Near-Infrared Spectroscopic Study of Supernova Ejecta and Supernova Dust in Cassiopeia A

NASA Astrophysics Data System (ADS)

Lee, Yong-Hyun; Koo, Bon-Chul; Moon, Dae-Sik; Lee, Jae-Joon; Burton, Michael G.

2016-06-01

We have carried out near-infrared (NIR) spectroscopic observations of the Cassiopeia A supernova (SN) remnant. We obtained medium-resolution, JHK (0.95 - 2.46 µm) spectra around the main ejecta shell. Using a clump-finding algorithm, we identified 63 'knots' in the two-dimensional dispersed images, and derived their spectroscopic properties. We first present the result of spectral classification of the knots using Principal Component (PC) Analysis. We found that the NIR spectral characteristics of the knots can be mostly (85%) represented by three PCs composed of different sets of emission lines: (1) recombination lines of H and He together with [N I] lines, (2) forbidden lines of Si, P, and S lines, and (3) forbidden Fe lines. The distribution of the knots in the PC planes matches well with the above spectral groups, and we classified the knots into the three corresponding groups, i.e., He-rich, S-rich, and Fe-rich knots. The kinematic and chemical properties of the former two groups match well with those of Quasi-Stationary Flocculi and Fast-Moving Knots known from optical studies. The Fe-rich knots show intermediate characteristics between the former two groups, and we suggest that they are the SN ejecta material from the innermost layer of the progenitor. We also present the results of extinction measurements using the flux ratios between the two NIR [Fe II] lines at 1.257 and 1.644 µm. We have found a clear correlation between the NIR extinction and the radial velocity of ejecta knots, indicating the presence of a large amount of SN dust inside and around the main ejecta shell. In a southern part of the ejecta shell, by analyzing the NIR extinction together with far-infrared thermal dust emission, we show that there are warm (˜100 K) and cool (˜40 K) SN dust components and that the former needs to be silicate grains while the latter, which is responsible for the observed NIR extinction, could be either small (.0.01 µm) Fe or large (&0.1 µm) Si grains. We

Infrared Imaging, Spectroscopic, and Photometric Studies of Comets

NASA Technical Reports Server (NTRS)

Gehrz, Robert D.

1997-01-01

We have continued our program of infrared (IR) photometric, imaging, spectroscopic, and polarimetric temporal observations of comets to study the properties of comet dust and comet nuclei. During the first two years we digitized our IR data base on P/Halley and other recent comets to facilitate further analysis and comparison with other data bases, and found compelling evidence for the emission of a burst of small grains from P/Halley's nucleus at perihelion. We reported imaging and photometric observations of Comets Austin 1990 V and Swift-Tuttle 1992. The Swift-Tuttle 1992t observations included IR photometry, several 7-14 micron long-slit spectra of the coma and a time-sequence of more than 150 10 micron broadband images of the coma. An analysis of near-IR images of the inner coma of P/Halley obtained on three consecutive nights in 1986 March showed sunwardjets. We completed our analysis of IR imaging spectrosco-photometric data on comets. We also obtained observations of Comets Hyakutake 1996 B2 and Hale/Bopp 1995 01. We obtained infrared imaging, photometric, spectroscopic and polarimetric temporal observations of bright comets using a network of five telescopes, with emphasis on simultaneous observations of comets at many wavelengths with different instruments. Our program offers several unique advantages: 1) rapid observational response to new comets with dedicated infrared telescopes; 2) observations within a few degrees of the sun when comets are near perihelion and 3) access to advanced infrared array imagers and spectrometers. In particular, reduction, analysis, publication and archiving of our Jupiter/sl-9 and Comet Hyakutake infrared data received special emphasis. Instrumentation development included installation of the latest version of the innovative FORTH telescope control and a data acquisition system that enables us to control three telescopes remotely by telephone from anywhere in the world for comet observations in broad daylight. We have

Evaluating the health of compromised tissues using a near-infrared spectroscopic imaging system in clinical settings: lessons learned

NASA Astrophysics Data System (ADS)

Leonardi, Lorenzo; Sowa, Michael G.; Hewko, Mark D.; Schattka, Bernhard J.; Payette, Jeri R.; Hastings, Michelle; Posthumus, Trevor B.; Mantsch, Henry H.

2003-07-01

The present and accepted standard for determining the status of tissue relies on visual inspection of the tissue. Based on the surface appearance of the tissue, medical personnel will make an assessment of the tissue and proceed to a course of action or treatment. Visual inspection of tissue is central to many areas of clinical medicine, and remains a cornerstone of dermatology, reconstructive plastic surgery, and in the management of chronic wounds, and burn injuries. Near infrared spectroscopic imaging holds the promise of being able to monitor the dynamics of tissue physiology in real-time and detect pathology in living tissue. The continuous measurement of metabolic, physiological, or structural changes in tissue is of primary concern in many clinical and biomedical domains. A near infrared hyperspectral imaging system was constructed for the assessment of burn injuries and skin flaps or skin grafts. This device merged basic science with engineering and integrated manufacturing to develop a device suitable to detect ischemic tissue. This device has the potential of providing measures of tissue physiology, oxygen delivery and tissue hydration during patient screening, in the operating room or during therapy and post-operative/treatment monitoring. Results from a pre-clinical burn injury study will be presented.

Integrated photonics for infrared spectroscopic sensing

NASA Astrophysics Data System (ADS)

Lin, Hongtao; Kita, Derek; Han, Zhaohong; Su, Peter; Agarwal, Anu; Yadav, Anupama; Richardson, Kathleen; Gu, Tian; Hu, Juejun

2017-05-01

Infrared (IR) spectroscopy is widely recognized as a gold standard technique for chemical analysis. Traditional IR spectroscopy relies on fragile bench-top instruments located in dedicated laboratory settings, and is thus not suitable for emerging field-deployed applications such as in-line industrial process control, environmental monitoring, and point-ofcare diagnosis. Recent strides in photonic integration technologies provide a promising route towards enabling miniaturized, rugged platforms for IR spectroscopic analysis. Chalcogenide glasses, the amorphous compounds containing S, Se or Te, have stand out as a promising material for infrared photonic integration given their broadband infrared transparency and compatibility with silicon photonic integration. In this paper, we discuss our recent work exploring integrated chalcogenide glass based photonic devices for IR spectroscopic chemical analysis, including on-chip cavityenhanced chemical sensing and monolithic integration of mid-IR waveguides with photodetectors.

A Near-Infrared Spectrometer Based on Novel Grating Light Modulators

PubMed Central

Wei, Wei; Huang, Shanglian; Wang, Ning; Jin, Zhu; Zhang, Jie; Chen, Weimin

2009-01-01

A near-infrared spectrometer based on novel MOEMS grating light modulators is proposed. The spectrum detection method that combines a grating light modulator array with a single near-infrared detector has been applied. Firstly, optics theory has been used to analyze the essential principles of the proposed spectroscopic sensor. Secondly, the grating light modulators have been designed and fabricated by micro-machining technology. Finally, the principles of this spectroscopic sensor have been validated and its key parameters have been tested by experiments. The result shows that the spectral resolution is better than 10 nm, the wavelength deviation is less than 1 nm, the deviation of the intensity of peak wavelength is no more than 0.5%, the driving voltage of grating light modulators array device is below 25 V and the response frequency of it is about 5 kHz. With low cost, satisfactory precision, portability and other advantages, the spectrometer should find potential applications in food safety and quality monitoring, pharmaceutical identification and agriculture product quality classification. PMID:22574065

A near-infrared spectrometer based on novel grating light modulators.

PubMed

Wei, Wei; Huang, Shanglian; Wang, Ning; Jin, Zhu; Zhang, Jie; Chen, Weimin

2009-01-01

A near-infrared spectrometer based on novel MOEMS grating light modulators is proposed. The spectrum detection method that combines a grating light modulator array with a single near-infrared detector has been applied. Firstly, optics theory has been used to analyze the essential principles of the proposed spectroscopic sensor. Secondly, the grating light modulators have been designed and fabricated by micro-machining technology. Finally, the principles of this spectroscopic sensor have been validated and its key parameters have been tested by experiments. The result shows that the spectral resolution is better than 10 nm, the wavelength deviation is less than 1 nm, the deviation of the intensity of peak wavelength is no more than 0.5%, the driving voltage of grating light modulators array device is below 25 V and the response frequency of it is about 5 kHz. With low cost, satisfactory precision, portability and other advantages, the spectrometer should find potential applications in food safety and quality monitoring, pharmaceutical identification and agriculture product quality classification.

Resonant antenna probes for tip-enhanced infrared near-field microscopy.

PubMed

Huth, Florian; Chuvilin, Andrey; Schnell, Martin; Amenabar, Iban; Krutokhvostov, Roman; Lopatin, Sergei; Hillenbrand, Rainer

2013-03-13

We report the development of infrared-resonant antenna probes for tip-enhanced optical microscopy. We employ focused-ion-beam machining to fabricate high-aspect ratio gold cones, which replace the standard tip of a commercial Si-based atomic force microscopy cantilever. Calculations show large field enhancements at the tip apex due to geometrical antenna resonances in the cones, which can be precisely tuned throughout a broad spectral range from visible to terahertz frequencies by adjusting the cone length. Spectroscopic analysis of these probes by electron energy loss spectroscopy, Fourier transform infrared spectroscopy, and Fourier transform infrared near-field spectroscopy corroborates their functionality as resonant antennas and verifies the broad tunability. By employing the novel probes in a scattering-type near-field microscope and imaging a single tobacco mosaic virus (TMV), we experimentally demonstrate high-performance mid-infrared nanoimaging of molecular absorption. Our probes offer excellent perspectives for optical nanoimaging and nanospectroscopy, pushing the detection and resolution limits in many applications, including nanoscale infrared mapping of organic, molecular, and biological materials, nanocomposites, or nanodevices.

Infrared spectroscopy and spectroscopic imaging in forensic science.

PubMed

Ewing, Andrew V; Kazarian, Sergei G

2017-01-16

Infrared spectroscopy and spectroscopic imaging, are robust, label free and inherently non-destructive methods with a high chemical specificity and sensitivity that are frequently employed in forensic science research and practices. This review aims to discuss the applications and recent developments of these methodologies in this field. Furthermore, the use of recently emerged Fourier transform infrared (FT-IR) spectroscopic imaging in transmission, external reflection and Attenuated Total Reflection (ATR) modes are summarised with relevance and potential for forensic science applications. This spectroscopic imaging approach provides the opportunity to obtain the chemical composition of fingermarks and information about possible contaminants deposited at a crime scene. Research that demonstrates the great potential of these techniques for analysis of fingerprint residues, explosive materials and counterfeit drugs will be reviewed. The implications of this research for the examination of different materials are considered, along with an outlook of possible future research avenues for the application of vibrational spectroscopic methods to the analysis of forensic samples.

Introducing cymantrene labels into scattering scanning near-field infrared microscopy.

PubMed

Kopf, Ilona; N'Dongo, Harmel W Peindy; Ballout, Fouad; Schatzschneider, Ulrich; Bründermann, Erik; Havenith, Martina

2012-11-07

In this paper we investigate metal-organic compounds as infrared (IR) active labels by scattering scanning near-field infrared microscopy (IR s-SNOM, often also abbreviated as s-SNIM) with a lateral resolution of 90 × 90 nm(2). Tailor-made IR spectroscopic probes based on cymantrene (CpMn(CO)(3) with Cp = η(5)-C(5)H(5)) conjugated to a cysteine-modified pseudoneurotensin (pNT-Cys-OH) peptide were prepared by automated microwave-assisted solid phase peptide synthesis (SPPS) and characterized by HPLC, ESI-MS and IR. Well-defined patterned self-assembled monolayers on a gold surface were prepared by microcontact printing of 1-octadecanethiol (ODT) followed by additional incubation in ethanolic solution of the cymantrene-peptide derivative. The self-assembled monolayers have been evidenced by infrared reflection absorption spectroscopy (IRRAS) and AFM. CO laser source radiation was tuned (1944, 1900, 1798 and 1658 cm(-1)) for imaging contrast with good matching correlation between spectroscopic and topographic patterns at specific characteristic metal carbonyl and amide bands (1944 cm(-1) (λ = 5.14 μm) and 1658 cm(-1) (λ = 6.03 μm)). Cymantrene probes provide an attractive method to tag a unique spectroscopic feature on any bio(macro)molecule. Introducing such probes into super-resolution IR s-SNOM will enable molecular tracking and distribution studies even in complex biological systems.

Near-infrared oxygen airglow from the Venus nightside

NASA Technical Reports Server (NTRS)

Crisp, D.; Meadows, V. S.; Allen, D. A.; Bezard, B.; Debergh, C.; Maillard, J.-P.

1992-01-01

Groundbased imaging and spectroscopic observations of Venus reveal intense near-infrared oxygen airglow emission from the upper atmosphere and provide new constraints on the oxygen photochemistry and dynamics near the mesopause (approximately 100 km). Atomic oxygen is produced by the Photolysis of CO2 on the dayside of Venus. These atoms are transported by the general circulation, and eventually recombine to form molecular oxygen. Because this recombination reaction is exothermic, many of these molecules are created in an excited state known as O2(delta-1). The airglow is produced as these molecules emit a photon and return to their ground state. New imaging and spectroscopic observations acquired during the summer and fall of 1991 show unexpected spatial and temporal variations in the O2(delta-1) airglow. The implications of these observations for the composition and general circulation of the upper venusian atmosphere are not yet understood but they provide important new constraints on comprehensive dynamical and chemical models of the upper mesosphere and lower thermosphere of Venus.

Infrared spectroscopic imaging for noninvasive detection of latent fingerprints.

PubMed

Crane, Nicole J; Bartick, Edward G; Perlman, Rebecca Schwartz; Huffman, Scott

2007-01-01

The capability of Fourier transform infrared (FTIR) spectroscopic imaging to provide detailed images of unprocessed latent fingerprints while also preserving important trace evidence is demonstrated. Unprocessed fingerprints were developed on various porous and nonporous substrates. Data-processing methods used to extract the latent fingerprint ridge pattern from the background material included basic infrared spectroscopic band intensities, addition and subtraction of band intensity measurements, principal components analysis (PCA) and calculation of second derivative band intensities, as well as combinations of these various techniques. Additionally, trace evidence within the fingerprints was recovered and identified.

Comment on "A spectroscopic comparison of selected Chinese kaolinite, coal bearing kaolinite and halloysite--a mid-infrared and near-infrared study" and "Infrared and infrared emission spectroscopic study of typical Chinese kaolinite and halloysite" by Hongfei Cheng et al. (2010).

PubMed

Kloprogge, J Theo

2015-02-05

In two papers Cheng et al. (2010) reported in this journal on the mid-infrared, near-infrared and infrared emission spectroscopy of a halloysite from Hunan Xianrenwan, China. This halloysite contains around 8% of quartz (SiO2) and nearly 9% gibbsite (Al(OH)3). In their interpretation of the spectra these impurities were completely ignored. Careful comparison with a phase pure halloysite from Southern Belgium, synthetic gibbsite, gibbsite from Minas Gerais, and quartz show that these impurities do have a marked influence on the mid-infrared and infrared emission spectra. In the near-infrared, the effect is much less pronounced. Quartz does not show bands in this region and the gibbsite bands will be very weak. Comparison still show that the presence of gibbsite does contribute to the overall spectrum and bands that were ascribed to the halloysite alone do coincide with those of gibbsite. Copyright © 2014 Elsevier B.V. All rights reserved.

Near infrared spectroscopy for prediction of antioxidant compounds in the honey.

PubMed

Escuredo, Olga; Seijo, M Carmen; Salvador, Javier; González-Martín, M Inmaculada

2013-12-15

The selection of antioxidant variables in honey is first time considered applying the near infrared (NIR) spectroscopic technique. A total of 60 honey samples were used to develop the calibration models using the modified partial least squares (MPLS) regression method and 15 samples were used for external validation. Calibration models on honey matrix for the estimation of phenols, flavonoids, vitamin C, antioxidant capacity (DPPH), oxidation index and copper using near infrared (NIR) spectroscopy has been satisfactorily obtained. These models were optimised by cross-validation, and the best model was evaluated according to multiple correlation coefficient (RSQ), standard error of cross-validation (SECV), ratio performance deviation (RPD) and root mean standard error (RMSE) in the prediction set. The result of these statistics suggested that the equations developed could be used for rapid determination of antioxidant compounds in honey. This work shows that near infrared spectroscopy can be considered as rapid tool for the nondestructive measurement of antioxidant constitutes as phenols, flavonoids, vitamin C and copper and also the antioxidant capacity in the honey. Copyright © 2013 Elsevier Ltd. All rights reserved.

Near- and far-field spectroscopic imaging investigation of resonant square-loop infrared metasurfaces.

PubMed

D' Archangel, Jeffrey; Tucker, Eric; Kinzel, Ed; Muller, Eric A; Bechtel, Hans A; Martin, Michael C; Raschke, Markus B; Boreman, Glenn

2013-07-15

Optical metamaterials have unique properties which result from geometric confinement of the optical conductivity. We developed a series of infrared metasurfaces based on an array of metallic square loop antennas. The far-field absorption spectrum can be designed with resonances across the infrared by scaling the geometric dimensions. We measure the amplitude and phase of the resonant mode as standing wave patterns within the square loops using scattering-scanning near-field optical microscopy (s-SNOM). Further, using a broad-band synchrotron-based FTIR microscope and s-SNOM at the Advanced Light Source, we are able to correlate far-field spectra to near-field modes of the metasurface as the resonance is tuned between samples. The results highlight the importance of multi-modal imaging for the design and characterization of optical metamaterials.

Near-infrared spectroscopic observations of massive young stellar object candidates in the central molecular zone

NASA Astrophysics Data System (ADS)

Nandakumar, G.; Schultheis, M.; Feldmeier-Krause, A.; Schödel, R.; Neumayer, N.; Matteucci, F.; Ryde, N.; Rojas-Arriagada, A.; Tej, A.

2018-01-01

Context. The central molecular zone (CMZ) is a 200 pc region around the Galactic centre. The study of star formation in the central part of the Milky Way is of great interest as it provides a template for the closest galactic nuclei. Aims: We present a spectroscopic follow-up of photometrically selected young stellar object (YSO) candidates in the CMZ of the Galactic centre. Our goal is to quantify the contamination of this YSO sample by reddened giant stars with circumstellar envelopes and to determine the star formation rate (SFR) in the CMZ. Methods: We obtained KMOS low-resolution near-infrared spectra (R 4000) between 2.0 and 2.5 μm of sources, many of which have been previously identified by mid-infrared photometric criteria as massive YSOs in the Galactic centre. Our final sample consists of 91 stars with good signal-to-noise ratio. We separated YSOs from cool late-type stars based on spectral features of CO and Brγ at 2.3 μm and 2.16 μm, respectively. We made use of spectral energy distribution (SED) model fits to the observed photometric data points from 1.25 to 24 μm to estimate approximate masses for the YSOs. Results: Using the spectroscopically identified YSOs in our sample, we confirm that existing colour-colour diagrams and colour-magnitude diagrams are unable to efficiently separate YSOs and cool late-type stars. In addition, we define a new colour-colour criterion that separates YSOs from cool late-type stars in the H-KS vs. H -[8.0] diagram. We use this new criterion to identify YSO candidates in the |l| < 1.̊5, |b| < 0.̊5, region and use model SED fits to estimate their approximate masses. By assuming an appropriate initial mass function (IMF) and extrapolating the stellar IMF down to lower masses, we determine a SFR of 0.046 ± 0.026 M⊙ yr-1 assuming an average age of 0.75 ± 0.25 Myr for the YSOs. This value is lower than estimates found using the YSO counting method in the literature. Conclusions: Our SFR estimate in the CMZ agrees

Influence of earlobe thickness on near infrared spectroscopy

NASA Astrophysics Data System (ADS)

Jiang, Jingying; Wang, Tianpei; Li, Si; Li, Lin; Liu, Jiajia; Xu, Kexin

2017-03-01

Near-infrared spectroscopy has been recognized as a potential technology for noninvasive blood glucose sensing. However, the detected spectral signal is unstable mainly because of (1) the weak light absorption of glucose itself within NIR range, (2) the influence of temperature and individual differences of biotissue. Our previous results demonstrated that the synergistic effect of both transmittance and reflectance could enhance the strength of the detection signal. In this talk, we design a set of experiments to analyze the effect of earlobe thickness on Near Infrared spectroscopic measurement by using home-made optical fiber probe within the wavelength of 1000-1600nm. Firstly, we made a MC simulation of single-layer skin model and five-layer skin model to get the diffused transmittance spectra and diffused reflectance spectra under different optaical path lengths. And then we obtain the spectra of the earlobes from different volunteers by the same way. The experimental results showed that with the increase of the thickness,the light intensity of diffused transmittance decreases, and the light intensity of diffused reflectance remaines substantially unchanged.

Near-infrared Spectroscopic Observations of Comet C/2013 R1 (Lovejoy) by WINERED: CN Red-system Band Emission

NASA Astrophysics Data System (ADS)

Shinnaka, Yoshiharu; Kawakita, Hideyo; Kondo, Sohei; Ikeda, Yuji; Kobayashi, Naoto; Hamano, Satoshi; Sameshima, Hiroaki; Fukue, Kei; Matsunaga, Noriyuki; Yasui, Chikako; Izumi, Natsuko; Mizumoto, Misaki; Otsubo, Shogo; Takenaka, Keiichi; Watase, Ayaka; Kawanishi, Takafumi; Nakanishi, Kenshi; Nakaoka, Tetsuya

2017-08-01

Although high-resolution spectra of the CN red-system band are considered useful in cometary sciences, e.g., in the study of isotopic ratios of carbon and nitrogen in cometary volatiles, there have been few reports to date due to the lack of high-resolution (R ≡ λ/Δλ > 20,000) spectrographs in the near-infrared region around ˜1 μm. Here, we present the high-resolution emission spectrum of the CN red-system band in comet C/2013 R1 (Lovejoy), acquired by the near-infrared high-resolution spectrograph WINERED mounted on the 1.3 m Araki telescope at the Koyama Astronomical Observatory, Kyoto, Japan. We applied our fluorescence excitation models for CN, based on modern spectroscopic studies, to the observed spectrum of comet C/2013 R1 (Lovejoy) to search for CN isotopologues (13C14N and 12C15N). We used a CN fluorescence excitation model involving both a “pure” fluorescence excitation model for the outer coma and a “fully collisional” fluorescence excitation model for the inner coma region. Our emission model could reproduce the observed 12C14N red-system band of comet C/2013 R1 (Lovejoy). The derived mixing ratio between the two excitation models was 0.94(+0.02/-0.03):0.06(+0.03/-0.02), corresponding to the radius of the collision-dominant region of ˜800-1600 km from the nucleus. No isotopologues were detected. The observed spectrum is consistent, within error, with previous estimates in comets of 12C/13C (˜90) and 14N/15N (˜150).

Near-Infrared Spectroscopy of Henan and Watsonia Family Asteroids

NASA Astrophysics Data System (ADS)

Bus, S. J.; Binzel, R. P.; Sunshine, J.; Burbine, T. H.; McCoy, T. J.

2002-09-01

We present visible and near-infrared spectra for members of both the Henan and Watsonia asteroid families. These two families are known to contain asteroids belonging to the taxonomic L class based on visible wavelength spectroscopy obtained during the second phase of the Small Main-belt Asteroid Spectroscopic Survey (SMASSII, Bus and Binzel 2002, Icarus in press). The L-type asteroids have visible-wavelength spectra similar to those of K-types but with steeper spectral slopes shortward of 0.75 micron, becoming relatively flat longward of 0.75 micron and showing little or no concave curvature related to a 1 micron silicon absorption band. Our current study of the Henan and Watsonia families uses data obtained with SpeX, a medium-resolution near-infrared spectrograph available at the NASA Infrared Telescope Facility (IRTF) on Mauna Kea. When combined with the SMASSII results, we find the near-infrared spectra of these asteroids contains very weak 1 micron bands but have moderately deep 2 micron bands. A possible interpretation of this anomalous spectral signature is the presence of spinel, suggested by Burbine et al. (1992, Meteoritics 27, 424) for the asteroids 387 Aquitania and 980 Anacostia, both likely members of the Watsonia family (Bus 1999, Ph.D. thesis). The work of Burbine et al. made use of combined ECAS and 52-color measurements covering the visible and near-IR wavelengths out to 2.5 microns. We can now use the high signal-to-noise data obtained with SpeX to more fully explore the mineralogy of the taxonomic L class and to search for evidence of mineralogical variations among the Henan and Watsonia asteroid family members.

Generation of Mid-Infrared Frequency Combs for Spectroscopic Applications

NASA Astrophysics Data System (ADS)

Maser, Daniel L.

Mid-infrared laser sources prove to be a valuable tool in exploring a vast array of phenomena, finding their way into applications ranging from trace gas detection to X-ray generation and carbon dating. Mid-infrared frequency combs, in particular, are well-suited for many of these applications, owing to their inherent low-noise and broadband nature. Frequency comb technology is well-developed in the near-infrared as a result of immense technological development by the telecommunication industry in silica fiber and the existence of readily-available glass dopants such as ytterbium and erbium that enable oscillators at 1 and 1.5 ?m. However, options become substantially more limited at longer wavelengths, as silica is no longer transparent and the components required in a mid-infrared frequency comb system (oscillators, fibers, and both fiber and free-space components) are far less technologically mature. This thesis explores several different approaches to generating frequency comb sources in the mid-infrared region, and the development of sources used in the nonlinear processes implemented to reach these wavelengths. An optical parametric oscillator, two approaches to difference frequency generation, and nonlinear spectral broadening in chip-scale waveguides are developed, characterized, and spectroscopic potential for these techniques is demonstrated. The source used for these nonlinear processes, the erbium-doped fiber amplifier, is also studied and discussed throughout the design and optimization process. The nonlinear optical processes critical to this work are numerically modeled and used to confirm and predict experimental behavior.

Atmospheric and spectroscopic research in the far infrared

NASA Technical Reports Server (NTRS)

Park, Kwangjai; Radostitz, James V.

1992-01-01

The University of Oregon (UO) has been a major participant in the development of far infrared spectroscopic research of the stratosphere for the purpose of understanding the ozone layer processes. The UO has had a 15-year collaboration with the Italian group of B. Carli, and have participated in the 1978/79 Sub-millimeter Infrared Balloon Experiment (SIBEX), in the Balloon Intercomparison Campaign, (BIC), in the Infrared Balloon Experiment (IBEX), and in the recently concluded Far Infrared Experiment for UARS Correlative Measurements (FIREX). Both IBEX and FIREX programs were conducted in collaboration with NASA Langley, and were designed as validation flights in support of the Upper Atmosphere Research Satellite (UARS) Program. The technique of atmospheric far infrared spectroscopy offers two important advantages. First, many chemically important species can be measured simultaneously and co-spatially in the atmosphere. Second, far infrared atmospheric spectra can be obtained in thermal emission without reference to the sun's position, enabling full diurnal and global coverage. Recent improvements in instrumentation, field measurements, and molecular concentration retrieval techniques are now making the far infrared a mature measurement technology. This work to date has largely focused on balloon-based studies, but the future efforts will focus also on satellite-based experiments. A program of research in the following general areas was proposed: Laboratory Pressure broadening coefficient studies; specialized detector system assembly and testing; and consultation and assistance with instrument and field support. The proposal was approved and a three-year research grant titled 'Atmospheric and Spectroscopic Research in the Far Infrared' was awarded. A summary of technical accomplishments attained during the grant period are presented.

Far Infrared Synchrotron Near-Field Nanoimaging and Nanospectroscopy

DOE PAGES

Khatib, Omar; Bechtel, Hans A.; Martin, Michael C.; ...

2018-05-11

Here, scattering scanning near-field optical microscopy (s-SNOM) has emerged as a powerful imaging and spectroscopic tool for investigating nanoscale heterogeneities in biology, quantum matter, and electronic and photonic devices. However, many materials are defined by a wide range of fundamental molecular and quantum states at far-infrared (FIR) resonant frequencies currently not accessible by s-SNOM. Here we show ultrabroadband FIR s-SNOM nanoimaging and spectroscopy by combining synchrotron infrared radiation with a novel fast and low-noise copper-doped germanium (Ge:Cu) photoconductive detector. This approach of FIR synchrotron infrared nanospectroscopy (SINS) extends the wavelength range of s-SNOM to 31 μm (320 cm –1, 9.7more » THz), exceeding conventional limits by an octave to lower energies. We demonstrate this new nanospectroscopic window by measuring elementary excitations of exemplary functional materials, including surface phonon polariton waves and optical phonons in oxides and layered ultrathin van der Waals materials, skeletal and conformational vibrations in molecular systems, and the highly tunable plasmonic response of graphene.« less

Far Infrared Synchrotron Near-Field Nanoimaging and Nanospectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khatib, Omar; Bechtel, Hans A.; Martin, Michael C.

Here, scattering scanning near-field optical microscopy (s-SNOM) has emerged as a powerful imaging and spectroscopic tool for investigating nanoscale heterogeneities in biology, quantum matter, and electronic and photonic devices. However, many materials are defined by a wide range of fundamental molecular and quantum states at far-infrared (FIR) resonant frequencies currently not accessible by s-SNOM. Here we show ultrabroadband FIR s-SNOM nanoimaging and spectroscopy by combining synchrotron infrared radiation with a novel fast and low-noise copper-doped germanium (Ge:Cu) photoconductive detector. This approach of FIR synchrotron infrared nanospectroscopy (SINS) extends the wavelength range of s-SNOM to 31 μm (320 cm –1, 9.7more » THz), exceeding conventional limits by an octave to lower energies. We demonstrate this new nanospectroscopic window by measuring elementary excitations of exemplary functional materials, including surface phonon polariton waves and optical phonons in oxides and layered ultrathin van der Waals materials, skeletal and conformational vibrations in molecular systems, and the highly tunable plasmonic response of graphene.« less

Near-infrared imaging spectroscopy for counterfeit drug detection

NASA Astrophysics Data System (ADS)

Arnold, Thomas; De Biasio, Martin; Leitner, Raimund

2011-06-01

Pharmaceutical counterfeiting is a significant issue in the healthcare community as well as for the pharmaceutical industry worldwide. The use of counterfeit medicines can result in treatment failure or even death. A rapid screening technique such as near infrared (NIR) spectroscopy could aid in the search for and identification of counterfeit drugs. This work presents a comparison of two laboratory NIR imaging systems and the chemometric analysis of the acquired spectroscopic image data. The first imaging system utilizes a NIR liquid crystal tuneable filter and is designed for the investigation of stationary objects. The second imaging system utilizes a NIR imaging spectrograph and is designed for the fast analysis of moving objects on a conveyor belt. Several drugs in form of tablets and capsules were analyzed. Spectral unmixing techniques were applied to the mixed reflectance spectra to identify constituent parts of the investigated drugs. The results show that NIR spectroscopic imaging can be used for contact-less detection and identification of a variety of counterfeit drugs.

Near-infrared Spectroscopic Observations of Comet C/2013 R1 (Lovejoy) by WINERED: CN Red-system Band Emission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shinnaka, Yoshiharu; Yasui, Chikako; Izumi, Natsuko

Although high-resolution spectra of the CN red-system band are considered useful in cometary sciences, e.g., in the study of isotopic ratios of carbon and nitrogen in cometary volatiles, there have been few reports to date due to the lack of high-resolution ( R  ≡  λ /Δ λ  > 20,000) spectrographs in the near-infrared region around ∼1 μ m. Here, we present the high-resolution emission spectrum of the CN red-system band in comet C/2013 R1 (Lovejoy), acquired by the near-infrared high-resolution spectrograph WINERED mounted on the 1.3 m Araki telescope at the Koyama Astronomical Observatory, Kyoto, Japan. We applied our fluorescence excitation models for CN, based onmore » modern spectroscopic studies, to the observed spectrum of comet C/2013 R1 (Lovejoy) to search for CN isotopologues ({sup 13}C{sup 14}N and {sup 12}C{sup 15}N). We used a CN fluorescence excitation model involving both a “pure” fluorescence excitation model for the outer coma and a “fully collisional” fluorescence excitation model for the inner coma region. Our emission model could reproduce the observed {sup 12}C{sup 14}N red-system band of comet C/2013 R1 (Lovejoy). The derived mixing ratio between the two excitation models was 0.94(+0.02/−0.03):0.06(+0.03/−0.02), corresponding to the radius of the collision-dominant region of ∼800–1600 km from the nucleus. No isotopologues were detected. The observed spectrum is consistent, within error, with previous estimates in comets of {sup 12}C/{sup 13}C (∼90) and {sup 14}N/{sup 15}N (∼150).« less

Transcutaneous analyte measuring method (TAMM): a reflective, noninvasive, near-infrared blood chemistry analyzer

NASA Astrophysics Data System (ADS)

Schlager, Kenneth J.; Ruchti, Timothy L.

1995-04-01

TAMM for Transcutaneous Analyte Measuring Method is a near infrared spectroscopic technique for the noninvasive measurement of human blood chemistry. A near infrared indium gallium arsenide (InGaAs) photodiode array spectrometer has been developed and tested on over 1,000 patients as a part of an SBIR program sponsored by the Naval Medical Research and Development Command. Nine (9) blood analytes have been measured and evaluated during pre-clinical testing: sodium, chloride, calcium, potassium, bicarbonate, BUN, glucose, hematocrit and hemoglobin. A reflective rather than a transmissive invasive approach to measurement has been taken to avoid variations resulting from skin color and sensor positioning. The current status of the instrumentation, neural network pattern recognition algorithms and test results will be discussed.

Hydrogen diffusion in Zircon

NASA Astrophysics Data System (ADS)

Ingrin, Jannick; Zhang, Peipei

2016-04-01

Hydrogen mobility in gem quality zircon single crystals from Madagascar was investigated through H-D exchange experiments. Thin slices were annealed in a horizontal furnace flushed with a gas mixture of Ar/D2(10%) under ambient pressure between 900 ° C to 1150 ° C. FTIR analyses were performed on oriented slices before and after each annealing run. H diffusion along [100] and [010] follow the same diffusion law D = D0exp[-E /RT], with log D0 = 2.24 ± 1.57 (in m2/s) and E = 374 ± 39 kJ/mol. H diffusion along [001] follows a slightly more rapid diffusion law, with log D0 = 1.11 ± 0.22 (in m2/s) and E = 334 ± 49 kJ/mol. H diffusion in zircon has much higher activation energy and slower diffusivity than other NAMs below 1150 ° C even iron-poor garnets which are known to be among the slowest (Blanchard and Ingrin, 2004; Kurka et al. 2005). During H-D exchange zircon incorporates also deuterium. This hydration reaction involves uranium reduction as it is shown from the exchange of U5+ and U4+ characteristic bands in the near infrared region during annealing. It is the first time that a hydration reaction U5+ + OH- = U4+ + O2- + 1/2H2, is experimentally reported. The kinetics of deuterium incorporation is slightly slower than hydrogen diffusion, suggesting that the reaction is limited by hydrogen mobility. Hydrogen isotopic memory of zircon is higher than other NAMs. Zircons will be moderately retentive of H signatures at mid-crustal metamorphic temperatures. At 500 ° C, a zircon with a radius of 300 μm would retain its H isotopic signature over more than a million years. However, a zircon is unable to retain this information for geologically significant times under high-grade metamorphism unless the grain size is large enough. Refrences Blanchard, M. and Ingrin, J. (2004) Hydrogen diffusion in Dora Maira pyrope. Physics and Chemistry of Minerals, 31, 593-605. Kurka, A., Blanchard, M. and Ingrin, J. (2005) Kinetics of hydrogen extraction and deuteration in

LoCuSS: the near-infrared luminosity and weak-lensing mass scaling relation of galaxy clusters

NASA Astrophysics Data System (ADS)

Mulroy, Sarah L.; Smith, Graham P.; Haines, Chris P.; Marrone, Daniel P.; Okabe, Nobuhiro; Pereira, Maria J.; Egami, Eiichi; Babul, Arif; Finoguenov, Alexis; Martino, Rossella

2014-10-01

We present the first scaling relation between weak-lensing galaxy cluster mass, MWL, and near-infrared luminosity, LK. Our results are based on 17 clusters observed with wide-field instruments on Subaru, the United Kingdom Infrared Telescope, the Mayall Telescope, and the MMT. We concentrate on the relation between projected 2D weak-lensing mass and spectroscopically confirmed luminosity within 1 Mpc, modelled as M_WL ∝ LK^b, obtaining a power-law slope of b=0.83^{+0.27}_{-0.24} and an intrinsic scatter of σ _{lnM_WL|LK}=10^{+8}_{-5} per cent. Intrinsic scatter of ˜10 per cent is a consistent feature of our results regardless of how we modify our approach to measuring the relationship between mass and light. For example, deprojecting the mass and measuring both quantities within r500, that is itself obtained from the lensing analysis, yields σ _{lnM_WL|LK}=10^{+7}_{-5} per cent and b=0.97^{+0.17}_{-0.17}. We also find that selecting members based on their (J - K) colours instead of spectroscopic redshifts neither increases the scatter nor modifies the slope. Overall our results indicate that near-infrared luminosity measured on scales comparable with r500 (typically 1 Mpc for our sample) is a low scatter and relatively inexpensive proxy for weak-lensing mass. Near-infrared luminosity may therefore be a useful mass proxy for cluster cosmology experiments.

Atmospheric and Spectroscopic Research in the Far Infrared

NASA Technical Reports Server (NTRS)

Park, Kwangjai

2001-01-01

The University of Oregon (UO) was a participant in a number of far infrared spectroscopic projects over the past three decades. These include Sub-millimeter Infrared Balloon Experiment (SIBEX), the Balloon Intercomparison Campaign (BIC), and the Infrared Balloon Experiment (IBEX). In addition to these field studies, the UO program contained a detector research component and a laboratory spectroscopy element. Through a productive collaboration with Dr. Carli's group in Italy, with Prof. Ade's group in England and with Dr. Chance of Harvard-Smithsonian, we have made substantial contributions to the development of far infrared spectroscopy as a mature measurement technology for the atmospheric science. This report summarizes the activities during the latest grant period, covering the span from February 22, 1998 to February 21, 2002.

Rare earth-doped barium gallo-germanate glasses and their near-infrared luminescence properties.

PubMed

Pisarska, Joanna; Sołtys, Marta; Górny, Agata; Kochanowicz, Marcin; Zmojda, Jacek; Dorosz, Jan; Dorosz, Dominik; Sitarz, Maciej; Pisarski, Wojciech A

2018-08-05

Near-infrared luminescence properties of Nd 3+ and Ho 3+ ions in barium gallo-germanate glasses have been reported. Several spectroscopic parameters for Nd 3+ and Ho 3+ ions have been determined from the Judd-Ofelt analysis and absorption/luminescence measurements. Quite large luminescence lifetime, quantum efficiency and stimulated emission cross-section have been obtained for the main 4 F 3/2  →  4 I 11/2 (Nd 3+ ) and 5 I 7  →  5 I 8 (Ho 3+ ) laser transitions of rare earths in barium gallo-germanate glasses. It suggests that barium gallo-germanate glass is promising for near-infrared laser application at emission wavelengths 1064 nm (Nd 3+ ) and 2020 nm (Ho 3+ ). Copyright © 2018 Elsevier B.V. All rights reserved.

Infrared laser spectroscopic trace gas sensing

NASA Astrophysics Data System (ADS)

Sigrist, Markus

2016-04-01

Chemical sensing and analyses of gas samples by laser spectroscopic methods are attractive owing to several advantages such as high sensitivity and specificity, large dynamic range, multi-component capability, and lack of pretreatment or preconcentration procedures. The preferred wavelength range comprises the fundamental molecular absorption range in the mid-infared between 3 and 15 μm, whereas the near-infrared range covers the (10-100 times weaker) higher harmonics and combination bands. The availability of near-infrared and, particularly, of broadly tunable mid-infrared sources like external cavity quantum cascade lasers (EC-QCLs), interband cascade lasers (ICLs), difference frequency generation (DFG), optical parametric oscillators (OPOs), recent developments of diode-pumped lead salt semiconductor lasers, of supercontinuum sources or of frequency combs have eased the implementation of laser-based sensing devices. Sensitive techniques for molecular absorption measurements include multipass absorption, various configurations of cavity-enhanced techniques such as cavity ringdown (CRD), or of photoacoustic spectroscopy (PAS) including quartz-enhanced (QEPAS) or cantilever-enhanced (CEPAS) techniques. The application requirements finally determine the optimum selection of laser source and detection scheme. In this tutorial talk I shall discuss the basic principles, present various experimental setups and illustrate the performance of selected systems for chemical sensing of selected key atmospheric species. Applications include an early example of continuous vehicle emission measurements with a mobile CO2-laser PAS system [1]. The fast analysis of C1-C4 alkanes at sub-ppm concentrations in gas mixtures is of great interest for the petrochemical industry and was recently achieved with a new type of mid-infrared diode-pumped piezoelectrically tuned lead salt vertical external cavity surface emitting laser (VECSEL) [2]. Another example concerns measurements on short

Near Infrared Spectroscopic Identification of Alkyl Aromatic Esters and Phenyl Ketones

NASA Astrophysics Data System (ADS)

Nelyubov, D. V.; Vazhenin, D. A.; Kudriavtsev, A. A.; Buzolina, A. Yu.

2018-03-01

Bands characterizing the content of carbon atoms in alkyl (7177-7205 cm-1) and phenyl structural fragments (9175-9192 cm-1) in organic molecules were revealed by studying the near infrared spectra of such compounds. The optical density at the maxima of these absorption bands was shown to depend strongly on the fraction of carbon atoms in the corresponding fragments. The developed models proved to be adequate for determining the fraction of carbon atoms in alkyl aromatic esters and phenyl ketones. The feasibility of modeling the molecular structure of alkyl aromatic esters using regression models was demonstrated for the product of the condensation of oleic acid and benzyl alcohol.

The High AV Quasar Survey: Reddened Quasi-Stellar Objects Selected from Optical/Near-Infrared Photometry—II

NASA Astrophysics Data System (ADS)

Krogager, J.-K.; Geier, S.; Fynbo, J. P. U.; Venemans, B. P.; Ledoux, C.; Møller, P.; Noterdaeme, P.; Vestergaard, M.; Kangas, T.; Pursimo, T.; Saturni, F. G.; Smirnova, O.

2015-03-01

Quasi-stellar objects (QSOs) whose spectral energy distributions (SEDs) are reddened by dust either in their host galaxies or in intervening absorber galaxies are to a large degree missed by optical color selection criteria like the ones used by the Sloan Digital Sky Survey (SDSS). To overcome this bias against red QSOs, we employ a combined optical and near-infrared (near-IR) color selection. In this paper, we present a spectroscopic follow-up campaign of a sample of red candidate QSOs which were selected from the SDSS and the UKIRT Infrared Deep Sky Survey (UKIDSS). The spectroscopic data and SDSS/UKIDSS photometry are supplemented by mid-infrared photometry from the Wide-field Infrared Survey Explorer. In our sample of 159 candidates, 154 (97%) are confirmed to be QSOs. We use a statistical algorithm to identify sightlines with plausible intervening absorption systems and identify nine such cases assuming dust in the absorber similar to Large Magellanic Cloud sightlines. We find absorption systems toward 30 QSOs, 2 of which are consistent with the best-fit absorber redshift from the statistical modeling. Furthermore, we observe a broad range in SED properties of the QSOs as probed by the rest-frame 2 μm flux. We find QSOs with a strong excess as well as QSOs with a large deficit at rest-frame 2 μm relative to a QSO template. Potential solutions to these discrepancies are discussed. Overall, our study demonstrates the high efficiency of the optical/near-IR selection of red QSOs.

Infrared spectroscopic ellipsometry of micrometer-sized SiO2 line gratings

NASA Astrophysics Data System (ADS)

Walder, Cordula; Zellmeier, Matthias; Rappich, Jörg; Ketelsen, Helge; Hinrichs, Karsten

2017-09-01

For the design and process control of periodic nano-structured surfaces spectroscopic ellipsometry is already established in the UV-VIS spectral regime. The objective of this work is to show the feasibility of spectroscopic ellipsometry in the infrared, exemplarily, on micrometer-sized SiO2 line gratings grown on silicon wafers. The grating period ranges from 10 to about 34 μm. The IR-ellipsometric spectra of the gratings exhibit complex changes with structure variations. Especially in the spectral range of the oxide stretching modes, the presence of a Rayleigh singularity can lead to pronounced changes of the spectrum with the sample geometry. The IR-ellipsometric spectra of the gratings are well reproducible by calculations with the RCWA method (Rigorous Coupled Wave Analysis). Therefore, infrared spectroscopic ellipsometry allows the quantitative characterization and process control of micrometer-sized structures.

Mid-infrared and near-infrared spectroscopic study of selected magnesium carbonate minerals containing ferric iron-Implications for the geosequestration of greenhouse gases.

PubMed

Frost, Ray L; Reddy, B Jagannadha; Bahfenne, Silmarilly; Graham, Jessica

2009-04-01

The proposal to remove greenhouse gases by pumping liquefied CO(2) several kilometres below the ground implies that many carbonate containing minerals will be formed. Among these minerals brugnatellite and coalingite are probable. Two ferric ion bearing minerals brugnatellite and coalingite with a hydrotalcite-like structure have been characterised by a combination of infrared and near-infrared (NIR) spectroscopy. The infrared spectra of the OH stretching region are characterised by OH and water stretching vibrations. Both the first and second fundamental overtones of these bands are observed in the NIR spectra in the 7030-7235 cm(-1) and 10,490-10,570 cm(-1) regions. Intense (CO(3))(2-) symmetric and antisymmetric stretching vibrations support the concept that the carbonate ion is distorted. The position of the water bending vibration indicates the water is strongly hydrogen bonded in the mineral structure. Split NIR bands at around 8675 and 11,100 cm(-1) indicate that some replacement of magnesium ions by ferrous ions in the mineral structure has occurred. Near-infrared spectroscopy is ideal for the assessment of the formation of carbonate minerals.

Infrared Spectroscopic Imaging of Latent Fingerprints and Associated Forensic Evidence

PubMed Central

Chen, Tsoching; Schultz, Zachary D.; Levin, Ira W.

2011-01-01

Fingerprints reflecting a specific chemical history, such as exposure to explosives, are clearly distinguished from overlapping, and interfering latent fingerprints using infrared spectroscopic imaging techniques and multivariate analysis. PMID:19684917

Do Infants Recognize the Arcimboldo Images as Faces? Behavioral and Near-Infrared Spectroscopic Study

ERIC Educational Resources Information Center

Kobayashi, Megumi; Otsuka, Yumiko; Nakato, Emi; Kanazawa, So; Yamaguchi, Masami K.; Kakigi, Ryusuke

2012-01-01

Arcimboldo images induce the perception of faces when shown upright despite the fact that only nonfacial objects such as vegetables and fruits are painted. In the current study, we examined whether infants recognize a face in the Arcimboldo images by using the preferential looking technique and near-infrared spectroscopy (NIRS). In the first…

Near-near-infrared thermal lens spectroscopy to assess overtones and combination bands of sulfentrazone pesticide

NASA Astrophysics Data System (ADS)

Ventura, M.; Silva, J. R.; Andrade, L. H. C.; Scorza Júnior, R. P.; Lima, S. M.

2018-01-01

Thermal lens spectroscopy (TLS) in the near-near-infrared region was used to explore the absorptions of overtones and combination bands of sulfentrazone (SFZ) herbicide diluted in methanol. This spectroscopic region was chosen in order to guarantee that only thermal lens effect is noted during the experimental procedure. The results showed that it was possible to detect very low concentrations ( 2 ng/μL) of SFZ in methanol by determining its thermal diffusivity or the absorption coefficient due to the 3ν(NH) + 1δ(CH) combination band. This minimum SFZ concentration is the limit observed by chromatography method. The findings demonstrated that the TLS can be used for precise and accurate assessment of pesticides in ecosystems. Besides, the 3ν(NH) + 1δ(CH) combination band at 960 nm can be used as a marker for SFZ in methanol.

The Cassini mission: Infrared and microwave spectroscopic measurements

NASA Technical Reports Server (NTRS)

Kunde, V. G.

1989-01-01

The Cassini Orbiter and Titan Probe model payloads include a number of infrared and microwave instruments. This document describes: (1) the fundamental scientific objectives for Saturn and Titan which can be addressed by infrared and microwave instrumentation, (2) the instrument requirements and the accompanying instruments, and (3) the synergism resulting from the comprehensive coverage of the total infrared and microwave spectrum by the complement of individual instruments. The baseline consists of four instruments on the orbiter and two on the Titan probe. The orbiter infrared instruments are: (1) a microwave spectrometer and radiometer; (2) a far to mid-infrared spectrometer; (3) a pressure modulation gas correlation spectrometer, and (4) a near-infrared grating spectrometer. The two Titan probe infrared instruments are: (1) a near-infrared instrument, and (2) a tunable diode laser infrared absorption spectrometer and nephelometer.

Near infrared photometric and optical spectroscopic study of 22 low mass star clusters embedded in nebulae

NASA Astrophysics Data System (ADS)

Soares, J. B.; Bica, E.; Ahumada, A. V.; Clariá, J. J.

2008-02-01

Aims:Among the star clusters in the Galaxy, those embedded in nebulae represent the youngest group, which has only recently been explored. The analysis of a sample of 22 candidate embedded stellar systems in reflection nebulae and/or HII environments is presented. Methods: We employed optical spectroscopic observations of stars in the directions of the clusters carried out at CASLEO (Argentina) together with near infrared photometry from the 2MASS catalogue. Our analysis is based on source surface density, colour-colour diagrams and on theoretical pre-main sequence isochrones. We take into account the field star contamination by carrying out a statistical subtraction. Results: The studied objects have the characteristics of low mass systems. We derive their fundamental parameters. Most of the cluster ages are younger than 2 Myr. The studied embedded stellar systems in reflection nebulae and/or HII region complexes do not have stars of spectral types earlier than B. The total stellar masses locked in the clusters are in the range 20-220 M⊙. They are found to be gravitationally unstable and are expected to dissolve in a timescale of a few Myr. Based on observations made at Complejo Astronómico El Leoncito, which is operated under agreement between the Consejo Nacional de Investigaciones Científicas y Técnicas de la República Argentina and the National Universities of La Plata, Córdoba and San Juan, Argentina.

Near-infrared spectroscopy of candidate red supergiant stars in clusters

NASA Astrophysics Data System (ADS)

Messineo, Maria; Zhu, Qingfeng; Ivanov, Valentin D.; Figer, Donald F.; Davies, Ben; Menten, Karl M.; Kudritzki, Rolf P.; Chen, C.-H. Rosie

2014-11-01

Context. Clear identifications of Galactic young stellar clusters farther than a few kpc from the Sun are rare, despite the large number of candidate clusters. Aims: We aim to improve the selection of candidate clusters rich in massive stars with a multiwavelength analysis of photometric Galactic data that range from optical to mid-infrared wavelengths. Methods: We present a photometric and spectroscopic analysis of five candidate stellar clusters, which were selected as overdensities with bright stars (Ks< 7 mag) in GLIMPSE and 2MASS images. Results: A total of 48 infrared spectra were obtained. The combination of photometry and spectroscopy yielded six new red supergiant stars with masses from 10 M⊙ to 15 M⊙. Two red supergiants are located at Galactic coordinates (l,b) = (16.°7, -0.°63) and at a distance of about ~3.9 kpc; four other red supergiants are members of a cluster at Galactic coordinates (l,b) = (49.°3, + 0.°72) and at a distance of ~7.0 kpc. Conclusions: Spectroscopic analysis of the brightest stars of detected overdensities and studies of interstellar extinction along their line of sights are fundamental to distinguish regions of low extinction from actual stellar clusters. The census of young star clusters containing red supergiants is incomplete; in the existing all-sky near-infrared surveys, they can be identified as overdensities of bright stars with infrared color-magnitude diagrams characterized by gaps. Based on observations collected at the European Southern Observatory (ESO Programme 60.A-9700(E), and 089.D-0876), and on observations collected at the UKIRT telescope (programme ID H243NS).MM is currently employed by the MPIfR. Part of this work was performed at RIT (2009), at ESA (2010), and at the MPIfR.Tables 3, 4, and 6 are available in electronic form at http://www.aanda.org

Development of a new diffuse near-infrared food measuring

NASA Astrophysics Data System (ADS)

Zhang, Jun; Piao, Renguan

2006-11-01

Industries from agriculture to petrochemistry have found near infrared (NIR) spectroscopic analysis useful for quality control and quantitative analysis of materials and products. The general chemical, polymer chemistry, petrochemistry, agriculture, food and textile industries are currently using NIR spectroscopic methods for analysis. In this study, we developed a new sort NIR instrument for food measuring. The instrument consists of a light source, 12 filters to the prismatic part. The special part is that we use a mirror to get two beams of light. And two PbS detectors were used. One detector collected the radiation of one light beam directly and the value was set as the standard instead the standard white surface. Another light beam irradiate the sample surface, and the diffuse light was collected by another detector. The value of the two detectors was compared and the absorbency was computed. We tested the performance of the NIR instrument in determining the protein and fat content of milk powder. The calibration showed the accuracy of the instrument in practice.

Near Infrared Luminescence Properties of Mn(5+): Ca5(PO4)3F

NASA Technical Reports Server (NTRS)

Davis, Valetta R.; Hoemmerich, Uwe; Loutts, George B.

1997-01-01

We report a spectroscopic investigation of Mn(5+) doped Ca5(PO4)(sub 3)F or FAP. Mn(5+) doped crystals have recently attracted world wide attention for potential solid-state laser applications. Following optical excitation of Mn: FAP with the 600 nm output of a Nd: YAG OPO laser system, we observed a strong near infrared luminescence centered at around 1150 nm. The room temperature luminescence decay time was measured to be approximately 635 microseconds. We attribute the infrared luminescence to the(1)E yields (3)A2 transition of tetrahedrally coordinated Mn5+ ions located in a strong crystal field environment. Absorption, luminescence and lifetime data of Mn: FAP will be presented and discussed.

Pyropheophorbide A and c(RGDyK) comodified chitosan-wrapped upconversion nanoparticle for targeted near-infrared photodynamic therapy.

PubMed

Zhou, Aiguo; Wei, Yanchun; Wu, Baoyan; Chen, Qun; Xing, Da

2012-06-04

Near-infrared (NIR)-to-visible upconversion nanoparticle (UCNP) has shown promising prospects in photodynamic therapy (PDT) as a drug carrier or energy donor. In this work, a photosensitizer pyropheophorbide a (Ppa) and RGD peptide c(RGDyK) comodified chitosan-wrapped NaYF(4):Yb/Er upconversion nanoparticle UCNP-Ppa-RGD was developed for targeted near-infrared photodynamic therapy. The properties of UCNP-Ppa-RGD, such as morphology, stability, optical spectroscopy and singlet oxygen generation efficiency, were investigated. The results show that covalently linked pyropheophorbide a molecule not only is stable but also retains its spectroscopic and functional properties. In vitro studies confirm a stronger targeting specificity of UCNP-Ppa-RGD to integrin α(v)β(3)-positive U87-MG cells compared with that in the corresponding negative group. The photosensitizer-attached nanostructure exhibited low dark toxicity and high phototoxicity against cancer cells upon 980 nm laser irradiation at an appropriate dosage. These results represent the first demonstration of a highly stable and efficient photosensitizer modified upconversion nanostructure for targeted near-infrared photodynamic therapy of cancer cells. The novel UCNP-Ppa-RGD nanoparticle may provide a powerful alternative for near-infrared photodynamic therapy with an improved tumor targeting specificity.

Near-infrared spectral methods for noninvasively measuring blood glucose

NASA Astrophysics Data System (ADS)

Fei, Sun; Kong, Deyi; Mei, Tao; Tao, Yongchun

2004-05-01

Determination of blood glucose concentrations in diabetic patients is a frequently occurring procedure and an important tool for diabetes management. Use of noninvasive detection techniques can relieve patients from the pain of frequent finger pokes and avoid the infection of disease via blood. This thesis discusses current research and analyzes the advantages and shortages of different measurement methods, including: optical methods (Transmission, Polarimetry and scattering), then, we give emphasis to analyze the technology of near-infrared (NIR) spectra. NIR spectral range 700 nm ~2300 nm was used because of its good transparency for biological tissue and presence of glucose absorption band. In this work, we present an outline of noninvasive blood glucose measurement. A near-infrared light beam is passed through the finger, and the spectral components of the emergent beam are measured using spectroscopic techniques. The device includes light sources having the wavelengths of 600 nm - 1800 nm to illuminate the tissue. Receptors associated with the light sources for receiving light and generating a transmission signal representing the light transmitted are also provided. Once a transmission signal is received by receptors, and the high and low values from each of the signals are stored in the device. The averaged values are then analyzed to determine the glucose concentration, which is displayed on the device.

VICS82: The VISTA–CFHT Stripe 82 Near-infrared Survey

NASA Astrophysics Data System (ADS)

Geach, J. E.; Lin, Y.-T.; Makler, M.; Kneib, J.-P.; Ross, N. P.; Wang, W.-H.; Hsieh, B.-C.; Leauthaud, A.; Bundy, K.; McCracken, H. J.; Comparat, J.; Caminha, G. B.; Hudelot, P.; Lin, L.; Van Waerbeke, L.; Pereira, M. E. S.; Mast, D.

2017-07-01

We present the VISTA–CFHT Stripe 82 (VICS82) survey: a near-infrared (J+Ks) survey covering 150 square degrees of the Sloan Digital Sky Survey (SDSS) equatorial Stripe 82 to an average depth of J = 21.9 AB mag and Ks = 21.4 AB mag (80% completeness limits; 5σ point-source depths are approximately 0.5 mag brighter). VICS82 contributes to the growing legacy of multiwavelength data in the Stripe 82 footprint. The addition of near-infrared photometry to the existing SDSS Stripe 82 coadd ugriz photometry reduces the scatter in stellar mass estimates to δ {log}({M}\\star )≈ 0.3 dex for galaxies with {M}\\star > {10}9 {M}ȯ at z≈ 0.5, and offers improvement compared to optical-only estimates out to z≈ 1, with stellar masses constrained within a factor of approximately 2.5. When combined with other multiwavelength imaging of the Stripe, including moderate-to-deep ultraviolet (GALEX), optical and mid-infrared (Spitzer-IRAC) coverage, as well as tens of thousands of spectroscopic redshifts, VICS82 gives access to approximately 0.5 Gpc3 of comoving volume. Some of the main science drivers of VICS82 include (a) measuring the stellar mass function of {L}\\star galaxies out to z∼ 1; (b) detecting intermediate-redshift quasars at 2≲ z≲ 3.5; (c) measuring the stellar mass function and baryon census of clusters of galaxies, and (d) performing cross-correlation experiments of cosmic microwave background lensing in the optical/near-infrared that link stellar mass to large-scale dark matter structure. Here we define and describe the survey, highlight some early science results, and present the first public data release, which includes an SDSS-matched catalog as well as the calibrated pixel data themselves.

Near infrared lasers in flow cytometry.

PubMed

Telford, William G

2015-07-01

Technology development in flow cytometry has closely tracked laser technology, the light source that flow cytometers almost exclusively use to excite fluorescent probes. The original flow cytometers from the 1970s and 1980s used large water-cooled lasers to produce only one or two laser lines at a time. Modern cytometers can take advantage of the revolution in solid state laser technology to use almost any laser wavelength ranging from the ultraviolet to the near infrared. Commercial cytometers can now be equipped with many small solid state lasers, providing almost any wavelength needed for cellular analysis. Flow cytometers are now equipped to analyze 20 or more fluorescent probes simultaneously, requiring multiple laser wavelengths. Instrument developers are now trying to increase this number by designing fluorescent probes that can be excited by laser wavelength at the "edges" of the visible light range, in the near ultraviolet and near-infrared region. A variety of fluorescent probes have been developed that excite with violet and long wavelength ultraviolet light; however, the near-infrared range (660-800 nm) has yet seen only exploitation in flow cytometry. Fortunately, near-infrared laser diodes and other solid state laser technologies appropriate for flow cytometry have been in existence for some time, and can be readily incorporated into flow cytometers to accelerate fluorescent probe development. The near infrared region represents one of the last "frontiers" to maximize the number of fluorescent probes that can be analyzed by flow cytometry. In addition, near infrared fluorescent probes used in biomedical tracking and imaging could also be employed for flow cytometry with the correct laser wavelengths. This review describes the available technology, including lasers, fluorescent probes and detector technology optimal for near infrared signal detection. Published by Elsevier Inc.

Near-opposition martian limb-darkening: Quantification and implication for visible-near-infrared bidirectional reflectance studies.

NASA Astrophysics Data System (ADS)

de Grenier, Muriel; Pinet, Patrick C.

1995-06-01

A nearly global coverage of the martian eastern hemisphere, acquired under small phase angles and varying observational geometries conditions, has been produced from 1988 opposition by spectral (0.5-1 μm) imaging data obtained at the Pic du Midi Observatory in France. From this data set, the methodology presented here permits a systematic analysis of martian photometric behavior at a regional scale of 100-300 km in the visible and near-infrared. The quantification of limb-darkening as a function of wavelength and surface albedo gives access in martian regional properties as a function of wavelength and surface albedo and results in the production of visible and near-infrared geometric albedo maps. A linear relation between the limb darkening parameter k and geometric albedo exists in the near infrared. Based on laboratory studies, it suggests a spectral response of particulate type for the martian soil. Conversely, in the visible, the value of k parameter is 0.6 independent of albedo and is consistent with a single scattering photometric behavior in the surface layer. However, the observed change in the martian photometry from single to multiple scattering may be partially due to a large contribution of atmospheric scattering above 0.7 μm. In the absence of a multitemporal dataset analysis, it must be emphasized that the present results are a priori only pertinent to the atmospheric and surface conditions existing on Mars at the time of observation. However, this analysis may contribute to characterize some physical properties, such as surface roughness. In the near-infrared, for bright terrains, k tends to 0.8 and agrees with the presence of very fine particulate materials. Photometry of dark areas is more irregular (0.48 < k < 0.64) and might result from surface roughness heterogeneities. However, a few dark areas reveal that k anomalous values in the range 0.7-0.8 may be caused by the presence of a coating of very fine materials or duricrust. Finally, we

Built-in hyperspectral camera for smartphone in visible, near-infrared and middle-infrared lights region (third report): spectroscopic imaging for broad-area and real-time componential analysis system against local unexpected terrorism and disasters

NASA Astrophysics Data System (ADS)

Hosono, Satsuki; Kawashima, Natsumi; Wollherr, Dirk; Ishimaru, Ichiro

2016-05-01

The distributed networks for information collection of chemical components with high-mobility objects, such as drones or smartphones, will work effectively for investigations, clarifications and predictions against unexpected local terrorisms and disasters like localized torrential downpours. We proposed and reported the proposed spectroscopic line-imager for smartphones in this conference. In this paper, we will mention the wide-area spectroscopic-image construction by estimating 6 DOF (Degrees Of Freedom: parallel movements=x,y,z and rotational movements=θx, θy, θz) from line data to observe and analyze surrounding chemical-environments. Recently, smartphone movies, what were photographed by peoples happened to be there, had worked effectively to analyze what kinds of phenomenon had happened around there. But when a gas tank suddenly blew up, we did not recognize from visible-light RGB-color cameras what kinds of chemical gas components were polluting surrounding atmospheres. Conventionally Fourier spectroscopy had been well known as chemical components analysis in laboratory usages. But volatile gases should be analyzed promptly at accident sites. And because the humidity absorption in near and middle infrared lights has very high sensitivity, we will be able to detect humidity in the sky from wide field spectroscopic image. And also recently, 6-DOF sensors are easily utilized for estimation of position and attitude for UAV (Unmanned Air Vehicle) or smartphone. But for observing long-distance views, accuracies of angle measurements were not sufficient to merge line data because of leverage theory. Thus, by searching corresponding pixels between line spectroscopic images, we are trying to estimate 6-DOF in high accuracy.

Near-near-infrared thermal lens spectroscopy to assess overtones and combination bands of sulfentrazone pesticide.

PubMed

Ventura, M; Silva, J R; Andrade, L H C; Scorza Júnior, R P; Lima, S M

2018-01-05

Thermal lens spectroscopy (TLS) in the near-near-infrared region was used to explore the absorptions of overtones and combination bands of sulfentrazone (SFZ) herbicide diluted in methanol. This spectroscopic region was chosen in order to guarantee that only thermal lens effect is noted during the experimental procedure. The results showed that it was possible to detect very low concentrations (~2ng/μL) of SFZ in methanol by determining its thermal diffusivity or the absorption coefficient due to the 3ν(NH)+1δ(CH) combination band. This minimum SFZ concentration is the limit observed by chromatography method. The findings demonstrated that the TLS can be used for precise and accurate assessment of pesticides in ecosystems. Besides, the 3ν(NH)+1δ(CH) combination band at 960nm can be used as a marker for SFZ in methanol. Copyright © 2017 Elsevier B.V. All rights reserved.

AKARI Near-infrared Spectroscopic Observations of Interstellar Ices in the Edge-on Starburst Galaxy NGC 253

NASA Astrophysics Data System (ADS)

Yamagishi, Mitsuyoshi; Kaneda, Hidehiro; Ishihara, Daisuke; Oyabu, Shinki; Onaka, Takashi; Shimonishi, Takashi; Suzuki, Toyoaki

2011-04-01

We present the spatially resolved near-infrared (2.5-5.0 μm) spectra of the edge-on starburst galaxy NGC 253 obtained with the Infrared Camera on board AKARI. Near the center of the galaxy, we clearly detect the absorption features of interstellar ices (H2O: 3.05 μm, CO2: 4.27 μm, and XCN: 4.62 μm) and the emission of polycyclic aromatic hydrocarbons (PAHs) at 3.29 μm and the hydrogen recombination line Brα at 4.05 μm. We find that the distributions of the ices differ from those of the PAH and gas. We calculate the column densities of the ices and derive the abundance ratios of N(CO2)/N(H2O) = 0.17 ± 0.05. They are similar to those obtained around the massive young stellar objects in our Galaxy (0.17 ± 0.03), although a much stronger interstellar radiation field and higher dust temperature are expected near the center of NGC 253.

Fourier transform mid-infrared (MIR) and near-infrared (NIR) spectroscopy for rapid quality assessment of Chinese medicine preparation Honghua Oil.

PubMed

Wu, Yan-Wen; Sun, Su-Qin; Zhou, Qun; Leung, Hei-Wun

2008-02-13

Honghua Oil (HHO), a traditional Chinese medicine (TCM) oil preparation, is a mixture of several plant essential oils. In this text, the extended ranges of Fourier transform mid-infrared (FT-MIR) and near infrared (FT-NIR) were recorded for 48 commercially available HHOs of different batches from nine manufacturers. The qualitative and quantitative analysis of three marker components, alpha-pinene, methyl salicylate and eugenol, in different HHO products were performed rapidly by the two vibrational spectroscopic methods, i.e. MIR with horizontal attenuated total reflection (HATR) accessory and NIR with direct sampling technique, followed by partial least squares (PLS) regression treatment of the set of spectra obtained. The results indicated that it was successful to identify alpha-pinene, methyl salicylate and eugenol in all of the samples by simple inspection of the MIR-HATR spectra. Both PLS models established with MIR-HATR and NIR spectral data using gas chromatography (GC) peak areas as calibration reference showed a good linear correlation for each of all three target substances in HHO samples. The above spectroscopic techniques may be the promising methods for the rapid quality assessment/quality control (QA/QC) of TCM oil preparations.

Near infrared spectroscopic evaluation of water in hyaline cartilage.

PubMed

Padalkar, M V; Spencer, R G; Pleshko, N

2013-11-01

In diseased conditions of cartilage such as osteoarthritis, there is typically an increase in water content from the average normal of 60-85% to greater than 90%. As cartilage has very little capability for self-repair, methods of early detection of degeneration are required, and assessment of water could prove to be a useful diagnostic method. Current assessment methods are either destructive, time consuming, or have limited sensitivity. Here, we investigated the hypotheses that non-destructive near infrared spectroscopy (NIRS) of articular cartilage can be used to differentiate between free and bound water, and to quantitatively assess water content. The absorbances centered at 5200 and 6890 cm(-1) were attributed to a combination of free and bound water, and to free water only, respectively. The integrated areas of both absorbance bands were found to correlate linearly with the absolute water content (R = 0.87 and 0.86) and with percent water content (R = 0.97 and 0.96) of the tissue. Partial least square models were also successfully developed and were used to predict water content, and percent free water. These data demonstrate that NIRS can be utilized to quantitatively determine water content in articular cartilage, and may aid in early detection of degenerative tissue changes in a laboratory setting, and with additional validations, possibly in a clinical setting.

Mid-infrared spectroscopic analysis of saccharides in aqueous solutions with sodium chloride.

