The Dual Antimelanogenic and Antioxidant Activities of the Essential Oil Extracted from the Leaves of Acorus macrospadiceus (Yamamoto) F. N. Wei et Y. K. Li

PubMed Central

Huang, Huey-Chun; Wang, Hsiao-Fen; Yih, Kuang-Hway; Chang, Long-Zen; Chang, Tsong-Min

2012-01-01

The antimelanogenic and antioxidant activities of the essential oil extracted from the leaves of Acorus macrospadiceus (Yamamoto) F. N. Wei et Y. K. Li have never been explored. The essential oil effectively inhibited mushroom tyrosinase activity (EC50 = 1.57 mg/mL) and B16F10 tyrosinase activity (IC50 = 1.01 mg/mL), decreased the melanin content (EC50 = 1.04 mg/mL), and depleted the cellular level of the reactive oxygen species (ROS) (EC50 = 1.87 mg/mL). The essential oil effectively scavenged 2,2-diphenyl-1-picryl-hydrazyl (DPPH) (EC50 = 0.121 mg/mL) and 2,2′-azino-bis (3-ethylbenzthiazoline-6-sulphonic acid) ABTS+ radicals (EC50 = 0.122 mg/mL). It also exhibited an apparent reducing power (EC50 = 0.021 mg/mL) and metal-ion chelating activity (EC50 = 0.029 mg/mL). The chemical constituents of the essential oil are ethers (55.73%), ketones (19.57%), monoterpenes (7.82%), alcohols (3.85%), esters (3.77%), sesquiterpenes (3.72%), and aromatic compounds (2.85%). The results confirm that A. macrospadiceus essential oil is a natural antioxidant and inhibitor of melanogenesis. PMID:23304214

Effects of simulated warming on soil respiration to XiaoPo lake

NASA Astrophysics Data System (ADS)

Zhao, Shuangkai; Chen, Kelong; Wu, Chengyong; Mao, Yahui

2018-02-01

The main flux of carbon cycling in terrestrial and atmospheric ecosystems is soil respiration, and soil respiration is one of the main ways of soil carbon output. This is of great significance to explore the dynamic changes of soil respiration rate and its effect on temperature rise, and the correlation between environmental factors and soil respiration. In this study, we used the open soil carbon flux measurement system (LI-8100, LI-COR, NE) in the experimental area of the XiaoPo Lake wetland in the Qinghai Lake Basin, and the Kobresia (Rs) were measured, and the soil respiration was simulated by simulated temperature (OTC) and natural state. The results showed that the temperature of 5 cm soil was 1.37 °C higher than that of the control during the experiment, and the effect of warming was obvious. The respiration rate of soil under warming and natural conditions showed obvious diurnal variation and monthly variation. The effect of warming on soil respiration rate was promoted and the effect of precipitation on soil respiration rate was inhibited. Further studies have shown that the relationship between soil respiration and 5 cm soil temperature under the control and warming treatments can be described by the exponential equation, and the correlation analysis between the two plots shows a very significant exponential relationship (p < 0.001). The warming treatment not only increased the Q10 value of soil respiration rate, but also increased the sensitivity of soil respiration rate. The relationship between soil respiration and soil moisture can be explained by the quadratic linear equation (p < 0.05). It can be concluded that under the condition of sufficient rainfall, the soil temperature is the main influencing factor of soil respiration in this region.

One new species of Amphinemura and description of the female of A. ancistroidea Li & Yang (Plecoptera: Nemouridae) from Guangxi Zhuang Autonomous Region of southern China.

PubMed

Mo, Raorao; Yang, Ding; Wang, Guoquan; Li, Weihai

2017-06-11

A new nemourid species, Amphinemura yao sp. nov. is described from the Daoyao Mountains of Guangxi Zhuang Autonomous Region of southern China. Amphinemura ancistroidea Li & Yang, 2007 is newly recorded from Guangxi and the female is described for the first time including the internal vaginal complex. The new species is compared with related taxa.

Peer review statement

NASA Astrophysics Data System (ADS)

2012-11-01

All papers published in this volume of Journal of Physics: Conference Series have been peer reviewed through processes administered by the editors of the 26th IAHR Symposium on Hydraulic Machinery and Systems proceedings. Reviews were conducted by expert referees from the International Technical Committee to the professional and scientific standards expected of a proceedings journal published by IOP Publishing. The members of the Scientific Committee who selected and reviewed the papers included in the Proceedings of the 26th IAHR Symposium on Hydraulic Machinery and Systems are: Yulin WU Tsinghua University China François AVELLAN EPFL-LMH Switzerland (principal) Xingqi LUO Xi'an University of Sci & Tech China Martin BÖHLE Kaiserslautern University Germany Gerard BOIS Arts et Métiers ParisTech France Luca D'AGOSTINO University of Pisa Italy Eduard EGUSQUIZA Polytechnical University Catalonia Spain Richard FISHER Voith Hydro Inc USA Regiane FORTES-PATELLA Institute Polytechnique de Grenoble France Aleksandar GAJIC University of Belgrade Serbia Wei YANG China Agriculture University China YinLu YOUNG University of Michigan USA Adrian LUNGU Dunarea de Jos University of Galati Romania Arpad FAY University of Miskolcz Hungary José GONZÁLEZ Universidad de Oviedo Spain Baoshan ZHU Tsinghua University China Hongxun CHEN Shanghai University China Chisachi KATO University of Tokyo Japan Zhenyue MA Dalian University of Sci & Tech China Honggang FAN Tsinghua University China François GUIBAULT Ecole Polytechnique de Montreal Canada Pengcheng GUO Xian University of Technology China Leqing WANG Zhejiang University China Toshiaki IKOHAGI Tohoku University Japan Jiandong YANG Wuhan University China Jianzhong ZHOU Huazhong University of Sci & Tech China Jinwei LI NULL China Rennian LI Lanzhou University of Sci & Tech China Houlin LIU NULL China Juan LIU Tsinghua University China Shuhong LIU Tsinghua University China Xianwu LUO Tsinghua University China Michihiro NISHI Tsinghua

Analysis of temporal and spatial trends of hydro-climatic variables in the Wei River Basin.

PubMed

Zhao, Jing; Huang, Qiang; Chang, Jianxia; Liu, Dengfeng; Huang, Shengzhi; Shi, Xiaoyu

2015-05-01

The Wei River is the largest tributary of the Yellow River in China. The relationship between runoff and precipitation in the Wei River Basin has been changed due to the changing climate and increasingly intensified human activities. In this paper, we determine abrupt changes in hydro-climatic variables and identify the main driving factors for the changes in the Wei River Basin. The nature of the changes is analysed based on data collected at twenty-one weather stations and five hydrological stations in the period of 1960-2010. The sequential Mann-Kendall test analysis is used to capture temporal trends and abrupt changes in the five sub-catchments of the Wei River Basin. A non-parametric trend test at the basin scale for annual data shows a decreasing trend of precipitation and runoff over the past fifty-one years. The temperature exhibits an increase trend in the entire period. The potential evaporation was calculated based on the Penman-Monteith equation, presenting an increasing trend of evaporation since 1990. The stations with a significant decreasing trend in annual runoff mainly are located in the west of the Wei River primarily interfered by human activities. Regression analysis indicates that human activity was possibly the main cause of the decline of runoff after 1970. Copyright © 2015. Published by Elsevier Inc.

Silica-volatile interaction and the geological cause of the Xuan Wei lung cancer epidemic

DOE Office of Scientific and Technical Information (OSTI.GOV)

David J. Large; Shona Kelly; Baruch Spiro

2009-12-01

Parts of Xuan Wei County, Yunnan Province, China have the highest known lung cancer mortality in nonsmoking women. This high mortality displays a clear spatial relationship to the mines producing coal from the uppermost Permian. Geochemical, petrographic, and grain size analyses were undertaken on a set of coal samples from Xuan Wei. Results demonstrate that the single geochemical property that makes this coal unusual is its high concentration of quartz (13.5 wt %) of which 35-55% occurs as < 10 {mu}m grains. We propose the potential for silica-volatile interaction (PSVI) as a new method for assessing the combined influence ofmore » silica and volatile organic matter and use this as a basis for re-evaluating existing ecological data. Published lung cancer mortality values are more strongly correlated with PSVI values for Xuan Wei coal than with volatiles or silica alone and the PSVI values measured are distinct from those of other coals. Finally we propose that the localization of this epidemic to Xuan Wei results from enhanced weathering of the local Emeishan basalts as a consequence of geochemical perturbations at the Permo-Triassic Boundary.« less

The epidemiology of lung cancer in Xuan Wei, China: current progress, issues, and research strategies.

PubMed

Chapman, R S; Mumford, J L; Harris, D B; He, Z Z; Jiang, W Z; Yang, R D

1988-01-01

In Xuan Wei, a rural Chinese county of about one million people, females' annual lung cancer mortality is China's highest, and males' is among China's highest. Xuan Wei's very high indoor air pollution levels (sometimes exceeding 20 mg/m3), residentially stable population, relatively uncomplicated lifestyle, and wide geographic variation in lung cancer mortality render it highly amenable to quantitative, interdisciplinary investigation of chemical carcinogens due to indoor air pollution. To date, epidemiologic findings reveal a closer association of lung cancer with the indoor burning of "smoky" coal (as opposed to "smokeless" coal or wood) than with tobacco use or occupation. Current aerometric, chemical, and toxicologic findings tend to confirm this association, though the specific carcinogenic constituents of Xuan Wei indoor air pollution have not yet been determined. Chinese and American investigators are conducting interdisciplinary field and laboratory investigations to quantify the lung cancer risk attendant on indoor air pollution relative to other factors, to measure and compare the characteristics of pollution from different Xuan Wei fuels, to determine the relative etiologic importance of pollution composition and concentration, and to develop quantitative relationships between air pollution dose and lung cancer risk.

Dynamic monitoring of blood-brain barrier integrity using water exchange index (WEI) during mannitol and CO2 challenges in mouse brain.

PubMed

Huang, Shuning; Farrar, Christian T; Dai, Guangping; Kwon, Seon Joo; Bogdanov, Alexei A; Rosen, Bruce R; Kim, Young R

2013-04-01

The integrity of the blood-brain barrier (BBB) is critical to normal brain function. Traditional techniques for the assessment of BBB disruption rely heavily on the spatiotemporal analysis of extravasating contrast agents. However, such methods based on the leakage of relatively large molecules are not suitable for the detection of subtle BBB impairment or for the performance of repeated measurements in a short time frame. Quantification of the water exchange rate constant (WER) across the BBB using strictly intravascular contrast agents could provide a much more sensitive method for the quantification of the BBB integrity. To estimate WER, we have recently devised a powerful new method using a water exchange index (WEI) biomarker and demonstrated BBB disruption in an acute stroke model. Here, we confirm that WEI is sensitive to even very subtle changes in the integrity of the BBB caused by: (i) systemic hypercapnia and (ii) low doses of a hyperosmolar solution. In addition, we have examined the sensitivity and accuracy of WEI as a biomarker of WER using computer simulation. In particular, the dependence of the WEI-WER relation on changes in vascular blood volume, T1 relaxation of cellular magnetization and transcytolemmal water exchange was explored. Simulated WEI was found to vary linearly with WER for typically encountered exchange rate constants (1-4 Hz), regardless of the blood volume. However, for very high WER (>5 Hz), WEI became progressively more insensitive to increasing WER. The incorporation of transcytolemmal water exchange, using a three-compartment tissue model, helped to extend the linear WEI regime to slightly higher WER, but had no significant effect for most physiologically important WERs (WER < 4 Hz). Variation in cellular T1 had no effect on WEI. Using both theoretical and experimental approaches, our study validates the utility of the WEI biomarker for the monitoring of BBB integrity. Copyright © 2012 John Wiley & Sons, Ltd.

Dynamic Monitoring of Blood-Brain Barrier Integrity using Water Exchange Index (WEI) During Mannitol and CO2 Challenges in Mouse Brain

PubMed Central

Huang, Shuning; Farrar, Christian T.; Dai, Guangping; Kwon, Seon Joo; Bogdanov, Alexei A.; Rosen, Bruce R.; Kim, Young R.

2012-01-01

The integrity of the blood-brain barrier (BBB) is critical to normal brain function. Traditional techniques for assessing BBB disruption rely heavily on the spatiotemporal analysis of extravasating contrast agents. But such methods based on the leakage of relatively large molecules are not suitable to detect subtle BBB impairment or to perform repeated measurements in a short time frame. Quantification of the water exchange rate constant (WER) across the BBB using strictly intravascular contrast agents could provide a much more sensitive method for quantifying the BBB integrity. For estimating the WER, we have recently devised a powerful new method using a water exchange index (WEI) biomarker and demonstrated BBB disruption in an acute stroke model. Here we confirm that the WEI is sensitive to even very subtle changes in the integrity of the BBB caused by (1) systemic hypercapnia and (2) low doses of a hyperosmolar solution. In addition, we have examined the sensitivity and accuracy of the WEI as a biomarker of the WER using computer simulation. In particular, the dependence of the WEI-WER relation on changes in vascular blood volume, T1 relaxation of cellular magnetization, and transcytolemmal water exchange was explored. The simulated WEI was found to vary linearly with the WER for typically encountered exchange rate constants (1–4 Hz) regardless of the blood volume. However, for very high WER (>5 Hz) the WEI became progressively more insensitive to increasing WER. The incorporation of transcytolemmal water exchange, using a three-compartment tissue model, helped to extend the linear WEI regime to slightly higher WER, but had no significant effect for most physiologically important water exchange rate constants (WER<4 Hz). Variation in the cellular T1 had no effect on the WEI. Using both theoretical and experimental approaches, our study validates the utility of the WEI biomarker for monitoring BBB integrity. PMID:23055278

[Clinical efficacy of special effect san xiao decoction on type 2 diabetes mellitus].

PubMed

Li, Zhi-Qiang; Chang, Hong-Juan; Sang, Wen-Feng

2013-01-01

To investigate the clinical efficacies of the special effect San Xiao decoction on type 2 diabetes mellitus and its impact on inflammatory factors. 116 patients with type 2 diabetes mellitus were randomly divided into control group and observation group from Aug. 2010 to Aug. 2012, and each group had 58 cases. Both of the two groups were given the conventional basic treatment and 0.5 g/time, oral, 2 times/d of metformin. The observation group was received 1 dose/d of special effect San Xiao decoction on the basis of the basic treatment, and the treatment course was 12 weeks. The fasting blood glucose (FBG), 2h postprandial blood glucose (PBG), glycosylated hemoglobin (HbA1c), tumor necrosis factor-alpha (TNF-alpha), interleukin-6 ( IL-6) and c-reactive protein (CRP) were observed after the treatment. The FBG, PBG, HbA1c and insulin sensitive index (ISI) of the observation group were better than those of the control group (P < 0.05 or P < 0.01); BMI and body weight of the observation group were lower than those of the control group (P < 0.05); The blood sugar control effect of the observation group was better than that of the control group (P < 0.05); The hypoglycemia incidence of the observation group was lower than that of the control group (P < 0.01); TNF-alpha, IL-6 and CRP of the observation group were lower than those of the control group (P < 0.01). The clinical efficacy of the special effect San Xiao decoction on type 2 diabetes mellitus is significant, it has the role of alleviating inflammatory response for diabetes and it also has less adverse reactions, which is worth to be applied in clinical.

Nanocomposite Electrodes for Advanced Lithium Batteries: The LiFePO4 Cathode

DTIC Science & Technology

2001-11-01

The LiFePO4 Cathode DISTRIBUTION: Approved for public release, distribution unlimited This paper is part of the following report: TITLE: Nanophase and...Nanocomposite Electrodes for Advanced Lithium Batteries: The LiFePO4 Cathode Shoufeng Yang, Yanning Song, Peter Y. Zavalij and M. Stanley Whittingham...Institute for Materials Research, Binghamton University, Binghamton, NY 13902-1600, U.S.A. ABSTRACT LiFePO4 was successfully synthesized by high temperature

[A Study on the quotations in the Wu xing da yi (The Gist of Five Phases) cited from Nei jing (Inner Canon)].

PubMed

Wang, Zheng-Shan; Zhang, Qi-Cheng

2013-07-01

In the Wu xing da yi (The Gist of Five Phases), written by Xiao Ji of the Sui Dynasty, there were 9 quotations cited from Huang di nei jing (Inner Canon of Huangdi). By comparison with current version of Huang di nei jing, most of the descriptions are similar, yet still with some differences, such as yin-yang nature of the five zang visceras, the liver being the root of "pi ji", the spleen being the root of "cang lin" etc. Wu xing da yi epitomizes the books about yin-yang and five phases before the Sui Dynasty, while Xiao Ji's quotations from Huang di nei jing interpreted from the views of yin-yang and five phases, are different from the annotations of later ages.

Anxiolytic and neuroprotective effects of the Traditional Chinese Medicinal formulation Dan-zhi-xiao-yao-san in a rat model of chronic stress.

PubMed

Cao, Guo-Ping; Gui, Dan; Fu, Lu-Di; Guo, Zhou-Ke; Fu, Wen-Jun

2016-08-01

Dan-zhi-xiao-yao-san is a Traditional Chinese Medicinal formulation widely used for the treatment of neuropsychological disorders. The present study examined the anxiolytic and neuroprotective effects of Dan-zhi-xiao-yao-san in a rat model of chronic stress. The results of an elevated plus maze test showed that Dan‑zhi‑xiao‑yao‑san significantly attenuated the levels of anxiety-induced stress as evidenced by increases in the time spent in the open arm region, as well as the percentage of entries into this area. In addition, Dan-zhi-xiao-yao-san alleviated stress‑induced neuronal death, as indicated by histological examination. Furthermore, mechanistic studies suggested that the anxiolytic and neuroprotective effects of Dan-zhi-xiao-yao-san may be mediated via attenuation of chronic stress‑induced upregulation of α‑synuclein and corticosterone, and downregulation of protein phosphatase 2A (PP2A) in the hippocampal region of the brain at the mRNA and protein level. In addition, Dan‑zhi‑xiao‑yao‑san decreased the serum levels of stress‑induced corticosterone in the model animals. In conclusion, the present study demonstrated that Dan‑zhi‑xiao‑yao‑san exerted anxiolytic and neuroprotective effects in a rat model of chronic stress via attenuation of stress‑induced upregulation of α‑synuclein and corticosterone, and downregulation of PP2A in the hippocampus.

Using the WEIS-SR to evaluate employee perceptions of their college work environment.

PubMed

Dorsey, Julie; Kaye, Miranda; Barratt, Jennifer; Biondi, Jennifer; Habrial, Amanda; Lane, Amanda; Marinelli, Victoria; Paulino, Tiffany; Singletary, Amanda

2016-04-06

Colleges have been experiencing reduced resource allocations, shifting student expectations, and organizational change. These changes increase employee stress at all levels. Ensuring that employee needs are being met and promoting a healthy and productive workforce has never been more important. To investigate employees' current perceptions of their work environments using the Work Environment Impact Scale-Self Rating (WEIS-SR). Full and part time employees on a small college campus in the United States were surveyed using the WEIS-SR through an online survey program to protect their anonymity. Perception of staffing levels, workplace support for a healthy lifestyle, number of supervisors, and personal health ratings contributed to employee perceptions of their work environment. There were also differences between staff, administration, and tenured and non-tenured faculty. From an occupational performance perspective, valuable information on employees' levels of volition, performance capacity and habituation, and perceptions of their physical and social environment in relation to their work environments was obtained. Further support for the use of the WEIS-SR and psychometric properties of the instrument (reliability and validity) was obtained.

Simulation of blue and green water resources in the Wei River basin, China

NASA Astrophysics Data System (ADS)

Xu, Z.; Zuo, D.

2014-09-01

The Wei River is the largest tributary of the Yellow River in China and it is suffering from water scarcity and water pollution. In order to quantify the amount of water resources in the study area, a hydrological modelling approach was applied by using SWAT (Soil and Water Assessment Tool), calibrated and validated with SUFI-2 (Sequential Uncertainty Fitting program) based on river discharge in the Wei River basin (WRB). Sensitivity and uncertainty analyses were also performed to improve the model performance. Water resources components of blue water flow, green water flow and green water storage were estimated at the HRU (Hydrological Response Unit) scales. Water resources in HRUs were also aggregated to sub-basins, river catchments, and then city/region scales for further analysis. The results showed that most parts of the WRB experienced a decrease in blue water resources between the 1960s and 2000s, with a minimum value in the 1990s. The decrease is particularly significant in the most southern part of the WRB (Guanzhong Plain), one of the most important grain production basements in China. Variations of green water flow and green water storage were relatively small on the spatial and temporal dimensions. This study provides strategic information for optimal utilization of water resources and planning of cultivating seasons in the Wei River basin.

Weiße und Braune Zwerge zeigen sich unwirtlich

NASA Astrophysics Data System (ADS)

Heller, René

2013-02-01

Mehr als 850 Exoplaneten haben Astronomen seit dem Jahr 1992 nachgewiesen. Die meisten von ihnen umkreisen normale Hauptreihensterne, aber es wurden auch Trabanten im Umlauf um Braune oder Weiße Zwerge aufgespürt. Nun haben Rory Barnes von der University of Washington in Seattle und René Heller am Leibniz-Institut für Astrophysik Potsdam die Bewohnbarkeit möglicher Planeten um solche Objekte untersucht und dabei festgestellt, dass sie für Leben, wie wir es kennen, ungeeignet sind.

Renewable Energy in China: Xiao Qing Dao Village Power Wind/Diesel Hybrid Pilot Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

2006-01-01

In 2000, DOE/NREL and the State Power Corporation of China (SPCC) developed a pilot project to electrify Xiao Qing Dao, a small island located in China's Yellow Sea. The project demonstrates the practicality of renewable energy systems for medium-scale, off-grid applications. It consists of four 10 k-W wind turbines connected to a 30-kW diesel generator, a 40-kW inverter and a battery bank.

Systematic chemical profiling of a multicomponent Chinese herbal formula Huo Luo Xiao Ling Dan by ultra high performance liquid chromatography coupled with electrospray ionization quadrupoletime-of-flight mass spectrometry.

PubMed

Wang, Fenrong; Ai, Yu; Wu, Yun; Ma, Wen; Bian, Qiaoxia; Lee, David Y-W; Dai, Ronghua

2015-03-01

Huo Luo Xiao Ling Dan, a Chinese herbal formula consisting of 11 different herbs, has been used in folk medicine for the treatment of arthritis and other chronic inflammatory diseases. However, the chemical compositions of Huo Luo Xiao Ling Dan are not completely characterized. In the present study, an ultra high performance liquid chromatography coupled with electrospray ionization quadrupole time-of-flight mass spectrometry method in positive and negative ion modes was employed to identify biochemical constitutes in Huo Luo Xiao Ling Dan. As a result, a total of 76 compounds including alkaloids, monoterpene glycosides, iridoids, phenolic acids, and tanshinones, coumarins, lactones, flavones, and their glycosides, triterpenes, and triterpene saponins were characterized by comparing the retention time and mass spectrometry data with reference standards within 5 ppm error or by reference to the reference literature. These results would provide the basis for a further in vivo study of Huo Luo Xiao Ling Dan and information for potential new drug candidates for treating arthritis and other chronic inflammatory diseases. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

An ecological compensation standard based on emergy theory for the Xiao Honghe River Basin.

PubMed

Guan, Xinjian; Chen, Moyu; Hu, Caihong

2015-01-01

The calculation of an ecological compensation standard is an important, but also difficult aspect of current ecological compensation research. In this paper, the factors affecting the ecological-economic system in the Xiao Honghe River Basin, China, including the flow of energy, materials, and money, were calculated using the emergy analysis method. A consideration of the relationships between the ecological-economic value of water resources and ecological compensation allowed the ecological-economic value to be calculated. On this basis, the amount of water needed for dilution was used to develop a calculation model for the ecological compensation standard of the basin. Using the Xiao Honghe River Basin as an example, the value of water resources and the ecological compensation standard were calculated using this model according to the emission levels of the main pollutant in the basin, chemical oxygen demand. The compensation standards calculated for the research areas in Xipin, Shangcai, Pingyu, and Xincai were 34.91 yuan/m3, 32.97 yuan/m3, 35.99 yuan/m3, and 34.70 yuan/m3, respectively, and such research output would help to generate and support new approaches to the long-term ecological protection of the basin and improvement of the ecological compensation system.

Concurrent administration of anticancer chemotherapy drug and herbal medicine on the perspective of pharmacokinetics.

PubMed

Cheng, Yung-Yi; Hsieh, Chen-Hsi; Tsai, Tung-Hu

2018-04-01

With an increasing number of cancer patients seeking an improved quality of life, complementary and alternative therapies are becoming more common ways to achieve such improvements. The potential risks of concurrent administration are serious and must be addressed. However, comprehensive evidence for the risks and benefits of combining anticancer drugs with traditional herbs is rare. Pharmacokinetic investigations are an efficient way to understand the influence of concomitant remedies. Therefore, this study aimed to collect the results of pharmacokinetic studies relating to the concurrent use of cancer chemotherapy and complementary and alternative therapies. According to the National Health Insurance (NHI) database in Taiwan and several publications, the three most commonly prescribed formulations for cancer patients are Xiang-Sha-Liu-Jun-Zi-Tang, Jia-Wei-Xiao-Yao-San and Bu-Zhong-Yi-Qi-Tang. The three most commonly prescribed single herbs for cancer patients are Hedyotis diffusa, Scutellaria barbata, and Astragalus membranaceus. Few studies have discussed herb-drug interactions involving these herbs from a pharmacokinetics perspective. Here, we reviewed Jia-Wei-Xiao-Yao-San, Long-Dan-Xie-Gan-Tang, Curcuma longa and milk thistle to provide information based on pharmacokinetic evidence for healthcare professionals to use in educating patients about the risks of the concomitant use of various remedies. Copyright © 2018. Published by Elsevier B.V.

Changes in the long-term hydrological regimes and the impacts of human activities in the main Wei River, China

NASA Astrophysics Data System (ADS)

Zhang, Hongbo; Huang, Qiang; Zhang, Qiang; Gu, Lei; Chen, Keyu; Yu, Qijun

2016-03-01

Under the combined influence of climate changes and human activities, the hydrological regime of the Wei River shows remarkable variations which have caused many issues in the Wei River in recent decades, such as a lack of freshwater, water pollution, disastrous flooding and channel sedimentation. Hence, hydrological regime changes and potential human-induced impacts have been drawing increasing attention from local government and hydrologists. This study investigates hydrological regime changes in the natural and measured runoff series at four hydrological stations on the main Wei River and quantifies features of their long-term change by analysing their historical annual and seasonal runoff data using several approaches, i.e., continuous wavelet transform, cross-wavelet, wavelet coherence, trend-free pre-whitening Mann-Kendall test and detrended fluctuation analysis. By contrasting two different analysis results between natural and measured river runoff series, the impacts of human activities on the long-term hydrological regime were investigated via the changes of spatio-temporal distribution in dominant periods, the trends and long-range memory of river runoff. The results show : (a) that periodic properties of the streamflow changes are the result of climate, referring to precipitation changes in particular, while human activities play a minor role; (b) a significant decreasing trend can be observed in the natural streamflow series along the entire main stream of the Wei River and the more serious decrease emerging in measured flow should result from human-induced influences in recent decades; and (c) continuous decreasing streamflow in the Wei River will trigger serious shortages of freshwater in the future, which may challenge the sustainability and safety of water resources development in the river basin, and should be paid great attention before 2020.

Endocrine Pancreas Regeneration

DTIC Science & Technology

2010-06-01

Rehman KK, Bertera S, Zhang J, Chen C, Papworth G, Watkins S, Trucco M, Robbins PD, Li J,Xiao X: Widespread and stable pancreatic gene transfer by AAV...G, Watkins S, Trucco M, Robbins PD, Li J,Xiao X: Widespread and stable pancreatic gene transfer by AAV vectors via different routes. Diabetes 55...J Clin Invest 114:877-883, 2004. 15. Tian C, Bagley J, Cretin N, Seth N, Wucherpfennig KW, Iacomini J: Prevention of type 1 diabetes by gene

[Simultaneous determination of ephedrine hydrochloride, D-pseudoephedrine and amygdalin in xiao'er pingchuan qutan granule by HPLC].

PubMed

Yang, De-Bin; Tong, Yan; Ma, Zhen-Shan; Wang, Lin; Dong, Mei-Hong; Li, Yan-Ling; Wang, Jin-Yu

2013-03-01

To establish an HPLC method for the determination of ephedrine hydrochloride, D-pseudo-ephedrine and amygdalin in Xiao'er Pingchuan Qutan granule. Pheny ether chromatographic column (4.6 mm x 250 mm, 5 microm) was adopted, with acetonitrile-0.1% phosphoric acid (containing 0.1% three ethylamine) (3:97) as the mobile phase. The UV detection wavelength was at 210 nm, with the flow rate of 1 mL x min(-1), and column temperature was at 35 degrees C. The linearity of ephedrine hydrochloride, D-pseudo-ephedrine and amygdalin ranged between 0.078 60-3.144 microg (r = 1.000 0), 0.103 4-2.068 microg (r = 0.999 7) and 0.430 5-3.157 microg (r = 0.999 8), respectively. Their average recoveries were 98.46% (RSD 1.1%), 103.0% (RSD 1.5%) and 97.15% (RSD 2.1%), respectively. The method is simple, stable and reliable that it can be used to determine the content of ephedrine hydrochloride, D-pseudo-ephedrine and amygdalin in Xiao'er Pingchuan Qutan granule.

Strength-based Supervision: Frameworks, Current Practice, and Future Directions A Wu-wei Method.

ERIC Educational Resources Information Center

Edwards, Jeffrey K.; Chen, Mei-Whei

1999-01-01

Discusses a method of counseling supervision similar to the wu-wei practice in Zen and Taoism. Suggests that this strength-based method and an understanding of isomorphy in supervisory relationships are the preferred practice for the supervision of family counselors. States that this model of supervision potentiates the person-of-the-counselor.…

Undercooling, Rapid Solidification, and Relations to Processing in Low Earth Orbit (A Review of the Works of Bingbo Wei)

NASA Technical Reports Server (NTRS)

deGroh, Henry C., III

1999-01-01

This is a survey of the published works of Prof. Bingbo Wei of the Department of Applied Physics at Northwestern Polytechnical University, Xian P.R. China. Transformations among solid - liquid - and vapor are fundamental to the foundations of life and culture on Earth. The development and understanding of materials has lead the evolution and advancement of the human race since antiquity. Materials and fluids research is continuing today, with us standing on the shoulders of those that have gone before us. Technological and scientific breakthroughs continue due to studies of greater and greater complexity, that include for example, research done at high pressures, in high magnetic fields, at temperatures near absolute zero, and in the low gravity environment of low Earth orbit. Of particular technological importance is the liquid to solid transformation of metals and alloys. Solidification processing is generally the most important factor in the final properties of objects made of metal; and undercooling is the fundamental driving force for all solidification. The interest and resources dedicated to the study of solidification and undercooling are great and World wide. For many years B. Wei and his coworkers have been studying undercooling and rapid solidification and have amassed a significant body of published research in this important field, contributing to the leading edge of the state-of-the-art. It is the goal of this memorandum to provide a review of the research of B. Wei et al.; publications in Chinese are included in the reference list but are not discussed. The bulk of Wei's work has been in the area of undercooling and rapid solidification [1-11, 13-16, 24-36] with papers dating back to 1989, the same year he earned his Ph.D. Below, discussions of Wei's undercooling and rapid solidification research have been grouped together mostly on the basis of alloy type, such as eutectic, intermetallic, or monotectic.

Nonminimal Wu-Yang wormhole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balakin, A. B.; Zayats, A. E.; Sushkov, S. V.

2007-04-15

We discuss exact solutions of a three-parameter nonminimal Einstein-Yang-Mills model, which describe the wormholes of a new type. These wormholes are considered to be supported by the SU(2)-symmetric Yang-Mills field, nonminimally coupled to gravity, the Wu-Yang ansatz for the gauge field being used. We distinguish between regular solutions, describing traversable nonminimal Wu-Yang wormholes, and black wormholes possessing one or two event horizons. The relation between the asymptotic mass of the regular traversable Wu-Yang wormhole and its throat radius is analyzed.

The Use and the Prescription Pattern of Traditional Chinese Medicine Among Urolithiasis Patients in Taiwan: A Population-Based Study.

PubMed

Lin, Po-Hung; Lin, Shun-Ku; Hsu, Ren-Jun; Cheng, Kuan-Chen; Liu, Jui-Ming

2016-01-01

To investigate the pattern of Traditional Chinese Medicine (TCM) usage for urolithiasis patients in Taiwan and to determine the most common Chinese herbal products used for urolithiasis. Retrospective review of urolithiasis patients treated with TCM treatment. One million randomly selected samples in the Taiwanese National Health Insurance Research Database between 1997 and 2008. Eighty-two thousand five hundred and fifty-one newly diagnosed urolithiasis patients. The correlation between TCM treatment, demographic factors, or medical conditions. A total of 62.6% of urolithiasis patients use TCM treatment. A younger age, female gender, polypharmacy, multiple comorbidities, and stone in the lower urinary tract result in a greater tendency to use TCM, after adjusting for demographic factors. Jia-Wei-Xiao-Yao-San Extract Powder and Ji-Sheng-Shen-Qi-Wan Extract Powder are the most frequently prescribed Chinese medicine formulae. This is the first study to examine the use of and the prescription pattern for TCM in urolithiasis patients using a random, national population-based sample. More than 62% of urolithiasis patients use TCM, and patients with polypharmacy, multiple comorbidities, and stone in the ureter are more likely to use TCM. The most frequently prescribed Chinese medicine formulae were Jia-Wei-Xiao-Yao-San Extract Powder and Ji-Sheng-Shen-Qi-Wan Extract Powder, which were reported to retard the progression of renal failure and alleviate flank pain or tenderness.

Deciphering the Mechanism of Alternative Cleavage and Polyadenylation in Mantle Cell Lymphoma (MCL)

DTIC Science & Technology

2013-10-01

also has human firefly luciferase cloned within the same reporter system allowing for intra-plasmid normalization of transfection eliminating problems...collaboration with Dr. Wei Li, a Bioinformaticist from Baylor College of Medicine whose lab specializes in developing complex algorithms to analyze genome...wide sequencing data. Dr. Wei Li and his postdoctoral fellow, Dr. Zheng Xia developed a customized algorithm that is able to detect and quantify

Radiation Environment at GEO from the FY2G Satellite Observations

NASA Astrophysics Data System (ADS)

Wang, C.

2016-12-01

WANG Chun-Qin1,2*, Zhang Shen-Yi1,2 Jing Tao1,2, Zhang Huan-Xin1,2 Li Jia-Wei3 Zhang Xiao-Xin3 Sun Yue-Qiang1,2 Liang Jin-Bao1,2 Wei Fei1,2 Shen Guo-Hong1,2 Huang Cong3 Shi Chun-Yan1,21.National Space Science Center, Chinese Academy of Sciences, Beijing 100190, China; 2.Beijing Key Laboratory of Space Environment Exploration, Beijing 100190,China 3.National Satellite Meteorological Center, National Center for Space Weather, Beijing 100081, China; Abstract Recent measurements of the high energy electrons and protons with energetic particle instrument carried on the FY-2G satellite are presented. The instrument consist of two detectors-the high energy electrons instrument which can measure 200keV to greater than 4MeV electrons with eleven channels, and the high energy protons and heavy ions instrument which mainly senses incident flux of solar protons with seven channels from 4MeV to 300 MeV. The paper shows electrons and protons observations from Jan 2015 until Oct 2015. A precise description and preliminary analysis of particle dynamic during disturbances of magnetic storms、substorms and solar eruptions suggest that both of the detectors show accurate response to various disturbances and provide refined particles data. Comparison results of FY2G satellite with GOES series satellites reflect obvious local difference in particle flux evolvement especially during intensive disturbances time, which can be helpful for data assimilation of multi-satellite as well as further research in more complicated magnetosphere energy particle dynamic.

Protein kinase Cβ activates fat mass and obesity-associated protein by influencing its ubiquitin/proteasome degradation.

PubMed

Tai, Haoran; Wang, Xiaobo; Zhou, Jiao; Han, Xiaojuan; Fang, Tingting; Gong, Hui; Huang, Ning; Chen, Honghan; Qin, Jianqiong; Yang, Ming; Wei, Xiawei; Yang, Li; Xiao, Hengyi

2017-10-01

Protein kinase Cβ (PKCβ) is a serine-threonine kinase associated with obesity and diabetic complications; its activation contributes to weight gain, and deletion of its gene results in resistance to genetic- and diet-induced obesity. Fat mass and obesity-associated (FTO) protein is a recently identified RNA demethylase, and its overexpression in mice leads to increased body weight as well as fat mass. Although sharing some features in anabolism regulation, PKCβ and FTO have not been investigated together; therefore, their relationship has not been established. We report that PKCβ positively regulates FTO on the posttranslation level, evidenced by the facts that PKCβ activation contributes to high-glucose-induced FTO up-regulation, and overexpression of PKCβ suppresses ubiquitin-proteasome degradation of FTO, whereas PKCβ inactivation acts in the opposite manner. It was also found that PKCβ can phosphorylate FTO on threonine, and this phosphorylation requires both catalytic and regulatory domains of PKCβ. Moreover, PKCβ inhibition can suppress 3T3-L1 cell differentiation in normal and FTO-overexpressing cells but not in FTO-silenced or -inhibited cells. We propose that PKCβ acts to suppress the degradation of FTO protein and reveals the associated role of PKCβ and FTO in adipogenesis, suggesting a new pathway that affects the development of obesity and metabolic diseases.-Tai, H., Wang, X., Zhou, J., Han, X., Fang, T., Gong, H., Huang, N., Chen, H., Qin, J., Yang, M., Wei, X., Yang, L., Xiao, H. Protein kinase Cβ activates fat mass and obesity-associated protein by influencing its ubiquitin/proteasome degradation. © FASEB.

POLYMORPHISMS IN THE DNA NUCLEOTIDE EXCISION REPAIR GENES AND LUNG CANCER RISK IN XUAN WEI, CHINA

EPA Science Inventory

The lung cancer mortality rate in Xuan Wei County, China is among the highest in the country and has been etiologically attributed to exposure to indoor smoky coal emissions that contain very high levels of polycyclic aromatic hydrocarbons (PAHs). Nucleotide excision repair (NE...

Advanced Materials and Processing 2010

NASA Astrophysics Data System (ADS)

Zhang, Yunfeng; Su, Chun Wei; Xia, Hui; Xiao, Pengfei

2011-06-01

Strain sensors made from MWNT/polymer nanocomposites / Gang Yin, Ning Hu and Yuan Li -- Shear band evolution and nanostructure formation in titanium by cold rolling / Dengke Yang, Peter D. Hodgson and Cuie Wen -- Biodegradable Mg-Zr-Ca alloys for bone implant materials / Yuncang Li ... [et al.] -- Hydroxyapatite synthesized from nanosized calcium carbonate via hydrothermal method / Yu-Shiang Wu, Wen-Ku Chang and Min Jou -- Modeling of the magnetization process and orthogonal fluxgate sensitivity of ferromagnetic micro-wire arrays / Fan Jie ... [et al.] -- Fabrication of silicon oxide nanowires on Ni coated silicon substrate by simple heating process / Bo Peng and Kwon-Koo Cho -- Deposition of TiOxNy thin films with various nitrogen flow rate: growth behavior and structural properties / S.-J. Cho ... [et al.] -- Observation on photoluminescence evolution in 300 KeV self-ion implanted and annealed silicon / Yu Yang ... [et al.] -- Facile synthesis of lithium niobate from a novel precursor H[symbol] / Meinan Liu ... [et al.] -- Effects of the buffer layers on the adhesion and antimicrobial properties of the amorphous ZrAlNiCuSi films / Pai-Tsung Chiang ... [et al.] -- Fabrication of ZnO nanorods by electrochemical deposition process and its photovoltaic properties / Jin-Hwa Kim ... [et al.] -- Cryogenic resistivities of NbTiAlVTaLax, CoCrFeNiCu and CoCrFeNiAl high entropy alloys / Xiao Yang and Yong Zhang -- Modeling of centrifugal force field and the effect on filling and solidification in centrifugal casting / Wenbin Sheng, Chunxue Ma and Wanli Gu -- Electrochemical properties of TiO[symbol] nanotube arrays film prepared by anodic oxidation / Young-Jin Choi ... [et al.] -- Effect of Ce additions on high temperature properties of Mg-5Sn-3Al-1Zn alloy / Byoung Soo Kang ... [et al.] -- Sono-electroless plating of Ni-Mo-P film / Atsushi Chiba, Masato Kanou and Wen-Chang Wu -- Diameter dependence of giant magneto-impedance effect in co-based melt extracted amorphous

Spatiotemporal variability and assessment of drought in the Wei River basin of China

NASA Astrophysics Data System (ADS)

Cai, Siyang; Zuo, Depeng; Xu, Zongxue; Han, Xianming; Gao, Xiaoxi

2018-06-01

The temporal and spatial variations of drought in the Wei River basin (WRB) were investigated by calculating the meteorological drought Index (Standardized Precipitation Index, SPI) and the agricultural drought index (Vegetation Health Index, VHI). Monthly precipitation and air temperature were from 22 meteorological stations over the region from 1960 to 2015. Monthly Normalized Difference Vegetation Index (NDVI) and 8-days Land Surface Temperature (LST) were provided from the National Aeronautics and Space Administration (NASA) for the period 2000-2015 were also adopted. The results showed that the drought initially increased and then decreased, reaching at the maximum value in 1990s. The spatial pattern of meteorological drought showed that the drought in northern WRB was heavier than that in southern WRB before 1990s, after that, the situation had the opposite. By comparing the agricultural drought index (VHI) with crop yield, it was proved that VHI was applicable in the WRB and could well reflect the fluctuation of agricultural drought. The WRB suffered from serious agricultural drought in 2000, 2001, 2007 and 2008. Through analysis of the historical precipitation and temperature data, it was found that precipitation had a greater contribution to creating agricultural drought conditions than temperature in the Wei River basin.

The utilization of traditional Chinese medicine in patients with dysfunctional uterine bleeding in Taiwan: a nationwide population-based study.

PubMed

Lin, Yi-Rong; Wu, Mei-Yao; Chiang, Jen-Huai; Yen, Hung-Rong; Yang, Su-Tso

2017-08-29

Many patients with gynecological disorders seek traditional medicine consultations in Asian countries. This study intended to investigate the utilization of traditional Chinese medicine (TCM) in patients with dysfunctional uterine bleeding (DUB) in Taiwan. We analyzed a cohort of one million individuals randomly selected from the National Health Insurance Research Database in Taiwan. We included 46,337 subjects with newly diagnosed DUB (ICD-9-CM codes 626.8) from January 1, 1997 to December 31, 2010. The patients were categorized into TCM seekers and non-TCM seekers according to their use of TCM. Among the subjects, 41,558 (89.69%) were TCM seekers and 4,779 (10.31%) were non-TCM seekers. Patients who were younger tended to be TCM seekers. Most of the patients had also taken Western medicine, especially tranexamic acid and non-steroidal anti-inflammatory drugs (NSAIDs). More than half of TCM seekers (55.41%) received combined treatment with both Chinese herbal remedies and acupuncture. The most commonly used TCM formula and single herb were Jia-Wei-Xiao-Yao-San (Bupleurum and Peony Formula) and Yi-Mu-Cao (Herba Leonuri), respectively. The core pattern of Chinese herbal medicine for DUB patients consisted of Jia-Wei-Xiao-Yao-San, Xiang-Fu (Rhizoma Cyperi), and Yi-Mu-Cao (Herba Leonuri). TCM use is popular among patients with DUB in Taiwan. Further pharmacological investigations and clinical trials are required to validate the efficacy and safety of these items.

1D Nanostructures: Controlled Fabrication and Energy Applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Michael Z.

2013-01-01

Jian Wei, Xuchun Song, Chunli Yang, and Michael Z. Hu, 1D Nanostructures: Controlled Fabrication and Energy Applications, Journal of Nanomaterials, published special issue (http://www.hindawi.com/journals/jnm/si/197254/) (2013).

Genoprotective effect of the Chinese herbal decoction xiao jian zhong tang.

PubMed

Szeto, Yim-Tong; Cheng, Ngok-Fung; Pak, Sok-Cheon; Kalle, Wouter

2013-03-01

The Chinese herbal decoction formula Xiao Jian Zhong Tang (XJZT) is one of the classic formulas from the classic traditional Chinese medicine (TCM). Previous studies on XJZT found that it is effective for treating peptic ulcer, irritable bowel syndrome, functional gastroenteritis and similar psychosomatic disorders of the digestive organs. It has also been shown that all the herbs used in XJZT contain antioxidants. In this study, we investigated the in vitro DNA protection effect of the individual herb extracts and the whole formula. Water extract of the herbs and XJZT were used to pre-treat human lymphocytes. The lymphocytes were then exposed to hydrogen peroxide. The in vitro DNA protection effect of the herbs was investigated by comet assay. No DNA protective effect (P < 0.05) was found for individual herb extracts, but XJZT showed protection of human lymphocytic DNA upon oxidative stress (P < 0.05). The in vitro DNA protection effect of XJZT was conferred by the synergistic effect of the herbs, while the individual herbs had no such effect.

Construction of the vessel-collateral theory and its guidance for prevention and treatment of vasculopathy.

PubMed

Wu, Yiling

2011-06-01

According to the self-discipline of traditional Chinese medicine, vessel-collateral theory was constructed systematically, which was important to improving prevention and treatment level of vasculopathy. The hypothesis of "homeostasis (Cheng), compensatory auto-adaptation (Zhi), regulation (Tiao) and equilibrium (Ping)" based on the "qi-yin-yang-five elements" coupled with the ying (nutrients)-wei (defense) theory, has become the core content of the vessel-collateral theory. Clinical and laboratory trials have been developed to further confirm the scientific connotations of the hypothesis, such as Tong Xin Luo capsule, as the representative drugs of vessel collateral theory, showed good efficacy in protecting the vascular endothelium, stabilizing the vulnerable plaque and reducing the blood vessel spasm. "Sou, ti, shu, tong" was the characteristics of Tong Xin Luo capsule in treating "microvascular damage" as the core mechanism of acute myocardial infarction, cerebral infarction and microvascular complications of diabetes. Shen Song Yang Xin capsules in the treatment of arrhythmia have made integrated adjustment advantage. Qi Li Qiang Xin capsules have been made treating both manifestation and root cause of chronic heart failure. These research have improved prevention and treatment level of major vascular system diseases.

Chemical characterization of indoor air of homes from communes in Xuan Wei, China, with high lung cancer mortality rates

EPA Science Inventory

In a rural county, Xuan Wei, China, the lung cancer mortality rate is among China's highest, especially in women. This mortality rate is more associated with indoor air burning of smoky coal, as opposed to smokeless coal or wood, for cooking and heating under unvented conditions....

[Estimation of carbonaceous gases emission from forest fires in Xiao Xing'an Mountains of Northeast China in 1953-2011].

PubMed

Hu, Hai-Qing; Luo, Bi-Zhen; Wei, Shu-Jing; Sun, Long; Wei, Shu-Wei; Wen, Zheng-Min

2013-11-01

Based on the forest resources investigation data and the forest fire inventory in 1953-2011, in combining with our field research in burned areas and our laboratory experiments, this paper estimated the carbonaceous gases carbon dioxide (CO2), carbon monoxide (CO), methane (CH4), and nonmethane hydrocarbons (NMHC) emission from the forest fires in Xiao Xing' an Mountains of Heilongjiang Province, Northeast China in 1953-2011. The total carbon emission from the forest fires in the Xiao Xing'an Mountains in 1953-2011 was 1.12 x 10(7) t, and the annual emission was averagely 1.90 x10(5) t, accounting for 1.7% of the annual average total carbon emission from the forest fires in China. The emission of CO2, CO, CH4, and NMHC was 3.39 x 10(7), 1.94 x 10(5), 1.09 x 10(5), and 7.46 x 10(4) t, respectively, and the corresponding annual average emission was 5.74 x 10(5), 3.29 x 10(4), 1.85 x 10(3), and 1.27 x 10(3) t, accounting for 1.4%, 1.2%, 1.7%, and 1.1% of the annual carbonaceous gases emitted from the forest fires in China, respectively. The combustion efficiency and the carbon emission per unit burned area of different forest types decreased in order of coniferous forest > broad-leaved forest > coniferous broadleaved mixed forest. Some rational forest fire management measures were put forward.

Micro-Raman analysis of the pigments on painted pottery figurines from two tombs of the Northern Wei Dynasty in Luoyang

NASA Astrophysics Data System (ADS)

Liu, Zhaojun; Han, Yunxia; Han, Ligang; Cheng, Yongjian; Ma, Yiqiang; Fang, Li

2013-05-01

The pigments on the painted pottery figurines from two tombs of Northern Wei Dynasty (AD 386-534) in Luoyang were analyzed by Raman microscopy. All the pigments were identified compared with the Raman spectra of standard pigments. The red pigments were identified as haematite, the blue pigment as lapis lazuli, the green pigment as malachite, the black pigment as carbon black and the white pigment as calcite. Similar pigments were used in the two tombs despite the pottery figurines were very different in artistic style. The use of lapis lazuli as blue pigment on Chinese painted pottery figurines was found for the first time. This pigment and the painted pottery figurine of Sogdians are of great archaeological significance because it demonstrated that the trade and cultural exchanges via the Silk Road had extended to Luoyang city in the Northern Wei Dynasty. The result also confirms that micro-Raman spectroscopy is a powerful analytical method for the identification of pigments on ancient artworks.

Erratum: Erratum to: Realistic interpretation of quantum mechanics and encounter-delayed-choice experiment

NASA Astrophysics Data System (ADS)

Long, GuiLu; Qin, Wei; Yang, Zhe; Li, Jun-Lin

2018-06-01

The article Realistic interpretation of quantum mechanics and encounter-delayed-choice experiment, written by GuiLu Long, Wei Qin, Zhe Yang, and Jun-Lin Li, was originally published online without open access. After publication in volume 61, issue 3: 030311 the author decided to opt for Open Choice and to make the article an open access publication. Therefore, the copyright of the article has been changed to The Author(s) 2017 and the article is forthwith distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits use, duplication, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The original article has been corrected.

Duality Quantum Simulation of the Yang-Baxter Equation

NASA Astrophysics Data System (ADS)

Zheng, Chao; Wei, Shijie

2018-04-01

The Yang-Baxter equation has become a significant theoretical tool in a variety of areas of physics. It is desirable to investigate the quantum simulation of the Yang-Baxter equation itself, exploring the connections between quantum integrability and quantum information processing, in which the unity of both the Yang-Baxter equation system and its quantum entanglement should be kept as a whole. In this work, we propose a duality quantum simulation algorithm of the Yang-Baxter equation, which contains the Yang-Baxter system and an ancillary qubit. Contrasting to conventional methods in which the two hand sides of the equation are simulated separately, they are simulated simultaneously in this proposal. Consequently, it opens up a way to further investigate entanglements in a Yang-Baxter equation.

Duality Quantum Simulation of the Yang-Baxter Equation

NASA Astrophysics Data System (ADS)

Zheng, Chao; Wei, Shijie

2018-07-01

The Yang-Baxter equation has become a significant theoretical tool in a variety of areas of physics. It is desirable to investigate the quantum simulation of the Yang-Baxter equation itself, exploring the connections between quantum integrability and quantum information processing, in which the unity of both the Yang-Baxter equation system and its quantum entanglement should be kept as a whole. In this work, we propose a duality quantum simulation algorithm of the Yang-Baxter equation, which contains the Yang-Baxter system and an ancillary qubit. Contrasting to conventional methods in which the two hand sides of the equation are simulated separately, they are simulated simultaneously in this proposal. Consequently, it opens up a way to further investigate entanglements in a Yang-Baxter equation.

Loop quantum corrected Einstein Yang-Mills black holes

NASA Astrophysics Data System (ADS)

Protter, Mason; DeBenedictis, Andrew

2018-05-01

In this paper, we study the homogeneous interiors of black holes possessing SU(2) Yang-Mills fields subject to corrections inspired by loop quantum gravity. The systems studied possess both magnetic and induced electric Yang-Mills fields. We consider the system of equations both with and without Wilson loop corrections to the Yang-Mills potential. The structure of the Yang-Mills Hamiltonian, along with the restriction to homogeneity, allows for an anomaly-free effective quantization. In particular, we study the bounce which replaces the classical singularity and the behavior of the Yang-Mills fields in the quantum corrected interior, which possesses topology R ×S2 . Beyond the bounce, the magnitude of the Yang-Mills electric field asymptotically grows monotonically. This results in an ever-expanding R sector even though the two-sphere volume is asymptotically constant. The results are similar with and without Wilson loop corrections on the Yang-Mills potential.

Mineralogical and compositional characteristics of Late Permian coals from an area of high lung cancer rate in Xuan Wei, Yunnan, China: Occurrence and origin of quartz and chamosite

USGS Publications Warehouse

Dai, S.; Tian, L.; Chou, C.-L.; Zhou, Y.; Zhang, M.; Zhao, L.; Wang, Jingyuan; Yang, Z.; Cao, H.; Ren, D.

2008-01-01

Some townships in Xuan Wei County, Yunnan Province, have one of the highest lung cancer mortality rates in China and the epidemic disease in the area has generally been attributed to the polycyclic aromatic hydrocarbons (PAHs) released from domestic coal burning. However, the cancer-causing culprit is not settled as Tian [Tian, L., 2005. Coal Combustion Emissions and Lung Cancer in Xuan Wei, China. Ph.D. thesis, University of California, Berkeley.] found nanometer quartz in these coals, soot emissions, and lung cancer tissues. We have conducted mineralogical and geochemical studies of the coals from Xuan Wei for the purpose of shedding light on the minerals which may be related to the epidemic lung cancer. In this paper, abundances, modes of occurrence, and origins of minerals and elements in the coals from two mines in Xuan Wei have been studied using optical microscope, low-temperature ashing, X-ray diffraction analysis, scanning electron microscope equipped with energy-dispersive X-ray spectrometer, and inductively-coupled plasma mass spectrometry. The minerals in the coals are mainly composed of quartz, chamosite, kaolinite, and calcite. The particle size of quartz is rather small, mostly less than 20????m and it is of authigenic origin. Chamosite occurs mainly as cell-fillings. The occurrence of quartz and chamosite indicates that they were derived from the hydrothermal fluids. Epigenetic calcite is derived from calcic fluids. Kaolinite is derived mainly from sediment source region of Kangdian Oldland to the west of coal basin. The composition of Xuan Wei coal is high in SiO2, Fe2O3, TiO2, CaO, MnO, V, Co, Ni, Cu, and Zn. The high SiO2 content is attributed to quartz, and the Fe2O3 content to chamosite. The high Mn and low Mg contents in the coal indicate the inputs of hydrothermal fluids. CaO occurs mainly in epigenetic calcite. Elements Ti, Co, Ni, Cu, Zn, and rare earth elements were derived from the basaltic rocks at sediment source region. ?? 2008

Experimental Determination of Dynamical Lee-Yang Zeros

NASA Astrophysics Data System (ADS)

Brandner, Kay; Maisi, Ville F.; Pekola, Jukka P.; Garrahan, Juan P.; Flindt, Christian

2017-05-01

Statistical physics provides the concepts and methods to explain the phase behavior of interacting many-body systems. Investigations of Lee-Yang zeros—complex singularities of the free energy in systems of finite size—have led to a unified understanding of equilibrium phase transitions. The ideas of Lee and Yang, however, are not restricted to equilibrium phenomena. Recently, Lee-Yang zeros have been used to characterize nonequilibrium processes such as dynamical phase transitions in quantum systems after a quench or dynamic order-disorder transitions in glasses. Here, we experimentally realize a scheme for determining Lee-Yang zeros in such nonequilibrium settings. We extract the dynamical Lee-Yang zeros of a stochastic process involving Andreev tunneling between a normal-state island and two superconducting leads from measurements of the dynamical activity along a trajectory. From the short-time behavior of the Lee-Yang zeros, we predict the large-deviation statistics of the activity which is typically difficult to measure. Our method paves the way for further experiments on the statistical mechanics of many-body systems out of equilibrium.

POLYMORPHISMS IN THE DNA BASE EXCISION REPAIR GENES APEX1 AND XRCC1 AND LUNG CANCER RISK IN XUAN WEI, CHINA

EPA Science Inventory

The lung cancer mortality rate in Xuan Wei County is among the highest in China and has been attributed to exposure to indoor smoky coal emissions that contain very high levels of polycyclic aromatic hydrocarbons (PAHs). Nucleotide excision repair (NER) plays a key role in revers...

Applying Spatial-Temporal Model and Game Theory to Asymmetric Threat Prediction

DTIC Science & Technology

2007-06-01

Genshe Chen, Denis Garagic, Xiaohuan Tan, Dongxu Li, Dan Shen, Mo Wei, Xu Wang, “Team Dynamics and Tactics for Mission Planning,” Proceedings...Cruz, Jr., Genshe Chen, Dongxu Li, and Denis Garagic, “Target Selection in UAV Cooperative Control Under Uncertain Environment: Genetic Algorithm

Synthesis and Electrochemical Properties Characterization of SnO2-coated LiNi1/3Co1/3Mn1/3O2 Cathode Material for Lithium Ion Batteries

DTIC Science & Technology

2009-01-01

Synthesis and electrochemical properties characterization of SnO2-coated LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries Ping Yang...electrochemical properties characterization of SnO2-coated LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries 5a. CONTRACT NUMBER 5b. GRANT NUMBER...electrochemical reaction. References 1. N Yabuuchi, T Ohzuku, “Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium - ion batteries ”, J

New Principles for Interfacial Engineering and Superstabilization of Biphase Systems by Using Particles with Engineered Structure and Properties

DTIC Science & Technology

2014-09-27

fresher foams are more resistant to destruction by a magnetic field since its higher water content and thicker films allowed for the movement of loose...of the carbonyl iron particles in the foam. As the strength of the applied magnetic field is increased, the strength of the particle chains resisting ...E. S.; Klamczynski, A.; Glenn, G. M., Starch -lignin Foams. eXPRESS Polym. Lett. 2010, 4, 311–320. 60. Wei, Z.; Yang, Y.; Yang, R.; Wang, C

Soluble Model Fluids with Complete Scaling and Yang-Yang Features

NASA Astrophysics Data System (ADS)

Cerdeiriña, Claudio A.; Orkoulas, Gerassimos; Fisher, Michael E.

2016-01-01

Yang-Yang (YY) and singular diameter critical anomalies arise in exactly soluble compressible cell gas (CCG) models that obey complete scaling with pressure mixing. Thus, on the critical isochore ρ =ρc , C˜ μ≔-T d2μ /d T2 diverges as |t |-α when t ∝T -Tc→0- while ρd-ρc˜|t |2β where ρd(T )=1/2 [ρliq+ρgas] . When the discrete local CCG cell volumes fluctuate freely, the YY ratio Rμ=C˜μ/CV may take any value -∞ 0 . More general decorated CCGs, including "hydrogen bonding" water models, illuminate energy-volume coupling as relevant to Rμ.

JPRS Report, China Red Flag No 15, 1 August 1987

DTIC Science & Technology

1987-10-07

9-13) (Xiao Ke) • • • • • 1* Consolidate and Develop a New Type of Army-Government and Army-People Relationship (pp 14-17) (Wang Fang, Li Qing...the Socialist Commodity Economy (pp 44-46) ( Li Guangyuan) 78 ’Emotional Investment’ Viewed From Various Angles (p 47) (Lei Ke) 85 Singing the...counted as a setback, but it was precisely during the setback of the great revolution that our Army was founded. During the 25,000- li Long March

Getting Beyond Taiwan? Chinese Foreign Policy and PLA Modernization

DTIC Science & Technology

2011-01-01

Interests] ( Beijing : Guofang Daxue Chubanshe, 2007); and Yang Mingshu, chief ed., Haishang Tongdao Anquan yu Guoji Hezuo [SLOC Security and International... Beijing : Guofang Daxue Chubanshe, 2009); Shou Xiaosong and Xu Jingnian, chief eds., Jundui Yingdui Fei- chuantong Anquan Weixie Yanjiu [Research on the...Xingdong [Non- War Military Operations] ( Beijing : Guofang Daxue Chubanshe, 2006); and Xiao Tianliang, Junshi Liliang de Feizhanzheng Yunyong [Non-War

Quantum groups, Yang-Baxter maps and quasi-determinants

NASA Astrophysics Data System (ADS)

Tsuboi, Zengo

2018-01-01

For any quasi-triangular Hopf algebra, there exists the universal R-matrix, which satisfies the Yang-Baxter equation. It is known that the adjoint action of the universal R-matrix on the elements of the tensor square of the algebra constitutes a quantum Yang-Baxter map, which satisfies the set-theoretic Yang-Baxter equation. The map has a zero curvature representation among L-operators defined as images of the universal R-matrix. We find that the zero curvature representation can be solved by the Gauss decomposition of a product of L-operators. Thereby obtained a quasi-determinant expression of the quantum Yang-Baxter map associated with the quantum algebra Uq (gl (n)). Moreover, the map is identified with products of quasi-Plücker coordinates over a matrix composed of the L-operators. We also consider the quasi-classical limit, where the underlying quantum algebra reduces to a Poisson algebra. The quasi-determinant expression of the quantum Yang-Baxter map reduces to ratios of determinants, which give a new expression of a classical Yang-Baxter map.

