Sedimentation in the Kane fracture zone, western North Atlantic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jaroslow, G.E.

1991-03-01

The Kane fracture zone, a deep narrow trough in oceanic crust, has provided an ideal depocenter for reservation on the seismic stratigraphic record of the North Atlantic basin. The acoustic stratigraphy in single-channel and multichannel seismic reflection profiles crossing the Kane fracture zone in the western North Atlantic has been examined in order to scrutinize age processes within a fracture zone. Maps of total sediment thickness have provided insight into overall sediment distribution and the influence of topography on sedimentation. Eight reflectors have been traced and correlated with lithostratigraphy at Deep Sea Drilling Project (DSDP) sites. The Bermuda Rise, amore » prominent topographic feature, has had a profound effect on the distribution of sediments within the fracture zone. Since late Eocene, the rise has blocked transport by turbidity currents of terrigenous sediments to distal portions of the fracture valley. A 1,000-m-thick turbidite pond within the fracture zone east of the Bermuda Rise has been determined to have been derived from local sources. Within the ponded sequence a seismic discontinuity is estimated to be early Oligocene and postdates the emergence of the Bermuda Rise, adding an independent age constraint on the development of the rise. The pond terminates against a structural dam at 55{degree}20W, east of which the fracture zone is essentially sediment starved.« less

Sonic logging for detecting the excavation disturbed and fracture zones

NASA Astrophysics Data System (ADS)

Lin, Y. C.; Chang, Y. F.; Liu, J. W.; Tseng, C. W.

2017-12-01

This study presents a new sonic logging method to detect the excavation disturbed zone (EDZ) and fracture zones in a tunnel. The EDZ is a weak rock zone where its properties and conditions have been changed by excavation, which results such as fracturing, stress redistribution and desaturation in this zone. Thus, the EDZ is considered as a physically less stable and could form a continuous and high-permeable pathway for groundwater flow. Since EDZ and fracture zone have the potential of affecting the safety of the underground openings and repository performance, many studies were conducted to characterize the EDZ and fracture zone by different methods, such as the rock mass displacements and strain measurements, seismic refraction survey, seismic tomography and hydraulic test, etc. In this study, we designed a new sonic logging method to explore the EDZ and fracture zone in a tunnel at eastern Taiwan. A high power and high frequency sonic system was set up which includes a two hydrophones pitch-catch technique with a common-offset immersed in water-filled uncased wells and producing a 20 KHz sound to scan the well rock. Four dominant sonic events were observed in the measurements, they are refracted P- and S-wave along the well rock, direct water wave and the reverberation in the well water. Thus the measured P- and S-wave velocities, the signal-to-noise ratio of the refraction and the amplitudes of reverberation along the well rock were used as indexes to determine the EDZ and fracture zone. Comparing these indexes with core samples shows that significant changes in the indexes are consistent with the EDZ and fracture zone. Thus, the EDZ and fracture zone can be detected by this new sonic method conclusively.

Stochastic Ground Water Flow Simulation with a Fracture Zone Continuum Model

USGS Publications Warehouse

Langevin, C.D.

2003-01-01

A method is presented for incorporating the hydraulic effects of vertical fracture zones into two-dimensional cell-based continuum models of ground water flow and particle tracking. High hydraulic conductivity features are used in the model to represent fracture zones. For fracture zones that are not coincident with model rows or columns, an adjustment is required for the hydraulic conductivity value entered into the model cells to compensate for the longer flowpath through the model grid. A similar adjustment is also required for simulated travel times through model cells. A travel time error of less than 8% can occur for particles moving through fractures with certain orientations. The fracture zone continuum model uses stochastically generated fracture zone networks and Monte Carlo analysis to quantify uncertainties with simulated advective travel times. An approach is also presented for converting an equivalent continuum model into a fracture zone continuum model by establishing the contribution of matrix block transmissivity to the bulk transmissivity of the aquifer. The methods are used for a case study in west-central Florida to quantify advective travel times from a potential wetland rehydration site to a municipal supply wellfield. Uncertainties in advective travel times are assumed to result from the presence of vertical fracture zones, commonly observed on aerial photographs as photolineaments.

Relating Cohesive Zone Model to Linear Elastic Fracture Mechanics

NASA Technical Reports Server (NTRS)

Wang, John T.

2010-01-01

The conditions required for a cohesive zone model (CZM) to predict a failure load of a cracked structure similar to that obtained by a linear elastic fracture mechanics (LEFM) analysis are investigated in this paper. This study clarifies why many different phenomenological cohesive laws can produce similar fracture predictions. Analytical results for five cohesive zone models are obtained, using five different cohesive laws that have the same cohesive work rate (CWR-area under the traction-separation curve) but different maximum tractions. The effect of the maximum traction on the predicted cohesive zone length and the remote applied load at fracture is presented. Similar to the small scale yielding condition for an LEFM analysis to be valid. the cohesive zone length also needs to be much smaller than the crack length. This is a necessary condition for a CZM to obtain a fracture prediction equivalent to an LEFM result.

Influence of the Amlia fracture zone on the evolution of the Aleutian Terrace forearc basin, central Aleutian subduction zone

USGS Publications Warehouse

Ryan, Holly F.; Draut, Amy E.; Keranen, Katie M.; Scholl, David W.

2012-01-01

During Pliocene to Quaternary time, the central Aleutian forearc basin evolved in response to a combination of tectonic and climatic factors. Initially, along-trench transport of sediment and accretion of a frontal prism created the accommodation space to allow forearc basin deposition. Transport of sufficient sediment to overtop the bathymetrically high Amlia fracture zone and reach the central Aleutian arc began with glaciation of continental Alaska in the Pliocene. As the obliquely subducting Amlia fracture zone swept along the central Aleutian arc, it further affected the structural evolution of the forearc basins. The subduction of the Amlia fracture zone resulted in basin inversion and loss of accommodation space east of the migrating fracture zone. Conversely, west of Amlia fracture zone, accommodation space increased arcward of a large outer-arc high that formed, in part, by a thickening of arc basement. This difference in deformation is interpreted to be the result of a variation in interplate coupling across the Amlia fracture zone that was facilitated by increasing subduction obliquity, a change in orientation of the subducting Amlia fracture zone, and late Quaternary intensification of glaciation. The change in coupling is manifested by a possible tear in the subducting slab along the Amlia fracture zone. Differences in coupling across the Amlia fracture zone have important implications for the location of maximum slip during future great earthquakes. In addition, shaking during a great earthquake could trigger large mass failures of the summit platform, as evidenced by the presence of thick mass transport deposits of primarily Quaternary age that are found in the forearc basin west of the Amlia fracture zone.

Fracture zones constrained by neutral surfaces in a fault-related fold: Insights from the Kelasu tectonic zone, Kuqa Depression

NASA Astrophysics Data System (ADS)

Sun, Shuai; Hou, Guiting; Zheng, Chunfang

2017-11-01

Stress variation associated with folding is one of the controlling factors in the development of tectonic fractures, however, little attention has been paid to the influence of neutral surfaces during folding on fracture distribution in a fault-related fold. In this study, we take the Cretaceous Bashijiqike Formation in the Kuqa Depression as an example and analyze the distribution of tectonic fractures in fault-related folds by core observation and logging data analysis. Three fracture zones are identified in a fault-related fold: a tensile zone, a transition zone and a compressive zone, which may be constrained by two neutral surfaces of fold. Well correlation reveals that the tensile zone and the transition zone reach the maximum thickness at the fold hinge and get thinner in the fold limbs. A 2D viscoelastic stress field model of a fault-related fold was constructed to further investigate the mechanism of fracturing. Statistical and numerical analysis reveal that the tensile zone and the transition zone become thicker with decreasing interlimb angle. Stress variation associated with folding is the first level of control over the general pattern of fracture distribution while faulting is a secondary control over the development of local fractures in a fault-related fold.

Time dependent fracture and cohesive zones

NASA Technical Reports Server (NTRS)

Knauss, W. G.

1993-01-01

This presentation is concerned with the fracture response of materials which develop cohesive or bridging zones at crack tips. Of special interest are concerns regarding crack stability as a function of the law which governs the interrelation between the displacement(s) or strain across these zones and the corresponding holding tractions. It is found that for some materials unstable crack growth can occur, even before the crack tip has experienced a critical COD or strain across the crack, while for others a critical COD will guarantee the onset of fracture. Also shown are results for a rate dependent nonlinear material model for the region inside of a craze for exploring time dependent crack propagation of rate sensitive materials.

Ultrasonic probing of the fracture process zone in rock using surface waves

NASA Technical Reports Server (NTRS)

Swanson, P. L.; Spetzler, H.

1984-01-01

A microcrack process zone is frequently suggested to accompany macrofractures in rock and play an important role in the resistance to fracture propagation. Attenuation of surface waves propagating through mode I fractures in wedge-loaded double-cantilever beam specimens of Westerly granite has been recorded in an attempt to characterize the structure of the fracture process zone. The ultrasonic measurements do not support the generally accepted model of a macroscopic fracture that incrementally propagates with the accompaniment of a cloud of microcracks. Instead, fractures in Westerly granite appear to form as gradually separating surfaces within a zone having a width of a few millimeters and a length of several tens of millimeters. A fracture process zone of this size would necessitate the use of meter-sized specimens in order for linear elastic fracture mechanics to be applicable.

Thermal stresses, differential subsidence, and flexure at oceanic fracture zones

NASA Technical Reports Server (NTRS)

Wessel, Pal; Haxby, William F.

1990-01-01

Geosat geoid undulations over four Pacific fracture zones have been analyzed. After correcting for the isostatic thermal edge effect, the amplitudes of the residuals are shown to be proportional to the age offset. The shape of the residuals seems to broaden with increasing age. Both geoid anomalies and available ship bathymetry data suggest that slip must sometimes occur on the main fracture zone or secondary faults. Existing models for flexure at fracture zones cannot explain the observed anomalies. A combination model accounting for slip and including flexure from thermal stresses and differential subsidence is presented. This model accounts for lateral variations in flexural rigidity from brittle and ductile yielding due to both thermal and flexural stresses and explains both the amplitudes and the shape of the anomalies along each fracture zone. The best fitting models have mechanical plate thicknesses that are described by the depth to the 600-700 C isotherms.

Discolored Fracture Zones in Martian Sandstone

NASA Image and Video Library

2015-12-17

This view from NASA's Curiosity Mars rover shows an example of discoloration closely linked to fractures in the Stimson formation sandstone on lower Mount Sharp. The pattern is evident along two perpendicular fractures. Curiosity's Navigation Camera (Navcam) acquired the component images of this mosaic on Aug. 23, 2015, during the 1.083rd Martian day, or sol, of the mission. The location is along the rover's path between "Marias Pass" and "Bridger Basin." In this region, the rover has found fracture zones to be associated with rock compositions enriched in silica, relative to surrounding bedrock. http://photojournal.jpl.nasa.gov/catalog/PIA20268

Consequences of the Thermal Transient on the Evolution of the Damaged Zone Around a Repository for Heat-Emitting High-Level Radioactive Waste in a Clay Formation: a Performance Assessment Perspective

NASA Astrophysics Data System (ADS)

Yu, Li; Weetjens, Eef; Sillen, Xavier; Vietor, Tim; Li, Xiangling; Delage, Pierre; Labiouse, Vincent; Charlier, Robert

2014-01-01

A proper evaluation of the perturbations of the host rock induced by the excavation and the emplacement of exothermic wastes is essential for the assessment of the long-term safety of high-level radioactive waste disposals in clay formations. The impact of the thermal transient on the evolution of the damaged zone (DZ) has been explored in the European Commission project TIMODAZ (thermal impact on the damaged zone around a radioactive waste disposal in clay host rocks, 2006-2010). This paper integrates the scientific results of the TIMODAZ project from a performance assessment (PA) point of view, showing how these results support and justify key PA assumptions and the values of PA model parameters. This paper also contextualises the significance of the thermal impact on the DZ from a safety case perspective, highlighting how the project outcomes result into an improved understanding of the thermo-hydro-mechanical behaviour of the clay host rocks. The results obtained in the TIMODAZ project strengthen the assessment basis of the safety evaluation of the current repository designs. There was no evidence throughout the TIMODAZ experimental observations of a temperature-induced additional opening of fractures nor of a significant permeability increase of the DZ. Instead, thermally induced plasticity, swelling and creep seem to be beneficial to the sealing of fractures and to the recovery of a very low permeability in the DZ, close to that of an undisturbed clay host rock. Results from the TIMODAZ project indicate that the favourable properties of the clay host rock, which guarantee the effectiveness of the safety functions of the repository system, are expected to be maintained after the heating-cooling cycle. Hence, the basic assumptions usually made in PA calculations so far are expected to remain valid, and the performance of the system should not be affected in a negative way by the thermal evolution of the DZ around a radioactive waste repository in clay host rock.

Delineation of a quick clay zone at Smørgrav, Norway, with electromagnetic methods under geotechnical constraints

NASA Astrophysics Data System (ADS)

Kalscheuer, Thomas; Bastani, Mehrdad; Donohue, Shane; Persson, Lena; Aspmo Pfaffhuber, Andreas; Reiser, Fabienne; Ren, Zhengyong

2013-05-01

In many coastal areas of North America and Scandinavia, post-glacial clay sediments have emerged above sea level due to iso-static uplift. These clays are often destabilised by fresh water leaching and transformed to so-called quick clays as at the investigated area at Smørgrav, Norway. Slight mechanical disturbances of these materials may trigger landslides. Since the leaching increases the electrical resistivity of quick clay as compared to normal marine clay, the application of electromagnetic (EM) methods is of particular interest in the study of quick clay structures. For the first time, single and joint inversions of direct-current resistivity (DCR), radiomagnetotelluric (RMT) and controlled-source audiomagnetotelluric (CSAMT) data were applied to delineate a zone of quick clay. The resulting 2-D models of electrical resistivity correlate excellently with previously published data from a ground conductivity metre and resistivity logs from two resistivity cone penetration tests (RCPT) into marine clay and quick clay. The RCPT log into the central part of the quick clay identifies the electrical resistivity of the quick clay structure to lie between 10 and 80 Ω m. In combination with the 2-D inversion models, it becomes possible to delineate the vertical and horizontal extent of the quick clay zone. As compared to the inversions of single data sets, the joint inversion model exhibits sharper resistivity contrasts and its resistivity values are more characteristic of the expected geology. In our preferred joint inversion model, there is a clear demarcation between dry soil, marine clay, quick clay and bedrock, which consists of alum shale and limestone.

Investigating Some Technical Issues on Cohesive Zone Modeling of Fracture

NASA Technical Reports Server (NTRS)

Wang, John T.

2011-01-01

This study investigates some technical issues related to the use of cohesive zone models (CZMs) in modeling fracture processes. These issues include: why cohesive laws of different shapes can produce similar fracture predictions; under what conditions CZM predictions have a high degree of agreement with linear elastic fracture mechanics (LEFM) analysis results; when the shape of cohesive laws becomes important in the fracture predictions; and why the opening profile along the cohesive zone length needs to be accurately predicted. Two cohesive models were used in this study to address these technical issues. They are the linear softening cohesive model and the Dugdale perfectly plastic cohesive model. Each cohesive model constitutes five cohesive laws of different maximum tractions. All cohesive laws have the same cohesive work rate (CWR) which is defined by the area under the traction-separation curve. The effects of the maximum traction on the cohesive zone length and the critical remote applied stress are investigated for both models. For a CZM to predict a fracture load similar to that obtained by an LEFM analysis, the cohesive zone length needs to be much smaller than the crack length, which reflects the small scale yielding condition requirement for LEFM analysis to be valid. For large-scale cohesive zone cases, the predicted critical remote applied stresses depend on the shape of cohesive models used and can significantly deviate from LEFM results. Furthermore, this study also reveals the importance of accurately predicting the cohesive zone profile in determining the critical remote applied load.

Hollow Cylinder Tests on Boom Clay: Modelling of Strain Localization in the Anisotropic Excavation Damaged Zone

NASA Astrophysics Data System (ADS)

François, Bertrand; Labiouse, Vincent; Dizier, Arnaud; Marinelli, Ferdinando; Charlier, Robert; Collin, Frédéric

2014-01-01

Boom Clay is extensively studied as a potential candidate to host underground nuclear waste disposal in Belgium. To guarantee the safety of such a disposal, the mechanical behaviour of the clay during gallery excavation must be properly predicted. In that purpose, a hollow cylinder experiment on Boom Clay has been designed to reproduce, in a small-scale test, the Excavation Damaged Zone (EDZ) as experienced during the excavation of a disposal gallery in the underground. In this article, the focus is made on the hydro-mechanical constitutive interpretation of the displacement (experimentally obtained by medium resolution X-ray tomography scanning). The coupled hydro-mechanical response of Boom Clay in this experiment is addressed through finite element computations with a constitutive model including strain hardening/softening, elastic and plastic cross-anisotropy and a regularization method for the modelling of strain localization processes. The obtained results evidence the directional dependency of the mechanical response of the clay. The softening behaviour induces transient strain localization processes, addressed through a hydro-mechanical second grade model. The shape of the obtained damaged zone is clearly affected by the anisotropy of the materials, evidencing an eye-shaped EDZ. The modelling results agree with experiments not only qualitatively (in terms of the shape of the induced damaged zone), but also quantitatively (for the obtained displacement in three particular radial directions).

Permeability of Granite Including Macro-Fracture Naturally Filled with Fine-Grained Minerals

NASA Astrophysics Data System (ADS)

Nara, Yoshitaka; Kato, Masaji; Niri, Ryuhei; Kohno, Masanori; Sato, Toshinori; Fukuda, Daisuke; Sato, Tsutomu; Takahashi, Manabu

2018-03-01

Information on the permeability of rock is essential for various geoengineering projects, such as geological disposal of radioactive wastes, hydrocarbon extraction, and natural hazard risk mitigation. It is especially important to investigate how fractures and pores influence the physical and transport properties of rock. Infiltration of groundwater through the damage zone fills fractures in granite with fine-grained minerals. However, the permeability of rock possessing a fracture naturally filled with fine-grained mineral grains has yet to be investigated. In this study, the permeabilities of granite samples, including a macro-fracture filled with clay and a mineral vein, are investigated. The permeability of granite with a fine-grained mineral vein agrees well with that of the intact sample, whereas the permeability of granite possessing a macro-fracture filled with clay is lower than that of the macro-fractured sample. The decrease in the permeability is due to the filling of fine-grained minerals and clay in the macro-fracture. It is concluded that the permeability of granite increases due to the existence of the fractures, but decreases upon filling them with fine-grained minerals.

The effect of early operative stabilization on late displacement of zone I and II sacral fractures.

PubMed

Emohare, Osa; Slinkard, Nathaniel; Lafferty, Paul; Vang, Sandy; Morgan, Robert

2013-02-01

This study was designed to evaluate the effect on displacement of early operative stabilization on unstable fractures when compared to stable fractures of the sacrum. Patient consisted of those sustaining traumatic pelvic fractures that also included sacral fractures of Denis type I and type II classification, who were over 18 at the time of the study. Patients were managed emergently, as judged appropriate at the time and then subsequently divided into two cohorts, comprising those who were either treated operatively or non-operatively. The operative group comprised those treated with either internal fixation or external fixation. Twenty-eight patients had zone II fractures, and 20 had zone I fractures. Zone II fractures showed average displacements of 6.5mm and 6.9mm in the rostral-caudal and anteroposterior directions, respectively, at final follow up. Zone I fractures had average displacements of 6.6mm and 6.1mm in both directions. There were no significant differences between zone I and II sacral fractures (rostral-caudal P=0.74, anteroposterior P=0.24). Average changes in fracture displacement in patients with zone I fractures were 0.6-1.0mm in both directions. Average changes in zone II fractures were 1.8-1.5mm in both directions. There were no significant differences between the average changes in zone I and II fractures in any direction (rostral-caudal P=0.64, anteroposterior P=0.68) or in average displacements at final follow up in any of zone or the entire cohort. Statistically significant differences were noted in average changes in displacement in zone II fractures in the anteroposterior plane (P=0.03) and the overall cohort in the anteroposterior plane (P=0.02). Operative fixation for unstable sacral fractures ensures displacement at follow up is comparable with stable fractures treated non operatively. Copyright © 2012 Elsevier Ltd. All rights reserved.

Teeth in the Line of Fracture: To Retain or Remove?

PubMed Central

Samson, Jimson; John, Reena; Jayakumar, Shalini

2010-01-01

The purpose of this study was to analyze mandibular fracture site, relationship of the fracture line to the periodontium, vitality of teeth, displacement of the fracture segments and their implications, and determine whether to retain or remove the teeth in the fracture line. Fifty patients with 62 fractures were involved in this study. An electric pulp tester was used to measure the pulpal response. The degree of fracture displacement and the relationship of the fracture line to the periodontium were evaluated using panoramic radiographs. Fractures of the parasymphysis region constituted a majority of 60.87% in the gross displacement category. Four of 50 patients showed no response presurgically and minimal response postoperatively on pulp vitality testing. Patients with teeth in the fracture line showing no response on pulp vitality testing should be advised extraction to avoid further complications. PMID:22132255

Triple Junction Reorganizations: A Mechanism for the Initiation of the Great Pacific Fractures Zones

NASA Astrophysics Data System (ADS)

Pockalny, R. A.; Larson, R. L.; Grindlay, N. R.

2001-12-01

There are two general explanations for the initiation of oceanic transform faults that eventually evolve into fracture zones: transforms inherited from continental break-up and transforms acquired in response to a change in plate motions. These models are sufficient to explain the fracture zones in oceans formed by continental break-up. However, neither model accounts for the initiation of the large-offset, great Pacific fracture zones that characterized the Pacific-Farallon plate boundary prior to 25 Ma. Primarily, these models are unable to explain why the initial age of these fracture zones becomes progressively younger from the Mendocino fracture zone (\\~{ } 160 Ma) southward down to the Resolution FZ (\\~{ }84 Ma). We propose a new transform initiation mechanism for the great Pacific fracture zones, which is intimately tied to tectonic processes at triple junctions and directly related to the growth of the Pacific Plate. Recently acquired multibeam bathymetry and marine geophysics data collected along Pandora's Escarpment in the southwestern Pacific have identified the escarpment as the trace of the Pacific-Farallon-Phoenix triple junction on the Pacific Plate. Regional changes in the trend of the triple junction trace between 84-121 Ma roughly coincide with the initiation of the Marquesas, Austral and Resolution fracture zones. Bathymetry and backscatter data from the projected intersections of these fracture zones with the triple junction trace identify several anomalous structures that suggest tectonic reorganizations of the triple junction. We believe this reorganization created the initial transform fault(s) that ultimately became the large-offset, great Pacific fracture zones. Several possible mechanisms for initiating the transform faults are explored including microplate formation, ridge-tip propagation, and spontaneous transform fault formation.

Radionuclide Transport in Fracture-Granite Interface Zones

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hu, Q; Mori, A

In situ radionuclide migration experiments, followed by excavation and sample characterization, were conducted in a water-conducting shear zone at the Grimsel Test Site (GTS) in Switzerland to study diffusion paths of radionuclides in fractured granite. In this work, we employed a micro-scale mapping technique that interfaces laser ablation sampling with inductively coupled plasma-mass spectrometry (LA/ICP-MS) to measure the fine-scale (micron-range) distribution of actinides ({sup 234}U, {sup 235}U, and {sup 237}Np) in the fracture-granite interface zones. Long-lived {sup 234}U, {sup 235}U, and {sup 237}Np were detected in flow channels, as well as in the adjacent rock matrix, using the sensitive, feature-basedmore » mapping of the LA/ICP-MS technique. The injected sorbing actinides are mainly located within the advective flowing fractures and the immediately adjacent regions. The water-conducting fracture studied in this work is bounded on one side by mylonite and the other by granitic matrix regions. These actinides did not penetrate into the mylonite side as much as the relatively higher-porosity granite matrix, most likely due to the low porosity, hydraulic conductivity, and diffusivity of the fracture wall (a thickness of about 0.4 mm separates the mylonite region from the fracture) and the mylonite region itself. Overall, the maximum penetration depth detected with this technique for the more diffusive {sup 237}Np over the field experimental time scale of about 60 days was about 10 mm in the granitic matrix, illustrating the importance of matrix diffusion in retarding radionuclide transport from the advective fractures. Laboratory tests and numerical modeling of radionuclide diffusion into granitic matrix was conducted to complement and help interpret the field results. Measured apparent diffusivity of multiple tracers in granite provided consistent predictions for radionuclide transport in the fractured granitic rock.« less

Fault imprint in clay units: magnetic fabric, structural and mineralogical signature

NASA Astrophysics Data System (ADS)

Moreno, Eva; Homberg, Catherine; Schnyder, Johann; Person, Alain; du Peloux1, Arthur; Dick, Pierre

2014-05-01

Fault-induced deformations in clay units can be difficult to decipher because strain markers are not always visible at outcrop scale or using geophysical methods. Previous studies have indicated that the anisotropy of magnetic susceptibility (ASM) provides a powerful and rapid technique to investigate tectonic deformation in clay units even when they appear quite homogenous and undeformed at the outcrop scale (Lee et al. 1990, Mattei et al. 1997). We report here a study based on ASM, structural analysis and magnetic and clay mineralogy from two boreholes (TF1 and ASM1)drilled horizontally in the Experimental Station of Tournemire of the Institute for Radiological Protection and Nuclear Safety (IRSN) in Aveyron (France). The boreholes intersect a N-S trending strike-slip fault from west to east. The ASM study indicates the evolution of the magnetic fabric from the undeformed host rock to the fault core. Also, all the fractures cutting the studied interval of the core have been measured as well as the slip vectors which are generally well preserved. In the two boreholes, the undeformed sediments outside the fault zone are characterized by an oblate fabric, a sub-vertical minimum susceptibility axis (k3) perpendicular to the bedding plane and without magnetic lineation. Within the fault zone, a tilt in the bedding plane has been observed in two boreholes TF1 and ASM1. In addition, in the TF1 core, the fault area presents a tectonic fabric characterized by a triaxial AMS ellipsoid. Moreover, the magnetic lineation increases and k3 switches from a vertical to a sub-horizontal plane. This kind of fabric has not been observed in borehole ASM1. The structural analysis of the individual fractures making the fault zone indicates a complex tectonic history with different imprint in the two fault segments cut by the two boreholes. The large majority of fractures correspond to dextral strike-slip faults but normal and reverse movements were observed and are more or less

Characterization of structures of the Nankai Trough accretionary prism from integrated analyses of LWD log response, resistivity images and clay mineralogy of cuttings: Expedition 338 Site C0002

NASA Astrophysics Data System (ADS)

Jurado, Maria Jose; Schleicher, Anja

2014-05-01

The objective of our research is a detailed characterization of structures on the basis of LWD oriented images and logs,and clay mineralogy of cuttings from Hole C0002F of the Nankai Trough accretionary prism. Our results show an integrated interpretation of structures derived from borehole images, petrophysical characterization on LWD logs and cuttings mineralogy. The geometry of the structure intersected at Hole C0002F has been characterized by the interpretation of oriented borehole resistivity images acquired during IODP Expedition 338. The characterization of structural features, faults and fracture zones is based on a detailed post-cruise interpretation of bedding and fractures on borehole images and also on the analysis of Logging While Drilling (LWD) log response (gamma radioactivity, resistivity and sonic logs). The interpretation and complete characterization of structures (fractures, fracture zones, fault zones, folds) was achieved after detailed shorebased reprocessing of resistivity images, which allowed to enhance bedding and fracture's imaging for geometry and orientation interpretation. In order to characterize distinctive petrophysical properties based on LWD log response, it could be compared with compositional changes derived from cuttings analyses. Cuttings analyses were used to calibrate and to characterize log response and to verify interpretations in terms of changes in composition and texture at fractures and fault zones defined on borehole images. Cuttings were taken routinely every 5 m during Expedition 338, indicating a clay-dominated lithology of silty claystone with interbeds of weakly consolidated, fine sandstones. The main mineralogical components are clay minerals, quartz, feldspar and calcite. Selected cuttings were taken from areas of interest as defined on LWD logs and images. The clay mineralogy was investigated on the <2 micron clay-size fraction, with special focus on smectite and illite minerals. Based on X-ray diffraction

Modeling biogechemical reactive transport in a fracture zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Molinero, Jorge; Samper, Javier; Yang, Chan Bing, and Zhang, Guoxiang

2005-01-14

A coupled model of groundwater flow, reactive solute transport and microbial processes for a fracture zone of the Aspo site at Sweden is presented. This is the model of the so-called Redox Zone Experiment aimed at evaluating the effects of tunnel construction on the geochemical conditions prevailing in a fracture granite. It is found that a model accounting for microbially-mediated geochemical processes is able to reproduce the unexpected measured increasing trends of dissolved sulfate and bicarbonate. The model is also useful for testing hypotheses regarding the role of microbial processes and evaluating the sensitivity of model results to changes inmore » biochemical parameters.« less

Characterisation of Fractures and Fracture Zones in a Carbonate Aquifer Using Electrical Resistivity Tomography and Pricking Probe Methodes

NASA Astrophysics Data System (ADS)

Szalai, Sandor; Kovacs, Attila; Kuslits, Lukács; Facsko, Gabor; Gribovszki, Katalin; Kalmar, Janos; Szarka, Laszlo

2018-04-01

Position, width and fragmentation level of fracture zones and position, significance and characteristic distance of fractures were aimed to determine in a carbonate aquifer. These are fundamental parameters, e.g. in hydrogeological modelling of aquifers, due to their role in subsurface water movements. The description of small scale fracture systems is however a challenging task. In the test area (Kádárta, Bakony Mts, Hungary), two methods proved to be applicable to get reasonable information about the fractures: Electrical Resistivity Tomography (ERT) and Pricking-Probe (PriP). PriP is a simple mechanical tool which has been successfully applied in archaeological investigations. ERT results demonstrated its applicability in this small scale fracture study. PriP proved to be a good verification tool both for fracture zone mapping and detecting fractures, but in certain areas, it produced different results than the ERT. The applicability of this method has therefore to be tested yet, although its problems most probably origin from human activity which reorganises the near-surface debris distribution. In the test site, both methods displayed fracture zones including a very characteristic one and a number of individual fractures and determined their characteristic distance and significance. Both methods prove to be able to produce hydrogeologically important parameters even individually, but their simultaneous application is recommended to decrease the possible discrepancies.

Tectonics of ridge-transform intersections at the Kane fracture zone

NASA Astrophysics Data System (ADS)

Karson, J. A.; Dick, H. J. B.

1983-03-01

The Kane Transform offsets spreading-center segments of the Mid-Atlantic Ridge by about 150 km at 24° N latitude. In terms of its first-order morphological, geological, and geophysical characteristics it appears to be typical of long-offset (>100 km), slow-slipping (2 cm yr-1) ridge-ridge transform faults. High-resolution geological observations were made from deep-towed ANGUS photographs and the manned submersible ALVIN at the ridge-transform intersections and indicate similar relationships in these two regions. These data indicate that over a distance of about 20 km as the spreading axes approach the fracture zone, the two flanks of each ridge axis behave in very different ways. Along the flanks that intersect the active transform zone the rift valley floor deepens and the surface expression of volcanism becomes increasingly narrow and eventually absent at the intersection where only a sediment-covered ‘nodal basin’ exists. The adjacent median valley walls have structural trends that are oblique to both the ridge and the transform and have as much as 4 km of relief. These are tectonically active regions that have only a thin (<200 m), highly fractured, and discontinuous carapace of volcanic rocks overlying a variably deformed and metamorphosed assemblage of gabbroic rocks. Overprinting relationships reveal a complex history of crustal extension and rapid vertical uplift. In contrast, the opposing flanks of the ridge axes, that intersect the non-transform zones appear to be similar in many respects to those examined elsewhere along slow-spreading ridges. In general, a near-axial horst and graben terrain floored by relatively young volcanics passes laterally into median valley walls with a simple block-faulted character where only volcanic rocks have been found. Along strike toward the fracture zone, the youngest volcanics form linear constructional volcanic ridges that transect the entire width of the fracture zone valley. These volcanics are continuous with

Deformation mechanisms and resealing of damage zones in experimentally deformed cemented and un-cemented clay-rich geomaterials, at low bulk strain

NASA Astrophysics Data System (ADS)

Desbois, Guillaume; Urai, Janos L.; Schuck, Bernhardt; Hoehne, Nadine; Oelker, Anne; Bésuelle, Pierre; Viggiani, Gioacchino; Schmatz, Joyce; Klaver, Jop

2017-04-01

for the development of the shear band. At the same time, evidence for dilatancy at low confining pressure indicates that deformation involves also brittle deformation. Our observations strongly suggest that the deformation mostly localizes in those regions of the specimen, where the original grain sizes are smaller. In COx, microstructures show evidence for dominantly cataclastic deformation involving intergranular - transgranular - and - intragranular micro fracturing, grain rotation and clay particle bending mechanisms, down to nm- scale. Micro fracturing of the original fabric results in fragments at a range of scales, which are reworked into a clay-rich cataclastic gouge during frictional flow. Intergranular and minor intragranular micro fracturing occur in regions of non localized deformation, whereas transgranular micro fracturing occurs at regions of localized deformation. These processes are accompanied by dilatancy, but also by progressive decrease of porosity and pore size in the gouge with the non-clay particles embedded in reworked clay. The mechanism of this compaction during shearing is interpreted to be a combination of cataclasis of the cemented clay matrix, and shear-induced rearrangement of clay particles around the fragments of non-clay particles.

Fracture Patterns within the Shale Hills Critical Zone Observatory

NASA Astrophysics Data System (ADS)

Singha, K.; White, T.; Perron, J.; Chattopadhyay, P. B.; Duffy, C.

2012-12-01

Rock fractures are known to exist within the deep Critical Zone and are expected to influence groundwater flow, but there are limited data on their orientation and spatial arrangement and no general framework for systematically predicting their effects. Here, we explore fracture patterns within the Susquehanna-Shale Hills Critical Zone Observatory, and consider how they may be influenced by weathering, rock structure, and stress via field observations of variable fracture orientation within the site, with implications for the spatial variability of structural control on hydrologic processes. Based on field observations from 16-m deep boreholes and surface outcrop, we suggest that the appropriate structural model for the watershed is steeply dipping strata with meter- to decimeter-scale folds superimposed, including a superimposed fold at the mouth of the watershed that creates a short fold limb with gently dipping strata. These settings would produce an anisotropy in the hydraulic conductivity and perhaps also flow, especially within the context of the imposed stress field. Recently conducted 2-D numerical stress modeling indicates that the proxy for shear fracture declines more rapidly with depth beneath valleys than beneath ridgelines, which may produce or enhance the spatial variability in permeability. Even if topographic stresses do not cause new fractures, they could activate and cause displacement on old fractures, making the rocks easier to erode and increasing the permeability, and potentially driving a positive feedback that enhances the growth of valley relief. Calculated stress fields are consistent with field observations, which show a rapid decline in fracture abundance with increasing depth below the valley floor, and predict a more gradual trend beneath ridgetops, leading to a more consistent (and lower) hydraulic conductivity with depth on the ridgetops when compared to the valley, where values are higher but more variable with depth. Hydraulic

Fracture Modes and Identification of Fault Zones in Wenchuan Earthquake Fault Scientific Drilling Boreholes

NASA Astrophysics Data System (ADS)

Deng, C.; Pan, H.; Zhao, P.; Qin, R.; Peng, L.

2017-12-01

After suffering from the disaster of Wenchuan earthquake on May 12th, 2008, scientists are eager to figure out the structure of formation, the geodynamic processes of faults and the mechanism of earthquake in Wenchuan by drilling five holes into the Yingxiu-Beichuan fault zone and Anxian-Guanxian fault zone. Fractures identification and in-situ stress determination can provide abundant information for formation evaluation and earthquake study. This study describe all the fracture modes in the five boreholes on the basis of cores and image logs, and summarize the response characteristics of fractures in conventional logs. The results indicate that the WFSD boreholes encounter enormous fractures, including natural fractures and induced fractures, and high dip-angle conductive fractures are the most common fractures. The maximum horizontal stress trends along the borehole are deduced as NWW-SEE according to orientations of borehole breakouts and drilling-induced fractures, which is nearly parallel to the strikes of the younger natural fracture sets. Minor positive deviations of AC (acoustic log) and negative deviation of DEN (density log) demonstrate their responses to fracture, followed by CNL (neutron log), resistivity logs and GR (gamma ray log) at different extent of intensity. Besides, considering the fact that the reliable methods for identifying fracture zone, like seismic, core recovery and image logs, can often be hampered by their high cost and limited application, this study propose a method by using conventional logs, which are low-cost and available in even old wells. We employ wavelet decomposition to extract the high frequency information of conventional logs and reconstruction a new log in special format of enhance fracture responses and eliminate nonfracture influence. Results reveal that the new log shows obvious deviations in fault zones, which confirm the potential of conventional logs in fracture zone identification.

Internal architecture, permeability structure, and hydrologic significance of contrasting fault-zone types

NASA Astrophysics Data System (ADS)

Rawling, Geoffrey C.; Goodwin, Laurel B.; Wilson, John L.

2001-01-01

The Sand Hill fault is a steeply dipping, large-displacement normal fault that cuts poorly lithified Tertiary sediments of the Albuquerque basin, New Mexico, United States. The fault zone does not contain macroscopic fractures; the basic structural element is the deformation band. The fault core is composed of foliated clay flanked by structurally and lithologically heterogeneous mixed zones, in turn flanked by damage zones. Structures present within these fault-zone architectural elements are different from those in brittle faults formed in lithified sedimentary and crystalline rocks that do contain fractures. These differences are reflected in the permeability structure of the Sand Hill fault. Equivalent permeability calculations indicate that large-displacement faults in poorly lithified sediments have little potential to act as vertical-flow conduits and have a much greater effect on horizontal flow than faults with fractures.

Woody plant roots fail to penetrate a clay-lined landfill: Managment implications

NASA Astrophysics Data System (ADS)

Robinson, George R.; Handel, Steven N.

1995-01-01

In many locations, regulatory agencies do not permit tree planting above landfills that are sealed with a capping clay, because roots might penetrate the clay barrier and expose landfill contents to leaching. We find, however, no empirical or theoretical basis for this restriction, and instead hypothesize that plant roots of any kind are incapable of penetrating the dense clays used to seal landfills. As a test, we excavated 30 trees and shrubs, of 12 species, growing over a clay-lined municipal sanitary landfill on Staten Island, New York. The landfill had been closed for seven years, and featured a very shallow (10 to 30-cm) soil layer over a 45-cm layer of compacted grey marl (Woodbury series) clay. The test plants had invaded naturally from nearby forests. All plants examined—including trees as tall as 6 m—had extremely shallow root plates, with deformed tap roots that grew entirely above and parallel to the clay layer. Only occasional stubby feeder roots were found in the top 1 cm of clay, and in clay cracks at depths to 6 cm, indicating that the primary impediment to root growth was physical, although both clay and the overlying soil were highly acidic. These results, if confirmed by experimental research should lead to increased options for the end use of many closed sanitary landfills.

Percolation and permeability of fracture networks in Excavated Damaged Zones

NASA Astrophysics Data System (ADS)

Mourzenko, V.; Thovert, J.; Adler, P. M.

2012-12-01

Generally, the excavation process of a gallery generates fractures in its immediate vicinity. The corresponding zone which is called the Excavated Damaged Zone (EDZ), has a larger permeability than the intact surrounding medium. The properties of the EDZ are attracting more and more attention because of their potential importance in repositories of nuclear wastes. The EDZ which is induced by the excavation process may create along the galleries of the repositories a high permeability zone which could directly connect the storage area with the ground surface. Therefore, the studies of its properties are of crucial importance for applications such as the storage of nuclear wastes. Field observations (such as the ones which have been systematically performed at Mont Terri by [1, 2]) suggest that the fracture density is an exponentially decreasing function of the distance to the wall with a characteristic length of about 0.5 m and that the fracture orientation is anisotropic (most fractures are subparallel to the tunnel walls) and well approximated by a Fisher law whose pole is orthogonal to the wall. Numerical samples are generated according to these prescriptions. Their percolation status and hydraulic transmissivity can be calculated by the numerical codes which are detailed in [3]. Percolation is determined by a pseudo diffusion algorithm. Flow determination necessitates the meshing of the fracture networks and the discretisation of the Darcy equation by a finite volume technique; the resulting linear system is solved by a conjugate gradient algorithm. Only the flow properties of the EDZ along the directions which are parallel to the wall are of interest when a pressure gradient parallel to the wall is applied. The transmissivity T which relates the total flow rate per unit width Q along the wall through the whole EDZ to the pressure gradient grad p, is defined by Q = - T grad p/mu where mu is the fluid viscosity. The percolation status and hydraulic transmissivity

The location and extent of exfoliation of clay on the fracture mechanisms in nylon 66-based ternary nanocomposites.

PubMed

Dasari, Aravind; Yu, Zhong-Zhen; Mai, Yiu-Wing; Yang, Mingshu

2008-04-01

The primary focus of this work is to elucidate the location and extent of exfoliation of clay on fracture (under both static and dynamic loading conditions) of melt-compounded nylon 66/clay/SEBS-g-MA ternary nanocomposites fabricated by different blending sequences. Distinct microstructures are obtained depending on the blending protocol employed. The state of exfoliation and dispersion of clay in nylon 66 matrix and SEBS-g-MA phase are quantified and the presence of clay in rubber is shown to have a negative effect on the toughness of the nanocomposites. The level of toughness enhancement of ternary nanocomposites depends on the blending protocol and the capability of different fillers to activate the plastic deformation mechanisms in the matrix. These mechanisms include: cavitation of SEBS-g-MA phase, stretching of voided matrix material, interfacial debonding of SEBS-g-MA particles, debonding of intercalated clay embedded inside the SEBS-g-MA phase, and delamination of intercalated clay platelets. Based on these results, new insights and approaches for the processing of better toughened polymer ternary nanocomposites are discussed.

Prediction of subsurface fracture in mining zone of Papua using passive seismic tomography based on Fresnel zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Setiadi, Herlan; Nurhandoko, Bagus Endar B.; Wely, Woen

Fracture prediction in a block cave of underground mine is very important to monitor the structure of the fracture that can be harmful to the mining activities. Many methods can be used to obtain such information, such as TDR (Time Domain Relectometry) and open hole. Both of them have limitations in range measurement. Passive seismic tomography is one of the subsurface imaging method. It has advantage in terms of measurements, cost, and rich of rock physical information. This passive seismic tomography studies using Fresnel zone to model the wavepath by using frequency parameter. Fresnel zone was developed by Nurhandoko inmore » 2000. The result of this study is tomography of P and S wave velocity which can predict position of fracture. The study also attempted to use sum of the wavefronts to obtain position and time of seismic event occurence. Fresnel zone tomography and the summation wavefront can predict location of geological structure of mine area as well.« less

Fracture zone drilling through Atotsugawa fault in central Japan - geological and geophysical structure -

NASA Astrophysics Data System (ADS)

Omura, K.; Yamashita, F.; Yamada, R.; Matsuda, T.; Fukuyama, E.; Kubo, A.; Takai, K.; Ikeda, R.; Mizuochi, Y.

2004-12-01

Drilling is an effective method to investigate the structure and physical state in and around the active fault zone, such as, stress and strength distribution, geological structure and materials properties. In particular, the structure in the fault zone is important to understand where and how the stress accumulates during the earthquake cycle. In previous studies, we did integrate investigation on active faults in central Japan by drilling and geophysical prospecting. Those faults are estimated to be at different stage in the earthquake cycle, i.e., Nojima fault which appeared on the surface by the 1995 Great Kobe earthquake (M=7.2), the Neodani fault which appeared by the 1891 Nobi earth-quake (M=8.0), the Atera fault, of which some parts have seemed to be dislocated by the 1586 Tensyo earthquake (M=7.9), and Gofukuji Fault that is considered to have activated about 1200 years ago. Each faults showed characteristic features of fracture zone structure according to their geological and geophysical situations. In a present study, we did core recovery and down hole measurements at the Atotsugawa fault, central Japan, that is considered to have activated at 1858 Hida earthquake (M=7.0). The Atotsugawa fault is characterized by active seismicity along the fault. But, at the same time, the shallow region in the central segment of the fault seems to have low seismicity. The high seismicity segment and low seismicity segments may have different mechanical, physical and material properties. A 350m depth borehole was drilled vertically beside the surface trace of the fault in the low seismicity segment. Recovered cores were overall heavily fractured and altered rocks. In the cores, we observed many shear planes holding fault gouge. Logging data showed that the apparent resistance was about 100 - 600 ohm-m, density was about 2.0 - 2.5g/cm3, P wave velocity was approximately 3.0 - 4.0 km/sec, neutron porosity was 20 - 40 %. Results of physical logging show features of fault

Investigation of translaminar fracture in fibrereinforced composite laminates---applicability of linear elastic fracture mechanics and cohesive-zone model

NASA Astrophysics Data System (ADS)

Hou, Fang

With the extensive application of fiber-reinforced composite laminates in industry, research on the fracture mechanisms of this type of materials have drawn more and more attentions. A variety of fracture theories and models have been developed. Among them, the linear elastic fracture mechanics (LEFM) and cohesive-zone model (CZM) are two widely-accepted fracture models, which have already shown applicability in the fracture analysis of fiber-reinforced composite laminates. However, there remain challenges which prevent further applications of the two fracture models, such as the experimental measurement of fracture resistance. This dissertation primarily focused on the study of the applicability of LEFM and CZM for the fracture analysis of translaminar fracture in fibre-reinforced composite laminates. The research for each fracture model consisted of two sections: the analytical characterization of crack-tip fields and the experimental measurement of fracture resistance parameters. In the study of LEFM, an experimental investigation based on full-field crack-tip displacement measurements was carried out as a way to characterize the subcritical and steady-state crack advances in translaminar fracture of fiber-reinforced composite laminates. Here, the fiber-reinforced composite laminates were approximated as anisotropic solids. The experimental investigation relied on the LEFM theory with a modification with respect to the material anisotropy. Firstly, the full-field crack-tip displacement fields were measured by Digital Image Correlation (DIC). Then two methods, separately based on the stress intensity approach and the energy approach, were developed to measure the crack-tip field parameters from crack-tip displacement fields. The studied crack-tip field parameters included the stress intensity factor, energy release rate and effective crack length. Moreover, the crack-growth resistance curves (R-curves) were constructed with the measured crack-tip field parameters

Mechanics of slip and fracture along small faults and simple strike-slip fault zones in granitic rock

NASA Astrophysics Data System (ADS)

Martel, Stephen J.; Pollard, David D.

1989-07-01

We exploit quasi-static fracture mechanics models for slip along pre-existing faults to account for the fracture structure observed along small exhumed faults and small segmented fault zones in the Mount Abbot quadrangle of California and to estimate stress drop and shear fracture energy from geological field measurements. Along small strike-slip faults, cracks that splay from the faults are common only near fault ends. In contrast, many cracks splay from the boundary faults at the edges of a simple fault zone. Except near segment ends, the cracks preferentially splay into a zone. We infer that shear displacement discontinuities (slip patches) along a small fault propagated to near the fault ends and caused fracturing there. Based on elastic stress analyses, we suggest that slip on one boundary fault triggered slip on the adjacent boundary fault, and that the subsequent interaction of the slip patches preferentially led to the generation of fractures that splayed into the zones away from segment ends and out of the zones near segment ends. We estimate the average stress drops for slip events along the fault zones as ˜1 MPa and the shear fracture energy release rate during slip as 5 × 102 - 2 × 104 J/m2. This estimate is similar to those obtained from shear fracture of laboratory samples, but orders of magnitude less than those for large fault zones. These results suggest that the shear fracture energy release rate increases as the structural complexity of fault zones increases.

Microseismic Velocity Imaging of the Fracturing Zone

NASA Astrophysics Data System (ADS)

Zhang, H.; Chen, Y.

2015-12-01

Hydraulic fracturing of low permeability reservoirs can induce microseismic events during fracture development. For this reason, microseismic monitoring using sensors on surface or in borehole have been widely used to delineate fracture spatial distribution and to understand fracturing mechanisms. It is often the case that the stimulated reservoir volume (SRV) is determined solely based on microseismic locations. However, it is known that for some fracture development stage, long period long duration events, instead of microseismic events may be associated. In addition, because microseismic events are essentially weak and there exist different sources of noise during monitoring, some microseismic events could not be detected and thus located. Therefore the estimation of the SRV is biased if it is solely determined by microseismic locations. With the existence of fluids and fractures, the seismic velocity of reservoir layers will be decreased. Based on this fact, we have developed a near real time seismic velocity tomography method to characterize velocity changes associated with fracturing process. The method is based on double-difference seismic tomography algorithm to image the fracturing zone where microseismic events occur by using differential arrival times from microseismic event pairs. To take into account varying data distribution for different fracking stages, the method solves the velocity model in the wavelet domain so that different scales of model features can be obtained according to different data distribution. We have applied this real time tomography method to both acoustic emission data from lab experiment and microseismic data from a downhole microseismic monitoring project for shale gas hydraulic fracturing treatment. The tomography results from lab data clearly show the velocity changes associated with different rock fracturing stages. For the field data application, it shows that microseismic events are located in low velocity anomalies. By

Hydrothermal alteration of deep fractured granite: Effects of dissolution and precipitation

NASA Astrophysics Data System (ADS)

Nishimoto, Shoji; Yoshida, Hidekazu

2010-03-01

This paper investigates the mineralogical effects of hydrothermal alteration at depth in fractures in granite. A fracture accompanied by an alteration halo and filled with clay was found at a depth of 200 m in a drill core through Toki granite, Gifu, central Japan. Microscopic observation, XRD, XRF, EPMA and SXAM investigations revealed that the microcrystalline clays consist of illite, quartz and pyrite and that the halo round the fracture can be subdivided into a phyllic zone adjacent to the fracture, surrounded by a propylitic zone in which Fe-phyllosilicates are present, and a distinctive outer alteration front characterized by plagioclase breakdown. The processes that result in these changes took place in three successive stages: 1) partial dissolution of plagioclase with partial chloritization of biotite; 2) biotite dissolution and precipitation of Fe-phyllosilicate in the dissolution pores; 3) dissolution of K-feldspar and Fe-phyllosilicate, and illite precipitation associated with development of microcracks. These hydrothermal alterations of the granite proceed mainly by a dissolution-precipitation process resulting from the infiltration of hydrothermal fluid along microcracks. Such infiltration causes locally high mobility of Al and increases the ratio of fluid to rock in the alteration halo. These results contribute to an understanding of how granitic rock becomes altered in orogenic fields such as the Japanese island arc.

Fracture zones in the equatorial Atlantic and the breakup of western Pangea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, E.J.W.

1987-06-01

The early breakup of western Pangea has been investigated by mapping the pattern of fracture zones and distribution of seismic reflectors within the sedimentary cover of the Atlantic between the Cape Verde Islands and the equator. Two distinct sets of transverse oceanic lineaments are present, separated by the Guinea Fracture Zone near lat 10/sup 0/N. Lineaments to the north are associated with the formation of the central Atlantic in the Late Jurassic and Early Cretaceous; those in the south relate to the Cretaceous opening of the South Atlantic. The Guinea Fracture Zone is thus the conjugate of the Jurassic transformmore » boundary under peninsular Florida, which linked the Atlantic with the Gulf of Mexico. The distribution of dated seismic reflectors suggests that deposition of deep-water sediments was confined to the region north of the Guinea transform until Aptian time, when the Sierra Leone Basin began to open. The latter started to widen at least 15 m.y. after the initiation of the Cape Basin off southwest Africa, an age difference that can be explained if a short-lived plate boundary developed in either Africa or South America during the Early Cretaceous. Neither the trends of the equatorial fracture zones nor the seismic stratigraphy supports the existence of a predrift gap between west Africa and Brazil.« less

Abyssal Upwelling in Mid-Ocean Ridge Fracture Zones

NASA Astrophysics Data System (ADS)

Clément, Louis; Thurnherr, Andreas M.

2018-03-01

Turbulence in the abyssal ocean plays a fundamental role in the climate system by sustaining the deepest branch of the overturning circulation. Over the western flank of the Mid-Atlantic Ridge in the South Atlantic, previously observed bottom-intensified and tidally modulated mixing of abyssal waters appears to imply a counterintuitive densification of deep and bottom waters. Here we show that inside fracture zones, however, turbulence is elevated away from the seafloor because of intensified downward propagating near-inertial wave energy, which decays below a subinertial shear maximum. Ray-tracing simulations predict a decay of wave energy subsequent to wave-mean flow interactions. The hypothesized wave-mean flow interactions drive a deep flow toward lighter densities of up to 0.6 Sv over the mid-ocean ridge flank in the Brazil Basin, and the same process may also cause upwelling of abyssal waters in other ocean basins with mid-ocean ridges with fracture zones.

Diagenesis of clay mineral assemblages in the Shikoku Basin: Inputs to the Nankai Trough megathrust and seismogenic zone

NASA Astrophysics Data System (ADS)

Underwood, M.; Guo, J.; Song, C.

2012-12-01

One of the essential components of the Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) is to document the composition and diagenetic alteration of sedimentary inputs to the subduction zone of SW Japan. Two sites were drilled seaward of the trench during IODP Expeditions 322 and 333 to demonstrate how those subduction inputs have been influenced by the basement topography of Shikoku Basin. Site C0011 was drilled on the NW flank of Kashinosaki Knoll, and Site C0012 is located near the seamount's summit. The lithostratigraphy expands and condenses from site to site, but the clay mineral assemblages are nearly identical when comparisons are made among coeval units. The early history of sedimentation (middle to late Miocene) was dominated by expandable clay minerals of the smectite group. Contents of smectite in strata older than 5.3 Ma typically exceed 65% of the clay-size fraction, and there are dozens of bentonite layers (altered volcanic ash) interbedded with the hemipelagic mudstones and turbidites. Those percentages amount to >45 wt-% smectite in the bulk mudstone. Volcanic sources for the Miocene clay probably included the ancestral Izu-Bonin island arc, the Izu-Honshu collision zone, and anomalous near-trench magma bodies in the Outer Zone of Honshu and Shikoku Island. As sedimentation progressed into the Pliocene and Pleistocene, mud supplies to the Shikoku Basin shifted increasingly to detrital illite and chlorite eroded from the uplifted accretionary complex (Outer Zone). At Site C0011, the younger hemipelagic-pyroclastic facies (upper Shikoku Basin) contains an average of 43% smectite, 36% illite, and 18% kaolinite + chlorite in the clay-size fraction. At Site C0012, comparable values are S = 51%, I = 32%, and K+C = 14%. XRD results show no evidence of smectite-to-illite diagenesis seaward of the trench, although it is important to note that Site C0011 was abandoned before reaching basaltic basement. We can predict the extent of smectite

Trabecular fracture zone might not be the higher strain region of the trabecular framework

NASA Astrophysics Data System (ADS)

Tassani, Simone; Pani, Martino; Noailly, Jerome; Gonzalez Ballester, Miguel Angel

2018-02-01

Trabecular bone fracture is a traumatic and localized event studied worldwide in order to predict it. During the years researchers focussed over the mechanical characterization of the trabecular tissue to understand its mechanics. Several studies pointed out the very local nature of the trabecular failure, finally identifying the fracture zone with the aim to study it separately. The complexity of the three-dimensional trabecular framework and the local nature of the fracture event do not allow the direct evaluation of a single trabecula’s behaviour within its natural environment. For this reason, micro-Finite Element Modelling have been seen as the best way to investigate this biomechanical issue. Mechanical strain analysis is adopted in the literature for the identification of micro fracture using criteria based on principal strains. However, it was never verified if the fracture zone is actually the zone where principal strains are concentrated. Here we show how the maximum strain of the tissue might not be directly correlated to the fracture. In the present work a previously validated technique was used to identify the fracture zone of 10 trabecular specimen mechanically tested in compression and scanned in micro-CT before and after the mechanical test. Before-compression datasets were used to develop 10 micro-FE models were the same boundary conditions of the mechanical test were reproduced. Our results show how the known linear behaviour of the trabecular framework might not be directly related to the development of the fracture suggesting other non-linear phenomenon, like buckling or micro-damage, as actual cause of the traumatic event. This result might have several implications both in micro-modelling and in clinical applications for the study of fracture related pathology, like osteoporosis.

Controls on fault zone structure and brittle fracturing in the foliated hanging wall of the Alpine Fault

NASA Astrophysics Data System (ADS)

Williams, Jack N.; Toy, Virginia G.; Massiot, Cécile; McNamara, David D.; Smith, Steven A. F.; Mills, Steven

2018-04-01

Three datasets are used to quantify fracture density, orientation, and fill in the foliated hanging wall of the Alpine Fault: (1) X-ray computed tomography (CT) images of drill core collected within 25 m of its principal slip zones (PSZs) during the first phase of the Deep Fault Drilling Project that were reoriented with respect to borehole televiewer images, (2) field measurements from creek sections up to 500 m from the PSZs, and (3) CT images of oriented drill core collected during the Amethyst Hydro Project at distances of ˜ 0.7-2 km from the PSZs. Results show that within 160 m of the PSZs in foliated cataclasites and ultramylonites, gouge-filled fractures exhibit a wide range of orientations. At these distances, fractures are interpreted to have formed at relatively high confining pressures and/or in rocks that had a weak mechanical anisotropy. Conversely, at distances greater than 160 m from the PSZs, fractures are typically open and subparallel to the mylonitic or schistose foliation, implying that fracturing occurred at low confining pressures and/or in rocks that were mechanically anisotropic. Fracture density is similar across the ˜ 500 m width of the field transects. By combining our datasets with measurements of permeability and seismic velocity around the Alpine Fault, we further develop the hierarchical model for hanging-wall damage structure that was proposed by Townend et al. (2017). The wider zone of foliation-parallel fractures represents an outer damage zone that forms at shallow depths. The distinct < 160 m wide interval of widely oriented gouge-filled fractures constitutes an inner damage zone. This zone is interpreted to extend towards the base of the seismogenic crust given that its width is comparable to (1) the Alpine Fault low-velocity zone detected by fault zone guided waves and (2) damage zones reported from other exhumed large-displacement faults. In summary, a narrow zone of fracturing at the base of the Alpine Fault

In situ stress and fracture permeability along the Stillwater fault zone, Dixie Valley Nevada

USGS Publications Warehouse

Hickman, S.H.; Barton, C.A.; Zoback, M.D.; Morin, R.; Sass, J.; Benoit, R.

1997-01-01

Borehole televiewer and hydrologic logging and hydraulic fracturing stress measurements were carried out in a 2.7-km-deep geothermal production well (73B-7) drilled into the Stillwater fault zone. Precision temperature and spinner flowmeter logs were also acquired in well 73B-7, with and without simultaneously injecting water into the well. Localized perturbations to well-bore temperature and flow were used to identify hydraulically conductive fractures. Comparison of these data with fracture orientations from the televiewer log indicates that permeable fractures within and adjacent to the Stillwater fault zone are critically stressed, potentially active shear planes in the current west-northwest extensional stress regime at Dixie Valley.

Predicting Fluid Flow in Stressed Fractures: A Quantitative Evaluation of Methods

NASA Astrophysics Data System (ADS)

Weihmann, S. A.; Healy, D.

2015-12-01

Reliable estimation of fracture stability in the subsurface is crucial to the success of exploration and production in the petroleum industry, and also for wider applications to earthquake mechanics, hydrogeology and waste disposal. Previous work suggests that fracture stability is related to fluid flow in crystalline basement rocks through shear or tensile instabilities of fractures. Our preliminary scoping analysis compares the fracture stability of 60 partly open (apertures 1.5-3 cm) and electrically conductive (low acoustic amplitudes relative to matrix) fractures from a 16 m section of a producing zone in a basement well in Bayoot field, Yemen, to a non-producing zone in the same well (also 16 m). We determine the Critically Stressed Fractures (CSF; Barton et al., 1995) and dilatation tendency (Td; Ferrill et al., 1999). We find that: 1. CSF (Fig. 1) is a poor predictor of high fluid flow in the inflow zone; 88% of the fractures are predicted to be NOT critically stressed and yet they all occur within a zone of high fluid flow rate 2. Td (Fig. 2) is also a poor predictor of high fluid flow in the inflow zone; 67% of the fractures have a LOW Td(< 0.6) 3. For the non-producing zone CSF is a very reliable predictor (100% are not critically stressed) whereas the values of Tdare consistent with their location in non-producing interval (81% are < 0.6) (Fig. 3 & 4). In summary, neither method correlates well with the observed abundance of hydraulically conductive fractures within the producing zone. Within the non-producing zone CSF and Td make reasonably accurate predictions. Fractures may be filled or partially filled with drilling mud or a lower density and electrically conductive fill such as clay in the producing zone and therefore appear (partly) open. In situ stress, fluid pressure, rock properties (friction, strength) and fracture orientation data used as inputs for the CSF and Td calculations are all subject to uncertainty. Our results suggest that scope

Water, oceanic fracture zones and the lubrication of subducting plate boundaries—insights from seismicity

NASA Astrophysics Data System (ADS)

Schlaphorst, David; Kendall, J.-Michael; Collier, Jenny S.; Verdon, James P.; Blundy, Jon; Baptie, Brian; Latchman, Joan L.; Massin, Frederic; Bouin, Marie-Paule

2016-03-01

We investigate the relationship between subduction processes and related seismicity for the Lesser Antilles Arc using the Gutenberg-Richter law. This power law describes the earthquake-magnitude distribution, with the gradient of the cumulative magnitude distribution being commonly known as the b-value. The Lesser Antilles Arc was chosen because of its along-strike variability in sediment subduction and the transition from subduction to strike-slip movement towards its northern and southern ends. The data are derived from the seismicity catalogues from the Seismic Research Centre of The University of the West Indies and the Observatoires Volcanologiques et Sismologiques of the Institut de Physique du Globe de Paris and consist of subcrustal events primarily from the slab interface. The b-value is found using a Kolmogorov-Smirnov test for a maximum-likelihood straight line-fitting routine. We investigate spatial variations in b-values using a grid-search with circular cells as well as an along-arc projection. Tests with different algorithms and the two independent earthquake cataloges provide confidence in the robustness of our results. We observe a strong spatial variability of the b-value that cannot be explained by the uncertainties. Rather than obtaining a simple north-south b-value distribution suggestive of the dominant control on earthquake triggering being water released from the sedimentary cover on the incoming American Plates, or a b-value distribution that correlates with on the obliquity of subduction, we obtain a series of discrete, high b-value `bull's-eyes' along strike. These bull's-eyes, which indicate stress release through a higher fraction of small earthquakes, coincide with the locations of known incoming oceanic fracture zones on the American Plates. We interpret the results in terms of water being delivered to the Lesser Antilles subduction zone in the vicinity of fracture zones providing lubrication and thus changing the character of the

Mapping Inherited Fractures in the Critical Zone Using Seismic Anisotropy From Circular Surveys

NASA Astrophysics Data System (ADS)

Novitsky, Christopher G.; Holbrook, W. Steven; Carr, Bradley J.; Pasquet, Sylvain; Okaya, David; Flinchum, Brady A.

