Chandra/XMM-Newton surveys and wide, shallow ROSAT surveys. Here, we present a catalog of 22,563 point sources and 442 extended sources and examine the number counts of the AGN and galaxy cluster populations. SACS provides excellent constraints on the AGN number counts at the bright end with negligible uncertainties due to cosmic variance, and these constraints are consistent with previous measurements. We use Wide-field Infrared Survey Explorer mid-infrared (MIR) colors to classify the sources. For AGNs we can roughly separate the point sources into MIR-red and MIR-blue AGNs, finding roughly equal numbers of each type in the soft X-ray band (0.5-2 keV), but fewer MIR-blue sources in the hard X-ray band (2-8 keV). The cluster number counts, with 5% uncertainties from cosmic variance, are also consistent with previous surveys but span a much larger continuous flux range. Deep optical or IR follow-up observations of this cluster sample will significantly increase the number of higher-redshift (z\\gt 0.5) X-ray-selected clusters.

Electrochemical characterization of nano-sized Pd-based catalysts as cathode materials in direct methanol fuel cells.

PubMed

Choi, M; Han, C; Kim, I T; An, J C; Lee, J J; Lee, H K; Shim, J

2011-01-01

To improve the catalytic activity of palladium (Pd) as a cathode catalyst in direct methanol fuel cells (DMFCs), we prepared palladium-titanium oxide (Pd-TiO2) catalysts which the Pd and TiO2 nanoparticles were simultaneously impregnated on carbon. We selected Pd and TiO2 as catalytic materials because of their electrochemical stability in acid solution. The crystal structure and the loading amount of Pd and TiO2 on carbon were characterized by X-ray diffraction (XRD) and energy dispersive X-ray microanalysis (EDX). The electrochemical characterization of Pd-TiO2/C catalysts for the oxygen reduction reaction was carried out in half and single cell systems. The catalytic activities of the Pd-TiO2 catalysts were strongly influenced by the TiO2 content. In the single cell test, the Pd-TiO2 catalysts showed very comparable performance to the Pt catalyst.

Coronal Activity in Low-Mass Pre-Main Sequence Stars: NGC 2264

NASA Technical Reports Server (NTRS)

Tebbe, H. J.; Patten, B. M.

2000-01-01

We present the preliminary results of an analysis of ROSAT images in the region of the populous young (age approx. 3 Myr) star-forming region NGC 2264. The cluster was imaged with the ROSAT HRI in two sets of pointings -- one set near the central region of the cluster, centered on the star LW Mon, and the other set in the southern part of the cluster, centered near the star V428 Mon, just south of the Cone Nebula. In total 113 unique X-ray sources have been identified in the ROSAT images with signal-to-noise ratios greater than 3. The limiting luminosities (log Lx(ergs/sec)) for 3-sigma detections are estimated to be 30.18, 30.23, and 30.08 for the northern field, southern field, and overlap region between the two fields respectively. Extensive optical photometry, classification spectroscopy, and proper motions, obtained from recent ground-based surveys of this region, were used to identify the most likely optical counterpart to each X-ray source. Although most of our X-ray selected sample appears to be associated with NGC 2264 members, we find that the vast majority of the cluster membership was undetected in the ROSAT HRI survey. The X-ray cumulative luminosity function for solar-mass stars in NGC 2264 shows that most of the low-mass members probably have X-ray luminosities similar to those seen for the X-ray brightest members of older clusters such as IC 2391/IC 2602 (age approx. 50 Myr) and the Pleiades (age approx. 100 Myr). This research was funded in part by the SAO Summer Intern Program and NASA grant NAG5-8120.

High-redshift Galaxies and Black Holes Detectable with the JWST: A Population Synthesis Model from Infrared to X-Rays

NASA Astrophysics Data System (ADS)

Volonteri, Marta; Reines, Amy E.; Atek, Hakim; Stark, Daniel P.; Trebitsch, Maxime

2017-11-01

The first billion years of the Universe has been a pivotal time: stars, black holes (BHs), and galaxies formed and assembled, sowing the seeds of galaxies as we know them today. Detecting, identifying, and understanding the first galaxies and BHs is one of the current observational and theoretical challenges in galaxy formation. In this paper we present a population synthesis model aimed at galaxies, BHs, and active galactic nuclei (AGNs) at high redshift. The model builds a population based on empirical relations. The spectral energy distribution of galaxies is determined by age and metallicity, and that of AGNs by BH mass and accretion rate. We validate the model against observations, and predict properties of galaxies and AGN in other wavelength and/or luminosity ranges, estimating the contamination of stellar populations (normal stars and high-mass X-ray binaries) for AGN searches from the infrared to X-rays, and vice versa for galaxy searches. For high-redshift galaxies with stellar ages < 1 {Gyr}, we find that disentangling stellar and AGN emission is challenging at restframe UV/optical wavelengths, while high-mass X-ray binaries become more important sources of confusion in X-rays. We propose a color-color selection in the James Webb Space Telescope bands to separate AGN versus star-dominated galaxies in photometric observations. We also estimate the AGN contribution, with respect to massive, hot, and metal-poor stars, at driving high-ionization lines, such as C IV and He II. Finally, we test the influence of the minimum BH mass and occupation fraction of BHs in low-mass galaxies on the restframe UV/near-IR and X-ray AGN luminosity function.

The Chandra COSMOS-Legacy Survey: Source X-Ray Spectral Properties

NASA Astrophysics Data System (ADS)

Marchesi, S.; Lanzuisi, G.; Civano, F.; Iwasawa, K.; Suh, H.; Comastri, A.; Zamorani, G.; Allevato, V.; Griffiths, R.; Miyaji, T.; Ranalli, P.; Salvato, M.; Schawinski, K.; Silverman, J.; Treister, E.; Urry, C. M.; Vignali, C.

2016-10-01

We present the X-ray spectral analysis of the 1855 extragalactic sources in the Chandra COSMOS-Legacy survey catalog having more than 30 net counts in the 0.5-7 keV band. A total of 38% of the sources are optically classified type 1 active galactic nuclei (AGNs), 60% are type 2 AGNs, and 2% are passive, low-redshift galaxies. We study the distribution of AGN photon index Γ and of the intrinsic absorption {N}{{H},{{z}}} based on the sources’ optical classification: type 1 AGNs have a slightly steeper mean photon index Γ than type 2 AGNs, which, on the other hand, have average {N}{{H},{{z}}} ˜ 3 times higher than type 1 AGNs. We find that ˜15% of type 1 AGNs have {N}{{H},{{z}}}\\gt {10}22 cm-2, I.e., are obscured according to the X-ray spectral fitting; the vast majority of these sources have {L}2{--10{keV}} \\gt 1044 erg s-1. The existence of these objects suggests that optical and X-ray obscuration can be caused by different phenomena, the X-ray obscuration being, for example, caused by dust-free material surrounding the inner part of the nuclei. Approximately 18% of type 2 AGNs have {N}{{H},{{z}}}\\lt {10}22 cm-2, and most of these sources have low X-ray luminosities (L {}2{--10{keV}} \\lt 1043 erg s-1). We expect a part of these sources to be low-accretion, unobscured AGNs lacking broad emission lines. Finally, we also find a direct proportional trend between {N}{{H},{{z}}} and host-galaxy mass and star formation rate, although part of this trend is due to a redshift selection effect.

Two New Sandwich-Type Polyoxomolybdates Functionalized with Diphosphonates: Efficient and Selective Oxidation of Sulfides to Sulfones

PubMed Central

Sun, Xiaopeng; Hu, Feng; Wan, Rong; Singh, Vikram; Ma, Pengtao; Wang, Jingping

2017-01-01

Two sandwich-type polyoxomolybdates Na8[MO2{Mo2O5(O3PCH3C(O)PO3)}2] (M = Ni2+ (1); Co2+ (2)) were synthesized by one-pot reaction of Na2HPMo12O40·14H2O, 1-hydroxy ethidene diphosphonic acid (HEDP=HOC(CH3)(PO3H2)2), and (1) NiCl2/CoCl2 (2). Compounds 1 and 2 were characterized by single crystal X-ray analysis, X-ray powder diffraction (XRPD), IR spectroscopy, 31P NMR spectra, UV-vis spectroscopy, and thermogravimetric analyses (TGA). Structural analysis reveals that 1 and 2 exhibit similar centrosymmetric structure, which consists of one transition metal (TM) ion sandwiched by two same subunits {Mo2O5(O3PCH3C(O)PO3)}. The clusters 1 and 2 show efficient catalytic activities for oxidation of thioanisole. Moreover, they are catalytically selective for oxidizing thioanisole. Both resuable polyoxomolybdates 1 and 2 catalysts show good thermo- and hydrolytic stability. It is noted that compound 1 shows outstanding catalytic activity for oxidation of various sulfides to corresponding sulfones with 93–100% selectivity at 97–100% conversion in one hour under mild conditions, which is potentially valuable to the removal of organic sulfides. PMID:29027947

Design and Tests of the Hard X-Ray Polarimeter X-Calibur

NASA Technical Reports Server (NTRS)

Beilicke, M.; Binns, W. R.; Buckley, J.; Cowsik, R.; Dowkontt, P.; Garson, A.; Guo, Q.; Israel, M. H.; Lee, K.; Krawczynski, H.;

Design and Tests of the Hard X-Ray Polarimeter X-Calibur

NASA Technical Reports Server (NTRS)

Beilicke, M.; Baring, M. G.; Barthelmy, S.; Binns, W. R.; Buckley, J.; Cowsik, R.; Dowkontt, P.; Garson, A.; Guo, Q.; Haba, Y.;

The XXL Survey XIV. AAOmega Redshifts for the Southern XXL Field

NASA Astrophysics Data System (ADS)

Lidman, C.; Ardila, F.; Owers, M.; Adami, C.; Chiappetti, L.; Civano, F.; Elyiv, A.; Finet, F.; Fotopoulou, S.; Goulding, A.; Koulouridis, E.; Melnyk, O.; Menanteau, F.; Pacaud, F.; Pierre, M.; Plionis, M.; Surdej, J.; Sadibekova, T.