Coprescription of Chinese herbal medicine and Western medication among female patients with breast cancer in Taiwan: analysis of national insurance claims.

PubMed

Wang, Bih-Ru; Chang, Yuh-Lih; Chen, Tzeng-Ji; Chiu, Jen-Hwey; Wu, Jing Chong; Wu, Min-Shan; Chou, Chia-Lin; Chou, Yueh-Ching

2014-01-01

Many female breast cancer (FBC) patients take Chinese herbal medicine (CHM) and Western medication (WM) concurrently in Taiwan. Despite the possibility of interactions between the CHM and WM mentioned in previous studies, the pattern of these coprescriptions in FBC patients remains unclear. Hence, the aim of the present study is to investigate the utilization of coprescriptions of CHM and WM among the FBC patients in Taiwan. The study was a cross-sectional survey using the sampled cohort in 2009 obtained from the National Health Insurance Research Database in Taiwan. There were 3,507 FBC patients identified from the registry for catastrophic illness patients. Ambulatory visit records, corresponding prescriptions, and the data of beneficiaries belonging to the FBC patients were further extracted. A total of 1,086 FBC patients used CHM at least once. CHM and WM prescribed within any overlapping duration were defined as coprescriptions. There were 868 (80.0%) patients simultaneously receiving CHM and WM. A total of 4,927 CHM prescriptions and 6,358 WM prescriptions were prescribed concurrently. Among these coprescriptions, the most frequently used CHM was jia-wei-xiao-yao-san (21.2%), and the most frequently coprescribed WM was acetaminophen (38.9%), followed by tamoxifen (25.5%). There were 346 patients using systemic adjuvant therapy and CHM concurrently. The most commonly coprescribed CHM with chemotherapy, endocrine therapy, and trastuzumab was xiang-sha-liu-jun-zi-tang, jia-wei-xiao-yao-san, and zhi-gan-cao-tang, respectively. The combined use of CHM with WM is prevalent. The main purpose of combining CHM with systemic cancer treatment is to alleviate the treatment-related adverse effects. However, the combination may result in the potential risk of drug-herb interactions. Further clinical studies are needed to evaluate the efficacy and safety of the CHM and WM coprescriptions for FBC patients.

The use of Chinese herbal products and its influence on tamoxifen induced endometrial cancer risk among female breast cancer patients: a population-based study.

PubMed

Tsai, Yueh-Ting; Lai, Jung-Nien; Wu, Chien-Tung

2014-09-11

The increased practice of traditional Chinese medicine (TCM) worldwide has raised concerns regarding herb-drug interactions. The purpose of our study was to analyze the use of Chinese herbal products (CHPs) and to estimate the influence of the use of CHP on tamoxifen induced endometrial cancer risk among female breast cancer patients in Taiwan. All patients newly diagnosed with invasive breast cancer receiving tamoxifen treatment from January 1, 1998 to December 31, 2008 were selected from the National Health Insurance Research Database. The usage, frequency of service, and CHPs prescribed among the 20,466 tamoxifen-treated female breast cancer patients were analyzed. The logistic regression method was employed to estimate the odds ratios (ORs) for utilization of CHPs. Cox proportional hazard regression was performed to calculate the hazard ratios (HRs) for subsequent endometrial cancer for CHP non-users and CHP users among female breast cancer patients who had undergone tamoxifen treatment. More than half of the subjects had ever used a CHP. Jia-Wei-Xiao-Yao-San (Augmented Rambling Powder) and Shu-Jing-Huo-Xue-Tang (Channel-Coursing Blood-Quickening Decoction) were the two most commonly used CHPs. The HR for the development of endometrial cancer among CHP users was 0.50-fold (95% CI=0.38-0.64) compared to that of CHP non-users. More than half of the study subjects had ever used a CHP. Jia-Wei-Xiao-Yao-San was the most commonly used CHP. Among female breast cancer patients who had undergone tamoxifen therapy, CHP consumption decreased the risk of subsequent endometrial cancer. Exploring potential Chinese herb-tamoxifen interactions and integrating both healthcare approaches are beneficial to the overall health outcomes of tamoxifen-treated female breast cancer patients. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Energy transfer ultraviolet photodetector with 8-hydroxyquinoline derivative-metal complexes as acceptors

NASA Astrophysics Data System (ADS)

Wu, Shuang-Hong; Li, Wen-Lian; Chen, Zhi; Li, Shi-Bin; Wang, Xiao-Hui; Wei, Xiong-Bang

2015-02-01

We choose 8-hydroxyquinoline derivative-metal complexes (Beq, Mgq, and Znq) as the acceptors (A) and 4,4',4”-tri-(2-methylphenyl phenylamino) triphenylaine (m-MTDATA) as the donor (D) respectively to study the existing energy transfer process in the organic ultraviolet (UV) photodetector (PD), which has an important influence on the sensitivity of PDs. The energy transfer process from D to A without exciplex formation is discussed, differing from the working mechanism of previous PDs with Gaq [Zisheng Su, Wenlian Li, Bei Chu, Tianle Li, Jianzhuo Zhu, Guang Zhang, Fei Yan, Xiao Li, Yiren Chen and Chun-Sing Lee 2008 Appl. Phys. Lett. 93 103309)] and REq [J. B. Wang, W. L. Li, B. Chu, L. L. Chen, G. Zhang, Z. S. Su, Y. R. Chen, D. F. Yang, J. Z. Zhu, S. H. Wu, F. Yan, H. H. Liu, C. S. Lee 2010 Org. Electron. 11 1301] used as an A material. Under 365-nm UV irradiation with an intensity of 1.2 mW/cm2, the m-MTDATA:Beq blend device with a weight ratio of 1:1 shows a response of 192 mA/W with a detectivity of 6.5× 1011 Jones, which exceeds those of PDs based on Mgq (146 mA/W) and Znq (182 mA/W) due to better energy level alignment between m-MTDATA/Beq and lower radiative decay. More photophysics processes of the PDs involved are discussed in detail. Project supported by the National Natural Science Foundation of China (Grant Nos. 61371046, 61405026, 61474016, and 61421002) and China Postdoctoral Science Foundation (Grant No. 2014M552330).

New molten salt systems for high temperature molten salt batteries: Ternary and quaternary molten salt systems based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr

NASA Astrophysics Data System (ADS)

Fujiwara, Syozo; Inaba, Minoru; Tasaka, Akimasa

Using a new simulative technique developed by us, we systematically investigated new ternary or quaternary molten salt systems, which are based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr binary systems, for use as electrolytes in thermal batteries, and evaluated their ionic conductivities and melting points experimentally. It was confirmed experimentally that LiF-LiBr-KF (melting point: 425 °C, ionic conductivity at 500 °C: 2.52 S cm -1), LiCl-LiBr-KF (405 °C, 2.56 S cm -1), LiCl-LiBr-NaF-KF (425 °C, 3.11 S cm -1), LiCl-LiBr-NaCl-KCl (420 °C, 2.73 S cm -1), and LiCl-LiBr-NaBr-KBr (420 °C, 2.76 S cm -1) meet our targets for both melting point (350-430 °C) and ionic conductivity (2.0 S cm -1 and higher at 500 °C). A single cell using the newly developed LiCl-LiBr-NaCl-KCl molten salt as an electrolyte was prepared, and the DC-IR of the cell decreased by 20% than that of a single cell using the conventional LiCl-KCl molten salt. It was therefore concluded that the use of new quaternary molten salt systems can improve the discharge rate-capability in practical battery applications because of their high ionic conductivities.

Computing Critical Properties with Yang-Yang Anomalies

NASA Astrophysics Data System (ADS)

Orkoulas, Gerassimos; Cerdeirina, Claudio; Fisher, Michael

2017-01-01

Computation of the thermodynamics of fluids in the critical region is a challenging task owing to divergence of the correlation length and lack of particle-hole symmetries found in Ising or lattice-gas models. In addition, analysis of experiments and simulations reveals a Yang-Yang (YY) anomaly which entails sharing of the specific heat singularity between the pressure and the chemical potential. The size of the YY anomaly is measured by the YY ratio Rμ =C μ /CV of the amplitudes of C μ = - T d2 μ /dT2 and of the total specific heat CV. A ``complete scaling'' theory, in which the pressure mixes into the scaling fields, accounts for the YY anomaly. In Phys. Rev. Lett. 116, 040601 (2016), compressible cell gas (CCG) models which exhibit YY and singular diameter anomalies, have been advanced for near-critical fluids. In such models, the individual cell volumes are allowed to fluctuate. The thermodynamics of CCGs can be computed through mapping onto the Ising model via the seldom-used great grand canonical ensemble. The computations indicate that local free volume fluctuations are the origins of the YY effects. Furthermore, local energy-volume coupling (to model water) is another crucial factor underlying the phenomena.

Nonminimal Einstein-Yang-Mills-Higgs theory: Associated, color, and color-acoustic metrics for the Wu-Yang monopole model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balakin, A. B.; Zayats, A. E.; Dehnen, H.

2007-12-15

We discuss a nonminimal Einstein-Yang-Mills-Higgs model with uniaxial anisotropy in the group space associated with the Higgs field. We apply this theory to the problem of propagation of color and color-acoustic waves in the gravitational background related to the nonminimal regular Wu-Yang monopole.

Relativistic collisions as Yang-Baxter maps

NASA Astrophysics Data System (ADS)

Kouloukas, Theodoros E.

2017-10-01

We prove that one-dimensional elastic relativistic collisions satisfy the set-theoretical Yang-Baxter equation. The corresponding collision maps are symplectic and admit a Lax representation. Furthermore, they can be considered as reductions of a higher dimensional integrable Yang-Baxter map on an invariant manifold. In this framework, we study the integrability of transfer maps that represent particular periodic sequences of collisions.

[Talk about nomenclature of twelve meridians from quantitative yin-yang theory].

PubMed

Zhao, Xi-xin; Wang, Xue-xia; Zhao, Zhao; Ran, Peng-fei; Lü, Xiao-rui

2009-03-01

Based on leads provided by Neijing and other literature, analyze origins of the three-yin and the three-yang and the their respective contents of yin and yang, indicating the principle that the order of yang-qi from more to less is Yang ming, Tai yang, Shao yang, and the order of yin-qi is Tai yin, Shao yin, Jue yin. According to the location of five (six) zang-organs, respective yin-qi content is defined, and according to the principle of more yin-qi matches more, and less yin-qi matches less, five (six) zang-organs match each other. The zang-organs above the diaphragm joints with The Hand-Channels and the zang-organs below the diaphragm with The Foot-Channels, completing the nomenclature of twelve meridians. The names of the six yang-channels correspond to the yin-channels of the exterior-interior relationship, the yin-channels link with hands (feet), and the yang-channels also link with hands (feet), and the amount of yin-qi of the zang-organs corresponding to the yin-channels and the amount of yang-qi of the fu-organs corresponding to yang-channels are in a state of balance. Based on this principle, nomenclature of six channels are completed. Emphasize that the nomenclature of twelve meridians contains profound TCM theories, especially, TCM, by yin-yang, three-yin and three- yang, illustrates living phenomena from the whole to the system and organ level in human body, and the scientific principle "yin-yang can be unlimitedly divided" and its significance, which must guide the studies on living phenomena with modern life sciences from the whole to the molecular level.

Delta-Tocotrienol Protects Mouse and Human Hematopoietic Progenitors from Gamma-Irradiation Through Erk/mTOR Signaling

DTIC Science & Technology

2010-01-01

δ- tocotrienol protects mouse and human hematopoietic progenitors from γ-irradiation through Erk/mTOR signaling by Xiang Hong Li, Dadin Fu, Nabil H...print] Citation: Li XH, Fu D, Latif NH, Mullaney CP, Ney PH, Mog SR, Whitnall MH, Srinivasan V, and Xiao M. δ- tocotrienol protects mouse and human...2010 2. REPORT TYPE 3. DATES COVERED 00-00-2010 to 00-00-2010 4. TITLE AND SUBTITLE !- tocotrienol protects mouse and human hematopoietic

Molecular Mechanism of Nkx3.1 Deregulation and Its Function in Murine Pten Prostate Cancer Model

DTIC Science & Technology

2005-09-01

we failed to detect any significant alterations in WT grafts. One possible explanation is that Pten null cells have became " addicted " to high levels...Freeman, D. J., Li, A. G., Wei, G., Li, H. H., Kertesz, N., Lesche, R., Whale , A. D., Martinez-Diaz, H., Rozengurt, N., Cardiff, R. D., et al. (2003

Lithium salts for advanced lithium batteries: Li-metal, Li-O 2, and Li-S

DOE PAGES

Younesi, Reza; Veith, Gabriel M.; Johansson, Patrik; ...

2015-06-01

Presently lithium hexafluorophosphate (LiPF 6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF 6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O 2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical andmore » chemical reactions and conditions within such cells. Furthermore, this review explores the critical role Li-salts play in ensuring in these batteries viability.« less

A hydrophobic hole transporting system to improve moisture stability of perovskite solar cells (Conference Presentation)

NASA Astrophysics Data System (ADS)

Xiao, Lixin

2016-09-01

Non-ion additive hole-transporting material (HTM) of hydrophobic oligothiophene derivative named DR3TBDTT and triphenylamine derivative of N,N'-di(3-methylphenyl)-N,N-diphenyl-4,4-diaminobiphenyl (TPD) were used for the organic-inorganic hybrid perovskite solar cells. The power conversion efficiency (PCE) was comparable to the device using Li-TFSI doped spiro-MeOTAD. Moreover, the PCE decreases by only 10% after approximately 1000 h without encapsulation, which suggests an alternative method to improve the stability of perovskite solar cells[1-3 ]. Figure 1. Schematic illustration of the energy diagram of the device without lithium salts REFERENCES [1] Zheng, L.; Ma, Y.; Chu, S.; Wang, S.; Qu, B.; Xiao, L.; Chen, Z.;Gong, Q.; Wu, Z.; Hou, X. Nanoscale 6, 8171-8176 (2014). [2] Zheng Lingling, Chung Yao-Hsien, Ma Yingzhuang, Zhang Lipei, Xiao Lixin, Chen Zhijian, Wang Shufeng, Qu Bo and Gong Qihuang, Chem. Commun. 50, 11196-11199 (2014). [3] Ma Yingzhuang, Chung Yao-Hsien, Zheng Lingling, Zhang Danfei, Yu Xiao, Xiao Lixin, Chen Zhijian, Wang Shufeng, Qu Bo, Gong Qihuang, and Zou Dechun, ACS Appl. Mater. Interfaces 7 (12), 6406-6411 (2015)

Two-spectral Yang-Baxter operators in topological quantum computation

NASA Astrophysics Data System (ADS)

Sanchez, William F.

2011-05-01

One of the current trends in quantum computing is the application of algebraic topological methods in the design of new algorithms and quantum computers, giving rise to topological quantum computing. One of the tools used in it is the Yang-Baxter equation whose solutions are interpreted as universal quantum gates. Lately, more general Yang-Baxter equations have been investigated, making progress as two-spectral equations and Yang-Baxter systems. This paper intends to apply these new findings to the field of topological quantum computation, more specifically, the proposition of the two-spectral Yang-Baxter operators as universal quantum gates for 2 qubits and 2 qutrits systems, obtaining 4x4 and 9x9 matrices respectively, and further elaboration of the corresponding Hamiltonian by the use of computer algebra software Mathematica® and its Qucalc package. In addition, possible physical systems to which the Yang-Baxter operators obtained can be applied are considered. In the present work it is demonstrated the utility of the Yang-Baxter equation to generate universal quantum gates and the power of computer algebra to design them; it is expected that these mathematical studies contribute to the further development of quantum computers

Heavy metal pollution and health risk assessment in the Wei River in China.

PubMed

Yang, Xuefu; Duan, Jinming; Wang, Lei; Li, Wei; Guan, Jianling; Beecham, Simon; Mulcahy, Dennis

2015-03-01

From data collected monthly at 26 monitoring cross sections in the Wei River in the Shaanxi Region of China during the period 2008-2012, the temporal pollution characteristics of heavy metals (Hg, Cd, Cr(VI), Pb, and As) were analyzed based on a heavy metal pollution index (HPI). The monthly HPI values of the five heavy metals in the river fluctuated greatly in 2008 and then declined gradually with time. This general trend of reduction in HPI appears not to have a seasonal variation and most likely resulted from the continued improvement in heavy metal pollution control strategies implemented by local environmental agencies combined with a significant improvement in wastewater treatment capacities. Among the five heavy metals, Cd and Pb were below 0.1 and 3 μg L(-1), respectively, at all the sampling points in the studied areas in the year 2012. The detection rates of As, Hg, and Cr(VI) were in the order of Hg > Cr(VI) > As. Hg, Cr(VI), and As exceeded, in a month of the dry season in 2012, the standard limits for category III surface waters according to the China Environment Quality Standards for Surface Water (CEQSSW). Based on the assessment using the HPI method, the pollution status of these heavy metals in water of the Wei River in the Shaanxi Region was generally at an acceptable level, but exhibited distinctive characteristics between the main stream river and tributaries. Most of the tributaries were more seriously polluted than the main river. A health risk assessment was conducted based on the Human Health Risk Assessment (HHRA) method recommended by the United States Environmental Protection Agency (USEPA). Apart from As, the health risk for the five heavy metals in the region were at acceptable levels for drinking water sources (hazard quotient (HQ) < 1, carcinogenic risk (CR) ranged from 10(-4)-10(-6)) according to the Risk Assessment Guidance for Superfund (RAGS), USEPA. Arsenic was identified as the most important pollutant of concern

GSTM1 AND GSTT1 GENOTYPES AND LUNG CANCER RISK ASSOCIATED WITH EXPOSURE TO INDOOR COAL EMISSIONS: A CASE-CONTROL STUDY IN XUAN WEI, CHINA

EPA Science Inventory

The lung cancer mortality rate in Xuan Wei County, China is among the highest in the country and has been associated with exposure to indoor smoky coal emissions that contain high levels of polycyclic aromatic hydrocarbons. This risk may be modified by variation in metabolism gen...

APC Yin-Yang haplotype associated with colorectal cancer risk

PubMed Central

GARRE, P.; DE LA HOYA, M.; INIESTA, P.; ROMERA, A.; LLOVET, P.; GONZALEZ, S.; PEREZ-SEGURA, P.; CAPELLA, G.; DIAZ-RUBIO, E.; CALDES, T.

2010-01-01

The Yin-Yang haplotype is defined as two mismatched haplotypes (Yin and Yang) representing the majority of the existing haplotypes in a particular genomic region. The human adenomatous polyposis coli (APC) gene shows a Yin-Yang haplotype pattern accounting for 84% of all of the haplotypes existing in the Spanish population. Several association studies have been published regarding APC gene variants (SNPs and haplotypes) and colorectal cancer (CRC) risk. However, no studies concerning diplotype structure and CRC risk have been conducted. The aim of the present study was to investigate whether the APC Yin-Yang homozygote diplotype is over-represented in patients with sporadic CRC when compared to its distribution in controls, and its association with CRC risk. TaqMan® assays were used to genotype three tagSNPs selected across the APC Yin-Yang region. Frequencies of the APC Yin-Yang tagSNP alleles, haplotype and diplotype of 378 CRC cases and 642 controls were compared. Two Spanish CRC group samples were included [Hospital Clínico San Carlos in Madrid (HCSC) and Instituto Catalán de Oncología in Barcelona (ICO)]. Analysis of 157 consecutive CRC patients and 405 control subjects from HCSC showed a significative effect for the risk of CRC (OR=1.93; 95% CI 1.32–2.81; P=0.001). However, this effect was not confirmed in 221 CRC patients and 237 control subjects from ICO (OR=0.89; 95% CI 0.61–1.28; P=0.521). We found a significant association between the APC homozygote Yin-Yang diplotype and the risk of colorectal cancer in the HCSC samples. However, we did not observe this association in the ICO samples. These observations suggest that a study with a larger Spanish cohort is necessary to confirm the effects of the APC Yin-Yang diplotype on the risk of CRC. PMID:22993613

APC Yin-Yang haplotype associated with colorectal cancer risk.

PubMed

Garre, P; DE LA Hoya, M; Iniesta, P; Romera, A; Llovet, P; Gonzalez, S; Perez-Segura, P; Capella, G; Diaz-Rubio, E; Caldes, T

2010-09-01

The Yin-Yang haplotype is defined as two mismatched haplotypes (Yin and Yang) representing the majority of the existing haplotypes in a particular genomic region. The human adenomatous polyposis coli (APC) gene shows a Yin-Yang haplotype pattern accounting for 84% of all of the haplotypes existing in the Spanish population. Several association studies have been published regarding APC gene variants (SNPs and haplotypes) and colorectal cancer (CRC) risk. However, no studies concerning diplotype structure and CRC risk have been conducted. The aim of the present study was to investigate whether the APC Yin-Yang homozygote diplotype is over-represented in patients with sporadic CRC when compared to its distribution in controls, and its association with CRC risk. TaqMan(®) assays were used to genotype three tagSNPs selected across the APC Yin-Yang region. Frequencies of the APC Yin-Yang tagSNP alleles, haplotype and diplotype of 378 CRC cases and 642 controls were compared. Two Spanish CRC group samples were included [Hospital Clínico San Carlos in Madrid (HCSC) and Instituto Catalán de Oncología in Barcelona (ICO)]. Analysis of 157 consecutive CRC patients and 405 control subjects from HCSC showed a significative effect for the risk of CRC (OR=1.93; 95% CI 1.32-2.81; P=0.001). However, this effect was not confirmed in 221 CRC patients and 237 control subjects from ICO (OR=0.89; 95% CI 0.61-1.28; P=0.521). We found a significant association between the APC homozygote Yin-Yang diplotype and the risk of colorectal cancer in the HCSC samples. However, we did not observe this association in the ICO samples. These observations suggest that a study with a larger Spanish cohort is necessary to confirm the effects of the APC Yin-Yang diplotype on the risk of CRC.

Holography and noncommutative yang-mills theory

PubMed

Li; Wu

2000-03-06

In this Letter a recently proposed gravity dual of noncommutative Yang-Mills theory is derived from the relations between closed string moduli and open string moduli recently suggested by Seiberg and Witten. The only new input one needs is a simple form of the running string tension as a function of energy. This derivation provides convincing evidence that string theory integrates with the holographical principle and demonstrates a direct link between noncommutative Yang-Mills theory and holography.

Combined pressure-thermal inactivation effect on spores in lu-wei beef--a traditional Chinese meat product.

PubMed

Wang, B-S; Li, B-S; Du, J-Z; Zeng, Q-X

2015-08-01

This study investigated the inactivation effect and kinetics of Bacillus coagulans and Geobacillus stearothermophilus spores suspended in lu-wei beef by combining high pressure (500 and 600 MPa) and moderate heat (70 and 80 °C or 80 and 90 °C). During pressurization, the temperature of pressure-transmitting fluid was tested with a K-type thermocouple, and the number of surviving cells was determined by a plate count method. The pressure come-up time and corresponding inactivation of Bacillus coagulans and G. stearothermophilus spores were considered during the pressure-thermal treatment. For the two types of spores, the results showed a higher inactivation effect in phosphate buffer solution than that in lu-wei beef. Among the bacteria evaluated, G. stearothermophilus spores had a higher resistance than B. coagulans spores during the pressure-thermal processing. One linear model and two nonlinear models (i.e. the Weibull and log-logistic models) were fitted to the survivor data to obtain relevant kinetic parameters, and the performance of these models was compared. The results suggested that the survival curve of the spores could be accurately described utilizing the log-logistic model, which produced the best fit for all inactivation data. The compression heating characteristics of different pressure-transmitting fluids should be considered when using high pressure to sterilize spores, particularly while the pressure is increasing. Spores can be inactivated by combining high pressure and moderate heat. The study demonstrates the synergistic inactivation effect of moderate heat in combination with high pressure in real-life food. The use of mathematical models to predict the inactivation for spores could help the food industry further to develop optimum process conditions. © 2015 The Society for Applied Microbiology.

Prostate Cancer in African-American Men: Serum Biomarkers for Early Detection Using Nanoparticles

DTIC Science & Technology

2008-11-01

breast cancer cells, Nanomedicine, (2008), 3(3), 283-292. 18 22. Shangguan, Dihua; Meng, Ling; Cao, Zehui Charles; Xiao, Zeyu; Fang, Xiaohong; Li...AD_________________ Award Number: W81XWH-06-1-0034 TITLE: Prostate Cancer in African-American Men...ORGANIZATION: Moffitt Cancer Center Tampa, FL 33612-9497 REPORT DATE: November 2008

Hydrogen retention in Li and Li-C-O films

NASA Astrophysics Data System (ADS)

Buzi, Luxherta; Nelson, Andrew O.; Yang, Yuxin; Kaita, Robert; Koel, Bruce E.

2017-10-01

The efficiency of Li in binding H isotopes has led to reduced recycling in magnetic fusion devices and improved plasma performance. Since elemental Li surfaces are challenging to maintain in fusion devices due to the presence of impurities, parameterizing and understanding the mechanisms for H retention in various Li compounds (Li-C-O), in addition to pure Li, is crucial for Li plasma-facing material applications. To determine H retention in Li and Li-C-O films, measurements were done under ultrahigh vacuum conditions using temperature programmed desorption (TPD). Thin Li films (20 monolayers) were deposited on a nickel single crystal substrate and irradiated with 500 eV H2+ions at surface temperatures from 90K to 520K. Initial measurements on Li and Li-O films showed that the retention was comparable and dropped exponentially with surface temperature, from 95% at 90 K to 35% at 520 K. Auger electron spectroscopy and TPD showed that H was retained as lithium hydride (LiH) in pure Li and as lithium hydroxide (LiOH) in Li2O, which decomposed to H2O and Li2O at temperatures higher than 470K. H retention in Li-C and Li-C-O films will be determined over a similar temperature range, and the sputtering rate of these layers with H ions will also be reported. This material is based upon work supported by the U.S. Department of Energy, Office of Science/Fusion Energy Sciences under Award Number DE-SC0012890.

Radiative double copy for Einstein-Yang-Mills theory

NASA Astrophysics Data System (ADS)

Chester, David

2018-04-01

Recently, a double-copy formalism was used to calculate gravitational radiation from classical Yang-Mills radiation solutions. This work shows that the Yang-Mills theory coupled to a biadjoint scalar field admits a radiative double copy that agrees with solutions in the Einstein-Yang-Mills theory at the lowest finite order. Within this context, the trace-reversed metric h¯μ ν is a natural double copy of the gauge boson Aμ a . This work provides additional evidence that solutions in gauge and gravity theories are related, even though their respective Lagrangians and nonlinear equations of motion appear to be different.

Development of High-Strength Nanostructured Magnesium Alloys for Light-Weight Weapon Systems and Vehicles

DTIC Science & Technology

2014-01-13

strength nanocrystalline Mg-alloys via cryomilling and spark - plasma - sintering , 2) demonstrate the unveil evidence of nanotwins in nanocrystalline...Christopher Melnyk, Wei H. Kao, Jenn-Ming Yang. Cryomilling and spark plasma sintering of nanocrystalline magnesium-based alloy, Journal of Materials...accomplished several important milestones: 1) manufacture of high strength nanocrystalline Mg-alloys via cryomilling and spark plasma sintering (SPS

Explicit formulae for Yang-Mills-Einstein amplitudes from the double copy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chiodaroli, Marco; Günaydin, Murat; Johansson, Henrik

Using the double-copy construction of Yang-Mills-Einstein theories formulated in our earlier work, we obtain compact presentations for single-trace Yang-Mills-Einstein tree amplitudes with up to five external gravitons and an arbitrary number of gluons. These are written as linear combinations of color-ordered Yang-Mills trees, where the coefficients are given by color/kinematics-satisfying numerators in a Yang-Mills + φ 3 theory. The construction outlined in this paper holds in general dimension and extends straightforwardly to supergravity theories. For one, two, and three external gravitons, our expressions give identical or simpler presentations of amplitudes already constructed through string-theory considerations or the scattering equations formalism.more » Our results are based on color/kinematics duality and gauge invariance, and strongly hint at a recursive structure underlying the single-trace amplitudes with an arbitrary number of gravitons. We also present explicit expressions for all-loop single-graviton Einstein-Yang-Mills amplitudes in terms of Yang-Mills amplitudes and, through gauge invariance, derive new all-loop amplitude relations for Yang-Mills theory.« less

Explicit formulae for Yang-Mills-Einstein amplitudes from the double copy

DOE PAGES

Chiodaroli, Marco; Günaydin, Murat; Johansson, Henrik; ...

2017-07-03

Using the double-copy construction of Yang-Mills-Einstein theories formulated in our earlier work, we obtain compact presentations for single-trace Yang-Mills-Einstein tree amplitudes with up to five external gravitons and an arbitrary number of gluons. These are written as linear combinations of color-ordered Yang-Mills trees, where the coefficients are given by color/kinematics-satisfying numerators in a Yang-Mills + φ 3 theory. The construction outlined in this paper holds in general dimension and extends straightforwardly to supergravity theories. For one, two, and three external gravitons, our expressions give identical or simpler presentations of amplitudes already constructed through string-theory considerations or the scattering equations formalism.more » Our results are based on color/kinematics duality and gauge invariance, and strongly hint at a recursive structure underlying the single-trace amplitudes with an arbitrary number of gravitons. We also present explicit expressions for all-loop single-graviton Einstein-Yang-Mills amplitudes in terms of Yang-Mills amplitudes and, through gauge invariance, derive new all-loop amplitude relations for Yang-Mills theory.« less

First Public Report on the Military Academy Chinese People’s Liberation Army Military Pictures Collection (Selected Articles),

DTIC Science & Technology

1986-10-10

Cooperation, by Liu Jienyang, Zhao Rueishan, Ze Fu .......... 35 > A Visit to the Institute of Guided Missile Technology, by Zhang Juzheng, Li Weiliang...4,. *1 .4 9- -I. .p *. .4 I-.- a. S.... .4 11 l.a. 9-.4 *49.4*~*9*~. ° - S’: Key: (1) Analyst Li Xien studies techniques hard in the field in...leader Chairman Hua, Vice Chairmen Ye Jianying , Deng Xiao- ping, Wang Dongxing and other leaders of the party, state and militaryarrived at the

[Herbs for calming liver and suppressing yang in treatment of hyperthyroidism with hyperactive liver yang: herbal effects on lymphocyte protein expression].

PubMed

Li, Xiangping; Yin, Tao; Zhong, Guangwei; Li, Wei; Luo, Yanhong; Xiang, Lingli; Liu, Zhehao

2011-07-01

To observe the herbal effects on hyperthyroidism patients with syndrome of hyperactivity of liver-Yang by method for calming the liver and suppressing Yang and investigate its effects on the lymphocyte protein expression. This approach may lay a foundation for the further investigation of the curative mechanisms of calming the liver and suppressing Yang treatment. A total of 48 hyperthyroidism patients with syndrome of hyperactivity of liver-Yang were randomly divided into treatment group and control group. The treatment group was treated by method for calming the liver and suppressing Yang in accordance with traditional Chinese medicine (TCM) and the control group with thiamazole tablets for three periods of treatment The therapeutic effects, the score of TCM symptom, electrocardiogram (P wave), thyroid hormones and ultrasound were observed in both groups before and after the treatment. The side effects in the treatment course were observed in both groups. The level of differential protein expression was analyzed by two-dimensional electrphoresis and matrix assisted laser desorption/ionizaton time-of-flight mass spectrometry. The treatment group has the effect on stepping down the heart rate, cutting down the P wave amplitude changes, regulating the level of thyroid hormones and decreasing the volume of thyromegaly. There are not statistically significant between the treatment group and control group. However, the treatment group has obviously better effect on regulating TCM symptom and decreasing the side reaction than the control group (P<0.05). There are not statistically significant on the total effective between the treatment group and control group. The average spots in lymphocyte for normal people, before and after treating hyperthyroidism patients with syndrome of hyperactivity of liver-Yang were (429 +/- 31), (452 +/- 28) and (437 +/- 36) spots respectively. Eight down-regulated protein expressions and 11 up-regulated protein expressions were obtained in

Spontaneous Vortices in Imbalance Populated Fermion Gas, Finite Size System

NASA Astrophysics Data System (ADS)

Su, Jung-Jung; Shim, Yun-Pil; Duine, Rembert; MacDonald, Allan H.

2006-05-01

Atomic Fermion gases with mismatched densities have attracted much interest recently both experimentally and theoretically. These gases are related to superconductors in a magnetic field, to color superconductivity in high density QCD and to other systems. The main focus of recent research is on the possibility of unusual pairing states, the Larkin-Ovchinnikov-Fulde-Ferrel(LOFF)[1] phase, the Deformed Fermi surface(DFS)[2] and other states have been suggested in the past few years. We work specifically on two-dimensional systems with circular hard walls which contain atoms with two different hyperfine states and different populations. In addition to phase separation, a phenomenon that has already been observed[3], we consider the possibility of the spontaneous formation of vortices and giant vortices in some regions of parameter space. [1] Qinghong Cui, C.-R. Hu, J.Y.T. Wei, and Kun Yang, cond-mat/0510717 [2] Armen Sedrakian, Jordi Mur-Petit, Artur Polls, Herbert M"uther , cond-mat/0404577 [3] Guthrie B. Partridge, Wenhui Li, Ramsey I. Kamar, Yean-an Liao, Randall G. Hulet, cond-mat/0511752

Impact of LUCC on streamflow based on the SWAT model over the Wei River basin on the Loess Plateau in China

NASA Astrophysics Data System (ADS)

Wang, Hong; Sun, Fubao; Xia, Jun; Liu, Wenbin

2017-04-01

Under the Grain for Green Project in China, vegetation recovery construction has been widely implemented on the Loess Plateau for the purpose of soil and water conservation. Now it is becoming controversial whether the recovery construction involving vegetation, particularly forest, is reducing the streamflow in the rivers of the Yellow River basin. In this study, we chose the Wei River, the largest branch of the Yellow River, with revegetated construction area as the study area. To do that, we apply the widely used Soil and Water Assessment Tool (SWAT) model for the upper and middle reaches of the Wei River basin. The SWAT model was forced with daily observed meteorological forcings (1960-2009) calibrated against daily streamflow for 1960-1969, validated for the period of 1970-1979, and used for analysis for 1980-2009. To investigate the impact of LUCC (land use and land cover change) on the streamflow, we firstly use two observed land use maps from 1980 and 2005 that are based on national land survey statistics merged with satellite observations. We found that the mean streamflow generated by using the 2005 land use map decreased in comparison with that using the 1980 one, with the same meteorological forcings. Of particular interest here is that the streamflow decreased on agricultural land but increased in forest areas. More specifically, the surface runoff, soil flow, and baseflow all decreased on agricultural land, while the soil flow and baseflow of forest areas increased. To investigate that, we then designed five scenarios: (S1) the present land use (1980) and (S2) 10 %, (S3) 20 %, (S4) 40 %, and (S5) 100 % of agricultural land that was converted into mixed forest. We found that the streamflow consistently increased with agricultural land converted into forest by about 7.4 mm per 10 %. Our modeling results suggest that forest recovery construction has a positive impact on both soil flow and baseflow by compensating for reduced surface runoff, which leads

Molecular Relaxation in LiNO3-LiClO4 and Li2CO3-Li2SO4 Solid Binary Systems

NASA Astrophysics Data System (ADS)

Aliev, A. R.; Akhmedov, I. R.; Kakagasanov, M. G.; Aliev, Z. A.; Gafurov, M. M.; Amirov, A. M.

2018-06-01

The paper presents spectroscopic combinational scattering investigations of the molecular relaxation in LiNO3-LiClO4 and Li2CO3-Li2SO4 solid binary systems. It is found that the relaxation time for ν1(A) vibrations of NO3 - anion in LiNO3-LiClO4 system is lower than in LiNO3 crystal. And the relaxation time for ν1(A) vibrations of CO3 2- anion in Li2CO3-Li2SO4 system is lower than in Li2CO3 crystal. The increase in the relaxation time is explained by the additional relaxation mechanism of the excited mode of nitrate and carbon ions which is observed in these systems. This mechanism is linked to the vibrations of other anions (ClO4 - or SO4 2-) and a nucleation of the lattice phonon. Experiments show that the additional relaxation mechanism occurs due to the vibration difference which corresponds to the area of rather a high density of states of the phonon spectrum.

Ab initio and kinetic Monte Carlo study of lithium diffusion in LiSi, Li12Si7, Li13Si5 and Li15Si4

NASA Astrophysics Data System (ADS)

Moon, Janghyuk; Lee, Byeongchan; Cho, Maenghyo; Cho, Kyeongjae

2016-10-01

The kinetics of lithium atoms in various Li-Si binary compounds are investigated using density functional theory calculations and kinetic Monte Carlo calculations. The values of the Li migration energy barriers are identified by NEB calculations with vacancy-mediated, interstitial and exchange migration mechanisms in crystalline LiSi, Li12Si7, Li13Si4, and Li15Si4. A comparison of these NEB results shows that the vacancy-mediated Li migration is identified as the dominant diffusion mechanisms in Li-Si compounds. The diffusion coefficients of Li in Li-Si compounds at room temperature are determined by KMC simulation. From the KMC results, the recalculated migration energy barriers in LiSi, Li12Si7, Li13Si4, and Li15Si4 correspond to 0.306, 0.301, 0.367 and 0.320 eV, respectively. Compared to the Li migration energy barrier of 0.6 eV in crystalline Si, the drastic reduction in the Li migration energy barriers in the lithiated silicon indicates that the initial lithiation of the Si anode is the rate-limiting step. Furthermore, it is also found that Si migration is possible in Li-rich configurations. On the basis of these findings, the underlying mechanisms of kinetics on the atomic scale details are elucidated.

Bäcklund Transformations in 10D SUSY Yang-Mills Theories

NASA Astrophysics Data System (ADS)

Gervais, Jean-Loup

A Bäcklund transformation is derived for the Yang's type (super) equations previously derived (hep-th/9811108) by M. Saveliev and the author, from the ten-dimensional super-Yang-Mills field equations in an on-shell light cone gauge. It is shown to be based upon a particular gauge transformation satisfying nonlinear conditions which ensure that the equations retain the same form. These Yang's type field equations are shown to be precisely such that they automatically provide a solution of these conditions. This Bäcklund transformation is similar to the one proposed by A. Leznov for self-dual Yang-Mills in four dimensions. In the introduction a personal recollection on the birth of supersymmetry is given.

Comment on ``Numerics of the lattice Boltzmann method: Effects of collision models on the lattice Boltzmann simulations''

NASA Astrophysics Data System (ADS)

Karlin, I. V.; Succi, S.; Chikatamarla, S. S.

2011-12-01

Critical comments on the entropic lattice Boltzmann equation (ELBE), by Li-Shi Luo, Wei Liao, Xingwang Chen, Yan Peng, and Wei Zhang in Ref. , are based on simulations, which make use of a model that, despite being referred to as the ELBE by the authors, is in fact equivalent to the standard lattice Bhatnagar-Gross-Krook equation for low Mach number simulations. In this Comment, a concise review of the ELBE is provided and illustrated by means of a three-dimensional turbulent flow simulation, which highlights the subgrid features of the ELBE.

Mengjin Yang | NREL

Science.gov Websites

on the formation of higher efficiency formamidinium lead triiodide-based solar cells," Chem -0003-2019-4298 Dr. Mengjin Yang received his Ph.D. in Materials Science from the University of Pittsburgh, where he investigated nanomaterials for solar energy conversion under the supervision of Prof

RNA Chimeras as a Gene Signature of Breast Cancer

DTIC Science & Technology

2014-06-01

respectively, migrated as expected from their formula molecular weight (FMW), when a 10% divergence, i.e 36-44 kD or 23-29 kD, is considered as the wild...yang2, Hai-hong Shen3, Gung-wei Chirn4, Jian-hua Zhou5, Emily Weiss2, Emily Pauline Holman2, D. Joshua Liao2* 1 Guangxi Veterinary Research Institute

Kinetic measurement and prediction of the hydrogen outgassing from the polycrystalline LiH/Li 2O/LiOH system

NASA Astrophysics Data System (ADS)

Dinh, L. N.; Grant, D. M.; Schildbach, M. A.; Smith, R. A.; Siekhaus, W. J.; Balazs, B.; Leckey, J. H.; Kirkpatrick, J. R.; McLean, W.

2005-12-01

Due to the exothermic reaction of lithium hydride (LiH) salt with water during transportation and handling, there is always a thin film of lithium hydroxide (LiOH) present on the LiH surface. In dry or vacuum storage, this thin LiOH film slowly decomposes. The technique of temperature-programmed reaction/decomposition (TPR) was employed in combination with the isoconversion method of thermal analysis to determine the outgassing kinetics of H 2O from pure LiOH and H 2 and H 2O from this thin LiOH film. H 2 production via the reaction of LiH with LiOH, forming a lithium oxide (Li 2O) interlayer, is thermodynamically favored, with the rate of further reaction limited by diffusion through the Li 2O and the stability of the decomposing LiOH. Lithium hydroxide at the LiOH/vacuum interface also decomposes easily to Li 2O, releasing H 2O which subsequently reacts with LiH in a closed system to form H 2. At the onset of dry decomposition, where H 2 is the predominant product, the activation energy for outgassing from a thin LiOH film is lower than that for bulk LiOH. However, as the reactions at the LiH/Li 2O/LiOH and at the LiOH/vacuum interfaces proceed, the overall activation energy barrier for the outgassing approaches that of bulk LiOH decomposition. The kinetics developed here predict a hydrogen evolution profile in good agreement with hydrogen release observed during long term isothermal storage.

Reliable Internet Routing

DTIC Science & Technology

2011-09-01

global coordination. IEEE/ACM Trans. Netw., 9(6):681–692, 2001. [39] S. Goldberg, D. Xiao, E. Tromer, B. Barak , and J. Rexford. Path-quality monitoring...RFC 4271). [81] Y. Rekhter, T. Li, and S. Hares. A border gateway protocol 4 (BGP-4), 2006. IETF RFC 4271. [82] E. Rosen , A. Viswanathan, and R. Callon

New molten salt systems for high-temperature molten salt batteries: LiF-LiCl-LiBr-based quaternary systems

NASA Astrophysics Data System (ADS)

Fujiwara, Syozo; Inaba, Minoru; Tasaka, Akimasa

To develop novel multi-component molten salt systems more effectively, we developed a simulative technique using the CALPHAD (Calculation of Phase Diagram and Thermodynamics) method to estimate the ionic conductivity and the melting point. The validity of this new simulative technique was confirmed by comparing the simulated ionic conductivities and melting points of typical high-temperature molten salts, such as LiF-LiCl-LiBr, LiF-LiBr-KBr, LiCl-LiBr-KBr, and LiCl-LiBr-LiI, with those reported data in the literature or experimentally obtained. This simulative technique was used to develop new quaternary molten salt systems for use as electrolytes in high-temperature molten salt batteries (called thermal batteries). The targets of the ionic conductivity and the melting point were set at 2.0 S cm -1 and higher at 500 °C, and in the range of 350-430 °C, respectively, to replace the LiCl-KCl system (1.85 S cm -1 at 500 °C) within the conventional design of the heat generation system for thermal batteries. Using the simulative method, six kinds of novel quaternary systems, LiF-LiCl-LiBr-MX (M = Na and K; X = F, Cl, and Br), which contain neither environmentally instable anions such as iodides nor expensive cations such as Rb + and Cs +, were proposed. Experimental results showed that the LiF-LiCl-LiBr-0.10NaX (X = Cl and Br) and LiF-LiCl-LiBr-0.10KX (X = F, Cl, and Br) systems meet our targets of both the ionic conductivity and the melting point.

Unravelling Li-Ion Transport from Picoseconds to Seconds: Bulk versus Interfaces in an Argyrodite Li6PS5Cl-Li2S All-Solid-State Li-Ion Battery.

PubMed

Yu, Chuang; Ganapathy, Swapna; de Klerk, Niek J J; Roslon, Irek; van Eck, Ernst R H; Kentgens, Arno P M; Wagemaker, Marnix

2016-09-07

One of the main challenges of all-solid-state Li-ion batteries is the restricted power density due to the poor Li-ion transport between the electrodes via the electrolyte. However, to establish what diffusional process is the bottleneck for Li-ion transport requires the ability to distinguish the various processes. The present work investigates the Li-ion diffusion in argyrodite Li6PS5Cl, a promising electrolyte based on its high Li-ion conductivity, using a combination of (7)Li NMR experiments and DFT based molecular dynamics simulations. This allows us to distinguish the local Li-ion mobility from the long-range Li-ion motional process, quantifying both and giving a coherent and consistent picture of the bulk diffusion in Li6PS5Cl. NMR exchange experiments are used to unambiguously characterize Li-ion transport over the solid electrolyte-electrode interface for the electrolyte-electrode combination Li6PS5Cl-Li2S, giving unprecedented and direct quantitative insight into the impact of the interface on Li-ion charge transport in all-solid-state batteries. The limited Li-ion transport over the Li6PS5Cl-Li2S interface, orders of magnitude smaller compared with that in the bulk Li6PS5Cl, appears to be the bottleneck for the performance of the Li6PS5Cl-Li2S battery, quantifying one of the major challenges toward improved performance of all-solid-state batteries.

China Report: Political, Sociological and Military Affairs. No. 429

DTIC Science & Technology

1983-06-10

according to the number of strokes in the family name. Wang Wei, (Wang Dachuan), (Wang Xinmin), Lu Liang, Lu Yukun, Zhu Danhua (female), (Liu Jiufeng...Li Shanyuan), He Shikun, (Shen Gan), Shen Hanqing, (Du Shijiu), Lu Xiaopeng, (Pu Jiguang), (Zhang Yulong), (Zhang Xiren), (Zhang Xiuxi), (Zhang...the session in accordance with the CPPCC Constitution. Wu Ping was elected chairman and Li Shizhang, Gu Jiguang, He Shikun, Lu Xiaopeng, Shen

N = 2* Yang-Mills on the Lattice

NASA Astrophysics Data System (ADS)

Joseph, Anosh

2018-03-01

The N = 2* Yang-Mills theory in four dimensions is a non-conformal theory that appears as a mass deformation of maximally supersymmetric N = 4 Yang-Mills theory. This theory also takes part in the AdS/CFT correspondence and its gravity dual is type IIB supergravity on the Pilch-Warner background. The finite temperature properties of this theory have been studied recently in the literature. It has been argued that at large N and strong coupling this theory exhibits no thermal phase transition at any nonzero temperature. The low temperature N = 2* plasma can be compared to the QCD plasma. We provide a lattice construction of N = 2* Yang-Mills on a hypercubic lattice starting from the N = 4 gauge theory. The lattice construction is local, gauge-invariant, free from fermion doubling problem and preserves a part of the supersymmetry. This nonperturbative formulation of the theory can be used to provide a highly nontrivial check of the AdS/CFT correspondence in a non-conformal theory.

No-go for partially massless spin-2 Yang-Mills

DOE PAGES

Garcia-Saenz, Sebastian; Hinterbichler, Kurt; Joyce, Austin; ...

2016-02-05

There are various no-go results forbidding self-interactions for a single partially massless spin-2 field. Given the photon-like structure of the linear partially massless field, it is natural to ask whether a multiplet of such fields can interact under an internal Yang-Mills like extension of the partially massless symmetry. In this paper, we give two arguments that such a partially massless Yang-Mills theory does not exist. The first is that there is no Yang-Mills like non-abelian deformation of the partially massless symmetry, and the second is that cubic vertices with the appropriate structure constants do not exist.

Madame Li Li: Communist Revolutionary, Adult Educator, Lifelong Learner

ERIC Educational Resources Information Center

Boshier, Roger; Huang, Yan

2009-01-01

Prior to 1949 the Chinese Communist Party orchestrated innovative and participatory forms of adult education. This article concerns Madame Li Li, a leading Chinese Communist woman adult educator. Western delegates at the International Council for Adult Education 1984 Shanghai symposium on adult education were fascinated by Madame Li Li because,…

On the Corrosion Performance of Monel 400 in Molten LiCl-Li2O-Li at 923 K

NASA Astrophysics Data System (ADS)

Phillips, William; Merwin, Augustus; Chidambaram, Dev

2018-06-01

The corrosion resistance of a Ni-Cu alloy, Monel 400, in molten LiCl-Li2O-Li at 923 K (650 °C) was investigated. Exposure testing of Monel 400 samples submerged in molten LiCl-2 wt pct Li2O solutions with Li concentrations between zero and 1 wt pct was performed at 923 K (650°C) for 20 hours. Post exposure surface analysis was performed using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, optical microscopy, micro-Vickers hardness testing, and X-ray photoelectron spectroscopy, while inductively coupled plasma optical emission spectroscopy was used to quantify the rate of material leaching. The extent of material degradation was observed to be strongly correlated to the concentration of metallic Li in the molten LiCl-Li2O system.

Li + Defects in a Solid-State Li Ion Battery: Theoretical Insights with a Li 3 OCl Electrolyte

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stegmaier, Saskia; Voss, Johannes; Reuter, Karsten

In a solid-state Li ion battery, the solid-state electrolyte exits principally in regions of high externally applied potentials, and this varies rapidly at the interfaces with electrodes due to the formation of electrochemical double layers. Here, we investigate the implications of these for a model solid-state Li ion battery Li|Li 3OCl|C, where C is simply a metallic intercalation cathode. We use DFT to calculate the potential dependence of the formation energies of the Li + charge carriers in superionic Li 3OCl. We find that Li+ vacancies are the dominant species at the cathode while Li+ interstitials dominate at the anode.more » With typical Mg aliovalent doping of Li 3OCl, Li + vacancies dominate the bulk of the electrolyte as well, with freely mobile vacancies only ~ 10 -4 of the Mg doping density at room temperature. We study the repulsive interaction between Li+ vacancies and find that this is extremely short range, typically only one lattice constant due to local structural relaxation around the vacancy and this is significantly shorter than pure electrostatic screening. We model a Li 3OCl- cathode interface by treating the cathode as a nearly ideal metal using a polarizable continuum model with an ε r = 1000. There is a large interface segregation free energy of ~ - 1 eV per Li + vacancy. Combined with the short range for repulsive interactions of the vacancies, this means that very large vacancy concentrations will build up in a single layer of Li 3OCl at the cathode interface to form a compact double layer. The calculated potential drop across the interface is ~ 3 V for a nearly full concentration of vacancies at the surface. This suggests that nearly all the cathode potential drop in Li 3OCl occurs at the Helmholtz plane rather than in a diffuse space-charge region. We suggest that the conclusions found here will be general to other superionic conductors as well.« less

Li + Defects in a Solid-State Li Ion Battery: Theoretical Insights with a Li 3 OCl Electrolyte

DOE PAGES

Stegmaier, Saskia; Voss, Johannes; Reuter, Karsten; ...

2017-04-26

In a solid-state Li ion battery, the solid-state electrolyte exits principally in regions of high externally applied potentials, and this varies rapidly at the interfaces with electrodes due to the formation of electrochemical double layers. Here, we investigate the implications of these for a model solid-state Li ion battery Li|Li 3OCl|C, where C is simply a metallic intercalation cathode. We use DFT to calculate the potential dependence of the formation energies of the Li + charge carriers in superionic Li 3OCl. We find that Li+ vacancies are the dominant species at the cathode while Li+ interstitials dominate at the anode.more » With typical Mg aliovalent doping of Li 3OCl, Li + vacancies dominate the bulk of the electrolyte as well, with freely mobile vacancies only ~ 10 -4 of the Mg doping density at room temperature. We study the repulsive interaction between Li+ vacancies and find that this is extremely short range, typically only one lattice constant due to local structural relaxation around the vacancy and this is significantly shorter than pure electrostatic screening. We model a Li 3OCl- cathode interface by treating the cathode as a nearly ideal metal using a polarizable continuum model with an ε r = 1000. There is a large interface segregation free energy of ~ - 1 eV per Li + vacancy. Combined with the short range for repulsive interactions of the vacancies, this means that very large vacancy concentrations will build up in a single layer of Li 3OCl at the cathode interface to form a compact double layer. The calculated potential drop across the interface is ~ 3 V for a nearly full concentration of vacancies at the surface. This suggests that nearly all the cathode potential drop in Li 3OCl occurs at the Helmholtz plane rather than in a diffuse space-charge region. We suggest that the conclusions found here will be general to other superionic conductors as well.« less

Description of two new species of the Neoperla montivaga group (Plecoptera: Perlidae) from Guangxi Zhuang Autonomous Region, China.

PubMed

Yang, Juan; Zhang, Sujiong; Li, Weihai

2017-03-05

The following two new species from Shiwandashan of Guangxi Zhuang Autonomous Region, China are described, Neoperla bicolor Yang, Zhang & Li, sp. nov. and N. muranyii Yang, Zhang & Li, sp. nov. The new species are compared with related congeners of their respective species subgroups.

ZN graded discrete Lax pairs and Yang-Baxter maps

NASA Astrophysics Data System (ADS)

Fordy, Allan P.; Xenitidis, Pavlos

2017-05-01

We recently introduced a class of ZN graded discrete Lax pairs and studied the associated discrete integrable systems (lattice equations). In this paper, we introduce the corresponding Yang-Baxter maps. Many well-known examples belong to this scheme for N=2, so, for N≥3, our systems may be regarded as generalizations of these. In particular, for each N we introduce a class of multi-component Yang-Baxter maps, which include H^{B_{III (of Papageorgiou et al. 2010 SIGMA 6, 003 (9 p). (doi:10.3842/SIGMA.2010.033)), when N=2, and that associated with the discrete modified Boussinesq equation, for N=3. For N≥5 we introduce a new family of Yang-Baxter maps, which have no lower dimensional analogue. We also present new multi-component versions of the Yang-Baxter maps FIV and FV (given in the classification of Adler et al. 2004 Commun. Anal. Geom. 12, 967-1007. (doi:10.4310/CAG.2004.v12.n5.a1)).}}

Understanding the polypharmacological anticancer effects of Xiao Chai Hu Tang via a computational pharmacological model

PubMed Central

ZHENG, CHUN-SONG; WU, YIN-SHENG; BAO, HONG-JUAN; XU, XIAO-JIE; CHEN, XING-QIANG; YE, HONG-ZHI; WU, GUANG-WEN; XU, HUI-FENG; LI, XI-HAI; CHEN, JIA-SHOU; LIU, XIAN-XIANG

2014-01-01

Xiao Chai Hu Tang (XCHT), a traditional herbal formula, is widely administered as a cancer treatment. However, the underlying molecular mechanisms of its anticancer effects are not fully understood. In the present study, a computational pharmacological model that combined chemical space mapping, molecular docking and network analysis was employed to predict which chemical compounds in XCHT are potential inhibitors of cancer-associated targets, and to establish a compound-target (C-T) network and compound-compound (C-C) association network. The identified compounds from XCHT demonstrated diversity in chemical space. Furthermore, they occupied regions of chemical space that were the same, or close to, those occupied by drug or drug-like compounds that are associated with cancer, according to the Therapeutic Targets Database. The analysis of the molecular docking and the C-T network demonstrated that the potential inhibitors possessed the properties of promiscuous drugs and combination therapies. The C-C network was classified into four clusters and the different clusters contained various multi-compound combinations that acted on different targets. The study indicated that XCHT has a polypharmacological role in treating cancer and the potential inhibitory components of XCHT require further investigation as potential therapeutic strategies for cancer patients. PMID:24926384

YANG-MILLS Theory in, Beyond, and Behind Observed Reality

NASA Astrophysics Data System (ADS)

Wilczek, Frank

The primary interactions of Yang-Mills theory [1] are visibly embodied in hard processes, most directly in jets. The character of jets also reflects the deep structure of effective charge, which is dominated by the influence of intrinsically non-Abelian gauge dynamics. These proven insights into fundamental physics ramify in many directions, and are far from being exhausted. I will discuss three rewarding explorations from my own experience, whose point of departure is the hard Yang-Mills interaction, and whose end is not yet in sight. Given an insight so profound and fruitful as Yang and Mills brought us, it is in order to try to consider its broadest implications, which I attempt at the end.

On integrability of the Yang-Baxter {sigma}-model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klimcik, Ctirad

2009-04-15

We prove that the recently introduced Yang-Baxter {sigma}-model can be considered as an integrable deformation of the principal chiral model. We find also an explicit one-to-one map transforming every solution of the principal chiral model into a solution of the deformed model. With the help of this map, the standard procedure of the dressing of the principal chiral solutions can be directly transferred into the deformed Yang-Baxter context.

Experimental realization of the Yang-Baxter Equation via NMR interferometry.

PubMed

Vind, F Anvari; Foerster, A; Oliveira, I S; Sarthour, R S; Soares-Pinto, D O; Souza, A M; Roditi, I

2016-02-10

The Yang-Baxter equation is an important tool in theoretical physics, with many applications in different domains that span from condensed matter to string theory. Recently, the interest on the equation has increased due to its connection to quantum information processing. It has been shown that the Yang-Baxter equation is closely related to quantum entanglement and quantum computation. Therefore, owing to the broad relevance of this equation, besides theoretical studies, it also became significant to pursue its experimental implementation. Here, we show an experimental realization of the Yang-Baxter equation and verify its validity through a Nuclear Magnetic Resonance (NMR) interferometric setup. Our experiment was performed on a liquid state Iodotrifluoroethylene sample which contains molecules with three qubits. We use Controlled-transfer gates that allow us to build a pseudo-pure state from which we are able to apply a quantum information protocol that implements the Yang-Baxter equation.

The Role of Stat3 Activation in Androgen Receptor Signaling and Prostate Cancer

DTIC Science & Technology

2006-07-01

S. C. & Xiao, G. (2003) Cancer Metastasis Rev. 22, 405–422. 10. Karin, M. & Greten , F. R. (2005) Nat. Rev. Immunol. 5, 749–759. 11. Karin, M., Cao, Y... Greten , F. R. & Li, Z. W. (2002) Nat. Rev. Cancer 2, 301–310. 12. Fan, C. M. & Maniatis, T. (1991) Nature 354, 395–398. 13. Betts, J. C. & Nabel, G

Functionalizing Carbon Nanotubes and Related Nanostructures for Various Applications

DTIC Science & Technology

2010-10-26

Hsu-Cheng Hsu, Ying-Chieh Liao, Po-Han Tseng, Yen -Ting Chen, Zhe-Chuan Feng, Li-Wei Tu, Mitch M. C. Chou, Li-Chyong Chen*, and Kuei-Hsien Chen*, J...Final Report for AOARD Grant 09-4050 “Functionalizing Carbon Nanotubes and Related Nanostructures for Various Applications” AFOSR/AOARD...Research Fellow Institute of Atomic and Molecular Sciences, Academia Sinica PO Box 23-166, Taipei 106, Taiwan Tel: 886-2-2366-8232; Fax: 886-2-2362

Systematics of the east Palaearctic pear psyllids (Hemiptera: Psylloidea) with particular focus on the Japanese and Korean fauna.