2018-04-01

Weathering and hydrological processes in Earth's shallow subsurface are influenced by inherited bedrock structures, such as bedding planes, faults, joints, and fractures. However, these structures are difficult to observe in soil-mantled landscapes. Steeply dipping structures with a dominant orientation are detectable by seismic anisotropy, with fast wave speeds along the strike of structures. We measured shallow ( 2-4 m) seismic anisotropy using "circle shots," geophones deployed in a circle around a central shot point, in a weathered granite terrain in the Laramie Range of Wyoming. The inferred remnant fracture orientations agree with brittle fracture orientations measured at tens of meters depth in boreholes, demonstrating that bedrock fractures persist through the weathering process into the shallow critical zone. Seismic anisotropy positively correlates with saprolite thickness, suggesting that inherited bedrock fractures may control saprolite thickness by providing preferential pathways for corrosive meteoric waters to access the deep critical zone.

Origin of the Louisville Ridge and its relationship to the Eltanin Fracture Zone System

NASA Astrophysics Data System (ADS)

Watts, A. B.; Weissel, J. K.; Duncan, R. A.; Larson, R. L.

1988-04-01

We have combined shipboard and Seasat altimeter derived data in an intergrated geological and geophysical study of the Louisville Ridge; a 3500-km-long seamount chain extending from the Tonga trench to the Eltanin Fracture Zone. A break in the smooth trend of the ridge at latitude 37.5°S has been recognized in both bathymetric and altimetric data. The 40Ar-39Ar dating of rocks dredged either side of the break suggest that it is analogous to the bend in the Hawaiian-Emperor seamount chain. Although the general trend of the ridge can be fit by small circles about Pacific absolute motion poles determined from other seamount chains, the new bathymetric and age data allow us to refine Pacific absolute motion poles. The continuity in smooth trend of the ridge and the Eltanin Fracture Zone suggests some relationship between them. However, a major offset developed on this transform between 60 and 80 Ma, prior to the oldest dated rocks from the ridge. Although magmatism was more or less continuous on the ridge during 28-60 Ma, it probably occurred on crust with little or no offset. Thus magmatism appears to have been little influenced by the developing fracture zone. By 28 Ma, the distance between the magmatic source and the fracture zone had decreased sufficiently for a portion of the ridge to have been emplaced on crust with an offset. After about 12 Ma, however, volcanic activity on the Louisville Ridge apparently waned, despite a possible influence on the magmatism of the fracture zone.

Geophysical evidence for the intersection of the St Paul, Cape Palmas and Grand Cess fracture zones with the continental margin of Liberia, West Africa

USGS Publications Warehouse

Behrendt, John C.; Schlee, J.; Robb, James M.

1974-01-01

PUBLISHED reconstructions of Gondwana continent1 (Fig. la) show a gap in fit near the junction of the Americas and Africa. To study this critical area, the Unitedgeo I made geophysical measurements and collected rock samples across the continental margin of Liberia (USGS-IDOE cruise leg 5) in November 1971. Figure Ib indicates the location of the 5,400 km of ship track on a generalised bathymetric map2. We shall discuss the data in detail elsewhere. Here we present the evidence for the existence of three fracture zones, two of which have not been reported previously, intersecting the continental margin at the north end of the South Atlantic, which remained closed probably until Cretaceous time. We suggest that Precambrian structures on the African continent controlled the location of these fracture zones. Figure Ic compares gravity and magnetic profiles and interpretations of the seismic profiles for three selected lines (27, 30 and 34) crossing the Grand Cess, Cape Palmas and St Paul fracture zones, respectively. ?? 1974 Nature Publishing Group.

Biodiversity and distribution of polynoid and spionid polychaetes (Annelida) in the Vema Fracture Zone, tropical North Atlantic

NASA Astrophysics Data System (ADS)

Guggolz, Theresa; Lins, Lidia; Meißner, Karin; Brandt, Angelika

2018-02-01

During the Vema-TRANSIT (Bathymetry of the Vema-Fracture Zone and Puerto Rico TRench and Abyssal AtlaNtic BiodiverSITy Study) expedition from December, 2014 to January, 2015, a transect along the Vema Fracture Zone in the equatorial Atlantic was surveyed and sampled at about 10°N. The Vema Fracture Zone is one of the largest fracture zones of the Mid-Atlantic Ridge and it is characterized by a large left-lateral offset. Benthic communities of the transect and the abyssal basins on both sides were investigated to examine whether the Mid-Atlantic Ridge serves as a physical barrier for these organisms, or if there is a potential connection from east to west via the Vema Fracture Zone. Samples comprised 4149 polychaetes, belonging to 42 families. Exemplary, Polynoidae and Spionidae, both typical deep-sea families with high abundances in all investigated regions, were identified up to species level. The present results show significant differences in polychaete faunistic composition between both sides of the Mid-Atlantic Ridge. Moreover, the eastern and western Vema Fracture Zone characterizes divergent habitats, since the two basins differ in sedimentology and environmental variables (e.g. temperature, salinity), hence characterizing divergent habitats. Most species found were restricted to either eastern or western VFZ, but there was a trans-Mid-Atlantic Ridge distribution of certain abundant species observed, indicating that the Mid-Atlantic Ridge might rather act limiting to dispersal between ocean basins than as an absolute barrier. Given the abyssal valley formed by the Vema Fracture Zone and its role in oceanic currents, this seafloor feature may well represent exchange routes between eastern and western faunas.

Specification of matrix cleanup goals in fractured porous media.

PubMed

Rodríguez, David J; Kueper, Bernard H

2013-01-01

Semianalytical transient solutions have been developed to evaluate what level of fractured porous media (e.g., bedrock or clay) matrix cleanup must be achieved in order to achieve compliance of fracture pore water concentrations within a specified time at specified locations of interest. The developed mathematical solutions account for forward and backward diffusion in a fractured porous medium where the initial condition comprises a spatially uniform, nonzero matrix concentration throughout the domain. Illustrative simulations incorporating the properties of mudstone fractured bedrock demonstrate that the time required to reach a desired fracture pore water concentration is a function of the distance between the point of compliance and the upgradient face of the domain where clean groundwater is inflowing. Shorter distances correspond to reduced times required to reach compliance, implying that shorter treatment zones will respond more favorably to remediation than longer treatment zones in which back-diffusion dominates the fracture pore water response. For a specified matrix cleanup goal, compliance of fracture pore water concentrations will be reached sooner for decreased fracture spacing, increased fracture aperture, higher matrix fraction organic carbon, lower matrix porosity, shorter aqueous phase decay half-life, and a higher hydraulic gradient. The parameters dominating the response of the system can be measured using standard field and laboratory techniques. © 2012, The Author(s). Ground Water © 2012, National Ground Water Association.

Fault and fracture patterns in low porosity chalk and their potential influence on sub-surface fluid flow-A case study from Flamborough Head, UK

NASA Astrophysics Data System (ADS)

Sagi, D. A.; De Paola, N.; McCaffrey, K. J. W.; Holdsworth, R. E.

2016-10-01

To better understand fault zone architecture and fluid flow in mesoscale fault zones, we studied normal faults in chalks with displacements up to 20 m, at two representative localities in Flamborough Head (UK). At the first locality, chalk contains cm-thick, interlayered marl horizons, whereas at the second locality marl horizons were largely absent. Cm-scale displacement faults at both localities display ramp-flat geometries. Mesoscale fault patterns in the marl-free chalk, including a larger displacement fault (20 m) containing multiple fault strands, show widespread evidence of hydraulically-brecciated rocks, whereas clays smears along fault planes, and injected into open fractures, and a simpler fault zone architecture is observed where marl horizons are present. Hydraulic brecciation and veins observed in the marl-free chalk units suggest that mesoscale fault patterns acted as localized fault conduit allowing for widespread fluid flow. On the other hand, mesoscale fault patterns developed in highly fractured chalk, which contains interlayered marl horizons can act as localized barriers to fluid flow, due to the sealing effect of clays smears along fault planes and introduced into open fractures in the damage zone. To support our field observations, quantitative analyses carried out on the large faults suggest a simple fault zone in the chalk with marl units with fracture density/connectivity decreasing towards the protolith. Where marls are absent, density is high throughout the fault zone, while connectivity is high only in domains nearest the fault core. We suggest that fluid flow in fractured chalk is especially influenced by the presence of marls. When present, it can smear onto fault planes, forming localised barriers. Fluid flow along relatively large displacement faults is additionally controlled by the complexity of the fault zone, especially the size/geometry of weakly and intensely connected damage zone domains.

Hydrogeological characterization of soil/weathered zone and underlying fractured bedrocks in DNAPL contaminated areas using the electromagnetic flowmeter

NASA Astrophysics Data System (ADS)

Kang, E.; Yeo, I.

2011-12-01

Flowmeter tests were carried out to characterize hydrogeology at DNAPL contaminated site in Wonju, Korea. Aquifer and slug tests determined hydraulic conductivity of soil/weathered zone and underlying fractured bed rocks to be 2.95×10-6 to 7.11×10-6 m/sec and 9.14×10-7 to 2.59×10-6 m/sec, respectively. Ambient flowmeter tests under natural hydraulic conditions revealed that the inflow and outflow take place through the borehole of soil/weathered zone with a tendency of down flow in the borehole. In particular, the most permeable layer of 22 to 30 m below the surface was found to form a major groundwater flow channel. On the contrary, a slight inflow and outflow was observed in the borehole, and the groundwater that inflows in the bottom section of the fractured bedrock flows up and exits through to the most permeable layer. Hydraulic heads measured at nearby multi-level boreholes confirmed the down flow in the soil/weathered zone and the up flow in fractured bedrocks. It was also revealed that the groundwater flow converges to the most permeable layer. TCE concentration in groundwater was measured at different depths, and in the borehole of the soil/weathered zone, high TCE concentration was found with higher than 10 mg/L near to the water table and decreased to about 6 mg/L with depth. The fractured bedrocks have a relatively constant low TCE concentration through a 20 m thick screen at less than l mg/L. The hydrogeology of the up flow in the soil/weathered zone and the down flow in underlying fractured bedrock leads the groundwater flow, and subsequently TCE plume, mainly to the most permeable layer that also restricts the advective transport of TCE plume to underlying fractured bedrocks. The cross borehole flowmeter test was carried out to find any hydrogeological connection between the soil/weathered zone and underlying fractured bedrocks. When pumping groundwater from the soil/weathered zone, no induced flow by groundwater extraction was observed at the

Habitat characterization of the Vema Fracture Zone and Puerto Rico Trench

NASA Astrophysics Data System (ADS)

Devey, C. W.; Augustin, N.; Brandt, A.; Brenke, N.; Köhler, J.; Lins, L.; Schmidt, C.; Yeo, I. A.

2018-02-01

Although many of the regions on and close to the mid-ocean ridges have been extensively mapped and sampled, the abyssal intraplate regions remain essentially unsampled and unmapped, leaving huge gaps in our understanding of their geologic history and present activity. Prominent bathymetric features in these intraplate regions are fracture zones. Here we present bathymetric and sampling information from a transatlantic transect along the Vema Fracture Zone (ca. 11°N), covering crustal ages from 109 - 0 Ma on the African plate and 0-62 Ma on the South American plate. The Vema Fracture Zone is the intraplate trace of the active Vema Transform plate boundary, which offsets the present-day Mid-Atlantic Ridge by ca. 300 km left-laterally, juxtaposing zero-age crust with crust of 20 million years age. Our results show clear evidence of tectonic activity along most of the Fracture Zone, in most places likely associated with active fluid flow. Within the active Vema Transform at crustal ages of ca. 10 Ma we found clear indications of fluid flow both in the sediments and the overlying water column. This region is > 120 km from the nearest spreading axis and increases by almost an order of magnitude the maximum off-axis distance that active hydrothermal discharge has been found on the oceanic crust. Sampling of the igneous seafloor was possible at all crustal ages and the accretionary fabric imprinted on the plate during its production was prominent everywhere. Seafloor sediments show signs of extensive bioturbation. In one area, high concentrations of spherical Mn-nodules were also found and sampled. At the end of the transect we also mapped and sampled the Puerto Rico Trough, a > 8000 m-deep basin north of the Caribbean arc. Here the seafloor morphology is more complicated and strongly influenced by transpressive tectonics.

Linking giant earthquakes with the subduction of oceanic fracture zones

NASA Astrophysics Data System (ADS)

Landgrebe, T. C.; Müller, R. D.; EathByte Group

2011-12-01

Giant subduction earthquakes are known to occur in areas not previously identified as prone to high seismic risk. This highlights the need to better identify subduction zone segments potentially dominated by relatively long (up to 1000 years and more) recurrence times of giant earthquakes. Global digital data sets represent a promising source of information for a multi-dimensional earthquake hazard analysis. We combine the NGDC global Significant Earthquakes database with a global strain rate map, gridded ages of the ocean floor, and a recently produced digital data set for oceanic fracture zones, major aseismic ridges and volcanic chains to investigate the association of earthquakes as a function of magnitude with age of the downgoing slab and convergence rates. We use a so-called Top-N recommendation method, a technology originally developed to search, sort, classify, and filter very large and often statistically skewed data sets on the internet, to analyse the association of subduction earthquakes sorted by magnitude with key parameters. The Top-N analysis is used to progressively assess how strongly particular "tectonic niche" locations (e.g. locations along subduction zones intersected with aseismic ridges or volcanic chains) are associated with sets of earthquakes in sorted order in a given magnitude range. As the total number N of sorted earthquakes is increased, by progressively including smaller-magnitude events, the so-called recall is computed, defined as the number of Top-N earthquakes associated with particular target areas divided by N. The resultant statistical measure represents an intuitive description of the effectiveness of a given set of parameters to account for the location of significant earthquakes on record. We use this method to show that the occurrence of great (magnitude ≥ 8) earthquakes on overriding plate segments is strongly biased towards intersections of oceanic fracture zones with subduction zones. These intersection regions are

Marine Geophysical Characterization of the Chain Fracture Zone in the Equatorial Atlantic

NASA Astrophysics Data System (ADS)

Harmon, N.; Rychert, C.; Agius, M. R.; Tharimena, S.; Kendall, J. M.

2017-12-01

The Chain Fracture zone is part of a larger system of fracture zones along the Mid Atlantic Ridge that is thought to be one of the original zones of weakness during the break up of Pangea. It is over 300 km long and produces earthquakes as large as Mw 6.9 on segments of the active fault zone. Here we present the results of two marine geophysical mapping campaigns over the active part of the Chain Fracture zone as part of the PI-LAB (Passive Imaging of the Lithosphere-Asthenosphere Boundary) experiment. We collected swath bathymetry, backscatter imagery, gravity and total field magnetic anomaly. We mapped the fault scarps within the transform fault system using the 50 m resolution swath and backscatter imagery. In addition, a 30-40 mGal residual Mantle Bouguer Anomaly determined from gravity analysis suggests the crust is by up to 1.4-2.0 km beneath the Chain relative to the adjacent ridge segments. However, in the eastern 75 km of the active transform we find evidence for thicker crust. The active fault system cuts through the region of thicker crust and there is a cluster of MW > 6 earthquakes in this region. There is a cluster of similar sized earthquakes on the western end where thinner crust is inferred. This suggests that variations in melt production and crustal thickness at the mid ocean ridge systems may have only a minor effect on the seismicity and longevity of the transform fault system.

Simulation of anisotropic fracture behaviour of polycrystalline round blank tungsten using cohesive zone model

NASA Astrophysics Data System (ADS)

Mahler, Michael; Gaganidze, Ermile; Aktaa, Jarir

2018-04-01

The experimental observation of anisotropic fracture behaviour of round blank polycrystalline tungsten was simulated using finite element (FE) method in combination with cohesive zone model. Experiments in the past had shown that due to the anisotropic microstructure the fracture toughness varies by factor of about two for different orientations. The reason is the crack propagation direction, which is - in some orientations - not the typical crack propagation direction for mode I fracture. In some directions the crack is not growing perpendicular to the crack opening tensile load. Nevertheless, in the present paper, the microstructure is modelled by FE mesh including cohesive zone elements which mimic grain boundaries (GB). This is based on the assumption that GB's are the weakest links in the structure. The use of the correct parameters to describe the fracture process allows the description of the observed experimental orientation dependent fracture toughness.

Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange

. For example, the excavation-damaged zone (EDZ) near repository tunnels can modify local permeability (resulting from induced fractures), potentially leading to less confinement capability (Tsang et al., 2005). Because of clay's swelling and shrinkage behavior (depending on whether the clay is in imbibition or drainage processes), fracture properties in the EDZ are quite dynamic and evolve over time as hydromechanical conditions change. To understand and model the coupled processes and their impact on repository performance is critical for the defensible performance assessment of a clay repository. Within the Natural Barrier System (NBS) group of the Used Fuel Disposition (UFD) Campaign at DOE's Office of Nuclear Energy, LBNL's research activities have focused on understanding and modeling such coupled processes. LBNL provided a report in this April on literature survey of studies on coupled processes in clay repositories and identification of technical issues and knowledge gaps (Tsang et al., 2010). This report will document other LBNL research activities within the natural system work package, including the development of constitutive relationships for elastic deformation of clay rock (Section 2), a THM modeling study (Section 3) and a THC modeling study (Section 4). The purpose of the THM and THC modeling studies is to demonstrate the current modeling capabilities in dealing with coupled processes in a potential clay repository. In Section 5, we discuss potential future R&D work based on the identified knowledge gaps. The linkage between these activities and related FEPs is presented in Section 6.« less

TECHNOLOGY EVALUATION REPORT: SITE PROGRAM DEMONSTRATION TEST - ACCUTECH PNEUMATIC FRACTURING EXTRACTION AND HOT GAS INJECTION, PHASE 1 - VOLUME I

EPA Science Inventory

The Pneumatic Fracturing Extraction (PFE) process developed by Accutech Remedial Systems, Inc. makes it possible to use vapor extraction to remove volatile organics at increased rates from a broader range of vadose zones. The low permeability of silts, clays, shales, etc. would o...

Approach for computing 1D fracture density: application to fracture corridor characterization

NASA Astrophysics Data System (ADS)

Viseur, Sophie; Chatelée, Sebastien; Akriche, Clement; Lamarche, Juliette

2016-04-01

Fracture density is an important parameter for characterizing fractured reservoirs. Many stochastic simulation algorithms that generate fracture networks indeed rely on the determination of a fracture density on volumes (P30) to populate the reservoir zones with individual fracture surfaces. However, only 1D fracture density (P10) are available from subsurface data and it is then important to be able to accurately estimate this entity. In this paper, a novel approach is proposed to estimate fracture density from scan-line or well data. This method relies on regression, hypothesis testing and clustering techniques. The objective of the proposed approach is to highlight zones where fracture density are statistically very different or similar. This technique has been applied on both synthetic and real case studies. These studies concern fracture corridors, which are particular tectonic features that are generally difficult to characterize from subsurface data. These tectonic features are still not well known and studies must be conducted to better understand their internal spatial organization and variability. The presented synthetic cases aim at showing the ability of the approach to extract known features. The real case study illustrates how this approach allows the internal spatial organization of fracture corridors to be characterized.

Effect of Segregation of Secondary Phase Particles and "S" Line on Tensile Fracture Behavior of Friction Stir-Welded 2024Al-T351 Joints

NASA Astrophysics Data System (ADS)

Zhang, Z.; Xiao, B. L.; Ma, Z. Y.

2013-09-01

A 5-mm-thick 2024Al-T351 plate was friction stir welded (FSWed) at welding speeds of 100, 200, and 400 mm min-1 with a constant rotation rate of 800 rpm, and the microstructure and tensile fracture behavior of the joints were investigated in detail. FSW resulted in the redistribution of secondary phase particles along the recrystallized grain boundaries at the nugget zone (NZ), forming linear segregation bands consisting of secondary phase particles. The segregation bands, mainly present in the shoulder-driven zone, were believed to result from periodic material flow, with the average band spacing on the longitudinal and horizontal cross sections equal to the tool advancement per revolution. At a low welding speed of 100 mm min-1, in spite of the highest density of segregation bands, the FSWed 2024Al-T351 joint fractured along the low hardness zone (LHZ) of the heat-affected zone because of large hardness gap between NZ and LHZ. Increasing the welding speed to 200 and 400 mm min-1 reduced both the hardness gap between NZ and LHZ and the density of segregation bands. In this case, the segregation bands played a role, resulting in unusual fracture of the joints along the segregation bands. The "S" line originated from the oxide film on the initial butting surfaces and did not affect the fracture behavior of the FSWed 2024Al-T351 joints.

The effect of offset on fracture permeability of rocks from the Southern Andes Volcanic Zone, Chile

NASA Astrophysics Data System (ADS)

Pérez-Flores, P.; Wang, G.; Mitchell, T. M.; Meredith, P. G.; Nara, Y.; Sarkar, V.; Cembrano, J.

2017-11-01

The Southern Andes Volcanic Zone (SVZ) represents one of the largest undeveloped geothermal provinces in the world. Development of the geothermal potential requires a detailed understanding of fluid transport properties of its main lithologies. The permeability of SVZ rocks is altered by the presence of fracture damage zones produced by the Liquiñe-Ofqui Fault System (LOFS) and the Andean Transverse Faults (ATF). We have therefore measured the permeability of four representative lithologies from the volcanic basement in this area: crystalline tuff, andesitic dike, altered andesite and granodiorite. For comparative purposes, we have also measured the permeability of samples of Seljadalur basalt, an Icelandic rock with widely studied and reported hydraulic properties. Specifically, we present the results of a systematic study of the effect of fractures and fracture offsets on permeability as a function of increasing effective pressure. Baseline measurements on intact samples of SVZ rocks show that the granodiorite has a permeability (10-18 m2), two orders of magnitude higher than that of the volcanic rocks (10-20 m2). The presence of throughgoing mated macro-fractures increases permeability by between four and six orders of magnitude, with the highest permeability recorded for the crystalline tuff. Increasing fracture offset to produce unmated fractures results in large increases in permeability up to some characteristic value of offset, beyond which permeability changes only marginally. The increase in permeability with offset appears to depend on fracture roughness and aperture, and these are different for each lithology. Overall, fractured SVZ rocks with finite offsets record permeability values consistent with those commonly found in geothermal reservoirs (>10-16 m2), which potentially allow convective/advective flow to develop. Hence, our results demonstrate that the fracture damage zones developed within the SVZ produce permeable regions, especially within the

The three-zone composite productivity model for a multi-fractured horizontal shale gas well

NASA Astrophysics Data System (ADS)

Qi, Qian; Zhu, Weiyao

2018-02-01

Due to the nano-micro pore structures and the massive multi-stage multi-cluster hydraulic fracturing in shale gas reservoirs, the multi-scale seepage flows are much more complicated than in most other conventional reservoirs, and are crucial for the economic development of shale gas. In this study, a new multi-scale non-linear flow model was established and simplified, based on different diffusion and slip correction coefficients. Due to the fact that different flow laws existed between the fracture network and matrix zone, a three-zone composite model was proposed. Then, according to the conformal transformation combined with the law of equivalent percolation resistance, the productivity equation of a horizontal fractured well, with consideration given to diffusion, slip, desorption, and absorption, was built. Also, an analytic solution was derived, and the interference of the multi-cluster fractures was analyzed. The results indicated that the diffusion of the shale gas was mainly in the transition and Fick diffusion regions. The matrix permeability was found to be influenced by slippage and diffusion, which was determined by the pore pressure and diameter according to the Knudsen number. It was determined that, with the increased half-lengths of the fracture clusters, flow conductivity of the fractures, and permeability of the fracture network, the productivity of the fractured well also increased. Meanwhile, with the increased number of fractures, the distance between the fractures decreased, and the productivity slowly increased due to the mutual interfere of the fractures.

Implant therapy in the esthetic zone: smile line assessment.

PubMed

Kourkouta, Stella

2011-04-01

Assessment of the smile or lip line is imperative when implant therapy is carried out in the esthetic zone. The smile is generally defined as high, average, or low. Females are reported to have higher lip lines than males, which means that they are at greater risk when placing and restoring implants in the esthetic zone. Maximum upper lip elevation, usually observed during a strained posed smile, should be assessed. This paper discusses some clinical observations and concepts in relation to smile line assessment for implant therapy in the esthetic zone. (Int J Periodontics Restorative Dent 2011;31:195-201.).

Seismic imaging of a fractured gas hydrate system in the Krishna-Godavari Basin offshore India

USGS Publications Warehouse

Riedel, M.; Collett, T.S.; Kumar, P.; Sathe, A.V.; Cook, A.

2010-01-01

Gas hydrate was discovered in the Krishna-Godavari (KG) Basin during the India National Gas Hydrate Program (NGHP) Expedition 1 at Site NGHP-01-10 within a fractured clay-dominated sedimentary system. Logging-while-drilling (LWD), coring, and wire-line logging confirmed gas hydrate dominantly in fractures at four borehole sites spanning a 500m transect. Three-dimensional (3D) seismic data were subsequently used to image the fractured system and explain the occurrence of gas hydrate associated with the fractures. A system of two fault-sets was identified, part of a typical passive margin tectonic setting. The LWD-derived fracture network at Hole NGHP-01-10A is to some extent seen in the seismic data and was mapped using seismic coherency attributes. The fractured system around Site NGHP-01-10 extends over a triangular-shaped area of ~2.5 km2 defined using seismic attributes of the seafloor reflection, as well as " seismic sweetness" at the base of the gas hydrate occurrence zone. The triangular shaped area is also showing a polygonal (nearly hexagonal) fault pattern, distinct from other more rectangular fault patterns observed in the study area. The occurrence of gas hydrate at Site NGHP-01-10 is the result of a specific combination of tectonic fault orientations and the abundance of free gas migration from a deeper gas source. The triangular-shaped area of enriched gas hydrate occurrence is bound by two faults acting as migration conduits. Additionally, the fault-associated sediment deformation provides a possible migration pathway for the free gas from the deeper gas source into the gas hydrate stability zone. It is proposed that there are additional locations in the KG Basin with possible gas hydrate accumulation of similar tectonic conditions, and one such location was identified from the 3D seismic data ~6 km NW of Site NGHP-01-10. ?? 2010.

Characterization of fractures and flow zones in a contaminated shale at the Watervliet Arsenal, Albany County, New York

USGS Publications Warehouse

Williams, John H.; Paillet, Frederick L.

2002-01-01

Flow zones in a fractured shale in and near a plume of volatile organic compounds at the Watervliet Arsenal in Albany County, N. Y. were characterized through the integrated analysis of geophysical logs and single- and cross-hole flow tests. Information on the fracture-flow network at the site was needed to design an effective groundwater monitoring system, estimate offsite contaminant migration, and evaluate potential containment and remedial actions.Four newly drilled coreholes and four older monitoring wells were logged and tested to define the distribution and orientation of fractures that intersected a combined total of 500 feet of open hole. Analysis of borehole-wall image logs obtained with acoustic and optical televiewers indicated 79 subhorizontal to steeply dipping fractures with a wide range of dip directions. Analysis of fluid resistivity, temperature, and heat-pulse and electromagnetic flowmeter logs obtained under ambient and short-term stressed conditions identified 14 flow zones, which consist of one to several fractures and whose estimated transmissivity values range from 0.1 to more than 250 feet squared per day.Cross-hole flow tests, which were used to characterize the hydraulic connection between fracture-flow zones intersected by the boreholes, entailed (1) injection into or extraction from boreholes that penetrated a single fracture-flow zone or whose zones were isolated by an inflatable packer, and (2) measurement of the transient response of water levels and flow in surrounding boreholes. Results indicate a wellconnected fracture network with an estimated transmissivity of 80 to 250 feet squared per day that extends for at least 200 feet across the site. This interconnected fracture-flow network greatly affects the hydrology of the site and has important implications for contaminant monitoring and remedial actions.

Predictive modelling of fault related fracturing in carbonate damage-zones: analytical and numerical models of field data (Central Apennines, Italy)

NASA Astrophysics Data System (ADS)

Mannino, Irene; Cianfarra, Paola; Salvini, Francesco

2010-05-01

Permeability in carbonates is strongly influenced by the presence of brittle deformation patterns, i.e pressure-solution surfaces, extensional fractures, and faults. Carbonate rocks achieve fracturing both during diagenesis and tectonic processes. Attitude, spatial distribution and connectivity of brittle deformation features rule the secondary permeability of carbonatic rocks and therefore the accumulation and the pathway of deep fluids (ground-water, hydrocarbon). This is particularly true in fault zones, where the damage zone and the fault core show different hydraulic properties from the pristine rock as well as between them. To improve the knowledge of fault architecture and faults hydraulic properties we study the brittle deformation patterns related to fault kinematics in carbonate successions. In particular we focussed on the damage-zone fracturing evolution. Fieldwork was performed in Meso-Cenozoic carbonate units of the Latium-Abruzzi Platform, Central Apennines, Italy. These units represent field analogues of rock reservoir in the Southern Apennines. We combine the study of rock physical characteristics of 22 faults and quantitative analyses of brittle deformation for the same faults, including bedding attitudes, fracturing type, attitudes, and spatial intensity distribution by using the dimension/spacing ratio, namely H/S ratio where H is the dimension of the fracture and S is the spacing between two analogous fractures of the same set. Statistical analyses of structural data (stereonets, contouring and H/S transect) were performed to infer a focussed, general algorithm that describes the expected intensity of fracturing process. The analytical model was fit to field measurements by a Montecarlo-convergent approach. This method proved a useful tool to quantify complex relations with a high number of variables. It creates a large sequence of possible solution parameters and results are compared with field data. For each item an error mean value is

Central Japan's Atera Active Fault's Wide-Fractured Zone: An Examination of the Structure and In-situ Crustal Stress

NASA Astrophysics Data System (ADS)

Ikeda, R.; Omura, K.; Matsuda, T.; Mizuochi, Y.; Uehara, D.; Chiba, A.; Kikuchi, A.; Yamamoto, T.

2001-12-01

In-situ downhole measurements and coring within and around an active fault zone are needed to better understand the structure and material properties of fault rocks as well as the physical state of active faults and intra-plate crust. Particularly, the relationship between the stress concentration state and the heterogeneous strength of an earthquake fault zone is important to estimate earthquake occurrence mechanisms which correspond to the prediction of an earthquake. It is necessary to compare some active faults in different conditions of the chrysalis stage and their relation to subsequent earthquake occurrence. To better understand such conditions, "Active Fault Zone Drilling Project" has been conducted in the central part of Japan by the National Research Institute for Earth Science and Disaster Prevention. The Nojima fault which appeared on the surface by the 1995 Great Kobe earthquake (M=7.2) and the Neodani fault created by the 1981 Nobi earthquake, the greatest inland earthquake M=8.0 in Japan, have been drilled through the fault fracture zones. During these past four years, a similar experiment and research at the Atera fault, of which some parts seem to have been dislocated by the 1586 Tensyo earthquake, has been undertaken. The features of the Atera fault are as follows: (1) total length is about 70 km, (2) general trend is NW45_Kwith a left-lateral strike slip, (3) slip rate is estimated as 3-5 m/1000 yrs. and the average recurrence time as 1700 yrs., (4) seismicity is very low at present, and (5) lithologies around the fault are basically granitic rocks and rhyolite. We have conducted integrated investigations by surface geophysical survey and drilling around the Atera fault. Six boreholes have been drilled from the depth of 400 m to 630 m. Four of these boreholes are located on a line crossing the fracture zone of the Atera fault. Resistivity and gravity structures inferred from surface geophysical surveys were compared with the physical properties

Tsunami potential assessment based on rupture zones, focal mechanisms and repeat times of strong earthquakes in the major Atlantic-Mediterranean seismic fracture zone

NASA Astrophysics Data System (ADS)

Agalos, Apostolos; Papadopoulos, Gerassimos A.; Kijko, Andrzej; Papageorgiou, Antonia; Smit, Ansie; Triantafyllou, Ioanna

2016-04-01

In the major Atlantic-Mediterranean seismic fracture zone, extended from Azores islands in the west to the easternmost Mediterranean Sea in the east, including the Marmara and Black Seas, a number of 22 tsunamigenic zones have been determined from historical and instrumental tsunami documentation. Although some tsunamis were produced by volcanic activity or landslides, the majority of them was generated by strong earthquakes. Since the generation of seismic tsunamis depends on several factors, like the earthquake size, focal depth and focal mechanism, the study of such parameters is of particular importance for the assessment of the potential for the generation of future tsunamis. However, one may not rule out the possibility for tsunami generation in areas outside of the 22 zones determined so far. For the Atlantic-Mediterranean seismic fracture zone we have compiled a catalogue of strong, potentially tsunamigenic (focal depth less than 100 km) historical earthquakes from various data bases and other sources. The lateral areas of rupture zones of these earthquakes were determined. Rupture zone is the area where the strain after the earthquake has dropped substantially with respect the strain before the earthquake. Aftershock areas were assumed to determine areas of rupture zones for instrumental earthquakes. For historical earthquakes macroseismic criteria were used such as spots of higher-degree seismic intensity and of important ground failures. For the period of instrumental seismicity, focal mechanism solutions from CMT, EMMA and other data bases were selected for strong earthquakes. From the geographical distribution of seismic rupture zones and the corresponding focal mechanisms in the entire Atlantic-Mediterranean seismic fracture zone we determined potentially tsunamigenic zones regardless they are known to have produced seismic tsunamis in the past or not. An attempt has been made to calculate in each one of such zones the repeat times of strong

Multiscale Modeling of Grain-Boundary Fracture: Cohesive Zone Models Parameterized From Atomistic Simulations

NASA Technical Reports Server (NTRS)

Glaessgen, Edward H.; Saether, Erik; Phillips, Dawn R.; Yamakov, Vesselin

2006-01-01

A multiscale modeling strategy is developed to study grain boundary fracture in polycrystalline aluminum. Atomistic simulation is used to model fundamental nanoscale deformation and fracture mechanisms and to develop a constitutive relationship for separation along a grain boundary interface. The nanoscale constitutive relationship is then parameterized within a cohesive zone model to represent variations in grain boundary properties. These variations arise from the presence of vacancies, intersticies, and other defects in addition to deviations in grain boundary angle from the baseline configuration considered in the molecular dynamics simulation. The parameterized cohesive zone models are then used to model grain boundaries within finite element analyses of aluminum polycrystals.

X-ray fractography on fatigue fractured surface of austenitic stainless steel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yajima, Zenjiro; Tokuyama, Hideki; Kibayashi, Yasuo

1995-12-31

X-ray diffraction observation of the material internal structure beneath fracture surfaces provide fracture analysis with useful information to investigate the conditions and mechanisms of fracture. X-ray fractography is a generic name given to this technique. In the present study, X-ray fractography was applied to fatigue fracture surfaces of austenitic stainless steel (AISI 304) which consisted of solution treatment. The fatigue tests were carried out on compact tension (CT) specimens. The plastic strain on the fracture surface was estimated from measuring the line broadening of X-ray diffraction profiles. The line broadening of X-ray diffraction profiles was measured on and beneath fatiguemore » fracture surfaces. The depth of the plastic zone left on fracture surfaces was evaluated from the line broadening. The results are discussed on the basis of fracture mechanics.« less

Imaging Inelastic Fracture Processes in Biomimetic Nanocomposites and Nacre by Laser Speckle for Better Toughness.

PubMed

Verho, Tuukka; Karppinen, Pasi; Gröschel, André H; Ikkala, Olli

2018-01-01

Mollusk nacre is a prototypical biological inorganic-organic composite that combines high toughness, stiffness, and strength by its brick-and-mortar microstructure, which has inspired several synthetic mimics. Its remarkable fracture toughness relies on inelastic deformations at the process zone at the crack tip that dissolve stress concentrations and stop cracks. The micrometer-scale structure allows resolving the size and shape of the process zone to understand the fracture processes. However, for better scalability, nacre-mimetic nanocomposites with aligned inorganic or graphene nanosheets are extensively pursued, to avoid the packing problems of mesoscale sheets like in nacre or slow in situ biomineralization. This calls for novel methods to explore the process zone of biomimetic nanocomposites. Here the fracture of nacre and nacre-inspired clay/polymer nanocomposite is explored using laser speckle imaging that reveals the process zone even in absence of changes in optical scattering. To demonstrate the diagnostic value, compared to nacre, the nacre-inspired nanocomposite develops a process zone more abruptly with macroscopic crack deflection shown by a flattened process zone. In situ scanning electron microscopy suggests similar toughening mechanisms in nanocomposite and nacre. These new insights guide the design of nacre-inspired nanocomposites toward better mechanical properties to reach the level of synergy of their biological model.

Molecular-dynamics Simulation-based Cohesive Zone Representation of Intergranular Fracture Processes in Aluminum

NASA Technical Reports Server (NTRS)

Yamakov, Vesselin I.; Saether, Erik; Phillips, Dawn R.; Glaessgen, Edward H.

2006-01-01

A traction-displacement relationship that may be embedded into a cohesive zone model for microscale problems of intergranular fracture is extracted from atomistic molecular-dynamics simulations. A molecular-dynamics model for crack propagation under steady-state conditions is developed to analyze intergranular fracture along a flat 99 [1 1 0] symmetric tilt grain boundary in aluminum. Under hydrostatic tensile load, the simulation reveals asymmetric crack propagation in the two opposite directions along the grain boundary. In one direction, the crack propagates in a brittle manner by cleavage with very little or no dislocation emission, and in the other direction, the propagation is ductile through the mechanism of deformation twinning. This behavior is consistent with the Rice criterion for cleavage vs. dislocation blunting transition at the crack tip. The preference for twinning to dislocation slip is in agreement with the predictions of the Tadmor and Hai criterion. A comparison with finite element calculations shows that while the stress field around the brittle crack tip follows the expected elastic solution for the given boundary conditions of the model, the stress field around the twinning crack tip has a strong plastic contribution. Through the definition of a Cohesive-Zone-Volume-Element an atomistic analog to a continuum cohesive zone model element - the results from the molecular-dynamics simulation are recast to obtain an average continuum traction-displacement relationship to represent cohesive zone interaction along a characteristic length of the grain boundary interface for the cases of ductile and brittle decohesion. Keywords: Crack-tip plasticity; Cohesive zone model; Grain boundary decohesion; Intergranular fracture; Molecular-dynamics simulation

Anomalous transport in fracture networks: field scale experiments and modelling

NASA Astrophysics Data System (ADS)

Kang, P. K.; Le Borgne, T.; Bour, O.; Dentz, M.; Juanes, R.

2012-12-01

fracture on the tailing behavior: where we inject makes the difference in the tailing. Blue line is a BTC with injection into a slow velocity zone under convergent flow configuration. The late-time tailing observed for the convergent test diminished for push-pull experiment performed in the same zone(red line). Black line is a BTC with injection into a high velocity zone under convergent flow configuration. Insets: illustration of convergent and push-pull tracer tests using a double packer system.

Ground Truthing Orbital Clay Mineral Observations with the APXS Onboard Mars Exploration Rover Opportunity

NASA Technical Reports Server (NTRS)

Schroeder, C.; Gellert, R.; VanBommel, S.; Clark, B. C.; Ming, D. W.; Mittlefehldt, D. S.; Yen, A. S.

2016-01-01

NASA's Mars Exploration Rover Opportunity has been exploring approximately 22 km diameter Endeavour crater since 2011. Its rim segments predate the Hesperian-age Burns formation and expose Noachian-age material, which is associated with orbital Fe3+-Mg-rich clay mineral observations [1,2]. Moving to an orders of magnitude smaller instrumental field of view on the ground, the clay minerals were challenging to pinpoint on the basis of geochemical data because they appear to be the result of near-isochemical weathering of the local bedrock [3,4]. However, the APXS revealed a more complex mineral story as fracture fills and so-called red zones appear to contain more Al-rich clay minerals [5,6], which had not been observed from orbit. These observations are important to constrain clay mineral formation processes. More detail will be added as Opportunity is heading into her 10th extended mission, during which she will investigate Noachian bedrock that predates Endeavour crater, study sedimentary rocks inside Endeavour crater, and explore a fluid-carved gully. ESA's ExoMars rover will land on Noachian-age Oxia Planum where abundant Fe3+-Mg-rich clay minerals have been observed from orbit, but the story will undoubtedly become more complex once seen from the ground.

Percutaneous internal fixation of proximal fifth metatarsal jones fractures (Zones II and III) with Charlotte Carolina screw and bone marrow aspirate concentrate: an outcome study in athletes.

PubMed

Murawski, Christopher D; Kennedy, John G

2011-06-01

Internal fixation is a popular first-line treatment method for proximal fifth metatarsal Jones fractures in athletes; however, nonunions and screw breakage can occur, in part because of nonspecific fixation hardware and poor blood supply. To report the results from 26 patients who underwent percutaneous internal fixation with a specialized screw system of a proximal fifth metatarsal Jones fracture (zones II and III) and bone marrow aspirate concentrate. Case series; Level of evidence, 4. Percutaneous internal fixation for a proximal fifth metatarsal Jones fracture (zones II and III) was performed on 26 athletic patients (mean age, 27.47 years; range, 18-47). All patients were competing at some level of sport and were assessed preoperatively and postoperatively using the Foot and Ankle Outcome Score and SF-12 outcome scores. The mean follow-up time was 20.62 months (range, 12-28). Of the 26 fractures, 17 were traditional zone II Jones fractures, and the remaining 9 were zone III proximal diaphyseal fractures. The mean Foot and Ankle Outcome Score significantly increased, from 51.15 points preoperatively (range, 14-69) to 90.91 at final follow-up (range, 71-100; P < .01). The mean physical component of the SF-12 score significantly improved, from 25.69 points preoperatively (range, 6-39) to 54.62 at final follow-up (range, 32-62; P < .01). The mean mental component of the SF-12 score also significantly improved, from 28.20 points preoperatively (range, 14-45) to 58.41 at final follow-up (range, 36-67; P < .01). The mean time to fracture healing on standard radiographs was 5 weeks after surgery (range, 4-24). Two patients did not return to their previous levels of sporting activity. One patient experienced a delayed union, and 1 healed but later refractured. Percutaneous internal fixation of proximal fifth metatarsal Jones fractures, with a Charlotte Carolina screw and bone marrow aspirate concentrate, provides more predictable results while permitting athletes a

Optimizing the design of vertical seismic profiling (VSP) for imaging fracture zones over hardrock basement geothermal environments

NASA Astrophysics Data System (ADS)

Reiser, Fabienne; Schmelzbach, Cedric; Maurer, Hansruedi; Greenhalgh, Stewart; Hellwig, Olaf

2017-04-01

A primary focus of geothermal seismic imaging is to map dipping faults and fracture zones that control rock permeability and fluid flow. Vertical seismic profiling (VSP) is therefore a most valuable means to image the immediate surroundings of an existing borehole to guide, for example, the placing of new boreholes to optimize production from known faults and fractures. We simulated 2D and 3D acoustic synthetic seismic data and processed it through to pre-stack depth migration to optimize VSP survey layouts for mapping moderately to steeply dipping fracture zones within possible basement geothermal reservoirs. Our VSP survey optimization procedure for sequentially selecting source locations to define the area where source points are best located for optimal imaging makes use of a cross-correlation statistic, by which a subset of migrated shot gathers is compared with a target or reference image from a comprehensive set of source gathers. In geothermal exploration at established sites, it is reasonable to assume that sufficient à priori information is available to construct such a target image. We generally obtained good results with a relatively small number of optimally chosen source positions distributed over an ideal source location area for different fracture zone scenarios (different dips, azimuths, and distances from the surveying borehole). Adding further sources outside the optimal source area did not necessarily improve the results, but rather resulted in image distortions. It was found that fracture zones located at borehole-receiver depths and laterally offset from the borehole by 300 m can be imaged reliably for a range of the different dips, but more source positions and large offsets between sources and the borehole are required for imaging steeply dipping interfaces. When such features cross-cut the borehole, they are particularly difficult to image. For fracture zones with different azimuths, 3D effects are observed. Far offset source positions

Combining steam injection with hydraulic fracturing for the in situ remediation of the unsaturated zone of a fractured soil polluted by jet fuel.

PubMed

Nilsson, Bertel; Tzovolou, Dimitra; Jeczalik, Maciej; Kasela, Tomasz; Slack, William; Klint, Knud E; Haeseler, Frank; Tsakiroglou, Christos D

2011-03-01

A steam injection pilot-scale experiment was performed on the unsaturated zone of a strongly heterogeneous fractured soil contaminated by jet fuel. Before the treatment, the soil was stimulated by creating sub-horizontal sand-filled hydraulic fractures at three depths. The steam was injected through one hydraulic fracture and gas/water/non-aqueous phase liquid (NAPL) was extracted from the remaining fractures by applying a vacuum to extraction wells. The injection strategy was designed to maximize the heat delivery over the entire cell (10 m × 10 m × 5 m). The soil temperature profile, the recovered NAPL, the extracted water, and the concentrations of volatile organic compounds (VOCs) in the gas phase were monitored during the field test. GC-MS chemical analyses of pre- and post-treatment soil samples allowed for the quantitative assessment of the remediation efficiency. The growth of the heat front followed the configuration of hydraulic fractures. The average concentration of total hydrocarbons (g/kg of soil) was reduced by ∼ 43% in the upper target zone (depth = 1.5-3.9 m) and by ∼ 72% over the entire zone (depth = 1.5-5.5 m). The total NAPL mass removal based on gas and liquid stream measurements and the free-NAPL product were almost 30% and 2%, respectively, of those estimated from chemical analyses of pre- and post-treatment soil samples. The dominant mechanisms of soil remediation was the vaporization of jet fuel compounds at temperatures lower than their normal boiling points (steam distillation) enhanced by the ventilation of porous matrix due to the forced convective flow of air. In addition, the significant reduction of the NAPL mass in the less-heated deeper zone may be attributed to the counter-current imbibition of condensed water from natural fractures into the porous matrix and the gravity drainage associated with seasonal fluctuations of the water table. Copyright © 2010 Elsevier Ltd. All rights reserved.

Imaging hydraulic fractures at Median Tectonic Line, Japan using multiply generated and scattered tube waves in a shallow VSP experiment

NASA Astrophysics Data System (ADS)

Minato, Shohei; Ghose, Ranajit; Tsuji, Takeshi; Ikeda, Michiharu; Onishi, Kozo

2016-04-01

Tube waves are low frequency guided waves that propagate along a fluid-filled borehole. The analysis of tube waves is a promising approach to image and characterize hydraulic fractures intersecting a borehole. It exploits tube waves generated by an external seismic wavefield which compresses fractures and injects fluid into the borehole. It also utilizes the attenuation of tube waves due to fluid exchange between the fracture and the borehole, which creates scattered waves (reflection and transmission). Conventional approaches consider tube waves due to a single fracture. However, when the spacing between multiple fractures is short relative to the wavelength of the tube waves, the generated and scattered tube waves interfere with each other, making it difficult to isolate the effect of a single fracture. The analysis of closely spaced fractures is important in highly fractured areas, such as a fault zone. In this study, we explore the possibility of prediction and utilization of generated and scattered tube waves due to multiple fractures. We derive a new integral equation of the full tube wavefield using 1D wavefield representation theory incorporating nonwelded interfaces. We adapt the recent developments in modeling tube wave generation/scattering at a fracture. In these models, a fracture is represented as a parallel wall or a thin poloelastic layer. This allowed us to consider the effects of a dynamic fracture aperture with fracture compliances and the permeability. The representation also leads to a new imaging method for the hydraulic fractures, using multiply-generated and scattered tube waves. This is achieved by applying an inverse operator to the observed tube waves, which focuses the tube waves to the depth where they are generated and/or scattered. The inverse operator is constructed by a tube wave Green's function with a known propagation velocity. The Median Tectonic Line (MTL) is the most significant fault in Japan, extending NE-SW for over 1000 km

Deformation mechanisms in experimentally deformed Boom Clay

NASA Astrophysics Data System (ADS)

Desbois, Guillaume; Schuck, Bernhard; Urai, Janos

2016-04-01

Bulk mechanical and transport properties of reference claystones for deep disposal of radioactive waste have been investigated since many years but little is known about microscale deformation mechanisms because accessing the relevant microstructure in these soft, very fine-grained, low permeable and low porous materials remains difficult. Recent development of ion beam polishing methods to prepare high quality damage free surfaces for scanning electron microscope (SEM) is opening new fields of microstructural investigation in claystones towards a better understanding of the deformation behavior transitional between rocks and soils. We present results of Boom Clay deformed in a triaxial cell in a consolidated - undrained test at a confining pressure of 0.375 MPa (i.e. close to natural value), with σ1 perpendicular to the bedding. Experiments stopped at 20 % strain. As a first approximation, the plasticity of the sample can be described by a Mohr-Coulomb type failure envelope with a coefficient of cohesion C = 0.117 MPa and an internal friction angle ϕ = 18.7°. After deformation test, the bulk sample shows a shear zone at an angle of about 35° from the vertical with an offset of about 5 mm. We used the "Lamipeel" method that allows producing a permanent absolutely plane and large size etched micro relief-replica in order to localize and to document the shear zone at the scale of the deformed core. High-resolution imaging of microstructures was mostly done by using the BIB-SEM method on key-regions identified after the "Lamipeel" method. Detailed BIB-SEM investigations of shear zones show the following: the boundaries between the shear zone and the host rock are sharp, clay aggregates and clastic grains are strongly reoriented parallel to the shear direction, and the porosity is significantly reduced in the shear zone and the grain size is smaller in the shear zone than in the host rock but there is no evidence for broken grains. Comparison of microstructures

Paleocurrents in the Charlie-Gibbs Fracture Zone during the Late Quaternary

NASA Astrophysics Data System (ADS)

Bashirova, L. D.; Dorokhova, E.; Sivkov, V.; Andersen, N.; Kuleshova, L. A.; Matul, A.

2017-12-01

The sedimentary processes prevailing in the Charlie-Gibbs Fracture Zone (CGFZ) are gravity flows. They rework pelagic sediments and contourites, and hereby mask the paleoceanographic information partly. The aim of this work is to study sediments of the AMK-4515 core taken in eastern part of the CGFZ. The sediment core AMK-4515 (52°03.14" N, 29°00.12" W; 370 cm length, water depth 3590 m) is located in the southern valley of the CGFZ. This natural deep corridor is influenced by both the westward Iceland-Scotland Overflow Water and underlying counterflow from the Newfoundland Basin. An alternation of the calcareous silty clays and hemipelagic clayey muds in the studied section indicates similarity between our core and long cores taking from CGFZ. A sharp facies shift was found at 80 cm depth in the investigated core. Only the upper section (0-80 cm) is valid for paleoreconstruction. Planktonic foraminiferal distribution and sea-surface temperature (SST) derived from these allow for tracing the PF and NAC latitudinal migrations during investigated period. So-called sortable silt mean size (SS) was used as proxy for reconstruction of bottom current intensity. The age model is based on δ18O and AMS 14C dating, as well as ice-rafted debris (IRD) counts and CaCO3 content. Stratigraphic subdivision of this section allows to allocate 2 marine isotope stages (MIS) covering the last 27 ka. We refer sediments below this level (80-370 cm) to upper part of turbidite, which was formed as a result of massive slide in the southern channel of the CGFZ. Sandy particles were deposited first, underlying silts and clays. This short-term event occurred so quickly that pelagic sedimentation played no role and was not reflected in the grain size distributions. There is evidence for the significant role of gravity flows in sedimentation in the southern channel of the CGFZ. According to our data, the massive sediment slide occurred in the CGFZ about 27 ka. The authors are grateful to RSF

Cyclical shear fracture and viscous flow during transitional ductile-brittle deformation in the Saddlebag Lake Shear Zone, California

NASA Astrophysics Data System (ADS)

Compton, Katharine E.; Kirkpatrick, James D.; Holk, Gregory J.

2017-06-01

Exhumed shear zones often contain folded and/or dynamically recrystallized structures, such as veins and pseudotachylytes, which record broadly contemporaneous brittle and ductile deformation. Here, we investigate veins within the Saddlebag Lake Shear Zone, central Sierra Nevada, California, to constrain the conditions and processes that caused fractures to form during ductile deformation. The shear zone mylonites contain compositional banding at centimeter- to meter- scales, and a ubiquitous, grain-scale, continuous- to spaced-foliation defined by aligned muscovite and chlorite grains. Veins of multiple compositions formed in two predominant sets: sub-parallel to the foliation and at high angle to the foliation. Some foliation sub-parallel veins show apparent shear offset consistent with the overall kinematics of the shear zone. These veins are folded with the foliation and are commonly boudinaged, showing they were rigid inclusions after formation. Quartz microstructures and fluid inclusion thermobarometry measurements indicate the veins formed by fracture at temperatures between 400-600 °C. Quartz, feldspar and tourmaline δ18O values (+ 2.5 to + 16.5) suggest extended fluid-rock interaction that involved magmatic, metamorphic, and meteoric-hydrothermal fluids. The orientation and spatial distribution of the veins shows that shear fractures formed along mechanically weak foliation planes. We infer fracture was promoted by perturbations to the strain rate and/or pore pressure during frictional-viscous deformation in a low effective stress environment. Evidence for repeated fracture and subsequent flow suggest both the stress and pore pressure varied, and that the tendency to fracture was controlled by the rates of pore pressure recovery, facilitated by fracture cementation. The tectonic setting and inferred phenomenological behavior were similar to intra-continental transform faults that host triggered tectonic tremor, suggesting the mechanisms that caused

Bottom-water observations in the Vema fracture zone

NASA Astrophysics Data System (ADS)

Eittreim, Stephen L.; Biscaye, Pierre E.; Jacobs, Stanley S.

1983-03-01

The Vema fracture zone trough, at 11°N between 41° and 45°E, is open to the west at the 5000-m level but is silled at the 4650-m level on the east where it intersects the axis of the Mid-Atlantic Ridge. The trough is filled with Antarctic Bottom Water (AABW) with a potential temperature of 1.32°C and salinity of 34.82 ppt. The bottom water is thermally well mixed in a nearly homogeneous layer about 700 m thick. The great thickness of this bottom layer, as compared with the bottom-water structure of the western Atlantic basin, may result from enhanced mixing induced by topographic constriction at the west end of the fracture zone trough. A benthic thermocline, with potential temperature gradients of about 1.2 mdeg m-1, is associated with an abrupt increase in turbidity with depth at about 1200 m above bottom. A transitional layer of more moderate temperature gradients, about 0.4 mdeg m-1, lies between the benthic thermocline above and the AABW below. The AABW layer whose depth-averaged suspended paniculate concentrations range from 8 to 19 μg L-1, is consistently higher in turbidity than the overlying waters. At the eastern end of the trough, 140 m below sill depth, very low northeastward current velocities, with maximums of 3 cm s-1, were recorded for an 11-day period.

Real-time 4D electrical resistivity imaging of tracer transport within an energically stimulated fracture zone

NASA Astrophysics Data System (ADS)

Johnson, T. C.

2016-12-01

Hydraulic fracture stimulation is used extensively in the subsurface energy sector to improve access between energy bearing formations and production boreholes. However, large uncertainties exist concerning the location and extent of stimulated fractures, and concerning the behavior of flow within those fractures. This uncertainty often results in significant risks, including induced seismicity and contamination of potable groundwater aquifers. Time-lapse electrical resistivity tomography (ERT) is a proven method of imaging fluid flow within fracture networks, by imaging the change in bulk conductivity induced by the presence of an electrically anomalous tracer within the fracture. In this work we demonstrate characterization and flow monitoring of a stimulated fracture using real-time four-dimensional ERT imaging within an unsaturated rhyolite formation. After stimulation, a conductive tracer was injected into the fracture zone. ERT survey data were continuously and autonomously collected, pre-processed on site, submitted to an off-site high performance computing system for inversion, and returned to the field for inspection. Surveys were collected at approximately 12 minute intervals. Data transmission and inversion required approximately 2 minutes per survey. The time-lapse imaging results show the dominant flow-paths within the stimulated fracture zone, thereby revealing the location and extent of the fracture, and the behavior of tracer flow within the fracture. Ultimately real-time imaging will enable site operators to better understand stimulation operations, and control post-stimulation reservoir operations for optimal performance and environmental protection.

49 CFR 71.7 - Boundary line between central and mountain zones.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 49 Transportation 1 2013-10-01 2013-10-01 false Boundary line between central and mountain zones... BOUNDARIES § 71.7 Boundary line between central and mountain zones. (a) Montana-North Dakota. Beginning at... south along the range line between Rs. 30 and 31 W. to the southwest corner of sec. 19, T. 33 N., R. 30...

49 CFR 71.7 - Boundary line between central and mountain zones.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 49 Transportation 1 2012-10-01 2012-10-01 false Boundary line between central and mountain zones... BOUNDARIES § 71.7 Boundary line between central and mountain zones. (a) Montana-North Dakota. Beginning at... south along the range line between Rs. 30 and 31 W. to the southwest corner of sec. 19, T. 33 N., R. 30...

49 CFR 71.7 - Boundary line between central and mountain zones.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 49 Transportation 1 2014-10-01 2014-10-01 false Boundary line between central and mountain zones... BOUNDARIES § 71.7 Boundary line between central and mountain zones. (a) Montana-North Dakota. Beginning at... south along the range line between Rs. 30 and 31 W. to the southwest corner of sec. 19, T. 33 N., R. 30...

Fracture properties from tight reservoir outcrop analogues with application to geothermal exploration

NASA Astrophysics Data System (ADS)

Philipp, Sonja L.; Reyer, Dorothea; Afsar, Filiz; Bauer, Johanna F.; Meier, Silke; Reinecker, John

2015-04-01

areas of palaeo¬geothermal fields in the Bristol Channel (1), all mineral veins, most of which are extension fractures, are of calcite. They are clearly associated with the faults and indicate that geothermal water was transported along the then-active faults into the host rocks with evidence of injection as hydrofractures. Layers with contrasting mechanical properties (in particular, stiffnesses), however, acted as stress barriers and lead to fracture arrest. Along some faults, veins propagated through the barriers along faults to shallower levels. In the Northwest German Basin (2) there are pronounced differences between normal-fault zones in carbonate and clastic rocks. Only in carbonate rocks clear damage zones occur, characterized by increased fracture frequencies and high amounts of fractures with large apertures. On the Upper Rhine Graben shoulders (3) damage zones in Triassic Muschelkalk limestones are well developed; fault cores are narrow and comprise breccia, clay smear, host rock lenses and mineralization. A large fault zone in Triassic Bunter sandstone shows a clearly developed fault core with fault gouge, slip zones, deformation bands and host rock lenses, a transition zone with mostly disturbed layering and highest fracture frequency, and a damage zone. The latter damage zone is compared to the damage zone of a large Bunter sandstone fault zone currently explored for geothermal energy production. The numerical models focus on stress field development, fracture propagation and associated permeability changes. These studies contribute to the understanding of the hydromechanical behaviour of fault zones and related fluid transport in fractured reservoirs complementing predictions based on geophysical measurements. Eventually we aim at classifying and quantifying fracture system properties in fault zones to improve exploration and exploitation of geothermal reservoirs. Acknowledgements The authors appreciate the support of 'Niedersächsisches Ministerium f

Plume persistence caused by back diffusion from thin clay layers in a sand aquifer following TCE source-zone hydraulic isolation.