PubMed

Kanou, Mikihito; Kameoka, Takaharu; Suehara, Ken-Ichiro; Hashimoto, Atsushi

2017-04-01

The infrared spectral characteristics of three different types of disaccharides (trehalose, maltose, and sucrose) and four different types of monosaccharides (glucose, mannose, galactose, and fructose) in aqueous solutions with sodium chloride (NaCl) were determined. The infrared spectra were obtained using the FT-IR/ATR method and the absorption intensities respected the interaction between the saccharide and water with NaCl were determined. This study also focused on not only the glycosidic linkage position and the constituent monosaccharides, but also the concentration of the saccharides and NaCl and found that they have a significant influence on the infrared spectroscopic characterization of the disaccharides in an aqueous solution with NaCl. The absorption intensities representing the interaction between a saccharide and water with NaCl were spectroscopically determined. Additionally, the applications of MIR spectroscopy to obtain information about saccharide-NaCl interactions in foods and biosystems were suggested.

Controlling plasmonic properties of epitaxial thin films of indium tin oxide in the near-infrared region

NASA Astrophysics Data System (ADS)

Kamakura, R.; Fujita, K.; Murai, S.; Tanaka, K.

2015-06-01

Epitaxial thin films of indium tin oxide (ITO) were grown on yttria-stabilized zirconia single-crystal substrates by using a pulsed laser deposition to examine their plasmonic properties. The dielectric function of ITO was characterized by spectroscopic ellipsometry. Through the concentration of SnO2 in the target, the carrier concentration in the films was modified, which directly leads to the tuning of the dielectric function in the near-infrared region. Variable-angle reflectance spectroscopy in the Kretschmann geometry shows the dip in the reflection spectrum of p-polarized light corresponding to the excitation of surface plasmon polaritions (SPPs) in the near-infrared region. The excitation wavelength of the SPPs was shifted with changing the dielectric functions of ITO, which is reproduced by the calculation using transfer matrix method.

Waves of the Future (for Mars): In-Situ Mid-infrared, Near-infrared, and Visible Spectroscopic Analysis of Antarctic Cryptoendolithic Communities.

NASA Astrophysics Data System (ADS)

Hand, K. P.; Calrson, R.; Sun, H.; Anderson, M.; Wynn, W.; Levy, R.

2005-12-01

We have analyzed both the surface expression and depth profile of cryptoendolithic microbial communities at Battleship Promontory, in the Dry Valleys of Antarctica. Data was collected on site with an active mid-infrared Fourier transform microspectrometer (2.6 - 15 um), a near-infrared spectrometer (0.9-1.8 um), and a visible spectrometer (0.4-1 um). The trio of instruments are connected to microscopes that yield ~1 mm2 spatial resolution on the sample and they are mounted on two perpendicular motorized stages that allow for spatial scanning over an area of ~2cm2. Here we present results on the surface expression of the subsurface microbes in these three spectral regions and we present results on the analysis of a colonized sample examined in cross section. The former case has direct application to the remote, robotic detection of life within the rocks of Mars and the later case provides fundamental insights into the geological and biological interactions that make the Antarctic cryptoendolithic ecosystems possible. Non-invasive surface detection of cyanobacterial dominated communities was possible through the observation of several distinct bands: the carbon-hydrogen stretching modes (symmetric and asymmetric) for CH, CH2, and CH3 in the regions of 3.3-3.6 um and 3.6-3.7 um; the NH2 scissoring and C=O stretch near 6.0 um; the amide I of beta-pleated structures at ~6.1 um; and the 6.4 um - 6.6 um bands of N-H in plane bend of the amide II functional group. In combination, these bands make a strong case for carbohydrates and proteins associated with life. Not surprisingly, as the integrity of the amorphous silica surface varnish improved, our ability to detected the subsurface biosignature decreased. We note, however, that by utilizing the JPL rock crusher in Antarctica, a device designed to fly on the Mars Science Laboratory mission, the mid-infrared biosignature was easily detected. In the cross-section analysis the mid-infrared data provide a depth profile

Emergence of two near-infrared windows for in vivo and intraoperative SERS.

PubMed

Lane, Lucas A; Xue, Ruiyang; Nie, Shuming

2018-04-06

Two clear windows in the near-infrared (NIR) spectrum are of considerable current interest for in vivo molecular imaging and spectroscopic detection. The main rationale is that near-infrared light can penetrate biological tissues such as skin and blood more efficiently than visible light because these tissues scatter and absorb less light at longer wavelengths. The first clear window, defined as light wavelengths between 650nm and 950nm, has been shown to be far superior for in vivo and intraoperative optical imaging than visible light. The second clear window, operating in the wavelength range of 1000-1700nm, has been reported to further improve detection sensitivity, spatial resolution, and tissue penetration because tissue photon scattering and background interference are further reduced at longer wavelengths. Here we discuss recent advances in developing biocompatible plasmonic nanoparticles for in vivo and intraoperative surface-enhanced Raman scattering (SERS) in both the first and second NIR windows. In particular, a new class of 'broad-band' plasmonic nanostructures is well suited for surface Raman enhancement across a broad range of wavelengths allowing a direct comparison of detection sensitivity and tissue penetration between the two NIR window. Also, optimized and encoded SERS nanoparticles are generally nontoxic and are much brighter than near-infrared quantum dots (QDs), raising new possibilities for ultrasensitive detection of microscopic tumors and image-guided precision surgery. Copyright © 2018 Elsevier Ltd. All rights reserved.

Electro-optic sampling of near-infrared waveforms

NASA Astrophysics Data System (ADS)

Keiber, Sabine; Sederberg, Shawn; Schwarz, Alexander; Trubetskov, Michael; Pervak, Volodymyr; Krausz, Ferenc; Karpowicz, Nicholas

2016-03-01

Access to the complete electric field evolution of a laser pulse is essential for attosecond science in general, and for the scrutiny and control of electron phenomena in solid-state physics specifically. Time-resolved field measurements are routine in the terahertz spectral range, using electro-optic sampling (EOS), photoconductive switches and field-induced second harmonic generation. EOS in particular features outstanding sensitivity and ease of use, making it the basis of time-resolved spectroscopic measurements for studying charge carrier dynamics and active optical devices. In this Letter, we show that careful optical filtering allows the bandwidth of this technique to be extended to wavelengths as short as 1.2 μm (230 THz) with half-cycle durations 2.3 times shorter than the sampling pulse. In a proof-of-principle application, we measure the influence of optical parametric amplification (OPA) on the electric field dynamics of a few-cycle near-infrared (NIR) pulse.

Near-infrared to Mid-infrared Observations of Galaxy Mergers: NGC 2782 and NGC 7727

NASA Astrophysics Data System (ADS)

Onaka, Takashi; Nakamura, Tomohiko; Sakon, Itsuki; Wu, Ronin; Ohsawa, Ryou; Kaneda, Hidehiro; Lebouteiller, Vianney; Roellig, Thomas L.

2018-01-01

We present the results of near-infrared-to-mid-infrared (NIR-to-MIR) imaging and NIR spectroscopic observations of two galaxy mergers, NGC 2782 (Arp 215) and NGC 7727 (Arp 222), with the Infrared Camera on board AKARI. NGC 2782 shows extended MIR emission in the eastern side of the galaxy, which corresponds to the eastern tidal tail seen in the H I 21 cm map, while NGC 7727 shows extended MIR emission in the north of the galaxy, which is similar to the plumes seen in the residual image at the K-band after subtracting a galaxy model. Both extended structures are thought to have formed in association with their merger events. They show excess emission at 7–15 μm, which can be attributed to emission from polycyclic aromatic hydrocarbons (PAHs), while the observed spectral energy distributions (SEDs) decline longward of 24 μm, suggesting that very small grains (VSGs) are deficient. These characteristics of the observed MIR SED may be explained if PAHs are formed by fragmentation of VSGs during merger events. The star formation rate is estimated from the MIR PAH emission in the eastern tail region of NGC 2782 and it is in fair agreement with those estimated from Hα and [C II] 158 μm. MIR observations are efficient for the study of dust processing and structures formed during merger events.

Near-infrared spectroscopic study on the effects of chewing on short-term memory.

PubMed

Wada, Mayumi; Hoshi, Yoko; Iguchi, Yoshinobu; Kida, Ikuhiro

2011-12-01

Using near-infrared spectroscopy, we examined whether chewing gum improves performance in a short-term memory task - immediate recall of random eight-digit numbers - by assessing cerebral hemodynamic response in the prefrontal cortex. We found that the oxyhemoglobin concentration during and after chewing gum was higher than that before chewing; further, the concentration increased during the task, and this increase was reduced with chewing, although non-significantly. Chewing did not improve task performance. Therefore, chewing-induced hemodynamic responses were unrelated to the performance in short-term memory tasks. Copyright © 2011 Elsevier Ltd. All rights reserved.

Infrared spectroscopic imaging: Label-free biochemical analysis of stroma and tissue fibrosis.

PubMed

Nazeer, Shaiju S; Sreedhar, Hari; Varma, Vishal K; Martinez-Marin, David; Massie, Christine; Walsh, Michael J

2017-11-01

Infrared spectroscopic tissue imaging is a potentially powerful adjunct tool to current histopathology techniques. By coupling the biochemical signature obtained through infrared spectroscopy to the spatial information offered by microscopy, this technique can selectively analyze the chemical composition of different features of unlabeled, unstained tissue sections. In the past, the tissue features that have received the most interest were parenchymal and epithelial cells, chiefly due to their involvement in dysplasia and progression to carcinoma; however, the field has recently turned its focus toward stroma and areas of fibrotic change. These components of tissue present an untapped source of biochemical information that can shed light on many diverse disease processes, and potentially hold useful predictive markers for these same pathologies. Here we review the recent applications of infrared spectroscopic imaging to stromal and fibrotic regions of diseased tissue, and explore the potential of this technique to advance current capabilities for tissue analysis. Copyright © 2017 Elsevier Ltd. All rights reserved.

Infrared Spectroscopic Analyses of Sulfate, Nitrate, and Carbonate-bearing Atacama Desert Soils: Analogs for the Interpretation of Infrared Spectra from the Martian Surface

NASA Technical Reports Server (NTRS)

Dalton, J. B.; Dalton, J. B.; Ewing, S. A.; Amundson, R.; McKay, C. P.

2005-01-01

The Atacama Desert of northern Chile is the driest desert on Earth, receiving only a few mm of rain per decade. The Mars climate may, in the past, have been punctuated by short-lived episodes of aqueous activity. The paleo-Martian environment may have had aqueous conditions similar to the current conditions that exist in the Atacama, and Mars soils may have formed with soil chemistry and mineralogy similar to those found in the Atacama. Remote and in-situ analysis of the Martian surface using infrared technology has a long heritage. Future investigations of the subsurface mineralogy are likely to build upon this heritage, and will benefit from real life lessons to be learned from terrestrial analog studies. To that end, preliminary results from a near- and mid-infrared spectroscopic study of Atacama soil profiled at a range of depths are presented.

Near-Infrared Coloring via a Contrast-Preserving Mapping Model.

PubMed

Chang-Hwan Son; Xiao-Ping Zhang

2017-11-01

Near-infrared gray images captured along with corresponding visible color images have recently proven useful for image restoration and classification. This paper introduces a new coloring method to add colors to near-infrared gray images based on a contrast-preserving mapping model. A naive coloring method directly adds the colors from the visible color image to the near-infrared gray image. However, this method results in an unrealistic image because of the discrepancies in the brightness and image structure between the captured near-infrared gray image and the visible color image. To solve the discrepancy problem, first, we present a new contrast-preserving mapping model to create a new near-infrared gray image with a similar appearance in the luminance plane to the visible color image, while preserving the contrast and details of the captured near-infrared gray image. Then, we develop a method to derive realistic colors that can be added to the newly created near-infrared gray image based on the proposed contrast-preserving mapping model. Experimental results show that the proposed new method not only preserves the local contrast and details of the captured near-infrared gray image, but also transfers the realistic colors from the visible color image to the newly created near-infrared gray image. It is also shown that the proposed near-infrared coloring can be used effectively for noise and haze removal, as well as local contrast enhancement.

Near infrared detection of ammonium minerals.

USGS Publications Warehouse

Krohn, M.D.; Altaner, S.P.

1987-01-01

Diagnostic near-infrared spectral features have been identified for minerals with ammonium (NH4+) bound in the crystal structure. Near-infrared detection of NH4-bearing minerals may provide useful information for prospecting for certain ore deposits and may provide a better understanding of the nitrogen cycle within geologic environments.-from Authors

Optical and Near-infrared Spectra of σ Orionis Isolated Planetary-mass Objects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zapatero Osorio, M. R.; Béjar, V. J. S.; Ramírez, K. Peña, E-mail: mosorio@cab.inta-csic.es, E-mail: vbejar@iac.es, E-mail: karla.pena@uantof.cl

We have obtained low-resolution optical (0.7–0.98 μ m) and near-infrared (1.11–1.34 μ m and 0.8–2.5 μ m) spectra of 12 isolated planetary-mass candidates ( J = 18.2–19.9 mag) of the 3 Myr σ Orionis star cluster with the aim of determining the spectroscopic properties of very young, substellar dwarfs and assembling a complete cluster mass function. We have classified our targets by visual comparison with high- and low-gravity standards and by measuring newly defined spectroscopic indices. We derived L0–L4.5 and M9–L2.5 using high- and low-gravity standards, respectively. Our targets reveal clear signposts of youth, thus corroborating their cluster membership andmore » planetary masses (6–13 M {sub Jup}). These observations complete the σ Orionis mass function by spectroscopically confirming the planetary-mass domain to a confidence level of ∼75%. The comparison of our spectra with BT-Settl solar metallicity model atmospheres yields a temperature scale of 2350–1800 K and a low surface gravity of log g ≈ 4.0 [cm s{sup −2}], as would be expected for young planetary-mass objects. We discuss the properties of the cluster’s least-massive population as a function of spectral type. We have also obtained the first optical spectrum of S Ori 70, a T dwarf in the direction of σ Orionis. Our data provide reference optical and near-infrared spectra of very young L dwarfs and a mass function that may be used as templates for future studies of low-mass substellar objects and exoplanets. The extrapolation of the σ Orionis mass function to the solar neighborhood may indicate that isolated planetary-mass objects with temperatures of ∼200–300 K and masses in the interval 6–13 M {sub Jup} may be as numerous as very low-mass stars.« less

Brown dwarf photospheres are patchy: A Hubble space telescope near-infrared spectroscopic survey finds frequent low-level variability

DOE Office of Scientific and Technical Information (OSTI.GOV)

Buenzli, Esther; Apai, Dániel; Radigan, Jacqueline

2014-02-20

Condensate clouds strongly impact the spectra of brown dwarfs and exoplanets. Recent discoveries of variable L/T transition dwarfs argued for patchy clouds in at least some ultracool atmospheres. This study aims to measure the frequency and level of spectral variability in brown dwarfs and to search for correlations with spectral type. We used Hubble Space Telescope/Wide Field Camera 3 to obtain spectroscopic time series for 22 brown dwarfs of spectral types ranging from L5 to T6 at 1.1-1.7 μm for ≈40 minutes per object. Using Bayesian analysis, we find six brown dwarfs with confident (p > 95%) variability in themore » relative flux in at least one wavelength region at sub-percent precision, and five brown dwarfs with tentative (p > 68%) variability. We derive a minimum variability fraction f{sub min}=27{sub −7}{sup +11}% over all covered spectral types. The fraction of variables is equal within errors for mid-L, late-L, and mid-T spectral types; for early-T dwarfs we do not find any confident variable but the sample is too small to derive meaningful limits. For some objects, the variability occurs primarily in the flux peak in the J or H band, others are variable throughout the spectrum or only in specific absorption regions. Four sources may have broadband peak-to-peak amplitudes exceeding 1%. Our measurements are not sensitive to very long periods, inclinations near pole-on and rotationally symmetric heterogeneity. The detection statistics are consistent with most brown dwarf photospheres being patchy. While multiple-percent near-infrared variability may be rare and confined to the L/T transition, low-level heterogeneities are a frequent characteristic of brown dwarf atmospheres.« less

High-Definition Infrared Spectroscopic Imaging

PubMed Central

Reddy, Rohith K.; Walsh, Michael J.; Schulmerich, Matthew V.; Carney, P. Scott; Bhargava, Rohit

2013-01-01

The quality of images from an infrared (IR) microscope has traditionally been limited by considerations of throughput and signal-to-noise ratio (SNR). An understanding of the achievable quality as a function of instrument parameters, from first principals is needed for improved instrument design. Here, we first present a model for light propagation through an IR spectroscopic imaging system based on scalar wave theory. The model analytically describes the propagation of light along the entire beam path from the source to the detector. The effect of various optical elements and the sample in the microscope is understood in terms of the accessible spatial frequencies by using a Fourier optics approach and simulations are conducted to gain insights into spectroscopic image formation. The optimal pixel size at the sample plane is calculated and shown much smaller than that in current mid-IR microscopy systems. A commercial imaging system is modified, and experimental data are presented to demonstrate the validity of the developed model. Building on this validated theoretical foundation, an optimal sampling configuration is set up. Acquired data were of high spatial quality but, as expected, of poorer SNR. Signal processing approaches were implemented to improve the spectral SNR. The resulting data demonstrated the ability to perform high-definition IR imaging in the laboratory by using minimally-modified commercial instruments. PMID:23317676

High-definition infrared spectroscopic imaging.

PubMed

Reddy, Rohith K; Walsh, Michael J; Schulmerich, Matthew V; Carney, P Scott; Bhargava, Rohit

2013-01-01

The quality of images from an infrared (IR) microscope has traditionally been limited by considerations of throughput and signal-to-noise ratio (SNR). An understanding of the achievable quality as a function of instrument parameters, from first principals is needed for improved instrument design. Here, we first present a model for light propagation through an IR spectroscopic imaging system based on scalar wave theory. The model analytically describes the propagation of light along the entire beam path from the source to the detector. The effect of various optical elements and the sample in the microscope is understood in terms of the accessible spatial frequencies by using a Fourier optics approach and simulations are conducted to gain insights into spectroscopic image formation. The optimal pixel size at the sample plane is calculated and shown much smaller than that in current mid-IR microscopy systems. A commercial imaging system is modified, and experimental data are presented to demonstrate the validity of the developed model. Building on this validated theoretical foundation, an optimal sampling configuration is set up. Acquired data were of high spatial quality but, as expected, of poorer SNR. Signal processing approaches were implemented to improve the spectral SNR. The resulting data demonstrated the ability to perform high-definition IR imaging in the laboratory by using minimally-modified commercial instruments.

Study of surfaces using near infrared optical fiber spectrometry

NASA Technical Reports Server (NTRS)

Workman, G. L.; Arendale, W. A.; Hughes, C.

1995-01-01

The measurement and control of cleanliness for critical surfaces during manufacturing and in service provides a unique challenge for fulfillment of environmentally benign operations. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This presentation will provide an introduction to the use of optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. Correlation of the Near Infrared (NIR) spectroscopic results with Optical Stimulated Electron Emission (OSEE) and ellipsometry will also be presented.

Near infrared and optical spectroscopy of FSC10214+4724

NASA Technical Reports Server (NTRS)

Soifer, B. T.; Cohen, J. G.; Armus, L.; Matthews, K.; Neugebauer, G.; Oke, J. B.

1995-01-01

New infrared and optical spectroscopic observations, obtained with the W.M. Keck Telescope, are reported for the highly luminous infrared source FSC10214+4724. The rest frame optical spectrum shows new emission lines of (NeIII, (NeV), (OI), (OII), (SII), and He(+) while the rest frame ultraviolet spectrum shows new lines of OIV+SiIV, NII, NIV, SiII, NeIV and possibly NII and (NeIII), as well as clearly showing the L alpha is self-absorbed. The emission line spectrum is most characteristic of a Seyfert 2 nucleus. The preponderance of spectroscopic evidence strengthens the case of a dust enshrouded AGN powering much or most of the observed luminosity. The various spectral lines lead to a wide range in the inferred reddening and ionization parameter for this system, suggesting that we are viewing several environments through differing extinctions.

Infrared Spectroscopic Imaging: The Next Generation

PubMed Central

Bhargava, Rohit

2013-01-01

Infrared (IR) spectroscopic imaging seemingly matured as a technology in the mid-2000s, with commercially successful instrumentation and reports in numerous applications. Recent developments, however, have transformed our understanding of the recorded data, provided capability for new instrumentation, and greatly enhanced the ability to extract more useful information in less time. These developments are summarized here in three broad areas— data recording, interpretation of recorded data, and information extraction—and their critical review is employed to project emerging trends. Overall, the convergence of selected components from hardware, theory, algorithms, and applications is one trend. Instead of similar, general-purpose instrumentation, another trend is likely to be diverse and application-targeted designs of instrumentation driven by emerging component technologies. The recent renaissance in both fundamental science and instrumentation will likely spur investigations at the confluence of conventional spectroscopic analyses and optical physics for improved data interpretation. While chemometrics has dominated data processing, a trend will likely lie in the development of signal processing algorithms to optimally extract spectral and spatial information prior to conventional chemometric analyses. Finally, the sum of these recent advances is likely to provide unprecedented capability in measurement and scientific insight, which will present new opportunities for the applied spectroscopist. PMID:23031693

Near-infrared Raman spectroscopy of single optically trapped biological cells

NASA Astrophysics Data System (ADS)

Xie, Changan; Dinno, Mumtaz A.; Li, Yong-Qing

2002-02-01

We report on the development and testing of a compact laser tweezers Raman spectroscopy (LTRS) system. The system combines optical trapping and near-infrared Raman spectroscopy for manipulation and identification of single biological cells in solution. A low-power diode laser at 785 nm was used for both trapping and excitation for Raman spectroscopy of the suspended microscopic particles. The design of the LTRS system provides high sensitivity and permits real-time spectroscopic measurements of the biological sample. The system was calibrated by use of polystyrene microbeads and tested on living blood cells and on both living and dead yeast cells. As expected, different images and Raman spectra were observed for the different cells. The LTRS system may provide a valuable tool for the study of fundamental cellular processes and the diagnosis of cellular disorders.

A near infrared spectroscopic study of the interstellar gas in the starburst core of M82

NASA Technical Reports Server (NTRS)

Lester, Dan F.; Carr, John; Joy, Marshall; Gaffney, Niall

1990-01-01

Researchers used the McDonald Observatory Infrared Grating Spectrometer, to complete a program of spatially resolved spectroscopy of M82. The inner 300 pc of the starburst was observed with 4 inch (50 pc) resolution. Complete J, H and K band spectra with resolution 0.0035 micron (lambda/delta lambda=620 at K) were measured at the near-infrared nucleus of the galaxy. Measurements of selected spectral features including lines of FeII, HII and H2 were observed along the starburst ridge-line, so the relative distribution of the diagnostic features could be understood. This information was used to better define the extinction towards the starburst region, the excitation conditions in the gas, and to characterize the stellar populations there.

ARNICA, the Arcetri Near-Infrared Camera

NASA Astrophysics Data System (ADS)

Lisi, F.; Baffa, C.; Bilotti, V.; Bonaccini, D.; del Vecchio, C.; Gennari, S.; Hunt, L. K.; Marcucci, G.; Stanga, R.

1996-04-01

ARNICA (ARcetri Near-Infrared CAmera) is the imaging camera for the near-infrared bands between 1.0 and 2.5 microns that the Arcetri Observatory has designed and built for the Infrared Telescope TIRGO located at Gornergrat, Switzerland. We describe the mechanical and optical design of the camera, and report on the astronomical performance of ARNICA as measured during the commissioning runs at the TIRGO (December, 1992 to December 1993), and an observing run at the William Herschel Telescope, Canary Islands (December, 1993). System performance is defined in terms of efficiency of the camera+telescope system and camera sensitivity for extended and point-like sources. (SECTION: Astronomical Instrumentation)

Near-infrared and optical spectroscopy of FSC 10214+4724

NASA Technical Reports Server (NTRS)

Soifer, B. T.; Cohen, J. G.; Armus, L.; Matthews, K.; Neugebauer, G.; Oke, J. B.

1995-01-01

New infrared and optical spectroscopic observations, obtained with the W. M. Keck Telescope, are reported for the highly luminous infrared source FSC 10214+4724. The rest frame optical spectrum shows new emission lines of (Ne III), (Ne V), (O I), (O II), (S II), and He(+), while the rest frame ultraviolet spectrum shows new lines of O IV) + Si IV, N III, N IV), Si II, Ne IV, and possibly N II and (Ne III), as well as clearly showing that Ly-alpha is self-absorbed. The emission-line spectrum is most characteristic of a Seyfert 2 nucleus. The preponderance of spectroscopic evidence strengthens the case for a dust-enshrouded Active galactic nuclei (AGN) powering much or most of the observed luminosity. The various spectral lines lead to a wide range in the inferred reddening and ionization parameter for this system, suggesting that we are viewing several environments through differing extinctions.

Implications of Bishop Tuff zircon U-Pb ages for rates of zircon growth and magma accumulation

NASA Astrophysics Data System (ADS)

Reid, M. R.; Schmitt, A. K.

2012-12-01

Rates of geologic processes obtained from natural studies rely on accurate geochronologic information. An important benchmark in geochronology as well as a valuable source of insights into the evolution of voluminous explosive eruptions is the >600 km3 Bishop Tuff (BT). A recently determined weighted mean 206Pb/238U date of 767.1±0.9 ka for a BT zircon population [1] is indistinguishable from the recalibrated 40Ar/39Ar sanidine date of 767.4±2.2 ka [2], potentially providing a key intercalibration point between astronomical and radio-isotopic dating approaches. Consequences of these results are linear zircon growth rates of >1×10-14 cm/sec and magma accumulation rates of >200 km3/ka. In contrast, spatially selective SIMS U-Pb dating of BT zircons yielded mean pre-eruption ages of 850 ka [3], a difference that raises questions about the validity of intercalibration between U-Pb and K-Ar dating methods and the history of magma accumulation. We obtained new SIMS analyses of the BT zircons using more spatially and analytically sensitive methods and verifying our accuracy against the TIMS dated Quaternary zircon 61.308A (2.488±0.002 Ma). Analyses were performed on zircon rims and on oriented cross-sections exposed during optical interferometry-calibrated serial sectioning removing the outermost ~31 μm. Sputtering by a 100 nA ion beam versus the normally employed 10-12 nA beam resulted in enhanced radiogenic Pb yields and analytical uncertainties for Quaternary zircon approaching the U-Pb age reproducibility of the primary zircon standard (~1-2 % for AS3). Ages obtained at ~31 μm depth (representing <5% of crystal growth in most cases) average 892±26ka (MSWD=0.29), corroborating previous evidence for residence times of several tens of ka. Rim ages average 781±22 ka (MSWD=0.61), overlapping Ar/Ar determinations of eruption age and corroborating the importance of near-eruption aged zircon growth. Our results confirm the presence of BT zircon domains that predate

Variable-temperature Fourier transform near-infrared imaging spectroscopy of the deuterium/hydrogen exchange in liquid D₂O.

PubMed

Unger, Miriam; Ozaki, Yukihiro; Siesler, Heinz W

2014-01-01

In the present publication, the deuterium/hydrogen (D/H) exchange of liquid D2O exposed to water vapor of the surrounding atmosphere has been studied by variable-temperature Fourier transform near-infrared (FT-NIR) imaging spectroscopy. Apart from the visualization of the exchange process in the time-resolved FT-NIR images, kinetic parameters and the activation energy for this D/H exchange reaction have been derived from the Arrhenius plot of the variable-temperature spectroscopic data.

Near-infrared spectroscopic monitoring during cardiopulmonary exercise testing detects anaerobic threshold.

PubMed

Rao, Rohit P; Danduran, Michael J; Loomba, Rohit S; Dixon, Jennifer E; Hoffman, George M

2012-06-01

Cardiopulmonary exercise testing (CPET) provides assessment of the integrative responses involving the pulmonary, cardiovascular, and skeletal muscle systems. Application of exercise testing remains limited to children who are able to understand and cooperate with the exercise protocol. Near-infrared spectroscopy (NIRS) provides a noninvasive, continuous method to monitor regional tissue oxygenation (rSO2). Our specific aim was to predict anaerobic threshold (AT) during CPET noninvasively using two-site NIRS monitoring. Achievement of a practical noninvasive technology for estimating AT will increase the compatibility of CPET. Patients without structural or acquired heart disease were eligible for inclusion if they were ordered to undergo CPET by a cardiologist. Data from 51 subjects was analyzed. The ventilatory anaerobic threshold (VAT) was computed on [Formula: see text] and respiratory quotient post hoc using the standard V-slope method. The inflection points of the regional rSO2 time-series were identified as the noninvasive regional NIRS AT for each of the two monitored regions (cerebral and kidney). AT calculation made using an average of kidney and brain NIRS matched the calculation made by VAT for the same patient. Two-site NIRS monitoring of visceral organs is a predictor of AT.

A near-infrared high-resolution spectroscopic survey of bulge stars - JASMINE prestudy

NASA Astrophysics Data System (ADS)

Tsujimoto, T.; Gouda, N.; Kobayashi, N.; Yasui, C.; Kondo, S.; Minami, A.; Motohara, K.; Ikeda, Y.

2006-08-01

We are developing a new near-infrared high-resolution (R[max]= 100,000) and high-sensitive spectrograph WINERED, which is specifically customized for short NIR bands at 0.9-1.35 μm. WINERED employs the novelty in the optical system; a potable design and a warm optics without any cold stops. The planned astrometric space mission JASMINE will provide the exact positions, distances, and proper motions of the bulge stars. The missing components, the radial velocity and chemical compositions will be measured by WINERED with high accuracies (δV< 1km/s). These combined data brought by JASMINE and WINERED will certainly reveal the nature of the Galactic bulge. We plan to complete this instrument for the observation of a single object by the end of 2008 and hope to attach it to various 4-10m telescopes as a PI-type instrument. In succession, we will develop it to the design for a simultaneous multi-object spectroscopy.

Heterogeneously integrated silicon photonics for the mid-infrared and spectroscopic sensing.

PubMed

Chen, Yu; Lin, Hongtao; Hu, Juejun; Li, Mo

2014-07-22

Besides being the foundational material for microelectronics, crystalline silicon has long been used for the production of infrared lenses and mirrors. More recently, silicon has become the key material to achieve large-scale integration of photonic devices for on-chip optical interconnect and signal processing. For optics, silicon has significant advantages: it offers a very high refractive index and is highly transparent in the spectral range from 1.2 to 8 μm. To fully exploit silicon’s superior performance in a remarkably broad range and to enable new optoelectronic functionalities, here we describe a general method to integrate silicon photonic devices on arbitrary foreign substrates. In particular, we apply the technique to integrate silicon microring resonators on mid-infrared compatible substrates for operation in the mid-infrared. These high-performance mid-infrared optical resonators are utilized to demonstrate, for the first time, on-chip cavity-enhanced mid-infrared spectroscopic analysis of organic chemicals with a limit of detection of less than 0.1 ng.

GNIRS-DQS: A Gemini Near Infrared Spectrograph Distant Quasar Survey

NASA Astrophysics Data System (ADS)

Matthews, Brandon; Shemmer, Ohad; Brotherton, Michael S.; Andruchow, Ileana; Boroson, Todd A.; Brandt, W. Niel; Cellone, Sergio; Ferrero, Gabriel; Gallagher, Sarah; Green, Richard F.; Hennawi, Joseph F.; Lira, Paulina; Myers, Adam D.; Plotkin, Richard; Richards, Gordon T.; Runnoe, Jessie; Schneider, Donald P.; Shen, Yue; Strauss, Michael A.; Willott, Chris J.; Wills, Beverley J.

2018-06-01

We describe an ongoing three-year Gemini survey, launched in 2017, that will obtain near-infrared spectroscopy of 416 Sloan Digital Sky Survey (SDSS) quasars between redshifts of 1.5 and 3.5 in the ~1.0-2.5 μm band. These spectra will cover critical diagnostic emission lines, such as Mg II, Hβ, and [O III], in each source. This project will more than double the existing inventory of near-infrared spectra of luminous quasars at these redshifts, including the era of fast quasar growth. Additional rest frame ultraviolet coverage of at least the C IV emission line is provided by the SDSS spectrum of each source. We will utilize the spectroscopic inventory to determine the most accurate and precise quasar black hole masses, accretion rates, and redshifts, and use the results to derive improved prescriptions for UV-based proxies for these parameters. The improved redshifts will establish velocities of quasar outflows that interact with the host galaxies, and will help constrain how imprecise distance estimates bias quasar clustering measurements. Furthermore, our measurements will facilitate a more complete understanding of how the rest-frame UV-optical spectral properties depend on redshift and luminosity, and test whether the physical properties of the quasar central engine evolve over cosmic time. We will make our data immediately available to the public, provide reduced spectra via a dedicated website, and produce a catalog of measurements and fundamental quasar properties.

The Kepler and K2 Near-Infrared Transit Survey (KNITS)

NASA Astrophysics Data System (ADS)

Colon, Knicole; Rodriguez, Joseph E.; Barentsen, Geert; Cardoso, Jose Vinicius de Miranda; Vanderburg, Andrew

2018-01-01

NASA's Kepler mission discovered a plethora of transiting exoplanets after observing a single region of the Galaxy for four years. After a second reaction wheel failed, NASA's Kepler spacecraft was repurposed as K2 to observe different fields along the ecliptic in ~80 day campaigns. To date, K2 has discovered ~130 exoplanets along with another ~400 candidates. The exoplanets that have been confirmed or validated from Kepler and K2 have been primarily subject to spectroscopic observations, high-resolution imaging, or statistical methods. However, most of these, along with all the remaining candidate exoplanets, have had no follow-up transit photometry. In addition, recent studies have shown that for single-planet systems, statistical validation alone can be unreliable and additional follow-up observations are required to reveal the true nature of the system. I will present the latest results from an ongoing program to use the 3.5-meter WIYN telescope at Kitt Peak National Observatory for near-infrared transit photometry of Kepler and K2 exoplanets and candidates. Our program of high-precision, high-cadence, high-spatial-resolution near-infrared transit photometry is providing new measurements of the transit ephemerides and planetary radii as well as weeding out false positives lurking within the candidate lists. To date, 25 K2 and 5 Kepler targets have been observed with WIYN. I will also describe upcoming observations with WIYN that will take place in January 2018 as part of a campaign to observe exoplanet transits in the near-infrared simultaneously with the Kepler spacecraft during K2 Campaign 16. Our program ultimately provides a vetted sample of exoplanets that could be targeted in the future by NASA’s James Webb Space Telescope (JWST) and also demonstrates WIYN’s capabilities for observations of exoplanets to be discovered by NASA's all-sky Transiting Exoplanet Survey Satellite (TESS).Data presented herein were obtained at the WIYN Observatory from

Graphene-Based Platform for Infrared Near-Field Nanospectroscopy of Water and Biological Materials in an Aqueous Environment.

PubMed

Khatib, Omar; Wood, Joshua D; McLeod, Alexander S; Goldflam, Michael D; Wagner, Martin; Damhorst, Gregory L; Koepke, Justin C; Doidge, Gregory P; Rangarajan, Aniruddh; Bashir, Rashid; Pop, Eric; Lyding, Joseph W; Thiemens, Mark H; Keilmann, Fritz; Basov, D N

2015-08-25

Scattering scanning near-field optical microscopy (s-SNOM) has emerged as a powerful nanoscale spectroscopic tool capable of characterizing individual biomacromolecules and molecular materials. However, applications of scattering-based near-field techniques in the infrared (IR) to native biosystems still await a solution of how to implement the required aqueous environment. In this work, we demonstrate an IR-compatible liquid cell architecture that enables near-field imaging and nanospectroscopy by taking advantage of the unique properties of graphene. Large-area graphene acts as an impermeable monolayer barrier that allows for nano-IR inspection of underlying molecular materials in liquid. Here, we use s-SNOM to investigate the tobacco mosaic virus (TMV) in water underneath graphene. We resolve individual virus particles and register the amide I and II bands of TMV at ca. 1520 and 1660 cm(-1), respectively, using nanoscale Fourier transform infrared spectroscopy (nano-FTIR). We verify the presence of water in the graphene liquid cell by identifying a spectral feature associated with water absorption at 1610 cm(-1).

Infrared spectroscopic study of super-critical water across the Widom line

NASA Astrophysics Data System (ADS)

Samanta, Tuhin; Dutta, Rajesh; Biswas, Rajib; Bagchi, Biman

2018-06-01

When density is varied at a constant temperature just above the gas-liquid critical temperature, the system is found to exhibit large scale density fluctuations which are often rationalized in terms of crossing of a Widom line. We use the discrete variable representation (DVR) scheme to construct the spectroscopic maps for transition frequencies and transition dipoles, and obtain the infrared spectrum of the Osbnd H stretch in the said temperature-density region of the phase diagram. The infrared lineshape shows a crossover from Lorentzian to Gaussian as we approach the Widom line. The width of the lineshape displays a pronounced maximum.

Spectroscopic data for thermal infrared remote sensing

NASA Technical Reports Server (NTRS)

Varanasi, P.; Nemtchinov, V.; Li, Z.

1995-01-01

There has been extensive world-wide use of chloro-fluoro-carbons (CFC's), especially CFC-11 (CFCl3) and CFC-12 (CF2Cl2), hydro-chloro-fluoro-carbons (HCFC's), HCFC-22 (CHFCl2) in particular, and sulphur hexaflouride (SF6) in numerous many industrial applications. These chemicals possess either a strong ozone-depletion potential or a global-warming potential, or both, and pose a threat to the inhabitability of our planet. Recognition of this fact has led to significant curtailment, if not total banishment, of their use globally. However, as recent satellite observations have shown, decline in their atmospheric concentrations may not be immediate. The marked depletion of ozone which has been observed in recent years at high latitudes has made infrared remote sensing of the atmosphere an activity of high priority. The success of any infrared remote sensing experiment conducted in the atmosphere depends upon the availability of accurate, high-resolution, spectroscopic data that are applicable to that experiment. This paper presents a preliminary phase of a multi-faceted work using a Fourier-transform spectrometer (FTS) which is in progress in our laboratory. The concept of how laboratory-borne measurements can be geared toward obtaining a database that is directly applicable to satellite-borne remote sensing missions is the main thrust of this paper which addresses itself to ongoing or planned international space missions. Spectroscopic data on the unresolvable bands of the above mentioned as well as several other man-made gases and on the individual spectral lines of such naturally present trace gases as CO2, N2O, NH3, and CH4 are presented. There is often significant overlap between the isolated lines of better known bands of the more abundant species and the weaker absorption features identifiable as bands of the currently less abundant CFC's, HCFC's, and SF6.

Development of an ultrahigh-performance infrared detector platform for advanced spectroscopic sensing systems

NASA Astrophysics Data System (ADS)

Jain, Manish; Wicks, Gary; Marshall, Andrew; Craig, Adam; Golding, Terry; Hossain, Khalid; McEwan, Ken; Howle, Chris

2014-05-01

Laser-based stand-off sensing of threat agents (e.g. explosives, toxic industrial chemicals or chemical warfare agents), by detection of distinct infrared spectral absorption signature of these materials, has made significant advances recently. This is due in part to the availability of infrared and terahertz laser sources with significantly improved power and tunability. However, there is a pressing need for a versatile, high performance infrared sensor that can complement and enhance the recent advances achieved in laser technology. This work presents new, high performance infrared detectors based on III-V barrier diodes. Unipolar barrier diodes, such as the nBn, have been very successful in the MWIR using InAs(Sb)-based materials, and in the MWIR and LWIR using type-II InAsSb/InAs superlattice-based materials. This work addresses the extension of the barrier diode architecture into the SWIR region, using GaSb-based and InAs-based materials. The program has resulted in detectors with unmatched performance in the 2-3 μm spectral range. Temperature dependent characterization has shown dark currents to be diffusion limited and equal to, or within a factor of 5, of the Rule 07 expression for Auger-limited HgCdTe detectors. Furthermore, D* values are superior to those of existing detectors in the 2-3 μm band. Of particular significance to spectroscopic sensing systems is the ability to have near-background limited performance at operation temperatures compatible with robust and reliable solid state thermoelectric coolers.

Near-infrared properties of quasar and Seyfert host galaxies

NASA Astrophysics Data System (ADS)

McLeod, Kim Katris

1994-01-01

We present near-infrared images of nearly 100 host galaxies of Active Galactic Nuclei (AGN). Our quasar sample is comprised of the 50 quasars from the Palomar Green Bright Quasar Survey with redshifts z less than or equal to 0.3. We have restricted the redshift range to ensure adequate spatial resolution, galaxy detectability, and minimal distance-dependent effects, while still giving a large sample of objects. For lower-luminosity AGN we have chosen to image the CfA Seyfert sample. This sample is composed of 48 Seyferts, roughly equally divided among types 1, 1.5-1.9, and 2. This sample was spectroscopically selected, and, therefore, is not biased towards Seyferts with significant star formation. Taken together, these samples allow a statistical look at the continuity of host galaxy properties over a factor of 10,000 in nuclear luminosity. We find the near-infrared light to be a good tracer of luminous mass in these galaxies. The Seyferts are found in galaxies of type SO to Sc. The radio quiet quasars live in similar kinds of galaxies spanning the same range of mass centered around L(*). However, for the most luminous quasars, there is a correlation between the minimum host galaxy mass and the luminosity of the active nucleus. Radio-loud quasars are generally found in hosts more massive than an L(*) galaxy. We also detect a population of low mass host galaxies with very low luminosity Seyfert nuclei. The low luminosity quasars and the Seyferts both tend to lie in host galaxies seen preferentially face-on, which suggests there is a substantial amount of obscuration coplanar with the galaxian disk. The obscuration must be geometrically thick (thickness-to-radius approximately 1) and must cover a significant fraction of the narrow line region (r greater than 100 pc). We have examined our images for signs of perturbations that could drive fuel toward the galaxy nucleus, but there are none we can identify at a significant level. The critical element for fueling is

Near-Infrared Properties of Quasar and Seyfert Host Galaxies

NASA Astrophysics Data System (ADS)

McLeod, Kim Katris

1995-01-01

We present near-infrared images of nearly 100 host galaxies of Active Galactic Nuclei (AGN). Our quasar sample is comprised of the 50 quasars from the Palomar Green Bright Quasar Survey with redshifts z\\<= 0.3. We have restricted the redshift range to ensure adequate spatial resolution, galaxy detectability, and minimal distance-dependent effects, while still giving a large sample of objects. For lower-luminosity AGN we have chosen to image the CfA Seyfert sample. This sample is composed of 48 Seyferts, roughly equally divided among types 1, 1.5-1.9, and 2. This sample was spectroscopically selected, and, therefore, is not biased towards Seyferts with significant star formation. Taken together, these samples allow a statistical look at the continuity of host-galaxy properties over a factor of 10,000 in nuclear luminosity. We find the near-infrared light to be a good tracer of luminous mass in these galaxies. The Seyferts are found in galaxies of type S0 to Sc. The radio quiet quasars live in similar kinds of galaxies spanning the same range of mass centered around L*. However, for the most luminous quasars, there is a correlation between the minimum host-galaxy mass and the luminosity of the active nucleus. Radio-loud quasars are generally found in hosts more massive than an L* galaxy. We also detect a population of low-mass host galaxies with very low-luminosity Seyfert nuclei. The low luminosity quasars and the Seyferts both tend to lie in host galaxies seen preferentially face-on, which suggests there is a substantial amount of obscuration coplanar with the galaxian disk. The obscuration must be geometrically thick (thickness-to-radius ~1) and must cover a significant fraction of the narrow line region (r>100 pc). We have examined our images for signs of perturbations that could drive fuel toward the galaxy nucleus, but there are none we can identify at a significant level. The critical element for fueling is evidently not reflected clearly in the large scale

Built-in hyperspectral camera for smartphone in visible, near-infrared and middle-infrared lights region (second report): sensitivity improvement of Fourier-spectroscopic imaging to detect diffuse reflection lights from internal human tissues for healthcare sensors

NASA Astrophysics Data System (ADS)

Kawashima, Natsumi; Hosono, Satsuki; Ishimaru, Ichiro

2016-05-01

We proposed the snapshot-type Fourier spectroscopic imaging for smartphone that was mentioned in 1st. report in this conference. For spectroscopic components analysis, such as non-invasive blood glucose sensors, the diffuse reflection lights from internal human skins are very weak for conventional hyperspectral cameras, such as AOTF (Acousto-Optic Tunable Filter) type. Furthermore, it is well known that the spectral absorption of mid-infrared lights or Raman spectroscopy especially in long wavelength region is effective to distinguish specific biomedical components quantitatively, such as glucose concentration. But the main issue was that photon energies of middle infrared lights and light intensities of Raman scattering are extremely weak. For improving sensitivity of our spectroscopic imager, the wide-field-stop & beam-expansion method was proposed. Our line spectroscopic imager introduced a single slit for field stop on the conjugate objective plane. Obviously to increase detected light intensities, the wider slit width of the field stop makes light intensities higher, regardless of deterioration of spatial resolutions. Because our method is based on wavefront-division interferometry, it becomes problems that the wider width of single slit makes the diffraction angle narrower. This means that the narrower diameter of collimated objective beams deteriorates visibilities of interferograms. By installing the relative inclined phaseshifter onto optical Fourier transform plane of infinity corrected optical systems, the collimated half flux of objective beams derived from single-bright points on objective surface penetrate through the wedge prism and the cuboid glass respectively. These two beams interfere each other and form the infererogram as spatial fringe patterns. Thus, we installed concave-cylindrical lens between the wider slit and objective lens as a beam expander. We successfully obtained the spectroscopic characters of hemoglobin from reflected lights from

Near-infrared transillumination photography of intraocular tumours.

PubMed

Krohn, Jørgen; Ulltang, Erlend; Kjersem, Bård

2013-10-01

To present a technique for near-infrared transillumination imaging of intraocular tumours based on the modifications of a conventional digital slit lamp camera system. The Haag-Streit Photo-Slit Lamp BX 900 (Haag-Streit AG) was used for transillumination photography by gently pressing the tip of the background illumination cable against the surface of the patient's eye. Thus the light from the flash unit was transmitted into the eye, leading to improved illumination and image resolution. The modification for near-infrared photography was done by replacing the original camera with a Canon EOS 30D (Canon Inc) converted by Advanced Camera Services Ltd. In this camera, the infrared blocking filter was exchanged for a 720 nm long-pass filter, so that the near-infrared part of the spectrum was recorded by the sensor. The technique was applied in eight patients: three with anterior choroidal melanoma, three with ciliary body melanoma and two with ocular pigment alterations. The good diagnostic quality of the photographs made it possible to evaluate the exact location and extent of the lesions in relation to pigmented intraocular landmarks such as the ora serrata and ciliary body. The photographic procedure did not lead to any complications. We recommend near-infrared transillumination photography as a supplementary diagnostic tool for the evaluation and documentation of anteriorly located intraocular tumours.

Intraoperative near-infrared autofluorescence imaging of parathyroid glands.

PubMed

Ladurner, Roland; Sommerey, Sandra; Arabi, Nora Al; Hallfeldt, Klaus K J; Stepp, Herbert; Gallwas, Julia K S

2017-08-01

To identify parathyroid glands intraoperatively by exposing their autofluorescence using near-infrared light. Fluorescence imaging was carried out during minimally invasive and open parathyroid and thyroid surgery. After identification, the parathyroid glands as well as the surrounding tissue were exposed to near-infrared (NIR) light with a wavelength of 690-770 nm using a modified Karl Storz near-infrared/indocyanine green (NIR/ICG) endoscopic system. Parathyroid tissue was expected to show near-infrared autofluorescence, captured in the blue channel of the camera. Whenever possible the visual identification of parathyroid tissue was confirmed histologically. In preliminary investigations, using the original NIR/ICG endoscopic system we noticed considerable interference of light in the blue channel overlying the autofluorescence. Therefore, we modified the light source by interposing additional filters. In a second series, we investigated 35 parathyroid glands from 25 patients. Twenty-seven glands were identified correctly based on NIR autofluorescence. Regarding the extent of autofluorescence, there were no noticeable differences between parathyroid adenomas, hyperplasia and normal parathyroid glands. In contrast, thyroid tissue, lymph nodes and adipose tissue revealed no substantial autofluorescence. Parathyroid tissue is characterized by showing autofluorescence in the near-infrared spectrum. This effect can be used to distinguish parathyroid glands from other cervical tissue entities.

Near-Infrared Spatially Resolved Spectroscopy for Tablet Quality Determination.

PubMed

Igne, Benoît; Talwar, Sameer; Feng, Hanzhou; Drennen, James K; Anderson, Carl A

2015-12-01

Near-infrared (NIR) spectroscopy has become a well-established tool for the characterization of solid oral dosage forms manufacturing processes and finished products. In this work, the utility of a traditional single-point NIR measurement was compared with that of a spatially resolved spectroscopic (SRS) measurement for the determination of tablet assay. Experimental designs were used to create samples that allowed for calibration models to be developed and tested on both instruments. Samples possessing a poor distribution of ingredients (highly heterogeneous) were prepared by under-blending constituents prior to compaction to compare the analytical capabilities of the two NIR methods. The results indicate that SRS can provide spatial information that is usually obtainable only through imaging experiments for the determination of local heterogeneity and detection of abnormal tablets that would not be detected with single-point spectroscopy, thus complementing traditional NIR measurement systems for in-line, and in real-time tablet analysis. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

Near-Infrared Plasmon-Assisted Water Oxidation.

PubMed

Nishijima, Yoshiaki; Ueno, Kosei; Kotake, Yuki; Murakoshi, Kei; Inoue, Haruo; Misawa, Hiroaki

2012-05-17

We report the stoichiometric evolution of oxygen via water oxidation by irradiating a plasmon-enhanced photocurrent generation system with near-infrared light (λ: 1000 nm), in which gold nanostructures were arrayed on the surface of TiO2 electrode. It is considered that multiple electron holes generated by plasmon-induced charge excitation led to the effective recovery of water oxidation after the electron transfer from gold to TiO2. The proposed system containing a gold nanostructured TiO2 electrode may be a promising artificial photosynthetic system using near-infrared light.

A validated near-infrared spectroscopic method for methanol detection in biodiesel

NASA Astrophysics Data System (ADS)

Paul, Andrea; Bräuer, Bastian; Nieuwenkamp, Gerard; Ent, Hugo; Bremser, Wolfram

2016-06-01

Biodiesel quality control is a relevant issue as biodiesel properties influence diesel engine performance and integrity. Within the European metrology research program (EMRP) ENG09 project ‘Metrology for Biofuels’, an on-line/at-site suitable near-infrared spectroscopy (NIRS) method has been developed in parallel with an improved EN14110 headspace gas chromatography (GC) analysis method for methanol in biodiesel. Both methods have been optimized for a methanol content of 0.2 mass% as this represents the maximum limit of methanol content in FAME according to EN 14214:2009. The NIRS method is based on a mobile NIR spectrometer equipped with a fiber-optic coupled probe. Due to the high volatility of methanol, a tailored air-tight adaptor was constructed to prevent methanol evaporation during measurement. The methanol content of biodiesel was determined from evaluation of NIRS spectra by partial least squares regression (PLS). Both GC analysis and NIRS exhibited a significant dependence on biodiesel feedstock. The NIRS method is applicable to a content range of 0.1% (m/m) to 0.4% (m/m) of methanol with uncertainties at around 6% relative for the different feedstocks. A direct comparison of headspace GC and NIRS for samples of FAMEs yielded that the results of both methods are fully compatible within their stated uncertainties.

LED-based near infrared sensor for cancer diagnostics

NASA Astrophysics Data System (ADS)

Bogomolov, Andrey; Ageev, Vladimir; Zabarylo, Urszula; Usenov, Iskander; Schulte, Franziska; Kirsanov, Dmitry; Belikova, Valeria; Minet, Olaf; Feliksberger, E.; Meshkovsky, I.; Artyushenko, Viacheslav

2016-03-01

Optical spectroscopic technologies are increasingly used for cancer diagnostics. Feasibility of differentiation between malignant and healthy samples of human kidney using Fluorescence, Raman, MIR and NIR spectroscopy has been recently reported . In the present work, a simplification of NIR spectroscopy method has been studied. Traditional high-resolution NIR spectrometry was replaced by an optical sensor based on a set of light-emitting diodes at selected wavelengths as light sources and a photodiode. Two prototypes of the sensor have been developed and tested using 14 in-vitro samples of seven kidney tumor patients. Statistical evaluation of results using principal component analysis and partial least-squares discriminant analysis has been performed. Despite only partial discrimination between tumor and healthy tissue achieved by the presented new technique, the results evidence benefits of LED-based near-infrared sensing used for oncological diagnostics. Publisher's Note: This paper, originally published on 4 March, 2016, was replaced with a corrected/revised version on 7 April, 2016. If you downloaded the original PDF but are unable to access the revision, please contact SPIE Digital Library Customer Service for assistance.

The cosmic infrared background experiment-2 (CIBER-2) for studying the near-infrared extragalactic background light

NASA Astrophysics Data System (ADS)

Shirahata, Mai; Arai, Toshiaki; Battle, John; Bock, James; Cooray, Asantha; Enokuchi, Akito; Hristov, Viktor; Kanai, Yoshikazu; Kim, Min Gyu; Korngut, Phillip; Lanz, Alicia; Lee, Dae-Hee; Mason, Peter; Matsumoto, Toshio; Matsuura, Shuji; Morford, Tracy; Ohnishi, Yosuke; Park, Won-Kee; Sano, Kei; Takeyama, Norihide; Tsumura, Kohji; Wada, Takehiko; Wang, Shiang-Yu; Zemcov, Michael

2016-07-01

We present the current status of the Cosmic Infrared Background ExpeRiment-2 (CIBER-2) project, whose goal is to make a rocket-borne measurement of the near-infrared Extragalactic Background Light (EBL), under a collaboration with U.S.A., Japan, South Korea, and Taiwan. The EBL is the integrated light of all extragalactic sources of emission back to the early Universe. At near-infrared wavelengths, measurement of the EBL is a promising way to detect the diffuse light from the first collapsed structures at redshift z˜10, which are impossible to detect as individual sources. However, recently, the intra-halo light (IHL) model is advocated as the main contribution to the EBL, and our new result of the EBL fluctuation from CIBER-1 experiment is also supporting this model. In this model, EBL is contributed by accumulated light from stars in the dark halo regions of low- redshift (z<2) galaxies, those were tidally stripped by the interaction of satellite dwarf galaxies. Thus, in order to understand the origin of the EBL, both the spatial fluctuation observations with multiple wavelength bands and the absolute spectroscopic observations for the EBL are highly required. After the successful initial CIBER- 1 experiment, we are now developing a new instrument CIBER-2, which is comprised of a 28.5-cm aluminum telescope and three broad-band, wide-field imaging cameras. The three wide-field (2.3×2.3 degrees) imaging cameras use the 2K×2K HgCdTe HAWAII-2RG arrays, and cover the optical and near-infrared wavelength range of 0.5-0.9 μm, 1.0-1.4 μm and 1.5-2.0 μm, respectively. Combining a large area telescope with the high sensitivity detectors, CIBER-2 will be able to measure the spatial fluctuations in the EBL at much fainter levels than those detected in previous CIBER-1 experiment. Additionally, we will use a linear variable filter installed just above the detectors so that a measurement of the absolute spectrum of the EBL is also possible. In this paper, the scientific

Medium-resolution near-infrared spectroscopy of massive young stellar objects

NASA Astrophysics Data System (ADS)

Pomohaci, R.; Oudmaijer, R. D.; Lumsden, S. L.; Hoare, M. G.; Mendigutía, I.

2017-12-01

We present medium-resolution (R ∼ 7000) near-infrared echelle spectroscopic data for 36 massive young stellar objects (MYSOs) drawn from the Red MSX Source survey. This is the largest sample observed at this resolution at these wavelengths of MYSOs to date. The spectra are characterized mostly by emission from hydrogen recombination lines and accretion diagnostic lines. One MYSO shows photospheric H I absorption, a comparison with spectral standards indicates that the star is an A-type star with a low surface gravity, implying that the MYSOs are probably swollen, as also suggested by evolutionary calculations. An investigation of the Brγ line profiles shows that most are in pure emission, while 13 ± 5 per cent display P Cygni profiles, indicative of outflow, while less than 8 ± 4 per cent have inverse P Cygni profiles, indicative of infall. These values are comparable with investigations into the optically bright Herbig Be stars, but not with those of Herbig Ae and T Tauri stars, consistent with the notion that the more massive stars undergo accretion in a different fashion than lower mass objects that are undergoing magnetospheric accretion. Accretion luminosities and rates as derived from the Br γ line luminosities agree with results for lower mass sources, providing tentative evidence for massive star formation theories based on scaling of low-mass scenarios. We present Br γ/Br12 line profile ratios exploiting the fact that optical depth effects can be traced as a function of Doppler shift across the lines. These show that the winds of MYSOs in this sample are nearly equally split between constant, accelerating and decelerating velocity structures. There are no trends between the types of features we see and bolometric luminosities or near-infrared colours.

The Use of NASA Light-Emitting Diode Near-Infrared Technology for Biostimulation

NASA Technical Reports Server (NTRS)

Whelan, Harry T.

2002-01-01

Studies on cells exposed to microgravity and hypergravity indicate that human cells need gravity to stimulate growth. As the gravitational force increases or decreases, the cell function responds in a linear fashion. This poses significant health risks for astronauts in long-term spaceflight. The application of light therapy with the use of NASA LEDs will significantly improve the medical care that is available to astronauts on long-term space missions. NASA LEDs stimulate the basic energy processes in the mitochondria (energy compartments) of each cell, particularly when near-infrared light is used to activate the color sensitive chemicals (chromophores, cytochrome systems) inside. Optimal LED wavelengths include 680, 730 and 880 nm and our laboratory has improved the healing of wounds in laboratory animals by using both NASA LED light and hyperbaric oxygen. Furthermore, DNA synthesis in fibroblasts and muscle cells has been quintupled using NASA LED light alone, in a single application combining 680, 730 and 880 nm each at 4 Joules per centimeter squared. Muscle and bone atrophy are well documented in astronauts, and various minor injuries occurring in space have been reported not to heal until landing on Earth. An LED blanket device may be used for the prevention of bone and muscle atrophy in astronauts. The depth of near-infrared light penetration into human tissue has been measured spectroscopically.

Flame: A Flexible Data Reduction Pipeline for Near-Infrared and Optical Spectroscopy

NASA Astrophysics Data System (ADS)

Belli, Sirio; Contursi, Alessandra; Davies, Richard I.

2018-05-01

We present flame, a pipeline for reducing spectroscopic observations obtained with multi-slit near-infrared and optical instruments. Because of its flexible design, flame can be easily applied to data obtained with a wide variety of spectrographs. The flexibility is due to a modular architecture, which allows changes and customizations to the pipeline, and relegates the instrument-specific parts to a single module. At the core of the data reduction is the transformation from observed pixel coordinates (x, y) to rectified coordinates (λ, γ). This transformation consists in the polynomial functions λ(x, y) and γ(x, y) that are derived from arc or sky emission lines and slit edge tracing, respectively. The use of 2D transformations allows one to wavelength-calibrate and rectify the data using just one interpolation step. Furthermore, the γ(x, y) transformation includes also the spatial misalignment between frames, which can be measured from a reference star observed simultaneously with the science targets. The misalignment can then be fully corrected during the rectification, without having to further resample the data. Sky subtraction can be performed via nodding and/or modeling of the sky spectrum; the combination of the two methods typically yields the best results. We illustrate the pipeline by showing examples of data reduction for a near-infrared instrument (LUCI at the Large Binocular Telescope) and an optical one (LRIS at the Keck telescope).

Characterization of semiconductor materials using synchrotron radiation-based near-field infrared microscopy and nano-FTIR spectroscopy.

PubMed

Hermann, Peter; Hoehl, Arne; Ulrich, Georg; Fleischmann, Claudia; Hermelink, Antje; Kästner, Bernd; Patoka, Piotr; Hornemann, Andrea; Beckhoff, Burkhard; Rühl, Eckart; Ulm, Gerhard

2014-07-28

We describe the application of scattering-type near-field optical microscopy to characterize various semiconducting materials using the electron storage ring Metrology Light Source (MLS) as a broadband synchrotron radiation source. For verifying high-resolution imaging and nano-FTIR spectroscopy we performed scans across nanoscale Si-based surface structures. The obtained results demonstrate that a spatial resolution below 40 nm can be achieved, despite the use of a radiation source with an extremely broad emission spectrum. This approach allows not only for the collection of optical information but also enables the acquisition of near-field spectral data in the mid-infrared range. The high sensitivity for spectroscopic material discrimination using synchrotron radiation is presented by recording near-field spectra from thin films composed of different materials used in semiconductor technology, such as SiO2, SiC, SixNy, and TiO2.

NEAR-INFRARED THERMAL EMISSION DETECTIONS OF A NUMBER OF HOT JUPITERS AND THE SYSTEMATICS OF GROUND-BASED NEAR-INFRARED PHOTOMETRY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Croll, Bryce; Albert, Loic; Lafreniere, David

We present detections of the near-infrared thermal emission of three hot Jupiters and one brown dwarf using the Wide-field Infrared Camera (WIRCam) on the Canada-France-Hawaii Telescope (CFHT). These include Ks-band secondary eclipse detections of the hot Jupiters WASP-3b and Qatar-1b and the brown dwarf KELT-1b. We also report Y-band, K {sub CONT}-band, and two new and one reanalyzed Ks-band detections of the thermal emission of the hot Jupiter WASP-12b. We present a new reduction pipeline for CFHT/WIRCam data, which is optimized for high precision photometry. We also describe novel techniques for constraining systematic errors in ground-based near-infrared photometry, so asmore » to return reliable secondary eclipse depths and uncertainties. We discuss the noise properties of our ground-based photometry for wavelengths spanning the near-infrared (the YJHK bands), for faint and bright stars, and for the same object on several occasions. For the hot Jupiters WASP-3b and WASP-12b we demonstrate the repeatability of our eclipse depth measurements in the Ks band; we therefore place stringent limits on the systematics of ground-based, near-infrared photometry, and also rule out violent weather changes in the deep, high pressure atmospheres of these two hot Jupiters at the epochs of our observations.« less

Coordinated U–Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.

Here, we present the results of a coordinated SIMS U–Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ~4.33 Ga, however they differ in thatmore » only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ≤300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb– 206Pb ages of 4.33 Ga. These grains are our best

Coordinated U-Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons

NASA Astrophysics Data System (ADS)

Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.

2017-04-01

We present the results of a coordinated SIMS U-Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ∼4.33 Ga, however they differ in that only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ⩽300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb-206Pb ages of 4.33 Ga. These grains are our best constraints on

Coordinated U–Pb geochronology, trace element, Ti-in-zircon thermometry and microstructural analysis of Apollo zircons

DOE PAGES

Crow, Carolyn A.; McKeegan, Kevin D.; Moser, Desmond E.

2016-12-28

Here, we present the results of a coordinated SIMS U–Pb, trace element, Ti-in-zircon thermometry, and microstructural study of 155 lunar zircons separated from Apollo 14, 15, and 17 breccia and soil samples that help resolve discrepancies between the zircon data, the lunar whole rock history and lunar magma ocean crystallization models. The majority of lunar grains are detrital fragments, some nearly 1 mm in length, of large parent crystals suggesting that they crystallized in highly enriched KREEP magmas. The zircon age distributions for all three landing sites exhibit an abundance of ages at ~4.33 Ga, however they differ in thatmore » only Apollo 14 samples have a population of zircons with ages between 4.1 and 3.9 Ga. These younger grains comprise only 10% of all dated lunar zircons and are usually small and highly shocked making them more susceptible to Pb-loss. These observations suggest that the majority of zircons crystallized before 4.1 Ga and that KREEP magmatism had predominantly ceased by this time. We also observed that trace element analyses are easily affected by contributions from inclusions (typically injected impact melt) within SIMS analyses spots. After filtering for these effects, rare-earth element (REE) abundances of pristine zircon are consistent with one pattern characterized by a negative Eu anomaly and no positive Ce anomaly, implying that the zircons formed in a reducing environment. This inference is consistent with crystallization temperatures based on measured Ti concentrations and new estimates of oxide activities which imply temperatures ranging between 958 ± 57 and 1321 ± 100 °C, suggesting that zircon parent magmas were anhydrous. Together, the lunar zircon ages and trace elements are consistent with a ≤300 My duration of KREEP magmatism under anhydrous, reducing conditions. We also report two granular texture zircons that contain baddeleyite cores, which both yield 207Pb– 206Pb ages of 4.33 Ga. These grains are our best

POLICAN: A near-infrared imaging polarimeter at OAGH

NASA Astrophysics Data System (ADS)

Devaraj, R.; Luna, A.; Carrasco, L.; Mayya, Y. D.; Serrano-Bernal, O.

2017-07-01

We present a near-infrared linear imaging polarimeter POLICAN, developed for the Cananea near-infrared camera (CANICA) at the 2.1m telescope of the Guillermo Haro Astrophysical Observatory (OAGH) located at Cananea, Sonora, México. POLICAN reaches a limiting magnitude to about 16th mag with a polarimetric accuracy of about 1% for bright sources.

Advances in Organic Near-Infrared Materials and Emerging Applications.

PubMed

Qi, Ji; Qiao, Wenqiang; Wang, Zhi Yuan

2016-06-01

Much progress has been made in the field of research on organic near-infrared materials for potential applications in photonics, communications, energy, and biophotonics. This account mainly describes our research work on organic near-infrared materials; in particular, donor-acceptor small molecules, organometallics, and donor-acceptor polymers with the bandgaps less than 1.2 eV. The molecular designs, structure-property relationships, unique near-infrared absorption, emission and color/wavelength-changing properties, and some emerging applications are discussed. © 2016 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Upconversion fiber-optic confocal microscopy under near-infrared pumping.

PubMed

Kim, Do-Hyun; Kang, Jin U; Ilev, Ilko K

2008-03-01

We present a simple upconversion fiber-optic confocal microscope design using a near-infrared laser for pumping of a rare-earth-doped glass powder. The nonlinear optical frequency conversion process is highly efficient with more than 2% upconversion fluorescence efficiency at a near-infrared pumping wavelength of 1.55 microm. The upconversion confocal design allows the use of conventional Si detectors and 1.55 microm near-infrared pump light. The lateral and axial resolutions of the system were equal to or better than 1.10 and 13.11 microm, respectively.

Reference-free spectroscopic determination of fat and protein in milk in the visible and near infrared region below 1000nm using spatially resolved diffuse reflectance fiber probe.

PubMed

Bogomolov, Andrey; Belikova, Valeria; Galyanin, Vladislav; Melenteva, Anastasiia; Meyer, Hans

2017-05-15

New technique of diffuse reflectance spectroscopic analysis of milk fat and total protein content in the visible (Vis) and adjacent near infrared (NIR) region (400-995nm) has been developed and tested. Sample analysis was performed through a probe having eight 200-µm fiber channels forming a linear array. One of the end fibers was used for the illumination and other seven - for the spectroscopic detection of diffusely reflected light. One of the detection channels was used as a reference to normalize the spectra and to convert them into absorbance-equivalent units. The method has been tested experimentally using a designed sample set prepared from industrial raw milk standards with widely varying fat and protein content. To increase the modelling robustness all milk samples were measured in three different homogenization degrees. Comprehensive data analysis has shown the advantage of combining both spectral and spatial resolution in the same measurement and revealed the most relevant channels and wavelength regions. The modelling accuracy was further improved using joint variable selection and preprocessing optimization method based on the genetic algorithm. The root mean-square errors of different validation methods were below 0.10% for fat and below 0.08% for total protein content. Based on the present experimental data, it was computationally shown that the full-spectrum analysis in this method can be replaced by a sensor measurement at several specific wavelengths, for instance, using light-emitting diodes (LEDs) for illumination. Two optimal sensor configurations have been suggested: with nine LEDs for the analysis of fat and seven - for protein content. Both simulated sensors exhibit nearly the same component determination accuracy as corresponding full-spectrum analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

21 CFR 882.1935 - Near Infrared (NIR) Brain Hematoma Detector.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Near Infrared (NIR) Brain Hematoma Detector. 882... Infrared (NIR) Brain Hematoma Detector. (a) Identification. A Near Infrared (NIR) Brain Hematoma Detector... evaluate suspected brain hematomas. (b) Classification. Class II (special controls). The special controls...

21 CFR 882.1935 - Near Infrared (NIR) Brain Hematoma Detector.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Near Infrared (NIR) Brain Hematoma Detector. 882... Infrared (NIR) Brain Hematoma Detector. (a) Identification. A Near Infrared (NIR) Brain Hematoma Detector... evaluate suspected brain hematomas. (b) Classification. Class II (special controls). The special controls...

[Identification of Animal Whole Blood Based on Near Infrared Transmission Spectroscopy].