PubMed

Cho, Geonho; Burckhardt, Daniel; Inoue, Hiromitsu; Luo, Xinyu; Lee, Seunghwan

2017-12-04

The confused taxonomy of the east Palaearctic pear psyllids, serious pests on cultivated pear, is reviewed. Fifty-six nominal species have been reported from Pyrus, 25 of which we consider valid and ten as not being associated with Pyrus. Our taxonomic revision suggests that, in Korea, four Cacopsylla species develop on pear: the univoltine C. burckhardti Luo et al. previously misidentified as C. pyrisuga (Foerster), the polyvoltine, seasonally dimorphic C. jukyungi (Kwon) (winter form 'cinereosignata' Luo et al., summer form 'jukyungi'), commonly found in Korean pear orchards, and C. maculatili Li (winter form 'maculatili', summer form 'qiuzili' Li) previously misidentified as C. pyricola (Foerster) by some authors, as well as the probably polyvoltine but not dimorphic C. sandolbaea (Park & Lee). The former three species (C. burckhardti, C. jukyungi, misidentified as C. chinensis (Yang & Li), and C. maculatili) occur also in Japan. Keys to the adult and fifth instar immatures as well as short biological notes are provided, and C. jukyungi and C. sandolbaea are redescribed. Following nomenclatorial changes are proposed: Cacopsylla betulaefoliae (Yang & Li, 1981) = Psylla heterobetulaefoliae Yang & Li, 1981, syn. nov.; Cacopsylla bidens (Šulc, 1907) = Psylla jiangli Yang & Li, 1981, syn. nov.; Cacopsylla jukyungi (Kwon) = C. cinereosignata Luo et al., syn. nov.; Cacopsylla maculatili Li = C. qiuzili Li, syn. nov.; Cacopsylla nigella (Konovalova), comb. nov. from Psylla. The synonymy of P. obongsana Kwon with C. sandolbaea is confirmed.

In Vivo Role of Six1 in Mammary Gland Tumorigenesis

DTIC Science & Technology

2008-04-01

overexpression is documented in a number of tumor types, including ovarian cancer, hepatocellular carcinoma , Wilms’ tumor, rhabdomyosarcomas and... hepatocellular carcinoma . British Journal of Cancer 95:1050-5. 5. Li, C.M., Guo, M., Borczuk, A., Powell, C.A., Wei, M., Thaker, H.M., Friedman, R

Opportunities and Challenges of Bilingualism. Contributions to the Sociology of Language.

ERIC Educational Resources Information Center

Wei, Li, Ed.; Dewaele, Jean-Marc, Ed.; Housen, Alex, Ed.

This collection of papers examines, from an international perspective, opportunities and challenges of societal bilingualism in the new millennium. The 18 papers include the following: "Introduction: Opportunities and Challenges of Bilingualism" (Li Wei, Jean-Marc Dewaele, and Alex Housen); "'Holy Languages' in the Context of…

Tests of conformal field theory at the Yang-Lee singularity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wydro, Tomasz; McCabe, John F.

2009-12-14

This paper studies the Yang-Lee edge singularity of 2-dimensional (2D) Ising model based on a quantum spin chain and transfer matrix measurements on the cylinder. Based on finite-size scaling, the low-lying excitation spectrum is found at the Yang-Lee edge singularity. Based on transfer matrix techniques, the single structure constant is evaluated at the Yang-Lee edge singularity. The results of both types of measurements are found to be fully consistent with the predictions for the (A{sub 4}, A{sub 1}) minimal conformal field theory, which was previously identified with this critical point.

Aβ Damages Learning and Memory in Alzheimer's Disease Rats with Kidney-Yang Deficiency

PubMed Central

Qi, Dongmei; Qiao, Yongfa; Zhang, Xin; Yu, Huijuan; Cheng, Bin; Qiao, Haifa

2012-01-01

Previous studies demonstrated that Alzheimer's disease was considered as the consequence produced by deficiency of Kidney essence. However, the mechanism underlying the symptoms also remains elusive. Here we report that spatial learning and memory, escape, and swimming capacities were damaged significantly in Kidney-yang deficiency rats. Indeed, both hippocampal Aβ 40 and 42 increases in Kidney-yang deficiency contribute to the learning and memory impairments. Specifically, damage of synaptic plasticity is involved in the learning and memory impairment of Kidney-yang deficiency rats. We determined that the learning and memory damage in Kidney-yang deficiency due to synaptic plasticity impairment and increases of Aβ 40 and 42 was not caused via NMDA receptor internalization induced by Aβ increase. β-Adrenergic receptor agonist can rescue the impaired long-term potential (LTP) in Kidney-yang rats. Taken together, our results suggest that spatial learning and memory inhibited in Kidney-yang deficiency might be induced by Aβ increase and the decrease of β 2 receptor function in glia. PMID:22645624

Kinetic Monte Carlo Study of Li Intercalation in LiFePO4.

PubMed

Xiao, Penghao; Henkelman, Graeme

2018-01-23

Even as a commercial cathode material, LiFePO 4 remains of tremendous research interest for understanding Li intercalation dynamics. The partially lithiated material spontaneously separates into Li-poor and Li-rich phases at equilibrium. Phase segregation is a surprising property of LiFePO 4 given its high measured rate capability. Previous theoretical studies, aiming to describe Li intercalation in LiFePO 4 , include both atomic-scale density functional theory (DFT) calculations of static Li distributions and entire-particle-scale phase field models, based upon empirical parameters, studying the dynamics of the phase separation. Little effort has been made to bridge the gap between these two scales. In this work, DFT calculations are used to fit a cluster expansion for the basis of kinetic Monte Carlo calculations, which enables long time scale simulations with accurate atomic interactions. This atomistic model shows how the phases evolve in Li x FePO 4 without parameters from experiments. Our simulations reveal that an ordered Li 0.5 FePO4 phase with alternating Li-rich and Li-poor planes along the ac direction forms between the LiFePO 4 and FePO 4 phases, which is consistent with recent X-ray diffraction experiments showing peaks associated with an intermediate-Li phase. The calculations also help to explain a recent puzzling experiment showing that LiFePO 4 particles with high aspect ratios that are narrower along the [100] direction, perpendicular to the [010] Li diffusion channels, actually have better rate capabilities. Our calculations show that lateral surfaces parallel to the Li diffusion channels, as well as other preexisting sites that bind Li weakly, are important for phase nucleation and rapid cycling performance.

Li Distribution Heterogeneity in Solid Electrolyte Li10GeP2S12 upon Electrochemical Cycling Probed by 7Li MRI.

PubMed

Chien, Po-Hsiu; Feng, Xuyong; Tang, Mingxue; Rosenberg, Jens T; O'Neill, Sean; Zheng, Jin; Grant, Samuel C; Hu, Yan-Yan

2018-04-19

All-solid-state rechargeable batteries embody the promise for high energy density, increased stability, and improved safety. However, their success is impeded by high resistance for mass and charge transfer at electrode-electrolyte interfaces. Li deficiency has been proposed as a major culprit for interfacial resistance, yet experimental evidence is elusive due to the challenges associated with noninvasively probing the Li distribution in solid electrolytes. In this Letter, three-dimensional 7 Li magnetic resonance imaging (MRI) is employed to examine Li distribution homogeneity in solid electrolyte Li 10 GeP 2 S 12 within symmetric Li/Li 10 GeP 2 S 12 /Li batteries. 7 Li MRI and the derived histograms reveal Li depletion from the electrode-electrolyte interfaces and increased heterogeneity of Li distribution upon electrochemical cycling. Significant Li loss at interfaces is mitigated via facile modification with a poly(ethylene oxide)/bis(trifluoromethane)sulfonimide Li salt thin film. This study demonstrates a powerful tool for noninvasively monitoring the Li distribution at the interfaces and in the bulk of all-solid-state batteries as well as a convenient strategy for improving interfacial stability.

Thermal stability of LiPF 6 salt and Li-ion battery electrolytes containing LiPF 6

NASA Astrophysics Data System (ADS)

Yang, Hui; Zhuang, Guorong V.; Ross, Philip N.

The thermal stability of the neat lithium hexafluorophosphate (LiPF 6) salt and of 1 molal (m) solutions of LiPF 6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line Fourier transform infrared (FTIR). Pure LiPF 6 salt is thermally stable up to 107 °C in a dry inert atmosphere, and its decomposition path is a simple dissociation producing lithium fluoride (LiF) as solid and PF 5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF 6 and water vapor to form phosphorous oxyfluoride (POF 3) and hydrofluoric acid (HF). No new products were observed in 1 m solutions of LiPF 6 in ethylene carbonate (EC), dimethyl carbonate (DMC) and ethyl methyl carbonate (EMC) by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 85 °C for 300-420 h did not produce any significant quantity of new products as well. In particular, no alkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF 6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

Li2S Film Formation on Lithium Anode Surface of Li-S batteries.

PubMed

Liu, Zhixiao; Bertolini, Samuel; Balbuena, Perla B; Mukherjee, Partha P

2016-02-01

The precipitation of lithium sulfide (Li2S) on the Li metal anode surface adversely impacts the performance of lithium-sulfur (Li-S) batteries. In this study, a first-principles approach including density functional theory (DFT) and ab initio molecular dynamics (AIMD) simulations is employed to theoretically elucidate the Li2S/Li metal surface interactions and the nucleation and growth of a Li2S film on the anode surface due to long-chain polysulfide decomposition during battery operation. DFT analyses of the energetic properties and electronic structures demonstrate that a single molecule adsorption on Li surface releases energy forming chemical bonds between the S atoms and Li atoms from the anode surface. Reaction pathways of the Li2S film formation on Li metal surfaces are investigated based on DFT calculations. It is found that a distorted Li2S (111) plane forms on a Li(110) surface and a perfect Li2S (111) plane forms on a Li(111) surface. The total energy of the system decreases along the reaction pathway; hence Li2S film formation on the Li anode surface is thermodynamically favorable. The calculated difference charge density of the Li2S film/Li surface suggests that the precipitated film would interact with the Li anode via strong chemical bonds. AIMD simulations reveal the role of the anode surface structure and the origin of the Li2S formation via decomposition of Li2S8 polysulfide species formed at the cathode side and dissolved in the electrolyte medium in which they travel to the anode side during battery cycling.

Spontaneously broken Yang-Mills-Einstein supergravities as double copies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chiodaroli, Marco; Günaydin, Murat; Johansson, Henrik

Color/kinematics duality and the double-copy construction have proved to be systematic tools for gaining new insight into gravitational theories. Extending our earlier work, in this article we introduce new double-copy constructions for large classes of spontaneously-broken Yang-Mills-Einstein theories with adjoint Higgs elds. One gaugetheory copy entering the construction is a spontaneously-broken (super-)Yang-Mills theory, while the other copy is a bosonic Yang-Mills-scalar theory with trilinear scalar interactions that display an explicitly-broken global symmetry. We show that the kinematic numerators of these gauge theories can be made to obey color/kinematics duality by exhibiting particular additional Lie-algebraic relations. We discuss in detail explicitmore » examples with N = 2 supersymmetry, focusing on Yang-Mills-Einstein supergravity theories belonging to the generic Jordan family in four and five dimensions, and identify the map between the supergravity and double-copy elds and parameters. We also briefly discuss the application of our results to N = 4 supergravity theories. The constructions are illustrated by explicit examples of tree-level and one-loop scattering amplitudes.« less

Spontaneously broken Yang-Mills-Einstein supergravities as double copies

DOE PAGES

Chiodaroli, Marco; Günaydin, Murat; Johansson, Henrik; ...

2017-06-13

Color/kinematics duality and the double-copy construction have proved to be systematic tools for gaining new insight into gravitational theories. Extending our earlier work, in this article we introduce new double-copy constructions for large classes of spontaneously-broken Yang-Mills-Einstein theories with adjoint Higgs elds. One gaugetheory copy entering the construction is a spontaneously-broken (super-)Yang-Mills theory, while the other copy is a bosonic Yang-Mills-scalar theory with trilinear scalar interactions that display an explicitly-broken global symmetry. We show that the kinematic numerators of these gauge theories can be made to obey color/kinematics duality by exhibiting particular additional Lie-algebraic relations. We discuss in detail explicitmore » examples with N = 2 supersymmetry, focusing on Yang-Mills-Einstein supergravity theories belonging to the generic Jordan family in four and five dimensions, and identify the map between the supergravity and double-copy elds and parameters. We also briefly discuss the application of our results to N = 4 supergravity theories. The constructions are illustrated by explicit examples of tree-level and one-loop scattering amplitudes.« less

[Efficacy of acupuncture-moxibustion periodic therapy on follicular maldevelopment differentiated as spleen and kidney yang deficiency].

PubMed

Yan, Yuxuan; Pan, Chang; Wu, Jie; Yang, Lijie

2017-01-12

To observe the clinical efficacy of acupuncture and moxibustion periodic therapy on folli-cular maldevelopment differentiated as spleen and kidney yang deficiency. Sixty patients of follicular maldevelopment differentiated as spleen and kidney yang deficiency were randomized as an observation group and a control group, 30 cases in each one. The conventional acupuncture-moxibustion therapy was used in the control group and the acupuncture-moxibustion periodic therapy was applied to the observation group. In the control group, the acupoints were selected in terms of spleen and kidney yang deficiency, such as Guanyuan (CV 4), Qihai (CV 6), Zusanli (ST 36), Sanyinjiao (SP 6), Taixi (KI 3), Xuehai (SP 10) and Zigong (EX-CA 1). In the observation group, the acupoints were selected in terms of the physiological characteristics of follicular phase, ovulatory phase, luteal phase and menstrual phase. The main acupoints were Zusanli (ST 36), Sanyinjiao (SP 6), Taixi (KI 3) and Xuehai (SP 10). The acupoints for benefiting kidney yin were added in the follicular phase, such as Guanyuan (CV 4) and Dahe (KI 12), etc. The acupoints for regulating qi and activating blood circulation were added in the ovulatory phase, such as Hegu (LI 4) and Taichong (LR 3), etc. The moxibustion was added for tonifying kidney yang in the luteal phase, such as Qihai (CV 6) and Guanyuan (CV 4). The treatment was discontinued during the menstrual phase in the two groups. In the rest phases, acupuncture and moxibustion were given once every two days, 30 min each time. The overall efficacy, basal body temperature (BBT), follicular development, the average endometrial thickness and morphology as well as TCM syndrome score of spleen and kidney yang deficiency were observed in the patients after 3-month menstrual periods. The adverse reactions were recorded in the two groups. In the observation group, one case gave up the treatment due to the personal reason and another one stopped the treatment due to

Recovery of Li from alloys of Al- Li and Li- Al using engineered scavenger compounds

DOEpatents

Riley, W. D.; Jong, B. W.; Collins, W. K.; Gerdemann, S. J.

1994-01-01

A method of producing lithium of high purity from lithium aluminum alloys using an engineered scavenger compound, comprising: I) preparing an engineered scavenger compound by: a) mixing and heating compounds of TiO2 and Li2CO3 at a temperature sufficient to dry the compounds and convert Li.sub.2 CO.sub.3 to Li.sub.2 O; and b) mixing and heating the compounds at a temperature sufficient to produce a scavenger Li.sub.2 O.3TiO.sub.2 compound; II) loading the scavenger into one of two electrode baskets in a three electrode cell reactor and placing an Al-Li alloy in a second electrode basket of the three electrode cell reactor; III) heating the cell to a temperature sufficient to enable a mixture of KCl-LiCl contained in a crucible in the cell to reach its melting point and become a molten bath; IV) immersing the baskets in the bath until an electrical connection is made between the baskets to charge the scavenger compound with Li until there is an initial current and voltage followed by a fall off ending current and voltage; and V) making a connection between the basket electrode containing engineered scavenger compound and a steel rod electrode disposed between the basket electrodes and applying a current to cause Li to leave the scavenger compound and become electrodeposited on the steel rod electrode.

Bilingualism: Beyond Basic Principles. Multilingual Matters.

ERIC Educational Resources Information Center

Dewaele, Jean-Marc, Ed.; Housen, Alex, Ed.; Wei, Li, Ed.

This collection of papers focuses on individual bilingualism and societal and educational phenomena. After "Introduction and Overview" (Jean-Marc Dewaele, Alex Housen, and Li Wei), 12 papers include: (1) "Who is Afraid of Bilingualism?" (Hugo Baetens Beardsmore); (2) "The Importance of being Bilingual" (John Edwards);…

Lee-Yang zero analysis for the study of QCD phase structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ejiri, Shinji

2006-03-01

We comment on the Lee-Yang zero analysis for the study of the phase structure of QCD at high temperature and baryon number density by Monte-Carlo simulations. We find that the sign problem for nonzero density QCD induces a serious problem in the finite volume scaling analysis of the Lee-Yang zeros for the investigation of the order of the phase transition. If the sign problem occurs at large volume, the Lee-Yang zeros will always approach the real axis of the complex parameter plane in the thermodynamic limit. This implies that a scaling behavior which would suggest a crossover transition will notmore » be obtained. To clarify this problem, we discuss the Lee-Yang zero analysis for SU(3) pure gauge theory as a simple example without the sign problem, and then consider the case of nonzero density QCD. It is suggested that the distribution of the Lee-Yang zeros in the complex parameter space obtained by each simulation could be more important information for the investigation of the critical endpoint in the (T,{mu}{sub q}) plane than the finite volume scaling behavior.« less

Quantum Yang-Mills Dark Energy

NASA Astrophysics Data System (ADS)

Pasechnik, Roman

2016-02-01

In this short review, I discuss basic qualitative characteristics of quantum non-Abelian gauge dynamics in the non-stationary background of the expanding Universe in the framework of the standard Einstein--Yang--Mills formulation. A brief outlook of existing studies of cosmological Yang--Mills fields and their properties will be given. Quantum effects have a profound impact on the gauge field-driven cosmological evolution. In particular, a dynamical formation of the spatially-homogeneous and isotropic gauge field condensate may be responsible for both early and late-time acceleration, as well as for dynamical compensation of non-perturbative quantum vacua contributions to the ground state of the Universe. The main properties of such a condensate in the effective QCD theory at the flat Friedmann--Lema\\'itre--Robertson--Walker (FLRW) background will be discussed within and beyond perturbation theory. Finally, a phenomenologically consistent dark energy can be induced dynamically as a remnant of the QCD vacua compensation arising from leading-order graviton-mediated corrections to the QCD ground state.

Yang Monopoles and Emergent Three-Dimensional Topological Defects in Interacting Bosons

NASA Astrophysics Data System (ADS)

Yan, Yangqian; Zhou, Qi

2018-06-01

The Yang monopole as a zero-dimensional topological defect has been well established in multiple fields in physics. However, it remains an intriguing question to understand the interaction effects on Yang monopoles. Here, we show that the collective motion of many interacting bosons gives rise to exotic topological defects that are distinct from Yang monopoles seen by a single particle. Whereas interactions may distribute Yang monopoles in the parameter space or glue them to a single giant one of multiple charges, three-dimensional topological defects also arise from continuous manifolds of degenerate many-body eigenstates. Their projections in lower dimensions lead to knotted nodal lines and nodal rings. Our results suggest that ultracold bosonic atoms can be used to create emergent topological defects and directly measure topological invariants that are not easy to access in solids.

New contributions to physics by Prof. C. N. Yang: 2009-2011

NASA Astrophysics Data System (ADS)

Ma, Zhong-Qi

2016-01-01

In a seminal paper of 1967, Professor Chen Ning Yang found the full solution of the one-dimensional Fermi gas with a repulsive delta function interaction by using the Bethe ansatz and group theory. This work with a brilliant discovery of the Yang-Baxter equation has been inspiring new developments in mathematical physics, statistical physics, and many-body physics. Based on experimental developments in simulating many-body physics of one-dimensional systems of ultracold atoms, during a period from 2009 to 2011, Prof. Yang published seven papers on the exact properties of the ground state of bosonic and fermionic atoms with the repulsive delta function interaction and a confined potential to one dimension. Here I would like to share my experience in doing research work fortunately under the direct supervision of Prof. Yang in that period.

New Contributions to Physics by Prof. C. N. Yang: 2009-2011

NASA Astrophysics Data System (ADS)

Ma, Zhong-Qi

In a seminal paper of 1967, Professor Chen Ning Yang found the full solution of the one-dimensional Fermi gas with a repulsive delta function interaction by using the Bethe ansatz and group theory. This work with a brilliant discovery of the Yang-Baxter equation has been inspiring new developments in mathematical physics, statistical physics, and many-body physics. Based on experimental developments in simulating many-body physics of one-dimensional systems of ultracold atoms, during a period from 2009 to 2011, Prof. Yang published seven papers on the exact properties of the ground state of bosonic and fermionic atoms with the repulsive delta function interaction and a confined potential to one dimension. Here I would like to share my experience in doing research work fortunately under the direct supervision of Prof. Yang in that period.

Ultralong Lifespan and Ultrafast Li Storage: Single-Crystal LiFePO4 Nanomeshes.

PubMed

Zhang, Yan; Zhang, Hui Juan; Feng, Yang Yang; Fang, Ling; Wang, Yu

2016-01-27

A novel LiFePO4 material, in the shape of a nanomesh, has been rationally designed and synthesized based on the low crystal-mismatch strategy. The LiFePO4 nanomesh possesses several advantages in morphology and crystal structure, including a mesoporous structure, its crystal orientation that is along the [010] direction, and a shortened Li-ion diffusion path. These properties are favorable for their application as cathode in Li-ion batteries, as these will accelerate the Li-ion diffusion rate, improve the Li-ion exchange between the LiFePO4 nanomesh and the electrolyte, and reduce the Li-ion capacitive behavior during Li intercalation. So the LiFePO4 nanomesh exhibits a high specific capacity, enhanced rate capability, and strengthened cyclability. The method developed here can also be extended to other similar systems, for instance, LiMnPO4 , LiCoPO4 , and LiNiPO4 , and may find more applications in the designed synthesis of functional materials. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

First Principles Investigation of Li/Fe-Oxide as a High Energy Material for Hybrid All-in-One Li-ion/Li-O2 Batteries

NASA Astrophysics Data System (ADS)

Kinaci, Alper; Trahey, Lynn; Thackeray, Michael M.; Kirklin, Scott; Wolverton, Christopher; Chan, Maria K. Y.; CenterElectrical Energy Storage Collaboration

2014-03-01

We recently introduced a vision for high energy all-in-one electrode/electrocatalyst materials that can be used in hybrid Li-ion/Li-O2 (Li-air) cells. Recent experiments using Li5FeO4 demonstrated substantially smaller voltage polarizations and hence higher energy efficiency compared to standard Li-O2 cells forming Li2O2. The mechanism by which the charge process activates the Li5FeO4, however, is not well understood. Here, we present first principles density functional theory (DFT) calculations to establish the thermodynamic conditions for the extraction of Li/Li +O from Li5FeO4. A step-by-step, history-dependent, removal process has been followed and the stability of the Li and Li +O deficient samples is investigated on the basis of the energies of the extraction reactions. Various stages of Li/Li +O removal are identified, and structural changes and electronic structure evolution, as well as computed XRD, XANES, and PDF characterizations are reported.

ℤ3 parafermionic chain emerging from Yang-Baxter equation.

PubMed

Yu, Li-Wei; Ge, Mo-Lin

2016-02-23

We construct the 1D ℤ3 parafermionic model based on the solution of Yang-Baxter equation and express the model by three types of fermions. It is shown that the ℤ3 parafermionic chain possesses both triple degenerate ground states and non-trivial topological winding number. Hence, the ℤ3 parafermionic model is a direct generalization of 1D ℤ2 Kitaev model. Both the ℤ2 and ℤ3 model can be obtained from Yang-Baxter equation. On the other hand, to show the algebra of parafermionic tripling intuitively, we define a new 3-body Hamiltonian H123 based on Yang-Baxter equation. Different from the Majorana doubling, the H123 holds triple degeneracy at each of energy levels. The triple degeneracy is protected by two symmetry operators of the system, ω-parity P [formula in text] and emergent parafermionic operator Γ, which are the generalizations of parity PM and emergent Majorana operator in Lee-Wilczek model, respectively. Both the ℤ3 parafermionic model and H123 can be viewed as SU(3) models in color space. In comparison with the Majorana models for SU(2), it turns out that the SU(3) models are truly the generalization of Majorana models resultant from Yang-Baxter equation.

Advanced Lithium Anodes for Li/Air and Li/Water Batteries

DTIC Science & Technology

2005-10-05

µm thick protective glass- ceramic membrane . The value of Li discharged capacity in this experiment is significantly larger than the Li thickness...polarization solid-state cell used for determination of electronic current across glass- ceramic membrane Final Report Page 27 of 45 10/05/2005...Li anode/aqueous electrolyte interface without destruction of the 50 µm thick protective glass- ceramic membrane . The thickness of the Li foil used in

Development of the scintillator-based probe for fast-ion losses in the HL-2A tokamak

NASA Astrophysics Data System (ADS)

Zhang, Y. P.; Liu, Yi; Luo, X. B.; Isobe, M.; Yuan, G. L.; Liu, Y. Q.; Hua, Y.; Song, X. Y.; Yang, J. W.; Li, X.; Chen, W.; Li, Y.; Yan, L. W.; Song, X. M.; Yang, Q. W.; Duan, X. R.

2014-05-01

A new scintillator-based lost fast-ion probe (SLIP) has been developed and operated in the HL-2A tokamak [L. W. Yan, X. R. Duan, X. T. Ding, J. Q. Dong, Q. W. Yang, Yi Liu, X. L. Zou, D. Q. Liu, W. M. Xuan, L. Y. Chen, J. Rao, X. M. Song, Y. Huang, W. C. Mao, Q. M. Wang, Q. Li, Z. Cao, B. Li, J. Y. Cao, G. J. Lei, J. H. Zhang, X. D. Li, W. Chen, J. Chen, C. H. Cui, Z. Y. Cui, Z. C. Deng, Y. B. Dong, B. B. Feng, Q. D. Gao, X. Y. Han, W. Y. Hong, M. Huang, X. Q. Ji, Z. H. Kang, D. F. Kong, T. Lan, G. S. Li, H. J. Li, Qing Li, W. Li, Y. G. Li, A. D. Liu, Z. T. Liu, C. W. Luo, X. H. Mao, Y. D. Pan, J. F. Peng, Z. B. Shi, S. D. Song, X. Y. Song, H. J. Sun, A. K. Wang, M. X. Wang, Y. Q. Wang, W. W. Xiao, Y. F. Xie, L. H. Yao, D. L. Yu, B. S. Yuan, K. J. Zhao, G. W. Zhong, J. Zhou, J. C. Yan, C. X. Yu, C. H. Pan, Y. Liu, and the HL-2A Team, Nucl. Fusion 51, 094016 (2011)] to measure the losses of neutral beam ions. The design of the probe is based on the concept of the α-particle detectors on Tokamak Fusion Test Reactor (TFTR) using scintillator plates. The probe is capable of traveling across an equatorial plane port and sweeping the aperture angle rotationally with respect to the axis of the probe shaft by two step motors, in order to optimize the radial position and the collimator angle. The energy and the pitch angle of the lost fast ions can be simultaneously measured if the two-dimensional image of scintillation light intensity due to the impact of the lost fast ions is detected. Measurements of the fast-ion losses using the probe have been performed during HL-2A neutral beam injection discharges. The clear experimental evidence of enhanced losses of beam ions during disruptions has been obtained by means of the SLIP system. A detailed description of the probe system and the first experimental results are reported.

Development of the scintillator-based probe for fast-ion losses in the HL-2A tokamak

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Y. P., E-mail: zhangyp@swip.ac.cn; Liu, Yi; Yuan, G. L.

A new scintillator-based lost fast-ion probe (SLIP) has been developed and operated in the HL-2A tokamak [L. W. Yan, X. R. Duan, X. T. Ding, J. Q. Dong, Q. W. Yang, Yi Liu, X. L. Zou, D. Q. Liu, W. M. Xuan, L. Y. Chen, J. Rao, X. M. Song, Y. Huang, W. C. Mao, Q. M. Wang, Q. Li, Z. Cao, B. Li, J. Y. Cao, G. J. Lei, J. H. Zhang, X. D. Li, W. Chen, J. Chen, C. H. Cui, Z. Y. Cui, Z. C. Deng, Y. B. Dong, B. B. Feng, Q. D. Gao, X. Y.more » Han, W. Y. Hong, M. Huang, X. Q. Ji, Z. H. Kang, D. F. Kong, T. Lan, G. S. Li, H. J. Li, Qing Li, W. Li, Y. G. Li, A. D. Liu, Z. T. Liu, C. W. Luo, X. H. Mao, Y. D. Pan, J. F. Peng, Z. B. Shi, S. D. Song, X. Y. Song, H. J. Sun, A. K. Wang, M. X. Wang, Y. Q. Wang, W. W. Xiao, Y. F. Xie, L. H. Yao, D. L. Yu, B. S. Yuan, K. J. Zhao, G. W. Zhong, J. Zhou, J. C. Yan, C. X. Yu, C. H. Pan, Y. Liu, and the HL-2A Team , Nucl. Fusion 51, 094016 (2011)] to measure the losses of neutral beam ions. The design of the probe is based on the concept of the α-particle detectors on Tokamak Fusion Test Reactor (TFTR) using scintillator plates. The probe is capable of traveling across an equatorial plane port and sweeping the aperture angle rotationally with respect to the axis of the probe shaft by two step motors, in order to optimize the radial position and the collimator angle. The energy and the pitch angle of the lost fast ions can be simultaneously measured if the two-dimensional image of scintillation light intensity due to the impact of the lost fast ions is detected. Measurements of the fast-ion losses using the probe have been performed during HL-2A neutral beam injection discharges. The clear experimental evidence of enhanced losses of beam ions during disruptions has been obtained by means of the SLIP system. A detailed description of the probe system and the first experimental results are reported.« less

Chinese Herbal Medicine Treatment Improves the Overall Survival Rate of Individuals with Hypertension among Type 2 Diabetes Patients and Modulates In Vitro Smooth Muscle Cell Contractility.

PubMed

Lin, Ying-Ju; Ho, Tsung-Jung; Yeh, Yi-Chun; Cheng, Chi-Fung; Shiao, Yi-Tzone; Wang, Chang-Bi; Chien, Wen-Kuei; Chen, Jin-Hua; Liu, Xiang; Tsang, Hsinyi; Lin, Ting-Hsu; Liao, Chiu-Chu; Huang, Shao-Mei; Li, Ju-Pi; Lin, Cheng-Wen; Pang, Hao-Yu; Lin, Jaung-Geng; Lan, Yu-Ching; Liu, Yu-Huei; Chen, Shih-Yin; Tsai, Fuu-Jen; Liang, Wen-Miin

2015-01-01

Type 2 diabetes (T2D) is a chronic, multifactorial, and metabolic disorder accounting for 90% diabetes cases worldwide. Among them, almost half of T2D have hypertension, which is responsible for cardiovascular disease, morbidity, and mortality in these patients. The Chinese herbal medicine (CHM) prescription patterns of hypertension individuals among T2D patients have yet to be characterized. This study, therefore, aimed to determine their prescription patterns and evaluate the CHM effect. A cohort of one million randomly sampled cases from the National Health Insurance Research Database (NHIRD) was used to investigate the overall survival rate of CHM users, and prescription patterns. After matching CHM and non-CHM users for age, gender and date of diagnosis of hypertension, 980 subjects for each group were selected. The CHM users were characterized with slightly longer duration time from diabetes to hypertension, and more cases for hyperlipidaemia. The cumulative survival probabilities were higher in CHM users than in non-CHM users. Among these top 12 herbs, Liu-Wei-Di-Huang-Wan, Jia-Wei-Xiao-Yao-San, Dan-Shen, and Ge-Gen were the most common herbs and inhibited in vitro smooth muscle cell contractility. Our study also provides a CHM comprehensive list that may be useful in future investigation of the safety and efficacy for individuals with hypertension among type 2 diabetes patients.

Chinese Herbal Medicine Treatment Improves the Overall Survival Rate of Individuals with Hypertension among Type 2 Diabetes Patients and Modulates In Vitro Smooth Muscle Cell Contractility

PubMed Central

Yeh, Yi-Chun; Cheng, Chi-Fung; Shiao, Yi-Tzone; Wang, Chang-Bi; Chien, Wen-Kuei; Chen, Jin-Hua; Liu, Xiang; Tsang, Hsinyi; Lin, Ting-Hsu; Liao, Chiu-Chu; Huang, Shao-Mei; Li, Ju-Pi; Lin, Cheng-Wen; Pang, Hao-Yu; Lin, Jaung-Geng; Lan, Yu-Ching; Liu, Yu-Huei; Chen, Shih-Yin; Tsai, Fuu-Jen; Liang, Wen-Miin

2015-01-01

Type 2 diabetes (T2D) is a chronic, multifactorial, and metabolic disorder accounting for 90% diabetes cases worldwide. Among them, almost half of T2D have hypertension, which is responsible for cardiovascular disease, morbidity, and mortality in these patients. The Chinese herbal medicine (CHM) prescription patterns of hypertension individuals among T2D patients have yet to be characterized. This study, therefore, aimed to determine their prescription patterns and evaluate the CHM effect. A cohort of one million randomly sampled cases from the National Health Insurance Research Database (NHIRD) was used to investigate the overall survival rate of CHM users, and prescription patterns. After matching CHM and non-CHM users for age, gender and date of diagnosis of hypertension, 980 subjects for each group were selected. The CHM users were characterized with slightly longer duration time from diabetes to hypertension, and more cases for hyperlipidaemia. The cumulative survival probabilities were higher in CHM users than in non-CHM users. Among these top 12 herbs, Liu-Wei-Di-Huang-Wan, Jia-Wei-Xiao-Yao-San, Dan-Shen, and Ge-Gen were the most common herbs and inhibited in vitro smooth muscle cell contractility. Our study also provides a CHM comprehensive list that may be useful in future investigation of the safety and efficacy for individuals with hypertension among type 2 diabetes patients. PMID:26699542

Masslessness of ghosts in equivariantly gauge-fixed Yang-Mills theories

DOE Office of Scientific and Technical Information (OSTI.GOV)

Golterman, Maarten; Zimmerman, Leah

2005-06-01

We show that the one-loop ghost self-energy in an equivariantly gauge-fixed Yang-Mills theory vanishes at zero momentum. A ghost mass is forbidden by equivariant BRST symmetry, and our calculation confirms this explicitly. The four-ghost self interaction which appears in the equivariantly gauge-fixed Yang-Mills theory is needed in order to obtain this result.

Effect of land use on the seasonal variation of streamwater quality in the Wei River basin, China

NASA Astrophysics Data System (ADS)

Yu, S.; Xu, Z.; Wu, W.; Zuo, D.

2015-05-01

The temporal effect of land use on streamwater quality needs to be addressed for a better understanding of the complex relationship between land use and streamwater quality. In this study, GIS and Pearson correlation analysis were used to determine whether there were correlations of land-use types with streamwater quality at the sub-basin scale in the Wei River basin, China, during dry and rainy seasons in 2012. Temporal variation of these relations was observed, indicating that relationships between water quality variables and proportions of different land uses were weaker in the rainy season than that in the dry season. Comparing with other land uses, agriculture and urban lands had a stronger relationship with water quality variables in both the rainy and dry seasons. These results suggest that the aspect of temporal effects should be taken into account for better land-use management.

Stoneflies of the genus Neoperla (Plecoptera, Perlidae) from Wuyi Mountain National Nature Reserve, Fujian of China

PubMed Central

Qin, Xue-Feng; Murányi, Dávid; Wang, Guo-Quan; Li, Wei-Hai

2013-01-01

Abstract The species of the genus Neoperla are reviewed from Wuyi Mountain National Nature Reserve located in the Fujian Province of southeastern China, including the description of a new species, Neoperla brevistyla sp. n. The new species is compared to similar taxa. The first records of five Neoperla species, Neoperla henana Li, Wu & Zhang, 2011, Neoperla similiserecta Wang & Li, 2012, Neoperla qingyuanensis Yang & Yang, 1995, Neoperla xuansongae Li & Li, 2013 and Neoperla tuberculata Wu, 1938 are given for the Wuyi Mountain. A provisional key is provided for facilitating the identification of these species. PMID:24039532

Stoneflies of the genus Neoperla (Plecoptera, Perlidae) from Wuyi Mountain National Nature Reserve, Fujian of China.

PubMed

Qin, Xue-Feng; Murányi, Dávid; Wang, Guo-Quan; Li, Wei-Hai

2013-01-01

The species of the genus Neoperla are reviewed from Wuyi Mountain National Nature Reserve located in the Fujian Province of southeastern China, including the description of a new species, Neoperla brevistyla sp. n. The new species is compared to similar taxa. The first records of five Neoperla species, Neoperla henana Li, Wu & Zhang, 2011, Neoperla similiserecta Wang & Li, 2012, Neoperla qingyuanensis Yang & Yang, 1995, Neoperla xuansongae Li & Li, 2013 and Neoperla tuberculata Wu, 1938 are given for the Wuyi Mountain. A provisional key is provided for facilitating the identification of these species.

The Impact of Li Grain Size on Coulombic Efficiency in Li Batteries.

PubMed

Mehdi, B Layla; Stevens, Andrew; Qian, Jiangfeng; Park, Chiwoo; Xu, Wu; Henderson, Wesley A; Zhang, Ji-Guang; Mueller, Karl T; Browning, Nigel D

2016-10-05

One of the most promising means to increase the energy density of state-of-the-art lithium Li-ion batteries is to replace the graphite anode with a Li metal anode. While the direct use of Li metal may be highly advantageous, at present its practical application is limited by issues related to dendrite growth and low Coulombic efficiency, CE. Here operando electrochemical scanning transmission electron microscopy (STEM) is used to directly image the deposition/stripping of Li at the anode-electrolyte interface in a Li-based battery. A non-aqueous electrolyte containing small amounts of H 2 O as an additive results in remarkably different deposition/stripping properties as compared to the "dry" electrolyte when operated under identical electrochemical conditions. The electrolyte with the additive deposits more Li during the first cycle, with the grain sizes of the Li deposits being significantly larger and more variable. The stripping of the Li upon discharge is also more complete, i.e., there is a higher cycling CE. This suggests that larger grain sizes are indicative of better performance by leading to more uniform Li deposition and an overall decrease in the formation of Li dendrites and side reactions with electrolyte components, thus potentially paving the way for the direct use of Li metal in battery technologies.

Deconfinement in Yang-Mills Theory through Toroidal Compactification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simic, Dusan; Unsal, Mithat; /Stanford U., Phys. Dept. /SLAC

2011-08-12

We introduce field theory techniques through which the deconfinement transition of four-dimensional Yang-Mills theory can be moved to a semi-classical domain where it becomes calculable using two-dimensional field theory. We achieve this through a double-trace deformation of toroidally compactified Yang-Mills theory on R{sup 2} x S{sub L}{sup 1} x S{sub {beta}}{sup 1}. At large N, fixed-L, and arbitrary {beta}, the thermodynamics of the deformed theory is equivalent to that of ordinary Yang-Mills theory at leading order in the large N expansion. At fixed-N, small L and a range of {beta}, the deformed theory maps to a two-dimensional theory with electricmore » and magnetic (order and disorder) perturbations, analogs of which appear in planar spin-systems and statistical physics. We show that in this regime the deconfinement transition is driven by the competition between electric and magnetic perturbations in this two-dimensional theory. This appears to support the scenario proposed by Liao and Shuryak regarding the magnetic component of the quark-gluon plasma at RHIC.« less

Garnet-type solid-state fast Li ion conductors for Li batteries: critical review.

PubMed

Thangadurai, Venkataraman; Narayanan, Sumaletha; Pinzaru, Dana

2014-07-07

Batteries are electrochemical devices that store electrical energy in the form of chemical energy. Among known batteries, Li ion batteries (LiBs) provide the highest gravimetric and volumetric energy densities, making them ideal candidates for use in portable electronics and plug-in hybrid and electric vehicles. Conventional LiBs use an organic polymer electrolyte, which exhibits several safety issues including leakage, poor chemical stability and flammability. The use of a solid-state (ceramic) electrolyte to produce all-solid-state LiBs can overcome all of the above issues. Also, solid-state Li batteries can operate at high voltage, thus, producing high power density. Various types of solid Li-ion electrolytes have been reported; this review is focused on the most promising solid Li-ion electrolytes based on garnet-type metal oxides. The first studied Li-stuffed garnet-type compounds are Li5La3M2O12 (M = Nb, Ta), which show a Li-ion conductivity of ∼10(-6) at 25 °C. La and M sites can be substituted by various metal ions leading to Li-rich garnet-type electrolytes, such as Li6ALa2M2O12, (A = Mg, Ca, Sr, Ba, Sr0.5Ba0.5) and Li7La3C2O12 (C = Zr, Sn). Among the known Li-stuffed garnets, Li6.4La3Zr1.4Ta0.6O12 exhibits the highest bulk Li-ion conductivity of 10(-3) S cm(-1) at 25 °C with an activation energy of 0.35 eV, which is an order of magnitude lower than that of the currently used polymer, but is chemically stable at higher temperatures and voltages compared to polymer electrolytes. Here, we discuss the chemical composition-structure-ionic conductivity relationship of the Li-stuffed garnet-type oxides, as well as the Li ion conduction mechanism.

Xiangkun Li | NREL

Science.gov Websites

Xiangkun Li Xiangkun Li Engineer - Energy Optimization Modeling Xiangkun.Li@nrel.gov | 303-275-4372 focus areas include renewable energy integration, energy systems optimization, and power flow modeling

Beauty and physics: 13 important contributions of Chen Ning Yang

NASA Astrophysics Data System (ADS)

Shi, Yu

2014-06-01

In 2012, Chen Ning Yang received a 90th birthday gift in the form of a black cube inscribed with his 13 most important contributions, which cover four major areas of physics: statistical mechanics, condensed matter physics, particle physics and field theory. We briefly describe these 13 contributions and make general comments about Yang's distinctive style as a trailblazing leader in research.

The Impact of Li Grain Size on Coulombic Efficiency in Li Batteries

PubMed Central

Mehdi, B. Layla; Stevens, Andrew; Qian, Jiangfeng; Park, Chiwoo; Xu, Wu; Henderson, Wesley A.; Zhang, Ji-Guang; Mueller, Karl T.; Browning, Nigel D.

2016-01-01

One of the most promising means to increase the energy density of state-of-the-art lithium Li-ion batteries is to replace the graphite anode with a Li metal anode. While the direct use of Li metal may be highly advantageous, at present its practical application is limited by issues related to dendrite growth and low Coulombic efficiency, CE. Here operando electrochemical scanning transmission electron microscopy (STEM) is used to directly image the deposition/stripping of Li at the anode-electrolyte interface in a Li-based battery. A non-aqueous electrolyte containing small amounts of H2O as an additive results in remarkably different deposition/stripping properties as compared to the “dry” electrolyte when operated under identical electrochemical conditions. The electrolyte with the additive deposits more Li during the first cycle, with the grain sizes of the Li deposits being significantly larger and more variable. The stripping of the Li upon discharge is also more complete, i.e., there is a higher cycling CE. This suggests that larger grain sizes are indicative of better performance by leading to more uniform Li deposition and an overall decrease in the formation of Li dendrites and side reactions with electrolyte components, thus potentially paving the way for the direct use of Li metal in battery technologies. PMID:27703188

The Impact of Li Grain Size on Coulombic Efficiency in Li Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mehdi, B. Layla; Stevens, Andrew; Qian, Jiangfeng

One of the most promising means to increase the energy density of state-of-the-art lithium (Li)-ion batteries is to replace the graphite anode with a Li metal anode1, 2, 3. While the direct use of Li metal may be highly advantageous4,5, at present its practical application is limited by issues related to dendrite growth and low Coulombic efficiency (CE)6. Here operando electrochemical scanning transmission electron microscopy (STEM) is used to directly image the deposition/stripping of Li at the anode-electrolyte interface in a Li-based battery. A non-aqueous electrolyte containing small amounts of H2O as an additive results in remarkably different deposition/stripping propertiesmore » as compared to the "dry" electrolyte when operated under identical electrochemical conditions. The electrolyte with the additive deposits more Li during the first cycle, with the grain sizes of the Li deposits being significantly larger and more variable. The stripping of the Li upon discharge is also more complete, i.e., there is a higher cycling CE. This suggests that larger grain sizes are indicative of better performance by leading to more uniform Li deposition and an overall decrease in the formation of Li dendrites and side reactions with electrolyte components, thus potentially paving the way for the direct use of Li metal in battery technologies.« less

Study on Strata Behavior Regularity of 1301 Face in Thick Bedrock of Wei - qiang Coal Mine

NASA Astrophysics Data System (ADS)

Gu, Shuancheng; Yao, Boyu

2017-09-01

In order to ensure the safe and efficient production of the thick bedrock face, the rule of the strata behavior of the thick bedrock face is discussed through the observation of the strata pressure of the 1301 first mining face in Wei qiang coal mine. The initial face is to press the average distance of 50.75m, the periodic weighting is to press the average distance of 12.1m; during the normal mining period, although the upper roof can not be broken at the same time, but the pressure step is basically the same; the working face for the first weighting and periodical weighting is more obvious to the change of pressure step change, when the pressure of the working face is coming, the stent force increased significantly, but there are still part of the stent work resistance exceeds the rated working resistance, low stability, still need to strengthen management.

Annual Staunton Hill Conference on China’s People Liberation Army (PLA) (2nd) Held in Staunton Hill, Virginia on September 6 - 8, 1991

DTIC Science & Technology

1991-09-01

discipline; 3) regionalism; 4) directly to consolidate the position of the Li Peng the succession to Deng; ind 5) reaction to the Soviet group. coup...by local fact that the 21st century policy serves the narrow leaders, local protectionism (most often in the form interest of Li Peng and not the...elite, Li Peng, Jiang Zemin, and debates over the PLA and its future political role are Yang Shangkun, only Yang has credibility with the calls for a

China Report: Political, Sociological and Military Affairs.

DTIC Science & Technology

1983-03-18

Production Brigade of Guangbao Commune in raising chickens and rabbits in a big way. We must mobilize the commune member house- holds to utilize...The state and the commune, production brigades, and production teams operate fish farms, some of which raise fry . Why not go ahead with raising fish...Wei Xinyi, Huang Yu, Yang Jike, Guo Tixiang, Meng Fulin, Hu Tan, Zhu Nong, Fang Shiliang, Wang Zenong, Pan Ezhang, Liu Zhengwen, Chen Tianren, Ma

Electrochemical behavior of Li/LiV3O8 secondary cells

NASA Astrophysics Data System (ADS)

Bak, Hyo Rim; Lee, Jae Ha; Kim, Bok Ki; Yoon, Woo Young

2013-03-01

Li/LiV3O8 secondary cells with Li-foil and Li-powder anodes were fabricated, and their electrical properties were compared. Using the powder anode, a cell with an initial discharge capacity of 260 mAh g-1 that could be operated for over 100 cycles was obtained. The porous Li-powder electrode was safely synthesized by pressing an emulsion droplet onto an SUS mesh. A threefold increase in the electrical conductivity of the LiV3O8 cathode was achieved by the addition of carbon using a vibration pot mill. Using the powder anode resulted in 80% capacity retention at the 100th cycle, while that using the foil electrode was 46%; the 1.0 Crate/ 0.1 C-rate capacity ratio also increased from 44% to 60%. A cell employing the LiV3O8-carbon composite cathode showed better electrical performance, a capacity retention of 90% after 50 cycles, and an increase in rate capacity ratio. The crystal structure and morphology of the LiV3O8-C composite were investigated by x-ray diffraction and scanning electron microscopy.

Generalizations of the classical Yang-Baxter equation and O-operators

NASA Astrophysics Data System (ADS)

Bai, Chengming; Guo, Li; Ni, Xiang

2011-06-01

Tensor solutions (r-matrices) of the classical Yang-Baxter equation (CYBE) in a Lie algebra, obtained as the classical limit of the R-matrix solution of the quantum Yang-Baxter equation, is an important structure appearing in different areas such as integrable systems, symplectic geometry, quantum groups, and quantum field theory. Further study of CYBE led to its interpretation as certain operators, giving rise to the concept of {O}-operators. The O-operators were in turn interpreted as tensor solutions of CYBE by enlarging the Lie algebra [Bai, C., "A unified algebraic approach to the classical Yang-Baxter equation," J. Phys. A: Math. Theor. 40, 11073 (2007)], 10.1088/1751-8113/40/36/007. The purpose of this paper is to extend this study to a more general class of operators that were recently introduced [Bai, C., Guo, L., and Ni, X., "Nonabelian generalized Lax pairs, the classical Yang-Baxter equation and PostLie algebras," Commun. Math. Phys. 297, 553 (2010)], 10.1007/s00220-010-0998-7 in the study of Lax pairs in integrable systems. Relations between O-operators, relative differential operators, and Rota-Baxter operators are also discussed.

Positioning and Repositioning: Linguistic Practices and Identity Negotiation of Overseas Returning Bilinguals in Hong Kong

ERIC Educational Resources Information Center

Chen, Katherine Hoi Ying

2008-01-01

Li Wei (1995) notes that relatively little sociolinguistic work on bilingualism has attempted to analyze and compare the complex relationships between aspects of language choice and code-switching among subgroups of the same community. This study aims to investigate the co-existence of two structurally different Cantonese-English code-switching…

Theoretical study of LiK and LiK+ in adiabatic representation

NASA Astrophysics Data System (ADS)

Al-dossary, Omar M.; Khelifi, Neji

2014-01-01

The potential energy curves have been calculated for the electronic states of the molecule LiK within the range 3 to 300 a.u., of the internuclear distance R. Using an ab initio method, through a semiempirical spin-orbit pseudo-potential for the Li (1 s 2) and K (1 s 22 s 22 p 63 s 23 p 6) cores and core valence correlation correction added to the electrostatic Hamiltonian with Gaussian basis sets for both atoms. The core valence effects including core-polarization and core-valence correlation are taken into account by using an l-dependent core-polarization potential. The molecular orbitals have been derived from self-consistent field (SCF) calculation. The spectroscopic constants, dipole moments and vibrational levels of the lowest electronic states of the LiK molecule dissociating into K (4 s, 4 p, 5 s, 3 d, and 5 p) + Li (2 s, 2 p, 3 s, and 3 p) in 1, 3Σ, 1, 3Π, and 1, 3Δ symmetries. Adiabatic results are also reported for 2Σ, 2Π, and 2Δ electronic states of the molecular ion LiK+ dissociating into Li (2 s, 2 p, 3 s, and 3 p) + K+ and Li+ + K (4 s, 4 p, 5 s, 3 d, and 5 p). The comparison of the present results with those available in the literature shows a very good agreement in spectroscopic constants of some lowest states of the LiK and LiK+ molecules, especially with the available theoretical works. The existence of numerous avoided crossing between electronic states of 2Σ and 2Π symmetries is related to the charge transfer process between the two ionic systems Li+K and LiK+.

Cluster-enriched Yang-Baxter equation from SUSY gauge theories

NASA Astrophysics Data System (ADS)

Yamazaki, Masahito

2018-04-01

We propose a new generalization of the Yang-Baxter equation, where the R-matrix depends on cluster y-variables in addition to the spectral parameters. We point out that we can construct solutions to this new equation from the recently found correspondence between Yang-Baxter equations and supersymmetric gauge theories. The S^2 partition function of a certain 2d N=(2,2) quiver gauge theory gives an R-matrix, whereas its FI parameters can be identified with the cluster y-variables.

Investigation of the role of 10Li resonances in the halo structure of 11Li through the 11Li (p , d)10Li transfer reaction

NASA Astrophysics Data System (ADS)

Sanetullaev, A.; Kanungo, R.; Tanaka, J.; Alcorta, M.; Andreoiu, C.; Bender, P.; Chen, A. A.; Christian, G.; Davids, B.; Fallis, J.; Fortin, J. P.; Galinski, N.; Gallant, A. T.; Garrett, P. E.; Hackman, G.; Hadinia, B.; Ishimoto, S.; Keefe, M.; Krücken, R.; Lighthall, J.; McNeice, E.; Miller, D.; Purcell, J.; Randhawa, J. S.; Roger, T.; Rojas, A.; Savajols, H.; Shotter, A.; Tanihata, I.; Thompson, I. J.; Unsworth, C.; Voss, P.; Wang, Z.

2016-04-01

The first measurement of the one-neutron transfer reaction 11Li(p,d)10Li performed using the IRIS facility at TRIUMF with a 5.7 A MeV11Li beam interacting with a solid H2 target is reported. The 10Li residue was populated strongly as a resonance peak with energy Er = 0.62 ± 0.04 MeV having a total width Γ = 0.33 ± 0.07 MeV. The angular distribution of this resonance is characterized by neutron occupying the 1p1/2 orbital. A DWBA analysis yields a spectroscopic factor of 0.67 ± 0.12 for p1/2 removal strength from the ground state of 11Li to the region of the peak.

The Interstellar 7Li/6Li Ratio in the Diffuse Gas Near IC 443

NASA Astrophysics Data System (ADS)

Ritchey, A. M.; Taylor, C. J.; Federman, S. R.; Lambert, D. L.

2010-11-01

Supernova remnants are believed to be the primary acceleration sites of Galactic cosmic rays (GCR), which are essential to gas-phase interstellar chemistry since they are a major source of ionization in both diffuse and dense environments. The interaction of accelerated particles with interstellar gas will also synthesize isotopes of the light elements Li, Be, and B through the spallation of CNO nuclei (producing all stable LiBeB isotopes) and through α+α fusion (yielding 6Li and 7Li, only). Type II supernovae may provide an additional source of 7Li and 11B during core collapse through neutrino-induced spallation in the He and C shells of the progenitor star (the ν-process). However, direct observational evidence for light element synthesis resulting from cosmic-ray or neutrino-induced spallation is rare. Here, we examine 7Li/6Li isotope ratios along four lines of sight through the supernova remnant IC 443 using observations of the Li I λ6707 doublet made with the Hobby-Eberly Telescope (HET) at McDonald Observatory. The 7Li/6Li ratio in the general interstellar medium is expected to be similar to the ratio of ~12 that characterizes solar system material. A local enhancement in the cosmic-ray flux will act to lower 7Li/6Li, yielding a ratio of ~2 when cosmic rays dominate Li synthesis. Gamma-ray emission from IC 443 provides strong evidence for the interaction of cosmic rays accelerated by the remnant with the ambient atomic and molecular gas. Yet this material has also been contaminated by the ejecta of a Type II supernova, which should be enriched in 7Li. We are seeking 7Li/6Li ratios that are either higher than the solar system ratio as a result of the ν-process or lower due to cosmic-ray spallation. Since the fine structure separation of the Li I doublet is comparable to the isotope shift (~7 km s-1) and each fine structure line is further split into hyperfine components, the velocity structure along the line of sight must be carefully constrained if

Li isotopes in archean zircons

NASA Astrophysics Data System (ADS)

Bouvier, A.; Ushikubo, T.; Kita, N.; Cavosie, A. J.; Kozdon, R.; Valley, J. W.

2009-12-01

Li is a fluid mobile, moderately incompatible element with a large mass difference between its two stable isotopes. Different processes can fractionate 7Li/6Li (fluid-rock interaction, metamorphic reactions, and Li diffusion), leading to variation by over 50‰ of δ7Li for common crustal material. These large variations make δ7Li a potential tracer of continental weathering and of the fluids affecting magma sources. Here, we report δ7Li and trace elements in Archean igneous zircons from TTG and sanukitoid granitoids from the Superior Province (Canada) in order to characterize Li in Archean zircons from well-described samples. These data are compared to detrital zircons from the Jack Hills (Western Australia) for which parent rock-type is uncertain. This study aims to better understand Li substitution in zircon and to evaluate the utility of δ7Li and [Li] for Archean petrogenesis. Zircons (n=71) were analyzed for δ7Li and trace elements (Li, P, Ca, Ti, V, Fe, Y, REE, U, Th) using an IMS-1280 ion microprobe. Most of the zircons display typical igneous REE patterns and zoning by CL. [Li] averages 13.1 ± 9 for TTG, 25.7 ± 19 for Sanukitoid and 31.0 ± 14 ppm for Jack Hills zircons, which are distinct from mantle-related zircons (<0.1 ppm). Values of δ7Li average 1.0 ± 4.5‰ for TTGs, 6.3 ± 4.4‰ for sanukitoids and -2.6 ± 8.8‰ for Jack Hills samples. Trace elements were analyzed from single spots in order to evaluate coupled substitutions. Atomic ratios (3Li+Y+REE)/P average 2.6, showing that Li and trivalent atoms are not charge-balanced by P, and suggesting that Li does not replace Zr, according to the xenotime substitution. However, (Y+REE)/(Li+P) atomic ratios average 1.0 ± 0.6, supporting the hypothesis that Li is interstitial and partly compensates trivalent cations. Several observations in this study suggest that [Li] is primary in the studied zircons: i) if Li is interstitial, charge-balance and slow diffusion of REE would control Li mobility

Investigation of the role of 10Li resonances in the halo structure of 11Li through the 11Li(p,d)10Li transfer reaction

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sanetullaev, A.; Kanungo, R.; Tanaka, J.

2016-03-02

Here, the first measurement of the one-neutron transfer reaction 11Li(p,d) 10Li performed using the IRIS facility at TRIUMF with a 5.7A MeV 11Li beam interacting with a solid H 2 target is reported. The 10Li residue was populated strongly as a resonance peak with energy E r = 0.62 ± 0.04 MeV having a total width Γ = 0.33 ± 0.07 MeV. The angular distribution of this resonance is characterized by neutron occupying the 1p 1/2 orbital. A DWBA analysis yields a spectroscopic factor of 0.67 ± 0.12 for p 1/2 removal strength from the ground state of 11Li tomore » the region of the peak.« less

[Formula: see text] graded discrete Lax pairs and Yang-Baxter maps.

PubMed

Fordy, Allan P; Xenitidis, Pavlos

2017-05-01

We recently introduced a class of [Formula: see text] graded discrete Lax pairs and studied the associated discrete integrable systems (lattice equations). In this paper, we introduce the corresponding Yang-Baxter maps. Many well-known examples belong to this scheme for N =2, so, for N ≥3, our systems may be regarded as generalizations of these. In particular, for each N we introduce a class of multi-component Yang-Baxter maps, which include H B III (of Papageorgiou et al. 2010 SIGMA 6, 003 (9 p). (doi:10.3842/SIGMA.2010.033)), when N =2, and that associated with the discrete modified Boussinesq equation, for N =3. For N ≥5 we introduce a new family of Yang-Baxter maps, which have no lower dimensional analogue. We also present new multi-component versions of the Yang-Baxter maps F IV and F V (given in the classification of Adler et al. 2004 Commun. Anal. Geom. 12, 967-1007. (doi:10.4310/CAG.2004.v12.n5.a1)).

G-LiHT: Goddard's LiDAR, Hyperspectral and Thermal Airborne Imager

NASA Technical Reports Server (NTRS)

Cook, Bruce; Corp, Lawrence; Nelson, Ross; Morton, Douglas; Ranson, Kenneth J.; Masek, Jeffrey; Middleton, Elizabeth

2012-01-01

Scientists at NASA's Goddard Space Flight Center have developed an ultra-portable, low-cost, multi-sensor remote sensing system for studying the form and function of terrestrial ecosystems. G-LiHT integrates two LIDARs, a 905 nanometer single beam profiler and 1550 nm scanner, with a narrowband (1.5 nanometers) VNIR imaging spectrometer and a broadband (8-14 micrometers) thermal imager. The small footprint (approximately 12 centimeters) LIDAR data and approximately 1 meter ground resolution imagery are advantageous for high resolution applications such as the delineation of canopy crowns, characterization of canopy gaps, and the identification of sparse, low-stature vegetation, which is difficult to detect from space-based instruments and large-footprint LiDAR. The hyperspectral and thermal imagery can be used to characterize species composition, variations in biophysical variables (e.g., photosynthetic pigments), surface temperature, and responses to environmental stressors (e.g., heat, moisture loss). Additionally, the combination of LIDAR optical, and thermal data from G-LiHT is being used to assess forest health by sensing differences in foliage density, photosynthetic pigments, and transpiration. Low operating costs (approximately $1 ha) have allowed us to evaluate seasonal differences in LiDAR, passive optical and thermal data, which provides insight into year-round observations from space. Canopy characteristics and tree allometry (e.g., crown height:width, canopy:ground reflectance) derived from G-LiHT data are being used to generate realistic scenes for radiative transfer models, which in turn are being used to improve instrument design and ensure continuity between LiDAR instruments. G-LiHT has been installed and tested in aircraft with fuselage viewports and in a custom wing-mounted pod that allows G-LiHT to be flown on any Cessna 206, a common aircraft in use throughout the world. G-LiHT is currently being used for forest biomass and growth estimation

Super Yang-Mills theory with impurity walls and instanton moduli spaces

NASA Astrophysics Data System (ADS)

Cherkis, Sergey A.; O'Hara, Clare; Sämann, Christian

2011-06-01

We explore maximally supersymmetric Yang-Mills theory with walls of impurities respecting half of the supersymmetries. The walls carry fundamental or bifundamental matter multiplets. We employ three-dimensional N=2 superspace language to identify the Higgs branch of this theory. We find that the vacuum conditions determining the Higgs branch are exactly the bow equations yielding Yang-Mills instantons on a multi-Taub-NUT space. Under electric-magnetic duality, the super Yang-Mills theory describing the bulk is mapped to itself, while the fundamental- and bifundamental-carrying impurity walls are interchanged. We perform a one-loop computation on the Coulomb branch of the dual theory to find the asymptotic metric on the original Higgs branch.