PubMed

Parker, Beth L; Chapman, Steven W; Guilbeault, Martin A

2008-11-14

This paper concludes that back diffusion from one or a few thin clayey beds in a sand aquifer can cause contaminant persistence above MCLs in a sand aquifer long after the source zone initially causing the plume is isolated or removed. This conclusion is based on an intensive case study of a TCE contaminated site in Florida, with the processes evaluated using numerical modeling. At this site, the TCE DNAPL zone formed decades ago, and was hydraulically isolated by means of an innovative system performing groundwater extraction, treatment and re-injection. Treated water is re-injected in a row of injection wells situated a short distance downgradient of the extraction wells, creating a clean-water displacement front to efficiently flush the downgradient plume. This scheme avoids the creation of stagnation zones typical of most groundwater pump-and-treat systems, thereby minimizing the time for aquifer flushing and therefore downgradient cleanup. The system began operation in August 2002 and although the performance monitoring shows substantial declines in concentrations, detectable levels of TCE and degradation products persist downgradient of the re-injection wells, long after the TCE should have disappeared based on calculations assuming a nearly homogenous sand aquifer. Three hypotheses were assessed for this plume persistence: 1) incomplete source-zone capture, 2) DNAPL occurrence downgradient of the re-injection wells, and 3) back diffusion from one or more thin clay beds in the aquifer. After careful consideration, the first two hypotheses were eliminated, leaving back diffusion as the only plausible hypothesis, supported by detailed measurements of VOC concentrations within and near the clay beds and also by numerical model simulations that closely represent the field site hydrogeologic conditions. The model was also used to simulate a more generalized, hypothetical situation where more thin clayey beds occur in a sand aquifer with an underlying aquitard

Structure of a seismogenic fault zone in dolostones: the Foiana Line (Italian Southern Alps)

NASA Astrophysics Data System (ADS)

Di Toro, G.; Fondriest, M.; Smith, S. A.; Aretusini, S.

2012-12-01

Fault zones in carbonate rocks (limestones and dolostones) represent significant upper crustal seismogenic sources in several areas worldwide (e.g. L'Aquila 2009 Mw = 6.3 in central Italy). Here we describe an exhumed example of a regionally-significant fault zone cutting dolostones. The Foiana Line (FL) is a major NNE-SSW-trending sinistral transpressive fault cutting sedimentary Triassic dolostones in the Italian Southern Alps. The FL has a cumulative vertical throw of 1.5-2 km that reduces toward its southern termination. The fault zone is 50-300 m wide and is exposed for ~ 10 km along strike within several outcrops exhumed from increasing depths from the south (1 km) to the north (2.5 km). The southern portion of the FL consists of heavily fractured (shattered) dolostones, with particles of a few millimeters in size (exposed in badlands topography over an area of 6 km2), cut by a dense network of 1-20 m long mirror-like fault surfaces with dispersed attitudes. The mirror-like faults have mainly dip-slip reverse kinematics and displacements ranging between 0.04 m and 0.5 m. The northern portion of the FL consists of sub-parallel fault strands spaced 2-5 m apart, surrounded by 2-3 m thick bands of shattered dolostones. The fault strands are characterized by smooth to mirror-like sub-vertical slip surfaces with dominant strike-slip kinematics. Overall, deformation is more localized moving from South to North along the FL. Mirror-like fault surfaces similar to those found in the FL were produced in friction experiments at the deformation conditions expected during seismic slip along the FL (Fondriest et al., this meeting). Scanning Electron Microscope investigations of the natural shattered dolostones beneath the mirror-like fault surfaces show: 1) lack of significant shear strain (even at a few micrometers from the slip surface), 2) pervasive extensional fracturing down to the micrometer scale, 3) exploded clasts with radial fractures, and 4) chains of split

Static versus dynamic fracturing in shallow carbonate fault zones

NASA Astrophysics Data System (ADS)

Fondriest, M.; Doan, M. L.; Aben, F. M.; Fusseis, F.; Mitchell, T. M.; Di Toro, G.

2015-12-01

Moderate to large earthquakes often nucleate within and propagate through carbonates in the shallow crust, therefore several field and experimental studies were recently aimed to constrain earthquake-related deformation processes within carbonate fault rocks. In particular, the occurrence of thick belts (10-100s m) of low-strain fault-related breccias (average size of rock fragments >1 cm), which is relatively common within carbonate damage zones, was generally interpreted as resulting from the quasi-static growth of fault zones rather than from the cumulative effect of multiple earthquake ruptures. Here we report the occurrence of up to hundreds of meters thick belts of intensely fragmented dolostones along the major transpressive Foiana Fault Zone (Italian Southern Alps) which was exhumed from < 2 km depth. Such dolostones are reduced into fragments ranging from few centimeters down to few millimeters in size with ultrafine-grained layers in proximity to the principal slip zones. Preservation of the original bedding indicates a lack of significant shear strain in the fragmented dolostones which seem to have been shattered in situ. To investigate the origin of the in-situ shattered rocks, the host dolostones were deformed in uniaxial compression both under quasi-static loading (strain rate ~10-3 s-1) and dynamic loading (strain rate >50 s-1). Dolostones deformed up to failure under low-strain rate were affected by single to multiple discrete (i.e. not interconnected) extensional fractures sub-parallel to the loading direction. Dolostones deformed under high-strain rate were shattered above a strain rate threshold of ~200 s-1(strain >1.2%) while they were split in few fragments or were macroscopically intact for lower strain rates. Experimentally shattered dolostones were reduced into a non-cohesive material with most rock fragments a few millimeters in size and elongated parallel to the loading direction. Fracture networks were investigated by X

Near-surface clay authigenesis in exhumed fault rock of the Alpine Fault Zone (New Zealand); O-H-Ar isotopic, XRD and chemical analysis of illite and chlorite

NASA Astrophysics Data System (ADS)

Boles, Austin; Mulch, Andreas; van der Pluijm, Ben

2018-06-01

Exhumed fault rock of the central Alpine Fault Zone (South Island, New Zealand) shows extensive clay mineralization, and it has been the focus of recent research that aims to describe the evolution and frictional behavior of the fault. Using Quantitative X-ray powder diffraction, 40Ar/39Ar geochronology, hydrogen isotope (δD) geochemistry, and electron microbeam analysis, we constrain the thermal and fluid conditions of deformation that produced two predominant clay phases ubiquitous to the exposed fault damage zone, illite and chlorite. Illite polytype analysis indicates that most end-member illite and chlorite material formed in equilibrium with meteoric fluid (δD = -55 to -75‰), but two locations preserve a metamorphic origin of chlorite (δD = -36 to -45‰). Chlorite chemical geothermometry constrains crystal growth to T = 210-296 °C. Isotopic analysis also constrains illite growth to T < 100 °C, consistent with the mineralogy, with Ar ages <0.5 Ma. High geothermal gradients in the study area promoted widespread, near-surface mineralization, and limited the window of clay authigenesis in the Alpine Fault Zone to <5 km for chlorite and <2 km for illite. This implies a significant contrast between fault rock exposed at the surface and that at depth, and informs discussions about fault strength, clays and frictional behavior.

Characterizing Fracturing of Clay-Rich Lower Watrous Rock: From Laboratory Experiments to Nonlocal Damage-Based Simulations

NASA Astrophysics Data System (ADS)

Guy, N.; Seyedi, D. M.; Hild, F.

2018-06-01

The work presented herein aims at characterizing and modeling fracturing (i.e., initiation and propagation of cracks) in a clay-rich rock. The analysis is based on two experimental campaigns. The first one relies on a probabilistic analysis of crack initiation considering Brazilian and three-point flexural tests. The second one involves digital image correlation to characterize crack propagation. A nonlocal damage model based on stress regularization is used for the simulations. Two thresholds both based on regularized stress fields are considered. They are determined from the experimental campaigns performed on Lower Watrous rock. The results obtained with the proposed approach are favorably compared with the experimental results.

Feasibility of Plasma Treated Clay in Clay/Polymer Nanocomposites Powders for use Laser Sintering (LS)

NASA Astrophysics Data System (ADS)

Almansoori, Alaa; Seabright, Ryan; Majewski, C.; Rodenburg, C.

2017-05-01

The addition of small quantities of nano-clay to nylon is known to improve mechanical properties of the resulting nano-composite. However, achieving a uniform dispersion and distribution of the clay within the base polymer can prove difficult. A demonstration of the fabrication and characterization of plasma-treated organoclay/Nylon12 nanocomposite was carried out with the aim of achieving better dispersion of clay platelets on the Nylon12 particle surface. Air-plasma etching was used to enhance the compatibility between clays and polymers to ensure a uniform clay dispersion in composite powders. Downward heat sintering (DHS) in a hot press is used to process neat and composite powders into tensile and XRD specimens. Morphological studies using Low Voltage Scanning Electron Microscopy (LV-SEM) were undertaken to characterize the fracture surfaces and clay dispersion in powders and final composite specimens. Thermogravimetric analysis (TGA) testing performed that the etched clay (EC) is more stable than the nonetched clay (NEC), even at higher temperatures. The influence of the clay ratio and the clay plasma treatment process on the mechanical properties of the nanocomposites was studied by tensile testing. The composite fabricated from (3% EC/N12) powder showed ~19 % improvement in elastic modulus while the composite made from (3% NEC/N12) powder was improved by only 14%). Most notably however is that the variation between tests is strongly reduced when etch clay is used in the composite. We attribute this to a more uniform distribution and better dispersion of the plasma treated clay within polymer powders and ultimately the composite.

Fracture overprinting history using Markov chain analysis: Windsor-Kennetcook subbasin, Maritimes Basin, Canada

NASA Astrophysics Data System (ADS)

Snyder, Morgan E.; Waldron, John W. F.

2018-03-01

The deformation history of the Upper Paleozoic Maritimes Basin, Atlantic Canada, can be partially unraveled by examining fractures (joints, veins, and faults) that are well exposed on the shorelines of the macrotidal Bay of Fundy, in subsurface core, and on image logs. Data were collected from coastal outcrops and well core across the Windsor-Kennetcook subbasin, a subbasin in the Maritimes Basin, using the circular scan-line and vertical scan-line methods in outcrop, and FMI Image log analysis of core. We use cross-cutting and abutting relationships between fractures to understand relative timing of fracturing, followed by a statistical test (Markov chain analysis) to separate groups of fractures. This analysis, previously used in sedimentology, was modified to statistically test the randomness of fracture timing relationships. The results of the Markov chain analysis suggest that fracture initiation can be attributed to movement along the Minas Fault Zone, an E-W fault system that bounds the Windsor-Kennetcook subbasin to the north. Four sets of fractures are related to dextral strike slip along the Minas Fault Zone in the late Paleozoic, and four sets are related to sinistral reactivation of the same boundary in the Mesozoic.

Impact of Vishnu Fracture Zone on Tectono-Stratigraphy of Kerala Deepwater Basin, India

NASA Astrophysics Data System (ADS)

Bastia, R.; Krishna, K. S.; Nathaniel, D. M.; Tenepalli, S.

2008-12-01

Integration of regional seismic data extending from coast to deep water with the gravity-magnetics reveals the expression and evolution of ridge systems and fracture zones in Indian Ocean. Kerala deepwater basin, situated in the south-western tip of India, is bounded by two prominent north-south oriented ocean fracture zones viz., Vishnu (west) and Indrani (east) of the Indian Ocean. Vishnu Fracture Zone (VFZ), which extends from the Kerala shelf southward to the Carlsberg-Ridge, over a length of more than 2500 km, has a strong bearing on the sedimentation as well as structural fabric of the basin. VFZ is identified as the transform plate margin formed during Late-Cretaceous-Tertiary separation of Seychelles from India. Represented by a highly deformed structural fabric, VFZ forms an abrupt boundary between ocean floors of about 65 MY in the west and 140 MY in the east, implying a great scope for sedimentary pile on this very older ocean floor. Armed with this premise of an older sedimentary pile towards east of VFZ, congenial for petroleum hunt, the implemented modern long offset seismic program with an objective to enhance sub-basalt (Deccan) imagery, gravity-magnetic modelling and plate-tectonic reconstructions unraveled huge Mesozoic Basin, unheard earlier. Multi-episodic rifting in western continental margin of India starting during Mid Jurassic Karoo rift along the western Madagascar, Kerala deepwater basin, and western Antarctica and conjugate margins of Africa forms the main corridor for sedimentation. Subsequent Late Cretaceous dextral oblique extension of Madagascar rift reactivated pre-existing structural framework creating major accommodation zones along the southern tip of India. Followed by separation of Seychelles during KT boundary led to the formation of VFZ (an oceanic fracture zone) forming a transform boundary between newly formed Tertiary oceanic crust to the west and older basin to the east. The pulses of right-lateral movement were associated

Hydrogeological impact of fault zones on a fractured carbonate aquifer, Semmering (Austria)

NASA Astrophysics Data System (ADS)

Mayaud, Cyril; Winkler, Gerfried; Reichl, Peter

2015-04-01

Fault zones are the result of tectonic processes and are geometrical features frequently encountered in carbonate aquifer systems. They can hamper the fluid migration (hydrogeological barriers), propagate the movement of fluid (draining conduits) or be a combination of both processes. Numerical modelling of fractured carbonate aquifer systems is strongly bound on the knowledge of a profound conceptual model including geological and tectonic settings such as fault zones. In further consequence, numerical models can be used to evaluate the conceptual model and its introduced approximations. The study was conducted in a fractured carbonate aquifer built up by permomesozoic dolo/limestones of the Semmering-Wechsel complex in the Eastern Alps (Austria). The aquifer has an assumed thickness of about 200 m and dips to the north. It is covered by a thin quartzite layer and a very low permeable layer of quartz-phyllite having a thickness of up to several hundred meters. The carbonate layer crops out only in the southern part of the investigation area, where it receives autogenic recharge. The geological complexity affects some uncertainties related to the extent of the model area, which was determined to be about 15 km². Three vertical fault zones cross the area approximately in a N-S direction. The test site includes an infrastructural pilot tunnel gallery of 4.3 km length with two pumping stations, respectively active since August 1997 and June 1998. The total pumping rate is about 90 l/s and the drawdown data were analysed analytically, providing a hydraulic conductivity of about 5E-05 m/s for the carbonate layer. About 120 m drawdown between the initial situation and situation with pumping is reported by piezometers. This led to the drying up of one spring located at the southern border of the carbonates. A continuum approach using MODFLOW-2005 was applied to reproduce numerically the observed aquifer behaviour and investigate the impact of the three fault zones. First

49 CFR 71.5 - Boundary line between eastern and central zones.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 1 2010-10-01 2010-10-01 false Boundary line between eastern and central zones... BOUNDARIES § 71.5 Boundary line between eastern and central zones. (a) Minnesota-Michigan-Wisconsin. From the junction of the western boundary of the State of Michigan with the boundary between the United States and...

Composition of abyssal macrofauna along the Vema Fracture Zone and the hadal Puerto Rico Trench, northern tropical Atlantic

NASA Astrophysics Data System (ADS)

Brandt, A.; Frutos, I.; Bober, S.; Brix, S.; Brenke, N.; Guggolz, T.; Heitland, N.; Malyutina, M.; Minzlaff, U.; Riehl, T.; Schwabe, E.; Zinkann, A.-C.; Linse, K.

2018-02-01

We analyzed composition and variations in benthic macrofaunal communities along a transect of the entire length of the Vema-Fracture Zone on board of RV Sonne (SO-237) between December 2014 and January 2015 in order to test whether the Mid-Atlantic Ridge serves as a barrier limiting benthic taxon distribution in the abyssal basins on both sides of the ridge or whether the fracture zone permits the migration of species between the western and eastern abyssal Atlantic basins. The Puerto Rico Trench, much deeper than the surrounding abyssal West Atlantic, was sampled to determine whether the biodiversity of its hadal macrofauna differs from that of the abyssal Atlantic. The composition of the macrofauna from the epibenthic sledge catches yielded a total of 21,332 invertebrates. Crustacea occurred most frequently (59%) with 12,538 individuals followed by Annelida (mostly Polychaeta) (26%) with 5491 individuals, Mollusca (7%) with 1458 individuals, Echinodermata (4%) with 778 individuals, Nematoda (2%) with 502 individuals and Chaetognatha (1%) with 152 and Porifera (1%) with 131 individuals. All other taxa occurred with overall less than ten individuals (Hemichordata, Phoronida, Priapulida, Brachiopoda, invertebrate Chordata, Echiurida, Foraminifera (here refereed to macrofaunal Komokiacea only), Chelicerata, Platyhelminthes). Within the Crustacea, Peracarida (62.6%) with 7848 individuals and Copepoda (36.1%) with 44,526 individuals were the most abundant taxa. Along the abyssal Vema-Fracture Zone macrofaunal abundances (ind./1000 m2) were generally higher on the eastern side, while the highest normalized abundance value was reported in the Puerto Rico Trench at abyssal station 14-1 2313 individuals/1000 m2. The lowest abundance was reported at station 11-4 with 120 ind./1000 m2 located at the western side of the Vema-Fracture Zone. The number of major macrofaunal taxa (phylum, class) ranged between five (stations 12-5, 13-4 and 13-5 at hadal depths in the Puerto Rico

Fracturation Pattern in the Limestone Loyaute Islands and its Relation to the Neighbouring Vanuatu Subduction Zone (SW PAcific)

NASA Astrophysics Data System (ADS)

Bogdanov, I.; Genthon, P.; Thovert, J.; Adler, P. M.

2006-12-01

The Loyauté Islands are a series of limestone karstified islands that are currently uplifted and deformed on the elastic bulge of the Australian plate before its subduction at the Vanuatu Trench (SW Pacific). As part of the SAGE program of the New Caledonian Province des Iles, they have been extensively surveyed for geology and hydrogeology. As part of this project, a map of fracturation deduced from aerial photos, and from SPOT4 and ENVISAT satellite data has been produced and a field trip allowed to verify that the main fracture orientations were also present on the most recent terranes bordering the islands. Since their formation during the Miocene, these islands are in a tectonically stable area. Thus, they provide a unique opportunity to study their fracture distribution in relation with their recent tectonic context. We will present the results of a statistical analysis of fracture distribution both in number and in fracture length and an attempt to model the fracture orientations as resulting from the elastic deformation of the Australian lithosphere before its subduction. Three main fracture families have been determined for the three island, with very few differences if fracture number of fracture length statistic is considered. These families are N62.5, N107.5, and N152.5 for Lifou, which is the largest and central island, which are further termed as F1, F2, F3. F2 is at least 5 times more important than F1 and F3, which are 45° apart on both sides of F2. The orientation of families F1-F3 are N 65, N110, and N155 in Maré, which located less than 100 km apart from the subduction zone, and N60, N105, and N150 in Ouvéa , which is the most distant island from the subduction and is only uplifted in its NorthEastern part. The main family F2 does not correspond either to the subduction zone orientation (N150) nor to that of the Loyauté ridge (N135) on which the three islands are located. Thus, the fracture pattern of the three island cannot be explained by

Numerical modeling of fracking fluid migration through fault zones and fractures in the North German Basin

NASA Astrophysics Data System (ADS)

Pfunt, Helena; Houben, Georg; Himmelsbach, Thomas

2016-09-01

Gas production from shale formations by hydraulic fracturing has raised concerns about the effects on the quality of fresh groundwater. The migration of injected fracking fluids towards the surface was investigated in the North German Basin, based on the known standard lithology. This included cases with natural preferential pathways such as permeable fault zones and fracture networks. Conservative assumptions were applied in the simulation of flow and mass transport triggered by a high pressure boundary of up to 50 MPa excess pressure. The results show no significant fluid migration for a case with undisturbed cap rocks and a maximum of 41 m vertical transport within a permeable fault zone during the pressurization. Open fractures, if present, strongly control the flow field and migration; here vertical transport of fracking fluids reaches up to 200 m during hydraulic fracturing simulation. Long-term transport of the injected water was simulated for 300 years. The fracking fluid rises vertically within the fault zone up to 485 m due to buoyancy. Progressively, it is transported horizontally into sandstone layers, following the natural groundwater flow direction. In the long-term, the injected fluids are diluted to minor concentrations. Despite the presence of permeable pathways, the injected fracking fluids in the reported model did not reach near-surface aquifers, either during the hydraulic fracturing or in the long term. Therefore, the probability of impacts on shallow groundwater by the rise of fracking fluids from a deep shale-gas formation through the geological underground to the surface is small.

Degradation of Nylon-6/Clay Nanocomposites in NO(x)

NASA Astrophysics Data System (ADS)

Shelley, J. S.; Devries, K. L.

2000-04-01

Nylon-6 is an important engineering polymer that, in its fully spherulitic (bulk) form, has many applications in gears, rollers, and other long life cycle components. In 1993, Toyota commercialized a nylon-6/clay nanocomposite out of which it produced the timing belt cover for the 1993 Camry. Although these hybrid nanocomposites show significant improvements in their mechanical response characteristics, including yield strength and heat distortion temperature, little is known about the degradation of these properties due to environmental pollutants like NOx. Nylon-6 fibers are severely degraded by interaction with NOx and other pollutants, showing a strong synergism between applied load and environmental degradation. While the nanocomposites show a significant reduction in permeability of gases and water due to the incorporation of lamellar clay, their susceptibility to non-diffusional mechano-chemical degradation is unknown. The fracture toughness of these nylon-6/day nanocomposites increases, not as a function of clay content, but as a function of the volume of nylon-6 polymer chains influenced by the clay lamellar surfaces. Both the clay and the constrained volume offer the nanocomposites some protection from the deleterious effects of NOx. The time-to-failure at a given stress intensity factor as a function of clay content and constrained volume will be discussed along with fracture toughness of the materials.

Experimental determination of sorption in fractured flow systems

NASA Astrophysics Data System (ADS)

Zimmerman, Mitchell D.; Bennett, Philip C.; Sharp, John M.; Choi, Wan-Joo

2002-09-01

Fracture "skins" are alteration zones on fracture surfaces created by a variety of biological, chemical, and physical processes. Skins increase surface area, where sorption occurs, compared to the unaltered rock matrix. This study examines the sorption of organic solutes on altered fracture surfaces in an experimental fracture-flow apparatus. Fracture skins containing abundant metal oxides, clays, and organic material from the Breathitt Formation (Kentucky, USA) were collected in a manner such that skin surface integrity was maintained. The samples were reassembled in the lab in a flow-through apparatus that simulated ˜2.7 m of a linear fracture "conduit." A dual-tracer injection scheme was utilized with the sorbing or reactive tracer compared to a non-reactive tracer (chloride) injected simultaneously. Sorption was assessed from the ratio of the first temporal moments of the breakthrough curves and from the loss of reactive tracer mass and evaluated as a function of flow velocity and solute type. The breakthrough curves suggest dual-flow regimes in the fracture with both sorbing and non-sorbing flow fields. Significant sorption occurs for the reactive components, and sorption increased with decreasing flow rate and decreasing compound solubility. Based on moment analysis, however, there was little retardation of the center of solute mass. These data suggest that non-equilibrium sorption processes dominate and that slow desorption and boundary layer diffusion cause extensive tailing in the breakthrough curves.

Toughness-Dominated Regime of Hydraulic Fracturing in Cohesionless Materials

NASA Astrophysics Data System (ADS)

Germanovich, L. N.; Hurt, R. S.; Ayoub, J.; Norman, W. D.

2011-12-01

This work examines the mechanisms of hydraulic fracturing in cohesionless particulate materials with geotechnical, geological, and petroleum applications. For this purpose, experimental techniques have been developed, and used to quantify the initiation and propagation of hydraulic fractures in saturated particulate materials. The fracturing liquid is injected into particulate materials, which are practically cohesionless. The liquid flow is localized in thin self-propagating crack-like conduits. By analogy we call them 'cracks' or 'hydraulic fractures.' When a fracture propagates in a solid, new surfaces are created by breaking material bonds. Consequently, the material is in tension at the fracture tip. Because the particulate material is already 'fractured,' no new surface is created and no fracturing process per se is involved. Therefore, the conventional fracture mechanics principles cannot be directly applied. Based on the laboratory observations, performed on three particulate materials (Georgia Red Clay, silica flour, and fine sand, and their mixtures), this work offers physical concepts to explain the observed phenomena. The goal is to determine the controlling parameters of fracture behavior and to quantify their effects. An important conclusion of our work is that all parts of the cohesionless particulate material (including the tip zone of hydraulic fracture) are likely to be in compression. The compressive stress state is an important characteristic of hydraulic fracturing in particulate materials with low, or no, cohesion (such as were used in our experiments). At present, two kinematic mechanisms of fracture propagation, consistent with the compressive stress regime, can be offered. The first mechanism is based on shear bands propagating ahead of the tip of an open fracture. The second is based on the tensile strain ahead of the fracture tip and reduction of the effective stresses to zero within the leak-off zone. Scaling indicates that in our

49 CFR 71.7 - Boundary line between central and mountain zones.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 1 2010-10-01 2010-10-01 false Boundary line between central and mountain zones. 71.7 Section 71.7 Transportation Office of the Secretary of Transportation STANDARD TIME ZONE... mountain standard time zone, except Murdo, S. Dak., which is in the central standard time zone. [Amdt. 71...

Fault-related clay authigenesis along the Moab Fault: Implications for calculations of fault rock composition and mechanical and hydrologic fault zone properties

USGS Publications Warehouse

Solum, J.G.; Davatzes, N.C.; Lockner, D.A.

2010-01-01

The presence of clays in fault rocks influences both the mechanical and hydrologic properties of clay-bearing faults, and therefore it is critical to understand the origin of clays in fault rocks and their distributions is of great importance for defining fundamental properties of faults in the shallow crust. Field mapping shows that layers of clay gouge and shale smear are common along the Moab Fault, from exposures with throws ranging from 10 to ???1000 m. Elemental analyses of four locations along the Moab Fault show that fault rocks are enriched in clays at R191 and Bartlett Wash, but that this clay enrichment occurred at different times and was associated with different fluids. Fault rocks at Corral and Courthouse Canyons show little difference in elemental composition from adjacent protolith, suggesting that formation of fault rocks at those locations is governed by mechanical processes. Friction tests show that these authigenic clays result in fault zone weakening, and potentially influence the style of failure along the fault (seismogenic vs. aseismic) and potentially influence the amount of fluid loss associated with coseismic dilation. Scanning electron microscopy shows that authigenesis promotes that continuity of slip surfaces, thereby enhancing seal capacity. The occurrence of the authigenesis, and its influence on the sealing properties of faults, highlights the importance of determining the processes that control this phenomenon. ?? 2010 Elsevier Ltd.

The memory of the accreting plate boundary and the continuity of fracture zones

USGS Publications Warehouse

Schouten, Hans; Klitgord, Kim D.

1982-01-01

A detailed aeromagnetic anomaly map of the Mesozoic seafloor-spreading lineations southwest of Bermuda reveals the dominant magnetic grain of the oceanic crust and the character of the accreting boundary at the time of crustal formation. The magnetic anomaly pattern is that of a series of elongate lobes perpendicular to the fracture zone (flowline) trends. The linear sets of magnetic anomaly peaks and troughs have narrow regions of reduced amplitude anomalies associated with the fracture zones. During the period of Mesozoic geomagnetic polarity reversals (when 1200 km of central North Atlantic seafloor formed), the Atlantic accreting boundary consisted of stationary, elongate, spreading center cells that maintained their independence even though sometimes only minor spatial offsets existed between cells. Normal oceanic crustal structure was formed in the spreading center cells, but structural anomalies and discontinuities characteristic of fracture zones were formed at their boundaries, which parallel flowlines of Mesozoic relative plate motion in the central North Atlantic. We suggest that the memory for a stationary pattern of independent spreading center cells resides in the young brittle lithosphere at the accreting boundary where the lithosphere is weakest; here, each spreading center cell independently goes through its cylce of stress buildup, stress release, and crustal accretion, after which its memory is refreshed. The temporal offset between the peaks of the accretionary activity that takes place within each cell may provide the mechanism for maintaining the independence of adjacent spreading center cells through times when no spatial offset between the cells exists.

Definition of a safe zone for antegrade lag screw fixation of fracture of posterior column of the acetabulum by 3D technology.

PubMed

Feng, Xiaoreng; Zhang, Sheng; Luo, Qiang; Fang, Jintao; Lin, Chaowen; Leung, Frankie; Chen, Bin

2016-03-01

The objective of this study was to define a safe zone for antegrade lag screw fixation of fracture of posterior column of the acetabulum using a novel 3D technology. Pelvic CT data of 59 human subjects were obtained to reconstruct three-dimensional (3D) models. The transparency of 3D models was then downgraded along the axial perspective (the view perpendicular to the cross section of the posterior column axis) to find the largest translucent area. The outline of the largest translucent area was drawn on the iliac fossa. The line segments of OA, AB, OC, CD, the angles of OAB and OCD that delineate the safe zone (ABDC) were precisely measured. The resultant line segments OA, AB, OC, CD, and angles OAB and OCD were 28.46mm(13.15-44.97mm), 45.89mm (34.21-62.85mm), 36.34mm (18.68-55.56mm), 53.08mm (38.72-75.79mm), 37.44° (24.32-54.96°) and 55.78° (43.97-79.35°) respectively. This study demonstrates that computer-assisted 3D modelling techniques can aid in the precise definition of the safe zone for antegrade insertion of posterior column lag screws. A full-length lag screw can be inserted into the zone (ABDC), permitting a larger operational error. Copyright © 2016 Elsevier Ltd. All rights reserved.

Three-dimensional characterization of microporosity and permeability in fault zones hosted in heterolithic succession

NASA Astrophysics Data System (ADS)

Riegel, H. B.; Zambrano, M.; Jablonska, D.; Emanuele, T.; Agosta, F.; Mattioni, L.; Rustichelli, A.

2017-12-01

The hydraulic properties of fault zones depend upon the individual contributions of the damage zone and the fault core. In the case of the damage zone, it is generally characterized by means of fracture analysis and modelling implementing multiple approaches, for instance the discrete fracture network model, the continuum model, and the channel network model. Conversely, the fault core is more difficult to characterize because it is normally composed of fine grain material generated by friction and wear. If the dimensions of the fault core allows it, the porosity and permeability are normally studied by means of laboratory analysis or in the other case by two dimensional microporosity analysis and in situ measurements of permeability (e.g. micro-permeameter). In this study, a combined approach consisting of fracture modeling, three-dimensional microporosity analysis, and computational fluid dynamics was applied to characterize the hydraulic properties of fault zones. The studied fault zones crosscut a well-cemented heterolithic succession (sandstone and mudstones) and may vary in terms of fault core thickness and composition, fracture properties, kinematics (normal or strike-slip), and displacement. These characteristics produce various splay and fault core behavior. The alternation of sandstone and mudstone layers is responsible for the concurrent occurrence of brittle (fractures) and ductile (clay smearing) deformation. When these alternating layers are faulted, they produce corresponding fault cores which act as conduits or barriers for fluid migration. When analyzing damage zones, accurate field and data acquisition and stochastic modeling was used to determine the hydraulic properties of the rock volume, in relation to the surrounding, undamaged host rock. In the fault cores, the three-dimensional pore network quantitative analysis based on X-ray microtomography images includes porosity, pore connectivity, and specific surface area. In addition, images were

Fracture network evaluation program (FraNEP): A software for analyzing 2D fracture trace-line maps

NASA Astrophysics Data System (ADS)

Zeeb, Conny; Gomez-Rivas, Enrique; Bons, Paul D.; Virgo, Simon; Blum, Philipp

2013-10-01

Fractures, such as joints, faults and veins, strongly influence the transport of fluids through rocks by either enhancing or inhibiting flow. Techniques used for the automatic detection of lineaments from satellite images and aerial photographs, LIDAR technologies and borehole televiewers significantly enhanced data acquisition. The analysis of such data is often performed manually or with different analysis software. Here we present a novel program for the analysis of 2D fracture networks called FraNEP (Fracture Network Evaluation Program). The program was developed using Visual Basic for Applications in Microsoft Excel™ and combines features from different existing software and characterization techniques. The main novelty of FraNEP is the possibility to analyse trace-line maps of fracture networks applying the (1) scanline sampling, (2) window sampling or (3) circular scanline and window method, without the need of switching programs. Additionally, binning problems are avoided by using cumulative distributions, rather than probability density functions. FraNEP is a time-efficient tool for the characterisation of fracture network parameters, such as density, intensity and mean length. Furthermore, fracture strikes can be visualized using rose diagrams and a fitting routine evaluates the distribution of fracture lengths. As an example of its application, we use FraNEP to analyse a case study of lineament data from a satellite image of the Oman Mountains.

Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Final report, March 1996--September 1998

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.

1998-12-01

This project was designed to analyze the structure of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas to suggest ways in which oil recovery can be improved. The Eutaw Formation comprises 7 major flow units and is dominated by low-resistivity, low-contrast play that is difficult to characterize quantitatively. Selma chalk produces strictly from fault-related fractures that were mineralized as warm fluid migrated from deep sources. Resistivity, dipmeter, and fracture identification logs corroborate that deformation is concentrated in the hanging-wall drag zones. New area balancing techniques were developed to characterize growth strata and confirm that strain is concentrated inmore » hanging-wall drag zones. Curvature analysis indicates that the faults contain numerous fault bends that influence fracture distribution. Eutaw oil is produced strictly from footwall uplifts, whereas Selma oil is produced from fault-related fractures. Clay smear and mineralization may be significant trapping mechanisms in the Eutaw Formation. The critical seal for Selma reservoirs, by contrast, is where Tertiary clay in the hanging wall is juxtaposed with poorly fractured Selma chalk in the footwall. Gilbertown Field can be revitalized by infill drilling and recompletion of existing wells. Directional drilling may be a viable technique for recovering untapped oil from Selma chalk. Revitalization is now underway, and the first new production wells since 1985 are being drilled in the western part of the field.« less

Effect of Hygrothermal Aging on the Mechanical Properties of Fluorinated and Nonfluorinated Clay-Epoxy Nanocomposites

PubMed Central

Hamim, Salah U.; Singh, Raman P.

2014-01-01

Hydrophilic nature of epoxy polymers can lead to both reversible and irreversible/permanent changes in epoxy upon moisture absorption. The permanent changes leading to the degradation of mechanical properties due to combined effect of moisture and elevated temperature on EPON 862, Nanomer I.28E, and Somasif MAE clay-epoxy nanocomposites are investigated in this study. The extent of permanent degradation on fracture and flexural properties due to the hygrothermal aging is determined by drying the epoxy and their clay-epoxy nanocomposites after moisture absorption. Significant permanent damage is observed for fracture toughness and flexural modulus, while the extent of permanent damage is less significant for flexural strength. It is also observed that permanent degradation in Somasif MAE clay-epoxy nanocomposites is higher compared to Nanomer I.28E clay-epoxy nanocomposites. Fourier transform infrared (FTIR) spectroscopy revealed that both clays retained their original chemical structure after the absorption-desorption cycle without undergoing significant changes. Scanning electron microscopy (SEM) images of the fracture surfaces provide evidence that Somasif MAE clay particles offered very little resistance to crack propagation in case of redried specimens when compared to Nanomer I.28E counterpart. The reason for the observed higher extent of permanent degradation in Somasif MAE clay-epoxy system has been attributed to the weakening of the filler-matrix interface. PMID:27379285

Effect of Hygrothermal Aging on the Mechanical Properties of Fluorinated and Nonfluorinated Clay-Epoxy Nanocomposites.

PubMed

Hamim, Salah U; Singh, Raman P

2014-01-01

Hydrophilic nature of epoxy polymers can lead to both reversible and irreversible/permanent changes in epoxy upon moisture absorption. The permanent changes leading to the degradation of mechanical properties due to combined effect of moisture and elevated temperature on EPON 862, Nanomer I.28E, and Somasif MAE clay-epoxy nanocomposites are investigated in this study. The extent of permanent degradation on fracture and flexural properties due to the hygrothermal aging is determined by drying the epoxy and their clay-epoxy nanocomposites after moisture absorption. Significant permanent damage is observed for fracture toughness and flexural modulus, while the extent of permanent damage is less significant for flexural strength. It is also observed that permanent degradation in Somasif MAE clay-epoxy nanocomposites is higher compared to Nanomer I.28E clay-epoxy nanocomposites. Fourier transform infrared (FTIR) spectroscopy revealed that both clays retained their original chemical structure after the absorption-desorption cycle without undergoing significant changes. Scanning electron microscopy (SEM) images of the fracture surfaces provide evidence that Somasif MAE clay particles offered very little resistance to crack propagation in case of redried specimens when compared to Nanomer I.28E counterpart. The reason for the observed higher extent of permanent degradation in Somasif MAE clay-epoxy system has been attributed to the weakening of the filler-matrix interface.

Field characterization of elastic properties across a fault zone reactivated by fluid injection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jeanne, Pierre; Guglielmi, Yves; Rutqvist, Jonny

In this paper, we studied the elastic properties of a fault zone intersecting the Opalinus Clay formation at 300 m depth in the Mont Terri Underground Research Laboratory (Switzerland). Four controlled water injection experiments were performed in borehole straddle intervals set at successive locations across the fault zone. A three-component displacement sensor, which allowed capturing the borehole wall movements during injection, was used to estimate the elastic properties of representative locations across the fault zone, from the host rock to the damage zone to the fault core. Young's moduli were estimated by both an analytical approach and numerical finite differencemore » modeling. Results show a decrease in Young's modulus from the host rock to the damage zone by a factor of 5 and from the damage zone to the fault core by a factor of 2. In the host rock, our results are in reasonable agreement with laboratory data showing a strong elastic anisotropy characterized by the direction of the plane of isotropy parallel to the laminar structure of the shale formation. In the fault zone, strong rotations of the direction of anisotropy can be observed. Finally, the plane of isotropy can be oriented either parallel to bedding (when few discontinuities are present), parallel to the direction of the main fracture family intersecting the zone, and possibly oriented parallel or perpendicular to the fractures critically oriented for shear reactivation (when repeated past rupture along this plane has created a zone).« less

Field characterization of elastic properties across a fault zone reactivated by fluid injection

DOE PAGES

Jeanne, Pierre; Guglielmi, Yves; Rutqvist, Jonny; ...

2017-08-12

In this paper, we studied the elastic properties of a fault zone intersecting the Opalinus Clay formation at 300 m depth in the Mont Terri Underground Research Laboratory (Switzerland). Four controlled water injection experiments were performed in borehole straddle intervals set at successive locations across the fault zone. A three-component displacement sensor, which allowed capturing the borehole wall movements during injection, was used to estimate the elastic properties of representative locations across the fault zone, from the host rock to the damage zone to the fault core. Young's moduli were estimated by both an analytical approach and numerical finite differencemore » modeling. Results show a decrease in Young's modulus from the host rock to the damage zone by a factor of 5 and from the damage zone to the fault core by a factor of 2. In the host rock, our results are in reasonable agreement with laboratory data showing a strong elastic anisotropy characterized by the direction of the plane of isotropy parallel to the laminar structure of the shale formation. In the fault zone, strong rotations of the direction of anisotropy can be observed. Finally, the plane of isotropy can be oriented either parallel to bedding (when few discontinuities are present), parallel to the direction of the main fracture family intersecting the zone, and possibly oriented parallel or perpendicular to the fractures critically oriented for shear reactivation (when repeated past rupture along this plane has created a zone).« less

The Damage and Geochemical Signature of a Crustal Scale Strike-Slip Fault Zone

NASA Astrophysics Data System (ADS)

Gomila, R.; Mitchell, T. M.; Arancibia, G.; Jensen Siles, E.; Rempe, M.; Cembrano, J. M.; Faulkner, D. R.

2013-12-01

Fluid-flow migration in the upper crust is strongly controlled by fracture network permeability and connectivity within fault zones, which can lead to fluid-rock chemical interaction represented as mineral precipitation in mesh veins and/or mineralogical changes (alteration) of the host rock. While the dimensions of fault damage zones defined by fracture intensity is beginning to be better understood, how such dimensions compare to the size of alteration zones is less well known. Here, we show quantitative structural and chemical analyses as a function of distance from a crustal-scale strike-slip fault in the Atacama Fault System, Northern Chile, to compare fault damage zone characteristics with its geochemical signature. The Jorgillo Fault (JF) is a ca. 18 km long NNW striking strike-slip fault cutting Mesozoic rocks with sinistral displacement of ca. 4 km. In the study area, the JF cuts through orthogranulitic and gabbroic rocks at the west (JFW) and the east side (JFE), respectively. A 200 m fault perpendicular transect was mapped and sampled for structural and XRF analyses of the core, damage zone and protolith. The core zone consists of a ca. 1 m wide cataclasite zone bounded by two fault gouge zones ca. 40 cm. The damage zone width defined by fracture density is ca. 50 m wide each side of the core. The damage zone in JFW is characterized by NW-striking subvertical 2 cm wide cataclastic rocks and NE-striking milimetric open fractures. In JFE, 1-20 mm wide chlorite, quartz-epidote and quartz-calcite veins, cut the gabbro. Microfracture analysis in JFW reveal mm-wide cataclasitic/ultracataclasitic bands with clasts of protolith and chlorite orientated subparallel to the JF in the matrix, calcite veins in a T-fractures orientation, and minor polidirectional chlorite veins. In JFE, chlorite filled conjugate fractures with syntaxial growth textures and evidence for dilational fracturing processes are seen. Closest to the core, calcite veins crosscut chlorite veins

Flow zone characterisation in a fractured aquifer using spring and open-well T and EC monitoring.

NASA Astrophysics Data System (ADS)

Agbotui, Prodeo; West, Landis; Bottrell, Simon

2017-04-01

The Cretaceous Chalk is a very important aquifer in England, and its relatively high transmissivity derives essentially from a well-developed network of solutionally-enhanced fractures and conduits. Like other fractured aquifers, characterisation and delineation of flow pathways and hence catchment boundaries is important. Determination of flow pathways for source catchment delineation (e.g. identification of safeguarding zones around wells) is critical for the effective management and protection of the groundwater resource. It also determines the areal extent of contamination from known sources, and enables the targeted sampling of flow zones e.g. for monitored natural attenuation (MNA). A rather simplistic conceptualisation of the unconfined chalk aquifer of East Yorkshire is currently used as a basis for numerical simulations: linearly reducing hydraulic conductivity (K) with depth below the maximum groundwater elevation, reducing to a minimum value below the zone of groundwater table fluctuation. This study represents an attempt to improve this conceptualisation via improved characterisation of permeable zones within the aquifer. The methods used are: pumping test drawdown analyses for transmissivity, ambient open-well dilution testing; rainfall, groundwater head, and spring / open-well specific electrical conductance (SEC) and temperature monitoring. Pumping test analyses yield overall well transmissivity; the open-well dilution/monitoring approach identifies inflow, outflow, crossflow zones and direction and rate of flow in wells; seasonal changes in flows in wells and springs reflect the annual recharge and recession cycle and the impact of seasonal hydraulic head variation on the activation/deactivation of permeable pathways. Variations in spring and well-water electrical conductivity / temperature provide insight into groundwater residence times and the degree of isolation of groundwater from atmospheric and soil zone sources of CO2. The results of the

DEMONSTRATION BULLETIN: HYDRAULIC FRACTURING OF CONTAMINATED SOIL

EPA Science Inventory

Hydraulic fracturing is a physical process that creates fractures in silty clay soil to enhance its permeability. The technology, developed by the Risk Reduction Engineering Laboratory (RREL) and the University of Cincinnati, creates sand-filled horizontal fractures up to 1 in. i...

Linear Elastic and Cohesive Fracture Analysis to Model Hydraulic Fracture in Brittle and Ductile Rocks

NASA Astrophysics Data System (ADS)

Yao, Yao

2012-05-01

Hydraulic fracturing technology is being widely used within the oil and gas industry for both waste injection and unconventional gas production wells. It is essential to predict the behavior of hydraulic fractures accurately based on understanding the fundamental mechanism(s). The prevailing approach for hydraulic fracture modeling continues to rely on computational methods based on Linear Elastic Fracture Mechanics (LEFM). Generally, these methods give reasonable predictions for hard rock hydraulic fracture processes, but still have inherent limitations, especially when fluid injection is performed in soft rock/sand or other non-conventional formations. These methods typically give very conservative predictions on fracture geometry and inaccurate estimation of required fracture pressure. One of the reasons the LEFM-based methods fail to give accurate predictions for these materials is that the fracture process zone ahead of the crack tip and softening effect should not be neglected in ductile rock fracture analysis. A 3D pore pressure cohesive zone model has been developed and applied to predict hydraulic fracturing under fluid injection. The cohesive zone method is a numerical tool developed to model crack initiation and growth in quasi-brittle materials considering the material softening effect. The pore pressure cohesive zone model has been applied to investigate the hydraulic fracture with different rock properties. The hydraulic fracture predictions of a three-layer water injection case have been compared using the pore pressure cohesive zone model with revised parameters, LEFM-based pseudo 3D model, a Perkins-Kern-Nordgren (PKN) model, and an analytical solution. Based on the size of the fracture process zone and its effect on crack extension in ductile rock, the fundamental mechanical difference of LEFM and cohesive fracture mechanics-based methods is discussed. An effective fracture toughness method has been proposed to consider the fracture process zone

The PETM in the mid-Atlantic Coastal Plain: A widespread record of unique climate signatures in shallow-shelf Marlboro Clay

NASA Astrophysics Data System (ADS)

Powars, D. S.; Edwards, L. E.; Kopp, R. E.; Self-Trail, J.; Schultz, A.

2009-12-01

structural zone produced syn- and post-depositional erosional thinning on uplifted sides of faults and thickening in downdropped areas. The Chesapeake Bay Impact Structure (CBIS) removed the Marlboro Clay across a large area of southeastern Virginia. Faults and folds associated with the CBIS appear to deform the clay in an outer-fracture-zone that extends up to 25-km outside the crater’s outer rim. The Marlboro Clay thickens and is slightly finer-grained in the deeper part of the Marlboro basin in where structure contours on the top-of-basement generally mimic the tectonic downwarp. The apparent deepest (>200 m below sea level) and thickest (>14 m) part of the Marlboro depositional basin appears to extend from just south of the mouth of the Potomac River northward to the lower Choptank River valley, Maryland, then turns sharply northeastward to beneath the central part of Delaware Bay. The Marlboro Clay of the mid-Atlantic United States thus provides a widespread deposit that in its regional and tectonic setting records, in its unusual sedimentary properties, the severe regional environmental changes associated with global climate change during the PETM.

Gas and water flow in an excavation-induced fracture network around an underground drift: A case study for a radioactive waste repository in clay rock

NASA Astrophysics Data System (ADS)

de La Vaissière, Rémi; Armand, Gilles; Talandier, Jean

2015-02-01

The Excavation Damaged Zone (EDZ) surrounding a drift, and in particular its evolution, is being studied for the performance assessment of a radioactive waste underground repository. A specific experiment (called CDZ) was designed and implemented in the Meuse/Haute-Marne Underground Research Laboratory (URL) in France to investigate the EDZ. This experiment is dedicated to study the evolution of the EDZ hydrogeological properties (conductivity and specific storage) of the Callovo-Oxfordian claystone under mechanical compression and artificial hydration. Firstly, a loading cycle applied on a drift wall was performed to simulate the compression effect from bentonite swelling in a repository drift (bentonite is a clay material to be used to seal drifts and shafts for repository closure purpose). Gas tests (permeability tests with nitrogen and tracer tests with helium) were conducted during the first phase of the experiment. The results showed that the fracture network within the EDZ was initially interconnected and opened for gas flow (particularly along the drift) and then progressively closed with the increasing mechanical stress applied on the drift wall. Moreover, the evolution of the EDZ after unloading indicated a self-sealing process. Secondly, the remaining fracture network was resaturated to demonstrate the ability to self-seal of the COx claystone without mechanical loading by conducting from 11 to 15 repetitive hydraulic tests with monitoring of the hydraulic parameters. During this hydration process, the EDZ effective transmissivity dropped due to the swelling of the clay materials near the fracture network. The hydraulic conductivity evolution was relatively fast during the first few days. Low conductivities ranging at 10-10 m/s were observed after four months. Conversely, the specific storage showed an erratic evolution during the first phase of hydration (up to 60 days). Some uncertainty remains on this parameter due to volumetric strain during the

Long Term Leaching of Chlorinated Solvents from Source Zones in Low Permeability Settings with Fractures

NASA Astrophysics Data System (ADS)

Bjerg, P. L.; Chambon, J.; Troldborg, M.; Binning, P. J.; Broholm, M. M.; Lemming, G.; Damgaard, I.

2008-12-01

Groundwater contamination by chlorinated solvents, such as perchloroethylene (PCE), often occurs via leaching from complex sources located in low permeability sediments such as clayey tills overlying aquifers. Clayey tills are mostly fractured, and contamination migrating through the fractures spreads to the low permeability matrix by diffusion. This results in a long term source of contamination due to back-diffusion. Leaching from such sources is further complicated by microbial degradation under anaerobic conditions to sequentially form the daughter products trichloroethylene, cis-dichloroethylene (cis-DCE), vinyl chloride (VC) and ethene. This process can be enhanced by addition of electron donors and/or bioaugmentation and is termed Enhanced Reductive Dechlorination (ERD). This work aims to improve our understanding of the physical, chemical and microbial processes governing source behaviour under natural and enhanced conditions. That understanding is applied to risk assessment, and to determine the relationship and time frames of source clean up and plume response. To meet that aim, field and laboratory observations are coupled to state of the art models incorporating new insights of contaminant behaviour. The long term leaching of chlorinated ethenes from clay aquitards is currently being monitored at a number of Danish sites. The observed data is simulated using a coupled fracture flow and clay matrix diffusion model. Sequential degradation is represented by modified Monod kinetics accounting for competitive inhibition between the chlorinated ethenes. The model is constructed using Comsol Multiphysics, a generic finite- element partial differential equation solver. The model is applied at two well characterised field sites with respect to hydrogeology, fracture network, contaminant distribution and microbial processes (lab and field experiments). At the study sites (Sortebrovej and Vadsbyvej), the source areas are situated in a clayey till with fractures

Revealing the unexplored fungal communities in deep groundwater of crystalline bedrock fracture zones in Olkiluoto, Finland.

PubMed

Sohlberg, Elina; Bomberg, Malin; Miettinen, Hanna; Nyyssönen, Mari; Salavirta, Heikki; Vikman, Minna; Itävaara, Merja

2015-01-01

The diversity and functional role of fungi, one of the ecologically most important groups of eukaryotic microorganisms, remains largely unknown in deep biosphere environments. In this study we investigated fungal communities in packer-isolated bedrock fractures in Olkiluoto, Finland at depths ranging from 296 to 798 m below surface level. DNA- and cDNA-based high-throughput amplicon sequencing analysis of the fungal internal transcribed spacer (ITS) gene markers was used to examine the total fungal diversity and to identify the active members in deep fracture zones at different depths. Results showed that fungi were present in fracture zones at all depths and fungal diversity was higher than expected. Most of the observed fungal sequences belonged to the phylum Ascomycota. Phyla Basidiomycota and Chytridiomycota were only represented as a minor part of the fungal community. Dominating fungal classes in the deep bedrock aquifers were Sordariomycetes, Eurotiomycetes, and Dothideomycetes from the Ascomycota phylum and classes Microbotryomycetes and Tremellomycetes from the Basidiomycota phylum, which are the most frequently detected fungal taxa reported also from deep sea environments. In addition some fungal sequences represented potentially novel fungal species. Active fungi were detected in most of the fracture zones, which proves that fungi are able to maintain cellular activity in these oligotrophic conditions. Possible roles of fungi and their origin in deep bedrock groundwater can only be speculated in the light of current knowledge but some species may be specifically adapted to deep subsurface environment and may play important roles in the utilization and recycling of nutrients and thus sustaining the deep subsurface microbial community.

Water recharge and solute transport through the vadose zone of fractured chalk under desert conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nativ, R.; Dahan, O.; Adar, E.

In the present study the inferred mechanism of groundwater recharge and contamination was studied using tracer concentrations in the fractured vadose zone of the Avdat chalk. The results of this study are important for an evaluation of groundwater contamination from existing and planned facilities in the northern Negev desert in Israel. This study focused on the vicinity of the Ramat Hovav industrial chemical complex in the northern Negev, which also includes the national site for hazardous waste. Water recharge and solute migration rates were examined in five core holes and one borehole which penetrate the entire vadose zone and enabledmore » the collection of rock samples for chemical and isotopic analyses, and an observation of fracture distribution with depth. Tritium profiles were used to estimate water percolation rates through the vadose zone, chloride profiles were used to assess the migration rate of nonreactive solutes, and bromide profiles were also used to evaluate the migration rate of nonreactive contaminants. Deuterium and oxygen 18 profiles were used to assess the evaporation of the infiltrating water at and near land surface.« less

Numerical model of water flow in a fractured basalt vadose zone: Box Canyon Site, Idaho

NASA Astrophysics Data System (ADS)

Doughty, Christine

2000-12-01

A numerical model of a fractured basalt vadose zone has been developed on the basis of the conceptual model described by Faybishenko et al. [[his issue]. The model has been used to simulate a ponded infiltration test in order to investigate infiltration through partially saturated fractured basalt. A key question addressed is how the fracture pattern geometry and fracture connectivity within a single basalt flow of the Snake River Plain basalt affect water infiltration. The two-dimensional numerical model extends from the ground surface to a perched water body 20 m below and uses an unconventional quasi-deterministic approach with explicit but highly simplified representation of major fractures and other important hydrogeologic features. The model adequately reproduces the majority of the field observation and provides insights into the infiltration process that cannot be obtained by data collection alone, demonstrating its value as a component of field studies.

Distribution of Subsurface Flexure zone caused by Uemachi Fault, Japan and its activity

NASA Astrophysics Data System (ADS)

Kitada, N.; Inoue, N.; Takemura, K.; Ito, H.; Mitamura, M.

2012-12-01

In Osaka, Uemachi Fault is one of the famous active faults. It across the center of Osaka and lies in N-S direction mainly and is more than 40 km in length. The faults bound sedimentary basins, where thick sedimentary deposits of the Pliocene-Quaternary Osaka Group have accumulated. The deposits consist primarily of sand and marine and non-marine clay, and the clay layers are key markers for the interpretation of glacial and interglacial cycles. In this study, we estimate the width of the flexure zone using a geotechnical borehole database. GI database collects more than 40,000 boreholes and includes both geological information and soil properties around Osaka by the Geo-database Information Committee of Kansai Area. Our results indicate that the deformation associated with the flexure zone is distributed primarily along the splay fault (NE-SW) and not along the main fault, suggesting that the splay fault might be the primary fault at present. We first examined the borehole data along the seismic reflection line and then considered the surrounding area. An Upper Pleistocene marine clay (Ma12) is a good indicator of the flexure zone. We constructed many cross sections in and around the fault zone and classified the deformation form into three categories around the flexure zone. The results of this study allowed us to map the distribution of folding in a zone in the west of the Osaka area. Folding can be classified into three types: (1) Ma12 folding, (2) Ma12 folding that does not continue toward the hanging wall, and (3) folding or displacement of old marine clay. These folding zone trends are N-W strike however these trace are serpentine. These folding zone information are not in worth to estimate the source fault, however these zone will be more serious damaged when the earthquake occurred. Our result agrees well with the average displacement speed of about 0.4 m/ka that was derived by the Headquarters for Earthquake Research Promotion of the Ministry of Education

76 FR 19698 - Safety Zone; Repair of High Voltage Transmission Lines to Logan International Airport, Saugus...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-08

...-AA00 Safety Zone; Repair of High Voltage Transmission Lines to Logan International Airport, Saugus... (COTP) Boston Zone to allow for repair of high voltage transmission lines to Logan Airport. This safety... voltage transmission lines. Entering into, transiting through, mooring or anchoring within this zone is...

Weathering, Fractures and Water in the deep Critical Zone: Geophysical investigations in the U.S. Critical Zone Observatories

NASA Astrophysics Data System (ADS)

Holbrook, W. S.; Carr, B.; Moon, S.; Perron, J. T.; Hayes, J. L.; Flinchum, B. A.; St Clair, J. T.; Riebe, C. S.; Richter, D., Jr.; Leone, J.

2015-12-01

The Critical Zone (CZ) is Earth's breathing skin: the thin layer from treetop to bedrock that supports most terrestrial life. Key hydrological, biogeochemical, and physical processes occur in the CZ, including physical and chemical weathering, soil production, erosion, nutrient cycling, and surface/groundwater exchange. These processes in turn influence subsurface water storage capacity, landscape evolution, ecological stability, aquifer recharge and stream flow. Because the deep CZ is hidden from direct observation, it can only be studied by drilling and/or geophysical measurements. Given the relative scarcity of such data, we lack a complete understanding of the architecture of the CZ, how it varies across landscapes, and what controls that variation. We present geophysical data that address these questions at six Critical Zone Observatories (CZO): Calhoun, Boulder Creek, Eel River, Reynolds Creek, Catalina-Jemez, and Southern Sierra. Conclusions include: (1) Regolith depth is influenced by the opening of fractures due to the release of regional and topographic stress as rocks are exhumed toward the surface. Stress models at Calhoun and Boulder Creek show remarkable agreement with seismic velocities in the shallow subsurface, suggesting that stress release controls the development of fracture porosity in the CZ. (2) Chemical weathering (plagioclase dissolution) begins at depths where fractures open (~40 m at Calhoun), implying that fracturing and chemical weathering are intimately paired in the deep CZ. (3) Volumetric strain is an underappreciated contributor to porosity in the CZ. In the Southern Sierra, strain dominates over chemical weathering in the upper 10 m, consistent with the stress-release model. (4) Geological structure and lithology can trump environmental controls (e.g., aspect and climate) on regolith development. At Catalina, strongly contrasting regolith thickness on north- and south-facing slopes, is not due to "northness", but rather to

The Comprehensive AOCMF Classification System: Mandible Fractures- Level 2 Tutorial

PubMed Central

Cornelius, Carl-Peter; Audigé, Laurent; Kunz, Christoph; Rudderman, Randal; Buitrago-Téllez, Carlos H.; Frodel, John; Prein, Joachim

2014-01-01

This tutorial outlines the details of the AOCMF image-based classification system for fractures of the mandible at the precision level 2 allowing description of their topographical distribution. A short introduction about the anatomy is made. Mandibular fractures are classified by the anatomic regions involved. For this purpose, the mandible is delineated into an array of nine regions identified by letters: the symphysis/parasymphysis region anteriorly, two body regions on each lateral side, combined angle and ascending ramus regions, and finally the condylar and coronoid processes. A precise definition of the demarcation lines between these regions is given for the unambiguous allocation of fractures. Four transition zones allow an accurate topographic assignment if fractures end up in or run across the borders of anatomic regions. These zones are defined between angle/ramus and body, and between body and symphysis/parasymphysis. A fracture is classified as “confined” as long as it is located within a region, in contrast to a fracture being “nonconfined” when it extents to an adjoining region. Illustrations and case examples of mandible fractures are presented to become familiar with the classification procedure in daily routine. PMID:25489388

Detection of Fracture Patterns Within the Southern Portion of a Residential Complex (Tepozanes), Los Reyes-La Paz County (Edo. de Mexico)

NASA Astrophysics Data System (ADS)

Chavez, R. E.; Arango, C.; Tejero, A.; Cifuentes, G.; Hernandez, E.

2008-12-01

Most of the urban zone within the Valley of Mexico is built on top of the sediments of the ancient lakes of Chalco, Xochimilco, Mexico, Texcoco, Xaltocan and Zumpango. The sediments that cover this great valley are mainly composed by highly saturated clay-sandy materials; which offer a weak resistance to the constructions built on top. In addition, the increasing need of water supply for the population living in the valley (~22 million inhabitants) has weakened the main groundwater aquifers. This has lead to a differentiated subsidence and collapse of buildings, habitation units and roads. These effects put in a serious risk the inhabitants and the infrastructure of the city. As an example, we present a case of an area located in a densely populated zone, within a low-income residential complex denominated Tepozanes. This is located in the Los Reyes-La Paz County (Mexico State), towards the southeastern portion of the Valley of Mexico. The area is geologically limited by the Chimalhuacan Hill to the N, by the Santa Catarina volcanic range to the S. The previously mentioned effects are evident in the constructions of some buildings, where an exposed fracture is found in the NE-SW direction. This feature is affecting the structure of one of them in the residential complex, where the fracture runs underneath. A geophysical study was proposed to characterize the subsoil and to define the fracturing patterns in the zone. The electrical resistivity tomography (ETR) method employing the capacitive and galvanic modes was used to define the fracturing patters and the position at depth of the saturated layers, which might affect the Residential buildings. As a complement, GPR (Ground Penetrating Radar) profiles were carried out on the same profiles to correlate the information obtained from the ETR capacitive method which has a better resolution in the shallower zone. The computed results show that the buildings foundations were set on top of a high resistivity layer (~1000

How Well Does Fracture Set Characterization Reduce Uncertainty in Capture Zone Size for Wells Situated in Sedimentary Bedrock Aquifers?

NASA Astrophysics Data System (ADS)

West, A. C.; Novakowski, K. S.

2005-12-01

Regional groundwater flow models are rife with uncertainty. The three-dimensional flux vector fields must generally be inferred using inverse modelling from sparse measurements of hydraulic head, from measurements of hydraulic parameters at a scale that is miniscule in comparison to that of the domain, and from none to a very few measurements of recharge or discharge rate. Despite the inherent uncertainty in these models they are routinely used to delineate steady-state or time-of-travel capture zones for the purpose of wellhead protection. The latter are defined as the volume of the aquifer within which released particles will arrive at the well within the specified time and their delineation requires the additional step of dividing the magnitudes of the flux vectors by the assumed porosity to arrive at the ``average linear groundwater velocity'' vector field. Since the porosity is usually assumed constant over the domain one could be forgiven for thinking that the uncertainty introduced at this step is minor in comparison to the flow model calibration step. We consider this question when the porosity in question is fracture porosity in flat-lying sedimentary bedrock. We also consider whether or not the diffusive uptake of solute into the rock matrix which lies between the source and the production well reduces or enhances the uncertainty. To evaluate the uncertainty an aquifer cross section is conceptualized as an array of horizontal, randomly-spaced, parallel-plate fractures of random aperture, with adjacent horizontal fractures connected by vertical fractures again of random spacing and aperture. The source is assumed to be a continuous concentration (i.e. a dirichlet boundary condition) representing a leaking tank or a DNAPL pool, and the receptor is a fully pentrating well located in the down-gradient direction. In this context the time-of-travel capture zone is defined as the separation distance required such that the source does not contaminate the well

Dynamic permeability in fault damage zones induced by repeated coseismic fracturing events

NASA Astrophysics Data System (ADS)

Aben, F. M.; Doan, M. L.; Mitchell, T. M.