2016-01-01

We present a catalogue containing the redshifts of 3 660 X-ray selected targets in the XXL southern field. The redshifts were obtained with the AAOmega spectrograph and 2dF fibre positioner on the Anglo-Australian Telescope. The catalogue contains 1 515 broad line AGN, 528 stars, and redshifts for 41 out of the 49 brightest X-ray selected clusters in the XXL southern field.

Coronal X-ray enhancements associated with H-alpha filament disappearances

NASA Technical Reports Server (NTRS)

Webb, D. F.; Krieger, A. S.; Rust, D. M.

1976-01-01

The X-ray telescope experiment aboard the Skylab/ATM mission provided high-resolution soft X-ray images of the lower corona away from active regions, revealing frequent large-scale transient X-ray enhancements which could often be associated with the disappearance of H-alpha filaments. The X-ray emitting structures featured peak brightnesses similar to those of nonflaring active region structures, durations from 3 to 40 hours, shapes that in general outlined the preexisting H-alpha filaments to as large as 400,000 km, apparent expansion velocities of the order of tens of km/sec, and observed peak temperatures of the order of a few million degrees. One such event is described and analyzed in detail. Two explanations of the events are discussed: (1) excess cool material is present in the filament cavity, contributing to the X-ray enhancement, and (2) the enhancement is due to the compression of preexisting material by a changing magnetic field.

A Search for X-ray Emission from the First Magnetically Active T Dwarf

NASA Astrophysics Data System (ADS)

Williams, Peter

2015-09-01

Ultracool dwarfs (spectral types >M7) were long expected to be magnetically inactive, but concerted X-ray and radio observations (mostly by our group) have led to the discovery of magnetic activity and a characterization of its basic properties. We have recently discovered periodic radio bursts from the T6.5 dwarf 2MASS 1047+21, by far the coolest (900 K) substellar object detected in the radio, implying high levels of magnetic activity well into the brown dwarf regime and making it a uniquely compelling target in the challenging search for ultracool X-ray emission. We propose a 40 ks observation with ACIS-S and the VLA that will cover 6 full rotations, place the deepest constraints on X-ray luminosity to date, and may lead to the first detection of X-ray emission from a T dwarf.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsoua, Hwei-Ru; MacEwana, Gloria; Birnberga, Gary

We discovered 2-(4-substituted-pyrrolo[2,3-b]pyridin-3-yl)methylene-4-hydroxybenzofuran-3(2H)-ones as potent and selective ATP-competitive inhibitors of the mammalian target of rapamycin (mTOR). Since phenolic OH groups pose metabolic liability, one of the two hydroxyl groups was selectively removed. The SAR data showed the structural features necessary for subnanomolar inhibitory activity against mTOR kinase as well as selectivity over PI3K?. An X-ray co-crystal structure of one inhibitor with the mTOR-related PI3K? revealed the key hydrogen bonding interactions.

Accretion and Outflows in X-ray Binaries: What's Really Going on During X-ray Quiescence

NASA Astrophysics Data System (ADS)

MacDonald, Rachel K. D.; Bailyn, Charles D.; Buxton, Michelle

2015-01-01

X-ray binaries, consisting of a star and a stellar-mass black hole, are wonderful laboratories for studying accretion and outflows. They evolve on timescales quite accessible to us, unlike their supermassive cousins, and allow the possibility of gaining a deeper understanding of these two common astrophysical processes. Different wavelength regimes reveal different aspects of the systems: radio emission is largely generated by outflows and jets, X-ray emission by inner accretion flows, and optical/infrared (OIR) emission by the outer disk and companion star. The search for relationships between these different wavelengths is thus an area of active research, aiming to reveal deeper connections between accretion and outflows.Initial evidence for a strong, tight correlation between radio and X-ray emission has weakened as further observations and newly-discovered sources have been obtained. This has led to discussions of multiple tracks or clusters, or the possibility that no overall relation exists for the currently-known population of X-ray binaries. Our ability to distinguish among these options is hampered by a relative lack of observations at lower luminosities, and especially of truly X-ray quiescent (non-outbursting) systems. Although X-ray binaries spend the bulk of their existence in quiescence, few quiescent sources have been observed and multiple observations of individual sources are largely nonexistent. Here we discuss new observations of the lowest-luminosity quiescent X-ray binary, A0620-00, and the place this object occupies in investigations of the radio/X-ray plane. For the first time, we also incorporate simultaneous OIR data with the radio and X-ray data.In December 2013 we took simultaneous observations of A0620-00 in the X-ray (Chandra), the radio (EVLA), and the OIR (SMARTS 1.3m). These X-ray and radio data allowed us to investigate similarities among quiescent X-ray binaries, and changes over time for this individual object, in the radio/X-ray plane. In addition, our OIR observations allowed us to examine the radio and X-ray information in relation to the different OIR states of behavior (passive and active) known to exist during X-ray quiescence.

DIRECT SPATIAL ASSOCIATION OF AN X-RAY FLARE WITH THE ERUPTION OF A SOLAR QUIESCENT FILAMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holman, Gordon D.; Foord, Adi, E-mail: gordon.d.holman@nasa.gov

Solar flares primarily occur in active regions. Hard X-ray flares have been found to occur only in active regions. They are often associated with the eruption of active region filaments and coronal mass ejections (CMEs). CMEs can also be associated with the eruption of quiescent filaments, not located in active regions. Here we report the first identification of a solar X-ray flare outside an active region observed by the Ramaty High Energy Solar Spectroscopic Imager (RHESSI). The X-ray emission was directly associated with the eruption of a long, quiescent filament and fast CME. Images from RHESSI show this flare emissionmore » to be located along a section of the western ribbon of the expanding, post-eruption arcade. EUV images from the Solar Dynamics Observatory Atmospheric Imaging Assembly show no connection between this location and nearby active regions. Therefore the flare emission is found not to be located in or associated with an active region. However, a nearby, small, magnetically strong dipolar region provides a likely explanation for the existence and location of the flare X-ray emission. This emerging dipolar region may have also triggered the filament eruption.« less

Mechanisms for dominance: Adh heterodimer formation in heterozygotes between ENU or x-ray induced null alleles and normal alleles in drosophila melanogaster

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, J.C.; Lee, W.R.; Chang, S.H.

1992-01-01

To study mechanisms for dominance of phenotype, eight ENU- and four x-ray-induced mutations at the alcohol dehydrogenase (Adh) locus were analyzed for partial dominance in their interaction with normal alleles. All ENU and one of the x-ray mutations were single base substitutions; the other three x-ray mutations were 9-21 base deletions. All but one of the 12 mutant alleles were selected for this study because they produced detectable mutant polypeptides, but seven of the 11 producing a peptide could not form dimers with the normal peptide and the enzyme activity of heterozygotes was about half that of normal homozygotes. Fourmore » mutations formed dimers with a decreased catalytic efficiency and two of these were near the limit of detectability; these two also inhibited the formation of normal homodimers. The mutant alleles therefore show multiple mechanisms leading to partial enzyme expression in heterozygotes and a wide range of dominance ranging from almost complete recessive to nearly dominant. All amino acid changes in mutant peptides that form dimers are located between amino acids 182 and 194, so this region is not critical for dimerization. It may, however, be an important surface domain for catalyzation. 34 refs., 8 figs., 2 tabs.« less

An audit of care received by patients injured during sporting activities.

PubMed

Grimble, S; Kendall, I G; Allen, M J

1993-09-01

A summary of injuries sustained by 340 sportsmen over 9 successive weekends from 16 November 1991 to 12 January 1992 attending an accident and emergency (A&E) department is presented. Most injuries occurred in young males usually as a result of soccer or rugby. Sixty-seven per cent of patients were discharged with no further followed up in hospital. Seventy-two per cent of patients were X-rayed, 33% of X-rays showed a fracture or dislocation. A total of 193 attendees received minimal treatment, (defined as discharge with advice only, simple analgesia or strapping only with no hospital follow-up) and of these 152 were X-rayed. A total of 100 patients who received minimal treatment were selected randomly by computer to receive a follow-up letter asking about certain issues relating to their care in the A&E department. Most patients felt that the A&E Department was the most appropriate source of treatment for their sports injury, and over half attended specifically for an X-ray examination. Despite the doctors view that many of these minor injuries could have been self-treated, few patients felt able to treat future similar minor injuries themselves. They were, however, more likely to go elsewhere for treatment on subsequent occasions.

An audit of care received by patients injured during sporting activities.