PubMed

Wan, Xiong; Wang, Jian; Liu, Peng-xi; Zhang, Ting-ting

2016-01-01

The inspection and classification for blood products are important but complicated in import-export ports or inspection and quarantine departments. For the inspection of whole blood products, open sampling can cause pollution and virulence factors in bloods samples may even endanger inspectors. Thus non-contact classification and identification methods for whole bloods of animals are needed. Spectroscopic techniques adopted in the flowcytometry need sampling blood cells during the detection; therefore they can not meet the demand of non-contact identification and classification for whole bloods of animals. Infrared absorption spectroscopy is a technique that can be used to analyze the molecular structure and chemical bonds of detected samples under the condition of non-contact. To find a feasible spectroscopic approach of non-contact detection for the species variation in whole blood samples, a near infrared transmitted spectra (NITS, 4 497.669 - 7 506.4 cm(-1)) experiment of whole blood samples of three common animals including chickens, dogs and cats has been conducted. During the experiment, the spectroscopic resolution is 5 cm(-1), and each spectrogram is an average of 5 measured spectral data. Experimental results show that all samples have a sharp absorption peak between 5 184 and 5 215 cm(-1), and a gentle absorption peak near 7 000 cm(-1). Besides, the NITS curves of different samples of same animals are similar, and only have slight differences in the whole transmittance. A correlation coefficient (CC) is induced to distinguish the differences of the three animals' whole bloods in NITS curves, and the computed CCs between NITS curves of different samples of the same animals, are greater than 0.99, whereas CCs between NITS curves of the whole bloods of different animals are from 0.509 48 to 0.916 13. Among which CCs between NITS curves of the whole bloods of chickens and cats are from 0.857 23 to 0.912 44, CCs between NITS curves of the whole bloods of

Complementarity in radiochemical and infrared spectroscopic characterization of electrode adsorption

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wieckowski, A.

1994-03-01

Radioactive labelling and infrared spectroscopy are frequently used as direct, in situ probes into the structure of the electrochemical solid/liquid interface. These techniques are compared, in a polemical fashion, in the context of a recent publication by Parry et al. (Langmuir 1993, 9, 1878) where the research potential of the former technique was not adequately depicted. It is shown that radiotracers can clearly differentiate between the surface and solution species, both neutrals and anions. In addition to the surface specificity, the radiotracers offer a quantitative determination of adsorbate surface concentrations, a feature not yet demonstrated with surface infrared spectroscopy inmore » electrochemistry. Therefore, these two techniques are complementary. Examples of the combined radiochemical and spectroscopic measurements of adsorption with equivalent (smooth) electrode surfaces are quoted. 11 refs., 2 figs.« less

Near infrared leaf reflectance modeling

NASA Technical Reports Server (NTRS)

Parrish, J. B.

1985-01-01

Near infrared leaf reflectance modeling using Fresnel's equation (Kumar and Silva, 1973) and Snell's Law successfully approximated the spectral curve for a 0.25-mm turgid oak leaf lying on a Halon background. Calculations were made for ten interfaces, air-wax, wax-cellulose, cellulose-water, cellulose-air, air-water, and their inverses. A water path of 0.5 mm yielded acceptable results, and it was found that assignment of more weight to those interfaces involving air versus water or cellulose, and less to those involving wax, decreased the standard deviation of the error for all wavelengths. Data suggest that the air-cell interface is not the only important contributor to the overall reflectance of a leaf. Results also argue against the assertion that the near infrared plateau is a function of cell structure within the leaf.

Low-Resolution Near-infrared Stellar Spectra Observed by the Cosmic Infrared Background Experiment (CIBER)

NASA Astrophysics Data System (ADS)

Kim, Min Gyu; Lee, Hyung Mok; Arai, Toshiaki; Bock, James; Cooray, Asantha; Jeong, Woong-Seob; Kim, Seong Jin; Korngut, Phillip; Lanz, Alicia; Lee, Dae Hee; Lee, Myung Gyoon; Matsumoto, Toshio; Matsuura, Shuji; Nam, Uk Won; Onishi, Yosuke; Shirahata, Mai; Smidt, Joseph; Tsumura, Kohji; Yamamura, Issei; Zemcov, Michael

2017-02-01

We present near-infrared (0.8-1.8 μm) spectra of 105 bright ({m}J < 10) stars observed with the low-resolution spectrometer on the rocket-borne Cosmic Infrared Background Experiment. As our observations are performed above the Earth's atmosphere, our spectra are free from telluric contamination, which makes them a unique resource for near-infrared spectral calibration. Two-Micron All-Sky Survey photometry information is used to identify cross-matched stars after reduction and extraction of the spectra. We identify the spectral types of the observed stars by comparing them with spectral templates from the Infrared Telescope Facility library. All the observed spectra are consistent with late F to M stellar spectral types, and we identify various infrared absorption lines.

The Y-type Brown Dwarfs: Estimates of Mass and Age from New Astrometry, Homogenized Photometry, and Near-infrared Spectroscopy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leggett, S. K.; Tremblin, P.; Esplin, T. L.

The survey of the mid-infrared sky by the Wide-field Infrared Survey Explorer ( WISE ) led to the discovery of extremely cold, low-mass brown dwarfs, classified as Y dwarfs, which extend the T class to lower temperatures. Twenty-four Y dwarfs are known at the time of writing. Here we present improved parallaxes for four of these, determined using Spitzer images. We give new photometry for four late-type T and three Y dwarfs and new spectra of three Y dwarfs, obtained at Gemini Observatory. We also present previously unpublished photometry taken from HST , ESO, Spitzer , and WISE archives ofmore » 11 late-type T and 9 Y dwarfs. The near-infrared data are put onto the same photometric system, forming a homogeneous data set for the coolest brown dwarfs. We compare recent models to our photometric and spectroscopic data set. We confirm that nonequilibrium atmospheric chemistry is important for these objects. Nonequilibrium cloud-free models reproduce well the near-infrared spectra and mid-infrared photometry for the warmer Y dwarfs with 425 ≤ T {sub eff} (K) ≤ 450. A small amount of cloud cover may improve the model fits in the near-infrared for the Y dwarfs with 325 ≤ T {sub eff} (K) ≤ 375. Neither cloudy nor cloud-free models reproduce the near-infrared photometry for the T {sub eff} = 250 K Y dwarf W0855. We use the mid-infrared region, where most of the flux originates, to constrain our models of W0855. We find that W0855 likely has a mass of 1.5–8 Jupiter masses and an age of 0.3–6 Gyr. The Y dwarfs with measured parallaxes are within 20 pc of the Sun and have tangential velocities typical of the thin disk. The metallicities and ages we derive for the sample are generally solar-like. We estimate that the known Y dwarfs are 3 to 20 Jupiter-mass objects with ages of 0.6–8.5 Gyr.« less

The Hubble Space Telescope: UV, Visible, and Near-Infrared Pursuits

NASA Technical Reports Server (NTRS)

Wiseman, Jennifer

2010-01-01

The Hubble Space Telescope continues to push the limits on world-class astrophysics. Cameras including the Advanced Camera for Surveys and the new panchromatic Wide Field Camera 3 which was installed nu last year's successful servicing mission S2N4,o{fer imaging from near-infrared through ultraviolet wavelengths. Spectroscopic studies of sources from black holes to exoplanet atmospheres are making great advances through the versatile use of STIS, the Space Telescope Imaging Spectrograph. The new Cosmic Origins Spectrograph, also installed last year, is the most sensitive UV spectrograph to fly io space and is uniquely suited to address particular scientific questions on galaxy halos, the intergalactic medium, and the cosmic web. With these outstanding capabilities on HST come complex needs for laboratory astrophysics support including atomic and line identification data. I will provide an overview of Hubble's current capabilities and the scientific programs and goals that particularly benefit from the studies of laboratory astrophysics.

Relative performance evaluation of a custom-made near infrared reflectance instrument and two commercial instruments (Foss and ASD) in the nondestructive moisture content measurement of in-shell peanuts

USDA-ARS?s Scientific Manuscript database

A custom made Near Infrared Reflectance (NIR) spectroscope was used to determine the moisture content of in-shell peanuts of Virginia type peanuts. Peanuts were conditioned to different moisture levels between 6 and 26 % (wet basis) and samples from different moisture levels were separated into two...

A near-infrared spectroscopic survey of massive jets towards extended green objects

NASA Astrophysics Data System (ADS)

Caratti o Garatti, A.; Stecklum, B.; Linz, H.; Garcia Lopez, R.; Sanna, A.

2015-01-01

Context. Protostellar jets and outflows are the main outcome of the star formation process, and their analysis can provide us with major clues about the ejection and accretion history of young stellar objects (YSOs). Aims: We aim at deriving the main physical properties of massive jets from near-infrared (NIR) observations, comparing them to those of a large sample of jets from low-mass YSOs, and relating them to the main features of their driving sources. Methods: We present a NIR imaging (H2 and Ks) and low-resolution spectroscopic (0.95-2.50 μm) survey of 18 massive jets towards GLIMPSE extended green objects (EGOs), driven by intermediate- and high-mass YSOs, which have bolometric luminosities (Lbol) between 4 × 102 and 1.3 × 105 L⊙. Results: As in low-mass jets, H2 is the primary NIR coolant, detected in all the analysed flows, whereas the most important ionic tracer is [Fe ii], detected in half of the sampled jets. Our analysis indicates that the emission lines originate from shocks at high temperatures and densities. No fluorescent emission is detected along the flows, regardless of the source bolometric luminosity. On average, the physical parameters of these massive jets (i.e. visual extinction, temperature, column density, mass, and luminosity) have higher values than those measured in their low-mass counterparts. The morphology of the H2 flows is varied, mostly depending on the complex, dynamic, and inhomogeneous environment in which these massive jets form and propagate. All flows and jets in our sample are collimated, showing large precession angles. Additionally, the presence of both knots and jets suggests that the ejection process is continuous with burst episodes, as in low-mass YSOs. We compare the flow H2 luminosity with the source bolometric luminosity confirming the tight correlation between these two quantities. Five sources, however, display a lower LH2/Lbol efficiency, which might be related to YSO evolution. Most important, the

Fluorescence Lifetime Imaging Microscopy Using Near-Infrared Contrast Agents

PubMed Central

Nothdurft, Ralph; Sarder, Pinaki; Bloch, Sharon; Culver, Joseph; Achilefu, Samuel

2013-01-01

Although single-photon fluorescence lifetime imaging microscopy (FLIM) is widely used to image molecular processes using a wide range of excitation wavelengths, the captured emission of this technique is confined to the visible spectrum. Here, we explore the feasibility of utilizing near-infrared (NIR) fluorescent molecular probes with emission >700 nm for FLIM of live cells. The confocal microscope is equipped with a 785 nm laser diode, a red-enhanced photomultiplier tube, and a time-correlated single photon counting card. We demonstrate that our system reports the lifetime distributions of NIR fluorescent dyes, cypate and DTTCI, in cells. In cells labeled separately or jointly with these dyes, NIR FLIM successfully distinguishes their lifetimes, providing a method to sort different cell populations. In addition, lifetime distributions of cells co-incubated with these dyes allow estimate of the dyes’ relative concentrations in complex cellular microenvironments. With the heightened interest in fluorescence lifetime-based small animal imaging using NIR fluorophores, this technique further serves as a bridge between in vitro spectroscopic characterization of new fluorophore lifetimes and in vivo tissue imaging. PMID:22788550

Spectroscopic determination of leaf traits using infrared spectra

NASA Astrophysics Data System (ADS)

Buitrago, Maria F.; Groen, Thomas A.; Hecker, Christoph A.; Skidmore, Andrew K.

2018-07-01

Leaf traits characterise and differentiate single species but can also be used for monitoring vegetation structure and function. Conventional methods to measure leaf traits, especially at the molecular level (e.g. water, lignin and cellulose content), are expensive and time-consuming. Spectroscopic methods to estimate leaf traits can provide an alternative approach. In this study, we investigated high spectral resolution (6612 bands) emissivity measurements from the short to the long wave infrared (1.4-16.0 μm) of leaves from 19 different plant species ranging from herbaceous to woody, and from temperate to tropical types. At the same time, we measured 14 leaf traits to characterise a leaf, including chemical (e.g., leaf water content, nitrogen, cellulose) and physical features (e.g., leaf area and leaf thickness). We fitted partial least squares regression (PLSR) models across the SWIR, MWIR and LWIR for each leaf trait. Then, reduced models (PLSRred) were derived by iteratively reducing the number of bands in the model (using a modified Jackknife resampling method with a Martens and Martens uncertainty test) down to a few bands (4-10 bands) that contribute the most to the variation of the trait. Most leaf traits could be determined from infrared data with a moderate accuracy (65 < Rcv2 < 77% for observed versus predicted plots) based on PLSRred models, while the accuracy using the whole infrared range (6612 bands) presented higher accuracies, 74 < Rcv2 < 90%. Using the full SWIR range (1.4-2.5 μm) shows similarly high accuracies compared to the whole infrared. Leaf thickness, leaf water content, cellulose, lignin and stomata density are the traits that could be estimated most accurately from infrared data (with Rcv2 above 0.80 for the full range models). Leaf thickness, cellulose and lignin were predicted with reasonable accuracy from a combination of single infrared bands. Nevertheless, for all leaf traits, a combination of a few bands yields moderate to

AKARI Infrared Camera Survey of the Large Magellanic Cloud

NASA Astrophysics Data System (ADS)

Shimonishi, Takashi; Kato, Daisuke; Ita, Yoshifusa; Onaka, Takashi

2015-08-01

The Large Magellanic Cloud (LMC) is one of the closest external galaxies to the Milky Way and has been playing a central role in various fields of modern astronomy and astrophysics. We conducted an unbiased near- to mid-infrared imaging and spectroscopic survey of the LMC with the infrared satellite AKARI. An area of about 10 square degrees of the LMC was observed by five imaging bands (each centered at 3.2, 7, 11, 15, and 24 micron) and the low-resolution slitless prism spectroscopy mode (2--5 micron, R~20) equipped with the Infrared Camera on board AKARI. Based on the data obtained in the survey, we constructed the photometric and spectroscopic catalogues of point sources in the LMC. The photometric catalogue includes about 650,000, 90,000, 49,000, 17,000, 7,000 sources at 3.2, 7, 11, 15, and 24 micron, respectively (Ita et al. 2008, PASJ, 60, 435; Kato et al. 2012, AJ, 144, 179), while the spectroscopic catalogue includes 1,757 sources (Shimonishi et al. 2013, AJ, 145, 32). Both catalogs are publicly released and available through a website (AKARI Observers Page, http://www.ir.isas.ac.jp/AKARI/Observation/). The catalog includes various infrared sources such as young stellar objects, asymptotic giant branch stars, giants/supergiants, and many other cool or dust-enshrouded stars. A large number of near-infrared spectral data, coupled with complementary broadband photometric data, allow us to investigate infrared spectral features of sources by comparison with their spectral energy distributions. Combined use of the present AKARI LMC catalogues with other infrared catalogues such as SAGE and HERITAGE possesses scientific potential that can be applied to various astronomical studies. In this presentation, we report the details of the AKARI photometric and spectroscopic catalogues of the LMC.

Application of a novel combination of near-infrared spectroscopy and a humidity-controlled 96-well plate to the characterization of the polymorphism of imidafenacin.

PubMed

Uchida, Hiroshi; Yoshinaga, Tokuji; Mori, Hirotoshi; Otsuka, Makoto

2010-11-01

This study aimed to apply a currently available chemometric near-infrared spectroscopy technique to the characterization of the polymorphic properties of drug candidates. The technique requires only small quantities of samples and is therefore applicable to drugs in the early stages of development. The combination of near-infrared spectroscopy and a patented 96-well plate divided into 32 individual, humidity-controlled, three-well compartments was used in the characterization of a hygroscopic drug, imidafenacin, which has two polymorphs and one pseudo-polymorph. Characterization was also conducted with powder X-ray diffraction and thermal analysis. The results were compared with those from routinely used conventional analyses. Both the microanalysis and conventional analysis successfully characterised the substance (transformation and relative stability among the two polymorphs and a pseudo-polymorph) depending on the storage conditions. Near-infrared spectroscopic analyses utilizing a humidity-controlled 96-well plate required only small amounts of the sample for characterization under the various conditions of relative humidity. Near-infrared microanalysis can be applied to polymorphic studies of small quantities of a drug candidate. The results also suggest that the method will predict the behaviors of a hygroscopic candidate in solid pharmaceutical preparations at the early stages of drug development. © 2010 The Authors. JPP © 2010 Royal Pharmaceutical Society of Great Britain.

Geochemical signatures and magmatic stability of terrestrial impact produced zircon

NASA Astrophysics Data System (ADS)

Wielicki, Matthew M.; Harrison, T. Mark; Schmitt, Axel K.

2012-03-01

Understanding the role of impacts on early Earth has major implications to near surface conditions, but the apparent lack of preserved terrestrial craters > 2 Ga does not allow a direct sampling of such events. Ion microprobe U-Pb ages, REE abundances and Ti-in-zircon thermometry for impact produced zircon are reported here. These results from terrestrial impactites, ranging in age from ~ 35 Ma to ~ 2 Ga, are compared with the detrital Hadean zircon population from Western Australia. Such comparisons may provide the only terrestrial constraints on the role of impacts during the Hadean and early Archean, a time predicted to have a high bolide flux. Ti-in-zircon thermometry indicates an average of 773 °C for impact-produced zircon, ~ 100 °C higher than the average for Hadean zircon crystals. The agreement between whole-rock based zircon saturation temperatures for impactites and Ti-in-zircon thermometry (at aTiO2 = 1) implies that Ti-in-zircon thermometry record actual crystallization temperatures for impact melts. Zircon saturation modeling of Archean crustal rock compositions undergoing thermal excursions associated with the Late Heavy Bombardment predicts equally high zircon crystallization temperatures. The lack of such thermal signatures in the Hadean zircon record implies that impacts were not a dominant mechanism of producing the preserved Hadean detrital zircon record.

Targeted vertical cross-sectional imaging with handheld near-infrared dual axes confocal fluorescence endomicroscope.

PubMed

Qiu, Zhen; Liu, Zhongyao; Duan, Xiyu; Khondee, Supang; Joshi, Bishnu; Mandella, Michael J; Oldham, Kenn; Kurabayashi, Katsuo; Wang, Thomas D

2013-02-01

We demonstrate vertical cross-sectional (XZ-plane) images of near-infrared (NIR) fluorescence with a handheld dual axes confocal endomicroscope that reveals specific binding of a Cy5.5-labeled peptide to pre-malignant colonic mucosa. This view is perpendicular to the tissue surface, and is similar to that used by pathologists. The scan head is 10 mm in outer diameter (OD), and integrates a one dimensional (1-D) microelectromechanical systems (MEMS) X-axis scanner and a bulky lead zirconate titanate (PZT) based Z-axis actuator. The microscope images in a raster-scanning pattern with a ±6 degrees (mechanical) scan angle at ~3 kHz in the X-axis (fast) and up to 10 Hz (0-400 μm) in the Z-axis (slow). Vertical cross-sectional fluorescence images are collected with a transverse and axial resolution of 4 and 5 μm, respectively, over a field-of-view of 800 μm (width) × 400 μm (depth). NIR vertical cross-sectional fluorescence images of fresh mouse colonic mucosa demonstrate histology-like imaging performance with this miniature instrument.

Targeted vertical cross-sectional imaging with handheld near-infrared dual axes confocal fluorescence endomicroscope

PubMed Central

Qiu, Zhen; Liu, Zhongyao; Duan, Xiyu; Khondee, Supang; Joshi, Bishnu; Mandella, Michael J.; Oldham, Kenn; Kurabayashi, Katsuo; Wang, Thomas D.

2013-01-01

We demonstrate vertical cross-sectional (XZ-plane) images of near-infrared (NIR) fluorescence with a handheld dual axes confocal endomicroscope that reveals specific binding of a Cy5.5-labeled peptide to pre-malignant colonic mucosa. This view is perpendicular to the tissue surface, and is similar to that used by pathologists. The scan head is 10 mm in outer diameter (OD), and integrates a one dimensional (1-D) microelectromechanical systems (MEMS) X-axis scanner and a bulky lead zirconate titanate (PZT) based Z-axis actuator. The microscope images in a raster-scanning pattern with a ±6 degrees (mechanical) scan angle at ~3 kHz in the X-axis (fast) and up to 10 Hz (0–400 μm) in the Z-axis (slow). Vertical cross-sectional fluorescence images are collected with a transverse and axial resolution of 4 and 5 μm, respectively, over a field-of-view of 800 μm (width) × 400 μm (depth). NIR vertical cross-sectional fluorescence images of fresh mouse colonic mucosa demonstrate histology-like imaging performance with this miniature instrument. PMID:23412564

Comparative hazard evaluation of near-infrared diode lasers.

PubMed

Marshall, W J

1994-05-01

Hazard evaluation methods from various laser protection standards differ when applied to extended-source, near-infrared lasers. By way of example, various hazard analyses are applied to laser training systems, which incorporate diode lasers, specifically those that assist in training military or law enforcement personnel in the proper use of weapons by simulating actual firing by the substitution of a beam of near-infrared energy for bullets. A correct hazard evaluation of these lasers is necessary since simulators are designed to be directed toward personnel during normal use. The differences among laser standards are most apparent when determining the hazard class of a laser. Hazard classification is based on a comparison of the potential exposures with the maximum permissible exposures in the 1986 and 1993 versions of the American National Standard for the Safe Use of Lasers, Z136.1, and the accessible emission limits of the federal laser product performance standard. Necessary safety design features of a particular system depend on the hazard class. The ANSI Z136.1-1993 standard provides a simpler and more accurate hazard assessment of low-power, near-infrared, diode laser systems than the 1986 ANSI standard. Although a specific system is evaluated, the techniques described can be readily applied to other near-infrared lasers or laser training systems.

A portable cross-shape near-infrared spectroscopic detector for bone marrow lesions diagnosis

NASA Astrophysics Data System (ADS)

Su, Yu; Li, Ting

2016-02-01

Bone marrow lesions (BMLs) is an incidence-increasing disease which seriously hazard to human health and possibly contribute to paralysis. Delayed treatment often occurred to BMLs patients due to its characteristics such as complex and diverse clinical manifestations, non-specific, easy to misdiagnosis and etc. The conventional diagnosis methods of BMLs mainly rely on bone marrow biopsy/aspiration, which are invasive, painful, high health risk, and discontinuous which disabled monitoring and during-surgery guidance. Thus we proposed to develop a noninvasive, real-time, continuous measurement, easy-operated device aimed at detecting bone marrow diseases. This device is based on near-infrared spectroscopy and the probe is designed with a cross-shape to tightly and comfortably attach human spine. Space-resolved source-detector placement and measurement algorithm are employed. Four selected wavelength were utilized here to extract BMLs-related component contents of oxy-, deoxy-hemoglobin, fat, scattering index corresponding to fibrosis. We carried out an ink experiment and one clinical measurement to verify the feasibility of our device. The potential of NIRS in BMLs clinics is revealed.

Near-room-temperature Mid-infrared Photoconductor Signal and Noise Characterization

DTIC Science & Technology

2012-09-01

Near-room-temperature Mid-infrared Photoconductor Signal and Noise Characterization by Justin R. Bickford, Neal K. Bambha, and Wayne H. Chang...Adelphi, MD 20783-1197 ARL-TR-6169 September 2012 Near-room-temperature Mid-infrared Photoconductor Signal and Noise Characterization...temperature Mid-infrared Photoconductor Signal and Noise Characterization 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6

Near-infrared metallicities, radial velocities, and spectral types for 447 nearby M dwarfs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newton, Elisabeth R.; Charbonneau, David; Irwin, Jonathan

We present metallicities, radial velocities, and near-infrared (NIR) spectral types for 447 M dwarfs determined from moderate resolution (R ≈ 2000) NIR spectra obtained with the NASA Infrared Telescope Facility (IRTF)/SpeX. These M dwarfs are primarily targets of the MEarth Survey, a transiting planet survey searching for super Earths around mid-to-late M dwarfs within 33 pc. We present NIR spectral types for each star and new spectral templates for the IRTF in the Y, J, H, and K-bands, created using M dwarfs with near-solar metallicities. We developed two spectroscopic distance calibrations that use NIR spectral type or an index basedmore » on the curvature of the K-band continuum. Our distance calibration has a scatter of 14%. We searched 27 NIR spectral lines and 10 spectral indices for metallicity sensitive features, taking into account correlated noise in our estimates of the errors on these parameters. We calibrated our relation using 36 M dwarfs in common proper pairs with an F-, G-, or K-type star of known metallicity. We validated the physical association of these pairs using proper motions, radial velocities, and spectroscopic distance estimates. Our resulting metallicity calibration uses the sodium doublet at 2.2 μm as the sole indicator for metallicity. It has an accuracy of 0.12 dex inferred from the scatter between the metallicities of the primaries and the estimated metallicities of the secondaries. Our relation is valid for NIR spectral types from M1V to M5V and for –1.0 dex < [Fe/H] < +0.35 dex. We present a new color-color metallicity relation using J – H and J – K colors that directly relates two observables: the distance from the M dwarf main sequence and equivalent width of the sodium line at 2.2 μm. We used radial velocities of M dwarf binaries, observations at different epochs, and comparison between our measurements and precisely measured radial velocities to demonstrate a 4 km s{sup –1} accuracy.« less

Near-infrared autofluorescence imaging to detect parathyroid glands in thyroid surgery.

PubMed

Ladurner, R; Al Arabi, N; Guendogar, U; Hallfeldt, Kkj; Stepp, H; Gallwas, Jks

2018-01-01

Objective To identify and save parathyroid glands during thyroidectomy by displaying their autofluorescence. Methods Autofluorescence imaging was carried out during thyroidectomy with and without central lymph node dissection. After visual recognition by the surgeon, the parathyroid glands and the surrounding tissue were exposed to near-infrared light with a wavelength of 690-770 nm using a modified Karl Storz near infrared/indocyanine green endoscopic system. Parathyroid tissue was expected to show near infrared autofluorescence at 820 nm, captured in the blue channel of the camera. Results We investigated 41 parathyroid glands from 20 patients; 37 glands were identified correctly based on near-infrared autofluorescence. Neither lymph nodes nor thyroid revealed substantial autofluorescence and nor did adipose tissue. Conclusions Parathyroid tissue is characterised by showing autofluorescence in the near-infrared spectrum. This effect can be used to identify and preserve parathyroid glands during thyroidectomy.

Zircon-scale insights into the history of a Supervolcano, Bishop Tuff, Long Valley, California, with implications for the Ti-in-zircon geothermometer

USGS Publications Warehouse

Reid, M.R.; Vazquez, J.A.; Schmitt, A.K.

2011-01-01

Zircon has the outstanding capacity to record chronological, thermal, and chemical information, including the storage history of zoned silicic magma reservoirs like the one responsible for the Bishop Tuff of eastern California, USA. Our novel ion microprobe approach reveals that Bishop zircon rims with diverse chemical characteristics surround intermediate domains with broadly similar compositions. The highest Y, REE, U, and Th concentrations tend to accompany the largest excesses in Y + REE3+:P beyond what can be explained by xenotime substitution in zircon. Apparent Ti-in-zircon temperatures of <720??C for zircon rims are distinctly lower than most of the range in eruption temperatures, as estimated from FeTi-oxide equilibria and zircon solubility at quench. While permissive of crystallization of zircon at near-solidus conditions, the low Ti-in-zircon temperatures are probably better explained by sources of inaccuracy in the temperature estimates. After apparently nucleating from different melts, zircons from across the Bishop Tuff compositional spectrum may have evolved to broadly similar chemical and thermal conditions and therefore it is possible that there was no significant thermal gradient in the magma reservoir at some stage in its evolution. There is also no compelling evidence for punctuated heat ?? chemical influxes during the intermediate stages of zircon growth. Judging by the zircon record, the main volume of the erupted magma evolved normally by secular cooling but the latest erupted portion is characterized by a reversal in chemistry that appears to indicate perfusion of the magma reservoir by-or zircon entrainment in-a less evolved melt from the one in which the zircons had previously resided. ?? 2010 Springer-Verlag.

HAFNIAN ZIRCONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

von Knorring, O.; Hornung, G.

1961-06-17

Two hafnia zircons were examined in detail, one from Mtoko in Southern Rhodesia, containing 21% HfO/sub 2/, and the other from Karibib in South-West Africa, with 31% HfO/sub 2/. In both cases the zircons are associated with the later tantalum-rich phase of mineralization. The Mtoko zircon forms small, mauve- colored, independent crystals in the albitic zone of the pegmatite. The zircon from Karibib occurs in larger reddish-brown masses, partly intergrown with minute manganotantalite crystals and set in a matrix of lithium-bearing mica, albite, quartz and kaolinized feldspar. Some crystals show dominant pyramid faces, with a suppressed prism. Both zircons exhibitmore » an intense golden-yellow fluorescence in UV light. The zircon from Karibib was found to be only weakly radioactive. Data are given concerning various properties of the two zircons. (P.C.H.)« less

High-dispersion infrared spectroscopic observations of comet 8P/Tuttle with VLT/CRIRES

NASA Astrophysics Data System (ADS)

Kobayashi, H.; Bockelée-Morvan, D.; Kawakita, H.; Dello Russo, N.; Jehin, E.; Manfroid, J.; Smette, A.; Hutsemékers, D.; Stüwe, J.; Weiler, M.; Arpigny, C.; Biver, N.; Cochran, A.; Crovisier, J.; Magain, P.; Sana, H.; Schulz, R.; Vervack, R. J.; Weaver, H.; Zucconi, J.-M.

2010-01-01

We report on the composition of the Halley-family comet (HFC) 8P/Tuttle investigated with high-dispersion near-infrared spectroscopic observations. The observations were carried out at the ESO VLT (Very Large Telescope) with the CRIRES instrument as part of a multi-wavelength observation campaign of 8P/Tuttle performed in late January and early February 2008. Radar observations suggested that 8P/Tuttle is a contact binary, and it was proposed that these components might be heterogeneous in chemistry. We determined mixing ratios of organic volatiles with respect to H2O and found that mixing ratios were consistent with previous near infrared spectroscopic observations obtained in late December 2007 and in late January 2008. It has been suggested that because 8P/Tuttle is a contact binary, it might be chemically heterogeneous. However, we find no evidence for chemical heterogeneity within the nucleus of 8P/Tuttle. We also compared the mixing ratios of organic molecules in 8P/Tuttle with those of both other HFCs and long period comets (LPCs) and found that HCN, C2H2, and C2H6 are depleted whereas CH4 and CH3OH have normal abundances. This may indicate that 8P/Tuttle was formed in a different region of the early solar nebula than other HFCs and LPCs. We estimated the conversion efficiency from C2H2 to C2H6 by hydrogen addition reactions on cold grains by employing the C2H6/(C2H6+C2H2) ratio. The C2H6/(C2H6+C2H2) ratio in 8P/Tuttle is consistent with the ratios found in other HFCs and LPCs within the error bars. We also discuss the source of C2 and CN based on our observations and conclude that the abundances of C2H2 and C2H6 are insufficient to explain the C2 abundances in comet 8P/Tuttle and that the abundance of HCN is insufficient to explain the CN abundances in the comet, so at least one additional parent is needed for each species, as pointed out in previous study. Based on observations collected at the European Southern Observatory, Paranal, Chile (ESO Prog. 080.C

PRIMitive Asteroids Spectroscopic Survey - PRIMASS: First Results

NASA Astrophysics Data System (ADS)

de Leon, Julia; Pinilla-Alonso, Noemi; Campins, Humberto; Lorenzi, Vania; Licandro, Javier; Morate, David; Tanga, Paolo; Cellino, Alberto; Delbo, Marco

2015-11-01

NASA OSIRIS-REx and JAXA Hayabusa 2 sample-return missions have targeted two near-Earth asteroids: (101955) Bennu and (162173) 1999 JU3, respectively. These are primitive asteroids that are believed to originate in the inner belt, where five distinct sources have been identified: four primitive collisional families (Polana, Erigone, Sulamitis, and Clarissa), and a population of low-albedo and low-inclination background asteroids. Identifying and characterizing the populations from which these two NEAs might originate will enchance the science return of the two missions.With this main objective in mind, we initiated in 2010 a spectroscopic survey in the visible and the near-infrared to characterize the primitive collisional families in the inner belt and the low-albedo background population. This is the PRIMitive Asteroids Spectroscopic Survey - PRIMASS. So far we have obtained more than 200 spectra using telescopes located at different observatories. PRIMASS uses a variety of ground based facilities. Most of the spectra have been obtained using the 10.4m Gran Telescopio Canarias (GTC), and the 3.6m Telescopio Nazionale Galileo (TNG), both located at the El Roque de los Muchachos Observatory (La Palma, Spain), and the 3.0m NASA Infrared Telescope Facility on Mauna Kea (Hawai, USA).We present the first results from our on-going survey (de Leon et al. 2015; Pinilla-Alonso et al. 2015; Morate et al. 2015), focused on the Polana and the Erigone primitive families, with visible and near-infrared spectra of more than 200 objects, most of them with no previous spectroscopic data. Our survey is already the largest database of primitive asteroids spectra, and we keep obtaining data on the Sulamitis and the Clarissa families, as well as on the background low-albedo population.

The enhanced and broadband near-infrared emission in Pr3+/Nd3+ co-doped tellurite glass

NASA Astrophysics Data System (ADS)

Zhou, Zizhong; Zhou, Yaxun; Cheng, Pan; Zhou, Minghan; Su, Xiue; Li, Jun

2017-11-01

This paper reports an enhanced and broadband near-infrared fluorescence emission in the Pr3+/Nd3+ co-doped tellurite glass, which was prepared using melt-quenching technique. Under the excitation of 488 nm laser diode (LD), three near-infrared emission bands at around 0.9, 1.04 and 1.30 μm from 3P1,0 → 1G4, 1G4→3H4 and 1G4→3H5 radiative transitions respectively were observed in the Pr3+ single-doped glass, and the fluorescence intensities increased further with the introduction of Nd3+ ions, which is mainly attributed to the energy transfers from Nd3+ to Pr3+ emissions. Meanwhile, the spectral overlapping of Pr3+:1G4→3H4 and Nd3+:4F3/2 → 4I11/2 radiative transitions resulted in a broadband emission ranging from 1000 to 1100 nm, whose full-width at half-maximum (FWHM) reached about 66 nm. Additionally, the spectroscopic properties of Nd3+ and Pr3+ ions were analyzed using Judd-Ofelt theory and the thermal stability property of prepared glass was characterized by the differential scanning calorimeter (DSC) measurement, and larger than 134 °C for the difference ΔT(=Tx -Tg) was observed, which indicates its feasibility for later fiber drawing. The enhanced fluorescence and broadband emission indicate that Pr3+/Nd3+ co-doped tellurite glass can be applied in the near-infrared band tunable lasers and broadband optical amplifiers.

Spot fat reduction by red and near infrared LED phototherapy

NASA Astrophysics Data System (ADS)

Lim, Sungkyoo; Park, Eal-Whan

2018-02-01

Low level light therapy (LLLT) using light from red and near infrared LEDs or Lasers have been reported effective as noninvasive methods for reducing spot fat. A total of 55 subjects were randomly divided into test groups and control groups for abdominal fat reduction clinical trial using red and near infrared LED phototherapy devices. Red and near infrared light with irradiance of 10 mW/cm2 were irradiated over the abdominal area to the test group for 30 minutes followed by 30 minutes of aerobic exercise, 3 times a week for 4 weeks. Control group used sham devices for 30 minutes and followed by 30 minutes of aerobic exercise. It is expected that red and near infrared LED phototherapy combined with aerobic exercise would be effective and safe for abdominal fat reduction without any side effects.

Far-infrared Spectroscopic Characterization of Anti-vinyl Alcohol

NASA Astrophysics Data System (ADS)

Bunn, Hayley; Soliday, Rebekah M.; Sumner, Isaiah; Raston, Paul L.

2017-09-01

We report a detailed analysis of the high-resolution far-infrared spectrum of anti-vinyl alcohol, which has been previously identified toward Sagittarius B2(N). The ν 15 OH torsional fundamental investigated here is more than 200 cm-1 removed from the next nearest vibration, making it practically unperturbed and ideal to help refine the ground state rotational constants that were previously determined from 25 microwave lines. We assigned 1335 lines within the ν 15 fundamental centered at 261.5512 cm-1, with J and K a ranges of 1-59 and 0-16, respectively. The microwave and far-infrared line positions were fit with Watson-type A- and S-reduced Hamiltonians, with the inclusion of quartic and select sextic distortion terms. This resulted in a significant refinement of the ground state constants, in addition to the determination of the {ν }15=1 state constants for the first time. The spectroscopic parameters are in good agreement with the results from anharmonic coupled-cluster calculations, and should be useful in searches for rotationally and/or vibrationally warm anti-vinyl alcohol in interstellar molecular clouds.

Near-infrared photodetectors utilizing MoS{sub 2}-based heterojunctions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Min Ji; Min, Jung Ki; Yi, Sum-Gyun

2015-07-28

Near-infrared photodetectors are developed using graphene/MoS{sub 2} and WSe{sub 2}/MoS{sub 2} vertical heterojunctions. These heterojunctions exhibit diode-rectifying behavior in the dark and enhanced photocurrent upon near-infrared irradiation. The photocurrent increases with increasing near-infrared power, leading to the photoresponsibility of 0.14 and 0.3 A W{sup −1} for the graphene/MoS{sub 2} and WSe{sub 2}/MoS{sub 2} heterojunctions, respectively, which are much higher than the photoresponsibility reported for a multilayer MoS{sub 2} phototransistor.

Near-infrared Thermal Emission Detections of a Number of Hot Jupiters and the Systematics of Ground-based Near-infrared Photometry

NASA Astrophysics Data System (ADS)

Croll, Bryce; Albert, Loic; Jayawardhana, Ray; Cushing, Michael; Moutou, Claire; Lafreniere, David; Johnson, John Asher; Bonomo, Aldo S.; Deleuil, Magali; Fortney, Jonathan

2015-03-01

We present detections of the near-infrared thermal emission of three hot Jupiters and one brown dwarf using the Wide-field Infrared Camera (WIRCam) on the Canada-France-Hawaii Telescope (CFHT). These include Ks-band secondary eclipse detections of the hot Jupiters WASP-3b and Qatar-1b and the brown dwarf KELT-1b. We also report Y-band, K CONT-band, and two new and one reanalyzed Ks-band detections of the thermal emission of the hot Jupiter WASP-12b. We present a new reduction pipeline for CFHT/WIRCam data, which is optimized for high precision photometry. We also describe novel techniques for constraining systematic errors in ground-based near-infrared photometry, so as to return reliable secondary eclipse depths and uncertainties. We discuss the noise properties of our ground-based photometry for wavelengths spanning the near-infrared (the YJHK bands), for faint and bright stars, and for the same object on several occasions. For the hot Jupiters WASP-3b and WASP-12b we demonstrate the repeatability of our eclipse depth measurements in the Ks band; we therefore place stringent limits on the systematics of ground-based, near-infrared photometry, and also rule out violent weather changes in the deep, high pressure atmospheres of these two hot Jupiters at the epochs of our observations. Based on observations obtained with WIRCam, a joint project of Canada-France-Hawaii Telescope (CFHT), Taiwan, Korea, Canada, France, at the CFHT, which is operated by the National Research Council (NRC) of Canada, the Institute National des Sciences de l'Univers of the Centre National de la Recherche Scientifique of France, and the University of Hawaii.

Transcranial Red and Near Infrared Light Transmission in a Cadaveric Model

PubMed Central

Jagdeo, Jared R.; Adams, Lauren E.; Brody, Neil I.; Siegel, Daniel M.

2012-01-01

Background and Objective Low level light therapy has garnered significant interest within the past decade. The exact molecular mechanisms of how red and near infrared light result in physiologic modulation are not fully understood. Heme moieties and copper within cells are red and near infrared light photoreceptors that induce the mitochondrial respiratory chain component cytochrome C oxidase, resulting in a cascade linked to cytoprotection and cellular metabolism. The copper centers in cytochrome C oxidase have a broad absorption range that peaks around 830 nm. Several in vitro and in vivo animal and human models exist that have demonstrated the benefits of red light and near infrared light for various conditions. Clinical applications for low level light therapy are varied. One study in particular demonstrated improved durable functional outcomes status post-stroke in patients treated with near infrared low level light therapy compared to sham treatment [1]. Despite previous data suggesting the beneficial effect in treating multiple conditions, including stroke, with low level light therapy, limited data exists that measures transmission in a human model. Study Design/Materials and Methods To investigate this idea, we measured the transmission of near infrared light energy, using red light for purposes of comparison, through intact cadaver soft tissue, skull bones, and brain using a commercially available LED device at 830 nm and 633 nm. Results Our results demonstrate that near infrared measurably penetrates soft tissue, bone and brain parenchyma in the formalin preserved cadaveric model, in comparison to negligible red light transmission in the same conditions. Conclusion These findings indicate that near infrared light can penetrate formalin fixed soft tissue, bone and brain and implicate that benefits observed in clinical studies are potentially related to direct action of near infrared light on neural tissue. PMID:23077622

Ti-in-zircon thermometry: applications and limitations

NASA Astrophysics Data System (ADS)

Fu, Bin; Page, F. Zeb; Cavosie, Aaron J.; Fournelle, John; Kita, Noriko T.; Lackey, Jade Star; Wilde, Simon A.; Valley, John W.

2008-08-01

The titanium concentrations of 484 zircons with U-Pb ages of ˜1 Ma to 4.4 Ga were measured by ion microprobe. Samples come from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons (32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413-433) without making corrections for reduced oxide activities (e.g., TiO2 or SiO2), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (˜15% melt residue for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually, the effects of reduced a_{TiO2} or a_{SiO2}, variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous melts with significantly lower crystallization temperature for the last 10-15% melt residue than that of the main rock. While some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once. However, there is no systematic change in Ti

Development and Testing of an LED-Based Near-Infrared Sensor for Human Kidney Tumor Diagnostics

PubMed Central

Zabarylo, Urszula; Kirsanov, Dmitry; Belikova, Valeria; Ageev, Vladimir; Usenov, Iskander; Galyanin, Vladislav; Minet, Olaf; Sakharova, Tatiana; Danielyan, Georgy; Feliksberger, Elena; Artyushenko, Viacheslav

2017-01-01

Optical spectroscopy is increasingly used for cancer diagnostics. Tumor detection feasibility in human kidney samples using mid- and near-infrared (NIR) spectroscopy, fluorescence spectroscopy, and Raman spectroscopy has been reported (Artyushenko et al., Spectral fiber sensors for cancer diagnostics in vitro. In Proceedings of the European Conference on Biomedical Optics, Munich, Germany, 21–25 June 2015). In the present work, a simplification of the NIR spectroscopic analysis for cancer diagnostics was studied. The conventional high-resolution NIR spectroscopic method of kidney tumor diagnostics was replaced by a compact optical sensing device constructively represented by a set of four light-emitting diodes (LEDs) at selected wavelengths and one detecting photodiode. Two sensor prototypes were tested using 14 in vitro clinical samples of 7 different patients. Statistical data evaluation using principal component analysis (PCA) and partial least-squares discriminant analysis (PLS-DA) confirmed the general applicability of the LED-based sensing approach to kidney tumor detection. An additional validation of the results was performed by means of sample permutation. PMID:28825612

Impact of the plasmonic near- and far-field resonance-energy shift on the enhancement of infrared vibrational signals.

PubMed

Vogt, Jochen; Huck, Christian; Neubrech, Frank; Toma, Andrea; Gerbert, David; Pucci, Annemarie

2015-09-07

We report on the impact of the differing spectral near- and far-field properties of resonantly excited gold nanoantennas on the vibrational signal enhancement in surface-enhanced infrared absorption (SEIRA). The knowledge on both spectral characteristics is of considerable importance for the optimization of plasmonic nanostructures for surface-enhanced spectroscopy techniques. From infrared micro-spectroscopic measurements, we simultaneously obtain spectral information on the plasmonic far-field response and, via SEIRA spectroscopy of a test molecule, on the near-field enhancement. The molecular test layer of 4,4'-bis(N-carbazolyl)-1,1'-biphenyl (CBP) was deposited on the surface of gold nanoantennas with different lengths and thus different far-field resonance energies. We carefully studied the Fano-type vibrational lines in a broad spectral window, in particular, how the various vibrational signals are enhanced in relation to the ratio of the far-field plasmonic resonance and the molecular vibrational frequencies. As a detailed experimental proof of former simulation studies, we show the clearly red-shifted maximum SEIRA enhancement compared to the far-field resonance.

Spectroscopic observations with the Stratospheric Observatory for Infrared Astronomy (SOFIA)

NASA Astrophysics Data System (ADS)

Becklin, E. E.; Tielens, A. G. G. M.; Callis, H. H. S.

The joint US and German SOFIA project to develop and operate a 2.5-meter infrared airborne telescope in a Boeing 747-SP is now in its final stages of development. Flying in the stratosphere, SOFIA allows observations through the infrared and submillimeter region, with an average transmission of greater than 80%. SOFIA is characterized by a wide instrument complement ranging from broadband imagers, through moderate resolution spectrographs capable of resolving broad features due to dust and large molecules, to high-resolution spectrometers suitable for kinematic studies of molecular and atomic gas lines at km/s resolution. This broad range in instruments will enable SOFIA to make unique contributions to a broad array of science topics. First science flights will begin in 2009 and the observatory is expected to operate for over 20 years. The sensitivity, characteristics, science instrument complement, and examples of first light spectroscopic science are discussed.

TIRCAM2: The TIFR near infrared imaging camera

NASA Astrophysics Data System (ADS)

Naik, M. B.; Ojha, D. K.; Ghosh, S. K.; Poojary, S. S.; Jadhav, R. B.; Meshram, G. S.; Sandimani, P. R.; Bhagat, S. B.; D'Costa, S. L. A.; Gharat, S. M.; Bakalkar, C. B.; Ninan, J. P.; Joshi, J. S.

2012-12-01

TIRCAM2 (TIFR near infrared imaging camera - II) is a closed cycle cooled imager that has been developed by the Infrared Astronomy Group at the Tata Institute of Fundamental Research for observations in the near infrared band of 1 to 3.7 μm with existing Indian telescopes. In this paper, we describe some of the technical details of TIRCAM2 and report its observing capabilities, measured performance and limiting magnitudes with the 2-m IUCAA Girawali telescope and the 1.2-m PRL Gurushikhar telescope. The main highlight is the camera's capability of observing in the nbL (3.59 mum) band enabling our primary motivation of mapping of Polycyclic Aromatic Hydrocarbon (PAH) emission at 3.3 mum.

Ultrabroadband infrared nanospectroscopic imaging

PubMed Central

Bechtel, Hans A.; Muller, Eric A.; Olmon, Robert L.; Martin, Michael C.; Raschke, Markus B.

2014-01-01

Characterizing and ultimately controlling the heterogeneity underlying biomolecular functions, quantum behavior of complex matter, photonic materials, or catalysis requires large-scale spectroscopic imaging with simultaneous specificity to structure, phase, and chemical composition at nanometer spatial resolution. However, as with any ultrahigh spatial resolution microscopy technique, the associated demand for an increase in both spatial and spectral bandwidth often leads to a decrease in desired sensitivity. We overcome this limitation in infrared vibrational scattering-scanning probe near-field optical microscopy using synchrotron midinfrared radiation. Tip-enhanced localized light–matter interaction is induced by low-noise, broadband, and spatially coherent synchrotron light of high spectral irradiance, and the near-field signal is sensitively detected using heterodyne interferometric amplification. We achieve sub-40-nm spatially resolved, molecular, and phonon vibrational spectroscopic imaging, with rapid spectral acquisition, spanning the full midinfrared (700–5,000 cm−1) with few cm−1 spectral resolution. We demonstrate the performance of synchrotron infrared nanospectroscopy on semiconductor, biomineral, and protein nanostructures, providing vibrational chemical imaging with subzeptomole sensitivity. PMID:24803431

Fourier transform near-infrared spectroscopy application for sea salt quality evaluation.

PubMed

Galvis-Sánchez, Andrea C; Lopes, João Almeida; Delgadillo, Ivonne; Rangel, António O S S

2011-10-26

Near-infrared (NIR) spectroscopy in diffuse reflectance mode was explored with the objective of discriminating sea salts according to their quality type (traditional salt vs "flower of salt") and geographical origin (Atlantic vs Mediterranean). Sea salts were also analyzed in terms of Ca(2+), Mg(2+), K(+), alkalinity, and sulfate concentrations to support spectroscopic results. High concentrations of Mg(2+) and K(+) characterized Atlantic samples, while a high Ca(2+) content was observed in traditional sea salts. A partial least-squares discriminant analysis model considering the 8500-7500 cm(-1) region permitted the discrimination of salts by quality types. The regions 4650-4350 and 5900-5500 cm(-1) allowed salts classification according to their geographical origin. It was possible to classify correctly 85.3 and 94.8% of the analyzed samples according to the salt type and to the geographical origin, respectively. These results demonstrated that NIR spectroscopy is a suitable and very efficient tool for sea salt quality evaluation.

[Near infrared light irradiator using halogen lamp].

PubMed

Ide, Yasuo

2012-07-01

The practical electric light bulb was invented by Thomas Alva Edison in 1879. Halogen lamp is the toughest and brightest electric light bulb. With light filter, it is used as a source of near infrared light. Super Lizer and Alphabeam are made as near infrared light irradiator using halogen lamp. The light emmited by Super Lizer is linear polarized near infrared light. The wave length is from 600 to 1,600 nm and strongest at about 1,000 nm. Concerning Super Lizer, there is evidence of analgesic effects and normalization of the sympathetic nervous system. Super Lizer has four types of probes. SG type is used for stellate ganglion irradiation. B type is used for narrow area irradiation. C and D types are for broad area irradiation. The output of Alphabeam is not polarized. The wave length is from 700 to 1,600 nm and the strongest length is about 1,000nm. Standard attachment is used for spot irradiation. Small attachment is used for stellate ganglion irradiation. Wide attachment is used for broad area irradiation. The effects of Alphabeam are thought to be similar to that of Super Lizer.

Application of miniaturized near-infrared spectroscopy for quality control of extemporaneous orodispersible films.

PubMed

Foo, Wen Chin; Widjaja, Effendi; Khong, Yuet Mei; Gokhale, Rajeev; Chan, Sui Yung

2018-02-20

Extemporaneous oral preparations are routinely compounded in the pharmacy due to a lack of suitable formulations for special populations. Such small-scale pharmacy preparations also present an avenue for individualized pharmacotherapy. Orodispersible films (ODF) have increasingly been evaluated as a suitable dosage form for extemporaneous oral preparations. Nevertheless, as with all other extemporaneous preparations, safety and quality remain a concern. Although the United States Pharmacopeia (USP) recommends analytical testing of compounded preparations for quality assurance, pharmaceutical assays are typically not routinely performed for such non-sterile pharmacy preparations, due to the complexity and high cost of conventional assay methods such as high performance liquid chromatography (HPLC). Spectroscopic methods including Raman, infrared and near-infrared spectroscopy have been successfully applied as quality control tools in the industry. The state-of-art benchtop spectrometers used in those studies have the advantage of superior resolution and performance, but are not suitable for use in a small-scale pharmacy setting. In this study, we investigated the application of a miniaturized near infrared (NIR) spectrometer as a quality control tool for identification and quantification of drug content in extemporaneous ODFs. Miniaturized near infrared (NIR) spectroscopy is suitable for small-scale pharmacy applications in view of its small size, portability, simple user interface, rapid measurement and real-time prediction results. Nevertheless, the challenge with miniaturized NIR spectroscopy is its lower resolution compared to state-of-art benchtop equipment. We have successfully developed NIR spectroscopy calibration models for identification of ODFs containing five different drugs, and quantification of drug content in ODFs containing 2-10mg ondansetron (OND). The qualitative model for drug identification produced 100% prediction accuracy. The quantitative

Near-infrared photodetector with reduced dark current

DOEpatents

Klem, John F; Kim, Jin K

2012-10-30

A photodetector is disclosed for the detection of near-infrared light with a wavelength in the range of about 0.9-1.7 microns. The photodetector, which can be formed as either an nBp device or a pBn device on an InP substrate, includes an InGaAs light-absorbing layer, an InAlGaAs graded layer, an InAlAs or InP barrier layer, and an InGaAs contact layer. The photodetector can detect near-infrared light with or without the use of an applied reverse-bias voltage and is useful as an individual photodetector, or to form a focal plane array.

Near-Infrared Irradiation Increases Length of Axial Pattern Flap Survival in Rats.

PubMed

Yasunaga, Yoshichika; Matsuo, Kiyoshi; Tanaka, Yohei; Yuzuriha, Shunsuke

2017-01-01

Objective: We previously reported that near-infrared irradiation nonthermally induces long-lasting vasodilation of the subdermal plexus by causing apoptosis of vascular smooth muscle cells. To clarify the possible application of near-infrared irradiation to prevent skin flap necrosis, we evaluated the length of axial pattern flap survival in rats by near-infrared irradiation. Methods: A bilaterally symmetric island skin flap was elevated under the panniculus carnosus on the rat dorsum. Half of the flap was subjected to near-infrared irradiation just before flap elevation with a device that simulates solar radiation, which has a specialized contact cooling apparatus to avoid thermal effects. The length of flap survival of the near-infrared irradiated side was measured 7 days after flap elevation and compared with the nonirradiated side. Results: The irradiated side showed elongation of flap survival compared with the nonirradiated side (73.3 ± 11.7 mm vs 67.3 ± 14.9 mm, respectively, P = .03). Conclusions: Near-infrared irradiation increases the survival length of axial pattern flaps in rats.

Thermal Infrared and Visible to Near-Infrared Spectral Analysis of Chert and Amorphous Silica

NASA Astrophysics Data System (ADS)

McDowell, M. L.; Hamilton, V. E.; Cady, S. L.; Knauth, P.

2009-03-01

We look in detail at the thermal infrared and visible to near-infrared spectra of various forms of chert and amorphous silica and compare the spectral variations between samples with variations in physical and chemical characteristics.

Correcting the effect of refraction and dispersion of light in FT-IR spectroscopic imaging in transmission through thick infrared windows.

PubMed

Chan, K L Andrew; Kazarian, Sergei G

2013-01-15

Transmission mode is one of the most common sampling methods for FT-IR spectroscopic imaging because the spectra obtained generally have a reasonable signal-to-noise ratio. However, dispersion and refraction of infrared light occurs when samples are sandwiched between infrared windows or placed underneath a layer of liquid. Dispersion and refraction cause infrared light to focus with different focal lengths depending on the wavelength (wavenumber) of the light. As a result, images obtained are in focus only at a particular wavenumber while they are defocused at other wavenumber values. In this work, a solution to correct this spread of focus by means of adding a lens on top of the infrared transparent window, such that a pseudo hemisphere is formed, has been investigated. Through this lens (or pseudo hemisphere), refraction of light is removed and the light across the spectral range has the same focal depth. Furthermore, the lens acts as a solid immersion objective and an increase of both magnification and spatial resolution (by 1.4 times) is demonstrated. The spatial resolution was investigated using an USAF resolution target, showing that the Rayleigh criterion can be achieved, as well as a sample with a sharp polymer interface to indicate the spatial resolution that can be expected in real samples. The reported approach was used to obtain chemical images of cross sections of cancer tissue and hair samples sandwiched between infrared windows showing the versatility and applicability of the method. In addition to the improved spatial resolution, the results reported herein also demonstrate that the lens can reduce the effect of scattering near the edges of tissue samples. The advantages of the presented approach, obtaining FT-IR spectroscopic images in transmission mode with the same focus across all wavenumber values and simultaneous improvement in spatial resolution, will have wide implications ranging from studies of live cells to sorption of drugs into tissues.

Effect of near-infrared rays on female menstrual pain in Korea.

PubMed

Lee, Jin-Min; Kim, Kye-Ha

2017-09-01

Most Korean women who experience menstrual pain have reported taking pain medicine and making use of complementary alternative therapies. However, because some interventions may cause side effects, more effective pain-relieving measures need to be identified. This study using a non-equivalent group design, evaluated the effects of near-infrared rays on dysmenorrhea among Korean women. The experimental group wore a near-infrared ray abdominal belt for the duration of one menstrual cycle until the end of the menstrual period, while the control group used hot packs. The level of menstrual pain, menstrual pain duration, and pain medicine use were measured. The menstrual pain, average menstrual pain duration, and use of analgesics were reduced in the near-infrared rays group. The results of this study indicate that the near-infrared ray LED belt was effective in reducing menstrual pain, menstrual pain duration compared to the use of analgesics in Korean women with dysmenorrhea. Therefore, near-infrared rays may be used to relieve menstrual pain and improve the quality of life of women with dysmenorrhea in Korea. © 2017 John Wiley & Sons Australia, Ltd.

Electric field detection of phase-locked near-infrared pulses using photoconductive antenna.

PubMed

Katayama, I; Akai, R; Bito, M; Matsubara, E; Ashida, M

2013-07-15

We have demonstrated that a photoconductive antenna gated with 5-fs ultrashort laser pulses can detect electric field transients of near-infrared pulses at least up to 180 THz. Measured sensitivity spectrum of the antenna shows a good agreement with a simple calculation, demonstrating the promising capability of the antenna to near infrared spectroscopy. Using this setup, near-infrared time-domain spectroscopy and characterization of phase controlled near-infrared pulses are demonstrated. Observed absorption spectrum of a polystyrene film and complex refractive index dispersion of a fused silica plate both agree well with those obtained by the conventional methods.

Near-infrared spectroscopy for burning plasma diagnostic applications.

PubMed

Soukhanovskii, V A

2008-10-01

Ultraviolet and visible (UV-VIS, 200-750 nm) atomic spectroscopy of neutral and ionized fuel species (H, D, T, and Li) and impurities (e.g., He, Be, C, and W) is a key element of plasma control and diagnosis on International Thermonuclear Experimental Reactor and future magnetically confined burning plasma experiments (BPXs). Spectroscopic diagnostic implementation and performance issues that arise in the BPX harsh nuclear environment in the UV-VIS range, e.g., degradation of first mirror reflectivity under charge-exchange atom bombardment (erosion) and impurity deposition, permanent and dynamic loss of window, and optical fiber transmission under intense neutron and gamma-ray fluxes, are either absent or not as severe in the near-infrared (NIR, 750-2000 nm) range. An initial survey of NIR diagnostic applications has been undertaken on the National Spherical Torus Experiment. It is demonstrated that NIR spectroscopy can be used for machine protection and plasma control applications, as well as contribute to plasma performance evaluation and physics studies. Emission intensity estimates demonstrate that NIR measurements are possible in the BPX plasma operating parameter range. Complications in the NIR range due to the parasitic background emissions are expected to occur at very high plasma densities, low impurity densities, and at high plasma-facing component temperatures.

Transformations to granular zircon revealed: Twinning, reidite, and ZrO2 in shocked zircon from Meteor Crater (Arizona, USA)

USGS Publications Warehouse

Cavosie, Aaron; Timms, Nicholas E.; Erickson, Timmons M.; Hagerty, Justin J.; Hörz, Friedrich

2016-01-01

Granular zircon in impact environments has long been recognized but remains poorly understood due to lack of experimental data to identify mechanisms involved in its genesis. Meteor Crater in Arizona (United States) contains abundant evidence of shock metamorphism, including shocked quartz, the high pressure polymorphs coesite and stishovite, diaplectic SiO2 glass, and lechatelierite (fused SiO2). Here we report the presence of granular zircon, a new shocked mineral discovery at Meteor Crater, that preserve critical orientation evidence of specific transformations that occurred during its formation at extreme impact conditions. The zircon grains occur as aggregates of sub-µm neoblasts in highly shocked Coconino Formation Sandstone (CFS) comprised of lechatelierite. Electron backscatter diffraction shows that each grain consists of multiple domains, some with boundaries disoriented by 65°, a known {112} shock-twin orientation. Other domains have crystallographic c-axes in alignment with {110} of neighboring domains, consistent with the former presence of the high pressure ZrSiO4 polymorph reidite. Additionally, nearly all zircon preserve ZrO2 + SiO2, providing evidence of partial dissociation. The genesis of CFS granular zircon started with detrital zircon that experienced shock-twinning and reidite formation from 20 to 30 GPa, ultimately yielding a phase that retained crystallographic memory; this phase subsequently recrystallized to systematically oriented zircon neoblasts, and in some areas partially dissociated to ZrO2. The lechatelierite matrix, experimentally constrained to form at >2000 °C, provided an ultra high-temperature environment for zircon dissociation (~1670 °C) and neoblast formation. The capacity of granular zircon to preserve a cumulative P-T record has not been recognized previously, and provides a new method for retrieving histories of impact-related mineral transformations in the crust at conditions far beyond which most rocks melt.

Analysis of Forensic Casework Utilizing Infrared Spectroscopic Imaging.

PubMed

Lanzarotta, Adam

2016-02-24

A search of the current scientific literature yields a limited number of studies that describe the use of Fourier transform infrared (FT-IR) spectroscopic imaging for the analysis of forensic casework, which is likely due to the fact that these instruments are fairly new commodities to the field of analytical chemistry and are therefore not yet commonplace in forensic laboratories. This report describes recent forensic case studies that have used the technique for determining the composition of a wide variety of multi-component sample types, including animal tissue sections for toxic inclusions, drugs/dietary supplements, an antibiotic with an active pharmaceutical ingredient (API) present as several different salt forms, an adulterated bulk API, unknown trace powders for illicit drugs and an ophthalmic solution suspected of being adulterated with bleach.

Fluorescence lifetime imaging microscopy using near-infrared contrast agents.

PubMed

Nothdurft, R; Sarder, P; Bloch, S; Culver, J; Achilefu, S

2012-08-01

Although single-photon fluorescence lifetime imaging microscopy (FLIM) is widely used to image molecular processes using a wide range of excitation wavelengths, the captured emission of this technique is confined to the visible spectrum. Here, we explore the feasibility of utilizing near-infrared (NIR) fluorescent molecular probes with emission >700 nm for FLIM of live cells. The confocal microscope is equipped with a 785 nm laser diode, a red-enhanced photomultiplier tube, and a time-correlated single photon counting card. We demonstrate that our system reports the lifetime distributions of NIR fluorescent dyes, cypate and DTTCI, in cells. In cells labelled separately or jointly with these dyes, NIR FLIM successfully distinguishes their lifetimes, providing a method to sort different cell populations. In addition, lifetime distributions of cells co-incubated with these dyes allow estimate of the dyes' relative concentrations in complex cellular microenvironments. With the heightened interest in fluorescence lifetime-based small animal imaging using NIR fluorophores, this technique further serves as a bridge between in vitro spectroscopic characterization of new fluorophore lifetimes and in vivo tissue imaging. © 2012 The Author Journal of Microscopy © 2012 Royal Microscopical Society.

Chemically Resolved Imaging of Biological Cells and Thin Films by Infrared Scanning Near-Field Optical Microscopy

PubMed Central

Cricenti, Antonio; Generosi, Renato; Luce, Marco; Perfetti, Paolo; Margaritondo, Giorgio; Talley, David; Sanghera, Jas S.; Aggarwal, Ishwar D.; Tolk, Norman H.; Congiu-Castellano, Agostina; Rizzo, Mark A.; Piston, David W.

2003-01-01

The infrared (IR) absorption of a biological system can potentially report on fundamentally important microchemical properties. For example, molecular IR profiles are known to change during increases in metabolic flux, protein phosphorylation, or proteolytic cleavage. However, practical implementation of intracellular IR imaging has been problematic because the diffraction limit of conventional infrared microscopy results in low spatial resolution. We have overcome this limitation by using an IR spectroscopic version of scanning near-field optical microscopy (SNOM), in conjunction with a tunable free-electron laser source. The results presented here clearly reveal different chemical constituents in thin films and biological cells. The space distribution of specific chemical species was obtained by taking SNOM images at IR wavelengths (λ) corresponding to stretch absorption bands of common biochemical bonds, such as the amide bond. In our SNOM implementation, this chemical sensitivity is combined with a lateral resolution of 0.1 μm (≈λ/70), well below the diffraction limit of standard infrared microscopy. The potential applications of this approach touch virtually every aspect of the life sciences and medical research, as well as problems in materials science, chemistry, physics, and environmental research. PMID:14507733

A near-infrared SETI experiment: instrument overview

NASA Astrophysics Data System (ADS)

Wright, Shelley A.; Werthimer, Dan; Treffers, Richard R.; Maire, Jérôme; Marcy, Geoffrey W.; Stone, Remington P. S.; Drake, Frank; Meyer, Elliot; Dorval, Patrick; Siemion, Andrew

2014-07-01

We are designing and constructing a new SETI (Search for Extraterrestrial Intelligence) instrument to search for direct evidence of interstellar communications via pulsed laser signals at near-infrared wavelengths. The new instrument design builds upon our past optical SETI experiences, and is the first step toward a new, more versatile and sophisticated generation of very fast optical and near-infrared pulse search devices. We present our instrumental design by giving an overview of the opto-mechanical design, detector selection and characterization, signal processing, and integration procedure. This project makes use of near-infrared (950 - 1650 nm) discrete amplification Avalanche Photodiodes (APD) that have > 1 GHz bandwidths with low noise characteristics and moderate gain (~104). We have investigated the use of single versus multiple detectors in our instrument (see Maire et al., this conference), and have optimized the system to have both high sensitivity and low false coincidence rates. Our design is optimized for use behind a 1m telescope and includes an optical camera for acquisition and guiding. A goal is to make our instrument relatively economical and easy to duplicate. We describe our observational setup and our initial search strategies for SETI targets, and for potential interesting compact astrophysical objects.

Preparation and infrared/raman classification of 630 spectroscopically encoded styrene copolymers.

PubMed

Fenniri, Hicham; Chun, Sangki; Terreau, Owen; Bravo-Vasquez, Juan-Pablo

2008-01-01

The barcoded resins (BCRs) were introduced recently as a platform for encoded combinatorial chemistry. One of the main challenges yet to be overcome is the demonstration that a large number of BCRs could be generated and classified with high confidence. Here, we describe the synthesis and classification of 630 polystyrene-based copolymers prepared from the combinatorial association of 15 spectroscopically active styrene monomers. Each of the 630 copolymers displayed a unique vibrational fingerprint (infrared and Raman), which was converted into a spectral vector. To each of the 630 copolymers, a vector of the known (reference) composition was assigned. Unknown (prediction) vectors were decoded using multivariate data analysis. From the inner product of the reference and prediction vectors, a correlation map comparing 396 900 copolymer pairs (630 x 630) was generated. In 100% of the cases, the highest correlation was obtained for polymer pairs in which the reference and prediction vectors correspond to copolymers prepared from identical styrene monomers, thus demonstrating the high reliability of this encoding strategy. We have also established that the spectroscopic barcodes generated from the Raman and infrared spectra are independent of the copolymers' morphology (beaded versus bulk polymers). Besides the demonstration of the generality of the polymer barcoding strategy, the analytical methods developed here could in principle be extended to the investigation of the composition and purity of any other synthetic polymer and biopolymer library, or even scaffold-based combinatorial libraries.

A near-infrared SETI experiment: A multi-time resolution data analysis

NASA Astrophysics Data System (ADS)

Tallis, Melisa; Maire, Jerome; Wright, Shelley; Drake, Frank D.; Duenas, Andres; Marcy, Geoffrey W.; Stone, Remington P. S.; Treffers, Richard R.; Werthimer, Dan; NIROSETI

2016-06-01

We present new post-processing routines which are used to detect very fast optical and near-infrared pulsed signals using the latest NIROSETI (Near-Infrared Optical Search for Extraterrestrial Intelligence) instrument. NIROSETI was commissioned in 2015 at Lick Observatory and searches for near-infrared (0.95 to 1.65μ) nanosecond pulsed laser signals transmitted by distant civilizations. Traditional optical SETI searches rely on analysis of coincidences that occur between multiple detectors at a fixed time resolution. We present a multi-time resolution data analysis that extends our search from the 1ns to 1ms range. This new feature greatly improves the versatility of the instrument and its search parameters for near-infrared SETI. We aim to use these algorithms to assist us in our search for signals that have varying duty cycles and pulse widths. We tested the fidelity and robustness of our algorithms using both synthetic embedded pulsed signals, as well as data from a near-infrared pulsed laser installed on the instrument. Applications of NIROSETI are widespread in time domain astrophysics, especially for high time resolution transients, and astronomical objects that emit short-duration high-energy pulses such as pulsars.

A near-infrared BSA coated DNA-AgNCs for cellular imaging.

PubMed

Mu, Wei-Yu; Yang, Rui; Robertson, Akrofi; Chen, Qiu-Yun

2018-02-01

Near-infrared silver nanoclusters, have potential applications in the field of biosensing and biological imaging. However, less stability of most DNA-AgNCs limits their application. To obtain stable near-infrared fluorescence DNA-AgNCs for biological imaging, a new kind of near-infrared fluorescent DNA-Ag nanoclusters was constructed using the C3A rich aptamer as a synthesis template, GAG as the enhancer. In particular, a new DNA-AgNCs-Trp@BSA was obtained based on the self-assembly of bovine serum albumin (BSA) and tryptophan loaded DNA-AgNCs by hydrophobic interaction. This self-assembly method can be used to stabilize DNAn-Ag (n = 1-3) nanoclusters. Hence, the near-infrared fluorescence DNA-AgNCs-Trp@BSA was applied in cellular imaging of HepG-2 cells. Copyright © 2017 Elsevier B.V. All rights reserved.

Near-infrared branding efficiently correlates light and electron microscopy.

PubMed

Bishop, Derron; Nikić, Ivana; Brinkoetter, Mary; Knecht, Sharmon; Potz, Stephanie; Kerschensteiner, Martin; Misgeld, Thomas

2011-06-05

The correlation of light and electron microscopy of complex tissues remains a major challenge. Here we report near-infrared branding (NIRB), which facilitates such correlation by using a pulsed, near-infrared laser to create defined fiducial marks in three dimensions in fixed tissue. As these marks are fluorescent and can be photo-oxidized to generate electron contrast, they can guide re-identification of previously imaged structures as small as dendritic spines by electron microscopy.