2017-12-01

Off-fault fracture damage in upper crustal fault zones change the fault zone properties and affect various co- and interseismic processes. One of these properties is the permeability of the fault damage zone rocks, which is generally higher than the surrounding host rock. This allows large-scale fluid flow through the fault zone that affects fault healing and promotes mineral transformation processes. Moreover, it might play an important role in thermal fluid pressurization during an earthquake rupture. The damage zone permeability is dynamic due to coseismic damaging. It is crucial for earthquake mechanics and for longer-term processes to understand how the dynamic permeability structure of a fault looks like and how it evolves with repeated earthquakes. To better detail coseismically induced permeability, we have performed uniaxial split Hopkinson pressure bar experiments on quartz-monzonite rock samples. Two sample sets were created and analyzed: single-loaded samples subjected to varying loading intensities - with damage varying from apparently intact to pulverized - and samples loaded at a constant intensity but with a varying number of repeated loadings. The first set resembles a dynamic permeability structure created by a single large earthquake. The second set resembles a permeability structure created by several earthquakes. After, the permeability and acoustic velocities were measured as a function of confining pressure. The permeability in both datasets shows a large and non-linear increase over several orders of magnitude (from 10-20 up to 10-14 m2) with an increasing amount of fracture damage. This, combined with microstructural analyses of the varying degrees of damage, suggests a percolation threshold. The percolation threshold does not coincide with the pulverization threshold. With increasing confining pressure, the permeability might drop up to two orders of magnitude, which supports the possibility of large coseismic fluid pulses over relatively

Clay with Desiccation Cracks is an Advection Dominated Environment

NASA Astrophysics Data System (ADS)

Baram, S.; Kurtzman, D.; Sher, Y.; Ronen, Z.; Dahan, O.

2012-04-01

Heavy clay sediments are regarded "safe" from the hydrological point of view due to their low hydraulic conductivities. However, the formation of desiccation cracks in dispersive clays may dramatically change their bulk hydraulic properties. The impact of desiccation cracks on water percolation, dissolved salts and contaminants transport and redox related reactions (microbial ammonium oxidation and denitrification) were investigated in 6 -12 m clay layer near a diary farm waste lagoon. The study implemented unique vadose-zone monitoring systems that enable in-situ measurements of the temporal variation of the sediment's water content along with frequent sampling of the sediment's pore water along the entire vadose zone (> 30 m). Results from four years of continuous measurements showed quick rises in sediment water content following rain events and temporal wastewater overflows. The percolation pattern indicated dominance of preferential flow through a desiccation-cracks network crossing the entire clay sediment layer. High water-propagation velocities (0.4 - 23.6 m h-1) were observed, indicating that the desiccation-crack network remains open and serves as a preferential flow pathway year-round, even at high sediment water content (~0.50 m3 m-3). The rapid percolation bypassed the most bio-geo-active parts of the soil, transporting even highly sorptive contaminants (testosterone and estrogen) in to the deep sections of the vadose zone, accelerating the underlying groundwater contamination. The ammonium and nitrate concentrations in the vadose zone and the high number of nitrifying and denitrifying bacteria (~108 gene copies gdry-sediemt-1, each) found in the sediment indicated that the entire vadose zone is aerated even at high water content conditions (~0.55 m3 m-3). The dissolved salts concentration in the pore-water and the δ2H-H2O and δ18O-H2O values of the pore-water substantially increased with depth (becoming less depleted) in the clay sediment

Do scaly clays control seismicity on faulted shale rocks?

NASA Astrophysics Data System (ADS)

Orellana, Luis Felipe; Scuderi, Marco M.; Collettini, Cristiano; Violay, Marie

2018-04-01

One of the major challenges regarding the disposal of radioactive waste in geological formations is to ensure isolation of radioactive contamination from the environment and the population. Shales are suitable candidates as geological barriers. However, the presence of tectonic faults within clay formations put the long-term safety of geological repositories into question. In this study, we carry out frictional experiments on intact samples of Opalinus Clay, i.e. the host rock for nuclear waste storage in Switzerland. We report experimental evidence suggesting that scaly clays form at low normal stress (≤20 MPa), at sub-seismic velocities (≤300 μm/s) and is related to pre-existing bedding planes with an ongoing process where frictional sliding is the controlling deformation mechanism. We have found that scaly clays show a velocity-weakening and -strengthening behaviour, low frictional strength, and poor re-strengthening over time, conditions required to allow the potential nucleation and propagation of earthquakes within the scaly clays portion of the formation. The strong similarities between the microstructures of natural and experimental scaly clays suggest important implications for the slip behaviour of shallow faults in shales. If natural and anthropogenic perturbations modify the stress conditions of the fault zone, earthquakes might have the potential to nucleate within zones of scaly clays controlling the seismicity of the clay-rich tectonic system, thus, potentially compromising the long-term safeness of geological repositories situated in shales.

Quantifying Seasonal Dynamic Water Storage in a Fractured Bedrock Vadose Zone With Borehole Nuclear Magnetic Resonance

NASA Astrophysics Data System (ADS)

Schmidt, L.; Minton, B.; Soto-Kerans, N.; Rempe, D.; Heidari, Z.

2017-12-01

In many uplands landscapes, water is transiently stored in the weathered and fractured bedrock that underlies soils. The timing and spatial pattern of this "rock moisture" has strong implications for ecological and biogeochemical processes that influence global cycling of water and solutes. However, available technologies for direct monitoring of rock moisture are limited. Here, we quantify temporal and spatial changes in rock moisture at the field scale across thick (up to 20 m) fractured vadose zone profiles using a novel narrow diameter borehole nuclear magnetic resonance system (BNMR). Successive BNMR surveys were performed using the Vista Clara Inc. Dart system in a network of boreholes within two steep, intensively hydrologically monitored hillslopes associated with the Eel River Critical Zone Observatory (ERCZO) in Northern California. BNMR data showed agreement with estimates of the temporal and spatial pattern of rock moisture depletion over the dry season via downhole neutron and gamma density surveys, as well as permanently installed continuous time domain reflectometry. Observable shifts in the BNMR-derived T2 distribution over time provide a direct measure of changes in the amount of water held within different pore sizes (large vs. small) in fractured rock. Analysis of both BNMR and laboratory-scale NMR (using a 2MHz benchtop NMR spectrometer) measurements of ERCZO core samples at variable saturation suggest that rock moisture changes associated with summer depletion occur within both large (fracture) and small (matrix) pore sizes. Collectively, our multi-method field- and laboratory- scale measurements highlight the potential for BNMR to improve quantification of rock moisture storage for better understanding of the biogeochemical and ecohydrological implications of rock moisture circulation in the Critical Zone.

Assessment of the mechanical properties of sisal fiber-reinforced silty clay using triaxial shear tests.

PubMed

Wu, Yankai; Li, Yanbin; Niu, Bin

2014-01-01

Fiber reinforcement is widely used in construction engineering to improve the mechanical properties of soil because it increases the soil's strength and improves the soil's mechanical properties. However, the mechanical properties of fiber-reinforced soils remain controversial. The present study investigated the mechanical properties of silty clay reinforced with discrete, randomly distributed sisal fibers using triaxial shear tests. The sisal fibers were cut to different lengths, randomly mixed with silty clay in varying percentages, and compacted to the maximum dry density at the optimum moisture content. The results indicate that with a fiber length of 10 mm and content of 1.0%, sisal fiber-reinforced silty clay is 20% stronger than nonreinforced silty clay. The fiber-reinforced silty clay exhibited crack fracture and surface shear fracture failure modes, implying that sisal fiber is a good earth reinforcement material with potential applications in civil engineering, dam foundation, roadbed engineering, and ground treatment.

Assessment of the Mechanical Properties of Sisal Fiber-Reinforced Silty Clay Using Triaxial Shear Tests

PubMed Central

Wu, Yankai; Li, Yanbin; Niu, Bin

2014-01-01

Fiber reinforcement is widely used in construction engineering to improve the mechanical properties of soil because it increases the soil's strength and improves the soil's mechanical properties. However, the mechanical properties of fiber-reinforced soils remain controversial. The present study investigated the mechanical properties of silty clay reinforced with discrete, randomly distributed sisal fibers using triaxial shear tests. The sisal fibers were cut to different lengths, randomly mixed with silty clay in varying percentages, and compacted to the maximum dry density at the optimum moisture content. The results indicate that with a fiber length of 10 mm and content of 1.0%, sisal fiber-reinforced silty clay is 20% stronger than nonreinforced silty clay. The fiber-reinforced silty clay exhibited crack fracture and surface shear fracture failure modes, implying that sisal fiber is a good earth reinforcement material with potential applications in civil engineering, dam foundation, roadbed engineering, and ground treatment. PMID:24982951

Structure and clay mineralogy: borehole images, log interpretation and sample analyses at Site C0002 Nankai Trough accretionary prism

NASA Astrophysics Data System (ADS)

Jurado, Maria Jose; Schleicher, Anja

2015-04-01

Our research focused on the characterization of fracture and fault structures from the deep Nankai Trough accretionary prism in Japan. Logging Data and cuttings samples from the two most recent International Ocean Discovery Program (IODP) Expeditions 338 and 348 of the NanTroSEIZE project were analyzed by Logging While Drilling (LWD) oriented images, geophysical logs and clay mineralogy. Both expeditions took place at Site C0002, but whereas Hole C0002F (Expedition 338) was drilled down to 2004.5 mbsf, Hole C0002N and C0002P (Expedition 348) reached a depth of 2325.5 mbsf and 3058.8 mbsf respectively. The structural interpretation of borehole imaging data illustrates the deformation within the fractured and faulted sections of the accretionary prism. All drill holes show distinct areas of intense fracturing and faulting within a very clay-dominated lithology. Here, smectite and illite are the most common clay minerals, but the properties and the role they may play in influencing the fractures, faults and folds in the accretionary prism is still not well understood. When comparing clay mineralogy and fracture/fault areas in hole C0002F (Expedition 338), a trend in the abundance of illite and smectite, and in particular the swelling behavior of smectite is recognizable. In general, the log data provided a good correlation with the actual mineralogy and the relative abundance of clay. Ongoing postcruise preliminary research on hole C0002 N and C0002P (Expedition 348) should confirm these results. The relationship between fracture and fault structures and the changes in clay mineralogy could be explained by the deformation of specific areas with different compaction features, fluid-rock interaction processes, but could also be related to beginning diagenetic processes related to depth. Our results show the integration of logging data and cutting sample analyses as a valuable tool for characterization of petrophysical and mineralogical changes of the structures of the

About the Transformation Phase Zones of Shape Memory Alloys' Fracture Tests on Single Edge-Cracked Specimen

NASA Astrophysics Data System (ADS)

Taillebot, V.; Lexcellent, C.; Vacher, P.

2012-03-01

The thermomechanical behavior of shape memory alloys is now well mastered. However, a hindrance to their sustainable use is the lack of knowledge of their fracture behavior. With the aim of filling this partial gap, fracture tests on edge-cracked specimens in NiTi have been made. Particular attention was paid to determine the phase transformation zones in the vicinity of the crack tip. In one hand, experimental kinematic fields are observed using digital image correlation showing strain localization around the crack tip. In the other hand, an analytical prediction, based on a modified equivalent stress criterion and taking into account the asymmetric behavior of shape memory alloys in tension-compression, provides shape and size of transformation outset zones. Experimental results are relatively in agreement with our analytical modeling.

Iceland Scotland Overflow Water flow through the Bight Fracture Zone in June-July 2015

NASA Astrophysics Data System (ADS)

Mercier, Herle; Petit, Tillys; Thierry, Virginie

2017-04-01

ISOW (Iceland Scotland Overflow Water) is the densest water in the northern Iceland Basin and a main constituent of the lower limb of the meridional overturning circulation (MOC). ISOW is the product of mixing of dense water originating from the Nordic Seas with Atlantic Water and Labrador Sea Water during its crossing of the Iceland-Faroe-Scotland Ridge and downstream acceleration. In the northern Iceland Basin, ISOW is characterized by potential density σ0 > 27.8 and salinity > 34.94. Downstream of the Iceland-Scotland Ridge, ISOW flows southwestward in a Deep Western Boundary Current along the eastern flank of the Reykjanes Ridge. Models and float trajectories previously suggested that part of the ISOW flow could cross the Reykjanes Ridge through the Bight Fracture Zone. However, no direct observations of the ISOW flow through the Bight Fracture Zone are available that would allow us to quantify its transport and water mass transformation. This lack of direct observations also prevents understanding the dynamics of the throughflow. In this study, we analyzed a set of CTDO2 and LADCP stations acquired in June-July 2015 during the Reykjanes Ridge Experiment cruise and provide new insights on the ISOW flow through the Bight Fracture Zone. The evolution of the properties as well as the velocity measurements confirm an ISOW flow from the Iceland Basin to the Irminger Sea. A main constrain to the throughflow is the presence of two sills of about 2150 m depth and two narrows. With potential densities between 27.8-27.87 kg m-3 and near bottom potential temperature of 3.02°C and salinity of 34.98, only the lightest variety of ISOW is found at the entrance of the BFZ east of the sills. In the central part of the Bight Fracture Zone, the evolution of ISOW is characterized by a decrease of 0.015 kg m-3 in the near bottom density, ascribed to the blocking of the densest ISOW variety by the sills and/or diapycnal mixing. To the West, at the exit of the BFZ, ISOW overlays

Molecular species delimitation and its implications for species descriptions using desmosomatid and nannoniscid isopods from the VEMA fracture zone as example taxa

NASA Astrophysics Data System (ADS)

Brix, Saskia; Bober, Simon; Tschesche, Claudia; Kihara, Terue-Cristina; Driskell, Amy; Jennings, Robert M.

2018-02-01

We found 72 species for COI and 45 for 16 S by species delimitation among 186 (from 195 extracted) desmosomatid (144) and nannoniscid (42) sequenced specimens of a total of > 400 specimens for both families. Multiple "discovery"-type species delimitation methods were used, so that consistency across methods could be assessed: The ABGD analysis detected a barcode gap of 3-6% for COI and 4-6% for 16 S, in the whole dataset. Most putative species have a horizontally limited distribution along the Vema fracture zone, although the details depend in part on the interpretation of species delimitation analyses. Putative species were mostly restricted to the eastern or western Vema fracture zone, with only eight crossing the complete Vema fracture zone. Our data suggest that even robustly-sampled species exhibited small ranges; the range estimates calculable from present data were around 500 km, and three were on the order of 1000-2500 km. We chose an abundant, but geographically restricted species (Eugerdella egoni Tschesche and Brix sp. nov.) collected at a single site in the Vema transform fault, and two species (Prochelator barnacki Bober and Brix sp. nov. and Whoia sockei Brix and Kihara sp. nov.) with a broad, but disjunct distribution in the Vema fracture zone for taxonomic description.

Origin and significance of clay-coated fractures in mudrock fragments of the SAFOD borehole (Parkfield, California)

USGS Publications Warehouse

Schleicher, A.M.; van der Pluijm, B.A.; Solum, J.G.; Warr, L.N.

2006-01-01

The clay mineralogy and texture of rock fragments from the SAFOD borehole at 3067 m and 3436 m measured depth (MD) was investigated by electron microscopy (SEM, TEM) and X-ray-diffraction (XRD). The washed and ultrasonically cleaned samples show slickenfiber striations and thin films of Ca-K bearing smectite that are formed on polished fault surfaces, along freshly opened fractures and within adjacent mineralized veins. The cation composition and hydration behavior of these films differ from the Namontmorillonite of the fresh bentonite drilling mud, although there is more similarity with circulated mud recovered from 3479 m MD. We propose that these thin film smectite precipitates formed by natural nucleation and crystal growth during fault creep, probably associated with the shallow circulation of low temperature aqueous fluids along this shallow portion of the San Andreas Fault. Copyright 2006 by the American Geophysical Union.

Computational modeling and simulation of spall fracture in polycrystalline solids by an atomistic-based interfacial zone model

PubMed Central

Lin, Liqiang; Zeng, Xiaowei

2015-01-01

The focus of this work is to investigate spall fracture in polycrystalline materials under high-speed impact loading by using an atomistic-based interfacial zone model. We illustrate that for polycrystalline materials, increases in the potential energy ratio between grain boundaries and grains could cause a fracture transition from intergranular to transgranular mode. We also found out that the spall strength increases when there is a fracture transition from intergranular to transgranular. In addition, analysis of grain size, crystal lattice orientation and impact speed reveals that the spall strength increases as grain size or impact speed increases. PMID:26435546

Fracture Toughness and Elastic Modulus of Epoxy-Based Nanocomposites with Dopamine-Modified Nano-Fillers

PubMed Central

Koh, Kwang Liang; Ji, Xianbai; Lu, Xuehong; Lau, Soo Khim; Chen, Zhong

2017-01-01

This paper examines the effect of surface treatment and filler shape factor on the fracture toughness and elastic modulus of epoxy-based nanocomposite. Two forms of nanofillers, polydopamine-coated montmorillonite clay (D-clay) and polydopamine-coated carbon nanofibres (D-CNF) were investigated. It was found that Young’s modulus increases with increasing D-clay and D-CNF loading. However, the fracture toughness decreases with increased D-clay loading but increases with increased D-CNF loading. Explanations have been provided with the aid of fractographic analysis using electron microscope observations of the crack-filler interactions. Fractographic analysis suggests that although polydopamine provides a strong adhesion between the fillers and the matrix, leading to enhanced elastic stiffness, the enhancement prohibits energy release via secondary cracking, resulting in a decrease in fracture toughness. In contrast, 1D fibre is effective in increasing the energy dissipation during fracture through crack deflection, fibre debonding, fibre break, and pull-out. PMID:28773136

Modeling of sheet metal fracture via cohesive zone model and application to spot welds

NASA Astrophysics Data System (ADS)

Wu, Joseph Z.

Even though the cohesive zone model (CZM) has been widely used to analyze ductile fracture, it is not yet clearly understood how to calibrate the cohesive parameters including the specific work of separation (the work of separation per unit crack area) and the peak stress. A systematic approach is presented to first determine the cohesive values for sheet metal and then apply the calibrated model to various structure problems including the failure of spot welds. Al5754-0 was chosen for this study since it is not sensitive to heat treatment so the effect of heat-affected-zone (HAZ) can be ignored. The CZM has been applied to successfully model both mode-I and mode-III fracture for various geometries including Kahn specimens, single-notch specimens, and deep double-notch specimens for mode-I and trouser specimens for mode-III. The mode-I fracture of coach-peel spot-weld nugget and the mixed-mode fracture of nugget pull-out have also been well simulated by the CZM. Using the mode-I average specific work of separation of 13 kJ/m2 identified in a previous work and the mode-III specific work of separation of 38 kJ/m 2 found in this thesis, the cohesive peak stress has been determined to range from 285 MPa to 600 MPa for mode-I and from 165 MPa to 280 MPa for mode-III, depending on the degree of plastic deformation. The uncertainty of these cohesive values has also been examined. It is concluded that, if the specific work of separation is a material constant, the peak stress changes with the degree of plastic deformation and is therefore geometry-dependent.

Morphology and Role of the Investigator Fracture Zone on the Sumatra Subduction Zone Process using High-resolution Bathymetry and Seismic Data

NASA Astrophysics Data System (ADS)

Villanueva-Robles, F.; Singh, S. C.; Bradley, K. E.; Hananto, N.; Leclerc, F.; Qin, Y.; Wei, S.; Carton, H. D.; Tapponnier, P.; Sieh, K.; Permana, H.; Avianto, P.

2016-12-01

The Sumatran subduction zone is one of the most seismically active areas on Earth. Within the last decade, it has produced three great earthquakes plus one earthquake that produced a much larger tsunami than predicted from the magnitude alone. However, the physical factors that limit the lateral extent of these ruptures as well as ancient earthquakes evidenced by paleogeodesy remain poorly understood. It has been suggested that subducted bathymetric features, such as seamounts and fracture zones, may be define many segment boundaries. Offshore of Central Sumatra, the Investigator Fracture Zone (IFZ) impinges on the trench and has been subducted to great depth beneath the overriding accretionary wedge. Where it is still exposed as a bathymetric feature, this fracture zone is 2000 km long and more than 100 km wide, and is composed of four individual ridges that exhibit up to 3.7 km of original relief. In order to study the role of the IFZ on subduction processes, we simultaneously acquired multibeam bathymetry and eight 35-km-long high-resolution seismic reflection profiles across the subduction front during the 2015 MegaTera experiment. We find that subduction of the IFZ ridges significantly deforms the morphology of the overriding accretionary wedge. The steep eastern slope of subducting ridges allowed the development of a long lived frontal thrust that reaches the surface at the trench and is associated with a very large frontal anticline and a flat portion of the accretionary wedge. Extensional deformation of the forearc and transverse basin formation occurs along the trailing edge of the ridges. We suggest that the subducted IFZ defines a segment boundary between the southern limit of coseismic slip of the Mw = 8.7, 2005 Simeulue-Nias earthquake and the northern limit of coseismic slip limit of a major 1797 earthquake recorded by coral paleogeodesy. The presence of four distinct ridges and an intervening 35-km-wide area of normal oceanic crust within the 105-km

Geophysical characterization of fractured bedrock at Site 8, former Pease Air Force Base, Newington, New Hampshire

USGS Publications Warehouse

Mack, Thomas J.; Degnan, James R.

2003-01-01

Borehole-geophysical logs collected from eight wells and direct-current resistivity data from three survey lines were analyzed to characterize the fractured bedrock and identify transmissive fractures beneath the former Pease Air Force Base, Newington, N.H. The following logs were used: caliper, fluid temperature and conductivity, natural gamma radiation, electromagnetic conductivity, optical and acoustic televiewer, and heat-pulse flowmeter. The logs indicate several foliation and fracture trends in the bedrock. Two fracture-correlated lineaments trending 28? and 29?, identified with low-altitude aerial photography, are coincident with the dominant structural trend. The eight boreholes logged at Site 8 generally have few fractures and have yields ranging from 0 to 40 gallons per minute. The fractures that probably resulted in high well yields (20?40 gallons per minute) strike northeast-southwest or by the right hand rule, have an orientation of 215?, 47?, and 51?. Two-dimensional direct-current resistivity methods were used to collect detailed subsurface information about the overburden, bedrock-fracture zone depths, and apparent-dip directions. Analysis of data inversions from data collected with dipole-dipole and Schlumberger arrays indicated electrically conductive zones in the bedrock that are probably caused by fractured rock. These zones are coincident with extensions of fracture-correlated lineaments. The fracture-correlated lineaments and geophysical-survey results indicate a possible northeast-southwest anisotropy to the fractured rock.

Using earthquake clusters to identify fracture zones at Puna geothermal field, Hawaii

NASA Astrophysics Data System (ADS)

Lucas, A.; Shalev, E.; Malin, P.; Kenedi, C. L.

2010-12-01

The actively producing Puna geothermal system (PGS) is located on the Kilauea East Rift Zone (ERZ), which extends out from the active Kilauea volcano on Hawaii. In the Puna area the rift trend is identified as NE-SW from surface expressions of normal faulting with a corresponding strike; at PGS the surface expression offsets in a left step, but no rift perpendicular faulting is observed. An eight station borehole seismic network has been installed in the area of the geothermal system. Since June 2006, a total of 6162 earthquakes have been located close to or inside the geothermal system. The spread of earthquake locations follows the rift trend, but down rift to the NE of PGS almost no earthquakes are observed. Most earthquakes located within the PGS range between 2-3 km depth. Up rift to the SW of PGS the number of events decreases and the depth range increases to 3-4 km. All initial locations used Hypoinverse71 and showed no trends other than the dominant rift parallel. Double difference relocation of all earthquakes, using both catalog and cross-correlation, identified one large cluster but could not conclusively identify trends within the cluster. A large number of earthquake waveforms showed identifiable shear wave splitting. For five stations out of the six where shear wave splitting was observed, the dominant polarization direction was rift parallel. Two of the five stations also showed a smaller rift perpendicular signal. The sixth station (located close to the area of the rift offset) displayed a N-S polarization, approximately halfway between rift parallel and perpendicular. The shear wave splitting time delays indicate that fracture density is higher at the PGS compared to the surrounding ERZ. Correlation co-efficient clustering with independent P and S wave windows was used to identify clusters based on similar earthquake waveforms. In total, 40 localized clusters containing ten or more events were identified. The largest cluster was located in the

Fluoride content of clay minerals and argillaceous earth materials

USGS Publications Warehouse

Thomas, Josephus; Glass, H.D.; White, W.A.; Trandel, R.M.

1977-01-01

A reliable method, utilizing a fluoride ion-selective electrode, is described for the determination of fluoride in clays and shales. Interference by aluminum and iron is minimal. The reproducibility of the method is about ±5% at different levels of fluoride concentration.Data are presented for various clay minerals and for the <2-µm fractions of marine and nonmarine clays and shales. Fluoride values range from 44 ppm (0.0044%) for nontronite from Colfax, WA, to 51,800 ppm (5.18%) for hectorite from Hector, CA. In general, clays formed under hydrothermal conditions are relatively high in fluoride content, provided the hydrothermal waters are high in fluoride content. Besides hectorite, dickite from Ouray, CO, was found to contain more than 50 times as much fluoride (6700 ppm) as highly crystalline geode kaolinite (125 ppm). The clay stratum immediately overlying a fluorite mineralized zone in southern Illinois was found to have a higher fluoride content than the same stratum in a nonmineralized zone approximately 1 mile away. Nonmarine shales in contact with Australian coals were found to be lower in fluoride content than were marine shales in contact with Illinois coals.It is believed that, in certain instances, peak shifts on DTA curves of similar clay minerals are the result of significant differences in their fluoride content.

Georadar and geoelectricity method to identify the determine zone of sliding landslide

NASA Astrophysics Data System (ADS)

Dalimunthe, Y. K.; Hamid, A.

2018-01-01

The aim of this research is to determine the contrast between the sliding plane by observing the parameters of rock types, fractures, and faults that could potentially land slides in Bandar Baru, Lampung Barat, Indonesia by both methods of georadar and geoelectricity. This research uses radar reflection profiling configuration for georadar and dipole-dipole configuration for geoelectricity. For georadar data processing has been done with Reflexwave software and for geoelectricity, data processing has been done with Earthimager 2DINV software to interpret subsurface section. Results of research by both methods of georadar and geoelectricity shows the area of contact between the sand stone with resistivity value of 200-1449 Ωm and clay stone with a resistivity value of 32-100 Ωm at the limit depth of 9 m as a potential zone of sliding landslides where the physical properties of clay stone easily derail massive material on it.

Characterization of the Fault Core and Damage Zone of the Borrego Fault, 2010 M7.2 Rupture

NASA Astrophysics Data System (ADS)

Dorsey, M. T.; Rockwell, T. K.; Girty, G.; Ostermeijer, G.; Mitchell, T. M.; Fletcher, J. M.

2017-12-01

We collected a continuous sample of the fault core and 23 samples of the damage zone out to 52 m across the rupture trace of the 2010 M7.2 El Mayor-Cucapa earthquake to characterize the physical damage and chemical transformations associated with this active seismic source. In addition to quantifying fracture intensity from macroscopic analysis, we cut a continuous thin section through the fault core and from various samples in the damage zone, and ran each sample for XRD analyses for clay mineralogy, XRF for bulk geochemical analyses, and bulk and grain density from which porosity and volumetric strain were derived. The parent rock is a hydrothermally-altered biotite tonalite, with biotite partially altered to chlorite. The presence of epidote with chlorite suggests that these rocks were subjected to relatively high temperatures of 300-400° C. Adjacent to the outermost damage zone is a chaotic breccia zone with distinct chemical and physical characteristics, indicating possible connection to an ancestral fault to the southwest. The damage zone consists of an outer zone of protocataclasite, which grades inward towards mesocataclasite with seams of ultracataclasite. The fault core is anomalous in that it is largely composed of a sliver of marble that has been translated along the fault, so direct comparison with the damage zone is impaired. From collected data, we observe that chloritization increases into the breccia and damage zones, as does the presence of illite. Porosity reaches maximum values in the damage zone adjacent to the core, and closely follows trends in fracture intensity. Statistically significant gains in Mg, Na, K, Mn, and total bulk mass occurred within the inner damage zone, with losses of Ca and P mass, which led to the formation of chlorite and albite. The outer damage zone displays gains in Mg and Na mass with losses in Ca and P mass. The breccia zone shows gains in mass of Mg and Mn and loss in total bulk mass. A gain in LOI in both the

Influence of Laser Radiation Power Density on the Intensity of Spectral Lines for Main Components in a Clay Laser-Induced Plasma

NASA Astrophysics Data System (ADS)

Anufrik, S. S.; Kurian, N. N.; Znosko, K. F.; Belkov, M. V.

2018-05-01

We have studied the intensity of the spectral lines for the main components in clay: Al I 309.4 nm, Al II 358.7 nm, Mg II 279.6 nm, Ti II 323.6 nm vs. the position of the object relative to the focus of the optical system when the samples are exposed to single laser pulses from a YAG:Nd3+ laser. We have determined the permissible ranges for positioning the object relative to the focus of the optical system (positive and negative defocusing) for which there is practically no change in the reproducibility of the intensity for the spectral lines for red and white clay samples. We show that the position of the object relative to the focus of the optical system should be within the range ΔZ ±1.5 mm for optimal laser pulse energies for the analyte spectral lines. We have calculated the radiation flux density for different laser pulse energies and different distances from the focus to the object. We have shown experimentally that reducing the radiation flux density leads to a decrease in the intensity of the analyte spectral lines.

76 FR 4575 - Safety Zone; Repair of High Voltage Transmission Lines to Logan International Airport, Saugus...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-26

...-AAOO Safety Zone; Repair of High Voltage Transmission Lines to Logan International Airport, Saugus... the Captain of the Port (COTP) Boston Zone to allow for repair of high voltage transmission lines to... the repair of high voltage transmission lines. Entering into, transiting through, mooring or anchoring...

Geophysical investigations of well fields to characterize fractured-bedrock aquifers in southern New Hampshire

USGS Publications Warehouse

Degnan, James R.; Moore, Richard Bridge; Mack, Thomas J.

2001-01-01

Bedrock-fracture zones near high-yield bedrock wells in southern New Hampshire well fields were located and characterized using seven surface and six borehole geophysical survey methods. Detailed surveys of six sites with various methods provide an opportunity to integrate and compare survey results. Borehole geophysical surveys were conducted at three of the sites to confirm subsurface features. Hydrogeologic settings, including a variety of bedrock and surface geologic materials, were sought to gain an insight into the usefulness of the methods in varied terrains. Results from 15 survey lines, 8 arrays, and 3 boreholes were processed and interpreted from the 6 sites. The surface geophysical methods used provided physical properties of fractured bedrock. Seismic refraction and ground-penetrating radar (GPR) primarily were used to characterize the overburden materials, but in a few cases indicated bedrock-fracture zones. Magnetometer surveys were used to obtain background information about the bedrock to compare with other results, and to search for magnetic lows, which may result from weathered fractured rock. Electromagnetic terrain conductivity surveys (EM) and very-low-frequency electromagnetic surveys (VLF) were used as rapid reconnaissance techniques with the primary purpose of identifying electrical anomalies, indicating potential fracture zones in bedrock. Direct-current (dc) resistivity methods were used to gather detailed subsurface information about fracture depth and orientation. Two-dimensional (2-D) dc-resistivity surveys using dipole-dipole and Schlumberger arrays located and characterized the overburden, bedrock, and bedrock-fracture zones through analysis of data inversions. Azimuthal square array dc-resistivity survey results indicated orientations of conductive steep-dipping bedrock-fracture zones that were located and characterized by previously applied geophysical methods. Various available data sets were used for site selection

Quantifying Preferential Flow and Seasonal Storage in an Unsaturated Fracture-Facial Domain

NASA Astrophysics Data System (ADS)

Nimmo, J. R.; Malek-Mohammadi, S.

2012-12-01

Preferential flow through deep unsaturated zones of fractured rock is hydrologically important to a variety of contaminant transport and water-resource issues. The unsaturated zone of the English Chalk Aquifer provides an important opportunity for a case study of unsaturated preferential flow in isolation from other flow modes. The chalk matrix has low hydraulic conductivity and stays saturated, owing to its fine uniform pores and the wet climate of the region. Therefore the substantial fluxes observed in the unsaturated chalk must be within fractures and interact minimally with matrix material. Price et al. [2000] showed that irregularities on fracture surfaces provide a significant storage capacity in the chalk unsaturated zone, likely accounting for volumes of water required to explain unexpected dry-season water-table stability during substantial continuing streamflow observed by Lewis et al. [1993] In this presentation we discuss and quantify the dynamics of replenishment and drainage of this unsaturated zone fracture-face storage domain using a modification of the source-responsive model of Nimmo [2010]. This model explains the processes in terms of two interacting flow regimes: a film or rivulet preferential flow regime on rough fracture faces, active on an individual-storm timescale, and a regime of adsorptive and surface-tension influences, resembling traditional diffuse formulations of unsaturated flow, effective mainly on a seasonal timescale. The modified model identifies hydraulic parameters for an unsaturated fracture-facial domain lining the fractures. Besides helping to quantify the unsaturated zone storage described by Price et al., these results highlight the importance of research on the topic of unsaturated-flow relations within a near-fracture-surface domain. This model can also facilitate understanding of mechanisms for reinitiation of preferential flow after temporary cessation, which is important in multi-year preferential flow through deep

Malunion of Long-Bone Fractures in a Conflict Zone in the Democratic Republic of Congo.

PubMed

Bauhahn, Grace; Veen, Harald; Hoencamp, Rigo; Olim, Nelson; Tan, Edward C T H

2017-09-01

Malunion is a well-recognized complication of long-bone fractures which accounts for more than 25% of injuries in conflict zones. The aim of this study was to investigate the rate of malunion sustained by casualties with penetrating gunshot wounds in an International Committee of the Red Cross (ICRC) surgical substitution project in the Democratic Republic of Congo (DRC) and compare these results with current literature. A retrospective cohort study was performed. All patients admitted to the ICRC facility between the periods of 01.10.2014 and 31.12.2015 with long-bone fractures caused by gunshot wound were included, and data were collected retrospectively from the patient's hospital notes. A total of 191 fractures caused by gunshot were treated in the DRC at the ICRC surgical substitution project during the study period. On average, the fractures were 3 days old on admission and were all open, with 62% also being comminuted. The ICRC management protocol, which emphasizes debridement, antibiotic prophylaxis and conservative fracture stabilization, was followed in all cases. Forty-eight percentage of the fractures were finally classified as 'union without complication'; however, 17% were classified as 'malunion'. This study indicates that open long-bone fractures that are managed by the ICRC surgical substitution project in DRC may have an increased likelihood of malunion as compared to long-bone fractures treated in developed countries. Patient delay and mechanism of injury may have caused increased rates of infection which are likely behind these increased rates of malunion, alongside the lack of definitive fracture treatment options made available to the surgical team.

Cohesive zone modelling of wafer bonding and fracture: effect of patterning and toughness variations

NASA Astrophysics Data System (ADS)

Kubair, D. V.; Spearing, S. M.

2006-03-01

Direct wafer bonding has increasingly become popular in the manufacture of microelectromechanical systems and semiconductor microelectronics components. The success of the bonding process is controlled by variables such as wafer flatness and surface preparation. In order to understand the effects of these variables, spontaneous planar crack propagation simulations were performed using the spectral scheme in conjunction with a cohesive zone model. The fracture-toughness on the bond interface is varied to simulate the effect of surface roughness (nanotopography) and patterning. Our analysis indicated that the energetics of crack propagation is sensitive to the local surface property variations. The patterned wafers are tougher (well bonded) than the unpatterned ones of the same average fracture-toughness.

Transfer zones in listric normal fault systems

NASA Astrophysics Data System (ADS)

Bose, Shamik

divergent and convergent transfer zones. Flat base plate setups have been used to build different configurations that would lead to approaching, normal offset and overlapping faults geometries. The results have been analyzed with respect to fault orientation, density, connectivity and 3D geometry from photographs taken from the three free surfaces and laser scans of the top surface of the clay cake respectively. The second chapter looks into the 3D structural analysis of the South Timbalier Block 54, offshore Louisiana in the Gulf of Mexico with the help of a 3D seismic dataset and associated well tops and velocity data donated by ExxonMobil Corporation. This study involves seismic interpretation techniques, velocity modeling, cross section restoration of a series of seismic lines and 3D subsurface modeling using depth converted seismic horizons, well tops and balanced cross sections. The third chapter deals with the clay experiments of listric normal fault systems and tries to understand the controls on geometries of fault systems with and without a ductile substrate. Sloping flat base plate setups have been used and silicone fluid underlain below the clay cake has been considered as an analog for salt. The experimental configurations have been varied with respect to three factors viz. the direction of slope with respect to extension, the termination of silicone polymer with respect to the basal discontinuities and overlap of the base plates. The analyses for the experiments have again been performed from photographs and 3D laser scans of the clay surface.

Concentrated aqueous sodium chloride solution in clays at thermodynamic conditions of hydraulic fracturing: Insight from molecular dynamics simulations

NASA Astrophysics Data System (ADS)

Svoboda, Martin; Lísal, Martin

2018-06-01

To address a high salinity of flow-back water during hydraulic fracturing, we use molecular dynamics (MD) simulations and study the thermodynamics, structure, and diffusion of concentrated aqueous salt solution in clay nanopores. The concentrated solution results from the dissolution of a cubic NaCl nanocrystal, immersed in an aqueous NaCl solution of varying salt concentration and confined in clay pores of a width comparable to the crystal size. The size of the nanocrystal equals to about 18 Å which is above a critical nucleus size. We consider a typical shale gas reservoir condition of 365 K and 275 bar, and we represent the clay pores as pyrophyllite and Na-montmorillonite (Na-MMT) slits. We employ the Extended Simple Point Charge (SPC/E) model for water, Joung-Cheatham model for ions, and CLAYFF for the slit walls. We impose the pressure in the normal direction and the resulting slit width varies from about 20 to 25 Å when the salt concentration in the surrounding solution increased from zero to an oversaturated value. By varying the salt concentration, we observe two scenarios. First, the crystal dissolves and its dissolution time increases with increasing salt concentration. We describe the dissolution process in terms of the number of ions in the crystal, and the crystal size and shape. Second, when the salt concentration reaches a system solubility limit, the crystal grows and attains a new equilibrium size; the crystal comes into equilibrium with the surrounding saturated solution. After crystal dissolution, we carry out canonical MD simulations for the concentrated solution. We evaluate the hydration energy, density profiles, orientation distributions, hydrogen-bond network, radial distribution functions, and in-plane diffusion of water and ions to provide insight into the microscopic behaviour of the concentrated aqueous sodium chloride solution in interlayer galleries of the slightly hydrophobic pyrophyllite and hydrophilic Na-MMT pores.

Concentrated aqueous sodium chloride solution in clays at thermodynamic conditions of hydraulic fracturing: Insight from molecular dynamics simulations.

PubMed

Svoboda, Martin; Lísal, Martin

2018-06-14

To address a high salinity of flow-back water during hydraulic fracturing, we use molecular dynamics (MD) simulations and study the thermodynamics, structure, and diffusion of concentrated aqueous salt solution in clay nanopores. The concentrated solution results from the dissolution of a cubic NaCl nanocrystal, immersed in an aqueous NaCl solution of varying salt concentration and confined in clay pores of a width comparable to the crystal size. The size of the nanocrystal equals to about 18 Å which is above a critical nucleus size. We consider a typical shale gas reservoir condition of 365 K and 275 bar, and we represent the clay pores as pyrophyllite and Na-montmorillonite (Na-MMT) slits. We employ the Extended Simple Point Charge (SPC/E) model for water, Joung-Cheatham model for ions, and CLAYFF for the slit walls. We impose the pressure in the normal direction and the resulting slit width varies from about 20 to 25 Å when the salt concentration in the surrounding solution increased from zero to an oversaturated value. By varying the salt concentration, we observe two scenarios. First, the crystal dissolves and its dissolution time increases with increasing salt concentration. We describe the dissolution process in terms of the number of ions in the crystal, and the crystal size and shape. Second, when the salt concentration reaches a system solubility limit, the crystal grows and attains a new equilibrium size; the crystal comes into equilibrium with the surrounding saturated solution. After crystal dissolution, we carry out canonical MD simulations for the concentrated solution. We evaluate the hydration energy, density profiles, orientation distributions, hydrogen-bond network, radial distribution functions, and in-plane diffusion of water and ions to provide insight into the microscopic behaviour of the concentrated aqueous sodium chloride solution in interlayer galleries of the slightly hydrophobic pyrophyllite and hydrophilic Na-MMT pores.

Segmentation along the Queen Charlotte Fault: The long-lived influence of plate-motion rotation and Explorer Ridge fracture zones

NASA Astrophysics Data System (ADS)

Miller, N. C.; Walton, M. A. L.; Brothers, D. S.; Haeussler, P. J.; Ten Brink, U. S.; Conrad, J. E.; Kluesner, J.; Andrews, B. D.

2017-12-01

The Queen Charlotte Fault (QCF) generally tracks the flow line for Pacific/North America (Pa/NA) relative motion since 20 Ma, indicating that the plate boundary localized along an optimally oriented small circle geometry. Rotation in Pa/NA motion at 10—12 Ma caused the QCF south of 53 N to be oblique to plate motion by 10—20. This oblique convergence appears to be accommodated in part by underthrusting of the Pacific Plate beneath Haida Gwaii and in part by slip on faults west of the QCF. On the west side of the QCF, a series of ridges and small basins oriented subparallel to either the QCF or relative plate motion form a 40-km-wide terrace. New high-resolution seismic reflection data image the seaward edge of the ridges as a vertical contact between horizontal or sometimes downwarped deep-sea sediments and west-vergent anticlinal structures within the ridges, supporting earlier interpretations that these ridges have accommodated some component of oblique motion. We argue that the ridges originated as step overs from fracture zones on Explorer Ridge, analogous to the current fault geometry at the southernmost end of the QCF. There, the Revere-Dellwood Fracture Zone (RDFZ) overlaps the QCF for 120 km and connects to the QCF via a more-optimally oriented extensional right step. 3.9—6.4 Mw strike-slip earthquakes along the RDFZ and a lack of contractional seafloor morphologies along the QCF south of the RDFZ-QCF right step suggest that the step over and reactivation along the RDFZ accommodates a majority of plate motion in this region. Kinematic reconstruction of ridges from 54—56 N indicates that they also originated in a similar location, potentially as right steps from either the RDFZ or Sovanco Fracture Zone. Similarly, the RDFZ flow path is coincident with a truncation of seafloor magnetic anomalies and the outer edge of the ridge-bounded terrace, which both parallel the QCF since at least the onset of Explorer Ridge spreading at 8 Ma. The RDFZ-QCF right

Evolution of the Jan Mayen Ridge - new geochemical and geophysical data from the Jan Mayen Fracture Zone

NASA Astrophysics Data System (ADS)

Slama, J.; Pedersen, R. B.; Kosler, J.; Kandilarov, A.; Hendriks, B. W. H.

2009-04-01

Geochronologic and geochemical data derived from sea-floor samples dredged from the Jan Mayen Fracture Zone together with seismic data provide new insight into the tectonomagmatic evolution of the Jan Mayen Ridge. Based on the seismic data, the Jan Mayen Ridge is believed to represent an off-rifted fragment of East Greenland continental lithosphere that since early Miocene has drifted 400 km into the North Atlantic as a result of sea-floor spreading along the Kolbeinsey Ridge. At present the Jan Mayen Ridge is uniquely located at the Mid-Atlantic Ridge north of Iceland. During the recent G.O.SARS research cruises a suite of volcanic rocks, as well as sandstones and conglomerates that are predominantly made up of volcaniclastic material were recovered from the southern escarpment of Jan Mayen Fracture Zone east of Jan Mayen. The conglomerates contain carbonate shell fragments that yielded 87Sr/86Sr age of ca. 32 Ma, which probably reflects the time of deposition of these volcano-sedimentary rocks. U-Pb ages of detrital zircon from the samples show age distribution consistent with an East Greenland source region characterized by a wide age pattern with significant Archaean and Early Proterozoic component. A population of angular zircons provides the youngest ages around 30 Ma, which are consistent with the Sr-age data from the shell fragment. These young zircons are most likely derived from the local volcanic material and do accordingly date the volcanic activity. Chemical analyses of individual volcanic clasts in the conglomerates show that they belong to the trachytic suite, and correspond mainly to hawaiites and trachyandesites. They are geochemically very similar to the recent volcanic rocks of the Jan Mayen Island. The maximum age of some of the volcanic clasts obtained by Ar-Ar whole-rock dating is consistent with the age of the youngest detrital zircons and with the Sr-age of the shell fragment. The new data suggest that the alkaline volcanism in the Jan Mayen

Anisotropy of electrical conductivity of the excavation damaged zone in the Mont Terri Underground Rock Laboratory

NASA Astrophysics Data System (ADS)

Nicollin, Florence; Gibert, Dominique; Lesparre, Nolwenn; Nussbaum, Christophe

2010-04-01

Electrical resistivity measurements were performed to characterize the anisotropy of electrical resistivity of the excavation damaged zone (EDZ) at the end-face of a gallery in the Opalinus clay of the Mont Terri Underground Rock Laboratory (URL). The data were acquired with a combination of square arrays in 18 zones on the gallery's face and in two series of four boreholes perpendicular to the face. Each data set is independently inverted using simulated annealing to recover the resistivity tensor. Both the stability and the non-uniqueness of the inverse problem are discussed with synthetic examples. The inversion of the data shows that the face is split in two domains separated by a tectonic fracture, with different resistivity values but with a common orientation. The direction of the maximum resistivity is found perpendicular to the bedding plane, and the direction of minimum resistivity is contained in the face's plane. These results show that the geo-electrical structure of the EDZ is controlled by a combination of effects due to tectonics, stratigraphy, and recent fracturing produced by the excavation of the gallery.

Synchrotron quantification of fracturing during maturation of shales

NASA Astrophysics Data System (ADS)

Figueroa Pilz, Fernando; Fauchille, Anne-Laure; Dowey, Patrick; Courtois, Loic; Bay, Brian; Ma, Lin; Taylor, Kevin; Mecklenburgh, Julian; Lee, Peter

2017-04-01

To understand both the hydrocarbon migration within and from shale rocks, and during hydraulic fracturing, is needed to evaluate and predict its environmental footprint. As a consequence, the time characterization of fracture networks in shale is particularly important. Time resolved synchrotron X-ray tomography was used to quantify the initiation and propagation of fractures during the simulated maturation of an organic-rich Kimmeridge Clay shale from the µm to mm scales. Scanning electron microscopy (SEM) observations were performed before and after maturation in order to compare the microstructure evolution and better understand the fracture location. Fracture and strain development during heating was quantified in 3D by Digital Volume Correlation (DVC) (Bay et al., 1999). The combination of DVC, X-Ray tomography and SEM obtained direct 4D strain measurements of the anisotropic mechanical behaviour of Kimmeridge shale with the temperature during an accelerated thermal maturation (Figueroa Pilz et al.). Such a combination has rarely been investigated in 4D at these scales in the past. In the study conditions, the results demonstrated the anisotropy in thermal expansion and the aperture fracture pathways through organic matter and clay matrix.

A study of damage zones or characteristic lengths as related to the fracture behavior of graphite/epoxy laminates

NASA Technical Reports Server (NTRS)

Yeow, Y. T.; Brinson, H. F.

1977-01-01

Uniaxial tensile tests conducted on a variety of graphite/epoxy laminates, containing narrow rectangular slits, square or circular holes with various aspect ratios are discussed. The techniques used to study stable crack or damage zone growth--namely, birefringence coatings, COD gages, and microscopic observations are discussed. Initial and final fracture modes are discussed as well as the effect of notch size and shape, and laminate type on the fracture process. Characteristic lengths are calculated and compared to each other using the point, average and inherent flaw theories. Fracture toughnesses are calculated by the same theories and compared to a boundary integral equation technique. Finite width K-calibration factors are also discussed.

Deep Seismic Reflection Images across a Major Reactivated Fracture Zone in the Wharton Basin: Implications for the Location of the Plate Boundary between India and Australia

NASA Astrophysics Data System (ADS)

Carton, H. D.; Singh, S. C.; Hananto, N. D.; Martin, J.; Djajadihardja, Y. S.; Udrekh, U.; Franke, D.; Gaedicke, C.

2012-12-01

The equatorial Indian Ocean has long been recognized to be hosting extensive "intra-plate" deformation. To west of the Ninety-East Ridge (NER), The Central Indian Ocean Basin is characterized by N-S compression in a broad region with E-W trending folds and high-angle reverse faulting. To the east of NER in the Wharton Basin, deformation mainly occurs along reactivated N5°E-trending oceanic fracture zones with left-lateral strike-slip motion. Near longitude 93°E in the Wharton Basin runs a major reactivated fracture zone, along which the epicenters of the two recent Mw=8.6 and Mw=8.2 strike-slip earthquakes of April 11, 2012, and an Mw=7.2 foreshock that occurred in January 2012 are aligned. The April 11 events are the largest known oceanic events occurring away from the main plate boundaries. They ruptured a 20-40 km thick section of the oceanic lithosphere, i.e. down to depths at which no direct images of fault zones have been obtained so far. Deep seismic reflection data acquired in the Mw=8.6 earthquake rupture zone ~100 km north of the epicenter shows the presence of sub-Moho reflectivity down to 37 km depth in the oceanic mantle. We interpret these events as reflections off the earthquake-generating fault plane in the oceanic mantle, in accordance with results suggesting that brittle deformation of the oceanic lithosphere extends well into the mantle down to the 600°C isotherm. The fracture zone near 93°E separates lithospheres of contrasting crustal thicknesses (3.5-4.5 km versus 6 km) with a 10 Ma age difference, and therefore seems to act as a rheological boundary. We find that the deep reflections could originate from either a plane trending approximately N105°E, at high angle to the fracture zone, or from the fracture zone itself if the dip of the fault surface decreases from nearly vertical in the sediments to about 45° in the oceanic mantle. We propose that this fracture zone is a major tectonic boundary in the Wharton Basin, and that the three

Hydraulic anisotropy characterization of pneumatic-fractured sediments using azimuthal self potential gradient

USGS Publications Warehouse

Wishart, D.N.; Slater, L.D.; Schnell, D.L.; Herman, G.C.

2009-01-01

The pneumatic fracturing technique is used to enhance the permeability and porosity of tight unconsolidated soils (e.g. clays), thereby improving the effectiveness of remediation treatments. Azimuthal self potential gradient (ASPG) surveys were performed on a compacted, unconsolidated clay block in order to evaluate their potential to delineate contaminant migration pathways in a mechanically-induced fracture network. Azimuthal resistivity (ARS) measurements were also made for comparative purposes. Following similar procedures to those used in the field, compressed kaolinite sediments were pneumatically fractured and the resulting fracture geometry characterized from strike analysis of visible fractures combined with strike data from optical borehole televiewer (BHTV) imaging. We subsequently injected a simulated treatment (electrolyte/dye) into the fractures. Both ASPG and ARS data exhibit anisotropic geoelectric signatures resulting from the fracturing. Self potentials observed during injection of electrolyte are consistent with electrokinetic theory and previous laboratory results on a fracture block model. Visual (polar plot) analysis and linear regression of cross plots show ASPG lobes are correlated with azimuths of high fracture strike density, evidence that the ASPG anisotropy is a proxy measure of hydraulic anisotropy created by the pneumatic fracturing. However, ARS data are uncorrelated with fracture strike maxima and resistivity anisotropy is probably dominated by enhanced surface conduction along azimuths of weak 'starter paths' formed from pulverization of the clay and increases in interfacial surface area. We find the magnitude of electrokinetic SP scales with the applied N2 gas pressure gradient (??PN2) for any particular hydraulically-active fracture set and that the positive lobe of the ASPG anomaly indicates the flow direction within the fracture network. These findings demonstrate the use of ASPG in characterizing the effectiveness of (1

Re-injection feasibility study of fracturing flow-back fluid in shale gas mining

NASA Astrophysics Data System (ADS)

Kang, Dingyu; Xue, Chen; Chen, Xinjian; Du, Jiajia; Shi, Shengwei; Qu, Chengtun; Yu, Tao

2018-02-01

Fracturing flow-back fluid in shale gas mining is usually treated by re-injecting into formation. After treatment, the fracturing flow-back fluid is injected back into the formation. In order to ensure that it will not cause too much damage to the bottom layer, feasibility evaluations of re-injection of two kinds of fracturing fluid with different salinity were researched. The experimental research of the compatibility of mixed water samples based on the static simulation method was conducted. Through the analysis of ion concentration, the amount of scale buildup and clay swelling rate, the feasibility of re-injection of different fracturing fluid were studied. The result shows that the swelling of the clay expansion rate of treated fracturing fluid is lower than the mixed water of treated fracturing fluid and the distilled water, indicating that in terms of clay expansion rate, the treated fracturing flow-back fluid is better than that of water injection after re-injection. In the compatibility test, the maximum amount of fouling in the Yangzhou oilfield is 12mg/L, and the maximum value of calcium loss rate is 1.47%, indicating that the compatibility is good. For the fracturing fluid with high salinity in the Yanchang oilfield, the maximum amount of scaling is 72mg/L, and the maximum calcium loss rate is 3.50%, indicating that the compatibility is better.

Does the Zone of Injury in Combat-Related Type III Open Tibia Fractures Preclude the Use of Local Soft Tissue Coverage?

DTIC Science & Technology

2010-11-01

delayed union , non- union , and deep infection.39 The large zone of injury surrounding the open fracture site led to the rationale that free flap coverage...also lower for the rotational flap cohort (7% versus 27%, P 0.08). The average time to fracture union for the free flap group was 9.5 months (range, 5...success of coverage, complication rates, visual pain scores, time to radiographic fracture union , and progression to amputation for local rotational

The metallogenic role of east-west fracture zones in South America with regard to the motion of lithospheric plates (with an example from Brazil)

USGS Publications Warehouse

Kutina, J.; Carter, William D.; Lopez, F.X.

1978-01-01

The role of east-west fracture zones in South America is discussed with regard to global fracturing and the motion of lithospheric plates. A set of major NW-trending lineaments has been derived which show a tendency to be spaced equidistantly and may correspond to a set of east-west fractures in the "pre-drift" position of the South American plate. Statistical analysis of linears in the ERTS-mosaics shows that NW-fractures are also among the most important ones in the Andes region, suggesting that the above major lineaments extend into the basement of the Andes. Some of the old major fractures, trending east-west in the present orientation of South America, are discussed and their NE orientation in the pre-drift position of the plate is considered. An example of structural control of ore deposition in the Brazilian Shield is presented, using the maps of the RADAM Project. It is concluded that the small tin-bearing granitic bodies concentrated in the region of Sao Felix do Xingu in the state of Para represent upper parts of an unexposed granitoid massif which is controlled by the intersection of a major east-west fracture zone probably represents westward extension of the Patos Lineament of the easternmost part of Brazil, connected with the east-west fracture zone of the Para state through the basement of the Maranhao Basin (Sineclise do Maranhao-Piaui). It is expected that the proposed "Patos-Para Lineament" extends further westward and may similarly control, at intersections with fractures of other trends, some mineralization centers in the western part of the state of Para and in the state of Amazonas.

Neocrystallization, fabrics and age of clay minerals from an exposure of the Moab Fault, Utah

USGS Publications Warehouse

Solum, J.G.; van der Pluijm, B.A.; Peacor, D.R.

2005-01-01

Pronounced changes in clay mineral assemblages are preserved along the Moab Fault (Utah). Gouge is enriched up to ???40% in 1Md illite relative to protolith, whereas altered protolith in the damage zone is enriched ???40% in illite-smectite relative to gouge and up to ???50% relative to protolith. These mineralogical changes indicate that clay gouge is formed not solely through mechanical incorporation of protolith, but also through fault-related authigenesis. The timing of mineralization is determined using 40Ar/39Ar dating of size fractions of fault rocks with varying detrital and authigenic clay content. We applied Ar dating of illite-smectite samples, as well as a newer approach that uses illite polytypes. Our analysis yields overlapping, early Paleocene ages for neoformed (1Md) gouge illite (63??2 Ma) and illite-smectite in the damage zone (60??2 Ma), which are compatible with results elsewhere. These ages represent the latest period of major fault motion, and demonstrate that the fault fabrics are not the result of recent alteration. The clay fabrics in fault rocks are poorly developed, indicating that fluids were not confined to the fault zone by preferentially oriented clays; rather we propose that fluids in the illite-rich gouge were isolated by adjacent lower permeability, illite-smectite-bearing rocks in the damage zone. ?? 2005 Elsevier Ltd. All rights reserved.

Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marcon, Virginia; Joseph, Craig; Carter, Kimberly E.

Hydraulic fracturing applied to organic-rich shales has significantly increased the recoverable volume of methane available for U.S. energy consumption. Fluid-shale reactions in the reservoir may affect long-term reservoir productivity and waste management needs through changes to fracture mineral composition and produced fluid chemical composition. We performed laboratory experiments with Marcellus Shale and lab-generated hydraulic fracturing fluid at elevated pressures and temperatures to evaluate mineral reactions and the release of trace elements into solution. Results from the experiment containing fracturing chemicals show evidence for clay and carbonate dissolution, secondary clay and anhydrite precipitation, and early-stage (24-48 h) fluid enrichment of certainmore » elements followed by depletion in later stages (i.e. Al, Cd, Co, Cr, Cu, Ni, Sc, Zn). Other elements such as As, Fe, Mn, Sr, and Y increased in concentration and remained elevated throughout the duration of the experiment with fracturing fluid. Geochemical modeling of experimental fluid data indicates primary clay dissolution, and secondary formation of smectites and barite, after reaction with fracturing fluid. Changes in aqueous organic composition were observed, indicating organic additives may be chemically transformed or sequestered by the formation after hydraulic fracturing. The NaCl concentrations in our fluids are similar to measured concentrations in Marcellus Shale produced waters, showing that these experiments are representative of reservoir fluid chemistries and can provide insight on geochemical reactions that occur in the field. These results can be applied towards evaluating the evolution of hydraulically-fractured reservoirs, and towards understanding geochemical processes that control the composition of produced water from unconventional shales.« less

Experimental insights into geochemical changes in hydraulically fractured Marcellus Shale

DOE PAGES

Marcon, Virginia; Joseph, Craig; Carter, Kimberly E.; ...

2016-11-09

Hydraulic fracturing applied to organic-rich shales has significantly increased the recoverable volume of methane available for U.S. energy consumption. Fluid-shale reactions in the reservoir may affect long-term reservoir productivity and waste management needs through changes to fracture mineral composition and produced fluid chemical composition. We performed laboratory experiments with Marcellus Shale and lab-generated hydraulic fracturing fluid at elevated pressures and temperatures to evaluate mineral reactions and the release of trace elements into solution. Results from the experiment containing fracturing chemicals show evidence for clay and carbonate dissolution, secondary clay and anhydrite precipitation, and early-stage (24-48 h) fluid enrichment of certainmore » elements followed by depletion in later stages (i.e. Al, Cd, Co, Cr, Cu, Ni, Sc, Zn). Other elements such as As, Fe, Mn, Sr, and Y increased in concentration and remained elevated throughout the duration of the experiment with fracturing fluid. Geochemical modeling of experimental fluid data indicates primary clay dissolution, and secondary formation of smectites and barite, after reaction with fracturing fluid. Changes in aqueous organic composition were observed, indicating organic additives may be chemically transformed or sequestered by the formation after hydraulic fracturing. The NaCl concentrations in our fluids are similar to measured concentrations in Marcellus Shale produced waters, showing that these experiments are representative of reservoir fluid chemistries and can provide insight on geochemical reactions that occur in the field. These results can be applied towards evaluating the evolution of hydraulically-fractured reservoirs, and towards understanding geochemical processes that control the composition of produced water from unconventional shales.« less

Enhanced cellular preservation by clay minerals in 1 billion-year-old lakes.

PubMed

Wacey, David; Saunders, Martin; Roberts, Malcolm; Menon, Sarath; Green, Leonard; Kong, Charlie; Culwick, Timothy; Strother, Paul; Brasier, Martin D

2014-07-28

Organic-walled microfossils provide the best insights into the composition and evolution of the biosphere through the first 80 percent of Earth history. The mechanism of microfossil preservation affects the quality of biological information retained and informs understanding of early Earth palaeo-environments. We here show that 1 billion-year-old microfossils from the non-marine Torridon Group are remarkably preserved by a combination of clay minerals and phosphate, with clay minerals providing the highest fidelity of preservation. Fe-rich clay mostly occurs in narrow zones in contact with cellular material and is interpreted as an early microbially-mediated phase enclosing and replacing the most labile biological material. K-rich clay occurs within and exterior to cell envelopes, forming where the supply of Fe had been exhausted. Clay minerals inter-finger with calcium phosphate that co-precipitated with the clays in the sub-oxic zone of the lake sediments. This type of preservation was favoured in sulfate-poor environments where Fe-silicate precipitation could outcompete Fe-sulfide formation. This work shows that clay minerals can provide an exceptionally high fidelity of microfossil preservation and extends the known geological range of this fossilization style by almost 500 Ma. It also suggests that the best-preserved microfossils of this time may be found in low-sulfate environments.