PubMed Central

Grimble, S; Kendall, I G; Allen, M J

1993-01-01

A summary of injuries sustained by 340 sportsmen over 9 successive weekends from 16 November 1991 to 12 January 1992 attending an accident and emergency (A&E) department is presented. Most injuries occurred in young males usually as a result of soccer or rugby. Sixty-seven per cent of patients were discharged with no further followed up in hospital. Seventy-two per cent of patients were X-rayed, 33% of X-rays showed a fracture or dislocation. A total of 193 attendees received minimal treatment, (defined as discharge with advice only, simple analgesia or strapping only with no hospital follow-up) and of these 152 were X-rayed. A total of 100 patients who received minimal treatment were selected randomly by computer to receive a follow-up letter asking about certain issues relating to their care in the A&E department. Most patients felt that the A&E Department was the most appropriate source of treatment for their sports injury, and over half attended specifically for an X-ray examination. Despite the doctors view that many of these minor injuries could have been self-treated, few patients felt able to treat future similar minor injuries themselves. They were, however, more likely to go elsewhere for treatment on subsequent occasions. PMID:8216595

Diatomite-supported Pd-M (M=Cu, Co, Ni) bimetal nanocatalysts for selective hydrogenation of long-chain aliphatic esters.

PubMed

Huang, Changliang; Zhang, Hongye; Zhao, Yanfei; Chen, Sha; Liu, Zhimin

2012-11-15

Diatomite supported Pd-M (M=Cu, Co, Ni) bimetal nanocatalysts with various metal compositions were prepared and characterized by means of X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. It was demonstrated that the metal nanoparticles were uniformly distributed on the support, and their size was centered around 8 nm with a relatively narrow size distribution. The catalysts were used to catalyze hydrogenation of long-chain aliphatic esters, including methyl palmitate, methyl stearate, and methyl laurate. It was indicated that the all diatomite-supported Pd-based bimetal catalysts were active to the selective hydrogenation of long-chain esters to corresponding alcohols at 270°C, originated from the synergistic effect between the metal particles and the diatomite support. For the selective hydrogenation of methyl palmitate, Pd-Cu/diatomite with metal loading of 1% and Pd/Cu=3 displayed the highest performance, giving a 1-hexadecanol yield of 82.9% at the substrate conversion of 98.8%. Copyright © 2012 Elsevier Inc. All rights reserved.

Mössbauer study of modified iron-molybdenum catalysts for methanol oxidation

NASA Astrophysics Data System (ADS)

Ivanov, K. I.; Mitov, I. G.; Krustev, St. V.; Boyanov, B. S.

2010-03-01

The preparation and catalytic properties of mixed Fe-Mo-W catalysts toward methanol oxidation are investigated. Mössbauer spectroscopy, X-ray diffraction and chemical studies revealed the formation of two types of solid solutions with compositions Fe2(MoxW1-xO4)3 and (MoxW1-x)O3. The solid solutions formed are characterized by high activity and selectivity upon methanol oxidation and are of interest in view of their practical application. Sodium-doped iron-molybdenum catalysts are also investigated and the NaFe(MoO4)2 formation was established.

Adjustable Grazing-Incidence X-Ray Optics

NASA Technical Reports Server (NTRS)

O'Dell, Stephen L.; Reid, Paul B.

2015-01-01

With its unique subarcsecond imaging performance, NASA's Chandra X-ray Observatory illustrates the importance of fine angular resolution for x-ray astronomy. Indeed, the future of x-ray astronomy relies upon x-ray telescopes with comparable angular resolution but larger aperture areas. Combined with the special requirements of nested grazing-incidence optics, mass, and envelope constraints of space-borne telescopes render such advances technologically and programmatically challenging. The goal of this technology research is to enable the cost-effective fabrication of large-area, lightweight grazing-incidence x-ray optics with subarcsecond resolution. Toward this end, the project is developing active x-ray optics using slumped-glass mirrors with thin-film piezoelectric arrays for correction of intrinsic or mount-induced distortions.

The Generation-X Vision Mission Study and Advanced Mission Concept

NASA Astrophysics Data System (ADS)

Brissenden, Roger J. V.; Generation-X Team

2008-03-01

The Generation-X (Gen-X) mission was selected as one of NASA's Vision Missions as a concept for a next generation X-ray telescope designed to study the very early universe with 1000-times greater sensitivity than current X-ray telescopes. The mission has also been proposed as an Advanced Mission Concept Study (AMCS) to further define the technology development plan and mission design. The scientific goals for Gen-X include studying the first generations of stars and black holes in the epoch z=10-20, the evolution of black holes and galaxies from high z to the present, the chemical evolution of the universe and the properties of matter under extreme conditions. The key parameters required to meet these goals define a challenging mission and include an effective area of 50 m2 at 1 keV, and an angular resolution (HPD) of 0.1 arcsec over an energy band of 0.1-10 keV. The required effective area implies that extremely lightweight grazing incidence X-ray optics must be developed. To achieve the required areal density of at least 100 times lower than in Chandra, thin ( 0.1 mm) mirrors that have active on-orbit figure control are required. We present the major findings from the Gen-X Vision Mission Study and a streamlined mission concept enabled by the Ares V launch capability, as proposed in response to the AMSC call.

Yeast cell metabolism investigated by CO{_2} production and soft X-ray irradiation

NASA Astrophysics Data System (ADS)

Masini, A.; Batani, D.; Previdi, F.; Milani, M.; Pozzi, A.; Turcu, E.; Huntington, S.; Takeyasu, H.

1999-01-01

Results obtained using a new technique for studying cell metabolism are presented. The technique, consisting in CO2 production monitoring, has been applied to Saccharomyces cerevisiae yeast cells. Also the cells were irradiated using the soft X-ray laser-plasma source at Rutherford Appleton Laboratory with the aim of producing a damage of metabolic processes at the wall level, responsible for fermentation, without great interference with respiration, taking place in mitochondria, and DNA activity. The source was calibrated with PIN diodes and X-ray spectrometers and used Teflon stripes as target, emitting X-rays at about 0.9 keV, with a very low penetration in biological material. X-ray doses delivered to the different cell compartments were calculated following a Lambert-Bouguet-Beer law. Immediately after irradiation, the damage to metabolic activity was measured again by monitoring CO2 production. Results showed a general reduction in gas production by irradiated samples, together with non-linear and non-monotone response to dose. There was also evidence of oscillations in cell metabolic activity and of X-ray induced changes in oscillation frequency.

Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect-Rich Plasma-Activated Silver Catalysts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mistry, Hemma; Choi, Yong-Wook; Bagger, Alexander

Efficient, stable catalysts with high selectivity for a single product are essential if electroreduction of CO 2 is to become a viable route to the synthesis of industrial feedstocks and fuels. A plasma oxidation pre-treatment of silver foil enhances the number of low-coordinated catalytically active sites, which dramatically lowers the overpotential and increases the activity of CO 2 electroreduction to CO. At -0.6 V versus RHE more than 90 % Faradaic efficiency towards CO was achieved on a pre-oxidized silver foil. While transmission electron microscopy (TEM) and operando X-ray absorption spectroscopy showed that oxygen species can survive in the bulkmore » of the catalyst during the reaction, quasi in situ X-ray photoelectron spectroscopy showed that the surface is metallic under reaction conditions. Finally, DFT calculations reveal that the defect-rich surface of the plasma-oxidized silver foils in the presence of local electric fields drastically decrease the overpotential of CO 2 electroreduction.« less

The discovery and preclinical evaluation of BMS-707035, a potent HIV-1 integrase strand transfer inhibitor.

PubMed

Naidu, B Narasimhulu; Walker, Michael A; Sorenson, Margaret E; Ueda, Yasutsugu; Matiskella, John D; Connolly, Timothy P; Dicker, Ira B; Lin, Zeyu; Bollini, Sagarika; Terry, Brian J; Higley, Helen; Zheng, Ming; Parker, Dawn D; Wu, Dedong; Adams, Stephen; Krystal, Mark R; Meanwell, Nicholas A

2018-07-01

BMS-707035 is an HIV-1 integrase strand transfer inhibitor (INSTI) discovered by systematic optimization of N-methylpyrimidinone carboxamides guided by structure-activity relationships (SARs) and the single crystal X-ray structure of compound 10. It was rationalized that the unexpectedly advantageous profiles of N-methylpyrimidinone carboxamides with a saturated C2-substitutent may be due, in part, to the geometric relationship between the C2-substituent and the pyrimidinone core. The single crystal X-ray structure of 10 provided support for this reasoning and guided the design of a spirocyclic series 12 which led to discovery of the morpholino-fused pyrimidinone series 13. Several carboxamides derived from this bicyclic scaffold displayed improved antiviral activity and pharmacokinetic profiles when compared with corresponding spirocyclic analogs. Based on the excellent antiviral activity, preclinical profiles and acceptable in vitro and in vivo toxicity profiles, 13a (BMS-707035) was selected for advancement into phase I clinical trials. Copyright © 2018 Elsevier Ltd. All rights reserved.

Acetic Acid Ketonization over Fe3O4/SiO2 for Pyrolysis Bio-Oil Upgrading.

