Quantitative determination of the mineral distribution in different collagen zones of calcifying tendon using high voltage electron microscopic tomography

NASA Technical Reports Server (NTRS)

McEwen, B. F.; Song, M. J.; Landis, W. J.

1991-01-01

High voltage electron microscopic tomography was used to make the first quantitative determination of the distribution of mineral between different regions of collagen fibrils undergoing early calcification in normal leg tendons of the domestic turkey, Meleagris gallopavo. The tomographic 3-D reconstruction was computed from a tilt series of 61 different views spanning an angular range of +/- 60 degrees in 2 degrees intervals. Successive applications of an interactive computer operation were used to mask the collagen banding pattern of either hole or overlap zones into separate versions of the reconstruction. In such 3-D volumes, regions specified by the mask retained their original image density while the remaining volume was set to background levels. This approach was also applied to the mineral crystals present in the same volumes to yield versions of the 3-D reconstructions that were masked for both the crystal mass and the respective collagen zones. Density profiles from these volumes contained a distinct peak corresponding only to the crystal mass. A comparison of the integrated density of this peak from each profile established that 64% of the crystals observed were located in the collagen hole zones and 36% were found in the overlap zones. If no changes in crystal stability occur once crystals are formed, this result suggests the possibilities that nucleation of mineral is preferentially and initially associated with the hole zones, nucleation occurs more frequently in the hole zones, the rate of crystal growth is more rapid in the hole zones, or a combination of these alternatives. All lead to the conclusion that the overall accumulation of mineral mass is predominant in the collagen hole zones compared to overlap zones during early collagen fibril calcification.

Rare-Earth Elements from Modern Mineral-Organic Associations in the Zone of Sulfide Ore Hypergenesis

NASA Astrophysics Data System (ADS)

Vakh, E. A.; Vakh, A. S.; Petukhov, V. I.; Barinov, N. N.

2018-01-01

The REE composition of modern mineral-organic associations in the sulfide ore hypergenesis zone of the Berezitovoe deposit in the Russian Far East was studied for the first time. It is shown that the mineral-organic associations widely abundant in the valley of Konstantinovskii Creek and represented by bright brown crusts on the surface of deluvial deposits were formed at the expense of the influence of acid highly mineralized mine waters from the Berezitovoe deposit. The mineral-organic associations found in the Creek valley may be considered as a new indicator for evaluation of the geoecological state of modern technogenic landscapes.

A Fourier Transform Infrared Spectroscopy Analysis of Carious Dentin from Transparent Zone to Normal Zone

PubMed Central

Liu, Y.; Yao, X.; Liu, Y.W.; Wang, Y.

2015-01-01

It is well known that caries invasion leads to the differentiation of dentin into zones with altered composition, collagen integrity and mineral identity. However, understanding of these changes from the fundamental perspective of molecular structure has been lacking so far. In light of this, the present work aims to utilize Fourier transform infrared spectroscopy (FTIR) to directly extract molecular information regarding collagen's and hydroxyapatite's structural changes as dentin transitions from the transparent zone (TZ) into the normal zone (NZ). Unembedded ultrathin dentin films were sectioned from carious teeth, and an FTIR imaging system was used to obtain spatially resolved FTIR spectra. According to the mineral-to-matrix ratio image generated from large-area low-spectral-resolution scan, the TZ, the NZ and the intermediate subtransparent zone (STZ) were identified. High-spectral-resolution spectra were taken from each zone and subsequently examined with regard to mineral content, carbonate distribution, collagen denaturation and carbonate substitution patterns. The integrity of collagen's triple helical structure was also evaluated based on spectra collected from demineralized dentin films of selected teeth. The results support the argument that STZ is the real sclerotic layer, and they corroborate the established knowledge that collagen in TZ is hardly altered and therefore should be reserved for reparative purposes. Moreover, the close resemblance between the STZ and the NZ in terms of carbonate content, and that between the STZ and the TZ in terms of being A-type carbonate-rich, suggest that the mineral that initially occludes dentin tubules is hydroxyapatite newly generated from odontoblastic activities, which is then transformed into whitlockite in the demineralization/remineralization process as caries progresses. PMID:24556607

A Fourier transform infrared spectroscopy analysis of carious dentin from transparent zone to normal zone.

PubMed

Liu, Y; Yao, X; Liu, Y W; Wang, Y

2014-01-01

It is well known that caries invasion leads to the differentiation of dentin into zones with altered composition, collagen integrity and mineral identity. However, understanding of these changes from the fundamental perspective of molecular structure has been lacking so far. In light of this, the present work aims to utilize Fourier transform infrared spectroscopy (FTIR) to directly extract molecular information regarding collagen's and hydroxyapatite's structural changes as dentin transitions from the transparent zone (TZ) into the normal zone (NZ). Unembedded ultrathin dentin films were sectioned from carious teeth, and an FTIR imaging system was used to obtain spatially resolved FTIR spectra. According to the mineral-to-matrix ratio image generated from large-area low-spectral-resolution scan, the TZ, the NZ and the intermediate subtransparent zone (STZ) were identified. High-spectral-resolution spectra were taken from each zone and subsequently examined with regard to mineral content, carbonate distribution, collagen denaturation and carbonate substitution patterns. The integrity of collagen's triple helical structure was also evaluated based on spectra collected from demineralized dentin films of selected teeth. The results support the argument that STZ is the real sclerotic layer, and they corroborate the established knowledge that collagen in TZ is hardly altered and therefore should be reserved for reparative purposes. Moreover, the close resemblance between the STZ and the NZ in terms of carbonate content, and that between the STZ and the TZ in terms of being A-type carbonate-rich, suggest that the mineral that initially occludes dentin tubules is hydroxyapatite newly generated from odontoblastic activities, which is then transformed into whitlockite in the demineralization/remineralization process as caries progresses. © 2014 S. Karger AG, Basel.

Development of a special approach of the mineralization localization zones prediction based on the combination and the geoinformation analysis of heterogeneous geodata

NASA Astrophysics Data System (ADS)

Ivanova, Julia

2014-05-01

The complexity of any task solving, including tasks in the Earth Sciences, depends on the completeness of the information that is available. The prediction of the mineralization zone localization is a task with incomplete information. The tasks of prediction are complicated because of search data difficult formalize, and the absent of single information structures of the representation of the search data. These facts complicate the process of structuring, processing and analysis of information. Geodata that need to process are presented in various formats: raster two-dimensional and three-dimensional fields, vector layers of polygons and lines, point markable layers, the spectral and discrete, quantized and continuous, analog and digital forms, as well as chemical formalization. In this form representative data cannot be combining into superclasses. At the same time the information content of geodata that are applied individually is very small. While a number of low informative features, which can be obtained in the process of research of mineralization zones are usually redundant. As a result the quality of knowledge that can be obtained from the search data decreases, as well as the technological cycle of information processing increases. Additionally, that leads to exploitation of datasets, and production of large shared datasets [1]. To solve efficiently the tasks of predicting, it is necessary to use union heterogeneous search features, accumulated factual data and modern science-based mathematical apparatus of processing and analysis of the information. As well young branches of human knowledge help to solve this task: remote sensing, geoinformatics, Earth and Space Science Informatics [2], apparatus of catastrophe theory and nonlinear dynamics, game theory. The purpose of the suggested approach is to increase informational content, and to reduce of geodata redundancy to improve the accuracy of the prediction of mineralization zones. The developed algorithm

Structural controls on Carlin-type gold mineralization in the gold bar district, Eureka County, Nevada

USGS Publications Warehouse

Yigit, O.; Nelson, E.P.; Hitzman, M.W.; Hofstra, A.H.

2003-01-01

The Gold Bar district in the southern Roberts Mountains, 48 km northwest of Eureka, Nevada, contains one main deposit (Gold Bar), five satellite deposits, and other resources. Approximately 0.5 Moz of gold have been recovered from a resource of 1,639,000 oz of gold in Carlin-type gold deposits in lower plate, miogeoclinal carbonate rocks below the Roberts Mountains thrust. Host rocks are unit 2 of the Upper Member of the Devonian Denay Formation and the Bartine Member of the McColley Canyon Formation. Spatial and temporal relations between structures and gold mineralization indicate that both pre-Tertiary and Tertiary structures were important controls on gold mineralization. Gold mineralization occurs primarily along high-angle Tertiary normal faults, some of which are reactivated reverse faults of Paleozoic or Mesozoic age. Most deposits are localized at the intersection of northwest- and northeast-striking faults. Alteration includes decalcification, and to a lesser extent, silicification along high-angle faults. Jasperoid (pervasive silicification), which formed along most faults and in some strata-bound zones, accounts for a small portion of the ore in every deposit. In the Gold Canyon deposit, a high-grade jasperoid pipe formed along a Tertiary normal fault which was localized along a zone of overturned fault-propagation folds and thrust faults of Paleozoic or Mesozoic age.

Integrated geophysical investigations for the delineation of source and subsurface structure associated with hydro-uranium anomaly: A case study from South Purulia Shear Zone (SPSZ), India

NASA Astrophysics Data System (ADS)

Sharma, S. P.; Biswas, A.

2012-12-01

South Purulia Shear Zone (SPSZ) is an important region for prospecting of uranium mineralization. Geological studies and hydro-uranium anomaly suggest the presence of Uranium deposit around Raghunathpur village which lies about 8 km north of SPSZ. However, detailed geophysical investigations have not been carried out in this region for investigation of uranium mineralization. Since surface signature of uranium mineralization is not depicted near the location, a deeper subsurface source is expected for hydro uranium anomaly. To delineate the subsurface structure and to investigate the origin of hydro-uranium anomaly present in the area, Vertical Electrical Sounding (VES) using Schlumberger array and Gradient Resistivity Profiling (GRP) were performed at different locations along a profile perpendicular to the South Purulia Shear Zone. Apparent resistivity computed from the measured sounding data at various locations shows a continuously increasing trend. As a result, conventional apparent resistivity data is not able to detect the possible source of hydro uranium anomaly. An innovative approach is applied which depicts the apparent conductivity in the subsurface revealed a possible connection from SPSZ to Raghunathpur. On the other hand resistivity profiling data suggests a low resistive zone which is also characterized by low Self-Potential (SP) anomaly zone. Since SPSZ is characterized by the source of uranium mineralization; hydro-uranium anomaly at Raghunathpur is connected with the SPSZ. The conducting zone has been delineated from SPSZ to Raghunathpur at deeper depths which could be uranium bearing. Since the location is also characterized by a low gravity and high magnetic anomaly zone, this conducting zone is likely to be mineralized zone. Keywords: Apparent resistivity; apparent conductivity; Self Potential; Uranium mineralization; shear zone; hydro-uranium anomaly.

Clay Mineral Crystal Structure Tied to Composition

NASA Image and Video Library

2016-12-13

This diagram illustrates how the dimensions of clay minerals' crystal structure are affected by which ions are present in the composition of the mineral. Different clay minerals were identified this way at two sites in Mars' Gale Crater: "Murray Buttes" and "Yellowknife Bay." In otherwise identical clay minerals, a composition that includes aluminum and ferric iron ions (red dots) results in slightly smaller crystalline unit cells than one that instead includes magnesium and ferrous iron ions (green dots). Ferric iron is more highly oxidized than ferrous iron. Crystalline cell units are the basic repeating building blocks that define minerals. X-ray diffraction analysis, a capability of the Chemistry and Mineralogy (CheMin) instrument on NASA's Curiosity Mars rover, identifies minerals from their crystalline structure. http://photojournal.jpl.nasa.gov/catalog/PIA21148

Field Integration of Worldview-3 as new Frontier of Mineral Exploration for Tropical Zone

NASA Astrophysics Data System (ADS)

Mahanta, P.; Maiti, S.

2017-12-01

Worldview-3 (WV-3) is a newly launched satellite program (2014) with total of 8 VNIR bands and 8 SWIR bands covering all possible absorption features of alteration minerals. Therefore integration of WV-3 dataset with conventional geological studies can be new frontier for mineral exploration. In the present study, we successfully accomplished that by identifying alteration mineral assemblage, field investigation, XRD, XRF and microscopic study etc. The chosen study area SPSZ, 120km long and 4-5km width corridor of highly sheared and deformed rock masses is unexplored in comparison to adjacent Singhbhum Shear Zone (SSZ). It demarcates the boundary between Proterozoic Chottanagpur Granite Gneissic Complex (CGGC) in north and Paleo proterozoic North Singhbhum Mobile belt (NSMB) in south. Discrete local studies indicated the presence of U, REE, Clay, Fe & Mn along with some Au and other polymetallic deposits of low concentration. Earlier attempts of remote sensing studies were hindered due to coarse spatial resolution, similarity between spectra of vegetation and alteration group of minerals like clay and mica, and lack of ground truthing with field spectra and laboratory analysis. Here involving WV-3, we identified and mapped alteration minerals kaolinite, montmorillonite, pyrophyllite, white mica, sericite, goethite, lemonite, hematite and quartz with better resolution and accuracy (78%). Further, field spectra and XRD analyses supports these results and confirm the presence of alterations. XRF analysis identified the presence of Cu (0.06±0.03), Ti (1.7±1), and V (0.03±0.02) anomaly pointing towards possible mineralization. Occurrences of alteration as vertically dipping and alternating with iron (red and black) and mica rich (white and gray) zones in hills as well as microscopic evidences of chloritization and sericitization of feldspars were collectively pointing towards their hydrothermal origin. Finally, we conclude that WV-3 will add a new direction to

Integrating gravity and magnetic field data to delineate structurally controlled gold mineralization in the Sefwi Belt of Ghana

NASA Astrophysics Data System (ADS)

Konadu Amoah, Bernard; Dadzie, Isaac; Takyi-Kyeremeh, Kwaku

2018-08-01

Gravity and magnetic surveys were used to delineate potential gold mineralization zones in the Sefwi belt of Ghana. The study area is an intrusive dominated area that hosts pockets of small scale mining operations locally referred to as Galamsey. These Galamsey operations are not guided by a scientific approach to back the trend of gold mineralization which is conventionally mined. The study aimed at mapping lithological units, structural setting and relating Galamsey sites to delineate potential zones of gold mineralization. A Scintrex CG5 gravimeter and GEM’s Overhauser magnetometer were used for gravity and magnetic data acquisition respectively. The magnetic data were corrected and enhancing filters such as reduction to the pole (RTP), analytical signal and first vertical derivative were applied using Oasis montaj 7.1. Gravity data were also reduced to the geoid using the Oasis montaj software to produce a complete Bouguer anomaly map. The regional/residual separation technique produced a residual gravity map. The RTP and analytical signal filters from the magnetic data and residual gravity anomaly map from the gravity data helped in mapping belt type (Dixcove) Birimian granitoids and mafic intrusive unit, interpreted as gabbro. The first vertical derivative filter was useful in mapping NE/SW minor faults and crosscutting dykes largely concentrated in the belt type Birimian granitoids. All the three mapped Galamsey sites fell on a minor fault and are associated with the belt type granitoids which were used in delineating four potential zones of gold mineralization.

To reactivate or not to reactivate: nature and varied behavior of structural inheritance in the Proterozoic basement of the Eastern Colorado mineral belt over 1.7 billion years of earth history

USGS Publications Warehouse

Caine, Jonathan S.; Ridley, John; Wessel, Zachary R.

2010-01-01

The eastern central Front Range of the Rocky Mountains in Colorado has long been a region of geologic interest because of Laramide-age hydrothermal polymetallic vein-related ores. The region is characterized by a well-exposed array of geologic structures associated with ductile and brittle deformation, which record crustal strain over 1.7 billion years of continental growth and evolution. The mineralized areas lie along a broad linear zone termed the Colorado Mineral Belt. This lineament has commonly been interpreted as following a fundamental boundary, such as a suture zone, in the North American Proterozoic crust that acted as a persistent zone of weakness localizing the emplacement of magmas and associated hydrothermal fluid flow. However, the details on the controls of the location, orientation, kinematics, density, permeability, and relative strength of various geological structures and their specific relationships to mineral deposit formation are not related to Proterozoic ancestry in a simple manner. The objectives of this field trip are to show key localities typical of the various types of structures present, show recently compiled and new data, offer alternative conceptual models, and foster dialogue. Topics to be discussed include: (1) structural history of the eastern Front Range; (2) characteristics, kinematics, orientations, and age of ductile and brittle structures and how they may or may not relate to one another and mineral deposit permeability; and (3) characteristics, localization, and evolution of the metal and non–metal-bearing hydrothermal systems in the eastern Colorado Mineral Belt.

A nearly water-saturated mantle transition zone inferred from mineral viscosity.

PubMed

Fei, Hongzhan; Yamazaki, Daisuke; Sakurai, Moe; Miyajima, Nobuyoshi; Ohfuji, Hiroaki; Katsura, Tomoo; Yamamoto, Takafumi

2017-06-01

An open question for solid-earth scientists is the amount of water in Earth's interior. The uppermost mantle and lower mantle contain little water because their dominant minerals, olivine and bridgmanite, have limited water storage capacity. In contrast, the mantle transition zone (MTZ) at a depth of 410 to 660 km is considered to be a potential water reservoir because its dominant minerals, wadsleyite and ringwoodite, can contain large amounts of water [up to 3 weight % (wt %)]. However, the actual amount of water in the MTZ is unknown. Given that water incorporated into mantle minerals can lower their viscosity, we evaluate the water content of the MTZ by measuring dislocation mobility, a property that is inversely proportional to viscosity, as a function of temperature and water content in ringwoodite and bridgmanite. We find that dislocation mobility in bridgmanite is faster by two orders of magnitude than in anhydrous ringwoodite but 1.5 orders of magnitude slower than in water-saturated ringwoodite. To fit the observed mantle viscosity profiles, ringwoodite in the MTZ should contain 1 to 2 wt % water. The MTZ should thus be nearly water-saturated globally.

Major Crustal Fault Zone Trends and Their Relation to Mineral Belts in the North-Central Great Basin, Nevada

USGS Publications Warehouse

Rodriguez, Brian D.; Sampson, Jay A.; Williams, Jackie M.

2007-01-01

The Great Basin physiographic province covers a large part of the western United States and contains one of the world's leading gold-producing areas, the Carlin Trend. In the Great Basin, many sedimentary-rock-hosted disseminated gold deposits occur along such linear mineral-occurrence trends. The distribution and genesis of these deposits is not fully understood, but most models indicate that regional tectonic structures play an important role in their spatial distribution. Over 100 magnetotelluric (MT) soundings were acquired between 1994 and 2001 by the U.S. Geological Survey to investigate crustal structures that may underlie the linear trends in north-central Nevada. MT sounding data were used to map changes in electrical resistivity as a function of depth that are related to subsurface lithologic and structural variations. Two-dimensional (2-D) resistivity modeling of the MT data reveals primarily northerly and northeasterly trending narrow 2-D conductors (1 to 30 ohm-m) extending to mid-crustal depths (5-20 km) that are interpreted to be major crustal fault zones. There are also a few westerly and northwesterly trending 2-D conductors. However, the great majority of the inferred crustal fault zones mapped using MT are perpendicular or oblique to the generally accepted trends. The correlation of strike of three crustal fault zones with the strike of the Carlin and Getchell trends and the Alligator Ridge district suggests they may have been the root fluid flow pathways that fed faults and fracture networks at shallower levels where gold precipitated in favorable host rocks. The abundant northeasterly crustal structures that do not correlate with the major trends may be structures that are open to fluid flow at the present time.

Application of gamma ray spectrometric measurements and VLF-EM data for tracing vein type uranium mineralization

NASA Astrophysics Data System (ADS)

Gaafar, Ibrahim

2015-12-01

This study is an attempt to use the gamma ray spectrometric measurements and VLF-EM data to identify the subsurface structure and map uranium mineralization along El Sela shear zone, South Eastern Desert of Egypt. Many injections more or less mineralized with uranium and associated with alteration processes were recorded in El Sela shear zone. As results from previous works, the emplacement of these injections is structurally controlled and well defined by large shear zones striking in an ENE-WSW direction and crosscut by NW-SE to NNW-SSE fault sets. VLF method has been applied to map the structure and the presence of radioactive minerals that have been delineated by the detection of high uranium mineralization. The electromagnetic survey was carried out to detect the presence of shallow and deep conductive zones that cross the granites along ENE-WSW fracturing directions and to map its spatial distribution. The survey comprised seventy N-S spectrometry and VLF-EM profiles with 20 m separation. The resulted data were displayed as composite maps for K, eU and eTh as well as VLF-Fraser map. Twelve profiles with 100 m separation were selected for detailed description. The VLF-EM data were interpreted qualitatively as well as quantitatively using the Fraser and the Karous-Hjelt filters. Fraser filtered data and relative current density pseudo-sections indicate the presence of shallow and deep conductive zones that cross the granites along ENE-WSW shearing directions. High uranium concentrations found just above the higher apparent current-density zones that coincide with El-Sela shear zone indicate a positive relation between conductivity and uranium minerals occurrence. This enables to infer that the anomalies detected by VLF-EM data are due to the highly conductive shear zone enriched with uranium mineralization extending for more than 80 m.

Radon exhalation and radiometric prospecting on rocks associated with Cu-U mineralizations in the Singhbhum shear zone, Bihar.

PubMed

Sengupta, D; Kumar, R; Singh, A K; Prasad, R

2001-12-01

The Singhbhum thrust belt is a 200 km long arcuate orogenic belt in Bihar, eastern India. The huge mineral resources, viz. copper, uranium, magnetite, apatite and molybdenite, etc., make it significant from an economic as well as a geological point of view. The belt hosts three types of mineralization: sulphides of copper and other metals, uranium oxides and apatite-magnetite. Several distinct geological episodes are responsible for the evolution of mineralization and the thrust zone itself. Extensive and reliable radiometric prospecting and assaying have been carried out by us for the past 5 years from Dhobani in the east to Turamdih in the west of the Singhbhum shear zone. The present work indicates uranium mineralization in the Pathargora-Rakha area presently being mined for copper and also within areas in the vicinity of Bhatin. Studies on radon emanation have also been undertaken in some parts of the shear zone which indicate reasonably high radon emanation of the soils and rocks studied. This suggests the need for regular monitoring and suitable controls on the mine environment (air quality) and its vicinity. Radon emanation studies coupled with gamma-ray spectrometry and the subsequent modelling of the radiometric and radon measurements will help in the application of radon as a geophysical tracer in exploration of radioactive ore bodies and in radon risk assessment as well as in delineating active and passive faults and even in petroleum exploration.

Structure of chitosan gels mineralized by sorption

NASA Astrophysics Data System (ADS)

Modrzejewska, Z.; Skwarczyńska, A.; Douglas, T. E. L.; Biniaś, D.; Maniukiewicz, W.; Sielski, J.

2015-10-01

The paper presents the structural studies of mineralized chitosan hydrogels. Hydrogels produced by using sodium beta-glycerophosphate (Na-β-GP) as a neutralizing agent. Mineralization was performed method "post loading", which consisted in sorption to the gels structure Ca ions. In order to obtain - in the structure of gels - compounds similar to the hydroxyapatites present naturally in bone tissue, gels after sorption were modified in: pH 7 buffer and sodium hydrogen phosphate. In order to determine the structural properties of the gels, the following methods were used: infrared spectroscopy with Fourier transformation, FTIR, X-ray diffractometry, XRD, scanning electron microscopy, SEM.

Structure of Masuleh Shear Zone: Evidence for Early–Middle Jurassic Dextral Shear Along Paleo-Tethys Suture Zone in the Western Alborz, NW Iran

NASA Astrophysics Data System (ADS)

Moosavi, E.; Rasouli-Jamadi, F.

2018-03-01

The Paleo-Tethys suture zone in northern Iran was formed when the Paleo-Tethys Ocean, (between Gonwana-derived Alborz Microcontinent and the Turan Plate), closed during the Eocimmerian orogeny and after they collided together in the Mid-Late Triassic. The NW-striking Boghrov-Dagh basement Fault Zone that lies in the vicinity of Masuleh village and the southern boundary of Gasht Metamorphic Complex is a part of the Eocimmerian suture zone in the Western Alborz. Along this part of the suture zone, tourmaline leucogranites intruded in metamorphic rocks. We recognize three distinct deformation stages (D1 to D3) in the study area especially in the Masuleh Shear Zone. D1 which was synchronous with formation of the main metamorphic minerals, such as sillimanite and staurolite under medium- to high-grade metamorphic conditions probably during the Hercynian event and a NE-directed shortening. The slaty cleavage in metamorphosed Upper Paleozoic rocks and crenulation cleavage and folds in the older rocks were produced due to D2 deformation during the Eocimmerian event under greenschist facies conditions. The Masuleh Shear Zone formed as a result of a ductile strike-slip shear during the Early-Middle Jurassic Mid-Cimmerian D3 event with a pure dextral to transtension shear sense at low to locally medium-grade conditions. All of the D3 structural features agree with a NNW-directed compression and an ENE-directed extension caused by overall dextral shear parallel to the Masuleh shear zone and the Boghrov-Dagh Fault Zone. Based on the available evidence, especially cross-cutting relationships between structural fabrics and rock units, emplacement of the Gasht-Masuleh leucogranites occurred after the D2 collisional event coeval to the possible slab break-off and before the D3 event, between Eocimmerian and Mid-Cimmerian movements.

Growth Oscillatory Zoning in Erythrite, Ideally Co3(AsO4)2·8H2O: Structural Variations in Vivianite-Group Minerals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Antao, Sytle M.; Dhaliwal, Inayat

The crystal structure of an oscillatory zoned erythrite sample from Aghbar mine, Bou Azzer, Morocco, was refined using synchrotron high-resolution powder X-ray diffraction (HRPXRD) data, Rietveld refinement, space group C2/m, and Z = 2. The crystal contains two sets of oscillatory zones that appear to have developed during epitaxial growth. The unit-cell parameters obtained are a = 10.24799(3) Å, b = 13.42490(7) Å, c = 4.755885(8) Å, β = 105.1116(3)°, and V = 631.680(4) Å3. The empirical formula for erythrite, obtained with electron-probe micro-analysis (EPMA), is [Co2.78Zn0.11Ni0.07Fe0.04]Σ3.00(AsO4)2·8H2O. Erythrite belongs to the vivianite-type structure that contains M1O2(H2O)4 octahedra and M22O6(H2O)4 octahedralmore » dimers that are linked by TO4 (T5+ = As or P) tetrahedra to form complex layers parallel to the (010) plane. These layers are connected by hydrogen bonds. The average [6] = 2.122(1) Å and average [6] = 2.088(1) Å. With space group C2/m, there are two solid solutions: M3(AsO4)2·8H2O and M3(PO4)2·8H2O where M2+ = Mg, Fe, Co, Ni, or Zn. In these As- and P-series, using data from this study and from the literature, we find that their structural parameters evolve linearly with V and in a nearly parallel manner despite of the large difference in size between P5+ (0.170 Å) and As5+ (0.355 Å) cations. Average [4], [6], and [6] distances increase linearly with V. The average distance is affected by M atoms, whereas the average distance is unaffected because it contains shorter and stronger P–O bonds. Although As- and P-series occur naturally, there is no structural reason why similar V-series vivianite-group minerals do not occur naturally or cannot be synthesized.« less

H2o Quantitative Analysis of Transition Zone Minerals Wadsleyite and Ringwoodite By Raman Spectroscopy

NASA Astrophysics Data System (ADS)

Novella, D.; Bolfan-Casanova, N.; Bureau, H.; Raepsaet, C.; Montagnac, G.

2014-12-01

Liquid H2O covers approximately 70% of the Earth's surface but it can also be incorporated as OH- groups in nominally anhydrous minerals (NAMs) that constitute the Earth's mantle, as observed in peridotitic xenoliths. The presence of even trace amounts (ppm wt) of hydrogen in mantle minerals strongly affect the physical, chemical and rheological properties of the mantle. The Earth's transition zone (410 to 660 km depth) is particularly important in this regard since it can store large amounts of H2O (wt%) as shown by experiments and recently by a natural sample. Addressing the behavior of H2O at high depths and its potential concentration in mantle NAMs is therefore fundamental to fully comprehend global-scale processes such as plate tectonics and magmatism. We developed an innovative technique to measure the H2O content of main transition zone NAMs wadsleyite and ringwoodite by Raman spectroscopy. This technique allows to use a beam of 1-3 µm size to measure small samples that are typical for high pressure natural and synthetic specimens. High pressure polyphasic samples are indeed very challenging to be measured in terms of H2O content by the routinely used Fourier transform infra-red (FTIR) spectroscopy and ion probe mass spectroscopy analyses, making the Raman approach a valid alternative. High quality crystals of wadsleyite and ringwoodite were synthesized at high pressure and temperature in a multi-anvil press and analyzed by Raman and FTIR spectroscopy as well as elastic recoil detection analyses (ERDA) which is an absolute, standard-free technique. We will present experimental data that allow to apply Raman spectroscopy to the determination of H2O content of the most abundant minerals in the transition zone. The data gathered in this study will also permit to investigate the absorption coefficients of wadsleyite and ringwoodite that are employed in FTIR quantitative analyses.

Parameters of microbial respiration in soils of the impact zone of a mineral fertilizer factory

NASA Astrophysics Data System (ADS)

Zhukova, A. D.; Khomyakov, D. M.

2015-08-01

The carbon content in the microbial biomass and the microbial production of CO2 (the biological component of soil respiration) were determined in the upper layer (0-10 cm) of soils in the impact zone of the OJSC Voskresensk Mineral Fertilizers, one of the largest factories manufacturing mineral fertilizers in Russia. Statistical characteristics and schematic distribution of the biological parameters in the soil cover of the impact zone were analyzed. The degree of disturbance of microbial communities in the studied objects varied from weak to medium. The maximum value (0.44) was observed on the sampling plot 4 km away from the factory and 0.5 km away from the place of waste (phosphogypsum) storage. Significantly lower carbon content in the microbial biomass and its specific respiration were recorded in the agrosoddy-podzolic soil as compared with the alluvial soil sampled at the same distance from the plant. The effects of potential soil pollutants (fluorine, sulfur, cadmium, and stable strontium) on the characteristics of soil microbial communities were described with reliable regression equations.

Minerals with metal-organic framework structures

PubMed Central

Huskić, Igor; Pekov, Igor V.; Krivovichev, Sergey V.; Friščić, Tomislav

2016-01-01

Metal-organic frameworks (MOFs) are an increasingly important family of advanced materials based on open, nanometer-scale metal-organic architectures, whose design and synthesis are based on the directed assembly of carefully designed subunits. We now demonstrate an unexpected link between mineralogy and MOF chemistry by discovering that the rare organic minerals stepanovite and zhemchuzhnikovite exhibit structures found in well-established magnetic and proton-conducting metal oxalate MOFs. Structures of stepanovite and zhemchuzhnikovite, exhibiting almost nanometer-wide and guest-filled apertures and channels, respectively, change the perspective of MOFs as exclusively artificial materials and represent, so far, unique examples of open framework architectures in organic minerals. PMID:27532051

Minerals with metal-organic framework structures.

PubMed

Huskić, Igor; Pekov, Igor V; Krivovichev, Sergey V; Friščić, Tomislav

2016-08-01

Metal-organic frameworks (MOFs) are an increasingly important family of advanced materials based on open, nanometer-scale metal-organic architectures, whose design and synthesis are based on the directed assembly of carefully designed subunits. We now demonstrate an unexpected link between mineralogy and MOF chemistry by discovering that the rare organic minerals stepanovite and zhemchuzhnikovite exhibit structures found in well-established magnetic and proton-conducting metal oxalate MOFs. Structures of stepanovite and zhemchuzhnikovite, exhibiting almost nanometer-wide and guest-filled apertures and channels, respectively, change the perspective of MOFs as exclusively artificial materials and represent, so far, unique examples of open framework architectures in organic minerals.