Enhanced cellular preservation by clay minerals in 1 billion-year-old lakes

PubMed Central

Wacey, David; Saunders, Martin; Roberts, Malcolm; Menon, Sarath; Green, Leonard; Kong, Charlie; Culwick, Timothy; Strother, Paul; Brasier, Martin D.

2014-01-01

Organic-walled microfossils provide the best insights into the composition and evolution of the biosphere through the first 80 percent of Earth history. The mechanism of microfossil preservation affects the quality of biological information retained and informs understanding of early Earth palaeo-environments. We here show that 1 billion-year-old microfossils from the non-marine Torridon Group are remarkably preserved by a combination of clay minerals and phosphate, with clay minerals providing the highest fidelity of preservation. Fe-rich clay mostly occurs in narrow zones in contact with cellular material and is interpreted as an early microbially-mediated phase enclosing and replacing the most labile biological material. K-rich clay occurs within and exterior to cell envelopes, forming where the supply of Fe had been exhausted. Clay minerals inter-finger with calcium phosphate that co-precipitated with the clays in the sub-oxic zone of the lake sediments. This type of preservation was favoured in sulfate-poor environments where Fe-silicate precipitation could outcompete Fe-sulfide formation. This work shows that clay minerals can provide an exceptionally high fidelity of microfossil preservation and extends the known geological range of this fossilization style by almost 500 Ma. It also suggests that the best-preserved microfossils of this time may be found in low-sulfate environments. PMID:25068404

Hydrogeology of a fractured shale (Opalinus Clay): Implications for deep geological disposal of radioactive wastes

NASA Astrophysics Data System (ADS)

Gautschi, Andreas

2001-01-01

As part of the Swiss programme for high-level radioactive-waste disposal, a Jurassic shale (Opalinus Clay) is being investigated as a potential host rock. Observations in clay pits and the results of a German research programme focusing on hazardous waste disposal have demonstrated that, at depths of 10-30 m, the permeability of the Opalinus Clay decreases by several orders of magnitude. Hydraulic tests in deeper boreholes (test intervals below 300 m) yielded hydraulic conductivities <10-12 m/s, even though joints and faults were included in some of the test intervals. These measurements are consistent with hydrogeological data from Opalinus Clay sections in ten tunnels in the Folded Jura of northern Switzerland. Despite extensive faulting, only a few indications of minor water inflow were encountered in more than 6,600 m of tunnel. All inflows were in tunnel sections where the overburden is less than 200 m. The hydraulic data are consistent with clay pore-water hydrochemical and isotopic data. The extensive hydrogeological data base - part of which derives from particularly unfavourable geological environments - provides arguments that advective transport through faults and joints is not a critical issue for the suitability of Opalinus Clay as a host rock for deep geological waste disposal. Résumé. Dans le cadre du programme suisse de stockage de déchets hautement radioactifs, une formation argileuse du Jurassique, l'argile à Opalinus, a été étudiée en tant que roche hôte potentielle. Des observations dans des cavités dans l'argile et les résultats du programme de recherche allemand consacré au stockage de déchets à risques ont démontré que, à des profondeur de 10 à 30 m, la perméabilité des argiles à Opalinus décroît de plusieurs ordres de grandeur. Des essais hydrauliques dans des forages plus profonds (intervalles de test á une profondeur de plus de 300 m) ont donné des conductivités hydrauliques inférieures à 10-12 m/s, m

Applying 3D Full Waveform Inversion in resolving fracture damage zones around a modelled geological disposal facility in granite

NASA Astrophysics Data System (ADS)

Bentham, H. L. M.; Morgan, J. V.; Angus, D. A.

2016-12-01

The UK has a large volume of high level and intermediate level radioactive waste and government policy is to dispose of this waste in a Geological Disposal Facility (GDF). This will be a highly-engineered facility capable of isolating radioactive waste within multiple protective barriers, deep underground, to ensure that no harmful quantities of radioactivity ever reach the surface environment. Although no specific GDF site in the UK has been chosen, granite is one of the candidate host rocks due to its strength, in engineering terms, and because of its low permeability in consideration of groundwater movement. We design time-lapse seismic surveys to characterise geological models of naturally fractured granite with GDF-related tunnel damage zones at a potential disposal depth of 1000 m (the UK GDF might be shallower). Additionally, we use effective medium models to calculate the velocity change when the fracture density is increased in the damage zones, and find a reduction of 60 m/s in P-wave velocity when the fracture density is doubled. Next, we simulate seismic surveys and apply 3D Full Waveform Inversion (FWI) to see how well we can recover the low-velocity damage zones. Furthermore we evaluate the effectiveness of using a survey design consisting of surface and tunnel receivers (a combined array) to resolve the target. After applying FWI we find the velocity anomaly within the damage zone can be resolved to within 2 m/s (3%) and the shape of the damage zone is resolved to 12.5 m (within a single grid cell). Using the combined array we are able to resolve the anomaly strength and shape more completely. When we add further complexity to the model by including tunnel infrastructure, we conclude the combined array is essential in recovering the tunnel damage zone. Our findings show that it is beneficial to use 3D FWI and novel survey designs for characterising subtle variations as may be present in granite, information that could assist in the GDF site selection

The method of lines in three dimensional fracture mechanics

NASA Technical Reports Server (NTRS)

Gyekenyesi, J.; Berke, L.

1980-01-01

A review of recent developments in the calculation of design parameters for fracture mechanics by the method of lines (MOL) is presented. Three dimensional elastic and elasto-plastic formulations are examined and results from previous and current research activities are reported. The application of MOL to the appropriate partial differential equations of equilibrium leads to coupled sets of simultaneous ordinary differential equations. Solutions of these equations are obtained by the Peano-Baker and by the recurrance relations methods. The advantages and limitations of both solution methods from the computational standpoint are summarized.

Petrophysical, Geochemical, and Hydrological Evidence for Extensive Fracture-Mediated Fluid and Heat Transport in the Alpine Fault's Hanging-Wall Damage Zone

NASA Astrophysics Data System (ADS)

Townend, John; Sutherland, Rupert; Toy, Virginia G.; Doan, Mai-Linh; Célérier, Bernard; Massiot, Cécile; Coussens, Jamie; Jeppson, Tamara; Janku-Capova, Lucie; Remaud, Léa.; Upton, Phaedra; Schmitt, Douglas R.; Pezard, Philippe; Williams, Jack; Allen, Michael John; Baratin, Laura-May; Barth, Nicolas; Becroft, Leeza; Boese, Carolin M.; Boulton, Carolyn; Broderick, Neil; Carpenter, Brett; Chamberlain, Calum J.; Cooper, Alan; Coutts, Ashley; Cox, Simon C.; Craw, Lisa; Eccles, Jennifer D.; Faulkner, Dan; Grieve, Jason; Grochowski, Julia; Gulley, Anton; Hartog, Arthur; Henry, Gilles; Howarth, Jamie; Jacobs, Katrina; Kato, Naoki; Keys, Steven; Kirilova, Martina; Kometani, Yusuke; Langridge, Rob; Lin, Weiren; Little, Tim; Lukacs, Adrienn; Mallyon, Deirdre; Mariani, Elisabetta; Mathewson, Loren; Melosh, Ben; Menzies, Catriona; Moore, Jo; Morales, Luis; Mori, Hiroshi; Niemeijer, André; Nishikawa, Osamu; Nitsch, Olivier; Paris, Jehanne; Prior, David J.; Sauer, Katrina; Savage, Martha K.; Schleicher, Anja; Shigematsu, Norio; Taylor-Offord, Sam; Teagle, Damon; Tobin, Harold; Valdez, Robert; Weaver, Konrad; Wiersberg, Thomas; Zimmer, Martin

2017-12-01

Fault rock assemblages reflect interaction between deformation, stress, temperature, fluid, and chemical regimes on distinct spatial and temporal scales at various positions in the crust. Here we interpret measurements made in the hanging-wall of the Alpine Fault during the second stage of the Deep Fault Drilling Project (DFDP-2). We present observational evidence for extensive fracturing and high hanging-wall hydraulic conductivity (˜10-9 to 10-7 m/s, corresponding to permeability of ˜10-16 to 10-14 m2) extending several hundred meters from the fault's principal slip zone. Mud losses, gas chemistry anomalies, and petrophysical data indicate that a subset of fractures intersected by the borehole are capable of transmitting fluid volumes of several cubic meters on time scales of hours. DFDP-2 observations and other data suggest that this hydrogeologically active portion of the fault zone in the hanging-wall is several kilometers wide in the uppermost crust. This finding is consistent with numerical models of earthquake rupture and off-fault damage. We conclude that the mechanically and hydrogeologically active part of the Alpine Fault is a more dynamic and extensive feature than commonly described in models based on exhumed faults. We propose that the hydrogeologically active damage zone of the Alpine Fault and other large active faults in areas of high topographic relief can be subdivided into an inner zone in which damage is controlled principally by earthquake rupture processes and an outer zone in which damage reflects coseismic shaking, strain accumulation and release on interseismic timescales, and inherited fracturing related to exhumation.

Fracture propagation and stability of ice shelves governed by ice shelf heterogeneity

NASA Astrophysics Data System (ADS)

Borstad, Chris; McGrath, Daniel; Pope, Allen

2017-05-01

Tabular iceberg calving and ice shelf retreat occurs after full-thickness fractures, known as rifts, propagate across an ice shelf. A quickly evolving rift signals a threat to the stability of Larsen C, the Antarctic Peninsula's largest ice shelf. Here we reveal the influence of ice shelf heterogeneity on the growth of this rift, with implications that challenge existing notions of ice shelf stability. Most of the rift extension has occurred in bursts after overcoming the resistance of suture zones that bind together neighboring glacier inflows. We model the stresses in the ice shelf to determine potential rift trajectories. Calving perturbations to ice flow will likely reach the grounding line. The stability of Larsen C may hinge on a single suture zone that stabilizes numerous upstream rifts. Elevated fracture toughness of suture zones may be the most important property that allows ice shelves to modulate Antarctica's contribution to sea level rise.

Characterizing Excavation Damaged Zone and Stability of Pressurized Lined Rock Caverns for Underground Compressed Air Energy Storage

NASA Astrophysics Data System (ADS)

Kim, Hyung-Mok; Rutqvist, Jonny; Jeong, Ju-Hwan; Choi, Byung-Hee; Ryu, Dong-Woo; Song, Won-Kyong

2013-09-01

In this paper, we investigate the influence of the excavation damaged zone (EDZ) on the geomechanical performance of compressed air energy storage (CAES) in lined rock caverns. We conducted a detailed characterization of the EDZ in rock caverns that have been excavated for a Korean pilot test program on CAES in (concrete) lined rock caverns at shallow depth. The EDZ was characterized by measurements of P- and S-wave velocities and permeability across the EDZ and into undisturbed host rock. Moreover, we constructed an in situ concrete lining model and conducted permeability measurements in boreholes penetrating the concrete, through the EDZ and into the undisturbed host rock. Using the site-specific conditions and the results of the EDZ characterization, we carried out a model simulation to investigate the influence of the EDZ on the CAES performance, in particular related to geomechanical responses and stability. We used a modeling approach including coupled thermodynamic multiphase flow and geomechanics, which was proven to be useful in previous generic CAES studies. Our modeling results showed that the potential for inducing tensile fractures and air leakage through the concrete lining could be substantially reduced if the EDZ around the cavern could be minimized. Moreover, the results showed that the most favorable design for reducing the potential for tensile failure in the lining would be a relatively compliant concrete lining with a tight inner seal, and a relatively stiff (uncompliant) host rock with a minimized EDZ. Because EDZ compliance depends on its compressibility (or modulus) and thickness, care should be taken during drill and blast operations to minimize the damage to the cavern walls.

Transport of Organic Solutes in Clay Formations

EPA Science Inventory

The research is a pilot investigation for the SERDP (Strategic Environmental Research and Development Program, DoD) founded project, Impact of Clay-DNAPL Interactions on Transport and Storage of Chlorinated Solvents in Low Permeability Zones, from 2010-2012. The report tries to s...

Iodide uptake by negatively charged clay interlayers?

PubMed

Miller, Andrew; Kruichak, Jessica; Mills, Melissa; Wang, Yifeng

2015-09-01

Understanding iodide interactions with clay minerals is critical to quantifying risk associated with nuclear waste disposal. Current thought assumes that iodide does not interact directly with clay minerals due to electrical repulsion between the iodide and the negatively charged clay layers. However, a growing body of work indicates a weak interaction between iodide and clays. The goal of this contribution is to report a conceptual model for iodide interaction with clays by considering clay mineral structures and emergent behaviors of chemical species in confined spaces. To approach the problem, a suite of clay minerals was used with varying degrees of isomorphic substitution, chemical composition, and mineral structure. Iodide uptake experiments were completed with each of these minerals in a range of swamping electrolyte identities (NaCl, NaBr, KCl) and concentrations. Iodide uptake behaviors form distinct trends with cation exchange capacity and mineral structure. These trends change substantially with electrolyte composition and concentration, but do not appear to be affected by solution pH. The experimental results suggest that iodide may directly interact with clays by forming ion-pairs (e.g., NaI(aq)) which may concentrate within the interlayer space as well as the thin areas surrounding the clay particle where water behavior is more structured relative to bulk water. Ion pairing and iodide concentration in these zones is probably driven by the reduced dielectric constant of water in confined space and by the relatively high polarizability of the iodide species. Copyright © 2015 Elsevier Ltd. All rights reserved.

The Comprehensive AOCMF Classification System: Condylar Process Fractures - Level 3 Tutorial.

PubMed

Neff, Andreas; Cornelius, Carl-Peter; Rasse, Michael; Torre, Daniel Dalla; Audigé, Laurent

2014-12-01

This tutorial outlines the detailed system for fractures of the condylar process at the precision level 3 and is organized in a sequence of sections dealing with the description of the classification system within topographical subdivisions along with rules for fracture coding and a series of case examples with clinical imaging. Basically, the condylar process comprises three fracture levels and is subdivided into the head region, the condylar neck, and the condylar base. Fractures of the condylar head show typical fracture lines either within the lateral pole zone, which may lead to loss of vertical height, or medially to the pole zone, with the latter ones usually not compromising the vertical condyle to fossa relation. In condylar head fractures, the morphology is further described by the presence of minor or major fragmentation, the vertical apposition of fragments at the plane of the head fracture, the displacement of the condylar head with regard to the fossa including a potential distortion of the condylar head congruency resulting in dystopic condyle to fossa relations and the presence or absence of a loss of vertical ramus height. A specific vertical fracture pattern extending from the head to the neck or base subregion is considered. Fractures of the condylar neck and base can be differentiated according to a newly introduced one-third to two-thirds rule with regard to the proportion of the fracture line above and below the level of the sigmoid notch, which is presented in the classification article, and are basically subdivided according to the presence or absence of displacement or dislocation. In both condylar neck and base fractures, the classification is again based on the above mentioned parameters such as fragmentation, displacement of the condylar head with regard to the fossa, including dystopic condyle to fossa relations and loss of vertical ramus height, that is, according to the measurement of the condylar process. In addition, the

Owen Fracture Zone: The Arabia-India plate boundary unveiled

NASA Astrophysics Data System (ADS)

Fournier, M.; Chamot-Rooke, N.; Rodriguez, M.; Huchon, P.; Petit, C.; Beslier, M. O.; Zaragosi, S.

2011-02-01

We surveyed the Owen Fracture Zone at the boundary between the Arabia and India plates in the NW Indian Ocean using a high-resolution multibeam echo-sounder (Owen cruise, 2009) for search of active faults. Bathymetric data reveal a previously unrecognized submarine fault scarp system running for over 800 km between the Sheba Ridge in the Gulf of Aden and the Makran subduction zone. The primary plate boundary structure is not the bathymetrically high Owen Ridge, but is instead a series of clearly delineated strike-slip fault segments separated by several releasing and restraining bends. Despite an abundant sedimentary supply by the Indus River flowing from the Himalaya, fault scarps are not obscured by recent deposits and can be followed over hundreds of kilometres, pointing to very active tectonics. The total strike-slip displacement of the fault system is 10-12 km, indicating that it has been active for the past ~ 3 to 6 Ma if its current rate of motion of 3 ± 1 mm yr- 1 has remained stable. We describe the geometry of this recent fault system, including a major pull-apart basin at the latitude 20°N, and we show that it closely follows an arc of small circle centred on the Arabia-India pole of rotation, as expected for a transform plate boundary.

UNDERSTANDING HARD ROCK HYDROGEOLOGY THROUGH AN EXPERIMENTAL HYDROGEOLOGICAL PARK IN SOUTH INDIA: Site development and investigations on the major role of the fractured zone in crystalline aquifers

NASA Astrophysics Data System (ADS)

Ahmed, S.; Guiheneuf, N.; Boisson, A.; Marechal, J.; Chandra, S.; Dewandel, B.; Perrin, J.

2012-12-01

In water stressed south India most of the groundwater used for irrigation is pumped from crystalline rocks aquifers. In those structures groundwater flow dominantly occur in a shallow higher-permeability zone that overlies a deeper lower-permeability zone hosting little flow. The fractured zone of the weathering profile plays an important role for groundwater. In order to understand clearly this impact on water availability and quality changes the Experimental Hydrogeological Park at Choutuppal, Andhra Pradesh, India is developed in the framework of the SORE H+ network. Several hydraulic tests (injection, flowmeter profiles, single-packer tests…) and geophysical measurements (ERT, Borehole logging…) are carried out on the site in order to characterize the depth-dependence of hydrodynamic parameters in the Indian Archean granite. Specific investigation on a borewell through packer tests demonstrate that the most conductive part of the aquifer corresponds to the upper part of the fractured layer, located just below the saprolite bottom, between 15 meters and 20 meters depth. There is no highly conductive fracture beyond 20 meters depth and no indication for any conductive fracture beyond 25 meters depth. Packer tests show that the upper part of the fractured layer (15-20 m depth) is characterized by a good vertical connectivity. On the contrary, the tests carried out below 20 m depth show no vertical connectivity at all. The geometry of the fracture network and associated hydrodynamic parameters are in agreement with the conceptual model of hard-rock aquifers that derive its properties from weathering processes. The general existence of such a highly conductive structure at the top of the fractured zone has a great impact on water prospection and exploitation in such crystalline aquifers.

Modelling Subduction Zone Magmatism Due to Hydraulic Fracture

NASA Astrophysics Data System (ADS)

Lawton, R.; Davies, J. H.

2014-12-01

The aim of this project is to test the hypothesis that subduction zone magmatism involves hydraulic fractures propagating from the oceanic crust to the mantle wedge source region (Davies, 1999). We aim to test this hypothesis by developing a numerical model of the process, and then comparing model outputs with observations. The hypothesis proposes that the water interconnects in the slab following an earthquake. If sufficient pressure develops a hydrofracture occurs. The hydrofracture will expand in the direction of the least compressive stress and propagate in the direction of the most compressive stress, which is out into the wedge. Therefore we can calculate the hydrofracture path and end-point, given the start location on the slab and the propagation distance. We can therefore predict where water is added to the mantle wedge. To take this further we have developed a thermal model of a subduction zone. The model uses a finite difference, marker-in-cell method to solve the heat equation (Gerya, 2010). The velocity field was prescribed using the analytical expression of cornerflow (Batchelor, 1967). The markers contained within the fixed grid are used to track the different compositions and their properties. The subduction zone thermal model was benchmarked (Van Keken, 2008). We used the hydrous melting parameterization of Katz et.al., (2003) to calculate the degree of melting caused by the addition of water to the wedge. We investigate models where the hydrofractures, with properties constrained by estimated water fluxes, have random end points. The model predicts degree of melting, magma productivity, temperature of the melt and water content in the melt for different initial water fluxes. Future models will also include the buoyancy effect of the melt and residue. Batchelor, Cambridge UP, 1967. Davies, Nature, 398: 142-145, 1999. Gerya, Cambridge UP, 2010. Katz, Geochem. Geophys. Geosy, 4(9), 2003 Van Keken et.al. Phys. Earth. Planet. In., 171:187-197, 2008.

Geophysical investigation of seamounts near the Ogasawara Fracture Zone, western Pacific

NASA Astrophysics Data System (ADS)

Lee, T.-G.; Lee, K.; Hein, J. R.; Moon, J.-W.

2009-03-01

This paper provides an analysis of multi-channel seismic data obtained during 2000-2001 on seamounts near the Ogasawara Fracture Zone (OFZ) northwest of the Marshall Islands in the western Pacific. The OFZ is unique in that it is a wide rift zone that includes many seamounts. Seven units are delineated on the basis of acoustic characteristics and depth: three units (I, II, and III) on the summit of seamounts and four units (IV, V, VI, and VII) in basins. Acoustic characteristics of layers on the summit of guyots and dredged samples indicate that the seamounts had been built above sea level by volcanism. This was followed by reef growth along the summit margin, which enabled deposition of shallow-water carbonates on the summit, and finally by subsidence of the edifices. The subsidence depth of the seamounts, estimated from the lower boundary of unit II, ranges between 1,550 and 2,040 m. The thick unit I of the southern seamounts is correlated with proximity to the equatorial high productivity zone, whereas local currents may have strongly affected the distribution of unit I on northern seamounts. A seismic profile in the basin around the Ita Mai Tai and OSM4 seamounts shows an unconformity between units IV and V, which is widespread from the East Mariana Basin to the Pigafetta Basin.

Delineation of faults, fractures, foliation, and ground-water-flow zones in fractured-rock, on the southern part of Manhattan, New York, through use of advanced borehole-geophysical techniques

USGS Publications Warehouse

Stumm, Frederick; Chu, Anthony; Monti, Jack

2004-01-01

Advanced borehole-geophysical techniques were used to assess the geohydrology of crystalline bedrock in 20 boreholes on the southern part of Manhattan Island, N.Y., in preparation for construction of a third water tunnel for New York City. The borehole-logging techniques included natural gamma, single-point resistance, short-normal resistivity, mechanical and acoustic caliper, magnetic susceptibility, borehole-fluid temperature and resistivity, borehole-fluid specific conductance, dissolved oxygen, pH, redox, heatpulse flowmeter (at selected boreholes), borehole deviation, acoustic and optical televiewer, and borehole radar (at selected boreholes). Hydraulic head and specific-capacity test data were collected from 29 boreholes. The boreholes penetrated gneiss, schist, and other crystalline bedrock that has an overall southwest to northwest-dipping foliation. Most of the fractures penetrated are nearly horizontal or have moderate- to high-angle northwest or eastward dip azimuths. Foliation dip within the potential tunnel-construction zone is northwestward and southeastward in the proposed North Water-Tunnel, northwestward to southwestward in the proposed Midtown Water-Tunnel, and northwestward to westward dipping in the proposed South Water-Tunnel. Fracture population dip azimuths are variable. Heat-pulse flowmeter logs obtained under pumping and nonpumping (ambient) conditions, together with other geophysical logs, indicate transmissive fracture zones in each borehole. The 60-megahertz directional borehole-radar logs delineated the location and orientation of several radar reflectors that did not intersect the projection of the borehole.Fracture indexes range from 0.12 to 0.93 fractures per foot of borehole. Analysis of specific-capacity tests from each borehole indicated that transmissivity ranges from 2 to 459 feet squared per day; the highest transmissivity is at the Midtown Water-Tunnel borehole (E35ST-D).

Trace Elements in Basalts From the Siqueiros Fracture Zone: Implications for Melt Migration Models

NASA Astrophysics Data System (ADS)

Pickle, R. C.; Forsyth, D. W.; Saal, A. E.; Nagle, A. N.; Perfit, M. R.

2008-12-01

Incompatible trace element (ITE) ratios in MORB from a variety of locations may provide insights into the melt migration process by constraining aggregated melt compositions predicted by mantle melting and flow models. By using actual plate geometries to create a 3-D thermodynamic mantle model, melt volumes and compositions at all depths and locations may be calculated and binned into cubes using the pHMELTS algorithm [Asimow et al., 2004]. These melts can be traced from each cube to the surface assuming several migration models, including a simplified pressure gradient model and one in which melt is guided upwards by a low permeability compacted layer. The ITE ratios of all melts arriving at the surface are summed, averaged, and compared to those of the actual sample compositions from the various MOR locales. The Siqueiros fracture zone at 8° 20' N on the East Pacific Rise (EPR) comprises 4 intra-transform spreading centers (ITSCs) across 140 km of offset between two longer spreading ridges, and is an excellent study region for several reasons. First, an abundance of MORB data is readily available, and the samples retrieved from ITSCs are unlikely to be aggregated in a long-lived magma chamber or affected by along-axis transport, so they represent melts extracted locally from the mantle. Additionally, samples at Siqueiros span a compositional range from depleted to normal MORB within the fracture zone yet have similar isotopic compositions to samples collected from the 9-10° EPR. This minimizes the effect of assuming a uniform source composition in our melting model despite a heterogeneous mantle, allowing us to consistently compare the actual lava composition with that predicted by our model. Finally, it has been demonstrated with preliminary migration models that incipient melts generated directly below an ITSC may not necessarily erupt at that ITSC but migrate laterally towards a nearby ridge due to enhanced pressure gradients. The close proximity of the

Influence of Clay Content, Mineralogy and Fabric On Radar Frequency Response of Aquifer Materials

NASA Astrophysics Data System (ADS)

West, L. J.; Handley, K.

High frequency electromagnetic methods such as ground penetrating radar (GPR) and time domain reflectometry (TDR) are widely employed to measure water saturation in the vadose zone and water filled porosity in the saturated zone. However, previous work has shown that radar frequency dielectric properties are strongly influenced by clay as well as by water content. They have also shown that that the dielectric response of clay minerals is strongly frequency dependent, and that even a small proportion of clay such as that present in many sandstone aquifers can have a large effect at typi- cal GPR frequencies (around 100MHz). Hence accurate water content/porosity deter- mination requires clay type and content to be taken into account. Reported here are dielectric measurements on clay-sand mixtures, aimed at investigating the influence of clay mineralogy, particle shape, and the geometrical arrangement of the mixture constituents on GPR and TDR response. Dielectric permittivity (at 50-1000MHz) was measured for mixtures of Ottawa Sand and various clay minerals or clay size quartz rock flour, using a specially constructed dielectric cell. Both homogeneous and layered mixtures were tested. The influence of pore water salinity, clay type, and particle arrangement on the dielectric response is interpreted in terms of dielectric dispersion mechanisms. The appropriateness of var- ious dielectric mixing rules such as the Complex Refractive Index Method (CRIM) for determination of water content or porosity from field GPR and TDR data are dis- cussed.

Atomistically derived cohesive zone model of intergranular fracture in polycrystalline graphene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guin, Laurent; Department of Mechanical Engineering, Columbia University, New York, New York 10027; Raphanel, Jean L.

2016-06-28

Pristine single crystal graphene is the strongest known two-dimensional material, and its nonlinear anisotropic mechanical properties are well understood from the atomic length scale up to a continuum description. However, experiments indicate that grain boundaries in the polycrystalline form reduce the mechanical behavior of polycrystalline graphene. Herein, we perform atomistic-scale molecular dynamics simulations of the deformation and fracture of graphene grain boundaries and express the results as continuum cohesive zone models (CZMs) that embed notions of the grain boundary ultimate strength and fracture toughness. To facilitate energy balance, we employ a new methodology that simulates a quasi-static controlled crack propagationmore » which renders the kinetic energy contribution to the total energy negligible. We verify good agreement between Griffith's critical energy release rate and the work of separation of the CZM, and we note that the energy of crack edges and fracture toughness differs by about 35%, which is attributed to the phenomenon of bond trapping. This justifies the implementation of the CZM within the context of the finite element method (FEM). To enhance computational efficiency in the FEM implementation, we discuss the use of scaled traction-separation laws (TSLs) for larger element sizes. As a final result, we have established that the failure characteristics of pristine graphene and high tilt angle bicrystals differ by less than 10%. This result suggests that one could use a unique or a few typical TSLs as a good approximation for the CZMs associated with the mechanical simulations of the polycrystalline graphene.« less

76 FR 76044 - Safety Zone; Power Line Replacement, West Bay, Panama City, FL

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-06

... DEPARTMENT OF HOMELAND SECURITY Coast Guard 33 CFR Part 165 [Docket No. USCG-2011-0983] RIN 1625-AA00 Safety Zone; Power Line Replacement, West Bay, Panama City, FL AGENCY: Coast Guard, DHS. ACTION..., West Bay, Panama City, FL (a) Location. The following area is a safety zone: A portion of West Bay...

Creep and Sliding in Clay Slopes: Mutual Effects of Interlayer Swelling and Ice Jacking.

DTIC Science & Technology

1983-04-24

calcite and feldspar constituents. Therefore a swelling clay with low diagenetic lithification (matrix forming) e fects. Therefore, the clay shows...were determined quantitatively (Tab. 2). The CEC depends mainly on the montmorillonite content and shows values up to 86 meq/lOOg, which Indicates...high montmorillonite clays. First freezing tests have been performed within a freezer. After freezing, three typical zones within the samples can be

Percolation characteristics of solvent invasion in rough fractures under miscible conditions

NASA Astrophysics Data System (ADS)

Korfanta, M.; Babadagli, T.; Develi, K.

2017-10-01

Surface roughness and flow rate effects on the solvent transport under miscible conditions in a single fracture are studied. Surface replicas of seven different rocks (marble, granite, and limestone) are used to represent different surface roughness characteristics each described by different mathematical models including three fractal dimensions. Distribution of dyed solvent is investigated at various flow rate conditions to clarify the effect of roughness on convective and diffusive mixing. After a qualitative analysis using comparative images of different rocks, the area covered by solvent with respect to time is determined to conduct a semi-quantitative analysis. In this exercise, two distinct zones are identified, namely the straight lines obtained for convective (early times) and diffusive (late times) flow. The bending point between these two lines is used to point the transition between the two zones. Finally, the slopes of the straight lines and the bending points are correlated to five different roughness parameters and the rate (Peclet number). It is observed that both surface roughness and flow rate have significant effect on solvent spatial distribution. The largest area covered is obtained at moderate flow rates and hence not only the average surface roughness characteristic is important, but coessentially total fracture surface area needs to be considered when evaluating fluid distribution. It is also noted that the rate effect is critically different for the fracture samples of large grain size (marbles and granite) compared to smaller grain sizes (limestones). Variogram fractal dimension exhibits the strongest correlation with the maximum area covered by solvent, and display increasing trend at the moderate flow rates. Equations with variogram surface fractal dimension in combination with any other surface fractal parameter coupled with Peclet number can be used to predict maximum area covered by solvent in a single fracture, which in turn can be

Identifying fracture‐zone geometry using simulated annealing and hydraulic‐connection data

USGS Publications Warehouse

Day-Lewis, Frederick D.; Hsieh, Paul A.; Gorelick, Steven M.

2000-01-01

A new approach is presented to condition geostatistical simulation of high‐permeability zones in fractured rock to hydraulic‐connection data. A simulated‐annealing algorithm generates three‐dimensional (3‐D) realizations conditioned to borehole data, inferred hydraulic connections between packer‐isolated borehole intervals, and an indicator (fracture zone or background‐K bedrock) variogram model of spatial variability. We apply the method to data from the U.S. Geological Survey Mirror Lake Site in New Hampshire, where connected high‐permeability fracture zones exert a strong control on fluid flow at the hundred‐meter scale. Single‐well hydraulic‐packer tests indicate where permeable fracture zones intersect boreholes, and multiple‐well pumping tests indicate the degree of hydraulic connection between boreholes. Borehole intervals connected by a fracture zone exhibit similar hydraulic responses, whereas intervals not connected by a fracture zone exhibit different responses. Our approach yields valuable insights into the 3‐D geometry of fracture zones at Mirror Lake. Statistical analysis of the realizations yields maps of the probabilities of intersecting specific fracture zones with additional wells. Inverse flow modeling based on the assumption of equivalent porous media is used to estimate hydraulic conductivity and specific storage and to identify those fracture‐zone geometries that are consistent with hydraulic test data.

Controls on fracture distribution in the Giddings Austin Chalk

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wagner, D.T.

1990-09-01

Fracture distribution in the Giddings Austin Chalk is controlled by both structure and the stratigraphy of the Austin Group. Parameters that most affect reservoir performance include fracture width, height, and spacing, as well as the number of fracture sets and their orientations. Lateral variance of these parameters is a function of structural position, while vertical change is related to stratigraphy. The Austin Chalk productive trend is thought to coincide with the hingeline of the Gulf Coast basin, where extension has been concentrated during subsidence of the basin. Fracturing is attributed to a number of mechanisms including normal faulting, bending overmore » buried structures, gravity creep, differential compaction, and aquathermal pressuring. A change in structural style from faulting to flexure takes place from west to east across the Giddings field, accompanied by a change in fracture distribution. In the west, fractures develop only in close proximity to faults whereas in the east they are more widely distributed over broad warps. Stratigraphic controls include lithology, porosity, bed thickness, and ductility contrast between adjacent beds. The Austin Chalk consists of sparse biomicrite interbedded with marls, shales, and clay seams. In general, thin beds are more highly fractured than thick beds, and clean limestone is more highly fractured than marl or shale. Where the more ductile marls and clays exceed a critical thickness, fractures tend to terminate within individual chalk beds, resulting in barriers to vertical flow within the reservoir.« less

Characterisation and monitoring of the Excavation Disturbed Zone (EDZ) in fractured gneisses of the Roselend underground laboratory: permeability measurements, transport property changes and related radon bursts

NASA Astrophysics Data System (ADS)

Wassermann, Jérôme; Sabroux, Jean-Christophe; Richon, Patrick; Pontreau, Sébastien; Guillon, Sophie; Pili, Eric

2010-05-01

pressure measurements between an obturated borehole and the tunnel is conducted to monitor the possible modifications of the transport properties of the EDZ due to hydraulical and/or mechanical sollicitations of the nearby Roselend reservoir lake. As radon level is controlled by emanation and transport path through the medium. The observed bursts of radon should be due to changes of the radon transport properties (Trique et al. 1999) of the EDZ. A correlation between the differential pressure variations and radon bursts is clearly observed. Radon bursts seem to be related to overpressure events that take place in the instrumented borehole. Which external sollicitations, hydraulical or mechanical, or both, induce such a behaviour? References Bossart, P., Meier, P. M., Moeri, A., Trick, T., and J.-C. Mayor (2002). Geological and hydraulic characterisation of the excavation disturbed zone in the Opalinus Clay of the Mont Terri Rock Laboratory, Engineering Geology, 66, 19-38. Dezayes, C., and T. Villemin (2002). Etat de la fracturation dans la galerie CEA de Roselend et analyse de la déformation cassante dans le massif du Méraillet, technical report, Lab. de Geodyn. de Chaisnes Alp., Univ. de Savoie, Savoie, France. Jakubick, A. T., and T. Franz (1993). Vacuum testing of the permeability of the excavation damaged zone, Rock Mech. Rock Engng., 26(2), 165-182. Patriarche, D., Pili, E., Adler, P. M., and J.-F. Thovert (2007). Stereological analysis of fractures in the Roselend tunnel and permeability determination, Water Resour. Res., 43, W09421. Richon, P., Perrier, F., Sabroux, J.-C., Trique, M., Ferry, C., Voisin, V., and E. Pili (2004). Spatial and time variations of radon-222 concentration in the atmosphere of a dead-end horizontal tunnel, J. Environ. Radioact., 78, 179-198. Richon, P., Perrier, F., Pili, E., and J.-C. Sabroux (2009). Detectability and significance of the 12hr barometric tide in radon-222 signal, dripwater flow rate, air temperature and carbon dioxide

Revised Pacific-Antarctic plate motions and geophysics of the Menard Fracture Zone

NASA Astrophysics Data System (ADS)

Croon, Marcel B.; Cande, Steven C.; Stock, Joann M.

2008-07-01

A reconnaissance survey of multibeam bathymetry and magnetic anomaly data of the Menard Fracture Zone allows for significant refinement of plate motion history of the South Pacific over the last 44 million years. The right-stepping Menard Fracture Zone developed at the northern end of the Pacific-Antarctic Ridge within a propagating rift system that generated the Hudson microplate and formed the conjugate Henry and Hudson Troughs as a response to a major plate reorganization ˜45 million years ago. Two splays, originally about 30 to 35 km apart, narrowed gradually to a corridor of 5 to 10 km width, while lineation azimuths experienced an 8° counterclockwise reorientation owing to changes in spreading direction between chrons C13o and C6C (33 to 24 million years ago). We use the improved Pacific-Antarctic plate motions to analyze the development of the southwest end of the Pacific-Antarctic Ridge. Owing to a 45° counterclockwise reorientation between chrons C27 and C20 (61 to 44 million years ago) this section of the ridge became a long transform fault connected to the Macquarie Triple Junction. Following a clockwise change starting around chron C13o (33 million years ago), the transform fault opened. A counterclockwise change starting around chron C10y (28 millions years ago) again led to a long transform fault between chrons C6C and C5y (24 to 10 million years ago). A second period of clockwise reorientation starting around chron C5y (10 million years ago) put the transform fault into extension, forming an array of 15 en echelon transform faults and short linking spreading centers.

Influence of diameter on particle transport in a fractured shale saprolite

USGS Publications Warehouse

Cumbie, D.H.; McKay, L.D.

1999-01-01

Experiments in an undisturbed, saturated column of weathered and fractured shale saprolite using fluorescent carboxylate-coated latex microspheres as tracers indicate that particle diameter plays a major role in controlling transport. In this study the optimum microsphere diameter for transport was approximately 0.5 ??m. Microspheres larger than the optimum size were present in the effluent at lower relative concentrations, apparently because of greater retention due to gravitational settling and/or physical straining. The smaller than optimum microspheres also experienced greater retention, apparently related to their higher rates of diffusion. Faster diffusion can lead to more frequent collisions with, and attachment to, fracture walls and may also lead to movement of particles into zones of relatively immobile pore water in the fractures or in the fine pore structure of the clay-rich matrix between fractures. Dismantling of the soil column and mapping of the distribution of retained microspheres indicated that there was substantial size-segregation of the microspheres between different fractures or in 'channels' within a fracture. Examination of small core samples showed that the smallest microspheres (0.05-0.1 ??m) were present in the fine pores of the matrix at distances of up to 3-4 mm from the nearest fracture, which supports the hypothesis that small particles can be retained by diffusion into the matrix. Calculations of settling velocity and diffusion rate using simple 1D approaches suggest that these processes could both cause significant retention of the larger and smaller particles, respectively, even for the fast advective transport rates (up to 32 m/day) observed during the experiments. Copyright (C) 1999 Elsevier Science B.V.

Quantitative Characterisation of Fracturing Around the Damage Zone Surrounding New Zealand's Alpine Fault Using X-ray CT Scans of DFDP-1 Core

NASA Astrophysics Data System (ADS)

Williams, J. N.; Toy, V.; Massiot, C.; Mcnamara, D. D.; Wang, T.

2015-12-01

X-ray computer tomography (CT) scans of core recovered from the first phase of the Deep Fault Drilling Project (DFDP-1) through the Alpine Fault provide an excellent opportunity to analyse brittle deformation around the fault. In particular, assessment can be made of the heavily fractured protolith constituting the damage zone. Damage zone structures are divided into two types that result from two distinct processes: (1) "off fault damage" formed by stress changes induced by the passage of a seismic rupture and (2) "off fault deformation" that represent structures, which accommodate strain around the fault that was not localised on the principal slip zone (PSZ). The distribution of these damage zones structures within CT scans of the recovered core was measured along a scanline parallel to the core axis and assessed using a weighted moving average technique to account for orientation bias. The results of this analysis reveal that within the part of the fault rocks sampled by DFDP-1 there is no increase in density of these structures towards the PSZ. This is in agreement with independent analysis using Borehole Televiewer Data of the DFDP-1B borehole. Instead, we consider the density of these structures to be controlled to the first order by lithology, which modulates the mechanical properties of the fault rocks such as its frictional strength and cohesion. Comparisons of fracture density to p-wave velocities obtained from wireline logs indicate they are independent of each other, therefore, for the cores sampled in this study fractures impart no influence on the elastic properties of the rock. This is consistent with the observation from core that the majority of fractures are cemented. We consider how this might influence future rupture dynamics.

Sub-seafloor acoustic characterization of seamounts near the Ogasawara Fracture Zone in the western Pacific using chirp (3-7 kHz) subbottom profiles

USGS Publications Warehouse

Lee, T.-G.; Hein, J.R.; Lee, Kenneth; Moon, J.-W.; Ko, Y.-T.

2005-01-01

A detailed analysis of chirp (3-7 kHz) subbottom profiles and bathymetry was performed on data collected from seamounts near the Ogasawara Fracture Zone (OFZ) in the western Pacific. The OFZ, which is a 150 km wide rift zone showing 600 km of right-lateral movement in a NW-SE direction, is unique among the fracture zones of the Pacific in that it includes many old seamounts (e.g., Magellan Seamounts and seamounts on Dutton Ridge). Sub-seafloor acoustic echoes on the seamounts are classified into nine specific types based on the nature and continuity of the echoes, subbottom structure, and morphology of the seafloor: (1) distinct echoes (types I-1, I-2, I-3), (2) indistinct echoes (types II-1, II-2, II-3), and (3) hyperbolic echoes (types III-1, III-2, III-3). Type I-2 pelagic sediments, characterized by thin and intermittent coverage, were probably deposited in topographically sheltered areas when bottom currents were strong, whereas type I-1 pelagic sediments accumulated during continuous and widespread sedimentation. Development of seamount flank rift zones in the OFZ may have been influenced by preexisting structures in the transform fracture zone at the time of volcanism, whereas those on Ita Mai Tai seamount in the Pigafetta Basin originated solely by edifice-building processes. Flank rift zones that formed by dike intrusions and eruptions played an important role in mass wasting. Mass-wasting processes included block faulting or block slides around the summit margin, sliding/slumping, debris flows, and turbidites, which may have been triggered by faulting, volcanism, dike injection, and weathering during various stages in the evolution of the seamounts. ?? 2005 Elsevier Ltd. All rights reserved.

Regional Survey of Structural Properties and Cementation Patterns of Fault Zones in the Northern Part of the Albuquerque Basin, New Mexico - Implications for Ground-Water Flow

USGS Publications Warehouse

Minor, Scott A.; Hudson, Mark R.

2006-01-01

Motivated by the need to document and evaluate the types and variability of fault zone properties that potentially affect aquifer systems in basins of the middle Rio Grande rift, we systematically characterized structural and cementation properties of exposed fault zones at 176 sites in the northern Albuquerque Basin. A statistical analysis of measurements and observations evaluated four aspects of the fault zones: (1) attitude and displacement, (2) cement, (3) lithology of the host rock or sediment, and (4) character and width of distinctive structural architectural components at the outcrop scale. Three structural architectural components of the fault zones were observed: (1) outer damage zones related to fault growth; these zones typically contain deformation bands, shear fractures, and open extensional fractures, which strike subparallel to the fault and may promote ground-water flow along the fault zone; (2) inner mixed zones composed of variably entrained, disrupted, and dismembered blocks of host sediment; and (3) central fault cores that accommodate most shear strain and in which persistent low- permeability clay-rich rocks likely impede the flow of water across the fault. The lithology of the host rock or sediment influences the structure of the fault zone and the width of its components. Different grain-size distributions and degrees of induration of the host materials produce differences in material strength that lead to variations in width, degree, and style of fracturing and other fault-related deformation. In addition, lithology of the host sediment appears to strongly control the distribution of cement in fault zones. Most faults strike north to north-northeast and dip 55? - 77? east or west, toward the basin center. Most faults exhibit normal slip, and many of these faults have been reactivated by normal-oblique and strike slip. Although measured fault displacements have a broad range, from 0.9 to 4,000 m, most are <100 m, and fault zones appear to

Preferential flow, diffuse flow, and perching in an interbedded fractured-rock unsaturated zone

NASA Astrophysics Data System (ADS)

Nimmo, John R.; Creasey, Kaitlyn M.; Perkins, Kim S.; Mirus, Benjamin B.

2017-03-01

Layers of strong geologic contrast within the unsaturated zone can control recharge and contaminant transport to underlying aquifers. Slow diffuse flow in certain geologic layers, and rapid preferential flow in others, complicates the prediction of vertical and lateral fluxes. A simple model is presented, designed to use limited geological site information to predict these critical subsurface processes in response to a sustained infiltration source. The model is developed and tested using site-specific information from the Idaho National Laboratory in the Eastern Snake River Plain (ESRP), USA, where there are natural and anthropogenic sources of high-volume infiltration from floods, spills, leaks, wastewater disposal, retention ponds, and hydrologic field experiments. The thick unsaturated zone overlying the ESRP aquifer is a good example of a sharply stratified unsaturated zone. Sedimentary interbeds are interspersed between massive and fractured basalt units. The combination of surficial sediments, basalts, and interbeds determines the water fluxes through the variably saturated subsurface. Interbeds are generally less conductive, sometimes causing perched water to collect above them. The model successfully predicts the volume and extent of perching and approximates vertical travel times during events that generate high fluxes from the land surface. These developments are applicable to sites having a thick, geologically complex unsaturated zone of substantial thickness in which preferential and diffuse flow, and perching of percolated water, are important to contaminant transport or aquifer recharge.

Preferential flow, diffuse flow, and perching in an interbedded fractured-rock unsaturated zone

USGS Publications Warehouse

Nimmo, John R.; Creasey, Kaitlyn M; Perkins, Kimberlie; Mirus, Benjamin B.

2017-01-01

Layers of strong geologic contrast within the unsaturated zone can control recharge and contaminant transport to underlying aquifers. Slow diffuse flow in certain geologic layers, and rapid preferential flow in others, complicates the prediction of vertical and lateral fluxes. A simple model is presented, designed to use limited geological site information to predict these critical subsurface processes in response to a sustained infiltration source. The model is developed and tested using site-specific information from the Idaho National Laboratory in the Eastern Snake River Plain (ESRP), USA, where there are natural and anthropogenic sources of high-volume infiltration from floods, spills, leaks, wastewater disposal, retention ponds, and hydrologic field experiments. The thick unsaturated zone overlying the ESRP aquifer is a good example of a sharply stratified unsaturated zone. Sedimentary interbeds are interspersed between massive and fractured basalt units. The combination of surficial sediments, basalts, and interbeds determines the water fluxes through the variably saturated subsurface. Interbeds are generally less conductive, sometimes causing perched water to collect above them. The model successfully predicts the volume and extent of perching and approximates vertical travel times during events that generate high fluxes from the land surface. These developments are applicable to sites having a thick, geologically complex unsaturated zone of substantial thickness in which preferential and diffuse flow, and perching of percolated water, are important to contaminant transport or aquifer recharge.

Fractures of the proximal fifth metatarsal: percutaneous bicortical fixation.

PubMed

Mahajan, Vivek; Chung, Hyun Wook; Suh, Jin Soo

2011-06-01

Displaced intraarticular zone I and displaced zone II fractures of the proximal fifth metatarsal bone are frequently complicated by delayed nonunion due to a vascular watershed. Many complications have been reported with the commonly used intramedullary screw fixation for these fractures. The optimal surgical procedure for these fractures has not been determined. All these observations led us to evaluate the effectiveness of percutaneous bicortical screw fixation for treating these fractures. Twenty-three fractures were operatively treated by bicortical screw fixation. All the fractures were evaluated both clinically and radiologically for the healing. All the patients were followed at 2 or 3 week intervals till fracture union. The patients were followed for an average of 22.5 months. Twenty-three fractures healed uneventfully following bicortical fixation, with a mean healing time of 6.3 weeks (range, 4 to 10 weeks). The average American Orthopaedic Foot & Ankle Society (AOFAS) score was 94 (range, 90 to 99). All the patients reported no pain at rest or during athletic activity. We removed the implant in all cases at a mean of 23.2 weeks (range, 18 to 32 weeks). There was no refracture in any of our cases. The current study shows the effectiveness of bicortical screw fixation for displaced intraarticular zone I fractures and displaced zone II fractures. We recommend it as one of the useful techniques for fixation of displaced zone I and II fractures.

Ability of modern distal tibia plates to stabilize comminuted pilon fracture fragments: Is dual plate fixation necessary?

PubMed

Penny, Phillip; Swords, Michael; Heisler, Jason; Cien, Adam; Sands, Andrew; Cole, Peter

2016-08-01

The purpose of this study was to examine the screw trajectory of ten commercially available distal tibia plates and compare them to common fracture patterns seen in OTA C type pilon fractures to determine their ability to stabilize the three most common fracture fragments while buttressing anterolateral zones of comminution. We hypothesized that a single plate for the distal tibia would fail to adequately stabilize all three main fracture fragments and zones of comminution in complex pilon fractures. Ten synthetic distal tibia sawbones models were used in conjunction with ten different locking distal tibia plate designs from three manufacturers (Depuy Synthes, J&J Co, Paoli, PA; Smith & Nephew, Memphis, TN; and Stryker, Mawa, NJ). Both medial and anterolateral plates from each company were utilized and separately applied to an individual sawbone model. Three implants allowing variable angle screw placement were used. The location of the locking screws and buttress effect 1cm above the articular surface was noted for each implant using axial computed tomography (CT). The images were then compared to a recently published "pilon fracture map" using an overlay technique to establish the relationship between screw location and known common fracture lines and areas of comminution. Each of the three main fragments was considered "captured" by a screw if it was purchased by at least two screws thereby controlling rotational forces on each fragment. Three of four anterolateral plates lacked stable fixation in the medial fragment. Of the 4 anterolateral plates used, only the variable angle anterolateral plate by Depuy Synthes captured the medial fragment with two screws. All four anterolateral plates buttressed the area of highest comminution and had an average of 1.25 screws in the medial fragment and an average of 3 screws in the posterolateral fragment. All five direct medial plates had variable fixation within anterolateral and posterolateral fragments with an average of

On sorption and swelling of CO 2 in clays

DOE PAGES

Busch, A.; Bertier, P.; Gensterblum, Y.; ...

2016-03-23

One well-studied technology is the geological storage of carbon dioxide (CO 2), and a number of demonstration projects around the world have proven its feasibility and challenges. Storage conformance and seal integrity are among the most important aspects, as they determine risk of leakage as well as limits for storage capacity and injectivity. By providing evidence for safe storage is critical for improving public acceptance. Most caprocks are composed of clays as dominant mineral type which can typically be illite, kaolinite, chlorite or smectite. A number of recent studies addressed the interaction between CO 2 and these different clays andmore » it was shown that clay minerals adsorb considerable quantities of CO 2. For smectite this uptake can lead to volumetric expansion followed by the generation of swelling pressures. On the one hand CO 2 adsorption traps CO 2, on the other hand swelling pressures can potentially change local stress regimes and in unfavourable situations shear-type failure is assumed to occur. Moreover, for storage in a reservoir having high clay contents the CO 2 uptake can add to storage capacity which is widely underestimated so far. Smectite-rich seals in direct contact with a dry CO 2 plume at the interface to the reservoir might dehydrate leading to dehydration cracks. Such dehydration cracks can provide pathways for CO 2 ingress and further accelerate dewatering and penetration of the seal by supercritical CO 2. At the same time, swelling may also lead to the closure of fractures or the reduction of fracture apertures, thereby improving seal integrity. Finally, the goal of this communication is to theoretically evaluate and discuss these scenarios in greater detail in terms of phenomenological mechanisms, but also in terms of potential risks or benefits for carbon storage.« less

Fracture of a composite reinforced by unidirectional fibers

NASA Astrophysics Data System (ADS)

Hasanov, F. F.

2014-11-01

An elastic medium weakened by a periodic system of circular holes filled with homogeneous elastic fibers whose surface is coated with a homogeneous film is considered. A fracture model for a medium with a periodic structure is proposed, which is based on an analysis of the fracture zone near the crack tip. It is assumed that the fracture zone is a layer of finite length containing a material with partially broken bonds between separate structural elements (end zone). The fracture zone is considered as part of the crack. The bonds between crack faces in the end zone are modeled by applying the cohesive forces caused by the presence of bonds to the crack surface. An analysis of the limit equilibrium of shear cracks in the end zone of the model is performed on the basis of a nonlocal fracture criterion together with a force condition for the motion of crack tip and a deformation condition for determining the motion of faces of end-zone cracks. In the analysis, relationships between the cohesive forces and the shear of crack faces are established, the stress state near the crack is assessed with account of external loading, cohesive forces, and fiber arrangement, and the critical external loads as functions of geometric parameters of the composite are determined.

The Comprehensive AOCMF Classification System: Condylar Process Fractures - Level 3 Tutorial

PubMed Central

Neff, Andreas; Cornelius, Carl-Peter; Rasse, Michael; Torre, Daniel Dalla; Audigé, Laurent

2014-01-01

This tutorial outlines the detailed system for fractures of the condylar process at the precision level 3 and is organized in a sequence of sections dealing with the description of the classification system within topographical subdivisions along with rules for fracture coding and a series of case examples with clinical imaging. Basically, the condylar process comprises three fracture levels and is subdivided into the head region, the condylar neck, and the condylar base. Fractures of the condylar head show typical fracture lines either within the lateral pole zone, which may lead to loss of vertical height, or medially to the pole zone, with the latter ones usually not compromising the vertical condyle to fossa relation. In condylar head fractures, the morphology is further described by the presence of minor or major fragmentation, the vertical apposition of fragments at the plane of the head fracture, the displacement of the condylar head with regard to the fossa including a potential distortion of the condylar head congruency resulting in dystopic condyle to fossa relations and the presence or absence of a loss of vertical ramus height. A specific vertical fracture pattern extending from the head to the neck or base subregion is considered. Fractures of the condylar neck and base can be differentiated according to a newly introduced one-third to two-thirds rule with regard to the proportion of the fracture line above and below the level of the sigmoid notch, which is presented in the classification article, and are basically subdivided according to the presence or absence of displacement or dislocation. In both condylar neck and base fractures, the classification is again based on the above mentioned parameters such as fragmentation, displacement of the condylar head with regard to the fossa, including dystopic condyle to fossa relations and loss of vertical ramus height, that is, according to the measurement of the condylar process. In addition, the

JOINTS AND SYN-SEDIMENTARY FAULTS NETWORKS IN MARINE CLAYS AND MUDSTONES. Importance for Radwaste storage

NASA Astrophysics Data System (ADS)

Arnould, M.

2009-12-01

There is a number of marine clays, mudstones, marls, 100 to 200 m thick, showing smectites, mixed layers illite/smectite, with a small percentage of organic matter and sulphides with a variable clay, silt, and carbonate content. I published (Arnould , 2006) examples from Lower Cambrian to Miocene in age and from the Baltic shore to Spain in Europe. Observations were made mostly in quarries and pits down to more than 40 m and in underground research laboratories (URL). Only visible on fresh cuts amongst a variety of fissures there is always a network of joints. Schematically one family is the bedding (horizontal) the two others are normal to the bedding and orthogonal between them. The orientations of vertical joints are different from the orientations of pits and quarries’s walls. The networks are intrinsic. It was first well described by Skempton & al (1969) in Eocene London Clay. Joints are matt in texture, clean, without filling or cement. The order of magnitude of their linear dimensions is decimeter to meter. It is necessary to start from the original sediment: mud. Deposited in flakes mud has a bee’s nest microscopic structure. Each nest is full of water. Hence mud may have a water content up to 300%, reported to its dry weight. Paradoxically mud is impervious. As proposed by Cosgrove (2001) progressive but discontinuous hydraulic fracturing could be the origin of vertical joints, with drainage upwards and compaction of the sediment. Geological observations show that ioints are formed during the sedimentation process. There is also a world literature concluding at the necessary early fracturing of mudstones and marls hosts of sand dykes. Very few faults are identified in field observations and on exploration logs. But it is obvious that drainage and compaction of mud over thousands square kilometers induced differential settlements with many syn-sedimentary non tectonic faults constituting another discontinuity network. These faults inside the same

A model for microbially induced precipitation of vadose-zone calcites in fractures at LOS Alamos, New Mexico, USA

NASA Astrophysics Data System (ADS)

Newman, Brent D.; Campbell, Andrew R.; Norman, David I.; Ringelberg, David B.

1997-05-01

Fractures are unique environments that can concentrate the flow of water, nutrients, and contaminants. As such, fractures play an important role in controlling the flux of various substances into and through the vadose zone. Calcite fracture fillings are present in the near surface in the Bandelier Tuff Formation at Los Alamos, New Mexico, and provide a record of the geochemical and hydrologic processes that have occurred in fractures. The objective of this study was to examine calcite fracture fills in order to improve understanding of processes within fractures, and in particular those that lead to precipitation of calcite. Samples of calcite fillings were collected from vertical and horizontal fractures exposed in a shallow waste-burial pit. Scanning electron microscopy show morphologies which suggest that plants, fungi, and bacteria were important in the precipitation process. Quadrupole mass spectrometric analyses of fluid inclusion gases show predominantly methane (17-99%) and little to no oxygen (0-8%), suggesting the development of anaerobic conditions in the fractures. Ester-linked phospholipid biomarkers are evidence for a diverse microbial community in the fractures, and the presence of di-ether lipids indicate that the methane was generated by anaerobic bacteria. The calcite fillings apparently resulted from multiple biological and chemical processes in which plant roots in the fractures were converted to calcite. Roots grew into the fractures, eventually died, and were decomposed by bacteria and fungi. Anaerobic gases were generated from encapsulated organic material within the calcite via microbial decomposition, or were generated by microbes simultaneously with calcite precipitation. It is likely that the biological controls on calcite formation that occurred in the Los Alamos fractures also occurs in soils, and may explain the occurrence of other types of pedogenic calcites.

Fracture toughness and fractography of dental cements, lining, build-up, and filling materials.

PubMed

Mueller, H J

1990-06-01

The plane strain fracture toughness (K1c) at 23 degrees C and the fractography of zinc phosphate and zinc polycarboxylate cements, buffered glass ionomer liner, amalgam alloy admixed glass ionomer build-up material, and glass ionomer, microfilled and conventionally filled bis-GMA resin composite filling materials were analyzed by elastic-plastic short-rod and scanning electron microscopy methodologies. Results indicated that significant differences occurred in their K1c's from the lowest to the highest in the following groups of materials, (i) buffered glass ionomer, (ii) zinc phosphate, glass ionomer, zinc polycarboxylate, and alloy mixed glass ionomer, (iii) microfilled resin, and (iv) conventionally filled resin. All materials except the microfilled resin, which fractured via crack jumping, fractured via smooth crack advance. Filler debonding without any crack inhibiting process was related to materials with low K1c values. The incorporation of either buffering compounds or alloy particles into glass ionomer had no beneficial effect upon fracture toughness. This was in contrast to microfilled and conventionally filled resins where either crack blunting or crack pinning processes, respectively, were likely involved with their increased K1c's. For microfilled resin, distinct radial zones positioned around the chevron apex and characterized by plastically deformed deposited material were related to distinct crack jumps that occurred in the load versus displacement behavior. Finally, for the two remaining materials of zinc phosphate and polycarboxylate, particle cleavage and matrix debonding for the former and shear yielding for the latter occurred.

The Multi-Porosity Multi-Permeability and Electrokinetic Natures of Shales and Their Effects in Hydraulic Fracturing of Unconventional Shale Reservoirs

NASA Astrophysics Data System (ADS)

Liu, C.; Hoang, S. K.; Tran, M. H.; Abousleiman, Y. N.

2013-12-01

Imaging studies of unconventional shale reservoir rocks have recently revealed the multi-porosity multi-permeability nature of these intricate formations. In particular, the porosity spectrum of shale reservoir rocks often comprises of the nano-porosity in the organic matters, the inter-particle micro-porosity, and the macroscopic porosity of the natural fracture network. Shale is also well-known for its chemically active behaviors, especially shrinking and swelling when exposed to aqueous solutions, as the results of pore fluid exchange with external environment due to the difference in electro-chemical potentials. In this work, the effects of natural fractures and electrokinetic nature of shale on the formation responses during hydraulic fracturing are examined using the dual-poro-chemo-electro-elasticity approach which is a generalization of the classical Biot's poroelastic formulation. The analyses show that the presence of natural fractures can substantially increase the leak-off rate of fracturing fluid into the formation and create a larger region of high pore pressure near the fracture face as shown in Fig.1a. Due to the additional fluid invasion, the naturally fractured shale swells up more and the fracture aperture closes faster compared to an intrinsically low permeability non-fractured shale formation as shown in Fig.1b. Since naturally fractured zones are commonly targeted as pay zones, it is important to account for the faster fracture closing rate in fractured shales in hydraulic fracturing design. Our results also show that the presence of negative fixed charges on the surface of clay minerals creates an osmotic pressure at the interface of the shale and the external fluid as shown in Fig.1c. This additional Donnan-induced pore pressure can result in significant tensile effective stresses and tensile damage in the shale as shown in Fig.1d. The induced tensile damage can exacerbate the problem of proppant embedment resulting in more fracture closure

Anti-inflammatory, anti-bacterial, and cytotoxic activity of fibrous clays.