PubMed

Bennett, James A; Parlett, Christopher M A; Isaacs, Mark A; Durndell, Lee J; Olivi, Luca; Lee, Adam F; Wilson, Karen

2017-05-10

A family of silica-supported, magnetite nanoparticle catalysts was synthesised and investigated for continuous-flow acetic acid ketonisation as a model pyrolysis bio-oil upgrading reaction. The physico-chemical properties of Fe 3 O 4 /SiO 2 catalysts were characterised by using high-resolution transmission electron microscopy, X-ray absorption spectroscopy, X-ray photo-electron spectroscopy, diffuse reflectance infrared Fourier transform spectroscopy, thermogravimetric analysis and porosimetry. The acid site densities were inversely proportional to the Fe 3 O 4 particle size, although the acid strength and Lewis character were size-invariant, and correlated with the specific activity for the vapour-phase acetic ketonisation to acetone. A constant activation energy (∼110 kJ mol -1 ), turnover frequency (∼13 h -1 ) and selectivity to acetone of 60 % were observed for ketonisation across the catalyst series, which implies that Fe 3 O 4 is the principal active component of Red Mud waste.

New spiro-oxindole constructed with pyrrolidine/thioxothiazolidin-4-one derivatives: Regioselective synthesis, X-ray crystal structures, Hirshfeld surface analysis, DFT, docking and antimicrobial studies

NASA Astrophysics Data System (ADS)

Barakat, Assem; Soliman, Saied M.; Al-Majid, Abdullah Mohammed; Ali, M.; Islam, Mohammad Shahidul; Elshaier, Yaseen A. M. M.; Ghabbour, Hazem A.

2018-01-01

In this work, polycyclic heterocycles containing spirooxindole, pyrrolidine, and thioxothiazolidin-4-one rings have been synthesized via the regioselective 1,3-dipolar cycloaddition of azomethine ylide, which is generated in situ by the condensation of the dicarbonyl compound isatin and the secondary amino acid (L-proline), with 5-arylidine-2-thioxothiazolidin-4-one as the dipolarophile. The structure of the synthesized compounds 4a and 4b were determined by using X-ray single crystal diffraction, and also, Hirshfeld surface analysis were reported. Their geometric parameters were calculated using density functional theory at the B3LYP/6-311G (d,p) level of theory. Both compounds showed antimicrobial and antifungal activity better than selected standards (ampicillin and gentamicin in case of antibacterial activity and Amphotericin A and fluconazole in case of antifungal activity). Molecular docking study of the synthesized compounds indicated that phenyl group plays an important role in determination of compound interaction inside the receptors.

Enhanced Carbon Dioxide Electroreduction to Carbon Monoxide over Defect-Rich Plasma-Activated Silver Catalysts

DOE PAGES

Mistry, Hemma; Choi, Yong-Wook; Bagger, Alexander; ...

2017-07-14

Efficient, stable catalysts with high selectivity for a single product are essential if electroreduction of CO 2 is to become a viable route to the synthesis of industrial feedstocks and fuels. A plasma oxidation pre-treatment of silver foil enhances the number of low-coordinated catalytically active sites, which dramatically lowers the overpotential and increases the activity of CO 2 electroreduction to CO. At -0.6 V versus RHE more than 90 % Faradaic efficiency towards CO was achieved on a pre-oxidized silver foil. While transmission electron microscopy (TEM) and operando X-ray absorption spectroscopy showed that oxygen species can survive in the bulkmore » of the catalyst during the reaction, quasi in situ X-ray photoelectron spectroscopy showed that the surface is metallic under reaction conditions. Finally, DFT calculations reveal that the defect-rich surface of the plasma-oxidized silver foils in the presence of local electric fields drastically decrease the overpotential of CO 2 electroreduction.« less

Perspectives of the lobster-eye telescope: The promising types of cosmic X-ray sources

NASA Astrophysics Data System (ADS)

Šimon, V.

2017-07-01

We show the astrophysical aspects of observing the X-ray sky with the planned lobster-eye telescope. This instrument is important because it is able to provide wide-field X-ray imaging. For the testing observations, we propose to include also X-ray binaries in which matter transfers onto the compact object (mostly the neutron star). We show the typical features of the long-term X-ray activity of such objects. Observing in the soft X-ray band is the most promising because their X-ray intensity is the highest in this band. Since these X-ray sources tend to concentrate toward the center of our Galaxy, several of them can be present in the field of view of the tested instrument.

X-ray Scattering Combined with Coordinate-Based Analyses for Applications in Natural and Artificial Photosynthesis

PubMed Central

Tiede, David M.; Mardis, Kristy L.; Zuo, Xiaobing

2009-01-01

Advances in x-ray light sources and detectors have created opportunities for advancing our understanding of structure and structural dynamics for supramolecular assemblies in solution by combining x-ray scattering measurement with coordinate-based modeling methods. In this review the foundations for x-ray scattering are discussed and illustrated with selected examples demonstrating the ability to correlate solution x-ray scattering measurements to molecular structure, conformation, and dynamics. These approaches are anticipated to have a broad range of applications in natural and artificial photosynthesis by offering possibilities for structure resolution for dynamic supramolecular assemblies in solution that can not be fully addressed with crystallographic techniques, and for resolving fundamental mechanisms for solar energy conversion by mapping out structure in light-excited reaction states. PMID:19636808

Characteristic of x-ray tomography performance using CdTe timepix detector

NASA Astrophysics Data System (ADS)

Zain, R. M.; O'Shea, V.; Maneuski, D.

2017-01-01

X-ray Computed Tomography (CT) is a non-destructive technique for visualizing interior features within solid objects, and for obtaining digital information on their 3-D geometries and properties. The selection of CdTe Timepix detector has a sufficient performance of imaging detector is based on quality of detector performance and energy resolution. The study of Modulation Transfer Function (MTF) shows a 70% contrast at 4 lp/mm was achieved for the 55 µm pixel pitch detector with the 60 kVp X-ray tube and 5 keV noise level. No significant degradation in performance was observed for X-ray tube energies of 20 - 60 keV. The paper discusses the application of the CdTe Timepix detector to produce a good quality image of X-ray tomography imaging.

X-ray and multiwavelength insights into the inner structure of high-luminosity disc-like emitters

NASA Astrophysics Data System (ADS)

Luo, B.; Brandt, W. N.; Eracleous, M.; Wu, Jian; Hall, P. B.; Rafiee, A.; Schneider, D. P.; Wu, Jianfeng

2013-02-01

We present X-ray and multiwavelength studies of a sample of eight high-luminosity active galactic nuclei (AGN) with disc-like Hβ emission-line profiles selected from the Sloan Digital Sky Survey Data Release 7. These sources have higher redshift (z ≈ 0.6) than the majority of the known disc-like emitters, and they occupy a largely unexplored space in the luminosity-redshift plane. Seven sources have typical AGN X-ray spectra with power-law photon indices of Γ ≈ 1.4-2.0; two of them show some X-ray absorption (column density NH ≈ 1021-1022 cm-2 for neutral gas). The other source, J0850+4451, has only three hard X-ray photons detected and is probably heavily obscured (NH ≳ 3 × 1023 cm-2). This object is also identified as a low-ionization broad absorption line (BAL) quasar based on Mg II λ2799 absorption; it is the first disc-like emitter reported that is also a BAL quasar. The infrared-to-ultraviolet (UV) spectral energy distributions (SEDs) of these eight sources are similar to the mean SEDs of typical quasars with a UV `bump', suggestive of standard accretion discs radiating with high efficiency, which differs from low-luminosity disc-like emitters. Studies of the X-ray-to-optical power-law slope parameters (αOX) indicate that there is no significant excess X-ray emission in these high-luminosity disc-like emitters. Energy budget analysis suggests that for disc-like emitters in general, the inner disc must illuminate and ionize the outer disc efficiently (≈15 per cent of the nuclear ionizing radiation is required on average) via direct illumination and/or scattering. Warped accretion discs are probably needed for direct illumination to work in high-luminosity objects, as their geometrically thin inner discs decrease the amount of direct illumination possible for a flat disc.

Soft X-Ray Observations of a Complete Sample of X-Ray--selected BL Lacertae Objects

NASA Astrophysics Data System (ADS)

Perlman, Eric S.; Stocke, John T.; Wang, Q. Daniel; Morris, Simon L.

1996-01-01

We present the results of ROSAT PSPC observations of the X-ray selected BL Lacertae objects (XBLs) in the complete Einstein Extended Medium Sensitivity Survey (EM MS) sample. None of the objects is resolved in their respective PSPC images, but all are easily detected. All BL Lac objects in this sample are well-fitted by single power laws. Their X-ray spectra exhibit a variety of spectral slopes, with best-fit energy power-law spectral indices between α = 0.5-2.3. The PSPC spectra of this sample are slightly steeper than those typical of flat ratio-spectrum quasars. Because almost all of the individual PSPC spectral indices are equal to or slightly steeper than the overall optical to X-ray spectral indices for these same objects, we infer that BL Lac soft X-ray continua are dominated by steep-spectrum synchrotron radiation from a broad X-ray jet, rather than flat-spectrum inverse Compton radiation linked to the narrower radio/millimeter jet. The softness of the X-ray spectra of these XBLs revives the possibility proposed by Guilbert, Fabian, & McCray (1983) that BL Lac objects are lineless because the circumnuclear gas cannot be heated sufficiently to permit two stable gas phases, the cooler of which would comprise the broad emission-line clouds. Because unified schemes predict that hard self-Compton radiation is beamed only into a small solid angle in BL Lac objects, the steep-spectrum synchrotron tail controls the temperature of the circumnuclear gas at r ≤ 1018 cm and prevents broad-line cloud formation. We use these new ROSAT data to recalculate the X-ray luminosity function and cosmological evolution of the complete EMSS sample by determining accurate K-corrections for the sample and estimating the effects of variability and the possibility of incompleteness in the sample. Our analysis confirms that XBLs are evolving "negatively," opposite in sense to quasars, with Ve/Va = 0.331±0.060. The statistically significant difference between the values for X-ray and radio-selected BL Lac objects remains a difficulty for models which unify these two types of objects. We have identified one addition to the sample, so that the sample now has 23 objects. We find no evidence for a substantial number of unidentified low-luminosity BL Lac objects hidden in our sample, as had been suggested by Browne & Marcha (1993) although a few such objects may be present.