Impacts of Quaternary History on Critical Zone Structure and Processes: Examples and a Conceptual Model from the Intensively Managed Landscapes Critical Zone Observatory

NASA Astrophysics Data System (ADS)

Anders, Alison M.; Bettis, E. Arthur; Grimley, David A.; Stumpf, Andrew J.; Kumar, Praveen

2018-03-01

The concept of a critical zone (CZ) supporting terrestrial life has fostered groundbreaking interdisciplinary science addressing complex interactions among water, soil, rock, air and life near Earth’s surface. Pioneering work has focused on the CZ in areas with residual soils and steady-state or erosional topography. CZ evolution in these areas is conceptualized as progressive weathering of local bedrock (e.g. in the flow-through reactor model). However, this model is not applicable to areas in which weathering profiles form in transported materials including the formerly glaciated portion of the Central Lowland of North America. We present a new conceptual model of CZ evolution in landscapes impacted by continental glaciation based on investigations at three study sites in the Intensively Managed Landscapes Critical Zone Observatory (IML-CZO) The IML-CZO is devoted to the study of CZ processes in a region characterized by thick surficial deposits resulting from multiple continental glaciations, with bedrock at depths of up to 150 m. Here the physical (glacial ice, loess, developing soil profiles) and biological (microbes, tundra, forest, prairie) components of the CZ vary significantly in time. Moreover, the spatial relationships between mineral components of the CZ record a history of glacial-interglacial cycles and landscape evolution. We present cross-sections from IML-CZO sites to provide specific examples of how environmental change is recorded by the structure of the mineral components of the CZ. We build on these examples to create an idealized model of CZ evolution through a glacial cycle that represents the IML-CZO sites and other areas of low relief that have experienced continental glaciation. In addition, we identify two main characteristics of CZ structure which should be included in a conceptual model of CZ development in the IML-CZO and similar settings: (1) mineral components have diverse origins and transport trajectories including alteration in

Application of kinematic vorticity and gold mineralization for the wall rock alterations of shear zone at Dungash gold mining, Central Eastern Desert, Egypt

NASA Astrophysics Data System (ADS)

Kassem, Osama M. K.; Abd El Rahim, Said H.; El Nashar, EL Said R.; AL Kahtany, Kaled M.

2016-11-01

The use of porphyroclasts rotating in a flowing matrix to estimate mean kinematic vorticity number (Wm) is important for quantifying the relative contributions of pure and simple shear in wall rocks alterations of shear zone at Dungash gold mine. Furthermore, it shows the relationship between the gold mineralization and deformation and also detects the orientation of rigid objects during progressive deformation. The Dungash gold mine area is situated in an EW-trending quartz vein along a shear zone in metavolcanic and metasedimentary host rocks in the Eastern Desert of Egypt. These rocks are associated with the major geologic structures which are attributed to various deformational stages of the Neoproterozoic basement rocks. We conclude that finite strain in the deformed rocks is of the same order of magnitude for all units of metavolcano-sedimentary rocks. The kinematic vorticity number for the metavolcanic and metasedimentary samples in the Dungash area range from 0.80 to 0.92, and together with the strain data suggest deviations from simple shear. It is concluded that nappe stacking occurred early during the underthrusting event probably by brittle imbrication and that ductile strain was superimposed on the nappe structure during thrusting. Furthermore, we conclude that disseminated mineralization, chloritization, carbonatization and silicification of the wall rocks are associated with fluids migrating along shearing, fracturing and foliation of the metamorphosed wall rocks.

Preservation of Archaeal Surface Layer Structure During Mineralization

NASA Astrophysics Data System (ADS)

Kish, Adrienne; Miot, Jennyfer; Lombard, Carine; Guigner, Jean-Michel; Bernard, Sylvain; Zirah, Séverine; Guyot, François

2016-05-01

Proteinaceous surface layers (S-layers) are highly ordered, crystalline structures commonly found in prokaryotic cell envelopes that augment their structural stability and modify interactions with metals in the environment. While mineral formation associated with S-layers has previously been noted, the mechanisms were unconstrained. Using Sulfolobus acidocaldarius a hyperthermophilic archaeon native to metal-enriched environments and possessing a cell envelope composed only of a S-layer and a lipid cell membrane, we describe a passive process of iron phosphate nucleation and growth within the S-layer of cells and cell-free S-layer “ghosts” during incubation in a Fe-rich medium, independently of metabolic activity. This process followed five steps: (1) initial formation of mineral patches associated with S-layer; (2) patch expansion; (3) patch connection; (4) formation of a continuous mineral encrusted layer at the cell surface; (5) early stages of S-layer fossilization via growth of the extracellular mineralized layer and the mineralization of cytosolic face of the cell membrane. At more advanced stages of encrustation, encrusted outer membrane vesicles are formed, likely in an attempt to remove damaged S-layer proteins. The S-layer structure remains strikingly well preserved even upon the final step of encrustation, offering potential biosignatures to be looked for in the fossil record.

Integrative interactive visualization of crystal structure, band structure, and Brillouin zone

NASA Astrophysics Data System (ADS)

Hanson, Robert; Hinke, Ben; van Koevering, Matthew; Oses, Corey; Toher, Cormac; Hicks, David; Gossett, Eric; Plata Ramos, Jose; Curtarolo, Stefano; Aflow Collaboration

The AFLOW library is an open-access database for high throughput ab-initio calculations that serves as a resource for the dissemination of computational results in the area of materials science. Our project aims to create an interactive web-based visualization of any structure in the AFLOW database that has associate band structure data in a way that allows novel simultaneous exploration of the crystal structure, band structure, and Brillouin zone. Interactivity is obtained using two synchronized JSmol implementations, one for the crystal structure and one for the Brillouin zone, along with a D3-based band-structure diagram produced on the fly from data obtained from the AFLOW database. The current website portal (http://aflowlib.mems.duke.edu/users/jmolers/matt/website) allows interactive access and visualization of crystal structure, Brillouin zone and band structure for more than 55,000 inorganic crystal structures. This work was supported by the US Navy Office of Naval Research through a Broad Area Announcement administered by Duke University.

Mineral types of hydrothermal alteration zones in the Dukat ore field and their relationships to leucogranite and epithermal gold-silver ore, northeastern Russia

NASA Astrophysics Data System (ADS)

Filimonova, L. G.; Trubkin, N. V.; Chugaev, A. V.

2014-05-01

The paper considers the localization of potassic and propylitic hydrothermal alteration zones in the domal volcanic-plutonic structure controlling the position of the Dukat ore field with the eponymous unique epithermal Au-Ag deposit. Comprehensive mineralogical and geochemical data on rocks and minerals in hydrothermal alteration zones and associated intrusions have shown that quartz-jarosite-sericite, quartz-pyrite-sericite, and quartz-adularia-chlorite alterations were formed with the participation of fluid flows related to a fingerlike projection of a high-K leucogranite porphyry intrusion with large phenocrysts. These hydrothermal alterations developed in the rifted graben under conditions of divergent plate boundaries, whereas quartz-clinozoisite-calcite, epidote-chlorite, and garnet-calcite-chlorite alterations were linked to K-Na leucogranite intrusive bodies and developed under conditions of convergent plate boundaries reactivated as a result of formation of the marginal Okhotsk-Chukotka volcanic belt. Phase separation and coagulation of specific portions of ascending fluids resulted in the formation and stabilization of small-sized particles of native silver and other ore components, which enabled involvement in flows of secondary geothermal solutions and ore-forming fluids. The Sr, Nd, and Pb isotopic compositions of rocks and minerals from the hydrothermal alteration zones, associated intrusions, and economic orebodies at the Dukat deposit indicate that their components have been derived from the juvenile continental crust, which was altered in pre-Cretaceous periods of endogenic activity. The components of gangue minerals of potassic and propylitic hydrothertmal alterations and associated intrusions have been taken from deep sources differing in 87Sr/86Sr and 143Nd/144Nd at similar U/Pb and Th/Pb ratios. Chalcophile lead in products of hydrothermal activity and melanocratic inclusions in leucogranite has been taken from regions with elevated U/Pb and

Crystallographic control of surface structure on the sectoral zoning of iron in a diopside from Orford nickel mine (Quebec), Canada

NASA Astrophysics Data System (ADS)

Paquette, J.; Zangooi, A.; Thornton, K.

2004-05-01

The influence of surface structure on partitioning between mineral and melt (or solution) has been noted by other workers in a handful of minerals, including calcite, dolomite, apatite, topaz and diamond. Each one of these minerals displays at least one crystallographic face where steps present during crystal growth are not equivalent by symmetry. When this is the case, sectors grown at the edge of these steps commonly show differential incorporation of minor or trace elements. In the diopside investigated here, electron probe microanalyses performed on the as-grown (100) surface of several crystals show concentric and sectoral zoning defined by variations in Fe content. Atomic force microscopy (AFM) was used to study the surfaces of the three crystallographic forms present on the diopside crystals, with the goal of relating the compositional zoning to the surface structure of the faces. The dominant {100} faces are covered with growth hillocks consisting of four vicinal faces defined by steps parallel to [010] and [001]. The steps are often bunched into macrosteps and the resulting hillocks are visible optically. The steps along the two crystallographic directions show significant differences in straightness and smoothness that indicate non-equivalent kinetics. The wavier steps correspond to Fe-enriched areas within the {100} sectors. The {010} faces, next in morphological importance, are dominated by a single step orientation and show no differential incorporation. They display topography related to polysynthetic twinning. The {110} faces are much smaller and very few show resolvable steps. Sector zoning (i.e. diffential partitioning among non-equivalent crystallographic faces) has been described in the past from pyroxenes. Explanations have invoked either differences in surface structure among non-equivalent faces or their unequal growth rates. This particular occurrence indicates that trace element incorporation is, in fact, highly site-specific and that

Remote sensing of geologic mineral occurrences for the Colorado mineral belt using LANDSAT data

NASA Technical Reports Server (NTRS)

Carpenter, R. H. (Principal Investigator); Trexler, D. W.

1976-01-01

The author has identified the following significant results. LANDSAT imagery was examined as a practical and productive tool for mineral exploration along the Colorado Mineral Belt. An attempt was made to identify all large, active and/or abandoned mining districts on the imagery which initially were discovered by surface manifestations. A number of strong photolinements, circular features, and color anomalies were identified. Some of these form a part of the structural and igneous volcanic framework in which mineral deposits occur. No specific mineral deposits such as veins or porphyries were identified. Promising linear and concentric features were field checked at several locations. Some proved to be fault zones and calderas; others were strictly topographic features related to stream or glacial entrenchment. The Silverton Caldera region and the Idaho Springs-Central City district were chosen and studied as case histories to evaluate the application of LANDSAT imagery to mineral exploration. Evidence of specific mineralization related to ore deposits in these two areas were observed only on low level photography.

Hydrothermal mineralization at seafloor spreading centers

NASA Astrophysics Data System (ADS)

Rona, Peter A.

1984-01-01

The recent recognition that metallic mineral deposits are concentrated by hydrothermal processes at seafloor spreading centers constitutes a scientific breakthrough that opens active sites at seafloor spreading centers as natural laboratories to investigate ore-forming processes of such economically useful deposits as massive sulfides in volcanogenic rocks on land, and that enhances the metallic mineral potential of oceanic crust covering two-thirds of the Earth both beneath ocean basins and exposed on land in ophiolite belts. This paper reviews our knowledge of processes of hydrothermal mineralization and the occurrence and distribution of hydrothermal mineral deposits at the global oceanic ridge-rift system. Sub-seafloor hydrothermal convection involving circulation of seawater through fractured rocks of oceanic crust driven by heat supplied by generation of new lithosphere is nearly ubiquitous at seafloor spreading centers. However, ore-forming hydrothermal systems are extremely localized where conditions of anomalously high thermal gradients and permeability increase hydrothermal activity from the ubiquitous low-intensity background level (⩽ 200°C) to high-intensity characterized by high temperatures ( > 200-c.400°C), and a rate and volume of flow sufficient to sustain chemical reactions that produce acid, reducing, metal-rich primary hydrothermal solutions. A series of mineral phases with sulfides and oxides as high- and low-temperature end members, respectively, are precipitated along the upwelling limb and in the discharge zone of single-phase systems as a function of increasing admixture of normal seawater. The occurrence of hydrothermal mineral deposits is considered in terms of spatial and temporal frames of reference. Spatial frames of reference comprise structural features along-axis (linear sections that are the loci of seafloor spreading alternating with transform faults) and perpendicular to axis (axial zone of volcanic extrusion and marginal

Demarcation of mineral rich zones in areas adjoining to a copper prospect in Rajasthan, India using ASTER, DEM (ALOS) and spaceborne gravity data

NASA Astrophysics Data System (ADS)

Sengar, Vivek K.; Champati Ray, P. K.; Chattoraj, Shovan L.; Venkatesh, A. S.; Sajeev, R.; Konwar, Purnima; Thapa, Shailaja

2017-10-01

The objective of this work is to identify the potential zones for detailed mineral exploration studies in areas adjoining to a copper prospect using Remotely Sensed data sets. In this study visualization of ASTER data has been enhanced to highlight the mineral-rich areas using various remote sensing techniques such as colour composites and band ratios. VNIR region of ASTER is significant to detect iron oxides while, clay minerals, carbonates and chlorites have characteristic absorption in the SWIR wavelength region. Therefore, an attempt has been made to target the mineral abundant regions through ASTER data processing. Height based information was extracted using high-resolution ALOSDEM to analyse the topographical controls in the region considering the fact that mineral deposits often found associated with geological structures and geomorphological units. Gravity data was used to generate gravity anomaly map which gives clues about subsurface density differences. In this context, base metal ores may show anomalous (high) gravity values in comparison to the non-mineralised areas. Outputs from all the data sets were analysed and correlated with the geological map and available literature. Final validation of results has been done through proper ground checks and laboratory analysis of rock samples collected from the litho-units present in the study area. Based on this study some new areas have been successfully demarcated which may be potential for base metal exploration.

Accessory minerals and subduction zone metasomatism: a geochemical comparison of two mélanges (Washington and California, U.S.A.)

USGS Publications Warehouse

Sorensen, Sorena S.; Grossman, Jeffrey N.

1993-01-01

Data from the Gee Point and Catalina mélanges suggest that the accessory minerals titanite, rutile, apatite, zircon and REE-rich epidote play a significant role in the enrichment of trace elements in both mafic and ultramafic rocks during subduction-related fluid-rock interaction. Mobilization of incompatible elements, and deposition of such elements in the accessory minerals of mafic and ultramafic rocks may be fairly common in fluid-rich metamorphic environments in subduction zones.

Physical heterogeneity control on effective mineral dissolution rates

NASA Astrophysics Data System (ADS)

Jung, Heewon; Navarre-Sitchler, Alexis

2018-04-01

Hydrologic heterogeneity may be an important factor contributing to the discrepancy in laboratory and field measured dissolution rates, but the governing factors influencing mineral dissolution rates among various representations of physical heterogeneity remain poorly understood. Here, we present multiple reactive transport simulations of anorthite dissolution in 2D latticed random permeability fields and link the information from local grid scale (1 cm or 4 m) dissolution rates to domain-scale (1m or 400 m) effective dissolution rates measured by the flux-weighted average of an ensemble of flow paths. We compare results of homogeneous models to heterogeneous models with different structure and layered permeability distributions within the model domain. Chemistry is simplified to a single dissolving primary mineral (anorthite) distributed homogeneously throughout the domain and a single secondary mineral (kaolinite) that is allowed to dissolve or precipitate. Results show that increasing size in correlation structure (i.e. long integral scales) and high variance in permeability distribution are two important factors inducing a reduction in effective mineral dissolution rates compared to homogeneous permeability domains. Larger correlation structures produce larger zones of low permeability where diffusion is an important transport mechanism. Due to the increased residence time under slow diffusive transport, the saturation state of a solute with respect to a reacting mineral approaches equilibrium and reduces the reaction rate. High variance in permeability distribution favorably develops large low permeability zones that intensifies the reduction in mixing and effective dissolution rate. However, the degree of reduction in effective dissolution rate observed in 1 m × 1 m domains is too small (<1% reduction from the corresponding homogeneous case) to explain several orders of magnitude reduction observed in many field studies. When multimodality in permeability

Protein–Mineral Interactions: Molecular Dynamics Simulations Capture Importance of Variations in Mineral Surface Composition and Structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andersen, Amity; Reardon, Patrick N.; Chacon, Stephany S.

Molecular dynamics simulations, conventional and metadynamics, were performed to determine the interaction of model protein Gb1 over kaolinite (001), Na+-montmorillonite (001), Ca2+-montmorillonite (001), goethite (100), and Na+-birnessite (001) mineral surfaces. Gb1, a small (56 residue) protein with a well-characterized solution-state nuclear magnetic resonance (NMR) structure and having α-helix, four-fold β-sheet, and hydrophobic core features, is used as a model protein to study protein soil mineral interactions and gain insights on structural changes and potential degradation of protein. From our simulations, we observe little change to the hydrated Gb1 structure over the kaolinite, montmorillonite, and goethite surfaces relative to its solvatedmore » structure without these mineral surfaces present. Over the Na+-birnessite basal surface, however, the Gb1 structure is highly disturbed as a result of interaction with this birnessite surface. Unraveling of the Gb1 β-sheet at specific turns and a partial unraveling of the α-helix is observed over birnessite, which suggests specific vulnerable residue sites for oxidation or hydrolysis possibly leading to fragmentation.« less

General overview on structure prediction of twilight-zone proteins.

PubMed

Khor, Bee Yin; Tye, Gee Jun; Lim, Theam Soon; Choong, Yee Siew

2015-09-04

Protein structure prediction from amino acid sequence has been one of the most challenging aspects in computational structural biology despite significant progress in recent years showed by critical assessment of protein structure prediction (CASP) experiments. When experimentally determined structures are unavailable, the predictive structures may serve as starting points to study a protein. If the target protein consists of homologous region, high-resolution (typically <1.5 Å) model can be built via comparative modelling. However, when confronted with low sequence similarity of the target protein (also known as twilight-zone protein, sequence identity with available templates is less than 30%), the protein structure prediction has to be initiated from scratch. Traditionally, twilight-zone proteins can be predicted via threading or ab initio method. Based on the current trend, combination of different methods brings an improved success in the prediction of twilight-zone proteins. In this mini review, the methods, progresses and challenges for the prediction of twilight-zone proteins were discussed.

Microstructural and mineral analysis on the fault gouge in the coseismic shear zone of the 2008 M w 7.9 Wenchuan earthquake

NASA Astrophysics Data System (ADS)

Yuan, Ren-mao; Zhang, Bing-liang; Xu, Xi-wei; Lin, Chuan-yong; Han, Zhu-jun

2015-07-01

The 2008 M w 7.9 Wenchuan earthquake formed two coseismic surface rupture zones with the trend of N35°E, known as the Beichuan-Yingxiu rupture and the Pengguan rupture. The Beichuan-Yingxiu rupture is the principle one with abundant fault gouge development along its length. In the exploratory trench at the Saba village along the Beichuan-Yingxiu rupture, the new fault gouge zone is only ~3 mm wide, which suggests that fault slip was constrained in a very narrow zone. In this study, we thus carried out detailed microstructural and mineral component analysis on the oriented fault gouge samples from the Saba exploratory trench to understand their features and geological implication. The results show that different microstructures of localized brittle deformation can be observed in the fault gouges, including Y-shear, R1-shear, R2-shear, P-shear as well as tension fracture, bookshelf glided structure and so on. These microstructures are commonly recognized as the product of seismic fault slipping. Furthermore, within the area between two parallel Y-shears of the fault gouge, a few of microstructures of distributed ductile deformations were developed, such as P-foliation, elongation and asymmetrical trailing structure of detrital particles. The microstructure features of fault gouges implicate the thrust movement of the fault during the Wenchuan earthquake. In addition, the fault gouge has less quartz and feldspar and more clay than the surrounding rocks, which indicates that some quartz and feldspar in the surrounding rocks were transformed into clay, whereas the fault gouge has more illite and less illite/montmorillonite mixed layers than the surrounding rocks, which shows that the illite/montmorillonite mixed layer was partly converted into illite due to temperature increasing induced by coseismic fault slipping friction (also being affected partly by the chemical action of solutions). Such microstructures features and mineral component changes recorded the

Evidence for a Battle Mountain-Eureka crustal fault zone, north-central Nevada, and its relation to Neoproterozoic-Early Paleozoic continental breakup

USGS Publications Warehouse

Grauch, V.J.S.; Rodriguez, B.D.; Bankey, V.; Wooden, J.L.

2003-01-01

Combined evidence from gravity, radiogenic isotope, and magnetotelluric (MT) data indicates a crustal fault zone that coincides with the northwest-trending Battle Mountain-Eureka (BME) mineral trend in north-central Nevada, USA. The BME crustal fault zone likely originated during Neoproterozoic-Early Paleozoic rifting of the continent and had a large influence on subsequent tectonic events, such as emplacement of allochthons and episodic deformation, magmatism, and mineralization throughout the Phanerozoic. MT models show the fault zone is about 10 km wide, 130-km long, and extends from 1 to 5 km below the surface to deep crustal levels. Isotope data and gravity models imply the fault zone separates crust of fundamentally different character. Geophysical evidence for such a long-lived structure, likely inherited from continental breakup, defies conventional wisdom that structures this old have been destroyed by Cenozoic extensional processes. Moreover, the coincidence with the alignment of mineral deposits supports the assertion by many economic geologists that these alignments are indicators of buried regional structures.

Clay Mineral Structure Similar to Clays Observed in Mudstone on Mars

NASA Image and Video Library

2013-12-09

This schematic shows the atomic structure of the smallest units that make up the layers and interlayer region of clay minerals. This structure is similar to the clay mineral in drilled rock powder collected by NASA Curiosity Mars rover.

Clay minerals related to the circulation of geothermal fluids in boreholes at Rittershoffen (Alsace, France)

NASA Astrophysics Data System (ADS)

Vidal, Jeanne; Patrier, Patricia; Genter, Albert; Beaufort, Daniel; Dezayes, Chrystel; Glaas, Carole; Lerouge, Catherine; Sanjuan, Bernard

2018-01-01

Two geothermal wells, GRT-1 and GRT-2, were drilled into the granite at Rittershoffen (Alsace, France) in the Upper Rhine Graben to exploit geothermal resources at the sediment-basement interface. Brine circulation occurs in a permeable fracture network and leads to hydrothermal alteration of the host rocks. The goal of the study was to characterize the petrography and mineralogy of the altered rocks with respect to the permeable fracture zones in the granitic basement. As clay minerals are highly reactive to hydrothermal alteration, they can be used as indicators of present-day and paleo-circulation systems. Special attention has been paid to the textural, structural and chemical properties of these minerals. The fine-grained clay fraction (< 5 μm) was analyzed around the originally permeable fracture zones to observe the crystal structure of clay minerals using X-ray diffraction. Chemical microanalysis of the clay minerals was performed using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy. The occurrences of mixed layers illite-smectite ( 10% smectite) provide a promising guide for identifying the fracture zones that control the present-day circulation of geothermal fluids in the Rittershoffen wells. However, multistage paleo-circulation systems could lead to an abundance of heterogeneous and fine-grained illitic minerals that could plug the fracture system. The permeability of fracture zones in the GRT-1 well was likely reduced because of an intense illitization, and the well was stimulated. The occurrence of chlorite in the permeable fracture zones of GRT-2 is indicative of less intense illitization, and the natural permeability is much higher in GRT-2 than in GRT-1.

Nanoscale Structure at Mineral-Fluid Interfaces

NASA Astrophysics Data System (ADS)

Sturchio, N. C.; Sturchio, N. C.; Fenter, P.; Cheng, L.; Park, C.; Zhang, Z.; Zhang, Z.; Nagy, K. L.; Schlegel, M. L.

2001-12-01

The nature of nanoparticles and their role in the natural environment is currently a subject of renewed interest. The high surface area (and surface area-to-volume ratio) of nanoparticles exerts a widespread influence on geochemical reactions and transport processes. A thorough understanding of the nanoscale world remains largely hypothetical, however, because of the challenges associated with characterizing nanoscale structures and processes. Recent insights gained from high-resolution synchrotron x-ray reflectivity measurements at the solid-fluid interfaces of macroscopic (i.e., mm-scale) mineral particles may provide relevant guidelines for expected nanoparticle surface structures. For example, at calcite-water and barite-water interfaces, undercoordinated surface cations bond with water species of variable protonation, and modest relaxations (to several hundredths of a nanometer) affect the outermost unit cells [1,2]. Undercoordinated tetrahedral ions at aluminosilicate surfaces also bond with water species, whereas interstitial or interlayer alkali or alkaline earth ions at the surface may readily exchange with hydronium or other ions; modest relaxations also affect the outermost unit cells [3,4]. Modulation of liquid water structure out to about one nanometer has been observed at the (001) cleavage surface of muscovite in deionized water, and may be present at other mineral-fluid interfaces [4]. Dissolution mechanisms at the orthoclase-water interface have been clarified by combining x-ray reflectivity and scanning force microscopy measurements [5]. Further progress in understanding nanoscale structures and processes at macroscopic mineral-water interfaces is likely to benefit nanoparticle studies. [1] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 1221-1228. [2] Fenter et al. (2001) J. Phys. Chem. B 105(34), 8112-8119. [3] Fenter et al. (2000) Geochim. Cosmochim. Acta 64, 3663-3673. [4] Cheng et al. (2001) Phys. Rev. Lett., (in press). [5] Teng et al

Incompletely Mixed Surface Transient Storage Zones at River Restoration Structures: Modeling Implications

NASA Astrophysics Data System (ADS)

Endreny, T. A.; Robinson, J.

2012-12-01

River restoration structures, also known as river steering deflectors, are designed to reduce bank shear stress by generating wake zones between the bank and the constricted conveyance region. There is interest in characterizing the surface transient storage (STS) and associated biogeochemical processing in the STS zones around these structures to quantify the ecosystem benefits of river restoration. This research explored how the hydraulics around river restoration structures prohibits application of transient storage models designed for homogenous, completely mixed STS zones. We used slug and constant rate injections of a conservative tracer in a 3rd order river in Onondaga County, NY over the course of five experiments at varying flow regimes. Recovered breakthrough curves spanned a transect including the main channel and wake zone at a j-hook restoration structure. We noted divergent patterns of peak solute concentration and times within the wake zone regardless of transect location within the structure. Analysis reveals an inhomogeneous STS zone which is frequently still loading tracer after the main channel has peaked. The breakthrough curve loading patterns at the restoration structure violated the assumptions of simplified "random walk" 2 zone transient storage models which seek to identify representative STS zones and zone locations. Use of structure-scale Weiner filter based multi-rate mass transfer models to characterize STS zones residence times are similarly dependent on a representative zone location. Each 2 zone model assumes 1 zone is a completely mixed STS zone and the other a completely mixed main channel. Our research reveals limits to simple application of the recently developed 2 zone models, and raises important questions about the measurement scale necessary to identify critical STS properties at restoration sites. An explanation for the incompletely mixed STS zone may be the distinct hydraulics at restoration sites, including a constrained

Performance analysis of mineral mapping method to delineate mineralization zones under tropical region

NASA Astrophysics Data System (ADS)

Wakila, M. H.; Saepuloh, A.; Heriawan, M. N.; Susanto, A.

2016-09-01

Geothermal explorations and productions are currently being intensively conducted at certain areas in Indonesia such as Wayang Windu Geothermal Field (WWGF) in West Java, Indonesia. The WWGF is located at wide area covering about 40 km2. An accurate method to map the distribution of heterogeneity minerals is necessary for wide areas such as WWGF. Mineral mapping is an important method in geothermal explorations to determine the distribution of minerals which indicate the surface manifestations of geothermal system. This study is aimed to determine the most precise and accurate methods for minerals mapping at geothermal field. Field measurements were performed to assess the accuracy of three proposed methods: 1) Minimum Noise Fraction (MNF), utilizing the linear transformation method to eliminate the correlation among the spectra bands and to reduce the noise in the data, 2) Pixel Purity Index (PPI), a designed method to find the most extreme spectrum pixels and their characteristics due to end-members mixing, 3) Spectral Angle Mapper (SAM), an image classification technique by measuring the spectral similarity between an unknown object with spectral reference in n- dimension. The output of those methods were mineral distribution occurrence. The performance of each mapping method was analyzed based on the ground truth data. Among the three proposed method, the SAM classification method is the most appropriate and accurate for mineral mapping related to spatial distribution of alteration minerals.

Probing the Detailed Seismic Velocity Structure of Subduction Zones Using Advanced Seismic Tomography Methods

NASA Astrophysics Data System (ADS)

Zhang, H.; Thurber, C. H.

2005-12-01

Subduction zones are one of the most important components of the Earth's plate tectonic system. Knowing the detailed seismic velocity structure within and around subducting slabs is vital to understand the constitution of the slab, the cause of intermediate depth earthquakes inside the slab, the fluid distribution and recycling, and tremor occurrence [Hacker et al., 2001; Obara, 2002].Thanks to the ability of double-difference tomography [Zhang and Thurber, 2003] to resolve the fine-scale structure near the source region and the favorable seismicity distribution inside many subducting slabs, it is now possible to characterize the fine details of the velocity structure and earthquake locations inside the slab, as shown in the study of the Japan subduction zone [Zhang et al., 2004]. We further develop the double-difference tomography method in two aspects: the first improvement is to use an adaptive inversion mesh rather than a regular inversion grid and the second improvement is to determine a reliable Vp/Vs structure using various strategies rather than directly from Vp and Vs [see our abstract ``Strategies to solve for a better Vp/Vs model using P and S arrival time'' at Session T29]. The adaptive mesh seismic tomography method is based on tetrahedral diagrams and can automatically adjust the inversion mesh according to the ray distribution so that the inversion mesh nodes are denser where there are more rays and vice versa [Zhang and Thurber, 2005]. As a result, the number of inversion mesh nodes is greatly reduced compared to a regular inversion grid with comparable spatial resolution, and the tomographic system is more stable and better conditioned. This improvement is quite valuable for characterizing the fine structure of the subduction zone considering the highly uneven distribution of earthquakes within and around the subducting slab. The second improvement, to determine a reliable Vp/Vs model, lies in jointly inverting Vp, Vs, and Vp/Vs using P, S, and S

Discrimination between mineralized and unmineralized alteration zones using primary geochemical haloes in the Darreh-Zar porphyry copper deposit in Kerman, southeastern Iran

NASA Astrophysics Data System (ADS)

Parsapoor, A.; Khalili, M.; Maghami, M.

2017-08-01

Primary geochemical haloes were studied at the Darreh-Zar porphyry Cu-deposit, southern Iran. In terms of geochemical signatures, high K2O/Na2O enrichment, HREEs and HFSE's depletion in the potassic alteration, high (La/Sm)cn, (La/Yb)cn and (Gd/Yb)cn ratios in mineralized sericitic and potassic zones and notable depletion in the REEs content in argillic alteration is recognized. Further, Mg, Li, Sc, P enrichment and W depletion can serve to separate potassic alteration from the other altered zones, while (Eu/Eu*)cn and (Ce/Ce*)cn don't show pronounced changes in different alteration zones. The coupled positive Tl, Se, S, Rb, Co, Cs, Mo, K and negative Te, Ta, Ti, Sr, Rb, As, Bi, Ga, Hf, In, Mn, Zn and Zr anomalies can be adequately used in discriminating between the mineralized zones (potassic, chlorite-sericite and sericite alterations) and the barren (propylitic zone). The behavior of the trace elements on isocon diagrams reveal that HFSEs are depleted in mineralized altered zones and display variations in the amounts in the barren facies. Zonality index in the axial direction from drill holes 146 to 124 estimates the zonality sequence as Pb-Zn-Ag-Cu-Pb-Zn in the surface horizons. The calculated zonality in five drill holes and six levels indicates that the level of 550 m at the DH 117 in the central part of the area has the highest value (0.76) for Cu. The zonality sequence from the surface to the depth is variable and can be demonstrated as follow: DH 146: Pb-Zn-Cu-Mo-Ag; DH 137: Zn-Cu-Mo-Pb-Ag; DH 117: Ag-Zn-Pb-Mo-Cu; DH: 121: Cu-Mo-Zn-Ag-Pb; DH 136: Pb-Ag-Zn-Cu-Mo; DH 124: Zn-Mo-Cu-Pb-Ag. Available data of the enrichment factors shows different enrichment for copper and molybdenum (i.e. EF > 10), selenium and silver (i.e. EF > 5), tin and LREEs (i.e. 1 < EF < 5).