Investigations of Li-containing SiCN(O) ceramics via 7Li MAS NMR.

PubMed

Gumann, Sina; Nestle, Nikolaus; Liebau-Kunzmann, Verena; Riedel, Ralf

2007-04-01

Lithium-containing silicon (oxy)carbonitride ceramics (SiCN(O):Li) were synthesized via precursor-to-ceramic-transformation of Li-containing (poly)silazanes. The precursors were obtained by lithiation of 2,4,6-trimethyl-2,4,6-trivinylcyclotrisilazane with n-butyllithium and by reaction of a commercial poly(organosilazane) VL20 with metallic lithium. The annealing treatment was carried out at temperatures between 200 and 1400 degrees C in argon (DeltaT=200 degrees C) and yielded Li-containing silicon (oxy)carbonitride. X-ray powder diffraction revealed that the resulting SiCN(O):Li ceramics were basically amorphous up to temperatures of 1000 degrees C and formed LiSi(2)N(3), graphite and silicon carbide as crystalline phases at higher temperatures. (7)Li MAS NMR spectroscopy was carried out to investigate the structure of the Li-containing phases and to study the reaction path of metallic Li with polysilazane. Based on the NMR spectra, there is almost no difference found in the chemical shift of the SiCN(O):Li ceramics obtained at different temperatures. Accordingly, Li is assigned to be mainly coordinated to N and O present as contaminant element. Relaxation time measurements showed that the most mobile Li(+) species seems to be present in the product obtained in the pyrolysis temperature range between 600 and 1000 degrees C.

Electrochemical performance of LiNi0.4Co0.2Mn0.4O2 prepared by different molten salt flux: LiNO3-LiCl and LiNO3-KNO3

NASA Astrophysics Data System (ADS)

Satyanarayana, M.; James, Joseph; U. V., Varadaraju

2017-10-01

LiNi0.4Co0.2Mn0.4O2 material synthesized at different temperatures by using LiNO3-LiCl and LiNO3-KNO3 molten salt as a reaction medium. The phase purity of the samples obtained by powder X-ray diffraction measurement which suggests layered α-NaFeO2 type is obtained at 800-900 °C using LiNO3-LiCl flux and at 750-850 °C using LiNO3-KNO3 flux. The surface morphology change with flux media at different temperature are obtained by scanning electron microscopy analysis. The galvanostatic cycling results show that the high stable reversible discharge capacity of 155 (±3) mAh g-1 obtained for treated compound at 900 °C for 1 h (using LiNO3-LiCl) with coloumbic efficiency of 99%. The reversible discharge capacity of 140 and 130 (±3) mAh g-1 obtained for treated compound at 750 and 850 °C, respectively (using LiNO3-KNO3).

Non-Abelian Yang-Mills analogue of classical electromagnetic duality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chan, Hong-Mo; Faridani, J.; Tsun, T.S.

The classic question of non-Abelian Yang-Mills analogue to electromagnetic duality is examined here in a minimalist fashion at the strictly four-dimensional, classical field, and point charge level. A generalization of the Abelian Hodge star duality is found which, though not yet known to give dual symmetry, reproduces analogues to many dual properties of the Abelian theory. For example, there is a dual potential, but it is a two-indexed tensor {ital T}{sub {mu}{nu}} of the Freedman-Townsend-type. Though not itself functioning as such, {ital T}{sub {mu}{nu}} gives rise to a dual parallel transport {ital {tilde A}}{sub {mu}} for the phase of themore » wave function of the color magnetic charge, this last being a monopole of the Yang-Mills field but a source of the dual field. The standard color (electric) charge itself is found to be a monpole of {ital {tilde A}}{sub {mu}}. At the same time, the gauge symmetry is found doubled from say SU({ital N}) to SU({ital N}){times}SU({ital N}). A novel feature is that all equations of motion, including the standard Yang-Mills and Wong equations, are here derived from a ``universal`` principle, namely, the Wu-Yang criterion for monpoles, where interactions arise purely as a consequence of the topological definition of the monopole charge. The technique used is the loop space formulation of Polyakov.« less

Metallic Li colloids studied by Li-7 MAS NMR in electron-irradiated LiF

NASA Astrophysics Data System (ADS)

Zogal, O. J.; Beuneu, F.; Vajda, P.; Florian, P.; Massiot, D.

Li-7 MAS NMR spectra of 2.5 MeV electron-irradiated LiF crystals have been measured in a field of 9.4 T. Besides the resonance line of the ionic compound, a second well-separated spectrum is observed in the region of the Knight shift value for metallic lithium. At room temperature, the latter can be decomposed into two components with different Knight shift and linewidth values. When the temperature is increased, line narrowing takes place at first, indicating shortening of correlation times for self-diffusion, independently in both components. Above 370 K, both lines broaden and approach each other before collapsing into a single line. The high ppm component disappears after crossing the melting temperature of metallic lithium (454 K). The two lines are attributed to different types of metallic Li: one to bulk-like metal, the other to Li present initially under pressure and relaxing to the former under thermal treatment.

The Hom-Yang-Baxter equation and Hom-Lie algebras

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yau, Donald

2011-05-15

Motivated by recent work on Hom-Lie algebras, a twisted version of the Yang-Baxter equation, called the Hom-Yang-Baxter equation (HYBE), was introduced by Yau [J. Phys. A 42, 165202 (2009)]. In this paper, several more classes of solutions of the HYBE are constructed. Some of the solutions of the HYBE are closely related to the quantum enveloping algebra of sl(2), the Jones-Conway polynomial, and Yetter-Drinfel'd modules. Under some invertibility conditions, we construct a new infinite sequence of solutions of the HYBE from a given one.

Li plating as unwanted side reaction in commercial Li-ion cells - A review

NASA Astrophysics Data System (ADS)

Waldmann, Thomas; Hogg, Björn-Ingo; Wohlfahrt-Mehrens, Margret

2018-04-01

Deposition of Lithium metal on anodes contributes significantly to ageing of Li-ion cells. Lithium deposition is connected not only to a drastic limitation of life-time, but also to fast-charging capability and safety issues. Lithium deposition in commercial Li-ion cells is not limited to operation conditions at low temperatures. In recent publications various types of commercial cells were investigated using complimentary analysis methods. Five cell types studied in literature (18650, 26650, pouch) serve as a basis for comparison when and why Li deposition happens in commercial Li-ion cells. In the present paper, we reviewed literature on (i) causes, (ii) hints and evidences for Li deposition, (iii) macroscopic morphology of Li deposition/plating, (iv) ageing mechanisms and shapes of capacity fade curves involving Li deposition, and (v) influences of Li deposition on safety. Although often discussed, safety issues regarding Li deposition are not only limited to dendrite growth and internal short circuits, but also to exothermic reactions in the presence of Lithium metal. Furthermore, we tried to connect knowledge from different length scales including the macroscopic level (Li-ion cells, operating conditions, gradients in cells, electrochemical tests, safety tests), the microscopic level (electrodes, particles, microstructure), and the atomic level (atoms, ions, molecules, energy barriers).

Yang-Mills Theory at 60: Milestones, Landmarks and Interesting Questions

NASA Astrophysics Data System (ADS)

Chau, Ling-Lie

On the auspicious occasion of celebrating the 60th anniversary of the Yang-Mills theory, and Professor Yang's many other important contributions to physics and mathematics, I will highlight the impressive milestones and landmarks that have been established in the last 60 years, as well as some interesting questions that are worthy of answers from future researches. The paper is written (without equations) for the interest of non-scientists as well as of scientists.

Insights into the Li Intercalation and SEI Formation on LiSi Nanoclusters

DOE PAGES

Hankins, Kie; Soto, Fernando A.; Balbuena, Perla B.

2017-01-01

We report a first-principles atomic level assessment of the lithiation and reactivity of pre-lithiated Si clusters. Density functional theory formation energy calculations reveal that the pre-lithiated Li 16Si 16 cluster exposed to two different Li fluxes can store Li between the concentrations of Li 2.5Si and Li 3.5Si. This increase in storage capacity is attributed to the start of an amorphization process in the cluster, and more importantly these results show that the intercalation reaction can be controlled by the flux of the Li-ions. However, in a real battery, the lithiation of the anode occurs simultaneously to the electrode-electrolyte reactions.more » Here we simulate the solid-electrolyte interphase (SEI) formation and simultaneous lithiation of a Li 16Si 16 cluster in contact with two different electrolyte solutions: one with pure ethylene carbonate (EC), and another with a 1 M solution of LiPF 6 in EC. Our ab initio molecular dynamics simulations show that the solvent and salt are decomposed leading to the initial stages of the SEI layer formation and large part of the added Li becomes part of the SEI. Interestingly, the pure EC solution results in lower storage capacity and higher reactivity, whereas the presence of the salt causes the opposite effect: higher lithiation and reduced reactivity.« less

Electrochemical performances of LiMnPO4 synthesized from non-stoichiometric Li/Mn ratio.

PubMed

Xiao, Jie; Chernova, Natasha A; Upreti, Shailesh; Chen, Xilin; Li, Zheng; Deng, Zhiqun; Choi, Daiwon; Xu, Wu; Nie, Zimin; Graff, Gordon L; Liu, Jun; Whittingham, M Stanley; Zhang, Ji-Guang

2011-10-28

In this paper, the influences of the lithium content in the starting materials on the final performances of as-prepared Li(x)MnPO(4) (x hereafter represents the starting Li content in the synthesis step which does not necessarily mean that Li(x)MnPO(4) is a single phase solid solution in this work.) are systematically investigated. It has been revealed that Mn(2)P(2)O(7) is the main impurity when Li < 1.0 while Li(3)PO(4) begins to form once x > 1.0. The interactions between Mn(2)P(2)O(7) or Li(3)PO(4) impurities and LiMnPO(4) are studied in terms of the structural, electrochemical, and magnetic properties. At a slow rate of C/50, the reversible capacity of both Li(0.5)MnPO(4) and Li(0.8)MnPO(4) increases with cycling. This indicates a gradual activation of more sites to accommodate a reversible diffusion of Li(+) ions that may be related to the interaction between Mn(2)P(2)O(7) and LiMnPO(4) nanoparticles. Among all of the different compositions, Li(1.1)MnPO(4) exhibits the most stable cycling ability probably because of the existence of a trace amount of Li(3)PO(4) impurity that functions as a solid-state electrolyte on the surface. The magnetic properties and X-ray absorption spectroscopy (XAS) of the MnPO(4)·H(2)O precursor, pure and carbon-coated Li(x)MnPO(4) are also investigated to identify the key steps involved in preparing a high-performance LiMnPO(4). This journal is © the Owner Societies 2011

[Plasma metabonomics of Guifu Dihuang Wan in the treatment of yang deficiency].

PubMed

Xiao, Ya; Jing, Yuan; Chen, Jie-Yu; Li, Fei; Cheng, Jing-Ru; Bi, Jian-Lu; Luo, Ren; Zhao, Xiao-Shan

2016-11-20

To assess the effect of Guifu Dihuang Wan (GFDHW) in the treatment of yang deficiency and explore the underlying molecular mechanism. Sixty-two participants without diseases were randomized into control group (n=31) and experimental group (n=31) and were given lifestyle intervention additional GFDHW treatment for a month. NMR technology was used for metabonomics analysis. Intervention with GFDHW resulted in significantly decreased conversion scores of yang deficiency in the experimental group compared with the control group (P<0.005). The concentrations of lactate, valine, proline, arginine and 3-hydroxybutyrate were increased in the plasma of yang-deficient subjects after lifestyle intervention. GFDHW treatment with lifestyle intervention significantly increased the concentrations of lactate, valine, proline, arginine and 3-hydroxybutyrate and also the levels of alanine, glutamine, alpha glucose, isoleucine, betaine and propylene glycol. GFDHW treatment improves yang deficiency possibly by increasing the concentrations of alanine, glutamine, alpha glucose, isoleucine, betaine and propylene glycol and promoting energy metabolism of the body.

Mechanistic insights of Li+ diffusion within doped LiFePO4 from Muon Spectroscopy.

PubMed

Johnson, Ian D; Ashton, Thomas E; Blagovidova, Ekaterina; Smales, Glen J; Lübke, Mechthild; Baker, Peter J; Corr, Serena A; Darr, Jawwad A

2018-03-07

The Li + ion diffusion characteristics of V- and Nb-doped LiFePO 4 were examined with respect to undoped LiFePO 4 using muon spectroscopy (µSR) as a local probe. As little difference in diffusion coefficient between the pure and doped samples was observed, offering D Li values in the range 1.8-2.3 × 10 -10  cm 2 s -1 , this implied the improvement in electrochemical performance observed within doped LiFePO 4 was not a result of increased local Li + diffusion. This unexpected observation was made possible with the µSR technique, which can measure Li + self-diffusion within LiFePO 4 , and therefore negated the effect of the LiFePO 4 two-phase delithiation mechanism, which has previously prevented accurate Li + diffusion comparison between the doped and undoped materials. Therefore, the authors suggest that µSR is an excellent technique for analysing materials on a local scale to elucidate the effects of dopants on solid-state diffusion behaviour.

Layered Li-Mn-M-oxides as cathodes for Li-ion batteries:. Recent trends

NASA Astrophysics Data System (ADS)

Shaju, K. M.; Subba Rao, G. V.; Chowdari, B. V. R.

2002-12-01

There is an increasing demand for manganese (Mn) based mixed oxides which can effectively replace the presently used LiCoO2 as cathode in Li-ion batteries (LIB). The well-studied spinel, LiMn2O4 and its doped derivatives give a capacity of 100-120 mAh/g, but show capacity-fading on cycling especially above 55°C. The layered LiMnO2, isostructural to LiCoO2 (so called O3-structure) can be a viable cathode. However, studies have shown that it undergoes conversion to spinel structure on cycling and thus gives capacity-fading. Other alternative systems recently studied are: O2-structured layered Li-M-Mn-oxides with the general formula Li(2/3)+x(MyMn1-y)O2, M = Li, Ni, Co; x ≤ 0.33 and y = 0.1-0.67, O3-Li(Ni1/2Mn1/2)O2, Li(NixCo1-2xMnx)O2, and M'-substituted Li2MnO3 (M' = Ni, Co, Cr). Some of them are shown to have stable cycling performance, good rate-capability and structural stability over charge-discharge cycling in the 2.5-4.6 V region. Further, the electrochemical processes in the above mixed oxides have been shown to involve Ni2+/4+ or Cr3+/6+ redox couple, thus invoking novel ideas to develop new cathode materials. A brief review of the work done on the above O2- and O3-layered Li-Mn-M-oxides (M = metal) as cathodes for LIB is presented.

Ab initio identification of the Li-rich phase in LiFePO4.

PubMed

Zeng, Hua; Gu, Yue; Teng, Gaofeng; Liu, Yimeng; Zheng, Jiaxin; Pan, Feng

2018-06-27

A recent discovery of anionic redox activity in Li-rich layered compounds opens a new direction for the design of high-capacity cathode materials for lithium-ion batteries. Here using extensive ab initio calculations, the thermodynamic existence of the Li-rich phase in LiFePO4 to form Li1+xFe1-xPO4 with x not exceeding 12.5% has been proved. Anionic redox activity and structural stability during delithiation are further investigated. Interestingly, it is found that Li1+xFe1-xPO4 cannot be delithiated completely and thus cannot achieve extra capacity by anionic redox activity, because the local oxygen-ion redox will cause the fracture of the rigid framework formed by phosphate tetrahedral polyanions. Although an extra capacity cannot be realized, the excess Li-ions at Fe sites can enhance the Li-ion diffusivity along the adjacent [010] channel and contribute to the shift from 1D to 2D/3D diffusion. This study provides a fresh perspective on olivine-type LiFePO4 and offers some important clues on designing Li-rich cathode materials with high energy density.

A comparative pharmacokinetic study of three flavonoids and three anthraquinones in normal and gastrointestinal motility disorders rat plasma after the oral administration of Wei-Chang-Shu tablet using high-performance liquid chromatography-tandem mass spectrometry.

PubMed

Ren, Yan; Zhao, Weiwei; Zhao, Juanjuan; Chen, Xiangming; Yu, Chen; Liu, Mengan

2017-11-01

A simple, fast and reliable high-performance liquid chromatography-tandem mass spectrometry method was developed and validated for the simultaneous quantification and pharmacokinetic study of three flavonoids (liquiritigenin, isoliquiritigenin and formononetin) and three anthraquinones (emodin, rhein and aloe-emodin), which are the bioactive ingredients of Wei-Chang-Shu tablet found in rat plasma. After extraction by liquid-liquid extraction with ethyl acetate, chromatographic separation was achieved on an Agilent Zorbax SB-C 18 column (4.6 × 150 mm, 5 μm) at a flow rate of 1 mL/min by gradient elution using 0.1% aqueous acetic acid and acetonitrile. The detection was performed using a triple quadrupole mass spectrometer equipped with electrospray ionization source in the negative ionization and selected reaction monitoring mode. Method validation was performed in terms of specificity, carryover, linearity (r > 0.99), intra-/inter-day precision (1.0-10.1%), accuracy (relative error, <7.6%), stability (0.6-13.2%), extract recovery (74.9-91.9%) and matrix effect (89.1-109%). The lower limits of quantification of the six analytes varied from 0.92 to 10.4 ng/mL. The validated method was successfully applied to compare the pharmacokinetic properties of Wei-Chang-Shu tablet in normal rats and in rats with gastrointestinal motility disorders. The results indicated that there were obvious differences in the pharmacokinetic behavior between normal and model rats. This study will be helpful in the clinical application of Wei-Chang-Shu tablet. Copyright © 2017 John Wiley & Sons, Ltd.

Computational Studies of Solubilities of LiO 2 and Li 2O 2 in Aprotic Solvents

DOE PAGES

Cheng, Lei; Redfern, Paul; Lau, Kah Chun; ...

2017-08-12

Knowledge of the solubilities of Li 2O 2 and LiO 2 in aprotic solvents is important for insight into the discharge and charge processes of Li-O 2 batteries, but these quantities are not well known. In this contribution, the solvation free energies of molecular LiO 2 and Li 2O 2 in various organic solvents were calculated using various explicit and implicit solvent models, as well as ab initio molecular dynamics (AIMD) methods. Best estimates for the solvation energies from these calculations along with calculated lattice energies of Li 2O 2 and LiO 2 were used to determine the solubility ofmore » bulk LiO 2 and Li 2O 2. The computed solubility of LiO 2 (1.8 × 10 -2 M) is about 15 orders higher than that of Li 2O 2 (2.0 × 10 -17 M) due to a much less negative lattice energy of bulk LiO 2 compared to that of Li 2O 2. The difference in solubilities between LiO 2 and Li 2O 2 likely will affect the nucleation and growth mechanisms and resulting morphologies of the products formed during battery discharge, influencing the performance of the battery cell. In conclusion, the calculated LiO 2 and Li 2O 2 solubilities provide important information for fundamental studies of discharge and charge chemistries in Li-O 2 batteries.« less

Computational Studies of Solubilities of LiO 2 and Li 2O 2 in Aprotic Solvents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Lei; Redfern, Paul; Lau, Kah Chun

Knowledge of the solubilities of Li 2O 2 and LiO 2 in aprotic solvents is important for insight into the discharge and charge processes of Li-O 2 batteries, but these quantities are not well known. In this contribution, the solvation free energies of molecular LiO 2 and Li 2O 2 in various organic solvents were calculated using various explicit and implicit solvent models, as well as ab initio molecular dynamics (AIMD) methods. Best estimates for the solvation energies from these calculations along with calculated lattice energies of Li 2O 2 and LiO 2 were used to determine the solubility ofmore » bulk LiO 2 and Li 2O 2. The computed solubility of LiO 2 (1.8 × 10 -2 M) is about 15 orders higher than that of Li 2O 2 (2.0 × 10 -17 M) due to a much less negative lattice energy of bulk LiO 2 compared to that of Li 2O 2. The difference in solubilities between LiO 2 and Li 2O 2 likely will affect the nucleation and growth mechanisms and resulting morphologies of the products formed during battery discharge, influencing the performance of the battery cell. In conclusion, the calculated LiO 2 and Li 2O 2 solubilities provide important information for fundamental studies of discharge and charge chemistries in Li-O 2 batteries.« less

Li14P2O3N6 and Li7PN4: Computational study of two nitrogen rich crystalline LiPON electrolyte materials

NASA Astrophysics Data System (ADS)

Al-Qawasmeh, Ahmad; Holzwarth, N. A. W.

2017-10-01

Two lithium oxonitridophosphate materials are computationally examined and found to be promising solid electrolytes for possible use in all solid-state batteries having metallic Li anodes - Li14P2O3N6 and Li7PN4. The first principles simulations are in good agreement with the structural analyses reported in the literature for these materials and the computed total energies indicate that both materials are stable with respect to decomposition into binary and ternary products. The computational results suggest that both materials are likely to form metastable interfaces with Li metal. The simulations also find both materials to have Li ion migration activation energies comparable or smaller than those of related Li ion electrolyte materials. Specifically, for Li7PN4, the experimentally measured activation energy can be explained by the migration of a Li ion vacancy stabilized by a small number of O2- ions substituting for N3- ions. For Li14P2O3N6, the activation energy for Li ion migration has not yet been experimentally measured, but simulations predict it to be smaller than that measured for Li7PN4.

HYM-flation: Yang-Mills cosmology with Horndeski coupling

NASA Astrophysics Data System (ADS)

Davydov, E.; Gal'tsov, D.

2016-02-01

We propose new mechanism for inflation using classical SU (2) Yang-Mills (YM) homogeneous and isotropic field non-minimally coupled to gravity via Horndeski prescription. This is the unique generally and gauge covariant ghost-free YM theory with the curvature-dependent action leading to second-order gravity and Yang-Mills field equations. We show that its solution space contains de Sitter boundary to which the trajectories are attracted for some finite time, ensuring the robust inflation with a graceful exit. The theory can be generalized to include the Higgs field leading to two-steps inflationary scenario, in which the Planck-scale YM-generated inflation naturally prepares the desired initial conditions for the GUT-scale Higgs inflation.

Solutions to Yang-Mills Equations on Four-Dimensional de Sitter Space

NASA Astrophysics Data System (ADS)

Ivanova, Tatiana A.; Lechtenfeld, Olaf; Popov, Alexander D.

2017-08-01

We consider pure SU(2) Yang-Mills theory on four-dimensional de Sitter space dS4 and construct a smooth and spatially homogeneous magnetic solution to the Yang-Mills equations. Slicing dS4 as R ×S3, via an SU(2)-equivariant ansatz, we reduce the Yang-Mills equations to ordinary matrix differential equations and further to Newtonian dynamics in a double-well potential. Its local maximum yields a Yang-Mills solution whose color-magnetic field at time τ ∈R is given by B˜a=-1/2 Ia/(R2cosh2τ ), where Ia for a =1 , 2, 3 are the SU(2) generators and R is the de Sitter radius. At any moment, this spatially homogeneous configuration has finite energy, but its action is also finite and of the value -1/2 j (j +1 )(2 j +1 )π3 in a spin-j representation. Similarly, the double-well bounce produces a family of homogeneous finite-action electric-magnetic solutions with the same energy. There is a continuum of other solutions whose energy and action extend down to zero.

Solution-processable glass LiI-Li 4SnS 4 superionic conductors for all-solid-state Li-ion batteries

DOE PAGES

Kern Ho Park; Oh, Dae Yang; Choi, Young Eun; ...

2015-12-22

The new, highly conductive (4.1 × 10 –4 S cm –1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li 4SnS 4 is prepared using a homogeneous methanol solution. Furthermore, the solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li 4SnS 4), resulting in considerable improvements in electrochemical performances of these electrodes over conventional mixture electrodes.

Li and δ 7Li in mudrocks from the British Caledonides: Metamorphism and source influences

NASA Astrophysics Data System (ADS)

Qiu, Lin; Rudnick, Roberta L.; McDonough, William F.; Merriman, Richard J.

2009-12-01

Mudrocks from three lower Paleozoic basins in the British Caledonides (southern Lake District, northern Lake District and Southern Uplands) were investigated to determine the influence of sub-greenschist facies metamorphism on Li and the factors that control Li in fine-grained terrigenous sedimentary rocks. Metamorphic grade, as determined by KI (Kübler index) does not correlate with Li content ([Li]) and δ 7Li, indicating that sub-greenschist facies metamorphism has negligible effect on Li in these rocks. Collectively, the data for all three basins show a negative correlation between [Li] and δ 7Li and a positive correlation between [Li] and the Chemical Index of Alteration (CIA), suggesting that provenance exerts the greatest control on Li in mudrocks. Samples from the northern Lake District, which were deposited in an extensional basin, have homogeneous REE patterns, similar to shale composites (PAAS), the highest CIA, Th/U and [Li] and the lowest δ 7Li and ɛNd, consistent with their derivation from a highly weathered, ancient continental source. By contrast, mudrocks from the Southern Uplands range to the lowest CIA, Th/U and [Li] and have the highest δ 7Li and ɛNd. These samples were deposited in a forearc basin on the southern margin of the Laurentian craton and contain volcanic detritus. Their REE patterns are the most variable, ranging from average shale-like patterns to less LREE-enriched patterns. The compositional heterogeneity within the Southern Uplands mudrocks is consistent with a mixed provenance that includes juvenile crustal materials (lower [Li], ɛNd and Th/U, higher δ 7Li), likely derived from the arc, as well as more highly weathered continental detritus. Mudrocks from the southern Lake District were deposited in a foreland basin, and exhibit geochemical characteristics intermediate between the northern Lake District and the Southern Uplands mudrocks, indicating their derivation from a mixed source. Our study shows that Li

Vafa-Witten theorem and Lee-Yang singularities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aguado, M.; Asorey, M.

2009-12-15

We prove the analyticity of the finite volume QCD partition function for complex values of the {theta}-vacuum parameter. The absence of singularities different from Lee-Yang zeros only permits and cusp singularities in the vacuum energy density and never or cusps. This fact together with the Vafa-Witten diamagnetic inequality implies the vanishing of the density of Lee-Yang zeros at {theta}=0 and has an important consequence: the absence of a first order phase transition at {theta}=0. The result provides a key missing link in the Vafa-Witten proof of parity symmetry conservation in vectorlike gauge theories and follows from renormalizability, unitarity, positivity, andmore » existence of Bogomol'nyi-Prasad-Sommerfield bounds. Generalizations of this theorem to other physical systems are also discussed, with particular interest focused on the nonlinear CP{sup N} sigma model.« less

Elastic, dynamical, and electronic properties of LiHg and Li3Hg: First-principles study

NASA Astrophysics Data System (ADS)

Wang, Yan; Hao, Chun-Mei; Huang, Hong-Mei; Li, Yan-Ling

2018-04-01

The elastic, dynamical, and electronic properties of cubic LiHg and Li3Hg were investigated based on first-principles methods. The elastic constants and phonon spectral calculations confirmed the mechanical and dynamical stability of the materials at ambient conditions. The obtained elastic moduli of LiHg are slightly larger than those of Li3Hg. Both LiHg and Li3Hg are ductile materials with strong shear anisotropy as metals with mixed ionic, covalent, and metallic interactions. The calculated Debye temperatures are 223.5 K and 230.6 K for LiHg and Li3Hg, respectively. The calculated phonon frequency of the T2 g mode in Li3Hg is 326.8 cm-1. The p states from the Hg and Li atoms dominate the electronic structure near the Fermi level. These findings may inspire further experimental and theoretical study on the potential technical and engineering applications of similar alkali metal-based intermetallic compounds.

The Stack of Yang-Mills Fields on Lorentzian Manifolds

NASA Astrophysics Data System (ADS)

Benini, Marco; Schenkel, Alexander; Schreiber, Urs

2018-03-01

We provide an abstract definition and an explicit construction of the stack of non-Abelian Yang-Mills fields on globally hyperbolic Lorentzian manifolds. We also formulate a stacky version of the Yang-Mills Cauchy problem and show that its well-posedness is equivalent to a whole family of parametrized PDE problems. Our work is based on the homotopy theoretical approach to stacks proposed in Hollander (Isr. J. Math. 163:93-124, 2008), which we shall extend by further constructions that are relevant for our purposes. In particular, we will clarify the concretification of mapping stacks to classifying stacks such as BG con.

[Warming acupuncture combined with conventional acupuncture for diabetic peripheral neuropathy with syndrome of yang deficiency and cold coagulation, obstruction of collaterals and blood stasis].

PubMed

Ma, Guoqing; Ye, Ting; Sun, Zhongren

2018-03-12

To compare the clinical efficacy differences between warming acupuncture and conventional acupuncture for diabetic peripheral neuropathy (DPN) with syndrome of yang deficiency and cold coagulation, obstruction of collaterals and blood stasis. A total of 64 patients were randomly divided into a warming acupuncture group and a conventional acupuncture group, 32 cases in each one. Based on basic treatment of blood glucose regulation, warming acupuncture was applied at Pishu (BL 20), Shenshu (BL 23), Guanyuanshu (BL 26), Zusanli (ST 36), Chongyang (ST 42), Quchi (LI 11) and Hegu (LI 4) in the warming acupuncture group, while acupuncture was applied at the identical acupoints in the conventional acupuncture group. Both the treatments were given once a day with an interval of one day every six days; totally the treatment was given for 4 weeks. The TCM symptom score, Toronto clinical scoring system (TCSS) and nerve conduction velocity (NCV) before and after treatment were compared in the two groups. After treatment, the TCM symptom scores in the two groups were significantly reduced (both P <0.01); the improvement of TCM symptom in the warming acupuncture group was superior to that in the conventional acupuncture group ( P <0.05). After treatment, the TCSS scores in the two groups were significantly reduced (both P <0.01); the TCSS score in the warming acupuncture group was significantly lower than that in the conventional acupuncture group ( P <0.05). After treatment, the NCV of motor nerve of tibial nerve and nervus peroneus communis, as well as sensory nerve of tibial nerve and sural nerve was improved in the warming acupuncture group (all P <0.05), while only the NCV of motor nerve and sensory nerve of tibial nerve was improved in the conventional acupuncture group (both P <0.05); there were no significant difference between the two groups (all P >0.05). Warming acupuncture and conventional acupuncture could both increase TCM symptom score, improve NCV in patients of

[Effect of jingui shenqi pill and its disassembled recipes on ovarian functions in shen yang deficiency female rats].

PubMed

Long, Yong-Ling; Li, Zheng-Mu

2013-07-01

To observe the effect of Jingui Shenqi Pill (JSP) and its disassembled recipes (supplementing Shen yang, supplementing Shen yin, and supplementing Shen yang and Shen yin) on ovarian functions of female rats of Shen yang deficiency syndrome (SYDS). Totally 55 SD female rats were randomly divided into 5 groups, i.e., the normal control group, the model group, the Shen yang supplementing group, the Shen yin supplementing group, the Shen yang and Shen yin supplementing group, 11 in each group. Except the normal control group, rats in the rest group were injected with hydrocortisone at the daily dose of 25 mg/kg at the muscle of femoribus internus for 12 successive days. From the 13th day after successful modeling, rats were administered by gastrogavage with different recipes at the dose of 1 mL/100 g (2.75 g/kg Shen yang supplementing recipe; 6.25 g/kg Shen yin supplementing recipe; 6.75 g/kg JSP), once daily for 20 successive days. Equal volume of normal saline was given to those in the normal control group and the model group, once daily for 20 successive days. Blood was withdrawn from the orbit on the 2nd day after intervention. The serum estradiol (E2) and progesterone (P) were detected using ELISA. The weight of uterus and ovarian index (VI) were calculated. The pathological changes were observed by HE staining. The general condition of rats in the Shen yang and Shen yin supplementing group were improved. The body weight (g) was added by 35.0 +/- 12.5 in the normal control group, 16.7 +/- 7.4 in the model group, 20.2 +/- 6.9 in the Shen yang supplementing group, 18.3 +/- 3.6 in the Shen yin supplementing group, and 29.4 +/- 12.2 in the Shen yang and Shen yin supplementing group. The uterus VI (mg/100 g) was 183.4 +/- 11.6 in the normal control group,144.0 +/- 6.5 in the model group,158.7 +/- 6.3 in the Shen yang supplementing group,152.1 +/- 6.9 in the Shen yin supplementing group, and 172.8 +/- 8.1 in the Shen yang and Shen yin supplementing group. The ovarian VI

Color Memory: A Yang-Mills Analog of Gravitational Wave Memory.

PubMed

Pate, Monica; Raclariu, Ana-Maria; Strominger, Andrew

2017-12-29

A transient color flux across null infinity in classical Yang-Mills theory is considered. It is shown that a pair of test "quarks" initially in a color singlet generically acquire net color as a result of the flux. A nonlinear formula is derived for the relative color rotation of the quarks. For a weak color flux, the formula linearizes to the Fourier transform of the soft gluon theorem. This color memory effect is the Yang-Mills analog of the gravitational memory effect.

Color Memory: A Yang-Mills Analog of Gravitational Wave Memory

NASA Astrophysics Data System (ADS)

Pate, Monica; Raclariu, Ana-Maria; Strominger, Andrew

2017-12-01

A transient color flux across null infinity in classical Yang-Mills theory is considered. It is shown that a pair of test "quarks" initially in a color singlet generically acquire net color as a result of the flux. A nonlinear formula is derived for the relative color rotation of the quarks. For a weak color flux, the formula linearizes to the Fourier transform of the soft gluon theorem. This color memory effect is the Yang-Mills analog of the gravitational memory effect.

Indicators of Provenance Weathering: Li and δ7Li in Mudrocks from the British Caledonides

NASA Astrophysics Data System (ADS)

Qiu, L.; Rudnick, R. L.; McDonough, W. F.; Merriman, R. J.

2008-12-01

We determined the Li concentration [Li] and isotopic composition (δ7Li), as well as major, trace element and Sr and Nd isotopic compositions of mudrocks (mudstone, shale, slate) from three Lower Paleozoic basins within the British Caledonides in order to determine the effects of sub-greenschist facies metamorphism on Li and the factors that control Li in mudrocks. [Li] varies widely, from 29 to 139 ppm, with mudrocks from the northern Lake District generally having higher concentrations (56-136 ppm, average 102 ppm) than those from the Scottish Southern Uplands (28-74 ppm, average 50 ppm) or southern Lake District (40-91 ppm, average 52 ppm) basins. δ7Li of mudrocks from the northern Lake District (δ7Li =-3.2 ±1.6 permil, 2σ) are relatively constant compared to those of the mudrocks from the southern Lake District (-3.4 permil to 0 permil) and the Southern Uplands (-4.4 permil to +3.7 permil). Metamorphic grade, determined by the Kübler index method, does not correlate with [Li] or δ7Li, indicating that sub-greenschist facies metamorphism had little effect on Li in these mudrocks. Collectively, the data for all three basins show a negative correlation between [Li] and δ7Li and a positive correlation between [Li] and the chemical index of alteration (CIA), suggesting that provenance exerts the greatest control on Li in mudrocks. Samples from the northern Lake District, which were deposited in an extensional basin, have homogeneous REE patterns, similar to shale composites (PAAS and NASC), the highest CIA, Th/U and [Li] and the lowest δ7Li and ɛNd, consistent with their derivation from a highly weathered ancient continental source. By contrast, mudrocks from the Southern Uplands range to the lowest CIA, Th/U and [Li] and have the highest δ7Li and ɛNd. These samples were deposited in a subudction zone on the southern margin of the Laurentian craton and contain volcanic detritus derived from a proximal arc. They have the most variable REE patterns, ranging

NASA Goddards LiDAR, Hyperspectral and Thermal (G-LiHT) Airborne Imager

NASA Technical Reports Server (NTRS)

Cook, Bruce D.; Corp, Lawrence A.; Nelson, Ross F.; Middleton, Elizabeth M.; Morton, Douglas C.; McCorkel, Joel T.; Masek, Jeffrey G.; Ranson, Kenneth J.; Ly, Vuong; Montesano, Paul M.

2013-01-01

The combination of LiDAR and optical remotely sensed data provides unique information about ecosystem structure and function. Here, we describe the development, validation and application of a new airborne system that integrates commercial off the shelf LiDAR hyperspectral and thermal components in a compact, lightweight and portable system. Goddard's LiDAR, Hyperspectral and Thermal (G-LiHT) airborne imager is a unique system that permits simultaneous measurements of vegetation structure, foliar spectra and surface temperatures at very high spatial resolution (approximately 1 m) on a wide range of airborne platforms. The complementary nature of LiDAR, optical and thermal data provide an analytical framework for the development of new algorithms to map plant species composition, plant functional types, biodiversity, biomass and carbon stocks, and plant growth. In addition, G-LiHT data enhance our ability to validate data from existing satellite missions and support NASA Earth Science research. G-LiHT's data processing and distribution system is designed to give scientists open access to both low- and high-level data products (http://gliht.gsfc.nasa.gov), which will stimulate the community development of synergistic data fusion algorithms. G-LiHT has been used to collect more than 6,500 km2 of data for NASA-sponsored studies across a broad range of ecoregions in the USA and Mexico. In this paper, we document G-LiHT design considerations, physical specifications, instrument performance and calibration and acquisition parameters. In addition, we describe the data processing system and higher-level data products that are freely distributed under NASA's Data and Information policy.

Feasibility tests of nickel as a containment material of molten Li2O-LiCl salt containing Li metal at 650 °C during electrolytic reduction

NASA Astrophysics Data System (ADS)

Choi, Eun-Young; Lee, Jeong

2017-11-01

In this study, we investigated the feasibility of nickel (Ni) as a material to contain molten Li2O-LiCl salt containing lithium (Li) metal at 650 °C as an electrolyte during the electrolytic reduction process of pyroprocessing (also known as oxide reduction, OR). First, the behaviors of Ni in four different LiCl salts (0.1 wt% Li-LiCl, 1 and 8 wt% Li2O-LiCl, and 8 wt% Li2O-0.1 wt% Li-LiCl) in an argon atmosphere were examined through immersion tests. Then, Ni was used as a vessel material for five consecutive OR runs of simulated oxide fuel using 1.0 wt% Li2O-LiCl salt. The tested Ni was analyzed by microbalance, X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Concentrations of Ni in the salt were measured using inductively coupled plasma atomic emission spectroscopy. No corrosion product of Ni, except Cr2Ni3, was observed on the Ni used for both the salt-immersion tests and the OR runs because the Ni was not exposed to oxygen gas. However, leaching of Ni in the OR salt containing excessive Li metal was observed. Therefore, Ni can be used as the salt containment material in the OR process when excessive Li metal and oxygen gas in the salt are maintained at low levels.

An Ultrahigh Capacity Graphite/Li 2S Battery with Holey-Li 2S Nanoarchitectures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ye, Fangmin; Noh, Hyungjun; Lee, Hongkyung

The pairing of high-capacity Li 2S cathode (1166 mAh g -1) and lithium-free anode (LFA) provides an unparalleled potential in developing safe and energy-dense next-generation secondary batteries. However, the low utilization of the Li 2S cathode and the lack of electrolytes compatible to both electrodes are impeding the development. Here, a novel graphite/Li 2S battery system, which features a self-assembled, holey-Li 2S nanoarchitecture and a stable solid electrolyte interface (SEI) on the graphite electrode, is reported. The holey structure on Li 2S is beneficial in decomposing Li 2S at the first charging process due to the enhanced Li ion extractionmore » and transfer from the Li 2S to the electrolyte. In addition, the concentrated dioxolane (DOL)-rich electrolyte designed lowers the irreversible capacity loss for SEI formation. By using the combined strategies, the graphite/holey-Li 2S battery delivers an ultrahigh discharge capacity of 810 mAh g -1 at 0.1 C (based on the mass of Li 2S) and of 714 mAh g -1 at 0.2 C. Moreover, it exhibits a reversible capacity of 300 mAh g -1 after a record lifecycle of 600 cycles at 1 C. These results suggest the great potential of the designed LFA/holey-Li 2S batteries for practical use.« less

An Ultrahigh Capacity Graphite/Li 2S Battery with Holey-Li 2S Nanoarchitectures

DOE PAGES

Ye, Fangmin; Noh, Hyungjun; Lee, Hongkyung; ...

2018-05-07

The pairing of high-capacity Li 2S cathode (1166 mAh g -1) and lithium-free anode (LFA) provides an unparalleled potential in developing safe and energy-dense next-generation secondary batteries. However, the low utilization of the Li 2S cathode and the lack of electrolytes compatible to both electrodes are impeding the development. Here, a novel graphite/Li 2S battery system, which features a self-assembled, holey-Li 2S nanoarchitecture and a stable solid electrolyte interface (SEI) on the graphite electrode, is reported. The holey structure on Li 2S is beneficial in decomposing Li 2S at the first charging process due to the enhanced Li ion extractionmore » and transfer from the Li 2S to the electrolyte. In addition, the concentrated dioxolane (DOL)-rich electrolyte designed lowers the irreversible capacity loss for SEI formation. By using the combined strategies, the graphite/holey-Li 2S battery delivers an ultrahigh discharge capacity of 810 mAh g -1 at 0.1 C (based on the mass of Li 2S) and of 714 mAh g -1 at 0.2 C. Moreover, it exhibits a reversible capacity of 300 mAh g -1 after a record lifecycle of 600 cycles at 1 C. These results suggest the great potential of the designed LFA/holey-Li 2S batteries for practical use.« less

Electronic structures of filled tetrahedral semiconductors LiMgN and LiZnN: conduction band distortion

NASA Astrophysics Data System (ADS)

Yu, L. H.; Yao, K. L.; Liu, Z. L.

2004-12-01

The band structures of the filled tetrahedral semiconductors LiMgN and LiZnN, viewed as the zinc-blende (MgN) - and (ZnN) - lattices partially filled with He-like Li + ion interstitials, were studied using the full-potential linearized augmented plane wave method (FP-LAPW) within density functional theory. The conduction band distortions of LiMgN and LiZnN, compared to their “parent” zinc-blende analog AlN and GaN, are discussed. It was found that the insertion of Li + ions at the interstitial sites near the cation or anion pushes the conduction band minimum of the X point in the Brillouin zone upward, relative to that of the Γ point, for both (MgN) - and (ZnN) - lattices (the valence band maximum is at Γ for AlN, GaN, LiMgN, and LiZnN), which provides a method to convert a zinc-blende indirect gap semiconductor into a direct gap material, but the conduction band distortion of the β phase (Li + near the cation) is quite stronger than that of the α phase (Li + near the anion). The total energy calculations show the α phase to be more stable than the β phase for both LiMgN and LiZnN. The Li-N and Mg-N bonds exhibit a strong ionic character, whereas the Zn-N bond has a strong covalent character in LiMgN and LiZnN.

LiGa(OTf)(sub 4) as an Electrolyte Salt for Li-Ion Cells

NASA Technical Reports Server (NTRS)

Reddy, V. Prakash; Prakash, G. K. Syria; Hu, Jinbo; Yan, Ping; Smart, Marshall; Bugga, ratnakumar; Chin, Keith; Surampudi, Subarao

2008-01-01

Lithium tetrakis(trifluoromethane sulfo - nato)gallate [abbreviated "LiGa(OTf)4" (wherein "OTf" signifies trifluoro - methanesulfonate)] has been found to be promising as an electrolyte salt for incorporation into both liquid and polymer electrolytes in both rechargeable and non-rechargeable lithium-ion electrochemical cells. This and other ingredients have been investigated in continuing research oriented toward im proving the performances of rechargeable lithium-ion electrochemical cells, especially at low temperatures. This research at earlier stages, and the underlying physical and chemical principles, were reported in numerous previous NASA Tech Briefs articles. As described in more detail in those articles, lithiumion cells most commonly contain nonaqueous electrolyte solutions consisting of lithium hexafluorophosphate (LiPF6) dissolved in mixtures of cyclic and linear alkyl carbonates, including ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), and ethyl methyl carbonate (EMC). Although such LiPF6-based electrolyte solutions are generally highly ionically conductive and electrochemically stable, as needed for good cell performance, there is interest in identifying alternate lithium electrolyte salts that, relative to LiPF6, are more resilient at high temperature and are less expensive. Experiments have been performed on LiGa(OTf)4 as well as on several other candidate lithium salts in pursuit of this interest. As part of these experiments, LiGa(OTf)4 was synthesized by the reaction of Ga(OTf)3 with an equimolar portion of LiOTf in a solvent consisting of anhydrous acetonitrile. Evaporation of the solvent yielded LiGa(OTf)4 as a colorless crystalline solid. The LiGa(OTf)4 and the other salts were incorporated into solutions with PC and DMC. The resulting electrolyte solutions exhibited reasonably high ionic conductivities over a relatively wide temperature range down to 40 C (see figure). In cyclic

Line Lists for LiF and LiCl in the X 1Σ+ Ground State

NASA Astrophysics Data System (ADS)

Bittner, Dror M.; Bernath, Peter F.

2018-03-01

Vibration–rotation line lists for 6LiF, 7LiF, 6Li35Cl, 6Li37Cl, 7Li35Cl, and 7Li37Cl in the X 1Σ+ ground states have been prepared. The rovibrational energy levels have been calculated using potential energy surfaces determined by direct potential-fitting employing the rotational and rovibrational transition frequencies of all isotopologues, and required the inclusion of Born–Oppenheimer breakdown terms. Dipole moment functions calculated ab initio at the MRCI/aug-cc-pwCV5Z level have been used for line strength calculations. Partition functions for temperatures up to 5000 K have been calculated. LiF and LiCl are predicted to be present in the atmospheres of hot rocky exoplanets, brown dwarfs, and cool stars.

Higgs Amplitudes from N=4 Supersymmetric Yang-Mills Theory.

PubMed

Brandhuber, Andreas; Kostacińska, Martyna; Penante, Brenda; Travaglini, Gabriele

2017-10-20

Higgs plus multigluon amplitudes in QCD can be computed in an effective Lagrangian description. In the infinite top-mass limit, an amplitude with a Higgs boson and n gluons is computed by the form factor of the operator TrF^{2}. Up to two loops and for three gluons, its maximally transcendental part is captured entirely by the form factor of the protected stress tensor multiplet operator T_{2} in N=4 supersymmetric Yang-Mills theory. The next order correction involves the calculation of the form factor of the higher-dimensional, trilinear operator TrF^{3}. We present explicit results at two loops for three gluons, including the subleading transcendental terms derived from a particular descendant of the Konishi operator that contains TrF^{3}. These are expressed in terms of a few universal building blocks already identified in earlier calculations. We show that the maximally transcendental part of this quantity, computed in nonsupersymmetric Yang-Mills theory, is identical to the form factor of another protected operator, T_{3}, in the maximally supersymmetric theory. Our results suggest that the maximally transcendental part of Higgs amplitudes in QCD can be entirely computed through N=4 super Yang-Mills theory.

Electrochemical behavior of LiV3O8 positive electrode in hybrid Li,Na-ion batteries

NASA Astrophysics Data System (ADS)

Maletti, S.; Sarapulova, A.; Tsirlin, A. A.; Oswald, S.; Fauth, F.; Giebeler, L.; Bramnik, N. N.; Ehrenberg, H.; Mikhailova, D.

2018-01-01

Vanadium(V)-containing oxides show superior intercalation properties for alkaline ions, although the performance of the material strongly depends on its surface morphology. In this work, intercalation activity of LiV3O8, prepared by a conventional solid state synthesis, is demonstrated for the first time in non-aqueous Li,Na-ion hybrid batteries with Na as negative electrode, and different Na/Li ratios in the electrolyte. In the pure Na-ion cell, one Na per formula unit of LiV3O8 can be reversibly inserted at room temperature via a two-step process, while further intercalation leads to gradual amorphisation of the material, with a specific capacity of 190 mAhg-1 after 10 cycles in the potential window of 0.8-3.4 V. Hybrid Li,Na-ion batteries feature simultaneous intercalation of Li+ and Na+ cations into LiV3O8, resulting in the formation of a second phase. Depending on the electrolyte composition, this second phase bears structural similarities either to Li0.7Na0.7V3O8 in Na-rich electrolytes, or to Li4V3O8 in Li-rich electrolytes. The chemical diffusion coefficients of Na+ and Li+ in crystalline LiV3O8 are very close, hence explaining the co-intercalation of these cations. As DFT calculations show, once formed, the Li0.7Na0.7V3O8-type structure favors intercalation of Na+, whereas the LiV3O8-type prefers to accommodate Li+ cations.

Li interactions with the B40 fullerene and its application in Li-ion batteries: DFT studies

NASA Astrophysics Data System (ADS)

Moradi, Morteza; Bagheri, Zargham; Bodaghi, Ali

2017-05-01

The interaction of Li and Li+ with a B40 all-boron fullerene was theoretically investigated at the B3LYP, and Minnesota 2006 levels of theory. It was found that, unexpectedly, the interaction Li+ cation with the electron deficient B40 fullerene is stronger than the Li atom. It indicates that the B40 fullerene does not act as a conventional Lewis acid because of its highly correlated structure. Frontier molecular orbitals, partial density of states, and natural bond orbital analyses were used to discuss this unusual behavior. Our calculations indicate that this behavior makes the B40 fullerene more appropriate for application in the Li-ion batteries as anode material. The calculated cell voltage is about 530 mV. Also, it was found that Hartree Fock (HF) exchange percentage of density functionals has a reverse effect on the adsorption energies of Li and Li+. This energy is increased and decreased, respectively, for Li+ and Li adsorptions by increasing %HF exchange. Finally, a potential energy surface for Li and Li+ penetration into B40 fullerene was predicted.

Analysis of Ward identities in supersymmetric Yang-Mills theory

NASA Astrophysics Data System (ADS)

Ali, Sajid; Bergner, Georg; Gerber, Henning; Montvay, Istvan; Münster, Gernot; Piemonte, Stefano; Scior, Philipp

2018-05-01

In numerical investigations of supersymmetric Yang-Mills theory on a lattice, the supersymmetric Ward identities are valuable for finding the critical value of the hopping parameter and for examining the size of supersymmetry breaking by the lattice discretisation. In this article we present an improved method for the numerical analysis of supersymmetric Ward identities, which takes into account the correlations between the various observables involved. We present the first complete analysis of supersymmetric Ward identities in N=1 supersymmetric Yang-Mills theory with gauge group SU(3). The results indicate that lattice artefacts scale to zero as O(a^2) towards the continuum limit in agreement with theoretical expectations.

Association and Diffusion of Li(+) in Carboxymethylcellulose Solutions for Environmentally Friendly Li-ion Batteries.

PubMed

Casalegno, Mosè; Castiglione, Franca; Passarello, Marco; Mele, Andrea; Passerini, Stefano; Raos, Guido

2016-07-21

Carboxymethylcellulose (CMC) has been proposed as a polymeric binder for electrodes in environmentally friendly Li-ion batteries. Its physical properties and interaction with Li(+) ions in water are interesting not only from the point of view of electrode preparation-processability in water is one of the main reasons for its environmental friendliness-but also for its possible application in aqueous Li-ion batteries. We combine molecular dynamics simulations and variable-time pulsed field gradient spin-echo (PFGSE) NMR spectroscopy to investigate Li(+) transport in CMC-based solutions. Both the simulations and experimental results show that, at concentrations at which Li-CMC has a gel-like consistency, the Li(+) diffusion coefficient is still very close to that in water. These Li(+) ions interact preferentially with the carboxylate groups of CMC, giving rise to a rich variety of coordination patterns. However, the diffusion of Li(+) in these systems is essentially unrestricted, with a fast, nanosecond-scale exchange of the ions between CMC and the aqueous environment. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CP Symmetry, Lee-Yang zeros and Phase Transitions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aguado, M.; Asorey, M.

2011-05-23

We analyze the analytic properties of {theta}-vacuum in QCD and its connection with spontaneous symmetry breaking of CP symmetry. A loss of analyticity in the {theta}-vacuum energy density can only be due to the accumulation of Lee-Yang zeros at some real values of {theta}. In the case of first order transitions these singularities are always associated to and cusp singularities and never to or cusps, which in the case {theta} = 0 are incompatible with the Vafa-Witten diamagnetic inequality This fact provides a key missing link in the Vafa-Witten proof of parity symmetry conservation in vector-like gauge theories like QCD.more » The argument is very similar to that used in the derivation of Bank-Casher formula for chiral symmetry breaking. However, the and behavior does not exclude the existence of a first phase transition at {theta} = {pi}, where a and cusp singularity is not forbidden by any inequality; in this case the topological charge condensate is proportional to the density of Lee-Yang zeros at {theta} = {pi}. Moreover, Lee-Yang zeros could give rise to a second order phase transition at {theta} = 0, which might be very relevant for the interpretation of the anomalous behavior of the topological susceptibility in the CP{sup 1} sigma model.« less

Reversible Li storage for nanosize cation/anion-disordered rocksalt-type oxyfluorides: LiMoO2 - x LiF (0 ≤ x ≤ 2) binary system

NASA Astrophysics Data System (ADS)

Takeda, Nanami; Hoshino, Satoshi; Xie, Lixin; Chen, Shuo; Ikeuchi, Issei; Natsui, Ryuichi; Nakura, Kensuke; Yabuuchi, Naoaki

2017-11-01

A binary system of LiMoO2 - x LiF (0 ≤ x ≤ 2), Li1+xMoO2Fx, is systematically studied as potential positive electrode materials for rechargeable Li batteries. Single phase and nanosized samples on this binary system are successfully prepared by using a mechanical milling route. Crystal structures and Li storage properties on the binary system are also examined. Li2MoO2F (x = 1), which is classified as a cation-/anion-disordered rocksalt-type structure and is a thermodynamically metastable phase, delivers a large reversible capacity of over 300 mAh g-1 in Li cells with good reversibility. Highly reversible Li storage is realized for Li2MoO2F consisting of nanosized particles based on Mo3+/Mo5+ two-electron redox as evidenced by ex-situ X-ray absorption spectroscopy coupled with ex-situ X-ray diffractometry. Moreover, the presence of the most electronegative element in the framework structure effectively increases the electrode potential of Mo redox through an inductive effect. From these results, potential of nanosized lithium molybdenum oxyfluorides for high-capacity positive electrode materials of rechargeable Li batteries are discussed.

Yang-Baxter σ -models, conformal twists, and noncommutative Yang-Mills theory

NASA Astrophysics Data System (ADS)

Araujo, T.; Bakhmatov, I.; Colgáin, E. Ó.; Sakamoto, J.; Sheikh-Jabbari, M. M.; Yoshida, K.

2017-05-01

The Yang-Baxter σ -model is a systematic way to generate integrable deformations of AdS5×S5 . We recast the deformations as seen by open strings, where the metric is undeformed AdS5×S5 with constant string coupling, and all information about the deformation is encoded in the noncommutative (NC) parameter Θ . We identify the deformations of AdS5 as twists of the conformal algebra, thus explaining the noncommutativity. We show that the unimodularity condition on r -matrices for supergravity solutions translates into Θ being divergence-free. Integrability of the σ -model for unimodular r -matrices implies the existence and planar integrability of the dual NC gauge theory.

Photoionization of Li2

NASA Astrophysics Data System (ADS)

Li, Y.; Pindzola, M. S.; Ballance, C. P.; Colgan, J.

2014-05-01

Single and double photoionization cross sections for Li2 are calculated using a time-dependent close-coupling method. The correlation between the outer two electrons of Li2 is obtained by relaxation of the close-coupled equations in imaginary time. Propagation of the close-coupled equations in real time yields single and double photoionization cross sections for Li2. The two active electron cross sections are compared with one active electron distorted-wave and close-coupling results for both Li and Li2. This work was supported in part by grants from NSF and US DoE. Computational work was carried out at NERSC in Oakland, California, NICS in Knoxville, Tennessee, and OLCF in Oak Ridge, Tennessee.

Confinement, holonomy, and correlated instanton-dyon ensemble: SU(2) Yang-Mills theory

NASA Astrophysics Data System (ADS)

Lopez-Ruiz, Miguel Angel; Jiang, Yin; Liao, Jinfeng

2018-03-01

The mechanism of confinement in Yang-Mills theories remains a challenge to our understanding of nonperturbative gauge dynamics. While it is widely perceived that confinement may arise from chromomagnetically charged gauge configurations with nontrivial topology, it is not clear what types of configurations could do that and how, in pure Yang-Mills and QCD-like (nonsupersymmetric) theories. Recently, a promising approach has emerged, based on statistical ensembles of dyons/anti-dyons that are constituents of instanton/anti-instanton solutions with nontrivial holonomy where the holonomy plays a vital role as an effective "Higgsing" mechanism. We report a thorough numerical investigation of the confinement dynamics in S U (2 ) Yang-Mills theory by constructing such a statistical ensemble of correlated instanton-dyons.

Anxiolytic effect of Kami-Shoyo-San (TJ-24) in mice: possible mediation of neurosteroid synthesis.

PubMed

Mizowaki, M; Toriizuka, K; Hanawa, T

2001-09-21

We assessed the anxiolytic effect of Kami-Shoyo-San (Jia-wei-xiao-yao-san; TJ-24), one of a traditional Chinese herbal medicine used for the treatment of menopausal anxiety, by the social interaction (SI) test in male mice. Acute administration of TJ-24 (25-100 mg/kg, p.o.), as well as the gamma-amino-butyric acidA/benzodiazepine (GABA(A)/BZP) receptor agonist diazepam (1-3 mg/kg, i.p.), dose dependently increased the SI time, respectively. The GABA(A) receptor antagonist picrotoxin blocked the effects of TJ-24 and diazepam. TJ-24-induced SI behavior was significantly blocked by the GABA(A)/BZP receptor inverse agonist Ro 15-4513 and the GABA(A)/BZP receptor antagonist flumazenil. In addition, 5alpha-reductase inhibitor finasteride potently blocked the effect of TJ-24 without attenuating the basal level by itself. These findings suggest that TJ-24 shows the anxiolytic effect through the neurosteroid synthesis followed by GABA(A)/BDZ receptor stimulations.

Noncommutative Yang-Mills from equivalence of star products

NASA Astrophysics Data System (ADS)

Jurčo, B.; Schupp, P.

2000-05-01

It is shown that the transformation between ordinary and noncommutative Yang-Mills theory as formulated by Seiberg and Witten is due to the equivalence of certain star products on the D-brane world-volume.

Complex Diffusion Mechanisms for Li in Feldspar: Re-thinking Li-in-Plag Geospeedometry

NASA Astrophysics Data System (ADS)

Holycross, M.; Watson, E. B.

2017-12-01

In recent years, the lithium isotope system has been applied to model processes in a wide variety of terrestrial environments. In igneous settings, Li diffusion gradients have been frequently used to time heating episodes. Lithium partitioning behavior during decompression or cooling events drives Li transfer between phases, but the extent of Li exchange may be limited by its diffusion rate in geologic materials. Lithium is an exceptionally fast diffuser in silicate media, making it uniquely suited to record short-lived volcanic phenomena. The Li-in-plagioclase geospeedometer is often used to time explosive eruptions by applying laboratory-calibrated Li diffusion coefficients to model concentration profiles in magmatic feldspar samples. To quantify Li transport in natural scenarios, experimental measurements are needed that account for changing temperature and oxygen fugacity as well as different feldspar compositions and crystallographic orientation. Ambient pressure experiments were run at RPI to diffuse Li from a powdered spodumene source into polished sanidine, albite, oligoclase or anorthite crystals over the temperature range 500-950 ºC. The resulting 7Li concentration gradients developed in the mineral specimens were evaluated using laser ablation ICP-MS. The new data show that Li diffusion in all feldspar compositions simultaneously operates by both a "fast" and "slow" diffusion mechanism. Fast path diffusivities are similar to those found by Giletti and Shanahan [1997] for Li diffusion in plagioclase and are typically 10 to 20 times greater than slow path diffusivities. Lithium concentration gradients in the feldspar experiments plot in the shape of two superimposed error function curves with the slow diffusion regime in the near-surface of the crystal. Lithium diffusion is most sluggish in sanidine and is significantly faster in the plagioclase feldspars. It is still unclear what diffusion mechanism operates in nature, but the new measurements may impact

[Evolution of Dissolved Organic Matter Properties in a Constructed Wetland of Xiao River, Hebei].

