Sample records for zirkonia hasil olah
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Additional Information US 4,394,247 LIQUEFACTION OF COALS USING RECYCLABLE SUPERACID CATALYST - Olah, George catalytic condensation using superacid catalysts. US 4,465,893 OXIDATIVE CONDENSATION OF NATURAL GAS OR ., synthetic transportation fuels or lower olefins) via catalytic condensation using superacid catalysts. US
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George A. Olah, Carbocation and Hydrocarbon Chemistry
. Final Technical Report. [HF:BF{sub 2}/H{sub 2}] , DOE Technical Report, 1980 Superacid Catalyzed Coal Conversion Chemistry. 1st and 2nd Quarterly Technical Progress Reports, September 1, 1983-March 30, 1984 , DOE Technical Report, 1984 Superacid Catalyzed Coal Conversion Chemistry. Final Technical Report
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Designing Their Own: Increasing Urban High School Teacher Capacity for Creating Interim Assessments
ERIC Educational Resources Information Center
Ado, Kathryn
2013-01-01
This case study analyzes and documents factors that affect teacher learning and instructional practices in connection to the design your own (DYO) interim or periodic assessment process at one newly developed high school in New York City. Examining these factors through Riggan and Nabors Olah's (2011) conceptual framework offers insights into the…
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1982-07-20
02NOCuOH Any mechanism suggested for the nitration of aromatic systems by titanium(IV) nitrate must take into account the observed similarity, in...occurs. -26- References 1. For recent reviews see (a) R. B. Moodie and K. Schofield, Accounts Chem. Res., 1976, 9, 287; (b) G. A. Olah and S. J. Kuhn...Ithaca, N.Y., 1969, Chapter VI; L. M. Stock, Prog. Phys. Org. Chem., 1976, 12, 21; J. G. Hoggett , R. B. Moodie, J. R. Penton, and K. Schofield
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2004-03-23
Phys. Chem. 1995, 99, 187. [11] G. Schatte, H. Willner, Z. Naturforsch. 1991 , 46b, 483. [12] G. Rasul, G. K. S. Prakash, G. A. Olah, J. Am. Chem. Soc...170. [18] T. Curtius, Ber. Dtsch. Chem. Ges. 1890, 23, 3023. [19] A. V. Pankratov , N. I. Savenkova, Russ. J. Inorg. Chem. 1968, 13, 1345. [20] K. O...Christe, R. D. Wilson, W. W. Wilson, R. Bau, S. Sukumar, D. A. Dixon, J. Am. Chem. Soc. 1991 , 113, 3795. [21] K. O. Christe, D. A. Dixon, D. McLemore, W
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Nuclear Magnetic Resonance Spectroscopy
1992-04-23
prototypical materials. NMR spectros- 3 copy has proven itself to be exceptionally adaptable to new Av I t 1 ab I 1 ty Godea SENiS 13 problem areas. A good ...8217 SENIS 4 as a scholarly enterprise is clearly in good health. Ironically, 3 the number of NMR articles published in this journal is down SENis 14...s tailed assessment of this method (JI) which also serves as a SEN0 o good overview of the relevant literature. Olah has published sRN12s NMR studies
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Olah, George A; Mathew, Thomas; Prakash, G K Surya; Rasul, Golam
2016-02-10
Astrophysically observed extraterrestrial molecular matter contains, besides hydrogen and water, methane and methanol as the most abundant species. Feasible pathways and chemical aspects of their formation as well as of derived hydrocarbon homologues and their ions (carbocations and carbanions) are discussed on the basis of observed similarities with our studied terrestrial chemistry. The preferred pathway for converting extraterrestrial methane according to Ali et al. is based on CH5(+) and Olah's related nonclassical carbonium ion chemistry. On the basis of the observed higher reactivity of methanol compared with methane in various chemical reactions, a feasible new pathway is proposed for the conversion of extraterrestrial methanol to hydrocarbons, their derivatives, and carbocations together with a possible connection with methonium ion-based chemistry.