The Genesis of tectonically and hydrothermally controlled industry mineral deposits: A geochemical and structural study

NASA Astrophysics Data System (ADS)

Wölfler, Anke; Prochaska, Walter; Henjes-Kunst, Friedhelm; Fritz, Harald

2010-05-01

The study aims to investigate the role of hydrothermal fluids in the formation of talc and magnesite deposits. These deposits occur in manifold geological and tectonical settings such as stockworks and veins within ultramafite hostrocks and monomineralic lenses within marine platform sediments. Along shear zones talc mineralizations may occur as a result of tectonical and hydrothermal activity. To understand the role of the fluids for the genesis of the mineralization, deposits in different geological and tectonical settings are investigated: Talc mineralization within in magnesite in low-grade palaeozoic nappe complexes (Gemerska Poloma, Slovakia): The magnesite body lies within the Gemer unit of the Inner Carpathians consisting of Middle Triassic metacarbonates and Upper Triassic pelagic limestones and radiolarites. The talc mineralization is bound to crosscutting veins. Two metamorphic events can be distinguished, one during Variscan orogeny and one related to the Alpine orogeny leading to the formation of talc along faults in an Mg carbonate body (Radvanec et al, 2004).The origin of the fluids as well as the tectonic events leading to the mineralization is still widely unknown. Talc mineralization in shearzones within Palaeozoic meta sedimentary rocks (Sa Matta, Sardinia): Variscan granitoids intruded Palaeozoic meta sedimentary rocks and were overprinted be NE striking tectonic structures that host talc mineralizations. The origin of Mg and fluids leading to the mineralization is still not answered satisfactorily (Grillo and Prochaska, 2007) and thus a tectonic model for the genesis of the talc deposit is missing. Talc mineralization within UHP pre-Alpine continental crust (Val Chisone, Italy): The talc deposit forms part of the Dora-Maira Massif. Geologicaly the massif derived from a Variscan basement that includes post-Variscan intrusions. The talc mineralization occurs as a sheetlike, conformable body. A possible tectonic emplacement of talc along shear

An integrated monitoring network for hydrologic, geochemical, and sediment fluxes to characterize carbon-mineral fate in the Christina River Basin Critical Zone Observatory

NASA Astrophysics Data System (ADS)

Sawyer, A. H.; Karwan, D. L.; Lazareva, O.

2011-12-01

Organic carbon (C) -mineral complexation mechanism plays an important role in C sequestration within watersheds. The primary goal of the Christina River Basin Critical Zone Observatory in SE Pennsylvania and N Delaware, USA (one of six National Science Foundation-funded observatories) is to quantify net carbon sink or source due to mineral production and transport and its dependence on land use. This effort requires an interdisciplinary understanding of carbon and mineral fluxes across interfaces between soil, aquifer, floodplain, and river. We have established a monitoring network that targets hydrologic, geochemical, and sedimentological transport processes across channel-floodplain-aquifer interfaces within White Clay Creek Watershed. Within the channel, suspended material is sampled and analyzed for organic and mineral composition as well as geochemical fingerprints. Surface water and groundwater are analyzed for C, Fe, and Mn chemistry. Within the floodplain, in-situ sensors monitor soil moisture, pressure, temperature, conductivity, and redox potential. Integrated data analysis should yield estimates of water and solute fluxes between the vadose zone, riparian aquifer, and stream. Our preliminary data show that storm events are important for carbon and mineral fluxes-suspended material in surface water changes in source and composition throughout the storm. Meanwhile, the variation in stream stage drives surface water-groundwater exchange, facilitating changes in redox potential and providing opportunity for enhanced transport and reactions involving C, Fe, and Mn in the riparian aquifer.

Introduction to the structures and processes of subduction zones

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhao, Zi-Fu

2017-09-01

Subduction zones have been the focus of many studies since the advent of plate tectonics in 1960s. Workings within subduction zones beneath volcanic arcs have been of particular interest because they prime the source of arc magmas. The results from magmatic products have been used to decipher the structures and processes of subduction zones. In doing so, many progresses have been made on modern oceanic subduction zones, but less progresses on ancient oceanic subduction zones. On the other hand, continental subduction zones have been studied since findings of coesite in metamorphic rocks of supracrustal origin in 1980s. It turns out that high-pressure to ultrahigh-pressure metamorphic rocks in collisional orogens provide a direct target to investigate the tectonism of subduction zones, whereas oceanic and continental arc volcanic rocks in accretionary orogens provide an indirect target to investigate the geochemistry of subduction zones. Nevertheless, metamorphic dehydration and partial melting at high-pressure to ultrahigh-pressure conditions are tectonically applicable to subduction zone processes at forearc to subarc depths, and crustal metasomatism is the physicochemical mechanism for geochemical transfer from the slab to the mantle in subduction channels. Taken together, these provide us with an excellent opportunity to find how the metamorphic, metasomatic and magmatic products are a function of the structures and processes in both oceanic and continental subduction zones. Because of the change in the thermal structures of subduction zones, different styles of metamorphism, metasomatism and magmatism are produced at convergent plate margins. In addition, juvenile and ancient crustal rocks have often suffered reworking in episodes independent of either accretionary or collisional orogeny, leading to continental rifting metamorphism and thus rifting orogeny for mountain building in intracontinental settings. This brings complexity to distinguish the syn

Introduction to the structures and processes of subduction zones

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhao, Zi-Fu

2017-09-01

Subduction zones have been the focus of many studies since the advent of plate tectonics in 1960s. Workings within subduction zones beneath volcanic arcs have been of particular interest because they prime the source of arc magmas. The results from magmatic products have been used to decipher the structures and processes of subduction zones. In doing so, many progresses have been made on modern oceanic subduction zones, but less progresses on ancient oceanic subduction zones. On the other hand, continental subduction zones have been studied since findings of coesite in metamorphic rocks of supracrustal origin in 1980s. It turns out that high-pressure to ultrahigh-pressure metamorphic rocks in collisional orogens provide a direct target to investigate the tectonism of subduction zones, whereas oceanic and continental arc volcanic rocks in accretionary orogens provide an indirect target to investigate the geochemistry of subduction zones. Nevertheless, metamorphic dehydration and partial melting at high-pressure to ultrahigh-pressure conditions are tectonically applicable to subduction zone processes at forearc to subarc depths, and crustal metasomatism is the physicochemical mechanism for geochemical transfer from the slab to the mantle in subduction channels. Taken together, these provide us with an excellent opportunity to find how the metamorphic, metasomatic and magmatic products are a function of the structures and processes in both oceanic and continental subduction zones. Because of the change in the thermal structures of subduction zones, different styles of metamorphism, metasomatism and magmatism are produced at convergent plate margins. In addition, juvenile and ancient crustal rocks have often suffered reworking in episodes independent of either accretionary or collisional orogeny, leading to continental rifting metamorphism and thus rifting orogeny for mountain building in intracontinental settings. This brings complexity to distinguish the syn

Mantle transition zone structure beneath the Canadian Shield

NASA Astrophysics Data System (ADS)

Thompson, D. A.; Helffrich, G. R.; Bastow, I. D.; Kendall, J. M.; Wookey, J.; Eaton, D. W.; Snyder, D. B.

2010-12-01

The Canadian Shield is underlain by one of the deepest and most laterally extensive continental roots on the planet. Seismological constraints on the mantle structure beneath the region are presently lacking due to the paucity of stations in this remote area. Presented here is a receiver function study on transition zone structure using data from recently deployed seismic networks from the Hudson Bay region. High resolution images based on high signal-to-noise ratio data show clear arrivals from the 410 km and 660 km discontinuities, revealing remarkably little variation in transition zone structure. Transition zone thickness is close to the global average (averaging 245 km across the study area), and any deviations in Pds arrival time from reference Earth models can be readily explained by upper-mantle velocity structure. The 520 km discontinuity is not a ubiquitous feature, and is only weakly observed in localised areas. These results imply that the Laurentian root is likely confined to the upper-mantle and if any mantle downwelling exists, possibly explaining the existence of Hudson Bay, it is also confined to the upper 400 km. Any thermal perturbations at transition zone depths associated with the existence of the root, whether they be cold downwellings or elevated temperatures due to the insulating effect of the root, are thus either non-existent or below the resolution of the study.

Geological structure and prospects of noble metal ore mineralization of the Khayrkhan gabbroid massif (Western Mongolia)

NASA Astrophysics Data System (ADS)

Kurumshieva, K. R.; Gertner, I. F.; Tishin, P. A.

2017-12-01

An analysis of the distribution of noble metals in zones of sulfide mineralization makes it possible to justify the isolation of four ore-bearing horizons with a specific geochemical zonation. A rise in the gold content relative to palladium and platinum is observed from the bottom upwards along the section of the stratified series of gabbroids. The study of the mineral phases of sulphides and the noble minerals itself indicates the evolution of hydrothermal solutions, which determines the different activity and mobility of the fluid (mercury, tellurium, sulfur) and ore (copper, nickel, iron, platinum, gold and silver) components.

Hydrocerussite-related minerals and materials: structural principles, chemical variations and infrared spectroscopy.

PubMed

Siidra, Oleg; Nekrasova, Diana; Depmeier, Wulf; Chukanov, Nikita; Zaitsev, Anatoly; Turner, Rick

2018-04-01

White lead or basic lead carbonate, 2PbCO 3 ·Pb(OH) 2 , the synthetic analogue of hydrocerussite Pb 3 (OH) 2 (CO 3 ) 2 , has been known since antiquity as the most frequently used white paint. A number of different minerals and synthetic materials compositionally and structurally related to hydrocerussite have been described within the last two decades. Herein, a review is given of general structural principles, chemical variations and IR spectra of the rapidly growing family of hydrocerussite-related minerals and synthetic materials. Only structures containing a hydroxo- and/or oxo-component, i.e. which are compositionally directly related with hydrocerussite and `white lead', are reviewed in detail. An essential structural feature of all the considered phases is the presence of electroneutral [PbCO 3 ] 0 cerussite-type layers or sheets. Various interleaved sheets can be incorporated between the cerussite-type sheets. Different sheets are stacked into two-dimensional blocks separated by the stereochemically active 6s 2 lone electron pairs on Pb 2+ cations. Minerals and synthetic materials described herein, together with a number of still hypothetical members, constitute a family of modular structures. Hydrocerussite, abellaite and grootfonteinite can be considered to constitute a merotype family of structures. The remaining hydrocerussite-related structures discussed are built on similar principles, but are more complex. Structural architectures of somersetite and slag phase from Lavrion, Attica, Greece, are unique for oxysalt mineral structures in general. Thus, the whole family of hydrocerussite-related phases can be denoted as a plesiotype family of modular structures. The crystal structures of hydrocerussite from Merehead quarry, Somerset, England, and of its synthetic analogue, both determined from single crystals, are reported here for the first time. The results of the infrared (IR) spectroscopy show that this method is useful for distinguishing several

Mineral resources of parts of the Departments of Antioquia and Caldas, Zone II, Colombia

USGS Publications Warehouse

Hall, R.B.; Feininger, Tomas; Barrero, L.; Dario, Rico H.; ,; Alvarez, A.

1970-01-01

The mineral resources of an area of 40,000 sq km, principally in the Department of Antioquia, but including small parts of the Departments of Caldas, C6rdoba, Risaralda, and Tolima, were investigated during the period 1964-68. The area is designated Zone II by the Colombian Inventario Minero Nacional(lMN). The geology of approximately 45 percent of this area, or 18,000 sq km, has been mapped by IMN. Zone II has been a gold producer for centuries, and still produces 75 percent of Colombia's gold. Silver is recovered as a byproduct. Ferruginous laterites have been investigated as potential sources of iron ore but are not commercially exploitable. Nickeliferous laterite on serpentinite near Ure in the extreme northwest corner of the Zone is potentially exploitable, although less promising than similar laterites at Cerro Matoso, north of the Zone boundary. Known deposits of mercury, chromium, manganese, and copper are small and have limited economic potentia1. Cement raw materials are important among nonmetallic resources, and four companies are engaged in the manufacture of portland cement. The eastern half of Zone II contains large carbonate rock reserves, but poor accessibility is a handicap to greater development at present. Dolomite near Amalfi is quarried for the glass-making and other industries. Clay saprolite is abundant and widely used in making brick and tiles in backyard kilns. Kaolin of good quality near La Union is used by the ceramic industry. Subbituminous coal beds of Tertiary are an important resource in the western part of the zone and have good potential for greater development. Aggregate materials for construction are varied and abundant. Deposits of sodic feldspar, talc, decorative stone, and silica are exploited on a small scale. Chrysotils asbestos deposits north of Campamento are being developed to supply fiber for Colombia's thriving asbestos-cement industry, which is presently dependent upon imported fiber. Wollastonite and andalusite are

Spatial and temporal zoning of hydrothermal alteration and mineralization in the Sossego iron oxide-copper-gold deposit, Carajás Mineral Province, Brazil: Paragenesis and stable isotope constraints

USGS Publications Warehouse

Monteiro, Lena V.S.; Xavier, R.P.; Carvalho, E.R.; Hitzman, M.W.; Johnson, C.A.; Souza, Filho C.R.; Torresi, I.

2008-01-01

The Sossego iron oxide–copper–gold deposit (245 Mt @ 1.1% Cu, 0.28 g/t Au) in the Carajás Mineral Province of Brazil consists of two major groups of orebodies (Pista–Sequeirinho–Baiano and Sossego–Curral) with distinct alteration assemblages that are separated from each other by a major high angle fault. The deposit is located along a regional WNW–ESE-striking shear zone that defines the contact between metavolcano–sedimentary units of the ∼2.76 Ga Itacaiúnas Supergroup and tonalitic to trondhjemitic gneisses and migmatites of the ∼2.8 Ga Xingu Complex. The deposit is hosted by granite, granophyric granite, gabbro, and felsic metavolcanic rocks. The Pista–Sequeirinho–Baiano orebodies have undergone regional sodic (albite–hematite) alteration and later sodic–calcic (actinolite-rich) alteration associated with the formation of massive magnetite–(apatite) bodies. Both these alteration assemblages display ductile to ductile–brittle fabrics. They are cut by spatially restricted zones of potassic (biotite and potassium feldspar) alteration that grades outward to chlorite-rich assemblages. The Sossego–Curral orebodies contain weakly developed early albitic alteration and very poorly developed subsequent calcic–sodic alteration. These orebodies contain well-developed potassic alteration assemblages that were formed during brittle deformation that resulted in the formation of breccia bodies. Breccia matrix commonly displays coarse mineral infill suggestive of growth into open space. Sulfides in both groups of deposits were precipitated first with potassic alteration and more importantly with a later assemblage of calcite–quartz–epidote–chlorite. In the Sequeirinho orebodies, sulfides range from undeformed to deformed; sulfides in the Sossego–Curral orebodies are undeformed. Very late, weakly mineralized hydrolytic alteration is present in the Sossego/Currral orebodies. The sulfide assemblage is dominated by chalcopyrite with

The Cascadia Subduction Zone: two contrasting models of lithospheric structure

USGS Publications Warehouse

Romanyuk, T.V.; Blakely, R.; Mooney, W.D.

1998-01-01

The Pacific margin of North America is one of the most complicated regions in the world in terms of its structure and present day geodynamic regime. The aim of this work is to develop a better understanding of lithospheric structure of the Pacific Northwest, in particular the Cascadia subduction zone of Southwest Canada and Northwest USA. The goal is to compare and contrast the lithospheric density structure along two profiles across the subduction zone and to interpet the differences in terms of active processes. The subduction of the Juan de Fuca plate beneath North America changes markedly along the length of the subduction zone, notably in the angle of subduction, distribution of earthquakes and volcanism, goelogic and seismic structure of the upper plate, and regional horizontal stress. To investigate these characteristics, we conducted detailed density modeling of the crust and mantle along two transects across the Cascadia subduction zone. One crosses Vancouver Island and the Canadian margin, the other crosses the margin of central Oregon.

TomoMiner and TomoMinerCloud: A software platform for large-scale subtomogram structural analysis

PubMed Central

Frazier, Zachary; Xu, Min; Alber, Frank

2017-01-01

SUMMARY Cryo-electron tomography (cryoET) captures the 3D electron density distribution of macromolecular complexes in close to native state. With the rapid advance of cryoET acquisition technologies, it is possible to generate large numbers (>100,000) of subtomograms, each containing a macromolecular complex. Often, these subtomograms represent a heterogeneous sample due to variations in structure and composition of a complex in situ form or because particles are a mixture of different complexes. In this case subtomograms must be classified. However, classification of large numbers of subtomograms is a time-intensive task and often a limiting bottleneck. This paper introduces an open source software platform, TomoMiner, for large-scale subtomogram classification, template matching, subtomogram averaging, and alignment. Its scalable and robust parallel processing allows efficient classification of tens to hundreds of thousands of subtomograms. Additionally, TomoMiner provides a pre-configured TomoMinerCloud computing service permitting users without sufficient computing resources instant access to TomoMiners high-performance features. PMID:28552576

Structural-tectonic zoning of the Arctic

NASA Astrophysics Data System (ADS)

Petrov, Oleg; Sobolev, Nikolay; Morozov, Andrey; Shokalsky, Sergey; Kashubin, Sergey; Grikurov, Garrik; Tolmacheva, Tatiana; Rekant, Pavel; Petrov, Evgeny

2017-04-01

Structural-tectonic zoning of the Arctic is based on the processing of geological and geophysical data and bottom sampling materials produced within the project "Atlas of Geological Maps of the Circumpolar Arctic." Zoning of the Arctic territories has been conducted taking into account the Earth's crust types, age of consolidated basement, and features of geological structure of the sedimentary cover. Developed legend for the zoning scheme incorporates five main groups of elements: continental and oceanic crust, folded platform covers, accretion-collision systems, and provinces of continental cover basalts. An important feature of the structural-tectonic zoning scheme is designation of continental crust in the central regions of the Arctic Ocean, the existence of which is assumed on the basis of numerous geological data. It has been found that most of the Arctic region has continental crust with the exception of the Eurasian Basin and the central part of the Canada Basin, which are characterized by oceanic crust type. Thickness of continental crust from seismic data varies widely: from 30-32 km on the Mendeleev Rise to 18-20 km on the Lomonosov Ridge, decreasing to 8-10 km in rift structures of the Podvodnikov-Makarov Basin at the expense of reduction of the upper granite layer. New data confirm similar basement structure on the western and eastern continental margins of the Eurasian oceanic basin. South to north, areas of Neoproterozoic (Baikalian) and Paleozoic (Ellesmerian) folding are successively distinguished. Neoproterozoic foldbelt is observed in Central Taimyr (Byrranga Mountains). Continuation of this belt in the eastern part of the Arctic is Novosibirsk-Chukchi fold system. Ellesmerian orogen incorporates the northernmost areas of Taimyr and Severnaya Zemlya, wherefrom it can be traced to the Geofizikov Spur of the Lomonosov Ridge and further across the De Long Archipelago and North Chukchi Basin to the north of Alaska Peninsula and in the Beaufort Sea

Three Types of Flower Structures in a Divergent-Wrench Fault Zone

NASA Astrophysics Data System (ADS)

Huang, Lei; Liu, Chi-yang

2017-12-01

Flower structures are typical features of wrench fault zones. In conventional studies, two distinct kinds of flower structures have been identified based on differences in their internal structural architecture: (1) negative flower structures characterized by synforms and normal separations and (2) positive flower structures characterized by antiforms and reverse separations. In addition to negative and positive flower structures, in this study, a third kind of flower structure was identified in a divergent-wrench fault zone, a hybrid characterized by both antiforms and normal separations. Negative flower structures widely occur in divergent-wrench fault zones, and their presence indicates the combined effects of extensional and strike-slip motion. In contrast, positive and hybrid flower structures occur only in fault restraining bends and step overs. A hybrid flower structure can be considered as product of a kind of structural deformation typical of divergent-wrench zones; it is the result of the combined effects of extensional, compressional, and strike-slip strains under a locally appropriate compressional environment. The strain situation in it represents the transition stage that in between positive and negative flower structures. Kinematic and dynamic characteristics of the hybrid flower structures indicate the salient features of structural deformation in restraining bends and step overs along divergent-wrench faults, including the coexistence of three kinds of strains (i.e., compression, extension, and strike-slip) and synchronous presence of compressional (i.e., typical fault-bend fold) and extensional (normal faults) deformation in the same place. Hybrid flower structures are also favorable for the accumulation of hydrocarbons because of their special structural configuration in divergent-wrench fault zones.

The Impact of Organo-Mineral Complexation on Mineral Weathering in the Soil Zone under Unsaturated Conditions

NASA Astrophysics Data System (ADS)

Michael, H. A.; Tan, F.; Yoo, K.; Imhoff, P. T.

2017-12-01

While organo-mineral complexes can protect organic matter (OM) from biodegradation, their impact on soil mineral weathering is not clear. Previous bench-scale experiments that focused on specific OM and minerals showed that the adsorption of OM to mineral surfaces accelerates the dissolution of some minerals. However, the impact of natural organo-mineral complexes on mineral dissolution under unsaturated conditions is not well known. In this study, soil samples prepared from an undisturbed forest site were used to determine mineral weathering rates under differing conditions of OM sorption to minerals. Two types of soil samples were generated: 1) soil with OM (C horizon soil from 84-100cm depth), and 2) soil without OM (the same soil as in 1) but with OM removed by heating to 350°for 24 h). Soil samples were column-packed and subjected to intermittent infiltration and drainage to mimic natural rainfall events. Each soil sample type was run in duplicate. The unsaturated condition was created by applying gas pressure to the column, and the unsaturated chemical weathering rates during each cycle were calculated from the effluent concentrations. During a single cycle, when applying the same gas pressure, soils with OM retained more moisture than OM-removed media, indicating increased water retention capacity under the impact of OM. This is consistent with the water retention data measured by evaporation experiments (HYPROP) and the dew point method (WP4C Potential Meter). Correspondingly, silicon (Si) denudation rates indicated that dissolution of silicate minerals was 2-4 times higher in OM soils, suggesting that organo-mineral complexes accelerate mineral dissolution under unsaturated conditions. When combining data from all cycles, the results showed that Si denudation rates were positively related to soil water content: denundation rate increased with increasing water content. Therefore, natural mineral chemical weathering under unsaturated conditions, while

Structural Health Monitoring of Railway Transition Zones Using Satellite Radar Data.

PubMed

Wang, Haoyu; Chang, Ling; Markine, Valeri

2018-01-31

Transition zones in railway tracks are locations with considerable changes in the rail-supporting structure. Typically, they are located near engineering structures, such as bridges, culverts and tunnels. In such locations, severe differential settlements often occur due to the different material properties and structure behavior. Without timely maintenance, the differential settlement may lead to the damage of track components and loss of passenger's comfort. To ensure the safety of railway operations and reduce the maintenance costs, it is necessary to consecutively monitor the structural health condition of the transition zones in an economical manner and detect the changes at an early stage. However, using the current in situ monitoring of transition zones is hard to achieve this goal, because most in situ techniques (e.g., track-measuring coaches) are labor-consuming and usually not frequently performed (approximately twice a year in the Netherlands). To tackle the limitations of the in situ techniques, a Satellite Synthetic Aperture Radar (InSAR) system is presented in this paper, which provides a potential solution for a consecutive structural health monitoring of transition zones with bi-/tri-weekly data update and mm-level precision. To demonstrate the feasibility of the InSAR system for monitoring transition zones, a transition zone is tested. The results show that the differential settlement in the transition zone and the settlement rate can be observed and detected by the InSAR measurements. Moreover, the InSAR results are cross-validated against measurements obtained using a measuring coach and a Digital Image Correlation (DIC) device. The results of the three measuring techniques show a good correlation, which proves the applicability of InSAR for the structural health monitoring of transition zones in railway track.

Structural Health Monitoring of Railway Transition Zones Using Satellite Radar Data

PubMed Central

Chang, Ling; Markine, Valeri

2018-01-01

Transition zones in railway tracks are locations with considerable changes in the rail-supporting structure. Typically, they are located near engineering structures, such as bridges, culverts and tunnels. In such locations, severe differential settlements often occur due to the different material properties and structure behavior. Without timely maintenance, the differential settlement may lead to the damage of track components and loss of passenger’s comfort. To ensure the safety of railway operations and reduce the maintenance costs, it is necessary to consecutively monitor the structural health condition of the transition zones in an economical manner and detect the changes at an early stage. However, using the current in situ monitoring of transition zones is hard to achieve this goal, because most in situ techniques (e.g., track-measuring coaches) are labor-consuming and usually not frequently performed (approximately twice a year in the Netherlands). To tackle the limitations of the in situ techniques, a Satellite Synthetic Aperture Radar (InSAR) system is presented in this paper, which provides a potential solution for a consecutive structural health monitoring of transition zones with bi-/tri-weekly data update and mm-level precision. To demonstrate the feasibility of the InSAR system for monitoring transition zones, a transition zone is tested. The results show that the differential settlement in the transition zone and the settlement rate can be observed and detected by the InSAR measurements. Moreover, the InSAR results are cross-validated against measurements obtained using a measuring coach and a Digital Image Correlation (DIC) device. The results of the three measuring techniques show a good correlation, which proves the applicability of InSAR for the structural health monitoring of transition zones in railway track. PMID:29385070

Mineral chemistry of isotropic gabbros from the Manamedu Ophiolite Complex, Cauvery Suture Zone, southern India: Evidence for neoproterozoic suprasubduction zone tectonics

NASA Astrophysics Data System (ADS)

Yellappa, T.; Tsunogae, T.; Chetty, T. R. K.; Santosh, M.

2016-11-01

The dismembered units of the Neoproterozoic Manamedu Ophiolite Complex (MOC) in the Cauvery Suture Zone, southern India comprises a well preserved ophiolitic sequence of ultramafic cumulates of altered dunites, pyroxenites, mafic cumulates of gabbros, gabbro-norites and anorthosites in association with plagiogranites, isotropic gabbros, metadolerites, metabasalts/amphibolites and thin layers of ferruginous chert bands. The isotropic gabbros occur as intrusions in association with gabbroic anorthosites, plagiogranite and metabasalts/amphibolites. The gabbros are medium to fine grained with euhedral to subhedral orthopyroxenes, clinopyroxenes and subhedral plagioclase, together with rare amphiboles. Mineral chemistry of isotropic gabbros reveal that the clinopyroxenes are diopsidic to augitic in composition within the compositional ranges of En(42-59), Fs(5-12), Wo(31-50). They are Ca-rich and Na poor (Na2O < 0.77 wt%) characterized by high-Mg (Mg# 79-86) and low-Ti (TiO2 < 0.35 wt%) contents. The tectonic discrimination plots of clinopyroxene data indicate island arc signature of the source magma. Our study further confirms the suprasubduction zone origin of the Manamedu ophiolitic suite, associated with the subduction-collision history of the Neoproterozoic Mozambique ocean during the assembly of Gondwana supercontinent.

The role of upper mantle mineral phase transitions on the current structure of large-scale Earth's mantle convection.

NASA Astrophysics Data System (ADS)

Thoraval, C.

2017-12-01

Describing the large-scale structures of mantle convection and quantifying the mass transfer between upper and lower mantle request to account for the role played by mineral phase transitions in the transition zone. We build a density distribution within the Earth mantle from velocity anomalies described by global seismic tomographic models. The density distribution includes thermal anomalies and topographies of the phase transitions at depths of 410 and 660 km. We compute the flow driven by this density distribution using a 3D spherical circulation model, which account for depth-dependent viscosity. The dynamic topographies at the surface and at the CMB and the geoid are calculated as well. Within the range of viscosity profiles allowing for a satisfying restitution of the long wavelength geoid, we perform a parametric study to decipher the role of the characteristics of phase diagrams - mainly the Clapeyron's slopes - and of the kinetics of phase transitions, which may modify phase transition topographies. Indeed, when a phase transition is delayed, the boundary between two mineral phases is both dragged by the flow and interfere with it. The results are compared to recent estimations of surface dynamic topography and to the phase transition topographies as revealed by seismic studies. The consequences are then discussed in terms of structure of mantle flow. Comparisons between various tomographic models allow us to enlighten the most robust features. At last, the role played by the phase transitions on the lateral variations of mass transfer between upper and lower mantle are quantified by comparison to cases with no phase transitions and confronted to regional tomographic models, which reflect the variability of the behaviors of the descending slabs in the transition zone.

Structure and stability of hydrous minerals at high pressure

NASA Technical Reports Server (NTRS)

Duffy, T. S.; Fei, Y.; Meade, C.; Hemley, R. J.; Mao, H. K.

1994-01-01

The presence of even small amounts of hydrogen in the Earth's deep interior may have profound effects on mantle melting, rheology, and electrical conductivity. The recent discovery of a large class of high-pressure H-bearing silicates further underscores the potentially important role for hydrous minerals in the Earth's mantle. Hydrogen may also be a significant component of the Earth's core, as has been recently documented by studies of iron hydride at high pressure. In this study, we explore the role of H in crystal structures at high pressure through detailed Raman spectroscopic and x ray diffraction studies of hydrous minerals compressed in diamond anvil cells. Brucite, Mg(OH)2, has a simple structure and serves as an analogue for the more complex hydrous silicates. Over the past five years, this material has been studied at high pressure using shock-compression, powder x ray diffraction, infrared spectroscopy, Raman spectroscopy, and neutron diffraction. In addition, we have recently carried out single-crystal synchrotron x-ray diffraction on Mg(OH)2 and Raman spectroscopy on Mg(OD)2 at elevated pressure. From all these studies, an interesting picture of the crystal chemical behavior of this material at high pressure is beginning to emerge. Some of the primary conclusions are as follows: First, hydrogen bonding is enhanced by the application of pressure. Second, layered minerals which are elastically anisotropic at low pressure may not be so at high pressure. Furthermore, the brucite data place constraints on the effect of hydrogen on seismic velocities and density at very high pressure. Third, the stability of hydrous minerals may be enhanced at high P by subtle structural rearrangements that are difficult to detect using traditional probes and require detailed spectroscopic analyses. Finally, brucite appears to be unique in that it undergoes pressure-induced disordering that is confined solely to the H-containing layers of the structure.

Gravity anomaly and density structure of the San Andreas fault zone

NASA Astrophysics Data System (ADS)

Wang, Chi-Yuen; Rui, Feng; Zhengsheng, Yao; Xingjue, Shi

1986-01-01

A densely spaced gravity survey across the San andreas fault zone was conducted near Bear Valley, about 180 km south of San Francisco, along a cross-section where a detailed seismic reflection profile was previously made by McEvilly (1981). With Feng and McEvilly's velocity structure (1983) of the fault zone at this cross-section as a constraint, the density structure of the fault zone is obtained through inversion of the gravity data by a method used by Parker (1973) and Oldenburg (1974). Although the resulting density picture cannot be unique, it is better constrained and contains more detailed information about the structure of the fault than was previously possible. The most striking feature of the resulting density structure is a deeply seated tongue of low-density material within the fault zone, probably representing a wedge of fault gouge between the two moving plates, which projects from the surface to the base of the seismogenic zone. From reasonable assumptions concerning the density of the solid grains and the state of saturation of the fault zone the average porosity of this low-density fault gouge is estimated as about 12%. Stress-induced cracks are not expected to create so much porosity under the pressures in the deep fault zone. Large-scaled removal of fault-zone material by hydrothermal alteration, dissolution, and subsequent fluid transport may have occurred to produce this pronounced density deficiency. In addition, a broad, funnel-shaped belt of low density appears about the upper part of the fault zone, which probably represents a belt of extensively shattered wall rocks.

Water Footprint in Nitrate Vulnerable Zones: Mineral vs. Organic Fertilization.