PubMed

Ma, Li-na; Zhang, Hui; Tan, Wen-bing; Yu, Min-da; Huang, Zhi-gang; Gao, Ru-tai; Xi, Bei-dou; He, Xiao-song

2016-01-01

The evolution of water DOC and COD, and the source, chemical structure, humification degree and redox of dissolved organic matter (DOM) in a constructed wetland of Xiao River, Hebei, was investigated by 3D excitation--emission matrix fluorescence spectroscopy coupled with ultraviolet spectroscopy and chemical reduction, in order to explore the geochemical processes and environmental effects of DOM. Although DOC contributes at least 60% to COD, its decrease in the constructed wetland is mainly caused by the more extensive degradation of elements N, H, S, and P than C in DOM, and 65% is contributed from the former. DOM is mainly consisted of microbial products based on proxies f470/520 and BIX, indicating that DOM in water is apparently affected by microbial degradation. The result based on PARAFAC model shows that DOM in the constructed wetland contains protein-like and humus-like components, and Fulvic- and humic-like components are relatively easier to degrade than protein-like components. Fulvic- and humic-like components undergo similar decomposition in the constructed wetland. A common source of chromophoric dissolved organic matter (CDOM) and fluorescent dissolved organic matter (FDOM) exists; both CDOM and FDOM are mainly composed of a humus-like material and do not exhibit selective degradation in the constructed wetland. The proxies E2 /E3, A240-400, r(A, C) and HIX in water have no changes after flowing into the constructed wetland, implying that the humification degree of DOM in water is hardly affected by wet constructed wetland. However, the constructed wetland environment is not only beneficial in forming the reduced state of DOM, but also facilitates the reduction of ferric. It can also improve the capability of DOM to function as an electron shuttle. This result may be related to the condition that the aromatic carbon of DOM can be stabilized well in the constructed wetland.

Low-lying electronic states of Li 2+ and Li 2-

NASA Astrophysics Data System (ADS)

Konowalow, Daniel D.; Fish, James L.

1984-02-01

Potential curves for the eight lowest lying electronic states of Li2+ and the two lowest-lying states of Li2- are obtained by valence configuration calculations which-utilize an effective core potential. The calculated ionization potential of the ground state of Li2 is found to b. 5.16 eV and its electron affinity is 0.429 eV. Both values are in excellent agreement with recent experimental values and with value deduced from other high quality ab initio quantum mechanical treatments. When our potential curve for the Li2+(12Σg+ state, is corrected for the core-valence correlation error we obtain spectroscopic constants which agree nicely with the experimental values of Bernheim, Gold and Tipton (BGT). For example, we findDe = 10460 ± 140 cm-1 while BGT reportDe = 10469 ± 6 cm-1.

Preparation and some properties of Cu-Li alloys containing up to 20 at. % Li

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mendelsohn, M.; Krauss, A.R.; Gruen, D.M.

1985-01-01

Lithium strongly segregates to the surface of Cu-Li alloys, thus substantially lowering the Cu sputtering yield relative to pure Cu. Use of Cu-Li limiters or divertors in tokamaks can therefore be expected to be beneficial in limiting high-Z plasma impurity influx. A large scale (100-200g) method for the preparation of Cu-Li alloys is described. Analysis reveals that on solidification from the melt stratification occurs which leads to compositional inhomogeneity. The results are discussed in the light of the Cu-Li binary phase diagram and rationalized on the basis of large density differences between Cu and Cu-Li solid solutions. It is concludedmore » that obtaining homogeneous Cu-Li solid solutions is a nontrivial task.« less

Glueball spectra from a matrix model of pure Yang-Mills theory

NASA Astrophysics Data System (ADS)

Acharyya, Nirmalendu; Balachandran, A. P.; Pandey, Mahul; Sanyal, Sambuddha; Vaidya, Sachindeo

2018-05-01

We present variational estimates for the low-lying energies of a simple matrix model that approximates SU(3) Yang-Mills theory on a three-sphere of radius R. By fixing the ground state energy, we obtain the (integrated) renormalization group (RG) equation for the Yang-Mills coupling g as a function of R. This RG equation allows to estimate the mass of other glueball states, which we find to be in excellent agreement with lattice simulations.

Yang-Mills matrix mechanics and quantum phases

NASA Astrophysics Data System (ADS)

Pandey, Mahul; Vaidya, Sachindeo

The SU(2) Yang-Mills matrix model coupled to fundamental fermions is studied in the adiabatic limit, and quantum critical behavior is seen at special corners of the gauge field configuration space. The quantum scalar potential for the gauge field induced by the fermions diverges at the corners, and is intimately related to points of enhanced degeneracy of the fermionic Hamiltonian. This in turn leads to superselection sectors in the Hilbert space of the gauge field, the ground states in different sectors being orthogonal to each other. The SU(2) Yang-Mills matrix model coupled to two Weyl fermions has three quantum phases. When coupled to a massless Dirac fermion, the number of quantum phases is four. One of these phases is the color-spin locked phase. This paper is an extended version of the lectures given by the second author (SV) at the International Workshop on Quantum Physics: Foundations and Applications, Bangalore, in February 2016, and is based on [1].

Observation of Li Diffusion in Cathode Sheets of Li-ion Battery by μ+SR

NASA Astrophysics Data System (ADS)

Umegaki, Izumi; Kawauchi, Shigehiro; Nozaki, Hiroshi; Sawada, Hiroshi; Nakano, Hiroyuki; Harada, Masashi; Cottrell, Stephen P.; Coomer, Fiona C.; Telling, Mark; Sugiyama, Jun

In order to know the change in Li diffusion during the operation of Li-ion batteries, we have initiated to measure Li diffusion not only in a powder sample but also in a cathode sheet with μ+SR. As the first step, we have measured μ+SR spectra on a cathode sheet, in which a mixture of a cathode material Li(Ni, Co)O2, a binder, and conducting additives is coated on an Al foil. The zero-field μ+SR spectrum exhibited a typical Kubo-Toyabe (KT) type relaxation at 100 K. By subtracting the contribution of the muons stopped in the Al foil, we found that Li+ ion starts to diffuse above 100 K in the Li(Ni, Co)O2. A self diffusion coefficient (DLi) at 300 K was estimated as 10-11 (cm2/s), which comparable with DLi (300 K) in the cathode materials previously reported. This leads to the future "in operando" measurements of DLi in Li-ion batteries.

Electrochemical behaviors of wax-coated Li powder/Li 4Ti 5O 12 cells

NASA Astrophysics Data System (ADS)

Park, Han Eol; Seong, Il Won; Yoon, Woo Young

The wax-coated Li powder specimen was effectively synthesized using the drop emulsion technique (DET). The wax layer on the powder was verified by SEM, Focused Ion Beam (FIB), EDX and XPS. The porosity of a sintered wax-coated Li electrode was measured by linear sweep voltammetry (LSV) and compared with that of a bare, i.e., un-coated Li electrode. The electrochemical behavior of the wax-coated Li powder anode cell was examined by the impedance analysis and cyclic testing methods. The cyclic behavior of the wax-coated Li powder anode with the Li 4Ti 5O 12 (LTO) cathode cell was examined at a constant current density of 0.35 mA cm -2 with the cut-off voltages of 1.2-2.0 V at 25 °C. Over 90% of the initial capacity of the cell remained even after the 300th cycle. The wax-coated Li powder was confirmed to be a stable anode material.

Comparative study of imide-based Li salts as electrolyte additives for Li-ion batteries

NASA Astrophysics Data System (ADS)

Sharova, Varvara; Moretti, Arianna; Diemant, Thomas; Varzi, Alberto; Behm, R. Jürgen; Passerini, Stefano

2018-01-01

Herein, we report the results of a detailed study on the use of different Li imide salts (LiTFSI, LiFSI, and LiFTFSI) as electrolyte additives for lithium-ion batteries. The introduction of lithium imide salts in the electrolyte is shown to considerably improve the first cycle coulombic efficiency and the long-term cycling stability of graphite/LiFePO4 cells. Using LiTFSI, a capacity fading of only ∼2% occurred over 600 cycles while the control cell with the state-of-the-art additive (VC) lost ∼20% of the initial capacity at 20 °C. The results of the XPS and impedance spectroscopy measurements of graphite electrodes show that, after the formation cycle, the SEI obtained in the presence of imide salts is thinner, contains more LiF and is less resistive than that obtained using VC. Despite the beneficial effect of the imide salts on the lithium-ion cell performance, a slightly reduced thermal stability of the SEI is observed.

A BRST gauge-fixing procedure for Yang Mills theory on sphere

NASA Astrophysics Data System (ADS)

Banerjee, Rabin; Deguchi, Shinichi

2006-01-01

A gauge-fixing procedure for the Yang-Mills theory on an n-dimensional sphere (or a hypersphere) is discussed in a systematic manner. We claim that Adler's gauge-fixing condition used in massless Euclidean QED on a hypersphere is not conventional because of the presence of an extra free index, and hence is unfavorable for the gauge-fixing procedure based on the BRST invariance principle (or simply BRST gauge-fixing procedure). Choosing a suitable gauge condition, which is proved to be equivalent to a generalization of Adler's condition, we apply the BRST gauge-fixing procedure to the Yang-Mills theory on a hypersphere to obtain consistent results. Field equations for the Yang-Mills field and associated fields are derived in manifestly O (n + 1) covariant or invariant forms. In the large radius limit, these equations reproduce the corresponding field equations defined on the n-dimensional flat space.

LiCl-LiI molten salt electrolyte with bismuth-lead positive electrode for liquid metal battery

NASA Astrophysics Data System (ADS)

Kim, Junsoo; Shin, Donghyeok; Jung, Youngjae; Hwang, Soo Min; Song, Taeseup; Kim, Youngsik; Paik, Ungyu

2018-02-01

Liquid metal batteries (LMBs) are attractive energy storage device for large-scale energy storage system (ESS) due to the simple cell configuration and their high rate capability. The high operation temperature caused by high melting temperature of both the molten salt electrolyte and metal electrodes can induce the critical issues related to the maintenance cost and degradation of electrochemical properties resulting from the thermal corrosion of materials. Here, we report a new chemistry of LiCl-LiI electrolyte and Bi-Pb positive electrode to lower the operation temperature of Li-based LMBs and achieve the long-term stability. The cell (Li|LiCl-LiI|Bi-Pb) is operated at 410 °C by employing the LiCl-LiI (LiCl:LiI = 36:64 mol %) electrolyte and Bi-Pb alloy (Bi:Pb = 55.5:44.5 mol %) positive electrode. The cell shows excellent capacity retention (86.5%) and high Coulombic efficiencies over 99.3% at a high current density of 52 mA cm-2 during 1000th cycles.

Configuring PSx tetrahedral clusters in Li-excess Li7P3S11 solid electrolyte

NASA Astrophysics Data System (ADS)

Jung, Wo Dum; Yun, Bin-Na; Jung, Hun-Gi; Choi, Sungjun; Son, Ji-Won; Lee, Jong-Ho; Lee, Jong-Heun; Kim, Hyoungchul

2018-04-01

We demonstrate that the Li-ion conductivity can be improved by adding a certain amount of Li (x = 0.25-0.5) as a charge carrier to the composition of glass-ceramic Li7+xP3S11. Structural analysis clarified that the structural changes caused by the ratio of ortho-thiophosphate tetrahedra PS43- and pyro-thiophosphate ditetrahedra P2S74- affect the Li-ion conductivity. The ratio of PS43- and P2S74- varies depending on x and the highest Li-ion conductivity (2.5 × 10-3 S cm-1) at x = 0.25. All-solid-state LiNi0.8Co0.15Al0.05O2/Li7.25P3S11/In-metal cell exhibits the discharge capacity of 106.2 mAh g-1. This ion conduction enhancement from excess Li is expected to contribute to the future design of sulfide-type electrolytes.

An instability of hyperbolic space under the Yang-Mills flow

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gegenberg, Jack; Day, Andrew C.; Liu, Haitao

2014-04-15

We consider the Yang-Mills flow on hyperbolic 3-space. The gauge connection is constructed from the frame-field and (not necessarily compatible) spin connection components. The fixed points of this flow include zero Yang-Mills curvature configurations, for which the spin connection has zero torsion and the associated Riemannian geometry is one of constant curvature. We analytically solve the linearized flow equations for a large class of perturbations to the fixed point corresponding to hyperbolic 3-space. These can be expressed as a linear superposition of distinct modes, some of which are exponentially growing along the flow. The growing modes imply the divergence ofmore » the (gauge invariant) perturbative torsion for a wide class of initial data, indicating an instability of the background geometry that we confirm with numeric simulations in the partially compactified case. There are stable modes with zero torsion, but all the unstable modes are torsion-full. This leads us to speculate that the instability is induced by the torsion degrees of freedom present in the Yang-Mills flow.« less

Li diffusion and the effect of local structure on Li mobility in Li2O-SiO2 glasses.

PubMed

Bauer, Ute; Welsch, Anna-Maria; Behrens, Harald; Rahn, Johanna; Schmidt, Harald; Horn, Ingo

2013-12-05

Aimed to improve the understanding of lithium migration mechanisms in ion conductors, this study focuses on Li dynamics in binary Li silicate glasses. Isotope exchange experiments and conductivity measurements were carried out to determine self-diffusion coefficients and activation energies for Li migration in Li2Si3O7 and Li2Si6O13 glasses. Samples of identical composition but different isotope content were combined for diffusion experiments in couples or triples. Diffusion profiles developed between 511 and 664 K were analyzed by femtosecond laser ablation combined with multiple collector inductively coupled plasma mass spectrometry (fs LA-MC-ICP-MS) and secondary ion mass spectrometry (SIMS). Analyses of diffusion profiles and comparison of diffusion data reveal that the isotope effect of lithium diffusion in silicate glasses is rather small, consistent with classical diffusion behavior. Ionic conductivity of glasses was measured between 312 and 675 K. The experimentally obtained self-diffusion coefficient, D(IE), and ionic diffusion coefficient, D(σ), derived from specific DC conductivity provided information about correlation effects during Li diffusion. The D(IE)/D(σ) is higher for the trisilicate (0.27 ± 0.05) than that for the hexasilicate (0.17 ± 0.02), implying that increasing silica content reduces the efficiency of Li jumps in terms of long-range movement. This trend can be rationalized by structural concepts based on nuclear magnetic resonance (NMR) and Raman spectroscopy as well as molecular dynamic simulations, that is, lithium is percolating in low-dimensional, alkali-rich regions separated by a silica-rich matrix.

Effects of substitutional Li on the ferromagnetic response of Li co-doped ZnO:Co nanoparticles.

PubMed

Awan, Saif Ullah; Hasanain, S K; Bertino, Massimo F; Jaffari, G Hassnain

2013-04-17

Li co-doped ZnO:Co (Zn0.96-yCo0.04LiyO , y ≤ 0.1) nanoparticles were synthesized by the sol-gel technique and the correlation between the structural, electronic and magnetic properties was investigated. All the samples show a single phase hexagonal (wurtzite) ZnO structure and no secondary phases were detected. Variational trends in lattice parameters suggest the incorporation of Li in the ZnO:Co system in both substitutional and interstitial sites. Detailed electronic studies have been performed by high-resolution x-ray photoelectron spectroscopy (XPS) to determine the states of Zn, O, Co and Li. It was determined that Co substitutes at Zn sites (CoZn) while the O vacancy and Zn defects did not show much variation with increasing Li concentration. Deconvolution of the Li XPS peak showed a clear non-monotonic trend in the variation of the substitutional Li (LiZn) and interstitial Li (Lii) defects with increasing Li concentration in the particles. The magnetization study of the samples showed that the variation of the moment closely followed the trend of variation of the LiZn defects. The data are interpreted in terms of substitutional Li acting as a hole dopant and optimizing the conditions for ferromagnetism in Co-doped ZnO. Interstitial Li is not seen to be playing this role.

[Application of Bayes Probability Model in Differentiation of Yin and Yang Jaundice Syndromes in Neonates].

PubMed

Mu, Chun-sun; Zhang, Ping; Kong, Chun-yan; Li, Yang-ning

2015-09-01

To study the application of Bayes probability model in differentiating yin and yang jaundice syndromes in neonates. Totally 107 jaundice neonates who admitted to hospital within 10 days after birth were assigned to two groups according to syndrome differentiation, 68 in the yang jaundice syndrome group and 39 in the yin jaundice syndrome group. Data collected for neonates were factors related to jaundice before, during and after birth. Blood routines, liver and renal functions, and myocardial enzymes were tested on the admission day or the next day. Logistic regression model and Bayes discriminating analysis were used to screen factors important for yin and yang jaundice syndrome differentiation. Finally, Bayes probability model for yin and yang jaundice syndromes was established and assessed. Factors important for yin and yang jaundice syndrome differentiation screened by Logistic regression model and Bayes discriminating analysis included mothers' age, mother with gestational diabetes mellitus (GDM), gestational age, asphyxia, or ABO hemolytic diseases, red blood cell distribution width (RDW-SD), platelet-large cell ratio (P-LCR), serum direct bilirubin (DBIL), alkaline phosphatase (ALP), cholinesterase (CHE). Bayes discriminating analysis was performed by SPSS to obtain Bayes discriminant function coefficient. Bayes discriminant function was established according to discriminant function coefficients. Yang jaundice syndrome: y1= -21. 701 +2. 589 x mother's age + 1. 037 x GDM-17. 175 x asphyxia + 13. 876 x gestational age + 6. 303 x ABO hemolytic disease + 2.116 x RDW-SD + 0. 831 x DBIL + 0. 012 x ALP + 1. 697 x LCR + 0. 001 x CHE; Yin jaundice syndrome: y2= -33. 511 + 2.991 x mother's age + 3.960 x GDM-12. 877 x asphyxia + 11. 848 x gestational age + 1. 820 x ABO hemolytic disease +2. 231 x RDW-SD +0. 999 x DBIL +0. 023 x ALP +1. 916 x LCR +0. 002 x CHE. Bayes discriminant function was hypothesis tested and got Wilks' λ =0. 393 (P =0. 000). So Bayes

Reversible superconductor-insulator transition in LiTi2O4 induced by Li-ion electrochemical reaction

PubMed Central

Yoshimatsu, K.; Niwa, M.; Mashiko, H.; Oshima, T.; Ohtomo, A.

2015-01-01

Transition metal oxides display various electronic and magnetic phases such as high-temperature superconductivity. Controlling such exotic properties by applying an external field is one of the biggest continuous challenges in condensed matter physics. Here, we demonstrate clear superconductor-insulator transition of LiTi2O4 films induced by Li-ion electrochemical reaction. A compact electrochemical cell of pseudo-Li-ion battery structure is formed with a superconducting LiTi2O4 film as an anode. Li content in the film is controlled by applying a constant redox voltage. An insulating state is achieved by Li-ion intercalation to the superconducting film by applying reduction potential. In contrast, the superconducting state is reproduced by applying oxidation potential to the Li-ion intercalated film. Moreover, superconducting transition temperature is also recovered after a number of cycles of Li-ion electrochemical reactions. This complete reversible transition originates in difference in potentials required for deintercalation of initially contained and electrochemically intercalated Li+ ions. PMID:26541508

Reversible superconductor-insulator transition in LiTi2O4 induced by Li-ion electrochemical reaction.

PubMed

Yoshimatsu, K; Niwa, M; Mashiko, H; Oshima, T; Ohtomo, A

2015-11-06

Transition metal oxides display various electronic and magnetic phases such as high-temperature superconductivity. Controlling such exotic properties by applying an external field is one of the biggest continuous challenges in condensed matter physics. Here, we demonstrate clear superconductor-insulator transition of LiTi2O4 films induced by Li-ion electrochemical reaction. A compact electrochemical cell of pseudo-Li-ion battery structure is formed with a superconducting LiTi2O4 film as an anode. Li content in the film is controlled by applying a constant redox voltage. An insulating state is achieved by Li-ion intercalation to the superconducting film by applying reduction potential. In contrast, the superconducting state is reproduced by applying oxidation potential to the Li-ion intercalated film. Moreover, superconducting transition temperature is also recovered after a number of cycles of Li-ion electrochemical reactions. This complete reversible transition originates in difference in potentials required for deintercalation of initially contained and electrochemically intercalated Li(+) ions.

Formation and reduction behaviors of zirconium oxide compounds in LiCl-Li2O melt at 923 K

NASA Astrophysics Data System (ADS)

Sakamura, Yoshiharu; Iizuka, Masatoshi; Kitawaki, Shinichi; Nakayoshi, Akira; Kofuji, Hirohide

2015-11-01

The reduction behaviors of ZrO2, Li2ZrO3 and (U,Pu,Zr)O2 in a LiCl-Li2O salt bath at 923 K were investigated. This study was conducted as part of a feasibility study on the pyrochemical treatment of damaged fuel debris generated by severe accidents at light water reactors. It was demonstrated in electrolytic reduction tests that the uranium in synthetic corium specimens of (U,Pu,Zr)O2 with various ZrO2 contents could be reduced to the metallic form and that part of the zirconium was converted to Li2ZrO3. Zirconium metal and Li2ZrO3 were obtained by the reduction of ZrO2. The reduction of Li2ZrO3 did not proceed even in LiCl containing no Li2O. Moreover, the stable chemical forms of the ZrO2-Li2O complex oxide were investigated as a function of the Li2O concentration in LiCl. ZrO2 was converted to Li2ZrO3 at a Li2O concentration of 0.018 wt%. As the Li2O concentration was increased, Li2ZrO3 was converted to Li6Zr2O7 and then to Li8ZrO6. It is suggested that the removal of Li2ZrO3 from the reduction product is a key point in the pyrochemical treatment of corium.

Presence of Li Clusters in Molten LiCl-Li

PubMed Central

Merwin, Augustus; Phillips, William C.; Williamson, Mark A.; Willit, James L.; Motsegood, Perry N.; Chidambaram, Dev

2016-01-01

Molten mixtures of lithium chloride and metallic lithium are of significant interest in various metal oxide reduction processes. These solutions have been reported to exhibit seemingly anomalous physical characteristics that lack a comprehensive explanation. In the current work, the physical chemistry of molten solutions of lithium chloride and metallic lithium, with and without lithium oxide, was investigated using in situ Raman spectroscopy. The Raman spectra obtained from these solutions were in agreement with the previously reported spectrum of the lithium cluster, Li8. This observation is indicative of a nanofluid type colloidal suspension of Li8 in a molten salt matrix. It is suggested that the formation and suspension of lithium clusters in lithium chloride is the cause of various phenomena exhibited by these solutions that were previously unexplainable. PMID:27145895

Presence of Li clusters in molten LiCl-Li

DOE PAGES

Merwin, Augustus; Phillips, William C.; Williamson, Mark A.; ...

2016-05-05

Molten mixtures of lithium chloride and metallic lithium are of significant interest in various metal oxide reduction processes. These solutions have been reported to exhibit seemingly anomalous physical characteristics that lack a comprehensive explanation. ln the current work, the physical chemistry of molten solutions of lithium chloride and metallic lithium, with and without lithium oxide, was investigated using in situ Raman spectroscopy. The Raman spectra obtained from these solutions were in agreement with the previously reported spectrum of the lithium cluster, Li 8. Furthermore, this observation is indicative of a nanofluid type colloidal suspension of Li 8, in a moltenmore » salt matrix. It is suggested that the formation and suspension of lithium clusters in lithium chloride is the cause of various phenomena exhibited by these solutions that were previously unexplainable.« less

Occurrence of chai hu (Bupleuri radix) in prescriptions of Chinese herbal medicine in Switzerland.

PubMed

Klein, Sabine D; Becker, Simon; Wolf, Ursula

2012-01-01

Chai hu (Bupleuri radix), one of the most frequently used herbs in Chinese herbal medicine, has 3 major functions, depending on dosage and combination with other herbs. The aim of this study was to investigate how chai hu is prescribed in everyday practice in Switzerland, and whether these prescription patterns reflect its various applications. A random sample of 1,053 prescriptions was drawn from the database of Lian Chinaherb AG, Wollerau, Switzerland, and analyzed regarding the most frequently used classical formulas containing chai hu, daily dosages and combinations with other herbs. 29.0% of all prescriptions contained chai hu, and 98.0% of these were in granular form. The most frequently used classical formulas were xiao yao san ('rambling powder'), jia wei xiao yao san ('augmented rambling powder') and chai hu shu gan san ('Bupleurum powder to spread the liver'). In more than half of the prescriptions, chai hu was combined with bai shao (Paeoniae Radix Alba), dang gui (Angelicae sinensis radix) or fu ling (Poria). 51.8% of the prescriptions contained a low daily dosage of chai hu, 24.9% a medium and 15.1% a high dosage. Chai hu was generally prescribed in classic combinations with other herbs and in a medium dosage. Due to the addition of supplementary herbs to classical formulas, its daily dose was often diminished from a high or medium dose to a low dose. This raises the question if chai hu would then still exert its desired function of, e.g., moving liver-qi in these prescriptions.

Asymptotic and near-target direct breakup of 6Li and 7Li

NASA Astrophysics Data System (ADS)

Kalkal, Sunil; Simpson, E. C.; Luong, D. H.; Cook, K. J.; Dasgupta, M.; Hinde, D. J.; Carter, I. P.; Jeung, D. Y.; Mohanto, G.; Palshetkar, C. S.; Prasad, E.; Rafferty, D. C.; Simenel, C.; Vo-Phuoc, K.; Williams, E.; Gasques, L. R.; Gomes, P. R. S.; Linares, R.

2016-04-01

Background: Li,76 and 9Be are weakly bound against breakup into their cluster constituents. Breakup location is important for determining the role of breakup in above-barrier complete fusion suppression. Recent works have pointed out that experimental observables can be used to separate near-target and asymptotic breakup. Purpose: Our purpose is to distinguish near-target and asymptotic direct breakup of Li,76 in reactions with nuclei in different mass regions. Method: Charged particle coincidence measurements are carried out with pulsed Li,76 beams on 58Ni and 64Zn targets at sub-barrier energies and compared with previous measurements using 208Pb and 209Bi targets. A detector array providing a large angular coverage is used, along with time-of-flight information to give definitive particle identification of the direct breakup fragments. Results: In interactions of 6Li with 58Ni and 64Zn, direct breakup occurs only asymptotically far away from the target. However, in interactions with 208Pb and 209Bi, near-target breakup occurs in addition to asymptotic breakup. Direct breakup of 7Li into α -t is not observed in interactions with 58Ni and 64Zn. However, near-target dominated direct breakup was observed in measurements with 208Pb and 209Bi. A modified version of the Monte Carlo classical trajectory model code platypus, which explicitly takes into account lifetimes associated with unbound states, is used to simulate sub-barrier breakup reactions. Conclusions: Near-target breakup in interactions with Li,76 is an important mechanism only for the heavy targets 208Pb and 209Bi. There is insignificant near-target direct breakup of 6Li and no direct breakup of 7Li in reactions with 58Ni and 64Zn. Therefore, direct breakup is unlikely to suppress the above-barrier fusion cross section in reactions of Li,76 with 58Ni and 64Zn nuclei.

Relaxation-Induced Memory Effect of LiFePO4 Electrodes in Li-Ion Batteries.

PubMed

Jia, Jianfeng; Tan, Chuhao; Liu, Mengchuang; Li, De; Chen, Yong

2017-07-26

In Li-ion batteries, memory effect has been found in several commercial two-phase materials as a voltage bump and a step in the (dis)charging plateau, which delays the two-phase transition and influences the estimation of the state of charge. Although memory effect has been first discovered in olivine LiFePO 4 , the origination and dependence are still not clear and are critical for regulating the memory effect of LiFePO 4 . Herein, LiFePO 4 has been synthesized by a home-built spray drying instrument, of which the memory effect has been investigated in Li-ion batteries. For as-synthesized LiFePO 4 , the memory effect is significantly dependent on the relaxation time after phase transition. Besides, the voltage bump of memory effect is actually a delayed voltage overshooting that is overlaid at the edge of stepped (dis)charging plateau. Furthermore, we studied the kinetics of LiFePO 4 electrode with electrochemical impedance spectroscopy (EIS), which shows that the memory effect is related to the electrochemical kinetics. Thereby, the underlying mechanism has been revealed in memory effect, which would guide us to optimize two-phase electrode materials and improve Li-ion battery management systems.

Perturbation Theory of Massive Yang-Mills Fields

DOE R&D Accomplishments Database

Veltman, M.

1968-08-01

Perturbation theory of massive Yang-Mills fields is investigated with the help of the Bell-Treiman transformation. Diagrams containing one closed loop are shown to be convergent if there are more than four external vector boson lines. The investigation presented does not exclude the possibility that the theory is renormalizable.

Yang-Monti Principle in Bridging Long Ureteral Defects: Cases Report and A Systemic Review.

PubMed

Bao, Jun Sheng; He, Qiqi; Li, Yuzhuo; Shi, Wei; Wu, Gongjin; Yue, Zhongjin

2017-07-02

Ureteric substitution using the Yang-Monti principle was reported as a modification of simple ileal ureter replacement. During April 2013 to June in 2015, 2 patients underwent ileal ureteral substitution using a reconfigured ileal segment of Yang Monti principle in our clinical center. Some slight modifications were made and then follow-up were carried out up to 12 months. For these 2 cases, no significant intra/post-operative complications occurred. In 1 year follow up, serum creatinine (Scr) and blood urea nitrogen (BUN) of both patients decreased to normal.Glomerular filtration rate (GFR), renogram and pyelogram showed a stable split renal function. To better understand the Yang-Monti principle and potential risks and complications, we conduct an systemic review by searching PubMed, Google Scholar and the Cochrane Library database from January 1996 through June 2016. 10 out of 644 publications were identified, which included 269 patients from cohort studies. The most usual indications for Yang-monti therapy were iatrogenic stricture and retroperitoneal fibrosis. Infection and ileus were indicated as themain short time postoperative complications while the fistula and re- strictures happened in long-term. In general,we believe Yang-Monti Principle is a safer and efficient technique for clinical partial and complete ureteral defects if patients and potential risks could be well prepared.

A highly efficient Li2O2 oxidation system in Li-O2 batteries.

PubMed

Hase, Yoko; Seki, Juntaro; Shiga, Tohru; Mizuno, Fuminori; Nishikoori, Hidetaka; Iba, Hideki; Takechi, Kensuke

2016-10-06

A novel indirect charging system that uses a redox mediator was demonstrated for Li-O 2 batteries. 4-Methoxy-2,2,6,6-tetramethylpiperidinyl-1-oxyl (MeO-TEMPO) was applied as a mediator to enable the oxidation of Li 2 O 2 , even though Li 2 O 2 is electrochemically isolated. This system promotes the oxidation of Li 2 O 2 without parasitic reactions attributed to electrochemical charging and reduces the charging time.

Molecular evolution of the Li/li chemical defence polymorphism in white clover (Trifolium repens L.).

PubMed

Olsen, K M; Sutherland, B L; Small, L L

2007-10-01

White clover (Trifolium repens) is naturally polymorphic for cyanogenesis (hydrogen cyanide release following tissue damage). The ecological factors favouring cyanogenic and acyanogenic plants have been examined in numerous studies over the last half century, making this one of the best-documented examples of an adaptive polymorphism in plants. White clover cyanogenesis is controlled by two, independently segregating Mendelian genes: Ac/ac controls the presence/absence of cyanogenic glucosides; and Li/li controls the presence/absence of their hydrolysing enzyme, linamarase. In this study, we examine the molecular evolution and population genetics of Li as it relates to the cyanogenesis polymorphism. We report here that Li exists as a single-copy gene in plants possessing linamarase activity, and that the absence of enzyme activity in li/li plants is correlated with the absence of much or all of the gene from the white clover genome. Consistent with this finding, we confirm by reverse transcription-polymerase chain reaction that Li gene expression is absent in plants lacking enzyme activity. In a molecular population genetic analysis of Li and three unlinked genes using a worldwide sample of clover plants, we find an absence of nucleotide variation and statistically significant deviations from neutrality at Li; these findings are consistent with recent positive directional selection at this cyanogenesis locus.

Al-Cu-Li and Al-Mg-Li alloys: Phase composition, texture, and anisotropy of mechanical properties (Review)

NASA Astrophysics Data System (ADS)

Betsofen, S. Ya.; Antipov, V. V.; Knyazev, M. I.

2016-04-01

The results of studying the phase transformations, the texture formation, and the anisotropy of the mechanical properties in Al-Cu-Li and Al-Mg-Li alloys are generalized. A technique and equations are developed to calculate the amounts of the S1 (Al2MgLi), T1 (Al2CuLi), and δ' (Al3Li) phases. The fraction of the δ' phase in Al-Cu-Li alloys is shown to be significantly higher than in Al-Mg-Li alloys. Therefore, the role of the T1 phase in the hardening of Al-Cu-Li alloys is thought to be overestimated, especially in alloys with more than 1.5% Li. A new model is proposed to describe the hardening of Al-Cu-Li alloys upon aging, and the results obtained with this model agree well with the experimental data. A texture, which is analogous to that in aluminum alloys, is shown to form in sheets semiproducts made of Al-Cu-Li and Al-Mg-Li alloys. The more pronounced anisotropy of the properties of lithium-containing aluminum alloys is caused by a significant fraction of the ordered coherent δ' phase, the deformation mechanism in which differs radically from that in the solid solution.

Preparation of Ce- and La-Doped Li4Ti5O12 Nanosheets and Their Electrochemical Performance in Li Half Cell and Li4Ti5O12/LiFePO4 Full Cell Batteries

PubMed Central

Qin, Meng; Li, Yueming; Lv, Xiao-Jun

2017-01-01

This work reports on the synthesis of rare earth-doped Li4Ti5O12 nanosheets with high electrochemical performance as anode material both in Li half and Li4Ti5O12/LiFePO4 full cell batteries. Through the combination of decreasing the particle size and doping by rare earth atoms (Ce and La), Ce and La doped Li4Ti5O12 nanosheets show the excellent electrochemical performance in terms of high specific capacity, good cycling stability and excellent rate performance in half cells. Notably, the Ce-doped Li4Ti5O12 shows good electrochemical performance as anode in a full cell which LiFePO4 was used as cathode. The superior electrochemical performance can be attributed to doping as well as the nanosized particle, which facilitates transportation of the lithium ion and electron transportation. This research shows that the rare earth doped Li4Ti5O12 nanosheets can be suitable as a high rate performance anode material in lithium-ion batteries. PMID:28632167

2.6-2.7 Ga continental crust growth in Yangtze craton, South China

NASA Astrophysics Data System (ADS)

Chen, K.; Gao, S.; Wu, Y.

2013-12-01

A combined study of zircon U-Pb and Lu-Hf isotopes and whole rock major and trace elements and Sr-Nd isotopes has been conducted for 10 granitic and tonalitic-trondhjemitic-granodioritic (TTG) gneisses from the Kongling terrain, the only known Archean microcontinent in the Yangtze craton, South China. The results reveal a significant magmatic event at ~2.6-2.7 Ga (Fig. 1), in addition to the previously reported ~2.9 Ga and ~3.2-3.3 Ga magmatism (Zhang et al., 2006; Jiao et al., 2009; Gao et al., 2011). The ~2.6-2.7 Ga rocks show relatively high REE (530-1074 ppm), apparently negative Eu anomaly (Eu/Eu* = 0.22-0.35), low #Mg (19.51-22.63) and low LaN/YbN (10.3-24.2). Besides, they have high K-feldspar proportion and relatively evaluated (K2O+Na2O)/CaO, TFeO/MgO, Zr, Nb, Ce and Y contents. Their 10000 × Ga/Al ratios range between 3.00 and 3.54. All these features suggest that the protoliths of these gneisses are A-type granites. Most of the ~2.6-2.7 Ga zircon grains have ɛHf(t) values >0 (up to 7.93, close to the depleted mantle value). This clearly indicates a considerably higher proportion of new crustal components in the ~2.6-2.7 Ga granitoids compared to the ~3.2-3.3 Ga and ~2.9 Ga TTGs. Our results support the conclusion of worldwide studies of igneous and detrital zircons that age peaks at 2.65-2.76 Ga represent increases in the volume of juvenile continental crust. The present study also confirms the existence of the two older magmatic events in the Kongling terrain. Both whole rock ɛNd(t) values (-3.74 to 1.59) and the zircon ɛHf(t) values (-11.18 to 3.55) for the ~2.9 Ga TTG and the Hf isotopes of ~3.2-3.3 Ga igneous zircons (-7.37 to 3.12) are chondritic or subchondritic, suggesting that they were mainly generated by reworking of older rocks with a small amount of new crustal additions. References Gao, S., Yang, J., Zhou, L., Li, M., Hu, Z.C., Guo, J.L., Yuan, H.L., Gong, H.J., Xiao, G.Q., Wei, J.Q., 2011. Age and growth of the Archean Kongling terrain

Rate-dependent, Li-ion insertion/deinsertion behavior of LiFePO4 cathodes in commercial 18650 LiFePO4 cells.

PubMed

Liu, Qi; He, Hao; Li, Zhe-Fei; Liu, Yadong; Ren, Yang; Lu, Wenquan; Lu, Jun; Stach, Eric A; Xie, Jian

2014-03-12

We have performed operando synchrotron high-energy X-ray diffraction (XRD) to obtain nonintrusive, real-time monitoring of the dynamic chemical and structural changes in commercial 18650 LiFePO4/C cells under realistic cycling conditions. The results indicate a nonequilibrium lithium insertion and extraction in the LiFePO4 cathode, with neither the LiFePO4 phase nor the FePO4 phase maintaining a static composition during lithium insertion/extraction. On the basis of our observations, we propose that the LiFePO4 cathode simultaneously experiences both a two-phase reaction mechanism and a dual-phase solid-solution reaction mechanism over the entire range of the flat voltage plateau, with this dual-phase solid-solution behavior being strongly dependent on charge/discharge rates. The proposed dual-phase solid-solution mechanism may explain the remarkable rate capability of LiFePO4 in commercial cells.

Expression Profiling of Transcriptome and Its Associated Disease Risk in Yang Deficiency Constitution of Healthy Subjects

PubMed Central

Yu, Ruoxi; Yang, Yin; Han, Yuanyuan; Hou, Pengwei; Li, Yingshuai; Li, Siqi

2016-01-01

Objectives. Differences among healthy subjects and associated disease risks are of substantial interest in clinical medicine. According to the theory of “constitution-disease correlation” in traditional Chinese medicine, we try to find out if there is any connection between intolerance of cold in Yang deficiency constitution and molecular evidence and if there is any gene expression basis in specific disorders. Methods. Peripheral blood mononuclear cells were collected from Chinese Han individuals with Yang deficiency constitution (n = 20) and balanced constitution (n = 8) (aged 18–28) and global gene expression profiles were determined between them using the Affymetrix HG-U133 Plus 2.0 array. Results. The results showed that when the fold change was ≥1.2 and q ≤ 0.05, 909 genes were upregulated in the Yang deficiency constitution, while 1189 genes were downregulated. According to our research differential genes found in Yang deficiency constitution were usually related to lower immunity, metabolic disorders, and cancer tendency. Conclusion. Gene expression disturbance exists in Yang deficiency constitution, which corresponds to the concept of constitution and gene classification. It also suggests people with Yang deficiency constitution are susceptible to autoimmune diseases, enteritis, arthritis, metabolism disorders, and cancer, which provides molecular evidence for the theory of “constitution-disease correlation.” PMID:28484499

Direct synthesis and characterization of mixed-valent Li 0.5$-$δCoPO 4, a Li-deficient derivative of the Cmcm polymorph of LiCoPO 4

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ludwig, Jennifer; Alarcon-Suesca, Carlos; Geprags, Stephan

While the majority of research activities on LiCoPO 4 is focussed on the thermodynamically stable olivine-type Pnma polymorph, the metastable Pna2 1 and Cmcm modifications have recently attracted considerable attention due to their interesting material properties. In this study, we present the first Li-deficient structural derivative of the Cmcm modification with the nominal composition Li 0.5–δCoPO 4. As opposed to the substoichiometric olivine ( Pnma) phases Li xCoPO 4 (x = 0; 2/3), which are exclusively accessible by electrochemical or chemical Li extraction techniques, this is also the first time that a direct soft-chemical synthesis route towards a Li xCoPOmore » 4-type material is accomplished. X-ray and neutron diffraction studies indicate that Cmcm-type Li 0.5–δCoPO 4 shows vacancies on both the Li and Co sites, whereas X-ray absorption spectra demonstrate that the structure features heterovalent Co ions (+2/+3) to compensate for the Li deficit. Magnetic measurements reveal a long-range antiferromagnetic order below 10.5 K. A thorough investigation of the thermal stability using thermogravimetric analysis, differential scanning calorimetry, and temperature-dependent in situ X-ray powder diffraction demonstrates that Li 0.5–δCoPO 4 is metastable and exhibits a complex, multi-step thermal decomposition mechanism. In the first step at 394 °C, it decomposes to α-Co 2P 2O 7 ( P2 1/c) and LiCoPO 4 ( Cmcm) upon O 2 release. The LiCoPO 4 ( Cmcm) intermediate is then irreversibly transformed to olivine-type LiCoPO 4 (Pnma) at 686 °C. Furthermore, the material properties of Li 0.5–δCoPO 4 are further compared to the fully lithiated, isostructural LiCoPO 4 ( Cmcm) phase, for which an improved structure solution as well as Co L 2,3-edge X-ray absorption spectra are reported for the first time.« less

Structural characterisation of the Li argyrodites Li7PS6 and Li7PSe6 and their solid solutions: quantification of site preferences by MAS-NMR spectroscopy.

PubMed

Kong, Shiao Tong; Gün, Ozgül; Koch, Barbara; Deiseroth, Hans Jörg; Eckert, Hellmut; Reiner, Christof

2010-05-03

Li(7)PS(6) and Li(7)PSe(6) belong to a class of new solids that exhibit high Li(+) mobility. A series of quaternary solid solutions Li(7)PS(6-x)Se(x) (0 < or = x < or = 6) were characterised by X-ray crystallography and magic-angle spinning nuclear magnetic resonance (MAS-NMR) spectroscopy. The high-temperature (HT) modifications were studied by single-crystal investigations (both F43m, Z=4, Li(7)PS(6): a=9.993(1) A, Li(7)PSe(6): a=10.475(1) A) and show the typical argyrodite structures with strongly disordered Li atoms. HT-Li(7)PS(6) and HT-Li(7)PSe(6) transform reversibly into low-temperature (LT) modifications with ordered Li atoms. X-ray powder diagrams show the structures of LT-Li(7)PS(6) and LT-Li(7)PSe(6) to be closely related to orthorhombic LT-alpha-Cu(7)PSe(6). Single crystals of the LT modifications are not available due to multiple twinning and formation of antiphase domains. The gradual substitution of S by Se shows characteristic site preferences closely connected to the functionalities of the different types of chalcogen atoms (S, Se). High-resolution solid-state (31)P NMR is a powerful method to differentiate quantitatively between the distinct (PS(4-n)Se(n))(3-) local environments. Their population distribution differs significantly from a statistical scenario, revealing a pronounced preference for P-S over P-Se bonding. This preference, shown for the series of LT samples, can be quantified in terms of an equilibrium constant specifying the melt reaction Se(P)+S(2-) <==>S(P)+Se(2-), prior to crystallisation. The (77)Se MAS-NMR spectra reveal that the chalcogen distributions in the second and third coordination sphere of the P atoms are essentially statistical. The number of crystallographically independent Li atoms in both LT modifications was analysed by means of (6)Li{(7)Li} cross polarisation magic angle spinning (CPMAS).

Direct synthesis and characterization of mixed-valent Li 0.5$-$δCoPO 4, a Li-deficient derivative of the Cmcm polymorph of LiCoPO 4

DOE PAGES

Ludwig, Jennifer; Alarcon-Suesca, Carlos; Geprags, Stephan; ...

2017-05-26

While the majority of research activities on LiCoPO 4 is focussed on the thermodynamically stable olivine-type Pnma polymorph, the metastable Pna2 1 and Cmcm modifications have recently attracted considerable attention due to their interesting material properties. In this study, we present the first Li-deficient structural derivative of the Cmcm modification with the nominal composition Li 0.5–δCoPO 4. As opposed to the substoichiometric olivine ( Pnma) phases Li xCoPO 4 (x = 0; 2/3), which are exclusively accessible by electrochemical or chemical Li extraction techniques, this is also the first time that a direct soft-chemical synthesis route towards a Li xCoPOmore » 4-type material is accomplished. X-ray and neutron diffraction studies indicate that Cmcm-type Li 0.5–δCoPO 4 shows vacancies on both the Li and Co sites, whereas X-ray absorption spectra demonstrate that the structure features heterovalent Co ions (+2/+3) to compensate for the Li deficit. Magnetic measurements reveal a long-range antiferromagnetic order below 10.5 K. A thorough investigation of the thermal stability using thermogravimetric analysis, differential scanning calorimetry, and temperature-dependent in situ X-ray powder diffraction demonstrates that Li 0.5–δCoPO 4 is metastable and exhibits a complex, multi-step thermal decomposition mechanism. In the first step at 394 °C, it decomposes to α-Co 2P 2O 7 ( P2 1/c) and LiCoPO 4 ( Cmcm) upon O 2 release. The LiCoPO 4 ( Cmcm) intermediate is then irreversibly transformed to olivine-type LiCoPO 4 (Pnma) at 686 °C. Furthermore, the material properties of Li 0.5–δCoPO 4 are further compared to the fully lithiated, isostructural LiCoPO 4 ( Cmcm) phase, for which an improved structure solution as well as Co L 2,3-edge X-ray absorption spectra are reported for the first time.« less

The properties of and analytical methods for detection of LiOH and Li2CO3

NASA Technical Reports Server (NTRS)

Selvaduray, Guna

1991-01-01

Lithium hydroxide (LiOH) is used as a CO2 absorbent in the Shuttle Extravehicular Mobility Unit (EMU) Portable Life Support System (PLSS). The first objective was to survey parameters that may be used to indicate conversion of LiOH to Li2CO3, and compile a list of all possible properties, including physical, chemical, structural, and electrical, that may serve to indicate the occurrence of reaction. These properties were compiled for the reactant (LiOH), the intermediate monohydrate compound (LiOH.H2O), and the final product (Li2CO3). The second objective was to survey measurement and analytical techniques which may be used in conjunction with each of the properties identified above, to determine the extent of conversion of LiOH to Li2CO3. Both real-time and post-run techniques were of interest. The techniques were also evaluated in terms of complexity, technology readiness, materials/equipment availability, and cost, where possible.

Thermodynamics of Pb17Li-bismuth interactions

NASA Astrophysics Data System (ADS)

Hubberstey, Peter; Sample, Tony

1994-09-01

Thermodynamic calculations of the PbBiLi ternary system have been completed to rationalise the formation of solid Li 3Bi on reaction of liquid Pb17Li with bismuth. At 723 K, the bismuth activity in equilibrium with liquid Pi17Li and solid Li 3Bi is calculated to be 9.50 × 10 -4; this can be correlated to a solubility of 2.09 × 10 -1 mol% Bi(2520 wppm). The corresponding bismuth activity in equilibrium with liquid Pb17Li and solid LiBi is 5.04 × 10 -2 (an extrapolated value as LiBi decomposes peritectically at 688 K). The minimum lithium content of PbLi alloys required to react with unit activity bismuth to form Li 3Bi at 723 K is calculated to be ˜ 1.8 mol% Li. The dominance of Li 3Bi in the PbBiLi system is attributed to its extreme stability as evidenced by both its high melting point (1418 K) and free energy of formation [ ΔGf0(Li 3Bi, c 723 K) = 212.8 kJ mol -1].

Three dimensional N=4 supersymmetric mechanics with Wu-Yang monopole

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bellucci, Stefano; Krivonos, Sergey; Sutulin, Anton

2010-05-15

We propose Lagrangian and Hamiltonian formulations of a N=4 supersymmetric three-dimensional isospin-carrying particle moving in the non-Abelian field of a Wu-Yang monopole and in some specific scalar potential. This additional potential is completely fixed by N=4 supersymmetry, and in the simplest case of flat metrics it coincides with that which provides the existence of the Runge-Lenz vector for the bosonic subsector. The isospin degrees of freedom are described on the Lagrangian level by bosonic auxiliary variables forming N=4 supermultiplet with additional, also auxiliary, fermions. Being quite general, the constructed systems include such interesting cases as N=4 superconformally invariant systems withmore » Wu-Yang monopole, the particles living in the flat R{sup 3} and in the RxS{sup 2} spaces and interacting with the monopole, and also the particles moving on three-dimensional sphere and pseudosphere with the Wu-Yang monopole sitting in the center. The superfield Lagrangian description of these systems is so simple that one could wonder to see how all couplings and the proper coefficients arise while passing to the component action.« less

A Li-Garnet composite ceramic electrolyte and its solid-state Li-S battery

NASA Astrophysics Data System (ADS)

Huang, Xiao; Liu, Cai; Lu, Yang; Xiu, Tongping; Jin, Jun; Badding, Michael E.; Wen, Zhaoyin

2018-04-01

A high strength Li-Garnet solid electrolyte composite ceramic is successfully prepared via conventional solid state method with Li6.4La3Zr1.4Ta0.6O12 and nano MgO powders. Well sintered ceramic pellets and bars are obtained with 0-9 wt.% MgO. Fracture strength is approximately 135 MPa for composite ceramics with 5-9 wt.% MgO, which is ∼50% higher than that of pure Li6.4La3Zr1.4Ta0.6O12 (90 MPa). Lithium-ion conductivity of the composite is above 5 × 10-4 S cm-1 at room temperature; comparable to the pure Li6.4La3Zr1.4Ta0.6O12 material. SEM cross-sections of the composite ceramic shows a much more uniform microstructure comparing with pure ones, owing to the grain growth inhibition effect of the MgO second phase. A battery cell consisting of Li/composite ceramics/Sulfur-Carbon at 25 °C exhibits a capacity of 685 mAh g-1 at 0.2 C at the 200th cycle, while maintaining a coulombic efficiency of 100%. These results indicate that the composite ceramic Li6.4La3Zr1.4Ta0.6O12-MgO is promising for the production of electrolyte membrane and fabrication of Li-Sulfur batteries.

Tailoring Anisotropic Li-Ion Transport Tunnels on Orthogonally Arranged Li-Rich Layered Oxide Nanoplates Toward High-Performance Li-Ion Batteries.

PubMed

Xu, Ming; Fei, Linfeng; Zhang, Weibing; Li, Tao; Lu, Wei; Zhang, Nian; Lai, Yanqing; Zhang, Zhian; Fang, Jing; Zhang, Kai; Li, Jie; Huang, Haitao

2017-03-08

High-performance Li-rich layered oxide (LRLO) cathode material is appealing for next-generation Li-ion batteries owing to its high specific capacity (>300 mAh g -1 ). Despite intense studies in the past decade, the low initial Coulombic efficiency and unsatisfactory cycling stability of LRLO still remain as great challenges for its practical applications. Here, we report a rational design of the orthogonally arranged {010}-oriented LRLO nanoplates with built-in anisotropic Li + ion transport tunnels. Such a novel structure enables fast Li + ion intercalation and deintercalation kinetics and enhances structural stability of LRLO. Theoretical calculations and experimental characterizations demonstrate the successful synthesis of target cathode material that delivers an initial discharge capacity as high as 303 mAh g -1 with an initial Coulombic efficiency of 93%. After 200 cycles at 1.0 C rate, an excellent capacity retention of 92% can be attained. Our method reported here opens a door to the development of high-performance Ni-Co-Mn-based cathode materials for high-energy density Li-ion batteries.

Single step transformation of sulphur to Li2S2/Li2S in Li-S batteries

PubMed Central

Helen, M.; Reddy, M. Anji; Diemant, Thomas; Golla-Schindler, Ute; Behm, R. Jürgen; Kaiser, Ute; Fichtner, Maximilian

2015-01-01

Lithium-sulphur batteries have generated tremendous research interest due to their high theoretical energy density and potential cost-effectiveness. The commercial realization of Li-S batteries is still hampered by reduced cycle life associated with the formation of electrolyte soluble higher-order polysulphide (Li2Sx, x = 4–8) intermediates, leading to capacity fading, self-discharge, and a multistep voltage profile. Herein, we have realized a practical approach towards a direct transformation of sulphur to Li2S2/Li2S in lithium-sulphur batteries by alteration of the reaction pathway. A coconut shell derived ultramicroporous carbon-sulphur composite cathode has been used as reaction directing template for the sulphur. The lithiation/delithiation and capacity fading mechanism of microporous carbon confined sulphur composite was revealed by analyzing the subsurface using X-ray photoelectron spectroscopy. No higher-order polysulphides were detected in the electrolyte, on the surface, and in the subsurface of the cathode composite. The altered reaction pathway is reflected by a single-step profile in the discharge/charge of a lithium-sulphur cell. PMID:26173723

Tuning Li-Ion Diffusion in α-LiMn 1–x Fe x PO 4 Nanocrystals by Antisite Defects and Embedded β-Phase for Advanced Li-Ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Jiangtao; Xiao, Yinguo; Tang, Hanting

Olivine-structured LiMn1-xFexPO4 has become a promising candidate for cathode materials owing to its higher working voltage of 4.1 V and thus larger energy density than that of LiFePO4, which has been used for electric vehicles batteries with the advantage of high safety but disadvantage of low energy density due to its lower working voltage of 3.4 V. One drawback of LiMn1-xFexPO4 electrode is its relatively low electronic and Li-ionic conductivity with Li-ion one-dimensional diffusion. Herein, olivine-structured α-LiMn0.5Fe0.5PO4 nanocrystals were synthesized with optimized Li-ion diffusion channels in LiMn1-xFexPO4 nanocrystals by inducing high concentrations of Fe2+-Li+ antisite defects, which showed impressive capacitymore » improvements of approaching 162, 127, 73, and 55 mAh g-1 at 0.1, 10, 50, and 100 C, respectively, and a long-term cycling stability of maintaining about 74% capacity after 1000 cycles at 10 C. By using high-resolution transmission electron microscopy imaging and joint refinement of hard X-ray and neutron powder diffraction patterns, we revealed that the extraordinary high-rate performance could be achieved by suppressing the formation of electrochemically inactive phase (β-LiMn1-xFexPO4, which is first reported in this work) embedded in α-LiMn0.5Fe0.5PO4. Because of the coherent orientation relationship between β- and α- phases, the β-phase embedded would impede the Li+ diffusion along the [100] and/or [001] directions that was activated by the high density of Fe2+-Li+ antisite (4.24%) in α-phase. Thus, by optimizing concentrations of Fe2+-Li+ antisite defects and suppressing β-phase-embedded olivine structure, Li-ion diffusion properties in LiMn1-xFexPO4 nanocrystals can be tuned by generating new Li+ tunneling. These findings may provide insights into the design and generation of other advanced electrode materials with improved rate performance.« less

Tuning Li-Ion Diffusion in α-LiMn 1–xFe xPO 4 Nanocrystals by Antisite Defects and Embedded β-Phase for Advanced Li-Ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Jiangtao; Xiao, Yinguo; Tang, Hanting

Olivine-structured LiMn 1–xFe xPO 4 has become a promising candidate for cathode materials owing to its higher working voltage of 4.1 V and thus larger energy density than that of LiFePO 4, which has been used for electric vehicles batteries with the advantage of high safety but disadvantage of low energy density due to its lower working voltage of 3.4 V. One drawback of LiMn 1–xFe xPO 4 electrode is its relatively low electronic and Li-ionic conductivity with Li-ion one-dimensional diffusion. In this paper, olivine-structured α-LiMn 0.5Fe 0.5PO 4 nanocrystals were synthesized with optimized Li-ion diffusion channels in LiMn 1–xFemore » xPO 4 nanocrystals by inducing high concentrations of Fe 2+–Li + antisite defects, which showed impressive capacity improvements of approaching 162, 127, 73, and 55 mAh g –1 at 0.1, 10, 50, and 100 C, respectively, and a long-term cycling stability of maintaining about 74% capacity after 1000 cycles at 10 C. By using high-resolution transmission electron microscopy imaging and joint refinement of hard X-ray and neutron powder diffraction patterns, we revealed that the extraordinary high-rate performance could be achieved by suppressing the formation of electrochemically inactive phase (β-LiMn 1–xFe xPO 4, which is first reported in this work) embedded in α-LiMn 0.5Fe 0.5PO 4. Because of the coherent orientation relationship between β- and α-phases, the β-phase embedded would impede the Li + diffusion along the [100] and/or [001] directions that was activated by the high density of Fe 2+–Li + antisite (4.24%) in α-phase. Thus, by optimizing concentrations of Fe 2+–Li + antisite defects and suppressing β-phase-embedded olivine structure, Li-ion diffusion properties in LiMn 1–xFe xPO 4 nanocrystals can be tuned by generating new Li + tunneling. Finally, these findings may provide insights into the design and generation of other advanced electrode materials with improved rate performance.« less

Tuning Li-Ion Diffusion in α-LiMn 1–xFe xPO 4 Nanocrystals by Antisite Defects and Embedded β-Phase for Advanced Li-Ion Batteries

DOE PAGES

Hu, Jiangtao; Xiao, Yinguo; Tang, Hanting; ...

2017-07-13

Olivine-structured LiMn 1–xFe xPO 4 has become a promising candidate for cathode materials owing to its higher working voltage of 4.1 V and thus larger energy density than that of LiFePO 4, which has been used for electric vehicles batteries with the advantage of high safety but disadvantage of low energy density due to its lower working voltage of 3.4 V. One drawback of LiMn 1–xFe xPO 4 electrode is its relatively low electronic and Li-ionic conductivity with Li-ion one-dimensional diffusion. In this paper, olivine-structured α-LiMn 0.5Fe 0.5PO 4 nanocrystals were synthesized with optimized Li-ion diffusion channels in LiMn 1–xFemore » xPO 4 nanocrystals by inducing high concentrations of Fe 2+–Li + antisite defects, which showed impressive capacity improvements of approaching 162, 127, 73, and 55 mAh g –1 at 0.1, 10, 50, and 100 C, respectively, and a long-term cycling stability of maintaining about 74% capacity after 1000 cycles at 10 C. By using high-resolution transmission electron microscopy imaging and joint refinement of hard X-ray and neutron powder diffraction patterns, we revealed that the extraordinary high-rate performance could be achieved by suppressing the formation of electrochemically inactive phase (β-LiMn 1–xFe xPO 4, which is first reported in this work) embedded in α-LiMn 0.5Fe 0.5PO 4. Because of the coherent orientation relationship between β- and α-phases, the β-phase embedded would impede the Li + diffusion along the [100] and/or [001] directions that was activated by the high density of Fe 2+–Li + antisite (4.24%) in α-phase. Thus, by optimizing concentrations of Fe 2+–Li + antisite defects and suppressing β-phase-embedded olivine structure, Li-ion diffusion properties in LiMn 1–xFe xPO 4 nanocrystals can be tuned by generating new Li + tunneling. Finally, these findings may provide insights into the design and generation of other advanced electrode materials with improved rate performance.« less

Next generation of CO2 enhanced water recovery with subsurface energy storage in China

NASA Astrophysics Data System (ADS)

Li, Qi; Kühn, Michael; Ma, Jianli; Niu, Zhiyong

2017-04-01

Carbon dioxide (CO2) utilization and storage (CCUS) is very popular in comparison with traditional CO2 capture and storage (CCS) in China. In particular, CO2 storage in deep saline aquifers with enhanced water recovery (CO2-EWR) [1] is gaining more and more attention as a cleaner production technology. The CO2-EWR was written into the "U.S.-China Joint Announcement on Climate Change" released November 11, 2014. "Both sides will work to manage climate change by demonstrating a new frontier for CO2 use through a carbon capture, use, and sequestration (CCUS) project that will capture and store CO2 while producing fresh water, thus demonstrating power generation as a net producer of water instead of a water consumer. This CCUS project with enhanced water recovery will eventually inject about 1.0 million tonnes of CO2 and create approximately 1.4 million cubic meters of freshwater per year." In this article, at first we reviewed the history of the CO2-EWR and addressed its current status in China. Then, we put forth a new generation of the CO2-EWR with emphasizing the collaborative solutions between carbon emission reductions and subsurface energy storage or renewable energy cycle [2]. Furthermore, we figured out the key challenging problems such as water-CCUS nexus when integrating the CO2-EWR with the coal chemical industry in the Junggar Basin, Xinjiang, China [3-5]. Finally, we addressed some crucial problems and strategic consideration of the CO2-EWR in China with focuses on its technical bottleneck, relative advantage, early opportunities, environmental synergies and other related issues. This research is not only very useful for the current development of CCUS in the relative "cold season" but also beneficial for the energy security and clean production in China. [1] Li Q, Wei Y-N, Liu G, Shi H (2015) CO2-EWR: a cleaner solution for coal chemical industry in China. Journal of Cleaner Production 103:330-337. doi:10.1016/j.jclepro.2014.09.073 [2] Streibel M

Chemical profiling approach to evaluate the influence of traditional and simplified decoction methods on the holistic quality of Da-Huang-Xiao-Shi decoction using high-performance liquid chromatography coupled with diode-array detection and time-of-flight mass spectrometry.