Swift detection of increased X-ray activity from gamma-ray flaring blazar PKS 1424-41

NASA Astrophysics Data System (ADS)

Ciprini, Stefano; Cutini, Sara

2013-01-01

Following enduring gamma-ray flaring activity of the flat spectrum radio quasar PKS 1424-41 (also known as 2FGL J1428.0-4206, Nolan et al. 2012, ApJS, 199, 31) detected by Fermi LAT during January 2013, two Swift target of opportunity observations were performed on January 24 and 27, 2013. Recent gamma-ray and X-ray flaring activity from the source was observed on January 6 and January 7 (ATel#4714 and ATel #4717).

The X-ray microscopy beamline UE46-PGM2 at BESSY

NASA Astrophysics Data System (ADS)

Follath, R.; Schmidt, J. S.; Weigand, M.; Fauth, K.

2010-06-01

The Max Planck Institute for Metal Physics in Stuttgart and the Helmholtz Center Berlin operate a soft X-ray microscopy beamline at the storage ring BESSY II. A collimated PGM serves as monochromator for a scanning X-ray microscope and a full field X-ray microscope at the helical undulator UE46. The selection between both instruments is accomplished via two switchable focusing mirrors. The scanning microscope (SM) is based on the ALS STXM microscope and fabricated by the ACCEL company. The full field microscope (FFM) is currently in operation at the U41-SGM beamline and will be relocated to its final location this year.

Elemental X-ray mapping of agglutinated foraminifer tests: A non- destructive technique for determining compositional characteristics.

USGS Publications Warehouse

Commeau, R.F.; Reynolds, Leslie A.; Poag, C.W.

1985-01-01

The composition of agglutinated foraminiferal tests vary remarkably in response to local substrate characteristics, physiochemical properties of the water column and species- dependant selectivity of test components. We have employed a technique that combines a scanning electron microscope with an energy dispersive X-ray spectrometer system to identify major and minor elemental constituents of agglutinated foraminiferal walls. As a sample is bombarded with a beam of high energy electrons, X-rays are generated that are characteristic of the elements present. As a result, X- ray density maps can be produced for each of several elements present in the tests of agglutinated foraminifers. 

A KPC-scale X-ray jet in the BL LAC Source S5 2007+777

NASA Technical Reports Server (NTRS)

Sambruna, Rita; Maraschi, Laura; Tavecchio, Fabrizio

2008-01-01

The BL Lac S3 2007++777, a classical radio-selected BL Lac from the sample of Stirkel et al. exhibiting an extended (19") radio jet. was observed with Chandra revealing an X-ray jet with simi1ar morphology. The hard X-ray spectrum and broad band SED is consistent with an IC/CMB origin for the X-ray emission, implying a highly relativistic flow at small angle to the line of sight with an unusually large deprojected length, 300 kpc. A structured jet consisting of a fast spine and slow wall is consistent with the observations.

Study of Swift/Bat Selected Low-luminosity Active Galactic Nuclei Observed with Suzaku

NASA Astrophysics Data System (ADS)

Kawamuro, Taiki; Ueda, Yoshihiro; Tazaki, Fumie; Terashima, Yuichi; Mushotzky, Richard

2016-11-01

We systematically analyze the broadband (0.5-200 keV) X-ray spectra of hard X-ray (>10 keV) selected local low-luminosity active galactic nuclei (LLAGNs) observed with Suzaku and Swift/BAT. The sample consists of 10 LLAGNs detected with Swift/BAT with intrinsic 14-195 keV luminosities smaller than 1042 erg s-1 available in the Suzaku archive, covering a wide range of the Eddington ratio from 10-5 to 10-2. The overall spectra can be reproduced with an absorbed cut-off power law, often accompanied by reflection components from distant cold matter, and/or optically thin thermal emission from the host galaxy. In all of the objects, relativistic reflection components from the innermost disk are not required. Eight objects show a significant narrow iron-Kα emission line. Comparing their observed equivalent widths with the predictions from the Monte-Carlo-based torus model by Ikeda et al. (2009), we constrain the column density in the equatorial plane to be {log} {N}{{H}}{{eq}}\\gt 22.7, or the torus half-opening angle θ oa < 70°. We infer that the Eddington ratio (λ Edd) is a key parameter that determines the torus structure of LLAGNs: the torus becomes large at λ Edd ≳ 2 × 10-4, whereas at lower accretion rates it is little developed. The luminosity correlation between the hard X-ray and mid-infrared (MIR) bands of the LLAGNs follows the same correlation as for more luminous AGNs. This implies that mechanisms other than AGN-heated dust are responsible for the MIR emission in low Eddington ratio LLAGNs.

X-Ray Spectral Properties of Seven Heavily Obscured Seyfert 2 Galaxies

NASA Astrophysics Data System (ADS)

Marchesi, S.; Ajello, M.; Comastri, A.; Cusumano, G.; La Parola, V.; Segreto, A.

2017-02-01

We present the combined Chandra and Swift-BAT spectral analysis of seven Seyfert 2 galaxies selected from the Swift-BAT 100 month catalog. We selected nearby (z ≤ 0.03) sources lacking a ROSAT counterpart that never previously been observed with Chandra in the 0.3-10 keV energy range, and targeted these objects with 10 ks Chandra ACIS-S observations. The X-ray spectral fitting over the 0.3-150 keV energy range allows us to determine that all the objects are significantly obscured, with N H ≥ 1023 cm-2 at a >99% confidence level. Moreover, one to three sources are candidate Compton-thick Active Galactic Nuclei (CT-AGNs; I.e., N H ≥ 1024 cm-2). We also test the recent spectral curvature method developed by Koss et al. to find candidate CT-AGNs, finding a good agreement between our results and their predictions. Because the selection criteria we adopted were effective in detecting highly obscured AGNs, further observations of these and other Seyfert 2 galaxies selected from the Swift-BAT 100 month catalog will allow us to create a statistically significant sample of highly obscured AGNs, therefore providing a better understanding of the physics of the obscuration processes.

Primary standardization of 57Co.

PubMed

Koskinas, Marina F; Moreira, Denise S; Yamazaki, Ione M; de Toledo, Fábio; Brancaccio, Franco; Dias, Mauro S

2010-01-01

This work describes the method developed by the Nuclear Metrology Laboratory in IPEN, São Paulo, Brazil, for the standardization of a (57)Co radioactive solution. Cobalt-57 is a radionuclide used for calibrating gamma-ray and X-ray spectrometers, as well as a gamma reference source for dose calibrators used in nuclear medicine services. Two 4pibeta-gamma coincidence systems were used to perform the standardization, the first used a 4pi(PC) counter coupled to a pair of 76 mm x 76 mm NaI(Tl) scintillators for detecting gamma-rays, the other one used a HPGe spectrometer for gamma detection. The measurements were performed by selecting a gamma-ray window comprising the (122 keV+136 keV) total absorption energy peaks in the NaI(Tl) and selecting the total absorption peak of 122 keV in the germanium detector. The electronic system used the TAC method developed at LMN for registering the observed events. The methodology recently developed by the LMN for simulating all detection processes in a 4pibeta-gamma coincidence system, by means of the Monte Carlo technique, was applied and the behavior of extrapolation curve compared to experimental data. The final activity obtained by the Monte Carlo calculation agrees with the experimental results within the experimental uncertainty. Copyright 2009 Elsevier Ltd. All rights reserved.

Ultrahigh resolution photographic films for X-ray/EUV/FUV astronomy

NASA Technical Reports Server (NTRS)

Hoover, Richard B.; Walker, Arthur B. C., Jr.; Deforest, Craig E.; Watts, Richard; Tarrio, Charles

1993-01-01

The quest for ultrahigh resolution full-disk images of the sun at soft X-ray/EUV/FUV wavelengths has increased the demand for photographic films with broad spectral sensitivity, high spatial resolution, and wide dynamic range. These requirements were made more stringent by the recent development of multilayer telescopes and coronagraphs capable of operating at normal incidence at soft X-ray/EUV wavelengths. Photographic films are the only detectors now available with the information storage capacity and dynamic range such as is required for recording images of the solar disk and corona simultaneously with sub arc second spatial resolution. During the Stanford/MSFC/LLNL Rocket X-Ray Spectroheliograph and Multi-Spectral Solar Telescope Array (MSSTA) programs, we utilized photographic films to obtain high resolution full-disk images of the sun at selected soft X-ray/EUV/FUV wavelengths. In order to calibrate our instrumentation for quantitative analysis of our solar data and to select the best emulsions and processing conditions for the MSSTA reflight, we recently tested several photographic films. These studies were carried out at the NIST SURF II synchrotron and the Stanford Synchrotron Radiation Laboratory. In this paper, we provide the results of those investigations.