Image-guided cancer surgery using near-infrared fluorescence

PubMed Central

Vahrmeijer, Alexander L.; Hutteman, Merlijn; van der Vorst, Joost R.; van de Velde, C.J.H.; Frangioni, John V.

2013-01-01

Paradigm shifts in surgery arise when surgeons are empowered to perform surgery faster, better, and/or less expensively. Optical imaging that exploits invisible near-infrared fluorescent light has the potential to improve cancer surgery outcomes while minimizing anesthesia time and lowering healthcare costs. Because of this, the last few years have witnessed an explosion of proof-of-concept clinical trials in the field. In this review, we introduce the concept of near-infrared fluorescence imaging for cancer surgery, review the clinical trial literature to date, outline the key issues pertaining to imaging system and contrast agent optimization, discuss limitations and leverage, and provide a framework for making the technology available for the routine care of cancer patients in the near future. PMID:23881033

AKARI/IRC NEAR-INFRARED SPECTRAL ATLAS OF GALACTIC PLANETARY NEBULAE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ohsawa, Ryou; Onaka, Takashi; Sakon, Itsuki

2016-04-15

Near-infrared (2.5–5.0 μm) low-resolution (λ/Δλ ∼ 100) spectra of 72 Galactic planetary nebulae (PNe) were obtained with the Infrared Camera (IRC) in the post-helium phase. The IRC, equipped with a 1′ × 1′ window for spectroscopy of a point source, was capable of obtaining near-infrared spectra in a slit-less mode without any flux loss due to a slit. The spectra show emission features including hydrogen recombination lines and the 3.3–3.5 μm hydrocarbon features. The intensity and equivalent width of the emission features were measured by spectral fitting. We made a catalog providing unique information on the investigation of the near-infrared emission ofmore » PNe. In this paper, details of the observations and characteristics of the catalog are described.« less

Near-infrared face recognition utilizing open CV software

NASA Astrophysics Data System (ADS)

Sellami, Louiza; Ngo, Hau; Fowler, Chris J.; Kearney, Liam M.

2014-06-01

Commercially available hardware, freely available algorithms, and authors' developed software are synergized successfully to detect and recognize subjects in an environment without visible light. This project integrates three major components: an illumination device operating in near infrared (NIR) spectrum, a NIR capable camera and a software algorithm capable of performing image manipulation, facial detection and recognition. Focusing our efforts in the near infrared spectrum allows the low budget system to operate covertly while still allowing for accurate face recognition. In doing so a valuable function has been developed which presents potential benefits in future civilian and military security and surveillance operations.

High definition infrared spectroscopic imaging for lymph node histopathology.

PubMed

Leslie, L Suzanne; Wrobel, Tomasz P; Mayerich, David; Bindra, Snehal; Emmadi, Rajyasree; Bhargava, Rohit

2015-01-01

Chemical imaging is a rapidly emerging field in which molecular information within samples can be used to predict biological function and recognize disease without the use of stains or manual identification. In Fourier transform infrared (FT-IR) spectroscopic imaging, molecular absorption contrast provides a large signal relative to noise. Due to the long mid-IR wavelengths and sub-optimal instrument design, however, pixel sizes have historically been much larger than cells. This limits both the accuracy of the technique in identifying small regions, as well as the ability to visualize single cells. Here we obtain data with micron-sized sampling using a tabletop FT-IR instrument, and demonstrate that the high-definition (HD) data lead to accurate identification of multiple cells in lymph nodes that was not previously possible. Highly accurate recognition of eight distinct classes - naïve and memory B cells, T cells, erythrocytes, connective tissue, fibrovascular network, smooth muscle, and light and dark zone activated B cells was achieved in healthy, reactive, and malignant lymph node biopsies using a random forest classifier. The results demonstrate that cells currently identifiable only through immunohistochemical stains and cumbersome manual recognition of optical microscopy images can now be distinguished to a similar level through a single IR spectroscopic image from a lymph node biopsy.

Infrared spectroscopic ellipsometry in semiconductor manufacturing

NASA Astrophysics Data System (ADS)

Guittet, Pierre-Yves; Mantz, Ulrich; Weidner, Peter; Stehle, Jean-Louis; Bucchia, Marc; Bourtault, Sophie; Zahorski, Dorian

2004-05-01

Infrared spectroscopic ellipsometry (IRSE) metrology is an emerging technology in semiconductor production environment. Infineon Technologies SC300 implemented the first worldwide automated IRSE in a class 1 clean room in 2002. Combining properties of IR light -- large wavelength, low absorption in silicon -- with a short focus optics -- no backside reflection -- which allow model-based analysis, a large number of production applications were developed. Part of Infineon IRSE development roadmap is now focused on depth monitoring for arrays of 3D dry-etched structures. In trench DRAM manufacturing, the areal density is high, and critical dimensions are much lower than mid-IR wavelength. Therefore, extensive use of effective medium theory is made to model 3D structures. IR-SE metrology is not limited by shrinking critical dimensions, as long as the areal density is above a specific cut-off value determined by trenches dimensions, trench-filling and surrounding materials. Two applications for depth monitoring are presented. 1D models were developed and successfully applied to the DRAM trench capacitor structures. Modeling and correlation to reference methods are shown as well as dynamic repeatability and gauge capability results. Limitations of the current tool configuration are reviewed for shallow structures.

Application of near-infrared image processing in agricultural engineering

NASA Astrophysics Data System (ADS)

Chen, Ming-hong; Zhang, Guo-ping; Xia, Hongxing

2009-07-01

Recently, with development of computer technology, the application field of near-infrared image processing becomes much wider. In this paper the technical characteristic and development of modern NIR imaging and NIR spectroscopy analysis were introduced. It is concluded application and studying of the NIR imaging processing technique in the agricultural engineering in recent years, base on the application principle and developing characteristic of near-infrared image. The NIR imaging would be very useful in the nondestructive external and internal quality inspecting of agricultural products. It is important to detect stored-grain insects by the application of near-infrared spectroscopy. Computer vision detection base on the NIR imaging would be help to manage food logistics. Application of NIR imaging promoted quality management of agricultural products. In the further application research fields of NIR image in the agricultural engineering, Some advices and prospect were put forward.

Development of a neurofeedback protocol targeting the frontal pole using near-infrared spectroscopy.

PubMed

Kinoshita, Akihide; Takizawa, Ryu; Yahata, Noriaki; Homae, Fumitaka; Hashimoto, Ryuichiro; Sakakibara, Eisuke; Kawasaki, Shingo; Nishimura, Yukika; Koike, Shinsuke; Kasai, Kiyoto

2016-11-01

Neurofeedback has been studied with the aim of controlling cerebral activity. Near-infrared spectroscopy is a non-invasive neuroimaging technique used for measuring hemoglobin concentration changes in cortical surface areas with high temporal resolution. Thus, near-infrared spectroscopy may be useful for neurofeedback, which requires real-time feedback of repeated brain activation measurements. However, no study has specifically targeted neurofeedback, using near-infrared spectroscopy, in the frontal pole cortex. We developed an original near-infrared spectroscopy neurofeedback system targeting the frontal pole cortex. Over a single day of testing, each healthy participant (n = 24) received either correct or incorrect (Sham) feedback from near-infrared spectroscopy signals, based on a crossover design. Under correct feedback conditions, significant activation was observed in the frontal pole cortex (P = 0.000073). Additionally, self-evaluation of control and metacognitive beliefs were associated with near-infrared spectroscopy signals (P = 0.006). The neurofeedback system developed in this study might be useful for developing control of frontal pole cortex activation. © 2016 The Authors. Psychiatry and Clinical Neurosciences © 2016 Japanese Society of Psychiatry and Neurology.

Near infrared spectra of muscovite, Tschermak substitution, and metamorphic reaction progress: Implications for remote sensing

NASA Astrophysics Data System (ADS)

Duke, Edward F.

1994-07-01

Near infrared (NIR) spectra of Precambrian metagraywacke in the Black Hills, South Dakota, demonstrate that reflectance spectroscopy can be used to monitor progressive changes in mineral chemistry as a function of metamorphic grade. The wavelength of a combination Al-O-H absorption band in muscovite, measured using both laboratory and field-portable NIR spectrometers, shifts from 2217 nm in the biotite zone to 2199 nm in the sillimanite + K-feldspar zone. The band shift corresponds to an increase in the Alvi content of muscovite, determined by electron microprobe, and is thus a monitor of Al2Si-1(Fe,Mg)-1 (Tschermak) exchange. Spectroscopic measurements such as these are useful in the case of aluminum-deficient rocks, which lack metamorphic index minerals or appropriate assemblages for thermobarometric studies, and in low-grade rocks (subgarnet zone), which lack quantitative indicators of metamorphic grade and are too fine grained for petrographic or microprobe studies. More important, spectroscopic detection of mineral-chemical variations in metamorphic rocks provides petrologists with a tool to recover information on metamorphic reaction histories from high-spectral-resolution aircraft or satellite remote sensing data.

Characterization of inclusions in terrestrial impact formed zircon: Constraining the formation conditions of Hadean zircon from Jack Hills, Western Australia

NASA Astrophysics Data System (ADS)

Faltys, J. P.; Wielicki, M. M.; Sizemore, T. M.

2017-12-01

Due to the discovery and subsequent geochemical analysis of Hadean terrestrial material (e.g. detrital zircon from Jack Hills, Western Australia), a dramatic paradigm shift has occurred in the hypothesized near surface conditions of the first 500 million years of Earth's evolution. From a hellish setting riddled with impactors and not fit for life to a much milder environment that may have been uniquely suitable for the origin of life. Geochemical analyses of these ancient materials have been used to suggest the presence of water at or near the surface as well as the existence of continental crust during the Hadean, both of which have been suggested as necessary for the origin of life. However, the intensity of extraterrestrial bombardment during the Hadean and the effects of such events on the origin of life remains poorly understood. Clearly, as evidenced by Phanerozoic impact events, extraterrestrial impactors have the potential to dramatically effect the environment, particularly the biosphere. Early Earth likely experienced multiple large impact events, as evidenced by the lunar record, however whether those impacts were sufficient to frustrate the origin of life remains an open question. Although multiple lines of evidence, including the inclusion population, suggest the formation of Hadean zircon from Jack Hills as crystallizing in an under-thrust environment from S-type magmas, a recent study has suggested their formation in an impact melt environment analogous to a portion of the Sudbury Igneous Complex at the Sudbury impact structure. To determine between these two formation scenarios we have under-taken an inclusion study of terrestrial impact formed zircon from four of the largest terrestrial impact structures (Sudbury, Canada; Manicouagan, Canada; Vredefort, South Africa; Morokweng, South Africa), to compare to the vast inclusion dataset that exists for Jack Hills zircon. Preliminary data suggests a different inclusion population, from Hadean zircon

Near-infrared spectroscopic assessment of oxygen delivery to free flaps on monkeys following vascular occlusions and inhalation of pure oxygen

NASA Astrophysics Data System (ADS)

Tian, Fenghua; Ding, Haishu; Cai, Zhigang; Wang, Guangzhi; Zhao, Fuyun

2002-04-01

In recent studies, near-infrared spectroscopy (NIRS) has been considered as a potentially ideal noninvasive technique for the postoperative monitoring of plastic surgery. In this study, free flaps were raised on rhesus monkeys' forearms and oxygen delivery to these flaps was monitored following vascular occlusions and inhalation of pure oxygen. Optical fibers were adopted in the probe of the oximeter so that the detection could be performed in reflectance mode. The distance between emitter and detector can be adjusted easily to achieve the best efficacy. Different and repeatable patterns of changes were measured following vascular occlusions (arterial occlusion, venous occlusion and total occlusion) on flaps. It is clear that the near-infrared spectroscopy is capable of postoperatively monitoring vascular problems in flaps. NIRS showed high sensitivity to detect the dynamic changes in flaps induced by inhalation of pure oxygen in this study. The experimental results indicated that it was potential to assess tissue viability utilizing the dynamic changes induced by a noninvasive stimulation. It may be a new assessing method that is rapid, little influenced by other factors and brings less discomfort to patients.

A near-infrared SETI experiment: commissioning, data analysis, and performance results

NASA Astrophysics Data System (ADS)

Maire, Jérôme; Wright, Shelley A.; Dorval, Patrick; Drake, Frank D.; Duenas, Andres; Isaacson, Howard; Marcy, Geoffrey W.; Siemion, Andrew; Stone, Remington P. S.; Tallis, Melisa; Treffers, Richard R.; Werthimer, Dan

2016-08-01

Over the last two decades, Optical Search for Extra-Terrestrial Intelligence experiments have been conducted to search for either continuous or pulsed visible-light laser beacons that could be used for interstellar communication or energy transmission. Near-infrared offers a compelling window for signal transmission since there is a decrease in interstellar extinction and Galactic background compared to optical wavelengths. An innovative Near-InfraRed and Optical SETI (NIROSETI) instrument has been designed and constructed to take advantage of a new generation of fast (> 1 Ghz) low-noise near-infrared avalanche photodiodes to search for nanosecond pulsed near-infrared (850 - 1650 nm) pulses. The instrument was successfully installed and commissioned at the Nickel (1m) telescope at Lick Observatory in March 2015. We will describe the overall design of the instrument with a focus on methods developed for data acquisition and reduction for near-infrared SETI. Time and height analyses of the pulses produced by the detectors are performed to search for periodicity and coincidences in the signals. We will further discuss our NIROSETI survey plans.

Studies on proofing of yeasted bread dough using near- and mid-infrared spectroscopy.

PubMed

Sinelli, Nicoletta; Casiraghi, Ernestina; Downey, Gerard

2008-02-13

Dough proofing is the resting period after mixing during which fermentation commences. Optimum dough proofing is important for production of high quality bread. Near- and mid-infrared spectroscopies have been used with some success to investigate macromolecular changes during dough mixing. In this work, both techniques were applied to a preliminary study of flour doughs during proofing. Spectra were collected contemporaneously by NIR (750-1100 nm) and MIR (4000-600 cm(-1)) instruments using a fiberoptic surface interactance probe and horizontal ATR cell, respectively. Studies were performed on flours of differing baking quality; these included strong baker's flour, retail flour, and gluten-free flour. Following principal component analysis, changes in the recorded spectral signals could be followed over time. It is apparent from the results that both vibrational spectroscopic techniques can identify changes in flour doughs during proofing and that it is possible to suggest which macromolecular species are involved.

Global View of Earth in the Near-Infrared

NASA Image and Video Library

1996-02-08

This near-infrared photograph of the Earth was taken by the Galileo spacecraft at 6:07 a.m. PST on Dec. 11, 1990, at a range of about 1.32 million miles. South America is prominent near the center. http://photojournal.jpl.nasa.gov/catalog/PIA00226

Visible/near-infrared spectra of experimentally shocked plagioclase feldspars

USGS Publications Warehouse

Johnson, J. R.; Horz, F.

2003-01-01

High shock pressures cause structural changes in plagioclase feldspars such as mechanical fracturing and disaggregation of the crystal lattice at submicron scales, the formation of diaplectic glass (maskelynite), and genuine melting. Past studies of visible/ near-infrared spectra of shocked feldspars demonstrated few spectral variations with pressure except for a decrease in the depth of the absorption feature near 1250-1300 nm and an overall decrease in reflectance. New visible/near-infrared spectra (400-2500 nm) of experimentally shocked (17-56 GPa) albite- and anorthite-rich rock powders demonstrate similar trends, including the loss of minor hydrated mineral bands near 1410, 1930, 2250, and 2350 nm. However, the most interesting new observations are increases in reflectance at intermediate pressures, followed by subsequent decreases in reflectance at higher pressures. The amount of internal scattering and overall sample reflectance is controlled by the relative proportions of micro-fractures, submicron grains, diaplectic glass, and melts formed during shock metamorphism. We interpret the observed reflectance increases at intermediate pressures to result from progressively larger proportions of submicron feldspar grains and diaplectic glass. The ensuing decreases in reflectance occur after diaplectic glass formation is complete and the proportion of genuine melt inclusions increases. The pressure regimes over which these reflectance variations occur differ between albite and anorthite, consistent with thermal infrared spectra of these samples and previous studies of shocked feldspars. These types of spectral variations associated with different peak shock pressures should be considered during interpretation and modeling of visible/near-infrared remotely sensed spectra of planetary and asteroidal surfaces.

Spectroscopic properties in Er3+-doped germanotellurite glasses and glass ceramics for mid-infrared laser materials.

PubMed

Kang, Shiliang; Xiao, Xiudi; Pan, Qiwen; Chen, Dongdan; Qiu, Jianrong; Dong, Guoping

2017-03-07

Transparent Er 3+ -doped germanotellurite glass ceramics (GCs) with variable Te/Ge ratio were prepared by controllable heat-treated process. X-ray diffraction (XRD) and transmission electron microscope (TEM) confirmed the formation of nanocrystals in glass matrix. Raman spectra were used to investigate the evolution of glass structure and photon energy. Fourier transform infrared (FTIR) spectra were introduced to characterize the change of hydroxyl group (OH - ) content. Enhanced 2.7 μm emission was achieved from Er 3+ -doped GCs upon excitation with a 980 nm laser diode (LD), and the influence of GeO 2 concentration and heat-treated temperature on the spectroscopic properties were also discussed in detail. It is found that the present Er 3+ -doped GC possesses large stimulated emission cross section at around 2.7 μm (0.85 × 10 -20  cm 2 ). The advantageous spectroscopic characteristics suggest that the obtained GC may be a promising material for mid-infrared fiber lasers.

Spectroscopic properties in Er3+-doped germanotellurite glasses and glass ceramics for mid-infrared laser materials

PubMed Central

Kang, Shiliang; Xiao, Xiudi; Pan, Qiwen; Chen, Dongdan; Qiu, Jianrong; Dong, Guoping

2017-01-01

Transparent Er3+-doped germanotellurite glass ceramics (GCs) with variable Te/Ge ratio were prepared by controllable heat-treated process. X-ray diffraction (XRD) and transmission electron microscope (TEM) confirmed the formation of nanocrystals in glass matrix. Raman spectra were used to investigate the evolution of glass structure and photon energy. Fourier transform infrared (FTIR) spectra were introduced to characterize the change of hydroxyl group (OH−) content. Enhanced 2.7 μm emission was achieved from Er3+-doped GCs upon excitation with a 980 nm laser diode (LD), and the influence of GeO2 concentration and heat-treated temperature on the spectroscopic properties were also discussed in detail. It is found that the present Er3+-doped GC possesses large stimulated emission cross section at around 2.7 μm (0.85 × 10−20 cm2). The advantageous spectroscopic characteristics suggest that the obtained GC may be a promising material for mid-infrared fiber lasers. PMID:28266570

Near-Infrared Fluorescent Materials for Sensing of Biological Targets

PubMed Central

Amiot, Carrie L.; Xu, Shuping; Liang, Song; Pan, Lingyun; Zhao, Julia Xiaojun

2008-01-01

Near-infrared fluorescent (NIRF) materials are promising labeling reagents for sensitive determination and imaging of biological targets. In the near-infrared region biological samples have low background fluorescence signals, providing high signal to noise ratio. Meanwhile, near-infrared radiation can penetrate into sample matrices deeply due to low light scattering. Thus, in vivo and in vitro imaging of biological samples can be achieved by employing the NIRF probes. To take full advantage of NIRF materials in the biological and biomedical field, one of the key issues is to develop intense and biocompatible NIRF probes. In this review, a number of NIRF materials are discussed including traditional NIRF dye molecules, newly developed NIRF quantum dots and single-walled carbon nanotubes, as well as rare earth metal compounds. The use of some NIRF materials in various nanostructures is illustrated. The enhancement of NIRF using metal nanostructures is covered as well. The fluorescence mechanism and bioapplications of each type of the NIRF materials are discussed in details. PMID:27879867

Continental crustal history in SE Asia: Insights from zircon geochronology

NASA Astrophysics Data System (ADS)

Sevastjanova, I.; Hall, R.; Gunawan, I.; Ferdian, F.; Decker, J.

2012-12-01

It is well known that SE Asia is underlain mostly by continental crust derived from Gondwana. However, there are still many uncertainties about the ages of protoliths, origin, arrival ages and history of different blocks, because much of the basement is unexposed. We have compiled previously published and new zircon U-Pb age and Hf isotope data from SE Asia. Our data set currently contains over 8400 U-Pb ages and over 600 Hf isotope analyses from sedimentary, metamorphic and igneous rocks and work is continuing to increase its size and the area covered. Zircons range in age from 3.4 Ga to near-zero. Archean zircons (>2.5 Ga) are rare in SE Asia and significant Archean populations (particularly zircons >2.8 Ga) are found only in East Java and the Sibumasu block of the Malay Peninsula. The presence of Archean zircons strongly suggests that the East Java and Sibumasu blocks were once situated near present-day Western Australia. Detrital Paleoproterozoic (ca. 1.9-1.8 Ga) zircons are abundant in many parts of SE Asia. In Sundaland (Malay Peninsula, Sumatra, West Java, Borneo) the most likely source for these zircons is the tin belt basement, but a north Australian source is more likely for eastern Indonesian samples. An early Mesoproterozoic (ca. 1.6-1.5 Ga) zircon population, particularly common in eastern Indonesia, is interpreted to be derived from central or northern Australia. Mesoproterozoic zircons, ca. 1.4 Ga, are common only on fragments that are now attached to or were previously part of the north Australian margin, such as the Bird's Head of New Guinea, Timor, Seram, Sulawesi and SW Borneo. Hf isotope characteristics of zircons from Seram are similar to those of zircons from eastern Australia. This supports the suggestion that Seram was part of the Australian margin. Late Meso- and early Neoproterozoic zircons (ca. 1.2-1.1 Ga, 900 Ma, and 600 Ma) are present, but not abundant, in SE Asia. Dominant Phanerozoic populations are Permian-Triassic, Cretaceous, and

Creation of a continent recorded in zircon zoning

USGS Publications Warehouse

Moser, D.E.; Bowman, J.R.; Wooden, J.; Valley, J.W.; Mazdab, F.; Kita, N.

2008-01-01

We have discovered a robust microcrystalline record of the early genesis of North American lithosphere preserved in the U-Pb age and oxygen isotope zoning of zircons from a lower crustal paragneiss in the Neoarchean Superior province. Detrital igneous zircon cores with ??18O values of 5.1???-7.1??? record creation of primitive to increasingly evolved crust from 2.85 ?? 0.02 Ga to 2.67 ?? 0.02 Ga. Sharp chemical unconformity between cores and higher ??18O (8.4???-10.4???) metamorphic overgrowths as old as 2.66 ?? 0.01 Ga dictates a rapid sequence of arc unroofing, burial of detrital zircons in hydrosphere-altered sediment, and transport to lower crust late in upper plate assembly. The period to 2.58 ?? 0.01 Ga included ???80 m.y. of high-temperature (???700-650 ??C), nearly continuous overgrowth events reflecting stages in maturation of the subjacent mantle root. Huronian continental rifting is recorded by the youngest zircon tip growth at 2512 ?? 8 Ma (??? 600 ??C) signaling magma intraplating and the onset of rigid plate behavior. This >150 m.y. microscopic isotope record in single crystals demonstrates the sluggish volume diffusion of U, Pb, and O in zircon throughout protracted regional metamorphism, and the consequent advances now possible in reconstructing planetary dynamics with zircon zoning. ?? 2008 The Geological Society of America.

At what conditions does zircon grow/dissolve during high-T metamorphism? Relating zircon textures to PT-conditions

NASA Astrophysics Data System (ADS)

Kunz, Barbara E.; Regis, Daniele; Manzotti, Paola; Engi, Martin

2015-04-01

A key question in ziconology is when and how zircon grows during metamorphism. To shed light on zircon forming processes and the corresponding PT-conditions during high-T metamorphism a case study was undertaken. The Ivrea Zone (N-Italy) exposes a lower continental crustal section in which a continuous metamorphic field gradient from amphibolite to granulite facies is documented. This field gradient is thought to reflect protracted heating during late Paleozoic times, with a probable high-T peak in the Permian. We present first results from a primarily textural study supported by U-Pb ages, Th/U ratios and Ti-in-Zrn thermometry. Four types of zircon were identified based on their overgrowth proportions and the preservation of detrital cores. Zircon grains were thus classified as Type1 - detrital grains with no overgrowth or very narrow rims (300 Ma) and appears to reflect an early dehydration phase. Rim2b has Permian ages (median 275 Ma), is by far the most common overgrowth type, found in a wide PT-range. Its development appears related to biotite breakdown. Rim3 is texturally indicative of magmatic zircon, occurs only in diatexites. Rim4 is the latest overgrowth and is locally found at all metamorphic grades. Textural features suggest late fluid-related recrystallization of existing zircon. At lowest grade (675±35°C, 6±2 kbar) zircons show type1 only, overgrowths are too thin to clearly identify the rim type. Further upgrade (~700°C, 7 kbar) type1 and type2 dominate. Type2 zircons show rim1, rim2a and occasionally rim4. At the Mu-out isograd (750±50°C, 8.2±1.4 kbar) most zircons are of type2, now with rim2b instead of 2a, in addition to rim1 and rim4. Near and in granulite facies (to 800°C, 8±2 kbar) mostly zircon type2 and type4 are present. While rim1 gets more narrow with increasing metamorphic grade, rim2b grows significantly thicker. Occasionally rim2a and rim4 occur. Close to the Bt-out isograd (~860°C, 9.2±1.7 kbar), mostly type3 and type4 are

Digital Breast Tomosynthesis guided Near Infrared Spectroscopy: Volumetric estimates of fibroglandular fraction and breast density from tomosynthesis reconstructions

PubMed Central

Vedantham, Srinivasan; Shi, Linxi; Michaelsen, Kelly E.; Krishnaswamy, Venkataramanan; Pogue, Brian W.; Poplack, Steven P.; Karellas, Andrew; Paulsen, Keith D.

2016-01-01

A multimodality system combining a clinical prototype digital breast tomosynthesis with its imaging geometry modified to facilitate near-infrared spectroscopic imaging has been developed. The accuracy of parameters recovered from near-infrared spectroscopy is dependent on fibroglandular tissue content. Hence, in this study, volumetric estimates of fibroglandular tissue from tomosynthesis reconstructions were determined. A kernel-based fuzzy c-means algorithm was implemented to segment tomosynthesis reconstructed slices in order to estimate fibroglandular content and to provide anatomic priors for near-infrared spectroscopy. This algorithm was used to determine volumetric breast density (VBD), defined as the ratio of fibroglandular tissue volume to the total breast volume, expressed as percentage, from 62 tomosynthesis reconstructions of 34 study participants. For a subset of study participants who subsequently underwent mammography, VBD from mammography matched for subject, breast laterality and mammographic view was quantified using commercial software and statistically analyzed to determine if it differed from tomosynthesis. Summary statistics of the VBD from all study participants were compared with prior independent studies. The fibroglandular volume from tomosynthesis and mammography were not statistically different (p=0.211, paired t-test). After accounting for the compressed breast thickness, which were different between tomosynthesis and mammography, the VBD from tomosynthesis was correlated with (r =0.809, p<0.001), did not statistically differ from (p>0.99, paired t-test), and was linearly related to, the VBD from mammography. Summary statistics of the VBD from tomosynthesis were not statistically different from prior studies using high-resolution dedicated breast computed tomography. The observation of correlation and linear association in VBD between mammography and tomosynthesis suggests that breast density associated risk measures determined for

Enhanced spatial near-infrared modulation of graphene-loaded perfect absorbers using plasmonic nanoslits.

PubMed

Cai, Yijun; Zhu, Jinfeng; Liu, Qing Huo; Lin, Timothy; Zhou, Jianyang; Ye, Longfang; Cai, Zhiping

2015-12-14

Modulating spatial near-infrared light for ultra-compact electro-optic devices is a critical issue in optical communication and imaging applications. To date, spatial near-infrared modulators based on graphene have been reported, but they showed limited modulation effects due to the relatively weak light-graphene interaction. In combination with graphene and metallic nanoslits, we design a kind of ultrathin near-infrared perfect absorber with enhanced spatial modulation effects and independence on a wide range of incident angles. The modulated spectral shift of central wavelength is up to 258.2 nm in the near-infrared range, which is more promising in applications than state-of-the-art devices. The modulation enhancement is attributed to the plasmonic nanoslit mode, in which the optical electric field is highly concentrated in the deep subwavelength scale and the light-graphene interaction is significantly strengthened. The physical insight is deeply revealed by a combination of equivalent circuit and electromagnetic field analysis. The design principles are not only crucial for spatial near-infrared modulators, but also provide a key guide for developing active near-infrared patch nanoantennas based on graphene.

Near infrared spectrum simulation applied to human skin for diagnosis

NASA Astrophysics Data System (ADS)

Tsai, Chen-Mu; Fang, Yi-Chin; Wang, Chih-Yu; Chiu, Pin-Chun; Wu, Guo-Ying; Zheng, Wei-Chi; Chemg, Shih-Hao

2007-11-01

This research proposes a new method for skin diagnose using near infrared as the light source (750nm~1300nm). Compared to UV and visible light, near infrared might penetrate relatively deep into biological soft tissue in some cases although NIR absorption property of tissue is not a constant for water, fat, and collagen etc. In the research, NIR absorption and scattering properties for skin are discussed firstly using the theory of molecule vibration from Quantum physics and Solid State Physics; secondly the practical model for various NIR absorption spectrum to skin tissue are done by optical simulation for human skin. Finally, experiments are done for further identification of proposed model for human skin and its reaction to near infrared. Results show success with identification from both theory and experiments.

Spectroscopic Study of Terahertz Generation in Mid-Infrared Quantum Cascade Lasers.

PubMed

Jiang, Yifan; Vijayraghavan, Karun; Jung, Seungyong; Jiang, Aiting; Kim, Jae Hyun; Demmerle, Frederic; Boehm, Gerhard; Amann, Markus C; Belkin, Mikhail A

2016-02-16

Terahertz quantum cascade laser sources based on intra-cavity difference-frequency generation are currently the only room-temperature mass-producible diode-laser-like emitters of coherent 1-6 THz radiation. Device performance has improved dramatically over the past few years to reach milliwatt-level power output and broad tuning from 1.2 to 5.9 THz, all at room-temperature. Terahertz output in these sources originates from intersubband optical nonlinearity in the laser active region. Here we report the first comprehensive spectroscopic study of the optical nonlinearity and investigate its dependence on the mid-infrared pump frequencies. Our work shows that the terahertz generation efficiency can vary by a factor of 2 or greater depending on the spectral position of the mid-infrared pumps for a fixed THz difference-frequency. We have also measured for the first time the linewidth for transitions between the lower quantum cascade laser states, which is critical for determining terahertz nonlinearity and predicting optical loss in quantum cascade laser waveguides.

Slitless spectroscopy with the James Webb Space Telescope Near-Infrared Camera (JWST NIRCam)

NASA Astrophysics Data System (ADS)

Greene, Thomas P.; Chu, Laurie; Egami, Eiichi; Hodapp, Klaus W.; Kelly, Douglas M.; Leisenring, Jarron; Rieke, Marcia; Robberto, Massimo; Schlawin, Everett; Stansberry, John

2016-07-01

The James Webb Space Telescope near-infrared camera (JWST NIRCam) has two 2.02 x 2.02 fields of view that are capable of either imaging or spectroscopic observations. Either of two R ~ 1500 grisms with orthogonal dispersion directions can be used for slitless spectroscopy over λ = 2.4 - 5.0 μm in each module, and shorter wavelength observations of the same fields can be obtained simultaneously. We present the latest predicted grism sensitivities, saturation limits, resolving power, and wavelength coverage values based on component measurements, instrument tests, and end-to-end modeling. Short wavelength (0.6 - 2.3 μm) imaging observations of the 2.4 - 5.0 μm spectroscopic field can be performed in one of several different filter bands, either in-focus or defocused via weak lenses internal to NIRCam. Alternatively, the possibility of 1.0 - 2.0 μm spectroscopy (simultaneously with 2.4 - 5.0 μm) using dispersed Hartmann sensors (DHSs) is being explored. The grisms, weak lenses, and DHS elements were included in NIRCam primarily for wavefront sensing purposes, but all have significant science applications. Operational considerations including subarray sizes, and data volume limits are also discussed. Finally, we describe spectral simulation tools and illustrate potential scientific uses of the grisms by presenting simulated observations of deep extragalactic fields, galactic dark clouds, and transiting exoplanets.

[Application of near infrared reflectance spectroscopy to predict meat chemical compositions: a review].

PubMed

Tao, Lin-Li; Yang, Xiu-Juan; Deng, Jun-Ming; Zhang, Xi

2013-11-01

In contrast to conventional methods for the determination of meat chemical composition, near infrared reflectance spectroscopy enables rapid, simple, secure and simultaneous assessment of numerous meat properties. The present review focuses on the use of near infrared reflectance spectroscopy to predict meat chemical compositions. The potential of near infrared reflectance spectroscopy to predict crude protein, intramuscular fat, fatty acid, moisture, ash, myoglobin and collagen of beef, pork, chicken and lamb is reviewed. This paper discusses existing questions and reasons in the current research. According to the published results, although published results vary considerably, they suggest that near-infrared reflectance spectroscopy shows a great potential to replace the expensive and time-consuming chemical analysis of meat composition. In particular, under commercial conditions where simultaneous measurements of different chemical components are required, near infrared reflectance spectroscopy is expected to be the method of choice. The majority of studies selected feature-related wavelengths using principal components regression, developed the calibration model using partial least squares and modified partial least squares, and estimated the prediction accuracy by means of cross-validation using the same sample set previously used for the calibration. Meat fatty acid composition predicted by near-infrared spectroscopy and non-destructive prediction and visualization of chemical composition in meat using near-infrared hyperspectral imaging and multivariate regression are the hot studying field now. On the other hand, near infrared reflectance spectroscopy shows great difference for predicting different attributes of meat quality which are closely related to the selection of calibration sample set, preprocessing of near-infrared spectroscopy and modeling approach. Sample preparation also has an important effect on the reliability of NIR prediction; in particular

Experimental study of near-field light collection efficiency of aperture fiber probe at near-infrared wavelengths.

PubMed

Tsumori, Nobuhiro; Takahashi, Motoki; Sakuma, Yoshiki; Saiki, Toshiharu

2011-10-10

We examined the near-field collection efficiency of near-infrared radiation for an aperture probe. We used InAs quantum dots as ideal point light sources with emission wavelengths ranging from 1.1 to 1.6 μm. We experimentally investigated the wavelength dependence of the collection efficiency and compared the results with computational simulations that modeled the actual probe structure. The observed degradation in the collection efficiency is attributed to the cutoff characteristics of the gold-clad tapered waveguide, which approaches an ideal conductor at near-infrared wavelengths. © 2011 Optical Society of America

Excitation Mechanisms of Near-Infrared Emission Lines in LINER Galaxies

NASA Astrophysics Data System (ADS)

Boehle, Anna

2017-01-01

I will present high spatial resolution, integral field spectroscopic observations of the nearby LINER (low ionization nuclear emission line region) galaxy NGC 404. LINERs are found at the centers of ~1/3 of galaxies within 40 Mpc, but their physical nature is not well understood. Although NGC 404 is thought to host a intermediate mass black hole at its center, it is unclear whether accretion onto the black hole or another mechanism such as shock excitation drives its LINER emission. We use the OSIRIS near-infrared integral field spectrograph at Keck Observatory behind laser guide star adaptive optics to map the strength and kinematics of [FeII], H2, and hydrogen recombination lines in the nucleus of NGC 404. These observations have a spatial pixel sampling of 0.5 pc and span the central 30 pc of the galaxy. We find that the ionized and molecular gas show differences in their morphology and kinematics on parsec scales. In particular, there are regions with line ratios of [FeII]/Pa-β that are much higher than previously seen in spatially integrated spectra, significantly restricting the possible excitation mechanisms of the near-infrared emission lines in this source. We are also applying these analysis techniques to 10 additional nearby LINERs, a part of a larger sample of 14 sources, to understand what drives the emission lines in these active galaxies. As a part of this program, I worked on the upgrade of the detector in the OSIRIS spectrograph, which has allowed observations for this survey obtained since January 2016 to be taken with increased instrument sensitivity of a factor of ~2 at J-band wavelengths (1.2 - 1.4 microns) and ~1.6 at H- and K-band wavelengths (1.5 - 2.4 microns). I will present results from the LINER survey, the OSIRIS detector upgrade, and also touch on related work using stellar orbits around the Milky Way supermassive black hole Sgr A* to constrain the mass and distance to our own Galactic Center.

Research on capability of detecting ballistic missile by near space infrared system

NASA Astrophysics Data System (ADS)

Lu, Li; Sheng, Wen; Jiang, Wei; Jiang, Feng

2018-01-01

The infrared detection technology of ballistic missile based on near space platform can effectively make up the shortcomings of high-cost of traditional early warning satellites and the limited earth curvature of ground-based early warning radar. In terms of target detection capability, aiming at the problem that the formula of the action distance based on contrast performance ignores the background emissivity in the calculation process and the formula is only valid for the monochromatic light, an improved formula of the detecting range based on contrast performance is proposed. The near space infrared imaging system parameters are introduced, the expression of the contrastive action distance formula based on the target detection of the near space platform is deduced. The detection range of the near space infrared system for the booster stage ballistic missile skin, the tail nozzle and the tail flame is calculated. The simulation results show that the near-space infrared system has the best effect on the detection of tail-flame radiation.

Analysis of Forensic Casework Utilizing Infrared Spectroscopic Imaging †

PubMed Central

Lanzarotta, Adam

2016-01-01

A search of the current scientific literature yields a limited number of studies that describe the use of Fourier transform infrared (FT-IR) spectroscopic imaging for the analysis of forensic casework, which is likely due to the fact that these instruments are fairly new commodities to the field of analytical chemistry and are therefore not yet commonplace in forensic laboratories. This report describes recent forensic case studies that have used the technique for determining the composition of a wide variety of multi-component sample types, including animal tissue sections for toxic inclusions, drugs/dietary supplements, an antibiotic with an active pharmaceutical ingredient (API) present as several different salt forms, an adulterated bulk API, unknown trace powders for illicit drugs and an ophthalmic solution suspected of being adulterated with bleach. PMID:26927101

Infrared and Raman spectroscopic features of plant cuticles: a review

PubMed Central

Heredia-Guerrero, José A.; Benítez, José J.; Domínguez, Eva; Bayer, Ilker S.; Cingolani, Roberto; Athanassiou, Athanassia; Heredia, Antonio

2014-01-01

The cuticle is one of the most important plant barriers. It is an external and continuous lipid membrane that covers the surface of epidermal cells and whose main function is to prevent the massive loss of water. The spectroscopic characterization of the plant cuticle and its components (cutin, cutan, waxes, polysaccharides and phenolics) by infrared and Raman spectroscopies has provided significant advances in the knowledge of the functional groups present in the cuticular matrix and on their structural role, interaction and macromolecular arrangement. Additionally, these spectroscopies have been used in the study of cuticle interaction with exogenous molecules, degradation, distribution of components within the cuticle matrix, changes during growth and development and characterization of fossil plants. PMID:25009549

Water pair potential of near spectroscopic accuracy. II. Vibration-rotation-tunneling levels of the water dimer

NASA Astrophysics Data System (ADS)

Groenenboom, G. C.; Wormer, P. E. S.; van der Avoird, A.; Mas, E. M.; Bukowski, R.; Szalewicz, K.

2000-10-01

Nearly exact six-dimensional quantum calculations of the vibration-rotation-tunneling (VRT) levels of the water dimer for values of the rotational quantum numbers J and K ⩽2 show that the SAPT-5s water pair potential presented in the preceding paper (paper I) gives a good representation of the experimental high-resolution far-infrared spectrum of the water dimer. After analyzing the sensitivity of the transition frequencies with respect to the linear parameters in the potential we could further improve this potential by using only one of the experimentally determined tunneling splittings of the ground state in (H2O)2. The accuracy of the resulting water pair potential, SAPT-5st, is established by comparison with the spectroscopic data of both (H2O)2 and (D2O)2: ground and excited state tunneling splittings and rotational constants, as well as the frequencies of the intermolecular vibrations.

Spectroscopic Infrared Extinction Mapping as a Probe of Grain Growth in IRDCs

NASA Astrophysics Data System (ADS)

Lim, Wanggi; Carey, Sean J.; Tan, Jonathan C.

2015-11-01

We present spectroscopic tests of MIR to FIR extinction laws in IRDC G028.36+00.07, a potential site of massive star and star cluster formation. Lim & Tan developed methods of FIR extinction mapping of this source using Spitzer-MIPS 24 μm and Herschel-PACS 70 μm images, and by comparing to MIR Spitzer-IRAC 3-8 μm extinction maps, found tentative evidence for grain growth in the highest mass surface density regions. Here we present results of spectroscopic infrared extinction mapping using Spitzer-IRS (14-38 μm) data of the same Infrared dark cloud (IRDC). These methods allow us to first measure the SED of the diffuse Galactic interstellar medium that is in the foreground of the IRDC. We then carry out our primary investigation of measuring the MIR to FIR opacity law and searching for potential variations as a function of mass surface density within the IRDC. We find relatively flat, featureless MIR-FIR opacity laws that lack the ˜12 and ˜35 μm features associated with the thick water ice mantle models of Ossenkopf & Henning. Their thin ice mantle models and the coagulating aggregate dust models of Ormel et al. are a generally better match to the observed opacity laws. We also find evidence for generally flatter MIR to FIR extinction laws as mass surface density increases, strengthening the evidence for grain and ice mantle growth in higher density regions.

Measuring Low Mass Galaxies In The WFC3 Infrared Spectroscopic Parallels Survey

NASA Astrophysics Data System (ADS)

Colbert, James; Teplitz, Harry; Scarlata, Claudia; Siana, Brian; Malkan, Matt; McCarthy, Patrick; Henry, Alaina; Atek, Hakim; Fosbury, Robert; Ross, Nathanial; Hathi, Nimish; Bridge, Carrie; Bunker, Andrew; Dressler, Alan; Shim, Hyunjin; Bedregal, Alejandro; Dominguez, Alberto; Rafelski, Marc; Masters, Dan; Martin, Crystal; Dai, Sophia

2015-10-01

The WFC3 Infrared Spectroscopic Parallel (WISP) Survey uses over 1800 HST orbits to study galaxy evolution over a majority of cosmic history. Its slitless grism spectroscopy over a wide, continuous spectral range (0.8-1.7 micron) provides an unbiased selection of thousands of emission line galaxies over 0.5 < z < 2.5. Hundreds of these galaxies are detected in multiple emission lines, allowing for important diagnostics of metallicity and dust extinction. We propose deep 3.6 micron imaging (5 sigma, 0.9 micro-Jy) of 60 of the deepest WISP fields observed with the combination of G102+G141 grisms, in order to detect emission-line galaxies down to 0.1 L* and masses below 10^8 Mo. Combined with our HST optical and near-IR photometry, these IRAC data will be critical to determining accurate stellar masses for both passive and active galaxies in our survey. We will determine the evolution of the faint end slope of the stellar mass function and the mass-metallicity relation down to low-mass galaxies. The addition of the IRAC photometry will also provide much stronger constraints on dust extinction and star formation history, especially when combined with information available from the emission lines themselves.

Infrared spectroscopic studies of myeloid leukemia (ML-1) cells at different phases of the cell cycle

NASA Astrophysics Data System (ADS)

Boydston-White, Susie; Diem, Max

1999-06-01

Advances in infrared spectroscopic methodology permit excellent infrared spectra to be collected from objects as small as single human cells. These advances have lead to an increased interest of the use of infrared spectroscopy as a medical diagnostic tool. Infrared spectra of myeloid leukemia (ML-1) cells are reported for cells derived from an asynchronous, exponentially-growing culture, as well as for cells that were fractionated according to their stage within the cell division cycle. The observed results suggest that the cells' DNA is detectable by infrared spectroscopy mainly when the cell is in the S phase, during the replication of DNA. In the G1 and G2 phases, the DNA is so tightly packed in the nucleus that it appears opaque to infrared radiation. Consequently, the nucleic acid spectral contributions in the G1 and G2 phases would be mostly that of cytoplasmic RNA. These results suggest that infrared spectral changes observed earlier between normal and abnormal cells may have been due to different distributions of cells within the stages of the cell division cycle.

An empirical evaluation of three vibrational spectroscopic methods for detection of aflatoxins in maize.

PubMed

Lee, Kyung-Min; Davis, Jessica; Herrman, Timothy J; Murray, Seth C; Deng, Youjun

2015-04-15

Three commercially available vibrational spectroscopic techniques, including Raman, Fourier transform near infrared reflectance (FT-NIR), and Fourier transform infrared (FTIR) were evaluated to help users determine the spectroscopic method best suitable for aflatoxin analysis in maize (Zea mays L.) grain based on their relative efficiency and predictive ability. Spectral differences of Raman and FTIR spectra were more marked and pronounced among aflatoxin contamination groups than those of FT-NIR spectra. From the observations and findings in our current and previous studies, Raman and FTIR spectroscopic methods are superior to FT-NIR method in terms of predictive power and model performance for aflatoxin analysis and they are equally effective and accurate in predicting aflatoxin concentration in maize. The present study is considered as the first attempt to assess how spectroscopic techniques with different physical processes can influence and improve accuracy and reliability for rapid screening of aflatoxin contaminated maize samples. Copyright © 2014 Elsevier Ltd. All rights reserved.

Interplay between up-regulation of cytochrome-c-oxidase and hemoglobin oxygenation induced by near-infrared laser

PubMed Central

Wang, Xinlong; Tian, Fenghua; Soni, Sagar S.; Gonzalez-Lima, F.; Liu, Hanli

2016-01-01

Photobiomodulation, also known as low-level laser/light therapy (LLLT), refers to the use of red-to-near-infrared light to stimulate cellular functions for physiological or clinical benefits. The mechanism of LLLT is assumed to rely on photon absorption by cytochrome c oxidase (CCO), the terminal enzyme in the mitochondrial respiratory chain that catalyzes the reduction of oxygen for energy metabolism. In this study, we used broadband near-infrared spectroscopy (NIRS) to measure the LLLT-induced changes in CCO and hemoglobin concentrations in human forearms in vivo. Eleven healthy participants were administered with 1064-nm laser and placebo treatments on their right forearms. The spectroscopic data were analyzed and fitted with wavelength-dependent, modified Beer-Lambert Law. We found that LLLT induced significant increases of CCO concentration (Δ[CCO]) and oxygenated hemoglobin concentration (Δ[HbO]) on the treated site as the laser energy dose accumulated over time. A strong linear interplay between Δ[CCO] and Δ[HbO] was observed for the first time during LLLT, indicating a hemodynamic response of oxygen supply and blood volume closely coupled to the up-regulation of CCO induced by photobiomodulation. These results demonstrate the tremendous potential of broadband NIRS as a non-invasive, in vivo means to study mechanisms of photobiomodulation and perform treatment evaluations of LLLT. PMID:27484673

Interplay between up-regulation of cytochrome-c-oxidase and hemoglobin oxygenation induced by near-infrared laser

NASA Astrophysics Data System (ADS)

Wang, Xinlong; Tian, Fenghua; Soni, Sagar S.; Gonzalez-Lima, F.; Liu, Hanli

2016-08-01

Photobiomodulation, also known as low-level laser/light therapy (LLLT), refers to the use of red-to-near-infrared light to stimulate cellular functions for physiological or clinical benefits. The mechanism of LLLT is assumed to rely on photon absorption by cytochrome c oxidase (CCO), the terminal enzyme in the mitochondrial respiratory chain that catalyzes the reduction of oxygen for energy metabolism. In this study, we used broadband near-infrared spectroscopy (NIRS) to measure the LLLT-induced changes in CCO and hemoglobin concentrations in human forearms in vivo. Eleven healthy participants were administered with 1064-nm laser and placebo treatments on their right forearms. The spectroscopic data were analyzed and fitted with wavelength-dependent, modified Beer-Lambert Law. We found that LLLT induced significant increases of CCO concentration (Δ[CCO]) and oxygenated hemoglobin concentration (Δ[HbO]) on the treated site as the laser energy dose accumulated over time. A strong linear interplay between Δ[CCO] and Δ[HbO] was observed for the first time during LLLT, indicating a hemodynamic response of oxygen supply and blood volume closely coupled to the up-regulation of CCO induced by photobiomodulation. These results demonstrate the tremendous potential of broadband NIRS as a non-invasive, in vivo means to study mechanisms of photobiomodulation and perform treatment evaluations of LLLT.

Interplay between up-regulation of cytochrome-c-oxidase and hemoglobin oxygenation induced by near-infrared laser.

PubMed

Wang, Xinlong; Tian, Fenghua; Soni, Sagar S; Gonzalez-Lima, F; Liu, Hanli

2016-08-03

Photobiomodulation, also known as low-level laser/light therapy (LLLT), refers to the use of red-to-near-infrared light to stimulate cellular functions for physiological or clinical benefits. The mechanism of LLLT is assumed to rely on photon absorption by cytochrome c oxidase (CCO), the terminal enzyme in the mitochondrial respiratory chain that catalyzes the reduction of oxygen for energy metabolism. In this study, we used broadband near-infrared spectroscopy (NIRS) to measure the LLLT-induced changes in CCO and hemoglobin concentrations in human forearms in vivo. Eleven healthy participants were administered with 1064-nm laser and placebo treatments on their right forearms. The spectroscopic data were analyzed and fitted with wavelength-dependent, modified Beer-Lambert Law. We found that LLLT induced significant increases of CCO concentration (Δ[CCO]) and oxygenated hemoglobin concentration (Δ[HbO]) on the treated site as the laser energy dose accumulated over time. A strong linear interplay between Δ[CCO] and Δ[HbO] was observed for the first time during LLLT, indicating a hemodynamic response of oxygen supply and blood volume closely coupled to the up-regulation of CCO induced by photobiomodulation. These results demonstrate the tremendous potential of broadband NIRS as a non-invasive, in vivo means to study mechanisms of photobiomodulation and perform treatment evaluations of LLLT.

Constraints on the age and provenance of the Chugach accretionary complex from detrital zircons in the Sitka Graywacke near Sitka, Alaska

USGS Publications Warehouse

Haeussler, Peter J.; Gehrels, George E.; Karl, Susan M.

2006-01-01

The Sitka Graywacke is the westernmost and youngest unit of the Chugach accretionary complex in southeastern Alaska. Using laser-ablation inductively coupled plasma mass spectroscopy, we obtained 492 detrital-zircon ages on seven typical samples of Sitka Graywacke turbidites, which were collected in a transect across much of the unit near Sitka, Alaska. Individual grains range in age from 66 to 1,802 m.y. The youngest peak ages on relative-probability plots of the western four samples (74, 72, 74, and 74 m.y., from west to east) are distinctly younger than the youngest peak ages of the eastern three samples (105, 103, and 97 m.y., from west to east). These youngest peak ages set maximum depositional ages for each sample. We suggest that these peak ages are not significantly older (within ~5 m.y.) than the depositional age of the Sitka Graywacke because the deposits accumulated in a trench along a convergent margin, where magmatic sources likely continuously introduced juvenile zircons. The differences in the youngest cluster of detrital-zircon ages between the eastern and western sample localities is likely due to both a change in provenance and a fault. The similarity of the youngest peak ages in the Sitka Graywacke to fossil ages in the Valdez Group, in Prince William Sound, implies that the western part of the Sitka Graywacke is correlative with the Valdez Group, as previously inferred. However, the eastern part of the Sitka Graywacke has youngest detrital-zircon ages older than fossil ages in the Valdez Group and younger than fossil ages in the McHugh Complex, which in south-central Alaska is the oldest part of the accretionary complex. The age distribution of zircons in the older, eastern sequence suggests sources along the British Columbia margin. The detrital-zircon ages in the younger, western sequence are similar to igneous ages from south-central Alaska to southern British Columbia. Right-lateral strike slip on various fault systems inboard of the Sitka

Mid-infrared laser phase-locking to a remote near-infrared frequency reference for high-precision molecular spectroscopy

NASA Astrophysics Data System (ADS)

Chanteau, B.; Lopez, O.; Zhang, W.; Nicolodi, D.; Argence, B.; Auguste, F.; Abgrall, M.; Chardonnet, C.; Santarelli, G.; Darquié, B.; Le Coq, Y.; Amy-Klein, A.

2013-07-01

We present a method for accurate mid-infrared frequency measurements and stabilization to a near-infrared ultra-stable frequency reference, transmitted with a long-distance fibre link and continuously monitored against state-of-the-art atomic fountain clocks. As a first application, we measure the frequency of an OsO4 rovibrational molecular line around 10 μm with an uncertainty of 8 × 10-13. We also demonstrate the frequency stabilization of a mid-infrared laser with fractional stability better than 4 × 10-14 at 1 s averaging time and a linewidth below 17 Hz. This new stabilization scheme gives us the ability to transfer frequency stability in the range of 10-15 or even better, currently accessible in the near infrared or in the visible, to mid-infrared lasers in a wide frequency range.

Brown carbon absorption in the red and near-infrared spectral region

NASA Astrophysics Data System (ADS)

Hoffer, András; Tóth, Ádám; Pósfai, Mihály; Eddy Chung, Chul; Gelencsér, András

2017-06-01

Black carbon (BC) aerosols have often been assumed to be the only light-absorbing carbonaceous particles in the red and near-infrared spectral regions of solar radiation in the atmosphere. Here we report that tar balls (a specific type of organic aerosol particles from biomass burning) do absorb red and near-infrared radiation significantly. Tar balls were produced in a laboratory experiment, and their chemical and optical properties were measured. The absorption of these particles in the range between 470 and 950 nm was measured with an aethalometer, which is widely used to measure atmospheric aerosol absorption. We find that the absorption coefficient of tar balls at 880 nm is more than 10 % of that at 470 nm. The considerable absorption of red and infrared light by tar balls also follows from their relatively low absorption Ångström coefficient (and significant mass absorption coefficient) in the spectral range between 470 and 950 nm. Our results support the previous finding that tar balls may play an important role in global warming. Due to the non-negligible absorption of tar balls in the near-infrared region, the absorption measured in the field at near-infrared wavelengths cannot solely be due to soot particles.

New spectroscopic tools and techniques for characterizing M dwarfs and discovering their planets in the near-infrared

NASA Astrophysics Data System (ADS)

Terrien, Ryan C.

M dwarfs are the least massive and most common stars in the Galaxy. Due to their prevalence and long lifetimes, these diminutive stars play an outsize role in several fields of astronomical study. In particular, it is now known that they commonly host planetary systems, and may be the most common hosts of Earth-size, rocky planets in the habitable zone. A comprehensive understanding of M dwarfs is crucial for understanding the origins and conditions of their planetary systems, including their potential habitability. Such an understanding depends on methods for precisely and accurately measuring their properties. These tools have broader applicability as well, underlying the use of M dwarfs as fossils of Galactic evolution, and helping to constrain the structures and interiors of these stars. The measurement of the fundamental parameters of M dwarfs is encumbered by their spectral complexity. Unlike stars of spectral type F, G, or K that are similar to our G type Sun, whose spectra are dominated by continuum emission and atomic features, the cool atmospheres of M dwarfs are dominated by complex molecular absorption. Another challenge for studies of M dwarfs is that these stars are optically faint, emitting much of their radiation in the near-infrared (NIR). The availability and performance of NIR spectrographs have lagged behind those of optical spectrographs due to the challenges of producing low-noise, high-sensitivity NIR detector arrays, which have only recently become available. This thesis discusses two related lines of work that address these challenges, motivated by the development of the Habitable Zone Planet Finder (HPF), a NIR radial velocity (RV) spectrograph under development at Penn State that will search for and confirm planets around nearby M dwarfs. This work includes the development and application of new NIR spectroscopic techniques for characterizing M dwarfs, and the development and optimization of new NIR instrumentation for HPF. The first line

Near infrared and visible face recognition based on decision fusion of LBP and DCT features

NASA Astrophysics Data System (ADS)

Xie, Zhihua; Zhang, Shuai; Liu, Guodong; Xiong, Jinquan

2018-03-01

Visible face recognition systems, being vulnerable to illumination, expression, and pose, can not achieve robust performance in unconstrained situations. Meanwhile, near infrared face images, being light- independent, can avoid or limit the drawbacks of face recognition in visible light, but its main challenges are low resolution and signal noise ratio (SNR). Therefore, near infrared and visible fusion face recognition has become an important direction in the field of unconstrained face recognition research. In order to extract the discriminative complementary features between near infrared and visible images, in this paper, we proposed a novel near infrared and visible face fusion recognition algorithm based on DCT and LBP features. Firstly, the effective features in near-infrared face image are extracted by the low frequency part of DCT coefficients and the partition histograms of LBP operator. Secondly, the LBP features of visible-light face image are extracted to compensate for the lacking detail features of the near-infrared face image. Then, the LBP features of visible-light face image, the DCT and LBP features of near-infrared face image are sent to each classifier for labeling. Finally, decision level fusion strategy is used to obtain the final recognition result. The visible and near infrared face recognition is tested on HITSZ Lab2 visible and near infrared face database. The experiment results show that the proposed method extracts the complementary features of near-infrared and visible face images and improves the robustness of unconstrained face recognition. Especially for the circumstance of small training samples, the recognition rate of proposed method can reach 96.13%, which has improved significantly than 92.75 % of the method based on statistical feature fusion.

Near infrared fluorescent chlorophyll nanoscale liposomes for sentinel lymph node mapping

PubMed Central

Fan, Lina; Wu, Qiang; Chu, Maoquan

2012-01-01

Background Sentinel lymph node (SLN) mapping using in vivo near infrared fluorescence imaging has attracted great attention during the past few years. Here we report on the early use of poorly water-soluble chlorophyll with near infrared fluorescence extracted from the leaf of Chimonanthus salicifolius, for mouse axillary SLN mapping. Methods and results To improve the water solubility and SLN targeting of the chlorophyll, we encapsulated the chlorophyll in nanoscale liposomes. The liposome-coated chlorophyll nanocomposites obtained were spherical in shape and had an average diameter of 21.7 ± 6.0 nm. The nanocomposites dispersed well in water, and in aqueous suspension they exhibited brighter near infrared fluorescence than chlorophyll alone. After incubation of the nanocomposites with normal liver cells (QSG-7701) and macrophage cells (Ana-1) for no more than 48 hours, there was no obvious reduction in cell viability. When the nanocomposites were injected intradermally into the paw of a mouse, the axillary SLN was found to be strongly fluorescent and was easily visualized in real time without a requirement for surgery. The intensity of the near infrared fluorescence emitted by the SLN was obviously brighter than that emitted by the SLN of another mouse that had been intradermally injected with chlorophyll alone. Conclusion Our data show that the liposome-coated chlorophyll nanocomposites could have great potential for clinical SLN mapping due to their lack of toxicity, bright near infrared fluorescence, and small diameter. PMID:22787402

JWST Near-Infrared Detectors: Latest Test Results

NASA Technical Reports Server (NTRS)

Smith, Erin C.; Rauscher, Bernard J.; Alexander, David; Brambora, Clifford K.; Chiao, Meng; Clemons, Brian L.; Derro, Rebecca; Engler, Chuck; Fox, Ori; Garrison, Matthew B.;

The optical and near-infrared colors of galaxies, 1: The photometric data

NASA Technical Reports Server (NTRS)

Bershady, Matthew A.; Hereld, Mark; Kron, Richard G.; Koo, David C.; Munn, Jeffrey A.; Majewski, Steven R.

1994-01-01

We present optical and near-infrared photometry and spectroscopic redshifts of a well defined sample of 171 field galaxies selected from three high galactic latitude fields. This data set forms the basis for subsequent studies to characterize the trends, dispersion, and evolution of rest-frame colors and image structure. A subset of 143 galaxies constitutes a magnitude-limited sample to B approx. 19.9-20.75 (depending on field), with a median redshift of 0.14, and a maximum redshift of 0.54. This subset is statistically representative in its sampling of the apparent color distribution of galaxies. Thirty six galaxies were selected to have the reddest red-optical colors in two redshift intervals between 0.2 less than z less than 0.3. Photometric passbands are similar to U, B, V, I, and K, and sample galaxy spectral energy distributions between 0.37 and 2.2 micrometers in the observed frame, or down to 0.26 micrometers in the rest frame for the most distant galaxies. B and K images of the entire sample are assembled to form the first optical and near-infrared atlas of a statistically-representative sample of field galaxies. We discuss techniques for faint field-galaxy photometry, including a working definition of a total magnitude, and a method for matching magnitudes in different passbands and different seeing conditions to ensure reliable, integrated colors. Photographic saturation, which substantially affects the brightest 12% of our sample in the optical bands, is corrected with a model employing measured plate-density distributions for each galaxy, calibrated via similar measurements for stars as a function of known saturation level. Both the relative and absolute calibration of our photometry are demonstrated.

Broadband near-field infrared spectroscopy with a high temperature plasma light source.

PubMed

Lahneman, D J; Huffman, T J; Xu, Peng; Wang, S L; Grogan, T; Qazilbash, M M

2017-08-21

Scattering-type scanning near-field optical microscopy (S-SNOM) has enormous potential as a spectroscopy tool in the infrared spectral range where it can probe phonon resonances and carrier dynamics at the nanometer lengths scales. However, its applicability is limited by the lack of practical and affordable table-top light sources emitting intense broadband infrared radiation in the 100 cm -1 to 2,500 cm -1 spectral range. This paper introduces a high temperature plasma light source that is both ultra-broadband and has much more radiant power in the infrared spectral range than conventional, table-top thermal light sources such as the globar. We implement this plasma lamp in our near-field optical spectroscopy set up and demonstrate its capability as a broadband infrared nano-spectroscopy light source by obtaining near-field infrared amplitude and phase spectra of the phonon resonances of SiO 2 and SrTiO 3 .

Near-infrared-spectroscopic study on processing of sounds in the brain; a comparison between native and non-native speakers of Japanese.

PubMed

Tsunoda, Koichi; Sekimoto, Sotaro; Itoh, Kenji

2016-06-01

Conclusions The result suggested that mother tongue Japanese and non- mother tongue Japanese differ in their pattern of brain dominance when listening to sounds from the natural world-in particular, insect sounds. These results reveal significant support for previous findings from Tsunoda (in 1970). Objectives This study concentrates on listeners who show clear evidence of a 'speech' brain vs a 'music' brain and determines which side is most active in the processing of insect sounds, using with near-infrared spectroscopy. Methods The present study uses 2-channel Near Infrared Spectroscopy (NIRS) to provide a more direct measure of left- and right-brain activity while participants listen to each of three types of sounds: Japanese speech, Western violin music, or insect sounds. Data were obtained from 33 participants who showed laterality on opposite sides for Japanese speech and Western music. Results Results showed that a majority (80%) of the MJ participants exhibited dominance for insect sounds on the side that was dominant for language, while a majority (62%) of the non-MJ participants exhibited dominance for insect sounds on the side that was dominant for music.

Enhanced broadband near-infrared luminescence from Pr3+-doped tellurite glass with silver nanoparticles

NASA Astrophysics Data System (ADS)

Cheng, Pan; Zhou, Yaxun; Zhou, Minghan; Su, Xiue; Zhou, Zizhong; Yang, Gaobo

2017-11-01

Pr3+-doped tellurite glasses containing metallic silver NPs were synthesized by the conventional melt-quenching technique. Structural, thermal and optical properties of the synthesized glass samples were characterized by X-Ray diffraction (XRD) curves, Raman spectra, differential scanning calorimeter (DSC) curves, transmission electron microscopy (TEM) images, UV/Vis/NIR absorption and near-infrared fluorescence emission spectra. The XRD curves confirmed the amorphous structural nature of the synthesized glasses, the Raman spectra identified the presence of different vibrational groups, the DSC curves verified the good thermal stability, and the TEM images revealed the nucleated silver NPs with average diameter about 10 nm dispersed in the glass matrix and its surface Plasmon resonance (SPR) absorption band was located at around 510 nm. Besides, Judd-Ofelt intensity parameters Ωt (t = 2, 4, 6) and other important spectroscopic parameters like transition probability, radiative lifetime, branching ratio were calculated to evaluate the radiative properties of Pr3+ levels from the measured optical absorption spectra. It was found that Pr3+-doped tellurite glasses could emit an ultra-broadband fluorescence extending from 1250 to 1650 nm under the 488 nm excitation, and this fluorescence emission increased further with the introduction of silver NPs. The enhanced fluorescence was mainly attributed to the increased local electric field around Pr3+ induced by silver NPs. The present results demonstrate that Pr3+-Ag codoped tellurite glass is a promising candidate for the near-infrared band ultra-broadband fiber amplifiers covering the expanded low-loss communication window.

Ultrashort Carbon Nanotubes That Fluoresce Brightly in the Near-Infrared.

PubMed

Danné, Noémie; Kim, Mijin; Godin, Antoine G; Kwon, Hyejin; Gao, Zhenghong; Wu, Xiaojian; Hartmann, Nicolai F; Doorn, Stephen K; Lounis, Brahim; Wang, YuHuang; Cognet, Laurent

2018-06-14

The intrinsic near-infrared photoluminescence observed in long single-walled carbon nanotubes is known to be quenched in ultrashort nanotubes due to their tiny size as compared to the exciton diffusion length in these materials (>100 nm). Here, we show that intense photoluminescence can be created in ultrashort nanotubes (∼40 nm length) upon incorporation of exciton-trapping sp 3 defect sites. Using super-resolution photoluminescence imaging at <25 nm resolution, we directly show the preferential localization of excitons at the nanotube ends, which separate by less than 40 nm and behave as independent emitters. This unexpected observation opens the possibility to synthesize fluorescent ultrashort nanotubes-a goal that has been long thought impossible-for bioimaging applications, where bright near-infrared photoluminescence and small size are highly desirable, and for quantum information science, where high quality and well-controlled near-infrared single photon emitters are needed.

New approach to optimize near-infrared spectra with design of experiments and determination of milk compounds as influence factors for changing milk over time.

PubMed

De Benedictis, Lorenzo; Huck, Christian

2016-12-01

The optimization of near-infrared spectroscopic parameters was realized via design of experiments. With this new approach objectivity can be integrated into conventional, rather subjective approaches. The investigated factors are layer thickness, number of scans and temperature during measurement. Response variables in the full factorial design consisted of absorption intensity, signal-to-noise ratio and reproducibility of the spectra. Optimized factorial combinations have been found to be 0.5mm layer thickness, 64 scans and 25°C ambient temperature for liquid milk measurements. Qualitative analysis of milk indicated a strong correlation of environmental factors, as well as the feeding of cattle with respect to the change in milk composition. This was illustrated with the aid of near-infrared spectroscopy and the previously optimized parameters by detection of altered fatty acids in milk, especially by the fatty acid content (number of carboxylic functions) and the fatty acid length. Copyright © 2016 Elsevier Ltd. All rights reserved.

Long open-path measurements of greenhouse gases in air using near-infrared Fourier transform spectroscopy

NASA Astrophysics Data System (ADS)

Griffith, David W. T.; Pöhler, Denis; Schmitt, Stefan; Hammer, Samuel; Vardag, Sanam N.; Platt, Ulrich

2018-03-01

In complex and urban environments, atmospheric trace gas composition is highly variable in time and space. Point measurement techniques for trace gases with in situ instruments are well established and accurate, but do not provide spatial averaging to compare against developing high-resolution atmospheric models of composition and meteorology with resolutions of the order of a kilometre. Open-path measurement techniques provide path average concentrations and spatial averaging which, if sufficiently accurate, may be better suited to assessment and interpretation with such models. Open-path Fourier transform spectroscopy (FTS) in the mid-infrared region, and differential optical absorption spectroscopy (DOAS) in the UV and visible, have been used for many years for open-path spectroscopic measurements of selected species in both clean air and in polluted environments. Near infrared instrumentation allows measurements over longer paths than mid-infrared FTS for species such as greenhouse gases which are not easily accessible to DOAS.In this pilot study we present the first open-path near-infrared (4000-10 000 cm-1, 1.0-2.5 µm) FTS measurements of CO2, CH4, O2, H2O and HDO over a 1.5 km path in urban Heidelberg, Germany. We describe the construction of the open-path FTS system, the analysis of the collected spectra, several measures of precision and accuracy of the measurements, and the results a four-month trial measurement period in July-November 2014. The open-path measurements are compared to calibrated in situ measurements made at one end of the open path. We observe significant differences of the order of a few ppm for CO2 and a few tens of ppb for CH4 between the open-path and point measurements which are 2 to 4 times the measurement repeatability, but we cannot unequivocally assign the differences to specific local sources or sinks. We conclude that open-path FTS may provide a valuable new tool for investigations of atmospheric trace gas composition in

Trace element chemistry of zircons from oceanic crust: A method for distinguishing detrital zircon provenance

USGS Publications Warehouse

Grimes, Craig B.; John, Barbara E.; Kelemen, P.B.; Mazdab, F.K.; Wooden, J.L.; Cheadle, Michael J.; Hanghoj, K.; Schwartz, J.J.