PubMed

Yan, Xuemei; Zhang, Qianying; Feng, Fang

2016-04-01

Da-Huang-Xiao-Shi decoction, consisting of Rheum officinale Baill, Mirabilitum, Phellodendron amurense Rupr. and Gardenia jasminoides Ellis, is a traditional Chinese medicine used for the treatment of jaundice. As described in "Jin Kui Yao Lue", a traditional multistep decoction of Da-Huang-Xiao-Shi decoction was required while simplified one-step decoction was used in recent repsorts. To investigate the chemical difference between the decoctions obtained by the traditional and simplified preparations, a sensitive and reliable approach of high-performance liquid chromatography coupled with diode-array detection and electrospray ionization time-of-flight mass spectrometry was established. As a result, a total of 105 compounds were detected and identified. Analysis of the chromatogram profiles of the two decoctions showed that many compounds in the decoction of simplified preparation had changed obviously compared with those in traditional preparation. The changes of constituents would be bound to cause the differences in the therapeutic effects of the two decoctions. The present study demonstrated that certain preparation methods significantly affect the holistic quality of traditional Chinese medicines and the use of a suitable preparation method is crucial for these medicines to produce special clinical curative effect. This research results elucidated the scientific basis of traditional preparation methods in Chinese medicines. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Interpersonal Harmony and Conflict for Chinese People: A Yin-Yang Perspective.

PubMed

Huang, Li-Li

2016-01-01

This article provides an overview on a series of original studies conducted by the author. The aim here is to present the ideas that the author reconstructed, based on the dialectics of harmonization, regarding harmony and conflict embodied in traditional Chinese thought, and to describe how a formal psychological theory/model on interpersonal harmony and conflict was developed based on the Yin-Yang perspective. The paper also details how essential theories on interpersonal harmony and conflict were constructed under this formal model by conducting a qualitative study involving in-depth interviews with 30 adults. Psychological research in Western society has, intriguingly, long been focused more on interpersonal conflict than on interpersonal harmony. By contrast, the author's work started from the viewpoint of a materialist conception of history and dialectics of harmonization in order to reinterpret traditional Chinese thought. Next, a "dynamic model of interpersonal harmony and conflict" was developed, as a formal psychological theory, based on the real-virtual notions in the Yin-Yang perspective. Under this model, interpersonal harmony and conflict can be classified into genuine versus superficial harmony and authentic versus virtual focus conflict, and implicit/hidden conflict is regarded as superficial harmony. Subsequently, the author conducted a series of quantitative studies on interpersonal harmony and conflict within parent-child, supervisor-subordinate, and friend-friend relationships in order to verify the construct validity and the predictive validity of the dynamic model of interpersonal harmony and conflict. The claim presented herein is that Chinese traditional thought and the psychological theory/model based on the Yin-Yang perspective can be combined. Accordingly, by combining qualitative and quantitative empirical research, the relative substantial theory can be developed and the concepts can be validated. Thus, this work represents the

Interpersonal Harmony and Conflict for Chinese People: A Yin–Yang Perspective

PubMed Central

Huang, Li-Li

2016-01-01

This article provides an overview on a series of original studies conducted by the author. The aim here is to present the ideas that the author reconstructed, based on the dialectics of harmonization, regarding harmony and conflict embodied in traditional Chinese thought, and to describe how a formal psychological theory/model on interpersonal harmony and conflict was developed based on the Yin–Yang perspective. The paper also details how essential theories on interpersonal harmony and conflict were constructed under this formal model by conducting a qualitative study involving in-depth interviews with 30 adults. Psychological research in Western society has, intriguingly, long been focused more on interpersonal conflict than on interpersonal harmony. By contrast, the author’s work started from the viewpoint of a materialist conception of history and dialectics of harmonization in order to reinterpret traditional Chinese thought. Next, a “dynamic model of interpersonal harmony and conflict” was developed, as a formal psychological theory, based on the real-virtual notions in the Yin–Yang perspective. Under this model, interpersonal harmony and conflict can be classified into genuine versus superficial harmony and authentic versus virtual focus conflict, and implicit/hidden conflict is regarded as superficial harmony. Subsequently, the author conducted a series of quantitative studies on interpersonal harmony and conflict within parent–child, supervisor–subordinate, and friend–friend relationships in order to verify the construct validity and the predictive validity of the dynamic model of interpersonal harmony and conflict. The claim presented herein is that Chinese traditional thought and the psychological theory/model based on the Yin–Yang perspective can be combined. Accordingly, by combining qualitative and quantitative empirical research, the relative substantial theory can be developed and the concepts can be validated. Thus, this work

Continuous flame aerosol synthesis of carbon-coated nano-LiFePO4 for Li-ion batteries

PubMed Central

Waser, Oliver; Büchel, Robert; Hintennach, Andreas; Novák, Petr; Pratsinis, Sotiris E.

2013-01-01

Core-shell, nanosized LiFePO4-carbon particles were made in one step by scalable flame aerosol technology at 7 g/h. Core LiFePO4 particles were made in an enclosed flame spray pyrolysis (FSP) unit and were coated in-situ downstream by auto thermal carbonization (pyrolysis) of swirl-fed C2H2 in an O2-controlled atmosphere. The formation of acetylene carbon black (ACB) shell was investigated as a function of the process fuel-oxidant equivalence ratio (EQR). The core-shell morphology was obtained at slightly fuel-rich conditions (1.0 < EQR < 1.07) whereas segregated ACB and LiFePO4 particles were formed at fuel-lean conditions (0.8 < EQR < 1). Post-annealing of core-shell particles in reducing environment (5 vol% H2 in argon) at 700 °C for up to 4 hours established phase pure, monocrystalline LiFePO4 with a crystal size of 65 nm and 30 wt% ACB content. Uncoated LiFePO4 or segregated LiFePO4-ACB grew to 250 nm at these conditions. Annealing at 800 °C induced carbothermal reduction of LiFePO4 to Fe2P by ACB shell consumption that resulted in cavities between carbon shell and core LiFePO4 and even slight LiFePO4 crystal growth but better electrochemical performance. The present carbon-coated LiFePO4 showed superior cycle stability and higher rate capability than the benchmark, commercially available LiFePO4. PMID:23407817

Chemical obtaining of LiMO2 and LiM2O4 (M=Co, Mn) oxides, for cathodic applications in Li-ion batteries

NASA Astrophysics Data System (ADS)

Y Neira-Guio, A.; Gómez Cuaspud, J. A.; López, E. Vera; Pineda Triana, Y.

2017-12-01

This paper describes the synthesis and characterization of two spinel and olivine-type multicomponent oxides based on LiMO2 and LiM2O4 systems (M=Co and Mn), which represent the current state of the art in the development of cathodes for Li-ion batteries. A simple combustion synthesis process was employed to obtain the nanometric oxides in powder form (crystal sizes around 5-8nm), with a number of improved surface characteristics. The characterization by X-Ray Diffraction (XRD), Scanning and Transmission Electron Microscopy (SEM, TEM) and X-Ray Fluorescence (XRF), allowed to evaluate the morphology and the stoichiometric compositions of solids, obtaining a concordant pure crystalline phase of LiCoO2 and LiMn2O4 oxides identified in a rhombohedral and cubic phase with punctual group R-3m (1 6 6) and Fm-3m (2 2 5) respectively. The electrical characterization of materials developed by impedance spectroscopy solid state, allowed to determine a p-type semiconducting behaviour with conductivity values of 6.2×10-3 and 2.7×10-7 S for LiCoO2 and LiMn2O4 systems, consistent with the state of the art for such materials.

LETTER TO THE EDITOR: Cross sections of 6Li(t,d1)7Li*[0.478] and 6Li(t,p1)8Li*[0.981] nuclear reactions in the 0-2 MeV energy range

NASA Astrophysics Data System (ADS)

Voronchev, V. T.; Kukulin, V. I.

2000-12-01

An original extrapolation technique developed previously is modified and applied to study nuclear reactions in the 6Li + T system at energies E = 0-2 MeV. Cross sections of gamma-ray-producing reactions 6Li(t,d1)7Li*[0.478] and 6Li(t,p1)8Li*[0.981] with important diagnostic implications are calculated. The (t,d1) nuclear data found exceed those accepted elsewhere by 2.5-3.5 times at sub-barrier energies. The cross sections of the (t,p1) reaction are calculated for the first time.

Relevance of LiPF6 as Etching Agent of LiMnPO4 Colloidal Nanocrystals for High Rate Performing Li-ion Battery Cathodes.

PubMed

Chen, Lin; Dilena, Enrico; Paolella, Andrea; Bertoni, Giovanni; Ansaldo, Alberto; Colombo, Massimo; Marras, Sergio; Scrosati, Bruno; Manna, Liberato; Monaco, Simone

2016-02-17

LiMnPO4 is an attractive cathode material for the next-generation high power Li-ion batteries, due to its high theoretical specific capacity (170 mA h g(-1)) and working voltage (4.1 V vs Li(+)/Li). However, two main drawbacks prevent the practical use of LiMnPO4: its low electronic conductivity and the limited lithium diffusion rate, which are responsible for the poor rate capability of the cathode. The electronic resistance is usually lowered by coating the particles with carbon, while the use of nanosize particles can alleviate the issues associated with poor ionic conductivity. It is therefore of primary importance to develop a synthetic route to LiMnPO4 nanocrystals (NCs) with controlled size and coated with a highly conductive carbon layer. We report here an effective surface etching process (using LiPF6) on colloidally synthesized LiMnPO4 NCs that makes the NCs dispersible in the aqueous glucose solution used as carbon source for the carbon coating step. Also, it is likely that the improved exposure of the NC surface to glucose facilitates the formation of a conductive carbon layer that is in intimate contact with the inorganic core, resulting in a high electronic conductivity of the electrode, as observed by us. The carbon coated etched LiMnPO4-based electrode exhibited a specific capacity of 118 mA h g(-1) at 1C, with a stable cycling performance and a capacity retention of 92% after 120 cycles at different C-rates. The delivered capacities were higher than those of electrodes based on not etched carbon coated NCs, which never exceeded 30 mA h g(-1). The rate capability here reported for the carbon coated etched LiMnPO4 nanocrystals represents an important result, taking into account that in the electrode formulation 80% wt is made of the active material and the adopted charge protocol is based on reasonable fast charge times.

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

PubMed Central

Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang; Zhu, Yizhou; Xu, Shaomao; Yao, Yonggang; Luo, Wei; Wang, Chengwei; Lacey, Steven D.; Dai, Jiaqi; Chen, Yanan; Mo, Yifei; Wachsman, Eric; Hu, Liangbing

2017-01-01

Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet–type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10−3 to 10−4 S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnet solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm·cm2 for the pristine garnet/Li and 75 ohm·cm2 for the surface-engineered garnet/Li. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries. PMID:28435874

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fu, Kun; Gong, Yunhui; Liu, Boyang

Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet–type Li 7La 3Zr 2O 12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10 -3 to 10 -4 S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnetmore » solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm·cm2 for the pristine garnet/Li and 75 ohm·cm 2 for the surface-engineered garnet/Li. Li 7La 2.75Ca 0.25Zr 1.75Nb 0.25O 12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries.« less

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

DOE PAGES

Fu, Kun; Gong, Yunhui; Liu, Boyang; ...

2017-04-07

Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet–type Li 7La 3Zr 2O 12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10 -3 to 10 -4 S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnetmore » solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm·cm2 for the pristine garnet/Li and 75 ohm·cm 2 for the surface-engineered garnet/Li. Li 7La 2.75Ca 0.25Zr 1.75Nb 0.25O 12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries.« less

Three-Dimensional Honeycomb-Structural LiAlO2-Modified LiMnPO4 Composite with Superior High Rate Capability as Li-Ion Battery Cathodes.

PubMed

Li, Junzhe; Luo, Shaohua; Ding, Xueyong; Wang, Qing; He, Ping

2018-04-04

In the efforts toward the rapidly increasing demands for high-power application, cathode materials with three-dimensional (3D) architectures have been proposed. Here, we report the construction of the 3D LiAlO 2 -LiMnPO 4 /C cathode materials for lithium-ion batteries in an innovation way. The as-prepared 3D active materials LiMnPO 4 /C and the honeycomb-like Li-ion conductor LiAlO 2 framework are used as working electrode directly without additional usage of polymeric binder. The electrochemical performance has been improved significantly due to the special designed core-shell architectures of LiMnPO 4 /C@LiAlO 2 . The 3D binder-free electrode exhibits high rate capability as well as superior cycling stability with a capability of ∼105 mAh g -1 and 98.4% capacity retention after 100 cycles at a high discharge rate of 10 C. Such synthesis method adopted in our work can be further extended to other promising candidates and would also inspire new avenues of development of 3D materials for lithium-ion batteries.

[100]-Oriented LiFePO4 Nanoflakes toward High Rate Li-Ion Battery Cathode.

PubMed

Li, Zhaojin; Peng, Zhenzhen; Zhang, Hui; Hu, Tao; Hu, Minmin; Zhu, Kongjun; Wang, Xiaohui

2016-01-13

[100] is believed to be a tough diffusion direction for Li(+) in LiFePO4, leading to the belief that the rate performance of [100]-oriented LiFePO4 is poor. Here we report the fabrication of 12 nm-thick [100]-oriented LiFePO4 nanoflakes by a simple one-pot solvothermal method. The nanoflakes exhibit unexpectedly excellent electrochemical performance, in stark contrast to what was previously believed. Such an exceptional result is attributed to a decreased thermodynamic transformation barrier height (Δμb) associated with increased active population.

CuLi2Sn and Cu2LiSn: Characterization by single crystal XRD and structural discussion towards new anode materials for Li-ion batteries.

PubMed

Fürtauer, Siegfried; Effenberger, Herta S; Flandorfer, Hans

2014-12-01

The stannides CuLi 2 Sn (CSD-427095) and Cu 2 LiSn (CSD-427096) were synthesized by induction melting of the pure elements and annealing at 400 °C. The phases were reinvestigated by X-ray powder and single-crystal X-ray diffractometry. Within both crystal structures the ordered CuSn and Cu 2 Sn lattices form channels which host Cu and Li atoms at partly mixed occupied positions exhibiting extensive vacancies. For CuLi 2 Sn, the space group F-43m. was verified (structure type CuHg 2 Ti; a =6.295(2) Å; wR 2 ( F ²)=0.0355 for 78 unique reflections). The 4( c ) and 4( d ) positions are occupied by Cu atoms and Cu+Li atoms, respectively. For Cu 2 LiSn, the space group P 6 3 / mmc was confirmed (structure type InPt 2 Gd; a =4.3022(15) Å, c =7.618(3) Å; wR 2 ( F ²)=0.060 for 199 unique reflections). The Cu and Li atoms exhibit extensive disorder; they are distributed over the partly occupied positions 2( a ), 2( b ) and 4( e ). Both phases seem to be interesting in terms of application of Cu-Sn alloys as anode materials for Li-ion batteries.

Modulation of solid electrolyte interphase of lithium-ion batteries by LiDFOB and LiBOB electrolyte additives

NASA Astrophysics Data System (ADS)

Huang, Shiqiang; Wang, Shuwei; Hu, Guohong; Cheong, Ling-Zhi; Shen, Cai

2018-05-01

Solid-electrolyte interphase (SEI) layer is an organic-inorganic composite layer that allows Li+ transport across but blocks electron flow across and prevents solvent diffusing to electrode surface. Morphology, thickness, mechanical and chemical properties of SEI are important for safety and cycling performance of lithium-ion batteries. Herein, we employ a combination of in-situ AFM and XPS to investigate the effects of two electrolyte additives namely lithium difluoro(oxalate)borate (LiDFOB) and lithium bis(oxalato)borate (LiBOB) on SEI layer. LiDFOB is found to result in a thin but hard SEI layer containing more inorganic species (LiF and LiCO3); meanwhile LiBOB promotes formation of a thick but soft SEI layer containing more organic species such as ROCO2Li. Findings from present study will help development of electrolyte additives that promote formation of good SEI layer.

Computer-aided Human Centric Cyber Situation Awareness

DTIC Science & Technology

2016-03-20

in Video, IJCAI: International Joint Conf. on Artificial Intelligence . 16-JUL-11, . : , Kun Sun, Sushil Jajodia, Jason Li, Yi Cheng, Wei Tang...Cyber-Security Conference, June 2015. 2. V.S. Subrahmanian, Invited Speaker, Summer School on Business Intelligence and Big Data Analysis, Capri, Italy... Cybersecurity Conference, Yuval Ne’eman Workshop for Science, Technology and Security, Tel Aviv University, the Israeli National Cyber Bureau, Prime

Equilibrium lithium isotope fractionation in Li-rich minerals

NASA Astrophysics Data System (ADS)

Liu, S.; Li, Y.; Liu, J.

2017-12-01

Lithium is the lightest alkali metal, and only exhibits +1 valence state in minerals. It is widely distributed on the Earth, and usually substitutes for Mg in silicate minerals. Li has two stable isotopes, 6Li and 7Li, with the relative abundances of 7.52% and 92.48%, respectively. The large mass difference between 6Li and 7Li could induce significant isotope fractionation in minerals. Li isotopes can provide an important geochemical tracer for mantle processes. However, the fractionation factors for Li in most minerals remain poorly known, which makes the geochemical implications of Li isotope fractionations in minerals difficult to assess. Here, we try to use the vibrational frequencies obtained by the first-principles methods based on density-functional theory to calculate the Li isotope fractionation parameters for amblygonite (LiAlPO4F), bikitaite (LiSi2AlO7H2), eucryptite (LiAlSiO4), lithiophilite (LiMnPO4), lithiophosphate (Li3PO4), montebrasite (LiAlPO5H), and spodumene (LiAlSi2O6) in the temperature range of 0-1200 ºC. For forsterite (Mg2SiO4) and diopside (CaMgSi2O6) in which Li takes the place of Mg, the equilibrium Li isotope fractionation between them also be studied. Our preliminary calculations show that the coordination number of Li seems to play an important role in controlling Li isotope fractionation in these minerals, and concentration of Li in forsterite and diopside seems to have great effects on Li isotope fractionation factors of them.

Measurements of the fundamental thermodynamic parameters of Li/BCX and Li/SOCl2 cells

NASA Technical Reports Server (NTRS)

Kalu, E. E.; White, R. E.; Darcy, E. C.

1992-01-01

Two experimental techniques - equilibrium or reversible cell discharge and measurement of open circuit potential as a function of temperature - are used to determine the thermodynamic data needed to estimate the heat generation characteristics of Li/BCX and Li/SOCl2 cells. The results obtained showed that the reversible cell potential, the temperature dependence of the reversible cell potential, and the thermoneutral potential of the BCX cell were 3.74 V, -0.857 +/- 0.198 mV/K, and 3.994 +/- 0.0603 V, respectively. The respective values obtained for the Li/SOCl2 cell were 3.67 V, -0.776 +/- 0.255 mV/K, and 3.893 +/- 0.0776 V. The difference between the thermoneutral potential of Li/BCX and Li/SCl2 cells is attributable to the difference in their electroactive components.

Reoxidation of uranium metal immersed in a Li2O-LiCl molten salt after electrolytic reduction of uranium oxide

NASA Astrophysics Data System (ADS)

Choi, Eun-Young; Jeon, Min Ku; Lee, Jeong; Kim, Sung-Wook; Lee, Sang Kwon; Lee, Sung-Jai; Heo, Dong Hyun; Kang, Hyun Woo; Jeon, Sang-Chae; Hur, Jin-Mok

2017-03-01

We present our findings that uranium (U) metal prepared by using the electrolytic reduction process for U oxide (UO2) in a Li2O-LiCl salt can be reoxidized into UO2 through the reaction between the U metal and Li2O in LiCl. Two salt types were used for immersion of the U metal: one was the salt used for electrolytic reduction, and the other was applied to the unused LiCl salts with various concentrations of Li2O and Li metal. Our results revealed that the degree of reoxidation increases with the increasing Li2O concentration in LiCl and that the presence of the Li metal in LiCl suppresses the reoxidation of the U metal.

7Li(d,p)8Li transfer reaction in the NCSM/RGM approach

NASA Astrophysics Data System (ADS)

Raimondi, F.; Hupin, G.; Navrátil, P.; Quaglioni, S.

2018-03-01

Recently, we applied an ab initio method, the no-core shell model combined with the resonating group method, to the transfer reactions with light p-shell nuclei as targets and deuteron as the projectile. In particular, we studied the elastic scattering of deuterium on 7Li and the 7Li(d,p)8Li transfer reaction starting from a realistic two-nucleon interaction. In this contribution, we review of our main results on the 7Li(d,p)8Li transfer reaction, and we extend the study of the relevant reaction channels, by showing the dominant resonant phase shifts of the scattering matrix. We assess also the impact of the polarization effects of the deuteron below the breakup on the positive-parity resonant states in the reaction. For this purpose, we perform an analysis of the convergence trend of the phase and eigenphase shifts, with respect to the number of deuteron pseudostates included in the model space.

Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

DOE PAGES

Lü, Xujie; Howard, John W.; Chen, Aiping; ...

2016-02-02

We prepared antiperovskite Li 3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10 -4 S cm -1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li 3OCl as a solid electrolyte for Li-ion batteries is demonstrated.

Electrodisintegration of Li 6

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bishop, G. R.; Bernheim, M.

1963-06-01

For the ( γ,n) reaction in Li 6 a model in which Li 6 splits into a deuteron and an alpha particle that separately absorb the photon energy was recently proposed. The model was tested by studying the inelastic scattering of 101.4-Mev electrons from Li 6. Expressions for the cross sections were obtained, and values calculated for a form factor in the cross sections confirm the validity of the model.

Single-crystalline LiFePO4 nanosheets for high-rate Li-ion batteries.

PubMed

Zhao, Yu; Peng, Lele; Liu, Borui; Yu, Guihua

2014-05-14

The lithiation/delithiation in LiFePO4 is highly anisotropic with lithium-ion diffusion being mainly confined to channels along the b-axis. Controlling the orientation of LiFePO4 crystals therefore plays an important role for efficient mass transport within this material. We report here the preparation of single crystalline LiFePO4 nanosheets with a large percentage of highly oriented {010} facets, which provide the highest pore density for lithium-ion insertion/extraction. The LiFePO4 nanosheets show a high specific capacity at low charge/discharge rates and retain significant capacities at high C-rates, which may benefit the development of lithium batteries with both favorable energy and power density.

Li-atoms-induced structure changes of Guinier–Preston–Bagaryatsky zones in AlCuLiMg alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duan, S.Y.; Le, Z.; Chen, Z.K.

2016-11-15

Guinier–Preston–Bagaryatsky (GPB) zones are the well-known strengthening precipitates of AlCuMg alloys formed upon thermal ageing. Here we report that when formed in AlCuLiMg alloys the GPB zones can change significantly in morphology and structure. It is shown that though they do still consist of Al, Cu and Mg elements fundamentally, the GPB zones in AlCuLiMg alloys have a rather different structure due to a featured Li-segregation at their interfaces with the matrix and possible Li-replacement of partial Mg atoms in the structure. As such the Li-containing GPB zones often develop from one-dimensional to quasi-two-dimensional precipitates. - Highlights: • We observemore » Guinier–Preston–Bagaryatsky zone variants in AlCuLiMg alloys. • We obtain atomic-resolution images of the precipitates and model their structures. • Li-atoms play a key role in modifying the structure of these precipitate variants.« less

On spinodal points and Lee-Yang edge singularities

NASA Astrophysics Data System (ADS)

An, X.; Mesterházy, D.; Stephanov, M. A.

2018-03-01

We address a number of outstanding questions associated with the analytic properties of the universal equation of state of the φ4 theory, which describes the critical behavior of the Ising model and ubiquitous critical points of the liquid–gas type. We focus on the relation between spinodal points that limit the domain of metastability for temperatures below the critical temperature, i.e. T < Tc , and Lee-Yang edge singularities that restrict the domain of analyticity around the point of zero magnetic field H for T > Tc . The extended analyticity conjecture (due to Fonseca and Zamolodchikov) posits that, for T < Tc , the Lee-Yang edge singularities are the closest singularities to the real H axis. This has interesting implications, in particular, that the spinodal singularities must lie off the real H axis for d < 4 , in contrast to the commonly known result of the mean-field approximation. We find that the parametric representation of the Ising equation of state obtained in the \\renewcommandε{\\varepsilon} \

Traditional Chinese medicine therapy improves the survival of systemic lupus erythematosus patients.

PubMed

Ma, Yi-Chun; Lin, Cheng-Chieh; Li, Chia-Ing; Chiang, Jen-Huai; Li, Tsai-Chung; Lin, Jaung-Geng

2016-04-01

No previous studies have evaluated the effect of traditional Chinese medicine (TCM) treatment on the survival of patients with systemic lupus erythematosus (SLE). Hence, in this study, we determined whether TCM treatment affects the survival of SLE patients. This nationwide population-based retrospective cohort study assessed 23,084 patients newly diagnosed with SLE between 1999 and 2009, using the database of the Taiwan National Health Insurance program. Among these patients, 9267 (40.15%) used TCM for SLE treatment and exhibited a significantly decreased risk of death [hazard ratio (HR) = 0.73; 95% confidence interval (CI): 0.68-0.78], with multivariate adjustment, compared with those without TCM use. A similar significant protective effect of TCM use was found across various subgroups of comorbidities. TCM use 1 year before diagnosis also reduced the risk of death. Our study findings indicated that Zhi Bo Di Huang Wan (HR = 0.54; 95% CI: 0.32-0.91), Jia Wei Xiao Yao San (HR = 0.35; 95% CI: 0.16-0.73), Liu Wei Di Huang Wan (HR = 0.51; 95% CI: 0.28-0.93), Gan Lu Yin (HR = 0.40; 95% CI: 0.17-0.96), and Yin Qiao San (HR = 0.22; 95% CI: 0.05-0.86) were the most effective TCM agents that improved survival. This nationwide retrospective cohort study provided information that combined therapy with TCM may improve the survival in SLE patients. This study also suggests that TCM may be used as an integral element of effective therapy for SLE. Copyright © 2016 Elsevier Inc. All rights reserved.

In-house fabrication and testing capabilities for Li and Li-ion 18650 cells

NASA Astrophysics Data System (ADS)

Nagasubramanian, G.

2010-04-01

For over 10 years Sandia Labs have been involved in an US DOE-funded program aimed at developing electric vehicle batteries for transportation applications. Currently this program is called "Advanced Battery Research (ABR)." In this effort we were preparing 18650 cells with electrodes supplied by or purchased from private companies for thermal abuse and electrical characterization studies. Lately, we are coating our own electrodes, building cells and evaluating performance. This paper describes our extensive in-house facilities for slurry making, electrode coating, cell winding etc. In addition, facilities for electrical testing and thermal abuse will be described. This facility allows us to readjust our focus quickly to the changing demands of the still evolving ABR program. Additionally, we continue to make cells for our internal use. We made several 18650 cells both primary (Li-CFx) and secondary (Li-ion) and evaluated performance. For example Li-CFx cells gave ~2.9Ahr capacity at room temperature. Our high voltage Li-ion cells consisting of carbon anode and cathode based on LiNi 0.4Mn 0.3Co 0.3O2 in organic electrolytes exhibited reproducible behavior and gave capacity on the order of 1Ahr. Performance of Li-ion cells at different temperatures and thermal abuse characteristics will be presented.

A High-Performance Li-O2 Battery with a Strongly Solvating Hexamethylphosphoramide Electrolyte and a LiPON-Protected Lithium Anode.

PubMed

Zhou, Bin; Guo, Limin; Zhang, Yantao; Wang, Jiawei; Ma, Lipo; Zhang, Wen-Hua; Fu, Zhengwen; Peng, Zhangquan

2017-08-01

The aprotic Li-O 2 battery has attracted a great deal of interest because theoretically it can store more energy than today's Li-ion batteries. However, current Li-O 2 batteries suffer from passivation/clogging of the cathode by discharged Li 2 O 2 , high charging voltage for its subsequent oxidation, and accumulation of side reaction products (particularly Li 2 CO 3 and LiOH) upon cycling. Here, an advanced Li-O 2 battery with a hexamethylphosphoramide (HMPA) electrolyte is reported that can dissolve Li 2 O 2 , Li 2 CO 3 , and LiOH up to 0.35, 0.36, and 1.11 × 10 -3 m, respectively, and a LiPON-protected lithium anode that can be reversibly cycled in the HMPA electrolyte. Compared to the benchmark of ether-based Li-O 2 batteries, improved capacity, rate capability, voltaic efficiency, and cycle life are achieved for the HMPA-based Li-O 2 cells. More importantly, a combination of advanced research techniques provide compelling evidence that operation of the HMPA-based Li-O 2 battery is backed by nearly reversible formation/decomposition of Li 2 O 2 with negligible side reactions. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Reactive transport modeling of Li isotope fractionation

NASA Astrophysics Data System (ADS)

Wanner, C.; Sonnenthal, E. L.

2013-12-01

The fractionation of Li isotopes has been used as a proxy for interaction processes between silicate rocks and any kind of fluids. In particular, Li isotope measurements are powerful because Li is almost exclusively found in silicate minerals. Moreover, the two stable Li isotopes, 6Li and 7Li, differ by 17% in mass introducing a large mass dependent isotope fractionation even at high temperature. Typical applications include Li isotope measurements along soil profiles and of river waters to track silicate weathering patterns and Li isotope measurements of geothermal wells and springs to assess water-rock interaction processes in geothermal systems. For this contribution we present a novel reactive transport modeling approach for the simulation of Li isotope fractionation using the code TOUGHREACT [1]. It is based on a 6Li-7Li solid solution approach similar to the one recently described for simulating Cr isotope fractionation [2]. Model applications include the simulation of granite weathering along a 1D flow path as well as the simulation of a column experiment related to an enhanced geothermal system. Results show that measured δ7Li values are mainly controlled by (i) the degree of interaction between Li bearing primary silicate mineral phases (e.g., micas, feldspars) and the corresponding fluid, (ii) the Li isotope fractionation factor during precipitation of secondary mineral phases (e.g., clays), (iii) the Li concentration in primary and secondary Li bearing mineral phases and (iv) the proportion of dissolved Li that adsorbs to negatively charged surfaces (e.g., clays, Fe/Al-hydroxides). To date, most of these parameters are not very well constrained. Reactive transport modeling thus currently has to rely on many assumptions. Nevertheless, such models are powerful because they are the only viable option if individual contributions of all potential processes on the resulting (i.e., measured) Li isotopic ratio have to be quantitatively assessed. Accordingly, we

Electrochemical performances of co-substituted (La and Li) LiLa{sub x−y}Li{sub y}Ni{sub 1−x}O{sub 2} cathode materials for rechargeable lithium-ion batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mohan, P.; Paruthimal Kalaignan, G., E-mail: pkalaignan@yahoo.com

2013-09-01

Graphical abstract: - Highlights: • LiLa{sub x−y}Li{sub x}Ni{sub 1−x}O{sub 2} powders were prepared by a sol–gel method at 600 °C for 10 h. • LiLa{sub x−y}Li{sub x}Ni{sub 1−x}O{sub 2} powder materials had well defined layer structure, and no impurities. • LiLa{sub 0.10}Li{sub 0.10}Ni{sub 0.80}O{sub 2} crystallite size was reduced compared with those of LiNiO{sub 2}. • Li/LiPF{sub 6}/LiLa{sub x−y}Li{sub x}Ni{sub 1−x}O{sub 2} cells were of high charge/discharge capacity, with columbic efficiency at 25 °C and 45 °C. • LiLa{sub 0.10}Li{sub 0.10}Ni{sub 0.80}O{sub 2} good cyclic stability, rate capability and better 45 °C. - Abstract: Co-substituted LiLa{sub x−y}Li{sub y}Ni{sub 1−x}O{sub 2}more » cathode materials were synthesized by sol–gel method using aqueous solutions of metal nitrates and tartaric acid as chelating agent at 600 °C for 10 h. The structure and electrochemical properties of the synthesized materials were characterized by using XRD, SEM, EDAX, TEM, cyclic voltammetry, charge/discharge and electrochemical impedance spectroscopy. XRD studies revealed a well defined layer structure and a linear variation of lattice parameters with the addition of lanthanum and lithium confirmed phase pure compounds in a rhombohedral structure. TEM and SEM analysis shows that LiLa{sub 0.10}Li{sub 0.10}Ni{sub 0.80}O{sub 2} has smaller particle size and regular morphological structure with narrow size distribution than those of LiNiO{sub 2}. Variations of dual mixing and hexagonal ordering with the substituted elements have enhanced the charge/discharge capacities at both room (25 °C) and elevated temperatures (45 °C), respectively. LiLa{sub 0.10}Li{sub 0.10}Ni{sub 0.80}O{sub 2} had high charge/discharge capacity, low irreversible capacity and better elevated temperature performance.« less

LiF dissolution by anion-binding-agent in LiCF x battery systems: Lower ohmic and interfacial resistance.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagasubramanian, Ganesan; Fenton, Kyle Ross

2015-02-01

In this paper we will discuss our preliminary thermal and electrochemical data aimed at developing a robust nonflammable Li-CFx cell capable of wide temperature operation. To accomplish this goal, we are evaluating a thermally stable solvent comprised of an anion binding agent (ABA) and lithium fluoride (LiF), typically at a 1:1 molar ratio. In conventional carbonate based electrolytes, ABA is soluble while LiF remains insoluble. However, the neutral ABA solubilizes LiF and forms a salt complex represented as Li+(ABAF-). We are exploiting this unique feature and apply this strategy to CFx chemistry to improve cell performance, due to the CFxmore » cell chemistry generating LiF as discharge product. Continuous solvation of the salt mixture during discharge allows for utilization of electrolytes initially containing sub stoichiometric amount of LiF. The practical benefits are reduced cell weight, mitigation of electrode fouling, and consequently better low temperature performance. Electrolytes containing dimethyl methyl phosphonate (DMMP), 1M tris(pentafluorophenyl) borane (TPFB) and varying concentrations of LiF (1M; 0.5M and 0.1M) were prepared and characterized for ionic conductivity and voltage stability. In general, ionic conductivity decreases with decreasing LiF concentration. The room temperature conductivity for the DMMP 1M TPFB:1M LiF is ~ 9mS/cm and ~3mS/cm for the 1M TPFB:0.1M LiF. Unlike the conductivity, the electrochemical voltage stability did not vary substantially with LiF concentration and the electrolytes showed a stable voltage window in the range 0-3.5V vs. Li +/Li, which is substantially wider than the Li-CFx cell voltage. Flammability measurement performed at our thermal abuse facility demonstrated that the electrolyte was nonflammable. Discharge performance of CFx materials obtained from several vendors was evaluated in 2032 coin cells at room temperature. Experimental results demonstrate a reduction in ohmic resistance and interfacial

Effect of [Li]/[Nb] ratio on composition and defect structure of Zr:Yb:Tm:LiNbO3 crystals

NASA Astrophysics Data System (ADS)

Liu, Chunrui; Dai, Li; Wang, Luping; Shao, Yu; Yan, Zhehua; Xu, Yuheng

2018-04-01

Zr:Yb:Tm:LiNbO3 crystals with various [Li]/[Nb] ratios (0.946, 1.05, 1.20 and 1.38) were grown by the Czochralski technique. Distribution coefficients of Zr4+, Yb3+ and Tm3+ ions were analyzed by the inductively coupled plasma-atomic emission spectrometer (ICP-AES). The influence of [Li]/[Nb] ratio on the composition and defect structure of Zr:Yb:Tm:LiNbO3 crystals was investigated by X-ray diffraction and IR transmission spectrum. The results show that as the [Li]/[Nb] ratio increases in the melt, the distribution coefficients of Yb3+ and Tm3+ ions both increase while that of Zr4+ ion deceases. When the [Li]/[Nb] ratio increases to 1.20 in the melt, Zr:Yb:Tm:LiNbO3 crystal is nearly stoichiometric. In addition, when the [Li]/[Nb] ratio reaches up to 1.38, NbLi4+ are completely replaced and Li+ starts to impel the Zr4+, Yb3+ and Tm3+ into the normal Li sites.

Body composition and personality traits in so-Yang type males.

PubMed

Yoon, Jiwon; Nam, Jiho; Leem, Chae Hun; Kim, Jong Yeol

2017-08-22

The purpose of the present study was to examine the body composition of So-Yang type males according to Sasang constitutional medicine, which is popular in Korea. Different Sasang constitutional types are associated with different muscle distributions, body shapes, and disease susceptibilities. We used the Sasang Personality Questionnaire (SPQ) as a measure of the temperament of each Sasang type. In total, 953 subjects aged over 20 years were recruited in Korea. We collected anthropometric parameters and bioimpedence information from the subjects and administered the SPQ. A logistic regression was conducted to calculate propensity scores. The percentage of skeletal muscle mass in So-Yang (SY) and non-So-Yang (non-SY) males was 45.8 ± 2.7 and 44.2 ± 3.3, respectively, before matching and 45.8 ± 2.6 and 44.9 ± 3.0, respectively, after propensity score matching. The extracellular water (ECW)/intracellular water (ICW) and extracellular water (ECW)/total body water (TBW) ratios and SPQ scores were significantly different between the SY and non-SY types. This study suggested that the SY type may be significantly and independently associated with body composition and could be associated with personality.

Fabrication and tritium release property of Li2TiO3-Li4SiO4 biphasic ceramics

NASA Astrophysics Data System (ADS)

Yang, Mao; Ran, Guangming; Wang, Hailiang; Dang, Chen; Huang, Zhangyi; Chen, Xiaojun; Lu, Tiecheng; Xiao, Chengjian

2018-05-01

Li2TiO3-Li4SiO4 biphasic ceramic pebbles have been developed as an advanced tritium breeder due to the potential to combine the advantages of both Li2TiO3 and Li4SiO4. Wet method was developed for the pebble fabrication and Li2TiO3-Li4SiO4 biphasic ceramic pebbles were successfully prepared by wet method using the powders synthesized by hydrothermal method. The tritium release properties of the Li2TiO3-Li4SiO4 biphasic ceramic pebbles were evaluated. The biphasic pebbles exhibited good tritium release property at low temperatures and the tritium release temperature was around 470 °C. Because of the isotope exchange reaction between H2 and tritium, the addition of 0.1%H2 to purge gas He could significantly enhance the tritium gas release and the fraction of molecular form of tritium increased from 28% to 55%. The results indicate that the Li2TiO3-Li4SiO4 biphasic ceramic pebbles fabricated by wet method exhibit good tritium release property and hold promising potential as advanced breeder pebbles.

Properties of the LiCl-KCl-Li2O system as operating medium for pyro-chemical reprocessing of spent nuclear fuel

NASA Astrophysics Data System (ADS)

Mullabaev, Albert; Tkacheva, Olga; Shishkin, Vladimir; Kovrov, Vadim; Zaikov, Yuriy; Sukhanov, Leonid; Mochalov, Yuriy

2018-03-01

Crystallization temperatures (liquidus and solidus) in the LiCl-Li2O and (LiCl-KCl)-Li2O systems with the KCl content of 10 and 20 mol.% were obtained with independent methods of thermal analysis using cooling curves, isothermal saturation, and differential scanning calorimetry. The linear sweep voltammetry was applied to control the time of the equilibrium establishment in the molten system after the Li2O addition, which depended on the composition of the base melt and the concentration of Li2O. The fragments of the binary LiCl-Li2O and quazi-binary [LiCl-KCl(10 mol.%)]-Li2O and [LiCl-KCl(20 mol.%)]-Li2O phase diagrams in the Li2O concentration range from 0 to 12 mol.% were obtained. The KCl presence in the LiCl-KCl-Li2O molten mixture in the amount of 10 and 20 mol.% reduces the liquidus temperature by 30 and 80°, respectively, but the region of the homogeneous molten state of the system is considerably narrowed, which complicates its practical application. The Li2O solubility in the molten LiCl, LiCl-KCl(10 mol.%) and LiCl-KCl(20 mol.%) decreases with increasing the KCl content and is equal to 11.5, 7.7 and 3.9 mol.% at 650°С, respectively. The LiCl-KCl melt with 10 mol.% KCl can be recommended for practical use as a medium for the SNF pyro-chemical reprocessing at temperature below 700 °C.

Identification of Novel Drug Targets and Lead Compounds for Advanced Prostate Cancer through Genomic and Cheminformatic Analyses

DTIC Science & Technology

2015-08-01

AW, Mo F, Wang K, McConeghy B, Brahmbhatt S, Jong L, Mitchell DM, Johnston RL, Haegert A, Li E, Liew J , Yeung J , Shrestha R, Lapuk AV, McPherson A...Shukin R, Bell RH, Anderson S, Bishop J , Hurtado-Coll A, Xiao H, Chinnaiyan AM, Mehra R, Lin D, Wang Y, Fazli L, Gleave ME, Volik SV, Collins CC...Heterogeneity in the inter-tumor transcriptome of high risk prostate cancer. Genome Biol. (2014). 15: 426. [6]. Song T, Hwang KB, Hsing M, Lee K, Bohn J

Basic molten salt process-A new route for synthesis of nanocrystalline Li 4Ti 5O 12-TiO 2 anode material for Li-ion batteries using eutectic mixture of LiNO 3-LiOH-Li 2O 2

NASA Astrophysics Data System (ADS)

Rahman, M. M.; Wang, Jia-Zhao; Hassan, Mohd Faiz; Chou, Shulei; Wexler, David; Liu, Hua-Kun

A nanocrystalline Li 4Ti 5O 12-TiO 2 duplex phase has been synthesized by a simple basic molten salt process (BMSP) using an eutectic mixture of LiNO 3-LiOH-Li 2O 2 at 400-500 °C. The microstructure and morphology of the Li 4Ti 5O 12-TiO 2 product are characterized by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The sample prepared by heat-treating at 300 °C for 3 h (S-1) reveals dense agglomerates of ultra-fine nanocrystalline Li 4Ti 5O 12; with heat treatment at 400 °C for 3 h (S-2), there is a duplex crystallite size (fine < 10 nm, and coarse > 20 nm) of Li 4Ti 5O 12-TiO 2; at 500 °C for 3 h (S-3), a much coarser and less-dense distribution of lithium titanate (crystallite size ∼15-30 nm) is observed. According to the results of electrochemical testing, the S-2 sample shows initial discharge capacities of 193 mAh g -1 at 0.2 C, 168 mAh g -1 at 0.5 C, 146 mAh g -1 at 1 C, 135 mAh g -1 at 2 C, and 117 mAh g -1 at 5 C. After 100 cycles, the discharge capacity is 138 mAh g -1 at 1 C with a capacity retention of 95%. The S-2 sample yields the best electrochemical performance in terms of charge-discharge capacity and rate capability compared with other samples. Its superior electrochemical performance can be mainly attributed to the duplex crystallite structure, composed of fine (<10 nm) and coarse (>20) nm nanoparticles, where lithium ions can be stored within the grain boundary interfaces between the spinel Li 4Ti 5O 12 and the anatase TiO 2.

Storage and Effective Migration of Li-Ion for Defected β-LiFePO4 Phase Nanocrystals.

PubMed

Guo, Hua; Song, Xiaohe; Zhuo, Zengqing; Hu, Jiangtao; Liu, Tongchao; Duan, Yandong; Zheng, Jiaxin; Chen, Zonghai; Yang, Wanli; Amine, Khalil; Pan, Feng

2016-01-13

Lithium iron phosphate, a widely used cathode material, crystallizes typically in olivine-type phase, α-LiFePO4 (αLFP). However, the new phase β-LiFePO4 (βLFP), which can be transformed from αLFP under high temperature and pressure, is originally almost electrochemically inactive with no capacity for Li-ion battery, because the Li-ions are stored in the tetrahedral [LiO4] with very high activation barrier for migration and the one-dimensional (1D) migration channels for Li-ion diffusion in αLFP disappear, while the Fe ions in the β-phase are oriented similar to the 1D arrangement instead. In this work, using experimental studies combined with density functional theory calculations, we demonstrate that βLFP can be activated with creation of effective paths of Li-ion migration by optimized disordering. Thus, the new phase of βLFP cathode achieved a capacity of 128 mAh g(-1) at a rate of 0.1 C (1C = 170 mA g(-1)) with extraordinary cycling performance that 94.5% of the initial capacity retains after 1000 cycles at 1 C. The activation mechanism can be attributed to that the induced disorder (such as FeLiLiFe antisite defects, crystal distortion, and amorphous domains) creates new lithium migration passages, which free the captive stored lithium atoms and facilitate their intercalation/deintercalation from the cathode. Such materials activated by disorder are promising candidate cathodes for lithium batteries, and the related mechanism of storage and effective migration of Li-ions also provides new clues for future design of disordered-electrode materials with high capacity and high energy density.

Spectroelectrochemistry of EuCl 3 in Four Molten Salt Eutectics; 3 LiCl−NaCl, 3 LiCl−2 KCl, LiCl−RbCl, and 3 LiCl−2 CsCl; at 873 K

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schroll, Cynthia A.; Chatterjee, Sayandev; Levitskaia, Tatiana

Key electrochemical properties affecting pyroprocessing of nuclear fuel were examined in four eutectic melts using using Eu3+/2+ as a representative probe. We report the electrochemical and spectroelectrochemical behavior of EuCl3 in four molten salt eutectics (3 LiCl – NaCl, 3 LiCl – 2 KCl, LiCl – RbCl and 3 LiCl – 2 CsCl) at 873 K. Cyclic voltammetry was used to determine the redox potential for Eu3+/2+ and the applied potentials for spectroelectrochemistry. Single step chronoabsorptometry and thin-layer spectroelectrochemistry were used to obtain the number of electrons transferred, redox potentials and diffusion coefficients for Eu3+ in each eutectic melt. Themore » redox potentials determined by thin-layer spectroelectrochemistry were extremely close to those obtained using cyclic voltammetry. The redox potential for Eu3+/2+ was most positive in the 3 LiCl - NaCl melt, showed a negative shift in the 3 LiCl - 2 KCl melt, and was the most negative in the LiCl - RbCl and 3 LiCl - 2 CsCl eutectics. The diffusion coefficient for Eu3+ followed this same trend; it was the largest in the 3 LiCl - NaCl melt and the smallest in the LiCl - RbCl and 3 LiCl - 2 CsCl melts. The basic one-electron reversible electron transfer for Eu3+/2+ was not changed by melt composition.« less

THE NEW DETECTIONS OF {sup 7}Li/{sup 6}Li ISOTOPIC RATIO IN THE INTERSTELLAR MEDIA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawanomoto, S.; Kajino, T.; Aoki, W.

We have determined the isotopic abundance ratio of {sup 7}Li/{sup 6}Li in the interstellar media (ISMs) along lines of sight to HD169454 and HD250290 using the High-Dispersion Spectrograph on the Subaru Telescope. We also observed {zeta} Oph for comparison with previous data. The observed abundance ratios were {sup 7}Li/{sup 6}Li = 8.1{sup +3.6} {sub -1.8} and 6.3{sup +3.0} {sub -1.7} for HD169454 and HD250290, respectively. These values are in reasonable agreement with those observed previously in the solar neighborhood ISMs within {+-}2{sigma} error bars and are also consistent with our measurement of {sup 7}Li/{sup 6}Li = 7.1{sup +2.9} {sub -1.6}more » for a cloud along the line of sight to {zeta} Oph. This is good evidence for homogeneous mixing and instantaneous recycling of the gas component in the Galactic disk. We also discuss several source compositions of {sup 7}Li, Galactic cosmic-ray interactions, stellar nucleosynthesis, and big bang nucleosynthesis.« less

Thermal and Cycle-Life Behavior of Commercial Li-ion and Li-Polymer Cells

NASA Technical Reports Server (NTRS)

Zimmerman, Albert H.; Quinzio, M. V.

2001-01-01

Accelerated and real-time LEO cycle-life test data will be presented for a range of commercial Li-ion and Li-polymer (gel type) cells indicating the ranges of performance that can be obtained, and the performance screening tests that must be done to assure long life. The data show large performance variability between cells, as well as a highly variable degradation signature during non-cycling periods within the life tests. High-resolution Dynamic Calorimetry data will be presented showing the complex series of reactions occurring within these Li cells as they are cycled. Data will also be presented for cells being tested using an Adaptive Charge Control Algorithm (ACCA) that continuously adapts itself to changes in cell performance, operation, or environment to both find and maintain the optimum recharge over life. The ACCA has been used to prevent all unneeded overcharge for Li cells, NiCd cells and NiH2 cells. While this is important for all these cell types, it is most critical for Li-ion cells, which are not designed with electrochemical tolerance for overcharge.

Rota-Baxter operators on sl (2,C) and solutions of the classical Yang-Baxter equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pei, Jun, E-mail: peitsun@163.com; Bai, Chengming, E-mail: baicm@nankai.edu.cn; Guo, Li, E-mail: liguo@rutgers.edu

2014-02-15

We explicitly determine all Rota-Baxter operators (of weight zero) on sl (2,C) under the Cartan-Weyl basis. For the skew-symmetric operators, we give the corresponding skew-symmetric solutions of the classical Yang-Baxter equation in sl (2,C), confirming the related study by Semenov-Tian-Shansky. In general, these Rota-Baxter operators give a family of solutions of the classical Yang-Baxter equation in the six-dimensional Lie algebra sl (2,C)⋉{sub ad{sup *}} sl (2,C){sup *}. They also give rise to three-dimensional pre-Lie algebras which in turn yield solutions of the classical Yang-Baxter equation in other six-dimensional Lie algebras.

Li-ion diffusion kinetics in LiCoPO 4 thin films deposited on NASICON-type glass ceramic electrolytes by magnetron sputtering

NASA Astrophysics Data System (ADS)

Xie, J.; Imanishi, N.; Zhang, T.; Hirano, A.; Takeda, Y.; Yamamoto, O.

LiCoPO 4 thin films were deposited on Li 1+ x+ yAl xTi 2- xSi yP 3- yO 12 (LATSP) solid electrolyte by radio frequency magnetron sputtering and were characterized by X-ray diffraction and scanning electron microscope. The films show a (1 1 1) preferred orientation upon annealing and are chemically stable with LATSP up to 600 °C in air. An all-solid-state Li/PEO 18-Li(CF 3SO 2) 2N/LATSP/LiCoPO 4/Au cell was fabricated to investigate the electrochemical performance and Li-ion chemical diffusion coefficients, D˜Li , of the LiCoPO 4 thin films. The potential dependence of D˜Li values of the LiCoPO 4 thin film was investigated by potentiostatic intermittent titration technique and was compared with those of the LiFePO 4 thin film. These results showed that the intercalation mechanism of Li-ion in LiCoPO 4 is different from that in LiFePO 4.

Fast Li-Ion Transport in Amorphous Li 2Si 2O 5: An Ab Initio Molecular Dynamics Simulation

DOE PAGES

Lei, Xueling; Wang, Jie; Huang, Kevin

2016-05-03

The present study reports an ab-initio molecular dynamics (AIMD) simulation of ionic diffusion in the amorphous Li 2Si 2O 5 in a temperature range of 573–823 K. The results show that the amorphous Li 2Si 2O 5 is primarily a Li + conductor with negligible O 2- and Si 4+ contributions. The obtained activation energy of 0.47 eV for Li + diffusion is higher than Na + in the analogue amorphous Na 2Si 2O 5, but close to other types of Li + conductors. The predicted Li + conductivity is on the order of 10 -2 S·cm -1 at 623–823more » K. Our simulations also reveal that Li + in the amorphous Li 2Si 2O 5 diffuses via a hopping mechanism between the nearest sites in the channels formed by two adjacent SiO 4 layers.« less

Synthesis of LiFePO4/Li2SiO3/reduced Graphene Oxide (rGO) Composite via Hydrothermal Method

NASA Astrophysics Data System (ADS)

Arifin, M.; Iskandar, F.; Aimon, A. H.; Munir, M. M.; Nuryadin, B. W.

2016-08-01

LiFePO4 is a type of cathode active material used for lithium ion batteries. It has a high electrochemical performance. However, it suffers from certain disadvantages such as a very low intrinsic electronic conductivity and low ionic diffusion. This study was conducted to increase the conductivity of LiFePO4. We have investigated the addition of Li2SiO3 and reduced graphene oxide (rGO) to LiFePO4. The objective of this research was to synthesize LiFePO4/Li2SiO3/rGO via hydrothermal method. Fourier transform infrared spectroscopy (FTIR) measurement showed that the peaks corresponded to the vibration of LiFePO4/Li2SiO3. Further, X-ray diffraction (XRD) measurement confirmed a single phase of LiFePO4. Finally, scanning electron microscopy (SEM) images showed that rGO was distributed on the LiFePO4/Li2SiO3 structure.

Density functional theory study of lithium diffusion at the interface between olivine-type LiFePO4 and LiMnPO4

NASA Astrophysics Data System (ADS)

Shi, Jianjian; Wang, Zhiguo; Qing Fu, Yong

2016-12-01

Coating LiMnPO4 with a thin layer of LiFePO4 shows a better electrochemical performance than the pure LiFePO4 and LiMnPO4, thus it is critical to understand Li diffusion at their interfaces to improve the performance of electrode materials. Li diffusion at the (1 0 0)\\text{LiFeP{{\\text{O}}4}} //(1 0 0)\\text{LiMnP{{\\text{O}}4}} , (0 1 0)\\text{LiFeP{{\\text{O}}4}} //(0 1 0)\\text{LiMnP{{\\text{O}}4}} , and (0 0 1)\\text{LiFeP{{\\text{O}}4}} //(0 0 1)\\text{LiMnP{{\\text{O}}4}} interfaces between LiFePO4 and LiMnPO4 was investigated using density functional theory. The calculated diffusion energy barriers are 0.55 eV for Li to diffuse along the (0 0 1) interface, 0.44 and 0.49 eV for the Li diffusion inside the LiMnPO4 and along the (1 0 0) interface, respectively. When Li diffuses from the LiFePO4 to LiMnPO4 by passing through the (0 1 0) interfaces, the diffusion barriers are 0.45 and 0.60 eV for the Li diffusions in both sides. The diffusion barriers for Li to diffuse in LiMnPO4 near the interfaces decrease compared with those in the pure LiMnPO4. The calculated diffusion coefficient of Li along the (1 0 0) interface is in the range of 3.65  ×  10-11-5.28  ×  10-12 cm2 s-1, which is larger than that in the pure LiMnPO4 with a value of 7.5  ×  10-14 cm2 s-1. Therefore, the charging/discharging rate performance of the LiMnPO4 can be improved by surface coating with the LiFePO4.

An insight into intrinsic interfacial properties between Li metals and Li10GeP2S12 solid electrolytes.

PubMed

Chen, Bingbing; Ju, Jiangwei; Ma, Jun; Zhang, Jianjun; Xiao, Ruijuan; Cui, Guanglei; Chen, Liquan

2017-11-29

Density functional theory simulations and experimental studies were performed to investigate the interfacial properties, including lithium ion migration kinetics, between lithium metal anode and solid electrolyte Li 10 GeP 2 S 12 (LGPS). The LGPS[001] plane was chosen as the studied surface because the easiest Li + migration pathway is along this direction. The electronic structure of the surface states indicated that the electrochemical stability was reduced at both the PS 4 - and GeS 4 -teminated surfaces. For the interface cases, the equilibrium interfacial structures of lithium metal against the PS 4 -terminated LGPS[001] surface (Li/PS 4 -LGPS) and the GeS 4 -terminated LGPS[001] surface (Li/GeS 4 -LGPS) were revealed based on the structural relaxation and adhesion energy analysis. Solid electrolyte interphases were expected to be formed at both Li/PS 4 -LGPS and Li/GeS 4 -LGPS interfaces, resulting in an unstable state of interface and large interfacial resistance, which was verified by the EIS results of the Li/LGPS/Li cell. In addition, the simulations of the migration kinetics show that the energy barriers for Li + crossing the Li/GeS 4 -LGPS interface were relatively low compared with the Li/PS 4 -LGPS interface. This may contribute to the formation of Ge-rich phases at the Li/LGPS interface, which can tune the interfacial structures to improve the ionic conductivity for future all-solid-state batteries. This work will offer a thorough understanding of the Li/LGPS interface, including local structures, electronic states and Li + diffusion behaviors in all-solid-state batteries.

Dynamic polarizabilities and Van der Waals coefficients for alkali atoms Li, Na and alkali dimer molecules Li2, Na2 and NaLi

NASA Astrophysics Data System (ADS)

Mérawa, M.; Dargelos, A.

1998-07-01

The present paper gives an account of investigations of the polarizability of the alkali atoms Li, Na, diatomics homonuclear and heteronuclear Li2, Na2 and NaLi at SCF (Self Consistent Field) level of approximation and at correlated level, using a time Time-Dependent Gauge Invariant method (TDGI). Our static polarizability values agree with the best experimental and theoretical determinations. The Van der Waals C6 coefficients for the atom-atom, atom-dimer and dimer-dimer interactions have been evaluated. Les polarisabilités des atomes alcalins Li, Na, et des molécules diatomiques homonucléaires et hétéronucléaire Li2, Na2 et NaLi, ont été calculées au niveau SCF (Self Consistent Field) et au niveau corrélé à partir d'une méthode invariante de jauge dépendante du temps(TDGI). Nos valeurs des polarisabilités statiques sont en accord avec les meilleurs déterminations expérimentales et théoriques. Les coefficients C6 de Van de Waals pour les interactions atome-atome, atome-dimère et dimère-dimère ont également été évalués.

Bulk thermal capacity determination for Li/BCX and Li/SOClN2 cells

NASA Technical Reports Server (NTRS)

Kalu, E. E.; White, R. E.; Darcy, E. C.

1992-01-01

The bulk heat capacities of Li/BCX and Li/SOClN2 cells were determined at 0 and 100 percent depth-of-discharge for 2.0 V cut-off voltage, in the temperature range 0 to 60 C by a method that did not involve the destruction of the cell nor the contact of cell with a liquid. The heat capacities are found to be dependent on state-of-charge, increasing with depth-of-discharge. The Li/BCX DD-cell has a lower heat capacity than a high rate Li/SOCl2 D-cell. The results obtained by this method compare favorably well with results reported in the literature through other methods. The bulk heat capacities of the cells did not change significantly in the temperature range 0 to 60 C.

Enabling High Energy Density Li-Ion Batteries through Li{sub 2}O Activation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abouimrane, Ali; Cui, Yanjie; Chen, Zonghai

2016-09-01

Lithium oxide (Li2O) is activated in the presence of a layered composite cathode material (HEM) significantly increasing the energy density of lithium-ion batteries. The degree of activation depends on the current rate, electrolyte salt, and anode type. In full-cell tests, the Li2O was used as a lithium source to counter the first-cycle irreversibility of high-capacity composite alloy anodes. When Li2O is mixed with HEM to serve as a cathode, the electrochemical performance was improved in a full cell having an SiO-SnCoC composite as an anode. The mechanism behind the Li2O activation could also explain the first charge plateau and themore » abnormal high capacity associated with these high energy cathode materials.« less

Chaperone Function in Androgen-Independent Prostate Cancer

DTIC Science & Technology

2012-05-01

differentiation. Proc Natl Acad Sci U S A 92, 11081-11085. Yong, W., Yang, Z., Periyasamy, S., Chen, H., Yucel, S., Li, W., Lin, L. Y., Wolf , I. M., Cohn, M...Biol Chem 282, 5026-5036. Yong, W., Yang, Z., Periyasamy, S., Chen, H., Yucel, S., Li, W., Lin, L. Y., Wolf , I. M., Cohn, M. J., Baskin, L. S., et... Reintroduction of AR into PC-3 cells activates the endogenous FKBP51 gene, an observation that is consistent with AR regulation of FKBP51 expression

Correlation of anisotropy and directional conduction in β-Li 3PS 4 fast Li + conductor

DOE PAGES

Chen, Yan; Cai, Lu; Liu, Zengcai; ...