NASA Astrophysics Data System (ADS)

Castellanos Serrano, María Teresa; Requejo Mariscal, María Isabel; Villena Gordo, Raquel; Cartagena Causapé, María Carmen; Arce Martínez, Augusto; Ribas Elcorobarrutia, Francisco; María Tarquis Alfonso, Ana

2017-04-01

In intensive agriculture, it is necessary to apply irrigation and fertilizers to increase the crop yield. An optimization of water and N application is necessary. An excess of irrigation implies nitrates washing which would contribute to the contamination of the groundwater. An excess of N, besides affecting the yield and fruit quality, causes serious environmental problems. Nitrate vulnerable zones (NVZs) are areas designated as being at risk from agricultural nitrate pollution. They include around 16% of land in Spain and in Castilla-La Mancha, the area studied, represents 45% of the total land. In several zones, the N content of the groundwater could be approximately 140 mg L-1, or even higher [1]. The input of nitrogen fertilizers (mineral or organic), applied with a poor management, could be increased considerably the pollution risks. The water footprint (WF) is as indicator for the total volume of direct and indirect freshwater used, consumed and/or polluted [2]. The WF includes both consumptive water use: blue water (volume of surface and groundwater consumed) and green water (rainwater consumed)). A third element is the water required to assimilate pollution (grey water) [2]. Under semiarid conditions with low irrigation water quality, green WF is zero because the effective rainfall is negligible. Blue WF includes: i) extra consumption or irrigation water that the farmer has to apply to compensate the fail of uniformity on discharge of drips, ii) percolation out of control or salts leaching, which depends on the salt tolerance of the crop, soil and quality of irrigation water, to ensure the fruit yield. In the NVZs, the major concern is grey WF, because the irrigation and nitrogen dose have to be adjusted to the crop needs in order to minimize nitrate pollution. This study focus on the assessment of mineral and organic fertilization on WF in a fertirrigated melon crop under semiarid conditions with a low water quality. During successive years, a melon crop

Microstructural and petrophysical characterization of a "structurally oversimplified" fault zone in poorly lithified sands: evidence for a coseismic rupture?

NASA Astrophysics Data System (ADS)

Balsamo, Fabrizio; Storti, Fabrizio

2010-05-01

We studied an extensional fault zone developed in poorly lithified, quartz-rich high porosity sandy sediments of the seismically active Crotone basin (southern Italy). The fault zone cuts across interlayered fine- to coarse-grained sands and consists of a cm-thick, discrete fault core embedded in virtually undeformed wall sediments. Consequently, it can be described as "structurally oversimplified" due to the lack of footwall and hanging wall damage zones. We acquired microstructural, grain size, grain shape, porosity, mineralogical and permeability data to investigate the influence of initial sedimentological characteristics of sands on the final faulted granular products and related hydrologic properties. Faulting evolves by a general grain size and porosity reduction with a combination of intragranular fracturing, spalling, and flaking of grain edges, irrespective of grain mineralogy. The dominance of cataclasis, also confirmed by fractal dimensions >2.6, is generally not expected at a deformation depth <1 km. Coarse-grained sand shows a much higher comminution intensity, grain shape variations and permeability drop than fine-grained sands. This is because coarser aggregates have (i) fewer grain-to-grain contacts for a given area, which results in higher stress concentration at contact points, and (ii) a higher probability of pre-existing intragranular microstructural defects that result in a lower grain strength. The peculiar structural architecture, the dominance of cataclasis over non-destructive particulate flow, and the compositional variations of clay minerals in the fault core, strongly suggest that the studied fault zone developed by a coseismic rupture.

Internal Structure of Taiwan Chelungpu Fault Zone Gouges

NASA Astrophysics Data System (ADS)

Song, Y.; Song, S.; Tang, M.; Chen, F.; Chen, Y.

2005-12-01

Gouge formation is found to exist in brittle faults at all scale (1). This fine-grain gouge is thought to control earthquake instability. And thus investigating the gouge textures and compositions is very important to an understanding of the earthquake process. Employing the transmission electron microscope (TEM) and a new transmission X-ray microscope (TXM), we study the internal structure of fault zone gouges from the cores of the Taiwan Chelungpu-fault Drilling Project (TCDP), which drilled in the fault zone of 1999 Chi-Chi earthquake. This X-ray microscope have installed at beamline BL01B of the Taiwan Light Source, National Synchrotron Radiation Research Center (NSRRC). It provides 2D imaging and 3D tomography at energy 8-11 keV with a spatial resolution of 25-60 nm, and is equipped with the Zernike-phase contrast capability for imaging light materials. In this work, we show the measurements of gouge texture, particle size distribution and 3D structure of the ultracataclasite in fault gouges within 12 cm about 1111.29 m depth. These characterizations in transition from the fault core to damage zone are related to the comminuting and the fracture energy in the earthquake faulting. The TXM data recently shows the particle size distributions of the ultracataclasite are between 150 nm and 900 nm in diameter. We will keep analyzing the characterization of particle size distribution, porosity and 3D structure of the fault zone gouges in transition from the fault core to damage zone to realize the comminuting and fracture surface energy in the earthquake faulting(2-5).The results may ascertain the implication of the nucleation, growth, transition, structure and permeability of the fault zones(6-8). Furthermore, it may be possible to infer the mechanism of faulting, the physical and chemical property of the fault, and the nucleation of the earthquake. References 1) B. Wilson, T. Dewerw, Z. Reches and J. Brune, Nature, 434 (2005) 749. 2) S. E. Schulz and J. P. Evans

Analysis of mixed-layer clay mineral structures

USGS Publications Warehouse

Bradley, W.F.

1953-01-01

Among the enormously abundant natural occurrences of clay minerals, many examples are encountered in which no single specific crystallization scheme extends through a single ultimate grain. The characterization of such assemblages becomes an analysis of the distribution of matter within such grains, rather than the simple identification of mineral species. It having become established that the particular coordination complex typified by mica is a common component of many natural subcrystalline assemblages, the opportunity is afforded to analyze scattering from random associations of these complexes with other structural units. Successful analyses have been made of mixed hydration states of montmorillonite, of montmorillonite with mica, of vermiculite with mica, and of montmorillonite with chlorite, all of which are variants of the mica complex, and of halloysite with hydrated halloysite.

Can dead zones create structures like a transition disk?

NASA Astrophysics Data System (ADS)

Pinilla, Paola; Flock, Mario; Ovelar, Maria de Juan; Birnstiel, Til

2016-12-01

Context. Regions of low ionisation where the activity of the magneto-rotational instability is suppressed, the so-called dead zones, have been suggested to explain gaps and asymmetries of transition disks. Dead zones are therefore a potential cause for the observational signatures of transition disks without requiring the presence of embedded planets. Aims: We investigate the gas and dust evolution simultaneously assuming simplified prescriptions for a dead zone and a magnetohydrodynamic (MHD) wind acting on the disk. We explore whether the resulting gas and dust distribution can create signatures similar to those observed in transition disks. Methods: We imposed a dead zone and/or an MHD wind in the radial evolution of gas and dust in protoplanetary disks. For the dust evolution, we included the transport, growth, and fragmentation of dust particles. To compare with observations, we produced synthetic images in scattered optical light and in thermal emission at mm wavelengths. Results: In all models with a dead zone, a bump in the gas surface density is produced that is able to efficiently trap large particles (≳ 1 mm) at the outer edge of the dead zone. The gas bump reaches an amplitude of a factor of 5, which can be enhanced by the presence of an MHD wind that removes mass from the inner disk. While our 1D simulations suggest that such a structure can be present only for 1 Myr, the structure may be maintained for a longer time when more realistic 2D/3D simulations are performed. In the synthetic images, gap-like low-emission regions are seen at scattered light and in thermal emission at mm wavelengths, as previously predicted in the case of planet-disk interaction. Conclusions: Main signatures of transition disks can be reproduced by assuming a dead zone in the disk, such as gap-like structure in scattered light and millimetre continuum emission, and a lower gas surface density within the dead zone. Previous studies showed that the Rossby wave instability can

Structural relations between collagen and mineral in bone as determined by high voltage electron microscopic tomography

NASA Technical Reports Server (NTRS)

Landis, W. J.; Hodgens, K. J.; Arena, J.; Song, M. J.; McEwen, B. F.

1996-01-01

Aspects of the ultrastructural interaction between collagen and mineral crystals in embryonic chick bone have been examined by the novel technique of high voltage electron microscopic tomography to obtain three-dimensional information concerning extracellular calcification in this tissue. Newly mineralizing osteoid along periosteal surfaces of mid-diaphyseal regions from normal chick tibiae was embedded, cut into 0.25 microns thick sections, and documented at 1.0 MV in the Albany AEI-EM7 high voltage electron microscope. The areas of the tissue studied contained electron dense mineral crystals associated with collagen fibrils, some marked by crystals disposed along their cylindrically shaped lengths. Tomographic reconstructions of one site with two mineralizing fibrils were computed from a 5 degrees tilt series of micrographs over a +/- 60 degrees range. Reconstructions showed that the mineral crystals were platelets of irregular shape. Their sizes were variable, measured here up to 80 x 30 x 8 nm in length, width, and thickness, respectively. The longest crystal dimension, corresponding to the c-axis crystallographically, was generally parallel to the collagen fibril long axis. Individual crystals were oriented parallel to one another in each fibril examined. They were also parallel in the neighboring but apparently spatially separate fibrils. Crystals were periodically (approximately 67 nm repeat distance) arranged along the fibrils and their location appeared to correspond to collagen hole and overlap zones defined by geometrical imaging techniques. The crystals appeared to be continuously distributed along a fibril, their size and number increasing in a tapered fashion from a relatively narrow tip containing smaller and infrequent crystals to wider regions having more densely packed and larger crystals. Defined for the first time by direct visual 3D imaging, these data describe the size, shape, location, orientation, and development of early crystals in normal

Geology and Mineral Deposits of the Snow Camp-Saxapahaw Area, Central North Carolina

USGS Publications Warehouse

Schmidt, Robert G.; Gumiel, Pablo; Payas, Alba

2006-01-01

The Snow Camp-Saxapahaw study area, in the Carolina slate belt in the Southeastern United States, is notable for large zones of high-sulfidation alteration in arc-related metavolcanic rocks. The area has potential for additional significant pyrophyllite and related aluminosilicate refractory mineral deposits and may have potential for small- to medium-size gold deposits also associated with the high-sulfidation hydrothermal systems. The Carolina slate belt is an elongate zone of mostly low-grade metamorphic rocks of Neoproterozoic to early Paleozoic age that extends from northeastern Georgia to southern Virginia. It is dominated by volcanic rocks but locally consists of fine-grained epiclastic sedimentary rocks. Plutons and subvolcanic bodies have intruded the rocks of the Carolina slate belt in many places and have been important in controlling the metamorphism and in localizing hydrothermal alteration. The Snow Camp-Saxapahaw area is mostly underlain by volcanic and volcaniclastic rocks and lesser amounts of intrusive shallow plutons. The volcanic rocks range in composition from basalt to rhyolite; however andesites, dacites, and rhyodacites are the most abundant. The intrusive bodies are largely granite and quartz monzonite; gabbroic bodies also are common. It was possible to establish the relative ages of only part of these rocks. Two northeast-trending fault zones and fractures divide the map area into three structural blocks; the central block was tilted down to the southwest to form a grabenlike structure. Most of the hydrothermally altered rocks and all of the intensely altered zones are confined to the downdropped block, which we think may have been calderalike in origin. A major volcanic unit, the Reedy Branch Tuff, is limited to the southwestern part of the graben and may be the youngest volcanic rock in the area. Layered rocks record one or more strong folding events, but the diversity of rock types, lack of recognizable stratigraphic markers, and

Seamount subduction at seismogenic depths: structural and metamorphic evidence from the Zagros suture zone

NASA Astrophysics Data System (ADS)

Bonnet, G.; Agard, P.; Angiboust, S.; Fournier, M.; Omrani, J.

2017-12-01

Large-scale seafloor topographic features, such as seamounts, are for the most part subducted with the downgoing oceanic plate. They are expected to critically impact the seismogenic and mechanic behavior of subduction zones, but their exact role is strongly debated (i.e., as to whether they represent barriers to propagation or asperities promoting nucleation). Rare natural examples of metamorphosed seamounts, which got sliced off the slab along the plate interface and escaped recycling into the mantle, are therefore precious witnesses to document processes operating at depths of 0-30 km. We herein report the existence of a large-scale oceanic topographic structure sandwiched in the Zagros suture zone (Siah Kuh - SK - unit), most probably a former seamount, along with other blueschist units (Angiboust et al., EPSL 2016). The main criteria for identifying this seamount are its: (1) shape: the SK unit is a 1.5-2 km thick, rounded-shaped body with a 15-20 km diameter, (2) lithologies: it is made mainly of a regular succession of massive basaltic flows, commonly as pillow basalts, minor ophiolite-type gabbros and serpentinite, together with subordinate more differenciated volcanic and plutonic rocks. (3) sedimentary cover: basalts are overlain by shallowly deposited reef limestone and deepening-up sediments with the occurrence of cherts and pelagic limestones (which points to possible subsidence). Basalts have been analyzed for trace elements and have usually a N-MORB to OIB signature, which might be explained by its potential origin as a mid-oceanic ridge seamount. HP-LT minerals (lawsonite, aragonite, blue amphiboles) found across the whole structure, particularly in zones of localized compressive deformation, indicate that this seamount was shallowly subducted at 20 km. This deformation, interpreted to be syn-subduction, is assisted by a décollement rooting in serpentinite and/or oceanic metasediments and is associated with rare cataclase in magmatic rocks. We

Interactions of structurally modified surfactants with reservoir minerals: Calorimetric, spectroscopic and electrokinetic study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Somasundaran, P.; Sivakumar, A.; Xu, Q.

1991-03-01

The objective of this project is to elucidate mechanisms of adsorption of structurally modified surfactants on reservoir minerals and to develop a full understanding of the effect of the surfactant structure on the nature of the adsorbed layers at the molecular level. An additional aim is to study the adsorption of surfactant mixtures on simple well-characterized minerals and on complex minerals representing real conditions. The practical goal of these studies is the identification of the optimum surfactant structures and their combinations for micellar flooding. In this work, the experiments on adsorption were focussed on the position of sulfonate and methylmore » groups on the aromatic ring of alkyl xylene sulfonates. A multi-pronged approach consisting of calorimetry, electrokinetics, wettability and spectroscopy is planned to elucidate the adsorption mechanism of surfactants and their mixtures on minerals such as alumina and kaolinite. 32 refs., 15 figs., 7 tabs.« less

Magmatic structure and geochemistry of the Luanga Mafic-Ultramafic Complex: Further constraints for the PGE-mineralized magmatism in Carajás, Brazil

NASA Astrophysics Data System (ADS)

Mansur, Eduardo Teixeira; Ferreira Filho, Cesar Fonseca

2016-12-01

The Luanga Complex is part of the Serra Leste Magmatic Suite, a cluster of PGE-mineralized mafic-ultramafic intrusions located in the northeastern portion of the Carajás Mineral Province. The Luanga Complex is a medium-sized layered intrusion consisting of three main zones: i. the lower Ultramafic Zone comprising ultramafic adcumulates (peridotite), ii. the Transition Zone comprising interlayered ultramafic and mafic cumulates (harzburgite, orthopyroxenite and norite) and iii. the upper Mafic Zone comprising a monotonous sequence of mafic cumulates (norite) with minor orthopyroxenite layers. Several PGE-mineralized zones occur in the Transition Zone but the bulk of the PGE resources are hosted within a 10-50 meter thick interval of disseminated sulfides at the contact of the Ultramafic and Transition Zones. The compositional range of cumulus olivine (Fo78.9-86.4) is comparable to those reported for layered intrusions originated from moderate primitive parental magmas. Mantle normalized alteration-resistant trace element patterns of noritic rocks are fractionated, as indicated by relative enrichment in LREE and Th, with negative Nb and Ta anomalies, suggesting assimilation of older continental crust. Ni contents in olivine in the Luanga Complex (up to 7500 ppm) stand among the highest values reported in layered intrusions globally. The highest Ni contents in olivine in the Luanga Complex occur in distinctively PGE enriched (Pt + Pd > 1 ppm) intervals of the Transition Zone, in both sulfide-poor and sulfide bearing (1-3 vol.%) rocks. The origin of the PGE- and Ni-rich parental magma of the Luanga Complex is discussed considering the upgrading of magmas through dissolution of previously formed Ni-rich sulfide melts. Our results suggest that high Ni contents in olivine and/or orthopyroxene provide an additional exploration tool for Ni-PGE deposits, particularly useful for target selection in large magmatic provinces.

Microbial reduction of structural iron in interstratified illite-smectite minerals by a sulfate-reducing bacterium

USGS Publications Warehouse

Liu, D.; Dong, H.; Bishop, M.E.; Zhang, Jiahua; Wang, Hongfang; Xie, S.; Wang, Shaoming; Huang, L.; Eberl, D.D.

2012-01-01

Clay minerals are ubiquitous in soils, sediments, and sedimentary rocks and could coexist with sulfate-reducing bacteria (SRB) in anoxic environments, however, the interactions of clay minerals and SRB are not well understood. The objective of this study was to understand the reduction rate and capacity of structural Fe(III) in dioctahedral clay minerals by a mesophilic SRB, Desulfovibrio vulgaris and the potential role in catalyzing smectite illitization. Bioreduction experiments were performed in batch systems, where four different clay minerals (nontronite NAu-2, mixed-layer illite-smectite RAr-1 and ISCz-1, and illite IMt-1) were exposed to D. vulgaris in a non-growth medium with and without anthraquinone-2,6-disulfonate (AQDS) and sulfate. Our results demonstrated that D. vulgaris was able to reduce structural Fe(III) in these clay minerals, and AQDS enhanced the reduction rate and extent. In the presence of AQDS, sulfate had little effect on Fe(III) bioreduction. In the absence of AQDS, sulfate increased the reduction rate and capacity, suggesting that sulfide produced during sulfate reduction reacted with the phyllosilicate Fe(III). The extent of bioreduction of structural Fe(III) in the clay minerals was positively correlated with the percentage of smectite and mineral surface area of these minerals. X-ray diffraction, and scanning and transmission electron microscopy results confirmed formation of illite after bioreduction. These data collectively showed that D. vulgaris could promote smectite illitization through reduction of structural Fe(III) in clay minerals. ?? 2011 Blackwell Publishing Ltd.

Hydrothermal minerals and microstructures in the Silangkitang geothermal field along the Great Sumatran fault zone, Sumatra, Indonesia

USGS Publications Warehouse

Moore, Diane E.; Hickman, S.; Lockner, D.A.; Dobson, P.F.

2001-01-01

Detailed study of core samples of silicic tuff recovered from three geothermal wells along the strike-slip Great Sumatran fault zone near Silangkitang, North Sumatra, supports a model for enhanced hydrothermal circulation adjacent to this major plate-boundary fault. Two wells (A and C) were drilled nearly vertically ??1 km southwest of the eastern (i.e., the principal) fault trace, and the third, directional well (B) was drilled eastward from the site of well A to within ??100 m of the principal fault trace. The examined core samples come from depths of 1650-2120 m at measured well temperatures of 180-320 ??C. The samples collected near the principal fault trace have the highest temperatures, the largest amount of secondary pore space that correlates with high secondary permeability, and the most extensive hydrothermal mineral development. Secondary permeability and the degree of hydrothermal alteration decrease toward the southwestern margin of the fault zone. These features indicate episodic, localized flow of hot, possibly CO2-rich fluids within the fault zone. The microstructure populations identified in the core samples correlate to the subsidiary fault patterns typical of strike-slip faults. The geothermal reservoir appears to be centered on the fault zone, with the principal fault strands and adjoining, highly fractured and hydrothermally altered rock serving as the main conduits for vertical fluid flow and advective heat transport from deeper magmatic sources.

Finite-Difference Modeling of Seismic Reflection Data in a Hard Rock Environment: An Example from the Mineralized Otago Schist, New Zealand

NASA Astrophysics Data System (ADS)

Leslie, A.; Gorman, A. R.

2004-12-01

The interpretation of seismic reflection data in non-sedimentary environments is problematic. In the Macraes Flat region near Dunedin (South Island, New Zealand), ongoing mining of mineralized schist has prompted the development of a seismic interpretation scheme that is capable of imaging a gold-bearing shear zone and associated mineralized structures accurately to the meter scale. The anisotropic and complex structural nature of this geological environment necessitates a cost-effective computer-based modeling technique that can provide information on the physical characteristics of the schist. Such a method has been tested on seismic data acquired in 1993 over a region that has since been excavated and logged. Correlation to measured structural data permits a direct comparison between the seismic data and the actual geology. Synthetic modeling utilizes a 2D visco-elastic finite difference routine to constrain the interpretation of observed seismic characteristics, including the velocity, anisotropy, and contrast, of the shear zone structures. Iterative refinements of the model result in a more representative synthetic model that most closely matches the seismic response. The comparison between the actual and synthetic seismic sections provides promising results that will be tested by new data acquisition over the summer of 2004/2005 to identify structures and zones of potential mineralization. As a downstream benefit, this research could also contribute to earthquake risk assessment analyses at active faults with similar characteristics.

Tracing mineral weathering reactions in the critical zone using Mg, Ca, and Sr isotopes, Luquillo Mountains, Puerto Rico

NASA Astrophysics Data System (ADS)

Buss, H. L.; White, A. F.; Vivit, D.; Bullen, T. D.; Blum, A. E.; Dessert, C.; Gaillardet, J.

2008-12-01

Mineral weathering in the critical zone directly impacts the availability of many important soil nutrients. As part of the USGS Water Energy and Biogeochemical Budgets (WEBB) program and the Critical Zone Exploration Network, we are investigating mineral nutrient distributions and fluxes in depth profiles (to 16 m) at five sites in the Bisley 1 catchment in the Luquillo Mountains of Puerto Rico. The Bisley 1 catchment contains a thick regolith developed on marine bedded, andesitic, volcaniclastic bedrock. Pore waters were sampled as a function of depth from nested suction water samplers. Pore water chemistry was analyzed and compared to total chemistry of solid samples taken from augered cores. Mg, Ca and Sr isotope ratios were measured of the pore waters at the Institut de Physique du Globe de Paris (Mg) and at the USGS in Menlo Park, CA (Ca, Sr). The Mg isotope ratios increase with increasing depth from δ26Mg = -0.772 at the surface to - 0.267 at depth, relative to the DSM3 standard. Sr isotope ratios vary from 0.70922 to 0.71016 87Sr/86Sr, with no discernible depth trend. The regolith is highly weathered and is depleted in primary minerals (except quartz) with respect to bedrock. Volumetric strain, calculated with respect to quartz, indicates approximately 25% volume collapse occurred relative to the original volume of the bedrock. Plagioclase, chlorite, pyroxene, and amphibole weather at the bedrock-regolith interface. The regolith contains quartz, kaolinite, other clays, and iron and manganese oxides. Increasing solid and pore water Mg concentrations and δ26Mg with depth likely indicate a two step weathering process wherein high-Mg chlorite dissolves at the bedrock-regolith interface and forms Mg-containing secondary clays and oxides, which then dissolve within the regolith profile.

Structural kinematics based damage zone prediction in gradient structures using vibration database

NASA Astrophysics Data System (ADS)

Talha, Mohammad; Ashokkumar, Chimpalthradi R.

2014-05-01

To explore the applications of functionally graded materials (FGMs) in dynamic structures, structural kinematics based health monitoring technique becomes an important problem. Depending upon the displacements in three dimensions, the health of the material to withstand dynamic loads is inferred in this paper, which is based on the net compressive and tensile displacements that each structural degree of freedom takes. These net displacements at each finite element node predicts damage zones of the FGM where the material is likely to fail due to a vibration response which is categorized according to loading condition. The damage zone prediction of a dynamically active FGMs plate have been accomplished using Reddy's higher-order theory. The constituent material properties are assumed to vary in the thickness direction according to the power-law behavior. The proposed C0 finite element model (FEM) is applied to get net tensile and compressive displacement distributions across the structures. A plate made of Aluminum/Ziconia is considered to illustrate the concept of structural kinematics-based health monitoring aspects of FGMs.

Internal architecture, permeability structure, and hydrologic significance of contrasting fault-zone types

NASA Astrophysics Data System (ADS)

Rawling, Geoffrey C.; Goodwin, Laurel B.; Wilson, John L.

2001-01-01

The Sand Hill fault is a steeply dipping, large-displacement normal fault that cuts poorly lithified Tertiary sediments of the Albuquerque basin, New Mexico, United States. The fault zone does not contain macroscopic fractures; the basic structural element is the deformation band. The fault core is composed of foliated clay flanked by structurally and lithologically heterogeneous mixed zones, in turn flanked by damage zones. Structures present within these fault-zone architectural elements are different from those in brittle faults formed in lithified sedimentary and crystalline rocks that do contain fractures. These differences are reflected in the permeability structure of the Sand Hill fault. Equivalent permeability calculations indicate that large-displacement faults in poorly lithified sediments have little potential to act as vertical-flow conduits and have a much greater effect on horizontal flow than faults with fractures.

Concentration-Discharge Relations in the Critical Zone: Implications for Resolving Critical Zone Structure, Function, and Evolution

NASA Astrophysics Data System (ADS)

Chorover, Jon; Derry, Louis A.; McDowell, William H.

2017-11-01

Critical zone science seeks to develop mechanistic theories that describe critical zone structure, function, and long-term evolution. One postulate is that hydrogeochemical controls on critical zone evolution can be inferred from solute discharges measured down-gradient of reactive flow paths. These flow paths have variable lengths, interfacial compositions, and residence times, and their mixing is reflected in concentration-discharge (C-Q) relations. Motivation for this special section originates from a U.S. Critical Zone Observatories workshop that was held at the University of New Hampshire, 20-22 July 2015. The workshop focused on resolving mechanistic CZ controls over surface water chemical dynamics across the full range of lithogenic (e.g., nonhydrolyzing and hydrolyzing cations and oxyanions) and bioactive solutes (e.g., organic and inorganic forms of C, N, P, and S), including dissolved and colloidal species that may cooccur for a given element. Papers submitted to this special section on "concentration-discharge relations in the critical zone" include those from authors who attended the workshop, as well as others who responded to the open solicitation. Submissions were invited that utilized information pertaining to internal, integrated catchment function (relations between hydrology, biogeochemistry, and landscape structure) to help illuminate controls on observed C-Q relations.

Microbial reduction of structural iron in interstratified illite-smectite minerals by a sulfate-reducing bacterium.

PubMed

Liu, D; Dong, H; Bishop, M E; Zhang, J; Wang, H; Xie, S; Wang, S; Huang, L; Eberl, D D

2012-03-01

Clay minerals are ubiquitous in soils, sediments, and sedimentary rocks and could coexist with sulfate-reducing bacteria (SRB) in anoxic environments, however, the interactions of clay minerals and SRB are not well understood. The objective of this study was to understand the reduction rate and capacity of structural Fe(III) in dioctahedral clay minerals by a mesophilic SRB, Desulfovibrio vulgaris and the potential role in catalyzing smectite illitization. Bioreduction experiments were performed in batch systems, where four different clay minerals (nontronite NAu-2, mixed-layer illite-smectite RAr-1 and ISCz-1, and illite IMt-1) were exposed to D. vulgaris in a non-growth medium with and without anthraquinone-2,6-disulfonate (AQDS) and sulfate. Our results demonstrated that D. vulgaris was able to reduce structural Fe(III) in these clay minerals, and AQDS enhanced the reduction rate and extent. In the presence of AQDS, sulfate had little effect on Fe(III) bioreduction. In the absence of AQDS, sulfate increased the reduction rate and capacity, suggesting that sulfide produced during sulfate reduction reacted with the phyllosilicate Fe(III). The extent of bioreduction of structural Fe(III) in the clay minerals was positively correlated with the percentage of smectite and mineral surface area of these minerals. X-ray diffraction, and scanning and transmission electron microscopy results confirmed formation of illite after bioreduction. These data collectively showed that D. vulgaris could promote smectite illitization through reduction of structural Fe(III) in clay minerals. © 2011 Blackwell Publishing Ltd.

The Tanami deep seismic reflection experiment: An insight into gold mineralization and Paleoproterozoic collision in the North Australian Craton

NASA Astrophysics Data System (ADS)

Goleby, Bruce R.; Huston, David L.; Lyons, Patrick; Vandenberg, Leon; Bagas, Leon; Davies, Brett M.; Jones, Leonie E. A.; Gebre-Mariam, Musie; Johnson, Wade; Smith, Tim; English, Luc

2009-07-01

Imaging of a major collision zone between the Tanami region and Aileron Province of the Arunta Orogen in Northern Australia, and recognition that several of the major gold deposits within the Tanami region are within near-surface antiformal stacks or uplifted and exhumed crustal sections associated with major crustal-penetrating shear zones, are fundamental results from the 2005 Tanami Seismic Collaborative Research Project. The suture, which is interpreted to have resulted from collision, separates the northwest-dipping structural grain of the Aileron Province crust in the south from the southeast-dipping structural grain of the Tanami crust in the northwest. The collision between the Tanami region and the Aileron Province is interpreted to have occurred prior to ca. 1840 Ma. The correlation between the surface extension of crustal-penetrating shear zones that extend to the Moho boundary and the locations of known gold-rich mineral fields is significant and has implications for minerals explorers within the Tanami region, and elsewhere. In the near-surface, where the crustal-penetrating structures cut relatively shallow upper crustal Tanami Group rocks, there is a significant increase in the degree of local deformation and results in through-going thrust faults, associated pop-up structures, ramp anticlines and antiformal stacking. All known ore deposits appear to be located within these more complexly deformed zones and therefore have a direct association with larger-scale structures.

Geology of the Vienna Mineralized Area, Blaine and Camas Counties, Idaho

USGS Publications Warehouse

Mahoney, J. Brian; Horn, Michael C.

2005-01-01

The Vienna mineralized area of south-central Idaho was an important silver-lead-producing district in the late 1800s and has intermittently produced lead, silver, zinc, copper, and gold since that time. The district is underlain by biotite granodiorite of the Cretaceous Idaho batholith, and all mineral deposits are hosted by the biotite granodiorite. The granodiorite intrudes Paleozoic sedimentary rocks of the Sun Valley Group, is overlain by rocks of the Eocene Challis Volcanic Group, and is cut by numerous northeast-trending Eocene faults and dikes. Two mineralogically and texturally distinct vein types are present in a northwest- and east-trending conjugate shear-zone system. The shear zones postdate granodiorite emplacement and joint formation, but predate Eocene fault and dike formation. Ribbon veins consist of alternating bands of massive vein quartz and silver-sulfide (proustite and pyrargyrite) mineral stringers. The ribbon veins were sheared and brecciated during multiple phases of injection of mineralizing fluids. A quartz-sericite-pyrite-galena vein system was subsequently emplaced in the brecciated shear zones. Both vein systems are believed to be the product of mesothermal, multiphase mineralization. K-Ar dating of shear-zone sericite indicates that sericitization occurred at 80.7?2.8 Ma; thus mineralization in the Vienna mineralized area probably is Late Cretaceous in age.

Thermal structure and geodynamics of subduction zones

NASA Astrophysics Data System (ADS)

Wada, Ikuko

The thermal structure of subduction zones depends on the age-controlled thermal state of the subducting slab and mantle wedge flow. Observations indicate that the shallow part of the forearc mantle wedge is stagnant and the slab-mantle interface is weakened. In this dissertation, the role of the interface strength in controlling mantle wedge flow, thermal structure, and a wide range of subduction zone processes is investigated through two-dimensional finite-element modelling and a global synthesis of geological and geophysical observations. The model reveals that the strong temperature-dependence of the mantle strength always results in full slab-mantle decoupling along the weakened part of the interface and hence complete stagnation of the overlying mantle. The interface immediately downdip of the zone of decoupling is fully coupled, and the overlying mantle is driven to flow at a rate compatible with the subduction rate. The sharpness of the transition from decoupling to coupling depends on the rheology assumed and increases with the nonlinearity of the flow system. This bimodal behaviour of the wedge flow gives rise to a strong thermal contrast between the cold stagnant and hot flowing parts of the mantle wedge. The maximum depth of decoupling (MDD) thus dictates the thermal regime of the forearc. Observed surface heat flow patterns and petrologically and geochemically estimated mantle wedge temperatures beneath the volcanic arc require an MDD of 70--80 km in most, if not all, subduction zones regardless of their thermal regime of the slab. The common MDD of 70--80 km explains the observed systematic variations of the petrologic, seismological, and volcanic processes with the thermal state of the slab and thus explains the rich diversity of subduction zones in a unified fashion. Models for warm-slab subduction zones such as Cascadia and Nankai predict shallow dehydration of the slab beneath the cold stagnant part of the mantle wedge, which provides ample fluid

Geology and mineral resources of central Antioquia Department (Zone IIA), Colombia

USGS Publications Warehouse

Hall, R.B.; Alvarez A., Jairo; Rico H., Hector

1973-01-01

This report summarizes the geology of an area of some 6000 square kilometers in the northern part of the Central Cordillera of the Colombian Andes. The area, in north-central Department of Antioquia, was mapped between 1964 and 1968 as part of the Inventario Minero Nacional (IMN) project. Mineral resources are summarized within a larger area, designated as subzone ILK of IMN Zone If, which comprises almost 22,000 sq. kin, including the area mapped geologically by IMN and additional areas mapped by other agencies. The oldest formation is a micaceous paragneiss of early Paleozoic or possibly late Precambrian age. A thick geosynclinal sedimentary series accumulated during the Paleozoic Era and became regionally metamorphosed to greenschist (locally amphibolite) facies during the Permian or early Triassic; these schists and gneisses are designated collectively as the Valdivia Group. The Permian(?) orogenic episode included intrusion of concordant syntectonic plutons, mostly of tonalitic composition. Rocks of unequivocal Triassic or Jurassic age are not recognized. The Cretaceous is well represented by both igneous and sedimentary assemblages. Eugeosynclinal alpine ophiolites comprising submarine basalt flows and numerous intrusions of gabbro and serpentinite are prominent in the Lower Cretaceous, together with flysch composed of marine shale and lesser sandstone and conglomerate. The Upper Cretaceous is represented along the west border of the mapped area by submarine basalt flows and pyroclastic rocks, locally Interbedded with fine-grained clastic sedimentary beds, and lenses of dark laminated chert, at least part of which is radiolarian. The Late Cretaceous was marked by an orogenic event that profoundly folded and faulted all rocks and in the Central Cordillera caused low-grade metamorphism, the overprint of which is hardly observable in pre-Cretaceous rocks elsewhere. The Late Cretaceous orogeny culminated with discordant intrusion of the epizonal tonalitic

Structural analysis characterization of permeability pathways across reservoir-seal interface - South-Eastern Utah; Results from integrated sedimentological, structural, and geochemical studies.