2007-01-01

We present newly acquired trace element compositions for more than 300 zircon grains in 36 gabbros formed at the slow-spreading Mid-Atlantic and Southwest Indian Ridges. Rare earth element patterns for zircon from modern oceanic crust completely overlap with those for zircon crystallized in continental granitoids. However, plots of U versus Yb and U/Yb versus Hf or Y discriminate zircons crystallized in oceanic crust from continental zircon, and provide a relatively robust method for distinguishing zircons from these environments. Approximately 80% of the modern ocean crust zircons are distinct from the field defined by more than 1700 continental zircons from Archean and Phanerozoic samples. These discrimination diagrams provide a new tool for fingerprinting ocean crust zircons derived from reservoirs like that of modern mid-ocean ridge basalt (MORB) in both modern and ancient detrital zircon populations. Hadean detrital zircons previously reported from the Acasta Gneiss, Canada, and the Narryer Gneiss terrane, Western Australia, plot in the continental granitoid field, supporting hypotheses that at least some Hadean detrital zircons crystallized in continental crust forming magmas and not from a reservoir like modern MORB. ?? 2007 The Geological Society of America.

Comparison between infrared and Raman spectroscopic analysis of maturing rabbit cortical bone.

PubMed

Turunen, Mikael J; Saarakkala, Simo; Rieppo, Lassi; Helminen, Heikki J; Jurvelin, Jukka S; Isaksson, Hanna

2011-06-01

The molecular composition of the organic and inorganic matrices of bone undergoes alterations during maturation. The aim of this study was to compare Fourier transform infrared (FT-IR) and near-infrared (NIR) Raman microspectroscopy techniques for characterization of the composition of growing and developing bone from young to skeletally mature rabbits. Moreover, the specificity and differences of the techniques for determining bone composition were clarified. The humeri of female New Zealand White rabbits, with age range from young to skeletally mature animals (four age groups, n = 7 per group), were studied. Spectral peak areas, intensities, and ratios related to organic and inorganic matrices of bone were analyzed and compared between the age groups and between FT-IR and Raman microspectroscopic techniques. Specifically, the degree of mineralization, type-B carbonate substitution, crystallinity of hydroxyapatite (HA), mineral content, and collagen maturity were examined. Significant changes during maturation were observed in various compositional parameters with one or both techniques. Overall, the compositional parameters calculated from the Raman spectra correlated with analogous parameters calculated from the IR spectra. Collagen cross-linking (XLR), as determined through peak fitting and directly from the IR spectra, were highly correlated. The mineral/matrix ratio in the Raman spectra was evaluated with multiple different peaks representing the organic matrix. The results showed high correlation with each other. After comparison with the bone mineral density (BMD) values from micro-computed tomography (micro-CT) imaging measurements and crystal size from XRD measurements, it is suggested that Raman microspectroscopy is more sensitive than FT-IR microspectroscopy for the inorganic matrix of the bone. In the literature, similar spectroscopic parameters obtained with FT-IR and NIR Raman microspectroscopic techniques are often compared. According to the present

Detrital Zircons Split Sibumasu in East Gondwana

NASA Astrophysics Data System (ADS)

Zhang, X.; Chung, S. L.

2017-12-01

It is widely accepted that Sibumasu developed as a united terrane and originated from NW Australian margin in East Gondwana. Here we report new detrital zircon U-Pb-Hf isotopic data from Sumatra that, in combination with literature data, challenge and refute the above long-held view. In particular, the East and West Sumatra terranes share nearly identical Precambrian to Paleozoic detrital zircon age distributions and Hf isotopes, indicating a common provenance/origin for them. The Sumatra detrital zircons exhibit a prominent population of ca. 1170-1070 Ma, indistinguishable from those of the Lhasa and West Burma terranes, with detritus most probably sourcing from western Australia. By contrast, Sibuma (Sibumasu excluding Sumatra) detrital zircons display a prevailing population of ca. 980-935 Ma, strongly resembling those of the western Qiangtang terrane, with detrital materials most likely derived from Greater India and Himalayas. Such markedly distinct detrital zircon age profiles between Sumatra and Sibuma require disparate sources/origin for them, provoking disintegration of the widely-adopted, but outdated, term Sibumasu and thus inviting a new configuration of East Gondwana in the early Paleozoic, with Sumatra and West Burma lying outboard the Lhasa terrane in the NW Australian margin and Sibuma situated in the northern Greater Indian margin. More future investigations are needed to establish the precise rifting and drifting histories of Sumatra and Sibuma, as two separated terranes, during the breakup of Gondwana.

Imperial College near infrared spectroscopy neuroimaging analysis framework.

PubMed

Orihuela-Espina, Felipe; Leff, Daniel R; James, David R C; Darzi, Ara W; Yang, Guang-Zhong

2018-01-01

This paper describes the Imperial College near infrared spectroscopy neuroimaging analysis (ICNNA) software tool for functional near infrared spectroscopy neuroimaging data. ICNNA is a MATLAB-based object-oriented framework encompassing an application programming interface and a graphical user interface. ICNNA incorporates reconstruction based on the modified Beer-Lambert law and basic processing and data validation capabilities. Emphasis is placed on the full experiment rather than individual neuroimages as the central element of analysis. The software offers three types of analyses including classical statistical methods based on comparison of changes in relative concentrations of hemoglobin between the task and baseline periods, graph theory-based metrics of connectivity and, distinctively, an analysis approach based on manifold embedding. This paper presents the different capabilities of ICNNA in its current version.

Near-infrared instrumentation for rapid-response astronomy

NASA Astrophysics Data System (ADS)

Capone, John Isaac

gamma-ray bursts (GRBs) are the Universe's most luminous transient events. Since the discovery of GRBs was announced in 1973, efforts have been ongoing to obtain data over a broader range of the electromagnetic spectrum at the earliest possible times following the initial detection. The discovery of the theorized "afterglow'' emission in radio through X-ray bands in the late 1990s confirmed the cosmological nature of these events. At present, GRB afterglows are among the best probes of the early Universe (z ≥ 9). In addition to informing theories about GRBs themselves, observations of afterglows probe the circum-burst medium (CBM), properties of the host galaxies and the progress of cosmic reionization. To explore the early-time variability of afterglows, I have developed a generalized analysis framework which models near-infrared (NIR), optical, ultra-violet (UV) and X-ray light curves without assuming an underlying model. These fits are then used to construct the spectral energy distribution (SED) of afterglows at arbitrary times within the observed window. Physical models are then used to explore the evolution of the SED parameter space with time. I demonstrate that this framework produces evidence of the photodestruction of dust in the CBM of GRB 120119A, similar to the findings from a previous study of this afterglow. The framework is additionally applied to the afterglows of GRB 140419A and GRB 080607. In these cases the evolution of the SEDs appears consistent with the standard fireball model. Having introduced the scientific motivations for early-time observations, I introduce the Rapid Infrared Imager-Spectrometer (RIMAS). Once commissioned on the 4.3 meter Discovery Channel Telescope (DCT), RIMAS will be used to study the afterglows of GRBs through photometric and spectroscopic observations beginning within minutes of the initial burst. The instrument will operate in the NIR, from 0.97 microm to 2.37 microm, permitting the detection of very high

Detection of cracks on tomatoes using hyperspectral near-infrared reflectance imaging system

USDA-ARS?s Scientific Manuscript database

The objective of this study was to evaluate the use of hyperspectral near-infrared (NIR) reflectance imaging techniques for detection of cuticle cracks on tomatoes. A hyperspectral near-infrared reflectance imaging system in the region of 1000-1700 nm was used to obtain hyperspectral reflectance ima...

Near-infrared Characterization of the Atmospheres of Alien Worlds

NASA Astrophysics Data System (ADS)

Croll, Bryce

In this thesis I present near-infrared detections of the thermal emission of a number of hot Jupiters and likely transit depth differences from different wavelength observations of a super-Earth. I have pioneered "Staring Mode" using the Wide-field Infrared Camera on the Canada-France-Hawaii Telescope to achieve the most accurate photometry to-date in the near- infrared from the ground. I also discuss avenues that should allow one to achieve even more accurate photometry in the future. Using WIRCam on CFHT my collaborators and I have detected the thermal emission of the following hot Jupiters: TrES-2b and TrES-3b in Ks-band, WASP-12b in the J, H & Ks-bands, and WASP-3b in the Ks-band on two occasions. Near- infrared detections of the thermal emission of hot Jupiters are important, because the majority of these planets' blackbodies peak in this wavelength range; near-infrared detections allow us to obtain the most model-independent constraints on these planets' atmospheric characteristics, their temperature-pressure profiles with depth and an estimate of their bolometric luminosities. With these detections we are able to answer such questions as: how efficiently these planets redistribute heat to their nightsides, if they're being inflated by tidal heating, whether there's any evidence that one of these planets is precessing, and whether another experiences extreme weather and violent storms? My collaborators and I have also observed several transits of the super-Earth GJ 1214b. We find a deeper transit depth in one of our near-infrared bands than the other. This is likely indicative of a spectral absorption feature. For the differences in the transit depth to be as large as we observed, the atmosphere of GJ 1214b must have a large scale height, low mean molecular weight and thus have a hydrogen/helium dominated atmosphere. Given that other researchers have not found similar transit depth differences, we also discuss the most likely atmospheric makeup for this

TESTING THE HYPOTHESIS THAT METHANOL MASER RINGS TRACE CIRCUMSTELLAR DISKS: HIGH-RESOLUTION NEAR-INFRARED AND MID-INFRARED IMAGING

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Buizer, James M.; Bartkiewicz, Anna; Szymczak, Marian, E-mail: jdebuizer@sofia.usra.edu

2012-08-01

Milliarcsecond very long baseline interferometry maps of regions containing 6.7 GHz methanol maser emission have lead to the recent discovery of ring-like distributions of maser spots and the plausible hypothesis that they may be tracing circumstellar disks around forming high-mass stars. We aimed to test this hypothesis by imaging these regions in the near- and mid-infrared at high spatial resolution and compare the observed emission to the expected infrared morphologies as inferred from the geometries of the maser rings. In the near-infrared we used the Gemini North adaptive optics system of ALTAIR/NIRI, while in the mid-infrared we used the combinationmore » of the Gemini South instrument T-ReCS and super-resolution techniques. Resultant images had a resolution of {approx}150 mas in both the near-infrared and mid-infrared. We discuss the expected distribution of circumstellar material around young and massive accreting (proto)stars and what infrared emission geometries would be expected for the different maser ring orientations under the assumption that the masers are coming from within circumstellar disks. Based upon the observed infrared emission geometries for the four targets in our sample and the results of spectral energy distribution modeling of the massive young stellar objects associated with the maser rings, we do not find compelling evidence in support of the hypothesis that methanol masers rings reside in circumstellar disks.« less

Femtowatt incoherent image conversion from mid-infrared light to near-infrared light

NASA Astrophysics Data System (ADS)

Huang, Nan; Liu, Hongjun; Wang, Zhaolu; Han, Jing; Zhang, Shuan

2017-03-01

We report on the experimental conversion imaging of an incoherent continuous-wave dim source from mid-infrared light to near-infrared light with a lowest input power of 31 femtowatt (fW). Incoherent mid-infrared images of light emission from a heat lamp bulb with an adjustable power supply at window wavelengths ranging from 2.9 µm to 3.5 µm are used for upconversion. The sum-frequency generation is realized in a laser cavity with the resonant wavelength of 1064 nm pumped by an LD at 806 nm built around a periodically poled lithium niobate (PPLN) crystal. The converted infrared image in the wavelength range ~785 nm with a resolution of about 120  ×  70 is low-noise detected using a silicon-based camera. By optimizing the system parameters, the upconversion quantum efficiency is predicted to be 28% for correctly polarized, on-axis and phase-matching light.

High-definition Fourier transform infrared spectroscopic imaging of prostate tissue

NASA Astrophysics Data System (ADS)

Wrobel, Tomasz P.; Kwak, Jin Tae; Kadjacsy-Balla, Andre; Bhargava, Rohit

2016-03-01

Histopathology forms the gold standard for cancer diagnosis and therapy, and generally relies on manual examination of microscopic structural morphology within tissue. Fourier-Transform Infrared (FT-IR) imaging is an emerging vibrational spectroscopic imaging technique, especially in a High-Definition (HD) format, that provides the spatial specificity of microscopy at magnifications used in diagnostic surgical pathology. While it has been shown for standard imaging that IR absorption by tissue creates a strong signal where the spectrum at each pixel is a quantitative "fingerprint" of the molecular composition of the sample, here we show that this fingerprint also enables direct digital pathology without the need for stains or dyes for HD imaging. An assessment of the potential of HD imaging to improve diagnostic pathology accuracy is presented.

Subaru Near Infrared Coronagraphic Images of T Tauri

NASA Astrophysics Data System (ADS)

Mayama, Satoshi; Tamura, Motohide; Hayashi, Masahiko; Itoh, Yoichi; Fukagawa, Misato; Suto, Hiroshi; Ishii, Miki; Murakawa, Koji; Oasa, Yumiko; Hayashi, Saeko S.; Yamashita, Takuya; Morino, Junichi; Oya, Shin; Naoi, Takahiro; Pyo, Tae-Soo; Nishikawa, Takayuki; Kudo, Tomoyuki; Usuda, Tomonori; Ando, Hiroyasu; Miyama, Shoken M.; Kaifu, Norio

2006-04-01

High angular resolution near-infrared (JHK) adaptive optics images of T Tau were obtained with the infrared camera Coronagraphic Imager with Adaptive Optics (CIAO) mounted on the 8.2m Subaru Telescope in 2002 and 2004. The images resolve a complex circumstellar structure around a multiple system. We resolved T Tau Sa and Sb as well as T Tau N and S. The estimated orbit of T Tau Sb indicates that it is probably bound to T Tau Sa. The K band flux of T Tau S decreased by ˜ 1.7 Jy in 2002 November compared with that in 2001 mainly because T Tau Sa became fainter. The arc-like ridge detected in our near-infrared images is consistent with what is seen at visible wavelengths, supporting the interpretation in previous studies that the arc is part of the cavity wall seen relatively pole-on. Halo emission is detected out to ˜2''from T Tau N. This may be light scattered off the common envelope surrounding the T Tauri multiple system.

Application of Near Infrared Reflectance Spectroscopy for Rapid and Non-Destructive Discrimination of Hulled Barley, Naked Barley, and Wheat Contaminated with Fusarium

PubMed Central

Lim, Jongguk; Kim, Giyoung; Mo, Changyeun; Oh, Kyoungmin; Kim, Geonseob; Ham, Hyeonheui; Kim, Seongmin; Kim, Moon S.

2018-01-01

Fusarium is a common fungal disease in grains that reduces the yield of barley and wheat. In this study, a near infrared reflectance spectroscopic technique was used with a statistical prediction model to rapidly and non-destructively discriminate grain samples contaminated with Fusarium. Reflectance spectra were acquired from hulled barley, naked barley, and wheat samples contaminated with Fusarium using near infrared reflectance (NIR) spectroscopy with a wavelength range of 1175–2170 nm. After measurement, the samples were cultured in a medium to discriminate contaminated samples. A partial least square discrimination analysis (PLS-DA) prediction model was developed using the acquired reflectance spectra and the culture results. The correct classification rate (CCR) of Fusarium for the hulled barley, naked barley, and wheat samples developed using raw spectra was 98% or higher. The accuracy of discrimination prediction improved when second and third-order derivative pretreatments were applied. The grains contaminated with Fusarium could be rapidly discriminated using spectroscopy technology and a PLS-DA discrimination model, and the potential of the non-destructive discrimination method could be verified. PMID:29301319

Discriminating oat and groat kernels from other grains using near infrared spectroscopy

USDA-ARS?s Scientific Manuscript database

Oat and groats can be discriminated from other grains such as barley, wheat, rye, and triticale (non-oats) using near infrared spectroscopy. The two instruments tested were the manual version of the ARS-USDA Single Kernel Near Infrared (SKNIR) and the automated QualySense QSorter Explorer high-speed...

Single Pixel Black Phosphorus Photodetector for Near-Infrared Imaging.

PubMed

Miao, Jinshui; Song, Bo; Xu, Zhihao; Cai, Le; Zhang, Suoming; Dong, Lixin; Wang, Chuan

2018-01-01

Infrared imaging systems have wide range of military or civil applications and 2D nanomaterials have recently emerged as potential sensing materials that may outperform conventional ones such as HgCdTe, InGaAs, and InSb. As an example, 2D black phosphorus (BP) thin film has a thickness-dependent direct bandgap with low shot noise and noncryogenic operation for visible to mid-infrared photodetection. In this paper, the use of a single-pixel photodetector made with few-layer BP thin film for near-infrared imaging applications is demonstrated. The imaging is achieved by combining the photodetector with a digital micromirror device to encode and subsequently reconstruct the image based on compressive sensing algorithm. Stationary images of a near-infrared laser spot (λ = 830 nm) with up to 64 × 64 pixels are captured using this single-pixel BP camera with 2000 times of measurements, which is only half of the total number of pixels. The imaging platform demonstrated in this work circumvents the grand challenges of scalable BP material growth for photodetector array fabrication and shows the efficacy of utilizing the outstanding performance of BP photodetector for future high-speed infrared camera applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

SPECTROSCOPIC INFRARED EXTINCTION MAPPING AS A PROBE OF GRAIN GROWTH IN IRDCs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lim, Wanggi; Carey, Sean J.; Tan, Jonathan C.

We present spectroscopic tests of MIR to FIR extinction laws in IRDC G028.36+00.07, a potential site of massive star and star cluster formation. Lim and Tan developed methods of FIR extinction mapping of this source using Spitzer-MIPS 24 μm and Herschel-PACS 70 μm images, and by comparing to MIR Spitzer-IRAC 3–8 μm extinction maps, found tentative evidence for grain growth in the highest mass surface density regions. Here we present results of spectroscopic infrared extinction mapping using Spitzer-IRS (14–38 μm) data of the same Infrared dark cloud (IRDC). These methods allow us to first measure the SED of the diffusemore » Galactic interstellar medium that is in the foreground of the IRDC. We then carry out our primary investigation of measuring the MIR to FIR opacity law and searching for potential variations as a function of mass surface density within the IRDC. We find relatively flat, featureless MIR–FIR opacity laws that lack the ∼12 and ∼35 μm features associated with the thick water ice mantle models of Ossenkopf and Henning. Their thin ice mantle models and the coagulating aggregate dust models of Ormel et al. are a generally better match to the observed opacity laws. We also find evidence for generally flatter MIR to FIR extinction laws as mass surface density increases, strengthening the evidence for grain and ice mantle growth in higher density regions.« less

Time-Resolved and Spectroscopic Three-Dimensional Optical Breast Tomography

DTIC Science & Technology

2009-03-01

polarization sensitive imaging 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT 18. NUMBER OF PAGES 19a. NAME OF RESPONSIBLE PERSON R. R...project; • Development of a near-infrared center of intensity time gated imaging approach; and • Polarization sensitive imaging. We provide an...spectroscopic imaging arrangement, and a multi-source illumination and multi- detector signal acquisition arrangement. 5 5.1.1. Time-resolved transillumination

Near-Infrared Scintillation of Liquid Argon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tilly, Elizabeth; Escobar, Carlos

2017-01-01

Liquid argon is well known to scintillate in the vacuum ultraviolet (VUV) range which is inherently difficult to detect. There has been recent evidence to suggest that it also emits near infrared (NIR) light. If this is the case, many large-scale time projection chambers and other similar detectors will be able to maximize light collection while minimizing cost. The goal of this project is to confirm and quantify this NIR emission. In order to accomplish this, an α-source was placed in a volume of highly purified liquid argon and observed using an infrared PMT with a filter excluding light withmore » wavelength <715 nm. Performing a simple counting experiment, there were indications of NIR scintillation. Further analysis is in progress.« less

Astronomical near-infrared echelle gratings

NASA Astrophysics Data System (ADS)

Hinkle, Kenneth H.; Joyce, Richard R.; Liang, Ming

2014-07-01

High-resolution near-infrared echelle spectrographs require coarse rulings in order to match the free spectral range to the detector size. Standard near-IR detector arrays typically are 2 K x 2 K or 4 K x 4 K. Detectors of this size combined with resolutions in the range 30000 to 100000 require grating groove spacings in the range 5 to 20 lines/mm. Moderately high blaze angles are desirable to reduce instrument size. Echelle gratings with these characteristics have potential wide application in both ambient temperature and cryogenic astronomical echelle spectrographs. We discuss optical designs for spectrographs employing immersed and reflective echelle gratings. The optical designs set constraints on grating characteristics. We report on market choices for obtaining these gratings and review our experiments with custom diamond turned rulings.

MIRIS observation of near-infrared diffuse Galactic light

NASA Astrophysics Data System (ADS)

Onishi, Yosuke; Sano, Kei; Matsuura, Shuji; Jeong, Woong-Seob; Pyo, Jeonghyun; Kim, Il-Jong; Seo, Hyun Jong; Han, Wonyong; Lee, DaeHee; Moon, Bongkon; Park, Wonkee; Park, Younsik; Kim, MinGyu; Matsumoto, Toshio; Matsuhara, Hideo; Nakagawa, Takao; Tsumura, Kohji; Shirahata, Mai; Arai, Toshiaki; Ienaka, Nobuyuki

2018-06-01

We report near-infrared (IR) observations of high Galactic latitude clouds to investigate diffuse Galactic light (DGL), which is starlight scattered by interstellar dust grains. The observations were performed at 1.1 and 1.6 μm with a wide-field camera instrument, the Multi-purpose Infra-Red Imaging System (MIRIS) onboard the Korean satellite STSAT-3. The DGL brightness is measured by correlating the near-IR images with a far-IR 100 μm map of interstellar dust thermal emission. The wide-field observation of DGL provides the most accurate DGL measurement achieved to-date. We also find a linear correlation between optical and near-IR DGL in the MBM32 field. To study interstellar dust properties in MBM32, we adopt recent dust models with and without μm-sized very large grains and predict the DGL spectra, taking into account the reddening effect of the interstellar radiation field. The result shows that the observed color of the near-IR DGL is closer to the model spectra without very large grains. This may imply that dust growth in the observed MBM32 field is not active owing to the low density of its interstellar medium.

Near-infrared light emitting device using semiconductor nanocrystals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Supran, Geoffrey J.S.; Song, Katherine W.; Hwang, Gyuweon

A near-infrared light emitting device can include semiconductor nanocrystals that emit at wavelengths beyond 1 .mu.m. The semiconductor nanocrystals can include a core and an overcoating on a surface of the core.

Near-infrared quantum dots for HER2 localization and imaging of cancer cells.

PubMed

Rizvi, Sarwat B; Rouhi, Sepideh; Taniguchi, Shohei; Yang, Shi Yu; Green, Mark; Keshtgar, Mo; Seifalian, Alexander M

2014-01-01

Quantum dots are fluorescent nanoparticles with unique photophysical properties that allow them to be used as diagnostic, therapeutic, and theranostic agents, particularly in medical and surgical oncology. Near-infrared-emitting quantum dots can be visualized in deep tissues because the biological window is transparent to these wavelengths. Their small sizes and free surface reactive groups that can be conjugated to biomolecules make them ideal probes for in vivo cancer localization, targeted chemotherapy, and image-guided cancer surgery. The human epidermal growth factor receptor 2 gene (HER2/neu) is overexpressed in 25%-30% of breast cancers. The current methods of detection for HER2 status, including immunohistochemistry and fluorescence in situ hybridization, are used ex vivo and cannot be used in vivo. In this paper, we demonstrate the application of near-infrared-emitting quantum dots for HER2 localization in fixed and live cancer cells as a first step prior to their in vivo application. Near-infrared-emitting quantum dots were characterized and their in vitro toxicity was established using three cancer cell lines, ie, HepG2, SK-BR-3 (HER2-overexpressing), and MCF7 (HER2-underexpressing). Mouse antihuman anti-HER2 monoclonal antibody was conjugated to the near-infrared-emitting quantum dots. In vitro toxicity studies showed biocompatibility of SK-BR-3 and MCF7 cell lines with near-infrared-emitting quantum dots at a concentration of 60 μg/mL after one hour and 24 hours of exposure. Near-infrared-emitting quantum dot antiHER2-antibody bioconjugates successfully localized HER2 receptors on SK-BR-3 cells. Near-infrared-emitting quantum dot bioconjugates can be used for rapid localization of HER2 receptors and can potentially be used for targeted therapy as well as image-guided surgery.

Crustal Zircons from the Podiform Chromitites in Luobusa Ophiolite, Tibet

NASA Astrophysics Data System (ADS)

Yamamoto, S.; Komiya, T.; Maruyama, S.

2004-12-01

For the past decade, diamonds and unusual mineral asemblages were reported in podiform chromitites of the Luobusa ophiolite, southern Tibet, China (Bai 1993, Bai 2000, Yan 2001) by heavy mineral separation. These include (1) native elements, (2) alloys, (3) carbide, (4) platinium group elements (PGE) and arsenides, (5) silicates (6) oxide, (7) carbonates, (8) minerals with unusual compositons. Despite many questions as to these minerals above still remain open, these mineral inclusions would provide us the important infomation on the formation of the podiform chromitites. In this study, over 100 zircons were discovered by heavy mineral separation of podiform chromitite in Luobusa ophiolite. The discovery of accessory zircons in chromitites allowed us to date the formation of the chromitite and history of tectonic evolutions. Here we report the U-Pb age and mineral inclusions of zircons and discuss with unusually old age zircons. 20 zircon grains in chromitites from No. 1 site were analyzed. Zircons from the chromitites in Luobusa ophiolite are usually euhedral-subhedral and some are rounded. Cathodoluminescence images of these zircons indicate that some zircons have clear oscillatory zoning, whereas other zircons show apparent homogeneous overgrowth. U-Pb dating of these zircons by LA-ICP-MS yielded two different ages. One group has relatively younger age, 107-534Ma, which plots nearly on a concordia line. Another group has older age 1460-1822Ma, which plots off the concordia line. There is insignificant difference of apparent ages within a single zircon grain. For example, a zircon has 1650 Ma in the core, whereas does 1654 Ma in the rim. We identified several mineral inclusions, quartz, feldspar, mica, apatite, within both yonger and older zircons using laser-Raman spectrometry and EPMA. No high-pressure minerals or mantle minerals were identified. This means that these unusually old zircons were formed in low-pressure crustal emvironment. Where did the zircons

Probing Reionization at z≥7 with HST's Near-Infrared Grisms

NASA Astrophysics Data System (ADS)

Borello Schmidt, Kasper

2015-08-01

The epoch of reionization, i.e. the transition of the IGM from neutral to fully ionized, is essential for our understanding of the evolution of the Universe and the formation of the first stars and galaxies. The first results at z≤ 7 suggest that the reionization happened in a patchy, rather than smooth, fashion. It is still unclear whether galaxies at z≥7 prefer a patchy reionization scenario as well. The Grism Lens-Amplified Survey from Space (GLASS) has obtained spectra of ten thousands of objects in and behind 10 massive galaxy clusters, including the six Hubble Frontier Fields. Coaming the Hubble grism spectroscopy from GLASS results in 100s of spectra of z≥7 galaxy candidates. Taking advantage of the lensing magnification from the foreground clusters, the GLASS spectra reaches unprecedented depths in the near-infrared with flux limits below 10-18 erg/s/cm2. This has resulted in several Lyα detections at z˜7, tight limits on the emission line fluxes for non-detections, and the equivalent width distribution of Lyα in the very earlier Universe. Taking advantage of the extensive spectroscopic samples of z≥7 galaxies from GLASS, I will show how these samples can give us and unprecedented view of the cosmic reionization at z≥7.

Paragneiss zircon geochronology and trace element geochemistry, North Qaidam HP/UHP terrane, western China

USGS Publications Warehouse

Mattinson, C.G.; Wooden, J.L.; Zhang, J.X.; Bird, D.K.

2009-01-01

In the southeastern part of the North Qaidam terrane, near Dulan, paragneiss hosts minor peridotite and UHP eclogite. Zircon geochronology and trace element geochemistry of three paragneiss samples (located within a ???3 km transect) indicates that eclogite-facies metamorphism resulted in variable degrees of zircon growth and recrystallization in the three samples. Inherited zircon core age groups at 1.8 and 2.5 Ga suggest that the protoliths of these rocks may have received sediments from the Yangtze or North China cratons. Mineral inclusions, depletion in HREE, and absence of negative Eu anomalies indicate that zircon U-Pb ages of 431 ?? 5 Ma and 426 ?? 4 Ma reflect eclogite-facies zircon growth in two of the samples. Ti-in-zircon thermometry results are tightly grouped at ???660 and ???600 ??C, respectively. Inclusions of metamorphic minerals, scarcity of inherited cores, and lack of isotopic or trace element inheritance demonstrate that significant new metamorphic zircon growth must have occurred. In contrast, zircon in the third sample is dominated by inherited grains, and rims show isotopic and trace element inheritance, suggesting solid-state recrystallization of detrital zircon with only minor new growth. ?? 2009 Elsevier Ltd.

Reliability of Near-Infrared Spectroscopy for Determining Muscle Oxygen Saturation during Exercise

ERIC Educational Resources Information Center

Austin, Krista G.; Daigle, Karen A.; Patterson, Patricia; Cowman, Jason; Chelland, Sara; Haymes, Emily M.

2005-01-01

Near-infrared spectroscopy is currently used to assess changes in the oxygen saturation of the muscle during exercise. The primary purpose of this study was to assess the reliability of near-infrared spectroscopy in determining muscle oxygen saturation (StO[subscript 2]) in the vastus lateralis during cycling and the gastrocnemius during running…

Graphene-enhanced infrared near-field microscopy.

PubMed

Li, Peining; Wang, Tao; Böckmann, Hannes; Taubner, Thomas

2014-08-13

Graphene is a promising two-dimensional platform for widespread nanophotonic applications. Recent theories have predicted that graphene can also enhance evanescent fields for subdiffraction-limited imaging. Here, for the first time we experimentally demonstrate that monolayer graphene offers a 7-fold enhancement of evanescent information, improving conventional infrared near-field microscopy to resolve buried structures at a 500 nm depth with λ/11-resolution.

MID-INFRARED SPECTROSCOPIC OBSERVATIONS OF THE DUST-FORMING CLASSICAL NOVA V2676 OPH

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kawakita, Hideyo; Arai, Akira; Shinnaka, Yoshiharu

2017-02-01

The dust-forming nova V2676 Oph is unique in that it was the first nova to provide evidence of C{sub 2} and CN molecules during its near-maximum phase and evidence of CO molecules during its early decline phase. Observations of this nova have revealed the slow evolution of its lightcurves and have also shown low isotopic ratios of carbon ({sup 12}C/{sup 13}C) and nitrogen ({sup 14}N/{sup 15}N) in its envelope. These behaviors indicate that the white dwarf (WD) star hosting V2676 Oph is a CO-rich WD rather than an ONe-rich WD (typically larger in mass than the former). We performed mid-infraredmore » spectroscopic and photometric observations of V2676 Oph in 2013 and 2014 (respectively 452 and 782 days after its discovery). No significant [Ne ii] emission at 12.8 μ m was detected at either epoch. These provided evidence for a CO-rich WD star hosting V2676 Oph. Both carbon-rich and oxygen-rich grains were detected in addition to an unidentified infrared feature at 11.4 μ m originating from polycyclic aromatic hydrocarbon molecules or hydrogenated amorphous carbon grains in the envelope of V2676 Oph.« less

High-Resolution Infrared Spectroscopic Measurements of Comet 2PlEncke: Unusual Organic Composition and Low Rotational Temperatures

NASA Technical Reports Server (NTRS)

Radeva, Yana L.; Mumma, Michael J.; Villanueva, Geronimo L.; Bonev, Boncho P.; DiSanti, Michael A.; A'Hearn, Michael F.; Dello Russo, Neil

2013-01-01

We present high-resolution infrared spectroscopic measurements of the ecliptic comet 2P/Encke, observed on 4-6 Nov. 2003 during its close approach to the Earth, using the Near Infrared Echelle Spectrograph on the Keck II telescope. We present flux-calibrated spectra, production rates, and mixing ratios for H2O, CH3OH, HCN, H2CO, C2H2, C2H6, CH4 and CO. Comet 2P/Encke is a dynamical end-member among comets because of its short period of 3.3 years. Relative to "organics-normal" comets, we determined that 2PlEncke is depleted in HCN, H2CO, C2H2, C2H6, CH4 and CO, but it is enriched in CH3OH. We compared mixing ratios of these organic species measured on separate dates, and we see no evidence of macroscopic chemical heterogeneity in the nucleus of 2P/Encke, however, this conclusion is limited by sparse temporal sampling. The depleted abundances of most measured species suggest that 2P/Encke may have formed closer to the young Sun, before its insertion to the Kuiper belt, compared with "organics-normal" comets - as was previously suggested for other depleted comets (e.g. C/1999 S4 (LINEAR)). We measured very low rotational temperatures of 20 - 30 K for H2O, CH3OH and HCN in the near nucleus region of 2P/Encke, which correlate with one of the lowest cometary gas production rates (approx. 2.6 x 10(exp 27) molecules/s) measured thus far in the infrared. This suggests that we are seeing the effects of more efficient radiative cooling, insufficient collisional excitation, and/or inefficient heating by fast H-atoms (and icy grains) in the observed region of the coma. Its extremely short orbital period, very low gas production rate, and classification as an ecliptic comet, make 2PlEncke an important addition to our growing database, and contribute significantly to the establishment of a chemical taxonomy of comets.

THE VARIABLE NEAR-INFRARED COUNTERPART OF THE MICROQUASAR GRS 1758–258

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luque-Escamilla, Pedro L.; Martí, Josep; Muñoz-Arjonilla, Álvaro J., E-mail: peter@ujaen.es, E-mail: jmarti@ujaen.es, E-mail: ajmunoz@ujaen.es

2014-12-10

We present a new study of the microquasar system GRS 1758–258 in the near-infrared domain based on archival observations with the Hubble Space Telescope and the NICMOS camera. In addition to confirming the near-infrared counterpart pointed out by Muñoz-Arjonilla et al., we show that this object displays significant photometric variability. From its average magnitudes, we also find that GRS 1758–258 fits well within the correlation between the optical/near-infrared and X-ray luminosity known to exist for low-mass, black-hole candidate X-ray binaries in a hard state. Moreover, the spectral energy distribution built using all radio, near-infrared, and X-ray data available closest inmore » time to the NICMOS observations can be reasonably interpreted in terms of a self-absorbed radio jet and an irradiated accretion disk model around a stellar-mass black hole. All these facts match the expected behavior of a compact binary system and strengthen our confidence in the counterpart identification.« less

Twinning in Zircon: Not a High-Pressure Phenomenon

NASA Astrophysics Data System (ADS)

Jones, G. A.; Moser, D.; Shieh, S. R.; Barker, I.

2017-12-01

Microtwins in zircon are commonly found in shocked terrestrial and extraterrestrial samples and are potentially important for shock history and crater reconstruction. Twinning is easily observed with both the optical microscope and variety of electron beam techniques. Twinning as a deformation mechanism is consistent with the high strain rates generated during impact. No constitutive relationships, or even general limits on the physical conditions required for twinning in zircon are known, however. Present speculation on the critical quantity for twin formation, i.e. 10s of GPa of shock pressure (Moser et al. 2011, Timms et al., 2012), has no basis in the underlying mechanisms of twin nucleation, which are related to the motion of dislocations. This erroneous value is due to conflation of twinning sensu stricto with a phase transformation to reidite. Reidite occurs as twin-like lamellae occupying the {112} planes which are thought to be a mirror plane for twinning. We review the crystallographic theory of twinning in zircon. We then evaulate several theories on the nucleation of twins along with their necessary stresses involved. Our aim is to show that shock microtwins in zircon can be a `low pressure' shock phenomenon. This 'low pressure' hypothesis is supported by natural samples. These zircons are from the lower crust nearly 80 km from the centre of the Vredefort impact structure—the most distal zircon shock microstructures yet found in the lithosphere. Twins are present in 10% of the zircon grains greater than 50 µm in diameter. As an extensive, 'low pressure' phenomenon, twins are an easily recognized and potentially widespread record of Earth's impact history.Moser, D.E., Cupelli, C. L., Barker, I., Flowers, R. M., Mowman, J. R., Wooden, J. and Hart, R. (2011) New zircon shock phenomena and their use for dating and […] analysis of the Vredefort dome, Canadian Journal of Earth Sciences 48(2), 117-139.Timms, N.E., Reddy, S. M., Healy, D., Nemchin, A. A

Wind diagnostics and correlations with the near-infrared excess in Herbig Ae/Be stars

NASA Astrophysics Data System (ADS)

Corcoran, M.; Ray, T. P.

1998-03-01

Intermediate dispersion spectroscopic observations of 37 Herbig Ae/Be stars reveal that the equivalent widths of their [OI]lambda 6300 and Hα emission lines, are related to their near-infrared colours in the same fashion as the T-Tauri stars. Such a correlation strongly supports the idea that the winds from Herbig Ae/Be stars arise in the same manner as those from T-Tauri stars, i.e. through accretion driven mass-loss. We also find that the [OI]lambda 6300 line luminosity correlates better with excess infrared luminosity than with stellar luminosities, again supporting the idea that Herbig Ae/Be winds are accretion driven. If one includes the lower mass analogues of the Herbig Ae/Be stars with forbidden line emission, i.e. the classical T-Tauri stars, the correlation between mass-loss rate and infrared excess spans 5 orders of magnitude in luminosity and a range of masses from 0.5Msun to approximately 10Msun. Our observations therefore extend the findings of Cohen et al. (1989) and Cabrit et al. (1990) for low mass young stars and, taken in conjunction with other evidence (Corcoran & Ray 1997), strongly support the presence of circumstellar disks around intermediate mass stars with forbidden line emission. An implication of our findings is that the same outflow model must be applicable to these Herbig Ae/Be stars and the classical T Tauri stars. Based on observations made at the La Palma Observatory, the Caltech Submillimeter Observatory, and the European Southern Observatory/Max Planck Institute 2.2m Telescope.

Comparison of spatial variability in visible and near-infrared spectral images

USGS Publications Warehouse

Chavez, P.S.

1992-01-01

The visible and near-infrared bands of the Landsat Thematic Mapper (TM) and the Satellite Pour l'Observation de la Terre (SPOT) were analyzed to determine which band contained more spatial variability. It is important for applications that require spatial information, such as those dealing with mapping linear features and automatic image-to-image correlation, to know which spectral band image should be used. Statistical and visual analyses were used in the project. The amount of variance in an 11 by 11 pixel spatial filter and in the first difference at the six spacings of 1, 5, 11, 23, 47, and 95 pixels was computed for the visible and near-infrared bands. The results indicate that the near-infrared band has more spatial variability than the visible band, especially in images covering densely vegetated areas. -Author

Near-infrared fundus autofluorescence in subclinical best vitelliform macular dystrophy.

PubMed

Parodi, Maurizio Battaglia; Iacono, Pierluigi; Del Turco, Claudia; Bandello, Francesco

2014-12-01

To describe fundus autofluorescence (FAF) on short-wavelength FAF and near-infrared FAF in the subclinical form of Best vitelliform macular dystrophy. Cross-sectional prospective study. Patients affected by the subclinical form of Best vitelliform macular dystrophy (positive testing for BEST1 gene mutation, fully preserved best-corrected visual acuity, normal fundus appearance) were recruited. Each patient underwent a complete ophthalmologic examination, including electro-oculogram (EOG), short-wavelength FAF, near-infrared FAF, spectral-domain OCT (SD OCT), and microperimetry. Main outcome measure was the identification of abnormal FAF patterns. Forty-six patients showing mutations in the BEST1 gene were examined. Forty patients presented a bilateral Best vitelliform macular dystrophy, 2 patients showed a unilateral Best vitelliform macular dystrophy, and 4 patients had a bilateral subclinical form. Patients with the unilateral form (2 eyes) and patients with the subclinical form (8 eyes) were analyzed. Three BEST1 sequence variants were identified: c.73C>T (p.Arg25Trp), c.28G>A (p.Ala10Thr), and c.652C>G (p.Arg218Gly). Short-wavelength FAF was normal in all eyes. Near-infrared FAF detected a pattern consisting of a central hypo-autofluorescence surrounded by a round area of hyper-autofluorescence. A bilateral reduced EOG response was detected in 1 patient. SD OCT revealed a thicker, well-defined, and more reflective interdigitation zone in 2 patients (4 eyes, 40%). Microperimetry of the central 10 degrees revealed a slight, diffuse reduction of retinal sensitivity. Mean retinal sensitivity within the central 2 and 4 degrees was lower and matched the hypo-autofluorescent area detected on near-infrared FAF. Additional relative scotomata were detected within the 10-degree area. No change in clinical, functional, or FAF pattern was found over the follow-up. Subclinical Best vitelliform macular dystrophy is characterized by the absence of biomicroscopic fundus

Up-regulation of cerebral cytochrome-c-oxidase and hemodynamics by transcranial infrared laser stimulation: A broadband near-infrared spectroscopy study.

PubMed

Wang, Xinlong; Tian, Fenghua; Reddy, Divya D; Nalawade, Sahil S; Barrett, Douglas W; Gonzalez-Lima, Francisco; Liu, Hanli

2017-12-01

Transcranial infrared laser stimulation (TILS) is a noninvasive form of brain photobiomulation. Cytochrome-c-oxidase (CCO), the terminal enzyme in the mitochondrial electron transport chain, is hypothesized to be the primary intracellular photoacceptor. We hypothesized that TILS up-regulates cerebral CCO and causes hemodynamic changes. We delivered 1064-nm laser stimulation to the forehead of healthy participants ( n = 11), while broadband near-infrared spectroscopy was utilized to acquire light reflectance from the TILS-treated cortical region before, during, and after TILS. Placebo experiments were also performed for accurate comparison. Time course of spectroscopic readings were analyzed and fitted to the modified Beer-Lambert law. With respect to the placebo readings, we observed (1) significant increases in cerebral concentrations of oxidized CCO (Δ[CCO]; >0.08 µM; p < 0.01), oxygenated hemoglobin (Δ[HbO]; >0.8 µM; p < 0.01), and total hemoglobin (Δ[HbT]; >0.5 µM; p < 0.01) during and after TILS, and (2) linear interplays between Δ[CCO] versus Δ[HbO] and between Δ[CCO] versus Δ[HbT]. Ratios of Δ[CCO]/Δ[HbO] and Δ[CCO]/Δ[HbT] were introduced as TILS-induced metabolic-hemodynamic coupling indices to quantify the coupling strength between TILS-enhanced cerebral metabolism and blood oxygen supply. This study provides the first demonstration that TILS causes up-regulation of oxidized CCO in the human brain, and contributes important insight into the physiological mechanisms.

All-photonic drying and sintering process via flash white light combined with deep-UV and near-infrared irradiation for highly conductive copper nano-ink

PubMed Central

Hwang, Hyun-Jun; Oh, Kyung-Hwan; Kim, Hak-Sung

2016-01-01

We developed an ultra-high speed photonic sintering method involving flash white light (FWL) combined with near infrared (NIR) and deep UV light irradiation to produce highly conductive copper nano-ink film. Flash white light irradiation energy and the power of NIR/deep UV were optimized to obtain high conductivity Cu films. Several microscopic and spectroscopic characterization techniques such as scanning electron microscopy (SEM), a x-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectroscopy were employed to characterize the Cu nano-films. Optimally sintered Cu nano-ink films produced using a deep UV-assisted flash white light sintering technique had the lowest resistivity (7.62 μΩ·cm), which was only 4.5-fold higher than that of bulk Cu film (1.68 μΩ•cm). PMID:26806215

All-photonic drying and sintering process via flash white light combined with deep-UV and near-infrared irradiation for highly conductive copper nano-ink.

PubMed

Hwang, Hyun-Jun; Oh, Kyung-Hwan; Kim, Hak-Sung

2016-01-25

We developed an ultra-high speed photonic sintering method involving flash white light (FWL) combined with near infrared (NIR) and deep UV light irradiation to produce highly conductive copper nano-ink film. Flash white light irradiation energy and the power of NIR/deep UV were optimized to obtain high conductivity Cu films. Several microscopic and spectroscopic characterization techniques such as scanning electron microscopy (SEM), a x-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectroscopy were employed to characterize the Cu nano-films. Optimally sintered Cu nano-ink films produced using a deep UV-assisted flash white light sintering technique had the lowest resistivity (7.62 μΩ·cm), which was only 4.5-fold higher than that of bulk Cu film (1.68 μΩ•cm).

First light observations with TIFR Near Infrared Imaging Camera (TIRCAM-II)

NASA Astrophysics Data System (ADS)

Ojha, D. K.; Ghosh, S. K.; D'Costa, S. L. A.; Naik, M. B.; Sandimani, P. R.; Poojary, S. S.; Bhagat, S. B.; Jadhav, R. B.; Meshram, G. S.; Bakalkar, C. B.; Ramaprakash, A. N.; Mohan, V.; Joshi, J.

TIFR near infrared imaging camera (TIRCAM-II) is based on the Aladdin III Quadrant InSb focal plane array (512×512 pixels; 27.6 μm pixel size; sensitive between 1 - 5.5 μm). TIRCAM-II had its first engineering run with the 2 m IUCAA telescope at Girawali during February - March 2011. The first light observations with TIRCAM-II were quite successful. Several infrared standard with TIRCAM-II were quite successful. Several infrared standard stars, the Trapezium Cluster in Orion region, McNeil's nebula, etc., were observed in the J, K and in a narrow-band at 3.6 μm (nbL). In the nbL band, some bright stars could be detected from the Girawali site. The performance of TIRCAM-II is discussed in the light of preliminary observations in near infrared bands.

Enhanced visible and near-infrared capabilities of the JET mirror-linked divertor spectroscopy system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lomanowski, B. A., E-mail: b.a.lomanowski@durham.ac.uk; Sharples, R. M.; Meigs, A. G.

2014-11-15

The mirror-linked divertor spectroscopy diagnostic on JET has been upgraded with a new visible and near-infrared grating and filtered spectroscopy system. New capabilities include extended near-infrared coverage up to 1875 nm, capturing the hydrogen Paschen series, as well as a 2 kHz frame rate filtered imaging camera system for fast measurements of impurity (Be II) and deuterium Dα, Dβ, Dγ line emission in the outer divertor. The expanded system provides unique capabilities for studying spatially resolved divertor plasma dynamics at near-ELM resolved timescales as well as a test bed for feasibility assessment of near-infrared spectroscopy.

Use of Advanced Spectroscopic Techniques for Predicting the Mechanical Properties of Wood Composites

Treesearch

Timothy G. Rials; Stephen S. Kelley; Chi-Leung So

2002-01-01

Near infrared (NIR) spectroscopy was used to characterize a set of medium-density fiberboard (MDF) samples. This spectroscopic technique, in combination with projection to latent structures (PLS) modeling, effectively predicted the mechanical strength of MDF samples with a wide range of physical properties. The stiffness, strength, and internal bond properties of the...

Near-infrared light absorption by brown carbon in the ambient atmosphere

NASA Astrophysics Data System (ADS)

Chung, C.; Hoffer, A.; Beres, N. D.; Moosmüller, H.; Liu, C.; Green, M.; Kim, S. W.; Engelbrecht, J. P.; Gelencser, A.

2017-12-01

Organic aerosols have been assumed to have little-to-no absorption in the red and near-infrared spectral regions of solar radiation, even though a class of organic aerosols were shown to absorb significantly in these spectral regions. Here, we show that ambient atmospheric data from commonly-used 7-wavelength aethalometers contain evidence of abundant near-infrared light absorption by organic aerosol. This evidence comes from the absorption Ångström exponent over 880 950 nm, which often exceeds values explainable by fresh or coated black carbon, or mineral dust. This evidence is not due to an artifact from the instrument random errors or biases, either. The best explanation for these large 880/950 nm absorption Ångström exponent values in the aethalometer data is near-infrared light absorption by tar balls. Tar balls are among common particles from forest fire.

[Near infrared spectroscopy study on water content in turbine oil].

PubMed

Chen, Bin; Liu, Ge; Zhang, Xian-Ming

2013-11-01

Near infrared (NIR) spectroscopy combined with successive projections algorithm (SPA) was investigated for determination of water content in turbine oil. Through the 57 samples of different water content in turbine oil scanned applying near infrared (NIR) spectroscopy, with the water content in the turbine oil of 0-0.156%, different pretreatment methods such as the original spectra, first derivative spectra and differential polynomial least squares fitting algorithm Savitzky-Golay (SG), and successive projections algorithm (SPA) were applied for the extraction of effective wavelengths, the correlation coefficient (R) and root mean square error (RMSE) were used as the model evaluation indices, accordingly water content in turbine oil was investigated. The results indicated that the original spectra with different water content in turbine oil were pretreated by the performance of first derivative + SG pretreatments, then the selected effective wavelengths were used as the inputs of least square support vector machine (LS-SVM). A total of 16 variables selected by SPA were employed to construct the model of SPA and least square support vector machine (SPA-LS-SVM). There is 9 as The correlation coefficient was 0.975 9 and the root of mean square error of validation set was 2.655 8 x 10(-3) using the model, and it is feasible to determine the water content in oil using near infrared spectroscopy and SPA-LS-SVM, and an excellent prediction precision was obtained. This study supplied a new and alternative approach to the further application of near infrared spectroscopy in on-line monitoring of contamination such as water content in oil.

[Rapid determination of fatty acids in soybean oils by transmission reflection-near infrared spectroscopy].

PubMed

Song, Tao; Zhang, Feng-ping; Liu, Yao-min; Wu, Zong-wen; Suo, You-rui

2012-08-01

In the present research, a novel method was established for determination of five fatty acids in soybean oil by transmission reflection-near infrared spectroscopy. The optimum conditions of mathematics model of five components (C16:0, C18:0, C18:1, C18:2 and C18:3) were studied, including the sample set selection, chemical value analysis, the detection methods and condition. Chemical value was analyzed by gas chromatography. One hundred fifty eight samples were selected, 138 for modeling set, 10 for testing set and 10 for unknown sample set. All samples were placed in sample pools and scanned by transmission reflection-near infrared spectrum after sonicleaning for 10 minute. The 1100-2500 nm spectral region was analyzed. The acquisition interval was 2 nm. Modified partial least square method was chosen for calibration mode creating. Result demonstrated that the 1-VR of five fatty acids between the reference value of the modeling sample set and the near infrared spectrum predictive value were 0.8839, 0.5830, 0.9001, 0.9776 and 0.9596, respectively. And the SECV of five fatty acids between the reference value of the modeling sample set and the near infrared spectrum predictive value were 0.42, 0.29, 0.83, 0.46 and 0.21, respectively. The standard error of the calibration (SECV) of five fatty acids between the reference value of testing sample set and the near infrared spectrum predictive value were 0.891, 0.790, 0.900, 0.976 and 0.942, respectively. It was proved that the near infrared spectrum predictive value was linear with chemical value and the mathematical model established for fatty acids of soybean oil was feasible. For validation, 10 unknown samples were selected for analysis by near infrared spectrum. The result demonstrated that the relative standard deviation between predict value and chemical value was less than 5.50%. That was to say that transmission reflection-near infrared spectroscopy had a good veracity in analysis of fatty acids of soybean oil.

Ischemic stroke assessment with near-infrared spectroscopy

NASA Astrophysics Data System (ADS)

Chen, Weiguo; Li, Pengcheng; Zeng, Shaoqun; Luo, Qingming; Hu, Bo

1999-09-01

Many authors have elucidated the theory about oxygenated hemoglobin, deoxygenated hemoglobin absorption in near-infrared spectrum. And the theory has opened a window to measure the hemodynamic changes caused by stroke. However, no proper animal model still has established to confirm the theory. The aim of this study was to validate near-infrared cerebral topography (NCT) as a practical tool and to try to trace the focal hemodynamic changes of ischemic stroke. In the present study, middle cerebral artery occlusion model and the photosensitizer induced intracranial infarct model had been established. NCT and functional magnetic resonance image (fMRI) were obtained during pre- and post-operation. The geometric shape and infarct area of NCT image was compared with the fMRI images and anatomical samples of each rat. The results of two occlusion models in different intervene factors showed the NCT for infarct focus matched well with fMRI and anatomic sample of each rats. The instrument might become a practical tool for short-term prediction of stroke and predicting the rehabilitation after stroke in real time.

Near infrared cavity enhanced absorption spectra of atmospherically relevant ether-1, 4-Dioxane.

PubMed

Chandran, Satheesh; Varma, Ravi

2016-01-15

1, 4-Dioxane (DX) is a commonly found ether in industrially polluted atmosphere. The near infrared absorption spectra of this compound has been recorded in the region 5900-8230 cm(-1) with a resolution of 0.08 cm(-1) using a novel Fourier transform incoherent broadband cavity-enhanced absorption spectrometer (FT-IBBCEAS). All recorded spectra were found to contain regions that are only weakly perturbed. The possible combinations of fundamental modes and their overtone bands corresponding to selected regions in the measured spectra are tabulated. Two interesting spectral regions were identified as 5900-6400 cm(-1) and 8100-8230 cm(-1). No significant spectral interference due to presence of water vapor was observed suggesting the suitability of these spectral signatures for spectroscopic in situ detection of DX. The technique employed here is much more sensitive than standard Fourier transform spectrometer measurements on account of long effective path length achieved. Hence significant enhancement of weaker absorption lines above the noise level was observed as demonstrated by comparison with an available measurement from database. Copyright © 2015 Elsevier B.V. All rights reserved.

Generalized Beer-Lambert model for near-infrared light propagation in thick biological tissues

NASA Astrophysics Data System (ADS)

Bhatt, Manish; Ayyalasomayajula, Kalyan R.; Yalavarthy, Phaneendra K.

2016-07-01

The attenuation of near-infrared (NIR) light intensity as it propagates in a turbid medium like biological tissue is described by modified the Beer-Lambert law (MBLL). The MBLL is generally used to quantify the changes in tissue chromophore concentrations for NIR spectroscopic data analysis. Even though MBLL is effective in terms of providing qualitative comparison, it suffers from its applicability across tissue types and tissue dimensions. In this work, we introduce Lambert-W function-based modeling for light propagation in biological tissues, which is a generalized version of the Beer-Lambert model. The proposed modeling provides parametrization of tissue properties, which includes two attenuation coefficients μ0 and η. We validated our model against the Monte Carlo simulation, which is the gold standard for modeling NIR light propagation in biological tissue. We included numerous human and animal tissues to validate the proposed empirical model, including an inhomogeneous adult human head model. The proposed model, which has a closed form (analytical), is first of its kind in providing accurate modeling of NIR light propagation in biological tissues.

Correction of Near-infrared High-resolution Spectra for Telluric Absorption at 0.90–1.35 μm

NASA Astrophysics Data System (ADS)

Sameshima, Hiroaki; Matsunaga, Noriyuki; Kobayashi, Naoto; Kawakita, Hideyo; Hamano, Satoshi; Ikeda, Yuji; Kondo, Sohei; Fukue, Kei; Taniguchi, Daisuke; Mizumoto, Misaki; Arai, Akira; Otsubo, Shogo; Takenaka, Keiichi; Watase, Ayaka; Asano, Akira; Yasui, Chikako; Izumi, Natsuko; Yoshikawa, Tomohiro

2018-07-01

We report a method of correcting a near-infrared (0.90–1.35 μm) high-resolution (λ/Δλ ∼ 28,000) spectrum for telluric absorption using the corresponding spectrum of a telluric standard star. The proposed method uses an A0 V star or its analog as a standard star from which on the order of 100 intrinsic stellar lines are carefully removed with the help of a reference synthetic telluric spectrum. We find that this method can also be applied to feature-rich objects having spectra with heavily blended intrinsic stellar and telluric lines and present an application to a G-type giant using this approach. We also develop a new diagnostic method for evaluating the accuracy of telluric correction and use it to demonstrate that our method achieves an accuracy better than 2% for spectral parts for which the atmospheric transmittance is as low as ∼20% if telluric standard stars are observed under the following conditions: (1) the difference in airmass between the target and the standard is ≲ 0.05; and (2) that in time is less than 1 hr. In particular, the time variability of water vapor has a large impact on the accuracy of telluric correction and minimizing the difference in time from that of the telluric standard star is important especially in near-infrared high-resolution spectroscopic observation.

[A digital micromirror device-based Hadamard transform near infrared spectrometer].

PubMed

Liu, Jia; Chen, Fen-Fei; Liao, Cheng-Sheng; Xu, Qian; Zeng, Li-Bo; Wu, Qiong-Shui

2011-10-01

A Hadamard transform near infrared spectrometer based on a digital micromirror device was constructed. The optical signal was collected by optical fiber, a grating was used for light diffraction, a digital micromirror device (DMD) was applied instead of traditional mechanical Hadamard masks for optical modulation, and an InGaAs near infrared detector was used as the optic sensor. The original spectrum was recovered by fast Hadamard transform algrithms. The advantages of the spectrometer, such as high resolution, signal-noise-ratio, stability, sensitivity and response speed were proved by experiments, which indicated that it is very suitable for oil and food-safety applications.

Nanoscale infrared absorption spectroscopy of individual nanoparticles enabled by scattering-type near-field microscopy.

PubMed

Stiegler, Johannes M; Abate, Yohannes; Cvitkovic, Antonija; Romanyuk, Yaroslav E; Huber, Andreas J; Leone, Stephen R; Hillenbrand, Rainer

2011-08-23

Infrared absorption spectroscopy is a powerful and widely used tool for analyzing the chemical composition and structure of materials. Because of the diffraction limit, however, it cannot be applied for studying individual nanostructures. Here we demonstrate that the phase contrast in substrate-enhanced scattering-type scanning near-field optical microscopy (s-SNOM) provides a map of the infrared absorption spectrum of individual nanoparticles with nanometer-scale spatial resolution. We succeeded in the chemical identification of silicon nitride nanoislands with heights well below 10 nm, by infrared near-field fingerprint spectroscopy of the Si-N stretching bond. Employing a novel theoretical model, we show that the near-field phase spectra of small particles correlate well with their far-field absorption spectra. On the other hand, the spectral near-field contrast does not scale with the volume of the particles. We find a nearly linear scaling law, which we can attribute to the near-field coupling between the near-field probe and the substrate. Our results provide fundamental insights into the spectral near-field contrast of nanoparticles and clearly demonstrate the capability of s-SNOM for nanoscale chemical mapping based on local infrared absorption. © 2011 American Chemical Society

[Design of flat field holographic concave grating for near-infrared spectrophotometer].

PubMed

Xiang, Xian-Yi; Wen, Zhi-Yu

2008-07-01

Near-infrared spectrum analysis can be used to determine the nature or test quantitatively some chemical compositions by detecting molecular double frequency and multiple frequency absorption. It has been used in agriculture, biology, petrifaction, foodstuff, medicament, spinning and other fields. Near-infrared spectrophotometer is the main apparatus for near-infrared spectrum analysis, and the grating is the most important part of the apparatus. Based on holographic concave grating theory and optic design software CODE V, a flat field holographic concave grating for near-infrared spectrophotometer was designed from primary structure, which relied on global optimization of the software. The contradiction between wide spectrum bound and limited spectrum extension was resolved, aberrations were reduced successfully, spectrum information was utilized fully, and the optic structure of spectrometer was highly efficient. Using CODE V software, complex high-order aberration equations need not be solved, the result can be evaluated quickly, flat field and resolving power can be kept in balance, and the work efficiency is also enhanced. A paradigm of flat field holographic concave grating is given, it works between 900 nm to 1 700 nm, the diameter of the concave grating is 25 mm, and F/ # is 1. 5. The design result was analyzed and evaluated. It was showed that if the slit source, whose width is 50 microm, is used to reconstruction, the theoretic resolution capacity is better than 6.3 nm.

Silicon based near infrared photodetector using self-assembled organic crystalline nano-pillars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ajiki, Yoshiharu, E-mail: yoshiharu-ajiki@ot.olympus.co.jp, E-mail: isao@i.u-tokyo.ac.jp; Kan, Tetsuo; Yahiro, Masayuki

We propose a silicon (Si) based near-infrared photodetector using self-assembled organic crystalline nano-pillars, which were formed on an n-type Si substrate and were covered with an Au thin-film. These structures act as antennas for near-infrared light, resulting in an enhancement of the light absorption on the Au film. Because the Schottky junction is formed between the Au/n-type Si, the electron excited by the absorbed light can be detected as photocurrent. The optical measurement revealed that the nano-pillar structures enhanced the responsivity for the near-infrared light by 89 (14.5 mA/W) and 16 (0.433 mA/W) times compared with those of the photodetector without nano-pillarsmore » at the wavelengths of 1.2 and 1.3 μm, respectively. Moreover, no polarization dependency of the responsivity was observed, and the acceptable incident angle ranged from 0° to 30°. These broad responses were likely to be due to the organic nano-pillar structures' having variation in their orientation, which is advantageous for near-infrared detector uses.« less

Hydrolysis of Baltic amber during thermal ageing--an infrared spectroscopic approach.

PubMed

Pastorelli, Gianluca; Shashoua, Yvonne; Richter, Jane

2013-04-01

To enable conservation of amber in museums, understanding of chemical changes is crucial. While oxidation has been investigated particularly well for this natural polymer, further degradation phenomena in relation to humidity and pollutants are poorly studied or still unknown. Attenuated total reflectance-Fourier transform infrared spectroscopy was explored with regard to Baltic amber. A systematic spectroscopic survey of a wide range of thermally aged model amber samples, exposed to different microclimatic conditions, showed significant changes in their spectra. Samples aged in a humid and acidic environment or exposed to a humid and alkaline atmosphere generally exhibited a higher absorbance intensity of carbonyl groups at frequencies assigned to acids than unaged samples, samples aged in drier conditions and samples immersed in an alkaline solution. Baltic amber comprises succinate ester, which may be hydrolysed into communol and succinic acid. The survey thus provided evidence about the progress of hydrolytic reactions during degradation of Baltic amber. Infrared spectroscopy was shown to have significant potential for providing qualitative and quantitative chemical information on hydrolysis of amber, which will be of interest for the development of preventive conservation techniques for museum collections of amber objects. Copyright © 2013 Elsevier B.V. All rights reserved.

Large Magellanic Cloud Near-infrared Synoptic Survey. V. Period–Luminosity Relations of Miras

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan, Wenlong; Macri, Lucas M.; He, Shiyuan

We study the near-infrared properties of 690 Mira candidates in the central region of the Large Magellanic Cloud, based on time-series observations at JHK{sub s}. We use densely sampled I -band observations from the OGLE project to generate template light curves in the near-infrared and derive robust mean magnitudes at those wavelengths. We obtain near-infrared Period–Luminosity relations for oxygen-rich Miras with a scatter as low as 0.12 mag at K{sub s}. We study the Period–Luminosity–Color relations and the color excesses of carbon-rich Miras, which show evidence for a substantially different reddening law.

Axial diffusion barriers in near-infrared nanopillar LEDs.

PubMed

Scofield, Adam C; Lin, Andrew; Haddad, Michael; Huffaker, Diana L

2014-11-12

The growth of GaAs/GaAsP axial heterostructures is demonstrated and implemented as diffusion current barriers in nanopillar light-emitting diodes at near-infrared wavelengths. The nanopillar light-emitting diodes utilize an n-GaAs/i-InGaAs/p-GaAs axial heterostructure for current injection. Axial GaAsP segments are inserted into the n- and p-GaAs portions of the nanopillars surrounding the InGaAs emitter region, acting as diffusion barriers to provide enhanced carrier confinement. Detailed characterization of growth of the GaAsP inserts and electronic band-offset measurements are used to effectively implement the GaAsP inserts as diffusion barriers. The implementation of these barriers in nanopillar light-emitting diodes provides a 5-fold increase in output intensity, making this a promising approach to high-efficiency pillar-based emitters in the near-infrared wavelength range.

Femtosecond measurements of near-infrared pulse induced mid-infrared transmission modulation of quantum cascade lasers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cai, Hong; Liu, Sheng; Center for Advanced Studied in Photonics Research

2014-05-26

We temporally resolved the ultrafast mid-infrared transmission modulation of quantum cascade lasers (QCLs) using a near-infrared pump/mid-infrared probe technique at room temperature. Two different femtosecond wavelength pumps were used with photon energy above and below the quantum well (QW) bandgap. The shorter wavelength pump modulates the mid-infrared probe transmission through interband transition assisted mechanisms, resulting in a high transmission modulation depth and several nanoseconds recovery lifetime. In contrast, pumping with a photon energy below the QW bandgap induces a smaller transmission modulation depth but much faster (several picoseconds) recovery lifetime, attributed to intersubband transition assisted mechanisms. The latter ultrafast modulationmore » (>60 GHz) could provide a potential way to realize fast QCL based free space optical communication.« less

Efficient near-infrared up-conversion photoluminescence in carbon nanotubes

PubMed Central

Akizuki, Naoto; Aota, Shun; Mouri, Shinichiro; Matsuda, Kazunari; Miyauchi, Yuhei

2015-01-01

Photoluminescence phenomena normally obey Stokes' law of luminescence according to which the emitted photon energy is typically lower than its excitation counterparts. Here we show that carbon nanotubes break this rule under one-photon excitation conditions. We found that the carbon nanotubes exhibit efficient near-infrared photoluminescence upon photoexcitation even at an energy lying >100–200 meV below that of the emission at room temperature. This apparently anomalous phenomenon is attributed to efficient one-phonon-assisted up-conversion processes resulting from unique excited-state dynamics emerging in an individual carbon nanotube with accidentally or intentionally embedded localized states. These findings may open new doors for energy harvesting, optoelectronics and deep-tissue photoluminescence imaging in the near-infrared optical range. PMID:26568250

Tissue phantom-based breast cancer detection using continuous near-infrared sensor

PubMed Central

Liu, Dan; Liu, Xin; Zhang, Yan; Wang, Qisong; Lu, Jingyang

2016-01-01

ABSTRACT Women's health is seriously threatened by breast cancer. Taking advantage of efficient diagnostic instruments to identify the disease is very meaningful in prolonging life. As a cheap noninvasive radiation-free technology, Near-infrared Spectroscopy is suitable for general breast cancer examination. A discrimination method of breast cancer is presented using the deference between absorption coefficients and applied to construct a blood oxygen detection device based on Modified Lambert-Beer theory. Combined with multi-wavelength multi-path near-infrared sensing technology, the proposed method can quantitatively distinguish the normal breast from the abnormal one by measuring the absorption coefficients of breast tissue and the blood oxygen saturation. An objective judgment about the breast tumor is made according to its high absorption of near-infrared light. The phantom experiment is implemented to show the presented method is able to recognize the absorption differences between phantoms and demonstrates its feasibility in the breast tumor detection. PMID:27459672

Tissue phantom-based breast cancer detection using continuous near-infrared sensor.

PubMed

Liu, Dan; Liu, Xin; Zhang, Yan; Wang, Qisong; Lu, Jingyang

2016-09-02

Women's health is seriously threatened by breast cancer. Taking advantage of efficient diagnostic instruments to identify the disease is very meaningful in prolonging life. As a cheap noninvasive radiation-free technology, Near-infrared Spectroscopy is suitable for general breast cancer examination. A discrimination method of breast cancer is presented using the deference between absorption coefficients and applied to construct a blood oxygen detection device based on Modified Lambert-Beer theory. Combined with multi-wavelength multi-path near-infrared sensing technology, the proposed method can quantitatively distinguish the normal breast from the abnormal one by measuring the absorption coefficients of breast tissue and the blood oxygen saturation. An objective judgment about the breast tumor is made according to its high absorption of near-infrared light. The phantom experiment is implemented to show the presented method is able to recognize the absorption differences between phantoms and demonstrates its feasibility in the breast tumor detection.

UNIVERSALITY OF THE NEAR-INFRARED EXTINCTION LAW BASED ON THE APOGEE SURVEY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shu; Jiang, B. W., E-mail: shuwang@mail.bnu.edu.cn, E-mail: bjiang@bnu.edu.cn

Whether the near-infrared (NIR) extinction law is universal has long been a debated topic. Based on the APOGEE H-band spectroscopic survey, a key project of SDSS-III, the intrinsic colors of a large number of giant stars are accurately determined from the stellar effective temperature. Taking advantage of this and using a sample of 5942 K-type giants, the NIR extinction law is carefully revisited. The color excess ratio E(J – H)/E(J – K {sub S}), representative of the NIR extinction law, shows no dependence on the color excess when E(J – K {sub S}) changes from ∼0.3 to ∼4.0, which implies amore » universal NIR extinction law from diffuse to dense regions. The constant value of E(J – H)/E(J – K {sub S}), 0.64, corresponds to a power law index of 1.95. The other two ratios, E(H – K {sub S})/E(J – K {sub S}) and E(J – H)/E(H – K {sub S}), are 0.36 and 1.78, respectively. The results are consistent with the MRN dust size distribution.« less

Determination of protein-dye association by near infrared fluorescence-detected circular dichroism.