PubMed

Cervini-Silva, Javiera; Nieto-Camacho, Antonio-; Ramírez-Apan, María Teresa; Gómez-Vidales, Virginia; Palacios, Eduardo; Montoya, Ascención; Ronquillo de Jesús, Elba

2015-05-01

Produced worldwide at 1.2m tons per year, fibrous clays are used in the production of pet litter, animal feed stuff to roof parcels, construction and rheological additives, and other applications needing to replace long-fiber length asbestos. To the authors' knowledge, however, information on the beneficial effects of fibrous clays on health remains scarce. This paper reports on the anti-inflammatory, anti-bacterial, and cytotoxic activity by sepiolite (Vallecas, Spain) and palygorskite (Torrejon El Rubio, Spain). The anti-inflammatory activity was determined using the 12-O-tetradecanoylphorbol-13-acetate (TPA) and myeloperoxidase (MPO) methods. Histological cuts were obtained for quantifying leukocytes found in the epidermis. Palygorkite and sepiolite caused edema inhibition and migration of neutrophils ca. 68.64 and 45.54%, and 80 and 65%, respectively. Fibrous clays yielded high rates of infiltration, explained by cleavage of polysomes and exposure of silanol groups. Also, fibrous clays showed high inhibition of myeloperoxidase contents shortly after exposure, but decreased sharply afterwards. In contrast, tubular clays caused an increasing inhibition of myeloperoxidase with time. Thus, clay structure restricted the kinetics and mechanism of myeloperoxidase inhibition. Fibrous clays were screened in vitro against human cancer cell lines. Cytotoxicity was determined using the protein-binding dye sulforhodamine B (SRB). Exposing cancer human cells to sepiolite or palygorskite showed growth inhibition varying with cell line. This study shows that fibrous clays served as an effective anti-inflammatory, limited by chemical transfer and cellular-level signals responding exclusively to an early exposure to clay, and cell viability decreasing significantly only after exposure to high concentrations of sepiolite. Copyright © 2015 Elsevier B.V. All rights reserved.

Geoelectric characteristics of portions of the Raha fault zone and surrounding rocks, Jabal As Silsilah Quadrangle, Kingdom of Saudi Arabia

USGS Publications Warehouse

Zablocki, Charles J.; Hajnour, M.O.

1987-01-01

Telluric-electric and auto-magnetotelluric measurements obtained in and around the Raha fault zone in the Buqaya area indicate that it dips steeply to the southwest. Large contrasts in the electrical properties of Qarnayn and Maraghan metasedimentary rocks located on either side of the fault are characteristic of the rocks within the fault zone. However, no large electrical contrasts were detected along several segments of a southern branch of the main fault in the Shiaila area, indicating that the rocks on either side of the fault are of similar composition. Extremely low resistivity readings in the Buqaya and Shiaila areas are associated with fracturing and clay-bearing gouge that accompany known shear zones. The locations of several shallow plutons have been inferred from these studies, one of which is probably a source of gold-bearing quartz veins in the metasedimentary rocks of the Shiaila area.

Resolution and sensitivity of boat-towed RMT data to delineate fracture zones - Example of the Stockholm bypass multi-lane tunnel

NASA Astrophysics Data System (ADS)

Mehta, Suman; Bastani, Mehrdad; Malehmir, Alireza; Pedersen, Laust B.

2017-04-01

The resolution and sensitivity of water-borne boat-towed multi-frequency radio-magnetotelluric (RMT) data for delineating zones of weaknesses in bedrock are examined in this study. 2D modeling of RMT data along 40 profiles in joint transverse electric (TE) and transverse magnetic (TM) as well as determinant mode was used for this purpose. The RMT data were acquired over two water passages from the Lake Mälaren near the city of Stockholm where one of the largest underground infrastructure projects, a multi-lane tunnel, in Europe is currently being developed. Comparison with available borehole coring, refraction seismic and bathymetric data was used to scrutinize the RMT resistivity models. A low-resistivity zone observed in the middle of all the profiles is suggested to be from fracture/fault zones striking in the same direction as the water passages. Drilling observations confirm the presence of brittle structures in the bedrock, which manifest themselves as zones of low-resistivity and low-velocity in the RMT and refraction seismic data, respectively. Nevertheless, RMT is an inductive electromagnetic method hence the presence of conductive lake sediments may shield detecting the underlying fractured bedrock. The loss of resolution at depth implies that the structures within the bedrock under the lake sediments cannot reliably be delineated. To support this, a synthetic data analysis was carried out providing useful information on how to improve and plan the lake measurements for future studies. Synthetic modeling results for example suggested that frequencies as low as 3 kHz would be required to reliably resolve the bedrock and fracture zone within it in the study area. The modeling further illustrated the advantage of a fresh water layer that acts as a near-surface homogeneous medium eliminating the static shift effects. While boat-towed RMT data provided substantial information about the subsurface geology, the acquisition system should be upgraded to enable

Estimating Hydraulic Conductivities in a Fractured Shale Formation from Pressure Pulse Testing and 3d Modeling

NASA Astrophysics Data System (ADS)

Courbet, C.; DICK, P.; Lefevre, M.; Wittebroodt, C.; Matray, J.; Barnichon, J.

2013-12-01

In the framework of its research on the deep disposal of radioactive waste in shale formations, the French Institute for Radiological Protection and Nuclear Safety (IRSN) has developed a large array of in situ programs concerning the confining properties of shales in their underground research laboratory at Tournemire (SW France). One of its aims is to evaluate the occurrence and processes controlling radionuclide migration through the host rock, from the disposal system to the biosphere. Past research programs carried out at Tournemire covered mechanical, hydro-mechanical and physico-chemical properties of the Tournemire shale as well as water chemistry and long-term behaviour of the host rock. Studies show that fluid circulations in the undisturbed matrix are very slow (hydraulic conductivity of 10-14 to 10-15 m.s-1). However, recent work related to the occurrence of small scale fractures and clay-rich fault gouges indicate that fluid circulations may have been significantly modified in the vicinity of such features. To assess the transport properties associated with such faults, IRSN designed a series of in situ and laboratory experiments to evaluate the contribution of both diffusive and advective process on water and solute flux through a clay-rich fault zone (fault core and damaged zone) and in an undisturbed shale formation. As part of these studies, Modular Mini-Packer System (MMPS) hydraulic testing was conducted in multiple boreholes to characterize hydraulic conductivities within the formation. Pressure data collected during the hydraulic tests were analyzed using the nSIGHTS (n-dimensional Statistical Inverse Graphical Hydraulic Test Simulator) code to estimate hydraulic conductivity and formation pressures of the tested intervals. Preliminary results indicate hydraulic conductivities of 5.10-12 m.s-1 in the fault core and damaged zone and 10-14 m.s-1 in the adjacent undisturbed shale. Furthermore, when compared with neutron porosity data from borehole

Zonation of shale reservoir stimulation modes: a conceptual model based on hydraulic fracturing data from the Baltic Basin (Poland).

NASA Astrophysics Data System (ADS)

Jarosiński, Marek; Pachytel, Radomir

2017-04-01

+ opening of horizontal bedding fractures, that do not prevail any microseismic mechanism, stabilizes the stresses at the level close to the thrust fault regime and opens space for large amount of proppant. This stimulation mode is undesirable because horizontal bedding fractures do not drain shale matrix efficiently due to low vertical permeability of shale and sealing of bedding planes by high clay content that enhances embedment effect on proppant. The number and order of stimulation zones is site- or basin-specific and may not apply directly to other locations. In the case of strong mechanical layering the stimulation mode can also vary among formations. Large number of preferentially oriented natural fractures (like in majority of boreholes in the BB), may cause the technological hydraulic fractures to play a subordinate role. Because in the BB tectonic fractures are filled with calcite, it may negatively influence gas drainage to stimulated fractures. In our scenario, also the primary shear failure mode is not achieved due to low differential stress in respect to compressive strength of shale. The shape of stimulation zones might not be regular but adjusted to the pattern of stimulated fractures creating principal pathways for hydraulic pressure propagation into reservoir. Bearing in mind the sequence of stimulation mode zones we are able to better understand the pattern of microseismic events and predict, to some extend, the proppant distribution within SRV.

Geochemistry, mineralization, structure, and permeability of a normal-fault zone, Casino mine, Alligator Ridge district, north central Nevada

NASA Astrophysics Data System (ADS)

Hammond, K. Jill; Evans, James P.

2003-05-01

We examine the geochemical signature and structure of the Keno fault zone to test its impact on the flow of ore-mineralizing fluids, and use the mined exposures to evaluate structures and processes associated with normal fault development. The fault is a moderately dipping normal-fault zone in siltstone and silty limestone with 55-100 m of dip-slip displacement in north-central Nevada. Across-strike exposures up to 180 m long, 65 m of down-dip exposure and 350 m of along-strike exposure allow us to determine how faults, fractures, and fluids interact within mixed-lithology carbonate-dominated sedimentary rocks. The fault changes character along strike from a single clay-rich slip plane 10-20 mm thick at the northern exposure to numerous hydrocarbon-bearing, calcite-filled, nearly vertical slip planes in a zone 15 m wide at the southern exposure. The hanging wall and footwall are intensely fractured but fracture densities do not vary markedly with distance from the fault. Fault slip varies from pure dip-slip to nearly pure strike-slip, which suggests that either slip orientations may vary on faults in single slip events, or stress variations over the history of the fault caused slip vector variations. Whole-rock major, minor, and trace element analyses indicate that Au, Sb, and As are in general associated with the fault zone, suggesting that Au- and silica-bearing fluids migrated along the fault to replace carbonate in the footwall and adjacent hanging wall rocks. Subsequent fault slip was associated with barite and calcite and hydrocarbon-bearing fluids deposited at the southern end of the fault. No correlation exists at the meter or tens of meter scale between mineralization patterns and fracture density. We suggest that the fault was a combined conduit-barrier system in which the fault provides a critical connection between the fluid sources and fractures that formed before and during faulting. During the waning stages of deposit formation, the fault behaved as

The seismogenic Gole Larghe Fault Zone (Italian Southern Alps): quantitative 3D characterization of the fault/fracture network, mapping of evidences of fluid-rock interaction, and modelling of the hydraulic structure through the seismic cycle

NASA Astrophysics Data System (ADS)

Bistacchi, A.; Mittempergher, S.; Di Toro, G.; Smith, S. A. F.; Garofalo, P. S.

2016-12-01

The Gole Larghe Fault Zone (GLFZ) was exhumed from 8 km depth, where it was characterized by seismic activity (pseudotachylytes) and hydrous fluid flow (alteration halos and precipitation of hydrothermal minerals in veins and cataclasites). Thanks to glacier-polished outcrops exposing the 400 m-thick fault zone over a continuous area > 1.5 km2, the fault zone architecture has been quantitatively described with an unprecedented detail, providing a rich dataset to generate 3D Discrete Fracture Network (DFN) models and simulate the fault zone hydraulic properties. The fault and fracture network has been characterized combining > 2 km of scanlines and semi-automatic mapping of faults and fractures on several photogrammetric 3D Digital Outcrop Models (3D DOMs). This allowed obtaining robust probability density functions for parameters of fault and fracture sets: orientation, fracture intensity and density, spacing, persistency, length, thickness/aperture, termination. The spatial distribution of fractures (random, clustered, anticlustered…) has been characterized with geostatistics. Evidences of fluid/rock interaction (alteration halos, hydrothermal veins, etc.) have been mapped on the same outcrops, revealing sectors of the fault zone strongly impacted, vs. completely unaffected, by fluid/rock interaction, separated by convolute infiltration fronts. Field and microstructural evidence revealed that higher permeability was obtained in the syn- to early post-seismic period, when fractures were (re)opened by off-fault deformation. We have developed a parametric hydraulic model of the GLFZ and calibrated it, varying the fraction of faults/fractures that were open in the post-seismic, with the goal of obtaining realistic fluid flow and permeability values, and a flow pattern consistent with the observed alteration/mineralization pattern. The fraction of open fractures is very close to the percolation threshold of the DFN, and the permeability tensor is strongly anisotropic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malin, Peter E.; Shalev, Eylon; Onacha, Stepthen A.

of the fault zones is constrained by geological, drilling, and geothermal production data. The objective is to determine interpretation techniques for evaluating structural controls of fluid circulation in hydrothermal systems. The conclusions are: • directions of MT polarization and anisotropy and MEQ S-splitting correlate. Polarization and anisotropy are caused by fluid filled fractures at the base of the clay cap. •Microearthquakes occur mainly on the boundary of low resistivity within the fracture zone and high resistivity in the host rock. Resistivity is lowest within the core of the fracture zone and increases towards the margins of the fracture zone. The heat source and the clay cap for the hydrothermal have very low resistivity of less than 5Ωm. •Fracture porosity imaged by resistivity indicates that it varies between 45-5% with most between 10-20%, comparable to values from core samples in volcanic areas in Kenya and Iceland. For resistivity values above 60Ωm, the porosity reduces drastically and therefore this might be used as the upper limit for modeling fracture porosity from resistivity. When resistivity is lower than 5Ωm, the modeled fracture porosity increases drastically indicating that this is the low resistivity limit. This is because at very low resistivity in the heat source and the clay cap, the resistivity is dominated by ionic conduction rather than fracture porosity. •Microearthquakes occur mainly above the heat source which is defined by low resistivity at a depth of 3-4.5 km at the Krafla hydrothermal system and 4-7 km in the Longonot hydrothermal system. •Conversions of S to P waves occur for microearthquakes located above the heat source within the hydrothermal system. Shallow microearthquakes occur mainly in areas that show both MT and S-wave anisotropy. •S-wave splitting and MT anisotropy occurs at the base of the clay cap and therefore reflects the variations in fracture porosity on top of the hydrothermal system. �

Evaluation of Used Fuel Disposition in Clay-Bearing Rock

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jove-Colon, Carlos F.; Weck, Philippe F.; Hammond, Glenn Edward

Deep geological disposal of nuclear waste in clay/shale/argillaceous rock formations has received much consideration given its desirable attributes such as isolation properties (low permeability), geochemically reduced conditions, slow diffusion, sorbtive mineralogy, and geologically widespread (Jové Colón et al., 2014). There is a wealth of gained scientific expertise on the behavior of clay/shale/ argillaceous rock given its focus in international nuclear waste repository programs that includes underground research laboratories (URLs) in Switzerland, France, Belgium, and Japan. Jové Colón et al. (2014) have described some of these investigative efforts in clay rock ranging from site characterization to research on the engineered barriermore » system (EBS). Evaluations of disposal options that include nuclear waste disposition in clay/shale/argillaceous rock have determined that this host media can accommodate a wide range of waste types. R&D work within the Used Fuel Disposition Campaign (UFDC) assessing thermal effects and fluid-mineral interactions for the disposition of heat-generating waste have so far demonstrated the feasibility for the EBS and clay host rock to withstand high thermal loads. This report represents the continuation of disposal R&D efforts on the advancement and refinement of coupled Thermal-Hydrological-Mechanical-Chemical (THMC), hydrothermal experiments on clay interactions, used fuel degradation (source term), and thermodynamic modeling and database development. The development and implementation of a clay/shale/argillite reference case described in Jové Colón et al. (2014) for FY15 will be documented in another report (Mariner et al. 2015) – only a brief description will be given here. This clay reference case implementation is the result of integration efforts between the GDSA PA and disposal in argillite work packages. The assessment of sacrificial zones in the EBS is being addressed through experimental work along with 1D

Evaluation of Pleistocene groundwater flow through fractured tuffs using a U-series disequilibrium approach, Pahute Mesa, Nevada, USA

USGS Publications Warehouse

Paces, James B.; Nichols, Paul J.; Neymark, Leonid A.; Rajaram, Harihar

2013-01-01

Groundwater flow through fractured felsic tuffs and lavas at the Nevada National Security Site represents the most likely mechanism for transport of radionuclides away from underground nuclear tests at Pahute Mesa. To help evaluate fracture flow and matrix–water exchange, we have determined U-series isotopic compositions on more than 40 drill core samples from 5 boreholes that represent discrete fracture surfaces, breccia zones, and interiors of unfractured core. The U-series approach relies on the disruption of radioactive secular equilibrium between isotopes in the uranium-series decay chain due to preferential mobilization of 234U relative to 238U, and U relative to Th. Samples from discrete fractures were obtained by milling fracture surfaces containing thin secondary mineral coatings of clays, silica, Fe–Mn oxyhydroxides, and zeolite. Intact core interiors and breccia fragments were sampled in bulk. In addition, profiles of rock matrix extending 15 to 44 mm away from several fractures that show evidence of recent flow were analyzed to investigate the extent of fracture/matrix water exchange. Samples of rock matrix have 234U/238U and 230Th/238U activity ratios (AR) closest to radioactive secular equilibrium indicating only small amounts of groundwater penetrated unfractured matrix. Greater U mobility was observed in welded-tuff matrix with elevated porosity and in zeolitized bedded tuff. Samples of brecciated core were also in secular equilibrium implying a lack of long-range hydraulic connectivity in these cases. Samples of discrete fracture surfaces typically, but not always, were in radioactive disequilibrium. Many fractures had isotopic compositions plotting near the 230Th-234U 1:1 line indicating a steady-state balance between U input and removal along with radioactive decay. Numerical simulations of U-series isotope evolution indicate that 0.5 to 1 million years are required to reach steady-state compositions. Once attained, disequilibrium 234U/238U

Effects of leachate concentration on the integrity of solidified clay liners.

PubMed

Xue, Qiang; Zhang, Qian

2014-03-01

This study aimed to evaluate the impact of landfill leachate concentration on the degradation behaviour of solidified clay liners and to propose a viable mechanism for the observed degradation. The results indicated that the unconfined compressive strength of the solidified clay decreased significantly, while the hydraulic conductivity increased with the leachate concentration. The large pore proportion in the solidified clay increased and the sum of medium and micro pore proportions decreased, demonstrating that the effect on the solidified clay was evident after the degradation caused by exposure to landfill leachate. The unconfined compressive strength of the solidified clay decreased with increasing leachate concentration as the leachate changed the compact structure of the solidified clay, which are prone to deformation and fracture. The hydraulic conductivity and the large pore proportion of the solidified clay increased with the increase in leachate concentration. In contrast, the sum of medium and micro pore proportions showed an opposite trend in relation to leachate concentration, because the leachate gradually caused the medium and micro pores to form larger pores. Notably, higher leachate concentrations resulted in a much more distinctive variation in pore proportions. The hydraulic conductivity of the solidified clay was closely related to the size, distribution, and connection of pores. The proportion of the large pores showed a positive correlation with the increase of hydraulic conductivity, while the sum of the proportions of medium and micro pores showed a negative correlation.

Impact of Oxidative Dissolution on Black Shale Fracturing: Implication for Shale Fracturing Treatment Design

NASA Astrophysics Data System (ADS)

You, L.; Chen, Q.; Kang, Y.; Cheng, Q.; Sheng, J.

2017-12-01

Black shales contain a large amount of environment-sensitive compositions, e.g., clay minerals, carbonate, siderite, pyrite, and organic matter. There have been numerous studies on the black shales compositional and pore structure changes caused by oxic environments. However, most of the studies did not focus on their ability to facilitate shale fracturing. To test the redox-sensitive aspects of shale fracturing and its potentially favorable effects on hydraulic fracturing in shale gas reservoirs, the induced microfractures of Longmaxi black shales exposed to deionized water, hydrochloric acid, and hydrogen peroxide at room-temperature for 240 hours were imaged by scanning electron microscopy (SEM) and CT-scanning in this paper. Mineral composition, acoustic emission, swelling, and zeta potential of the untreated and oxidative treatment shale samples were also recorded to decipher the coupled physical and chemical effects of oxidizing environments on shale fracturing processes. Results show that pervasive microfractures (Fig.1) with apertures ranging from tens of nanometers to tens of microns formed in response to oxidative dissolution by hydrogen peroxide, whereas no new microfracture was observed after the exposure to deionized water and hydrochloric acid. The trajectory of these oxidation-induced microfractures was controlled by the distribution of phyllosilicate framework and flaky or stringy organic matter in shale. The experiments reported in this paper indicate that black shales present the least resistance to crack initiation and subcritical slow propagation in hydrogen peroxide, a process we refer to as oxidation-sensitive fracturing, which are closely related to the expansive stress of clay minerals, dissolution of redox-sensitive compositions, destruction of phyllosilicate framework, and the much lower zeta potential of hydrogen peroxide solution-shale system. It could mean that the injection of fracturing water with strong oxidizing aqueous solution may

77 FR 60897 - Safety Zone: America's Cup World Series Finish-Line, San Francisco, CA

Federal Register 2010, 2011, 2012, 2013, 2014

2012-10-05

...-AA00 Safety Zone: America's Cup World Series Finish-Line, San Francisco, CA AGENCY: Coast Guard, DHS..., approximately 1,250 yards east of Anita Rock in San Francisco Bay, in support of the 2012 America's Cup World... World Series. The Coast Guard intends to enforce a temporary safety zone in order to protect spectators...

Geophysical investigation of seamounts near the Ogasawara fracture zone, western Pacific

USGS Publications Warehouse

Lee, T.-G.; Lee, Kenneth; Hein, J.R.; Moon, J.-W.

2009-01-01

This paper provides an analysis of multi-channel seismic data obtained during 2000-2001 on seamounts near the Ogasawara Fracture Zone (OFZ) northwest of the Marshall Islands in the western Pacific. The OFZ is unique in that it is a wide rift zone that includes many seamounts. Seven units are delineated on the basis of acoustic characteristics and depth: three units (I, II, and III) on the summit of seamounts and four units (IV, V, VI, and VII) in basins. Acoustic characteristics of layers on the summit of guyots and dredged samples indicate that the seamounts had been built above sea level by volcanism. This was followed by reef growth along the summit margin, which enabled deposition of shallow-water carbonates on the summit, and finally by subsidence of the edifices. The subsidence depth of the seamounts, estimated from the lower boundary of unit II, ranges between 1,550 and 2,040 m. The thick unit I of the southern seamounts is correlated with proximity to the equatorial high productivity zone, whereas local currents may have strongly affected the distribution of unit I on northern seamounts. A seismic profile in the basin around the Ita Mai Tai and OSM4 seamounts shows an unconformity between units IV and V, which is widespread from the East Mariana Basin to the Pigafetta Basin. Copyright ?? The Society of Geomagnetism and Earth, Planetary and Space Sciences (SGEPSS); The Seismological Society of Japan; The Volcanological Society of Japan; The Geodetic Society of Japan; The Japanese Society for Planetary Sciences; TERRAPUB.

Preferential flow and pesticide transport in a clay-rich till: Field, laboratory, and modeling analysis

NASA Astrophysics Data System (ADS)

JøRgensen, Peter R.; Hoffmann, Martin; Kistrup, Jens P.; Bryde, Claus; Bossi, Rossana; Villholth, Karen G.

2002-11-01

This study investigates vertical flow and pesticide transport along fractures in water saturated unoxidized clayey till. From two experimental fields, each 40 m2, 96% and 98%, respectively, of total vertical flow was conducted along fractures in the till, while the remaining 2-4% of flow occurred in the clay matrix at very slow flow rate. An applied dye tracer was observed only along 10-26% of the total fracture length measured on the horizontal surface of the experimental fields. In vertical sections the dyed fracture portions constituted root channels, which penetrated the till vertically along the fractures into the local aquifer at 5 m depth. No dye tracer was observed in the fractures without root channels or in the unfractured clay matrix, suggesting that root growth along the fracture surfaces was the principal agent of fracture aperture enhancement. Using hydraulic fracture aperture values determined from large undisturbed column (LUC) collected from one of the experimental fields, it was estimated that 94% of flow in the fractures was conducted along the fracture root channels, while only 6% of flow was conducted along the fracture sections without root channels. For natural vertical hydraulic gradients (0.8-2.3 at the site), flow rates of 0.8-2 km/d were determined for a fracture root channel, while fracture sections without root channels revealed flow rates of 9-22 m/d. Corresponding flow rates in the unfractured matrix were 7-19 mm/yr. For infiltrated bromide (nonreactive tracer) and mobile pesticides mecoprop (MCPP) and metsulfuron, very rapid migration (0.28-0.5 m/d) and high relative breakthrough concentrations (30-60%) into the aquifer were observed to occur along the fracture root channels using a constant hydraulic gradient of 1. Only traces were measured from infiltration of the strongly sorbed pesticide prochloraz. The concentrations of the bromide and pesticides in the monitoring wells were modeled with a discrete fracture matrix diffusion

Slip events propagating along a ductile mid-crustal strike-slip shear zone (Malpica-Lamego line, Variscan Orogen, NW Iberia)

NASA Astrophysics Data System (ADS)

Llana-Fúnez, Sergio; de Paola, Nicola; Pozzi, Giacomo; Lopez-Sanchez, Marco Antonio

2017-04-01

The current level of erosion in NW Iberian peninsula exposes Variscan mid-crustal depths, where widespread deformation during orogenesis produced dominantly ductile structures. It constitutes an adequate window for the observation of structures close to the brittle-plastic transition in the continental crust. The shear zone object of this work is the Malpica-Lamego line (MLL), a major Variscan structure formed in the late stages of the Variscan collision. The MLL is a mostly strike-slip major structure that offsets laterally by several kilometres the assembly of allochthonous complexes, that contain a sub-horizontal suture zone, which are the remnants of the plate duplication during the Variscan convergence. The shear zone is exposed along the northern coast of Galicia (NW Spain). It is characterized by phyllonites and quartz-mylonites in a zone which is tens of meters in thickness. Within the phyllonites, a few seams of cataclastic rocks have been found in bands along the main fabric. Their cohesive character, the parallelism between the different bands, the fact that host rocks maintain mineral assemblage and that no cross-cutting relations in the field were identified, are considered indicative of these brittle structures forming coetaneously with the ductile shearing producing the phyllonites. Samples from the phyllonites, also from quartz-mylonites, were prepared and powdered to characterize friction properties in a rotary shear apparatus at high, seismic velocities (m/s). Preliminary experiments run at room temperature and effective normal stresses between 10 to 25 MPa, show that friction coefficients µ are relatively high and a limited drop in friction coefficient occurs after 10-20 cm of slip, with µ decreasing from 0.7 to 0.5. Fracturing seems coetaneous with dominant ductile shearing within the shear zone, however, given the frictional properties of the phyllonites, it is unlikely that brittle deformation nucleates within these fault rocks. Instead, it

Ratios of molecular hydrogen line intensities in shocked gas - Evidence for cooling zones

NASA Technical Reports Server (NTRS)

Brand, P. W. J. L.; Moorhouse, A.; Bird, M.; Burton, M. G.; Geballe, T. R.

1988-01-01

Column densities of molecular hydrogen have been calculated from 19 infrared vibration-rotation and pure rotational line intensities measured at peak 1 of the Orion molecular outflow. The run of column density with energy level is similar to a simple coolng zone model of the line-emitting region, but is not well fitted by predictions of C-shock models current in the literature.

An integrated geophysical and geochemical exploration of critical zone weathering on opposing montane hillslope

NASA Astrophysics Data System (ADS)

Singha, K.; Navarre-Sitchler, A.; Bandler, A.; Pommer, R. E.; Novitsky, C. G.; Holbrook, S.; Moore, J.

2017-12-01

Quantifying coupled geochemical and hydrological properties and processes that operate in the critical zone is key to predicting rock weathering and subsequent transmission and storage of water in the shallow subsurface. Geophysical data have the potential to elucidate geochemical and hydrologic processes across landscapes over large spatial scales that are difficult to achieve with point measurements alone. Here, we explore the connections between weathering and fracturing, as measured from integrated geochemical and geophysical borehole data and seismic velocities on north- and south-facing aspects within one watershed in the Boulder Creek Critical Zone Observatory. We drilled eight boreholes up to 13 m deep on north- and south-facing aspects within Upper Gordon Gulch, and surface seismic refraction data were collected near these wells to explore depths of regolith and bedrock, as well as anisotropic characteristics of the subsurface material due to fracturing. Optical televiewer data were collected in these wells to infer the dominant direction of fracturing and fracture density in the near surface to corroborate with the seismic data. Geochemical samples were collected from four of these wells and a series of shallow soil pits for bulk chemistry, clay fraction, and exchangeable cation concentrations to identify depths of chemically altered saprolite. Seismic data show that depth to unweathered bedrock, as defined by p-wave seismic velocity, is slightly thicker on the north-facing slopes. Geochemical data suggest that the depth to the base of saprolite ranges from 3-5 m, consistent with a p-wave velocity value of 1200 m/s. Based on magnitude and anisotropy of p-wave velocities together with optical televiewer data, regolith on north-facing slopes is thought to be more fractured than south-facing slopes, while geochemical data indicate that position on the landscape is another important characteristic in determining depths of weathering. We explore the importance

[Dynamics of diazotrophic bacteria number in the root zone of wheat Vrn lines isogenic by genes].

PubMed

Samoĭlov, A M; Zhmurko, V V

2012-01-01

The number of diazotrophic bacteria and nitrogenase activity in the root zone of isogenic monogene-dominant Vrn lines were measured in the field experiments throughout their vegetation from tillering to heading. The total number of diazotrophic bacteria and nitrogenase activity in the root zone of these lines during this period were increased irrespective of their genotypes. The above indices of the winter cultivar (Vrn loci bottom recessive) were lower than those of the spring lines--Vrn-A1, Vrn-B1 and Vrn-D1. Plants of Vrn-B1 line have the lowest indices among the spring lines with the exception of some indices. This line plants flowered later than those of Vrn-A1 and Vrn-D1 lines. We hypothesized the differences between plants of these lines as to nitrogen fixation activity and the number of diazotrophic bacteria are mediately determined by Vrn loci through their effects on metabolism intensity and assimilate reflux in the form of root exudates, therefore the total number of diazotrophic bacteria and nitrogenase activity increases.

Evolution of the Median Tectonic Line fault zone, SW Japan, during exhumation

NASA Astrophysics Data System (ADS)

Shigematsu, Norio; Kametaka, Masao; Inada, Noriyuki; Miyawaki, Masahiro; Miyakawa, Ayumu; Kameda, Jun; Togo, Tetsuhiro; Fujimoto, Koichiro

2017-01-01

Like many crustal-scale fault zones, the Median Tectonic Line (MTL) fault zone in Japan preserves fault rocks that formed across a broad range of physical conditions. We examined the architecture of the MTL at a large new outcrop in order to understand fault behaviours under different crustal levels. The MTL here strikes almost E-W, dips to the north, and juxtaposes the Sanbagawa metamorphic rocks to the south against the Izumi Group sediments to the north. The fault core consists mainly of Sanbagawa-derived fault gouges. The fault zone can be divided into several structural units, including two slip zones (upper and lower slip zones), where the lower slip zone is more conspicuous. Crosscutting relationships among structures and kinematics indicate that the fault zone records four stages of deformation. Microstructures and powder X-ray diffraction (XRD) analyses indicate that the four stages of deformation occurred under different temperature conditions. The oldest deformation (stage 1) was widely distributed, and had a top-to-the-east (dextral) sense of slip at deep levels of the seismogenic zone. Deformation with the same sense of slip, then became localised in the lower slip zone (stage 2). Subsequently, the slip direction in the lower slip zone changed to top-to-the-west (sinistral-normal) (stage 3). The final stage of deformation (stage 4) involved top-to-the-north normal faulting along the two slip zones within the shallow crust (near the surface). The widely distributed stage 1 damage zone characterises the deeper part of the seismogenic zone, while the sets of localised principal slip zones and branching faults of stage 4 characterise shallow depths. The fault zone architecture described in this paper leads us to suggest that fault zones display different behaviours at different crustal levels.

Preliminary Fracture Description from Core, Lithological Logs, and Borehole Geophysical Data in Slimhole Wells Drilled for Project Hotspot: the Snake River Geothermal Drilling Project

NASA Astrophysics Data System (ADS)

Kessler, J. A.; Evans, J. P.; Shervais, J. W.; Schmitt, D.

2011-12-01

2,000 m depth is 102°C. The rock types at Kimama and Kimberly are primarily basalt and rhyolite, respectively, with interbedded thin sedimentary layers. We identify anomalies in the physical properties of igneous rocks using porosity logs (neutron and acoustic), lithology logs (gamma ray and magnetic susceptibility) and fracture/saturation logs (televiewer and electrical resistivity). The core will be used to constrain the geophysical data and confirm the ability to identify permeability in fracture zones and saturated zones through analysis of the wireline log data. The matrix porosity of these igneous lithologies is near zero aside from porosity from vugs and vesicles. However, open and sealed fractures indicate that mineralizing fluids form connected pathways in the rock. Core samples show a series of alteration phases, including amygdaloidal fine-grained calcite and secondary clays. The geophysical data will be used to predict anomalies in lithology and identify open fractures and saturated zones with high permeability.

Tritium and 36Cl as constraints on fast fracture flow and percolation flux in the unsaturated zone at Yucca Mountain.

PubMed

Guerin, M

2001-10-01

An analysis of tritium and 36Cl data collected at Yucca Mountain, Nevada suggests that fracture flow may occur at high velocities through the thick unsaturated zone. The mechanisms and extent of this "fast flow" in fractures at Yucca Mountain are investigated with data analysis, mixing models and several one-dimensional modeling scenarios. The model results and data analysis provide evidence substantiating the weeps model [Gauthier, J.H., Wilson, M.L., Lauffer, F.C., 1992. Proceedings of the Third Annual International High-level Radioactive Waste Management Conference, vol. 1, Las Vegas, NV. American Nuclear Society, La Grange Park, IL, pp. 891-989] and suggest that fast flow in fractures with minimal fracture-matrix interaction may comprise a substantial proportion of the total infiltration through Yucca Mountain. Mixing calculations suggest that bomb-pulse tritium measurements, in general, represent the tail end of travel times for thermonuclear-test-era (bomb-pulse) infiltration. The data analysis shows that bomb-pulse tritium and 36Cl measurements are correlated with discrete features such as horizontal fractures and areas where lateral flow may occur. The results presented here imply that fast flow in fractures may be ubiquitous at Yucca Mountain, occurring when transient infiltration (storms) generates flow in the connected fracture network.

Tritium and 36Cl as constraints on fast fracture flow and percolation flux in the unsaturated zone at Yucca Mountain

NASA Astrophysics Data System (ADS)

Guerin, Marianne

2001-10-01

An analysis of tritium and 36Cl data collected at Yucca Mountain, Nevada suggests that fracture flow may occur at high velocities through the thick unsaturated zone. The mechanisms and extent of this "fast flow" in fractures at Yucca Mountain are investigated with data analysis, mixing models and several one-dimensional modeling scenarios. The model results and data analysis provide evidence substantiating the weeps model [Gauthier, J.H., Wilson, M.L., Lauffer, F.C., 1992. Proceedings of the Third Annual International High-level Radioactive Waste Management Conference, vol. 1, Las Vegas, NV. American Nuclear Society, La Grange Park, IL, pp. 891-989] and suggest that fast flow in fractures with minimal fracture-matrix interaction may comprise a substantial proportion of the total infiltration through Yucca Mountain. Mixing calculations suggest that bomb-pulse tritium measurements, in general, represent the tail end of travel times for thermonuclear-test-era (bomb-pulse) infiltration. The data analysis shows that bomb-pulse tritium and 36Cl measurements are correlated with discrete features such as horizontal fractures and areas where lateral flow may occur. The results presented here imply that fast flow in fractures may be ubiquitous at Yucca Mountain, occurring when transient infiltration (storms) generates flow in the connected fracture network.

Field characterization plan for the 216-U-8 vitrified clay pipeline

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rowley, C.A.

1994-01-21

The 216-U-8 Crib was constructed in 1952 and received waste from 1952 to 1960 as described in Appendix A. This description of work details the field activities associated with the characterization of the vitrified clay pipe (VCP) delivery line to the 216-U-8 Crib and subsurface soil sampling along the pipe route in the 200 West Area of Hanford U Plant. It will serves as a field guide for those performing the work. Soil sampling locations will be determined by a combination of radiological surface surveys and internal camera surveys of the VCP line. Depending on the condition of the pipelinemore » and field conditions, the objectives are as follows: examine the internal condition of the VCP with a survey camera to the extent allowed by field conditions; determine precise location and depth of the VCP; document VCP integrity; document gamma radiation profile through the VCP; and correlate any relationships between surface contamination zones at grade above the VCP to identify breaches in the pipe integrity.« less

Poly(vinyl acetate)/clay nanocomposite materials for organic thin film transistor application.

PubMed

Park, B J; Sung, J H; Park, J H; Choi, J S; Choi, H J

2008-05-01

Nanocomposite materials of poly(vinyl acetate) (PVAc) and organoclay were fabricated, in order to be utilized as dielectric materials of the organic thin film transistor (OTFT). Spin coating condition of the nanocomposite solution was examined considering shear viscosity of the composite materials dissolved in chloroform. Intercalated structure of the PVAc/clay nanocomposites was characterized using both wide-angle X-ray diffraction and TEM. Fracture morphology of the composite film on silicon wafer was also observed by SEM. Dielectric constant (4.15) of the nanocomposite materials shows that the PVAc/clay nanocomposites are applicable for the gate dielectric materials.

Imaging groundwater infiltration dynamics in the karst vadose zone with long-term ERT monitoring

NASA Astrophysics Data System (ADS)

Watlet, Arnaud; Kaufmann, Olivier; Triantafyllou, Antoine; Poulain, Amaël; Chambers, Jonathan E.; Meldrum, Philip I.; Wilkinson, Paul B.; Hallet, Vincent; Quinif, Yves; Van Ruymbeke, Michel; Van Camp, Michel

2018-03-01

Water infiltration and recharge processes in karst systems are complex and difficult to measure with conventional hydrological methods. In particular, temporarily saturated groundwater reservoirs hosted in the vadose zone can play a buffering role in water infiltration. This results from the pronounced porosity and permeability contrasts created by local karstification processes of carbonate rocks. Analyses of time-lapse 2-D geoelectrical imaging over a period of 3 years at the Rochefort Cave Laboratory (RCL) site in south Belgium highlight variable hydrodynamics in a karst vadose zone. This represents the first long-term and permanently installed electrical resistivity tomography (ERT) monitoring in a karst landscape. The collected data were compared to conventional hydrological measurements (drip discharge monitoring, soil moisture and water conductivity data sets) and a detailed structural analysis of the local geological structures providing a thorough understanding of the groundwater infiltration. Seasonal changes affect all the imaged areas leading to increases in resistivity in spring and summer attributed to enhanced evapotranspiration, whereas winter is characterised by a general decrease in resistivity associated with a groundwater recharge of the vadose zone. Three types of hydrological dynamics, corresponding to areas with distinct lithological and structural features, could be identified via changes in resistivity: (D1) upper conductive layers, associated with clay-rich soil and epikarst, showing the highest variability related to weather conditions; (D2) deeper and more resistive limestone areas, characterised by variable degrees of porosity and clay contents, hence showing more diffuse seasonal variations; and (D3) a conductive fractured zone associated with damped seasonal dynamics, while showing a great variability similar to that of the upper layers in response to rainfall events. This study provides detailed images of the sources of drip

Electrokinetic-enhanced bioaugmentation for remediation of chlorinated solvents contaminated clay

PubMed Central

Mao, Xuhui; Wang, James; Ciblak, Ali; Cox, Evan E.; Riis, Charlotte; Terkelsen, Mads; Gent, David B.; Alshawabkeh, Akram N.

2012-01-01

Successful bioremediation of contaminated soils is controlled by the ability to deliver bioremediation additives, such as bacteria and/or nutrients, to the contaminated zone. Because hydraulic advection is not practical for delivery in clays, electrokinetic (EK) injection is an alternative for efficient and uniform delivery of bioremediation additive into low-permeability soil and heterogeneous deposits. EK–enhanced bioaugmentation for remediation of clays contaminated with chlorinated solvents is evaluated. Dehalococcoides (Dhc) bacterial strain and lactate ions are uniformly injected in contaminated clay and complete dechlorination of chlorinated ethene is observed in laboratory experiments. The injected bacteria can survive, grow, and promote effective dechlorination under EK conditions and after EK application. The distribution of Dhc within the clay suggests that electrokinetic transport of Dhc is primarily driven by electroosmosis. In addition to biodegradation due to bioaugmentation of Dhc, an EK-driven transport of chlorinated ethenes is observed in the clay, which accelerates cleanup of chlorinated ethenes from the anode side. Compared with conventional advection-based delivery, EK injection is significantly more effective forestablis hingmicrobial reductive dechlorination capacity in low-permeability soils. PMID:22365139

Fish DNA-modified clays: Towards highly flame retardant polymer nanocomposite with improved interfacial and mechanical performance.

PubMed

Zabihi, Omid; Ahmadi, Mojtaba; Khayyam, Hamid; Naebe, Minoo

2016-12-05

Deoxyribonucleic Acid (DNA) has been recently found to be an efficient renewable and environmentally-friendly flame retardant. In this work, for the first time, we have used waste DNA from fishing industry to modify clay structure in order to increase the clay interactions with epoxy resin and take benefit of its additional thermal property effect on thermo-physical properties of epoxy-clay nanocomposites. Intercalation of DNA within the clay layers was accomplished in a one-step approach confirmed by FT-IR, XPS, TGA, and XRD analyses, indicating that d-space of clay layers was expanded from ~1.2 nm for pristine clay to ~1.9 nm for clay modified with DNA (d-clay). Compared to epoxy nanocomposite containing 2.5%wt of Nanomer I.28E organoclay (m-clay), it was found that at 2.5%wt d-clay loading, significant enhancements of ~14%, ~6% and ~26% in tensile strength, tensile modulus, and fracture toughness of epoxy nanocomposite can be achieved, respectively. Effect of DNA as clay modifier on thermal performance of epoxy nanocomposite containing 2.5%wt d-clay was evaluated using TGA and cone calorimetry analysis, revealing significant decreases of ~4000 kJ/m 2 and ~78 kW/m 2 in total heat release and peak of heat release rate, respectively, in comparison to that containing 2.5%wt of m-clay.

Fish DNA-modified clays: Towards highly flame retardant polymer nanocomposite with improved interfacial and mechanical performance

NASA Astrophysics Data System (ADS)

Zabihi, Omid; Ahmadi, Mojtaba; Khayyam, Hamid; Naebe, Minoo

2016-12-01

Deoxyribonucleic Acid (DNA) has been recently found to be an efficient renewable and environmentally-friendly flame retardant. In this work, for the first time, we have used waste DNA from fishing industry to modify clay structure in order to increase the clay interactions with epoxy resin and take benefit of its additional thermal property effect on thermo-physical properties of epoxy-clay nanocomposites. Intercalation of DNA within the clay layers was accomplished in a one-step approach confirmed by FT-IR, XPS, TGA, and XRD analyses, indicating that d-space of clay layers was expanded from ~1.2 nm for pristine clay to ~1.9 nm for clay modified with DNA (d-clay). Compared to epoxy nanocomposite containing 2.5%wt of Nanomer I.28E organoclay (m-clay), it was found that at 2.5%wt d-clay loading, significant enhancements of ~14%, ~6% and ~26% in tensile strength, tensile modulus, and fracture toughness of epoxy nanocomposite can be achieved, respectively. Effect of DNA as clay modifier on thermal performance of epoxy nanocomposite containing 2.5%wt d-clay was evaluated using TGA and cone calorimetry analysis, revealing significant decreases of ~4000 kJ/m2 and ~78 kW/m2 in total heat release and peak of heat release rate, respectively, in comparison to that containing 2.5%wt of m-clay.

Fish DNA-modified clays: Towards highly flame retardant polymer nanocomposite with improved interfacial and mechanical performance

PubMed Central

Zabihi, Omid; Ahmadi, Mojtaba; Khayyam, Hamid; Naebe, Minoo

2016-01-01

Deoxyribonucleic Acid (DNA) has been recently found to be an efficient renewable and environmentally-friendly flame retardant. In this work, for the first time, we have used waste DNA from fishing industry to modify clay structure in order to increase the clay interactions with epoxy resin and take benefit of its additional thermal property effect on thermo-physical properties of epoxy-clay nanocomposites. Intercalation of DNA within the clay layers was accomplished in a one-step approach confirmed by FT-IR, XPS, TGA, and XRD analyses, indicating that d-space of clay layers was expanded from ~1.2 nm for pristine clay to ~1.9 nm for clay modified with DNA (d-clay). Compared to epoxy nanocomposite containing 2.5%wt of Nanomer I.28E organoclay (m-clay), it was found that at 2.5%wt d-clay loading, significant enhancements of ~14%, ~6% and ~26% in tensile strength, tensile modulus, and fracture toughness of epoxy nanocomposite can be achieved, respectively. Effect of DNA as clay modifier on thermal performance of epoxy nanocomposite containing 2.5%wt d-clay was evaluated using TGA and cone calorimetry analysis, revealing significant decreases of ~4000 kJ/m2 and ~78 kW/m2 in total heat release and peak of heat release rate, respectively, in comparison to that containing 2.5%wt of m-clay. PMID:27917901

Fault interaction and stresses along broad oceanic transform zone: Tjörnes Fracture Zone, north Iceland

NASA Astrophysics Data System (ADS)

Homberg, C.; Bergerat, F.; Angelier, J.; Garcia, S.

2010-02-01

Transform motion along oceanic transforms generally occurs along narrow faults zones. Another class of oceanic transforms exists where the plate boundary is quite large (˜100 km) and includes several subparallel faults. Using a 2-D numerical modeling, we simulate the slip distribution and the crustal stress field geometry within such broad oceanic transforms (BOTs). We examine the possible configurations and evolution of such BOTs, where the plate boundary includes one, two, or three faults. Our experiments show that at any time during the development of the plate boundary, the plate motion is not distributed along each of the plate boundary faults but mainly occurs along a single master fault. The finite width of a BOT results from slip transfer through time with locking of early faults, not from a permanent distribution of deformation over a wide area. Because of fault interaction, the stress field geometry within the BOTs is more complex than that along classical oceanic transforms and includes stress deflections close to but also away from the major faults. Application of this modeling to the 100 km wide Tjörnes Fracture Zone (TFZ) in North Iceland, a major BOT of the Mid-Atlantic Ridge that includes three main faults, suggests that the Dalvik Fault and the Husavik-Flatey Fault developed first, the Grismsey Fault being the latest active structure. Since initiation of the TFZ, the Husavik-Flatey Fault accommodated most of the plate motion and probably persists until now as the main plate structure.

Fracture Mechanics Analysis of LH2 Feed Line Flow Liners

NASA Technical Reports Server (NTRS)

James, Mark A.; Dawicke, David S.; Brzowski, Matthew B.; Raju, Ivatury S.; Elliott, Kenny B.; Harris, Charles E.

2006-01-01

Inspections of the Space Shuttle Main Engine revealed fatigue cracks growing from slots in the flow liner of the liquid hydrogen (LH2) feed lines. During flight, the flow liners experience complex loading induced by flow of LH2 and the resonance characteristics of the structure. The flow liners are made of Inconel 718 and had previously not been considered a fracture critical component. However, fatigue failure of a flow liner could have catastrophic effect on the Shuttle engines. A fracture mechanics study was performed to determine if a damage tolerance approach to life management was possible and to determine the sensitivity to the load spectra, material properties, and crack size. The load spectra were derived separately from ground tests and material properties were obtained from coupon tests. The stress-intensity factors for the fatigue cracks were determined from a shell-dynamics approach that simulated the dominant resonant frequencies. Life predictions were obtained using the NASGRO life prediction code. The results indicated that adequate life could not be demonstrated for initial crack lengths of the size that could be detected by traditional NDE techniques.

Effects of simulated clay gouges on the sliding behavior of Tennessee sandston

NASA Astrophysics Data System (ADS)

Shimamoto, Toshihiko; Logan, John M.

1981-06-01

The effects of simulated fault gouge on the sliding behavior of Tennessee sandstone are studied experimentally with special reference to the stabilizing effect of clay minerals mixed into the gouge. About 30 specimens with gouge composed of pure clays, of homogeneously mixed clay and anhydrite, or of layered clay and anhydrite, along a 35° precut are deformed dry in a triaxial apparatus at a confining pressure of 100 MPa, with a shortening rate of about 5 · 10 -4/sec, and at room temperature. Pure clay gouges exhibit only stable sliding, and the ultimate frictional strength is very low for bentonite (mont-morillonite), intermediate for chlorite and illite, and considerably higher for kaolinite. Anhydrite gouge shows violent stick-slip at 100 MPa confining pressure. When this mineral is mixed homogeneously with clays, the frictional coefficient of the mixed gouge, determined at its ultimate frictional strength, decreases monotonically with an increase in the clay content. The sliding mode changes from stick-slip to stable sliding when the frictional coefficient of the mixed clay-anhydrite gouge is lowered down below 90-95% of the coefficient of anhydrite gouge. The stabilizing effect of clay in mixed gouge is closely related to the ultimate frictional strength of pure clays; that is, the effect is conspicuous only for a mineral with low frictional strength. Only 15-20% of bentonite suppresses the violent stick-slip of anhydrite gouge. In contrast, violent stick-slip occurs even if the gouge contains as much as 75% of kaolinite. The behavior of illite and chlorite is intermediate between that of kaolinite and bentonite. Bentonite—anhydrite two-layer gouge exhibits stable sliding even when the bentonite content is only 5%. Thus, the presence of a thin, clay-rich layer in a fault zone stabilizes the behavior much more effectively than do the clay minerals mixed homogeneously with the gouge. This result brings out the mechanical significance of internal structures

Clays, specialty

USGS Publications Warehouse

Virta, R.L.

1998-01-01

Part of a special section on the state of industrial minerals in 1997. The state of the specialty clay industry worldwide for 1997 is discussed. The specialty clays mined in the U.S. are ball clay, fuller's earth, bentonite, fire clay, and kaolin. Sales of specialty clays in the U.S. were around 17 Mt in 1997. Approximately 53 kt of specialty clays were imported.

Nonlinear fracture of concrete and ceramics

NASA Technical Reports Server (NTRS)

Kobayashi, Albert S.; Du, Jia-Ji; Hawkins, Niel M.; Bradt, Richard C.

1989-01-01

The nonlinear fracture process zones in an impacted unnotched concrete bend specimen, a prenotched ceramic bend specimen, and an unnotched ceramic/ceramic composite bend specimen were estimated through hybrid experimental numerical analysis. Aggregate bridging in concrete, particulate bridging in ceramics, and fiber bridging in ceramic/ceramic composite are modeled by Barenblatt-type cohesive zones which are incorporated into the finite-element models of the bend specimens. Both generation and propagation analyses are used to estimate the distribution of crack closure stresses in the nonlinear fracture process zones. The finite-element models are then used to simulate fracture tests consisting of rapid crack propagation in an impacted concrete bend specimen, and stable crack growth and strain softening in a ceramic and ceramic/ceramic composite bend specimens.

Influence of nanoclay on interlaminar shear strength and fracture toughness of glass fiber reinforced nanocomposites

NASA Astrophysics Data System (ADS)

Senthil Kumar, M. S.; Chithirai Pon Selvan, M.; Sampath, P. S.; Raja, K.; Balasundaram, K.

2018-04-01

Multilayer glass fiber reinforced polymer (GFRP) laminates filled with nanoclay was manufactured with compression moulding machine. In the present work, five kinds of nanoclay (Cloisite 25A) loadings viz. 2, 4, 6, 8 and 10% on weight basis of epoxy resin were employed to modify the interlaminar shear strength (ILSS), critical energy release rate (GIc) and impact energy properties of GFRP laminates. Experimental results obtained from ILSS test on clay filled GFRP confirm that the superior strength was attained at low clay content of 155.10 MPa. Furthermore, the mode I interlaminar fracture toughness test conducted on DCB specimens revealed that the commanding improvement of GIc was obtained at 2 wt.% clay content level. On the other hand, both ILSS and fracture toughness was getting reduced at higher clay loadings. At last, the impact strength of the test samples was investigated by using Izod impact test apparatus and observed that the impact energy was increased by 44.39% for 2 wt.% and followed by 24.87% for 4 wt.% clay loadings.

How Deep is the Critical Zone: A Scientific Question with Potential Impact For Decision-makers in Areas of Shale-Gas Development and Hydraulic Fracturing

NASA Astrophysics Data System (ADS)

Brantley, S. L.

2014-12-01

Citizens living in areas of shale-gas development such as the Marcellus gas play in Pennsylvania and surrounding states are cognizant of the possibility that drilling and production of natural gas -- including hydraulic fracturing -- may have environmental impacts on their water. The Critical Zone is defined as the zone from vegetation canopy to the lower limits of groundwater. This definition is nebulous in terms of the lower limit, and yet, defining the bottom of the Critical Zone is important if citizens are to embrace shale-gas development. This is because, although no peer-reviewed study has been presented that documents a case where hydraulic fracturing or formation fluids have migrated upwards from fracturing depths to drinking water resources, a few cases of such leakage have been alleged. On the other hand, many cases of methane migration into aquifers have been documented to occur and some have been attributed to shale-gas development. The Critical Zone science community has a role to play in understanding such contamination problems, how they unfold, and how they should be ameliorated. For example, one big effort of the Critical Zone science community is to promote sharing of data describing the environment. This data effort has been extended to provide data for citizens to understand water quality by a team known as the Shale Network. As scientists learn to publish data online, these efforts must also be made accessible to non-scientists. As citizens access the data, the demand for data will grow and all branches of government will eventually respond by providing more accessible data that will help the public and policy-makers make decisions.

Juxta-articular Plate Fixation in Distal Radius Intra-articular Fractures with Accompanying Volar Free Fragments beyond the Watershed Line

PubMed Central

Lee, Jun-Ku; Lee, Soo-Hyun; Sim, Young-Suk; Kim, Tae-Ho; Baek, Eugene

2018-01-01

Background Although distal radius fractures (DRF) are common fractures, intra-articular comminuted DRF with volar free fragments are uncommon. There is considerable difficulty in the fixation of free fragments beyond the watershed line using the existing volar locking plate. We aimed to examine the efficacy and potential complications associated with the use of juxta-articular volar plates in intra-articular DRF accompanied by free fragments beyond the watershed line. Methods The patients were enrolled in a consecutive manner between 2007 and 2016. In cases of DRF with free fragments beyond the watershed line, we employed a 2.4-mm small fragment juxta-articular volar locking compression plate using a volar Henry approach. A total of 32 patients were included in this study. There were 15 males and 17 females with a mean age of 52.3 years (range, 33 to 69 years). The mean follow-up period was 14.5 months (range, 10 to 24 months). Preoperative radiographs and three-dimensional computed tomography images were used to analyze fracture patterns and assess the free fragments beyond the watershed line. The mean number of free fracture fragments beyond the watershed line was 2.33. Plain radiographs of immediate postoperative and last follow-up were used to confirm fracture union, incongruence, radial height, volar tilt, radial inclination, and arthritic changes. For functional assessment, we measured grip strength, range of motion (ROM), modified Mayo wrist score (MMWS) and determined Disabilities of Arm, Shoulder and Hand (DASH) scores at the last follow-up. Postoperative complications were monitored during the follow-up period. Results All patients obtained sound union without significant complications. At the last follow-up, 16 cases presented with an articular step-off of more than 1 mm (mean, 1.10 mm). The mean MMWS was 76.3 (range, 55 to 90), mean DASH score was 15.38 (range, 9 to 22), mean visual analogue scale score for pain was 1.2 and mean grip strength was 75

Experiment 2033. Injection Test of Upper EE-3 Fracture Zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grigsby, Charles O.

1983-09-12

This experiment is designed to investigate the apparent lithologic boundary between the low-opening-pressure fracture system (upper EE-3 fracture and Phase I system) and the high-opening-pressure fracture system (lower fracture in EE-3 and in EE-2). The experiment will test for resistence to breakthrough into the lower EE-2 fracture system at relatively low pressure and will define the veting behavior of the low pressure system.

Ball clay

USGS Publications Warehouse

Virta, R.L.

2013-01-01

Four companies — H.C. Spinks Clay Co., Inc., Imerys, Old Hickory Clay Co. and Unimin Corp. — mined ball clay in five U.S. states in 2012. Production, on the basis of preliminary data, was 900 kt (992,000 st), with an estimated value of $42.3 million. This was a slight increase in tonnage from 886 kt (977,000 st), with a value of $40.9 million in 2011. Tennessee was the leading ball clay producing state, with 63 percent of domestic production, followed by Texas, Mississippi, Kentucky and Indiana. Reported ball clay production from Indiana probably was fire clay rather than ball clay. About 69 percent of total ball clay production was airfloat, 20 percent was crude and 11 percent was water-slurried.

The rheological behaviour of fracture-filling cherts: example of Barite Valley dikes, Barberton Greenstone Belt, South Africa

NASA Astrophysics Data System (ADS)

Ledevin, M.; Arndt, N.; Davaille, A.; Ledevin, R.; Simionovici, A.

2015-02-01

In the Barberton Greenstone Belt, South Africa, a 100-250 m thick complex of carbonaceous chert dikes marks the transition from the Mendon Formation to the Mapepe Formation (3260 Ma). The sub-vertical- to vertical position of the fractures, the abundance of highly shattered zones with poorly rotated angular fragments and common jigsaw fit, radial structures, and multiple injection features point to repetitive hydraulic fracturing that released overpressured fluids trapped within the shallow crust. The chemical and isotopic compositions of the chert favour a model whereby seawater-derived fluids circulated at low temperature (< 100-150 °C) within the shallow crust. From the microscopic structure of the chert, the injected material was a slurry of abundant clay-sized, rounded particles of silica, carbonaceous matter and minor clay minerals, all suspended in a siliceous colloidal solution. The dike geometry and characteristics of the slurry concur on that the chert was viscoelastic, and most probably thixotropic at the time of injection: the penetration of black chert into extremely fine fractures is evidence for low viscosity at the time of injection and the suspension of large country rock fragments in the chert matrix provides evidence of high viscosity soon thereafter. We explain the rheology by the particulate and colloidal structure of the slurry, and by the characteristic of silica suspensions to form cohesive 3-D networks through gelation. Our results provide valuable information about the compositions, physical characteristics and rheological properties of the fluids that circulated through Archean volcano-sedimentary sequences, which is an additional step to understand conditions on the floor of Archean oceans, the habitat of early life.

Killer clays! Natural antibacterial clay minerals

USGS Publications Warehouse

Williams, L.B.; Holland, M.; Eberl, D.D.; Brunet, T.; De Courrsou, L. B.

2004-01-01

The clay chemical properties that may be important in medicine were investigated. It was found that natural clay minerals can have striking and very specific effects on microbial populations. The effects can range from potentially enhanced microbial growth to complete sterilization. This paper presents evidence that natural clay minerals can be effective antimicrobial agents.

Ball clay

USGS Publications Warehouse

Virta, Robert L.

2010-01-01

The article reports on the global market performance of ball clay in 2009 and presents an outlook for its 2010 performance. Several companies mined ball call in the country including Old Hickey Clay Co., Kentucky-Tennessee Clay Co., and H.C. Spinks Clay Co. Information on the decline in ball clay imports and exports is also presented.

Supracrustal origin of plagiogranite from the Gallieni Fracture Zone, Southwest Indian Ridge

NASA Astrophysics Data System (ADS)

Zhu, Jihao; Li, Zhenggang; Chu, Fengyou; Fu, Bin; Dong, Yanhui; Chen, Ling; Liu, Jiqiang

2017-04-01

Small amounts of felsic rocks such as tonalite, trondjhemite and diorite often called oceanic plagiogranites were found at all structure levels of the oceanic crust. They can be formed either by partial melting of hydrated gabbros and/or sheeted dikes, or by late-stage differentiation of parental mid-ocean ridge basalt melts. Here we report a granodiorite sampled in the Gallieni Fracture Zone, Southwest Indian Ridge, shows no ocean crust affinity but the nature of the continental crust. The granodiorite is extremely enriched in K2O (3.72%) and its rare-earth-element distribution pattern is incomparable to any type of oceanic plagiogranites from mid-ocean ridge and ophiolites, but similar to the Upper Continental Crust. Moreover, the in-situ zircon O isotopes (δ18O=5.9-7.5‰) are much higher than the plagiogranites from all the tectonic settings relevant to ocean crust generation, while Hf isotope compositions (ɛHf(0) =-4.0 to -7.9) are much lower than global oceanic basalts. In addition, the granodiorite suffered low-grade metamorphism as reflected by the penetration of late-stage felsic veins and the occurrence of metamorphic minerals such as epidote and chlorite. Secondary vein quartz has negative δ18O values as low as -3.9‰, suggesting the involvement of meteoric water. Zircon U-Pb age (183.7±1.2Ma) shows that the granodiorite was formed contemporarily with Karoo volcanism associating with the breakup of Gondwanaland. We suggest that it may be formed by the anataxis of continental crustal materials by underplated Karoo basaltic magma. Combining our unreported high-grade quartzite with zircon U-Pb ages of more than 500Ma and a Jurassic quartz diorite reported earlier which all sampled in or near the Gallieni Fracture Zone, we propose that a continental block probably from the South Madagascar was split during continental breakup but retained near the ridge segment as a result of repeated ridge jumping and transform migration. Keywords: zircon Hf-O isotopes

Water chemistry at Snowshoe Mountain, Colorado: mixed processes in a common bedrock

USGS Publications Warehouse

Hoch, A.R.; Reddy, M.M.

2001-01-01

At Snowshoe Mountain the primary bedrock is quite homogeneous, but weathering processes vary as waters moves through the soils, vadose zone and phreatic zone of the subsurface. In the thin soil, physical degradation of tuff facilitates preferential dissolution of potassium ion from glass within the rock matrix, while other silicate minerals remain unaltered. In the vadose zone, in the upper few meters of fractured bedrock, dilute water infiltrates during spring snowmelt and summer storms, leading to preferential dissolution of augite exposed on fracture surfaces. Deeper yet, in the phreatic zone of the fractured bedrock, Pleistocene calcite fracture fillings dissolve, and dioctahedral and trioctahedral clays form as penetrative weathering alters feldspar and pyroxene. Alkalinity is generated and silica concentrations are buffered by mineral alteration reactions.