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Panzer, René; Guhrenz, Chris; Haubold, Danny; Hübner, René; Gaponik, Nikolai; Eychmüller, Alexander; Weigand, Jan J
2017-11-13
Tri(pyrazolyl)phosphanes (5 R1,R2 ) are utilized as an alternative, cheap and low-toxic phosphorus source for the convenient synthesis of InP/ZnS quantum dots (QDs). From these precursors, remarkably long-term stable stock solutions (>6 months) of P(OLA) 3 (OLAH=oleylamine) are generated from which the respective pyrazoles are conveniently recovered. P(OLA) 3 acts simultaneously as phosphorus source and reducing agent in the synthesis of highly emitting InP/ZnS core/shell QDs. These QDs are characterized by a spectral range between 530-620 nm and photoluminescence quantum yields (PL QYs) between 51-62 %. A proof-of-concept white light-emitting diode (LED) applying the InP/ZnS QDs as a color-conversion layer was built to demonstrate their applicability and processibility. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Nitration of naphthalene and remarks on the mechanism of electrophilic aromatic nitration.
Olah, G A; Narang, S C; Olah, J A
1981-06-01
Naphthalene was nitrated with a variety of nitrating agents. Comparison of data with Perrin's electrochemical nitration [Perrin, C. L. (1977) J. Am. Chem. Soc. 99, 5516-5518] shows that nitration of naphthalene gives an alpha-nitronaphthalene to beta-nitronaphthalene ratio that varies between 9 and 29 and is thus not constant. Perrin's data, therefore, are considered to be inconclusive evidence for the proposed one-electron transfer mechanism for the nitration of naphthalene and other reactive aromatics. Moodie and Schoefield [Hoggett, J. G., Moodie, R. B., Penton, J. R. & Schoefield, K. (1971) Nitration and Aromatic Reactivity (Cambridge Univ. Press, London)], as well as Perrin, independently concluded that, in the general scheme of nitration of reactive aromatics, there is the necessity to introduce into the classical Ingold mechanism an additional step involving a distinct intermediate preceding the formation of the Wheland intermediate (sigma complexes). This view coincides with our two-step mechanistic picture [Kuhn, S. J. & Olah, G. A. (1961) J. Am. Chem. Soc. 83, 4564-4571] of the nitronium salt nitration of aromatic hydrocarbons (including benzene and toluene), in which low substrate selectivity but high positional selectivity was found, indicating the independence of substrate from positional selectivity.
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Nitration of naphthalene and remarks on the mechanism of electrophilic aromatic nitration*
Olah, George A.; Narang, Subhash C.; Olah, Judith A.
1981-01-01
Naphthalene was nitrated with a variety of nitrating agents. Comparison of data with Perrin's electrochemical nitration [Perrin, C. L. (1977) J. Am. Chem. Soc. 99, 5516-5518] shows that nitration of naphthalene gives an α-nitronaphthalene to β-nitronaphthalene ratio that varies between 9 and 29 and is thus not constant. Perrin's data, therefore, are considered to be inconclusive evidence for the proposed one-electron transfer mechanism for the nitration of naphthalene and other reactive aromatics. Moodie and Schoefield [Hoggett, J. G., Moodie, R. B., Penton, J. R. & Schoefield, K. (1971) Nitration and Aromatic Reactivity (Cambridge Univ. Press, London)], as well as Perrin, independently concluded that, in the general scheme of nitration of reactive aromatics, there is the necessity to introduce into the classical Ingold mechanism an additional step involving a distinct intermediate preceding the formation of the Wheland intermediate (σ complexes). This view coincides with our two-step mechanistic picture [Kuhn, S. J. & Olah, G. A. (1961) J. Am. Chem. Soc. 83, 4564-4571] of the nitronium salt nitration of aromatic hydrocarbons (including benzene and toluene), in which low substrate selectivity but high positional selectivity was found, indicating the independence of substrate from positional selectivity. PMID:16593026
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DOE Office of Scientific and Technical Information (OSTI.GOV)
Tsz-Keung, Cheung; d`Itri, J.L.; Lange, F.C.