NASA Astrophysics Data System (ADS)

Petrie, E. S.; Evans, J. P.; Richey, D.; Flores, S.; Barton, C.; Mozley, P.

2015-12-01

Sedimentary rocks in the San Rafael Swell, Utah, were deformed by Laramide compression and subsequent Neogene extension. We evaluate the effect of fault damage zone morphology as a function of structural position, and changes in mechanical stratigraphy on the distribution of secondary minerals across the reservoir-seal pair of the Navajo Sandstone and overlying Carmel Formation. We decipher paleo-fluid migration and examine the effect faults and fractures have on reservoir permeability and efficacy of top seal for a range of geo-engineering applications. Map-scale faults have an increased probability of allowing upward migration of fluids along the fault plane and within the damage zone, potentially bypassing the top seal. Field mapping, mesoscopic structural analyses, petrography, and geochemical observations demonstrate that fault zone thickness increases at structural intersections, fault relay zones, fault-related folds, and fault tips. Higher densities of faults with meters of slip and dense fracture populations are present in relay zones relative to single, discrete faults. Curvature analysis of the San Rafael monocline and fracture density data show that fracture density is highest where curvature is highest in the syncline hinge and near faults. Fractures cross the reservoir-seal interface where fracture density is highest and structural diagensis includes mineralization events and bleaching and calcite and gypsum mineralization. The link between fracture distributions and structural setting implys that transmissive fractures have predictable orientations and density distributions. At the m- to cm- scale, deformation-band faults and joints in the Navajo Sandstone penetrate the reservoir-seal interface and transition into open-mode fractures in the caprock seal. Scanline analysis and petrography of veins provide evidence for subsurface mineralization and fracture reactivation, suggesting that the fractures act as loci for fluid flow through time

Plants Rather than Mineral Fertilization Shape Microbial Community Structure and Functional Potential in Legacy Contaminated Soil.

PubMed

Ridl, Jakub; Kolar, Michal; Strejcek, Michal; Strnad, Hynek; Stursa, Petr; Paces, Jan; Macek, Tomas; Uhlik, Ondrej

2016-01-01

Plant-microbe interactions are of particular importance in polluted soils. This study sought to determine how selected plants (horseradish, black nightshade and tobacco) and NPK mineral fertilization shape the structure of soil microbial communities in legacy contaminated soil and the resultant impact of treatment on the soil microbial community functional potential. To explore these objectives, we combined shotgun metagenomics and 16S rRNA gene amplicon high throughput sequencing with data analysis approaches developed for RNA-seq. We observed that the presence of any of the selected plants rather than fertilization shaped the microbial community structure, and the microbial populations of the root zone of each plant significantly differed from one another and/or from the bulk soil, whereas the effect of the fertilizer proved to be insignificant. When we compared microbial diversity in root zones versus bulk soil, we observed an increase in the relative abundance of Alphaproteobacteria, Betaproteobacteria, Gammaproteobacteria or Bacteroidetes, taxa which are commonly considered copiotrophic. Our results thus align with the theory that fast-growing, copiotrophic, microorganisms which are adapted to ephemeral carbon inputs are enriched in the vegetated soil. Microbial functional potential indicated that some genetic determinants associated with signal transduction mechanisms, defense mechanisms or amino acid transport and metabolism differed significantly among treatments. Genetic determinants of these categories tend to be overrepresented in copiotrophic organisms. The results of our study further elucidate plant-microbe relationships in a contaminated environment with possible implications for the phyto/rhizoremediation of contaminated areas.

Remote sensing applied to geological mapping; comparative geomorphology and identification of mineral zones of zinc and lead in the region of Vazante, MG. [Brazil

NASA Technical Reports Server (NTRS)

Nascimento, F. S. D. (Principal Investigator); Nascimento, M. A. L. S. D.

1977-01-01

The author has identified the following significant results. Results showed that the black and white aerial photographs and the color infrared transparencies were efficient for mapping of three lithological units of the Paraopeba formation and for mineralized zones identification, respectively. Multispectral transparencies of I2S made it easier to separate dolomites, which were the rocks conditioning zinc and lead mineralization. Statistical analysis of morphometric indexes obtained from black and white photographs and topographic charts showed significant difference among three lithological units of Paraopeba formation which can be defined as Crest, Hilly, and Karstic reliefs.

Seismic Structure of Mantle Transition Zone beneath Northwest Pacific Subduction Zone and its Dynamic Implication

NASA Astrophysics Data System (ADS)

Li, J.; Guo, G.; WANG, X.; Chen, Q.

2017-12-01

The northwest Pacific subduction region is an ideal location to study the interaction between the subducting slab and upper mantle discontinuities. Various and complex geometry of the Pacific subducting slab can be well traced downward from the Kuril, Japan and Izu-Bonin trench using seismicity and tomography images (Fukao and Obayashi, 2013). Due to the sparse distribution of seismic stations in the sea, investigation of the deep mantle structure beneath the broad sea regions is very limited. In this study, we applied the well- developed multiple-ScS reverberations method (Wang et al., 2017) to analyze waveforms recorded by the Chinese Regional Seismic Network, the densely distributed temporary seismic array stations installed in east Asia. A map of the topography of the upper mantle discontinuities beneath the broad oceanic regions in northwest Pacific subduction zone is imaged. We also applied the receiver function analysis to waveforms recorded by stations in northeast China and obtain the detailed topography map beneath east Asia continental regions. We then combine the two kinds of topography of upper mantle discontinuities beneath oceanic and continental regions respectively, which are obtained from totally different methods. A careful image matching and spatial correlation is made in the overlapping study regions to calibrate results with different resolution. This is the first time to show systematically a complete view of the topography of the 410-km and 660-km discontinuities beneath the east Asia "Big mantle wedge" (Zhao and Ohtani, 2009) covering the broad oceanic and continental regions in the Northwestern Pacific Subduction zone. Topography pattern of the 660 and 410 is obtained and discussed. Especially we discovered a broad depression of the 410-km discontinuity covering more than 1000 km in lateral, which seems abnormal in the cold subducting tectonic environment. Based on plate tectonic reconstruction studies and HTHP mineral experiments, we

Vectorial structures of linear-polarized Butterfly-Gauss vortex beams in the far zone

NASA Astrophysics Data System (ADS)

Cheng, Ke; Zhou, Yan; Lu, Gang; Yao, Na; Zhong, Xianqiong

2018-05-01

By introducing the Butterfly catastrophe to optics, the far-zone vectorial structures of Butterfly-Gauss beam with vortex and non-vortex are studied using the angular spectrum representation and stationary phase method. The influence of topological charge, linear-polarized angle, off-axis distance and scaling length on the far-zone vectorial structures, especially in the Poynting vector and angular momentum density of the corresponding beam is emphasized. The results show that the embedded optical vortex at source plane lead to special dark zones in the far zone, where the number of dark zone equals the absolute value of topological charge of optical vortex. Furthermore, the symmetry and direction of the special dark zones can be controlled by off-axis distance and scaling length, respectively. The linear-polarized angle adjusts only the Poynting vectors of TE and TM terms, but it does not affect those of whole beam. Finally, the vectorial expressions also indicate that the total angular momentum density is certainly zero owing to the far-zone stable structures rather than rotation behaviors.

Zircon growth in shear zones

NASA Astrophysics Data System (ADS)

Kaulina, Tatiana

2013-04-01

The possibility of direct dating of the deformation process is critical for understanding of orogenic belts evolution. Establishing the age of deformation by isotopic methods is indispensable in the case of uneven deformation overlapping, when later deformation inherits the structural plan of the early strains, and to distinguish them on the basis of the structural data only is impossible. A good example of zircon from the shear zones is zircon formed under the eclogite facies conditions. On the one hand, the composition of zircon speaks about its formation simultaneously to eclogitic paragenesis (Rubatto, Herman, 1999; Rubatto et al., 2003). On the other hand, geological studies show that mineral reactions of eclogitization are often held only in areas of shear deformations, which provides access of fluid to the rocks (Austrheim, 1987; Jamtveit et al., 2000; Bingen et al., 2004). Zircons from mafic and ultramafic rocks of the Tanaelv and Kolvitsa belts (Kola Peninsula, the Baltic Shield) have showed that the metamorphic zircon growth is probably controlled by the metamorphic fluid regime, as evidenced by an increase of zircon quantity with the degree of shearing. The internal structure of zircon crystals can provide an evidence of zircon growth synchronous with shearing. The studied crystals have a sector zoning and often specific "patchy" zoning (Fig. 1), which speaks about rapid change of growth conditions. Such internal structure can be compared with the "snowball" garnet structure reflecting the rotation of crystals during their growth under a shift. Rapidly changing crystallization conditions can also be associated with a small amount of fluid, where supersaturation is changing even at a constant temperature. Thus, the growth of metamorphic zircon in shear zones is more likely to occur in the fluid flow synchronous with deformation. A distinctive feature of zircons in these conditions is isometric shape and sector "patchy" zoning. The work was supported by

Using remote sensing techniques and field-based structural analysis to explore new gold and associated mineral sites around Al-Hajar mine, Asir terrane, Arabian Shield

NASA Astrophysics Data System (ADS)

Sonbul, Abdullah R.; El-Shafei, Mohamed K.; Bishta, Adel Z.

2016-05-01

Modern earth resource satellites provide huge amounts of digital imagery at different resolutions. These satellite imageries are considered one of the most significant sources of data for mineral exploration. Image processing techniques were applied to the exposed rocks around the Al-Aqiq area of the Asir terrane in the southern part of the Arabian Shield. The area under study has two sub-parallel N-S trending metamorphic belts of green-schist facies. The first belt is located southeast of Al-Aqiq, where the Al-Hajar Gold Mine is situated. It is essentially composed of metavolcanics and metasedimentary rocks, and it is intruded by different plutonic rocks of primarily diorite, syenite and porphyritic granite. The second belt is located northwest of Al-Aqiq, and it is composed of metavolcanics and metasedimentary rocks and is intruded by granite bodies. The current study aimed to distinguish the lithological units, detect and map the alteration zones, and extract the major fault lineaments around the Al-Hajar gold prospect. Digital satellite imageries, including Landsat 7 ETM + multispectral and panchromatic and SPOT-5 were used in addition to field verification. Areas with similar spectral signatures to the prospect were identified in the nearby metamorphic belt; it was considered as a target area and was inspected in the field. The relationships between the alteration zones, the mineral deposits and the structural elements were used to locate the ore-bearing zones in the subsurface. The metasedimentary units of the target area showed a dextral-ductile shearing top-to-the-north and the presence of dominant mineralized quartz vein-system. The area to the north of the Al-Hajar prospect showed also sub-parallel shear zones along which different types of alterations were detected. Field-based criteria such as hydrothermal breccia, jasper, iron gossans and porphyritic granite strongly indicate the presence of porphyry-type ore deposits in Al-Hajar metamorphic belt that

Structural Analysis of the Exhumed SEMP Fault Zone, Austria: Towards an Understanding of Fault Zone Architecture Throughout the Seismogenic Crust

NASA Astrophysics Data System (ADS)

Frost, E. K.; Dolan, J. F.; Sammis, C.; Hacker, B.; Ratschbacher, L.

2006-12-01

One of the most exciting and important frontiers in earthquake science is the linkage between the internal structure and the mechanical behavior of fault zones. In particular, little is known about how fault-zone structure varies as a function of depth, from near-surface conditions down through the seismogenic crust and into the ductile lower crust. Such understanding is vital if we are to understand the mechanical instabilities that control the nucleation and propagation of seismic ruptures. This imperative has led us to the Oligo-Miocene Salzach-Ennstal-Mariazell-Puchberg [SEMP] fault zone in Austria, a major left-lateral strike-slip fault that has been exhumed differentially such that it exposes a continuum of structural levels along strike. This exhumed fault system provides a unique opportunity to systematically examine depth-dependent changes in fault-zone geometry and structure along a single fault. In order to establish the structure of the fault zone in the seismogenic crust, we are studying exposures of this fault at a variety of exhumation levels, from <1 km near the eastern end of the fault, downward through the seismogenic crust, across the brittle-ductile transition, and into the uppermost part of the lower crust in western Austria. Here we present our results from one of these study sites, a spectacular exposure of the fault zone near the town of Gstatterboden in central Austria. The fault, which at this location has been exhumed from a depth of ~ 2-3 km, juxtaposes limestone of the Wettersteinkalk on the south with dolomite of the Ramsaudolomit on the north. We conducted two detailed structural traverses over a fault-perpendicular width of over 200 m. Analysis of the density and orientation of outcrop scale features, such as faults and fractures, reveals a highly asymmetric pattern of fault zone damage. Dolomite to the north of the fault is extensively shattered, while the limestone unit to the south shows only minor evidence of fault damage

Carbonate, Halide, and Other New Mineral Inclusions in Diamond and Deep-Seated Carbonatitic Magma

NASA Astrophysics Data System (ADS)

Kaminsky, F.; Wirth, R.; Matsyuk, S.

2009-05-01

A series of uncommon micro- and nano-inclusions was identified in diamonds from the Juina area: carbonates, halides, and others. Carbonates are represented by calcite (with Sr and Ba), K-rich nyerereite (K2O = 10.0-13.78 wt. %), and nahcolite. Halides are NaCl, KCl, CaCl2 and PbCl2. Minerals of the periclase- wüstite series belong to two separate groups: wüstite and Mg-wüstite with Mg# = 1.9-15.3, and Fe-periclase and periclase with Mg# = 84.9-92.1. Wollastonite-II (high, Ca: Si = 0.992) has a triclinic structure. Ca-rich garnet has a noticeable admixture of Zr; it belongs to the andradite - kimzeyite - schorlomite group. Two types of spinel were distinguished among mineral inclusions in diamond: zoned magnesioferrite (with Mg# varying from 13.5 in a core to 90.8 in a rim) and Fe-spinel (magnetite). Olivine (Mg# = 93.6), intergrown with nyerereite, forms elongated, lath-shaped crystal and, probably, is a retrograde transformation of ringwoodite or wadsleyite. Some apatite grains are enriched in La, Ce and Nd. Among other minerals, there are anhydrite, cuspidine, phlogopite, TiO2 with an α-PbO2 structure, native Fe. All inclusions are polymineralic solid inclusions. These minerals form a carbonatitic-type mineral association in diamond which may have been originated in lower mantle and/or transition zone. Wüstite inclusions with Mg# = 1.9-3.4, according to the experimental data, may have been formed in the lowermost mantle. The source for the observed carbonatitic-type mineral association in diamond is deep-seated carbonatitic, most likely natrocarbonatitic magma.

Low-Temperature Thermochronology for Unraveling Thermal Processes and Dating of Fault Zones

NASA Astrophysics Data System (ADS)

Tagami, T.

2016-12-01

Thermal signatures as well as timing of fault motions can be constrained by thermochronological analyses of fault-zone rocks (e.g., Tagami, 2012). Fault-zone materials suitable for such analyses are produced by tectocic and geochemical processes, such as (1) mechanical fragmentation of host rocks, grain-size reduction of fragments and recrystallization of grains to form mica and clay minerals, (2) secondary heating/melting of host rocks by frictional fault motions, and (3) mineral vein formation as a consequence of fluid advection associated with fault motions. The geothermal structure of fault zones are primarily controlled by the following three factors: (a) regional geothermal structure around the fault zone that reflect background thermo-tectonic history of studied province, (b) frictional heating of wall rocks by fault motions and resultant heat transfer into surrounding rocks, and (c) thermal influences by hot fluid advection in and around the fault zone. Thermochronological methods widely applied in fault zones are K-Ar (40Ar/39Ar), fission-track (FT), and U-Th methods. In addition, OSL, TL, ESR and (U-Th)/He methods are applied in some fault zones, in order to extract temporal imformation related to low temperature and/or very recent fault activities. Here I briefly review the thermal sensitivity of individual thermochronological systems, which basically controls the response of each method against faulting processes. Then, the thermal sensitivity of FTs is highlighted, with a particular focus on the thermal processes characteristic to fault zones, i.e., flash and hydrothermal heating. On these basis, representative examples as well as key issues, including sampling strategy, are presented to make thermochronologic analysis of fault-zone materials, such as fault gouges, pseudotachylytes and mylonites, along with geological, geomorphological and seismological implications. Finally, the thermochronologic analyses of the Nojima fault are overviewed, as an

Mineral exploration and fracture trends in Utah and Nevada, by ERTS-1 imagery

NASA Technical Reports Server (NTRS)

Jensen, M. L. (Principal Investigator); Smith, M. R.

1973-01-01

The author has identified the following significant results. Major structural trends have been compiled on five separate maps, at a scale of 1:1,000,000, of Utah and Nevada from ERTS-1 imagery. An arbitrary length of ten kilometers has been chosen as a minimum length of the trends. The selection is based upon: (1) obvious displacement of structures; (2) continuity or persistence of trends across structures; (3) line-up of outcrop patterns, drainage, erosional features or vegetation; and (4) near-linear trends. Several recognizable trend directions have noted, viz., N 10-15 deg W, N 35 deg W, N 80 deg W, N 30 deg E, and E-W. More than 1500 structural trends have been identified, some of which are mineralized and extend into pediment or shallow alluvial cover. Those fracture trends that exhibit mineralization in exposed bedrock will be assayed for mercury content with a soil-gas analyzer and similar collection will be done over alluvial posture blankets by the same technique with the hope of discovering blind mineralized zones that are not exposed on the surface.

Crystallographic controls on the frictional behavior of dry and water-saturated sheet structure minerals

USGS Publications Warehouse

Moore, Diane E.; Lockner, D.A.

2004-01-01

We compare the frictional strengths of 17 sheet structure mineral powders, measured under dry and water-saturated conditions, to identify the factors that cause many of them to be relatively weak. The dry coefficient of friction ?? ranges upward from 0.2 for graphite, leveling off at 0.8 for margarite, clintonite, gibbsite, kaolinite, and lizardite. The values of ?? (dry) correlate directly with calculated (001) interlayer bond strengths of the minerals. This correlation occurs because shear becomes localized along boundary and Riedel shears and the platy minerals in them rotate into alignment with the shear planes. For those gouges with ?? (dry) < 0.8, shear occurs by breaking the interlayer bonds to form new cleavage surfaces. Where ?? (dry) = 0.8, consistent with Byerlee's law, the interlayer bonds are sufficiently strong that other frictional processes dominate. The transition in dry friction mechanisms corresponds to calculated surface energies of 2-3 J/m2. Adding water causes ?? to decrease for every mineral tested except graphite. If the minerals are separated into groups with similar crystal structures, ?? (wet) increases with increasing interlayer bond strength within each group. This relationship also holds for the swelling clay montmorillonite, whose water-saturated strength is consistent with the strengths of nonswelling clays of similar crystal structure. Water in the saturated gouges forms thin, structured films between the plate surfaces. The polar water molecules are bonded to the plate surfaces in proportion to the mineral's surface energy, and ?? (wet) reflects the stresses required to shear through the water films. Copyright 2004 by the American Geophysical Union.

Redox properties of structural Fe in clay minerals: 3. Relationships between smectite redox and structural properties.

PubMed

Gorski, Christopher A; Klüpfel, Laura E; Voegelin, Andreas; Sander, Michael; Hofstetter, Thomas B

2013-01-01

Structural Fe in clay minerals is an important redox-active species in many pristine and contaminated environments as well as in engineered systems. Understanding the extent and kinetics of redox reactions involving Fe-bearing clay minerals has been challenging due to the inability to relate structural Fe(2+)/Fe(total) fractions to fundamental redox properties, such as reduction potentials (EH). Here, we overcame this challenge by using mediated electrochemical reduction (MER) and oxidation (MEO) to characterize the fraction of redox-active structural Fe (Fe(2+)/Fe(total)) in smectites over a wide range of applied EH-values (-0.6 V to +0.6 V). We examined Fe(2+)/Fe(total )- EH relationships of four natural Fe-bearing smectites (SWy-2, SWa-1, NAu-1, NAu-2) in their native, reduced, and reoxidized states and compared our measurements with spectroscopic observations and a suite of mineralogical properties. All smectites exhibited unique Fe(2+)/Fe(total) - EH relationships, were redox active over wide EH ranges, and underwent irreversible electron transfer induced structural changes that were observable with X-ray absorption spectroscopy. Variations among the smectite Fe(2+)/Fe(total) - EH relationships correlated well with both bulk and molecular-scale properties, including Fe(total) content, layer charge, and quadrupole splitting values, suggesting that multiple structural parameters determined the redox properties of smectites. The Fe(2+)/Fe(total) - EH relationships developed for these four commonly studied clay minerals may be applied to future studies interested in relating the extent of structural Fe reduction or oxidation to EH-values.

Geophysical ore guides along the Colorado mineral belt

USGS Publications Warehouse

Case, James E.

1967-01-01

A 40-50-mgal gravity low trends northeast along the Colorado mineral belt between Monarch Pass and Breckenridge, Colorado. The low is probably caused by a silicic Tertiary batholith of lower density than adjacent Precambrian crystalline rocks. Many major mining districts associated with silicic Tertiary intrusives are near the axis of the low. Positive and negative aeromagnetic anomalies are present over the larger silicic Tertiary intrusive bodies. A good correlation exists between the magnetic lows and zones of altered, mineralized porphyry. Apparently, original magnetite in the silicic porphyries has been altered to relatively nonmagnetic pyrite or iron oxides. The regional gravity low aids in defining the limits of the mineral belt, and the magnetic lows over the porphyries indicate specific alteration zones and the possibility of associated mineral deposits.

[Study on shape and structure of calcified cartilage zone in normal human knee joint].

PubMed

Wang, Fuyou; Yang, Liu; Duan, Xiaojun; Tan, Hongbo; Dai, Gang

2008-05-01

To explore the shape and structure of calcified cartilage zone and its interface between the non-calcified articular cartilage and subchondral bone plate. The normal human condyles of femur (n=20) were obtained from the tissue bank donated by the residents, 10 males and 10 females, aged 17-45 years. The longitudinal and transverse paraffin sections were prepared by the routine method. The shape and structure of calcified cartilage zone were observed with the Safranin O/fast green and von kossa stain method. The interface conjunction among zones of cartilage was researched by SEM and the 3D structural model was established by serial sections and modeling technique. Articular bone-cartilage safranin O/fast green staining showed that cartilage was stained red and subchondral bone was stained blue. The calcified cartilage zone was located between the tidemark and cement line. Von kossa staining showed that calcified cartilage zone was stained black and sharpness of structure border. Upper interface gomphosised tightly with the non-calcified cartilage by the wave shaped tidemark and lower interface anchored tightly with the subchondral bone by the uneven comb shaped cement line. The non-calcified cartilage zone was interlocked tightly in the manner of "ravine-engomphosis" by the calcified cartilage zone as observed under SEM, and the subchondral bone was anchored tightly in the manner of"comb-anchor" by the in the calcified cartilage zone 3D reconstruction model. The calcified cartilage zone is an important structure in the articular cartilage. The articular cartilage is fixed firmly into subchondral bone plate by the distinctive conjunct interfaces of calcified cartilage zone.

Mantle transition zone structure beneath India and Western China from migration of PP and SS precursors

NASA Astrophysics Data System (ADS)

Lessing, Stephan; Thomas, Christine; Rost, Sebastian; Cobden, Laura; Dobson, David P.

2014-04-01

We investigate the seismic structure of the upper-mantle and mantle transition zone beneath India and Western China using PP and SS underside reflections off seismic discontinuities, which arrive as precursors to the PP and SS arrival. We use high-resolution array seismic techniques to identify precursory energy and to map lateral variations of discontinuity depths. We find deep reflections off the 410 km discontinuity (P410P and S410S) beneath Tibet, Western China and India at depths of 410-440 km and elevated underside reflections of the 410 km discontinuity at 370-390 km depth beneath the Tien Shan region and Eastern Himalayas. These reflections likely correspond to the olivine to wadsleyite phase transition. The 410 km discontinuity appears to deepen in Central and Northern Tibet. We also find reflections off the 660 km discontinuity beneath Northern China at depths between 660 and 700 km (P660P and S660S) which could be attributed to the mineral transformation of ringwoodite to magnesiowuestite and perovskite. These observations could be consistent with the presence of cold material in the middle and lower part of the mantle transition zone in this region. We also find a deeper reflector between 700 and 740 km depth beneath Tibet which cannot be explained by a depressed 660 km discontinuity. This structure could, however, be explained by the segregation of oceanic crust and the formation of a neutrally buoyant garnet-rich layer beneath the mantle transition zone, due to subduction of oceanic crust of the Tethys Ocean. For several combinations of sources and receivers we do not detect arrivals of P660P and S660S although similar combinations of sources and receivers give well-developed P660P and S660S arrivals. Our thermodynamic modelling of seismic structure for a range of compositions and mantle geotherms shows that non-observations of P660P and S660S arrivals could be caused by the dependence of underside reflection coefficients on the incidence angle of the

Imaging and Analytical Approaches for Characterization of Soil Mineral Weathering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dohnalkova, Alice; Arey, Bruce; Varga, Tamas

Soil minerals weathering is the primary natural source of nutrients necessary to sustain productivity in terrestrial ecosystems. Soil microbial communities increase soil mineral weathering and mineral-derived nutrient availability through physical and chemical processes. Rhizosphere, the zone immediately surrounding plant roots, is a biogeochemical hotspot with microbial activity, soil organic matter production, mineral weathering, and secondary phase formation all happening in a small temporally ephemeral zone of steep geochemical gradients. The detailed exploration of the micro-scale rhizosphere is essential to our better understanding of large-scale processes in soils, such as nutrient cycling, transport and fate of soil components, microbial-mineral interactions, soilmore » erosion, soil organic matter turnover and its molecular-level characterization, and predictive modeling.« less

Spatial variation of sediment mineralization supports differential CO2 emissions from a tropical hydroelectric reservoir.

PubMed

Cardoso, Simone J; Vidal, Luciana O; Mendonça, Raquel F; Tranvik, Lars J; Sobek, Sebastian; Fábio, Roland

2013-01-01

Substantial amounts of organic matter (OM) from terrestrial ecosystems are buried as sediments in inland waters. It is still unclear to what extent this OM constitutes a sink of carbon, and how much of it is returned to the atmosphere upon mineralization to carbon dioxide (CO2). The construction of reservoirs affects the carbon cycle by increasing OM sedimentation at the regional scale. In this study we determine the OM mineralization in the sediment of three zones (river, transition, and dam) of a tropical hydroelectric reservoir in Brazil as well as identify the composition of the carbon pool available for mineralization. We measured sediment organic carbon mineralization rates and related them to the composition of the OM, bacterial abundance and pCO2 of the surface water of the reservoir. Terrestrial OM was an important substrate for the mineralization. In the river and transition zones most of the OM was allochthonous (56 and 48%, respectively) while the dam zone had the lowest allochthonous contribution (7%). The highest mineralization rates were found in the transition zone (154.80 ± 33.50 mg C m(-) (2) d(-) (1)) and the lowest in the dam (51.60 ± 26.80 mg C m(-) (2) d(-) (1)). Moreover, mineralization rates were significantly related to bacterial abundance (r (2) = 0.50, p < 0.001) and pCO2 in the surface water of the reservoir (r (2) = 0.73, p < 0.001). The results indicate that allochthonous OM has different contributions to sediment mineralization in the three zones of the reservoir. Further, the sediment mineralization, mediated by heterotrophic bacteria metabolism, significantly contributes to CO2 supersaturation in the water column, resulting in higher pCO2 in the river and transition zones in comparison with the dam zone, affecting greenhouse gas emission estimations from hydroelectric reservoirs.

Mechanical Properties of Mineralized Collagen Fibrils As Influenced By Demineralization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Balooch, M.; Habelitz, S.; Kinney, J.H.

2009-05-11

Dentin and bone derive their mechanical properties from a complex arrangement of collagen type-I fibrils reinforced with nanocrystalline apatite mineral in extra- and intrafibrillar compartments. While mechanical properties have been determined for the bulk of the mineralized tissue, information on the mechanics of the individual fibril is limited. Here, atomic force microscopy was used on individual collagen fibrils to study structural and mechanical changes during acid etching. The characteristic 67 nm periodicity of gap zones was not observed on the mineralized fibril, but became apparent and increasingly pronounced with continuous demineralization. AFM-nanoindentation showed a decrease in modulus from 1.5 GPamore » to 50 MPa during acid etching of individual collagen fibrils and revealed that the modulus profile followed the axial periodicity. The nanomechanical data, Raman spectroscopy and SAXS support the hypothesis that intrafibrillar mineral etches at a substantially slower rate than the extrafibrillar mineral. These findings are relevant for understanding the biomechanics and design principles of calcified tissues derived from collagen matrices.« less

Diagenesis of clay mineral assemblages in the Shikoku Basin: Inputs to the Nankai Trough megathrust and seismogenic zone

NASA Astrophysics Data System (ADS)

Underwood, M.; Guo, J.; Song, C.

2012-12-01

One of the essential components of the Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE) is to document the composition and diagenetic alteration of sedimentary inputs to the subduction zone of SW Japan. Two sites were drilled seaward of the trench during IODP Expeditions 322 and 333 to demonstrate how those subduction inputs have been influenced by the basement topography of Shikoku Basin. Site C0011 was drilled on the NW flank of Kashinosaki Knoll, and Site C0012 is located near the seamount's summit. The lithostratigraphy expands and condenses from site to site, but the clay mineral assemblages are nearly identical when comparisons are made among coeval units. The early history of sedimentation (middle to late Miocene) was dominated by expandable clay minerals of the smectite group. Contents of smectite in strata older than 5.3 Ma typically exceed 65% of the clay-size fraction, and there are dozens of bentonite layers (altered volcanic ash) interbedded with the hemipelagic mudstones and turbidites. Those percentages amount to >45 wt-% smectite in the bulk mudstone. Volcanic sources for the Miocene clay probably included the ancestral Izu-Bonin island arc, the Izu-Honshu collision zone, and anomalous near-trench magma bodies in the Outer Zone of Honshu and Shikoku Island. As sedimentation progressed into the Pliocene and Pleistocene, mud supplies to the Shikoku Basin shifted increasingly to detrital illite and chlorite eroded from the uplifted accretionary complex (Outer Zone). At Site C0011, the younger hemipelagic-pyroclastic facies (upper Shikoku Basin) contains an average of 43% smectite, 36% illite, and 18% kaolinite + chlorite in the clay-size fraction. At Site C0012, comparable values are S = 51%, I = 32%, and K+C = 14%. XRD results show no evidence of smectite-to-illite diagenesis seaward of the trench, although it is important to note that Site C0011 was abandoned before reaching basaltic basement. We can predict the extent of smectite

The Importance of Southern Hemisphere CZOs for Evaluating Spatial Patterns of Chemical Structure in the Critical Zone and Assisting Human Development

NASA Astrophysics Data System (ADS)

Chadwick, O.