Proximal third humeral shaft fractures -- a fracture entity not fully characterized by conventional AO classification.

PubMed

Stedtfeld, H W; Biber, R

2014-01-01

The retrospective study was made to evaluate the fracture patterns at the proximal humeral shaft for which the long version of a standard proximal humeral nail (PHNLV) has been used. The indication has been decided by the individual surgeons. Over a five year period 72 consecutive PHNLV cases of an acute fracture were identified and were included in the study. Mean patient age was 68.9 years. Gender ratio was m/f=22/50. 86.1% of the patients fractured their humerus by a fall, the rest by a high velocity accident. We analysed patient comorbidity, ASA score, osteoporosis, social status before accident, additional injuries affecting local soft tissues or other anatomic regions. We analysed the expansion of the fractures, dividing the humerus into five zones. Fracture morphology was categorized according to the standard AO/ASIF classification (if applicable). Comorbidities were found in 76.4% of the patients. Almost all patients (93.1%) had been living independently at home before the accident. 47.2% of patients had osteoporosis in their medical history. Five patients (6.9%) had a primary palsy of the radial nerve. Six fractures chosen for PHNLV fixation were clearly restricted to the humeral head. The remaining 66 fractures were located in the humeral shaft (AO region 12). There were 5 segmental fractures. Of the remaining 67 fractures affecting the proximal third of the humeral shaft 49.3 percent extended into the humeral head. 98 percent of these fractures displayed spiral morphology. Proximal humeral shaft fractures are amazingly similar to subtrochanteric and distal tibial shaft fractures: Spiral fracture types with different grades of comminution are absolutely dominant; a great proportion of the fractures extend into the humeral head with growing tendency of displacement if located closer to the humeral head. Diverging traction of deltoid and pectoralis muscle causes typical displacement if the fracture line runs in between their attachments substantiating the

Ball clay

USGS Publications Warehouse

Virta, R.L.

2011-01-01

The article discusses the latest developments in the global ball clay mining industry, particularly in the U.S., as of June 2011. It cites several firms that are involved in ball clay mining in the U.S., including HC Spins Clay Co. Inc., the Imerys Group and Old Hickory Clay Co. Among the products made from ball clay are ceramic tiles, sanitaryware, as well as fillers, extenders and binders.

Clay Mineralogy, Authigenic Smectite Concentration, and Fault Weakening of the San Gregorio Fault; Moss Beach, California

NASA Astrophysics Data System (ADS)

Mazzoni, S.; Moore, J.; Bish, D. L.

2002-12-01

The apparently weak nature of the San Andreas fault system poses a fundamental geophysical question. The San Gregorio fault at Moss Beach, CA is an active splay of the right-lateral San Andreas fault zone and has a total offset of about 150 km. At Moss Beach, the San Gregorio fault offsets Pliocene sedimentary rocks and consists of a clay-rich gouge zone, eastern sandstone block, and western mudstone block. In the presence of fluids, smectite clays can swell and become very weak to shearing. We studied a profile of samples across the fault zone and wall rocks to determine if there is a concentration of smectite in the gouge zone and propose a possible formation mechanism. Samples were analyzed using standard quantitative X-ray diffraction methods and software recently developed at Los Alamos National Lab. XRD results show a high smectite/illite (weak clay/strong clay) ratio in the gouge (S/I ratio=2-4), lower in the mudstone (S/I ratio=2), and very low in the sandstone (S/I ratio=1). The variability of smectite/illite ratio in the gouge zone may be evidence of preferential alteration where developed shear planes undergo progressive smectite enrichment. The amount of illite layers in illite/smectites is 5-30%, indicating little illitization; therefore, these fault rocks have not undergone significant diagenesis above 100 degrees C and illite present must be largely detrital. Bulk mineralogy shows significant anti-correlation of smectite with feldspar, especially in the gouge, suggesting authigenic smectite generation from feldspar. Under scanning-electron microscope inspection, smectites have fibrous, grain coating growth fabrics, also suggesting smectite authigenesis. If in situ production of smectite via chemical alteration is possible in active faults, it could have significant implications for self-generated weakening of faults above the smectite-to-illite transition (<150 degrees C, or 5-7km).

Delineating the Groundwater Recharge Zone in the Pingtung Plan , Taiwan with Electrical Resistivity Surveys

NASA Astrophysics Data System (ADS)

Wu, C.; Chang, P.; Chang, L.; Chen, J.; Huang, C.

2012-12-01

In this study we used the two-dimensional electrical resistivity imaging (ERI) method, as well as the core records of monitoring wells to help determine the groundwater recharge zone in Pingtung plain in southwestern Taiwan. Pingtung fluvial plain is one of the major groundwater resources in Taiwan which is composed of several alluvial fans deriving from the uplifted mountain area to the east and north of the plain. The thick gravel layer constitutes the main recharge area of the upper alluvial fans and the conductive clay sediments dominate most of the lower fans. With the core records, we found that, the gravel layers have higher resistivity (mostly over 200 Ohm-m) and the resistivities of the clayey layers are low (about 1~10 Ohm-m). Therefore with the resistivity surveys we can have more confidences for determining the boundary of the groundwater recharge area in the area in-between the monitoring wells. In the past two years, we have finished 24 two-dimensional electrical resistivity imaging profile lines from Meinong to Fangliao, the lines are oriented in the east-west direction, and each line was about 400 meters long. With the inverted results, we are able to characterize two major alluvial systems and their recharge zones in the Pingtung fluvial plain. The resistivities we measured almost are consistent to the core records of monitoring wells except for the Wanluan site, which shows thick gravel layer in the drilling records but has low resistivity in the nearby resistivity survey. A reasonable explanation is that the electrical resistivity is sensitive to clayey materials with lower resistivities. The intercalated clay within the gravel layers is not shown in the churn drilling records.

Characterization of a high-transmissivity zone by well test analysis: Steady state case

USGS Publications Warehouse

Tiedeman, Claire; Hsieh, Paul A.; Christian, Sarah B.

1995-01-01

A method is developed to analyze steady horizontal flow to a well pumped from a confined aquifer composed of two homogeneous zones with contrasting transmissivities. Zone 1 is laterally unbounded and encloses zone 2, which is elliptical in shape and is several orders of magnitude more transmissive than zone 1. The solution for head is obtained by the boundary integral equation method. Nonlinear least squares regression is used to estimate the model parameters, which include the transmissivity of zone 1, and the location, size, and orientation of zone 2. The method is applied to a hypothetical aquifer where zone 2 is a long and narrow zone of vertical fractures. Synthetic data are generated from three different well patterns, representing different areal coverage and proximity to the fracture zone. When zone 1 of the hypothetical aquifer is homogeneous, the method correctly estimates all model parameters. When zone 1 is a randomly heterogeneous transmissivity field, some parameter estimates, especially the length of zone 2, become highly uncertain. To reduce uncertainty, the pumped well should be close to the fracture zone, and surrounding observation wells should cover an area similar in dimension to the length of the fracture zone. Some prior knowledge of the fracture zone, such as that gained from a surface geophysical survey, would greatly aid in designing the well test.

Patterns and perspectives in applied fracture mechanics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Merkle, J.G.

1994-12-31

This lecture begins with a overview of applied fracture mechanics pertinent to safety of pressure vessels. It then progresses to a chronological panorama of experimental and analytical results. To be useful and dependable in safety analysis of real structures, new analysis developments must be physically realistic, which means that they must accurately describe physical cause and effect. Consequently, before mathematical modeling can begin, cause and effect must be established from experimental data. This can be difficult and time consuming, but worth the effort. Accordingly, the theme of this paper is that the search for patterns is constant and vital. Thismore » theme is illustrated by the development of small, single-specimen, fracture toughness testing techniques. It is also illustrated by the development, based on two different published large-strain, elastic-plastic, three-dimensional finite-element analyses, of a hypothesis concerning three-dimensional loss of constraint. When a generalization of Irwin`s thickness-normalized plastic-zone parameter, reaches a value close to 2{pi}, the through-thickness contraction strain at the apex of the near-tip logarithmic-spiral slip-line region becomes the dominant negative strain accommodating crack opening. Because slip lines passing from the midplane to the stress-free side surfaces do not have to curve, once these slip lines are established, stresses near the crack tip are only elevated by strain hardening and constraint becomes significantly relaxed. This hypothesis, based on published three-dimensional elastic-plastic analyses, provides a potentially valuable means for gaining additional insight into constraint effects on fracture toughness by considering the roles played by the plastic strains as well as the stresses that develop near a crack tip.« less

Treatment of proximal fifth metatarsal bone fractures in athletes.

PubMed

Japjec, M; Starešinić, M; Starjački, M; Žgaljardić, I; Štivičić, J; Šebečić, B

2015-11-01

Proximal fifth metatarsal (V MT) bone fractures are common injuries that are a major diagnostic and therapeutic challenge. Lawrence and Botte considered different treatment options and the possibility of recovery and divided these fractures into three different regions: tuberosity avulsion fractures (zone I), acute fractures of the metaphysis at the level of the intermetatarsal junction (zone II) and proximal diaphysis stress fracture (zone III). A total of 42 athletes with fracture of the V MT bone in zone II and III were treated in our institution during a 6-year period. All patients were offered surgical treatment, but nine patients refused surgery. Thus, the patients were divided into two groups: group 1 comprised 33 patients who underwent an intramedullary screw fixation operation under regional anaesthesia immediately after the fracture was diagnosed; group 2 contained the remaining nine patients who had refused surgery and received conservative therapy with non-weight-bearing short-leg casts or orthosis. Follow-up ranged from 6 to 24 months. All fractures healed in group 1: healing occurred within 8 weeks in 26 patients and was prolonged to 16 to 18 weeks in four patients. In group 2, fractures healed in four patients but did not heal in five patients even after 6 months. Four of the five patients in whom the fracture did not heal required subsequent osteosynthesis because they had constant problems that caused absence from sport. After the operation, their fractures healed in an average of 10 weeks. One patient decided not to undergo the operation due to the absence of subjective symptoms. Three patients in group 1 who started intensive training sustained a refracture and underwent re-operation in which osteosynthesis was performed with a stronger screw. The fractures then healed again. Treatment results were evaluated radiologically and clinically using the Modified Foot Score. Results in group 1 were significantly better than those in group 2 and there

Distribution of stress drop, stiffness, and fracture energy over earthquake rupture zones

USGS Publications Warehouse

Fletcher, Joe B.; McGarr, A.

2006-01-01

Using information provided by slip models and the methodology of McGarr and Fletcher (2002), we map static stress drop, stiffness (k = ????/u, where ???? is static stress drop and u is slip), and fracture energy over the slip surface to investigate the earthquake rupture process and energy budget. For the 1994 M6.7 Northridge, 1992 M7.3 Landers, and 1995 M6.9 Kobe earthquakes, the distributions of static stress drop show strong heterogeneity, emphasizing the importance of asperities in the rupture process. Average values of static stress drop are 17, 11, and 4 Mpa for Northridge, Landers, and Kobe, respectively. These values are substantially higher than estimates based on simple crack models, suggesting that the failure process involves the rupture of asperities within the larger fault zone. Stress drop as a function of depth for the Northridge and Landers earthquakes suggests that stress drops are limited by crustal strength. For these two earthquakes, regions of high slip are surrounded by high values of stiffness. Particularly for the Northridge earthquake, the prominent patch of high slip in the central part of the fault is bordered by a ring of high stiffness and is consistent with expectations based on the failure of an asperity loaded at its edge due to exterior slip. Stiffness within an asperity is inversely related to its dimensions. Estimates of fracture energy, based on static stress drop, slip, and rupture speed, were used to investigate the nature of slip weakening at four locations near the hypocenter of the Kobe earthquake for comparison with independent results based on a dynamic model of this earthquake. One subfault updip and to the NE of the hypocenter has a fracture energy of 1.1 MJ/m2 and a slip-weakening distance, Dc, of 0.66 m. Right triangles, whose base and height are Dc and the dynamic stress drop, respectively, approximately overlie the slip-dependent stress given by Ide and Takeo (1997) for the same locations near the hypocenter. The

Zooplankton and micronekton biovolume at the Mid-Atlantic Ridge and Charlie-Gibbs Fracture Zone estimated by multi-frequency acoustic survey

NASA Astrophysics Data System (ADS)

Cox, Martin J.; Letessier, Tom B.; Brierley, Andrew S.

2013-12-01

To examine the potential influence of the Mid-Atlantic Ridge and Charlie-Gibbs Fracture Zone on zooplankton and micronekton biovolume in the upper 200 m of the water column, multi-frequency acoustic data (18, 38, 70, 120 and 200 kHz) were acquired at four study sites from the RRS James Cook using hull-mounted scientific echosounders. Multi-frequency inversion techniques were employed to classify each 20 m depth×500 m along-track region of the water column to a zooplankton or micronekton acoustic scatterering class, such as copepod or euphausiid, and to estimate biovolume. We found a highly significant north-south (across fracture zone) difference in areal biovolume (p-value=0.01) but no significant east-west (across ridge) difference (p-value=0.07). Areal biovolume at all sites was dominated by the acoustic scatter class ‘euphausiid’, with higher biovolumes occurring in the southern stations. Our acoustic observations suggest the existence of different pelagic communities to the north and south of the SPF, with the southern community having a greater proportion of fish.

SERDP and ESTCP Expert Panel Workshop on Reducing the Uncertainty of DNAPL Source Zone Remediation

DTIC Science & Technology

2006-09-01

Conventional – Wells – Geoprobe • Pneumatic Fracturing • Hydraulic Fracturing • Pressure Pulse Success is achieved when enough Oxidant/Reductant is...al, 2003; Parker et al, 2004). In fractured aquitards (i.e., silts/clays and shales/mudstones), where the bulk hydraulic conductivity is...relatively low, DNAPL can readily migrate into these units via the fractures and, after a few years to decades, nearly all the mass resides in the low

Ball clay

USGS Publications Warehouse

Virta, R.L.

2007-01-01

The article offers information on ball clay. Among the companies that mine ball clay in the U.S. are H.C. Spinks Clay, Kentucky-Tennessee Clay and Old Hickory Clay. In 2006, an estimated 1.2 million tons of the mineral was sold or used domestically and exported. Forty-percent of the total sales is accounted for ceramic floor and wall tile followed by sanitaryware and miscellaneous ceramics. Its average value was $ 45 per ton in 2006.

Safe Zone of Posterior Screw Insertion for Talar Neck Fractures on 3-Dimensional Reconstruction Model.

PubMed

Wu, Jian-Qun; Ma, Sheng-Hui; Liu, Song; Qin, Cheng-He; Jin, Dan; Yu, Bin

2017-02-01

To investigate the optimal posterior screw placement and the geometry of safe zones for screw insertion in the talar neck. Computed tomography data for 15 normal feet were imported into Mimics 10.01 software for 3-dimensional reconstruction; 4.0-mm-diameter screws were simulated from the lateral tubercle of the posterior process of the talus to the talar head. The range of screw paths trajectories and screw lengths at nine locations that did not breach the cortex of the talus were evaluated. In addition, the farthest (point a) and nearest point (point b) of the safe zone to the subtalar joint at each location, the anteversion angle (angle A), which is parallel to the sagittal plane, and the horizontal angle (angle B), which is perpendicular to the sagittal plane, were measured. The safe zone was mainly between the 30% location and the 60% location; the width of each safe zone was 13.6° ± 1.4°; the maximum height of each safe zone was 7.8° ± 1.2°. The height of the safe zone was lowest at the 30% location (4.5°) and highest at the 50% location (7.3°). The mixed safe zone of all tali was between the 50% location and the 60% location. When a screw was inserted at point a, the safe entry distance (screw length) ranged from 48.8 to 49.5 mm, and when inserted to point b, the distance ranged from 48.2 to 48.9 mm. And inserting a 48.7 mm screw, 5.6° laterally and 7.4° superiorly, from the lateral tubercle of the posterior process of the talus towards the talar head is safest. The safe zone of posterior screw fixation have been defined applying to most talus, assuming the fractures are well reduced, this may strengthen the stability, shorten the operation time and reduce the incidence of surgical complications. © 2017 Chinese Orthopaedic Association and John Wiley & Sons Australia, Ltd.

Measurement of the "safe zone" and the "dangerous zone" for the screw placement on the quadrilateral surface in the treatment of pelvic and acetabular fractures with Stoppa approach by computational 3D technology.

PubMed

Zhang, Sheng; Su, Wanhan; Luo, Qiang; Leung, Frankie; Chen, Bin

2014-01-01

This study is aimed at definition of the safe and dangerous zone for screw placement with Stoppa approach for rapid identification during operation and a new way for the studies on the "safe zone." Pelvic CT data of 84 human subjects were recruited to reconstruct the three-dimensional (3D) models. The distances between the edges of the "safe zone," "dangerous zone," and specific anatomic landmarks such as the obturator canal and the pelvic brim were precisely measured, respectively. The results show that the absolute "dangerous zone" was from the pelvic brim to 3.07 cm below it and within 2.86 cm of the obturator canal, while the region 3.56 cm below the pelvic brim or 3.85 cm away from the obturator canal was the absolute "safe zone" for screw placement. The region between the absolute "safe zone" and the absolute "dangerous zone" was the relatively "dangerous zone." As a conclusion, application of computer-assisted 3D modeling techniques aids in the precise measurement of "safe zone" and "dangerous zone" in combination with Stoppa incision. It was not recommended to place screws on the absolute dangerous zone, while, for the relatively "dangerous zone," it depends on the individual variations in bony anatomy and the fracture type.

Spatial and Temporal Variation of in-situ Stress in and around Active Fault zones in Central Japan

NASA Astrophysics Data System (ADS)

Ikeda, R.; Omura, K.; Matsuda, T.; Iio, Y.

2002-12-01

In the "Active Fault Zone Drilling Project in Japan," we have compared the relationship between the stress concentration state and the heterogeneous strength of an earthquake fault zone in different conditions. The Nojima fault which appeared on the surface by the 1995 Great Kobe earthquake (M=7.2) and the Neodani fault which appeared by the 1891 Nobi earthquake (M=8.0), have been drilled through their fault fracture zones. A similar experiment conducted on and research of the Atera fault, of which some parts have seemed to be dislocated by the 1586 Tensyo earthquake (M=7.9). We can use a deep borehole as a reliable tool to understand overall fault structure and composed materials directly. Additionally, the stress states in and around the fault fractured zones were obtained from in-situ stress measurements by the hydraulic fracturing method. Important phenomena such as rapid stress drop in the fault fracture zones were observed in the Neodani well (1300 m deep) and the Nojima well (1800 m) of the fault zone drillings, as well as in the Ashio well (2,000 m) in the focal area. In the Atera fault project, we have conducted integrated investigations by surface geophysical survey and drilling around the Atera fault. Four boreholes (400 m to 600 m deep) were located on a line crossing the fracture zone of the Atera fault. We noted that the stress magnitude decreases in the area closer to the center of the fracture zone. Furthermore the orientation of the maximum horizontal compressive stress was almost reverse of the fault moving direction. These results support the idea that the differential stress is extremely small at narrow zones adjoining fracture zones. We also noted that the frictional strength of the crust adjacent to the faults is high and the level of shear stress in the crust adjacent to the faults is principally controlled by the frictional strength of rock. We argue that the stress state observed in these sites exists only if the faults are quite "weak." As

Deposition of Suspended Clay to Open and Sand-Filled Framework Gravel Beds in a Laboratory Flume

NASA Astrophysics Data System (ADS)

Mooneyham, Christian; Strom, Kyle

2018-01-01

Pulses of fine sediment composed of sand, silt, and clay can be introduced to gravel bed rivers through runoff from burn-impacted hillslopes, landslides, bank failure, or the introduction of reservoir sediment as a result of sluicing or dam decommissioning. Here we present a study aimed at quantifying exchange between suspensions of clay and gravel beds. The questions that motivate the work are: how do bed roughness and pore space characteristics, shear velocity (u∗), and initial concentration (C0) affect clay deposition on or within gravel beds? Where does deposition within these beds occur, and can deposited clay be resuspended while the gravel is immobile? We examine these questions in a laboratory flume using acrylic, open-framework gravel, and armored sand-gravel beds under conditions of varying u∗ and C0. Deposition of clay occurred to all beds (even with Rouse numbers ˜ 0.01). We attribute deposition under full suspension conditions to be an outcome of localized protected zones where clay can settle and available pore space in the bed. For smooth wall cases, protection came from the viscous wall region and the development of bed forms; for the rough beds, protection came from separation zones and low-velocity pore spaces. Bed porosity was the strongest influencer of nondimensional deposition rate; deposition increased with porosity. Deposition was inversely related to u∗ for the acrylic bed runs; no influence of u∗ was found for the porous bed runs. Increases in discharge resulted in resuspension of clay from acrylic beds; no resuspension was observed in the porous bed runs.

Clay Play

ERIC Educational Resources Information Center

Rogers, Liz; Steffan, Dana

2009-01-01

This article describes how to use clay as a potential material for young children to explore. As teachers, the authors find that their dialogue about the potential of clay as a learning medium raises many questions: (1) What makes clay so enticing? (2) Why are teachers noticing different play and conversation around the clay table as compared to…

Clay at Nili Fossae

NASA Technical Reports Server (NTRS)

2006-01-01

at the upper right, the small mesa -- a flat-topped hill -- at the center of the image is a remnant of an overlying rock layer that was eroded away. The greenish clay areas at the base of the hill were exposed by erosion of the overlying rock. The images at the upper right and lower left both show that the reddish-toned olivine occurs as sand dunes on top of the greenish clay deposits. The image at the lower right shows details of the clay-rich rock, including that they are extensively fractured into small, polygonal blocks just a few meters in size. Taken together, the CRISM and HiRISE data show that the clay-rich rocks are the oldest at the site, that they are exposed where overlying rock has been eroded away, and that the olivine is not part of the clay-rich rock. Rather it occurs in sand dunes blowing across the clay.

Many more images of Nili Fossae and other clay-rich areas will be taken over the next two years. They will be used to try to understand the earliest climate of Mars that is recorded in the planet's rocks.

The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) is one of six science instruments on NASA's Mars Reconnaissance Orbiter. Led by The Johns Hopkins University Applied Physics Laboratory, the CRISM team includes expertise from universities, government agencies and small businesses in the United States and abroad.

CRISM's mission: Find the spectral fingerprints of aqueous and hydrothermal deposits and map the geology, composition and stratigraphy of surface features. The instrument will also watch the seasonal variations in Martian dust and ice aerosols, and water content in surface materials o leading to new understanding of the climate.

NASA's Jet Propulsion Laboratory, a division of the Califonia Institute of Technology, Pasadena, manages the Mars Reconnaissance Orbiter for the NASA Science Mission Directorate, Washington. Lockheed Martin Space Systems, Denver, is the prime contractor and built the spacecraft.

Characterization of fracture permeability with high-resolution vertical flow measurements during borehole pumping.

USGS Publications Warehouse

Paillet, Frederick L.; Hess, A.E.; Cheng, C.H.; Hardin, E.

1987-01-01

The distribution of fracture permeability in granitic rocks was investigated by measuring the distribution of vertical flow in boreholes during periods of steady pumping. Pumping tests were conducted at two sites chosen to provide examples of moderately fractured rocks near Mirror Lake, New Hampshire and intensely fractured rocks near Oracle, Arizona. A sensitive heat-pulse flowmeter was used for accurate measurements of vertical flow as low as 0.2 liter per minute. Results indicate zones of fracture permeability in crystalline rocks are composed of irregular conduits that cannot be approximated by planar fractures of uniform aperture, and that the orientation of permeability zones may be unrelated to the orientation of individual fractures within those zones.-Authors

Subcritical fracture propagation in rocks: An examination using the methods of fracture mechanics and non-destructive testing. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Swanson, P. L.

1984-01-01

An experimental investigation of tensile rock fracture is presented with an emphasis on characterizing time dependent crack growth using the methods of fracture mechanics. Subcritical fracture experiments were performed in moist air on glass and five different rock types at crack velocities using the double torsion technique. The experimental results suggest that subcritical fracture resistance in polycrystals is dominated by microstructural effects. Evidence for gross violations of the assumptions of linear elastic fracture mechanics and double torsion theory was found in the tests on rocks. In an effort to obtain a better understanding of the physical breakdown processes associated with rock fracture, a series of nondestructive evaluation tests were performed during subcritical fracture experiments on glass and granite. Comparison of the observed process zone shape with that expected on the basis of a critical normal principal tensile stress criterion shows that the zone is much more elongated in the crack propagation direction than predicted by the continuum based microcracking model alone.

Fire clay

USGS Publications Warehouse

Virta, R.L.

2013-01-01

Four companies mined fire clay in three states in 2012. Production, based on a preliminary survey of the fire clay industry, was estimated to be 230 kt (254,000 st) valued at $6.98 million, an increase from 215 kt (237,000 st) valued at $6.15 million in 2011. Missouri was the leading producing state, followed by Colorado and Texas, in decreasing order by quantity. The number of companies mining fire clay declined in 2012 because several common clay producers that occasionally mine fire clay indicated that they did not do so in 2012.

Flows of bottom water in fractures of the North Mid-Atlantic Ridge

NASA Astrophysics Data System (ADS)

Morozov, E. G.; Tarakanov, R. Yu.; Demidova, T. A.; Makarenko, N. I.

2017-06-01

It has been shown that the total transport of Antarctic Bottom Water (AABW) in the northern fractures (Kane, Cabo Verde, Marathon) are one order of magnitude smaller than in the southern fractures (Vema, Doldrums, Vernadsky). The estimates of AABW transport through this group of fractures based on measurements in 2014 were approximately 0.28 Sv, which is about 25% of the transport through the Vema Fracture Zone. However, the coldest water flows through the Vema Fracture Zone.

Ball clay

USGS Publications Warehouse

Virta, R.L.

2001-01-01

Part of the 2000 annual review of the industrial minerals sector. A general overview of the ball clay industry is provided. In 2000, sales of ball clay reached record levels, with sanitary ware and tile applications accounting for the largest sales. Ball clay production, consumption, prices, foreign trade, and industry news are summarized. The outlook for the ball clay industry is also outlined.

Hydraulic Properties of Closely Spaced Dipping Open Fractures Intersecting a Fluid-Filled Borehole Derived From Tube Wave Generation and Scattering

NASA Astrophysics Data System (ADS)

Minato, Shohei; Ghose, Ranajit; Tsuji, Takeshi; Ikeda, Michiharu; Onishi, Kozo

2017-10-01

Fluid-filled fractures and fissures often determine the pathways and volume of fluid movement. They are critically important in crustal seismology and in the exploration of geothermal and hydrocarbon reservoirs. We introduce a model for tube wave scattering and generation at dipping, parallel-wall fractures intersecting a fluid-filled borehole. A new equation reveals the interaction of tube wavefield with multiple, closely spaced fractures, showing that the fracture dip significantly affects the tube waves. Numerical modeling demonstrates the possibility of imaging these fractures using a focusing analysis. The focused traces correspond well with the known fracture density, aperture, and dip angles. Testing the method on a VSP data set obtained at a fault-damaged zone in the Median Tectonic Line, Japan, presents evidences of tube waves being generated and scattered at open fractures and thin cataclasite layers. This finding leads to a new possibility for imaging, characterizing, and monitoring in situ hydraulic properties of dipping fractures using the tube wavefield.

Numerical examination of the factors controlling DNAPL migration through a single fracture.

PubMed

Reynolds, D A; Kueper, B H

2002-01-01

The migration of five dense nonaqueous phase liquids (DNAPLs) through a single fracture in a clay aquitard was numerically simulated with the use of a compositional simulator. The effects of fracture aperture, fracture dip, matrix porosity, and matrix organic carbon content on the migration of chlorobenzene, 1,2-dichloroethylene, trichloroethylene, tetra-chloroethylene, and 1,2-dibromoethane were examined. Boundary conditions were chosen such that DNAPL entry into the system was allowed to vary according to the stresses applied. The aperture is the most important factor of those studied controlling the migration rate of DNAPL through a single fracture embedded in a clay matrix. Loss of mass to the matrix through diffusion does not significantly retard the migration rate of the DNAPL, particularly in larger aperture fractures (e.g., 50 microm). With time, the ratio of diffusive loss to the matrix to DNAPL flux into the fracture approaches an asymptotic value lower than unity. The implication is that matrix diffusion cannot arrest the migration of DNAPL in a single fracture. The complex relationships between density, viscosity, and solubility that, to some extent, govern the migration of DNAPL through these systems prevent accurate predictions without the use of numerical models. The contamination potential of the migrating DNAPL is significantly increased through the transfer of mass to the matrix. The occurrence of opposite concentration gradients within the matrix can cause dissolved phase contamination to exist in the system for more than 1000 years after the DNAPL has been completely removed from the fracture.

Drill-back studies examine fractured, heated rock

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wollenberg, H.A.; Flexser, S.; Myer, L.R.

1990-01-01

To investigate the effects of heating on the mineralogical, geochemical, and mechanical properties of rock by high-level radioactive waste, cores are being examined from holes penetrating locations where electric heaters simulated the presence of a waste canister, and from holes penetration natural hydrothermal systems. Results to date indicate the localized mobility and deposition of uranium in an open fracture in heated granitic rock, the mobility of U in a breccia zone in an active hydrothermal system in tuff, and the presence of U in relatively high concentration in fracture-lining material in tuff. Mechanical -- property studies indicate that differences inmore » compressional- and shear-wave parameters between heated and less heated rock can be attributed to differences in the density of microcracks. Emphasis has shifted from initial studies of granitic rock at Stripa, Sweden to current investigations of welded tuff at the Nevada Test Site. 7 refs., 8 figs.« less

A Fracture Decoupling Experiment

NASA Astrophysics Data System (ADS)

Stroujkova, A. F.; Bonner, J. L.; Leidig, M.; Ferris, A. N.; Kim, W.; Carnevale, M.; Rath, T.; Lewkowicz, J.

2012-12-01

Multiple observations made at the Semipalatinsk Test Site suggest that conducting nuclear tests in the fracture zones left by previous explosions results in decreased seismic amplitudes for the second nuclear tests (or "repeat shots"). Decreased seismic amplitudes reduce both the probability of detection and the seismically estimated yield of a "repeat shot". In order to define the physical mechanism responsible for the amplitude reduction and to quantify the degree of the amplitude reduction in fractured rocks, Weston Geophysical Corp., in collaboration with Columbia University's Lamont Doherty Earth Observatory, conducted a multi-phase Fracture Decoupling Experiment (FDE) in central New Hampshire. The FDE involved conducting explosions of various yields in the damage/fracture zones of previously detonated explosions. In order to quantify rock damage after the blasts we performed well logging and seismic cross-hole tomography studies of the source region. Significant seismic velocity reduction was observed around the source regions after the initial explosions. Seismic waves produced by the explosions were recorded at near-source and local seismic networks, as well as several regional stations throughout northern New England. Our analysis confirms frequency dependent seismic amplitude reduction for the repeat shots compared to the explosions in un-fractured rocks. The amplitude reduction is caused by pore closing and/or by frictional losses within the fractured media.

Fault zone hydrogeologic properties and processes revealed by borehole temperature monitoring

NASA Astrophysics Data System (ADS)

Fulton, P. M.; Brodsky, E. E.

2015-12-01

High-resolution borehole temperature monitoring can provide valuable insight into the hydrogeologic structure of fault zones and transient processes that affect fault zone stability. Here we report on results from a subseafloor temperature observatory within the Japan Trench plate boundary fault. In our efforts to interpret this unusual dataset, we have developed several new methods for probing hydrogeologic properties and processes. We illustrate how spatial variations in the thermal recovery of the borehole after drilling and other spectral characteristics provide a measure of the subsurface permeability architecture. More permeable zones allow for greater infiltration of cool drilling fluids, are more greatly thermally disturbed, and take longer to recover. The results from the JFAST (Japan Trench Fast Drilling Project) observatory are consistent with geophysical logs, core data, and other hydrologic observations and suggest a permeable damage zone consisting of steeply dipping faults and fractures overlays a low-permeability clay-rich plate boundary fault. Using high-resolution time series data, we have also developed methods to map out when and where fluid advection occurs in the subsurface over time. In the JFAST data, these techniques reveal dozens of transient earthquake-driven fluid pulses that are spatially correlated and consistently located around inferred permeable areas of the fault damage zone. These observations are suspected to reflect transient fluid flow driven by pore pressure changes in response to dynamic and/or static stresses associated with nearby earthquakes. This newly recognized hydrologic phenomenon has implications for understanding subduction zone heat and chemical transport as well as the redistribution of pore fluid pressure which influences fault stability and can trigger other earthquakes.

Multi-scale fracture networks within layered shallow water tight carbonates

NASA Astrophysics Data System (ADS)

Panza, Elisa; Agosta, Fabrizio; Rustichelli, Andrea; Vinciguerra, Sergio; Zambrano, Miller; Prosser, Giacomo; Tondi, Emanuele

2015-04-01

The work is aimed at deciphering the contribution of background deformation and persistent fracture zones on the fluid flow properties of tight platform carbonates. Taking advantage of 3D exposures present in the Murge area of southern Italy, the fracture networks crosscutting at different scales the layered Cretaceous limestone of the Altamura Fm. were analyzed. The rock multi-layer is characterized by 10's of cm-thick, sub-horizontal, laterally continuous carbonate beds. Each bed commonly represents a shallowing-upward peritidal cycle made up of homogeneous micritic limestones grading upward to cm-thick stromatolitic limestones and/or fenestral limestones. The bed interfaces are formed by sharp maximum flooding surfaces. Porosity measurements carried out on 40 limestone samples collected from a single carbonate bed show values ranging between 0,5% and 5,5%. Background deformation includes both stratabound and non-stratabound fractures. The former elements consist of bed-perpendicular joints and sheared joints, which are confined within a single bed and often displace small, bed-parallel stylolites. Non-stratabound fractures consist of incipient, cm offset, sub-vertical strike-slip faults, which crosscut the bed interfaces. The aforementioned elements are often confined within individual bed-packages, which are identified by presence of pronounced surfaces locally marked by veneers of reddish clayey paleosoils. Persistent fracture zones consist of 10's of m-high, 10's of cm-offset strike-slip faults that offset the bed-package interfaces and are confined within individual bed-packages association. Laterally discontinuous, cm- to a few m-thick paleokarstic breccia levels separate the different bed-packages associations. Persistent fracture zones include asymmetric fractured damage zones and mm-thick veneers of discontinuous fault rocks. The fracture networks that pervasively crosscut the study limestone multi-layer are investigated by mean of scanline and scanarea

Fault zone architecture within Miocene-Pliocene syn-rift sediments, Northwestern Red Sea, Egypt

NASA Astrophysics Data System (ADS)

Zaky, Khairy S.

2017-04-01

The present study focusses on field description of small normal fault zones in Upper Miocene-Pliocene sedimentary rocks on the northwestern side of the Red Sea, Egypt. The trend of these fault zones is mainly NW-SE. Paleostress analysis of 17 fault planes and slickenlines indicate that the tension direction is NE-SW. The minimum ( σ3) and intermediate ( σ2) paleostress axes are generally sub-horizontal and the maximum paleostress axis ( σ1) is sub-vertical. The fault zones are composed of damage zones and fault core. The damage zone is characterized by subsidiary faults and fractures that are asymmetrically developed on the hanging wall and footwall of the main fault. The width of the damage zone varies for each fault depending on the lithology, amount of displacement and irregularity of the fault trace. The average ratio between the hanging wall and the footwall damage zones width is about 3:1. The fault core consists of fault gouge and breccia. It is generally concentrated in a narrow zone of ˜0.5 to ˜8 cm width. The overall pattern of the fault core indicates that the width increases with increasing displacement. The faults with displacement < 1 m have fault cores ranging from 0.5 to 4.0 cm, while the faults with displacements of > 2 m have fault cores ranging from 4.0 to 8.0 cm. The fault zones are associated with sliver fault blocks, clay smear, segmented faults and fault lenses' structural features. These features are mechanically related to the growth and linkage of the fault arrays. The structural features may represent a neotectonic and indicate that the architecture of the fault zones is developed as several tectonic phases.

Clays, common

USGS Publications Warehouse

Virta, R.L.

1998-01-01

Part of a special section on the state of industrial minerals in 1997. The state of the common clay industry worldwide for 1997 is discussed. Sales of common clay in the U.S. increased from 26.2 Mt in 1996 to an estimated 26.5 Mt in 1997. The amount of common clay and shale used to produce structural clay products in 1997 was estimated at 13.8 Mt.

Fire clay

USGS Publications Warehouse

Virta, R.L.

2011-01-01

The article discusses the latest developments in the fire clay industry, particularly in the U.S., as of June 2011. It claims that the leading fire clay producer in the U.S. is the state of Missouri. The other major producers include California, Texas and Washington. It reports that the use of heavy clay products made of fire clay like brick, cement and lightweight aggregate has increased slightly in 2010.

Use of advanced borehole geophysical techniques to delineate fractured-rock ground-water flow and fractures along water-tunnel facilities in northern Queens County, New York

USGS Publications Warehouse

Stumm, Frederick; Chu, Anthony; Lange, Andrew D.; Paillet, Frederick L.; Williams, John H.; Lane, John W.

2001-01-01

Advanced borehole geophysical methods were used to assess the geohydrology of crystalline bedrock along the course of a new water tunnel for New York City. The logging methods include natural gamma, spontaneous potential, single-point resistance, mechanical and acoustic caliper, focused electromagnetic induction, electromagnetic resistivity, magnetic susceptibility, borehole-fluid temperature and conductance, differential temperature, heat-pulse flowmeter, acoustic televiewer, borehole deviation, optical televiewer, and borehole radar. Integrated interpretation of the geophysical logs from an 825-foot borehole (1) provided information on the extent, orientation, and structure (foliation and fractures) within the entire borehole, including intensely fractured intervals from which core recovery may be poor; (2) delineated transmissive fracture zones intersected by the borehole and provided estimates of their transmissivity and hydraulic head; and (3) enabled mapping of the location and orientation of structures at distances as much as 100 ft from the borehole.Analyses of the borehole-wall image and the geophysical logs from the borehole on Crescent Street, in northern Queens County, are presented here to illustrate the application of the methods. The borehole penetrates gneiss and other crystalline bedrock that has predominantly southeastward dipping foliation and nearly horizontal and southeastward-dipping fractures. The heat-pulse flowmeter logs obtained under pumping and nonpumping conditions, together with the other geophysical logs, indicate five transmissive fracture zones. More than 90 percent of the open-hole transmissivity is associated with a fracture zone 272 feet BLS (below land surface). A transmissive zone at 787 feet BLS that consists of nearly parallel fractures lies within the projected tunnel path; here the hydraulic head is 12 to 15 feet lower than that of transmissive zones above the 315-foot depth. The 60-megahertz directional borehole radar logs

New Hexactinellid Sponge Chaunoplectella megapora sp. nov. (Lyssacinosida: Leucopsacidae) from Clarion-Clipperton Fracture Zone, Eastern Pacific Ocean.

PubMed

Wang, Chunsheng; Zhang, Yuan; Lu, Bo; Wang, Dexiang

2018-01-23

The new Hexactinellid sponge Chaunoplectella megapora sp. nov. reported in this study was collected from the COMRA contract area, the western part of Clarion-Clipperton Fracture Zone (CCFZ) in the eastern Pacific Ocean at a depth of 5258 m. This sponge's extraordinary multiporous body with the presence of unique codonhexasters, sigmatocomes, toothed discohexasters and hemidiscohexasters, as well as stellate disocohexasters, characterizes it as a new species in the genus Chaunoplectella. This report presents the first record of family Leucopsacidae at this site in the eastern Pacific Ocean.

Modelling of the CO2-Induced Degradation of a Fractured Caprock During Leakage: Potential for a Mechanical Self-Limiting Process

NASA Astrophysics Data System (ADS)

Rohmer, J.; Tremosa, J.; Marty, N. C. M.; Audigane, P.

2017-10-01

In the present study, we assess the potential for initiating ductile failure in a fractured caprock due to the chemical alteration of its mechanical properties under pressure increase induced by CO2 leakage and fixed in situ boundary conditions. In this view, 2D numerically coupled reactive-transport simulations were set up by using the Opalinus Clay formation as an analogue for a caprock layer. The fractured system was viewed as a compartmentalised system that consists of a main highly permeable pathway, a moderately permeable damage zone and the intact rock. The outputs of the numerical simulations (mineral fraction, porosity changes, gas saturation, pore-fluid pressure) were converted into parameter changes of the yield surface by viewing the rock material of the three compartments (fault, damage zone and intact rock) as a composite system that consists of a clayey solid material, pores and mineral inclusions (such as carbonate and quartz). Three alteration processes were considered: (1) the effect of the mineral fraction and porosity evolution on the yield surface, (2) changes in the resulting poro-elastic properties and (3) the suction effect, i.e. the bounding effect induced by the presence of two phases, water and CO2. Our numerical investigations showed that the decrease in the friction coefficient remained negligible during leakage, while the pre-consolidation stress mainly decreased. Consequently, the damage zone of the fractured system became more collapsible over time, which was driven by low-to-moderate pressure build-up of the fluid penetrating the fault (1 MPa in our case). For the considered case, the initiation of ductile failure is likely under conditions of fixed vertical stress and zero lateral strain. This process could potentially limit the spatial spreading of CO2-induced alteration, although this remains very site specific. We recommend that characterisation efforts be intensified to obtain better insight into the properties of fracture

Root-Zone Redox Dynamics - In Search for the Cause of Damage to Treated-Wastewater Irrigated Orchards in Clay Soils

NASA Astrophysics Data System (ADS)

Yalin, David; Shenker, Moshe; Schwartz, Amnon; Assouline, Shmuel; Tarchitzky, Jorge

2016-04-01

Treated wastewater (TW) has become a common source of water for agriculture. However recent findings raise concern regarding its use: a marked decrease (up to 40%) in yield appeared in orchards irrigated with TW compared with fresh water (FW) irrigated orchards. These detrimental effects appeared predominantly in orchards cultivated in clay soils. The association of the damage with clay soils rather than sandy soils led us to hypothesize that the damage is linked to soil aeration problems. We suspected that in clay soils, high sodium adsorption ratio (SAR) and high levels of organic material, both typical of TW, may jointly lead to an extreme decrease in soil oxygen levels, so as to shift soil reduction-oxidation (redox) state down to levels that are known to damage plants. Two-year continuous measurement of redox potential, pH, water tension, and oxygen were conducted in the root-zone (20-35 cm depth) of avocado trees planted in clay soil and irrigated with either TW or FW. Soil solution composition was sampled periodically in-situ and mineral composition was sampled in tree leaves and woody organs biannually. In dry periods the pe+pH values indicated oxic conditions (pe+pH>14), and the fluctuations in redox values were small in both TW and FW plots. Decreases in soil water tension following irrigation or rain were followed by drops in soil oxygen and pe+pH values. TW irrigated plots had significantly lower minimum pe+pH values compared with FW-irrigated plots, the most significant differences occurred during the irrigation season rather than the rain season. A linear correlation appeared between irrigation volume and reduction severity in TW-irrigated plots, but not in the FW plots, indicating a direct link to the irrigation regime in TW-irrigated plots. The minimum pe+pH values measured in the TW plots are indicative of suboxic conditions (9

Clay and Shale Permeability at Lab to Regional Scale

NASA Astrophysics Data System (ADS)

Neuzil, C.

2017-12-01

Because clays, shales, and other clay-rich media tend to be only poorly permeable, and are laterally extensive and voluminous, they play key roles in problems as diverse as groundwater supply, waste confinement, exploitation of conventional and unconventional oil and gas, and deformation and failure in the crust. Clay and shale permeability is a crucial but often highly uncertain analysis parameter; direct measurements are challenging, error-prone, and - perhaps most importantly - provide information only at quite small scales. Fortunately, there has been a dramatic increase in clay and shale permeability data from sources that include scientific ocean drilling, nuclear waste repository research, groundwater resource studies, liquid waste and CO2 sequestration, and oil and gas research. The effect of lithology as well as porosity on matrix permeability can now be examined and permeability - scale relations are becoming discernable. A significant number of large-scale permeability estimates have been obtained by inverse methods that essentially treat large-scale flow systems as natural experiments. They suggest surprisingly little scale-dependence in clay and shale permeabilities in subsiding basins and accretionary complexes. Stable continental settings present a different picture; as depths increase beyond 1 km, scale dependence mostly disappears even over the largest areas. At depths less than 1 km, secondary permeability is not always present over areas of 1 - 10 km2, but always evident for areas in excess of about 103 km2. Transmissive fractures have been observed in very low porosity (< 0.03) shales in these settings, but the cause of scale dependence in other cases is unclear; it may reflect time-dependent, or "dynamic" conditions, including irreversible and ongoing changes imposed on subsurface flow systems by human activities.

Low resistivity and permeability in actively deforming shear zones on the San Andreas Fault at SAFOD

USGS Publications Warehouse

Morrow, Carolyn A.; Lockner, David A.; Hickman, Stephen H.

2015-01-01

The San Andreas Fault Observatory at Depth (SAFOD) scientific drillhole near Parkfield, California crosses the San Andreas Fault at a depth of 2.7 km. Downhole measurements and analysis of core retrieved from Phase 3 drilling reveal two narrow, actively deforming zones of smectite-clay gouge within a roughly 200 m-wide fault damage zone of sandstones, siltstones and mudstones. Here we report electrical resistivity and permeability measurements on core samples from all of these structural units at effective confining pressures up to 120 MPa. Electrical resistivity (~10 ohm-m) and permeability (10-21 to 10-22 m2) in the actively deforming zones were one to two orders of magnitude lower than the surrounding damage zone material, consistent with broader-scale observations from the downhole resistivity and seismic velocity logs. The higher porosity of the clay gouge, 2 to 8 times greater than that in the damage zone rocks, along with surface conduction were the principal factors contributing to the observed low resistivities. The high percentage of fine-grained clay in the deforming zones also greatly reduced permeability to values low enough to create a barrier to fluid flow across the fault. Together, resistivity and permeability data can be used to assess the hydrogeologic characteristics of the fault, key to understanding fault structure and strength. The low resistivities and strength measurements of the SAFOD core are consistent with observations of low resistivity clays that are often found in the principal slip zones of other active faults making resistivity logs a valuable tool for identifying these zones.

Operative Treatment of Fifth Metatarsal Jones Fractures (Zones II and III) in the NBA.

PubMed

O'Malley, Martin; DeSandis, Bridget; Allen, Answorth; Levitsky, Matthew; O'Malley, Quinn; Williams, Riley

2016-05-01

Proximal fractures of the fifth metatarsal (zone II and III) are common in the elite athlete and can be difficult to treat because of a tendency toward delayed union, nonunion, or refracture. The purpose of this case series was to report our experience in treating 10 NBA players, determine the healing rate, return to play, refracture rate, and role of foot type in these athletes. The records of 10 professional basketball players were retrospectively reviewed. Seven athletes underwent standard percutaneous internal fixation with bone marrow aspirate concentrate (BMAC) whereas the other 3 had open bone grafting primarily in addition to fixation and BMAC. Radiographic features evaluated included fourth-fifth intermetatarsal, fifth metatarsal lateral deviation, calcaneal pitch, and metatarsus adductus angles. Radiographic healing was observed at an overall average of 7.5 weeks and return to play was 9.8 weeks. Three athletes experienced refractures. There were no significant differences in clinical features or radiographic measurements except that the refracture group had the highest metatatarsus adductus angles. Most athletes were pes planus and 9 of 10 had a bony prominence under the fifth metatarsal styloid. This is the largest published series of operatively treated professional basketball players who exemplify a specific patient population at high risk for fifth metatarsal fracture. These players were large and possessed a unique foot type that seemed to be associated with increased risk of fifth metatarsal fracture and refracture. This foot type had forefoot metatarsus adductus and a fifth metatarsal that was curved with a prominent base. We continue to use standard internal fixation with bone marrow aspirate but advocate additional prophylactic open bone grafting in patients with high fourth-to-fifth intermetatarsal, fifth metatarsal lateral deviation, and metatarsus adductus angles as well as prominent fifth metatarsal styloids in order to improve fracture

Insights into the base of the critical zone from geophysical logging and groundwater flow testing at U.S. Critical Zone Observatories (CZO) and critical zone study sites (CZs)

NASA Astrophysics Data System (ADS)

Carr, B.; Zhang, Y.; Ren, S.; Flinchum, B. A.; Parsekian, A.; Holbrook, S.; Riebe, C. S.; Moravec, B. G.; Chorover, J.; Pelletier, J. D.; Richter, D. D., Jr.

2017-12-01

Four prominent hypotheses exist and predict conceptual models defining the base of the critical zone. These hypotheses lack insights and constraints from borehole data since few deep (> 20 m) boreholes (and even fewer connected wellfields) are present in the U.S. Critical Zone Observatories (CZO) and similar critical zone study sites (CZs). The influence and interaction of fracture presence, fracture density, fracture orientation, groundwater presence and groundwater flow have only begun to be analyzed relative to any definition of the base of the critical zone. In this presentation, we examine each hypothesis by jointly evaluating borehole geophysical logs and groundwater testing datasets collected by the Wyoming Center for Environmental Hydrology and Geophysics (WyCEHG) since 2014 at these deep CZO or CZ boreholes. Deep boreholes allow a unique opportunity to observe the factors influencing groundwater transmissivity/storage capacity within the three main subsurface CZ layers: Unconsolidated (soil/saprolite), Fractured/weathered Bedrock, and Protolith bedrock (i.e. less fractured bedrock). The boreholes used in this study consist of: 1) nine wells of the Blair-Wallis (WY) WyCEHG CZ, 2) two wells in Catalina-Jemez CZO (Valle Caldera NM) and 3) one borehole at the Calhoun (SC) CZO. At this time, these are the only sites that contain boreholes with depths ranging from at least 20 m up to 70m that have been geophysically logged with full-waveform seismic, acoustic and optical televiewer, electric, electromagnetic, flowmeter (impeller and heat pulse), fluid temperature, fluid conductivity and nuclear magnetic resonance. Further, the Blair-Wallis CZ site contains five hydraulically connected wells that allow us to estimate formation transmissivity and storage coefficients at increasing scales by conducting: slug tests, FLUTe™ borehole profiling, and cross-hole pumping tests. These well tests provide direct hydraulic data of the bedrock (both fractured and protolith

Meiofauna abundance and community patterns along a transatlantic transect in the Vema Fracture Zone and in the hadal zone of the Puerto Rico trench

NASA Astrophysics Data System (ADS)

Schmidt, Christina; Escobar Wolf, Kaibil; Lins, Lidia; Martínez Arbizu, Pedro; Brandt, Angelika

2018-02-01

Despite the increasing sampling effort that occurred in the deep-sea environment during the last decades, knowledge about meiofauna ecology in trenches and Fracture Zones is still scarce. Based on the lack of this information, a longitudinal transect across the Vema Fracture Zone in the North Atlantic was sampled to test whether meiofauna abundances differ between Northeast and Northwest Atlantic basins, separated by the Mid-Atlantic Ridge. Also, for examination of meiofauna depth pattern, the Puerto Rico trench floor, its upper trench slope and the Western North Atlantic abyssal were investigated. In this study, meiofauna communities were dominated by Nematoda (93%) and Copepoda (4%). The highest total abundance of meiofauna was found in the Puerto Rico trench and the lowest in the Western basin. We found significant differences between the Eastern and Western Atlantic basins, which were potentially caused by differences in current regimes. Stronger currents observed in the Western basin possibly led to the coarser sediment grain size observed in this region, and consequently to the lower abundances of the major groups found there. Besides grain size, the total abundance of meiofauna was significantly correlated with total nitrogen, total organic carbon, and water depth. Moreover, our study reveals a trend of increasing abundance of total meiofauna with increasing water depth in the Puerto Rico trench. Also, significant differences between the Western abyssal and the Puerto Rico trench were discovered. Generally, the meiofauna abundance in the investigated area decreased from East to West but increased with increasing water depth in the Puerto Rico trench. Due to funnelling of organic sediments increased food availability towards deeper regions in trenches could occur and promote higher abundance.

29 CFR Appendix D to Subpart R of... - Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying With § 1926.760(c)(3) D Appendix D... of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying..., tapes, or equivalent materials, and supporting stanchions as follows: (i) Each line is rigged and...

29 CFR Appendix D to Subpart R of... - Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying With § 1926.760(c)(3) D Appendix D... of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying..., tapes, or equivalent materials, and supporting stanchions as follows: (i) Each line is rigged and...

Multi-scale geophysical study to model the distribution and development of fractures in relation to the knickpoint in the Luquillo Critical Zone Observatory (Puerto Rico)

NASA Astrophysics Data System (ADS)

Comas, X.; Wright, W. J.; Hynek, S. A.; Ntarlagiannis, D.; Terry, N.; Job, M. J.; Fletcher, R. C.; Brantley, S.

2017-12-01

Previous studies in the Rio Icacos watershed in the Luquillo Mountains (Puerto Rico) have shown that regolith materials are rapidly developed from the alteration of quartz diorite bedrock, and create a blanket on top of the bedrock with a thickness that decreases with proximity to the knickpoint. The watershed is also characterized by a system of heterogeneous fractures that likely drive bedrock weathering and the formation of corestones and associated spheroidal fracturing and rindlets. Previous efforts to characterize the spatial distribution of fractures were based on aerial images that did not account for the architecture of the critical zone below the subsurface. In this study we use an array of near-surface geophysical methods at multiple scales to better understand how the spatial distribution and density of fractures varies with topography and proximity to the knickpoint. Large km-scale surveys using ground penetrating radar (GPR), terrain conductivity, and capacitively coupled resistivity, were combined with smaller scale surveys (10-100 m) using electrical resistivity imaging (ERI), and shallow seismics, and were directly constrained with boreholes from previous studies. Geophysical results were compared to theoretical models of compressive stress as due to gravity and regional compression, and showed consistency at describing increased dilation of fractures with proximity to the knickpoint. This study shows the potential of multidisciplinary approaches to model critical zone processes at multiple scales of measurement and high spatial resolution. The approach can be particularly efficient at large km-scales when applying geophysical methods that allow for rapid data acquisition (i.e. walking pace) at high spatial resolution (i.e. cm scales).

Mechanical reinforcement and environmental effects on a nylon-6/clay nanocomposite

NASA Astrophysics Data System (ADS)

Shelley, J. Stebbins

2000-10-01

Hybridization, or modifying the organic polymers with inorganic constituents, is one method of achieving mechanical property improvements in polymeric materials while preserving processing characteristics. Toyota Central Research developed, and Ube Industries commercialized, one such hybrid nanocomposite: nylon-6/montmorillonite clay. This dissertation explores mechanisms of reinforcement in these nylon-6/clay nanocomposites and studies their degradation by atmospheric pollutants. A 100% improvement in modulus, 77% improvement in yield stress, and 54°C improvement in heat distortion temperature over nylon-6 were observed in extruded 5 wt% clay nanocomposite sheets. Infrared absorption spectrography and dynamic mechanical analysis were used to investigate the mechanisms of reinforcement in these nanocomposites. The improved mechanical properties, increased heat distortion temperature, reduced diffusion rate, and lower susceptibility to degradation in NO x observed where attributed to constraint of polymer chain motion by interaction with clay lamellae. Changes in the loss tangent peak in the glass transition region of the dynamic mechanical data provide an estimate of the volume of chains constrained by complexation of their mid-chain amide oxygen groups with the charged clay lamellae. X-ray analysis, optical microscopy, and light scattering were used to study changes in crystallization due to this complexation. Photomicrographs indicate that the morphology of the crystallites change from spherulitic to planar with the addition of clay. Decreases in diffusion rates of water and total water absorption were demonstrated in immersion experiments. Complexation of nylon-6 with 5 wt% clay reduces the total absorption of water by over 16%. The plane stress fracture toughness of extruded 5 wt% clay nanocomposite was 46% greater than that of nylon-6. The degradation of the nanocomposites in calcium chloride solution and NOx was examined through post exposure residual

Numerical Experiments on Ductile Fracture in Granites

NASA Astrophysics Data System (ADS)

Regenauer-Lieb, K.; Weinberg, R. F.

2006-12-01

Ceramics and, by analogy rocks, are brittle at low temperatures, however, at high temperature and high pressure a second ductile mode of fracture based on dislocation and/or diffusion processes predominates. For ceramics 0.5-0.7 times the melting temperature suffice to create creep/ductile fracture which occurs typically after long time of deformation 104-1010 s (1). Ductile creep fractures make up for the low stress by profiting from accumulated strain and diffusion during slow creep deformation. Creep fractures typically nucleate on grain or phase boundaries, rigid or soft inclusions. Ultimately, the localized inhomogeneous damaged zone, begin to spread laterally and coalesce to create or follow a propagating shear band. The creep fracture sequence of crack nucleation, growth and coalescence relies on a mechanism of self-organization of fluids into a shear band during deformation and converts macroscopically to the crack like propagation of localized shear zones. Numerical experiments are used to test the ductile fracture hypothesis for the segregation and transfer of melts in granites. Ref: (1) C. Ghandi, M. F. Ashby, Acta Metallurgica 27, 1565 (1979).

On gravity from SST, geoid from SEASAT, and plate age and fracture zones in the Pacific

NASA Technical Reports Server (NTRS)

Marsh, B. D.; Marsh, J. G.; Williamson, R. G.

1983-01-01

Data from an additional 50 satellite-to-satellite tracking (SST) passes were combined with earlier measurements of the high degree and order (n, m, 12) gravity in the central Pacific. A composite map was produced which shows good agreement with conventional GEM models. Data from the SEASAT altimeter was reduced and found to agree well with both the SST and the GEM fields. The maps are dominated especially in the east, by a pattern of roughly east-west anomalies with a transverse wavelength of about 2000 km. Further comparison with regional bathymetric data shows a remarkably close correlation with plate age. Each anomaly band is framed by those major fracture zones having large offsets. The regular spacing of these fractures seems to account for the fabric in the gravity fields. Other anomalies are accounted for by hot spots. The source of part of these anomalies is in the lithosphere itself. The possible plume size and ascent velocity necessary to supply deep mantle material to the upper mantel without complete thermal equilibration is considered.

Investigation of nanoscopic free volume and interfacial interaction in an epoxy resin/modified clay nanocomposite using positron annihilation spectroscopy.

PubMed

Patil, Pushkar N; Sudarshan, Kathi; Sharma, Sandeep K; Maheshwari, Priya; Rath, Sangram K; Patri, Manoranjan; Pujari, Pradeep K

2012-12-07

Epoxy/clay nanocomposites are synthesized using clay modified with the organic modifier N,N-dimethyl benzyl hydrogenated tallow quaternary ammonium salt (Cloisite 10A). The purpose is to investigate the influence of the clay concentration on the nanostructure, mainly on the free-volume properties and the interfacial interactions, of the epoxy/clay nanocomposite. Nanocomposites having 1, 3, 5 and 7.5 wt. % clay concentrations are prepared using the solvent-casting method. The dispersion of clay silicate layers and the morphologies of the fractured surfaces in the nanocomposites are studied using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The observed XRD patterns reveal an exfoliated clay structure in the nanocomposite with the lowest clay concentration (≤1 wt. %). The ortho-positronium lifetime (τ(3)), a measure of the free-volume size, as well as the fractional free volume (f(v)) are seen to decrease in the nanocomposites as compared to pristine epoxy. The intensity of free positron annihilation (I(2)), an index of the epoxy-clay interaction, decreases with the addition of clay (1 wt. %) but increases linearly at higher clay concentrations. Positron age-momentum correlation measurements are also carried out to elucidate the positron/positronium states in pristine epoxy and in the nanocomposites. The results suggest that in the case of the nanocomposite with the studied lowest clay concentration (1 wt. %), free positrons are primarily localized in the epoxy-clay interfaces, whereas at higher clay concentrations, annihilation takes place from the intercalated clay layers. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

An integrated geophysical and hydraulic investigation to characterize a fractured-rock aquifer, Norwalk, Connecticut

USGS Publications Warehouse

Lane, J.W.; Williams, J.H.; Johnson, C.D.; Savino, D.M.; Haeni, F.P.