Application of an oscillation-type linear cadmium telluride detector to enhanced gadolinium K-edge computed tomography

NASA Astrophysics Data System (ADS)

Matsukiyo, Hiroshi; Sato, Eiichi; Hagiwara, Osahiko; Abudurexiti, Abulajiang; Osawa, Akihiro; Enomoto, Toshiyuki; Watanabe, Manabu; Nagao, Jiro; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2011-03-01

A linear cadmium telluride (CdTe) detector is useful for carrying out energy-discrimination X-ray imaging, including computed tomography (CT). To perform enhanced gadolinium K-edge CT, we used an oscillation-type linear CdTe detector with an energy resolution of 1.2 keV. CT is performed by repeating the linear scan and the rotation of an object. Penetrating X-ray photons from the object are detected by the CdTe detector, and event signals of X-ray photons are produced using charge-sensitive and shaping amplifiers. Both the photon energy and the energy width are selected using a multichannel analyzer, and the number of photons is counted by a counter card. In energy-discrimination CT, tube voltage and current were 80 kV and 20 μA, respectively, and X-ray intensity was 1.55 μGy/s at 1.0 m from the source at a tube voltage of 80 kV. Demonstration of enhanced gadolinium K-edge X-ray CT was carried out by selecting photons with energies just beyond gadolinium K-edge energy of 50.3 keV.

[Activities of Center for Nondestructive Evaluation, Iowa State University

NASA Technical Reports Server (NTRS)

Gray, Joe

2002-01-01

The final report of NASA funded activities at Iowa State University (ISU) for the period between 1/96 and 1/99 includes two main areas of activity. The first is the development and delivery of an x-ray simulation package suitable for evaluating the impact of parameters affects the inspectability of an assembly of parts. The second area was the development of images processing tools to remove reconstruction artifacts in x-ray laminagraphy images. The x-ray simulation portion of this work was done by J. Gray and the x-ray laminagraphy work was done by J. Basart. The report is divided into two sections covering the two activities respectively. In addition to this work reported the funding also covered NASA's membership in the NSF University/Industrial Cooperative Research Center.

Cancer diagnosis using a conventional x-ray fluorescence camera with a cadmium-telluride detector

NASA Astrophysics Data System (ADS)

Sato, Eiichi; Enomoto, Toshiyuki; Hagiwara, Osahiko; Abudurexiti, Abulajiang; Sato, Koetsu; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2011-10-01

X-ray fluorescence (XRF) analysis is useful for mapping various atoms in objects. Bremsstrahlung X-rays are selected using a 3.0 mm-thick aluminum filter, and these rays are absorbed by indium, cerium and gadolinium atoms in objects. Then XRF is produced from the objects, and photons are detected by a cadmium-telluride detector. The Kα photons are discriminated using a multichannel analyzer, and the number of photons is counted by a counter card. The objects are moved and scanned by an x-y stage in conjunction with a two-stage controller, and X-ray images obtained by atomic mapping are shown on a personal computer monitor. The scan steps of the x and y axes were both 2.5 mm, and the photon-counting time per mapping point was 0.5 s. We carried out atomic mapping using the X-ray camera, and Kα photons from cerium and gadolinium atoms were produced from cancerous regions in nude mice.

Conventional X-ray fluorescence camera with a cadmium-telluride detector and its application to cancer diagnosis

NASA Astrophysics Data System (ADS)

Enomoto, Toshiyuki; Sato, Eiichi; Abderyim, Purkhet; Abudurexiti, Abulajiang; Hagiwara, Osahiko; Matsukiyo, Hiroshi; Osawa, Akihiro; Watanabe, Manabu; Nagao, Jiro; Sato, Shigehiro; Ogawa, Akira; Onagawa, Jun

2011-04-01

X-ray fluorescence (XRF) analysis is useful for mapping various molecules in objects. Bremsstrahlung X-rays are selected using a 3.0-mm-thick aluminum filter, and these rays are absorbed by iodine, cerium, and gadolinium molecules in objects. Next, XRF is produced from the objects, and photons are detected by a cadmium-telluride detector. The Kα photons are discriminated using a multichannel analyzer, and the number of photons is counted by a counter card. The objects are moved and scanned by an x- y stage in conjunction with a two-stage controller, and X-ray images obtained by molecular mapping are shown on a personal computer monitor. The scan steps of x and y axes were both 2.5 mm, and the photon-counting time per mapping point was 0.5 s. We carried out molecular mapping using the X-ray camera, and Kα photons from cerium and gadolinium molecules were produced from cancerous regions in nude mice.

Electron-positron pairs, Compton reflection, and the X-ray spectra of active galactic nuclei

NASA Technical Reports Server (NTRS)

Zdziarski, Andrzej A.; Ghisellini, Gabriele; George, Ian M.; Fabian, A. C.; Svensson, Roland; Done, Chris

1990-01-01

It is shown here that reprocessing of radiation fron nonthermal pair cascades by cold material in the central parts of active galactic nuclei (AGN) gives rise to X-ray and gamma-ray spectra that satisfy current observational constraints. An average 1-30 keV X-ray spectral index alpha(x) of about 0.7 in the compact range 30-300 is obtained for a wide range of Lorentz factors of the injected electrons. The gamma-ray spectra are steep, with alpha(gamma) about two, and satisfy the observational constraints. Radiation from pair cascades exhibits steep power law decreases in soft X-rays similar to those observed in AGN. The overall picture is consistent with AGN having an accretion disk which intercepts and reprocesses a substantial fraction of the nonthermal continuum incident upon it from above and below.

Spacelab

NASA Image and Video Library

1989-01-01

In 1986, NASA introduced a Shuttle-borne ultraviolet observatory called Astro. The Astro Observatory was designed to explore the universe by observing and measuring the ultraviolet radiation from celestial objects. Astronomical targets of observation selected for Astro missions included planets, stars, star clusters, galaxies, clusters of galaxies, quasars, remnants of exploded stars (supernovae), clouds of gas and dust (nebulae), and the interstellar medium. Astro-1 used a Spacelab pallet system with an instrument pointing system and a cruciform structure for bearing the three ultraviolet instruments mounted in a parallel configuration. The three instruments were: The Hopkins Ultraviolet Telescope (HUT), which was designed to obtain far-ultraviolet spectroscopic data from white dwarfs, emission nebulae, active galaxies, and quasars; the Wisconsin Ultraviolet Photo-Polarimeter Experiment (WUPPE) which was to study polarized ultraviolet light from magnetic white dwarfs, binary stars, reflection nebulae, and active galaxies; and the Ultraviolet Imaging Telescope (UIT) which was to record photographic images in ultraviolet light of galaxies, star clusters, and nebulae. The star trackers that supported the instrument pointing system were also mounted on the cruciform. Also in the payload bay was the Broad Band X-Ray Telescope (BBXRT), which was designed to obtain high-resolution x-ray spectra from stellar corona, x-ray binary stars, active galactic nuclei, and galaxy clusters. Managed by the Marshall Space Flight Center, the Astro-1 observatory was launched aboard the Space Shuttle Orbiter Columbia (STS-35) on December 2, 1990.

The Atacama Cosmology Telescope: Physical Properties and Purity of a Galaxy Cluster Sample Selected Via the Sunyaev-Zel'Dovich Effect

NASA Technical Reports Server (NTRS)

Menanteau, Felipe; Gonzalez, Jorge; Juin, Jean-Baptiste; Marriage, Tobias; Reese, Erik D.; Acquaviva, Viviana; Aguirre, Paula; Appel, John Willam; Baker, Andrew J.; Barrientos, L. Felipe;

Future Hard X-ray and Gamma-Ray Missions

NASA Astrophysics Data System (ADS)

Krawczynski, Henric; Physics of the Cosmos (PCOS) Gamma Ray Science Interest Group (GammaSIG) Team

2017-01-01

With four major NASA and ESA hard X-ray and gamma-ray missions in orbit (Swift, NuSTAR, INTEGRAL, and Fermi) hard X-ray and gamma-ray astronomy is making major contributions to our understanding of the cosmos. In this talk, I will summarize the current and upcoming activities of the Physics of the Cosmos Gamma Ray Science Interest Group and highlight a few of the future hard X-ray and gamma-ray mission discussed by the community. HK thanks NASA for the support through the awards NNX14AD19G and NNX16AC42G and for PCOS travel support.

ALMA 26 arcmin2 Survey of GOODS-S at One-millimeter (ASAGAO): X-Ray AGN Properties of Millimeter-selected Galaxies

NASA Astrophysics Data System (ADS)

Ueda, Y.; Hatsukade, B.; Kohno, K.; Yamaguchi, Y.; Tamura, Y.; Umehata, H.; Akiyama, M.; Ao, Y.; Aretxaga, I.; Caputi, K.; Dunlop, J. S.; Espada, D.; Fujimoto, S.; Hayatsu, N. H.; Imanishi, M.; Inoue, A. K.; Ivison, R. J.; Kodama, T.; Lee, M. M.; Matsuoka, K.; Miyaji, T.; Morokuma-Matsui, K.; Nagao, T.; Nakanishi, K.; Nyland, K.; Ohta, K.; Ouchi, M.; Rujopakarn, W.; Saito, T.; Tadaki, K.; Tanaka, I.; Taniguchi, Y.; Wang, T.; Wang, W.-H.; Yoshimura, Y.; Yun, M. S.