2014-12-01

The US Critical Zone Exploration Network (CZEN) is a network of sites designed to provide a better understanding of the integrated Earth surface system. The capacity of the critical zone to withstand perturbations, whether driven by climate, land use change, or spread of invasive species, depends on its chemical composition and physical state, which in turn depends on the time evolution of the critical zone. Many temperate and/or tectonically active critical zones contain a relatively short history due to rapid erosion but tectonically quiescent, tropical regions of the planet contain much longer records that need to be understood to cover the full suite of critical zone processes. Southern Hemisphere Critical Zone Observatories such as those proposed for Kruger National Park (KNP) in South Africa and for portions of the Yilgarn Craton in Western Australa will allow us to extend our temporal understanding of development of spatial heterogeneity in the chemical and physical structure of the critical zone. In addition to considering Earth and climate boundary conditions, these sites incorporate the roles that humans play in driving critical zone processes. For instance along the edges of KNP there is strong evidence of soil erosions due to periurbanization and small-scale agriculture. The existence of KNP provides an important contrast between a "natural" and "human-dominated" landscape that can be exploited to evaluate human impacts on critical zone resources and to develop targeted mitigation strategies. Western Australia has an exploitive economy that relies on large-scale agriculture and mineral extraction, both are intensive users of water which is scarce. The proposed CZO there will be partly focused on managing water under intense economic pressures. It is evident that if funding can be found for these sites they will enhance both critical zone science and practical applied science.

Fine-tuning structural RNA alignments in the twilight zone

PubMed Central

2010-01-01

Background A widely used method to find conserved secondary structure in RNA is to first construct a multiple sequence alignment, and then fold the alignment, optimizing a score based on thermodynamics and covariance. This method works best around 75% sequence similarity. However, in a "twilight zone" below 55% similarity, the sequence alignment tends to obscure the covariance signal used in the second phase. Therefore, while the overall shape of the consensus structure may still be found, the degree of conservation cannot be estimated reliably. Results Based on a combination of available methods, we present a method named planACstar for improving structure conservation in structural alignments in the twilight zone. After constructing a consensus structure by alignment folding, planACstar abandons the original sequence alignment, refolds the sequences individually, but consistent with the consensus, aligns the structures, irrespective of sequence, by a pure structure alignment method, and derives an improved sequence alignment from the alignment of structures, to be re-submitted to alignment folding, etc.. This circle may be iterated as long as structural conservation improves, but normally, one step suffices. Conclusions Employing the tools ClustalW, RNAalifold, and RNAforester, we find that for sequences with 30-55% sequence identity, structural conservation can be improved by 10% on average, with a large variation, measured in terms of RNAalifold's own criterion, the structure conservation index. PMID:20433706

Fine-tuning structural RNA alignments in the twilight zone.

PubMed

Bremges, Andreas; Schirmer, Stefanie; Giegerich, Robert

2010-04-30

A widely used method to find conserved secondary structure in RNA is to first construct a multiple sequence alignment, and then fold the alignment, optimizing a score based on thermodynamics and covariance. This method works best around 75% sequence similarity. However, in a "twilight zone" below 55% similarity, the sequence alignment tends to obscure the covariance signal used in the second phase. Therefore, while the overall shape of the consensus structure may still be found, the degree of conservation cannot be estimated reliably. Based on a combination of available methods, we present a method named planACstar for improving structure conservation in structural alignments in the twilight zone. After constructing a consensus structure by alignment folding, planACstar abandons the original sequence alignment, refolds the sequences individually, but consistent with the consensus, aligns the structures, irrespective of sequence, by a pure structure alignment method, and derives an improved sequence alignment from the alignment of structures, to be re-submitted to alignment folding, etc.. This circle may be iterated as long as structural conservation improves, but normally, one step suffices. Employing the tools ClustalW, RNAalifold, and RNAforester, we find that for sequences with 30-55% sequence identity, structural conservation can be improved by 10% on average, with a large variation, measured in terms of RNAalifold's own criterion, the structure conservation index.

A petro-structural review of the Zermatt-Saas Fee zone

NASA Astrophysics Data System (ADS)

Schenker, Filippo Luca; Markus Schmalholz, Stefan; Baumgartner, Lukas

2014-05-01

The Zermatt-Saas Fee zone (ZSZ) is an imbricate of fragments of blueschist- to eclogite-facies metabasalts and metagabbros, serpentinites and mélange zones containing blocks of the above mentioned rocks. The ZSZ is usually interpreted as a fragment of oceanic crust belonging to the Piemont-Ligurian (Tethyan) Ocean that was accreted into the Alpine nappe pile. In the last decades the discovery of several Ultra-High Pressure (UHP, >2.7 GPa at 550-600 °C from coesite bearing eclogites and diamond-bearing fluid inclusions in garnet) localities lead to the interpretation of deep subduction (> 100 km) of the ZSZ in the Eocene, and subsequent uplift from mantle depth with high exhumation rates (e.g. Amato et al., 1999). However, these high pressures are in apparent contrast to the regional metamorphic conditions that reflect pressures peaking at < 2 GPa for 550-600°C (blueschist and eclogite mineral assemblages in mafic rocks). These latter metamorphic conditions do not need anomalous high burial histories and exhumation velocities higher than the plate velocities. The magnitude and distribution of pressure in the tectonic units of the ZSZ are important for constraining dynamic models for the evolution of the ZSZ and the Western Alps. Before entering into dynamic models, we propose a petro-structural overview where the published petrological data on pressure and temperature are critically reviewed, and positioned on a geological map and cross section in order to integrate them into the proper structural and tectonic framework. The questions we seek to answer are: How is the pressure distributed within the main tectonic units and within the entire ZSZ? Do we observe sharp or gradual pressure gradients within the ZSZ? Can the UHP conditions be averaged/extended to the entire ZSZ? If not, do they correspond to conditions of observable subunits, or do they reflect anomalies in the pressure field? Answering these questions is fundamental to better understand the

Permeability and strength structure around an ancient exhumed subduction-zone fault

NASA Astrophysics Data System (ADS)

Kato, A.; Sakaguchi, A.; Yoshida, S.; Kaneda, Y.

2003-12-01

Investigating the transporting properties of subduction zone faults is crucial for understanding shear strength and slip-stability, or instability, of subduction zone faults. Despite the influence of pore pressure on a wide range of subduction-zone fault processes, few previous studies have evaluated the permeability structure around the fault placed in a well-defined structural context. In this study, the aim is to gain the entire permeability and the shear strength structure around the ancient subduction zone fault. We have conducted a series of permeability measurements and shear failure experiments in seismogenic environments using intact rocks sampled at the outcrop of an exhumed fault zone in the Cretaceous Shimanto accretionary complex, in Shikoku, SW Japan, where a typical evidence for seismic fault rock of pseudotachylyte has been demonstrated [Ikesawa et al., 2003]. This fault zone is located at boundary between the sandstone-dominant coherent unit of the Nonokawa Formation and the Okitsu mélange. The porosity of each rock sample is less than 1 %, except for the shear zone. Cylindrical test specimens (length = 40 mm, diameter = 20 mm) were cored to an accuracy of within 0.02 mm. Most of values of permeability were evaluated at confining pressure Pc of 140 MPa and pore pressure Pp of 115 MPa simulating the depth of 5 km (suprahydrostatic pore pressure). It is found that the permeability at room temperature shows the heterogeneous structure across the fault zone. The permeability of sandstone-dominant coherent unit is the lowest (10-19 m2) across the fault zone. In contrast, high shear zone has the highest permeability (10-16 m2). Following the increase in temperature, permeability evolution has been investigated. The permeability at 250oC continuously decreases with hold time for all types of rock specimens, and the reduction rate of permeability against hold time seems to become small with hold time. It seems that the reduction rate does not

New approach to the boundary-parallel plastic / viscous diapiric flow patterns in the curvilinear boundary zones: an implication for structural geology studies

NASA Astrophysics Data System (ADS)

Sarkarinejad, Khalil

2010-05-01

New approach to the boundary-parallel plastic / viscous diapiric flow patterns in the curvilinear boundary zones: an implication for structural geology studies Khalil Sarkarinejad and Abdolreza Partabian Department of Earth Sciences, College of Sciences, Shiraz University, Shiraz, Iran (Sarkarinejad@geology.susc.ac.ir). In the oceanic diverging away plates, the asthenospheric flow at solidus high-temperature conditions typically produces mineral foliations and lineations in peridotites. Foliation and lineation of mantle are defined by preferred flattening and alignment of olivine, pyroxene and spinel. In the areas with steep foliations trajectories which are associated with the steeply plunging stretching lineation trajectories, reflecting localized vertical flow and has been related to mantle diapir. The mantle flow patterns are well documented through detail structural mapping of the Neyriz ophiolite along the Zagros inclined dextral transpression and Oman ophiolite. Such models of the diverging asthenaspheric mantle flow and formation of mantle diapir are rarely discussed and paid any attention in the mathematical models of transpressional deformation in converging continental crusts. Systematic measurements of the mineral preferred orientations and construction of the foliation and lineation trajectories of the Zagros high-strain zone reveal two diapers with the shape of the inclined NW-SE boundary-parallel semi-ellipses shape and one rotated asymmetric diapir. These diapers made of quartzo-feldspathic gneiss and garnet amphibolite core with phyllite, phyllonite, muscovite schist and deformed conglomerate as a cover sequences. These boundary-parallel and rotated diapirs are formed by the interaction of Afro-Arabian lower to middle continental detachment and hot subdacting Tethyan oceanic crust, due to increasing effective pressure and temperature. The plastic/viscous gneissic diapers were squeezed between in Zagros transpression curvilinear boundary zones in an

[Effect of Seasonal Temperature Increasing on Nitrogen Mineralization in Soil of the Water Level Fluctuating Zone of Three Gorge Tributary During the Dry Period].

PubMed

Lin, Jun-jie; Zhang, Shuai; Liu, Dan; Zhou, Bin; Xiao, Xiao-jun; Ma, Hui-yan; Yu, Zhi-guo

2016-02-15

To reveal the effect of seasonal temperature increasing on nitrogen mineralization in soil of the water level fluctuating soil zone of three gorge reservoir areas in the Yangtze river tributary during the dry period, surface soils were collected from the water level fluctuating zone of Pengxi river crossing two hydrological sections, i.e., upstream and downstream and three water level altitudes, 155 m (low), 165 m (middle) and 175 m (high). We incubated the soil at 25 degrees C and 35 degrees C to determine the transformation rates of nitrogen in soil of Pengxi river basin during the dry period. The result showed that TN and NO3- -N contents in the soil of upstream section and higher (175 m) altitude of water level were higher than those in downstream and low (165 m) altitude of water level, whereas the pattern for NH4+ -N was different, with higher NH4+ -N contents in downstream and low water level. The inorganic nitrogen was dominated by NO3- -N, which accounted for up to 57.4%-84.7% of inorganic nitrogen. Generally, soil ammoniation, nitration and net N mineralization increased with the rising water level altitude and stream sections (P < 0.05). In summary, nitration and net N mineralization significantly increased with increasing temperature, (P < 0.05), while ammoniation showed no difference (P > 0.05).

Crystal structure of ilyukhinite, a new mineral of the eudialyte group

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rastsvetaeva, R. K., E-mail: rast@crys.ras.ru; Rozenberg, K. A.; Chukanov, N. V.

The crystal structure of ilyukhinite, a new mineral of the eudialyte group, is studied by X-ray diffraction. The mineral found in pegmatite bodies of the Kukisvumchorr Mountain (Khibiny alkaline complex) is characterized by low sodium content, high degree of hydration, and predominance of manganese over iron. The trigonal cell has the following parameters: a = 14.1695(6) and c = 31.026(1) Å; space group R3m. The structure is refined to final R = 0.046 in the anisotropic approximation of atomic displacements using 1527F > 3σF. The idealized formula of ilyukhinite (Z = 3) is written as (H{sub 3}O,Na){sub 14}Ca{sub 6}Mn{sub 2}Zr{submore » 3}Si{sub 26}O{sub 72}(OH){sub 2} · 3H{sub 2}O. The new mineral differs from other representatives of the eudialyte group by the predominance of both oxonium in the N positions of extra-framework cations and manganese in the Ðœ2 position centering the tetragonal pyramid.« less

The hydraulic structure of the Gole Larghe Fault Zone (Italian Southern Alps) through the seismic cycle

NASA Astrophysics Data System (ADS)

Bistacchi, A.; Mittempergher, S.; Di Toro, G.; Smith, S. A. F.; Garofalo, P. S.

2017-12-01

The 600 m-thick, strike slip Gole Larghe Fault Zone (GLFZ) experienced several hundred seismic slip events at c. 8 km depth, well-documented by numerous pseudotachylytes, was then exhumed and is now exposed in beautiful and very continuous outcrops. The fault zone was also characterized by hydrous fluid flow during the seismic cycle, demonstrated by alteration halos and precipitation of hydrothermal minerals in veins and cataclasites. We have characterized the GLFZ with > 2 km of scanlines and semi-automatic mapping of faults and fractures on several photogrammetric 3D Digital Outcrop Models (3D DOMs). This allowed us obtaining 3D Discrete Fracture Network (DFN) models, based on robust probability density functions for parameters of fault and fracture sets, and simulating the fault zone hydraulic properties. In addition, the correlation between evidences of fluid flow and the fault/fracture network parameters have been studied with a geostatistical approach, allowing generating more realistic time-varying permeability models of the fault zone. Based on this dataset, we have developed a FEM hydraulic model of the GLFZ for a period of some tens of years, covering one seismic event and a postseismic period. The higher permeability is attained in the syn- to early post-seismic period, when fractures are (re)opened by off-fault deformation, then permeability decreases in the postseismic due to fracture sealing. The flow model yields a flow pattern consistent with the observed alteration/mineralization pattern and a marked channelling of fluid flow in the inner part of the fault zone, due to permeability anisotropy related to the spatial arrangement of different fracture sets. Amongst possible seismological applications of our study, we will discuss the possibility to evaluate the coseismic fracture intensity due to off-fault damage, and the heterogeneity and evolution of mechanical parameters due to fluid-rock interaction.

Surface-structural Control on Minor Element Zoning and Growth Mechanism in Synthetic Magmatic Clinopyroxene

NASA Astrophysics Data System (ADS)

Paquette, J.; Deakin, M.; Baker, D. R.

2006-12-01

Because in situ observations of actively growing surfaces are technically impractical, our understanding of crystal growth mechanisms at hydrothermal and magmatic conditions lags behind that of minerals that can be grown from aqueous solutions at or near room temperature. Growing silicate minerals from hydrous synthetic carbonate melts offers the opportunity to relate directly minor element incorporation to their surface microtopography. Natural hydrothermal diopside was used to seed experiments in which synthetic clinopyroxene crystals were grown at 800 degrees C and 10 kbars for 24 hours, from alkaline melts modelled after the lavas of the Tanzanian volcano Oldoinyo Lengai. The melts were prepared from Na2CO3, K2CO3, CaCO3, MgCO3 and Fe3O4 reagents. One run was anhydrous and the others contained either 2.5 or 5 wt. % H2O. Euhedral tabular crystals ranging in size from 100 to 300 ìm across were found in all three runs, hand-picked and freed from their carbonate matrix by overnight immersion in dilute acetic acid. The crystals consist of \\{110\\} prism, \\{100\\} and \\{001\\} pinacoids and a \\{111\\} dipyramid. AFM images resolved a distinct surface microtopography on each form: arrays of broad macrosteps on \\{100\\}, lens- shaped islands on \\{001\\} facets and striated fiber-like crystallites on \\{110\\}. EMP analyses of polished grain mounts show that compositional zoning of Na and Fe occurs not only among non-equivalent growth sectors but also within single \\{100\\} sectors. Electron microprobe maps of sequentially polished sections indicate that zoning within \\{100\\} sectors reflects differential uptake of Na and Fe on symmetrically non-equivalent steps. Near the crystal surface, the non- equivalent coeval vicinal faces of growth hillocks on \\{100\\} are either diopside-like, Na.007Ca1.00(Mg0.754Fe2+0.22Mn2+0.013Al_{0.003)Si2.00O6 , or acmitic, Ca0.63Na0.35(Mg0.64Fe3+ 0.36)Al0.01Si1.99O6 in composition. Step-specific incorporation of minor elements

Subsurface structures of the active reverse fault zones in Japan inferred from gravity anomalies.

NASA Astrophysics Data System (ADS)

Matsumoto, N.; Sawada, A.; Hiramatsu, Y.; Okada, S.; Tanaka, T.; Honda, R.

2016-12-01

The object of our study is to examine subsurface features such as continuity, segmentation and faulting type, of the active reverse fault zones. We use the gravity data published by the Gravity Research Group in Southwest Japan (2001), the Geographical Survey Institute (2006), Yamamoto et al. (2011), Honda et al. (2012), and the Geological Survey of Japan, AIST (2013) in this study. We obtained the Bouguer anomalies through terrain corrections with 10 m DEM (Sawada et al. 2015) under the assumed density of 2670 kg/m3, a band-pass filtering, and removal of linear trend. Several derivatives and structural parameters calculated from a gravity gradient tensor are applied to highlight the features, such as a first horizontal derivatives (HD), a first vertical derivatives (VD), a normalized total horizontal derivative (TDX), a dip angle (β), and a dimensionality index (Di). We analyzed 43 reverse fault zones in northeast Japan and the northern part of southwest Japan among major active fault zones selected by Headquarters for Earthquake Research Promotion. As the results, the subsurface structural boundaries clearly appear along the faults at 21 faults zones. The weak correlations appear at 13 fault zones, and no correlations are recognized at 9 fault zones. For example, in the Itoigawa-Shizuoka tectonic line, the subsurface structure boundary seems to extend further north than the surface trace. Also, a left stepping structure of the fault around Hakuba is more clearly observed with HD. The subsurface structures, which detected as the higher values of HD, are distributed on the east side of the surface rupture in the north segments and on the west side in the south segments, indicating a change of the dip direction, the east dipping to the west dipping, from north to south. In the Yokote basin fault zone, the subsurface structural boundary are clearly detected with HD, VD and TDX along the fault zone in the north segment, but less clearly in the south segment. Also, Di

Bone geometry, structure and mineral distribution using Dual energy X ray Absorptiometry (DXA)

NASA Technical Reports Server (NTRS)

Whalen, Robert; Cleek, Tammy

1993-01-01

Dual energy x-ray absorptiometry (DXA) is currently the most widely used method of analyzing regional and whole body changes in bone mineral content (BMC) and areal (g/sq cm) bone mineral density (BMD). However, BMC and BMD do not provide direct measures of long bone geometry, structure, or strength nor do regional measurements detect localized changes in other regions of the same bone. The capabilities of DXA can be enhanced significantly by special processing of pixel BMC data which yields cross-sectional geometric and structural information. We have extended this method of analysis in order to develop non-uniform structural beam models of long bones.

Nanoparticles of noble metals in the supergene zone

NASA Astrophysics Data System (ADS)

Zhmodik, S. M.; Kalinin, Yu. A.; Roslyakov, N. A.; Mironov, A. G.; Mikhlin, Yu. L.; Belyanin, D. K.; Nemirovskaya, N. A.; Spiridonov, A. M.; Nesterenko, G. V.; Airiyants, E. V.; Moroz, T. N.; Bul'bak, T. A.

2012-04-01

Formation of noble metal nanoparticles is related to various geological processes in the supergene zone. Dispersed mineral phases appear during weathering of rocks with active participation of microorganisms, formation of soil, in aqueous medium and atmosphere. Invisible gold and other noble metals are incorporated into oxides, hydroxides, and sulfides, as well as in dispersed organic and inorganic carbonic matter. Sulfide minerals that occur in bedrocks and ores unaltered by exogenic processes and in cementation zone are among the main concentrators of noble metal nanoparticles. The ability of gold particles to disaggregate is well-known and creates problems in technological and analytical practice. When Au and PGE nanoparticles and clusters occur, these problems are augmented because of their unusual reactions and physicochemical properties. The studied gold, magnetite, titanomagnetite and pyrite microspherules from cementation zone and clay minerals of laterites in Republic of Guinea widen the knowledge of their abundance and inferred formation conditions, in particular, in the contemporary supergene zone. Morphology and composition of micrometer-sized Au mineral spherules were studied with SEM and laser microprobe. The newly formed segregations of secondary gold on the surface of its residual grains were also an object of investigation. The character of such overgrowths is the most indicative for nanoparticles. The newly formed Au particles provide evidence for redistribution of ultradispersed gold during weathering. There are serious prerequisites to state that microorganisms substantially control unusual nano-sized microspherical morphology of gold particles in the supergene zone. This is supported by experiments indicating active absorption of gold by microorganisms and direct evidence for participation of Ralstonia metallidurans bacteria in the formation of peculiar corroded bacteriomorphic surface of gold grains. In addition, the areas enriched in carbon

The upper-mantle transition zone beneath the Chile-Argentina flat subduction zone

NASA Astrophysics Data System (ADS)

Bagdo, Paula; Bonatto, Luciana; Badi, Gabriela; Piromallo, Claudia

2016-04-01

The main objective of the present work is the study of the upper mantle structure of the western margin of South America (between 26°S and 36°S) within an area known as the Chile-Argentina flat subduction zone. For this purpose, we use teleseismic records from temporary broad band seismic stations that resulted from different seismic experiments carried out in South America. This area is characterized by on-going orogenic processes and complex subduction history that have profoundly affected the underlying mantle structure. The detection and characterization of the upper mantle seismic discontinuities are useful to understand subduction processes and the dynamics of mantle convection; this is due to the fact that they mark changes in mantle composition or phase changes in mantle minerals that respond differently to the disturbances caused by mantle convection. The discontinuities at a depth of 410 km and 660 km, generally associated to phase changes in olivine, vary in width and depth as a result of compositional and temperature anomalies. As a consequence, these discontinuities are an essential tool to study the thermal and compositional structure of the mantle. Here, we analyze the upper-mantle transition zone discontinuities at a depth of 410 km and 660 km as seen from Pds seismic phases beneath the Argentina-Chile flat subduction.

Hyperspectral remote sensing applied to mineral exploration in southern Peru: A multiple data integration approach in the Chapi Chiara gold prospect

NASA Astrophysics Data System (ADS)

Carrino, Thais Andressa; Crósta, Alvaro Penteado; Toledo, Catarina Labouré Bemfica; Silva, Adalene Moreira

2018-02-01

Remote sensing is a strategic key tool for mineral exploration, due to its capacity of detecting hydrothermal alteration minerals or alteration mineral zones associated with different types of mineralization systems. A case study of an epithermal system located in southern Peru is presented, aimed at the characterization of mineral assemblies for discriminating potential high sulfidation epithermal targets, using hyperspectral imagery integrated with petrography, XRD and magnetic data. HyMap images were processed using the Mixture Tuned Matched Filtering (MTMF) technique for producing alteration map in the Chapi Chiara epithermal gold prospect. Extensive areas marked by advanced argillic alteration (alunite-kaolinite-dickite ± topaz) were mapped in detail, as well as limited argillic (illite-smectite) and propylitic (chlorite spectral domain) alteration. The magmatic-hydrothermal processes responsible for the formation of hypogene minerals were also related to the destruction of ferrimagnetic minerals (e.g., magnetite) of host rocks such as andesite, and the remobilization/formation of paramagnetic Fe-Ti oxides (e.g., rutile, anatase). The large alteration zones of advanced argillic alteration are controlled by structures related to a regional NW-SE trend, and also by local NE-SW and ENE-WSW ones.

Mineral resources prospecting by synthetic application of TM/ETM+, Quickbird and Hyperion data in the Hatu area, West Junggar, Xinjiang, China

PubMed Central

Liu, Lei; Zhou, Jun; Jiang, Dong; Zhuang, Dafang; Mansaray, Lamin R.; Hu, Zhijun; Ji, Zhengbao

2016-01-01

The Hatu area, West Junggar, Xinjiang, China, is situated at a potential gold-copper mineralization zone in association with quartz veins and small granitic intrusions. In order to identify the alteration zones and mineralization occurrences in this area, the Landsat Thematic Mapper (TM) and Enhanced Thematic Mapper (ETM+), Quickbird, Hyperion data and laboratory measured spectra were combined in identifying structures, alteration zones, quartz veins and small intrusions. The hue-saturation-intensity (HSI) color model transformation was applied to transform principal component analysis (PCA) combinations from R (Red), G (Green) and B (Blue) to HSI space to enhance faults. To wipe out the interference of the noise, a method, integrating Crosta technique and anomaly-overlaying selection, was proposed and implemented. Both Jet Propulsion Laboratory Spectral Library spectra and laboratory-measured spectra, combining with matched filtering method, were used to process Hyperion data. In addition, high-resolution Quickbird data were used for unraveling the quartz veins and small intrusions along the alteration zones. The Baobei fault and a SW-NE-oriented alteration zone were identified for the first time. This study eventually led to the discovery of four weak gold-copper mineralized locations through ground inspection and brought new geological knowledge of the region’s metallogeny. PMID:26911195

Mapping Hydrothermal Alteration Zones at a Sediment-Hosted Gold Deposit - Goldstrike Mining District, Utah, Using Ground-Based Hyperspectral Imaging

NASA Astrophysics Data System (ADS)

Krupnik, D.; Khan, S.; Crockett, M.

2017-12-01

Understanding the origin, genesis, as well as depositional and structural mechanisms of gold mineralization as well as detailed mapping of gold-bearing mineral phases at centimeter scale can be useful for exploration. This work was conducted in the Goldstrike mining district near St. George, UT, a structurally complex region which contains Carlin-style disseminated gold deposits in permeable sedimentary layers near high-angle fault zones. These fault zones are likely a conduit for gold-bearing hydrothermal fluids, are silicified, and are frequently gold-bearing. Alteration patterns are complex, difficult to distinguish visually, composed of several phases, and vary significantly over centimeter to meter scale distances. This makes identifying and quantifying the extent of the target zones costly, time consuming, and discontinuous with traditional geochemical methods. A ground-based hyperspectral scanning system with sensors collecting data in the Visible Near Infrared (VNIR) and Short-Wave Infrared (SWIR) portions of the electromagnetic spectrum are utilized for close-range outcrop scanning. Scans were taken of vertical exposures of both gold-bearing and barren silicified rocks (jasperoids), with the intent to produce images which delineate and quantify the extent of each phase of alteration, in combination with discrete geochemical data. This ongoing study produces mineralogical maps of surface minerals at centimeter scale, with the intent of mapping original and alteration minerals. This efficient method of outcrop characterization increases our understanding of fluid flow and alteration of economic deposits.

Detailed mineral and chemical relations in two uranium-vanadium ores

USGS Publications Warehouse

Garrels, Robert M.; Larsen, E. S.; Pommer, A.M.; Coleman, R.G.

1956-01-01

Channel samples from two mines on the Colorado Plateau have been studied in detail both mineralogically and chemically. A channel sample from the Mineral Joe No. 1 mine, Montrose County, Colo., extends from unmineralized rock on one side, through a zone of variable mineralization, into only weakly mineralized rock. The unmineralized rock is a fairly clean quartz sand cemented with gypsum and contains only minor amounts of clay minerals. One boundary between unmineralized and mineralized rock is quite sharo and is nearly at right angles to the bedding. Vanadium clay minerals, chiefly mixed layered mica-montmorillonite and chlorite-monmorillonite, are abundant throughout the mineralized zone. Except in the dark "eye" of the channel sample, the vanadium clay minerals are accompanied by hewettite, carnotite, tyuyamunite, and probably unidentified vanadates. In the dark "eye," paramontroseite, pyrite, and marcasite are abundant, and bordered on each side by a zone containing abundant corvusite. No recognizable uranium minerals were seen in the paramontroseite zone although uranium is abundant there. Coaly material is recognizable throughout all of the channel but is most abundant in and near the dark "eye." Detailed chemical studies show a general increase in Fe, Al, U, and V, and a decrease in SO4 toward the "eye" of the channel. Reducing capacity studies indicate that V(IV) and Fe(II) are present in the clay mineral throughout the channel, but only in and near the "eye" are other V(IV) minerals present (paramontroseite and corvusite). The uranium is sexivalent, although its state of combination is conjectural where it is associated with paramontroseite. Where the ore boundary is sharp, the boundary of introduced trace elements is equally sharp. Textural and chemical relations leave no doubt that the "eye: is a partially oxidized remnant of a former lower-valence ore, and the remainder of the channel is a much more fully oxidized remnant. A channel sample from the

Importance of interlayer H bonding structure to the stability of layered minerals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conroy, Michele; Soltis, Jennifer A.; Wittman, Rick S.

2017-10-16

The exact atomic structures of layered minerals have been difficult to characterize because the layers often possess out-of-plane hydrogen atoms that cannot be detected by many analytical techniques. However, the ordering of these bonds are thought to play a fundamental role in the structural stability and solubility of layered minerals. We report a new strategy of using the intense radiation field of a focused electron beam to probe the effect of differences in hydrogen bonding networks on mineral solubility while simultaneously imaging the dissolution behavior in real time via liquid cell electron microscopy. We show the loss in hydrogens frommore » interlayers of boehmite (γ-AlOOH) resulted in 2D nanosheets exfoliating from the bulk that subsequently and rapidly dissolved. However gibbsite (γ-Al(OH)3), with its higher concentration of OH terminating groups, was more accommodating to the deprotonation and stable under the beam.« less

Structure and chemical characteristics of natural mineral deposit Terbunskaya (Lipetsk region, Russia)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Motyleva, S., E-mail: motyleva-svetlana@mail.ru; Mertvishcheva, M.; Shchuchka, R.

New knowledge about the mineralogical features Terbunsky mineral. Investigated 5 fractions isolated from the incision (2-2,5 m). Terbunskaya deposit belongs to minerals Santonian age. Scanning electron microscopy and energy dispersive analysis of fractions isolated studied in detail. In the coarse fractions found ancient organic remains of algae and micro-organisms that have been sedimented together with the mineral component during geological periods. The share of organic inclusions does not exceed 1.5%. Chemical composition confirms the presence of silicon and carbonate organisms. Advantageously proportion of minerals having a layered structure with a plurality of micro and nano pore size 600 - 80-nm andmore » an average chemical composition (wt%): Na (0,64), Mg (0,54), Al (13.48), Si (27 57), K (2.39) Ca (0.75)« less

Mineral Types and Tree Species Determine the Functional and Taxonomic Structures of Forest Soil Bacterial Communities.

PubMed

Colin, Y; Nicolitch, O; Turpault, M-P; Uroz, S

2017-03-01

Although minerals represent important soil constituents, their impact on the diversity and structure of soil microbial communities remains poorly documented. In this study, pure mineral particles with various chemistries (i.e., obsidian, apatite, and calcite) were considered. Each mineral type was conditioned in mesh bags and incubated in soil below different tree stands (beech, coppice with standards, and Corsican pine) for 2.5 years to determine the relative impacts of mineralogy and mineral weatherability on the taxonomic and functional diversities of mineral-associated bacterial communities. After this incubation period, the minerals and the surrounding bulk soil were collected to determine mass loss and to perform soil analyses, enzymatic assays, and cultivation-dependent and -independent analyses. Notably, our 16S rRNA gene pyrosequencing analyses revealed that after the 2.5-year incubation period, the mineral-associated bacterial communities strongly differed from those of the surrounding bulk soil for all tree stands considered. When focusing only on minerals, our analyses showed that the bacterial communities associated with calcite, the less recalcitrant mineral type, significantly differed from those that colonized obsidian and apatite minerals. The cultivation-dependent analysis revealed significantly higher abundances of effective mineral-weathering bacteria on the most recalcitrant minerals (i.e., apatite and obsidian). Together, our data showed an enrichment of Betaproteobacteria and effective mineral-weathering bacteria related to the Burkholderia and Collimonas genera on the minerals, suggesting a key role for these taxa in mineral weathering and nutrient cycling in nutrient-poor forest ecosystems. IMPORTANCE Forests are usually developed on nutrient-poor and rocky soils, while nutrient-rich soils have been dedicated to agriculture. In this context, nutrient recycling and nutrient access are key processes in such environments. Deciphering how soil

Mineral Types and Tree Species Determine the Functional and Taxonomic Structures of Forest Soil Bacterial Communities

PubMed Central

Colin, Y.; Nicolitch, O.; Turpault, M.-P.