PubMed

Meadows, F; Narayanan, N; Patonay, G

2000-01-10

Near-infrared (NIR) squarylium dye spectral properties were evaluated by absorption, fluorescence, circular dichroism (CD), and fluorescence-detected circular dichroism (FDCD). Substituents of the two NN dyes differed at R(1) and R(2), located symmetrically on the chromophore. The side chains of NN525 are R(1)=hexanoic acid, R(2)=butyl sulfonate and R(1)=R(2)=ethyl for NN127. FDCD signals were first confirmed by denaturing BSA with 2-8 M urea showing a diminution of dye FDCD peaks, but no change occurred in spectral properties of the dyes in urea. This indicated that the observed cotton effects occurred by noncovalent interactions with the secondary structure of the protein. The average BSA-dye association constants found by fluorescence, absorbance, and FDCD were 1.27 x 10(6) (n=1) and 3.3 x 10(6) M(-1) (n=1) for NN127 and NN525 respectively. These values were in good agreement when calculated by the three spectroscopic methods validating the use of NIRFDCD for optical parameter calculations. These results are useful to describe NIR squarylium dye labeling of BSA.

Determination of double bond conversion in dental resins by near infrared spectroscopy.

PubMed

Stansbury, J W; Dickens, S H

2001-01-01

This study determined the validity and practicality of near infrared (NIR) spectroscopic techniques for measurement of conversion in dental resins. Conversion measurements by NIR and mid-IR were compared using two techniques: (1) The conversion of 3mm thick photopolymerized Bis-GMA/TEGDMA resin specimens was determined by transmission NIR. Specimens were then ground and reanalyzed in KBr pellet form by mid-IR. (2) As further verification, thin resin films were photocured and analyzed by mid-IR. Multiple thin films were then compressed into a thick pellet for examination by NIR. Conversion values obtained by NIR and mid-IR techniques did not differ significantly. A correction for changing specimen thickness due to polymerization shrinkage was applied to NIR conversion measurements since an internal standard reference peak was not employed. Sensitivity of the NIR technique was superior to those based on the mid-IR. The nondestructive analysis of conversion in dental resins by NIR offers advantages of convenience, practical specimen dimensions and precision compared with standard mid-IR analytical procedures. Because glass is virtually transparent in the NIR spectrum, this technique has excellent potential for use with filled dental resins as well.

Interaction of cytidine 5'-monophosphate with Au(111): an in situ infrared spectroscopic study.

PubMed

Doneux, Thomas; Fojt, Lukás

2009-07-13

The interaction of cytidine 5'-monophosphate (CMP) with gold surfaces is studied by means of in situ infrared spectroscopy and cyclic voltammetry at the Au(111)|aqueous solution interface. Similar to other nucleic acid components, cytidine 5'-monophosphate is chemisorbed on the surface at positive potentials, and the amount of adsorbed CMP increases with the potential. Subtractively normalized interfacial Fourier-transform infrared spectroscopy (SNIFTIRS) is used to identify the adsorbed and desorbed species. Upon electrochemical desorption, the molecules released in solution are unprotonated on the N3 atom. Striking similarities are found between the spectrum of adsorbed CMP and the solution spectrum of protonated CMP. The origin of such similarities is discussed. The results strongly suggest that chemisorption occurs through the N3 atom of the pyrimidine ring. A comparison is drawn with cytidine, whose electrochemical and spectroscopic behaviors are also investigated.

Evaluation of a near-infrared photomultiplier

NASA Technical Reports Server (NTRS)

Evans, W. E.

1978-01-01

A high performance near infrared sensitive photomultiplier tube was procured and evaluated with emphasis on those characteristics affecting its use over the very large amplitude range of signals encountered by an airborne lidar intended for mapping the distribution of stratospheric aerosols. A cathode quantum efficiency of 4.3 percent at 1.06 micrometer wavelength and a background count of less than 10,000 per second were realized. It is recommended that the tube be stored and operated at a temperature near -20 C, or cooler. Performance was found acceptable for the application in both pulse counting and analog modes, but careful design, probably including dynamic gain control, will be required to effectively utilize both modes on the same lidar shot.

Fourier transform infrared spectroscopic study of intact cells of the nitrogen-fixing bacterium Azospirillum brasilense

NASA Astrophysics Data System (ADS)

Kamnev, A. A.; Ristić, M.; Antonyuk, L. P.; Chernyshev, A. V.; Ignatov, V. V.

1997-06-01

The data of Fourier transform infrared (FTIR) spectroscopic measurements performed on intact cells of the soil nitrogen-fixing bacterium Azospirillum brasilense grown in a standard medium and under the conditions of an increased metal uptake are compared and discussed. The structural FTIR information obtained is considered together with atomic absorption spectrometry (AAS) data on the content of metal cations in the bacterial cells. Some methodological aspects concerning preparation of bacterial cell samples for FTIR measurements are also discussed.

Visualization of Near-Infrared Spectral Data of Eros Using the Small Body Mapping Tool

NASA Astrophysics Data System (ADS)

Klima, Rachel L.; Ernst, Carolyn

2016-10-01

One of the primary drivers for many missions visiting asteroids is to advance our understanding of their composition beyond what can be (and is) already measured by telescopes. Without sample return or lander missions, this task relies primarily on resolved near-infrared spectroscopic measurements. Scientific analysis using spectral data collected by point spectrometers is not as straightforward as for imaging spectrometers, where the local spatial context is immediately available. In the case of Eros and other highly non-spherical bodies, this problem becomes even more severe when trying to locate spectra that cross a mapped feature that bends over an irregularly shaped surface. Thus, it is often the case that outside of the mission teams, few from the community at large delve into these data sets, as they lack the tools necessary to incorporate the spectral information into geological analyses of the asteroids. Ultimately, we seek to make such spectral datasets, which NASA has invested significant amounts of money to obtain, more widely accessible and user-friendly. The Small Bodies Mapping Tool (SBMT) is a Java-based, interactive, three-dimensional visualization tool written and developed at APL to map and analyze features on irregularly shaped solar system bodies. The SBMT can be used to locate and then "drape" spacecraft images, spectra, and laser altimetry around the shape model of such bodies. It provides a means for rapid identification of available data in a region of interest and allows features to be mapped directly onto the shape model. The program allows the free rotation of a shape model (including any overlain data) in all directions, so that the correlation and distribution of mapped features can be easily and globally observed.We will present the results of our work on the NEAR/Near-Infrared Spectrograph (NIS) data, including improvements to the calibration made by using the geometric information provided by the SBMT and improvements to the SMBT

IR CMOS: near infrared enhanced digital imaging (Presentation Recording)

NASA Astrophysics Data System (ADS)

Pralle, Martin U.; Carey, James E.; Joy, Thomas; Vineis, Chris J.; Palsule, Chintamani

2015-08-01

SiOnyx has demonstrated imaging at light levels below 1 mLux (moonless starlight) at video frame rates with a 720P CMOS image sensor in a compact, low latency camera. Low light imaging is enabled by the combination of enhanced quantum efficiency in the near infrared together with state of the art low noise image sensor design. The quantum efficiency enhancements are achieved by applying Black Silicon, SiOnyx's proprietary ultrafast laser semiconductor processing technology. In the near infrared, silicon's native indirect bandgap results in low absorption coefficients and long absorption lengths. The Black Silicon nanostructured layer fundamentally disrupts this paradigm by enhancing the absorption of light within a thin pixel layer making 5 microns of silicon equivalent to over 300 microns of standard silicon. This results in a demonstrate 10 fold improvements in near infrared sensitivity over incumbent imaging technology while maintaining complete compatibility with standard CMOS image sensor process flows. Applications include surveillance, nightvision, and 1064nm laser see spot. Imaging performance metrics will be discussed. Demonstrated performance characteristics: Pixel size : 5.6 and 10 um Array size: 720P/1.3Mpix Frame rate: 60 Hz Read noise: 2 ele/pixel Spectral sensitivity: 400 to 1200 nm (with 10x QE at 1064nm) Daytime imaging: color (Bayer pattern) Nighttime imaging: moonless starlight conditions 1064nm laser imaging: daytime imaging out to 2Km

Combining Dark Energy Survey Science Verification data with near-infrared data from the ESO VISTA Hemisphere Survey

DOE Office of Scientific and Technical Information (OSTI.GOV)

Banerji, M.; Jouvel, S.; Lin, H.

2014-11-25

We present the combination of optical data from the Science Verification phase of the Dark Energy Survey (DES) with near-infrared (NIR) data from the European Southern Observatory VISTA Hemisphere Survey (VHS). The deep optical detections from DES are used to extract fluxes and associated errors from the shallower VHS data. Joint seven-band ( grizYJK) photometric catalogues are produced in a single 3 sq-deg dedicated camera field centred at 02h26m-04d36m where the availability of ancillary multiwavelength photometry and spectroscopy allows us to test the data quality. Dual photometry increases the number of DES galaxies with measured VHS fluxes by a factormore » of ~4.5 relative to a simple catalogue level matching and results in a ~1.5 mag increase in the 80 per cent completeness limit of the NIR data. Almost 70 per cent of DES sources have useful NIR flux measurements in this initial catalogue. Photometric redshifts are estimated for a subset of galaxies with spectroscopic redshifts and initial results, although currently limited by small number statistics, indicate that the VHS data can help reduce the photometric redshift scatter at both z < 0.5 and z > 1. We present example DES+VHS colour selection criteria for high-redshift luminous red galaxies (LRGs) at z ~ 0.7 as well as luminous quasars. Using spectroscopic observations in this field we show that the additional VHS fluxes enable a cleaner selection of both populations with <10 per cent contamination from galactic stars in the case of spectroscopically confirmed quasars and <0.5 per cent contamination from galactic stars in the case of spectroscopically confirmed LRGs. The combined DES+VHS data set, which will eventually cover almost 5000 sq-deg, will therefore enable a range of new science and be ideally suited for target selection for future wide-field spectroscopic surveys.« less

Combining Dark Energy Survey Science Verification data with near-infrared data from the ESO VISTA Hemisphere Survey

DOE Office of Scientific and Technical Information (OSTI.GOV)

Banerji, M.; Jouvel, S.; Lin, H.

2014-11-25

We present the combination of optical data from the Science Verification phase of the Dark Energy Survey (DES) with near-infrared (NIR) data from the European Southern Observatory VISTA Hemisphere Survey (VHS). The deep optical detections from DES are used to extract fluxes and associated errors from the shallower VHS data. Joint seven-band (grizYJK) photometric catalogues are produced in a single 3 sq-deg dedicated camera field centred at 02h26m-04d36m where the availability of ancillary multiwavelength photometry and spectroscopy allows us to test the data quality. Dual photometry increases the number of DES galaxies with measured VHS fluxes by a factor ofmore » similar to 4.5 relative to a simple catalogue level matching and results in a similar to 1.5 mag increase in the 80 per cent completeness limit of the NIR data. Almost 70 per cent of DES sources have useful NIR flux measurements in this initial catalogue. Photometric redshifts are estimated for a subset of galaxies with spectroscopic redshifts and initial results, although currently limited by small number statistics, indicate that the VHS data can help reduce the photometric redshift scatter at both z < 0.5 and z > 1. We present example DES VHS colour selection criteria for high-redshift luminous red galaxies (LRGs) at z similar to 0.7 as well as luminous quasars. Using spectroscopic observations in this field we show that the additional VHS fluxes enable a cleaner selection of both populations with <10 per cent contamination from galactic stars in the case of spectroscopically confirmed quasars and <0.5 per cent contamination from galactic stars in the case of spectroscopically confirmed LRGs. The combined DES+VHS data set, which will eventually cover almost 5000 sq-deg, will therefore enable a range of new science and be ideally suited for target selection for future wide-field spectroscopic surveys.« less

Near--Infrared Imaging of the Starburst Ring in UGC12815

NASA Astrophysics Data System (ADS)

Smith, D. A.; Herter, T.; Haynes, M. P.; Neff, S. G.

1995-05-01

Starburst galaxies define an enigmatic class of objects undergoing a brief, intense episode of star formation. In order to investigate the nature of nearby starbursts, we have analyzed the 20 starburst galaxies with the highest 4.85 GHz luminosities from the survey of Condon, Frayer, & Broderick (1991, AJ, 101, 362) at infrared and optical wavelengths. As part of our study, we recently used the Cassegrain Infrared Camera at the Hale 5 m telescope to obtain high spatial resolution near--infrared images of the cores of 17 of these galaxies in order to better understand the starburst triggering mechanism. We find that one galaxy, UGC12815 (NGC7771), possesses a nucleus surrounded by a bright starburst ring. We present 1.25, 1.65, and 2.2 microns (J, H, and K band) images of the nuclear region of UGC12815 and a preliminary analysis of the properties of the starburst ring. The resolution of our K band image is 0.6('') FWHM. The ring is ~ 1.6 kpc (6('') ) in diameter assuming H_0=75 km/s/Mpc; several knots are detected in the ring at 2.2 microns. The spatial distribution of these knots is compared to that observed at 6 cm. The luminosities of the ring and nucleus, as mapped in the near--infrared and radio, are also discussed. Color maps (H-K and J-H) constructed from the near--infrared images trace the relative roles of extinction, and emission from evolved red stars, blue stars, thermal gas, and hot dust in the nucleus and starburst ring. A comparison between UGC12815 and other systems with circumnuclear starbursts is also made.

Near-infrared spectroscopic studies of the hydrogen bonding between thioacetamide and N, N-disubstituted benzamide derivatives in CCl 4

NASA Astrophysics Data System (ADS)

Choi, Young Sang; Kim, Jeongkwon; Park, Jeunghee; Yu, Jeong-A.; Yoon, Chang-Ju

1996-11-01

The hydrogen bonding interactions between thioacetamide (TA) and several N, N-disubstituted benzamides ( N, N-dimethylbenzamide (DMBA), N-methoxy- N-methylbenzamide (MMBA), N, N-diethyl- m-toluamide (DEMT), and N, N-diethyl-2,5-difluorobenzamide (DEDF)) have been studied using near-infrared absorption spectroscopy. Thermodynamic parameters for the interactions between TA and benzamides were determined by analyzing the νN-Has + amide II combination band of TA. The - ΔH0 values, indicating the intrinsic strength of hydrogen bonding, are -17.4, -21.6, -21.9 and -20.8 kJ mol -1 for DMBA, MMBA, DEMT and DEDF, respectively. The results show that the inductive and resonance effects of substituents appear to influence the formation of hydrogen bonds.

Gratings and Random Reflectors for Near-Infrared PIN Diodes

NASA Technical Reports Server (NTRS)

Gunapala, Sarath; Bandara, Sumith; Liu, John; Ting, David

2007-01-01

Crossed diffraction gratings and random reflectors have been proposed as means to increase the quantum efficiencies of InGaAs/InP positive/intrinsic/ negative (PIN) diodes designed to operate as near-infrared photodetectors. The proposal is meant especially to apply to focal-plane imaging arrays of such photodetectors to be used for near-infrared imaging. A further increase in quantum efficiency near the short-wavelength limit of the near-infrared spectrum of such a photodetector array could be effected by removing the InP substrate of the array. The use of crossed diffraction gratings and random reflectors as optical devices for increasing the quantum efficiencies of quantum-well infrared photodetectors (QWIPs) was discussed in several prior NASA Tech Briefs articles. While the optical effects of crossed gratings and random reflectors as applied to PIN photodiodes would be similar to those of crossed gratings and random reflectors as applied to QWIPs, the physical mechanisms by which these optical effects would enhance efficiency differ between the PIN-photodiode and QWIP cases: In a QWIP, the multiple-quantum-well layers are typically oriented parallel to the focal plane and therefore perpendicular or nearly perpendicular to the direction of incidence of infrared light. By virtue of the applicable quantum selection rules, light polarized parallel to the focal plane (as normally incident light is) cannot excite charge carriers and, hence, cannot be detected. A pair of crossed gratings or a random reflector scatters normally or nearly normally incident light so that a significant portion of it attains a component of polarization normal to the focal plane and, hence, can excite charge carriers. A pair of crossed gratings or a random reflector on a PIN photodiode would also scatter light into directions away from the perpendicular to the focal plane. However, in this case, the reason for redirecting light away from the perpendicular is to increase the length of the

Hierarchical Models for Type Ia Supernova Light Curves in the Optical and Near Infrared

NASA Astrophysics Data System (ADS)

Mandel, Kaisey; Narayan, G.; Kirshner, R. P.

2011-01-01

I have constructed a comprehensive statistical model for Type Ia supernova optical and near infrared light curves. Since the near infrared light curves are excellent standard candles and are less sensitive to dust extinction and reddening, the combination of near infrared and optical data better constrains the host galaxy extinction and improves the precision of distance predictions to SN Ia. A hierarchical probabilistic model coherently accounts for multiple random and uncertain effects, including photometric error, intrinsic supernova light curve variations and correlations across phase and wavelength, dust extinction and reddening, peculiar velocity dispersion and distances. An improved BayeSN MCMC code is implemented for computing probabilistic inferences for individual supernovae and the SN Ia and host galaxy dust populations. I use this hierarchical model to analyze nearby Type Ia supernovae with optical and near infared data from the PAIRITEL, CfA3, and CSP samples and the literature. Using cross-validation to test the robustness of the model predictions, I find that the rms Hubble diagram scatter of predicted distance moduli is 0.11 mag for SN with optical and near infrared data versus 0.15 mag for SN with only optical data. Accounting for the dispersion expected from random peculiar velocities, the rms intrinsic prediction error is 0.08-0.10 mag for SN with both optical and near infrared light curves. I discuss results for the inferred intrinsic correlation structures of the optical-NIR SN Ia light curves and the host galaxy dust distribution captured by the hierarchical model. The continued observation and analysis of Type Ia SN in the optical and near infrared is important for improving their utility as precise and accurate cosmological distance indicators.

Detecting and Segregating Black Tip-Damaged Wheat Kernels Using Visible and Near Infrared Spectroscopy

USDA-ARS?s Scientific Manuscript database

Detection of individual wheat kernels with black tip symptom (BTS) and black tip damage (BTD) was demonstrated using near infrared reflectance spectroscopy (NIRS) and silicon light-emitting-diode (LED) based instruments. The two instruments tested, a single kernel near-infrared spectroscopy instrume...

Comparison of Attenuated Total Reflectance Mid-Infrared, Near Infrared, and 1H-Nuclear Magnetic Resonance Spectroscopies for the Determination of Coffee's Geographical Origin.

PubMed

Medina, Jessica; Caro Rodríguez, Diana; Arana, Victoria A; Bernal, Andrés; Esseiva, Pierre; Wist, Julien

2017-01-01

The sensorial properties of Colombian coffee are renowned worldwide, which is reflected in its market value. This raises the threat of fraud by adulteration using coffee grains from other countries, thus creating a demand for robust and cost-effective methods for the determination of geographical origin of coffee samples. Spectroscopic techniques such as Nuclear Magnetic Resonance (NMR), near infrared (NIR), and mid-infrared (mIR) have arisen as strong candidates for the task. Although a body of work exists that reports on their individual performances, a faithful comparison has not been established yet. We evaluated the performance of 1 H-NMR, Attenuated Total Reflectance mIR (ATR-mIR), and NIR applied to fraud detection in Colombian coffee. For each technique, we built classification models for discrimination by species ( C. arabica versus C. canephora (or robusta )) and by origin (Colombia versus other C. arabica ) using a common set of coffee samples. All techniques successfully discriminated samples by species, as expected. Regarding origin determination, ATR-mIR and 1 H-NMR showed comparable capacity to discriminate Colombian coffee samples, while NIR fell short by comparison. In conclusion, ATR-mIR, a less common technique in the field of coffee adulteration and fraud detection, emerges as a strong candidate, faster and with lower cost compared to 1 H-NMR and more discriminating compared to NIR.

Comparison of Attenuated Total Reflectance Mid-Infrared, Near Infrared, and 1H-Nuclear Magnetic Resonance Spectroscopies for the Determination of Coffee's Geographical Origin

PubMed Central

Caro Rodríguez, Diana; Arana, Victoria A.; Bernal, Andrés; Esseiva, Pierre

2017-01-01

The sensorial properties of Colombian coffee are renowned worldwide, which is reflected in its market value. This raises the threat of fraud by adulteration using coffee grains from other countries, thus creating a demand for robust and cost-effective methods for the determination of geographical origin of coffee samples. Spectroscopic techniques such as Nuclear Magnetic Resonance (NMR), near infrared (NIR), and mid-infrared (mIR) have arisen as strong candidates for the task. Although a body of work exists that reports on their individual performances, a faithful comparison has not been established yet. We evaluated the performance of 1H-NMR, Attenuated Total Reflectance mIR (ATR-mIR), and NIR applied to fraud detection in Colombian coffee. For each technique, we built classification models for discrimination by species (C. arabica versus C. canephora (or robusta)) and by origin (Colombia versus other C. arabica) using a common set of coffee samples. All techniques successfully discriminated samples by species, as expected. Regarding origin determination, ATR-mIR and 1H-NMR showed comparable capacity to discriminate Colombian coffee samples, while NIR fell short by comparison. In conclusion, ATR-mIR, a less common technique in the field of coffee adulteration and fraud detection, emerges as a strong candidate, faster and with lower cost compared to 1H-NMR and more discriminating compared to NIR. PMID:29201055

Multilayer Black Phosphorus Near-Infrared Photodetectors.

PubMed

Hou, Chaojian; Yang, Lijun; Li, Bo; Zhang, Qihan; Li, Yuefeng; Yue, Qiuyang; Wang, Yang; Yang, Zhan; Dong, Lixin

2018-05-23

Black phosphorus (BP), owing to its distinguished properties, has become one of the most competitive candidates for photodetectors. However, there has been little attention paid on photo-response performance of multilayer BP nanoflakes with large layer thickness. In fact, multilayer BP nanoflakes with large layer thickness have greater potential from the fabrication viewpoint as well as due to the physical properties than single or few layer ones. In this report, the thickness-dependence of the intrinsic property of BP photodetectors in the dark was initially investigated. Then the photo-response performance (including responsivity, photo-gain, photo-switching time, noise equivalent power, and specific detectivity) of BP photodetectors with relative thicker thickness was explored under a near-infrared laser beam ( λ IR = 830 nm). Our experimental results reveal the impact of BP's thickness on the current intensity of the channel and show degenerated p-type BP is beneficial for larger current intensity. More importantly, the photo-response of our thicker BP photodetectors exhibited a larger responsivity up to 2.42 A/W than the few-layer ones and a fast response photo-switching speed (response time is ~2.5 ms) comparable to thinner BP nanoflakes was obtained, indicating BP nanoflakes with larger layer thickness are also promising for application for ultra-fast and ultra-high near-infrared photodetectors.

The Munich Near-Infrared Cluster Survey - IV. Biases in the completeness of near-infrared imaging data

NASA Astrophysics Data System (ADS)

Snigula, J.; Drory, N.; Bender, R.; Botzler, C. S.; Feulner, G.; Hopp, U.

2002-11-01

We present the results of completeness simulations for the detection of point sources as well as redshifted elliptical and spiral galaxies in the K'-band images of the Munich Near-Infrared Cluster Survey (MUNICS). The main focus of this work is to quantify the selection effects introduced by threshold-based object detection algorithms used in deep imaging surveys. Therefore, we simulate objects obeying the well-known scaling relations between effective radius and central surface brightness, for both de Vaucouleurs and exponential profiles. The results of these simulations, while presented for the MUNICS project, are applicable in a much wider context to deep optical and near-infrared selected samples. We investigate the detection probability as well as the reliability for recovering the true total magnitude with Kron-like (adaptive) aperture photometry. The results are compared with the predictions of the visibility theory of Disney and Phillipps in terms of the detection rate and the lost-light fraction. Additionally, the effects attributable to seeing are explored. The results show a bias against detecting high-redshifted massive elliptical galaxies in comparison to disc galaxies with exponential profiles, and that the measurements of the total magnitudes for intrinsically bright elliptical galaxies are systematically too faint. Disc galaxies, in contrast, show no significant offset in the magnitude measurement of luminous objects. Finally, we present an analytic formula to predict the completeness of point sources using only basic image parameters.

Variable selection in near-infrared spectroscopy: benchmarking of feature selection methods on biodiesel data.

PubMed

Balabin, Roman M; Smirnov, Sergey V

2011-04-29

During the past several years, near-infrared (near-IR/NIR) spectroscopy has increasingly been adopted as an analytical tool in various fields from petroleum to biomedical sectors. The NIR spectrum (above 4000 cm(-1)) of a sample is typically measured by modern instruments at a few hundred of wavelengths. Recently, considerable effort has been directed towards developing procedures to identify variables (wavelengths) that contribute useful information. Variable selection (VS) or feature selection, also called frequency selection or wavelength selection, is a critical step in data analysis for vibrational spectroscopy (infrared, Raman, or NIRS). In this paper, we compare the performance of 16 different feature selection methods for the prediction of properties of biodiesel fuel, including density, viscosity, methanol content, and water concentration. The feature selection algorithms tested include stepwise multiple linear regression (MLR-step), interval partial least squares regression (iPLS), backward iPLS (BiPLS), forward iPLS (FiPLS), moving window partial least squares regression (MWPLS), (modified) changeable size moving window partial least squares (CSMWPLS/MCSMWPLSR), searching combination moving window partial least squares (SCMWPLS), successive projections algorithm (SPA), uninformative variable elimination (UVE, including UVE-SPA), simulated annealing (SA), back-propagation artificial neural networks (BP-ANN), Kohonen artificial neural network (K-ANN), and genetic algorithms (GAs, including GA-iPLS). Two linear techniques for calibration model building, namely multiple linear regression (MLR) and partial least squares regression/projection to latent structures (PLS/PLSR), are used for the evaluation of biofuel properties. A comparison with a non-linear calibration model, artificial neural networks (ANN-MLP), is also provided. Discussion of gasoline, ethanol-gasoline (bioethanol), and diesel fuel data is presented. The results of other spectroscopic

Near-infrared scattering as a dust diagnostic

NASA Astrophysics Data System (ADS)

Saajasto, Mika; Juvela, Mika; Malinen, Johanna

2018-06-01

Context. Regarding the evolution of dust grains from diffuse regions of space to dense molecular cloud cores, many questions remain open. Scattering at near-infrared wavelengths, or "cloudshine", can provide information on cloud structure, dust properties, and the radiation field that is complementary to mid-infrared "coreshine" and observations of dust emission at longer wavelengths. Aims: We examine the possibility of using near-infrared scattering to constrain the local radiation field and the dust properties, the scattering and absorption efficiency, the size distribution of the grains, and the maximum grain size. Methods: We use radiative transfer modelling to examine the constraints provided by the J, H, and K bands in combination with mid-infrared surface brightness at 3.6 μm. We use spherical one-dimensional and elliptical three-dimensional cloud models to study the observable effects of different grain size distributions with varying absorption and scattering properties. As an example, we analyse observations of a molecular cloud in Taurus, TMC-1N. Results: The observed surface brightness ratios of the bands change when the dust properties are changed. However, even a change of ±10% in the surface brightness of one band changes the estimated power-law exponent of the size distribution γ by up to 30% and the estimated strength of the radiation field KISRF by up to 60%. The maximum grain size Amax and γ are always strongly anti-correlated. For example, overestimating the surface brightness by 10% changes the estimated radiation field strength by 20% and the exponent of the size distribution by 15%. The analysis of our synthetic observations indicates that the relative uncertainty of the parameter distributions are on average Amax, γ 25%, and the deviation between the estimated and correct values ΔQ < 15%. For the TMC-1N observations, a maximum grain size Amax > 1.5μm and a size distribution with γ > 4.0 have high probability. The mass weighted

Theoretical design of near - infrared organic compounds

NASA Astrophysics Data System (ADS)

Brymora, Katarzyna; Ducasse, Laurent; Dautel, Olivier; Lartigau-Dagron, Christine; Castet, FréDéRic

The world follows the path of digital development faster than ever before. In consequence, the Human Machine Interfaces (HMI) market is growing as well and it requires some innovations. The goal of our work is to achieve an organic Infra-Red (IR) photodetectors hitting the performance requirements for HMI applications. The quantum chemical calculations are used to guide the synthesis and technology development. In this work, in the framework of density functional theory (DFT) and time-dependent density functional theory (TD-DFT), we consider a large variety of materials exploring small donor-acceptor-donor molecules and copolymers alternating donor and acceptor monomers. We provide a structure-property relationship in view of designing new Near-Infrared (NIR) absorbing organic molecules and polymers.

A near infrared luminescent metal-organic framework for temperature sensing in the physiological range.

PubMed

Lian, Xiusheng; Zhao, Dian; Cui, Yuanjing; Yang, Yu; Qian, Guodong

2015-12-28

A near infrared pumped luminescent metal-organic framework thermometer Nd(0.577)Yb(0.423)BDC-F4, with near infrared fluorescence and excellent sensitivity in the physiological temperature range (293-313 K), has been first realized, and might be potentially applied for biomedical systems.

Near infrared spectroscopic examination of charred pine wood, bark, cellulose and lignin: Implications for the quantitative determination of charcoal in soils

USGS Publications Warehouse

Reeves, J. B.; McCarty, G.W.; Rutherford, D.W.; Wershaw, R. L.

2007-01-01

The objective of this research was to investigate the effect of charring on near infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred carbon in soils. Four materials (cellulose, lignin, pine bark and pine wood) and char from these materials created by charring for various durations (1 to 168 h) and at various temperatures (200 to 450??C) were studied. Near infrared spectra and measures of acidity (total acids, carboxylic acids, lactones and phenols as determined by titration) were available for 56 different samples (Not all samples charred at all temperatures/durations). Results showed spectral changes that varied with the material, temperature and duration of charring. Examination of spectra and correlation plots indicated that changes in the constituents of the materials in question, such as loss of OH groups in carbohydrates, rather than direct determination of typical products produced by charring, such as carboxylic acids, lactones and phenols, were the basis for the spectral changes. Finally, while the spectral changes resulting from charring appeared to be relatively unique to each material, PLS calibrations for total acids, carboxylic acids, lactones and phenols were successfully created (with R2 of 0.991, 0.943, 0.931 and 0.944, respectively) indicating that there is a sufficient commonality in the changes to develop calibrations without the need for unique calibrations for each specific set of charring conditions (i.e. material, temperature and time of heating). ?? IM Publications 2007.

ARNICA, the Arcetri near-infrared camera: Astronomical performance assessment.

NASA Astrophysics Data System (ADS)

Hunt, L. K.; Lisi, F.; Testi, L.; Baffa, C.; Borelli, S.; Maiolino, R.; Moriondo, G.; Stanga, R. M.

1996-01-01

The Arcetri near-infrared camera ARNICA was built as a users' instrument for the Infrared Telescope at Gornergrat (TIRGO), and is based on a 256x256 NICMOS 3 detector. In this paper, we discuss ARNICA's optical and astronomical performance at the TIRGO and at the William Herschel Telescope on La Palma. Optical performance is evaluated in terms of plate scale, distortion, point spread function, and ghosting. Astronomical performance is characterized by camera efficiency, sensitivity, and spatial uniformity of the photometry.

Absorption and electrochromic modulation of near-infrared light: realized by tungsten suboxide

NASA Astrophysics Data System (ADS)

Li, Guilian; Zhang, Shouhao; Guo, Chongshen; Liu, Shaoqin

2016-05-01

In the present study, needle-like tungsten suboxide W18O49 nanocrystals were fabricated as the optical active substance to realize the aim of optical control of near-infrared light. The W18O49 nanocrystals were selected in this regard due to their unique optical performance. As revealed by the powder absorption result, the needle-like W18O49 nanocrystals show strong and wide photoabsorption in the entire near infrared region of 780-2500 nm, from which thin films with the W18O49 nanocrystal coating thus benefits and can strongly shield off almost all near infrared irradiation, whereas transmitting the majority of visible light. To make it more tunable, the W18O49 nanocrystals were finally assembled onto an ITO glass via the layer-by-layer strategy for later electrochromic investigation. The nanostructured architectures of the W18O49 nanocrystal electrochromic films exhibit high contrast, faster switching response, higher coloration efficiencies (150 cm2 C-1 at 650 nm and 255 cm2 C-1 at 1300 nm), better long-term redox switching stability (reversibility of 98% after 500 cycles) and wide electrochromic spectrum coverage of both the visible and infrared regions.In the present study, needle-like tungsten suboxide W18O49 nanocrystals were fabricated as the optical active substance to realize the aim of optical control of near-infrared light. The W18O49 nanocrystals were selected in this regard due to their unique optical performance. As revealed by the powder absorption result, the needle-like W18O49 nanocrystals show strong and wide photoabsorption in the entire near infrared region of 780-2500 nm, from which thin films with the W18O49 nanocrystal coating thus benefits and can strongly shield off almost all near infrared irradiation, whereas transmitting the majority of visible light. To make it more tunable, the W18O49 nanocrystals were finally assembled onto an ITO glass via the layer-by-layer strategy for later electrochromic investigation. The nanostructured

Indium phosphide all air-gap Fabry-Pérot filters for near-infrared spectroscopic applications

NASA Astrophysics Data System (ADS)

Ullah, A.; Butt, M. A.; Fomchenkov, S. A.; Khonina, S. N.

2016-08-01

Food quality can be characterized by noninvasive techniques such as spectroscopy in the Near Infrared wavelength range. For example, 930 -1450 nm wavelength range can be used to detect diseases and differentiate between meat samples. Miniaturization of such NIR spectrometers is useful for quick and mobile characterization of food samples. Spectrometers can be miniaturized, without compromising the spectral resolution, using Fabry-Pérot (FP) filters consisting of two highly reflecting mirrors with a central cavity in between. The most commonly used mirrors in the design of FP filters are Distributed Bragg Reflections (DBRs) consisting of alternating high and low refractive index material pairs, due to their high reflectivity compared to metal mirrors. However, DBRs have high reflectivity for a selected range of wavelengths known as the stopband of the DBR. This range is usually much smaller than the sensitivity range of the spectrometer detector. Therefore, a bandpass filter is usually required to restrict wavelengths outside the stopband of the FP DBRs. Such bandpass filters are difficult to design and implement. Alternatively, high index contrast materials must be can be used to broaden the stopband width of the FP DBRs. In this work, Indium phosphide all air-gap filters are proposed in conjunction with InGaAs based detectors. The designed filter has a wide stopband covering the entire InGaAs detector sensitivity range. The filter can be tuned in the 950-1450 nm with single mode operation. The designed filter can hence be used for noninvasive meat quality control.

low-Cost, High-Performance Alternatives for Target Temperature Monitoring Using the Near-Infrared Spectrum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Virgo, Mathew; Quigley, Kevin J.; Chemerisov, Sergey

A process is being developed for commercial production of the medical isotope Mo-99 through a photo-nuclear reaction on a Mo-100 target using a highpower electron accelerator. This process requires temperature monitoring of the window through which a high-current electron beam is transmitted to the target. For this purpose, we evaluated two near infrared technologies: the OMEGA Engineering iR2 pyrometer and the Ocean Optics Maya2000 spectrometer with infrared-enhanced charge-coupled device (CCD) sensor. Measuring in the near infrared spectrum, in contrast to the long-wavelength infrared spectrum, offers a few immediate advantages: (1) ordinary glass or quartz optical elements can be used; (2)more » alignment can be performed without heating the target; and (3) emissivity corrections to temperature are typically less than 10%. If spatial resolution is not required, the infrared pyrometer is attractive because of its accuracy, low cost, and simplicity. If spatial resolution is required, we make recommendations for near-infrared imaging based on our data augmented by calculations« less

Near-infrared induced optical quenching effects on mid-infrared quantum cascade lasers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guo, Dingkai, E-mail: dingk1@umbc.edu; Talukder, Muhammad Anisuzzaman; Chen, Xing

In space communications, atmospheric absorption and Rayleigh scattering are the dominant channel impairments. Transmission using mid-infrared (MIR) wavelengths offers the benefits of lower loss and less scintillation effects. In this work, we report the telecom wavelengths (1.55 μm and 1.3 μm) induced optical quenching effects on MIR quantum cascade lasers (QCLs), when QCLs are operated well above their thresholds. The QCL output power can be near 100% quenched using 20 mW of near-infrared (NIR) power, and the quenching effect depends on the input NIR intensity as well as wavelength. Time resolved measurement was conducted to explore the quenching mechanism. The measured recovery timemore » is around 14 ns, which indicates that NIR generated electron-hole pairs may play a key role in the quenching process. The photocarrier created local field and band bending can effectively deteriorate the dipole transition matrix element and quench the QCL. As a result, MIR QCLs can be used as an optical modulator and switch controlled by NIR lasers. They can also be used as “converters” to convert telecom optical signals into MIR optical signals.« less

7 CFR 801.7 - Reference methods and tolerances for near-infrared spectroscopy (NIRS) analyzers.

Code of Federal Regulations, 2010 CFR

2010-01-01

... 7 Agriculture 7 2010-01-01 2010-01-01 false Reference methods and tolerances for near-infrared spectroscopy (NIRS) analyzers. 801.7 Section 801.7 Agriculture Regulations of the Department of Agriculture... methods and tolerances for near-infrared spectroscopy (NIRS) analyzers. (a) Reference methods. (1) The...

Far-infrared elastic scattering proposal for the Avogadro Project's silicon spheres

NASA Astrophysics Data System (ADS)

Humayun, Muhammad Hamza; Khan, Imran; Azeem, Farhan; Chaudhry, Muhammad Rehan; Gökay, Ulaş Sabahattin; Murib, Mohammed Sharif; Serpengüzel, Ali

2018-05-01

Avogadro constant determines the number of particles in one mole of a substance, thus relating the molar mass of the substance to the mass of this substance. Avogadro constant is related to Système Internationale base units by defining the very concept of chemical quantity. Revisions of the base units created a need to redefine the Avogadro constant, where a collaborative work called the Avogadro Project is established to employ optical interferometry to measure the diameter of high quality 100 mm silicon spheres. We propose far-infrared spectroscopy for determining the Avogadro constant by using elastic scattering from the 100 mm Avogadro Project silicon spheres. Similar spectroscopic methods are already in use in the near-infrared, relating whispering gallery modes of the 1 mm silicon spheres to the diameter of the spheres. We present numerical simulations in the far-infrared and the near-infrared, as well as spatially scaled down elastic scattering measurements in the near-infrared. These numerical and experimental results show that, the diameter measurements of 100 mm single crystal silicon spheres with elastic scattering in the far-infrared can be considered as an alternative to optical interferometry.

Spectroscopic diagnosis of laryngeal carcinoma using near-infrared Raman spectroscopy and random recursive partitioning ensemble techniques.

PubMed

Teh, Seng Khoon; Zheng, Wei; Lau, David P; Huang, Zhiwei

2009-06-01

In this work, we evaluated the diagnostic ability of near-infrared (NIR) Raman spectroscopy associated with the ensemble recursive partitioning algorithm based on random forests for identifying cancer from normal tissue in the larynx. A rapid-acquisition NIR Raman system was utilized for tissue Raman measurements at 785 nm excitation, and 50 human laryngeal tissue specimens (20 normal; 30 malignant tumors) were used for NIR Raman studies. The random forests method was introduced to develop effective diagnostic algorithms for classification of Raman spectra of different laryngeal tissues. High-quality Raman spectra in the range of 800-1800 cm(-1) can be acquired from laryngeal tissue within 5 seconds. Raman spectra differed significantly between normal and malignant laryngeal tissues. Classification results obtained from the random forests algorithm on tissue Raman spectra yielded a diagnostic sensitivity of 88.0% and specificity of 91.4% for laryngeal malignancy identification. The random forests technique also provided variables importance that facilitates correlation of significant Raman spectral features with cancer transformation. This study shows that NIR Raman spectroscopy in conjunction with random forests algorithm has a great potential for the rapid diagnosis and detection of malignant tumors in the larynx.

Elemental Analysis of Zircon by High Mass Resolution USGS-Stanford SHRIMP-RG: Measuring and Evaluating Ti-in-zircon Temperatures and Compositional Characteristics

NASA Astrophysics Data System (ADS)

Wooden, J. L.; Mazdab, F. K.; Claiborne, L. L.; Miller, C. F.; Barth, A. P.

2006-12-01

High mass resolution of SHRIMP-RG permits measurement of a large set of trace elements for zircon, including 48Ti, Sc, and Nb (requiring better than 9,000 MR) and Be, B, F, P, 49Ti, V, Y, all the REE, Hf, Th, and U (Mazdab and Wooden 2006). A 15-20 micron spot allows analysis of numerous discrete CL zones from single zircons with minimal contributions from unknown material below the exposed surface. Data from suites of zircons from more than 20 individual granitoid samples suggest several general observations: (1) Temperatures calculated by Ti-in-zircon (Watson et al 2006) are entirely compatible with petrologic constraints; uncertainty in a(TiO2) introduces uncertainty in calculated T, but for reasonable values between 0.5 and 0.8 T's consistently fall between 650 and 900 C, mostly in the lower half of the range; (2) T can vary by 150-200 C within suites of zircons from individual samples and even in single zircons, where zonation may be normal (high to low, core to rim), reverse (low to high) or fluctuating; (3) Hf concentrations increase with decreasing T because of Zr/Hf fractionation between zircon and melt (Claiborne et al in press); (4) Many elements and element ratios show a co-variation with T and Hf concentration e.g., Th/U and MREE/HREE decrease with increasing Hf and decreasing T. Hf concentrations can continue to increase after a minimum T is reached, indicating continuing zircon growth from remaining (near eutectic?) melt. Yb/Gd (steepness of the HREE pattern) is an excellent monitor of fractionation, particularly at lower T (below 750 C) where the ratio increases rapidly. This trend may result from co-fractionation of accessory minerals and/or be driven by the thermodynamics of crystal growth, and/or may involve other factors and processes as yet poorly understood. Magmatic zircons commonly have a negative Eu anomaly of about 0.5 or lower which may change little or become more pronounced with falling T; anomalies probably reflect feldspar

Molecular Shocks Associated with Massive Young Stars: CO Line Images with a New Far-Infrared Spectroscopic Camera on the Kuiper Airborne Observatory

NASA Technical Reports Server (NTRS)

Watson, Dan M.

1997-01-01

Under the terms of our contract with NASA Ames Research Center, the University of Rochester (UR) offers the following final technical report on grant NAG 2-958, Molecular shocks associated with massive young stars: CO line images with a new far-infrared spectroscopic camera, given for implementation of the UR Far-Infrared Spectroscopic Camera (FISC) on the Kuiper Airborne Observatory (KAO), and use of this camera for observations of star-formation regions 1. Two KAO flights in FY 1995, the final year of KAO operations, were awarded to this program, conditional upon a technical readiness confirmation which was given in January 1995. The funding period covered in this report is 1 October 1994 - 30 September 1996. The project was supported with $30,000, and no funds remained at the conclusion of the project.

Remote Observations in the Near Infrared

NASA Astrophysics Data System (ADS)

Gavryusev, V.; Baffa, C.; Giani, E.

We present our experiences in remote observations in Near Infrared bands operating a bidimensional instrument ARNICA. ARNICA, an infrared CCD detector operating at a telescope (TIRGO, Gornergrat, Switzerland) was controlled by an observer from Firenze, Italy. Despite the rather slow Internet link available, we were able to perform the observations in quite an acceptable way. The user interface process (a widget based X11 client) was executed locally on a Sun workstation. All processes responsible for hardware support (initialization of devices and their dynamic control and data acquisition itself) were executed remotely under DESQview/X on a PC dedicated to the control of ARNICA. The traffic was reduced to a minimum due to the truly distributed software used. In normal conditions this is just an exchange of short primitives which describe the task to be performed and of informative messages. There is also the possibility of a continuous display of the obtained images, with flexible control of display parameters.

Near-infrared spatially resolved spectroscopy of (136108) Haumea's multiple system

NASA Astrophysics Data System (ADS)

Gourgeot, F.; Carry, B.; Dumas, C.; Vachier, F.; Merlin, F.; Lacerda, P.; Barucci, M. A.; Berthier, J.

2016-08-01

Context. The transneptunian region of the solar system is populated by a wide variety of icy bodies showing great diversity in orbital behavior, size, surface color, and composition. Aims: The dwarf planet (136108) Haumea is among the largest transneptunian objects (TNOs) and is a very fast rotator (~3.9 h). This dwarf planet displays a highly elongated shape and hosts two small moons that are covered with crystalline water ice, similar to their central body. A particular region of interest is the Dark Red Spot (DRS) identified on the surface of Haumea from multiband light-curve analysis (Lacerda et al. 2008). Haumea is also known to be the largest member of the sole TNO family known to date, and an outcome of a catastrophic collision that is likely responsible for the unique characteristics of Haumea. Methods: We report here on the analysis of a new set of near-infrared Laser Guide Star assisted observations of Haumea obtained with the Integral Field Unit (IFU) Spectrograph for INtegral Field Observations in the Near Infrared (SINFONI) at the European Southern Observatory (ESO) Very Large Telescope (VLT) Observatory. Combined with previous data published by Dumas et al. (2011), and using light-curve measurements in the optical and far infrared to associate each spectrum with its corresponding rotational phase, we were able to carry out a rotationally resolved spectroscopic study of the surface of Haumea. Results: We describe the physical characteristics of the crystalline water ice present on the surface of Haumea for both regions, in and out of the DRS, and analyze the differences obtained for each individual spectrum. The presence of crystalline water ice is confirmed over more than half of the surface of Haumea. Our measurements of the average spectral slope (1.45 ± 0.82% by 100 nm) confirm the redder characteristic of the spot region. Detailed analysis of the crystalline water-ice absorption bands do not show significant differences between the DRS and the

Mechanisms and timescales of generating eruptible rhyolitic magmas at Yellowstone caldera from zircon and sanidine geochronology and geochemistry

USGS Publications Warehouse

Stelten, Mark; Cooper, Kari M.; Vazquez, Jorge A.; Calvert, Andrew T.; Glessner, Justin G

2015-01-01

We constrain the physical nature of the magma reservoir and the mechanisms of rhyolite generation at Yellowstone caldera via detailed characterization of zircon and sanidine crystals hosted in three rhyolites erupted during the (ca. 170 – 70 ka) Central Plateau Member eruptive episode – the most recent post-caldera magmatism at Yellowstone. We present 238U-230Th crystallization ages and trace-element compositions of the interiors and surfaces (i.e., unpolished rims) of individual zircon crystals from each rhyolite. We compare these zircon data to 238U- 230Th crystallization ages of bulk sanidine separates coupled with chemical and isotopic data from single sanidine crystals. Zircon age and trace-element data demonstrate that the magma reservoir that sourced the Central Plateau Member rhyolites was long-lived (150 – 250 kyr) and genetically related to the preceding episode of magmatism, which occurred ca. 256 ka. The interiors of most zircons in each rhyolite were inherited from unerupted material related to older stages of Central Plateau Member magmatism or the preceding late Upper Basin Member magmatism (i.e., are antecrysts). Conversely, most zircon surfaces crystallized near the time of eruption from their host liquids (i.e., are autocrystic). The repeated recycling of zircon interiors from older stages of magmatism demonstrates that sequentially erupted Central Plateau Member rhyolites are genetically related. Sanidine separates from each rhyolite yield 238U-230Th crystallization ages at or near the eruption age of their host magmas, coeval with the coexisting zircon surfaces, but are younger than the coexisting zircon interiors. Chemical and isotopic data from single sanidine crystals demonstrate that the sanidines in each rhyolite are in equilibrium with their host melts, which considered along with their near-eruption crystallization ages suggests that nearly all CPM sanidines are autocrystic. The paucity of antecrystic sanidine crystals relative to

Unbiased Large Spectroscopic Surveys of Galaxies Selected by SPICA Using Dust Bands

NASA Astrophysics Data System (ADS)

Kaneda, H.; Ishihara, D.; Oyabu, S.; Yamagishi, M.; Wada, T.; Armus, L.; Baes, M.; Charmandaris, V.; Czerny, B.; Efstathiou, A.; Fernández-Ontiveros, J. A.; Ferrara, A.; González-Alfonso, E.; Griffin, M.; Gruppioni, C.; Hatziminaoglou, E.; Imanishi, M.; Kohno, K.; Kwon, J.; Nakagawa, T.; Onaka, T.; Pozzi, F.; Scott, D.; Smith, J.-D. T.; Spinoglio, L.; Suzuki, T.; van der Tak, F.; Vaccari, M.; Vignali, C.; Wang, L.

2017-11-01

The mid-infrared range contains many spectral features associated with large molecules and dust grains such as polycyclic aromatic hydrocarbons and silicates. These are usually very strong compared to fine-structure gas lines, and thus valuable in studying the spectral properties of faint distant galaxies. In this paper, we evaluate the capability of low-resolution mid-infrared spectroscopic surveys of galaxies that could be performed by SPICA. The surveys are designed to address the question how star formation and black hole accretion activities evolved over cosmic time through spectral diagnostics of the physical conditions of the interstellar/circumnuclear media in galaxies. On the basis of results obtained with Herschel far-infrared photometric surveys of distant galaxies and Spitzer and AKARI near- to mid-infrared spectroscopic observations of nearby galaxies, we estimate the numbers of the galaxies at redshift z > 0.5, which are expected to be detected in the polycyclic aromatic hydrocarbon features or dust continuum by a wide (10 deg2) or deep (1 deg2) blind survey, both for a given observation time of 600 h. As by-products of the wide blind survey, we also expect to detect debris disks, through the mid-infrared excess above the photospheric emission of nearby main-sequence stars, and we estimate their number. We demonstrate that the SPICA mid-infrared surveys will efficiently provide us with unprecedentedly large spectral samples, which can be studied further in the far-infrared with SPICA.

[Theragnostic approaches using gold nanorods and near infrared light].

PubMed

Niidome, Takuro; Shiotani, Atsushi; Akiyama, Yasuyuki; Ohga, Akira; Nose, Keisuke; Pissuwan, Dakrong; Niidome, Yasuro

2010-12-01

Gold nanoparticles have unique optical properties such as surface-plasmon and photothermal effects. Such properties have resulted in gold nanoparticles having several clinical applications. Gold nanorods (which are rod-shaped gold nanoparticles) show a surface plasmon band in the near-infrared region. They have therefore been proposed as contrast agents for bioimaging, or as heating devices for photothermal therapy. Polyethylene glycol-modified gold nanorods systemically administrated into mice can be detected with integrating sphere, and the stability of the gold nanorods in blood flow evaluated. After intravenous injection of gold nanorods followed by near-infrared laser irradiation, significant tumor damage triggered by the photothermal effect was observed. To deliver gold nanorods to the target tissue, thermosensitive polymer gel-coated gold nanorods were prepared. After intravenous injection of the gel-modified gold nanorods and irradiation of the tumor, a larger amount of gold was detected in the irradiated tumor than in the non-irradiated tumor. This effect is due to the hydrophobic interaction between the cellular membrane or the extracellular matrix and the gel surfaces induced by the photothermal effect. Furthermore, the photothermal effect enhanced the permeability of the stratum corneum of the skin. As a result of treatment of the skin with ovalbumin and gold nanorods followed by near-infrared light irradiation, a significant amount of protein was detected in the skin. The gold nanorods therefore showed several functions as a photothermal nanodevice for bioimaging, thermal therapy, and a drug delivery system.

Book Review: Reiner Salzer and Heinz W. Siesler (Eds.): Infrared and Raman spectroscopic imaging, 2nd ed.

DOE PAGES

Moore, David Steven

2015-05-10

This second edition of "Infrared and Raman Spectroscopic Imaging" propels practitioners in that wide-ranging field, as well as other readers, to the current state of the art in a well-produced and full-color, completely revised and updated, volume. This new edition chronicles the expanded application of vibrational spectroscopic imaging from yesterday's time-consuming point-by-point buildup of a hyperspectral image cube, through the improvements afforded by the addition of focal plane arrays and line scan imaging, to methods applicable beyond the diffraction limit, instructs the reader on the improved instrumentation and image and data analysis methods, and expounds on their application to fundamentalmore » biomedical knowledge, food and agricultural surveys, materials science, process and quality control, and many others.« less

Near-infrared scintillation of liquid argon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alexander, T.; Escobar, C. O.; Lippincott, W. H.

2016-03-03

Since the 1970s it has been known that noble gases scintillate in the near infrared (NIR) region of the spectrum (0.7more » $$\\mu$$m < $$\\lambda$$; < 1.5$$\\mu$$m). More controversial has been the question of the NIR light yield for condensed noble gases. We first present the motivation for using the NIR scintillation in liquid argon detectors, then briefly review early as well as more recent efforts and finally show encouraging preliminary results of a test performed at Fermilab.« less

Infrared spectroscopy of interplanetary dust in the laboratory

NASA Technical Reports Server (NTRS)

Fraundorf, P.; Patel, R. I.; Freeman, J. J.

1981-01-01

A mount containing three crushed chondritic interplanetary dust particles (IDPs) collected in the earth's stratosphere and subjected to infrared spectroscopic measurements shows features near 1000 and 500/cm, suggesting crystalline pyroxene rather than crystalline olivine, amorphous olivine, or meteoritic clay minerals. Chondritic IDP structural diversity and atmospheric heating effects must be considered when comparing this spectrum with interplanetary and cometary dust astrophysical spectra. TEM and infrared observations of one member of the rare subset of IDPs resembling hydrated carbonaceous chondrite matrix material shows a close infrared spectrum resemblance between 4000 and 400/cm to the C2 meteorite Murchison. TEM observations suggest that this class of particles may be used as an atmospheric entry heating-process thermometer.

The near-infrared continuum emission of visual reflection nebulae

NASA Technical Reports Server (NTRS)

Sellgren, K.

1984-01-01

In the past, reflection nebulae have provided an astrophysical laboratory well suited for the study of the reflection properties of interstellar dust grains at visual and ultraviolet wavelengths. The present investigation is concerned with observations which were begun with the objective to extend to near-infrared wavelengths the study of grains in reflection. Observations of three classical visual reflection nebulae were conducted in the wavelength range from 1.25 to 2.2 microns, taking into account NGC 7023, 2023, and 2068. All three nebulae were found to have similar near-infrared colors, despite widely different colors of their illuminating stars. The brightness level shown by two of the nebulae at 2.2 microns was too high to be easily accounted for on the basis of reflected light. Attention is given to a wide variety of possible emission mechanisms.

Phosphonated Near-Infrared Fluorophores for Biomedical Imaging of Bone**

PubMed Central

Hyun, Hoon; Wada, Hideyuki; Bao, Kai; Gravier, Julien; Yadav, Yogesh; Laramie, Matt; Henary, Maged; Frangioni, John V.

2014-01-01

The conventional method for creating targeted contrast agents is to conjugate separate targeting and fluorophore domains. In this study we report a new strategy based on incorporation of targeting moieties into the non-resonant structure of pentamethine and heptamethine indocyanines. Using the known affinity of phosphonates for bone minerals as a model system, we have synthesized two families of bifunctional molecules that target bone without the need for a traditional bisphosphonate. With peak fluorescence emission at ≈ 700 nm or ≈ 800 nm, these molecules can be used for FLARE dual-channel imaging. Longitudinal FLARE studies in mice demonstrate that phosphonated near-infrared fluorophores remain stable in bone for over 5 weeks, and histological analysis demonstrates incorporation into bone matrix. Taken together, we describe a new strategy for creating ultracompact, targeted, near-infrared fluorophores for various bioimaging applications. PMID:25139079

Simulation of the fixed optical path difference of near infrared wind imaging interferometer

NASA Astrophysics Data System (ADS)

Rong, Piao; Zhang, Chunmin; Yan, Tingyu; Liu, Dongdong; Li, Yanfen

2017-02-01

As an important part of the earth, atmosphere plays a vital role in filtering the solar radiation, adjusting the temperature and organizing the water circulation and keeping human survival. The passive atmospheric wind measurement is based on the imaging interferometer technology and Doppler effect of electromagnetic wave. By using the wind imaging interferometer to get four interferograms of airglow emission lines, the atmospheric wind velocity, temperature, pressure and emission rate can be derived. Exploring the multi-functional and integrated innovation of detecting wind temperature, wind velocity and trace gas has become a research focus in the field. In the present paper, the impact factors of the fixed optical path difference(OPD) of near infrared wind imaging interferometer(NIWII) are analyzed and the optimum value of the fixed optical path difference is simulated, yielding the optimal results of the fixed optical path difference is 20 cm in near infrared wave band (the O2(a1Δg) airglow emission at 1.27 microns). This study aims at providing theoretical basis and technical support for the detection of stratosphere near infrared wind field and giving guidance for the design and development of near infrared wind imaging interferometer.

A Spectroscopic study on the fuel value of softwoods in relation to chemical composition

Treesearch

Chi-Leung So; Thomas L. Eberhardt; Les Groom; Todd F. Shupe

2012-01-01

The recent focus on bioenergy has led to interest in developing alternative technologies for assessing the fuel value of available biomass resources. In this study, both near- and mid-infrared spectroscopic datawere used to predict fuel value in relation to extractives and lignin contents for longleaf pine wood. Samples were analyzed both before and after extraction....

Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon.

PubMed

Bell, Elizabeth A; Boehnke, Patrick; Harrison, T Mark; Mao, Wendy L

2015-11-24

Evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ∼ 3.5 billion years (Ga), the chemofossil record arguably to ∼ 3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in a crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ(13)CPDB of -24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ∼ 300 My earlier than has been previously proposed.

Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon

PubMed Central

Bell, Elizabeth A.; Harrison, T. Mark; Mao, Wendy L.

2015-01-01

Evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ∼3.5 billion years (Ga), the chemofossil record arguably to ∼3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in a crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ13CPDB of −24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ∼300 My earlier than has been previously proposed. PMID:26483481

Nebular Phase Observations of the Type Ia Supernova 2014J in the Near Infrared

NASA Astrophysics Data System (ADS)

Diamond, Tiara

2018-01-01

Late-time spectra of SNe Ia show numerous strong emission features of iron and cobalt throughout the near infrared region. As the spectrum ages, the cobalt features fade as is expected from the decay of 56Co to 56Fe. The strong 1.6440 μm [Fe II] feature is sensitive to the central density of the white dwarf just prior to the runaway because of electron capture in the early stages of burning, hence the line profile width and evolution can be used to probe possible progenitor scenarios. The line profile is dependent on the extent of mixing during any deflagration burning in addition to asymmetries in the distribution of burning products or an off-center ignition. We present observations of SN 2014J from 300–500 days post-explosion. The data are consistent with spherical models of a MCh explosion with a deflagration-to-detonation transition, central density of 0.7×109 g/cm3, and limited mixing. An asymmetry in the line profile of the last spectrum could indicate an off-center ignition or burning products that are not centered on the kinetic center of the explosion. These and other late-time spectroscopic observations in the infrared of a significant sample of SNe Ia will provide insight into the natural variety of these objects, improving our understanding of the underlying physical processes and their usability in cosmology.

Near infrared photographic sky survey - A field index

NASA Technical Reports Server (NTRS)

Rossano, G. S.; Craine, E. R.

1980-01-01

The book presents an index of previously cataloged objects located in the fields of the northern sky included in the Steward Observatory Near Infrared Photographic Sky Survey, which was intended to be used for identification purposes in an effort to locate extremely red objects. The objects included in the index were taken from 16 catalogs of bright nebulae, dark nebulae, infrared objects, reflection nebulae, supernova remnants and other objects, and appear with their corresponding field numbers, computed field center coordinates, object name and 1950 epoch equatorial coordinates, as well as supplementary descriptive information as available. An appendix is also provided in which the center coordinates of each field are listed.

Characterization of the functional near-infrared spectroscopy response to nociception in a pediatric population.

PubMed

Olbrecht, Vanessa A; Jiang, Yifei; Viola, Luigi; Walter, Charlotte M; Liu, Hanli; Kurth, Charles D

2018-02-01

Near-infrared spectroscopy can interrogate functional optical signal changes in regional brain oxygenation and blood volume to nociception analogous to functional magnetic resonance imaging. This exploratory study aimed to characterize the near-infrared spectroscopy signals for oxy-, deoxy-, and total hemoglobin from the brain in response to nociceptive stimulation of varying intensity and duration, and after analgesic and neuromuscular paralytic in a pediatric population. We enrolled children 6 months-21 years during propofol sedation before surgery. The near-infrared spectroscopy sensor was placed on the forehead and nociception was produced from an electrical current applied to the wrist. We determined the near-infrared spectroscopy signal response to increasing current intensity and duration, and after fentanyl, sevoflurane, and neuromuscular paralytic. Heart rate and arm movement during electrical stimulation was also recorded. The near-infrared spectroscopy signals for oxy-, deoxy-, and total hemoglobin were calculated as optical density*time (area under curve). During electrical stimulation, nociception was evident: tachycardia and arm withdrawal was observed that disappeared after fentanyl and sevoflurane, whereas after paralytic, tachycardia persisted while arm withdrawal disappeared. The near-infrared spectroscopy signals for oxy-, deoxy-, and total hemoglobin increased during stimulation and decreased after stimulation; the areas under the curves were greater for stimulations 30 mA vs 15 mA (13.9 [5.6-22.2], P = .0021; 5.6 [0.8-10.5], P = .0254, and 19.8 [10.5-29.1], P = .0002 for HbO 2 , Hb, and Hb T , respectively), 50 Hz vs 1 Hz (17.2 [5.8-28.6], P = .0046; 7.5 [0.7-14.3], P = .0314, and 21.9 [4.2-39.6], P = .0177 for HbO 2 , Hb, and Hb T , respectively) and 45 seconds vs 15 seconds (16.3 [3.4-29.2], P = .0188 and 22.0 [7.5-36.5], P = .0075 for HbO 2 and Hb T , respectively); the areas under the curves were attenuated by

Mid-Infrared Spectroscopy of Mercury from the Kuiper Airborne Observatory

NASA Astrophysics Data System (ADS)

Sprague, A. L.; Witteborn, F. C.; Kozlowski, R. W. H.; Wooden, D. H.

1996-03-01

We present mid-infrared (5 - 10mic) spectroscopic measurements of the planet Mercury obtained from the Kuiper Airborne Observatory (KAO) using the High Efficiency Infrared Faint Object Grating Spectrograph (HIFOGS). Spectra show features characteristic of plagioclase feldspar that was previously observed near 120 deg mercurian longitude. The spectra also show spectral features that could be interpreted indicative of the presence of pyrrhotite (pyrr). An analysis that fully accounts for the effects of large field of view (FOV), thermal gradients, rough surface and absolute calibration is still underway.

Two-photon absorption and efficient encapsulation of near-infrared-emitting CdSexTe1-x quantum dots

NASA Astrophysics Data System (ADS)

Szeremeta, Janusz; Lamch, Lukasz; Wawrzynczyk, Dominika; Wilk, Kazimiera A.; Samoc, Marek; Nyk, Marcin

2015-07-01

Hydrophobic CdSexTe1-x quantum dots with near infrared emission in the 700-750 nm range were synthesized by a wet chemistry technique. Their nonlinear optical properties were studied using Z-scan technique with a tunable femtosecond laser system. The peak value of the two-photon absorption cross section was found to be ∼2400 GM at 1400 nm. To demonstrate a possible way of utilizing the CdSexTe1-x quantum dots in aqueous environment we describe here a convenient method of preparation of Brij 58® micellar systems loaded with the quantum dots. The obtained nanoconstructs were characterized using optical spectroscopy, TEM and DLS. The micelles colloidal stability, and the influence of the encapsulation process on the spectroscopic properties of the quantum dots are discussed. In particular, we have observed a 60 nm blue-shift of the emission maxima upon loading quantum dots inside the micelles.

Design of a multiband near-infrared sky brightness monitor using an InSb detector.

PubMed

Dong, Shu-Cheng; Wang, Jian; Tang, Qi-Jie; Jiang, Feng-Xin; Chen, Jin-Ting; Zhang, Yi-Hao; Wang, Zhi-Yue; Chen, Jie; Zhang, Hong-Fei; Jiang, Hai-Jiao; Zhu, Qing-Feng; Jiang, Peng; Ji, Tuo

2018-02-01

Infrared sky background level is an important parameter of infrared astronomy observations from the ground, particularly for a candidate site of an infrared capable observatory since low background level is required for such a site. The Chinese astronomical community is looking for a suitable site for a future 12 m telescope, which is designed for working in both optical and infrared wavelengths. However, none of the proposed sites has been tested for infrared observations. Nevertheless, infrared sky background measurements are also important during the design of infrared observing instruments. Based on the requirement, in order to supplement the current site survey data and guide the design of future infrared instruments, a multiband near-infrared sky brightness monitor (MNISBM) based on an InSb sensor is designed in this paper. The MNISBM consists of an optical system, mechanical structure and control system, detector and cooler, high gain readout electronics, and operational software. It is completed and tested in the laboratory. The results show that the sensitivity of the MNISBM meets the requirements of the measurement of near-infrared sky background level of several well-known astronomical infrared observing sites.

Design of a multiband near-infrared sky brightness monitor using an InSb detector

NASA Astrophysics Data System (ADS)

Dong, Shu-cheng; Wang, Jian; Tang, Qi-jie; Jiang, Feng-xin; Chen, Jin-ting; Zhang, Yi-hao; Wang, Zhi-yue; Chen, Jie; Zhang, Hong-fei; Jiang, Hai-jiao; Zhu, Qing-feng; Jiang, Peng; Ji, Tuo

2018-02-01

Infrared sky background level is an important parameter of infrared astronomy observations from the ground, particularly for a candidate site of an infrared capable observatory since low background level is required for such a site. The Chinese astronomical community is looking for a suitable site for a future 12 m telescope, which is designed for working in both optical and infrared wavelengths. However, none of the proposed sites has been tested for infrared observations. Nevertheless, infrared sky background measurements are also important during the design of infrared observing instruments. Based on the requirement, in order to supplement the current site survey data and guide the design of future infrared instruments, a multiband near-infrared sky brightness monitor (MNISBM) based on an InSb sensor is designed in this paper. The MNISBM consists of an optical system, mechanical structure and control system, detector and cooler, high gain readout electronics, and operational software. It is completed and tested in the laboratory. The results show that the sensitivity of the MNISBM meets the requirements of the measurement of near-infrared sky background level of several well-known astronomical infrared observing sites.

Prefrontal cerebral blood volume patterns while playing video games--a near-infrared spectroscopy study.

PubMed

Nagamitsu, Shinichiro; Nagano, Miki; Yamashita, Yushiro; Takashima, Sachio; Matsuishi, Toyojiro

2006-06-01

Video game playing is an attractive form of entertainment among school-age children. Although this activity reportedly has many adverse effects on child development, these effects remain controversial. To investigate the effect of video game playing on regional cerebral blood volume, we measured cerebral hemoglobin concentrations using near-infrared spectroscopy in 12 normal volunteers consisting of six children and six adults. A Hitachi Optical Topography system was used to measure hemoglobin changes. For all subjects, the video game Donkey Kong was played on a Game Boy device. After spectroscopic probes were positioned on the scalp near the target brain regions, the participants were asked to play the game for nine periods of 15s each, with 15-s rest intervals between these task periods. Significant increases in bilateral prefrontal total-hemoglobin concentrations were observed in four of the adults during video game playing. On the other hand, significant decreases in bilateral prefrontal total-hemoglobin concentrations were seen in two of the children. A significant positive correlation between mean oxy-hemoglobin changes in the prefrontal region and those in the bilateral motor cortex area was seen in adults. Playing video games gave rise to dynamic changes in cerebral blood volume in both age groups, while the difference in the prefrontal oxygenation patterns suggested an age-dependent utilization of different neural circuits during video game tasks.

Spectroscopic Capabilities and Possibilities of the Far Infrared and Submillimeter Telescope Mission

NASA Technical Reports Server (NTRS)

Pearson, J. C.

2000-01-01

The Far Infrared and Submillimeter Telescope (FIRST) mission is the fourth European Space Agency corner stone mission. FIRST will be an observatory with a passively cooled (80 Kelvin) 3.5 meter class telescope and three cryogenic instruments covering the 670 to 80 mm spectral region. The mission is slated for a 4.5 year operational lifetime in an L2 orbit. It will share an Arian 5 launch with PLANCK in early 2007. The three payload instruments include the Spectral and Photometric Imaging Receiver (SPIRE), which is a bolometer array with Martin-Puplett FTS for 200-670 microns, the Photoconductor Array Camera and Spectrometer (PACS), which is a photoconductor array with a grating spectrometer for 80-210 microns and the Heterodyne Instrument for FIRST (HIFI), which is a series of seven heterodyne receivers covering 480-1250 GHz and portions of 1410-1910 GHz and 2400-2700 GHz. FIRST will make many detailed spectral surveys of a wide variety of objects previously obscured by the atmosphere and in regions of the spectrum seldom used for astronomical observations, With all of the spectroscopic capability on FIRST a great deal of laboratory spectroscopic support will be needed for accurate interpretation of the spectral data.

Spectroscopic infrared extinction mapping as a probe of grain growth in IRDCs

NASA Astrophysics Data System (ADS)

Lim, Wanggi; Carey, Sean J.

2014-07-01

We present photometric and spectroscopic tests of MIR to FIR extinction laws toward IRDC G028.36+00.07, a potential site of massive star formation. Lim & Tan (2014, hereafter LT14) developed methods of FIR extinction mapping of this source using Spitzer-MIPS 24 micron and Herschel-PACS 70 micron images, and extending the MIR 8 micron mapping methods of (Butler & Tan 2012, hereafter BT12), finding evidence for grain growth in the highest mass surface density regions. Here we present initial results of spectroscopic infrared extinction (SIREX) mapping using Spitzer-IRS (14 to 38 micron) data of the same IRDC. These methods allow us to measure the SED of the diffuse Galactic ISM, which we compare to theoretical models of Draine & Li (2007), as well as to search for opacity law variations with mass surface density within the IRDC. By comparison with theoretical dust models, e.g., Ossenkopf & Henning (1994) and Ormel et al. (2011), we are able to search for compositional signatures of the grain ices, such as water and methanol. We find evidence for generally flatter MIR to FIR extinction laws as mass surface density increases, strengthening the evidence for grain and ice mantle growth in higher density regions.