2018-01-01

We investigate the X-ray active galactic nucleus (AGN) properties of millimeter galaxies in the Great Observatories Origins Deep Survey South (GOODS-S) field detected with the Atacama Large Millimeter/submillimeter Array (ALMA), by utilizing the Chandra 7-Ms data, the deepest X-ray survey to date. Our millimeter galaxy sample comes from the ASAGAO survey covering 26 arcmin2 (12 sources at a 1.2 mm flux-density limit of ≈ 0.6 mJy), supplemented by the deeper but narrower 1.3 mm survey of a part of the ASAGAO field by Dunlop et al. Ofthe 25 total millimeter galaxies, 14 have Chandra counterparts. The observed AGN fractions at z=1.5{--}3 are found to be {90}-19+8% and {57}-25+23% for the ultra-luminous and luminous infrared galaxies with log {L}{IR}/{L}ȯ = 12–12.8 and log {L}{IR}/{L}ȯ = 11.5–12, respectively. The majority (∼2/3) of the ALMA and/or Herschel detected X-ray AGNs at z = 1.5‑3 appear to be star-formation-dominant populations, having {L}{{X}}/ {L}{IR} ratios smaller than the “simultaneous evolution” value expected from the local black-hole-mass-to-stellar-mass ({M}{BH}–M *) relation. On the basis of the {L}{{X}} and stellar mass relation, we infer that a large fraction of star-forming galaxies at z=1.5{--}3 have black hole masses that are smaller than those expected from the local {M}{BH}–M * relation. This contrasts previous reports on luminous AGNs at the same redshifts detected in wider and shallower surveys, which are subject to selection biases against lower luminosity AGNs. Our results are consistent with an evolutionary scenario in which star formation occurs first, and an AGN-dominant phase follows later, in objects that finally evolve into galaxies with classical bulges.

Evolution of the X-ray luminosity in young HII galaxies

NASA Astrophysics Data System (ADS)

Rosa González, D.; Terlevich, E.; Jiménez Bailón, E.; Terlevich, R.; Ranalli, P.; Comastri, A.; Laird, E.; Nandra, K.

2009-10-01

In an effort to understand the correlation between X-ray emission and present star formation rate, we obtained XMM-Newton data to estimate the X-ray luminosities of a sample of actively star-forming HII galaxies. The obtained X-ray luminosities are compared to other well-known tracers of star formation activity such as the far-infrared and the ultraviolet luminosities. We also compare the obtained results with empirical laws from the literature and with recently published analysis applying synthesis models. We use the time delay between the formation of the stellar cluster and that of the first X-ray binaries, in order to put limits on the age of a given stellar burst. We conclude that the generation of soft X-rays, as well as the Hα or infrared luminosities is instantaneous. The relation between the observed radio and hard X-ray luminosities, on the other hand, points to the existence of a time delay between the formation of the stellar cluster and the explosion of the first massive stars and the consequent formation of supernova (SN) remnants and high-mass X-ray binaries, which originate the radio and hard X-ray fluxes, respectively. When comparing hard X-rays with a star formation indicator that traces the first million years of evolution (e.g. Hα luminosities), we found a deficit in the expected X-ray luminosity. This deficit is not found when the X-ray luminosities are compared with infrared luminosities, a star formation tracer that represents an average over the last 108yr. The results support the hypothesis that hard X-rays are originated in X-ray binaries which, as SN remnants, have a formation time delay of a few mega years after the star-forming burst. Partially based on observations obtained with XMM-Newton, an ESA science mission with instruments and contributions directly funded by ESA Member States and NASA. E-mail: danrosa@inaoep.mx ‡ Visiting Fellow, IoA, Cambridge, UK.

Beta-glucosidase activity of ER-bodies in Arabidopsis thaliana seedlings under clinorotation and after X-ray irradiation

NASA Astrophysics Data System (ADS)

Romanchuk, Svitlana

Realization of long-term space flight requires the life support bioregenerative systems, an indispensable component of which are plants as a source of oxygen, water and food. Although it is well known now that plants adopt to spaceflight factors, in particular to microgravity, by changing some their patterns at the cellular, physiological, biochemical and molecular levels, many questions on cause and effect of these changes are still open. In addition, it is necessary to find the plant species which will be the most suited to the conditions in a space craft cabin. Plants of the family Brassicaceae are known to be resistant to a variety of abiotic stresses, including irradiation. Among them there are many cultivated plants with which we encounter every day: cabbage, radish, mustard, rapeseed, etc., and Arabidopsis thaliana - a convenient model object. The family Brassicaceae to be characterized by the presence of ER-bodies in plant cells, which are derivative of granular endoplasmic reticulum. Earlier, an enzyme beta-glucosidase (beta-D-glucoside glucohydrolase; EC 3.2.1.21) with an ER retention signal has been shown to accumulate selectively in such bodies in response to different unfavorable factors. Recently, we reported that formation of ER-bodies in A. thaliana seedling roots is sensitive to the clinorotation and X-ray irradiation, as their quantity and size in creased under the influence of these factors in comparison with control.begin{itemize} Therefore, we determined the beta-glucosidase activity in A. thaliana (line Columbia) seedlings grown in the stationary conditions and under clinorotation (a); and after X-ray irradiation (b): a) 3- and 7-day-old seedlings grown on a slow horizontal clinostat (2rpm); b) 3-day-old seedlings were treated with X-ray radiation dose of 0.5, 1.0, 2.0, 4.0, 6.0, 8.0, 10 and 12 Gray. For the first time, an increase in beta-glucosidase activity, which is the main component of the ER-bodies in A. thaliana seedlings, were found under clinorotation and after X-ray irradiation. The obtained data are discussed in the connection with concepts on the influence of clinorotation and X-ray irradiation on plant cell metabolism.

Spectral and Timing Investigations of Dwarf Novae Selected in Hard X-Rays

NASA Technical Reports Server (NTRS)

Thorstensen, John; Remillard, Ronald A.

2000-01-01

There are 9 dwarf novae (DN) among the 43 cataclysmic variables (accreting white dwarfs in close binary systems) that were detected during the HEAO-1 all-sky X-ray survey (1977-1979). On the other hand, there are roughly one hundred dwarf novae that are closer and/or optically brighter and yet they were not detected as hard X-ray sources. Two of the HEAO-1 DN show evidence for X-ray pulsations that imply strong magnetic fields on the white dwarf surface, and magnetic CVs are known to be strong X-ray sources. However, substantial flux in hard X-rays may be caused by non-magnetic effects, such as an optically thin boundary layer near a massive white dwarf. We proposed RXTE observations to measure plasma temperatures and to search for X-ray pulsations. The observations would distinguish whether these DN belong to one of (rare) magnetic subclasses. For those that do not show pulsations, the observations support efforts to define empirical relations between X-ray temperature, the accretion rate, and the mass of the white dwarf. The latter is determined via optical studies of the dynamics of the binary constituents.

High efficient photocatalytic selective oxidation of benzyl alcohol to benzaldehyde by solvothermal-synthesized ZnIn{sub 2}S{sub 4} microspheres under visible light irradiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, Zhixin, E-mail: czx@fzu.edu.cn; Instrumental Measurement and Analysis Center, Fuzhou University, Fuzhou 350002; Xu, Jingjing

Hexagonal ZnIn{sub 2}S{sub 4} samples have been synthesized by a solvothermal method. Their properties have been determined by X-ray diffraction, ultraviolet–visible-light diffuse reflectance spectra, field emission scanning electron microscopy, nitrogen adsorption–desorption and X-ray photoelectron spectra. These results demonstrate that ethanol solvent has significant influence on the morphology, optical and electronic nature for such marigold-like ZnIn{sub 2}S{sub 4} microspheres. The visible light photocatalytic activities of the ZnIn{sub 2}S{sub 4} have been evaluated by selective oxidation of benzyl alcohol to benzaldehyde using molecular oxygen as oxidant. The results show that 100% conversion along with >99% selectivity are reached over ZnIn{sub 2}S{sub 4}more » prepared in ethanol solvent under visible light irradiation (λ>420 nm) of 2 h, but only 58% conversion and 57% yield are reached over ZnIn{sub 2}S{sub 4} prepared in aqueous solvent. A possible mechanism of the high photocatalytic activity for selective oxidation of benzyl alcohol over ZnIn{sub 2}S{sub 4} is proposed and discussed. - Graphical abstract: Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a solvothermal method. The high visible photocatalytic activities of ZnIn{sub 2}S{sub 4} were evaluated by selective oxidation of benzyl alcohol to benzaldehyde under mild conditions. Display Omitted - Highlights: • Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a solvothermal method. • The solvents have a remarkably influence on the morphology and properties of samples. • It is the first time to apply ZnIn{sub 2}S{sub 4} for selective oxidation of benzyl alcohol. • ZnIn{sub 2}S{sub 4} shows high photocatalytic activity for selective oxidation of benzyl alcohol.« less

Obscuration-dependent Evolution of Active Galactic Nuclei

NASA Astrophysics Data System (ADS)

Buchner, Johannes; Georgakakis, Antonis; Nandra, Kirpal; Brightman, Murray; Menzel, Marie-Luise; Liu, Zhu; Hsu, Li-Ting; Salvato, Mara; Rangel, Cyprian; Aird, James; Merloni, Andrea; Ross, Nicholas

2015-04-01

We aim to constrain the evolution of active galactic nuclei (AGNs) as a function of obscuration using an X-ray-selected sample of ~2000 AGNs from a multi-tiered survey including the CDFS, AEGIS-XD, COSMOS, and XMM-XXL fields. The spectra of individual X-ray sources are analyzed using a Bayesian methodology with a physically realistic model to infer the posterior distribution of the hydrogen column density and intrinsic X-ray luminosity. We develop a novel non-parametric method that allows us to robustly infer the distribution of the AGN population in X-ray luminosity, redshift, and obscuring column density, relying only on minimal smoothness assumptions. Our analysis properly incorporates uncertainties from low count spectra, photometric redshift measurements, association incompleteness, and the limited sample size. We find that obscured AGNs with N H > 1022 cm-2 account for {77}+4-5% of the number density and luminosity density of the accretion supermassive black hole population with L X > 1043 erg s-1, averaged over cosmic time. Compton-thick AGNs account for approximately half the number and luminosity density of the obscured population, and {38}+8-7% of the total. We also find evidence that the evolution is obscuration dependent, with the strongest evolution around N H ≈ 1023 cm-2. We highlight this by measuring the obscured fraction in Compton-thin AGNs, which increases toward z ~ 3, where it is 25% higher than the local value. In contrast, the fraction of Compton-thick AGNs is consistent with being constant at ≈35%, independent of redshift and accretion luminosity. We discuss our findings in the context of existing models and conclude that the observed evolution is, to first order, a side effect of anti-hierarchical growth.