2002-01-01

The U.S. Geological Survey conducted an integrated geophysical and hydraulic investigation at the Norden Systems, Inc. site in Norwalk, Connecticut, where chlorinated solvents have contaminated a fractured-rock aquifer. Borehole, borehole-to-borehole, surface-geophysical, and hydraulic methods were used to characterize the site bedrock lithology and structure, fractures, and transmissive zone hydraulic properties. The geophysical and hydraulic methods included conventional logs, borehole imagery, borehole radar, flowmeter under ambient and stressed hydraulic conditions, and azimuthal square-array direct-current resistivity soundings. Integrated interpretation of geophysical logs at borehole and borehole-to-borehole scales indicates that the bedrock foliation strikes northwest and dips northeast, and strikes north-northeast to northeast and dips both southeast and northwest. Although steeply dipping fractures that cross-cut foliation are observed, most fractures are parallel or sub-parallel to foliation. Steeply dipping reflectors observed in the radar reflection data from three boreholes near the main building delineate a north-northeast trending feature interpreted as a fracture zone. Results of radar tomography conducted close to a suspected contaminant source area indicate that a zone of low electromagnetic (EM) velocity and high EM attenuation is present above 50 ft in depth - the region containing the highest density of fractures. Flowmeter logging was used to estimate hydraulic properties in the boreholes. Thirty-three transmissive fracture zones were identified in 11 of the boreholes. The vertical separation between transmissive zones typically is 10 to 20 ft. Open-hole and discrete-zone transmissivity was estimated from heat-pulse flowmeter data acquired under ambient and stressed conditions. The open-hole transmissivity ranges from 2 to 86 ft2/d. The estimated transmissivity of individual transmissive zones ranges from 0.4 to 68 ft2/d. Drawdown monitoring

The Role of Texture, Cracks, and Fractures in Highly Anisotropic Shales

NASA Astrophysics Data System (ADS)

Baird, Alan F.; Kendall, J. Michael; Fisher, Quentin J.; Budge, Jessica

2017-12-01

Organic shales generally have low permeability unless fractures are present. However, how gas, oil, and water flows into these fractures remains enigmatic. The alignment of clay minerals and the alignment of fractures and cracks are effective means to produce seismic anisotropy. Thus, the detection and characterization of this anisotropy can be used to infer details about lithology, rock fabric, and fracture and crack properties within the subsurface. We present a study characterizing anisotropy using S wave splitting from microseismic sources in a highly anisotropic shale. We observe very strong anisotropy (up to 30%) with predominantly VTI (vertical transverse isotropy) symmetry, but with evidence of an HTI (horizontal transverse isotropy) overprint due to a NE striking vertical fracture set parallel to the maximum horizontal compressive stress. We observe clear evidence of a shear wave triplication due to anisotropy, which to our knowledge is one of only a very few observations of such triplications in field-scale data. We use modal proportions of minerals derived from X-ray fluorescence data combined with realistic textures to estimate the contribution of intrinsic anisotropy as well as possible contributions of horizontally aligned cracks. We find that aligned clays can explain much of the observed anisotropy and that any cracks contributing to the vertical transverse isotropy (VTI) must have a low ratio of normal to tangential compliance (ZN/ZT), typical of isolated cracks with low hydraulic connectivity. Subhorizontal cracks have also been observed in the reservoir, and we propose that their reactivation during hydraulic fracturing may be an important mechanism to facilitate gas flow.

The Influence of Fracturing Fluids on Fracturing Processes: A Comparison Between Water, Oil and SC-CO2

NASA Astrophysics Data System (ADS)

Wang, Jiehao; Elsworth, Derek; Wu, Yu; Liu, Jishan; Zhu, Wancheng; Liu, Yu

2018-01-01

Conventional water-based fracturing treatments may not work well for many shale gas reservoirs. This is due to the fact that shale gas formations are much more sensitive to water because of the significant capillary effects and the potentially high contents of swelling clay, each of which may result in the impairment of productivity. As an alternative to water-based fluids, gaseous stimulants not only avoid this potential impairment in productivity, but also conserve water as a resource and may sequester greenhouse gases underground. However, experimental observations have shown that different fracturing fluids yield variations in the induced fracture. During the hydraulic fracturing process, fracturing fluids will penetrate into the borehole wall, and the evolution of the fracture(s) then results from the coupled phenomena of fluid flow, solid deformation and damage. To represent this, coupled models of rock damage mechanics and fluid flow for both slightly compressible fluids and CO2 are presented. We investigate the fracturing processes driven by pressurization of three kinds of fluids: water, viscous oil and supercritical CO2. Simulation results indicate that SC-CO2-based fracturing indeed has a lower breakdown pressure, as observed in experiments, and may develop fractures with greater complexity than those developed with water-based and oil-based fracturing. We explore the relation between the breakdown pressure to both the dynamic viscosity and the interfacial tension of the fracturing fluids. Modeling demonstrates an increase in the breakdown pressure with an increase both in the dynamic viscosity and in the interfacial tension, consistent with experimental observations.

An integrated approach to characterization of fractured reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Datta-Gupta, A.; Majer, E.; Vasco, D.

1995-12-31

This paper summarizes an integrated hydrologic and seismic characterization of a fractured limestone formation at the Conoco Borehole Test Facility (CBTF) in Kay County, Oklahoma. Transient response from pressure interference tests were first inverted in order to identify location and orientation of dominant fractures at the CBTF. Subsequently, high resolution (1000 to 10000 Hz) cross-well and single-well seismic surveys were conducted to verify the preferential slow paths indicated by hydrologic analysis. Seismic surveys were conducted before and after an air injection in order to increase the visibility of the fracture zone to seismic imaging. Both Seismic and hydrologic analysis weremore » found to yield consistent results in detecting the location of a major fracture zone.« less

Ball clay

USGS Publications Warehouse

Virta, R.L.

2000-01-01

Part of the 1999 Industrial Minerals Review. The state of the ball clay industry in 1999 is presented. Record highs in the sales and use of ball clay were attained in 1999 due to the continued strength of the U.S. economy. U.S. production was estimated at 1.25 million st for the year, with more than half of that amount mined in Tennessee. Details of the consumption, price, imports, and exports of ball clay in 1999 and the outlook for ball clay over the next few years are provided.

Cyclic sedimentation, synsedimentary volcanism, microfabrics, and fracture intensity in the Austin Chalk, Texas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hovorka, S.D.

1992-01-01

Pelagic depositional environments of the Austin Chalk (Coniacian-Santonian) were influenced by sea-level variation, planktonic productivity, and allochthonous detrital input. Subtle differences in chalk facies influence fracture intensity, therefore imposing stratigraphic variability on hydrologic properties of the Austin Chalk. Variations in fracture intensity may affect ground-water flow through the Superconducting Super Collider (SSC) site south of Dallas in the same way that they influence hydrocarbon production in South Texas. The lower Austin Chalk was deposited during transgression. Glauconitic sandstone is overlain by cyclic chalk containing chalk-filled channels. Meter-thick chalk/marl cycles have frequencies in the Milankovitch spectrum. Marl accumulated during episodes ofmore » decreased planktonic productivity. Maximum flooding is indicated by organic-rich marls in the upper part of the Lower Austin Chalk. Shallowing during deposition of the middle and upper Austin Chalk is indicated by increasing abundance of winnowed lag deposits and firm grounds, resulting in increased faunal diversity. Authigenic clay, a product of alteration of volcanic ash codeposited with the chalk and marl, increases ductility in the middle Austin Chalk. The stratigraphic distribution of authigenic clay corresponds to disseminated biotite, quartz, and feldspar phenocrysts in most samples of the middle Austing Chalk. Authigenic clay decreases porosity, influences porosity-permeability relationships, and provides a regionally traceable low SP log response that correlates with low fracture intensity.« less

Clay for Little Fingers.

ERIC Educational Resources Information Center

Koster, Joan Bouza

1999-01-01

Discusses the renewed interest in clay as a modeling compound in early childhood programs; describes the nature of clay and presents a working vocabulary. Suggests methods of working with clay, including introducing clay to children, discovering its uses, clean up, firing clay, and finishing baked clay. Includes activity suggestions and…

29 CFR Appendix D to Subpart R of... - Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non...

Code of Federal Regulations, 2012 CFR

2012-07-01

... of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying... 29 Labor 8 2012-07-01 2012-07-01 false Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying With § 1926.760(c)(3) D Appendix D...

29 CFR Appendix D to Subpart R of... - Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non...

Code of Federal Regulations, 2010 CFR

2010-07-01

... of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying... 29 Labor 8 2010-07-01 2010-07-01 false Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying With § 1926.760(c)(3) D Appendix D...

29 CFR Appendix D to Subpart R of... - Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non...

Code of Federal Regulations, 2013 CFR

2013-07-01

... of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying... 29 Labor 8 2013-07-01 2013-07-01 false Illustration of the Use of Control Lines To Demarcate Controlled Decking Zones (CDZs): Non-mandatory Guidelines for Complying With § 1926.760(c)(3) D Appendix D...

San Andreas fault zone drilling project: scientific objectives and technological challenges

USGS Publications Warehouse

Hickman, Stephen; Younker, Leland; Zobeck, Mark; Cooper, George; ,

1994-01-01

We are leading a new international initiative to conduct scientific drilling within the San Andreas fault zone at depths of up to 10 km. This project is motivated by the need to understand the physical and chemical processes operating within the fault zone and to answer fundamental questions about earthquake generation along major plate-boundary faults. Through an integrated program of coring, fluid sampling, in-situ and laboratory experimentation and long-term monitoring, we hope to provide fundamental constraints on the structure, composition, mechanical behavior and physical state of the San Andreas fault system at depths comparable to the nucleation zones of great earthquakes. The drilling, sampling and observational requirements needed to ensure the success of this project are stringent. These include: 1) drilling stable vertical holes to depths of about 9 km in fractured rock at temperatures of up to 300??C; 2) continuous coring of inclined holes branched off these vertical boreholes to intersect the fault at depths of 3, 6 and 9 km; 3) conducting sophisticated borehole geophysical measurements and fluid/rock sampling at high temperatures and pressures; and 4) instrumenting some or all of these inclined core holes for continuous monitoring of seismicity and a broad range of physical and chemical properties over periods of up to several decades. For all of these tasks, because of the overpressured clay-rich formations anticipated within the fault zone at depth, we expect to encounter difficult drilling, coring and hole-completion conditions in the regions of greatest scientific interest.

San Andreas fault zone drilling project: scientific objectives and technological challenges

USGS Publications Warehouse

Hickman, S.H.; Younker, L.W.; Zoback, M.D.

1995-01-01

We are leading a new international initiative to conduct scientific drilling within the San Andreas fault zone at depths of up to 10 km. This project is motivated by the need to understand the physical and chemical processes operating within the fault zone and to answer fundamental questions about earthquake generation along major plate-boundary faults. Through a comprehensive program of coring, fluid sampling, downhole measurements, laboratory experimentation, and long-term monitoring, we hope to obtain critical information on the structure, composition, mechanical behavior and physical state of the San Andreas fault system at depths comparable to the nucleation zones of great earthquakes. The drilling, sampling and observational requirements needed to ensure the success of this project are stringent. These include: 1) drilling stable vertical holes to depths of about 9 km in fractured rock at temperatures of up to 300°C; 2) continuous coring and completion of inclined holes branched off these vertical boreholes to intersect the fault at depths of 3, 6, and 9 km; 3) conducting sophisticated borehole geophysical measurements and fluid/rock sampling at high temperatures and pressures; and 4) instrumenting some or all of these inclined core holes for continuous monitoring of earthquake activity, fluid pressure, deformation and other parameters for periods of up to several decades. For all of these tasks, because of the overpressured clay-rich formations anticipated within the fault zone at depth, we expect to encounter difficult drilling, coring and hole-completion conditions in the region of greatest scientific interest.

Design and Implementation of Energized Fracture Treatment in Tight Gas Sands

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mukul Sharma; Kyle Friehauf

2009-12-31

Hydraulic fracturing is essential for producing gas and oil at an economic rate from low permeability sands. Most fracturing treatments use water and polymers with a gelling agent as a fracturing fluid. The water is held in the small pore spaces by capillary pressure and is not recovered when drawdown pressures are low. The un-recovered water leaves a water saturated zone around the fracture face that stops the flow of gas into the fracture. This is a particularly acute problem in low permeability formations where capillary pressures are high. Depletion (lower reservoir pressures) causes a limitation on the drawdown pressuremore » that can be applied. A hydraulic fracturing process can be energized by the addition of a compressible, sometimes soluble, gas phase into the treatment fluid. When the well is produced, the energized fluid expands and gas comes out of solution. Energizing the fluid creates high gas saturation in the invaded zone, thereby facilitating gas flowback. A new compositional hydraulic fracturing model has been created (EFRAC). This is the first model to include changes in composition, temperature, and phase behavior of the fluid inside the fracture. An equation of state is used to evaluate the phase behavior of the fluid. These compositional effects are coupled with the fluid rheology, proppant transport, and mechanics of fracture growth to create a general model for fracture creation when energized fluids are used. In addition to the fracture propagation model, we have also introduced another new model for hydraulically fractured well productivity. This is the first and only model that takes into account both finite fracture conductivity and damage in the invaded zone in a simple analytical way. EFRAC was successfully used to simulate several fracture treatments in a gas field in South Texas. Based on production estimates, energized fluids may be required when drawdown pressures are smaller than the capillary forces in the formation. For this

Heterogeneous alternation of fractured rock driven by preferential carbonate dissolution

NASA Astrophysics Data System (ADS)

Wen, H.; Zhi, W.; Li, L.

2016-12-01

Understanding the alternation of fractured rock induced by geochemical reactions is critical for predicting the flow, solute transport and energy production in geosystems. Most existing studies on fracture alterations focus on rocks with single minerals where reactions occur at the fracture wall resulting in fracture aperture alteration while ignoring rock matrix properties (e.g. the formation and development of altered zones). In this work, we aimed to mechanistically understand the role of preferential calcite dissolution in the long-term evolution of fracture and rock matrix. We use direct simulation of physics-based reactive transport processes in an image of fractured rock at the resolution of tens of micrometers. Three numerical experiments were carried out with the same initial physical properties however different calcite content. Simulation results show that the formation and development of altered zones in the rock matrix is highly related to the abundance of fast-dissolving calcite. Abundant calcite (50% (v/v), calcite50) leads to a localized, thick zone of large porosity increase while low calcite content (10% (v/v), calcite10) creates an extended and narrow zone of small porosity increase resulting in surprisingly larger change in effective transport property. After 300 days of dissolution, although with relatively similar dissolved calcite mass and matrix porosity increase, effective matrix diffusion coefficients increase by 9.9 and 19.6 times in calcite50 and calcite10, respectively. In turn, calcite dissolution rates are directly limited by diffusive transport in the altered matrix and the shape of the altered zone. This work sheds light on the unique characteristics of reactive transport in fractured, mineralogically complex rocks that are different from those with single minerals (Wen et al., 2016). Reference: Wen, H., Li, L., Crandall, D. and Hakala, J.A. (2016) Where Lower Calcite Abundance Creates More Alteration: Enhanced Rock Matrix

Variation of mechanical properties due to hygrothermal ageing and permanent changes upon redrying in clay/epoxy nanocomposites

NASA Astrophysics Data System (ADS)

Hamim, Salah Uddin Ahmed

2011-12-01

Epoxy polymers are an important class of material for use in various applications. Due to their hydrophilic nature, epoxy resins tend to absorb moisture. Absorption of moisture degrades the functional, structural and mechanical properties. For polymers, moisture absorption can lead to both reversible and irreversible changes. In this study, the combined effect of moisture and elevated temperature on the mechanical properties of Epon 862 and its nanocomposites were investigated. The extent of permanent damage on fracture toughness and flexural properties of epoxy, due to the aggressive degradation provided by hygrothermal ageing, was determined by drying the epoxy and their clay/epoxy nanocomposites after moisture absorption. From the investigation it was found out that, clay can help in reducing the negative effect of hygrothermal ageing. Significant permanent damage was observed for fracture toughness and modulus, while the extent of permanent damage was less significant for flexural strength. Failure mechanism of this nanocomposites were studied by using Scanning Electron Microscopy (SEM).

Appropriate hinge position for prevention of unstable lateral hinge fracture in open wedge high tibial osteotomy.

PubMed

Nakamura, R; Komatsu, N; Fujita, K; Kuroda, K; Takahashi, M; Omi, R; Katsuki, Y; Tsuchiya, H

2017-10-01

Open wedge high tibial osteotomy (OWHTO) for medial-compartment osteoarthritis of the knee can be complicated by intra-operative lateral hinge fracture (LHF). We aimed to establish the relationship between hinge position and fracture types, and suggest an appropriate hinge position to reduce the risk of this complication. Consecutive patients undergoing OWHTO were evaluated on coronal multiplanar reconstruction CT images. Hinge positions were divided into five zones in our new classification, by their relationship to the proximal tibiofibular joint (PTFJ). Fractures were classified into types I, II, and III according to the Takeuchi classification. Among 111 patients undergoing OWHTOs, 22 sustained lateral hinge fractures. Of the 89 patients without fractures, 70 had hinges in the zone within the PTFJ and lateral to the medial margin of the PTFJ (zone WL), just above the PTFJ. Among the five zones, the relative risk of unstable fracture was significantly lower in zone WL (relative risk 0.24, confidence interval 0.17 to 0.34). Zone WL appears to offer the safest position for the placement of the osteotomy hinge when trying to avoid a fracture at the osteotomy site. Cite this article: Bone Joint J 2017;99B10:1313-18. ©2017 The British Editorial Society of Bone & Joint Surgery.

Clay Houses

ERIC Educational Resources Information Center

Pedro, Cathy

2011-01-01

In this article, the author describes a project designed for fourth-graders that involves making clay relief sculptures of houses. Knowing the clay houses will become a family heirloom makes this lesson even more worth the time. It takes three classes to plan and form the clay, and another two to underglaze and glaze the final products.

Fracture distribution and porosity in a fault-bound hydrothermal system (Grimsel Pass, Swiss Alps)

NASA Astrophysics Data System (ADS)

Egli, Daniel; Küng, Sulamith; Baumann, Rahel; Berger, Alfons; Baron, Ludovic; Herwegh, Marco

2017-04-01

The spatial distribution, orientation and continuity of brittle and ductile structures strongly control fluid pathways in a rock mass by joining existing pores and creating new pore space (fractures, joints) but can also act as seals to fluid flow (e.g. ductile shear zones, clay-rich fault gouges). In long-lived hydrothermal systems, permeability and the related fluid flow paths are therefore dynamic in space and time. Understanding the evolution and behaviour of naturally porous and permeable rock masses is critical for the successful exploration and sustainable exploitation of hydrothermal systems and can advance methods for planning and implementation of enhanced geothermal systems. This study focuses on an active fault-bound hydrothermal system in the crystalline basement of the Aar Massif (hydrothermal field Grimsel Pass, Swiss Alps) that has been exhumed from few kilometres depth and which documents at least 3 Ma of hydrothermal activity. The explored rock unit of the Aar massif is part of the External Crystalline Massifs that hosts a multitude of thermal springs on its southern border in the Swiss Rhône valley and furthermore represents the exhumed equivalent of potentially exploitable geothermal reservoirs in the deep crystalline subsurface of the northern Alpine foreland basin. This study combines structural data collected from a 125 m long drillhole across the hydrothermal zone, the corresponding drill core and surface mapping. Different methods are applied to estimate the porosity and the structural evolution with regard to porosity, permeability and fracture distribution. Analyses are carried out from the micrometre to decametre scale with main focus on the flow path evolution with time. This includes a large variety of porosity-types including fracture-porosity with up to cm-sized aperture down to grain-scale porosity. Main rock types are granitoid host rocks, mylonites, paleo-breccia and recent breccias. The porosity of the host rock as well as the

Zeolite-clay mineral zonation of volcaniclastic sediments within the McDermitt caldera complex of Nevada and Oregon

USGS Publications Warehouse

Glanzman, Richard K.; Rytuba, James J.

1979-01-01

Volcaniclastic sediments deposited in the moat of the collapsed McDermitt caldera complex have been altered chiefly to zeolites and potassium feldspar. The original rhyolitic and peralkaline ash-flow tuffs are included in conglomerates at the caldera rims and grade into a lacustrine series near the center of the collapse. The tuffs show a lateral zeolitic alteration from almost fresh glass to clinoptilolite, clinoptilolite-mordenite, and erionite; to analcime-potassium feldspar; and finally to potassium feldspar. Vertical zonation is in approximately the same order. Clay minerals in associated mudstones, on the other hand, show little lateral variation but a distinct vertical zonation, having a basal dioctahedral smectite, a medial trioctahedral smectite, and an upper dioctahedral smectite. The medial trioctahedral smectite is enriched in lithium (as much as 6,800 ppm Li). Hydrothermal alteration of the volcaniclastic sediments, forming both mercury and uranium deposits, caused a distinct zeolite and clay-mineral zonation within the general lateral zonation. The center of alteration is generally potassium feldspar, commonly associated with alunite. Potassium feldspar grades laterally and vertically to either clinoptilolite or clinoptilolite-mordenite, generally associated with gypsum. This zone then grades vertically and laterally into fresh glass. The clay minerals are a dioctahedral smectite, a mixed-layer clay mineral, and a 7-A clay mineral. The mixed-layer and 7-A clay minerals are associated with the potassium feldspar-alunite zone of alteration, and the dioctahedral smectite is associated with clinoptilolite. This mineralogical zonation may be an exploration guide for mercury and uranium mineralization in the caldera complex environment.

Diffuse-flow hydrothermal field in an oceanic fracture zone setting, Northeast Pacific: Deposit composition

USGS Publications Warehouse

Hein, J.R.; Koski, R.A.; Embley, R.W.; Reid, J.; Chang, S.-W.

1999-01-01

This is the first reported occurrence of an active hydrothermal field in an oceanic fracture zone setting. The hydrothermal field occurs in a pull-apart basin within the Blanco Fracture Zone (BFZ), which has four distinct mineral deposit types: (1) barite mounds and chimneys, (2) barite stockwork breccia, (3) silica-barite beds, and (4) silica, barite, and Fe-Mn oxyhydroxide in sediments. All deposit types contain minor amounts of sulfides. In barite stockwork, silica-barite beds, and mineralized sediment, Ba, Ph, Ag, S, Au, Zn, Cu, Hg, TI, As, Mo, Sb, U, Cd, and Cu are enriched relative to unmineralized rocks and sediments of the BFZ. Fe and Mn are not enriched in the barite stockwork or silica-barite beds, but along with P, Co, and Mg are enriched in the mineralized sediments. Silver contents in deposits of the hydrothermal field range up to 86 ppm, gold to 0.7 ppm, zinc to 3.2%, copper to 0.8%, and barium to 22%. Mineralization occurred by diffuse, low to intermediate temperature (mostly <250??C) discharge of hydrothermal fluids through pillow lavas and ponds of mixed volcaniclastic and biosiliceous sediments. Bacterial mats were mineralized by silica, barite, and minor Fe hydroxides, or less commonly, by Mn oxyhydroxides. Pervasive mineralization of bacterial mats resulted in formation of silica-barite beds. Silica precipitated from hydrothermal fluids by conductive cooling and mixing with seawater. Sulfate, U, and rare earth elements (REEs) in barite were derived from seawater, whereas the REE content of hydrothermal silica deposits and mineralized sediments is associated with the aluminosilicate detrital fraction. Fe-, Zn-, Cu-, Pb-, and Hg-sulfide minerals, Ba in barite, and Eu in all mineralized deposits were derived from hydrothermal fluids. Manganese oxides and associated elements (Co, Sb, Mo, W, Cl, and Cu) and Fe oxides and associated elements (Be, B, P, and Mo) precipitated as the result of mixing of hydrothermal fluids with seawater. ?? 2001 Canadian

On the origin of mixed-layered clay minerals from the San Andreas Fault at 2.5-3 km vertical depth (SAFOD drillhole at Parkfield, California)

NASA Astrophysics Data System (ADS)

Schleicher, A. M.; Warr, L. N.; van der Pluijm, B. A.

2009-02-01

A detailed mineralogical study is presented of the matrix of mudrocks sampled from spot coring at three key locations along the San Andreas Fault Observatory at depth (SAFOD) drill hole. The characteristics of authigenic illite-smectite (I-S) and chlorite-smectite (C-S) mixed-layer mineral clays indicate a deep diagenetic origin. A randomly ordered I-S mineral with ca. 20-25% smectite layers is one of the dominant authigenic clay species across the San Andreas Fault zone (sampled at 3,066 and 3,436 m measured depths/MD), whereas an authigenic illite with ca. 2-5% smectite layers is the dominant phase beneath the fault (sampled at 3,992 m MD). The most smectite-rich mixed-layered assemblage with the highest water content occurs in the actively deforming creep zone at ca. 3,300-3,353 m (true vertical depth of ca. 2.7 km), with I-S (70:30) and C-S (50:50). The matrix of all mudrock samples show extensive quartz and feldspar (both plagioclase and K-feldspar) dissolution associated with the crystallization of pore-filling clay minerals. However, the effect of rock deformation in the matrix appears only minor, with weak flattening fabrics defined largely by kinked and fractured mica grains. Adopting available kinetic models for the crystallization of I-S in burial sedimentary environments and the current borehole depths and thermal structure, the conditions and timing of I-S growth can be evaluated. Assuming a typical K+ concentration of 100-200 ppm for sedimentary brines, a present-day geothermal gradient of 35°C/km and a borehole temperature of ca. 112°C for the sampled depths, most of the I-S minerals can be predicted to have formed over the last 4-11 Ma and are probably still in equilibrium with circulating fluids. The exception to this simple burial pattern is the occurrence of the mixed layered phases with higher smectite content than predicted by the burial model. These minerals, which characterize the actively creeping section of the fault and local thin film

The influence of third molars in the line of mandibular angle fractures on wound and bone healing.

PubMed

Ulbrich, N; Ettl, T; Waiss, W; Gosau, M; Moralis, A; Reichert, T E; Mueller, S

2016-07-01

The objective of this study was to evaluate postoperative complications after removal or retention of the third molar in the line of mandibular angle fractures. This retrospective study included the data of 98 patients with a molar in the line of a mandibular angle fracture treated with internal reduction and mini-plate fixation at our department over 9 years. Patients were classified into two groups: tooth removal during osteosynthesis (n = 45) and tooth retention (n = 55). The primary target criterion was the incidence of minor (outpatient treatment, local measures) and major (surgical revision, rehospitalisation) complications. Time between trauma and surgery was 1.4 days (range 0 to 12), and the average follow-up 291 days (range 66 to 863). Regarding the eruption status, 26 of 52 (50.0 %) impacted third molars, 11 of 19 (57.9 %) incompletely erupted and 8 of 27 (29.6 %) completely erupted molars had been removed during open reduction. Overall, 17 (17.3 %) patients had postoperative minor (n = 7) or major (n = 10) complications, in detail 10/45 (22.0 %) patients after tooth removal and 7/55 (13 %) patients after tooth retention (p = 0.286). Complication rates between impacted and incompletely erupted third molars (impacted molars 15.0 %, incompletely erupted molars 10.0 %) did not differ significantly, but completely erupted molars had a complication rate of 26.0 %. Mandibular angle fractures with a completely erupted third molar show the highest complication rate after open reduction and osteosynthesis. Retention of a non-infectious third molar facilitates open reduction and does not increase the complication risk. The study helps with the decision of removing or retention of a third molar during surgical treatment of a mandibular angle fracture.

How to fracture formations (in Spanish)

DOE Office of Scientific and Technical Information (OSTI.GOV)

del Risco V.M.

1971-01-01

Government-owned Petroleos del Peru has found the limited-entry fracturing technique to be the most suitable under prevailing conditions for its NW. Peruvian oil fields. There, most formations available for stimulation are low- permeability and highly compact sands interbedded with thin and thick layers of clay. After experimenting with 8 different commercially available methods, a detailed analysis of the results showed the Shoot-Frac system to be the most effective.

Biodiversity of nematode assemblages from the region of the Clarion-Clipperton Fracture Zone, an area of commercial mining interest.

PubMed

Lambshead, P John D; Brown, Caroline J; Ferrero, Timothy J; Hawkins, Lawrence E; Smith, Craig R; Mitchell, Nicola J

2003-01-09

The possibility for commercial mining of deep-sea manganese nodules is currently under exploration in the abyssal Clarion-Clipperton Fracture Zone. Nematodes have potential for biomonitoring of the impact of commercial activity but the natural biodiversity is unknown. We investigate the feasibility of nematodes as biomonitoring organisms and give information about their natural biodiversity. The taxonomic composition (at family to genus level) of the nematode fauna in the abyssal Pacific is similar, but not identical to, the North Atlantic. Given the immature state of marine nematode taxonomy, it is not possible to comment on the commonality or otherwise of species between oceans. The between basin differences do not appear to be directly linked to current ecological factors. The abyssal Pacific region (including the Fracture Zone) could be divided into two biodiversity subregions that conform to variations in the linked factors of flux to the benthos and of sedimentary characteristics. Richer biodiversity is associated with areas of known phytodetritus input and higher organic-carbon flux. Despite high reported sample diversity, estimated regional diversity is less than 400 species. The estimated regional diversity of the CCFZ is a tractable figure for biomonitoring of commercial activities in this region using marine nematodes, despite the immature taxonomy (i.e. most marine species have not been described) of the group. However, nematode ecology is in dire need of further study.

Self organized spatio-temporal structure within the fractured Vadose Zone: The influence of dynamic overloading at fracture intersections

NASA Astrophysics Data System (ADS)

LaViolette, Randall A.; Glass, Robert J.

2004-09-01

Under low flow conditions (where gravity and capillary forces dominate) within an unsaturated fracture network, fracture intersections act as capillary barriers to integrate flow from above and then release it as a pulse below. Water exiting a fracture intersection is often thought to enter the single connected fracture with the lowest invasion pressure. When the accumulated volume varies between intersections, the smaller volume intersections can be overloaded to cause all of the available fractures exiting an intersection to flow. We included the dynamic overloading process at fracture intersections within our previously discussed model where intersections were modeled as tipping buckets connected within a two-dimensional diamond lattice. With dynamic overloading, the flow behavior transitioned smoothly from diverging to converging flow with increasing overload parameter, as a consequence of a heterogeneous field, and they impose a dynamic structure where additional pathways activate or deactivate in time.

Modified clay sorbents

DOEpatents

Fogler, H. Scott; Srinivasan, Keeran R.

1990-01-01

A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

Can clays ensure nuclear waste repositories?

NASA Astrophysics Data System (ADS)

Zaoui, A.; Sekkal, W.

2015-03-01

Research on argillite as a possible host rock for nuclear waste disposal is still an open subject since many issues need to be clarified. In the Underground Research Laboratories constructed for this purpose, a damaged zone around the excavation has been systematically observed and characterized by the appearance of micro-fissures. We analyse here -at nanoscale level- the calcite/clay assembly, the main constituents of argillite, under storage conditions and show the fragility of the montmorillonite with respect to calcite. Under anisotropic stress, we have observed a shear deformation of the assembly with the presence of broken bonds in the clay mineral, localised in the octahedral rather than the tetrahedral layers. The stress/strain curve leads to a failure strength point at 18.5 MPa. The obtained in-plane response of the assembly to perpendicular deformation is characterized by smaller perpendicular moduli Ez = 48.28 GPa compared to larger in-plane moduli Ex = 141.39 GPa and Ey = 134.02 GPa. Our calculations indicate the instability of the assembly without water molecules at the interface in addition to an important shear deformation.

Clay preference and particle transport behavior of Formosan subterranean termites (Isoptera: Rhinotermitidae): a laboratory study.

PubMed

Wang, Cai; Henderson, Gregg

2014-12-01

Although preference and utilization of clay have been studied in many higher termites, little attention has been paid to lower termites, especially subterranean termites. The Formosan subterranean termite, Coptotermes formosanus Shiraki, can modify its habitat by using clay to fill tree cavities. Here, the biological significance of clay on C. formosanus was investigated. Choice tests showed that significantly more termites aggregated in chambers where clay blocks were provided, regardless of colony group, observation period, or nutritional condition (fed or starved). No-choice tests showed that clay had no observable effect on survivorship, live or dry biomass, water content, and tunneling activity after 33-35 d. However, clay appeared to significantly decrease filter paper consumption (dry weight loss). Active particle (sand, paper, and clay) transport behavior was observed in both choice and no-choice tests. When present, clay was preferentially spread on the substrate, attached to the smooth surfaces of the containers, and used to line sand tunnels. Mechanisms and potential application of clay attraction are discussed. © 2013 Institute of Zoology, Chinese Academy of Sciences.

Nano-iron Tracer Test for Characterizing Preferential Flow Path in Fractured Rock

NASA Astrophysics Data System (ADS)

Chia, Y.; Chuang, P. Y.

2015-12-01

Deterministic description of the discrete features interpreted from site characterization is desirable for developing a discrete fracture network conceptual model. It is often difficult, however, to delineate preferential flow path through a network of discrete fractures in the field. A preliminary cross-borehole nano-iron tracer test was conducted to characterize the preferential flow path in fractured shale bedrock at a hydrogeological research station. Prior to the test, heat-pulse flowmeter measurements were performed to detect permeable fracture zones at both the injection well and the observation well. While a few fracture zones are found permeable, most are not really permeable. Chemical reduction method was used to synthesize nano zero-valent iron particles with a diameter of 50~150 nm. The conductivity of nano-iron solution is about 3100 μs/cm. The recorded fluid conductivity shows the arrival of nano-iron solution in the observation well 11.5 minutes after it was released from the injection well. The magnetism of zero-valent iron enables it to be absorbed on magnet array designed to locate the depth of incoming tracer. We found nearly all of absorbed iron on the magnet array in the observation well were distributed near the most permeable fracture zone. The test results revealed a preferential flow path through a permeable fracture zone between the injection well and the observation well. The estimated hydraulic conductivity of the connected fracture is 2.2 × 10-3 m/s. This preliminary study indicated that nano-iron tracer test has the potential to characterize preferential flow path in fractured rock.

Fracture characterization and fracture-permeability estimation at the underground research laboratory in southeastern Manitoba, Canada

USGS Publications Warehouse

Paillet, Frederick L.

1988-01-01

Various conventional geophysical well logs were obtained in conjunction with acoustic tube-wave amplitude and experimental heat-pulse flowmeter measurements in two deep boreholes in granitic rocks on the Canadian shield in southeastern Manitoba. The objective of this study is the development of measurement techniques and data processing methods for characterization of rock volumes that might be suitable for hosting a nuclear waste repository. One borehole, WRA1, intersected several major fracture zones, and was suitable for testing quantitative permeability estimation methods. The other borehole, URL13, appeared to intersect almost no permeable fractures; it was suitable for testing methods for the characterization of rocks of very small permeability and uniform thermo-mechanical properties in a potential repository horizon. Epithermal neutron , acoustic transit time, and single-point resistance logs provided useful, qualitative indications of fractures in the extensively fractured borehole, WRA1. A single-point log indicates both weathering and the degree of opening of a fracture-borehole intersection. All logs indicate the large intervals of mechanically and geochemically uniform, unfractured granite below depths of 300 m in the relatively unfractured borehole, URL13. Some indications of minor fracturing were identified in that borehole, with one possible fracture at a depth of about 914 m, producing a major acoustic waveform anomaly. Comparison of acoustic tube-wave attenuation with models of tube-wave attenuation in infinite fractures of given aperture provide permeability estimates ranging from equivalent single-fractured apertures of less than 0.01 mm to apertures of > 0.5 mm. One possible fracture anomaly in borehole URL13 at a depth of about 914 m corresponds with a thin mafic dike on the core where unusually large acoustic contrast may have produced the observed waveform anomaly. No indications of naturally occurring flow existed in borehole URL13; however

Localizing Fracture Hydromechanical Response using Fiber Optic Distributed Acoustic Sensing in a Fractured Bedock Aquifer

NASA Astrophysics Data System (ADS)

Chevrot, S.; Wang, Y.; Monteiller, V.; Komatitsch, D.; Martin, R.

2016-12-01

Measuring fracture mechanical behavior in response to changes in fluid pressure is critical for understanding flow through petroleum reservoirs, predicting hydrothermal responses in geothermal fields, and monitoring geologic carbon sequestration injection. Distributed acoustic sensing (DAS) is new, but commercially available fiber optic technology that offers a novel approach to characterize fractured bedrock systems. DAS was originally designed to measure the amplitude, frequency, and phase of an acoustic wave, and is therefore capable of detecting strains at exceedingly small scales. Though normally used to measure frequencies in the Hz to kHz range, we adapted DAS to measure fracture displacements in response to periodic hydraulic pulses in the mHz frequency range. A field experiment was conducted in a fractured bedrock aquifer to test the ability of DAS to measure fracture mechanical response to oscillatory well tests. Fiber optic cable was deployed in a well, and coupled to the borehole wall using a flexible impermeable liner designed with an air coupled transducer to measure fluid pressure at the target fracture zone. Two types of cable were tested, a loose tube and tight buffered, to determine the effects of cable construction. Both strain and pressure were measured across the known fracture zone hydraulically connected to a well 30 m away. The companion well was subjected to alternating pumping and injection with periods between 2 and 18 minutes. Raw DAS data were collected as strain rate measured every 0.25 m along the fiber with a gauge length of 10 m, at a sampling rate of 1 kHz. Strain rate was converted to strain by integrating with respect to time. DAS measured periodic strains of less than 1 nm/m in response to periodic injection and pumping at the companion well. Strain was observed by DAS only at the depth of the hydraulically connected fracture zone. Thus, the magnitude and response of the strain could be both localized with depth and measured

Localizing Fracture Hydromechanical Response using Fiber Optic Distributed Acoustic Sensing in a Fractured Bedock Aquifer

NASA Astrophysics Data System (ADS)

Ciervo, C.; Becker, M.; Cole, M. C.; Coleman, T.; Mondanos, M.

2017-12-01

Measuring fracture mechanical behavior in response to changes in fluid pressure is critical for understanding flow through petroleum reservoirs, predicting hydrothermal responses in geothermal fields, and monitoring geologic carbon sequestration injection. Distributed acoustic sensing (DAS) is new, but commercially available fiber optic technology that offers a novel approach to characterize fractured bedrock systems. DAS was originally designed to measure the amplitude, frequency, and phase of an acoustic wave, and is therefore capable of detecting strains at exceedingly small scales. Though normally used to measure frequencies in the Hz to kHz range, we adapted DAS to measure fracture displacements in response to periodic hydraulic pulses in the mHz frequency range. A field experiment was conducted in a fractured bedrock aquifer to test the ability of DAS to measure fracture mechanical response to oscillatory well tests. Fiber optic cable was deployed in a well, and coupled to the borehole wall using a flexible impermeable liner designed with an air coupled transducer to measure fluid pressure at the target fracture zone. Two types of cable were tested, a loose tube and tight buffered, to determine the effects of cable construction. Both strain and pressure were measured across the known fracture zone hydraulically connected to a well 30 m away. The companion well was subjected to alternating pumping and injection with periods between 2 and 18 minutes. Raw DAS data were collected as strain rate measured every 0.25 m along the fiber with a gauge length of 10 m, at a sampling rate of 1 kHz. Strain rate was converted to strain by integrating with respect to time. DAS measured periodic strains of less than 1 nm/m in response to periodic injection and pumping at the companion well. Strain was observed by DAS only at the depth of the hydraulically connected fracture zone. Thus, the magnitude and response of the strain could be both localized with depth and measured

Pore- and fracture-filling gas hydrate reservoirs in the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II Green Canyon 955 H well

USGS Publications Warehouse

Lee, M.W.; Collett, T.S.

2012-01-01

High-quality logging-while-drilling (LWD) downhole logs were acquired in seven wells drilled during the Gulf of MexicoGasHydrateJointIndustryProjectLegII in the spring of 2009. Well logs obtained in one of the wells, the GreenCanyon Block 955Hwell (GC955-H), indicate that a 27.4-m thick zone at the depth of 428 m below sea floor (mbsf; 1404 feet below sea floor (fbsf)) contains gashydrate within sand with average gashydrate saturations estimated at 60% from the compressional-wave (P-wave) velocity and 65% (locally more than 80%) from resistivity logs if the gashydrate is assumed to be uniformly distributed in this mostly sand-rich section. Similar analysis, however, of log data from a shallow clay-rich interval between 183 and 366 mbsf (600 and 1200 fbsf) yielded average gashydrate saturations of about 20% from the resistivity log (locally 50-60%) and negligible amounts of gashydrate from the P-wave velocity logs. Differences in saturations estimated between resistivity and P-wave velocities within the upper clay-rich interval are caused by the nature of the gashydrate occurrences. In the case of the shallow clay-rich interval, gashydrate fills vertical (or high angle) fractures in rather than fillingpore space in sands. In this study, isotropic and anisotropic resistivity and velocity models are used to analyze the occurrence of gashydrate within both the clay-rich and sand dominated gas-hydrate-bearing reservoirs in the GC955-Hwell.

First-order Description of the Mechanical Fracture Behavior of Fine-Grained Surficial Marine Sediments During Gas Bubble Growth

DTIC Science & Technology

2010-01-01

Mechanical analysis of idealized shallow hydraulic fracture, / Geotech . Geoenviron. Eng., 128, 488-495, doi:10.1061/ (ASCE) 1090-0241 (2002) 128:6(488...F. Chiu, and H.-J. Chai (2007), Experimental study on fracture behavior of a silty clay, Geotech . Test. J., 30, 1-9, doi: I0.1520/GTJI00715

Spatial distribution of jet fuel in the vadoze zone of a heterogeneous and fractured soil.

PubMed

Tzovolou, D N; Benoit, Y; Haeseler, F; Klint, K E; Tsakiroglou, C D

2009-04-01

The goal of the present work is to screen and evaluate all available data before selecting and testing remediation technologies on heterogeneous soils polluted by jet fuel. The migration pathways of non-aqueous phase liquids (NAPLs) in the subsurface relate closely with soil properties. A case study is performed on the vadoze zone of a military airport of north-west Poland contaminated by jet fuel. Soil samples are collected from various depths of two cells, and on-site and off-site chemical analyses of hydrocarbons are conducted by using Pollut Eval apparatus and GC-MS, respectively. The geological conceptual model of the site along with microscopic and hydraulic properties of the porous matrix and fractures enable us to interpret the non-uniform spatial distribution of jet fuel constituents. The total concentration of the jet fuel and its main hydrocarbon families (n-paraffins, major aromatics) over the two cells is governed by the slow preferential flow of NAPL through the porous matrix, the rapid NAPL convective flow through vertical desiccation and sub-horizontal glaciotectonic fractures, and n-paraffin biodegradation in upper layers where the rates of oxygen transfer is not limited by complexities of the pore structure. The information collected is valuable for the selection, implementation and evaluation of two in situ remediation methods.

Nanoparticles migration in fractured rocks and affects on contaminant migration

NASA Astrophysics Data System (ADS)

Missana, Tiziana; Garcia-Gutierrez, Miguel; Alonso, Ursula

2014-05-01

In previous studies, the transport behavior of artificial (gold and latex) and natural (smectite clay) colloids, within a planar fracture in crystalline rock, was analyzed. In order to better understand the effects of colloid size, shape and surface charge on nanoparticle migration and especially on filtration processes on natural rock surfaces, different clay colloids and oxide nanoparticles were selected and their transport studied as a function of the residence time. In all the cases, (a fraction of) the nanoparticles travelled in the fracture as fast as or faster than water (with a retardation factor, Rf ≤ 1) and the observed Rf, was related to the Taylor dispersion coefficient, accounting for colloid size, water velocity and fracture width. However, under most of the cases, in contrast to the behavior of a conservative tracer, colloids recovery was much lower than 100 %. Differences in recovery between different nanoparticles, under similar residence times, were analyzed. In order to evaluate the possible consequences, on contaminant migration, of the presence of nanoparticles in the system, transport tests were carried out with both colloids and sorbing radionuclides. The overall capacity for colloids of enhancing radionuclide migration in crystalline rock fractures is discussed. Acknowledgments: The research leading to these results received funding from EU FP7/2007-2011 grant agreement Nº 295487 (BELBAR, Bentonite Erosion: effects on the Long term performance of the engineered Barrier and Radionuclide Transport) and by the Spanish Government under the project NANOBAG (CTM2011-2797).

Fire clay

USGS Publications Warehouse

Virta, R.L.

2006-01-01

In 2005, six companies mined fire clay in Missouri, Ohio and South Carolina. Production was estimate to be 300 kt with a value of $8.3 million. Missouri was the leading producer state followed by Ohio and South Carolina. For the third consecutive year, sales and use of fire clays have been relatively unchanged. For the next few years, sales of fire clay is forecasted to remain around 300 kt/a.

The relation of sediment texture to macro- and microplastic abundance in intertidal zone

NASA Astrophysics Data System (ADS)

Wahyuningsih, H.; Bangun, A. P.; Muhtadi, A.

2018-02-01

The intertidal zone is a waters area directly affected by the contamination of plastic debris from land and sea. The aim of this research were to analyze the relation of sediment texture to macro- and micro plastic abundance and also to determine appropriate management strategy. This research was conducted in intertidal zone Jaring Halus Village Langkat Regency North Sumatera Province on February-April 2017. Plastic debris was collected using quadrat transect. Sediment was collected with correct, up to a depth of least 30 cm. Abundance of micro plastic in Station 1 were positively tolerated with clay (0.509), and silt (0.787) and negatively correlations with sand (0.709) Station 2 were positively correlations with sand (0.645) and negatively correlations with clay (0.575), and silt (0.626) Station 3 were positively correlations with clay (0.435), and silt (0.466) and negatively correlations with sand (0.599). The abundance of microplastic was positively correlations with the abundance of microplastic (0.765). Microplastic density is directly proportional to the content of clay and dust. The higher the clay and dust content the higher the micro plastic density.

Flow-path textures and mineralogy in tuffs of the unsaturated zone

USGS Publications Warehouse

Levy, Schön; Chipera, Steve; WoldeGabriel, Giday; Fabryka-Martin, June; Roach, Jeffrey; Sweetkind, Donald S.; Haneberg, William C.; Mozley, Peter S.; Moore, J. Casey; Goodwin, Laurel B.

1999-01-01

The high concentration of chlorine-36 (36Cl) produced by above-ground nuclear tests (bomb-pulse) provides a fortuitous tracer for infiltration during the last 50 years, and is used to detect fast flow in the unsaturated zone at Yucca Mountain, Nevada, a thick deposit of welded and nonwelded tuffs. Evidence of fast flow as much as 300 m into the mountain has been found in several zones in a 7.7-km tunnel. Many zones are associated with faults that provide continuous fracture flow paths from the surface. In the Sundance fault zone, water with the bomb-pulse signature has moved into subsidiary fractures and breccia zones. We found no highly distinctive mineralogic associations of fault and fracture samples containing bomb-pulse 36Cl. Bomb-pulse sites are slightly more likely to have calcite deposits than are non-bomb-pulse sites. Most other mineralogic and textural associations of fast-flow paths reflect the structural processes leading to locally enhanced permeability rather than the effects of ground-water percolation. Water movement through the rock was investigated by isotopic analysis of paired samples representing breccia zones and fractured wall rock bounding the breccia zones. Where bomb-pulse 36Cl is present, the waters in bounding fractures and intergranular pores of the fast pathways are not in equilibrium with respect to the isotopic signal. In structural domains that have experienced extensional deformation, fluid flow within a breccia is equivalent to matrix flow in a particulate rock, whereas true fracture flow occurs along the boundaries of a breccia zone. Where shearing predominated over extension, the boundary between wall rock and breccia is rough and irregular with a tight wallrock/breccia contact. The absence of a gap between the breccia and the wall rock helps maintain fluid flow within the breccia instead of along the wallrock/breccia boundary, leading to higher 36Cl/Cl values in the breccia than in the wall rock.

Clay-mineral assemblages from some levels of K-118 drill core of Maha Sarakham evaporites, northeastern Thailand

NASA Astrophysics Data System (ADS)

Suwanich, Parkorn

Clay-mineral assemblages in Middle Clastic, Middle Salt, Lower Clastic, Potash Zone, and Lower Salt, totalling 13 samples from K-118 drill core, in the Maha Sarakham Formation, Khorat Basin, northeastern Thailand were studied. The clay-size particles were separated from the water-soluble salt by water leaching. Then the samples were leached again in the EDTA solution and separated into clay-size particles by using the timing sedimentation. The EDTA-clay residues were divided and analyzed by using the XRD and XRF method. The XRD peaks show that the major-clay minerals are chlorite, illite, and mixed-layer corrensite including traces of rectorite? and paragonite? The other clay-size particles are quartz and potassium feldspar. The XRF results indicate Mg-rich values and moderate MgAl atom ratio values in those clay minerals. The variable Fe, Na, and K contents in the clay-mineral assemblages can explain the environment of deposition compared to the positions of the samples from the core. Hypothetically, mineralogy and the chemistry of the residual assemblages strongly indicate that severe alteration and Mg-enrichment of normal clay detritus occurred in the evaporite environment through brine-sediment interaction. The various Mg-enrichment varies along the various members reflecting whether sedimentation is near or far from the hypersaline brine.

An Application of Hydraulic Tomography to a Large-Scale Fractured Granite Site, Mizunami, Japan.

PubMed

Zha, Yuanyuan; Yeh, Tian-Chyi J; Illman, Walter A; Tanaka, Tatsuya; Bruines, Patrick; Onoe, Hironori; Saegusa, Hiromitsu; Mao, Deqiang; Takeuchi, Shinji; Wen, Jet-Chau

2016-11-01

While hydraulic tomography (HT) is a mature aquifer characterization technology, its applications to characterize hydrogeology of kilometer-scale fault and fracture zones are rare. This paper sequentially analyzes datasets from two new pumping tests as well as those from two previous pumping tests analyzed by Illman et al. (2009) at a fractured granite site in Mizunami, Japan. Results of this analysis show that datasets from two previous pumping tests at one side of a fault zone as used in the previous study led to inaccurate mapping of fracture and fault zones. Inclusion of the datasets from the two new pumping tests (one of which was conducted on the other side of the fault) yields locations of the fault zone consistent with those based on geological mapping. The new datasets also produce a detailed image of the irregular fault zone, which is not available from geological investigation alone and the previous study. As a result, we conclude that if prior knowledge about geological structures at a field site is considered during the design of HT surveys, valuable non-redundant datasets about the fracture and fault zones can be collected. Only with these non-redundant data sets, can HT then be a viable and robust tool for delineating fracture and fault distributions over kilometer scales, even when only a limited number of boreholes are available. In essence, this paper proves that HT is a new tool for geologists, geophysicists, and engineers for mapping large-scale fracture and fault zone distributions. © 2016, National Ground Water Association.

Use of satellite pictures for determining major shield fractures relevant for ore prospecting, northern Finland

NASA Technical Reports Server (NTRS)

Tuominen, H. V.; Aarnisalo, J. (Principal Investigator)

1976-01-01

The author has identified the following significant results. A combined analysis of LANDSAT 1 imagery, aeromagnetic and other maps, and aerial photos has revealed a dense network of bedrock fractures in northern Finland. They form several fracturing zones, which obviously represent surficial manifestations of major fractures. The fractures follow, in general, the eight main trends of crustal shear characteristics of the Baltic Shield, but show distinct deviations from them in detail. The major fracture zones divide the bedrock into a mosaic of polygonal blocks, which in many cases coincide with the main rock units of the area and are characterized by different patterns of internal fracturing. Known mineralizations show a tendency to concentrate along the fracture zones. Optical filtering of original LANDSAT images might provide a rapid tool for the analysis of major structural trends in extensive areas such as shields or entire continents.

Integrated approach for quantification of fractured tight reservoir rocks: Porosity, permeability analyses and 3D fracture network characterisation on fractured dolomite samples

NASA Astrophysics Data System (ADS)

Voorn, Maarten; Barnhoorn, Auke; Exner, Ulrike; Baud, Patrick; Reuschlé, Thierry

2015-04-01

Fractured reservoir rocks make up an important part of the hydrocarbon reservoirs worldwide. A detailed analysis of fractures and fracture networks in reservoir rock samples is thus essential to determine the potential of these fractured reservoirs. However, common analyses on drill core and plug samples taken from such reservoirs (including hand specimen analysis, thin section analysis and laboratory porosity and permeability determination) suffer from various problems, such as having a limited resolution, providing only 2D and no internal structure information, being destructive on the samples and/or not being representative for full fracture networks. In this study, we therefore explore the use of an additional method - non-destructive 3D X-ray micro-Computed Tomography (μCT) - to obtain more information on such fractured samples. Seven plug-sized samples were selected from narrowly fractured rocks of the Hauptdolomit formation, taken from wellbores in the Vienna Basin, Austria. These samples span a range of different fault rocks in a fault zone interpretation, from damage zone to fault core. 3D μCT data is used to extract porosity, fracture aperture, fracture density and fracture orientations - in bulk as well as locally. The 3D analyses are complemented with thin sections made to provide some 2D information with a much higher detail than the μCT data. Finally, gas- and water permeability measurements under confining pressure provide an important link (at least in order of magnitude) of the µCT results towards more realistic reservoir conditions. Our results show that 3D μCT can be applied efficiently on plug-sized samples of naturally fractured rocks, and that several important parameters can be extracted. μCT can therefore be a useful addition to studies on such reservoir rocks, and provide valuable input for modelling and simulations. Also permeability experiments under confining pressure provide important additional insights. Combining these and other

Halloysite clay nanotubes for resveratrol delivery to cancer cells.

PubMed

Vergaro, Viviana; Lvov, Yuri M; Leporatti, Stefano

2012-09-01

Halloysite is natural aluminosilicate clay with hollow tubular structure which allows loading with low soluble drugs using their saturated solutions in organic solvents. Resveratrol, a polyphenol known for having antioxidant and antineoplastic properties, is loaded inside these clay nanotubes lumens. Release time of 48 h is demonstrated. Spectroscopic and ζ-potential measurements are used to study the drug loading/release and for monitoring the nanotube layer-by-layer (LbL) coating with polyelectrolytes for further release control. Resveratrol-loaded clay nanotubes are added to breast cell cultures for toxicity tests. Halloysite functionalization with LbL polyelectrolyte multilayers remarkably decrease nanotube self-toxicity. MTT measurements performed with a neoplastic cell lines model system (MCF-7) as function of the resveratrol-loaded nanotubes concentration and incubation time indicate that drug-loaded halloysite strongly increase of cytotoxicity leading to cell apoptosis. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Water saturation of hydrothermal smectite-rich clay might have promoted slope instability prior to the 1998 debris avalanche at Casita volcano, Nicaragua

NASA Astrophysics Data System (ADS)

Delmelle, P.; Opfergelt, S.; Boivin, P.; Delvaux, B.

2006-12-01

In October 1998, a relatively small collapse (1 600 000 cubic meters) of a pre-existing scarp occurred on the southern flank of the dormant Casita volcano, Nicaragua. It resulted in a debris avalanche, which quickly transformed into a disastrous debris flow that destroyed two towns and killed more than 2500 people. The failure was shown to be triggered by an excess pore water pressure within highly fractured rocks, following prolonged seasonal rains and precipitations from Hurricane Mitch. This pressure was linked to the water saturation of a hydrothermally-altered clay bedrock impeding in-depth infiltration. Yet, the nature and amounts of the clay material involved in the slope failure were still unknown. Here we report on physical, chemical and mineralogical investigations aimed at quantifying the clay content, and identifying the layer silicates of the hydrothermally-altered clays uncovered by the 1998 debris avalanche. The fine clay material was exceptionally rich in smectite (up to 50 wt. percent), which swells upon wetting and shrinks during dry conditions (Opfergelt et al., 2006, Geophys. Res. Lett., 33 (15), L15305). The smectite belonged to the beidellite-montmorillonite series. The pervasive presence of water-saturated smectitic clay strongly reduced the permeability in depth, and also altered the rheological and mechanical properties of both the pre-failure rock mass and flow materials. The shrink-swell behavior progressively decreased the rock's shear strength, and gradually destabilized the overlying rock mass in the decades and centuries before the landslide, thereby contributing to slope instability. Prolonged intense rainfall led to the formation of incipient weak failure surfaces in the superficial rock mass. As provoked by water saturation, this process was likely favored by the rapid change of the mechanical properties of smectite-rich clays deposited in fracture, joint and gouge interfaces. We suggest that hazard assessments associated with

Microphysical characteristics of squall-line stratiform precipitation and transition zones inferred using an ice particle property-evolving model

NASA Astrophysics Data System (ADS)

Jensen, A. A.; Harrington, J. Y.; Morrison, H.

2017-12-01

A quasi-idealized 3D squall line (based on a June 2007 Oklahoma case) is simulated using a novel bulk microphysics scheme called the Ice-Spheroids Habit Model with Aspect-ratio Evolution (ISHMAEL). In ISHMAEL, the evolution of ice particle properties, such as mass, shape, maximum diameter, density, and fall speed, are tracked as these properties evolve from vapor growth, sublimation, riming, and melting. Thus, ice properties evolve from various microphysical processes without needing separate unrimed and rimed ice categories. Simulation results show that ISHMAEL produces both a squall-line transition zone and an enhanced stratiform precipitation region. The ice particle properties produced in this simulation are analyzed and compared to observations to determine the characteristics of ice that lead to the development of these squall-line features. It is shown that rimed particles advected rearward from the convective region produce the enhanced stratiform precipitation region. The development of the transition zone results from hydrometer sorting: the evolution of ice particle properties in the convective region produces specific fall speeds that favor significant ice advecting rearward of the transition zone before reaching the melting level, causing a local minimum in precipitation rate and reflectivity there. Microphysical sensitivity studies, for example turning rime splintering off, that lead to changes in ice particle properties reveal that the fall speed of ice particles largely determines both the location of the enhanced stratiform precipitation region and whether or not a transition zone forms.

Reservoir fracture mapping using microearthquakes: Austin chalk, Giddings field, TX and 76 field, Clinton Co., KY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, W.S.; Rutledge, J.T.; Gardner, T.L.

1996-11-01

Patterns of microearthquakes detected downhole defined fracture orientation and extent in the Austin chalk, Giddings field, TX and the 76 field, Clinton Co., KY. We collected over 480 and 770 microearthquakes during hydraulic stimulation at two sites in the Austin chalk, and over 3200 during primary production in Clinton Co. Data were of high enough quality that 20%, 31% and 53% of the events could be located, respectively. Reflected waves constrained microearthquakes to the stimulated depths at the base of the Austin chalk. In plan view, microearthquakes defined elongate fracture zones extending from the stimulation wells parallel to the regionalmore » fracture trend. However, widths of the stimulated zones differed by a factor of five between the two Austin chalk sites, indicating a large difference in the population of ancillary fractures. Post-stimulation production was much higher from the wider zone. At Clinton Co., microearthquakes defined low-angle, reverse-fault fracture zones above and below a producing zone. Associations with depleted production intervals indicated the mapped fractures had been previously drained. Drilling showed that the fractures currently contain brine. The seismic behavior was consistent with poroelastic models that predicted slight increases in compressive stress above and below the drained volume.« less

Reservoir fracture mapping using microearthquakes: Austin chalk, Giddings field, TX and 76 field, Clinton Co., KY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, W.S.; Rutledge, J.T.; Fairbanks, T.D.

1996-12-31

Patterns of microearthquakes detected downhole defined fracture orientation and extent in the Austin chalk, Giddings field, TX and the 76 field, Clinton Co., KY. We collected over 480 and 770 microearthquakes during hydraulic stimulation at two sites in the Austin chalk, and over 3200 during primary production in Clinton Co. Data were of high enough quality that 20%, 31% and 53% of the events could be located, respectively. Reflected waves constrained microearthquakes to the stimulated depths at the base of the Austin chalk. In plan view, microearthquakes defined elongate fracture zones extending from the stimulation wells parallel to the regionalmore » fracture trend. However, widths of the stimulated zones differed by a factor of live between the two Austin chalk sites, indicating a large difference in the population of ancillary fractures. Post-stimulation production was much higher from the wider zone. At Clinton Co., microearthquakes defined low-angle, reverse-fault fracture zones above and below a producing zone. Associations with depleted production intervals indicated the mapped fractures had been previously drained. Drilling showed that the fractures currently contain brine. The seismic behavior was consistent with poroelastic models that predicted slight increases in compressive stress above and below the drained volume.« less

Clays in prebiological chemistry

NASA Technical Reports Server (NTRS)

Rao, M.; Oro, J.; Odom, D. G.

1980-01-01

The ways in which clays have been utilized in studies of prebiological chemistry are reviewed, and an assessment is given of the possible role of clays in prebiological systems. The adsorption of organic molecules on clays has been demonstrated, as has the synthesis of bioorganic monomers in the presence of clays. For instance, amino acids, purines and pyrimidines have been obtained from carbon monoxide and nitric acid in the presence of clays at relatively high temperatures (250-325 C). The oligomerization of biochemical monomers, mediated by clays, has also been shown to result in the formation of polymer molecules basic to life. Clays have also been found to affect the condensation of mononucleotides to oligonucleotides.

Reactive Transport Modeling and Changes in Porosity at Reactive Interfaces in a HLW repository in Clay

NASA Astrophysics Data System (ADS)

Samper, J.; Mon, A.; Montenegro, L.; Naves, A.; Fernández, J.

2016-12-01

High-level radioactive waste disposal in a deep geological repository is based on a multibarrier concept which combines natural barriers such as the geological formation and artificial barriers such as metallic containers, bentonite and concrete buffers and sealing materials. The stability and performance of the bentonite barrier could be affected by the corrosion products at the canister-bentonite interface and the hyperalkaline conditions caused by the degradation of concrete at the bentonite-concrete interface. Additionally, the host clay formation could also be affected by the hyperalkaline plume at the concrete-clay interface. Here we present a nonisothermal reactive transport model of the long-term interactions of the compacted bentonite with the corrosion products of a carbon-steel canister and the concrete liner of the engineered barrier of a high-level radioactive waste repository in clay. This problem involves large pH changes with a hyperalkaline high-pH plume, complex mineral dissolution/precipitation patterns, cation exchange reactions and proton surface complexation. These reactions lead to large changes in porosity which can even lead to pore clogging. Model results show that magnetite, the main corrosion product, precipitates and reduces significantly the porosity of the bentonite near the canister. The degradation of the concrete liner leads to the precipitation of secondary minerals and the reduction of the porosity of the bentonite and the clay formation at their interfaces with the concrete liner. The zones affected by pore clogging at the canister-bentonite, bentonite-concrete and concrete-clay interfaces at 1 Ma are equal to 10, 25 and 25 mm thick, respectively. The results of our simulations share many of the features of the models reported by others for engineered barrier systems at similar chemical conditions, including: 1) Narrow alteration zones; and 2) Pore clogging at the canister-bentonite, bentonite-concrete and concrete-clay