Near-Infrared Confocal Laser Reflectance Cytoarchitectural Imaging of the Substantia Nigra and Cerebellum in the Fresh Human Cadaver.

PubMed

Cheyuo, Cletus; Grand, Walter; Balos, Lucia L

2017-01-01

Cytoarchitectural neuroimaging remains critical for diagnosis of many brain diseases. Fluorescent dye-enhanced, near-infrared confocal in situ cellular imaging of the brain has been reported. However, impermeability of the blood-brain barrier to most fluorescent dyes limits clinical utility of this modality. The differential degree of reflectance from brain tissue with unenhanced near-infrared imaging may represent an alternative technique for in situ cytoarchitectural neuroimaging. We assessed the utility of unenhanced near-infrared confocal laser reflectance imaging of the cytoarchitecture of the cerebellum and substantia nigra in 2 fresh human cadaver brains using a confocal near-infrared laser probe. Cellular images based on near-infrared differential reflectance were captured at depths of 20-180 μm from the brain surface. Parts of the cerebellum and substantia nigra imaged using the probe were subsequently excised and stained with hematoxylin and eosin for histologic correlation. Near-infrared reflectance imaging revealed the 3-layered cytoarchitecture of the cerebellum, with Purkinje cells appearing hyperreflectant. In the substantia nigra, neurons appeared hyporeflectant with hyperreflectant neuromelanin cytoplasmic inclusions. Cytoarchitecture of the cerebellum and substantia nigra revealed on near-infrared imaging closely correlated with the histology on hematoxylin-eosin staining. We showed that unenhanced near-infrared reflectance imaging of fresh human cadaver brain can reliably identify and distinguish neurons and detailed cytoarchitecture of the cerebellum and substantia nigra. Copyright © 2016 Elsevier Inc. All rights reserved.

Near infrared diffuse reflection and laser-induced fluorescence spectroscopy for myocardial tissue characterisation

NASA Astrophysics Data System (ADS)

Nilsson, A. M. K.; Heinrich, D.; Olajos, J.; Andersson-Engels, S.

1997-10-01

In order to evaluate the potential of cardiovascular tissue characterisation using near-infrared (NIR) spectroscopy, spectra in a previously unexplored wavelength region 0.8-2.3 μm were recorded from various pig heart tissue samples in vitro: normal myocardium (with and without endo/epicardium), aorta, fatty and fibrous heart tissue. The spectra were analysed with principal component analysis (PCA), revealing several spectroscopically characteristic features enabling tissue classification. Several of the identified spectral features could be attributed to specific tissue constituents by comparing the tissue signals with spectra obtained from water, elastin, collagen and cholesterol as well as with published data. The results obtained with the NIR spectroscopy technique in terms of its potential to classify different tissue types were compared with those from laser-induced fluorescence (LIF) using 337 nm excitation. LIF and NIR spectroscopy can in combination with PCA be used to discriminate between all previously mentioned tissue groups, apart from fatty versus fibrous tissue (LIF) and aorta versus fibrous tissue (NIR), respectively. The NIR analysis was improved by focusing the PCA to the wavelength segment 2.0-2.3 μm, resulting in successful spectral characterisation of all cardiovascular tissue groups.

Titan's Thermal Emission: Analysis Of Near-surface Temperatures Via Mid-infrared Measurements

NASA Astrophysics Data System (ADS)

Sadino, Jeff; Parrish, P. D.; Orton, G. S.; Burl, M. C.; Davies, A. G.; Irwin, P. G.; Teanby, N. A.; Flasar, F. M.; Cassini/CIRS investigation Team

2006-09-01

After Courtin and Kim 2002, tropospheric and near-surface temperatures of Titan may be obtained by examining mid-infrared radiances at 300 and 500 wavenumbers (33 and 20 microns). Here, the measured radiance is (respectively) sensitive to the temperature near the tropopause and sufficient to discern variations in surface topography and emissivity. Our search, as a function of location and time, compares brightness temperatures derived from measurements by the Cassini Composite Infrared Spectrometer (CIRS) and variations of radiance as a function of Titan's rotation derived from ground-based measurements at NASA's Infrared Telescope Facility. Although the variation of the tropopause and zonal near-surface temperatures are fairly homogenous, similar to Courtin and Kim 2002, the meridional distribution of near-surface temperatures varies symmetrically from Equator to pole. While no significant thermal variations suggestive of localized hotspots have yet been observed, such diversity is suggestive of active surface geology, in support of other optical and near-infrared investigations. Although the spatial coverage of the CIRS dataset is severely limited, the approximately 10 degrees field of view (450km at the Equator) is de-convolved somewhat to extract meaningful, sub-pixel maps of Titan's surface. Courtin, R. and Kim, S. (2002). Planet. and Sp. Sci., 50: 309-321. The acquisition of data described here was accomplished through the coordinated effort of Cassini-Huygens project staff, Deep Space Network personnel and the CIRS instrument and science-planning teams with funding provided by the National Research Council, NASA/JPL and NASA/GSFC and the UK Particle Physics and Astronomy council.

Near-Infrared Fluorescence-Enhanced Optical Tomography

PubMed Central

2016-01-01

Fluorescence-enhanced optical imaging using near-infrared (NIR) light developed for in vivo molecular targeting and reporting of cancer provides promising opportunities for diagnostic imaging. The current state of the art of NIR fluorescence-enhanced optical tomography is reviewed in the context of the principle of fluorescence, the different measurement schemes employed, and the mathematical tools established to tomographically reconstruct the fluorescence optical properties in various tissue domains. Finally, we discuss the recent advances in forward modeling and distributed memory parallel computation to provide robust, accurate, and fast fluorescence-enhanced optical tomography. PMID:27803924

Near-Infrared Fluorescence-Enhanced Optical Tomography.

PubMed

Zhu, Banghe; Godavarty, Anuradha

2016-01-01

Fluorescence-enhanced optical imaging using near-infrared (NIR) light developed for in vivo molecular targeting and reporting of cancer provides promising opportunities for diagnostic imaging. The current state of the art of NIR fluorescence-enhanced optical tomography is reviewed in the context of the principle of fluorescence, the different measurement schemes employed, and the mathematical tools established to tomographically reconstruct the fluorescence optical properties in various tissue domains. Finally, we discuss the recent advances in forward modeling and distributed memory parallel computation to provide robust, accurate, and fast fluorescence-enhanced optical tomography.

Jupiter in blue, ultraviolet and near infrared

NASA Technical Reports Server (NTRS)

2000-01-01

These three images of Jupiter, taken through the narrow angle camera of NASA's Cassini spacecraft from a distance of 77.6 million kilometers (48.2 million miles) on October 8, reveal more than is apparent to the naked eye through a telescope.

The image on the left was taken through the blue filter. The one in the middle was taken in the ultraviolet. The one on the right was taken in the near infrared.

The blue-light filter is within the part of the electromagnetic spectrum detectable by the human eye. The appearance of Jupiter in this image is, consequently, very familiar. The Great Red Spot (below and to the right of center) and the planet's well-known banded cloud lanes are obvious. The brighter bands of clouds are called zones and are probably composed of ammonia ice particles. The darker bands are called belts and are made dark by particles of unknown composition intermixed with the ammonia ice.

Jupiter's appearance changes dramatically in the ultraviolet and near infrared images. These images are near negatives of each other and illustrate the way in which observations in different wavelength regions can reveal different physical regimes on the planet.

All gases scatter sunlight efficiently at short wavelengths; this is why the sky appears blue on Earth. The effect is even more pronounced in the ultraviolet. The gases in Jupiter's atmosphere, above the clouds, are no different. They scatter strongly in the ultraviolet, making the deep banded cloud layers invisible in the middle image. Only the very high altitude haze appears dark against the bright background. The contrast is reversed in the near infrared, where methane gas, abundant on Jupiter but not on Earth, is strongly absorbing and therefore appears dark. Again the deep clouds are invisible, but now the high altitude haze appears relatively bright against the dark background. High altitude haze is seen over the poles and the equator.

The Great Red Spot, prominent in all images, is

Airborne laser systems for atmospheric sounding in the near infrared

NASA Astrophysics Data System (ADS)

Sabatini, Roberto; Richardson, Mark A.; Jia, Huamin; Zammit-Mangion, David

2012-06-01

This paper presents new techniques for atmospheric sounding using Near Infrared (NIR) laser sources, direct detection electro-optics and passive infrared imaging systems. These techniques allow a direct determination of atmospheric extinction and, through the adoption of suitable inversion algorithms, the indirect measurement of some important natural and man-made atmospheric constituents, including Carbon Dioxide (CO2). The proposed techniques are suitable for remote sensing missions performed by using aircraft, satellites, Unmanned Aerial Vehicles (UAV), parachute/gliding vehicles, Roving Surface Vehicles (RSV), or Permanent Surface Installations (PSI). The various techniques proposed offer relative advantages in different scenarios. All are based on measurements of the laser energy/power incident on target surfaces of known geometric and reflective characteristics, by means of infrared detectors and/or infrared cameras calibrated for radiance. Experimental results are presented relative to ground and flight trials performed with laser systems operating in the near infrared (NIR) at λ = 1064 nm and λ = 1550 nm. This includes ground tests performed with 10 Hz and 20 KHz PRF NIR laser systems in a variety of atmospheric conditions, and flight trials performed with a 10 Hz airborne NIR laser system installed on a TORNADO aircraft, flying up to altitudes of 22,000 ft above ground level. Future activities are planned to validate the atmospheric retrieval algorithms developed for CO2 column density measurements, with emphasis on aircraft related emissions at airports and other high air-traffic density environments.

Near-infrared SN Ia Cosmology

NASA Astrophysics Data System (ADS)

Avelino, Arturo; Kirshner, Robert; Mandel, Kaisey; Challis, Peter; Friedman, Andrew; RAISIN Team

2018-01-01

Observations of SN Ia in the near infrared (NIR) are a promising way to construct an accurate cosmic expansion history to constrain the properties of dark energy. SN Ia are more nearly standard candles in NIR than in optical bands, while dust absorption is less of a problem at NIR wavelengths. This allows us to investigate the dark energy properties in a way that is less sensitive to systematic errors due to the variations in the intrinsic brightness of SN Ia or the properties of dust in their host galaxies. In this talk, I present preliminary results from our RAISIN 1 (HST GO-13046) and RAISIN 2 (HST GO-14216) programs with the Hubble Space Telescope, where we have constructed a Hubble diagram combining optical + NIR photometric data using a sample of low and high redshift SN Ia. I will discuss our current results, challenges, and the advantage of using optical + NIR data to derive accurate cosmic distances and improve knowledge of the dark energy equation of state. This research is supported by NSF grants AST-156854 and AST-1211196.

Pulsed near-infrared photoacoustic spectroscopy of blood

NASA Astrophysics Data System (ADS)

Laufer, Jan G.; Elwell, Clare E.; Delpy, Dave T.; Beard, Paul C.

2004-07-01

The aim of this study was to use pulsed near infrared photoacoustic spectroscopy to determine the oxygen saturation (SO2) of a saline suspension of red blood cells in vitro. The photoacoustic measurements were made in a cuvette which formed part of a larger circuit through which the red blood cell suspension was circulated. Oxygen saturation of the red blood cell suspension was altered between 2-3% to 100% in step increments using a membrane oxygenator and at each increment an independent measurement of oxygen saturation was made using a co-oximeter. An optical parametric oscillator laser system provided nanosecond excitation pulses at a number of wavelengths in the near-infrared spectrum (740-1040nm) which were incident on the cuvette. The resulting acoustic signals were detected using a broadband (15MHz) Fabry-Perot polymer film transducer. The optical transport coefficient and amplitude were determined from the acoustic signals as a function of wavelength. These data were then used to calculate the relative concentrations of oxy- and deoxyhaemoglobin, using their known specific absorption coefficients and an empirically determined wavelength dependence of optical scattering over the wavelength range investigated. From this, the oxygen saturation of the suspension was derived with an accuracy of +/-5% compared to the co-oximeter SO2 measurements.

Infrared spectroscopic imaging detects chemical modifications in liver fibrosis due to diabetes and disease

PubMed Central

Sreedhar, Hari; Varma, Vishal K.; Gambacorta, Francesca V.; Guzman, Grace; Walsh, Michael J.

2016-01-01

The importance of stroma as a rich diagnostic region in tissue biopsies is growing as there is an increasing understanding that disease processes in multiple organs can affect the composition of adjacent connective tissue regions. This may be especially true in the liver, since this organ’s central metabolic role exposes it to multiple disease processes. We use quantum cascade laser infrared spectroscopic imaging to study changes in the chemical status of hepatocytes and fibrotic regions of liver tissue that result from the progression of liver cirrhosis to hepatocellular carcinoma and the potentially confounding effects of diabetes mellitus. PMID:27375956

Observations and controls on the occurrence of inherited zircon in Concord-type granitoids, New Hampshire

USGS Publications Warehouse

Harrison, T.M.; Aleinikoff, J.N.; Compston, W.

1987-01-01

U-Pb analyses of zircons separated from two Concord-type plutons near Sunapee and Dixville Notch, New Hampshire, reveal differences in the pattern and magnitude of zircon inheritance which are related to differences in melt chemistry. The Sunapee pluton contains only slightly more Zr than required to saturate the melt at the peak temperature of 700 ?? 30??C. Traces of inherited zircon in this separate are inferred to be present as small, largely resorbed grains. In contrast, the Long Mountain pluton, near Dixville Notch, contains about 240% more Zr than required to saturate the melt. Thus, more than half of the Zr existed as stable, inherited zircon crystals during the partial fusion event, consistent with the observation of substantial inheritance in all grain size fractions. Ion probe intra-grain analyses of zircon from the Long Mountain pluton indicate a complex pattern of inheritance with contributions from at least two Proterozoic terrenes and caution against simple interpretations of upper and lower intercepts of chords containing an inherited component. Ion probe analyses of zircons from the Sunapee pluton reveal clear evidence of U loss which results in incorrect apparent conventional U-Pb ages. Ages of crystallization for the Long Mountain and Sunapee pluton are ~350 and 354 ?? 5 Ma, respectively. A Sm/Nd measurement for the Long Mountain pluton yields a depleted mantle model age of 1.5 Ga, consistent with the observed inheritance pattern. In contrast, a Sm/Nd model age for the Sunapee pluton is improbably old due to minor monazite fractionation. ?? 1987.

New Insights on the Recrystallization and New Growth of Extensively Radiation-damaged Zircon

NASA Astrophysics Data System (ADS)

Hanchar, J. M.; Schmitz, M. D.; Wirth, R.

2012-12-01

Approximately 10 grams of cm-sized nearly metamict zircon crystals from the Saranac Prospect in the Bancroft District of Ontario were combined by breaking into small pieces and then ground under ethanol to a fine powder with an agate mortar and pestle in order to make enough homogeneously mixed material for multiple powder X-Ray and diffraction scans, high-resolution transmission electron microscopy (HR-TEM) measurements, and chemical abrasion isotope dilution thermal ionization mass spectrometry (CA-TIMS). While these large zircon crystals ground to a powder have a larger surface area and not in the same physical state (i.e., brown and metamict) as what is typically analyzed in single zircon CA-ID-TIMS U-Pb analysis (clear euhedral grains), the physical and chemical changes that occur during the heat treatment used in CA-TIMS are thought to be similar processes. Aliquots of the ground zircon powder were annealed in situ using a Pt furnace in a powder diffractometer during which time simultaneous powder diffraction patterns were acquired starting at 25°C, at elevated temperature (from 500°C to 1400°C) at selected time intervals, and then again at 25°C. The powder X-ray diffraction results indicate that below ~900°C the recrystallization of the zircon powder commences but is incomplete, even after 36 hours, with diffuse low intensity diffraction peaks. At 1150°C the zircon powder shows significant recrystallization. At 1150°C, the recrystallization is essentially complete in less than one hour. Before heating the zircon powder samples consisted of clear, transparent to brown, translucent, complexly zoned fragments. After heating at 900°C the zircon powder retained a smaller percentage of clear or brown complexly zoned fragments, while the majority of material had transformed to oscillatory or irregularly zoned, dominantly white opaque microcrystalline fragments. The clear fragments were hypothesized to be preexisting original crystalline zircon, the brown

A quantitative evaluation of spurious results in the infrared spectroscopic measurement of CO2 isotope ratios

NASA Astrophysics Data System (ADS)

Mansfield, C. D.; Rutt, H. N.

2002-02-01

The possible generation of spurious results, arising from the application of infrared spectroscopic techniques to the measurement of carbon isotope ratios in breath, due to coincident absorption bands has been re-examined. An earlier investigation, which approached the problem qualitatively, fulfilled its aspirations in providing an unambiguous assurance that 13C16O2/12C16O2 ratios can be confidently measured for isotopic breath tests using instruments based on infrared absorption. Although this conclusion still stands, subsequent quantitative investigation has revealed an important exception that necessitates a strict adherence to sample collection protocol. The results show that concentrations and decay rates of the coincident breath trace compounds acetonitrile and carbon monoxide, found in the breath sample of a heavy smoker, can produce spurious results. Hence, findings from this investigation justify the concern that breath trace compounds present a risk to the accurate measurement of carbon isotope ratios in breath when using broadband, non-dispersive, ground state absorption infrared spectroscopy. It provides recommendations on the length of smoking abstention required to avoid generation of spurious results and also reaffirms, through quantitative argument, the validity of using infrared absorption spectroscopy to measure CO2 isotope ratios in breath.

Near-infrared spectroscopy can reveal increases in brain activity related to animal-assisted therapy.

PubMed

Morita, Yuka; Ebara, Fumio; Morita, Yoshimitsu; Horikawa, Etsuo

2017-08-01

[Purpose] Previous studies have indicated that animal-assisted therapy can promote recovery of psychological, social, and physiological function in mental disorders. This study was designed as a pilot evaluation of the use of near-infrared spectroscopy to objectively identify changes in brain activity that could mediate the effect of animal-assisted therapy. [Subjects and Methods] The participants were 20 healthy students (10 males and 10 females; age 19-21 years) of the Faculty of Agriculture, Saga University. Participants were shown a picture of a Tokara goat or shack (control) while prefrontal cortical oxygenated haemoglobin levels (representing neural activity) were measured by near-infrared spectroscopy. [Results] The prefrontal cortical near-infrared spectroscopy signal was significantly higher during viewing of the animal picture than during a rest condition or during viewing of the control picture. [Conclusion] Our results suggest that near-infrared spectroscopy can be used to objectively identify brain activity changes during human mentation regarding animals; furthermore, these preliminary results suggest the efficacy of animal-assisted therapy could be related to increased activation of the prefrontal cortex.

Validation of a high-power, time-resolved, near-infrared spectroscopy system for measurement of superficial and deep muscle deoxygenation during exercise.

PubMed

Koga, Shunsaku; Barstow, Thomas J; Okushima, Dai; Rossiter, Harry B; Kondo, Narihiko; Ohmae, Etsuko; Poole, David C

2015-06-01

Near-infrared assessment of skeletal muscle is restricted to superficial tissues due to power limitations of spectroscopic systems. We reasoned that understanding of muscle deoxygenation may be improved by simultaneously interrogating deeper tissues. To achieve this, we modified a high-power (∼8 mW), time-resolved, near-infrared spectroscopy system to increase depth penetration. Precision was first validated using a homogenous optical phantom over a range of inter-optode spacings (OS). Coefficients of variation from 10 measurements were minimal (0.5-1.9%) for absorption (μa), reduced scattering, simulated total hemoglobin, and simulated O2 saturation. Second, a dual-layer phantom was constructed to assess depth sensitivity, and the thickness of the superficial layer was varied. With a superficial layer thickness of 1, 2, 3, and 4 cm (μa = 0.149 cm(-1)), the proportional contribution of the deep layer (μa = 0.250 cm(-1)) to total μa was 80.1, 26.9, 3.7, and 0.0%, respectively (at 6-cm OS), validating penetration to ∼3 cm. Implementation of an additional superficial phantom to simulate adipose tissue further reduced depth sensitivity. Finally, superficial and deep muscle spectroscopy was performed in six participants during heavy-intensity cycle exercise. Compared with the superficial rectus femoris, peak deoxygenation of the deep rectus femoris (including the superficial intermedius in some) was not significantly different (deoxyhemoglobin and deoxymyoglobin concentration: 81.3 ± 20.8 vs. 78.3 ± 13.6 μM, P > 0.05), but deoxygenation kinetics were significantly slower (mean response time: 37 ± 10 vs. 65 ± 9 s, P ≤ 0.05). These data validate a high-power, time-resolved, near-infrared spectroscopy system with large OS for measuring the deoxygenation of deep tissues and reveal temporal and spatial disparities in muscle deoxygenation responses to exercise. Copyright © 2015 the American Physiological Society.

Aqueous synthesis of near-infrared highly fluorescent platinum nanoclusters

NASA Astrophysics Data System (ADS)

García Fernández, Jenifer; Trapiella-Alfonso, Laura; Costa-Fernández, José M.; Pereiro, Rosario; Sanz-Medel, Alfredo

2015-05-01

A one-step synthesis of near infrared fluorescent platinum nanoclusters (PtNCs) in aqueous medium is described. The proposed optimized procedure for PtNC synthesis is rather simple, fast and it is based on the direct metal reduction with NaBH4. Bidentated thiol ligands (lipoic acid) were selected as nanoclusters stabilizers in water media. The structural characterization revealed attractive features of the PtNCs, including small size, high water solubility, near-infrared luminescence centered at 680 nm, long-term stability and the highest quantum yield in water reported so far (47%) for PtNCs. Moreover, their stability in different pH media and an ionic strength of 0.2 M NaCl was studied and no significant changes in fluorescence emission were detected. In brief, they offer a new type of fluorescent noble metal nanoprobe with a great potential to be applied in several fields, including biolabeling and imaging experiments.

Near-field effect in the infrared range through periodic Germanium subwavelength arrays.

PubMed

Dong, Wei; Hirohata, Toru; Nakajima, Kazutoshi; Wang, Xiaoping

2013-11-04

Using finite-difference-time-domain simulation, we have studied the near-field effect of Germanium (Ge) subwavelength arrays designed in-plane with a normal incidence. Spectra of vertical electric field component normal to the surface show pronounced resonance peaks in an infrared range, which can be applied in a quantum well infrared photodetector. Unlike the near-field optics in metallic systems that are commonly related to surface plasmons, the intense vertical field along the surface of the Ge film can be interpreted as a combination of diffraction and waveguide theory. The existence of the enhanced field is confirmed by measuring the Fourier transform infrared spectra of fabricated samples. The positions of the resonant peaks obtained in experiment are in good agreement with our simulations.

Phase-locked, erbium-fiber-laser-based frequency comb in the near infrared.

PubMed

Washburn, Brian R; Diddams, Scott A; Newbury, Nathan R; Nicholson, Jeffrey W; Yan, Man F; Jørgensen, Carsten G

2004-02-01

A phase-locked frequency comb in the near infrared is demonstrated with a mode-locked, erbium-doped, fiber laser whose output is amplified and spectrally broadened in dispersion-flattened, highly nonlinear optical fiber to span from 1100 to >2200 nm. The supercontinuum output comprises a frequency comb with a spacing set by the laser repetition rate and an offset by the carrier-envelope offset frequency, which is detected with the standard f-to-2f heterodyne technique. The comb spacing and offset frequency are phase locked to a stable rf signal with a fiber stretcher in the laser cavity and by control of the pump laser power, respectively. This infrared comb permits frequency metrology experiments in the near infrared in a compact, fiber-laser-based system.

Confocal Retinal Imaging Using a Digital Light Projector with a Near Infrared VCSEL Source

PubMed Central

Muller, Matthew S.; Elsner, Ann E.

2018-01-01

A custom near infrared VCSEL source has been implemented in a confocal non-mydriatic retinal camera, the Digital Light Ophthalmoscope (DLO). The use of near infrared light improves patient comfort, avoids pupil constriction, penetrates the deeper retina, and does not mask visual stimuli. The DLO performs confocal imaging by synchronizing a sequence of lines displayed with a digital micromirror device to the rolling shutter exposure of a 2D CMOS camera. Real-time software adjustments enable multiply scattered light imaging, which rapidly and cost-effectively emphasizes drusen and other scattering disruptions in the deeper retina. A separate 5.1″ LCD display provides customizable visible stimuli for vision experiments with simultaneous near infrared imaging. PMID:29899586

Confocal retinal imaging using a digital light projector with a near infrared VCSEL source

NASA Astrophysics Data System (ADS)

Muller, Matthew S.; Elsner, Ann E.

2018-02-01

A custom near infrared VCSEL source has been implemented in a confocal non-mydriatic retinal camera, the Digital Light Ophthalmoscope (DLO). The use of near infrared light improves patient comfort, avoids pupil constriction, penetrates the deeper retina, and does not mask visual stimuli. The DLO performs confocal imaging by synchronizing a sequence of lines displayed with a digital micromirror device to the rolling shutter exposure of a 2D CMOS camera. Real-time software adjustments enable multiply scattered light imaging, which rapidly and cost-effectively emphasizes drusen and other scattering disruptions in the deeper retina. A separate 5.1" LCD display provides customizable visible stimuli for vision experiments with simultaneous near infrared imaging.

Zircon growth in shear zones

NASA Astrophysics Data System (ADS)

Kaulina, Tatiana

2013-04-01

The possibility of direct dating of the deformation process is critical for understanding of orogenic belts evolution. Establishing the age of deformation by isotopic methods is indispensable in the case of uneven deformation overlapping, when later deformation inherits the structural plan of the early strains, and to distinguish them on the basis of the structural data only is impossible. A good example of zircon from the shear zones is zircon formed under the eclogite facies conditions. On the one hand, the composition of zircon speaks about its formation simultaneously to eclogitic paragenesis (Rubatto, Herman, 1999; Rubatto et al., 2003). On the other hand, geological studies show that mineral reactions of eclogitization are often held only in areas of shear deformations, which provides access of fluid to the rocks (Austrheim, 1987; Jamtveit et al., 2000; Bingen et al., 2004). Zircons from mafic and ultramafic rocks of the Tanaelv and Kolvitsa belts (Kola Peninsula, the Baltic Shield) have showed that the metamorphic zircon growth is probably controlled by the metamorphic fluid regime, as evidenced by an increase of zircon quantity with the degree of shearing. The internal structure of zircon crystals can provide an evidence of zircon growth synchronous with shearing. The studied crystals have a sector zoning and often specific "patchy" zoning (Fig. 1), which speaks about rapid change of growth conditions. Such internal structure can be compared with the "snowball" garnet structure reflecting the rotation of crystals during their growth under a shift. Rapidly changing crystallization conditions can also be associated with a small amount of fluid, where supersaturation is changing even at a constant temperature. Thus, the growth of metamorphic zircon in shear zones is more likely to occur in the fluid flow synchronous with deformation. A distinctive feature of zircons in these conditions is isometric shape and sector "patchy" zoning. The work was supported by

Topological Crystalline Insulator SnTe/Si Vertical Heterostructure Photodetectors for High-Performance Near-Infrared Detection.

PubMed

Zhang, Hongbin; Man, Baoyuan; Zhang, Qi

2017-04-26

Due to the gapless surface state and narrow bulk band gap, the light absorption of topological crystalline insulators covers a broad spectrum ranging from terahertz to infrared, revealing promising applications in new generation optoelectronic devices. To date, the photodetectors based on topological insulators generally suffer from a large dark current and a weaker photocurrent especially under the near-infrared lights, which severely limits the practical application of devices. Owing to the lower excitation energy of infrared lights, the photodetection application of topological crystalline insulators in the near-infrared region relies critically on understanding the preparation and properties of their heterostructures. Herein, we fabricate the high-quality topological crystalline insulator SnTe film/Si vertical heterostructure by a simple physical vapor deposition process. The resultant heterostructure exhibits an excellent diode characteristic, enabling the construction of high-performance near-infrared photodetectors. The built-in electric field at SnTe/Si interface enhances the absorption efficiency of near-infrared lights and greatly facilitates the separation of photogenerated carriers, making the device capable of operating as a self-driven photodetector. The as-grown SnTe film acts as the hole transport layer in heterostructure photodetectors, promoting the transport of holes to electrode and reducing electron-hole recombination effectively. These merits enable the SnTe/Si heterostructure photodetector to have a high responsivity of 2.36 AW -1 , a high detectivity of 1.54 × 10 14 Jones, and a large bandwidth of 10 4 Hz in the near-infrared wavelength, which makes the detector have a promising market in novel device applications.

Mesenteric near-infrared spectroscopy and risk of gastrointestinal complications in infants undergoing surgery for congenital heart disease.

PubMed

Iliopoulos, Ilias; Branco, Ricardo G; Brinkhuis, Nadine; Furck, Anke; LaRovere, Joan; Cooper, David S; Pathan, Nazima

2016-04-01

We hypothesised that lower mesenteric near-infrared spectroscopy values would be associated with a greater incidence of gastrointestinal complications in children weighing <10 kg who were recovering from cardiac surgery. We evaluated mesenteric near-infrared spectroscopy, central venous oxygen saturation, and arterial blood gases for 48 hours post-operatively. Enteral feeding intake, gastrointestinal complications, and markers of organ dysfunction were monitored for 7 days. A total of 50 children, with median age of 16.7 (3.2-31.6) weeks, were studied. On admission, the average mesenteric near-infrared spectroscopy value was 71±18%, and the systemic oxygen saturation was 93±7.5%. Lower admission mesenteric near-infrared spectroscopy correlated with longer time to establish enteral feeds (r=-0.58, p<0.01) and shorter duration of feeds at 7 days (r=0.48, p<0.01). Children with gastrointestinal complications had significantly lower admission mesenteric near-infrared spectroscopy (58±18% versus 73±17%, p=0.01) and higher mesenteric arteriovenous difference of oxygen at admission [39 (23-47) % versus 19 (4-27) %, p=0.02]. Based on multiple logistic regression, admission mesenteric near-infrared spectroscopy was independently associated with gastrointestinal complications (Odds ratio, 0.95; 95% confidence interval, 0.93-0.97; p=0.03). Admission mesenteric near-infrared spectroscopy showed an area under the receiver operating characteristic curve of 0.76 to identify children who developed gastrointestinal complications, with a suggested cut-off value of 72% (78% sensitivity, 68% specificity). In this pilot study, we conclude that admission mesenteric near-infrared spectroscopy is associated with gastrointestinal complications and enteral feeding tolerance in children after cardiac surgery.

Intraoperative Near-Infrared Fluorescence Imaging using indocyanine green in colorectal carcinomatosis surgery: Proof of concept.

PubMed

Barabino, G; Klein, J P; Porcheron, J; Grichine, A; Coll, J-L; Cottier, M

2016-12-01

This study assesses the value of using Intraoperative Near Infrared Fluorescence Imaging and Indocyanine green to detect colorectal carcinomatosis during oncological surgery. In colorectal carcinomatosis cancer, two of the most important prognostic factors are completeness of staging and completeness of cytoreductive surgery. Presently, intraoperative assessment of tumoral margins relies on palpation and visual inspection. The recent introduction of Near Infrared fluorescence image guidance provides new opportunities for surgical roles, particularly in cancer surgery. The study was a non-randomized, monocentric, pilot "ex vivo" blinded clinical trial validated by the ethical committee of University Hospital of Saint Etienne. Ten patients with colorectal carcinomatosis cancer scheduled for cytoreductive surgery were included. Patients received 0.25 mg/kg of Indocyanine green intravenously 24 h before surgery. A Near Infrared camera was used to detect "ex-vivo" fluorescent lesions. There was no surgical mortality. Each analysis was done blindly. In a total of 88 lesions analyzed, 58 were classified by a pathologist as cancerous and 30 as non-cancerous. Among the 58 cancerous lesions, 42 were correctly classified by the Intraoperative Near-Infrared camera (sensitivity of 72.4%). Among the 30 non-cancerous lesions, 18 were correctly classified by the Intraoperative Near-Infrared camera (specificity of 60.0%). Near Infrared fluorescence imaging is a promising technique for intraoperative tumor identification. It could help the surgeon to determine resection margins and reduce the risk of locoregional recurrence. Copyright © 2016 Elsevier Ltd, BASO ~ the Association for Cancer Surgery, and the European Society of Surgical Oncology. All rights reserved.

Infrared-spectroscopic single-shot laser mapping ellipsometry: Proof of concept for fast investigations of structured surfaces and interactions in organic thin films

NASA Astrophysics Data System (ADS)

Furchner, Andreas; Kratz, Christoph; Gkogkou, Dimitra; Ketelsen, Helge; Hinrichs, Karsten

2017-11-01

We present a novel infrared-spectroscopic laser mapping ellipsometer based on a single-shot measurement concept. The ellipsometric set-up employs multiple analyzers and detectors to simultaneously measure the sample's optical response under different analyzer azimuths. An essential component is a broadly tunable quantum cascade laser (QCL) covering the important marker region of 1800-1540 cm-1. The ellipsometer allows for fast single-wavelength as well as spectroscopic studies with thin-film sensitivity at temporal resolutions of 60 ms per wavelength. We applied the single-shot mapping ellipsometer for the characterization of metal-island enhancement surfaces as well as of molecular interactions in organic thin films. In less than 3 min, a linescan with 1600 steps revealed profile and infrared-enhancement properties of a gradient gold-island film for sensing applications. Spectroscopic measurements were performed to probe the amide I band of thin films of poly(N-isopropylacrylamide) [PNIPAAm], a stimuli-responsive polymer for bioapplications. The QCL spectra agree well with conventional FT-IR ellipsometric results, showing different band components associated with hydrogen-bond interactions between polymer and adsorbed water. Multi-wavelength ellipsometric maps were used to analyze homogeneity and surface contaminations of the polymer films.

KENNEDY SPACE CENTER, FLA. - Workers in KSC's Vertical Processing Facility inspect the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) on its handling fixture. NICMOS is one of two new scientific instruments that will replace two outdated instruments on the Hubble Space Telescope (HST). NICMOS will provide HST with the capability for infrared imaging and spectroscopic observations of astronomical targets. The refrigerator-sized NICMOS also is HST's first cryogenic instrument — its sensitive infrared detectors must operate at very cold temperatures of minus 355 degrees Fahrenheit or 58 degrees Kelvin. NICMOS will be installed in Hubble during STS-82, the second Hubble Space Telescope servicing mission. Liftoff is targeted Feb. 11 aboard Discovery with a crew of seven.

NASA Image and Video Library

1997-01-18

KENNEDY SPACE CENTER, FLA. - Workers in KSC's Vertical Processing Facility inspect the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) on its handling fixture. NICMOS is one of two new scientific instruments that will replace two outdated instruments on the Hubble Space Telescope (HST). NICMOS will provide HST with the capability for infrared imaging and spectroscopic observations of astronomical targets. The refrigerator-sized NICMOS also is HST's first cryogenic instrument — its sensitive infrared detectors must operate at very cold temperatures of minus 355 degrees Fahrenheit or 58 degrees Kelvin. NICMOS will be installed in Hubble during STS-82, the second Hubble Space Telescope servicing mission. Liftoff is targeted Feb. 11 aboard Discovery with a crew of seven.

KENNEDY SPACE CENTER, FLA. - Workers in KSC's Vertical Processing Facility lower the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) into the Second Axial Carrier. NICMOS is one of two new scientific instruments that will replace two outdated instruments on the Hubble Space Telescope (HST). NICMOS will provide HST with the capability for infrared imaging and spectroscopic observations of astronomical targets. The refrigerator-sized NICMOS also is HST's first cryogenic instrument — its sensitive infrared detectors must operate at very cold temperatures of minus 355 degrees Fahrenheit or 58 degrees Kelvin. NICMOS will be installed in Hubble during STS-82, the second Hubble Space Telescope servicing mission. Liftoff is targeted Feb. 11 aboard Discovery with a crew of seven.

NASA Image and Video Library

1997-01-18

KENNEDY SPACE CENTER, FLA. - Workers in KSC's Vertical Processing Facility lower the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) into the Second Axial Carrier. NICMOS is one of two new scientific instruments that will replace two outdated instruments on the Hubble Space Telescope (HST). NICMOS will provide HST with the capability for infrared imaging and spectroscopic observations of astronomical targets. The refrigerator-sized NICMOS also is HST's first cryogenic instrument — its sensitive infrared detectors must operate at very cold temperatures of minus 355 degrees Fahrenheit or 58 degrees Kelvin. NICMOS will be installed in Hubble during STS-82, the second Hubble Space Telescope servicing mission. Liftoff is targeted Feb. 11 aboard Discovery with a crew of seven.

KENNEDY SPACE CENTER, FLA. - Workers in KSC's Vertical Processing Facility lower the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) into the Second Axial Carrier. NICMOS is one of two new scientific instruments that will replace two outdated instruments on the Hubble Space Telescope (HST). NICMOS will provide HST with the capability for infrared imaging and spectroscopic observations of astronomical targets. The refrigerator-sized NICMOS is HST's first cryogenic instrument -- its sensitive infrared detectors must operate at very cold temperatures of minus 355 degrees Fahrenheit or 58 derees Kelvin. NICMOS will be installed in Hubble during STS-82, the second Hubble Space Telescope servicing mission. Liftoff is targeted Feb. 11 aboard Discovery with a crew of seven.

NASA Image and Video Library

1997-01-16

KENNEDY SPACE CENTER, FLA. - Workers in KSC's Vertical Processing Facility lower the Near Infrared Camera and Multi-Object Spectrometer (NICMOS) into the Second Axial Carrier. NICMOS is one of two new scientific instruments that will replace two outdated instruments on the Hubble Space Telescope (HST). NICMOS will provide HST with the capability for infrared imaging and spectroscopic observations of astronomical targets. The refrigerator-sized NICMOS is HST's first cryogenic instrument -- its sensitive infrared detectors must operate at very cold temperatures of minus 355 degrees Fahrenheit or 58 derees Kelvin. NICMOS will be installed in Hubble during STS-82, the second Hubble Space Telescope servicing mission. Liftoff is targeted Feb. 11 aboard Discovery with a crew of seven.

Time-Resolved Near-Infrared Photometry of Extreme Kuiper Belt Object Haumea

NASA Astrophysics Data System (ADS)

Lacerda, Pedro

2009-02-01

We present time-resolved near-infrared (J and H) photometry of the extreme Kuiper belt object (136108) Haumea (formerly 2003 EL61) taken to further investigate rotational variability of this object. The new data show that the near-infrared peak-to-peak photometric range is similar to the value at visible wavelengths, ΔmR = 0.30 ± 0.02 mag. Detailed analysis of the new and previous data reveals subtle visible/near-infrared color variations across the surface of Haumea. The color variations are spatially correlated with a previously identified surface region, redder in B - R and darker than the mean surface. Our photometry indicates that the J - H colors of Haumea (J - H = -0.057 ± 0.016 mag) and its brightest satellite Hi'iaka (J - H = -0.399 ± 0.034 mag) are significantly (greater than 9σ) different. The satellite Hi'iaka is unusually blue in J - H, consistent with strong 1.5 μm water-ice absorption. The phase coefficient of Haumea is found to increase monotonically with wavelength in the range 0.4 < λ < 1.3. We compare our findings with other solar system objects and discuss implications regarding the surface of Haumea.

Near-infrared laser irradiation improves the development of mouse pre-implantation embryos

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yokoo, Masaki; Mori, Miho

The aim of the present study was to assess the effects of near-infrared laser irradiation on the in vitro development of mouse embryos. Female ICR mice were superovulated with pregnant mare serum gonadotropin and human chorionic gonadotropin (hCG), and mated with male mice. Two-cell stage embryos were collected 40 h after administering hCG and cultured in M16 medium. Two-cell embryos (0 h after culture), 8-cell embryos (approx. 30 h after culture), morula (approx. 48 h after culture), and blastocysts (approx. 73 h after culture) were irradiated at 904 nm for 60 s. These embryos were cultured in a time-lapse monitoring system and the timing ofmore » blastocyst hatching was evaluated. Some of the irradiated blastocysts were transferred to the uterine horns of pseudopregnant recipients immediately after irradiation. Pregnancy rates, and offspring growth and fertility, were evaluated. Near-infrared laser irradiation increased the speed of in vitro mouse embryo development. In irradiated blastocysts, hatching was faster than in control (non-irradiated) blastocysts (18.4 vs. 28.2 h, P < 0.05). When 195 irradiated blastocysts were transferred to 18 pseudopregnant mice, all became pregnant and 92 (47.2%) normal-looking pups were born alive. When 182 control blastocysts were transferred to 17 pseudopregnant mice, 14 (82.4%) became pregnant and 54 (29.7%) normal-looking pups were born alive. The growth trajectories (up to 5 weeks) of offspring from irradiated blastocysts were similar to those from control blastocysts. Second generation offspring from transplanted animals were all fertile. These results indicate that near-infrared laser irradiation improves the quality of mouse embryo development in vitro, and increases the live birth rate without affecting the normality of the offspring. Thus, the near-infrared laser method may enhance the quality of embryos and contribute to improvements in reproductive technologies in mammals. - Highlights: • Irradiation of

Towards a low-cost mobile subcutaneous vein detection solution using near-infrared spectroscopy.

PubMed

Juric, Simon; Flis, Vojko; Debevc, Matjaz; Holzinger, Andreas; Zalik, Borut

2014-01-01

Excessive venipunctures are both time- and resource-consuming events, which cause anxiety, pain, and distress in patients, or can lead to severe harmful injuries. We propose a low-cost mobile health solution for subcutaneous vein detection using near-infrared spectroscopy, along with an assessment of the current state of the art in this field. The first objective of this study was to get a deeper overview of the research topic, through the initial team discussions and a detailed literature review (using both academic and grey literature). The second objective, that is, identifying the commercial systems employing near-infrared spectroscopy, was conducted using the PubMed database. The goal of the third objective was to identify and evaluate (using the IEEE Xplore database) the research efforts in the field of low-cost near-infrared imaging in general, as a basis for the conceptual model of the upcoming prototype. Although the reviewed commercial devices have demonstrated usefulness and value for peripheral veins visualization, other evaluated clinical outcomes are less conclusive. Previous studies regarding low-cost near-infrared systems demonstrated the general feasibility of developing cost-effective vein detection systems; however, their limitations are restricting their applicability to clinical practice. Finally, based on the current findings, we outline the future research direction.

Towards a Low-Cost Mobile Subcutaneous Vein Detection Solution Using Near-Infrared Spectroscopy

PubMed Central

Flis, Vojko; Debevc, Matjaz; Holzinger, Andreas; Zalik, Borut

2014-01-01

Excessive venipunctures are both time- and resource-consuming events, which cause anxiety, pain, and distress in patients, or can lead to severe harmful injuries. We propose a low-cost mobile health solution for subcutaneous vein detection using near-infrared spectroscopy, along with an assessment of the current state of the art in this field. The first objective of this study was to get a deeper overview of the research topic, through the initial team discussions and a detailed literature review (using both academic and grey literature). The second objective, that is, identifying the commercial systems employing near-infrared spectroscopy, was conducted using the PubMed database. The goal of the third objective was to identify and evaluate (using the IEEE Xplore database) the research efforts in the field of low-cost near-infrared imaging in general, as a basis for the conceptual model of the upcoming prototype. Although the reviewed commercial devices have demonstrated usefulness and value for peripheral veins visualization, other evaluated clinical outcomes are less conclusive. Previous studies regarding low-cost near-infrared systems demonstrated the general feasibility of developing cost-effective vein detection systems; however, their limitations are restricting their applicability to clinical practice. Finally, based on the current findings, we outline the future research direction. PMID:24883388

Near Infrared Emission from Defects in Few-Layer Phosphorene

NASA Astrophysics Data System (ADS)

Aghaeimeibodi, Shahriar; Kim, Je-Hyung; Waks, Edo

Atomically thin films of black phosphorus have recently received significant attention as low dimensional optical materials with a direct exciton emission whose wavelength is tunable by controlling the number of layers. In addition to this excitonic emission, recent work has revealed emission from defect states and reported new methods to manipulate them. Monolayer phosphorene exhibits emission from localized defect states at wavelengths near 920 nm. Increasing the number of layers should shift defect emission to longer wavelengths, enabling the material to span a broader spectral range. But defect emission from few-layer phosphorene has not yet been reported. Here, we demonstrate a new class of near infrared defects in few layer phosphorene. Photoluminescence measurement shows a bright emission around 1240 nm with a sublinear growth of emission intensity with linear increase of excitation intensity, confirming the defect nature of this emission. From time-resolved lifetime measurements we determine an emission lifetime of 1.2 ns, in contrast to exciton and trion lifetimes from few layer phosphorene previously reported to be in the range of a few hundred picoseconds. This work highlights the potential of bright defects of phosphorene for near infrared optoelectronic applications.

Near-field infrared vibrational dynamics and tip-enhanced decoherence.

PubMed

Xu, Xiaoji G; Raschke, Markus B

2013-04-10

Ultrafast infrared spectroscopy can reveal the dynamics of vibrational excitations in matter. In its conventional far-field implementation, however, it provides only limited insight into nanoscale sample volumes due to insufficient spatial resolution and sensitivity. Here, we combine scattering-scanning near-field optical microscopy (s-SNOM) with femtosecond infrared vibrational spectroscopy to characterize the coherent vibrational dynamics of a nanoscopic ensemble of C-F vibrational oscillators of polytetrafluoroethylene (PTFE). The near-field mode transfer between the induced vibrational molecular coherence and the metallic scanning probe tip gives rise to a tip-mediated radiative IR emission of the vibrational free-induction decay (FID). By increasing the tip–sample coupling, we can enhance the vibrational dephasing of the induced coherent vibrational polarization and associated IR emission, with dephasing times up to T2(NF) is approximately equal to 370 fs in competition against the intrinsic far-field lifetime of T2(FF) is approximately equal to 680 fs as dominated by nonradiative damping. Near-field antenna-coupling thus provides for a new way to modify vibrational decoherence. This approach of ultrafast s-SNOM enables the investigation of spatiotemporal dynamics and correlations with nanometer spatial and femtosecond temporal resolution.

Computer-aided design of peptide near infrared fluorescent probe for tumor diagnosis

NASA Astrophysics Data System (ADS)

Zhang, Congying; Gu, Yueqing

2014-09-01

Integrin αvβ3 receptors are expressed on activated endothelial cells during neovascularization to maintain tumor growth, so they become hot research tagets in cancer diagnosis. Peptides possess several attractive features when compared to protein and small molecule, such as small size and high structural compatibility with target proteins. Efficient design of high-affinity peptide ligands to Integrin αvβ3 receptors has been an important problem. Designed peptides in silico provide a valuable and high-selectivity peptide, meanwhile decrease the time of drug screening. In this study, we design peptide which can bind with integrin αvβ3 via computer, and then synthesis near infrared fluorescent probe. The characterization of this near infrared fluorescent probe was detected by UV. To investigate the tumor cell targeting of this probe, it was labeled with visible fluorescent dye Rhodamine B (RhB) for microscopy. To evaluate the targeting capability of this near infrared fluorescent probe, mice bearing integrin αvβ3 positive tumor xenografts were used. In vitro cellular experiments indicated that this probe have a clear binding affinity to αvβ3-positive tumor cells. In vivo experiments confirmed the receptor binding specificity of this probe. The peptide of computational design can bind with integrin αvβ3. Combined peptide near-infrared fluorescent probe with imaging technology use for clinical and tumor diagnosis have a greater development in future.

Optical constants of neat liquid-chemical warfare agents and related materials measured by infrared spectroscopic ellipsometry

NASA Astrophysics Data System (ADS)

Yang, C. S.-C.; Williams, B. R.; Hulet, M. S.; Tiwald, T. E.; Miles, R. W., Jr.; Samuels, A. C.

2011-05-01

We studied various liquids using a vertical attenuated total reflection (ATR) liquid sampling assembly in conjunction with Infrared Variable Angle Spectroscopic Ellipsometry (IR-VASE), to determine the infrared optical constants of several bulk liquids related to chemical warfare. The index of refraction, n, and the extinction coefficient, k, of isopropyl methylphosphonofluoridate (Sarin or GB), isopropyl alcohol (IPA) (a precursor of GB), and dimethyl methylphosphonate (DMMP)-a commonly employed simulant for GB, measured by our vertical ATR IR-VASE setup are closely matched to those found in other studies. We also report the optical constants of cyclohexyl methylphosphonofluoridate (GF), 2-(diisopropylamino)ethyl methylphosphonothioate (VX), bis-(2-chloroethyl) sulfide (HD), and 2-chlorovinyl dichloroarsine (L, Lewisite). The ATR IR-VASE technique affords an accurate measurement of the optical constants of these hazardous compounds.

Circumnuclear Regions In Barred Spiral Galaxies. 1; Near-Infrared Imaging

NASA Technical Reports Server (NTRS)

Perez-Ramirez, D.; Knapen, J. H.; Peletier, R. F.; Laine, S.; Doyon, R.; Nadeau, D.

2000-01-01

We present sub-arcsecond resolution ground-based near-infrared images of the central regions of a sample of twelve barred galaxies with circumnuclear star formation activity, which is organized in ring-like regions typically one kiloparsec in diameter. We also present Hubble Space Telescope near-infrared images of ten of our sample galaxies, and compare them with our ground-based data. Although our sample galaxies were selected for the presence of circumnuclear star formation activity, our broad-band near-infrared images are heterogeneous, showing a substantial amount of small-scale structure in some galaxies, and practically none in others. We argue that, where it exists, this structure is caused by young stars, which also cause the characteristic bumps or changes in slope in the radial profiles of ellipticity, major axis position angle, surface brightness and colour at the radius of the circumnuclear ring in most of our sample galaxies. In 7 out of 10 HST images, star formation in the nuclear ring is clearly visible as a large number of small emitting regions, organised into spiral arm fragments, which are accompanied by dust lanes. NIR colour index maps show much more clearly the location of dust lanes and, in certain cases, regions of star formation than single broad-band images. Circumnuclear spiral structure thus outlined appears to be common in barred spiral galaxies with circumnuclear star formation.

Luminescence studies and infrared emission of erbium-doped calcium zirconate phosphor.

PubMed

Tiwari, Neha; Dubey, Vikas

2016-05-01

The near-infrared-to-visible upconversion luminescence behaviour of Er(3+)-doped CaZrO3 phosphor is discussed in this manuscript. The phosphor was prepared by a combustion synthesis technique that is suitable for less-time-taking techniques for nanophosphors. The starting materials used for sample preparation were Ca(NO3)2.4H2O, Zr(NO3)4 and Er(NO3)2, and urea was used as a fuel. The prepared sample was characterized by X-ray diffraction (XRD). The surface morphology of prepared phosphor was determined by field emission gun scanning electron microscopy (FEGSEM). The functional group analysis was determined by Fourier transform infrared (FTIR) spectroscopy. All prepared phosphors with variable Er(3+) concentrations (0.5-2.5 mol%) were studied by photoluminescence analysis. It was found that the excitation spectra of the prepared phosphor showed a sharp excitation peak centred at 980 nm. The emission spectra with variable Er(3+) concentrations showed strong peaks in the 555 nm and 567 nm range, with a dominant peak at 555 nm due to the ((2)H(11/2),(4)S(3/2)) transition and a weaker transition at 567 nm associated with 527 nm. Spectrophotometric determination of the peak was evaluated by the Commission Internationale de I'Eclairage (CIE) method These upconverted emissions were attributed to a two-photon process. The excitation wavelength dependence of the upconverted luminescence, together with its time evolution after infrared pulsed excitation, suggested that energy transfer upconversion processes were responsible for the upconversion luminescence. The upconversion mechanisms were studied in detail through laser power dependence. Excited state absorption and energy transfer processes were discussed as possible upconversion mechanisms. The cross-relaxation process in Er(3+) was also investigated. Copyright © 2015 John Wiley & Sons, Ltd.

Spectroscopic planetary detection

NASA Technical Reports Server (NTRS)

Deming, Drake

1991-01-01

One of the most promising methods for the detection of extra-solar planets is the spectroscopic method, where a small Doppler shift (approx. 10 meter/sec) in the spectrum of the parent star reveals the presence of planetary companions. However, solar type stars may show spurious Doppler shifts due to surface activity. If these effects are periodic, as is the solar activity cycle, then they may masquerade as planetary companions. The goal of this study was to determine whether the solar cycle affects the Doppler stability of integrated sunlight. Observations of integrated sunlight were made in the near infrared (approx. 2 micron), using the Kitt Peak McMath Fourier transform spectrometer, with a N2O gas absorption cell for calibration. An accuracy of approx. 5 meter/sec was achieved.

Near-infrared diode laser based spectroscopic detection of ammonia: a comparative study of photoacoustic and direct optical absorption methods

NASA Technical Reports Server (NTRS)

Bozoki, Zoltan; Mohacsi, Arpad; Szabo, Gabor; Bor, Zsolt; Erdelyi, Miklos; Chen, Weidong; Tittel, Frank K.

2002-01-01

A photoacoustic spectroscopic (PAS) and a direct optical absorption spectroscopic (OAS) gas sensor, both using continuous-wave room-temperature diode lasers operating at 1531.8 nm, were compared on the basis of ammonia detection. Excellent linear correlation between the detector signals of the two systems was found. Although the physical properties and the mode of operation of both sensors were significantly different, their performances were found to be remarkably similar, with a sub-ppm level minimum detectable concentration of ammonia and a fast response time in the range of a few minutes.

The Coma Cluster Luminosity Function from Ultraviolet to Near-Infrared

NASA Astrophysics Data System (ADS)

Andreon, S.; Cuillandre, J.-C.; Pello, R.

The Coma cluster luminosity function (LF) from ultraviolet (2000 AA ) to the near-infrared (H band) is summarized. In the UV the LF is very steep, much steeper than in the optical. The steep Coma UV LF implies that faint and bright galaxies give similar contributions to the total UV flux and to the total metal production rate. The ComaUV LF is dominated in number and luminosity by blue galaxies, which are often faint in the optical. Therefore the Coma UV LF is dominated by star forming galaxies, not by massive and large galaxies. The optical Coma LF is relatively steep (alpha=-1.4) over the 11 magnitudes sampled, but its slope and shape depend on considered filter and magnitude. We found a clear steeping of the FL going from B to R bands, indicative of the presence of a large number of red dwarfs, as faint as three bright globular clusters. Furthermore, using Hubble Space Telescope images, we discover that blends of globular clusters, not resolved in individual components due to seeing, look like dwarf galaxies when observed from the ground and are numerous and bright. The existence of these fake extended sources increases the steepness of the LF at faint magnitudes, if not deal on. This concern affects previous deep probing of the luminosity function, but not the present work. The near-infrared LF wa s computed on a near-infrared selected sample of galaxies which photometry is complete down to the typical dwarf (M* +5) luminosity. The Coma LF can be described by a Schechter function with intermediate slope (alpha sim-1.3), plus a dip at MH~-22 mag. The shape of the Coma LF in H band is quite similar to th e one found in the B band. The similarity of the LF in the optical and H bands implies that in the central region of Coma there is no new population of galaxies which is too faint to be observed in the optical band (because dust enshrouded, for instance), down to the magnitudes of dwarfs. The exponential cut of the LF at the bright end is in good agreement with

Infrared spectroscopic study of the synthetic Mg-Ni talc series

NASA Astrophysics Data System (ADS)

Blanchard, Marc; Méheut, Merlin; Delon, Louise; Poirier, Mathilde; Micoud, Pierre; Le Roux, Christophe; Martin, François

2018-05-01

Five talc samples [(Mg,Ni)3Si4O10(OH)2] covering the entire Mg-Ni solid solution were synthesized following a recently developed and patented process (Dumas et al., Process for preparing a composition comprising synthetic mineral particles and composition, 2013a; Procédé de préparation d'une composition comprenant des particules minérales synthétiques et composition, 2013b), which produces sub-micron talc particles replying to industrial needs. Near- and mid-infrared spectra were collected and compared to infrared spectra modeled from first-principles calculations based on density functional theory. The good agreement between experimental and theoretical spectra allowed assigning unambiguously all absorption bands. We focused in particular on the four main OH stretching bands, which represent good probes of their local physical and chemical environment. The description of the vibrational modes at the origin of these absorption bands and the theoretical determination of absorption coefficients provide a firm basis for quantifying the talc chemical composition from infrared spectroscopy and for discussing the distribution of divalent cations in the octahedral sheet. Results confirm that these synthetic talc samples have a similar structure as natural talc, with a random distribution of Mg and Ni atoms. They only differ from natural talc by their hydrophilic character, which is due to their large proportion of reactive sites on sheet edges due to sub-micronic size of the particles. Therefore, the contribution on infrared spectra of hydroxyls adsorbed on edge sites has also been investigated by computing the infrared signature of hydroxyls of surface models.

Utilization of functional near infrared spectroscopy for non-invasive evaluation

NASA Astrophysics Data System (ADS)

Halim, A. A. A.; Laili, M. H.; Aziz, N. A.; Laili, A. R.; Salikin, M. S.; Rusop, M.

2016-07-01

The goal of this brief review is to report the techniques of functional near infrared spectroscopy for non-invasive evaluation in human study. The development of functional near infrared spectroscopy (fNIRS) technologies has advanced quantification signal using multiple wavelength and detector to solve the propagation of light inside the tissues including the absorption, scattering coefficient and to define the light penetration into tissues multilayers. There are a lot of studies that demonstrate signal from fNIRS which can be used to evaluate the changes of oxygenation level and measure the limitation of muscle performance in human brain and muscle tissues. Comprehensive reviews of diffuse reflectance based on beer lambert law theory were presented in this paper. The principle and development of fNIRS instrumentation is reported in detail.

Near-infrared emission from mesoporous crystalline germanium

NASA Astrophysics Data System (ADS)

Boucherif, Abderraouf; Korinek, Andreas; Aimez, Vincent; Arès, Richard

2014-10-01

Mesoporous crystalline germanium was fabricated by bipolar electrochemical etching of Ge wafer in HF-based electrolyte. It yields uniform mesoporous germanium layers composed of high density of crystallites with an average size 5-7 nm. Subsequent extended chemical etching allows tuning of crystallites size while preserving the same chemical composition. This highly controllable nanostructure exhibits photoluminescence emission above the bulk Ge bandgap, in the near-infrared range (1095-1360nm) with strong evidence of quantum confinement within the crystallites.

ITO/Au/ITO sandwich structure for near-infrared plasmonics.

PubMed

Fang, Xu; Mak, Chee Leung; Dai, Jiyan; Li, Kan; Ye, Hui; Leung, Chi Wah

2014-09-24

ITO/Au/ITO trilayers with varying gold spacer layer thicknesses were deposited on glass substrates by pulsed laser deposition. Transmission electron microscopy measurements demonstrated the continuous nature of the Au layer down to 2.4 nm. XRD patterns clearly showed an enhanced crystallinity of the ITO films promoted by the insertion of the gold layer. Compared with a single layer of ITO with a carrier concentration of 7.12 × 10(20) cm(-3), the ITO/Au/ITO structure achieved an effective carrier concentration as high as 3.26 × 10(22) cm(-3). Transmittance and ellipsometry measurements showed that the optical properties of ITO/Au/ITO films were greatly influenced by the thickness of the inserted gold layer. The cross-point wavelength of the trilayer samples was reduced with increasing gold layer thickness. Importantly, the trilayer structure exhibited a reduced loss (compared with plain Au) in the near-infrared region, suggesting its potential for plasmonic applications in the near-infrared range.

DMDs for multi-object near-infrared spectrographs in astronomy

NASA Astrophysics Data System (ADS)

Smee, Stephen A.; Barkhouser, Robert; Hope, Stephen; Conley, Devin; Gray, Aidan; Hope, Gavin; Robberto, Massimo

2018-02-01

The Digital Micromirror Device (DMD), typically used in projection screen technology, has utility in instrumentation for astronomy as a digitally programmable slit in a spectrograph. When placed at an imaging focal plane the device can be used to selectively direct light from astronomical targets into the optical path of a spectrograph, while at the same time directing the remaining light into an imaging camera, which can be used for slit alignment, science imaging, or both. To date the use of DMDs in astronomy has been limited, especially for instruments that operate in the near infrared (1 - 2.5 μm). This limitation is due in part to a host of technical challenges with respect to DMDs that, to date, have not been thoroughly explored. Those challenges include operation at cryogenic temperature, control electronics that facilitate DMD use at these temperatures, window coatings properly coated for the near infrared bandpass, and scattered light. This paper discusses these technical challenges and presents progress towards understanding and mitigating them.

Near-infrared selective dynamic windows controlled by charge transfer impedance at the counter electrode.

PubMed

Pattathil, Praveen; Scarfiello, Riccardo; Giannuzzi, Roberto; Veramonti, Giulia; Sibillano, Teresa; Qualtieri, Antonio; Giannini, Cinzia; Cozzoli, P Davide; Manca, Michele

2016-12-08

Recent developments in the exploitation of transparent conductive oxide nanocrystals paved the way to the realization of a new class of electrochemical systems capable of selectively shielding the infrared heat loads carried by sunlight and prospected the blooming of a key enabling technology to be implemented in the next generation of "zero-energy" building envelopes. Here we report the fabrication of a set of electrochromic devices embodying an engineered nanostructured electrode made by high aspect-ratio tungsten oxide nanorods, which allow for selectively and dynamically controlling sunlight transmission over the near-infrared to visible range. Varying the intensity of applied voltage makes the spectral response of the device change across three different optical regimes, namely fully transparent, near-infrared only blocking and both visible and near-infrared blocking. It is demonstrated that the degree of reversible modulation of the thermal radiation entering the glazing element can approach a remarkable 85%, accompanied by only a modest reduction in the luminous transmittance.

Response of zircon to melting and metamorphism in deep arc crust, Fiordland (New Zealand): implications for zircon inheritance in cordilleran granites

NASA Astrophysics Data System (ADS)

Bhattacharya, Shrema; Kemp, A. I. S.; Collins, W. J.

2018-04-01

. Thus, our integrative approach provides the opportunity to discriminate between igneous and metamorphic zircon within deep-crustal complexes. Also, without the tight field relations at Mt Daniel, the scatter beyond a statistically coherent group might be ascribed to the presence of "antecrysts", but it is clear that the WFO solidified before the MDC was emplaced, and these older "igneous" grains are inherited. The bimodal age range of inherited igneous grains, dominated by 125 Ma and 350-320 Ma age clusters, indicate that the adjacent WFO and a Carboniferous metaigneous basement were the main sources of the MDC magmas. Mafic lenses, stretched and highly attenuated into wisps within the MDC and dominated by 124 Ma inherited zircons, are considered to be entrained restitic material from the WFO. A comparison with lower- and upper-crustal, high Sr/Y metaluminous granites elsewhere in Fiordland shows that zircon inheritance is common in the deep crust, near the source region, but generally much less so in coeval, shallow magma chambers (plutons). This is consistent with previous modelling on rapid zircon dissolution rates and high Zr saturation concentrations in metaluminous magmas. Accordingly, unless unusual circumstances exist, such as MDC preservation in the deep crust, low temperatures of magma generation, or rapid emplacement and crystallization at higher structural levels, information on zircon inheritance in upper crustal, Cordilleran plutons is lost during zircon dissolution, along with information on the age, nature and variety of the source material. The observation that dioritic magmas can form at these low temperatures (< 750 °C) also suggests that the petrogenesis of mafic rocks in the arc root might need to be re-assessed.

High-efficiency electroluminescence and amplified spontaneous emission from a thermally activated delayed fluorescent near-infrared emitter

NASA Astrophysics Data System (ADS)

Kim, Dae-Hyeon; D'Aléo, Anthony; Chen, Xian-Kai; Sandanayaka, Atula D. S.; Yao, Dandan; Zhao, Li; Komino, Takeshi; Zaborova, Elena; Canard, Gabriel; Tsuchiya, Youichi; Choi, Eunyoung; Wu, Jeong Weon; Fages, Frédéric; Brédas, Jean-Luc; Ribierre, Jean-Charles; Adachi, Chihaya

2018-02-01

Near-infrared organic light-emitting diodes and semiconductor lasers could benefit a variety of applications including night-vision displays, sensors and information-secured displays. Organic dyes can generate electroluminescence efficiently at visible wavelengths, but organic light-emitting diodes are still underperforming in the near-infrared region. Here, we report thermally activated delayed fluorescent organic light-emitting diodes that operate at near-infrared wavelengths with a maximum external quantum efficiency of nearly 10% using a boron difluoride curcuminoid derivative. As well as an effective upconversion from triplet to singlet excited states due to the non-adiabatic coupling effect, this donor-acceptor-donor compound also exhibits efficient amplified spontaneous emission. By controlling the polarity of the active medium, the maximum emission wavelength of the electroluminescence spectrum can be tuned from 700 to 780 nm. This study represents an important advance in near-infrared organic light-emitting diodes and the design of alternative molecular architectures for photonic applications based on thermally activated delayed fluorescence.

Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon

DOE PAGES

Bell, Elizabeth A.; Boehnke, Patrick; Harrison, T. Mark; ...

2015-10-19

Here, evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ~3.5 billion years (Ga), the chemofossil record arguably to ~3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in amore » crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ 13C PDB of –24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ~300 My earlier than has been previously proposed.« less

Potentially biogenic carbon preserved in a 4.1 billion-year-old zircon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bell, Elizabeth A.; Boehnke, Patrick; Harrison, T. Mark

Here, evidence of life on Earth is manifestly preserved in the rock record. However, the microfossil record only extends to ~3.5 billion years (Ga), the chemofossil record arguably to ~3.8 Ga, and the rock record to 4.0 Ga. Detrital zircons from Jack Hills, Western Australia range in age up to nearly 4.4 Ga. From a population of over 10,000 Jack Hills zircons, we identified one >3.8-Ga zircon that contains primary graphite inclusions. Here, we report carbon isotopic measurements on these inclusions in a concordant, 4.10 ± 0.01-Ga zircon. We interpret these inclusions as primary due to their enclosure in amore » crack-free host as shown by transmission X-ray microscopy and their crystal habit. Their δ 13C PDB of –24 ± 5‰ is consistent with a biogenic origin and may be evidence that a terrestrial biosphere had emerged by 4.1 Ga, or ~300 My earlier than has been previously proposed.« less

Ceramic with zircon coating

NASA Technical Reports Server (NTRS)

Wang, Hongyu (Inventor)

2003-01-01

An article comprises a silicon-containing substrate and a zircon coating. The article can comprise a silicon carbide/silicon (SiC/Si) substrate, a zircon (ZrSiO.sub.4) intermediate coating and an external environmental/thermal barrier coating.

Near-infrared counterparts to the Galactic Bulge Survey X-ray source population

NASA Astrophysics Data System (ADS)

Greiss, S.; Steeghs, D.; Jonker, P. G.; Torres, M. A. P.; Maccarone, T. J.; Hynes, R. I.; Britt, C. T.; Nelemans, G.; Gänsicke, B. T.

2014-03-01

We report on the near-infrared matches, drawn from three surveys, to the 1640 unique X-ray sources detected by Chandra in the Galactic Bulge Survey (GBS). This survey targets faint X-ray sources in the bulge, with a particular focus on accreting compact objects. We present all viable counterpart candidates and associate a false alarm probability (FAP) to each near-infrared match in order to identify the most likely counterparts. The FAP takes into account a statistical study involving a chance alignment test, as well as considering the positional accuracy of the individual X-ray sources. We find that although the star density in the bulge is very high, ˜90 per cent of our sources have an FAP <10 per cent, indicating that for most X-ray sources, viable near-infrared counterparts candidates can be identified. In addition to the FAP, we provide positional and photometric information for candidate counterparts to ˜95 per cent of the GBS X-ray sources. This information in combination with optical photometry, spectroscopy and variability constraints will be crucial to characterize and classify secure counterparts.

Absolute flatness measurements of silicon mirrors by a three-intersection method by near-infrared interferometry

PubMed Central

2013-01-01

Absolute flatness of three silicon plane mirrors have been measured by a three-intersection method based on the three-flat method using a near-infrared interferometer. The interferometer was constructed using a near-infrared laser diode with a 1,310-nm wavelength light where the silicon plane mirror is transparent. The height differences at the coordinate values between the absolute line profiles by the three-intersection method have been evaluated. The height differences of the three flats were 4.5 nm or less. The three-intersection method using the near-infrared interferometer was useful for measuring the absolute flatness of the silicon plane mirrors. PMID:23758916

Fast, Low-Cost and Non-Destructive Physico-Chemical Analysis of Virgin Olive Oils Using Near-Infrared Reflectance Spectroscopy

PubMed Central

Garrido-Varo, Ana; Sánchez, María-Teresa; De la Haba, María-José; Torres, Irina; Pérez-Marín, Dolores

2017-01-01

Near-Infrared (NIR) Spectroscopy was used for the non-destructive assessment of physico-chemical quality parameters in olive oil. At the same time, the influence of the sample presentation mode (spinning versus static cup) was evaluated using two spectrophotometers with similar optical characteristics. A total of 478 olive oil samples were used to develop calibration models, testing various spectral signal pre-treatments. The models obtained by applying MPLS regression to spectroscopic data yielded promising results for olive oil quality measurements, particularly for acidity, the peroxide index and alkyl and ethyl ester content. The results obtained indicate that this non-invasive technology can be used successfully by the olive oil sector to categorize olive oils, to detect potential fraud and to provide consumers with more reliable information. Although both sample presentation modes yielded comparable results, equations constructed with samples scanned using the spinning mode provided greater predictive capacity. PMID:29144417

Single-walled carbon nanotubes as near-infrared optical biosensors for life sciences and biomedicine.