2015-07-06

Our letter reports the correlation of anisotropy and directional conduction in the fast Li + conductor β-Li 3PS 4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligiblemore » thermal expansion was observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li + conduction channels with incomplete Li occupancy and a flexible connection of LiS 4 and PS 4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li + conductor.« less

Storage and Effective Migration of Li-Ion for Defected β-LiFePO 4 Phase Nanocrystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, Hua; Song, Xiaohe; Zhuo, Zengqing

2016-01-13

Lithium iron phosphate, a widely used cathode material, crystallizes typically in olivine-type phase, α-LiFePO4 (αLFP). However, the new phase β-LiFePO4 (βLFP), which can be transformed from αLFP under high temperature and pressure, is originally almost electrochemically inactive with no capacity for Li-ion battery, because the Li-ions are stored in the tetrahedral [LiO4] with very high activation barrier for migration and the one-dimensional (1D) migration channels for Li-ion diffusion in αLFP disappear, while the Fe ions in the β-phase are oriented similar to the 1D arrangement instead. In this work, using experimental studies combined with density functional theory calculations, we demonstratemore » that βLFP can be activated with creation of effective paths of Li-ion migration by optimized disordering. Thus, the new phase of βLFP cathode achieved a capacity of 128 mAh g–1 at a rate of 0.1 C (1C = 170 mA g–1) with extraordinary cycling performance that 94.5% of the initial capacity retains after 1000 cycles at 1 C. The activation mechanism can be attributed to that the induced disorder (such as FeLiLiFe antisite defects, crystal distortion, and amorphous domains) creates new lithium migration passages, which free the captive stored lithium atoms and facilitate their intercalation/deintercalation from the cathode. Such materials activated by disorder are promising candidate cathodes for lithium batteries, and the related mechanism of storage and effective migration of Li-ions also provides new clues for future design of disordered-electrode materials with high capacity and high energy density.« less

Li-ion transport in all-solid-state lithium batteries with LiCoO 2 using NASICON-type glass ceramic electrolytes

NASA Astrophysics Data System (ADS)

Xie, J.; Imanishi, N.; Zhang, T.; Hirano, A.; Takeda, Y.; Yamamoto, O.

LiCoO 2 thin films were deposited on the NASICON-type glass ceramics, Li 1+ x+ yAl xTi 2- xSi yP 3- yO 12, by radio frequency (RF) magnetron sputtering and were annealed at different temperatures. The as-deposited and the annealed LiCoO 2 thin films were characterized by X-ray diffraction (XRD), Raman spectroscopy and scanning electron microscopy (SEM). It was found that the films exhibited a (1 0 4) preferred orientation after annealing and Co 3O 4 was observed by annealing over 500 °C due to the reaction between the LiCoO 2 and the glass ceramics. The effect of annealing temperature on the interfacial resistance of glass ceramics/LiCoO 2 and Li-ion transport in the bulk LiCoO 2 thin film was investigated by galvanostatic cycling, cyclic voltammetry (CV), potentiostatic intermittent titration technique (PITT) and electrochemical impedance spectroscopy (EIS) with the Li/PEO/glass ceramics/LiCoO 2 cell. The cell performance was limited by the Li-ion diffusion resistance in Ohara/LiCoO 2 interface as well as in bulk LiCoO 2.

Relaxation-phenomena in LiAl/FeS-cells

NASA Astrophysics Data System (ADS)

Borger, W.; Kappus, W.; Panesar, H. S.

A theoretical model of the capacity of strongly relaxing electrochemical systems is applied to the LiAl/FeS system. Relaxation phenomena in LiAl and FeS electrodes can be described by this model. Experimental relaxation data indicate that lithium transport through the alpha-LiAl layer to the particle surface is the capacity limiting process at high discharge current density in the LiAl electrode in LiCl-KCl and LiF-LiCl-LiBr mixtures. Strong relaxation is observed in the FeS electrode with LiCl-KCl electrolyte caused by lithium concentration gradients and precipitation of KCl in the pores.

Classical Yang-Baxter equations and quantum integrable systems

NASA Astrophysics Data System (ADS)

Jurčo, Branislav

1989-06-01

Quantum integrable models associated with nondegenerate solutions of classical Yang-Baxter equations related to the simple Lie algebras are investigated. These models are diagonalized for rational and trigonometric solutions in the cases of sl(N)/gl(N)/, o(N) and sp(N) algebras. The analogy with the quantum inverse scattering method is demonstrated.

From chemistry to mechanics: bulk modulus evolution of Li-Si and Li-Sn alloys via the metallic electronegativity scale.

PubMed

Li, Keyan; Xie, Hui; Liu, Jun; Ma, Zengsheng; Zhou, Yichun; Xue, Dongfeng

2013-10-28

Toward engineering high performance anode alloys for Li-ion batteries, we proposed a useful method to quantitatively estimate the bulk modulus of binary alloys in terms of metallic electronegativity (EN), alloy composition and formula volume. On the basis of our proposed potential viewpoint, EN as a fundamental chemistry concept can be extended to be an important physical parameter to characterize the mechanical performance of Li-Si and Li-Sn alloys as anode materials for Li-ion batteries. The bulk modulus of binary alloys is linearly proportional to the combination of average metallic EN and atomic density of alloys. We calculated the bulk moduli of Li-Si and Li-Sn alloys with different Li concentrations, which can agree well with the reported data. The bulk modulus of Li-Si and Li-Sn alloys decreases with increasing Li concentration, leading to the elastic softening of the alloys, which is essentially caused by the decreased strength of constituent chemical bonds in alloys from the viewpoint of EN. This work provides a deep understanding of mechanical failure of Si and Sn anodes for Li-ion batteries, and permits the prediction of the composition dependent bulk modulus of various lithiated alloys on the basis of chemical formula, metallic EN and cell volume (or alloy density), with no structural details required.

Composite Li metal anode with vertical graphene host for high performance Li-S batteries

NASA Astrophysics Data System (ADS)

Zhang, Y. J.; Liu, S. F.; Wang, X. L.; Zhong, Y.; Xia, X. H.; Wu, J. B.; Tu, J. P.

2018-01-01

Efficient and stable operation of a lithium metal anode has become the enabling factor for next-generation high energy density storage system. Here, vertical graphene (VG) arrays are used as the scaffold structure for high performance Li metal batteries. The melt infusion method is employed to encapsulate Li inside the VG scaffold structure, and the lithiophilic Si layer is coated onto the array surface by magnetron sputtering to assist this melt-infusion process. The porous scaffold structure can control the volume expansion and inhibit the formation of dendritic lithium significantly, leading to the excellent electrochemical performance of the Li composite anode. In addition, the Li-S full batteries with the composite anode display enhanced cycling reversibility.

Li Anode Technology for Improved Performance

NASA Technical Reports Server (NTRS)

Chen, Tuqiang

2011-01-01

A novel, low-cost approach to stabilization of Li metal anodes for high-performance rechargeable batteries was developed. Electrolyte additives are selected and used in Li cell electrolyte systems, promoting formation of a protective coating on Li metal anodes for improved cycle and safety performance. Li batteries developed from the new system will show significantly improved battery performance characteristics, including energy/power density, cycle/ calendar life, cost, and safety.

Pressure-induced ferroelectric to paraelectric transition in LiTaO 3 and (Li,Mg)TaO 3

DOE PAGES

Yamanaka, Takamitsu; Nakamoto, Yuki; Takei, Fumihiko; ...

2016-02-16

X-ray powder diffraction and Raman scattering of LiTaO 3 (LT) and (Li,Mg)TaO 3 (LMT) have been measured under pressure up to 46 GPa. Above 30 GPa, the ferroelectric rhombohedral phase (R3c, Z – 6) of LiTaO 3 transforms to a paraelectric orthorhombic phase (Pnma with Z – 4) with a large hysteresis. Rietveld profile fitting analysis shows that the Li-O bond is compressed and approaches that of Ta-O with pressure. The cation distribution analysis of the orthorhombic perovskite structure shows that Li and Ta are located in the octahedral 8-fold coordination sites. Difference Fourier |F obs(hkl)| - |F cal(hkl)| mapsmore » of LiTaO 3 and (Li,Mg)TaO 3 indicate polarization in the c axis direction and a more distinct electron density distribution around the Ta position for (Li,Mg)TaO 3 compared to LiTaO 3. The observed effective charges indicate that for (Li,Mg)TaO 3 without vacancies Ta 5+ becomes less ionized as a function of Mg substitution. Considering both site occupancy and effective charge analysis, Ta 5+ is reduced to Ta 4.13+. Mg 2+ and O 2- change to Mg 1.643+ and O 1.732 -, respectively. The space- and time-averaged structures of the dynamical vibration of atoms can be elucidated from the electron density analysis by difference Fourier and temperature factors T(hkl) in the structure refinement. The refinement of the temperature factor is consistent with the cation distribution assuming full stoichiometry. The residual electron density induced from the excess electron in (Li,Mg)TaO 3 indicates more electrons around the Ta site, as confirmed by the effective charge analysis. Raman spectra of LiTaO 3 and (Li,Mg)TaO 3 show notable changes over the measured pressure range. Raman peaks centered at 250 cm –1 and 350 cm –1 at ambient pressure merge above 8 GPa, which we associate with the diminishing of difference in distances between Li-O and Ta-O bonds with pressure in both materials. Finally, Raman spectra show significant changes at 28 GPa and 33 GPa for

Composited reduced graphene oxide into LiFePO4/Li2SiO3 and its electrochemical impedance spectroscopy properties

NASA Astrophysics Data System (ADS)

Arifin, M.; Rus, Y. B.; Aimon, A. H.; Iskandar, F.; Winata, T.; Abdullah, M.; Khairurrijal, K.

2017-03-01

LiFePO4 is commonly used as cathode material for Li-ion batteries due to its stable operational voltage and high specific capacity. However, it suffers from certain disadvantages such as low intrinsic electronic conductivity and low ionic diffusion. This study was conducted to analyse the effect of reduced graphene oxide (rGO) on the electrochemical properties of LiFePO4/Li2SiO3 composite. This composite was synthesized by a hydrothermal method. Fourier transform infrared spectroscopy measurement identified the O-P-O, Fe-O, P-O, and O-Si-O- bands in the LiFePO4/Li2SiO3 composite. X-ray diffraction measurement confirmed the formation of LiFePO4. Meanwhile, Raman spectroscopy confirmed the number of rGO layers. Further, scanning electron microscopy images showed that rGO was distributed around the LiFePO4/Li2SiO3 particles. Finally, the electrochemical impedance spectroscopy results showed that the addition of 1 wt% of rGO to the LiFePO4/Li2SiO3 composite reduced charge transfer resistance. It may be concluded that the addition of 1 wt% rGO to LiFePO4/Li2SiO3 composite can enhance its electrochemical performance as a cathode material.

The traditional Chinese medicine prescription patterns for migraine patients in Taiwan: a population-based study.

PubMed

Chang, Yu-Yun; Tsai, Yueh-Ting; Lai, Jung-Nien; Yeh, Chia-Hao; Lin, Shun-Ku

2014-02-12

Traditional Chinese medicine (TCM), when given for symptom relief, has gained widespread popularity among migraine patients. The aim of this study is to analyze the utilization of TCM among migraine patients in Taiwan. The usage, frequency of service, and the Chinese herbal products prescribed for migraine were evaluated using a representative sample of one million subjects selected at random from the 22 million beneficiaries of the National Health Insurance scheme of Taiwan. Overall, 89.3% (N=12,827) migraine patients utilized TCM and 24.2% of them sought TCM with the intention of treating their migraine-related symptoms. Migraine patients who are living in urban area and those with an episodic migraine pattern (<15 days/month) (aOR=3.18, 95% CI: 2.75-3.67) were more likely to be TCM users than those living in a rural area and those who suffered from chronic migraine (≥15 days/month) (aOR=1.00). Overall, 81.2% of TCM visits involved the prescription of a Chinese herbal remedy or remedies and Chuan-Xiong-Cha-Tiao-San, Jia-Wei-Xiao-Yao-San, Ge-Gen-Tang, Xue-Fu-Zhu-Yu-Tang, Ban-Xia-Bai-Zhu-Tian-Ma-Tang, Qing-Shang-Juan-Tong-Tang, Xiao-Chai-Hu-Tang, Tian-Ma-Gou-Teng-Yin, Bu-Zhong-Yi-Qi-Tang, and Tian-Wang-Bu-Xin-Dan were the ten most frequently prescribed formula for treating migraine based on syndrome differentiation. Chuan-Xiong-Cha-Tiao-San, which contains sedative and anti-inflammatory agents, is the most commonly prescribed Chinese herbal formula for the treatment of migraine-related phenomena. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Rechargeable LiNiO2/carbon cells

NASA Astrophysics Data System (ADS)

Dahn, J. R.; von Sacken, U.; Juzkow, M. W.; Al-Janaby, H.

1991-08-01

Rechargeable cells can be made using two different intercalation compounds, in which the chemical potential of the intercalant differs by several eV, for the electrodes. The factors that play a role in the selection of appropriate lithium intercalation compounds for such cells are discussed. For the ease of cell assembly, the cathode should be stable in air when it is fully intercalated, like LiNiO2. For the anode, the chemical potential of the intercalated Li should be close to that of Li metal, like it is in Li(x)C6. The intercalation of Li in LiNiO2 is discussed, and then in petroleum coke. Then, it is shown that LiNiO2/coke cells have high energy density, long cycle life, excellent high-temperature performance, low self-discharge rates, can be repeatedly discharged to zero volts without damage, and are easily fabricated. It is considered that this type of cell shows far more promise for widespread applications than traditional secondary Li cells using metallic Li anodes.

Capturing and Processing Soil GHG Fluxes Using the LI-COR LI-8100A

NASA Astrophysics Data System (ADS)

Xu, Liukang; McDermitt, Dayle; Hupp, Jason; Johnson, Mark; Madsen, Rod

2015-04-01

The LI-COR LI-8100A Automated Soil CO2 Flux System is designed to measure soil CO2 efflux using automated chambers and a non-steady state measurement protocol. While CO2 is an important gas in many contexts, it is not the only gas of interest for many research applications. With some simple plumbing modifications, many third party analyzers capable of measuring other trace gases, e.g. N2O, CH4, or 13CO2 etc., can be interfaced with the LI-8100A System, and LI-COR's data processing software (SoilFluxPro™) can be used to compute fluxes for these additional gases. In this paper we describe considerations for selecting an appropriate third party analyzer to interface with the system, how to integrate data into the system, and the procedure used to compute fluxes of additional gases in SoilFluxPro™. A case study is presented to demonstrate methane flux measurements using an Ultra-Portable Greenhouse Gas Analyzer (Ultra-Portable GGA, model 915-0011), manufactured by Los Gatos Research and integrated into the LI-8100A System. Laboratory and field test results show that the soil CO2 efflux based on the time series of CO2 data measured either with the LI-8100A System or with the Ultra-Portable GGA are essentially the same. This suggests that soil GHG fluxes measured with both systems are reliable.

Li4SiO4-Based Artificial Passivation Thin Film for Improving Interfacial Stability of Li Metal Anodes.

PubMed

Kim, Ji Young; Kim, A-Young; Liu, Guicheng; Woo, Jae-Young; Kim, Hansung; Lee, Joong Kee

2018-03-14

An amorphous SiO 2 (a-SiO 2 ) thin film was developed as an artificial passivation layer to stabilize Li metal anodes during electrochemical reactions. The thin film was prepared using an electron cyclotron resonance-chemical vapor deposition apparatus. The obtained passivation layer has a hierarchical structure, which is composed of lithium silicide, lithiated silicon oxide, and a-SiO 2 . The thickness of the a-SiO 2 passivation layer could be varied by changing the processing time, whereas that of the lithium silicide and lithiated silicon oxide layers was almost constant. During cycling, the surface of the a-SiO 2 passivation layer is converted into lithium silicate (Li 4 SiO 4 ), and the portion of Li 4 SiO 4 depends on the thickness of a-SiO 2 . A minimum overpotential of 21.7 mV was observed at the Li metal electrode at a current density of 3 mA cm -2 with flat voltage profiles, when an a-SiO 2 passivation layer of 92.5 nm was used. The Li metal with this optimized thin passivation layer also showed the lowest charge-transfer resistance (3.948 Ω cm) and the highest Li ion diffusivity (7.06 × 10 -14 cm 2 s -1 ) after cycling in a Li-S battery. The existence of the Li 4 SiO 4 artificial passivation layer prevents the corrosion of Li metal by suppressing Li dendritic growth and improving the ionic conductivity, which contribute to the low charge-transfer resistance and high Li ion diffusivity of the electrode.

Scattering amplitudes in $$\\mathcal{N}=2 $$ Maxwell-Einstein and Yang-Mills/Einstein supergravity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chiodaroli, Marco; Gunaydin, Murat; Johansson, Henrik

We expose a double-copy structure in the scattering amplitudes of the generic Jordan family of N = 2 Maxwell-Einstein and Yang-Mills/Einstein supergravity theories in four and five dimensions. The Maxwell-Einstein supergravity amplitudes are obtained through the color/kinematics duality as a product of two gauge-theory factors; one originating from pure N = 2 super-Yang-Mills theory and the other from the dimensional reduction of a bosonic higher-dimensional pure Yang-Mills theory. We identify a specific symplectic frame in four dimensions for which the on-shell fields and amplitudes from the double-copy construction can be identified with the ones obtained from the supergravity Lagrangian andmore » Feynman-rule computations. The Yang-Mills/Einstein supergravity theories are obtained by gauging a compact subgroup of the isometry group of their Maxwell-Einstein counterparts. For the generic Jordan family this process is identified with the introduction of cubic scalar couplings on the bosonic gauge-theory side, which through the double copy are responsible for the non-abelian vector interactions in the supergravity theory. As a demonstration of the power of this structure, we present explicit computations at treelevel and one loop. Lastly, the double-copy construction allows us to obtain compact expressions for the supergravity superamplitudes, which are naturally organized as polynomials in the gauge coupling constant.« less

Scattering amplitudes in $$\\mathcal{N}=2 $$ Maxwell-Einstein and Yang-Mills/Einstein supergravity

DOE PAGES

Chiodaroli, Marco; Gunaydin, Murat; Johansson, Henrik; ...

2015-01-15

We expose a double-copy structure in the scattering amplitudes of the generic Jordan family of N = 2 Maxwell-Einstein and Yang-Mills/Einstein supergravity theories in four and five dimensions. The Maxwell-Einstein supergravity amplitudes are obtained through the color/kinematics duality as a product of two gauge-theory factors; one originating from pure N = 2 super-Yang-Mills theory and the other from the dimensional reduction of a bosonic higher-dimensional pure Yang-Mills theory. We identify a specific symplectic frame in four dimensions for which the on-shell fields and amplitudes from the double-copy construction can be identified with the ones obtained from the supergravity Lagrangian andmore » Feynman-rule computations. The Yang-Mills/Einstein supergravity theories are obtained by gauging a compact subgroup of the isometry group of their Maxwell-Einstein counterparts. For the generic Jordan family this process is identified with the introduction of cubic scalar couplings on the bosonic gauge-theory side, which through the double copy are responsible for the non-abelian vector interactions in the supergravity theory. As a demonstration of the power of this structure, we present explicit computations at treelevel and one loop. Lastly, the double-copy construction allows us to obtain compact expressions for the supergravity superamplitudes, which are naturally organized as polynomials in the gauge coupling constant.« less

The influence of temperature and salinity on the Li/Ca and d7Li of inorganic and biogenic carbonates

NASA Astrophysics Data System (ADS)

Marriott, C.; Staubwasser, M.; Crompton, R.; Henderson, G.

2003-04-01

Lithium is the sixth most abundant metal in the ocean. It is conservative with a residence time of around 1Ma and has two stable isotopes ^7Li and ^6Li that are not actively involved in biological processes. Isotopic fractionation is observed during incorporation into calcium carbonate but no previous work has systematically examined the controls on this fractionation. We have investigated Li incorporation and isotopic fraction in both inorganically precipitated calcite and coralline aragonite (1). In both cases there is an inverse correlation of Li concentration with temperature and no significant variation in isotopic fractionation. A decrease in D Li/Ca from 0.0092 to 0.0030 is seen over a temperature range of 5--30^oC, whilst an offset of approximately -8.5 ppm is seen in the δ^7Li ratio relative to the growth solution. The temperature dependence of Li/Ca has an increased sensitivity at low temperatures and might therefore be useful in examining changes in bottom water temperature. We are now investigating Li/Ca and δ^7Li of foraminifera. Previous work (2) has suggested little variability in Li/Ca with temperature, although this was for samples from warmer water where Li/Ca is not sensitive. In this study, Uvigerina are examined in a series of core top samples from the Arabian Sea with a depth range of 95--1800m and corresponding temperature range of 5--20^oC. A series of inorganic calcite samples have also been precipitated in order to examine the effect of salinity on Li/Ca, δ^7Li and δ44Ca over a salinity range of 10--50 psu. The distribution coefficient of Li shows a positive correlation with salinity over this range. δ^7Li and δ44Ca measurements for these samples are presently being analysed. (1) Marriott et al., 2002, GCA, 66, A485 (2) Delaney et al., 1985, GCA, 49, 1327

The effect of Li2CO3 substitution on synthesis of LiBOB compounds as salt of electrolyte battery lithium ion

NASA Astrophysics Data System (ADS)

Lestariningsih, Titik; Wigayati, Etty Marty; Sabrina, Qolby; Prihandoko, Bambang; Priyono, Slamet

2018-04-01

Development of the synthesis of LiB(C2O4)2 compounds continues to evolve along with the need for electrolyte salts to support the research of the manufacture of lithium ion batteries. A study had been conducted on the effect of Li2CO3 substitution on the synthesis of LiB(C2O4)2 or LiBOB compounds. LiBOB was a major candidate to replace LiPF6 as a highly toxic lithium battery electrolyte and harmful to human health. Synthesis of Lithium bis(oxalato) borate used powder metallurgy method. The raw materials used are H2C2O4.2H2O, Li2CO3 or LiOH and H2BO3 from Merck Germany products. The materials are mixed with 2: 1: 1 mol ratio until homogeneous. The synthesis of LiBOB refers to previous research, where the heating process was done gradually. The first stage heating is carried out at 120°C for 4 hours, then the next stage heating is carried out at 240°C for 7 hours. The sample variation in this study was to distinguish the lithium source from Li2CO3 and LiOH. Characterization was done by XRD to know the phase formed, FTIR to confirm that functional group of LiB(C2O4)2 compound, SEM to know the morphological structure, and TG/DTA to know the thermal properties. The results of the analysis shows that LiBOB synthesis using Lithium source from Li2CO3 has succeeded to form LiBOB compound with more LiBOB phase composition is 59.1% and 40.9% LiBOB hydrate phase, SEM morphology shows powder consist of elongated round particle porous and similar to LiBOB commercial and show higher thermal stability.

Development of many-body polarizable force fields for Li-battery applications: 2. LiTFSI-doped Oligoether, polyether, and carbonate-based electrolytes.

PubMed

Borodin, Oleg; Smith, Grant D

2006-03-30

A quantum chemistry study of Li(+) interactions with ethers, carbonates, alkanes, and a trifluoromethanesulfonylimide anion (TFSI(-)) was performed at the MP2, B3LYP, and HF levels using the aug-cc-pvDz basis set for solvents and TFSI(-) anion, and [8s4p3d/5s3p2d]-type basis set for Li. A classical many-polarizable force field was developed for the LiTFSI salt interacting with ethylene carbonate (EC), gamma-butyrolactone (GBL), dimethyl carbonate (DMC), acetone, oligoethers, n-alkanes, and perfluoroalkanes. Molecular dynamics (MD) simulations were performed for EC/LiTFSI, PC/LiTFSI, GBL/LiTFSI, DMC/LiTFSI, 1,2-dimethoxyethane/LiTFSI, pentaglyme/LiTFSI, and poly(ethylene oxide) (MW = 2380)/LiTFSI electrolytes at temperatures from 298 to 423 K and salt concentrations from 0.3 to 5 M. The ion and solvent self-diffusion coefficients, electrolyte conductivity, electrolyte density, LiTFSI apparent molar volumes, and structure of the Li(+) cation environment predicted by MD simulations were found in good agreement with experimental data.

Excellent rate capability and cycling stability in Li+-conductive Li2SnO3-coated LiNi0.5Mn1.5O4 cathode materials for lithium-ion batteries.

PubMed

Mou, Jirong; Deng, Yunlong; Song, Zhicui; Zheng, Qiaoji; Lam, Kwok Ho; Lin, Dunmin

2018-05-22

High-voltage LiNi0.5Mn1.5O4 is a promising cathode candidate for lithium-ion batteries (LIBs) due to its considerable energy density and power density, but the material generally undergoes serious capacity fading caused by side reactions between the active material and organic electrolyte. In this work, Li+-conductive Li2SnO3 was coated on the surface of LiNi0.5Mn1.5O4 to protect the cathode against the attack of HF, mitigate the dissolution of Mn ions during cycling and improve the Li+ diffusion coefficient of the materials. Remarkable improvement in cycling stability and rate performance has been achieved in Li2SnO3-coated LiNi0.5Mn1.5O4. The 1.0 wt% Li2SnO3-coated LiNi0.5Mn1.5O4 cathode exhibits excellent cycling stability with a capacity retention of 88.2% after 150 cycles at 0.1 C and rate capability at high discharge rates of 5 C and 10 C, presenting discharge capacities of 119.5 and 112.2 mAh g-1, respectively. In particular, a significant improvement in cycling stability at 55 °C is obtained after the coating of 1.0 wt% Li2SnO3, giving a capacity retention of 86.8% after 150 cycles at 1 C and 55 °C. The present study provides a significant insight into the effective protection of Li-conductive coating materials for a high-voltage LiNi0.5Mn1.5O4 cathode material.

Yang-Mills condensate as dark energy: A nonperturbative approach

NASA Astrophysics Data System (ADS)

Donà, Pietro; Marcianò, Antonino; Zhang, Yang; Antolini, Claudia

2016-02-01

Models based on the Yang-Mills condensate (YMC) have been advocated for in the literature and claimed as successful candidates for explaining dark energy. Several variations on this simple idea have been considered, the most promising of which are reviewed here. Nevertheless, the previously attained results relied heavily on the perturbative approach to the analysis of the effective Yang-Mills action, which is only adequate in the asymptotically free limit, and were extended into a regime, the infrared limit, in which confinement is expected. We show that if a minimum of the effective Lagrangian in θ =-Fμν aFa μ ν/2 exists, a YMC forms that drives the Universe toward an accelerated de Sitter phase. The details of the models depend weakly on the specific form of the effective Yang-Mills Lagrangian. Using nonperturbative techniques mutated from the functional renormalization-group procedure, we finally show that the minimum in θ of the effective Lagrangian exists. Thus, a YMC can actually take place. The nonperturbative model has properties similar to the ones in the perturbative model. In the early stage of the Universe, the YMC equation of state has an evolution that resembles the radiation component, i.e., wy→1 /3 . However, in the late stage, wy naturally runs to the critical state with wy=-1 , and the Universe transitions from a matter-dominated into a dark energy dominated stage only at latest time, at a redshift whose value depends on the initial conditions that are chosen while solving the dynamical system.

Phase transitions in Yang-Mills theories and their gravity duals

NASA Astrophysics Data System (ADS)

Marsano, Joseph Daniel

This thesis is a study of the thermal phase structure of systems that admit dual gauge theory and string theory descriptions. In a pair of examples, we explore the connection between perturbative Yang-Mills and gravitational thermodynamics which arises from the fact that these descriptions probe different corners of a single phase diagram. The structure that emerges from a detailed study of these isolated regions generally suggests a natural conjecture how they may be connected to one another within the full phase diagram. This permits the identification of interesting phenomena in the gauge and gravity regimes under a continuous change in parameters. We begin by studying the AdS5/CFT 4 system which, when the supergravity description is valid, exhibits a first order Hawking-Page phase transition as a function of temperature from a thermal gas of gravitons to a large black hole. In the perturbative Yang-Mills regime, we find that the free theory exhibits a weakly first order deconfinement transition whose precise nature at small nonzero coupling depends on the result of a nontrivial perturbative computation. It is conjectured that this deconfinement transition is continuously connected in the full phase diagram to the Hawking-Page transition at strong coupling, with the confined phase identified with the graviton gas and the deconfined phase identified with the black hole. We then turn to the study of Gregory-Laflamme (GL) black hole/black string transitions in supergravity and their realization in a setup that admits a dual description via the maximally supersymmetric Yang-Mills theory on T2. The thermodynamics of Yang-Mills theories on low dimensional tori is studied in detail revealing an intricate structure of which the GL transition at strong coupling is a small piece. We are led to conjecture that GL physics is continuously connected to deconfinement in maximally supersymmetric 0 + 1-dimensional gauged matrix quantum mechanics. This identification will then

Electrodeposition of Mg-Li-Al-La Alloys on Inert Cathode in Molten LiCl-KCl Eutectic Salt

NASA Astrophysics Data System (ADS)

Han, Wei; Chen, Qiong; Sun, Yi; Jiang, Tao; Zhang, Milin

2011-12-01

Electrochemical preparation of Mg-Li-Al-La alloys on inert electrodes was investigated in LiCl-KCl melt at 853 K (580 °C). Cyclic voltammograms (CVs) and square wave voltammograms (SWVs) show that the existence of AlCl3 or AlF3 could promote La deposition on an active Al substrate, which is predeposited on inert electrodes. All electrochemical tests show that the reduction of La3+ is a one-step reduction process with three electrons exchanged. The reduction of La(III)→La(0) occurred at -2.04 V, and the underpotential deposition (UPD) of La was detected at -1.55 V ( vs Ag/AgCl). The same phenomena concerning La UPD were observed on two inert cathodes, W and Mo. In addition, Mg-Li-Al-La alloys were obtained by galvanostatic electrolysis on the W cathode from La2O3 in LiCl-KCl-MgCl2-KF melts with aluminum as the anode. X-ray diffraction (XRD) measurements indicated that various phases like the Al2La, Al12Mg17, and βLi phase (LiMg/Li3Mg7) existed in the Mg-Li-Al-La alloys. The distribution of Mg, Al, and La in Mg-Li-Al-La alloys from the analysis of a scan electron micrograph (SEM) and energy dispersive spectrometry (EDS) indicated that the elements Mg, Al, and La distributed homogeneously in the alloys.

Electrochemical characteristics of Li/LiMn 2O 4 cells using gel polymer electrolytes

NASA Astrophysics Data System (ADS)

Kim, Dong-Won; Ko, Jang-Myoun; Chun, Jong-Han

Gel polymer electrolytes composed of acrylonitrile-methylmethacrylate (AM) copolymer and 1 M LiClO 4-ethylene carbonate (EC)/propylene carbonate (PC) are prepared. The ionic conductivity reaches 1.9×10 -3 S cm -1 in a gel polymer electrolyte with 20 wt.% of AM copolymer and 80 wt.% of LiClO 4-EC/PC at room temperature. These systems showed no solvent exudation from the matrix polymer due to enhanced compatibility between AM copolymer and organic liquid electrolyte. A Li/gel polymer electrolyte/LiMn 2O 4 cell has a reversible capacity of 132 mAh g -1 in the voltage range of 3.0-4.3 V at the C/5 rate and shows good cycling performance with a coulombic efficiency >99%.

Electronic structure of LiCoO2 thin films: A combined photoemission spectroscopy and density functional theory study

NASA Astrophysics Data System (ADS)

Ensling, David; Thissen, Andreas; Laubach, Stefan; Schmidt, Peter C.; Jaegermann, Wolfram

2010-11-01

The electronic properties of LiCoO2 have been studied by theoretical band-structure calculations (using density functional theory) and experimental methods (photoemission). Synchrotron-induced photoelectron spectroscopy, resonant photoemission spectroscopy (ResPES), and soft x-ray absorption (XAS) have been applied to investigate the electronic structure of both occupied and unoccupied states. High-quality PES spectra were obtained from stoichiometric and highly crystalline LiCoO2 thin films deposited “in situ” by rf magnetron sputtering. An experimental approach of separating oxygen- and cobalt-derived (final) states by ResPES in the valence-band region is presented. The procedure takes advantage of an antiresonant behavior of cobalt-derived states at the 3p-3d excitation threshold. Information about the unoccupied density of states has been obtained by OK XAS. The structure of the CoL absorption edge is compared to semiempirical charge-transfer multiplet calculations. The experimental results are furthermore compared with band-structure calculations considering three different exchange potentials [generalized gradient approximation (GGA), using a nonlocal Hubbard U (GGA+U) and using a hybrid functional (Becke, three-parameter, Lee-Yang-Parr [B3LYP])]. For these different approaches total density of states and partial valence-band density of states have been investigated. The best qualitative agreement with experimental results has been obtained by using a GGA+U functional with U=2.9eV .

Nonperturbative finite-temperature Yang-Mills theory

NASA Astrophysics Data System (ADS)

Cyrol, Anton K.; Mitter, Mario; Pawlowski, Jan M.; Strodthoff, Nils

2018-03-01

We present nonperturbative correlation functions in Landau-gauge Yang-Mills theory at finite temperature. The results are obtained from the functional renormalisation group within a self-consistent approximation scheme. In particular, we compute the magnetic and electric components of the gluon propagator, and the three- and four-gluon vertices. We also show the ghost propagator and the ghost-gluon vertex at finite temperature. Our results for the propagators are confronted with lattice simulations and our Debye mass is compared to hard thermal loop perturbation theory.

Simulation and analysis of stress in a Li-ion battery with a blended LiMn2O4 and LiNi0.8Co0.15Al0.05O2 cathode

NASA Astrophysics Data System (ADS)

Dai, Yiling; Cai, Long; White, Ralph E.

2014-02-01

Stress generation due to Li ion insertion into/extraction from LiMn2O4 particles is studied with a mathematical model for a lithium ion battery with pure LiMn2O4 or mixed LiMn2O4 and LiNi0.8Co0.15Al0.05O2 cathode. The simulated stress profile in a pure LiMn2O4 electrode shows nonuniformity across the positive electrode. The cathode blended model predicts that the stress generated in the LiMn2O4 particles is reduced at the end of discharge due to adding LiNi0.8Co0.15Al0.05O2 to the cathode. The effect of the variation in the blend ratio on the stress generation is also investigated.

Yangians and Yang-Baxter R-operators for ortho-symplectic superalgebras

NASA Astrophysics Data System (ADS)

Fuksa, J.; Isaev, A. P.; Karakhanyan, D.; Kirschner, R.

2017-04-01

Yang-Baxter relations symmetric with respect to the ortho-symplectic superalgebras are studied. We start with the formulation of graded algebras and the linear superspace carrying the vector (fundamental) representation of the ortho-symplectic supergroup. On this basis we study the analogy of the Yang-Baxter operators considered earlier for the cases of orthogonal and symplectic symmetries: the vector (fundamental) R-matrix, the L-operator defining the Yangian algebra and its first and second order evaluations. We investigate the condition for L (u) in the case of the truncated expansion in inverse powers of u and give examples of Lie algebra representations obeying these conditions. We construct the R-operator intertwining two superspinor representations and study the fusion of L-operators involving the tensor product of such representations.

High resolution Li depth profiling of solid state Li ion battery by TERD technique with high energy light ions

NASA Astrophysics Data System (ADS)

Morita, K.; Tsuchiya, B.; Ohnishi, J.; Yamamoto, T.; Iriyama, Y.; Tsuchida, H.; Majima, T.; Suzuki, K.

2018-07-01

Li depth profiles in Au/Si/LiPON/LCO/Au (LCO = LiCoO2, LiPON = Li3.3PO3.8N0.2) thin films battery under charging condition, prepared on self-supporting Al substrate, have been in situ measured by means of transmission elastic recoil detection (TERD) and Rutherford backscattering spectroscopy (RBS) techniques not only with 5.4 MeV He2+ ion beam without absorber, but also 9 MeV O4+ ion beam with Al absorber. In experiments with 5.4 MeV He2+, well-resolved step-wise TERD spectra have been observed, from which thickness and Li composition of constituent films of the battery are directly estimated. The Li transport from LCO to Si films through LiPON as well as return-back of Li from Si to LCO films and Li leakage into the Al substrate out of the battery system by over-charging under charging condition have been observed in the experiments both 5.4 MeV He2+ and 9 MeV O4+. The latter result indicates that these techniques are applicable to testing degradation of the battery performance by repetition of charging and discharging. Both results are compared in details with each other.

Chen Ning Yang, Weak Interactions, and Parity Violation

Science.gov Websites

absolute law of parity conservation had been violated." 2 "Yang overturned Paul ... Dirac's explained that symmetry laws generate the law of conservation. The law of right-left symmetry contributed to the formulation of the law of conservation of parity in 1924. Eventually, this law of conservation was

Radiation and Thermal Transformations of Hydrogen Defects in Li6F and LiF:OH

NASA Astrophysics Data System (ADS)

Akhvlediani, Z. G.; Akhvlediani, I. G.

2010-11-01

Hydrogen and tritium defects formed in LiF under the action of neutron radiation under different conditions have been studied. It is shown that U-centers are registered in LiF:OH without additional heating of the sample after irradiation. The behavior of H0 and T0 atoms in Li6 F irradiated at 20 K was studied, and the places of their stabilization were established.

On the thermal behavior of model Li-Li xCoO 2 systems containing ionic liquids in standard electrolyte solutions

NASA Astrophysics Data System (ADS)

Larush, L.; Borgel, V.; Markevich, E.; Haik, O.; Zinigrad, E.; Aurbach, D.; Semrau, G.; Schmidt, M.

We report herein on the possibility of using ionic liquids (ILs) as additives to conventional electrolyte solutions, based on alkyl carbonates and LiPF 6 for attenuating thermal reactions in Li battery systems. As a model, a Li-Li 0.5CoO 2 system was used. The ionic liquids chosen included cations based on derivatives of pyrrolidinium and imidazolium, and the anions bioxalato borate (C 4O 8B -, BOB), (CH 3SO 2) 2N - (TFSI), and PF 3(C 2S 5) 3 - (FAP). The thermal behavior of solutions alone, solutions with Li metal, Li 0.5CoO 2 and Li metal + Li 0.5CoO 2 was studied. It was found that the presence of 10% of ILs, with derivatives of pyrrolidinium cations and FAP or TFSI anions in standard EC-DMC/LiPF 6 solutions, improves considerably the thermal stability of Li 0.5CoO 2 in electrolyte solutions. The onset temperatures of the thermal reactions of Li 0.5CoO 2 with solution species are higher and their heat evolution is considerably lower, when they contain these ionic liquids as additives. This finding opens the door for further studies and optimization of the use of selected ILs as additives that may improve the safety features of Li-ion batteries.

Li-adsorption on doped Mo2C monolayer: A novel electrode material for Li-ion batteries

NASA Astrophysics Data System (ADS)

Mehta, Veenu; Tankeshwar, K.; Saini, Hardev S.

2018-04-01

A first principle calculation has been used to study the electronic and magnetic properties of pristine and N/Mn-doped Mo2C with and without Li-adsorption. The pseudopotential method implemented in SIESTA code based on density functional theory with generalized gradient approximation (GGA) as exchange-correlation (XC) potential has been employed. Our calculated results revealed that the Li gets favorably adsorbed on the hexagonal centre in pristine Mo2C and at the top of C-atom in case of N/Mn-doped Mo2C. The doping of Mn and N atom increases the adsorption of Li in Mo2C monolayer which may results in enhancement of storage capacity in Li-ion batteries. The metallic nature of Li-adsorbed pristine and N/Mn-doped Mo2C monolayer implies a good electronic conduction which is crucial for anode materials for its applications in rechargeable batteries. Also, the open circuit voltage for single Li-adsorption in doped Mo2C monolayer comes in the range of 0.4-1.0 eV which is the optimal range for any material to be used as an anode material. Our result emphasized the enhanced performance of doped Mo2C as an anode material in Li-ion batteries.

Yangian Symmetry and Integrability of Planar N=4 Supersymmetric Yang-Mills Theory.

PubMed

Beisert, Niklas; Garus, Aleksander; Rosso, Matteo

2017-04-07

In this Letter, we establish Yangian symmetry of planar N=4 supersymmetric Yang-Mills theory. We prove that the classical equations of motion of the model close onto themselves under the action of Yangian generators. Moreover, we propose an off-shell extension of our statement, which is equivalent to the invariance of the action and prove that it is exactly satisfied. We assert that our relationship serves as a criterion for integrability in planar gauge theories by explicitly checking that it applies to the integrable Aharony-Bergman-Jafferis-Maldacena theory but not to the nonintegrable N=1 supersymmetric Yang-Mills theory.

Lost in Translation (LiT)

PubMed Central

Dollery, Colin T

2014-01-01

Translational medicine is a roller coaster with occasional brilliant successes and a large majority of failures. Lost in Translation 1 (‘LiT1’), beginning in the 1950s, was a golden era built upon earlier advances in experimental physiology, biochemistry and pharmacology, with a dash of serendipity, that led to the discovery of many new drugs for serious illnesses. LiT2 saw the large-scale industrialization of drug discovery using high-throughput screens and assays based on affinity for the target molecule. The links between drug development and university sciences and medicine weakened, but there were still some brilliant successes. In LiT3, the coverage of translational medicine expanded from molecular biology to drug budgets, with much greater emphasis on safety and official regulation. Compared with R&D expenditure, the number of breakthrough discoveries in LiT3 was disappointing, but monoclonal antibodies for immunity and inflammation brought in a new golden era and kinase inhibitors such as imatinib were breakthroughs in cancer. The pharmaceutical industry is trying to revive the LiT1 approach by using phenotypic assays and closer links with academia. LiT4 faces a data explosion generated by the genome project, GWAS, ENCODE and the ‘omics’ that is in danger of leaving LiT4 in a computerized cloud. Industrial laboratories are filled with masses of automated machinery while the scientists sit in a separate room viewing the results on their computers. Big Data will need Big Thinking in LiT4 but with so many unmet medical needs and so many new opportunities being revealed there are high hopes that the roller coaster will ride high again. PMID:24428732

The Use of Redox Mediators for Enhancing Utilization of Li2S Cathodes for Advanced Li-S Battery Systems.

PubMed

Meini, Stefano; Elazari, Ran; Rosenman, Ariel; Garsuch, Arnd; Aurbach, Doron

2014-03-06

The development of Li2S electrodes is a crucial step toward industrial manufacturing of Li-S batteries, a promising alternative to Li-ion batteries due to their projected two times higher specific capacity. However, the high voltages needed to activate Li2S electrodes, and the consequent electrolyte solution degradation, represent the main challenge. We present a novel concept that could make feasible the widespread application of Li2S electrodes for Li-S cell assembly. In this concept, the addition of redox mediators as additives to the standard electrolyte solution allows us to recover most of Li2S theoretical capacity in the activation cycle at potentials as low as 2.9 VLi, substantially lower than the typical potentials >4 VLi needed with standard electrolyte solution. Those novel additives permit us to preserve the electrolyte solution from being degraded, allowing us to achieve capacity as high as 500 mAhg(-1)Li2S after 150 cycles with no major structural optimization of the electrodes.

Xiao Yao San Improves Depressive-Like Behaviors in Rats with Chronic Immobilization Stress through Modulation of Locus Coeruleus-Norepinephrine System.

PubMed

Ding, Xiu-Fang; Zhao, Xiao-Hua; Tao, Yang; Zhong, Wei-Chao; Fan, Qin; Diao, Jian-Xin; Liu, Yuan-Liang; Chen, Yu-Yao; Chen, Jia-Xu; Lv, Zhi-Ping

2014-01-01

Most research focuses on the hypothalamic-pituitary-adrenal (HPA) axis, hypothalamus-pituitary-thyroid (HPT) axis, and hypothalamus-pituitary-gonadal (HPGA) axis systems of abnormalities of emotions and behaviors induced by stress, while no studies of Chinese herbal medicine such as Xiao Yao San (XYS) on the mechanisms of locus coeruleus-norepinephrine (LC-NE) system have been reported. Therefore, experiments were carried out to observe mechanism of LC-NE system in response to chronic immobilization stress (CIS) and explore the antidepressant effect of XYS. Rat model was established by CIS. LC morphology in rat was conducted. The serum norepinephrine (NE) concentrations and NE biosynthesis such as tyrosine hydroxylase (TH), dopamine-β-hydroxylase (DBH), and corticotrophin-releasing-factor (CRF) in LC were determined. Results showed that there were no discernible alterations in LC in rats. The serum NE concentrations, positive neurons, mean optical density (MOD), and protein levels of TH, DBH, and CRF in model group were significantly increased compared to the control group. But XYS-treated group displayed a significantly decreased in NE levels and expressions of TH, DBH, and CRF compared to the model group. In conclusion, CIS can activate LC-NE system to release NE and then result in a significant decrease in rats. XYS treatment can effectively improve depressive-like behaviors in rats through inhibition of LC-NE neurons activity.

Serum metabonomics study of anti-depressive effect of Xiao-Chai-Hu-Tang on rat model of chronic unpredictable mild stress.

PubMed

Xiong, Zhili; Yang, Jie; Huang, Yue; Zhang, Kuo; Bo, Yunhai; Lu, Xiumei; Su, Guangyue; Ma, Jie; Yang, Jingyu; Zhao, Longshan; Wu, Chunfu

2016-09-01

Xiao-Chai-Hu-Tang (XCHT) has been proven to be effective for the clinical treatment of depression. However, the mechanisms of definite antidepressant-like effects and detailed metabolic biomarkers were still unclear in this prior study. Here, we have investigated the metabolic profiles and potential biomarkers in a chronic unpredictable mild stress model after treatment with XCHT. Metabonomics based on ultra-high performance liquid chromatography coupled with mass spectrometry was used to profile the metabolic fingerprints of serum obtained from a rat model with chronic unpredictable mild stress with and without XCHT treatment. The model rats showed a significant decrease in sucrose preference and food consumption, and these depression-like symptoms were significantly improved by XCHT. Through principal component analysis (PCA), nine potential biomarkers of tryptophan, uric acid, phenylalanine, cholic acid and lysophosphatidylcholine (C18:0 LPC, C16:0 LPC, C16:1 LPC, C18:1 LPC, C20:4 LPC) were characterized as potential biomarkers involved the pathogenesis of depression. The therapeutic effect of XCHT on depression may involve in amino acid metabolism, lipid metabolism, oxidative stress and inflammation response. The present investigation highlights that metabonomics is a valuable tool for studying the essence of depression as well as evaluating the efficacy of the corresponding drug treatment. Copyright © 2016 Elsevier B.V. All rights reserved.

Xiao Yao San Improves Depressive-Like Behaviors in Rats with Chronic Immobilization Stress through Modulation of Locus Coeruleus-Norepinephrine System

PubMed Central

Ding, Xiu-Fang; Zhao, Xiao-Hua; Tao, Yang; Zhong, Wei-Chao; Fan, Qin; Diao, Jian-Xin; Liu, Yuan-Liang; Chen, Yu-Yao; Chen, Jia-Xu; Lv, Zhi-Ping

2014-01-01

Most research focuses on the hypothalamic-pituitary-adrenal (HPA) axis, hypothalamus-pituitary-thyroid (HPT) axis, and hypothalamus-pituitary-gonadal (HPGA) axis systems of abnormalities of emotions and behaviors induced by stress, while no studies of Chinese herbal medicine such as Xiao Yao San (XYS) on the mechanisms of locus coeruleus-norepinephrine (LC-NE) system have been reported. Therefore, experiments were carried out to observe mechanism of LC-NE system in response to chronic immobilization stress (CIS) and explore the antidepressant effect of XYS. Rat model was established by CIS. LC morphology in rat was conducted. The serum norepinephrine (NE) concentrations and NE biosynthesis such as tyrosine hydroxylase (TH), dopamine-β-hydroxylase (DBH), and corticotrophin-releasing-factor (CRF) in LC were determined. Results showed that there were no discernible alterations in LC in rats. The serum NE concentrations, positive neurons, mean optical density (MOD), and protein levels of TH, DBH, and CRF in model group were significantly increased compared to the control group. But XYS-treated group displayed a significantly decreased in NE levels and expressions of TH, DBH, and CRF compared to the model group. In conclusion, CIS can activate LC-NE system to release NE and then result in a significant decrease in rats. XYS treatment can effectively improve depressive-like behaviors in rats through inhibition of LC-NE neurons activity. PMID:25610478

Xiao-Yao-San, a Chinese Medicine Formula, Ameliorates Chronic Unpredictable Mild Stress Induced Polycystic Ovary in Rat

PubMed Central

Sun, Hao-Yu; Li, Quan; Liu, Yu-Ying; Wei, Xiao-Hong; Pan, Chun-Shui; Fan, Jing-Yu; Han, Jing-Yan

2017-01-01

Chronic stress induces endocrine disturbance, which contributes to the development of polycystic ovary syndrome (PCOS), a condition that remains a challenge for clinicians to cope with. The present study investigated the effect of Xiao-Yao-San (XYS), a traditional Chinese medicine formula used for treatment of gynecological disease, on the chronic stress-induced polycystic ovary and its underlying mechanism. Female Sprague-Dwaley rats underwent a 3 weeks chronic unpredictable mild stress (CUMS) procedure to establish the PCOS model, followed by 4 weeks treatment with XYS (0.505 g/kg or 1.01 g/kg) by gavage. Granulosa cells were exposed to noradrenaline (1 mM) in vitro for 24 h, followed by incubation with or without XYS-treated rat serum for 24 h. Post-treatment with XYS ameliorated CUMS-induced irregular estrous cycles and follicles development abnormalities, decrease of estradiol and progesterone level as well as increase of luteinizing hormone in serum, reduced cystic follicles formation and the apoptosis and autophagy of granulosa cells, attenuated the increase in dopamine beta hydroxylase and c-fos level in locus coeruleus, the noradrenaline level in serum and ovarian tissue, and the expression of beta 2 adrenergic receptor in ovarian tissue. Besides, XYS alleviated the reduction of phosphorylation of ribosomal protein S6 kinase polypeptide I and protein kinase B, as well as the increase of microtubule-associated protein light chain 3-I to microtubule-associated protein light chain 3-II conversion both in vivo and in vitro. This study demonstrated XYS as a potential strategy for CUMS induced polycystic ovary, and suggested that the beneficial role of XYS was correlated with the regulation of the sympathetic nerve activity. PMID:29018356

Dopant occupancy and exposure energy in Hf:Nd:LiNbO3 crystal as a function of [Li]/[Nb] ratios

NASA Astrophysics Data System (ADS)

Dai, Li; Liu, Chunrui; Han, Xianbo; Yan, Zhehua; Tan, Chao; Wang, Luping; Xu, Yuheng

2017-09-01

A series of Hf: Nd: LiNbO3 crystals with various [Li]/[Nb] ratios ([Li]/[Nb] = 0.94, 1.05, 1.20, 1.38) in the melt were grown by conventional Czochralski technique. The distribution coefficients of Hf4+ and Nd3+ ions were recorded by an inductively coupled plasma-atomic emission spectrometer (ICP-AES). The effective distribution coefficient of Hf4+ is reduced and that of Nd3+ is increased with the increase of [Li]/[Nb] ratio in the melts. In all cases, the effective distribution coefficients is less than 1. The IR transmission spectroscopy of the Hf: Nd: LiNbO3 crystals were measured, getting the results that Hf: Yb: Ho: LiNbO3 crystals with 1.05 [Li]/[Nb] ratios was the stoichiometric. The optical damage resistance ability of Hf:Nd:LiNbO3 crystals were studied by light-induced scattering exposure energy flux threshold method and it increases with the increasing of [Li]/[Nb] ratios. When the [Li]/[Nb] ratio is 1.38 in the melt (the sample 4#), the exposure energy achieves 687.35 J/cm2, approximately 441 folds than that of the sample 1# ([Li]/[Nb] = 0.94) in magnitude.

Data mining of molecular dynamics data reveals Li diffusion characteristics in garnet Li7La3Zr2O12

NASA Astrophysics Data System (ADS)

Chen, Chi; Lu, Ziheng; Ciucci, Francesco

2017-01-01

Understanding Li diffusion in solid conductors is essential for the next generation Li batteries. Here we show that density-based clustering of the trajectories computed using molecular dynamics simulations helps elucidate the Li diffusion mechanism within the Li7La3Zr2O12 (LLZO) crystal lattice. This unsupervised learning method recognizes lattice sites, is able to give the site type, and can identify Li hopping events. Results show that, while the cubic LLZO has a much higher hopping rate compared to its tetragonal counterpart, most of the Li hops in the cubic LLZO do not contribute to the diffusivity due to the dominance of back-and-forth type jumps. The hopping analysis and local Li configuration statistics give evidence that Li diffusivity in cubic LLZO is limited by the low vacancy concentration. The hopping statistics also shows uncorrelated Poisson-like diffusion for Li in the cubic LLZO, and correlated diffusion for Li in the tetragonal LLZO in the temporal scale. Further analysis of the spatio-temporal correlation using site-to-site mutual information confirms the weak site dependence of Li diffusion in the cubic LLZO as the origin for the uncorrelated diffusion. This work puts forward a perspective on combining machine learning and information theory to interpret results of molecular dynamics simulations.

Y-doped Li 8ZrO 6: A Li-Ion Battery Cathode Material with High Capacity

DOE PAGES

Huang, Shuping; Wilson, Benjamin E.; Wang, Bo; ...

2015-08-11

We study—experimentally and theoretically—the energetics, structural changes, and charge flows during the charging and discharging processes for a new high-capacity cathode material, Li 8ZrO 6 (LZO), which we study both pure and yttrium-doped. We quantum mechanically calculated the stable delithiated configurations, the delithiation energy, the charge flow during delithiation, and the stability of the delithiated materials. We find that Li atoms are easier to extract from tetrahedral sites than octahedral ones. We calculate a large average voltage of 4.04 eV vs Li/Li + for delithiation of the first Li atom in a primitive cell, which is confirmed by galvanostatic charge/dischargemore » cycling data. Energy calculations indicate that topotactic delithiation is kinetically favored over decomposition into Li, ZrO 2, and O 2 during the charging process, although the thermodynamic energy of the topotactic reaction is less favorable. When one or two lithium atoms are extracted from a primitive cell of LZO, its volume and structure change little, whereas extraction of the third lithium greatly distorts the layered structure. The Li 6ZrO 6 and Li 5ZrO 6 delithiation products can be thermodynamically metastable to release of O 2. Experimentally, materials with sufficiently small particle size for efficient delithiation and relithiation were achieved within an yttrium-doped LZO/carbon composite cathode that exhibited an initial discharge capacity of at least 200 mAh/g over the first 10 cycles, with 142 mAh/g maintained after 60 cycles. Computations predict that during the charging process, the oxygen ion near the Li vacancy is oxidized for both pure LZO and yttrium-doped LZO, which leads to a small-polaron hole.« less

Y-doped Li 8ZrO 6: A Li-Ion Battery Cathode Material with High Capacity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Shuping; Wilson, Benjamin E.; Wang, Bo

We study—experimentally and theoretically—the energetics, structural changes, and charge flows during the charging and discharging processes for a new high-capacity cathode material, Li 8ZrO 6 (LZO), which we study both pure and yttrium-doped. We quantum mechanically calculated the stable delithiated configurations, the delithiation energy, the charge flow during delithiation, and the stability of the delithiated materials. We find that Li atoms are easier to extract from tetrahedral sites than octahedral ones. We calculate a large average voltage of 4.04 eV vs Li/Li + for delithiation of the first Li atom in a primitive cell, which is confirmed by galvanostatic charge/dischargemore » cycling data. Energy calculations indicate that topotactic delithiation is kinetically favored over decomposition into Li, ZrO 2, and O 2 during the charging process, although the thermodynamic energy of the topotactic reaction is less favorable. When one or two lithium atoms are extracted from a primitive cell of LZO, its volume and structure change little, whereas extraction of the third lithium greatly distorts the layered structure. The Li 6ZrO 6 and Li 5ZrO 6 delithiation products can be thermodynamically metastable to release of O 2. Experimentally, materials with sufficiently small particle size for efficient delithiation and relithiation were achieved within an yttrium-doped LZO/carbon composite cathode that exhibited an initial discharge capacity of at least 200 mAh/g over the first 10 cycles, with 142 mAh/g maintained after 60 cycles. Computations predict that during the charging process, the oxygen ion near the Li vacancy is oxidized for both pure LZO and yttrium-doped LZO, which leads to a small-polaron hole.« less

Factors Affecting Domestic Water Consumption in Rural Households upon Access to Improved Water Supply: Insights from the Wei River Basin, China

PubMed Central

Fan, Liangxin; Liu, Guobin; Wang, Fei; Geissen, Violette; Ritsema, Coen J.

2013-01-01

Comprehensively understanding water consumption behavior is necessary to design efficient and effective water use strategies. Despite global efforts to identify the factors that affect domestic water consumption, those related to domestic water use in rural regions have not been sufficiently studied, particularly in villages that have gained access to improved water supply. To address this gap, we investigated 247 households in eight villages in the Wei River Basin where three types of improved water supply systems are implemented. Results show that domestic water consumption in liters per capita per day was significantly correlated with water supply pattern and vegetable garden area, and significantly negatively correlated with family size and age of household head. Traditional hygiene habits, use of water appliances, and preference for vegetable gardening remain dominant behaviors in the villages with access to improved water supply. Future studies on rural domestic water consumption should pay more attention to user lifestyles (water appliance usage habits, outdoor water use) and cultural backgrounds (age, education). PMID:23977190

Factors affecting domestic water consumption in rural households upon access to improved water supply: insights from the Wei River Basin, China.

PubMed

Fan, Liangxin; Liu, Guobin; Wang, Fei; Geissen, Violette; Ritsema, Coen J

2013-01-01

Comprehensively understanding water consumption behavior is necessary to design efficient and effective water use strategies. Despite global efforts to identify the factors that affect domestic water consumption, those related to domestic water use in rural regions have not been sufficiently studied, particularly in villages that have gained access to improved water supply. To address this gap, we investigated 247 households in eight villages in the Wei River Basin where three types of improved water supply systems are implemented. Results show that domestic water consumption in liters per capita per day was significantly correlated with water supply pattern and vegetable garden area, and significantly negatively correlated with family size and age of household head. Traditional hygiene habits, use of water appliances, and preference for vegetable gardening remain dominant behaviors in the villages with access to improved water supply. Future studies on rural domestic water consumption should pay more attention to user lifestyles (water appliance usage habits, outdoor water use) and cultural backgrounds (age, education).

Simulation of First-Charge Oxygen-Dimerization and Mn-Migration in Li-Rich Layered Oxides xLi 2MnO 3 ·(1 – x )Li MO 2 and Implications for Voltage Fade

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benedek, Roy; Iddir, Hakim

The instabilities of Li-rich layered oxide xLi 2MnO 3•(1-x)LiMO 2 (lithium-ion-battery cathode materials) during the first charge are investigated using first-principles dynamical simulation. To complement our earlier simulations for (x = 0.4, M = Ni 0.5Mn 0.5), we address here: pure Li 2MnO 3; small x; M compositions that include Co; a composite with Co spinel: Li 2MnO 3•Li 2M 2O 4; a Li 2MnO 3 slab. Lastly, we discuss how the threshold fraction f of Li 2(1-f)MnO 3 delithiation at which instabilities occur at the surface, fth(surface), differs from that in the bulk, f th(bulk). Approaches to inhibit voltagemore » fade are discussed.« less

Simulation of First-Charge Oxygen-Dimerization and Mn-Migration in Li-Rich Layered Oxides xLi 2MnO 3 ·(1 – x )Li MO 2 and Implications for Voltage Fade

DOE PAGES

Benedek, Roy; Iddir, Hakim

2017-03-08

The instabilities of Li-rich layered oxide xLi 2MnO 3•(1-x)LiMO 2 (lithium-ion-battery cathode materials) during the first charge are investigated using first-principles dynamical simulation. To complement our earlier simulations for (x = 0.4, M = Ni 0.5Mn 0.5), we address here: pure Li 2MnO 3; small x; M compositions that include Co; a composite with Co spinel: Li 2MnO 3•Li 2M 2O 4; a Li 2MnO 3 slab. Lastly, we discuss how the threshold fraction f of Li 2(1-f)MnO 3 delithiation at which instabilities occur at the surface, fth(surface), differs from that in the bulk, f th(bulk). Approaches to inhibit voltagemore » fade are discussed.« less

Quantum supergroups and solutions of the Yang-Baxter equation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bracken, A.J.; Gould, M.D.; Zhang, R.B.