2016-01-01

ABSTRACT Although minerals represent important soil constituents, their impact on the diversity and structure of soil microbial communities remains poorly documented. In this study, pure mineral particles with various chemistries (i.e., obsidian, apatite, and calcite) were considered. Each mineral type was conditioned in mesh bags and incubated in soil below different tree stands (beech, coppice with standards, and Corsican pine) for 2.5 years to determine the relative impacts of mineralogy and mineral weatherability on the taxonomic and functional diversities of mineral-associated bacterial communities. After this incubation period, the minerals and the surrounding bulk soil were collected to determine mass loss and to perform soil analyses, enzymatic assays, and cultivation-dependent and -independent analyses. Notably, our 16S rRNA gene pyrosequencing analyses revealed that after the 2.5-year incubation period, the mineral-associated bacterial communities strongly differed from those of the surrounding bulk soil for all tree stands considered. When focusing only on minerals, our analyses showed that the bacterial communities associated with calcite, the less recalcitrant mineral type, significantly differed from those that colonized obsidian and apatite minerals. The cultivation-dependent analysis revealed significantly higher abundances of effective mineral-weathering bacteria on the most recalcitrant minerals (i.e., apatite and obsidian). Together, our data showed an enrichment of Betaproteobacteria and effective mineral-weathering bacteria related to the Burkholderia and Collimonas genera on the minerals, suggesting a key role for these taxa in mineral weathering and nutrient cycling in nutrient-poor forest ecosystems. IMPORTANCE Forests are usually developed on nutrient-poor and rocky soils, while nutrient-rich soils have been dedicated to agriculture. In this context, nutrient recycling and nutrient access are key processes in such environments. Deciphering

Prospects of gold mineralization in the Gilgit-Baltistan Province of Pakistan

NASA Astrophysics Data System (ADS)

Shah, M. T.; Khan, S. D.; Tahirkheli, T.; Ahmad, L.; Miandad, S.; Rehman, A. U.; Ali, L.

2012-12-01

Gilgit-Baltistan province is the northern most province of Pakistan having its eastern, northern and western boarders with India, China and Afghanistan respectively. The geology of this province is unique as it has the spectacular tectonic entities of Asiatic plate (AP), Indian plate (IP) and the Kohistan-Ladakh arc (KLA). The Northern Suture Zone (NSZ) or Main Karakoram Thrust (MKT) separate the KLA from AP in the north while the Maim Mantle Thrust (MMT) separate the KLA from IP in the south. These different tectonic events have generated various types of igneous and metamorphic rocks in the form of gigantic mountain chains in the region. Considering the metallogenic provinces related to such types of tectonic environments world over, it can be suggested that the Gigit-Baltistan province may have the potential for the occurrence of economic mineral deposits. The present study is the follow-up of the previous studies for exploration of gold and base metals conducted by the Austrominerals and the Pakistan Mineral Development Corporation (PMDC) in the region. On the basis of PMDC extensive stream sediments geochemical survey of the province and delineated number of anomalous catchment areas for gold mineralization. In order to find the source bed-rock of gold, we have identified various alteration zones in these catchment areas by applying Remote sensing techniques by using both multispectral (LANDSAT, ASTER and Geoeye) and hyperspectral (Hyperion) data. Most of the alteration zones were found in steep high altitude inaccessible terrains. During this study, few of the accessible alteration zones in Golo Das, Bagrot valley, Shigri Bala, Machulu and Ranthak areas were selected for geological filed work and collection of proper samples from the alteration zones and host rocks for the identification of possible gold mineralization. In all these localities, the alteration zones are present along shear zones where the sulfide mineralization commonly occurs in the form of

3-D ore body modeling and structural settings of syn-to late orogenic Variscan hydrothermal mineralization, Siegerland district, Rhenish Massif, NW Germany

NASA Astrophysics Data System (ADS)

Peters, Meike; Hellmann, André; Meyer, Franz Michael

2013-04-01

The Siegerland district is located in the fold-and thrust-belt of the Rhenish Massif and hosts diverse syn-to late orogenic mineralization styles. Peak-metamorphism and deformation occurred at 312-316±10 Ma (Ahrendt et al., 1978) at temperature-pressure conditions of 280-320°C and 0.7-1.4 kbar (Hein, 1993). In addition to syn-orogenic siderite-quartz mineralization at least four different syn-to late orogenic mineralization stages are identified comprising Co-Ni-Cu-Au, Pb-Zn-Cu, Sb-Au, and hematite-digenite-bornite ores (Hellmann et al., 2012). The earliest type of syn-orogenic ore mineralization is formed by siderite-quartz veins, trending N-S, E-W and NE-SW. The vein systems are closely related to fold and reverse fault geometries (Hellmann et al., 2012). The most important structural feature is the first-order Siegen main reverse fault showing an offset into three major faults (Peters et al., 2012). The structural control on ore formation is demonstrated by the Co-Ni-Cu-Au mineralization generally hosted by NE-ENE trending reverse faults and associated imbrication zones that have reactivated the older siderite-quartz veins. In this study, we developed a 3-D model of the Alte Buntekuh ore bodies in the Siegerland district, using Datamine Studio3 to investigate the structural setting of Co-Ni-Cu-Au mineralization. The salient structural and spatial data for the 3-D model were taken from old mine level plans as well as from geological and topographical maps. The ore bodies are located immediately in the hanging wall of the southern branch of the Siegen main reverse fault (Peters et al., 2012). From the model it becomes obvious, that the earlier siderite-quartz veins, dipping steeply to the NW, are cross-cut and segmented by oppositely dipping oblique reverse faults. Individual ore body segments are rotated and displaced, showing a plunge direction to the SW. The 3-D model further reveals the presence of hook-like, folded vein arrays, highly enriched in cobalt

Geoelectrical structure of the central zone of Piton de la Fournaise volcano (Reunion)

USGS Publications Warehouse

Lenat, J.-F.; Fitterman, D.; Jackson, D.B.; Labazuy, P.

2000-01-01

A study of the geoelectrical structure of the central part of Piton de la Fournaise volcano (Reunion, Indian Ocean) was made using direct current electrical (DC) and transient electromagnetic soundings (TEM). Piton de la Fournaise is a highly active oceanic basaltic shield and has been active for more than half a million years. Joint interpretation of the DC and TEM data allows us to obtain reliable 1D models of the resistivity distribution. The depth of investigation is of the order of 1.5 km but varies with the resistivity pattern encountered at each sounding. Two-dimensional resistivity cross sections were constructed by interpolation between the soundings of the 1D interpreted models. Conductors with resistivities less than 100 ohm-m are present at depth beneath all of the soundings and are located high in the volcanic edifice at elevations between 2000 and 1200 m. The deepest conductor has a resistivity less than 20 ohm-m for soundings located inside the Enclos and less than 60-100 ohm-m for soundings outside the Enclos. From the resistivity distributions, two zones are distinguished: (a) the central zone of the Enclos; and (b) the outer zone beyond the Enclos. Beneath the highly active summit area, the conductor rises to within a few hundred meters of the surface. This bulge coincides with a 2000-mV self-potential anomaly. Low-resistivity zones are inferred to show the presence of a hydrothermal system where alteration by steam and hot water has lowered the resistivity of the rocks. Farther from the summit, but inside the Enclos the depth to the conductive layers increases to approximately 1 km and is inferred to be a deepening of the hydrothermally altered zone. Outside of the Enclos, the nature of the deep, conductive layers is not established. The observed resistivities suggest the presence of hydrated minerals, which could be found in landslide breccias, in hydrothermally altered zones, or in thick pyroclastic layers. Such formations often create perched

Distribution Analysis of Sulphide Mineral (Pyrite) Using Induced Polarization Method in Libureng, Bone, South Sulawesi

NASA Astrophysics Data System (ADS)

Altin Massinai, Muhammad; Lantu; Latuconsina, Hidayat; Fawzy Ismullah M, Muhammad

2018-03-01

Sulphide minerals are any member of a group of compounds of sulphur with one or more metals. Some of these sulphide minerals are economically important. This study used induced polarization method to identify distribution and mineralized zone of sulphide mineral (Pyrite), in Libureng, Bone Regency, South Sulawesi. The data processing yielded resistivity value, percent frequency effect (PPE) value, and metal factor (MF) value which were then used to produce 2-D and 3-D section model. Based on the data interpretation, an anomaly linked to pyrite deposits was seen in four trajectories with resistivity value < = 50, PFE = > 3%, and MF > = 150, deposited in hydrothermal alteration zone, sericite zone.

Phosphorus availability and microbial immobilization in a Nitisol with the application of mineral and organo-mineral fertilizers.

PubMed

Morais, Francisco A; Gatiboni, Luciano C

2015-01-01

The aim of this study was to evaluate P availability, P and C contained in the microbial biomass, and enzymatic activity (acid phosphatases and β-glucosidases) in a Nitisol with the application of mineral and organo-mineral fertilizers. The experiment was performed in a protected environment with control over air temperature and soil moisture. The experimental design was organized in a "5 x 4" factorial arrangement with five sources of P and four times of soil incubation. The sources were: control (without P), triple superphosphate, diammonium phosphate, natural Arad reactive rock phosphate, and organo-mineral fertilizer. The experimental units consisted of PVC columns filled with agricultural soil. The columns were incubated and broken down for analysis at 1, 20, 40, and 60 days after application of the fertilizers. In each column, samples were taken at the layers of 0-2.5, 2.5-5.0, and 5.0-15.0 cm below the zone of the fertilizers. The application of soluble phosphates and organo-mineral fertilizer temporarily increased P availability in the zone near the fertilizers (0-2.5 cm), with maximum availability occurring at approximately 32 days. Microbial immobilization showed behavior similar to P availability, and the greatest immobilizations occurred at approximately 30 days. The organo-mineral fertilizer was not different from soluble phosphates.

Geology and mineral deposits of the St. Regis-Superior area, Mineral County, Montana

USGS Publications Warehouse

Campbell, Arthur B.

1960-01-01

County, has been traced to the east edge of the St. Regis- Superior area, thus extending the mapped length of the fault to about 100 miles. Evidence indicates that this major fault has diminished in intensity in this area and that most of the stress has been relieved along the Boyd Mountain fault that apparently splits from the Osburn fault a few miles west of St. Regis. Stratigraphic and structural evidence indicates a strike-slip right-lateral movement of about 3 miles along the Osburn fault. Horizontal stratigraphic separation along the Boyd Mountain fault indicates a right-lateral movement of about 13 miles.Low-grade regional metamorphism of the sedimentary rocks in the area has caused the recrystallization of quartz grains and the formation of sericite. Argillite and quartzite have been converted to phyllite and foliated quartzite by dynamic metamorphism in a large area north of the central part of the Osburn fault. Some of the shear zones contain a large amount of introduced carbonate minerals. From 1901 through 1953 this area has produced 8,086,827 pounds of zinc, 7,932,958 pounds of lead, 2,053,715 pounds of copper, 584,168 fine ounces of silver, and 588 fine ounces of gold. The lead, sine, and silver have come chiefly from veins in highly foliated rocks near the Osburn fault zone. The attitudes of these veins are controlled in large part by the cleavage. The principal ore minerals are galena, sphalerite, tetrahedrite, and boulangerite, and the gangue minerals are quartz, carbonate minerals, and barite. Most of the copper has come from the Amador vein where chalcopyrite and bornite are the principal ore minerals, and the gangue minerals are pyrite, quartz, and carbonate minerals. The Amador vein occurs in a belt of copper deposits that extends westward into the Coeur d'Alene district. These copper deposits may be genetically associated with diorite dikes and sills lying within the same belt. Fluorspar has been found in three closely spaced prospects along a

Dynamics of seismogenerating structures in the frontal zone of the Kolyma-Omolon superterrane

NASA Astrophysics Data System (ADS)

Imaeva, L. P.; Imaev, V. S.; Koz'min, B. M.

2016-07-01

To develop a model for the dynamics of seismogenerating structures in the frontal zone of the Kolyma-Omolon superterrane (Chersky seismotectonic zone), the following aspects are analyzed: structural-tectonic position, deep structure parameters, active faults, and fields of tectonic stresses as revealed from solutions of focal mechanisms of strong earthquakes and kinematic types of Late Cenozoic fold deformations and faults. It is found that a certain dynamic setting under transpressional conditions takes place and it was caused by the interaction between structures of the Eurasian, North American, and Okhotsk lithospheric plates within regional segments of the Chersky zone (Yana-Indigirka and Indigirka-Kolyma). These conditions are possible if the Kolyma-Omolon block located in the frontal zone of the North American Plate was an indenter. Due to this, some terranes of different geodynamic origin underwent horizontal shortening, under which particular blocks of segments were pushed out laterally along the orogenic belt, on a system of conjugated strike-slip faults of different directions and hierarchical series, in the northwest and southeast directions, respectively, to form the main seismogenerating reverse-fault and thrust structures with the maximum seismic potential ( M ≥ 6.5).

On the mineral core of ferritin-like proteins: structural and magnetic characterization

NASA Astrophysics Data System (ADS)

García-Prieto, A.; Alonso, J.; Muñoz, D.; Marcano, L.; Abad Díaz de Cerio, A.; Fernández de Luis, R.; Orue, I.; Mathon, O.; Muela, A.; Fdez-Gubieda, M. L.

2015-12-01

It is generally accepted that the mineral core synthesized by ferritin-like proteins consists of a ferric oxy-hydroxide mineral similar to ferrihydrite in the case of horse spleen ferritin (HoSF) and an oxy-hydroxide-phosphate phase in plant and prokaryotic ferritins. The structure reflects a dynamic process of deposition and dissolution, influenced by different biological, chemical and physical variables. In this work we shed light on this matter by combining a structural (High Resolution Transmission Electron Microscopy (HRTEM) and Fe K-edge X-ray Absorption Spectroscopy (XAS)) and a magnetic study of the mineral core biomineralized by horse spleen ferritin (HoSF) and three prokaryotic ferritin-like proteins: bacterial ferritin (FtnA) and bacterioferritin (Bfr) from Escherichia coli and archaeal ferritin (PfFtn) from Pyrococcus furiosus. The prokaryotic ferritin-like proteins have been studied under native conditions and inside the cells for the sake of preserving their natural attributes. They share with HoSF a nanocrystalline structure rather than an amorphous one as has been frequently reported. However, the presence of phosphorus changes drastically the short-range order and magnetic response of the prokaryotic cores with respect to HoSF. The superparamagnetism observed in HoSF is absent in the prokaryotic proteins, which show a pure atomic-like paramagnetic behaviour attributed to phosphorus breaking the Fe-Fe exchange interaction.It is generally accepted that the mineral core synthesized by ferritin-like proteins consists of a ferric oxy-hydroxide mineral similar to ferrihydrite in the case of horse spleen ferritin (HoSF) and an oxy-hydroxide-phosphate phase in plant and prokaryotic ferritins. The structure reflects a dynamic process of deposition and dissolution, influenced by different biological, chemical and physical variables. In this work we shed light on this matter by combining a structural (High Resolution Transmission Electron Microscopy (HRTEM

Grain Boundary Plane Orientation Fundamental Zones and Structure-Property Relationships

PubMed Central

Homer, Eric R.; Patala, Srikanth; Priedeman, Jonathan L.

2015-01-01

Grain boundary plane orientation is a profoundly important determinant of character in polycrystalline materials that is not well understood. This work demonstrates how boundary plane orientation fundamental zones, which capture the natural crystallographic symmetries of a grain boundary, can be used to establish structure-property relationships. Using the fundamental zone representation, trends in computed energy, excess volume at the grain boundary, and temperature-dependent mobility naturally emerge and show a strong dependence on the boundary plane orientation. Analysis of common misorientation axes even suggests broader trends of grain boundary energy as a function of misorientation angle and plane orientation. Due to the strong structure-property relationships that naturally emerge from this work, boundary plane fundamental zones are expected to simplify analysis of both computational and experimental data. This standardized representation has the potential to significantly accelerate research in the topologically complex and vast five-dimensional phase space of grain boundaries. PMID:26498715

Grain boundary plane orientation fundamental zones and structure-property relationships

DOE Office of Scientific and Technical Information (OSTI.GOV)

Homer, Eric R.; Patala, Srikanth; Priedeman, Jonathan L.

2015-10-26

Grain boundary plane orientation is a profoundly important determinant of character in polycrystalline materials that is not well understood. This work demonstrates how boundary plane orientation fundamental zones, which capture the natural crystallographic symmetries of a grain boundary, can be used to establish structure-property relationships. Using the fundamental zone representation, trends in computed energy, excess volume at the grain boundary, and temperature-dependent mobility naturally emerge and show a strong dependence on the boundary plane orientation. Analysis of common misorientation axes even suggests broader trends of grain boundary energy as a function of misorientation angle and plane orientation. Due to themore » strong structure-property relationships that naturally emerge from this work, boundary plane fundamental zones are expected to simplify analysis of both computational and experimental data. This standardized representation has the potential to significantly accelerate research in the topologically complex and vast five-dimensional phase space of grain boundaries.« less

Structure of the Sumatra-Andaman subduction zone

NASA Astrophysics Data System (ADS)

Pesicek, Jeremy Dale

We have conducted studies of the Sumatra-Andaman subduction zone using newly available teleseismic data resulting from the aftershock sequences of the 2004, 2005, and 2007 great earthquakes that occurred offshore of the island of Sumatra. In order to better exploit the new data, existing methodologies have been adapted and advanced in several ways to obtain results at a level of precision not previously possible from teleseismic data. Seismic tomography studies of the mantle were conducted using an improved iterative technique that accounts for fine-scale three-dimensional (3-D) velocity variations inside the study region and coarser global velocity variations outside the region. More precise earthquake locations were determined using a double-difference technique that has been extended to teleseismic distances using spherical ray tracing through the nested 3-D regional-global velocity models. Earthquake relocation was included in the iterative tomography scheme and was found to significantly enhance the recovery of slab velocity anomalies. Finally, because crustal structure is poorly constrained by the teleseismic data, 3-D density modeling of the crust was conducted using newly available satellite gravity data and a spherical prism gravity algorithm. The results of these studies better constrain the structure of the Sumatra-Andaman subduction zone, including the geometry of the mantle slab, position of the megathrust, and structural features of the downgoing plate. Tomography results reveal continuous upper mantle slab anomalies with significant variations in dip throughout the region. Broad curvature of the fast anomalies beneath northern Sumatra, similar to curvature of the trench and volcanic arc at the surface, is interpreted as folding of the upper mantle slab. Earthquake relocations show systematic shifts of the hypocenters to the northeast and to shallower depths, each with average changes of 5 km. Reduced scatter in the relocations better constrain the

30 CFR 250.226 - What Coastal Zone Management Act (CZMA) information must accompany the EP?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the EP? 250.226 Section 250.226 Mineral Resources MINERALS MANAGEMENT SERVICE... and Information Contents of Exploration Plans (ep) § 250.226 What Coastal Zone Management Act (CZMA...

Sorption and mineralization of S-metolachlor and its ionic metabolites in soils and vadose zone solids: consequences on groundwater quality in an alluvial aquifer (Ain Plain, France).

PubMed

Baran, Nicole; Gourcy, Laurence

2013-11-01

This study characterizes the transfer of S-metolachlor (SMOC) and its metabolites, metolachlor ethane sulfonic acid (MESA) and metolachlor oxanilic acid (MOXA) to the alluvial aquifer. Sorption and mineralization of SMOC and its two ionic metabolites were characterized for cultivated soils and solids from the vadose (unsaturated) zone in the Ain Plain (France). Under sterile soil conditions, the absence of mineralization confirms the importance of biotic processes in SMOC degradation. There is some adsorption and mineralization of the parent molecule and its metabolites in the unsaturated zone, though less than in soils. For soils, the MESA adsorption constant is statistically higher than that of MOXA and the sorption constants of the two metabolites are significantly lower than that of SMOC. After 246 days, for soils, maximums of 26% of the SMOC, 30% of the MESA and 38% of the MOXA were mineralized. This partly explains the presence of these metabolites in the groundwater at concentrations generally higher than those of the parent molecule for MESA, although there is no statistical difference in the mineralization of the 3 molecules. The laboratory results make it possible to explain the field observations made during 27 months of groundwater quality monitoring (monthly sampling frequency). The evolution of both metabolite concentrations in the groundwater is directly related to recharge dynamics; there is a positive correlation between concentrations and the groundwater level. The observed lag of several months between the signals of the parent molecule and those of the metabolites is probably due to greater sorption of the parent molecule than of its metabolites and/or to degradation kinetics. © 2013.

Geochemistry of continental subduction-zone fluids

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Hermann, Joerg

2014-12-01

The composition of continental subduction-zone fluids varies dramatically from dilute aqueous solutions at subsolidus conditions to hydrous silicate melts at supersolidus conditions, with variable concentrations of fluid-mobile incompatible trace elements. At ultrahigh-pressure (UHP) metamorphic conditions, supercritical fluids may occur with variable compositions. The water component of these fluids primarily derives from structural hydroxyl and molecular water in hydrous and nominally anhydrous minerals at UHP conditions. While the breakdown of hydrous minerals is the predominant water source for fluid activity in the subduction factory, water released from nominally anhydrous minerals provides an additional water source. These different sources of water may accumulate to induce partial melting of UHP metamorphic rocks on and above their wet solidii. Silica is the dominant solute in the deep fluids, followed by aluminum and alkalis. Trace element abundances are low in metamorphic fluids at subsolidus conditions, but become significantly elevated in anatectic melts at supersolidus conditions. The compositions of dissolved and residual minerals are a function of pressure-temperature and whole-rock composition, which exert a strong control on the trace element signature of liberated fluids. The trace element patterns of migmatic leucosomes in UHP rocks and multiphase solid inclusions in UHP minerals exhibit strong enrichment of large ion lithophile elements (LILE) and moderate enrichment of light rare earth elements (LREE) but depletion of high field strength elements (HFSE) and heavy rare earth elements (HREE), demonstrating their crystallization from anatectic melts of crustal protoliths. Interaction of the anatectic melts with the mantle wedge peridotite leads to modal metasomatism with the generation of new mineral phases as well as cryptic metasomatism that is only manifested by the enrichment of fluid-mobile incompatible trace elements in orogenic peridotites

Zinc and copper mineralization of the Vazante area, Minas Gerais, Brazil

USGS Publications Warehouse

Moore, Samuel L.

1956-01-01

A large body of zinc and copper mineralization is exposed in a line of low hills about 5 kilometers east of the small village of Vazante in the northwestern part of the state of Minas Gerais, Brazil. The Vazante area can be reached by roads leading north from the State of Sao Paulo, via Araxa; west from Balo Horizonte, Minas Gerais; and south from Paracatu, Minas Gerais. The deposit is in branching, sub-parallel fault breccia zones. Calamine (H2Zn2SiO5), and willomite (ZnSiO4), along with small quantities of smithsonite (ZnCO3), form the matrix of the fault breccia. The zinc mineralization is cut by narrow veins of chalcocite in platy crystal aggregate thought to be pseudomorphous after covellite. The chalcocite veins contain small quantities of sphalterite, galena, covellite and calamine. Faults that contain breccia zones displace shale and dolomite. The sedimentary rocks are thought to be Silurian in age. The fault breccia zones have a regional trend of N 40 degrees E and crop out over a strike length of more than four kilometers. The mineralization of the fault zones was observed to continue to the north for an additional four kilometers. The mineralized fault breccia zones range from a few meters to 60 meters in width. A large ore body is indicated that from available samples may average 35 percent zinc.

Atom exchange between aqueous Fe(II) and structural Fe in clay minerals.

PubMed

Neumann, Anke; Wu, Lingling; Li, Weiqiang; Beard, Brian L; Johnson, Clark M; Rosso, Kevin M; Frierdich, Andrew J; Scherer, Michelle M

2015-03-03

Due to their stability toward reductive dissolution, Fe-bearing clay minerals are viewed as a renewable source of Fe redox activity in diverse environments. Recent findings of interfacial electron transfer between aqueous Fe(II) and structural Fe in clay minerals and electron conduction in octahedral sheets of nontronite, however, raise the question whether Fe interaction with clay minerals is more dynamic than previously thought. Here, we use an enriched isotope tracer approach to simultaneously trace Fe atom movement from the aqueous phase to the solid ((57)Fe) and from the solid into the aqueous phase ((56)Fe). Over 6 months, we observed a significant decrease in aqueous (57)Fe isotope fraction, with a fast initial decrease which slowed after 3 days and stabilized after about 50 days. For the aqueous (56)Fe isotope fraction, we observed a similar but opposite trend, indicating that Fe atom movement had occurred in both directions: from the aqueous phase into the solid and from the solid into aqueous phase. We calculated that 5-20% of structural Fe in clay minerals NAu-1, NAu-2, and SWa-1 exchanged with aqueous Fe(II), which significantly exceeds the Fe atom layer exposed directly to solution. Calculations based on electron-hopping rates in nontronite suggest that the bulk conduction mechanism previously demonstrated for hematite1 and suggested as an explanation for the significant Fe atom exchange observed in goethite2 may be a plausible mechanism for Fe atom exchange in Fe-bearing clay minerals. Our finding of 5-20% Fe atom exchange in clay minerals indicates that we need to rethink how Fe mobility affects the macroscopic properties of Fe-bearing phyllosilicates and its role in Fe biogeochemical cycling, as well as its use in a variety of engineered applications, such as landfill liners and nuclear repositories.

Mineral distributions at the developing tendon enthesis.

PubMed

Schwartz, Andrea G; Pasteris, Jill D; Genin, Guy M; Daulton, Tyrone L; Thomopoulos, Stavros

2012-01-01

Tendon attaches to bone across a functionally graded interface, "the enthesis". A gradient of mineral content is believed to play an important role for dissipation of stress concentrations at mature fibrocartilaginous interfaces. Surgical repair of injured tendon to bone often fails, suggesting that the enthesis does not regenerate in a healing setting. Understanding the development and the micro/nano-meter structure of this unique interface may provide novel insights for the improvement of repair strategies. This study monitored the development of transitional tissue at the murine supraspinatus tendon enthesis, which begins postnatally and is completed by postnatal day 28. The micrometer-scale distribution of mineral across the developing enthesis was studied by X-ray micro-computed tomography and Raman microprobe spectroscopy. Analyzed regions were identified and further studied by histomorphometry. The nanometer-scale distribution of mineral and collagen fibrils at the developing interface was studied using transmission electron microscopy (TEM). A zone (∼20 µm) exhibiting a gradient in mineral relative to collagen was detected at the leading edge of the hard-soft tissue interface as early as postnatal day 7. Nanocharacterization by TEM suggested that this mineral gradient arose from intrinsic surface roughness on the scale of tens of nanometers at the mineralized front. Microcomputed tomography measurements indicated increases in bone mineral density with time. Raman spectroscopy measurements revealed that the mineral-to-collagen ratio on the mineralized side of the interface was constant throughout postnatal development. An increase in the carbonate concentration of the apatite mineral phase over time suggested possible matrix remodeling during postnatal development. Comparison of Raman-based observations of localized mineral content with histomorphological features indicated that development of the graded mineralized interface is linked to endochondral

Evaluation of commercial utility of ERTS-A imagery in structural reconnaissance for minerals and petroleum

NASA Technical Reports Server (NTRS)

Saunders, D. F. (Principal Investigator)

1973-01-01

The author has identified the following significant results. The only area that has been analyzed to date is Area 3 where results have already been reported. However, work progressing in Area 1 and 2 seem to indicate a good correlation between lineament zones previously reported, mineralized areas and lineaments currently being picked from ERTS-1 imagery. There also appear to be many lineaments on ERTS-1 imagery in these areas which have not been reported in any other literature.

Re-Os, Sm-Nd, U-Pb, and stepwise lead leaching isotope systematics in shear-zone hosted gold mineralization: genetic tracing and age constraints of crustal hydrothermal activity

NASA Astrophysics Data System (ADS)

Frei, R.; Nägler, Th. F.; Schönberg, R.; Kramers, J. D.

1998-06-01

A combined Re-Os, Sm-Nd, U-Pb, and stepwise Pb leaching (PbSL) isotope study of hydrothermal (Mo-W)-bearing minerals and base metal sulfides from two adjacent shear zone hosted gold deposits (RAN, Kimberley) in the Harare-Shamva greenstone belt (Zimbabwe) constrain the timing of the mineralizing events to two periods. During an initial Late Archean event (2.60 Ga) a first molybdenite-scheelite bearing paragenesis was deposited in both shear zone systems, followed by a local reactivation of the shear systems during an Early Proterozoic (1.96 Ga) tectono-thermal overprint, during which base metal sulfides and most of the gold was (re-)deposited. While PbSL has revealed an open-system behavior of the U-Pb systematics in molybdenite and wolframite from the RAN mine, initial Archean Re-Os ages are still preserved implying that this system in these minerals was more resistant to the overprint. A similar retentivity could be shown for the Sm-Nd system in scheelite and powellite associated with the above ore minerals. Re-Os isotopic data from the Proterozoic mineralization in the Kimberley mine point to a recent gain of Re, most pronouncedly affecting Fe-rich sulfides such as pyrrhotite. A significant Re-loss in powellitic scheelite (an alteration phase of molybdenite-bearing scheelite), coupled with a marked loss of U in W-Mo ore minerals, complements the observation of a major Re uptake in Fe-sulfides during oxidizing conditions in a weathering environment. Pyrrhotite under these conditions behaves as an efficient Re-sink. Lead isotope signatures from PbSL residues of molybdenite, powellite, and quartz indicate a continental crustal source and/or contamination for the mineralizing fluid by interaction of the fluids with older sedimentary material as represented by the direct host country rocks. Our investigation reveals the potential of the Re-Os isotopic system applied to crustal hydrothermal ore minerals for genetic tracing and dating purposes. The simplified chemical

The mineral economy of Brazil--Economia mineral do Brasil

USGS Publications Warehouse

Gurmendi, Alfredo C.; Barboza, Frederico Lopes; Thorman, Charles H.

1999-01-01

This study depicts the Brazilian government structure, mineral legislation and investment policy, taxation, foreign investment policies, environmental laws and regulations, and conditions in which the mineral industry operates. The report underlines Brazil's large and diversified mineral endowment. A total of 37 mineral commodities, or groups of closely related commodities, is discussed. An overview of the geologic setting of the major mineral deposits is presented. This report is presented in English and Portuguese in pdf format.

Li-atoms-induced structure changes of Guinier–Preston–Bagaryatsky zones in AlCuLiMg alloys

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duan, S.Y.; Le, Z.; Chen, Z.K.

2016-11-15

Guinier–Preston–Bagaryatsky (GPB) zones are the well-known strengthening precipitates of AlCuMg alloys formed upon thermal ageing. Here we report that when formed in AlCuLiMg alloys the GPB zones can change significantly in morphology and structure. It is shown that though they do still consist of Al, Cu and Mg elements fundamentally, the GPB zones in AlCuLiMg alloys have a rather different structure due to a featured Li-segregation at their interfaces with the matrix and possible Li-replacement of partial Mg atoms in the structure. As such the Li-containing GPB zones often develop from one-dimensional to quasi-two-dimensional precipitates. - Highlights: • We observemore » Guinier–Preston–Bagaryatsky zone variants in AlCuLiMg alloys. • We obtain atomic-resolution images of the precipitates and model their structures. • Li-atoms play a key role in modifying the structure of these precipitate variants.« less

The nature of the mineral component of bone and the mechanism of calcification.