PubMed

Jain, Astha; Homayoun, Aida; Bannister, Christopher W; Yum, Kyungsuk

2015-03-01

Single-walled carbon nanotubes that emit photostable near-infrared fluorescence have emerged as near-infrared optical biosensors for life sciences and biomedicine. Since the discovery of their near-infrared fluorescence, researchers have engineered single-walled carbon nanotubes to function as an optical biosensor that selectively modulates its fluorescence upon binding of target molecules. Here we review the recent advances in the single-walled carbon nanotube-based optical sensing technology for life sciences and biomedicine. We discuss the structure and optical properties of single-walled carbon nanotubes, the mechanisms for molecular recognition and signal transduction in single-walled carbon nanotube complexes, and the recent development of various single-walled carbon nanotube-based optical biosensors. We also discuss the opportunities and challenges to translate this emerging technology into biomedical research and clinical use, including the biological safety of single-walled carbon nanotubes. The advances in single-walled carbon nanotube-based near-infrared optical sensing technology open up a new avenue for in vitro and in vivo biosensing with high sensitivity and high spatial resolution, beneficial for many areas of life sciences and biomedicine. Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Near-infrared spectra of the Martian surface: Reading between the lines

NASA Technical Reports Server (NTRS)

Crisp, D.; Bell, J. F., III

1993-01-01

Moderate-resolution near-infrared (NIR) spectra of Mars have been widely used in studies of the Martian surface because many candidate surface materials have distinctive absorption features at these wavelengths. Recent advances in NIR detector technology and instrumentation have also encouraged studies in this spectral region. The use of moderate spectral resolution has often been justified for NIR surface observations because the spectral features produced by most surface materials are relatively broad, and easily discriminated at this resolution. In spite of this, NIR spectra of Mars are usually very difficult to interpret quantitatively. One problem is that NIR surface absorption features are often only a few percent deep, requiring observations with great signal-to-noise ratios. A more significant problem is that gases in the Martian atmosphere contribute numerous absorption features at these wavelengths. Ground-based observers must also contend with variable absorption by several gases in the Earth's atmosphere (H2O, CO2, O3, N2O, CH4, O2). The strong CO2 bands near 1.4, 1.6, 2.0, 2.7, 4.3, and 4.8 micrometers largely preclude the analysis of surface spectral features at these wavelengths. Martian atmospheric water vapor also contributes significant absorption near 1.33, 1.88, and 2.7 micrometers, but water vapor in the Earth's atmosphere poses a much larger problem to ground-based studies of these spectral regions. The third most important NIR absorber in the Martian atmosphere is CO. This gas absorbs most strongly in the relatively-transparent spectral windows near 4.6 and 2.3 micrometers. It also produces 1-10 percent absorption in the solar spectrum at these NIR wavelengths. This solar CO absorption cannot be adequately removed by dividing the Martian spectrum by that of a star, as is commonly done to calibrate ground-based spectroscopic observations, because most stars do not have identical amounts of CO absorption in their spectra. Here, we describe tow

Length-free near infrared measurement of newborn malnutrition

NASA Astrophysics Data System (ADS)

Mustafa, Fatin Hamimi; Bek, Emily J.; Huvanandana, Jacqueline; Jones, Peter W.; Carberry, Angela E.; Jeffery, Heather E.; Jin, Craig T.; McEwan, Alistair L.

2016-11-01

Under-nutrition in neonates can cause immediate mortality, impaired cognitive development and early onset adult disease. Body fat percentage measured using air-displacement-plethysmography has been found to better indicate under-nutrition than conventional birth weight percentiles. However, air-displacement-plethysmography equipment is expensive and non-portable, so is not suited for use in developing communities where the burden is often the greatest. We proposed a new body fat measurement technique using a length-free model with near-infrared spectroscopy measurements on a single site of the body - the thigh. To remove the need for length measurement, we developed a model with five discrete wavelengths and a sex parameter. The model was developed using air-displacement-plethysmography measurements in 52 neonates within 48 hours of birth. We identified instrumentation required in a low-cost LED-based screening device and incorporated a receptor device that can increase the amount of light collected. This near-infrared method may be suitable as a low cost screening tool for detecting body fat levels and monitoring nutritional interventions for malnutrition in neonates and young children in resource-constrained communities.

Spatially Resolved Far-Infrared Spectroscopic Analysis of Planetary Nebulae

NASA Astrophysics Data System (ADS)

Rattray, Rebecca; Ueta, Toshiya

2015-01-01

Planetary Nebulae (PNs) are late-life intermediate-mass (1-8 solar mass) stars that have shed their outer layers. A wide variety of morphologies and physical conditions is seen in PNs, but a complete understanding of what causes these various conditions is still needed. Spatially resolved far-infrared spectroscopic analysis has been performed on 11 targets using both PACS and SPIRE instruments on the Herschel Space Observatory as part of the Herschel Planetary Nebula Survey (HerPlaNS). Far-IR lines probe the ionized parts of the nebulae and suffer less extinction than optical lines, so observations in the far-IR are critical to our complete understanding of PNs. Because PNs are extended objects, the spectral mapping capabilities of both PACS and SPIRE allow us to better understand the spatial variations of the objects by tracking line strengths as a function of location within the nebula. The far-IR lines detected in this study can be used as tracers of electron density and electron temperature which are critical parameters in radiative transfer modeling of PNs. Information on atomic, ionic, and molecular lines identified in these 11 targets will be presented.

The study on the near infrared spectrum technology of sauce component analysis

NASA Astrophysics Data System (ADS)

Li, Shangyu; Zhang, Jun; Chen, Xingdan; Liang, Jingqiu; Wang, Ce

2006-01-01

The author, Shangyu Li, engages in supervising and inspecting the quality of products. In soy sauce manufacturing, quality control of intermediate and final products by many components such as total nitrogen, saltless soluble solids, nitrogen of amino acids and total acid is demanded. Wet chemistry analytical methods need much labor and time for these analyses. In order to compensate for this problem, we used near infrared spectroscopy technology to measure the chemical-composition of soy sauce. In the course of the work, a certain amount of soy sauce was collected and was analyzed by wet chemistry analytical methods. The soy sauce was scanned by two kinds of the spectrometer, the Fourier Transform near infrared spectrometer (FT-NIR spectrometer) and the filter near infrared spectroscopy analyzer. The near infrared spectroscopy of soy sauce was calibrated with the components of wet chemistry methods by partial least squares regression and stepwise multiple linear regression. The contents of saltless soluble solids, total nitrogen, total acid and nitrogen of amino acids were predicted by cross validation. The results are compared with the wet chemistry analytical methods. The correlation coefficient and root-mean-square error of prediction (RMSEP) in the better prediction run were found to be 0.961 and 0.206 for total nitrogen, 0.913 and 1.215 for saltless soluble solids, 0.855 and 0.199 nitrogen of amino acids, 0.966 and 0.231 for total acid, respectively. The results presented here demonstrate that the NIR spectroscopy technology is promising for fast and reliable determination of major components of soy sauce.

Clinical evaluation of near-infrared light transillumination in approximal dentin caries detection.

PubMed

Ozkan, Gokhan; Guzel, Kadriye Gorkem Ulu

2017-08-01

The objective of this clinical study was to compare conventional caries detection techniques, pen-type laser fluorescence device, and near-infrared light transillumination method in approximal dentin caries lesions. The study included 157 patients, aged 12-18, without any cavity in the posterior teeth. Two calibrated examiners carried out the assessments of selected approximal caries sites independently. After the assessments, the unopened sites were excluded and a total of 161 approximal sites were included in the study. When both the examiners arrived at a consensus regarding the presence of dentin caries, the detected lesions were opened with a conical diamond burr, the cavity extent was examined and validated (gold standard). Sensitivity, specificity, negative predictive value, positive predictive value, accuracy, and area under the ROC curve (Az) values among the caries detection methods were calculated. Bitewing radiography and near-infrared (NIR) light transillumination methods showed the highest sensitivity (0.83-0.82) and accuracy (0.82-0.80) among the methods. Visual inspection showed the lowest sensitivity (0.54). Laser fluorescence device and visual inspection showed nearly equal performance. Near-infrared light transillumination can be used as an alternative method to approximal dentin caries detection. Visual inspection and laser fluorescence device alone should not be used for approximal dentin caries.

Analysis of albumin Raman scattering in visible and near-infrared ranges

NASA Astrophysics Data System (ADS)

Lykina, Anastasia A.; Artemyev, Dmitry N.

2018-04-01

In this work the analysis of the shape and intensity of albumin Raman signals in visible and near-IR ranges was carried out. The experimental setup using lasers from the visible region first of all excites the fluorescence of the albumin solution, the main contribution to which is produced by sodium chloride, which is a component of the tested sample. At the same time, lasers from the near-infrared range excited the Raman signal of albumin most effectively. It was found that the highest ratio of Raman scattering to autofluorescence intensities in the detected signal was obtained using a laser with a wavelength of 1064 nm. To determine the albumin solution concentration by type of spectrum, a regression approach with the projection to latent structures method was applied. The lowest predicted error of albumin concentration of 2-3 g/l was obtained by using the near-infrared range lasers.

Estimating the marine signal in the near infrared for atmospheric correction of satellite ocean-color imagery over turbid waters

NASA Astrophysics Data System (ADS)

Bourdet, Alice; Frouin, Robert J.

2014-11-01

The classic atmospheric correction algorithm, routinely applied to second-generation ocean-color sensors such as SeaWiFS, MODIS, and MERIS, consists of (i) estimating the aerosol reflectance in the red and near infrared (NIR) where the ocean is considered black (i.e., totally absorbing), and (ii) extrapolating the estimated aerosol reflectance to shorter wavelengths. The marine reflectance is then retrieved by subtraction. Variants and improvements have been made over the years to deal with non-null reflectance in the red and near infrared, a general situation in estuaries and the coastal zone, but the solutions proposed so far still suffer some limitations, due to uncertainties in marine reflectance modeling in the near infrared or difficulty to extrapolate the aerosol signal to the blue when using observations in the shortwave infrared (SWIR), a spectral range far from the ocean-color wavelengths. To estimate the marine signal (i.e., the product of marine reflectance and atmospheric transmittance) in the near infrared, the proposed approach is to decompose the aerosol reflectance in the near infrared to shortwave infrared into principal components. Since aerosol scattering is smooth spectrally, a few components are generally sufficient to represent the perturbing signal, i.e., the aerosol reflectance in the near infrared can be determined from measurements in the shortwave infrared where the ocean is black. This gives access to the marine signal in the near infrared, which can then be used in the classic atmospheric correction algorithm. The methodology is evaluated theoretically from simulations of the top-of-atmosphere reflectance for a wide range of geophysical conditions and angular geometries and applied to actual MODIS imagery acquired over the Gulf of Mexico. The number of discarded pixels is reduced by over 80% using the PC modeling to determine the marine signal in the near infrared prior to applying the classic atmospheric correction algorithm.

Near-infrared analysis of hydrogen-bonding in glass- and rubber-state amorphous saccharide solids.

PubMed

Izutsu, Ken-ichi; Hiyama, Yukio; Yomota, Chikako; Kawanishi, Toru

2009-01-01

Near-infrared (NIR) spectroscopic analysis of noncrystalline polyols and saccharides (e.g., glycerol, sorbitol, maltitol, glucose, sucrose, maltose) was performed at different temperatures (30-80 degrees C) to elucidate the effect of glass transition on molecular interaction. Transmission NIR spectra (4,000-12,000 cm(-1)) of the liquids and cooled-melt amorphous solids showed broad absorption bands that indicate random configuration of molecules. Heating of the samples decreased an intermolecular hydrogen-bonding OH vibration band intensity (6,200-6,500 cm(-1)) with a concomitant increase in a free and intramolecular hydrogen-bonding OH group band (6,600-7,100 cm(-1)). Large reduction of the intermolecular hydrogen-bonding band intensity at temperatures above the glass transition (T(g)) of the individual solids should explain the higher molecular mobility and lower viscosity in the rubber state. Mixing of the polyols with a high T(g) saccharide (maltose) or an inorganic salt (sodium tetraborate) shifted both the glass transition and the inflection point of the hydrogen-bonding band intensity to higher temperatures. The implications of these results for pharmaceutical formulation design and process monitoring (PAT) are discussed.

Near-infrared strong coupling between metamaterials and epsilon-near-zero modes in degenerately doped semiconductor nanolayers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Campione, Salvatore; Wendt, Joel R.; Keeler, Gordon Arthur

Epsilon-near-zero (ENZ) modes provide a new path for tailoring light–matter interactions at the nanoscale. In this paper, we analyze a strongly coupled system at near-infrared frequencies comprising plasmonic metamaterial resonators and ENZ modes supported by degenerately doped semiconductor nanolayers. In strongly coupled systems that combine optical cavities and intersubband transitions, the polariton splitting (i.e., the ratio of Rabi frequency to bare cavity frequency) scales with the square root of the wavelength, thus favoring the long-wavelength regime. In contrast, we observe that the polariton splitting in ENZ/metamaterial resonator systems increases linearly with the thickness of the nanolayer supporting the ENZ modes.more » In this work, we employ an indium-tin-oxide nanolayer and observe a large experimental polariton splitting of approximately 30% in the near-infrared. As a result, this approach opens up many promising applications, including nonlinear optical components and tunable optical filters based on controlling the polariton splitting by adjusting the frequency of the ENZ mode.« less

Near-infrared strong coupling between metamaterials and epsilon-near-zero modes in degenerately doped semiconductor nanolayers

DOE PAGES

Campione, Salvatore; Wendt, Joel R.; Keeler, Gordon Arthur; ...

2016-01-14

Epsilon-near-zero (ENZ) modes provide a new path for tailoring light–matter interactions at the nanoscale. In this paper, we analyze a strongly coupled system at near-infrared frequencies comprising plasmonic metamaterial resonators and ENZ modes supported by degenerately doped semiconductor nanolayers. In strongly coupled systems that combine optical cavities and intersubband transitions, the polariton splitting (i.e., the ratio of Rabi frequency to bare cavity frequency) scales with the square root of the wavelength, thus favoring the long-wavelength regime. In contrast, we observe that the polariton splitting in ENZ/metamaterial resonator systems increases linearly with the thickness of the nanolayer supporting the ENZ modes.more » In this work, we employ an indium-tin-oxide nanolayer and observe a large experimental polariton splitting of approximately 30% in the near-infrared. As a result, this approach opens up many promising applications, including nonlinear optical components and tunable optical filters based on controlling the polariton splitting by adjusting the frequency of the ENZ mode.« less

Hf isotope compositions In detrital zircons as a new tool for provenance studies

NASA Astrophysics Data System (ADS)

Jacobsen, Y. J.; Münker, C.; Mezger, K.

2003-04-01

Identifying the provenance of continental sediments is a major issue in palaeo-tectonic studies, providing important information for paleogeographic reconstructions. Isotope studies, e.g. those of whole rock Sm-Nd or detrital zircon U-Pb dating, have widely been used for this purpose. Here we assess the potential of combined Lu-Hf data and U-Pb ages determined on the same single detrital zircons as a new tool for provenance studies. Due to the low Lu/Hf ratios in zircons the Hf isotope composition of a zircon changes insignificantly after its crystallization. Thus each particular grain preserves information on the Hf-siotpe composition of its source and the age of this source. Provided that both the U-Pb and Lu-Hf isotope systems have not been disturbed, this information can be used to constrain the sources of each individual zircon. In order to demonstrate the capability of Hf isotope studies on detrital zircons for provenance studies, we obtained combined U-Pb ages and Lu-Hf isotope data for zircons from the Cambrian Junction Formation in New Zealand. The Junction Formation was deposited on the (present) SE margin of Gondwana near the Australian continent and consists of turbidites, siltstones and conglomerates [1]. Typical continent derived Paleozoic sediments in SE Gondwana generally show characteristic age maxima at 500-600 Ma, 1000-1200 Ma (Grenvillian) and additional older peaks (early Proterozoic to Archean) [2]. We focused on two groups of detrital zircons with Grenvillian and Proterozoic to Late Archean ages. The initial ɛHf values for these zircons range from 0.7 to -15.5 for the Grenvillian and from -5.2 to -14.1 for the Proterozoic/Archean zircons. Corresponding two stage Hf model ages range from ca. 1500 to 2500 Ma for the Grenvillian and from ca. 3200 to 3600 Ma for the Proterozoic/Archean zircons. Furthermore it can be shown that the Grenvillian zircons must have been derived from recycled Grenvillian provinces. Comparison of these Hf model ages

Pocket-size near-infrared spectrometer for narcotic materials identification

NASA Astrophysics Data System (ADS)

Pederson, Christopher G.; Friedrich, Donald M.; Hsiung, Chang; von Gunten, Marc; O'Brien, Nada A.; Ramaker, Henk-Jan; van Sprang, Eric; Dreischor, Menno

2014-05-01

While significant progress has been made towards the miniaturization of Raman, mid-infrared (IR), and near-infrared (NIR) spectrometers for homeland security and law enforcement applications, there remains continued interest in pushing the technology envelope for smaller, lower cost, and easier to use analyzers. In this paper, we report on the use of the MicroNIR Spectrometer, an ultra-compact, handheld near infrared (NIR) spectrometer, the, that weighs less than 60 grams and measures < 50mm in diameter for the classification of 140 different substances most of which are controlled substances (such as cocaine, heroin, oxycodone, diazepam), as well as synthetic cathinones (also known as bath salts), and synthetic cannabinoids. A library of the materials was created from a master MicroNIR spectrometer. A set of 25 unknown samples were then identified with three other MicroNIRs showing: 1) the ability to correctly identify the unknown with a very low rate of misidentification, and 2) the ability to use the same library with multiple instruments. In addition, we have shown that through the use of innovative chemometric algorithms, we were able to identify the individual compounds that make up an unknown mixture based on the spectral library of the individual compounds only. The small size of the spectrometer is enabled through the use of high-performance linear variable filter (LVF) technology.

Red and near-infrared spectral reflectance of snow

NASA Technical Reports Server (NTRS)

Obrien, H. W.; Munis, R. H.

1975-01-01

The spectral reflectance of snow in the range of 0.60 to 2.50 microns wavelengths was studied in a cold laboratory using natural snow and simulated preparations of snow. A white barium sulfate powder was used as the standard for comparison. The high reflectance (usually nearly 100%) of fresh natural snow in visible wavelengths declines rapidly at wavelengths longer than the visible, as the spectral absorption coefficients of ice increase. Aging snow becomes only somewhat less reflective than fresh snow in the visible region and usually retains a reflectance greater than 80%. In the near infrared, aging snow tends to become considerably less reflective than fresh snow.

Detectors for the James Webb Space Telescope near-infrared spectrograph

NASA Astrophysics Data System (ADS)

Rauscher, Bernard J.; Figer, Donald F.; Regan, Michael W.; Boeker, Torsten; Garnett, James; Hill, Robert J.; Bagnasco, Giorgio; Balleza, Jesus; Barney, Richard; Bergeron, Louis E.; Brambora, Clifford; Connelly, Joe; Derro, Rebecca; DiPirro, Michael J.; Doria-Warner, Christina; Ericsson, Aprille; Glazer, Stuart D.; Greene, Charles; Hall, Donald N.; Jacobson, Shane; Jakobsen, Peter; Johnson, Eric; Johnson, Scott D.; Krebs, Carolyn; Krebs, Danny J.; Lambros, Scott D.; Likins, Blake; Manthripragada, Sridhar; Martineau, Robert J.; Morse, Ernie C.; Moseley, Samuel H.; Mott, D. Brent; Muench, Theo; Park, Hongwoo; Parker, Susan; Polidan, Elizabeth J.; Rashford, Robert; Shakoorzadeh, Kamdin; Sharma, Rajeev; Strada, Paolo; Waczynski, Augustyn; Wen, Yiting; Wong, Selmer; Yagelowich, John; Zuray, Monica

2004-10-01

The Near-Infrared Spectrograph (NIRSpec) is the James Webb Space Telescope"s primary near-infrared spectrograph. NASA is providing the NIRSpec detector subsystem, which consists of the focal plane array, focal plane electronics, cable harnesses, and software. The focal plane array comprises two closely-butted λco ~ 5 μm Rockwell HAWAII-2RG sensor chip assemblies. After briefly describing the NIRSpec instrument, we summarize some of the driving requirements for the detector subsystem, discuss the baseline architecture (and alternatives), and presents some recent detector test results including a description of a newly identified noise component that we have found in some archival JWST test data. We dub this new noise component, which appears to be similar to classical two-state popcorn noise in many aspects, "popcorn mesa noise." We close with the current status of the detector subsystem development effort.

Detectors for the James Webb Space Telescope Near-Infrared Spectrograph

NASA Technical Reports Server (NTRS)

Rauscher, Bernard J.; Figer, Donald F.; Regan, Michael W.; Boeker, Torsten; Garnett, James; Hill, Robert J.; Bagnasco, Georgio; Balleza, Jesus; Barney, Richard; Bergeron, Louis E.

2004-01-01

The Near-Infrared Spectrograph (NIRSpec) is the James Webb Space Telescope's primary near-infrared spectrograph. NASA is providing the NIRSpec detector subsystem, which consists of the focal plane array, focal plane electronics, cable harnesses, and software. The focal plane array comprises two closely-butted lambda (sub co) approximately 5 micrometer Rockwell HAWAII- 2RG sensor chip assemblies. After briefly describing the NIRSpec instrument, we summarize some of the driving requirements for the detector subsystem, discuss the baseline architecture (and alternatives), and presents some recent detector test results including a description of a newly identified noise component that we have found in some archival JWST test data. We dub this new noise component, which appears to be similar to classical two-state popcorn noise in many aspects, "popcorn mesa noise." We close with the current status of the detector subsystem development effort.

Mid-infrared integrated photonics on silicon: a perspective

NASA Astrophysics Data System (ADS)

Lin, Hongtao; Luo, Zhengqian; Gu, Tian; Kimerling, Lionel C.; Wada, Kazumi; Agarwal, Anu; Hu, Juejun

2017-12-01

The emergence of silicon photonics over the past two decades has established silicon as a preferred substrate platform for photonic integration. While most silicon-based photonic components have so far been realized in the near-infrared (near-IR) telecommunication bands, the mid-infrared (mid-IR, 2-20-μm wavelength) band presents a significant growth opportunity for integrated photonics. In this review, we offer our perspective on the burgeoning field of mid-IR integrated photonics on silicon. A comprehensive survey on the state-of-the-art of key photonic devices such as waveguides, light sources, modulators, and detectors is presented. Furthermore, on-chip spectroscopic chemical sensing is quantitatively analyzed as an example of mid-IR photonic system integration based on these basic building blocks, and the constituent component choices are discussed and contrasted in the context of system performance and integration technologies.

A Cross-Sectional Survey of Near-Infrared Spectroscopy Use in Pediatric Cardiac ICUs in the United Kingdom, Ireland, Italy, and Germany.

PubMed

Hoskote, Aparna U; Tume, Lyvonne N; Trieschmann, Uwe; Menzel, Christoph; Cogo, Paola; Brown, Katherine L; Broadhead, Michael W

2016-01-01

Despite the increasing use of near-infrared spectroscopy across pediatric cardiac ICUs, there is significant variability and equipoise with no universally accepted management algorithms. We aimed to explore the use of near-infrared spectroscopy in pediatric cardiac ICUs in the United Kingdom, Ireland, Italy, and Germany. A cross-sectional multicenter, multinational electronic survey of one consultant in each pediatric cardiac ICU. Pediatric cardiac ICUs in the United Kingdom and Ireland (n = 13), Italy (n = 12), and Germany (n = 33). Questionnaire targeted to establish use, targets, protocols/thresholds for intervention, and perceived usefulness of near-infrared spectroscopy monitoring. Overall, 42 of 58 pediatric cardiac ICUs (72%) responded: United Kingdom and Ireland, 11 of 13 (84.6%); Italy, 12 of 12 (100%); and Germany, 19 of 33 (57%, included all major centers). Near-infrared spectroscopy usage varied with 35% (15/42) reporting that near-infrared spectroscopy was not used at all (7/42) or occasionally (8/42); near-infrared spectroscopy use was much less common in the United Kingdom (46%) when compared with 78% in Germany and all (100%) in Italy. Only four units had a near-infrared spectroscopy protocol, and 18 specifically used near-infrared spectroscopy in high-risk patients; 37 respondents believed that near-infrared spectroscopy added value to standard monitoring and 23 believed that it gave an earlier indication of deterioration, but only 19 would respond based on near-infrared spectroscopy data alone. Targets for absolute values and critical thresholds for intervention varied widely between units. The reasons cited for not or occasionally using near-infrared spectroscopy were expense (n = 6), limited evidence and uncertainty on how it guides management (n = 4), difficulty in interpretation, and unreliability of data (n = 3). Amongst the regular or occasional near-infrared spectroscopy users (n = 35), 28 (66%) agreed that a multicenter study is warranted

Ti-in-Zircon Thermometer: Preliminary Results

NASA Astrophysics Data System (ADS)

Fu, B.; Cavosie, A. J.; Clechenko, C. C.; Fournelle, J.; Kita, N. T.; Lackey, J.; Page, F.; Wilde, S. A.; Valley, J. W.

2005-12-01

The titanium in zircon thermometer has been applied to 167 zircons from diverse rock types. These rocks include metamorphosed anorthosite and gabbro (1.15 Ga, intrusion age), and unmetamorphosed granitic pegmatite (0.9 Ga) from the Adirondack Highlands; metaluminous and peraluminous granites (114-90 Ma) of the Sierra Nevada Batholith; megacrysts from kimberlite pipes in southern Africa, Brazil, and Siberia; and detrital zircons (4.4-3.9 Ga) of metaconglomerate from Jack Hills, Western Australia. Titanium concentration in zircon was analysed using a CAMECA IMS-1280 ion microprobe (see Page et al., this volume). Spot analyses were correlated to U-Pb SHRIMP pits especially for Adirondack and Jack Hills zircons. The majority of zircons have Ti-content less than 10 ppm. Variability, in excess of analytical precision, within individual zircons is observed in about one-third of crystals. In general, there is no systematic change in Ti from core to rim (identified by cathodoluminescence) of zircons, or with regard to age, U content, Th/U ratio, or U-Pb age concordance for these non-metamict grains. The average temperatures for zircon crystallization in different rock suites using the experimental/empirical calibration of Watson and Harrison (W&H, 2005, Science 308:841), assuming the presence of rutile and quartz, are estimated to be: anorthosite 735±41°C (1SD, n=24; Ti = 10±5 ppm); metagabbro 714±31°C (n=19; Ti = 8±4 ppm); Adirondack pegmatite 500±16°C (n=5; Ti = 0.3±0.1 ppm); metaluminous and peraluminous granites from Sierra Nevada 681±67°C (n=53; Ti = 6±5 ppm) and 613±75°C (n=68; Ti = 3±3 ppm); kimberlite megacrysts 740±64°C (n=169; Ti = 14±13 ppm) (Page et al., this volume); and detrital zircons from Jack Hills metaconglomerate 718±63°C (n=64; Ti = 10±9 ppm). Most of the host rocks contain ilmenite or titanite suggesting that α(TiO2)>0.5, but rutile activity is unknown for megacrysts and detrital zircons. Pegmatite contains no Ti-rich minerals

Detrital Zircon Geochronology of Cretaceous and Paleogene Strata Across the South-Central Alaskan Convergent Margin

USGS Publications Warehouse

Bradley, Dwight; Haeussler, Peter J.; O'Sullivan, Paul; Friedman, Rich; Till, Alison; Bradley, Dan; Trop, Jeff

2009-01-01

Ages of detrital zircons are reported from ten samples of Lower Cretaceous to Paleogene metasandstones and sandstones from the Chugach Mountains, Talkeetna Mountains, and western Alaska Range of south-central Alaska. Zircon ages are also reported from three igneous clasts from two conglomerates. The results bear on the regional geology, stratigraphy, tectonics, and mineral resource potential of the southern Alaska convergent margin. Chugach Mountains - The first detrital zircon data are reported here from the two main components of the Chugach accretionary complex - the inboard McHugh Complex and the outboard Valdez Group. Detrital zircons from sandstone and two conglomerate clasts of diorite were dated from the McHugh Complex near Anchorage. This now stands as the youngest known part of the McHugh Complex, with an inferred Turonian (Late Cretaceous) depositional age no older than 91-93 Ma. The zircon population has probability density peaks at 93 and 104 Ma and a smattering of Early Cretaceous and Jurassic grains, with nothing older than 191 Ma. The two diorite clasts yielded Jurassic U-Pb zircon ages of 179 and 181 Ma. Together, these findings suggest a Mesozoic arc as primary zircon source, the closest and most likely candidate being the Wrangellia composite terrane. The detrital zircon sample from the Valdez Group contains zircons as young as 69 and 77 Ma, consistent with the previously assigned Maastrichtian to Campanian (Late Cretaceous) depositional age. The zircon population has peaks at 78, 91, 148, and 163 Ma, minor peaks at 129, 177, 330, and 352 Ma, and no concordant zircons older than Devonian. A granite clast from a Valdez Group conglomerate yielded a Triassic U-Pb zircon age of 221 Ma. Like the McHugh Complex, the Valdez Group appears to have been derived almost entirely from Mesozoic arc sources, but a few Precambrian zircons are also present. Talkeetna Mountains - Detrital zircons ages were obtained from southernmost metasedimentary rocks of the

On the longevity of silicic magma based on multi-isotope investigation of zircons and modeling their survivals destinies

NASA Astrophysics Data System (ADS)

Bindeman, I. N.; Wotzlaw, J. F.; Melnik, O. E.

2015-12-01

Large volumes of crystal poor, near-liquidus rhyolites are erupted worldwide as tuffs and lavas in rift and hot spots more common previously on early earth, creating temporally very high magma production rates. In this contribution we combine results of IDTIMS dating of zircons with numerical modeling of zircon crystallization. New investigation of zircons in major Yellowstone tuffs: Huckleberry Ridge (Members A,B,C), Mesa Falls, and Lava Creek (A,B) tuffs was done by a combination of in situ measurements of oxygen isotopes followed by ID-TIMS U-Pb dating, Hf isotopes and trace elemental investigation of single crystals. We discover that nearly all zircons are of eruption age, but display significant isotope (O,Hf) diversity and often show decoupled O and Hf isotope systematics. This record rapid (~103yrs) double or triple remelting and sequestration from diverse Archean crust and hydrothermally altered shallow-crustal rocks from previous eruptive cycles, followed by effective mixing of co-existing magma reservoirs with diverse zircons prior to eruptions. Similar results characterize other studied Snake River Plain rhyolites in pre-Yellowstone Heise complex. These results collectively suggest that zircons crystallize after reheating above saturation rejuvenation in isotopically-diverse areas of the crust in the magma plumbing system. Modeling of zircon and quartz dissolution and crystallization trajectories outline conditions of survival (inheritance) vs complete dissolution on conductive timescales, and when combined with a phase diagram, magma T-t paths can be computed. Zircon rejuvenation requires hot, >770-800°C peak temperatures lasting 10-102yrs. We speculate that near liquidus hot and dry Yellowstone rhyolites are kept alive in a multi-batch state by a series of interconnected pods and sills that can rapidly get thermomechanically assembled into large, shallow and eruptable supervolcanoic magma bodies. We suggest that overpressure and roof dynamics and

Developing Novel Fluorescent Materials with Near Infrared Emission by Using m-Phenylene

NASA Technical Reports Server (NTRS)

Pang, Yi; Liao, Ling; Meador, Michael A.

2003-01-01

Our research focuses on development of novel p-conjugated polymers with desired emission. In the current study, the structure of a highly green-emitting poly[(m-phenylenevinylene)- alt-( p-phenylenevinylene)] has been modified by increasing the content of p-phenylene to achieve red- and infrared-emission. The polymer is synthesized via Wittig-Horner condensation, which is known to lead to trans-olefin linkage. The polymer is soluble in common organic solvents such as toluene, chloroform and THF. The spectroscopic properties of the polymer in both solution and film states will be discussed in comparison with its model compound.

Infrared spectroscopic analysis of skin tumor of mice treated with several medicinal plants

PubMed Central

Ali, Huma; Dixit, Savita

2013-01-01

Objective To evaluate the differences between cancerous tissue, drug treated tissue and its corresponding normal tissue by infrared spectroscopic analysis. Methods Methanolic extracts of Azadirachta indica, Ocimum sanctum, Aloe barbandesis, Tinospora cordifolia and Triticum aestivum were assessed for the isolation and purification of active compound. After that, combine crude and combine isolated samples were prepared. Skin tumor was induced by topical application of 7, 12-dimethyl benz (a) anthracene and promoted by croton oil in Swiss albino mice. To assess the chemopreventive potential of different drugs, it was administered at a concentration of 400 mg/kg body weight daily up to 16 weeks. Fourier transform infrared spectroscopy analysis was used to differentiate the drug treated tissues with the normal and cancerous tissue. In the present study, spectra of different tissues were recorded in the range of 400-4 000 cm−1. Results The results of the present study have shown that the remarkable difference exists between the IR spectra of normal, drugs treated and cancerous tissue in terms of frequencies and intensities of prominent bands of cellular biomolecules. Conclusions Fourier transform infrared spectroscopy analysis suggests the chemopreventive effect of above treated drugs and the best result was observed in combine crude sample and in combine isolated sample or synergistic effect of individual crude and isolated extract in 7, 12-dimethyl benz (a) anthracene croton oil induced skin carcinogenesis in Swiss albino mice.

Exploring the detection limits of infrared near-field microscopy regarding small buried structures and pushing them by exploiting superlens-related effects.

PubMed

Jung, Lena; Hauer, Benedikt; Li, Peining; Bornhöfft, Manuel; Mayer, Joachim; Taubner, Thomas

2016-03-07

We present a study on subsurface imaging with an infrared scattering-type scanning near-field optical microscope (s-SNOM). The depth-limitation for the visibility of gold nanoparticles with a diameter of 50 nm under Si 3 N 4 is determined to about 50 nm. We first investigate spot size and signal strength concerning their particle-size dependence for a dielectric cover layer with positive permittivity. The experimental results are confirmed by model calculations and a comparison to TEM images. In the next step, we investigate spectroscopically also the regime of negative permittivity of the capping layer and its influence on lateral resolution and signal strength in experiment and simulations. The explanation of this observation combines subsurface imaging and superlensing, and shows up limitations of the latter regarding small structure sizes.

Analysis of Urinary Calculi Using Infrared Spectroscopic Imaging

NASA Astrophysics Data System (ADS)

Sablinskas, Valdas; Lesciute, Daiva; Hendrixson, Vaiva

2009-06-01

Kidney stone disease is a cosmopolitan disease, occurring in both industrialized and developing countries and mainly affecting adults aged 2060 years. The formation of kidney stones is a process that includes many factors. Its primary and contributing pathogenic factors are genetic, nutritional and environmental, but also include personal habits. Information about the chemical structure of kidney stones is of great importance to the treatment of the kidney diseases. The usefulness of such information was first recognized in early 1950s. Analysis of urinary stones by various chemical methods, polarization microscopy, x-ray diffraction, porosity determination, solid phase NMR, and thermo analytical procedures have been widely used. Unfortunately, no one method is sufficient to provide all the clinically useful information about the structure and composition of the stones. Infrared spectroscopy can be considered a relatively new method of kidney stone analysis. It allows to identify any organic or inorganic molecules the constituents of kidney stones. So far this method had never been used to collect information about kidney stone component patterns in Lithuania. Since no epidemiological studies have been performed in this field, the medical treatment of kidney stone disease is empirical and often ineffective in hospitals around the country. The aim of this paper is to present some results of analysis of kidney stones extracted from local patients using FTIR spectroscopical microscopy.

Characteristics of zircon suitable for REE extraction

NASA Astrophysics Data System (ADS)

Watanabe, Y.; Hoshino, M.

2011-12-01

Zircons (ZrSiO4) from Naegi and Ohro granitic pegmatites, Japan and from Saigon alkaline basalt, Vietnam, were mineralogically characterized by inductively couples plasma mass spectrometry (ICP-MS), electron-microprobe analysis (EMPA), X-ray powder diffraction, micro-Raman spectroscopy and leaching experiment. The powder XRD and Raman spectra analyses show that the degree of crystallinity decreases from Saigon, to Ohro and Naegi zircons. Quantitative analytical results by the EMPA indicate that the Naegi and Ohro zircon samples contain a large amount of REE2O3, while REE contents in Saigon zircon are below detection limit. The leaching experiments for the present zircons under the condition of a solvent 1M-HCl, at a room temperature to 250 °C and retention time of 30h resulted in about 100 %, 50 % and 1 % recoveries of REE from the Naegi, Ohro and Saigon zircons, respectively. Leaching experiments for the Naegi zircon under the condition of a solvent 1N-HCl, heating temperature of 50 °C, 100 °C, 150 °C and 200 °C, and retention time 30h, showed that a significant amount of REE was leached out at a temperature above 150 °C. However, the leaching experiments of the Naegi and Ohro zircons at room temperature (about 25 °C) show that REE were hard to be leached. These results indicates that both low crystallinity of zircon and higher leaching temperature are requisite for effective leaching of REE from zircon.

Infrared LED Enhanced Spectroscopic CdZnTe Detector Working under High Fluxes of X-rays

PubMed Central

Pekárek, Jakub; Dědič, Václav; Franc, Jan; Belas, Eduard; Rejhon, Martin; Moravec, Pavel; Touš, Jan; Voltr, Josef

2016-01-01

This paper describes an application of infrared light-induced de-polarization applied on a polarized CdZnTe detector working under high radiation fluxes. We newly demonstrate the influence of a high flux of X-rays and simultaneous 1200-nm LED illumination on the spectroscopic properties of a CdZnTe detector. CdZnTe detectors operating under high radiation fluxes usually suffer from the polarization effect, which occurs due to a screening of the internal electric field by a positive space charge caused by photogenerated holes trapped at a deep level. Polarization results in the degradation of detector charge collection efficiency. We studied the spectroscopic behavior of CdZnTe under various X-ray fluxes ranging between 5×105 and 8×106 photons per mm2 per second. It was observed that polarization occurs at an X-ray flux higher than 3×106 mm−2·s−1. Using simultaneous illumination of the detector by a de-polarizing LED at 1200 nm, it was possible to recover X-ray spectra originally deformed by the polarization effect. PMID:27690024

Near-infrared hyperspectral imaging of water evaporation dynamics for early detection of incipient caries.

PubMed

Usenik, Peter; Bürmen, Miran; Fidler, Aleš; Pernuš, Franjo; Likar, Boštjan

2014-10-01

Incipient caries is characterized as demineralization of the tooth enamel reflecting in increased porosity of enamel structure. As a result, the demineralized enamel may contain increased amount of water, and exhibit different water evaporation dynamics than the sound enamel. The objective of this paper is to assess the applicability of water evaporation dynamics of sound and demineralized enamel for detection and quantification of incipient caries using near-infrared hyperspectral imaging. The time lapse of water evaporation from enamel samples with artificial and natural caries lesions of different stages was imaged by a near-infrared hyperspectral imaging system. Partial least squares regression was used to predict the water content from the acquired spectra. The water evaporation dynamics was characterized by a first order logarithmic drying model. The calculated time constants of the logarithmic drying model were used as the discriminative feature. The conducted measurements showed that demineralized enamel contains more water and exhibits significantly faster water evaporation than the sound enamel. By appropriate modelling of the water evaporation process from the enamel surface, the contrast between the sound and demineralized enamel observed in the individual near infrared spectral images can be substantially enhanced. The presented results indicate that near-infrared based prediction of water content combined with an appropriate drying model presents a strong foundation for development of novel diagnostic tools for incipient caries detection. The results of the study enhance the understanding of the water evaporation process from the sound and demineralized enamel and have significant implications for the detection of incipient caries by near-infrared hyperspectral imaging. Copyright © 2014 Elsevier Ltd. All rights reserved.

Thermal events documented in Hadean zircons by ion microprobe depth profiles

NASA Astrophysics Data System (ADS)

Trail, Dustin; Mojzsis, Stephen J.; Harrison, T. Mark

2007-08-01

We report the first U-Th-Pb ion microprobe depth profiles of four Hadean zircons from the Jack Hills and Mount Narryer supracrustal belts of the Narryer Gneiss Complex (NGC), Western Australia. This ultra-high spatial resolution technique probes the age and origin of sub-micron features in individual crystals that can record episodes of zircon growth. Near-surface grain dates of 2700 Ma or older are coincident with post-depositional growth/modification. Some ages may coincide with documented pre-deposition metamorphic events for the NGC and igneous emplacement at ca. 3700 Ma. Separate events that do not correlate in time with known geologic episodes prior to the preserved rock record are also present on pre-4000 Ma zircons. We find evidence for a ˜3.9 Ga event, which is coterminous within age uncertainty with one or several large basin-forming impacts (e.g. Nectaris) on the Moon attributed to the late heavy bombardment of the inner solar system.

Near-infrared observations of the variable crab nebula

NASA Astrophysics Data System (ADS)

Yamamoto, M.; Mori, K.; Shibata, S.; Tsujimoto, M.; Misawa, T.; Burrows, D.; Kawai, N.

We present three near-infrared NIR observations of the Crab Nebula obtained with CISCO on the Subaru Telescope and Quick Infrared Camera on the University of HAWAII 88 inch Telescope The observations were performed on 2004 September 2005 February and 2005 October and were coordinated with X-ray observations obtained with the Chandra X-ray observatory within 10 days As shown in previous optical and X-ray monitoring observations outward-moving wisps and variable knots are detected also in our NIR observations The NIR variations are closely correlated with variations in the X-ray observations indicating that both variations are driven by the same physical process We discuss the origin of NIR-emitting particles based on the temporal variations as well as the spectral energy distributions of each variable component

Mid-Infrared (MIR) and Near-Infrared (NIR) Detection of Rhizoctonia solani AG 2-2 IIIB on Barley-Based Artificial Inoculum.

PubMed

Webb, Kimberly M; Calderón, Francisco J

2015-10-01

The amount of Rhizoctonia solani in the soil and how much must be present to cause disease in sugar beet (Beta vulgaris L.) is relatively unknown. This is mostly because of the usually low inoculum densities found naturally in soil and the low sensitivity of traditional serial dilution assays. We investigated the usefulness of Fourier transform mid-infrared (MIR) and near-infrared (NIR) spectroscopic properties in identifying the artificial colonization of barley grains with R. solani AG 2-2 IIIB and in detecting R. solani populations in plant tissues and inoculants. The objectives of this study were to compare the ability of traditional plating assays to NIR and MIR spectroscopies to identify R. solani in different-size fractions of colonized ground barley (used as an artificial inoculum) and to differentiate colonized from non-inoculated barley. We found that NIR and MIR spectroscopies were sensitive in resolving different barley particle sizes, with particles that were <0.25 and 0.25-0.5 mm having different spectral properties than coarser particles. Moreover, we found that barley colonized with R. solani had different MIR spectral properties than the non-inoculated samples for the larger fractions (0.5-1.0, 1.0-2.0, and >2.0 mm) of the ground barley. This colonization was confirmed using traditional plating assays. Comparisons with the spectra from pure fungal cultures and non-inoculated barley suggest that the MIR spectrum of colonized barley is different because of the consumption of C substrates by the fungus rather than because of the presence of fungal bands in the spectra of the colonized samples. We found that MIR was better than NIR spectroscopy in differentiating the colonized from the control samples.

Correction: Spectroscopic characteristics of the OSIRIS near-backscattering crystal analyser spectrometer on the ISIS pulsed neutron source.

PubMed

Telling, Mark T F; Campbell, Stuart I; Engberg, Dennis; Martín Y Marero, David; Andersen, Ken H

2016-03-21

Correction for 'Spectroscopic characteristics of the OSIRIS near-backscattering crystal analyser spectrometer on the ISIS pulsed neutron source' by Mark T. F. Telling et al., Phys. Chem. Chem. Phys., 2005, 7, 1255-1261.

Social Perception in Infancy: A Near Infrared Spectroscopy Study

ERIC Educational Resources Information Center

Lloyd-Fox, Sarah; Blasi, Anna; Volein, Agnes; Everdell, Nick; Elwell, Claire E.; Johnson, Mark H.

2009-01-01

The capacity to engage and communicate in a social world is one of the defining characteristics of the human species. While the network of regions that compose the social brain have been the subject of extensive research in adults, there are limited techniques available for monitoring young infants. This study used near infrared spectroscopy to…

THE NASA AMES POLYCYCLIC AROMATIC HYDROCARBON INFRARED SPECTROSCOPIC DATABASE: THE COMPUTED SPECTRA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bauschlicher, C. W.; Ricca, A.; Boersma, C.

The astronomical emission features, formerly known as the unidentified infrared bands, are now commonly ascribed to polycyclic aromatic hydrocarbons (PAHs). The laboratory experiments and computational modeling done at the NASA Ames Research Center to create a collection of PAH IR spectra relevant to test and refine the PAH hypothesis have been assembled into a spectroscopic database. This database now contains over 800 PAH spectra spanning 2-2000 {mu}m (5000-5 cm{sup -1}). These data are now available on the World Wide Web at www.astrochem.org/pahdb. This paper presents an overview of the computational spectra in the database and the tools developed to analyzemore » and interpret astronomical spectra using the database. A description of the online and offline user tools available on the Web site is also presented.« less

Silicon Nitride Photonic Integration Platforms for Visible, Near-Infrared and Mid-Infrared Applications

PubMed Central

Micó, Gloria; Pastor, Daniel; Pérez, Daniel; Doménech, José David; Fernández, Juan; Baños, Rocío; Alemany, Rubén; Sánchez, Ana M.; Cirera, Josep M.; Mas, Roser

2017-01-01

Silicon nitride photonics is on the rise owing to the broadband nature of the material, allowing applications of biophotonics, tele/datacom, optical signal processing and sensing, from visible, through near to mid-infrared wavelengths. In this paper, a review of the state of the art of silicon nitride strip waveguide platforms is provided, alongside the experimental results on the development of a versatile 300 nm guiding film height silicon nitride platform. PMID:28895906

Mid- and Near-infrared spectral properties of a sample of Swift-BAT X-ray selected AGNs

NASA Astrophysics Data System (ADS)

Castro, Angel; Miyaji, Takamitsu; Malkan, Matthew A.; Ichikawa, Kohei; Ueda, Yoshihiro; Shirahata, M.; Nakagawa, Takao; Imanishi, Masatoshi; Oyabu, Shinki

2015-08-01

We present a comparative study of the mid- (MIR) to near-infrared (NIR) properties of a sample of X-ray selected AGNs from the Swift/Burst Alert Telescope (BAT) 70-month all-sky hard X-ray (14-195 keV) survey. For a sample of 78 AGNs, including both Seyfert 1 and Seyfert 2 sources with black hole masses derived from 2MASS K-band magnitudes and literature, we obtain spectroscopic data from the IRC (2.5 - 5 μm) and IRS (in the 5-14 μm band) instruments onboard the Akari and Spitzer satellites, respectively. We test possible correlations between the 3.3, 6.2, 7.7, 8.6, 11.2 and 12.7 μm polycyclic aromatic hydrocarbon (PAH) emission features, the continuum slope and CO optical depth, as well as CO2, H2O, and amorphous silicates. Using the 3.3, 6.2 and 11.3 μm PAH emission features as a proxy for the star-formation rate (SFR) we report the AGN type and Eddington-ratio dependences of circum-nuclear star formation.

Mapping polycyclic aromatic hydrocarbon and total toxicity equivalent soil concentrations by visible and near-infrared spectroscopy.

PubMed

Okparanma, Reuben N; Coulon, Frederic; Mayr, Thomas; Mouazen, Abdul M

2014-09-01

In this study, we used data from spectroscopic models based on visible and near-infrared (vis-NIR; 350-2500 nm) diffuse reflectance spectroscopy to develop soil maps of polycyclic aromatic hydrocarbons (PAHs) and total toxicity equivalent concentrations (TTEC) of the PAH mixture. The TTEC maps were then used for hazard assessment of three petroleum release sites in the Niger Delta province of Nigeria (5.317°N, 6.467°E). As the paired t-test revealed, there were non-significant (p > 0.05) differences between soil maps of PAH and TTEC developed with chemically measured and vis-NIR-predicted data. Comparison maps of PAH showed a slight to moderate agreement between measured and predicted data (Kappa coefficient = 0.19-0.56). Using proposed generic assessment criteria, hazard assessment showed that the degree of action for site-specific risk assessment and/or remediation is similar for both measurement methods. This demonstrates that the vis-NIR method may be useful for monitoring hydrocarbon contamination in a petroleum release site. Copyright © 2014 Elsevier Ltd. All rights reserved.

Direct noninvasive observation of near infrared photobleaching of autofluorescence in human volar side fingertips in vivo

NASA Astrophysics Data System (ADS)

Deng, Bin; Wright, Colin; Lewis-Clark, Eric; Shaheen, G.; Geier, Roman; Chaiken, J.

2010-02-01

Human transdermal in vivo spectroscopic applications for tissue analysis involving near infrared (NIR) light often must contend with broadband NIR fluorescence that, depending on what kind of spectroscopy is being employed, can degrade signal to noise ratios and dynamic range. Such NIR fluorescence, i.e. "autofluorescence" is well known to originate in blood tissues and various other endogenous materials associated with the static tissues. Results of recent experiments on human volar side fingertips in vivo are beginning to provide a relative ordering of the contributions from various sources. Preliminary results involving the variation in the bleaching effect across different individuals suggest that for 830 nm excitation well over half of the total fluorescence comes from the static tissues and remainder originates with the blood tissues, i.e. the plasma and the hematocrit. Of the NIR fluorescence associated with the static tissue, over half originates with products of well-known post-enzymatic glycation reactions, i.e. Maillard chemistry, in the skin involving glucose and other carbohydrates and skin proteins like collagen and cytosol proteins.

Exploring the early dust-obscured phase of galaxy formation with blind mid-/far-infrared spectroscopic surveys

NASA Astrophysics Data System (ADS)

Bonato, M.; Negrello, M.; Cai, Z.-Y.; De Zotti, G.; Bressan, A.; Lapi, A.; Gruppioni, C.; Spinoglio, L.; Danese, L.

2014-03-01

While continuum imaging data at far-infrared to submillimetre wavelengths have provided tight constraints on the population properties of dusty star-forming galaxies up to high redshifts, future space missions like the Space Infrared Telescope for Cosmology and Astrophysics (SPICA) and ground-based facilities like the Cerro Chajnantor Atacama Telescope (CCAT) will allow detailed investigations of their physical properties via their mid-/far-infrared line emission. We present updated predictions for the number counts and the redshift distributions of star-forming galaxies spectroscopically detectable by these future missions. These predictions exploit a recent upgrade of evolutionary models, that include the effect of strong gravitational lensing, in the light of the most recent Herschel and South Pole Telescope data. Moreover the relations between line and continuum infrared luminosity are re-assessed, considering also differences among source populations, with the support of extensive simulations that take into account dust obscuration. The derived line luminosity functions are found to be highly sensitive to the spread of the line to continuum luminosity ratios. Estimates of the expected numbers of detections per spectral line by SPICA/SpicA FAR-infrared Instrument (SAFARI) and by CCAT surveys for different integration times per field of view at fixed total observing time are presented. Comparing with the earlier estimates by Spinoglio et al. we find, in the case of SPICA/SAFARI, differences within a factor of 2 in most cases, but occasionally much larger. More substantial differences are found for CCAT.

Tunable broadband near-infrared absorber based on ultrathin phase-change material

NASA Astrophysics Data System (ADS)

Hu, Er-Tao; Gu, Tong; Guo, Shuai; Zang, Kai-Yan; Tu, Hua-Tian; Yu, Ke-Han; Wei, Wei; Zheng, Yu-Xiang; Wang, Song-You; Zhang, Rong-Jun; Lee, Young-Pak; Chen, Liang-Yao

2017-11-01

In this work, a tunable broadband near-infrared light absorber was designed and fabricated with a simple and lithography free approach by introducing an ultrathin phase-change material Ge2Sb2Te5 (GST) layer into the metal-dielectric multilayered film structure with the structure parameters as that: SiO2 (72.7 nm)/Ge2Sb2Te5 (6.0 nm)/SiO2 (70.2 nm)/Cu (>100.0 nm). The film structure exhibits a modulation depth of ∼72.6% and an extinction ratio of ∼8.8 dB at the wavelength of 1410 nm. The high light absorption (95%) of the proposed film structure at the wavelength of 450 nm in both of the amorphous and crystalline phase of GST, indicates that the intensity of the reflectance in the infrared region can be rapidly tuned by the blue laser pulses. The proposed planar layered film structure with layer thickness as the only controllable parameter and large reflectivity tuning range shows the potential for practical applications in near-infrared light modulation and absorption.

Broadband near-field infrared spectromicroscopy using photothermal probes and synchrotron radiation.

PubMed

Donaldson, Paul M; Kelley, Chris S; Frogley, Mark D; Filik, Jacob; Wehbe, Katia; Cinque, Gianfelice

2016-02-08

In this paper, we experimentally demonstrate the use of infrared synchrotron radiation (IR-SR) as a broadband source for photothermal near-field infrared spectroscopy. We assess two methods of signal transduction; cantilever resonant thermal expansion and scanning thermal microscopy. By means of rapid mechanical chopping (50-150 kHz), we modulate the IR-SR at rates matching the contact resonance frequencies of atomic force microscope (AFM) cantilevers, allowing us to record interferograms yielding Fourier transform infrared (FT-IR) photothermal absorption spectra of polystyrene and cyanoacrylate films. Complementary offline measurements using a mechanically chopped CW IR laser confirmed that the resonant thermal expansion IR-SR measurements were below the diffraction limit, with a spatial resolution better than 500 nm achieved at a wavelength of 6 μm, i.e. λ/12 for the samples studied. Despite achieving the highest signal to noise so far for a scanning thermal microscopy measurement under conditions approaching near-field (dictated by thermal diffusion), the IR-SR resonant photothermal expansion FT-IR spectra measured were significantly higher in signal to noise in comparison with the scanning thermal data.

An Infrared Multi-Object Spectrograph (IRMS) with adaptive optics for TMT: the science case

NASA Astrophysics Data System (ADS)

Mobasher, Bahram; Crampton, David; Simard, Luc

2010-07-01

It has been recognized that a Near-Infrared Multi-object Spectrograph (IRMS) as one of the first light instrument on the Thirty Meter Telescope (TMT) would significantly increase the scientific capability of the observatory. The IRMS is planned to be a clone of the MOSFIRE instrument on the Keck telescope. As a result, we use the already available MOSFIRE design and expertise, significantly reducing the total cost and its development time. The IRMS will be a quasi diffraction limited multi-slit spectrograph with moderate resolution (R~4000), fed by Narrow-Field Infrared Adaptive Optics System (NFIRAOS). It images over the 2 arcmin diameter field of view of the NFIRAOS. There are a number of exceedingly important scientific questions, waiting to be addressed by the TMT/IRMS combination. Given its relatively small field of view, it is less affected by the sky background, which is a limiting factor in ground-based observations at near-IR wavelengths. The IRMS is the ideal instrument for studying spectroscopic properties of galaxies at the re-ionization epoch (z > 7), where the Lyman alpha line shifts to the near-ir wavelenghths. It can be used to measure rotation curves of spiral and velocity dispersion of elliptical galaxies at z~2-3 and hence, their spectroscopic mass. It can be used to search for population III stars via their spectroscopic signature and to perform measurement of spectroscopic lines at high redshifts, diagnostic of metallicity. Finally, IRMS allows measurement of the blue shifts in the rest-frame MgII line for high redshift galaxies, used to study the winds, leading to the feedback mechanism, responsible for quenching star formation activity in galaxies.

The science enabled by the Maunakea Spectroscopic Explorer

NASA Astrophysics Data System (ADS)

Martin, N. F.; Babusiaux, C.

2017-12-01

With its unique wide-field, multi-object, and dedicated spectroscopic capabilities, the Maunakea Spectroscopic Explorer (MSE) is a powerful facility to shed light on the faint Universe. Built around an upgrade of the Canada-France Hawaii Telescope (CFHT) to a 11.25-meter telescope with a dedicated ˜1.5 deg^2, 4,000-fiber wide-field spectrograph that covers the optical and near-infrared wavelengths at resolutions between 2,500 and 40,000, the MSE is the essential follow-up complement to the current and next generations of multi-wavelength imaging surveys, such as the LSST, Gaia, Euclid, eROSITA, SKA, and WFIRST, and is an ideal feeder facility for the extremely large telescopes that are currently being built (E-ELT, GMT, and TMT). The science enabled by the MSE is vast and would have an impact on almost all aspects of astronomy research.

Spectroscopic methods for the photodiagnosis of nonmelanoma skin cancer.

PubMed

Drakaki, Eleni; Vergou, Theognosia; Dessinioti, Clio; Stratigos, Alexander J; Salavastru, Carmen; Antoniou, Christina

2013-06-01

The importance of dermatological noninvasive imaging techniques has increased over the last decades, aiming at diagnosing nonmelanoma skin cancer (NMSC). Technological progress has led to the development of various analytical tools, enabling the in vivo/in vitro examination of lesional human skin with the aim to increase diagnostic accuracy and decrease morbidity and mortality. The structure of the skin layers, their chemical composition, and the distribution of their compounds permits the noninvasive photodiagnosis of skin diseases, such as skin cancers, especially for early stages of malignant tumors. An important role in the dermatological diagnosis and disease monitoring has been shown for promising spectroscopic and imaging techniques, such as fluorescence, diffuse reflectance, Raman and near-infrared spectroscopy, optical coherence tomography, and confocal laser-scanning microscopy. We review the use of these spectroscopic techniques as noninvasive tools for the photodiagnosis of NMSC.

Spectroscopic methods for the photodiagnosis of nonmelanoma skin cancer

NASA Astrophysics Data System (ADS)

Drakaki, Eleni; Vergou, Theognosia; Dessinioti, Clio; Stratigos, Alexander J.; Salavastru, Carmen; Antoniou, Christina

2013-06-01

The importance of dermatological noninvasive imaging techniques has increased over the last decades, aiming at diagnosing nonmelanoma skin cancer (NMSC). Technological progress has led to the development of various analytical tools, enabling the in vivo/in vitro examination of lesional human skin with the aim to increase diagnostic accuracy and decrease morbidity and mortality. The structure of the skin layers, their chemical composition, and the distribution of their compounds permits the noninvasive photodiagnosis of skin diseases, such as skin cancers, especially for early stages of malignant tumors. An important role in the dermatological diagnosis and disease monitoring has been shown for promising spectroscopic and imaging techniques, such as fluorescence, diffuse reflectance, Raman and near-infrared spectroscopy, optical coherence tomography, and confocal laser-scanning microscopy. We review the use of these spectroscopic techniques as noninvasive tools for the photodiagnosis of NMSC.

Bi-color near infrared thermoreflectometry: a method for true temperature field measurement.

PubMed

Sentenac, Thierry; Gilblas, Rémi; Hernandez, Daniel; Le Maoult, Yannick

2012-12-01

In a context of radiative temperature field measurement, this paper deals with an innovative method, called bicolor near infrared thermoreflectometry, for the measurement of true temperature fields without prior knowledge of the emissivity field of an opaque material. This method is achieved by a simultaneous measurement, in the near infrared spectral band, of the radiance temperature fields and of the emissivity fields measured indirectly by reflectometry. The theoretical framework of the method is introduced and the principle of the measurements at two wavelengths is detailed. The crucial features of the indirect measurement of emissivity are the measurement of bidirectional reflectivities in a single direction and the introduction of an unknown variable, called the "diffusion factor." Radiance temperature and bidirectional reflectivities are then merged into a bichromatic system based on Kirchhoff's laws. The assumption of the system, based on the invariance of the diffusion factor for two near wavelengths, and the value of the chosen wavelengths, are then discussed in relation to a database of several material properties. A thermoreflectometer prototype was developed, dimensioned, and evaluated. Experiments were carried out to outline its trueness in challenging cases. First, experiments were performed on a metallic sample with a high emissivity value. The bidirectional reflectivity was then measured from low signals. The results on erbium oxide demonstrate the power of the method with materials with high emissivity variations in near infrared spectral band.

Infrared spectroscopic characterization of monocytic microvesicles (microparticles) released upon lipopolysaccharide stimulation.

PubMed

Lee, Joonsup; Wen, Beryl; Carter, Elizabeth A; Combes, Valery; Grau, Georges E R; Lay, Peter A

2017-07-01

Microvesicles (MVs) are involved in cell-cell interactions, including disease pathogenesis. Nondestructive Fourier-transform infrared (FTIR) spectra from MVs were assessed as a technique to provide new biochemical insights into a LPS-induced monocyte model of septic shock. FTIR spectroscopy provided a quick method to investigate relative differences in biomolecular content of different MV populations that was complementary to traditional semiquantitative omics approaches, with which it is difficult to provide information on relative changes between classes (proteins, lipids, nucleic acids, carbohydrates) or protein conformations. Time-dependent changes were detected in biomolecular contents of MVs and in the monocytes from which they were released. Differences in phosphatidylcholine and phosphatidylserine contents were observed in MVs released under stimulation, and higher relative concentrations of RNA and α-helical structured proteins were present in stimulated MVs compared with MVs from resting cells. FTIR spectra of stimulated monocytes displayed changes that were consistent with those observed in the corresponding MVs they released. LPS-stimulated monocytes had reduced concentrations of nucleic acids, α-helical structured proteins, and phosphatidylcholine compared with resting monocytes but had an increase in total lipids. FTIR spectra of MV biomolecular content will be important in shedding new light on the mechanisms of MVs and the different roles they play in physiology and disease pathogenesis.-Lee, J., Wen, B., Carter, E. A., Combes, V., Grau, G. E. R., Lay, P. A. Infrared spectroscopic characterization of monocytic microvesicles (microparticles) released upon lipopolysaccharide stimulation. © FASEB.

Eye safety related to near infrared radiation exposure to biometric devices.

PubMed

Kourkoumelis, Nikolaos; Tzaphlidou, Margaret

2011-03-01

Biometrics has become an emerging field of technology due to its intrinsic security features concerning the identification of individuals by means of measurable biological characteristics. Two of the most promising biometric modalities are iris and retina recognition, which primarily use nonionizing radiation in the infrared region. Illumination of the eye is achieved by infrared light emitting diodes (LEDs). Even if few LED sources are capable of causing direct eye damage as they emit incoherent light, there is a growing concern about the possible use of LED arrays that might pose a potential threat. Exposure to intense coherent infrared radiation has been proven to have significant effects on living tissues. The purpose of this study is to explore the biological effects arising from exposing the eye to near infrared radiation with reference to international legislation.

Near-Infrared Scintillation of Liquid Argon: Recent Results Obtained with the NIR Facility at Fermilab

DOE Office of Scientific and Technical Information (OSTI.GOV)

Escobar, C. O.; Rubinov, P.; Tilly, E.

After a short review of previous attempts to observe and measure the near-infrared scintillation in liquid argon, we present new results obtained with NIR, a dedicated cryostat at the Fermilab Proton Assembly Building (PAB). The new results give confidence that the near-infrared light can be used as the much needed light signal in large liquid argon time projection chambers.11 pages,

[Study on rapid determination and analysis of rocket kerosene by near infrared spectrum and chemometrics].

PubMed

Xia, Ben-Li; Cong, Ji-Xin; Li, Xia; Wang, Xuan-Jun

2011-06-01

The rocket kerosene quality properties such as density, distillation range, viscosity and iodine value were successfully measured based on their near-infrared spectrum (NIRS) and chemometrics. In the present paper, more than 70 rocket kerosene samples were determined by near infrared spectrum, the models were built using the partial least squares method within the appropriate wavelength range. The correlation coefficients (R2) of every rocket kerosene's quality properties ranged from 0.862 to 0.999. Ten unknown samples were determined with the model, and the result showed that the prediction accuracy of near infrared spectrum method accords with standard analysis requirements. The new method is well suitable for replacing the traditional standard method to rapidly determine the properties of the rocket kerosene.

Classification of Fusarium-Infected Korean Hulled Barley Using Near-Infrared Reflectance Spectroscopy and Partial Least Squares Discriminant Analysis

PubMed Central

Lim, Jongguk; Kim, Giyoung; Mo, Changyeun; Oh, Kyoungmin; Yoo, Hyeonchae; Ham, Hyeonheui; Kim, Moon S.

2017-01-01

The purpose of this study is to use near-infrared reflectance (NIR) spectroscopy equipment to nondestructively and rapidly discriminate Fusarium-infected hulled barley. Both normal hulled barley and Fusarium-infected hulled barley were scanned by using a NIR spectrometer with a wavelength range of 1175 to 2170 nm. Multiple mathematical pretreatments were applied to the reflectance spectra obtained for Fusarium discrimination and the multivariate analysis method of partial least squares discriminant analysis (PLS-DA) was used for discriminant prediction. The PLS-DA prediction model developed by applying the second-order derivative pretreatment to the reflectance spectra obtained from the side of hulled barley without crease achieved 100% accuracy in discriminating the normal hulled barley and the Fusarium-infected hulled barley. These results demonstrated the feasibility of rapid discrimination of the Fusarium-infected hulled barley by combining multivariate analysis with the NIR spectroscopic technique, which is utilized as a nondestructive detection method. PMID:28974012

Uniformly mantle-like δ18O in zircons from oceanic plagiogranites and gabbros

NASA Astrophysics Data System (ADS)

Grimes, Craig B.; Ushikubo, Takayuki; John, Barbara E.; Valley, John W.

2011-01-01

Lower ocean crust is primarily gabbroic, although 1-2% felsic igneous rocks that are referred to collectively as plagiogranites occur locally. Recent experimental evidence suggests that plagiogranite magmas can form by hydrous partial melting of gabbro triggered by seawater-derived fluids, and thus they may indicate early, high-temperature hydrothermal fluid circulation. To explore seawater-rock interaction prior to and during the genesis of plagiogranite and other late-stage magmas, oxygen-isotope ratios preserved in igneous zircon have been measured by ion microprobe. A total of 197 zircons from 43 plagiogranite, evolved gabbro, and hydrothermally altered fault rock samples have been analyzed. Samples originate primarily from drill core acquired during Ocean Drilling Program and Integrated Ocean Drilling Program operations near the Mid-Atlantic and Southwest Indian Ridges. With the exception of rare, distinctively luminescent rims, all zircons from ocean crust record remarkably uniform δ18O with an average value of 5.2 ± 0.5‰ (2SD). The average δ18O(Zrc) would be in magmatic equilibrium with unaltered MORB [δ18O(WR) ~ 5.6-5.7‰], and is consistent with the previously determined value for equilibrium with the mantle. The narrow range of measured δ18O values is predicted for zircon crystallization from variable parent melt compositions and temperatures in a closed system, and provides no indication of any interactions between altered rocks or seawater and the evolved parent melts. If plagiogranite forms by hydrous partial melting, the uniform mantle-like δ18O(Zrc) requires melting and zircon crystallization prior to significant amounts of water-rock interactions that alter the protolith δ18O. Zircons from ocean crust have been proposed as a tectonic analog for >3.9 Ga detrital zircons from the earliest (Hadean) Earth by multiple workers. However, zircons from ocean crust are readily distinguished geochemically from zircons formed in continental crustal

Ratiometric near infrared luminescent thermometer based on lanthanide metal-organic frameworks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yue, Dan; Zhang, Jun; Zhao, Dian

2016-09-15

A near infrared luminescent MOFs thermometer (Nd{sub 0.676}Yb{sub 0.324}BTC) was prepared via a simple solvothermal method using Ln{sup 3+} (Ln=Nd, Yb) ions and 1, 3, 5-benznenetricarboxylic acid (H{sub 3}BTC), and characterized by PXRD, TGA, ICP, and photoluminescence (PL) spectrum. These results indicate that the Nd{sub 0.676}Yb{sub 0.324}BTC displays high relative sensitivity and excellent repeatability in the physiological temperature range (288–323 K), and the maximum relative sensitivity is determined to be 1.187% K{sup −1} at 323 K. These NIR luminescent MOFs may have potential applications in physiological temperature sensing. - Graphical abstract: A near infrared luminescent MOFs thermometer (Nd{sub 0.054}Yb{sub 0.946}BTCmore » ) displays high relative sensitivity and excellent repeatability in the physiological temperature range (288–323 K). Display Omitted - Highlights: • A ratiometric near infrared luminescent MOFs thermometer (Nd{sub 0.676}Yb{sub 0.324}BTC) was prepared via a simple solvothermal method. • The maximum relative sensitivity of Nd{sub 0.676}Yb{sub 0.324}BTC is determined to be 1.187% K{sup −1} at 323 K. • Nd{sub 0.676}Yb{sub 0.324}BTC showed excellent repeatability in the physiological temperature range (288–323 K).« less