1990-05-10

A method is developed for systematically constructing trigonometric and rational solutions of the Yang-Baxter equation using the representation theory of quantum supergroups. New quantum R-matrices are obtained by applying the method to the vector representations of quantum osp(1/2) and gl(m/n).

The crystalline phases present in carbon cathodes of discharged Li/SOCl/sub 2/-LiAlCl/sub 4/ cells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Williams, R.M.; Surampudi, S.; Bankston, C.P.

1989-05-01

The authors describe the x-ray diffraction patterns of 100% discharged Schawinigan black cathodes from Li/SOCl/sub 2-/LiAlCl/sub 4/ cells obtained using a high resolution Guinier camera. The previous assignments of the diffraction lines to Li/sub 2/O/sub 2/ and rhombohedral sulfur are all found to be incorrect; all sharp Bragg diffraction lines not assignable to anhydrous LiCl can be assigned to LiCl1 . H/sub 2/O.

Some optical properties of KTP, LiIO3, and LiNbO3

NASA Technical Reports Server (NTRS)

Gettemy, Donald J.; Harker, William C.; Lindholm, Glenn; Barnes, Norman P.

1988-01-01

Measurements of the absorption coefficient for KTP, LiIO3, and LiNbO3 are discussed. The variation of the refractive index with temperature has been measured for KTP and LiIO3. It is necessary to know both the absorption coefficient beta and the variation in the indexes of refraction with temperature change dn/dT to determine the average power limit of a nonlinear interaction. With the dn/dT information, it is also possible to estimate the temperature half width of any nonlinear interaction by calculating the variation of the phase-matching condition with temperature.

Is Traditional Chinese medicine effective for reducing hyperthyroidism?

PubMed

Chang, Cheng-Chieh; Huang, Sheng-Teng

2010-11-01

Graves' disease is an autoimmune disease that can affect a few patients with hyperthyroidism. In this case report, we demonstrated that Traditional Chinese Medicine (TCM) was effective for the patient with hyperthyroidism induced by Graves' disease. The patient also remained in the euthyroid state for several years after the treatment. SUBJECT AND SETTING: A 33-year-old woman had palpitations, fatigability, and weight loss and was diagnosed as having Graves' disease. Urticaria and itching skin appeared after she took an antithyroid drug. Therefore, she sought treatment with TCM. After regular therapy with Jia Wei Xiao Yao San in addition to Xia Ku Cao, Bei Mu, and oyster shell, her symptoms subsided and the thyroid function level returned to normal range with 3 years' treatment. She still remained in the euthyroid state for 3 years after discontinuing the TCM treatment up to the present. Neither complications nor side-effects were noted during the TCM treatment. This case demonstrates that TCM is an effective and alternative option for hyperthyroidism induced by Graves' disease, especially for patients who have an allergic reaction caused by thioamides.

A reporter gene assay for the detection of phytoestrogens in traditional Chinese medicine.

PubMed

Miller-Martini, D M; Chan, R Y; Ip, N Y; Sheu, S J; Wong, Y H

2001-09-01

Bupleurum & Peony Formula (Jia Wei Xiao Yao San) is a herbal formula which possesses a clinical history for the treatment of menopausal syndrome and menstrual irregularity. The present investigation reports the ability to monitor the formula's phytoestrogen content that will allow for the implementation of a standardization protocol that is based on a quantifiable biological response. Utilizing an oestrogen-sensitive chimeric receptor/reporter gene element which has been stably transfected into HeLa cells, the botanical formula was shown to induce the expression of the reporter gene, luciferase, in a dose dependent manner. Pretreatment of the HeLa cells with the botanical formula produced a 5-fold increase in bioluminescence compared with the control. Additionally, our studies showed that the response of the cells, when challenged by the botanical formula, was oestrogen specific. Pretreatment of the cells with tamoxifen effectively blocked the activation of the chimeric oestrogen receptor by the botanical formula. The cell line provides a sensitive assay that can easily detect the presence of phytoestrogens in complex botanical formulas. Copyright 2001 John Wiley & Sons, Ltd.

GL/sub 3/-invariant solutions of the Yang-Baxter equation and associated quantum systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kulish, P.P.; Reshetikhin, N.Yu.

1987-05-20

The authors investigate the GL/sub 3/-invariant finite-dimensional solutions of the Yang-Baxter equation acting in the tensor product of two irreducible representations of the GL/sub 3/ group. Relationships obtained for the transfer matrices demonstrate the link between representation theory and the Bethe ansatz in GL/sub 3/-invariant models. Some examples of quantum and classical integrable systems associated with GL/sub 3/-invariant solutions of the Yang-Baxter equation are given.

Synthesis and optical characterization of LiKB4O7, Li2B6O10, and LiCsB6O10 glasses.

PubMed

Adamiv, V; Teslyuk, I; Dyachok, Ya; Romanyuk, G; Krupych, O; Mys, O; Martynyuk-Lototska, I; Burak, Ya; Vlokh, R

2010-10-01

In the current work we report on the synthesis of LiKB(4)O(7), Li(2)B(6)O(10), and LiCsB(6)O(10) borate glasses. The results for their piezo-optic, acousto-optic, acoustic, elastic, refractive, optical transmission, and optical resistance properties are also presented. It is shown that some of these glasses represent efficient acousto-optic materials that are transparent down to the vacuum ultraviolet range and highly resistant to laser radiation.

Electrochemical Codeposition of Al-Li-Mg Alloys at Solid Aluminum Electrode from LiCl-KCl-MgCl2 Molten Salt System

NASA Astrophysics Data System (ADS)

Ye, Ke; Zhang, Mi Lin; Chen, Ye; Han, Wei; de Yan, Yong; Cao, Peng

2010-06-01

The electrochemical codeposition of Mg and Li at an aluminium electrode in LiCl-KCl (50:50 wt pct) melts containing different concentrations of MgCl2 at 893 K (620 °C) to form Al-Li-Mg alloys was investigated. Cyclic voltammograms showed that the potential of Li metal deposition at an Al electrode, before the addition of MgCl2, is more positive than that of Li metal deposition at an Mo electrode, which indicated the formation of an Al-Li alloy. The underpotential deposition of magnesium at an aluminium electrode leads to the formation of Al-Mg alloys, and the succeeding underpotential deposition of lithium on predeposited Al-Mg alloys leads to the formation of Al-Li-Mg alloys. Chronopotentiometric measurements indicated that the codeposition of Mg and Li occurs at current densities lower than -0.668 A cm-2 in LiCl-KCl-MgCl2 (8 wt pct) melts at an aluminium electrode. The chronoamperometric studies indicated that the onset potential for the codeposition of Mg and Li is -2.000 V, and the codeposition of Mg and Li at an aluminium electrode is formed into Al-Li-Mg alloys when the applied potentials are more negative than -2.000 V. X-ray diffraction and inductively coupled plasma analysis indicated that Al-Li-Mg alloys with different lithium and magnesium contents were prepared via potentiostatic and galvanostatic electrolysis. The microstructure of typical dual phases of the Al-Li-Mg alloy was characterized by an optical microscope and by scanning electron microscopy. The analysis of energy dispersive spectrometry showed that the elements of Al and Mg distribute homogeneously in the Al-Li-Mg alloy. The lithium and magnesium contents of Al-Li-Mg alloys can be controlled by MgCl2 concentrations and by electrolytic parameters.

A Stable, Magnetic, and Metallic Li3O4 Compound as a Discharge Product in a Li-Air Battery.

PubMed

Yang, Guochun; Wang, Yanchao; Ma, Yanming

2014-08-07

The Li-air battery with the specific energy exceeding that of a Li ion battery has been aimed as the next-generation battery. The improvement of the performance of the Li-air battery needs a full resolution of the actual discharge products. Li2O2 has been long recognized as the main discharge product, with which, however, there are obvious failures on the understanding of various experimental observations (e.g., magnetism, oxygen K-edge spectrum, etc.) on discharge products. There is a possibility of the existence of other Li-O compounds unknown thus far. Here, a hitherto unknown Li3O4 compound as a discharge product of the Li-air battery was predicted through first-principles swarm structure searching calculations. The new compound has a unique structure featuring the mixture of superoxide O2(-) and peroxide O2(2-), the first such example in the Li-O system. The existence of superoxide O2(-) creates magnetism and hole-doped metallicity. Findings of Li3O4 gave rise to direct explanations of the unresolved experimental magnetism, triple peaks of oxygen K-edge spectra, and the Raman peak at 1125 cm(-1) of the discharge products. Our work enables an opportunity for the performance of capacity, charge overpotential, and round-trip efficiency of the Li-air battery.

An 80-year summer temperature history from the Xiao Dongkemadi ice core in the central Tibetan Plateau and its association with atmospheric circulation

NASA Astrophysics Data System (ADS)

Li, Xiangying; Ding, Yongjian; Yu, Zhongbo; Mika, Sillanpää; Liu, Shiyin; Shangguan, Donghui; Lu, Chengyang

2015-02-01

The climate significance of oxygen isotopes from the central Tibetan Plateau (cTP) ice cores is a debated issue because of large scale atmospheric circulation. A high-resolution δ18O record was recovered from the Xiao Dongkemadi (XD) ice core, which expanded the spatial coverage of δ18O data in this region. Annual average δ18O correlated significantly with nearby MJJAS air temperatures, suggesting the δ18O can be used as a proxy to reconstruct regional climate change. The reconstructed temperature anomaly is related to the regional and global warming trends, and the greater warming amplitude since 1970s is related to the elevation dependency of the warming signal. The close relationship of the warming to variations in glacier mass balances and discharge reveal that recent warming has led to obvious glacier shrinkage and runoff increase. Correlation analysis suggests that monsoon and westerly moisture substantially influence the cTP ice core records, along with an increase in their level of contribution to the XD core accumulation in recent decades, and confirms a teleconnection of regional climate of the cTP ice cores with climate parameters in the Indian and North Atlantic Oceans.

Emergence of Metallic Properties at LiFePO4 Surfaces and LiFePO4/Li2S Interfaces: An Ab Initio Study.

PubMed

Timoshevskii, Vladimir; Feng, Zimin; Bevan, Kirk H; Zaghib, Karim

2015-08-26

The atomic and electronic structures of the LiFePO4 (LFP) surface, both bare and reconstructed upon possible oxygenation, are theoretically studied by ab initio methods. On the basis of total energy calculations, the atomic structure of the oxygenated surface is proposed, and the effect of surface reconstruction on the electronic properties of the surface is clarified. While bare LFP(010) surface is insulating, adsorption of oxygen leads to the emergence of semimetallic behavior by inducing the conducting states in the band gap of the system. The physical origin of these conducting states is investigated. We further demonstrate that deposition of Li2S layers on top of oxygenated LFP(010) surface leads to the formation of additional conducting hole states in the first layer of Li2S surface because of the charge transfer from sulfur p-states to the gap states of LFP surface. This demonstrates that oxygenated LFP surface not only provides conducting layers itself, but also induces conducting channels in the top layer of Li2S. These results help to achieve further understanding of potential role of LFP particles in improving the performance of Li-S batteries through emergent interface conductivity.

cathode material for Li-ion batteries

NASA Astrophysics Data System (ADS)

Wang, Yanming; Wang, Yajing; Wang, Fei

2014-05-01

Well-crystallized Li2NiTiO4 nanoparticles are rapidly synthesized by a molten salt method using a mixture of NaCl and KCl salts. X-ray diffraction pattern and scanning electron microscopic image show that Li2NiTiO4 has a cubic rock salt structure with an average particle size of ca. 50 nm. Conductive carbon-coated Li2NiTiO4 is obtained by a facile ball milling method. As a novel 4 V positive cathode material for Li-ion batteries, the Li2NiTiO4/C delivers high discharge capacities of 115 mAh g-1 at room temperature and 138 mAh g-1 and 50°C, along with a superior cyclability.

Data mining of molecular dynamics data reveals Li diffusion characteristics in garnet Li7La3Zr2O12

PubMed Central

Chen, Chi; Lu, Ziheng; Ciucci, Francesco

2017-01-01

Understanding Li diffusion in solid conductors is essential for the next generation Li batteries. Here we show that density-based clustering of the trajectories computed using molecular dynamics simulations helps elucidate the Li diffusion mechanism within the Li7La3Zr2O12 (LLZO) crystal lattice. This unsupervised learning method recognizes lattice sites, is able to give the site type, and can identify Li hopping events. Results show that, while the cubic LLZO has a much higher hopping rate compared to its tetragonal counterpart, most of the Li hops in the cubic LLZO do not contribute to the diffusivity due to the dominance of back-and-forth type jumps. The hopping analysis and local Li configuration statistics give evidence that Li diffusivity in cubic LLZO is limited by the low vacancy concentration. The hopping statistics also shows uncorrelated Poisson-like diffusion for Li in the cubic LLZO, and correlated diffusion for Li in the tetragonal LLZO in the temporal scale. Further analysis of the spatio-temporal correlation using site-to-site mutual information confirms the weak site dependence of Li diffusion in the cubic LLZO as the origin for the uncorrelated diffusion. This work puts forward a perspective on combining machine learning and information theory to interpret results of molecular dynamics simulations. PMID:28094317

Dehydrogenation kinetics and reversibility of LiAlH4-LiBH4 doped with Ti-based additives and MWCNT

NASA Astrophysics Data System (ADS)

Thaweelap, Natthaporn; Utke, Rapee

2016-11-01

Dehydrogenation kinetics and reversibility of LiAlH4-LiBH4 doped with Ti-based additives (TiCl3 and Ti-isopropoxide), multiwall carbon nanotubes (MWCNT), and MWCNT impregnated with Ti-based additives are proposed. Reduction of dehydrogenation temperature as well as improvements of kinetics and reversibility, especially decomposition of thermodynamically stable hydride (LiBH4) is obtained from the samples doped with Ti-isopropoxide and MWCNT. This can be due to the fact that the formations of LixAl(1-x)B2 and LiH-Al containing phase during dehydrogenation favor decomposition of LiH, leading to increment of hydrogen capacity, and stabilization of boron in solid state, resulting in improvement of reversibility. Besides, the curvatures and thermal conductivity of MWCNT benefit hydrogen diffusion and heat transfer during de/rehydrogenation. Nevertheless, deficient hydrogen content reversible is observed in all samples due to the irreversible of LiAlH4 and/or Li3AlH6 as well as the formation of stable phase (Li2B12H12) during de/rehydrogenation.

Quantum Chemical Insight into the LiF Interlayer Effects in Organic Electronics: Reactions between Al Atom and LiF Clusters.

PubMed

Wu, Shui-Xing; Kan, Yu-He; Li, Hai-Bin; Zhao, Liang; Wu, Yong; Su, Zhong-Min

2015-08-06

It is well known that the aluminum cathode performs dramatically better when a thin lithium fluoride (LiF) layer inserted in organic electronic devices. The doping effect induced by the librated Li atom via the chemical reactions producing AlF3 as byproduct was previously proposed as one of possible mechanisms. However, the underlying mechanism discussion is quite complicated and not fully understood so far, although the LiF interlayer is widely used. In this paper, we perform theoretical calculations to consider the reactions between an aluminum atom and distinct LiF clusters. The reaction pathways of the Al-(LiF)n (n = 2, 4, 16) systems were discovered and the energetics were theoretically evaluated. The release of Li atom and the formation of AlF3 were found in two different chemical reaction routes. The undissociated Al-(LiF)n systems have chances to change to some structures with loosely bound electrons. Our findings about the interacted Al-(LiF)n systems reveal new insights into the LiF interlayer effects in organic electronics applications.

Improved charging performance of Li-O2 batteries by forming Ba-incorporated Li2O2 as the discharge product

NASA Astrophysics Data System (ADS)

Matsuda, Shoichi; Uosaki, Kohei; Nakanishi, Shuji

2017-06-01

Although Li-O2 batteries can potentially achieve greater than two-fold higher energy densities than Li-ion batteries, the basic performance of Li-O2 batteries remains poor. In particular, the large over-potential of positive electrode reactions during the charging process results in low round-trip energy efficiency and limited cycle life, and is therefore the main barrier to the practical use of rechargeable Li-O2 batteries. In the present study, we demonstrate that the charging performance of Li-O2 batteries can be significantly improved by simply adding barium (Ba) ions into the electrolyte. Elemental analysis revealed that Ba-incorporated Li2O2 was obtained as the main discharge product of a Li-O2 cell operated in the presence of Ba2+. Notably, the improvement of charging performance was confirmed to originate from the Ba-incorporated Li2O2 deposits, rather than the Ba2+ present in the electrolyte. The present results suggest that the incorporation of heteroatoms into the discharge product is an effective approach for improving the charging performance of Li-O2 batteries.

Intermittency and dynamical Lee-Yang zeros of open quantum systems.

PubMed

Hickey, James M; Flindt, Christian; Garrahan, Juan P

2014-12-01

We use high-order cumulants to investigate the Lee-Yang zeros of generating functions of dynamical observables in open quantum systems. At long times the generating functions take on a large-deviation form with singularities of the associated cumulant generating functions-or dynamical free energies-signifying phase transitions in the ensemble of dynamical trajectories. We consider a driven three-level system as well as the dissipative Ising model. Both systems exhibit dynamical intermittency in the statistics of quantum jumps. From the short-time behavior of the dynamical Lee-Yang zeros, we identify critical values of the counting field which we attribute to the observed intermittency and dynamical phase coexistence. Furthermore, for the dissipative Ising model we construct a trajectory phase diagram and estimate the value of the transverse field where the stationary state changes from being ferromagnetic (inactive) to paramagnetic (active).

Facile molten salt synthesis of Li2NiTiO4 cathode material for Li-ion batteries.

PubMed

Wang, Yanming; Wang, Yajing; Wang, Fei

2014-01-01

Well-crystallized Li2NiTiO4 nanoparticles are rapidly synthesized by a molten salt method using a mixture of NaCl and KCl salts. X-ray diffraction pattern and scanning electron microscopic image show that Li2NiTiO4 has a cubic rock salt structure with an average particle size of ca. 50 nm. Conductive carbon-coated Li2NiTiO4 is obtained by a facile ball milling method. As a novel 4 V positive cathode material for Li-ion batteries, the Li2NiTiO4/C delivers high discharge capacities of 115 mAh g(-1) at room temperature and 138 mAh g(-1) and 50°C, along with a superior cyclability.

Facile molten salt synthesis of Li2NiTiO4 cathode material for Li-ion batteries

PubMed Central

2014-01-01

Well-crystallized Li2NiTiO4 nanoparticles are rapidly synthesized by a molten salt method using a mixture of NaCl and KCl salts. X-ray diffraction pattern and scanning electron microscopic image show that Li2NiTiO4 has a cubic rock salt structure with an average particle size of ca. 50 nm. Conductive carbon-coated Li2NiTiO4 is obtained by a facile ball milling method. As a novel 4 V positive cathode material for Li-ion batteries, the Li2NiTiO4/C delivers high discharge capacities of 115 mAh g-1 at room temperature and 138 mAh g-1 and 50°C, along with a superior cyclability. PMID:24855459

China Report, Political, Sociological and Military Affairs

DTIC Science & Technology

1985-02-05

away long ago. However, their in- domitable spirit and their spirit of heroic struggle are still fresh in my memory. At that time, Cao Rui, the... Cao Rui were compelled to solve the problem through legal means by transferring the representatives in custody to the Hebei Provincial Court of...Zhang Ming, Tang Shudi, Want Zibo, Wang Jingmin, Li Baoqi. Wei Jinshan, and Chen Hui: advisers of the military region Sun Keji, Zhang Yuhua , and Wu

Li-S batteries: Firing for compactness

NASA Astrophysics Data System (ADS)

Li, Yanguang; Chen, Fengjiao

2017-07-01

Conventional Li-S batteries have a non-compact cathode structure containing low areal loading of active materials. Now, a strategy of burning Li foils in a CS2 vapour is presented, which leads to the formation of highly compact Li2S nanoparticles as a lithiated sulfur cathode, offering promising battery performance.

Continuum strong-coupling expansion of Yang-Mills theory: quark confinement and infra-red slavery

NASA Astrophysics Data System (ADS)

Mansfield, Paul

1994-04-01

We solve Schrödinger's equation for the ground-state of four-dimensional Yang-Mills theory as an expansion in inverse powers of the coupling. Expectation values computed with the leading-order approximation are reduced to a calculation in two-dimensional Yang-Mills theory which is known to confine. Consequently the Wilson loop in the four-dimensional theory obeys an area law to leading order and the coupling becomes infinite as the mass scale goes to zero.

A review of the cavernicolous genus Guiaphaenops Deuve, with the description of a new species (Coleoptera, Carabidae, Trechinae).

PubMed

Feng, Bin; Wei, Guofu; Tian, Mingyi

2017-01-01

The subterranean ground beetle genus Guiaphaenops Deuve, 2002 is taxonomically reviewed. This poorly known genus is different from Guizhaphaenops Vigna Taglianti, 1997 in having convex propleura which is visible from above and elytral chaetotaxy especially the humeral group of the marginal umbilicate series, in which the 1 st pore is transversely and backwardly shifted. The second species, G. deuvei Tian, Feng & Wei, sp. n. , is described from a limestone cave at Yangli Cun (Village), Lingyun Xian (County), Baise Shi (Prefecture), northwestern Guangxi Zhuang Autonomous Region, China. A key to the species and a distribution map of Guiaphaenops are also provided.

Yang Baxter and anisotropic sigma and lambda models, cyclic RG and exact S-matrices

NASA Astrophysics Data System (ADS)

Appadu, Calan; Hollowood, Timothy J.; Price, Dafydd; Thompson, Daniel C.

2017-09-01

Integrable deformation of SU(2) sigma and lambda models are considered at the classical and quantum levels. These are the Yang-Baxter and XXZ-type anisotropic deformations. The XXZ type deformations are UV safe in one regime, while in another regime, like the Yang-Baxter deformations, they exhibit cyclic RG behaviour. The associ-ated affine quantum group symmetry, realized classically at the Poisson bracket level, has q a complex phase in the UV safe regime and q real in the cyclic RG regime, where q is an RG invariant. Based on the symmetries and RG flow we propose exact factorizable S-matrices to describe the scattering of states in the lambda models, from which the sigma models follow by taking a limit and non-abelian T-duality. In the cyclic RG regimes, the S-matrices are periodic functions of rapidity, at large rapidity, and in the Yang-Baxter case violate parity.

Stabilization of Li Metal Anode in DMSO-Based Electrolytes via Optimization of Salt-Solvent Coordination for Li-O 2 Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Bin; Xu, Wu; Yan, Pengfei

The conventional DMSO-based electrolyte (1 M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in DMSO) is unstable against the Li metal anode and therefore cannot be used directly in practical Li-O2 batteries. Here, we demonstrate that a highly concentrated electrolyte based on LiTFSI in DMSO (with a molar ratio of 1:3) can greatly improve the stability of the Li metal anode against DMSO and significantly improve the cycling stability of Li-O2 batteries. This highly concentrated electrolyte contains no free DMSO solvent molecules, but only complexes of (TFSI–)a-Li+-(DMSO)b (where a + b = 4), and thus enhances their stability with Li metal anodes. In addition,more » such salt-solvent complexes have higher Gibbs activation energy barriers than the free DMSO solvent molecules, indicating improved stability of the electrolyte against the attack of superoxide radical anions. Therefore, the stability of this highly concentrated electrolyte at both Li metal anodes and carbon-based air electrodes has been greatly enhanced, resulting in improved cyclic stability of Li-O2 batteries. The fundamental stability of the electrolyte with free-solvent against the chemical and electrochemical reactions can also be used to enhance the stability of other electrochemical systems.« less

Synthesis and characterization of PVA blended LiClO4 as electrolyte material for battery Li-ion

NASA Astrophysics Data System (ADS)

Gunawan, I.; Deswita; Sugeng, B.; Sudaryanto

2017-07-01

It have been synthesized the materials for Li ion battery electrolytes, namely PVA with the addition of LiClO4 salt were varied 0, 5, 10, 15 and 20% by weight respectively. The objective of this study is to control the ionic conductivity in traditional polymer electrolytes, to improve ionic conductivity with the addition of lithium perchlorat (LiClO4). These electrolyte materials prepared by PVA powder was dissolved into distilled water and added LiClO4 salt were varied. After drying the solution, PVA sheet blended LiClO4 salt as electrolyte material for Li ion battery obtained. PVA blended LiClO4 salt crystallite form was confirmed using X-Ray Difraction (XRD) equipment. Observation of the morphology done by using Scanning Electron Microscope (SEM). While the electrical conductivity of the material is measured using LCR meter. The results of XRD pattern of LiClO4 shows intense peaks at angles 2θ = 23.2, 32.99, and 36.58°, which represent the crystalline nature of the salt. Particles morphology of the sample revealed by scanning electron microscopy are irregular in shape and agglomerated, with mean size 200-300 nm. It can be concluded that polycrystalline particles are composed of large number of crystallites. The study of conductivity by using LCR meter shows that all the graphs represent the DC and AC conductivity phenomena.

[The Yin and Yang movement in the cosmology of Chinese medicine].

PubMed

Coutinho, Bernardo Diniz; Dulcetti, Pérola Goretti Sichero

2015-01-01

After being developed in the East, based on Taoist cosmology, Chinese medicine has been practiced in the West based on scientific foundations and biomedical paradigms. Some traditional elements of this philosophy were abandoned, such as the theory of Yin and Yang, knowledge that is essential for understanding the health-disease process resulting from the circulation of the body's energy flow. This article studies the movement of the dual elements of Yin and Yang in Chinese medical teaching, seeking to understand how this line of thought developed and how it has contributed towards establishing a system of diagnosis and therapy. The methodology employed was to analyze literature on the subject, based on theoretical references to Taoist thought and traditional Chinese medicine.

Li2.97Mg0.03VO4: High rate capability and cyclability performances anode material for rechargeable Li-ion batteries

NASA Astrophysics Data System (ADS)

Dong, Youzhong; Zhao, Yanming; Duan, He; Singh, Preetam; Kuang, Quan; Peng, Hongjian

2016-07-01

Mg-doped composite, Li2.97Mg0.03VO4, with an orthorhombic structure was prepared by a sol-gel method. The effects of the Mg doping on the structure and electrochemical performance of Li3VO4 were investigated. The X-ray diffraction pattern shows that the Mg doping does not change the crystal structure of Li3VO4. The EDS mappings indicated the fairly uniform distribution of Mg throughout the grains of Li2.97Mg0.03VO4. Electronic conductivity of Mg-doped Li3VO4 increased by two orders of magnitude compared to that of pure Li3VO4. CV and EIS measurement confirms that the Li2.97Mg0.03VO4 sample exhibits a smaller polarization and transfer resistance and a higher lithium diffusion coefficient compared with the pure Li3VO4. Due to the better electrochemical kinetics properties, Mg-doped Li3VO4 showed a significant improved performance compared to the pure Li3VO4, especially for the high rate capability. At the higher discharge/charge rate (2C), the discharge and charge capacities of 415.5 and 406.1 mAh/g have been obtained for the Li2.97Mg0.03VO4 which is more than three times higher the discharge/charge capacities of Li3VO4. The discharge and charge capacities of pure Li3VO4 are only 126.4 and 125.8 mAh/g respectively. The excellent electrochemical performance of Li2.97Mg0.03VO4 enables it as a promising anode material for rechargeable lithium-ion batteries.

A taxonomy review of Oreoderus Burmeister, 1842 from China with a geometric morphometric evaluation (Coleoptera, Scarabaeidae, Valgini)

PubMed Central

Li, Sha; Ricchiardi, Enrico; Bai, Ming; Yang, Xingke

2016-01-01

Abstract The species of the genus Oreoderus are morphologically similar, and can be challenging to distinguish without dissecting the male genitalia. In this study, the Oreoderus species from China are reviewed. Three new species of Oreoderus are described: Oreoderus dasystibialis Li & Yang, sp. n., Oreoderus brevitarsus Li & Yang, sp. n. and Oreoderus oblongus Li & Yang, sp. n. A key of the male Oreoderus and a distribution map are provided. Oreoderus coomani Paulian, 1961 was found as a new record in China. The first description of the female of Oreoderus arrowi Ricchiardi, 2001 is provided. Oreoderus humeralis Gestro, 1891, Oreoderus quadricarinatus Arrow, 1944, Oreoderus crassipes Arrow, 1944, and Oreoderus momeitensis Arrow, 1910 are excluded from the Chinese fauna. Furthermore, we utilize geometric morphometric approaches (GM) to analyze the shape variation of four characters (pronotum, elytra, protibia and aedeagus) in Oreoderus. The morphological variations of Oreoderus and the taxonomic value of each character are discussed. The combined analysis of geometric morphometrics and comparative morphology support recognition of the three new species. PMID:26865816

Li2S/Carbon Nanocomposite Strips from a Low-Temperature Conversion of Li2SO4 as High-Performance Lithium-Sulfur Cathodes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ye, Fangmin; Noh, Hyungjun; Lee, Jin Hong

2018-03-12

Carbothermal conversion of Li2SO4 provides a cost-effective strategy to fabricate high-capacity Li2S cathodes, however, Li2S cathodes derived from Li2SO4 at high temperatures (> 800 oC), having high crystallinity and large crystal size, result in a low utilization of Li2S. Here, we report a Li2SO4/poly(vinyl alcohol)-derived Li2S/Carbon nanocomposite (Li2S@C) strips at a record low temperature of 635 oC. These Li2S@C nanocomposite strips as a cathode shows a low initial activation potential (2.63 V), a high initial discharge capacity (805 mAh g-1 Li2S) and a high cycling stability (0.2 C and 1 C). These improvedresults could be ascribed to the nano-sized Li2Smore » particles as well as their low crystallinity due to the PVA-induced carbon network and the low conversion temperature, respectively. An XPS analysis reveals that the C=C and C=O bonds derived from the carbonization of PVA can promote the conversion of Li2SO4 at the low temperature.« less

A Preliminary Study on the Yang-cheon-cheok (量天尺) in the Late Joseon Dynasty

NASA Astrophysics Data System (ADS)

Kim, Sang Hyuk; Mihn, Byeong-Hee; Lee, Yong Sam

2015-12-01

We investigated the six remaining Yang-cheon-cheoks (量天尺), which were first described in the Veritable Record of King Sukjong (肅宗實錄). These woodblock sundials from Korea are structurally very similar to a Gyupyo (圭表, gnomon) or an altitude sundial and are light, compact, and portable. The front side of a Yang-cheon-cheok has two holes for styluses and several hour-lines. We compared the intervals of the hour-lines from the originating point of the stylus placement on all Yang-cheon-cheoks and found that two of the relics had the same hour-lines using the standard of the unit of 1 chon (寸). These two were actually the same sundial although the physical size was different. In spite of the lack of time accuracy, we hypothesize that various-sized Yang-cheon-cheoks were made and widely distributed throughout the public in the late Joseon Dynasty.

Revision of the Li13Si4 structure.

PubMed

Zeilinger, Michael; Fässler, Thomas F

2013-11-06

Besides Li17Si4, Li16.42Si4, and Li15Si4, another lithium-rich representative in the Li-Si system is the phase Li13Si4 (trideca-lithium tetra-silicide), the structure of which has been determined previously [Frank et al. (1975 ▶). Z. Naturforsch. Teil B, 30, 10-13]. A careful analysis of X-ray diffraction patterns of Li13Si4 revealed discrepancies between experimentally observed and calculated Bragg positions. Therefore, we redetermined the structure of Li13Si4 on the basis of single-crystal X-ray diffraction data. Compared to the previous structure report, decisive differences are (i) the introduction of a split position for one Li site [occupancy ratio 0.838 (7):0.162 (7)], (ii) the anisotropic refinement of atomic displacement parameters for all atoms, and (iii) a high accuracy of atom positions and unit-cell parameters. The asymmetric unit of Li13Si4 contains two Si and seven Li atoms. Except for one Li atom situated on a site with symmetry 2/m, all other atoms are on mirror planes. The structure consists of isolated Si atoms as well as Si-Si dumbbells surrounded by Li atoms. Each Si atom is either 12- or 13-coordinated. The isolated Si atoms are situated in the ab plane at z = 0 and are strictly separated from the Si-Si dumbbells at z = 0.5.

Interfacial Li-ion localization in hierarchical carbon anodes

DOE PAGES

McNutt, Nicholas W.; Rios, Orlando; Maroulas, Vasileios; ...

2016-10-24

An understanding of the nanoscale structure and energetics of carbon composites is critical for their applications in electric energy storage. Here, we study the properties of carbon anodes synthesized from low-cost renewable lignin biopolymers for use in energy storage applications such as Li-ion batteries. The anodes possess both nanoscale and mesoscale order, consisting of carbon nanocrystallites distributed within an amorphous carbon matrix. Molecular dynamics simulations of an experimentally validated model of the anode is used to elucidate the nature of Li-ion storage. We report the discovery of a novel mechanism of Li-ion storage, one in which Li+ is not intercalatedmore » between layers of carbon (as is the case in graphitic anodes), but rather is localized at the interface of crystalline carbon domains. In particular, the effects of Li-ion binding energy on the Li-Li, Li-H, and Li-C pair distribution functions are revealed, along with the effect on charge distribution. As a result, the atomic environments surrounding the Li-ions are grouped on the basis of ion energy and then convolved into archetypal structural motifs that reveal deep insight into the geometry of ion localization in disordered systems.« less

Metabolites identification of Huo Luo Xiao Ling Dan in rat urine by UPLC coupled with electrospray ionization time-of-flight mass spectrometry.

PubMed

Wang, Fenrong; Wu, Yun; Ai, Yu; Bian, Qiaoxia; Ma, Wen; Lee, David Y-W; Dai, Ronghua

2016-03-01

Huo Luo Xiao Ling Dan (HLXLD), a Chinese herbal formula, is used in folk medicine for the treatment of arthritis and other chronic inflammatory diseases. However, the in vivo integrated metabolism of its multiple components remains unknown. In this paper, an ultra-performance liquid chromatography coupled with quadrupole time-of-flight tandem mass spectrometry (UPLC-Q-TOF-MS) method was developed for detection and identification of HLXLD metabolites in rat urine at high and normal clinical dosages. The prototype constituents and their metabolites in urine were analyzed. The mass measurements were accurate within 8 ppm, and subsequent fragment ions offered higher quality structural information for interpretation of the fragmentation pathways of various compounds. A total of 85 compounds were detected in high dosages urine samples by a highly sensitive extracted ion chromatograms method, including 31 parent compounds and 54 metabolites. Our results indicated that phase 2 reactions (e.g. glucuronidation, glutathionidation and sulfation) were the main metabolic pathways of lactones, alkaloids and flavones, while phase I reactions (e.g. hydrogenation and hydroxylation) were the major metabolic reaction for coumarins, paeoniflorin and iridoids. This investigation provided important structural information on the metabolism of HLXLD and provided scientific evidence to obtain a more comprehensive metabolic profile. Copyright © 2015 John Wiley & Sons, Ltd.

Nanotechnology in Li-ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukaibo, Hitomi

2010-06-04

This is the second of three talks on nanostructures for li-ion batteries. The talks provide an up-to-date review of the issues and challenges facing Li-ion battery research with special focus on how nanostructures/ nanotechnology are being applied to this field. Novel materials reported as prospective candidates for anode, cathode and electrolyte will be summarized. The expected role of nanostructures in improving the performance of Li-ion batteries and the actual pros and cons of using such structures in this device will be addressed. Electrochemical experiments used to study Li-ion batteries will also be discussed. This includes the introduction to the standardmore » experimental set-up and how experimental data (from charge-discharge experiments, cyclic voltammetry, impedance spectroscopy, etc) are interpreted.« less

Switching of the substrate specificity of protein tyrosine phosphatase N12 by cyclin-dependent kinase 2 phosphorylation orchestrating 2 oncogenic pathways.

PubMed

Li, Hui; Yang, Duxiao; Ning, Shanglei; Xu, Yinghui; Yang, Fan; Yin, Rusha; Feng, Taihu; Han, Shouqing; Guo, Lu; Zhang, Pengju; Qu, Wenjie; Guo, Renbo; Song, Chen; Xiao, Peng; Zhou, Chengjun; Xu, Zhigang; Sun, Jin-Peng; Yu, Xiao

2018-01-01

The protein tyrosine phosphatase nonreceptor type 12 (PTPN12) is a multifunctional protein and has elicited much research attention because its decreased protein level has been associated with poor prognosis of several types of cancers. Recently, we have solved the crystal structure of the phosphatase domain of PTPN12, which disclosed a specific PTPN12-insert-loop harboring a cyclin-dependent kinase 2 (CDK2) phosphorylation site. However, the functional significance of this phosphorylation is undefined. In the present study, we found that S19 site phosphorylation of PTPN12 by CDK2 discharged its antitumor activity by down-regulation of its inhibitory role in cell migration, but not affecting its other regulatory functions. Phosphorylation of PTPN12 at the S19 site changed its substrate interface, and by doing so, selectively decreased its activity toward the human epidermal growth factor receptor 2 (HER2)- pY 1196 site, but not other HER2 phosphorylation sites or other known PTPN12 substrates. A further in-depth mechanism study revealed that the phosphorylation of PTPN12 by CDK2 impaired recruitment of the serine/threonine-protein kinase 1 (PAK1) to HER2, resulted in the blockade of the HER2-pY 1196 -PAK1-T 423 signaling pathway, thus increased tumor cell motility. Taken together, our results identified a new phosphorylation-based substrate recognition mechanism of PTPN12 by CDK2, which orchestrated signaling crosstalk between the oncogenic CDK2 and HER2 pathways. The newly identified governing mechanism of the substrate selectivity of a particular phosphatase was previously unappreciated and exemplifies how a phospho-network is precisely controlled in different cellular contexts.-Li, H., Yang, D., Ning, S., Xu, Y., Yang, F., Yin, R., Feng, T., Han, S., Guo, L., Zhang, P., Qu, W., Guo, R., Song, C., Xiao, P., Zhou, C., Xu, Z., Sun, J.-P., Yu, X. Switching of the substrate specificity of protein tyrosine phosphatase N12 by cyclin-dependent kinase 2 phosphorylation

Finite-action solutions of Yang-Mills equations on de Sitter dS4 and anti-de Sitter AdS4 spaces

NASA Astrophysics Data System (ADS)

Ivanova, Tatiana A.; Lechtenfeld, Olaf; Popov, Alexander D.

2017-11-01

We consider pure SU(2) Yang-Mills theory on four-dimensional de Sitter dS4 and anti-de Sitter AdS4 spaces and construct various solutions to the Yang-Mills equations. On de Sitter space we reduce the Yang-Mills equations via an SU(2)-equivariant ansatz to Newtonian mechanics of a particle moving in R^3 under the influence of a quartic potential. Then we describe magnetic and electric-magnetic solutions, both Abelian and non-Abelian, all having finite energy and finite action. A similar reduction on anti-de Sitter space also yields Yang-Mills solutions with finite energy and action. We propose a lower bound for the action on both backgrounds. Employing another metric on AdS4, the SU(2) Yang-Mills equations are reduced to an analytic continuation of the above particle mechanics from R^3 to R^{2,1} . We discuss analytical solutions to these equations, which produce infinite-action configurations. After a Euclidean continuation of dS4 and AdS4 we also present self-dual (instanton-type) Yang-Mills solutions on these backgrounds.

Enhanced ionic conductivity with Li 7O 2Br 3 phase in Li 3OBr anti-perovskite solid electrolyte

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Jinlong; Li, Shuai; Zhang, Yi

Cubic anti-perovskites with general formula Li 3OX (X = Cl, Br, I) were recently reported as superionic conductors with the potential for use as solid electrolytes in all-solid-state lithium ion batteries. These electrolytes are nonflammable, low-cost, and suitable for thermoplastic processing. However, the primary obstacle of its practical implementation is the relatively low ionic conductivity at room temperature. In this work, we synthesized a composite material consisting of two anti-perovskite phases, namely, cubic Li 3OBr and layered Li 7O 2Br 3, by solid state reaction routes. The results indicate that with the phase fraction of Li 7O 2Br 3 increasingmore » to 44 wt. %, the ionic conductivity increased by more than one order of magnitude compared with pure phase Li 3OBr. Formation energy calculations revealed the meta-stable nature of Li 7O 2Br 3, which supports the great difficulty in producing phase-pure Li 7O 2Br 3 at ambient pressure. Here, methods of obtaining phase-pure Li 7O 2Br 3 will continue to be explored, including both high pressure and metathesis techniques.« less

Enhanced ionic conductivity with Li 7O 2Br 3 phase in Li 3OBr anti-perovskite solid electrolyte

DOE PAGES

Zhu, Jinlong; Li, Shuai; Zhang, Yi; ...

2016-09-07

Cubic anti-perovskites with general formula Li 3OX (X = Cl, Br, I) were recently reported as superionic conductors with the potential for use as solid electrolytes in all-solid-state lithium ion batteries. These electrolytes are nonflammable, low-cost, and suitable for thermoplastic processing. However, the primary obstacle of its practical implementation is the relatively low ionic conductivity at room temperature. In this work, we synthesized a composite material consisting of two anti-perovskite phases, namely, cubic Li 3OBr and layered Li 7O 2Br 3, by solid state reaction routes. The results indicate that with the phase fraction of Li 7O 2Br 3 increasingmore » to 44 wt. %, the ionic conductivity increased by more than one order of magnitude compared with pure phase Li 3OBr. Formation energy calculations revealed the meta-stable nature of Li 7O 2Br 3, which supports the great difficulty in producing phase-pure Li 7O 2Br 3 at ambient pressure. Here, methods of obtaining phase-pure Li 7O 2Br 3 will continue to be explored, including both high pressure and metathesis techniques.« less

Concentration dependence of Li+/Na+ diffusion in manganese hexacyanoferrates

NASA Astrophysics Data System (ADS)

Takachi, Masamitsu; Fukuzumi, Yuya; Moritomo, Yutaka

2016-06-01

Manganese hexacyanoferrates (Mn-HCFs) with a jungle-gym-type structure are promising cathode materials for Li+/Na+ secondary batteries (LIBs/SIBs). Here, we investigated the diffusion constants D Li/D Na of Li+/Na+ against the Li+/Na+ concentration x Na/x Li and temperature (T) of A 1.32Mn[Fe(CN)6]0.833.6H2O (A = Li and Na). We evaluated the activation energy E\\text{a}\\text{Li}/E\\text{a}\\text{Na} of D Li/D Na against x Na/x Li. We found that E\\text{a}\\text{Na} steeply increases with x Na from 0.41 eV at x Na = 0.69 to 0.7 eV at 1.1. The increase in E\\text{a}\\text{Na} is ascribed to the occupancy effect of the Na+ site. The increase in E\\text{a}\\text{Li} is suppressed, probably because the number of Li+ sites is three times that of Na+ sites.

GL/sub 3/-invariant solutions of the Yang-Baxter equation and associated quantum systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kulish, P.P.; Reshetikin N.Y.

1986-09-01

GL/sub 3/-invariant, finite-dimensional solutions of the Yang-Baxter equations acting in the tensor product of two irreducible representations of the group GL/sub 3/ are investigated. A number of relations are obtained for the transfer matrices which demonstrate the connection of representation theory and the Bethe Ansatz in GL/sub 3/invariant models. Some of the most interesting quantum and classical integrable systems connected with GL/sub 3/-invariant solutions of the Yang-Baxter equation are presented.

GL/sub 3/-invariant solutions of the Yang-Baxter equation and associated quantum systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kulish, P.P.; Reshetikhin, N.Yu.

1986-09-10

GL/sub 3/-invariant, finite-dimensional solutions of the Yang-Baxter equations acting in the tensor product of two irreducible representations of the group GL/sub 3/ are investigated. A number of relations are obtained for the transfer matrices which demonstrate the connection of representation theory and the Bethe Ansatz in GL/sub 3/-invariant models. Some of the most interesting quantum and classical integrable systems connected with GL/sub 3/-invariant solutions of the Yang-Baxter equation are presented.

Influence of Li3BO3 additives on the Li+ conductivity and stability of Ca/Ta-substituted Li6.55(La2.95Ca0.05)(Zr1.5Ta0.5)O12 electrolytes

NASA Astrophysics Data System (ADS)

Zhang, L. C.; Yang, J. F.; Gao, Y. X.; Wang, X. P.; Fang, Q. F.; Chen, C. H.

2017-07-01

The cubic Ca/Ta-substituted Li6.55(La2.95Ca0.05)(Zr1.5Ta0.5)O12 (LLCZTO) electrolytes were synthesized at 800 °C with Li3BO3 as additives. The optimal amount of Li3BO3 and its influences on the microstructure, crystal structures, Li+ conductivity and the stability of the Li6.55(La2.95Ca0.05)(Zr1.5Ta0.5)O12 were studied by SEM, XRD and EIS. Among all the samples, when the molar ratio of Li3BO3 to the Li6.55(La2.95Ca0.05)(Zr1.5Ta0.5)O12 is 4:5, the highest Li+ conductivity of 1.33 × 10-4 S cm-1 at 30 °C is obtained. When the LLCZTO samples are exposed in air, the Li+ conductivity is deteriorated possibly owing to the side reactions between the LLCZTO and the H2O or CO2 in the air. The Li3BO3 addition can alleviate such deterioration of the Li+ conductivity.

LiDAR for data efficiency.

DOT National Transportation Integrated Search

2011-09-30

This report documents the AHMCT research project: LiDAR for Data Efficiency for the Washington State Department of Transportation (WSDOT). The research objective was to evaluate mobile LiDAR technology to enhance safety, determine efficiency ga...

Albert LiVecchi | NREL

Science.gov Websites

Albert LiVecchi Photo of Al Livecchi Albert LiVecchi Laboratory Program Manager- Water Power Al.Livecchi@nrel.gov | 303-384-7138 Al has been part of the Wind and Water Power Program Management Team at focuses on marine and hydrokinetic technologies. As Water Power Laboratory Program Manager, Al is

EGFR LI and Ki-67 LI are independent prognostic parameters influencing survivals of surgically treated squamous cell lung cancer patients.

PubMed

Niemiec, J; Kolodziejski, L; Dyczek, S

2005-01-01

In literature there are still opinion differences concerning the prognostic significance of epidermal growth factor receptor (EGFR) expression and proliferative potential in patients with non small cell lung cancer (NSCLC). This prompted us to study those parameters. The Ki-67 labeling index (Ki-67 LI), EGFR labeling index (EGFR LI), and mitotic index (MI) were analyzed in the group of 78 consecutive, surgically treated squamous cell lung cancer (SqCLC) patients. The expression of Ki-67 and EGFR protein was visualized on formalin fixed, paraffin embedded sections using immunohistochemistry (IHC). Mitotic index was assessed on formalin fixed, paraffin embedded sections, stained with hematoxylin and eosin using morphological criteria. Mean values of Ki-67 LI and MI were higher for G2+G3 tumors than for G1 tumors. EGFR LI was higher for G1+G2 than for G3 tumors, and for pT3 than for pT1+pT2 tumors. Patients having tumors with Ki-67 < or =28% or (EGFR LI < or =13% or EGFR LI >80%) survived significantly shorter than those having tumors with Ki-67 LI >28% or 13%< EGFR LI < or =80%. In multivariate analysis, 13%> or = EGFR LI <80% and Ki-67 LI < or =28% were independent negative prognostic parameters influencing survivals of SqCLC patients.

Yang-Lee zeros, Julia sets, and their singularity spectra

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, B.; Lin, B.

1989-05-01

We have studied the global scaling properties of the Julia sets of the Yang-Lee zeros of the s-state Potts model on the diamond hierarchical lattice. The singularity spectrum f(..cap alpha..) and the generalized dimension D/sub q/ are calculated for different s values. General observations are made on their variations.

Vacuum structure and string tension in Yang-Mills dimeron ensembles

NASA Astrophysics Data System (ADS)

Zimmermann, Falk; Forkel, Hilmar; Müller-Preußker, Michael

2012-11-01

We numerically simulate ensembles of SU(2) Yang-Mills dimeron solutions with a statistical weight determined by the classical action and perform a comprehensive analysis of their properties as a function of the bare coupling. In particular, we examine the extent to which these ensembles and their classical gauge interactions capture topological and confinement properties of the Yang-Mills vacuum. This also allows us to put the classic picture of meron-induced quark confinement, with the confinement-deconfinement transition triggered by dimeron dissociation, to stringent tests. In the first part of our analysis we study spacial, topological-charge and color correlations at the level of both the dimerons and their meron constituents. At small to moderate couplings, the dependence of the interactions between the dimerons on their relative color orientations is found to generate a strong attraction (repulsion) between nearest neighbors of opposite (equal) topological charge. Hence, the emerging short- to mid-range order in the gauge-field configurations screens topological charges. With increasing coupling this order weakens rapidly, however, in part because the dimerons gradually dissociate into their less localized meron constituents. Monitoring confinement properties by evaluating Wilson-loop expectation values, we find the growing disorder due to the long-range tails of these progressively liberated merons to generate a finite and (with the coupling) increasing string tension. The short-distance behavior of the static quark-antiquark potential, on the other hand, is dominated by small, “instantonlike” dimerons. String tension, action density and topological susceptibility of the dimeron ensembles in the physical coupling region turn out to be of the order of standard values. Hence, the above results demonstrate without reliance on weak-coupling or low-density approximations that the dissociating dimeron component in the Yang-Mills vacuum can indeed produce a

Critical phenomena in the general spherically symmetric Einstein-Yang-Mills system

NASA Astrophysics Data System (ADS)

Maliborski, Maciej; Rinne, Oliver

2018-02-01

We study critical behavior in gravitational collapse of a general spherically symmetric Yang-Mills field coupled to the Einstein equations. Unlike the magnetic ansatz used in previous numerical work, the general Yang-Mills connection has two degrees of freedom in spherical symmetry. This fact changes the phenomenology of critical collapse dramatically. The magnetic sector features both type I and type II critical collapse, with universal critical solutions. In contrast, in the general system type I disappears and the critical behavior at the threshold between dispersal and black hole formation is always type II. We obtain values of the mass scaling and echoing exponents close to those observed in the magnetic sector, however we find some indications that the critical solution differs from the purely magnetic discretely self-similar attractor and exact self-similarity and universality might be lost. The additional "type III" critical phenomenon in the magnetic sector, where black holes form on both sides of the threshold but the Yang-Mills potential is in different vacuum states and there is a mass gap, also disappears in the general system. We support our dynamical numerical simulations with calculations in linear perturbation theory; for instance, we compute quasi-normal modes of the unstable attractor (the Bartnik-McKinnon soliton) in type I collapse in the magnetic sector.

Evaluation of Li{sub 3}N accumulation in a fused LiCl/Li salt matrix

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eberle, C.S.

1998-09-01

Pyrochemical conditioning of spent nuclear fuel for the purpose of final disposal is currently being demonstrated at Argonne National Laboratory (ANL), and ongoing research in this area includes the demonstration of this process on spent oxide fuel. In conjunction with this research, a pilot scale of the preprocessing stage is being designed by ANL-West to demonstrate the in situ hot cell capability of the chemical reduction process. An impurity evaluation was completed for a Li/LiCl salt matrix in the presence of spent light water reactor uranium oxide fuel. A simple analysis was performed in which the sources of impurities inmore » the salt matrix were only from the cell atmosphere. Only reactions with the lithium were considered. The levels of impurities were shown to be highly sensitive system conditions. A predominance diagram for the Li-O-N system was constructed for the device, and the general oxidation, nitridation, and combined reactions were calculated as a function of oxygen and nitrogen partial pressure. These calculations and hot cell atmosphere data were used to determine the total number and type of impurities expected in the salt matrix, and the mass rate for the device was determined.« less

Li2 B12 and Li3 B12 : Prediction of the Smallest Tubular and Cage-like Boron Structures.

PubMed

Dong, Xue; Jalife, Said; Vásquez-Espinal, Alejandro; Ravell, Estefanía; Pan, Sudip; Cabellos, José Luis; Liang, Wei-Yan; Cui, Zhong-Hua; Merino, Gabriel

2018-04-16

An intriguing structural transition from the quasi-planar form of B 12 cluster upon the interaction with lithium atoms is reported. High-level computations show that the lowest energy structures of LiB 12 , Li 2 B 12 , and Li 3 B 12 have quasi-planar (C s ), tubular (D 6d ), and cage-like (C s ) geometries, respectively. The energetic cost of distorting the B 12 quasi-planar fragment is overcompensated by an enhanced electrostatic interaction between the Li cations and the tubular or cage-like B 12 fragments, which is the main reason of such drastic structural changes, resulting in the smallest tubular (Li 2 B 12 ) and cage-like (Li 3 B 12 ) boron structures reported to date. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Burning lithium in CS2 for high-performing compact Li2 S-graphene nanocapsules for Li-S batteries

NASA Astrophysics Data System (ADS)

Tan, Guoqiang; Xu, Rui; Xing, Zhenyu; Yuan, Yifei; Lu, Jun; Wen, Jianguo; Liu, Cong; Ma, Lu; Zhan, Chun; Liu, Qi; Wu, Tianpin; Jian, Zelang; Shahbazian-Yassar, Reza; Ren, Yang; Miller, Dean J.; Curtiss, Larry A.; Ji, Xiulei; Amine, Khalil

2017-07-01

Tremendous efforts have been made to design the cathode of Li-S batteries to improve their energy density and cycling life. However, challenges remain in achieving fast electronic and ionic transport while accommodating the significant cathode volumetric change, especially for the cathode with a high practical mass loading. Here we report a cathode architecture, which is constructed by burning lithium foils in a CS2 vapour. The obtained structure features crystalline Li2S nanoparticles wrapped by few-layer graphene (Li2S@graphene nanocapsules). Because of the improvement on the volumetric efficiency for accommodating sulfur active species and electrical properties, the cathode design enables promising electrochemical performance. More notably, at a loading of 10 mgLi2S cm-2, the electrode exhibits a high reversible capacity of 1,160 mAh g-1s, namely, an area capacity of 8.1 mAh cm-2. Li2S@graphene cathode demonstrates a great potential for Li-ion batteries, where the Li2S@graphene-cathode//graphite-anode cell displays a high capacity of 730 mAh g-1s as well as stable cycle performance.

High-pressure synthesis and electrochemical behavior of layered (1-a)LiNi{sub 1-y}Al{sub y}O{sub 2}.aLi[Li{sub 1/3}Ni{sub 2/3}]O{sub 2} oxides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shinova, E.; Zhecheva, E.; Stoyanova, R.

Layered (1-a)LiNi{sub 1-y}Al{sub y}O{sub 2}.aLi[Li{sub 1/3}Ni{sub 2/3}]O{sub 2} oxides, 0=Li{sub 2}O{sub 2} under high pressure. The structural characterization of the layered oxides was performed using powder XRD, IR spectroscopy and EPR spectroscopy at 9.23 and 115GHz. It has been found that the high-pressure favors Al substitution for Ni in the NiO{sub 2}-layers of layered LiNiO{sub 2}. A random Al/Ni distribution in the layer was found. The incorporation of extra Li in the Ni{sub 1-y}Al{sub y}O{sub 2}-layer starts at a precursor composition Li/(Ni+Al)>1.2. While pure NiO{sub 2}-layersmore » are able to incorporate under high-pressure up to 1/3Li, the appearance of Al in the NiO{sub 2}-layers hinders Li{sup +} dissolution (Li<(1-y)/3). In addition, with increasing Al content there is a strong cationic mixing between the layers. High-frequency EPR of Ni{sup 3+} indicates that the structural interaction of LiAl{sub y}Ni{sub 1-y}O{sub 2} with Li[Li{sub 1/3}Ni{sub 2/3}]O{sub 2} proceeds via the formation of domains comprising different amount of Ni{sup 3+} ions. The use of Li{sub 1.08}Al{sub 0.09}Ni{sub 0.83}O{sub 2} as a cathode material in a lithium ion cells displays a first irreversible Li extraction at 4.8V, after which a reversible lithium insertion/extraction between 3.0 and 4.5V is observed on further cycling.« less

[Summary of professor YANG Jun's experience for intractable facial paralysis].

PubMed

Wang, Tao; Li, Zaiyuan; Ge, Tingqiu; Zhang, Man; Yuan, Aihong; Yang, Jun

2017-06-12

Professor YANG Jun 's experience of diagnosis and treatment for intractable facial paralysis is introduced. Professor YANG focuses on the thinking model that combines TCM, western medicine and acupuncture, and adopts the differentiation system that combines disease differentiation, syndrome differentiation and meridian differentiation; he adopts the treatment integrates etiological treatment, overall regulation, symptomatic treatment as well as acupuncture, moxibustion, medication and flash cupping. The acupoints of yangming meridians are mostly selected, and acupoints of governor vessel such as Dazhui (GV 14) and Jinsuo (GV 8) are highly valued. The multiple-needles shallow-penetration-insertion twirling lifting and thrusting technique are mostly adopted to achieve slow and mild acupuncture sensation; in addition, the facial muscles are pulled up with mechanics action. The intensive stimulation with electroacupuncture is recommended at Qianzheng (Extra), Yifeng (TE 17) and Yangbai (GB 14), which is given two or three treatments per week.

The Nature of Electrochemical Delithiation of Li-Mg Alloy Electrodes: Neutron Computed Tomography and Modeling of Li Diffusion and Delithiation Phenomenon

DOE PAGES

Zhang, Yuxuan; Chandran, K.S. Ravi; Jagannathan, M.; ...

2016-12-05

Li-Mg alloys are promising as positive electrodes (anodes) for Li-ion batteries due to the high Li storage capacity and the relatively lower volume change during the lithiation/delithiation process. They also present a unique opportunity to image the Li distribution through the electrode thickness at various delithiation states. In this work, spatial distributions of Li in electrochemically delithiated Li-Mg alloy electrodes have been quantitatively determined using neutron tomography. Specifically, the Li concentration profiles along thickness direction are determined. A rigorous analytical model to quantify the diffusion-controlled delithiation, accompanied by phase transition and boundary movement, has also been developed to explain themore » delithiation mechanism. The analytical modeling scheme successfully predicted the Li concentration profiles which agreed well with the experimental data. It is demonstrated that during discharge Li is removed by diffusion through the solid solution Li-Mg phases and this proceeds with β→α phase transition and the associated phase boundary movement through the thickness of the electrode. This is also accompanied by electrode thinning due to the change in molar volume during delithiation. In conclusion, following the approaches developed here, one can develop a rigorous and quantitative understanding of electrochemical delithiation in electrodes of electrochemical cells, similar to that in the present Li-Mg electrodes.« less

The Nature of Electrochemical Delithiation of Li-Mg Alloy Electrodes: Neutron Computed Tomography and Modeling of Li Diffusion and Delithiation Phenomenon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Yuxuan; Chandran, K.S. Ravi; Jagannathan, M.

Li-Mg alloys are promising as positive electrodes (anodes) for Li-ion batteries due to the high Li storage capacity and the relatively lower volume change during the lithiation/delithiation process. They also present a unique opportunity to image the Li distribution through the electrode thickness at various delithiation states. In this work, spatial distributions of Li in electrochemically delithiated Li-Mg alloy electrodes have been quantitatively determined using neutron tomography. Specifically, the Li concentration profiles along thickness direction are determined. A rigorous analytical model to quantify the diffusion-controlled delithiation, accompanied by phase transition and boundary movement, has also been developed to explain themore » delithiation mechanism. The analytical modeling scheme successfully predicted the Li concentration profiles which agreed well with the experimental data. It is demonstrated that during discharge Li is removed by diffusion through the solid solution Li-Mg phases and this proceeds with β→α phase transition and the associated phase boundary movement through the thickness of the electrode. This is also accompanied by electrode thinning due to the change in molar volume during delithiation. In conclusion, following the approaches developed here, one can develop a rigorous and quantitative understanding of electrochemical delithiation in electrodes of electrochemical cells, similar to that in the present Li-Mg electrodes.« less