BAT AGN Spectroscopic Survey (BASS) - VI. The ΓX-L/LEdd relation

NASA Astrophysics Data System (ADS)

Trakhtenbrot, Benny; Ricci, Claudio; Koss, Michael J.; Schawinski, Kevin; Mushotzky, Richard; Ueda, Yoshihiro; Veilleux, Sylvain; Lamperti, Isabella; Oh, Kyuseok; Treister, Ezequiel; Stern, Daniel; Harrison, Fiona; Baloković, Mislav; Gehrels, Neil

2017-09-01

We study the relation between accretion rate (in terms of L/LEdd) and shape of the hard X-ray spectral energy distribution (namely the photon index Γx) for a large sample of 228 hard X-ray-selected, low-redshift active galactic nuclei (AGNs), drawn from the Swift/BAT AGN Spectroscopic Survey (BASS). This includes 30 AGNs for which black hole mass (and therefore L/LEdd) is measured directly through masers, spatially resolved gas or stellar dynamics, or reverberation mapping. The high-quality and broad energy coverage of the data provided through BASS allow us to examine several alternative determinations of both Γx and L/LEdd. For the BASS sample as a whole, we find a statistically significant, albeit very weak correlation between Γx and L/LEdd. The best-fitting relations we find, Γx ≃ 0.15 log L/LEdd + const., are considerably shallower than those reported in previous studies. Moreover, we find no corresponding correlations among the subsets of AGN with different MBH determination methodology. In particular, we find no robust evidence for a correlation when considering only those AGN with direct or single-epoch MBH estimates. This latter finding is in contrast to several previous studies which focused on z > 0.5 broad-line AGN. We discuss this tension and conclude that it can be partially accounted for if one adopts a simplified, power-law X-ray spectral model, combined with L/LEdd estimates that are based on the continuum emission and on single-epoch broad-line spectroscopy in the optical regime. We finally highlight the limitations on using Γx as a probe of supermassive black hole evolution in deep extragalactic X-ray surveys.

Eclipse and Collapse of the Colliding Wind X-ray Emission from Eta Carinae

NASA Technical Reports Server (NTRS)

Hamaguchi, Kenji; Corcoran, Michael F.

2012-01-01

X-ray emission from the massive stellar binary system, Eta Carinae, drops strongly around periastron passage; the event is called the X-ray minimum. We launched a focused observing campaign in early 2009 to understand the mechanism of causing the X-ray minimum. During the campaign, hard X-ray emission (<10 keV) from Eta Carinae declined as in the previous minimum, though it recovered a month earlier. Extremely hard X-ray emission between 15-25 keV, closely monitored for the first time with the Suzaku HXD/PIN, decreased similarly to the hard X-rays, but it reached minimum only after hard X-ray emission from the star had already began to recover. This indicates that the X-ray minimum is produced by two composite mechanisms: the thick primary wind first obscured the hard, 2-10 keV thermal X-ray emission from the wind-wind collision (WWC) plasma; the WWC activity then decays as the two stars reach periastron.

Frontiers of X-Ray Astronomy

NASA Astrophysics Data System (ADS)

Fabian, Andrew C.; Pounds, Kenneth A.; Blandford, Roger D.

2004-07-01

Preface; 1. Forty years on from Aerobee 150: a personal perspective K. Pounds; 2. X-ray spectroscopy of astrophysical plasmas S. M. Kahn, E. Behar, A. Kinkhabwala and D. W. Savin; 3. X-rays from stars M. Gudel; 4. X-ray observations of accreting white-dwarf systems M. Cropper, G. Ramsay, C. Hellier, K. Mukai, C. Mauche and D. Pandel; 5. Accretion flows in X-ray binaries C. Done; 6. Recent X-ray observations of supernova remnants C. R. Canizares; 7. Luminous X-ray sources in spiral and star-forming galaxies M. Ward; 8. Cosmological constraints from Chandra observations of galaxy clusters S. W. Allen; 9. Clusters of galaxies: a cosmological probe R. Mushotzky; 10. Obscured active galactic nuclei: the hidden side of the X-ray Universe G. Matt; 11. The Chandra Deep Field-North Survey and the cosmic X-ray background W. N. Brandt, D. M. Alexander, F. E. Bauer and A. E. Hornschemeier; 12. Hunting the first black holes G. Hasinger; 13. X-ray astronomy in the new millennium: a summary R. D. Blandford.

Experimental and computational assessment of mycosynthesized CdO nanoparticles towards biomedical applications.

PubMed

S, Gowri; K, Gopinath; A, Arumugam

2018-03-01

The present study reports the biogenic synthesis of Cadmium Oxide Nanoparticles (CdO NPs) using plant pathogenic fungus Nigrospora oryzae culture filtrate. Further, the effect of the NPs on the cancer cell line (HeLa) is explored. The sample was characterized using Thermogravimetric/Differential Thermal (TG/DTA), Powder X-ray Diffraction (XRD), X-ray Photoelectron spectroscopy (XPS), UV-Visible Diffuse Reflectance Spectroscopy (UV-DRS), Field Emission Transmission Electron Microscopy (FE-SEM) with Energy Dispersive X-ray Spectroscopy (EDX), High Resolution Transmission Electron Microscopy (HR-TEM) and Selected Area Electron Diffraction (SAED) analysis. Antibacterial activity was evaluated against both Gram positive and Gram negative bacterial strains and it showed maximum activity against Proteus vulgaris. The larvicidal activity was performed to evaluate the maximum ability of synthesized CdO NPs against Anopheles stephensi. Subsequently, MTT assay also depicted the dose-dependent anticancer activity of CdO NPs against cancer cell line (HeLa). Additionally, the inhibitory effect of CdO NPs was analyzed through extensive docking with cancerous protein agent. Results enlighten that Transketolase protein exhibited high docking score of -4.8 k/mol with H-bond interactions found with Lys75 and Asn185 amino acid residues. DFT study was performed on CdO to understand the charge transfer reaction for the inhibitory mechanism. Convincingly, this study explores the understanding of CdO NPs against HeLa cells. Copyright © 2018. Published by Elsevier B.V.

Multispectral variable magnification glancing incidence x ray telescope

NASA Technical Reports Server (NTRS)

Hoover, Richard B. (Inventor)

1992-01-01

A multispectral, variable magnification, glancing incidence, x-ray telescope capable of broadband, high resolution imaging of solar and stellar x-ray and extreme ultraviolet radiation sources is discussed. The telescope includes a primary optical system which focuses the incoming radiation to a primary focus. Two or more rotatable mirror carriers, each providing a different magnification, are positioned behind the primary focus at an inclination to the optical axis. Each carrier has a series of ellipsoidal mirrors, and each mirror has a concave surface covered with a multilayer (layered synthetic microstructure) coating to reflect a different desired wavelength. The mirrors of both carriers are segments of ellipsoids having a common first focus coincident with the primary focus. A detector such as an x-ray sensitive photographic film is positioned at the second respective focus of each mirror so that each mirror may reflect the image at the first focus to the detector at the second focus. The carriers are selectively rotated to position a selected mirror for receiving radiation from the primary optical system, and at least the first carrier may be withdrawn from the path of the radiation to permit a selected mirror on the second carrier to receive the radiation.

A Potential Waste to be Selected as Media for Metal and Nutrient Removal

NASA Astrophysics Data System (ADS)

Zayadi, N.; Othman, N.; Hamdan, R.

2016-07-01

This study describes the potential of application of cassava peel, banana peel, coconut shell, and coconut coir to be selected as metal removal while limestone and steel slag for nutrient removal. The media were characterized by X-Ray Fluorescence (XRF), Fourier Transform Infrared (FTIR), Field Emission Scanning Electron Microscopy-Energy Dispersive X-Ray (FESEM-EDX), and X-Ray Powder Diffraction (XRD). The results of XRF analysis medias show the present of calcium oxide, CaO which confirm the high efficiency in adsorbing metal ions and nutrient which is in agreement with the result of XRD. The characteristics of medias by FTIR analysis also confirmed the involvement of alcohol, carboxylic, alkanes, amines and ethers which play important role to reduce ions while FESEM-EDX indicates the porous structures of study medias. The characterization analysis highlight that cassava peel and steel slag were selected as a potential media in this study.