1995-12-31
The primary goal of this project is to evaluate the potential value of solid superacid catalysts of the sulfated zirconia type for light hydrocarbon conversion. The key experiments catalytic testing of the performance of such catalysts in a flow reactor fed with streams containing, for example, n-butane or propane. Fe- and Mn-promoted sulfated zirconia was used to catalyze the conversion of n-butane at atmospheric pressure, 225-450{degrees}C, and n-butane partial pressures in the range of 0.0025-0.01 atm. At temperatures <225{degrees}C, these reactions were accompanied by cracking; at temperatures >350{degrees}C, cracking and isomerization occurred. Catalyst deactivation, resulting at least in part frommore » coke formation, was rapid. The primary cracking products were methane, ethane, ethylene, and propylene. The observation of these products along with an ethane/ethylene molar ratio of nearly 1 at 450{degrees}C is consistent with cracking occurring, at least in part, by the Haag-Dessau mechanism, whereby the strongly acidic catalyst protonates n-butane to give carbonium ions. The rate of methane formation from n-butane cracking catalyzed by Fe- and Mn-promoted sulfated zirconia at 450{degrees}C was about 3 x 10{sup -8} mol/(g of catalyst {center_dot}s). The observation of butanes, pentanes, and methane as products is consistent with Olah superacid chemistry, whereby propane is first protonated by a very strong acid to form a carbonium ion. The carbonium ion then decomposes into methane and an ethyl cation which undergoes oligocondensation reactions with propane to form higher molecular weight alkanes. The results are consistent with the identification of iron- and manganese-promoted sulfated zirconia as a superacid.« less
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NASA Astrophysics Data System (ADS)
Syukriani, Andi; Juniati, Dwi; Siswono, Tatag Yuli Eko
2017-08-01
The purpose of this study was to explore the strategic competence of senior secondary school students in solving mathematics problems. Terdapat dua subjek, satu bergaya kognitif field-independent dan satu bergaya kognitif field-dependent tetapi keduanya memiliki tingkat prestasi belajar matematika yang setara. There were two subjects, one field-independent cognitive style and one field-dependent cognitive style. They had an equivalent high level of mathematics achievement. Keduanya dipilih berdasarkan hasil tes kompetensi matematika dan GEFT (Group Embedded Figures Test). Subjects were selected based on the test results of mathematics competence and GEFT (Group Embedded Figures Test). Kompetensi strategis dapat merangsang perkembangan otonomi dan fleksibilitas dalam diri siswa karena merupakan keterampilan yang sangat dibutuhkan di sepanjang abad 21. Gaya kognitif merupakan kecenderungan siswa dalam mengolah informasi sangat mempengaruhi performance dalam menyelesaikan masalah matematika. Strategic competence can stimulate the development of autonomy and flexibility of students and they are skills which are needed in the 21st century. Cognitive style is the tendency of students in processing informations and it greatly affects the performance in solving mathematics problems. Hasil penelitian menunjukkan bahwa subjek FI cenderung analitis baik pada pembentukan bayangannya maupun pada gambar yang dibuatnya untuk memproses informasi berdasarkan dengan struktur pengetahuannya sendiri (Internally directed). The research result showed that subject FI tended to be analytical both in forming the mental imagination and the picture to process information in accordance with his own knowledge structure (internally directed). Subjek FD kurang analitis dan tidak dapat mengenal bentuk sederhana (konsep matematika) dari bentuk yang kompleks (Exeternally directed) sehingga menerima ide sebagaimana yang disajikan. Subject FD was less analytical and unable to recognize simple form
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NASA Astrophysics Data System (ADS)
Ali, A.; Sittler, E. C.; Chornay, D.; Rowe, B. R.; Puzzarini, C.
2015-05-01
The discovery of carbocations and carbanions by Ion Neutral Mass Spectrometer (INMS) and the Cassini Plasma Spectrometer (CAPS) instruments onboard the Cassini spacecraft in Titan's upper atmosphere is truly amazing for astrochemists and astrobiologists. In this paper we identify the reaction mechanisms for the growth of the complex macromolecules observed by the CAPS Ion Beam Spectrometer (IBS) and Electron Spectrometer (ELS). This identification is based on a recently published paper (Ali et al., 2013. Planet. Space Sci. 87, 96) which emphasizes the role of Olah's nonclassical carbonium ion chemistry in the synthesis of the organic molecules observed in Titan's thermosphere and ionosphere by INMS. The main conclusion of that work was the demonstration of the presence of the cyclopropenyl cation - the simplest Huckel's aromatic molecule - and its cyclic methyl derivatives in Titan's atmosphere at high altitudes. In this study, we present the transition from simple aromatic molecules to the complex ortho-bridged bi- and tri-cyclic hydrocarbons, e.g., CH2+ mono-substituted naphthalene and phenanthrene, as well as the ortho- and peri-bridged tri-cyclic aromatic ring, e.g., perinaphthenyl cation. These rings could further grow into tetra-cyclic and the higher order ring polymers in Titan's upper atmosphere. Contrary to the pre-Cassini observations, the nitrogen chemistry of Titan's upper atmosphere is found to be extremely rich. A variety of N-containing hydrocarbons including the N-heterocycles where a CH group in the polycyclic rings mentioned above is replaced by an N atom, e.g., CH2+ substituted derivative of quinoline (benzopyridine), are found to be dominant in Titan's upper atmosphere. The mechanisms for the formation of complex molecular anions are discussed as well. It is proposed that many closed-shell complex carbocations after their formation first, in Titan's upper atmosphere, undergo the kinetics of electron recombination to form open-shell neutral
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NASA Astrophysics Data System (ADS)
Walsh, Edward J.
1999-10-01
. xxxiii + 426 pp. ISBN 0-471-33135-x. 135.00.
Surfaces, Interfaces, and Colloids: Principles and Applications, 2nd edition
Drew Myers. Wiley-VCH: New York, 1999. xx + 501 pp. ISBN 0-471-33060-4. 94.95.
Onium Ions
George A. Olah, Kenneth K. Laali, Qi Wang, and G. K. Surya Prakash. Wiley-Interscience: New York, 1998. xv + 509 pp. ISBN 0-471-14877-6. 110.00.
Environmental Soil and Water Chemistry: Principles and Applications V. P. Evangelou. Wiley-Interscience: New York, 1998. xix + 564 pp. ISBN 0-471-16515-8. 79.95.
1001 Chemicals in Everyday Products, 2nd edition
Grace Ross Lewis. Wiley-Interscience: New York, 1999. x + 388 pp. ISBN 0-471-29212-5. 39.95.
Organic Coatings: Science and Technology, 2nd edition
Zeno W. Wicks Jr., Frank N. Jones, and S. Peter Pappas. Wiley-Interscience: New York, 1999. xxi + 630 pp. ISBN 0-471-24507-0. 125.00.
Progress in Inorganic Chemistry, Vol. 48
Kenneth D. Karlin, Ed. Wiley-Interscience: New York, 1999. vi + 603 pp. ISBN 0-471-32623-2. 145.00.
Occupational Biomechanics, 3rd edition
Don B. Chaffin, Gunnar B. Andersson, and Bernard J. Martin. Wiley-Interscience: New York, 1999. xvii + 579 pp. ISBN 0-471-24697-2. 69.95.
Advances in Photochemistry, Vol. 25
Douglas C. Neckers, David H. Volman, and Gunther Von Bünau. Wiley-Interscience: New York, 1999. xi + 238 pp. ISBN 0-471-32708-5. 110.00.
Distillation
Johann G. Stichlmair and James R. Fair. Wiley-VCH: New York, 1998. xiii + 524 pp. ISBN 0-471-25241-7. 94.95.
Ammonia - Principles and Industrial Practice
Maz Appl. Wiley-VCH: New York, 1999. ix + 301 pp. ISBN 3-527-29593-3. 160.00.
Precursor-Derived Ceramics: Synthesis