PubMed

Glimcher, M J

1987-01-01

From the physical chemical standpoint, the formation of a solid phase of Ca-P in bone represents a phase transformation, a process exemplified by the formation of ice from water. Considering the structural complexity and abundance of highly organized macromolecules in the cells and extracellular tissue spaces of mineralized tissues generally and in bone particularly, it is inconceivable that this phase transformation occurs by homogeneous nucleation, i.e., without the active participation of an organic component acting as a nucleator. This is almost surely true in biologic mineralization in general. Electron micrographs and low-angle neutron and X-ray diffraction studies clearly show that calcification of collagen fibrils occurs in an extremely intimate and highly organized fashion: initiation of crystal formation within the collagen fibrils in the hole zone region, with the long axes (c-axis) of the crystals aligned roughly parallel to the long axis of the fibril within which they are located. Crystals are initially formed in hole zone regions within individual fibrils separated by unmineralized regions. Calcification is initiated in spatially distinct nucleation sites. This indicates that such regions within a single, undirectional fibril represents independent sites for heterogeneous nucleation. Clearly, sites where mineralization is initiated in adjacent collagen fibrils are even further separated, emphasizing even more clearly that the process of progressive calcification of the collagen fibrils and therefore of the tissue is characterized principally by the presence of increasing numbers of independent nucleation sites within additional hole zone regions of the collagen fibrils. The increase in the mass of Ca-P apatite accrues principally by multiplication of more crystals, mostly by secondary nucleation from the crystals initially deposited in the hole zone region. Very little additional growth of the crystals occurs with time, the additional increase in

Metabauxite horizons containing remobilized-origin gem diaspore and related mineralization, Milas-Muğla province, SW Turkey

NASA Astrophysics Data System (ADS)

Hatipoğlu, Murat; Türk, Necdet; Chamberlain, Steven C.; Murat Akgün, A.

2010-10-01

Remobilized-origin gem diaspore and related minerals occur as infill within structurally controlled voids that developed in the upper of two distinct karst unconformity-type metabauxite (diasporite) horizons in the İlbir Mountains area of the Milas-Muğla province, SW Turkey. Colour-change diaspore (trademarked as zultanite) and associated mineral specimens (greenish muscovite, chloritoid, donbassite, specular hematite, ilmenite, goethite, and younger calcite) occur in fracture zones (veins and open structures) that cross-cut the metabauxite horizons. The mineralized fracture zones do not extend into the enclosing marbles, probably because of the ductility contrast between the brittle bauxite and relatively plastic carbonate beds. Thick, white to light gray and dark gray limestone beds were deposited in the İlbir Mountains area during the Cretaceous (146-65 Ma), and contain two stratigraphically distinct karst-fill bauxite horizons. Al-, Fe-, Si- and Ti-rich solutions that infiltrated the karstified limestone probably originated from altered schist and gneiss that surround the basin. The limestone beds (>2000 m thick) were subjected to burial metamorphism, forming marble. Subsequently, the marble block was folded during nappe emplacement toward the SSW as part of late Alpine contractional deformation during the Paleogene (65-23.8 Ma). The upper bauxite horizons within the folded block were cross-cut by fracture zones because of their relatively brittle rheology. At this time, increased pressure and temperature in the bauxite horizons resulted in remobilization of the primary constituents of the bauxite within an aqueous complex, resulting in the crystallization of coarse-grained assemblages in the cross-cutting structures. Ultimately, erosion and mineral exploration revealed the steeply dipping bauxite outcrops and mine workings evident today. This paper focuses on the mine geology of surface outcrops of diasporic bauxite, the upper bauxite horizon within

Phanerozoic Rifting Phases And Mineral Deposits

NASA Astrophysics Data System (ADS)

Hassaan, Mahmoud

2016-04-01

In North Africa occur Mediterranean and Red Sea metallogenic provinces. In each province distribute 47 iron- manganese- barite and lead-zinc deposits with tectonic-structural control. The author presents in this paper aspects of position of these deposits in the two provinces with Phanerozoic rifting . The Mediterranean Province belongs to two epochs, Hercynian and Alpine. The Hercynian Epoch manganese deposits in only Moroccoa- Algeria belong to Paleozoic tectonic zones and Proterozoic volcanics. The Alpine Epoch iron-manganese deposits are of post-orogenic exhalative-sedimentary origin. Manganese deposits in southern Morocco occur in Kabil-Rief quartz-chalcedony veins controlled by faults in andesitic sheets and in bedded pelitic tuffs, strata-form lenses and ore veins, in Precambrian schist and in Triassic and Cretaceous dolomites. Disseminated manganese with quartz and barite and effusive hydrothermal veins are hosted in Paleocene volcanics. Manganese deposits in Algeria are limited and unrecorded in Tunisia. Strata-form iron deposits in Atlas Heights are widespread in sub-rift zone among Jurassic sediments inter-bedding volcanic rocks. In Algeria, Group Beni-Saf iron deposits are localized along the Mediterranean coast in terrigenous and carbonate rocks of Jurassic, Cretaceous and Eocene age within faults and bedding planes. In Morocco strata-form hydrothermal lead-zinc deposits occur in contact zone of Tertiary andesite inter-bedding Cambrian shale, Lias dolomites and Eocene andesite. In both Algeria and Tunisia metasomatic Pb-Zn veins occur in Campanian - Maastrichtian carbonates, Triassic breccia, Jurassic limestone, Paleocene sandstones and limestone and Neogene conglomerates and sandstones. The Red Sea metallogenic province belongs to the Late Tertiary-Miocene times. In Wadi Araba hydrothermal iron-manganese deposits occur in Cretaceous sediments within 320°and 310 NW faults related to Tertiary basalt. Um-Bogma iron-manganese deposits are closely

In situ determination of crystal structure and chemistry of minerals at Earth's deep lower mantle conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuan, Hongsheng; Zhang, Li

Recent advances in experimental techniques and data processing allow in situ determination of mineral crystal structure and chemistry up to Mbar pressures in a laser-heated diamond anvil cell (DAC), providing the fundamental information of the mineralogical constitution of our Earth's interior. This work highlights several recent breakthroughs in the field of high-pressure mineral crystallography, including the stability of bridgmanite, the single-crystal structure studies of post-perovskite and H-phase as well as the identification of hydrous minerals and iron oxides in the deep lower mantle. The future development of high-pressure crystallography is also discussed.

The Alaskan Mineral Resource Assessment Program; background information to accompany folio of geologic and mineral resource maps of the Circle quadrangle, Alaska

USGS Publications Warehouse

Foster, Helen Laura; Menzie, W.D.; Cady, J.W.; Simpson, S.L.; Aleinikoff, J.N.; Wilson, Frederic H.; Tripp, R.B.

1987-01-01

The geology, geochemistry, geophysics, and Landsat imagery of the Circle quadrangle were investigated by an interdisciplinary research team for the purpose of assessing the mineral potential of the area. The quadrangle covers approximately 15,765 km2 in east-central Alaska; most of it is included in the mountainous Yukon-Tanana Upland physiographic division, but the northernmost part is in the low-lying Yukon Flats section. The Circle mining district, in the east-central part of the quadrangle, has been a major producing area of placer gold since its discovery in 1893. For descriptive purposes, the Circle quadrangle is divided into three areas: the northwest Circle quadrangle, the area north of the Tintina fault zone, and the area south of the Tintina fault zone. The Tintina fault zone extends northwesterly through the northern part of the quadrangle. The northwest Circle quadrangle contains mostly folded and faulted, slightly metamorphosed sedimentary rocks that are intruded by Tertiary granitic plutons. In the northern part of the area north of the Tintina fault zone (Little Crazy Mountains and northern east Crazy Mountains), the rocks consist primarily of the gabbro and basalt of the Circle Volcanics and minor associated chert, graywacke, and limestone. Elsewhere in this area (south of the Circle Volcanics and in the western Crazy Mountains), the rocks are mostly slightly metamorphosed Paleozoic sedimentary rocks that have been folded and faulted. Rocks in the largest part of the quadrangle, the area south of the Tintina fault zone, consist largely of pelitic rocks that are regionally metamorphosed to greenschist and amphibolite facies. Felsic plutons, mostly Tertiary in age, occur throughout the area. The metamorphic rocks are separated from sedimentary rocks on the northwest by thrust faulting. The aeromagnetic and gravity data show clear differences between the areas north and south of the Tintina fault zone. The metamorphic terrane to the south has low

Alteration and geochemical zoning in Bodie Bluff, Bodie mining district, eastern California

USGS Publications Warehouse

Herrera, P.A.; Closs, L.G.; Silberman, M.L.

1993-01-01

Banded, epithermal quartz-adularia veins have produced about 1.5 million ounces of gold and 7 million ounces of silver from the Bodie mining district, eastern California. The veins cut dacitic lava flows, pyroclastic rocks and intrusions. Sinter boulders occur in a graben structure at the top of Bodie Bluff and fragments of sinter and mineralized quartz veins occur in hydrothermal breccias nearby. Explosive venting evidently was part of the evolution of the ore-forming geothermal systems which, at one time, must had reached the paleosurface. Previous reconnaissance studies at Bodie Bluff suggested that the geometry of alteration mineral assemblages and distribution of some of the major and trace elements throughout the system correspond to those predicted by models of hot-spring, volcanic rock hosted precious metal deposits (Silberman, 1982; Silberman and Berger, 1985). The current study was undertaken to evaluate these sugestions further. About 500 samples of quartz veins and altered rocks, including sinter, collected over a vertical extent of 200 meters within Bodie Bluff were petrographically examined and chemically analyzed for trace elements by emission spectrographic and atomic absorption methods. Sixty-five samples were analyzed for major elements by X-ray fluorescence methods. The results of these analyses showed that, in general, alteration mineral assemblage and vertical geochemical zoning patterns follow those predicted for hot-spring deposits, but that geochemical zoning patterns for sinter and quartz veins (siliceous deposits), and altered wall rocks are not always similar. The predicted depth-concentration patterns for some elements, notably Au, Ag, Hg, and Tl in quartz veins, and Hg, As and Ag in wall rocks were not as expected, or were perturbed by the main ore producing zone. For both quartz veins and altered wall rocks, the main ore zone had elevated metal contents. Increased concentration of many of these elements could indicate proximity to this

The Effect of Riparian Zones in Structuring Small Mammal Communities in the Southern Appalachians

Treesearch

Joshua Laerm; Michael A. Menzel; Dorothy J. Wolf; James R. Welch

1997-01-01

Riparian zones have been shown to be important in structuring vertebrate communities and in maintaining biodiversity. We examined the role of riparian zones in structuring small mammal communities in a southern Appalachian watershed at Coweeta Hydrological Laboratory, Macon County, North Carolina. We established pitfall and live-trap grids in three replicates each of...

Thermal-field propagation in an exocontact zone of a magmatic body and its impact on radiogenic isotope concentrations in minerals.

PubMed

Brandt, I S; Rasskazov, S V; Brandt, S B; Ivanov, A V

2002-03-01

In application of radioactive isotope systems (K-Ar, Rb-Sr etc.) during the last decades, experience was gained not only on their geochronometrical uses, but also on estimations of some important parameters of geological processes, especially temperatures and durations of superimposed thermal events. In this paper, the formation of an exocontact thermal field of a magmatic intrusion is considered as a spreading of a thermal source delta-function. Appropriate solutions of the heat-transfer equation are deduced and correlated with diffusion parameters of the radiogenic argon, coupling radioactive, thermal and kinetic parameters in an exocontant zone of a magmatic body. These solutions were used for quantitative reinterpretations of data taken from Hart's classical paper [The petrology and isotopic mineral age relations of a contact zone in the Front Range, Colorado. J. Geol., 1964, v. 72, pp. 493-525]. Theoretic and measured radiogenic argon and strontium concentrations within exocontact aureoles are found to be in good concordance.

Complex fragmentation and silicification structures in fault zones: quartz crystallization and repeated fragmentation in the Rusey fault zone (Cornwall/UK)

NASA Astrophysics Data System (ADS)

Yilmaz, Tim I.; Blenkinsop, Tom; Duschl, Florian; Kruhl, Jörn H.

2015-04-01

Silicified fault rocks typically show structures resulting from various stages of fragmentation and quartz crystallization. Both processes interact episodically and result in complex structures on various scales, which require a wide spectrum of analysis tools. Based on field and microstructural data, the spatial-temporal connection between deformation, quartz crystallization and fluid and material flow along the Rusey fault zone was investigated. The fault can be examined in detail in three dimensions on the north Cornwall coast, UK. It occurs within Carboniferous sandstones, siltstones, mudstones and slates of the Culm basin, and is likely to have had a long history. The fault rocks described here formed during the younger events, possibly due to Tertiary strike-slip reactivation. Frequent fragmentation, flow and crystallization events and their interaction led to various generations of complex-structured quartz units, among them quartz-mantled and partly silicified wall-rock fragments, microcrystalline quartz masses of different compositions and structures, and quartz vein patterns of various ages. Lobate boundaries of quartz masses indicate viscous flow. Fragments are separated by quartz infill, which contains cm-sized open pores, in which quartz crystals have pyramidal terminations. Based on frequent occurrence of feathery textures and the infill geometry, quartz crystallization from chalcedony appears likely, and an origin from silica gel is discussed. Fragmentation structures are generally fractal. This allows differentiation between various processes, such as corrosive wear, wear abrasion and hydraulic brecciation. Material transport along the brittle shear zone, and displacement of the wall-rocks, were at least partly governed by flow of mobile fluid-quartz-particle suspensions. The complex meso- to microstructures were generated by repeated processes of fragmentation, quartz precipitation and grain growth. In general, the brittle Rusey fault zone

Influence of graphite and serpentine minerals along landslide failure surfaces

NASA Astrophysics Data System (ADS)

Alberti, Stefano; Battista Crosta, Giovanni; Wang, Gonghui; Dattola, Giuseppe; Bertolo, Davide

2017-04-01

Landslides and deep-seated gravitational slope deformation (DSGSD) often are concentrated in sedimentary and metasedimentary rocks (e.g. Ambrosi and Crosta, 2006) and in carbonaceous materials (CM), where weaker slip surfaces can be generated more easily, with a behaviour similar to that of fault zone (e.g. Zulauf et al., 1990; Craw, 2002; Oohashi et al., 2011, Nakamura et al., 2015). Among the carbonaceous minerals, graphite (grouped with other silicate sheet minerals) acts as a "solid lubrificant" and plays a key role on frictional properties of the slip surface (Yamasaki et al., 2015). These minerals have one key characteristic in common: the presence of weak bonding along (001) planes. Graphite also has one of the weakest bonding in the crystal structure, and it is characterized by a markedly low coefficient of friction (ca 0.1). A similar behaviour is found in serpentine minerals series and chlorite. We performed these tests on different samples derived from Mont de La Saxe landslide and Chervaz landslide. The first one is located in the upper Aosta Valley, the second in the central part of the Aosta Valley. Both these landslides are characterized by metasedimentary sequences. The undisturbed samples derived by core recovery surveys. We performed a petrographic characterization by XRD (X-Ray Diffraction), XRF (X-Ray Refraction) and SEM (Scansion Electron Microscope) with microprobe in addition to laboratory tests on samples from shear zones. Along these shear zones grains are crushed, their size and shapes are changed and these changes necessarily affect pore-water pressure due to volume change in the shear zone. We performed tests using a dynamic-loading ring-shear apparatus (DPRI-5, Sassa et al., 1997). This apparatus allows to simulate the entire process of failure, from initial static or dynamic loading, through shear failure, pore-pressure changes and possible liquefaction, to large-displacement, steady-state shear movement. It is also possible to

Imaging of Fine Shallow Structure Beneath the Longmenshan Fault Zone from Ambient Noise Tomography

NASA Astrophysics Data System (ADS)

Zhao, P.; Campillo, M.; Chen, J.; Liu, Q.

2016-12-01

Short period seismic ambient noise group velocity dispersion curve, obtained from cross correlation of vertical component of 57 stations around the Longmenshan fault zone deployed after the Wenchuan earthquake and continuously observed for 1 year, is used to inverse the S wave velocity structure of the top 25 km of the central to northern part of Longmenshan fault zone. A iterative correction method based on 3-D simulation is proposed to reduce the influence of elevation. After 7 times of correction, a fine shllow S-wave velocity structure comes out. The results show that (1) Velocity structure above 10 km keeps good consistency with the surface fault system around Longmenshan, and controls the deep extension features of most major faults. Below the depth of 15 km, the velocity structure presents cross tectonic frame work along both Longmenshan and Minshan. The complex structure may have affected the rupture process of the Wenchuan earthquake. (2) The depth velocity structure profiles give good constraint for the deep geometry of main faults. The characteristics of the high angle, listric, reverse structure of the Longmenshan faults is further confirmed by our results.(3) At southern part of the study area, low-velocity structure is found at about 20km depth beneath the Pengguan massif, which is related to the low velocity layer in the middle crust of Songpan-Ganzi block. This may be an evidence for the existence of brittle-ductile transition zone in southern part of the rupture zone of the Wenchuan earthquake at the depth around 22km. Our results show the great potential of short period ambient noise tomography with data from densepassive seismic array in the study of fine velocity structure and fault zone imaging.

Structures, microfabrics, fractal analysis and temperature-pressure estimation of the Mesozoic Xingcheng-Taili ductile shear zone in the North China craton

NASA Astrophysics Data System (ADS)

Liang, Chenyue; Neubauer, Franz; Liu, Yongjiang; Jin, Wei; Zeng, Zuoxun; Bernroider, Manfred; Li, Weimin; Wen, Quanbo; Han, Guoqing; Zhao, Yingli

2014-05-01

The ductile shear zone in Xingcheng-Taili area (western Liaoning Province in China) is tectonically located in the eastern section of the northern margin of the North China craton, and dominantly comprises deformed granitic rocks of Neoarchean and Triassic to Late Jurassic age, which were affected by shearing within middle- to low-grade metamorphic conditions. Because a high-temperature metamorphic overprint is lacking, microstructures attesting to low-temperature ductile deformation are well preserved. However, the rocks and its structures have not been previously analyzed in detail except by U-Pb zircon dating and some geochemistry. Here, we describe the deformation characteristics and tectonic evolution of the Xingcheng-Taili ductile shear zone, in order to understand the mode of lithosphericscale reactivation, extension and thinning of the North China craton. The ductile deformation history comprises four successive deformation phases: (1) In the Neoarchean granitic rocks, a steep gneissosity and banded structures trend nearly E-W (D1). (2) A NE-striking sinistral structure of Upper Triassic rocks may indicate a deformation event (D2) in Late Triassic times, which ductile deformation structures superimposed on Neoarchean granitic rocks. (3) A gneissose structure with S-C fabrics as well as an ENE-trending sinistral strike-slip characteristic (D3) developed in Upper Jurassic biotite adamellite and show the deformation characteristics of a shallow crustal level and generated mylonitic fabrics superimposed on previous structures. (4) Late granitic dykes show different deformational behavior, and shortening with D4 folds. The attitude of the foliation S and mineral stretching lineation of three main types of rocks shows remarkable differences in orientation. The shapes of recrystallized quartz grains from three main types of granitic rocks with their jagged and indented boundaries were natural records of deformation conditions (D1to D3). Crystal preferred

Importance of interlayer H bonding structure to the stability of layered minerals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conroy, Michele; Soltis, Jennifer A.; Wittman, Rick S.

Layered (oxy) hydroxide minerals often possess out-of-plane hydrogen atoms that form hydrogen bonding networks which stabilize the layered structure. However, less is known about how the ordering of these bonds affects the structural stability and solubility of these minerals. Here, we report a new strategy that uses the focused electron beam to probe the effect of differences in hydrogen bonding networks on mineral solubility. In this regard, the dissolution behavior of boehmite (γ-AlOOH) and gibbsite (γ-Al(OH)3) were compared and contrasted in real time via liquid cell electron microscopy. Under identical such conditions, 2D-nanosheets of boehmite (γ-AlOOH) exfoliated from the bulkmore » and then rapidly dissolved, whereas gibbsite was stable. Further, substitution of only 1% Fe(III) for Al(III) in the structure of boehmite inhibited delamination and dissolution. Factors such as pH, radiolytic species, and knock on damage were systematically studied and eliminated as proximal causes for boehmite dissolution. Instead, the creation of electron/hole pairs was considered to be the mechanism that drove dissolution. The widely disparate behaviors of boehmite, gibbsite, and Fe-doped boehmite are discussed in the context of differences in the OH bond strengths, hydrogen bonding networks, and the presence or absence of electron/hole recombination centers.« less

Importance of interlayer H bonding structure to the stability of layered minerals

DOE PAGES

Conroy, Michele; Soltis, Jennifer A.; Wittman, Rick S.; ...

2017-10-16

Layered (oxy) hydroxide minerals often possess out-of-plane hydrogen atoms that form hydrogen bonding networks which stabilize the layered structure. However, less is known about how the ordering of these bonds affects the structural stability and solubility of these minerals. Here, we report a new strategy that uses the focused electron beam to probe the effect of differences in hydrogen bonding networks on mineral solubility. In this regard, the dissolution behavior of boehmite (γ-AlOOH) and gibbsite (γ-Al(OH)3) were compared and contrasted in real time via liquid cell electron microscopy. Under identical such conditions, 2D-nanosheets of boehmite (γ-AlOOH) exfoliated from the bulkmore » and then rapidly dissolved, whereas gibbsite was stable. Further, substitution of only 1% Fe(III) for Al(III) in the structure of boehmite inhibited delamination and dissolution. Factors such as pH, radiolytic species, and knock on damage were systematically studied and eliminated as proximal causes for boehmite dissolution. Instead, the creation of electron/hole pairs was considered to be the mechanism that drove dissolution. The widely disparate behaviors of boehmite, gibbsite, and Fe-doped boehmite are discussed in the context of differences in the OH bond strengths, hydrogen bonding networks, and the presence or absence of electron/hole recombination centers.« less

Seismic velocity structure in the western part of Nankai subduction zone

NASA Astrophysics Data System (ADS)

Yamamoto, Y.; Obana, K.; Takahashi, T.; Nakanishi, A.; Kodaira, S.; Kaneda, Y.

2011-12-01

In the Nankai Trough, three major seismogenic zones of megathrust earthquake exist (Tokai, Tonankai and Nankai earthquake regions). The Hyuga-nada region was distinguished from these seismogenic zones because of the lack of megathrust earthquake. However, recent studies show the possibility of simultaneous rupture of the Nankai and Hyuga-nada segments was also pointed out [e.g., Furumura et al, 2010 JGR]. Because seismic velocity structure is one of the useful and basic information for understanding the possibility of seismic linkage of Nankai and Hyuga-nada segments, Japan Agency for Marine-Earth Science and Technology has been carried out a series of wide-angle active source surveys and local seismic observations among the three major seismogenic zones and Hyuga-nada segment from 2008, as a part of "Research concerning Interaction Between the Tokai, Tonankai and Nankai Earthquakes' funded by Ministry of Education, Culture, Sports, Science and Technology, Japan". We are performing two set of three-dimensional seismic velocity tomographic inversions, one is in the Hyuga-nada region and the other is western part of the coseismic rupture area of 1946 Nankai earthquake, to discuss the relationship between the structural heterogeneities and the location of segment boundary between Hyuga-nada and Nankai segment. For the analysis of Hyuga-nada segment, we used both active and passive source data. The obtained velocity model clearly showed the subducted Kyushu-Palau ridge as thick low velocity Philippine Sea slab in the southwestern part. Our velocity image also indicates that "the thin oceanic crust zone" located between Nankai segment and Kyushu-Palau Ridge segment, founded by Nakanishi et al [2010, AGU] by analyzing of the active source survey, continuously exists from trough axis to near the coastline of Kyushu Island. The overriding plate just above the coseismic slip area of 1968 Hyuga-nada earthquake shows relatively high velocity. Although the tomographic study in

Characterizing the structural maturity of fault zones using high-resolution earthquake locations.

NASA Astrophysics Data System (ADS)

Perrin, C.; Waldhauser, F.; Scholz, C. H.

2017-12-01

We use high-resolution earthquake locations to characterize the three-dimensional structure of active faults in California and how it evolves with fault structural maturity. We investigate the distribution of aftershocks of several recent large earthquakes that occurred on immature faults (i.e., slow moving and small cumulative displacement), such as the 1992 (Mw7.3) Landers and 1999 (Mw7.1) Hector Mine events, and earthquakes that occurred on mature faults, such as the 1984 (Mw6.2) Morgan Hill and 2004 (Mw6.0) Parkfield events. Unlike previous studies which typically estimated the width of fault zones from the distribution of earthquakes perpendicular to the surface fault trace, we resolve fault zone widths with respect to the 3D fault surface estimated from principal component analysis of local seismicity. We find that the zone of brittle deformation around the fault core is narrower along mature faults compared to immature faults. We observe a rapid fall off of the number of events at a distance range of 70 - 100 m from the main fault surface of mature faults (140-200 m fault zone width), and 200-300 m from the fault surface of immature faults (400-600 m fault zone width). These observations are in good agreement with fault zone widths estimated from guided waves trapped in low velocity damage zones. The total width of the active zone of deformation surrounding the main fault plane reach 1.2 km and 2-4 km for mature and immature faults, respectively. The wider zone of deformation presumably reflects the increased heterogeneity in the stress field along complex and discontinuous faults strands that make up immature faults. In contrast, narrower deformation zones tend to align with well-defined fault planes of mature faults where most of the deformation is concentrated. Our results are in line with previous studies suggesting that surface fault traces become smoother, and thus fault zones simpler, as cumulative fault slip increases.

Chemical and oxygen isotope zonings in garnet from subducted continental crust record mineral replacement and metasomatism

NASA Astrophysics Data System (ADS)

Vho, Alice; Rubatto, Daniela; Regis, Daniele; Baumgartner, Lukas; Bouvier, Anne-Sophie

2017-04-01

Garnet is a key mineral in metamorphic petrology for constraining pressure, temperature and time paths. Garnet can preserve multiple growth stages due to its wide P-T stability field and the relatively slow diffusivity for major and trace elements at sub-solidus temperatures. Pressure-temperature-time-fluid paths of the host rock may be reconstructed by combining metamorphic petrology with microscale trace element and oxygen isotope measurements in garnet. Subduction zones represent relevant geological settings for geochemical investigation of element exchanges during aqueous fluid-rock interactions. The Sesia Zone consists of a complex continental sequence containing a variety of mono-metamorphic and poly-metamorphic lithologies such as metagranitoids, sediments and mafic boudins. The precursor Varisican-Permian amphibolite-facies basement (6-9 kbar 650-850°C; Lardeaux and Spalla, 1991; Robyr et al., 2013) experienced high pressure metamorphism (15-22 kbar 500-550°C; Regis, et al. 2014; Robyr et al., 2013) during Alpine subduction. In different lithologies of the Internal Complex (Eclogitic Micaschist Complex), including metabasites from the Ivozio Complex, Ti-rich metasediments from Val Malone and pre-Alpine Mn-quartzites associated to metagabbros from Cima Bonze, garnet is abundant and shows a variety of complex textures that cannot be reconciled with typical growth zoning, but indicate resorption and replacement processes and possible metasomatism. In-situ, microscale oxygen isotopes analysis of garnet zones was performed by ion microprobe with the SwissSIMS Cameca IMS 1280-HR at University of Lausanne and SHRIMP-SI at the Australian National University. Each sample has a distinct δ18O composition, and the δ18O values show different degrees of variation between domains. Homogeneously low values of < 5‰ are measured in the garnets from the Ivozio Complex metagabbro. Intragrain variations of up to 3.5‰ in the porphyroblasts from Val Malone metasediments

Metasomatic Reaction Zones as Monitors of Trace Element Transfer at the Slab-Mantle Interface: the Case of the Hochwart Peridotite (Ulten Zone, Italy)

NASA Astrophysics Data System (ADS)

Marocchi, M.; Hermann, J.; Bargossi, G. M.; Mair, V.; Morten, L.

2006-12-01

Ultramafic blocks belonging to the Hochwart peridotite outcrop (Ulten Zone, Italian Alps) preserve a series of metasomatic mineral zones generated by infiltration of Si-rich hydrous fluids which occurred at the gneiss- peridotite interface. The age of the high pressure metamorphism for the Hochwart complex has been constrained at 330 Ma (Tumiati et al., 2003, EPSL, 210, 509-526). The country rocks are stromatic gneisses consisting mainly of quartz, K-feldspar, garnet, kyanite, biotite and muscovite. The ultramafic body consists of strongly serpentinized metaperidotites which are exposed as a hectometre-size lens along a steep gully, associated to monomineralic zones that developed at the contact between the peridotite body and the garnet gneiss country rocks. The composition of the metasomatic zones has been investigated in detail and records an order of metasomatic zoning formed by phlogopite-rich to tremolite-anthophyllite-rich rocks going from the host gneiss towards the peridotite. In some cases, the ultramafics fade into the gneisses developing serpentine and talc which has replaced, presumably at lower temperatures, the serpentine matrix and occurs in association with chlorite. Phlogopite aggregates (phlogopitite) with accessory minerals (quartz + zircon + apatite) and metabasic pods (phlogopite and hornblende) also occur. Black tourmaline (schorl-dravite solid solution) has been found for the first time in the contact near the phlogopite zone, suggesting an external addition of elements (boron and fluorine) to the system at high temperature. The formation of the metasomatic zones composed exclusively of hydrous phases must have involved extensive H2O-metasomatism as already documented for the Ulten peridotites. The source for these fluids can be a system of trondhjemitic-pegmatitic dikes cutting the peridotite that would have channelled aqueous fluids into the ultramafic rocks. Whole-rock geochemistry and trace element (LA ICP-MS) composition of hydrous

Fracture zone drilling through Atotsugawa fault in central Japan - geological and geophysical structure -

NASA Astrophysics Data System (ADS)

Omura, K.; Yamashita, F.; Yamada, R.; Matsuda, T.; Fukuyama, E.; Kubo, A.; Takai, K.; Ikeda, R.; Mizuochi, Y.

2004-12-01

Drilling is an effective method to investigate the structure and physical state in and around the active fault zone, such as, stress and strength distribution, geological structure and materials properties. In particular, the structure in the fault zone is important to understand where and how the stress accumulates during the earthquake cycle. In previous studies, we did integrate investigation on active faults in central Japan by drilling and geophysical prospecting. Those faults are estimated to be at different stage in the earthquake cycle, i.e., Nojima fault which appeared on the surface by the 1995 Great Kobe earthquake (M=7.2), the Neodani fault which appeared by the 1891 Nobi earth-quake (M=8.0), the Atera fault, of which some parts have seemed to be dislocated by the 1586 Tensyo earthquake (M=7.9), and Gofukuji Fault that is considered to have activated about 1200 years ago. Each faults showed characteristic features of fracture zone structure according to their geological and geophysical situations. In a present study, we did core recovery and down hole measurements at the Atotsugawa fault, central Japan, that is considered to have activated at 1858 Hida earthquake (M=7.0). The Atotsugawa fault is characterized by active seismicity along the fault. But, at the same time, the shallow region in the central segment of the fault seems to have low seismicity. The high seismicity segment and low seismicity segments may have different mechanical, physical and material properties. A 350m depth borehole was drilled vertically beside the surface trace of the fault in the low seismicity segment. Recovered cores were overall heavily fractured and altered rocks. In the cores, we observed many shear planes holding fault gouge. Logging data showed that the apparent resistance was about 100 - 600 ohm-m, density was about 2.0 - 2.5g/cm3, P wave velocity was approximately 3.0 - 4.0 km/sec, neutron porosity was 20 - 40 %. Results of physical logging show features of fault

Oxygen isotopes in garnet and accessory minerals to constrain fluids in subducted crust

NASA Astrophysics Data System (ADS)

Rubatto, Daniela; Gauthiez-Putallaz, Laure; Regis, Daniele; Rosa Scicchitano, Maria; Vho, Alice; Williams, Morgan

2017-04-01

Fluids are considered a fundamental agent for chemical exchanges between different rock types in the subduction system. Constraints on the sources and pathways of subduction fluids thus provide crucial information to reconstruct subduction processes. Garnet and U-Pb accessory minerals constitute some of the most robust and ubiquitous minerals in subducted crust and can preserve multiple growth zones that track the metamorphic evolution of the sample they are hosted in. Microbeam investigation of the chemical (major and trace elements) and isotopic composition (oxygen and U-Pb) of garnet and accessory minerals is used to track significant fluid-rock interaction at different stages of the subduction system. This approach requires consideration of the diffusivity of oxygen isotopes particularly in garnet, which has been investigated experimentally. The nature of the protolith and ocean floor alteration is preserved in relict accessory phases within eclogites that have been fully modified at HP conditions (e.g. Monviso and Dora Maira units in the Western Alps). Minerals in the lawsonite-blueschists of the Tavsanli zone in Turkey record pervasive fluid exchange between mafic and sedimentary blocks at the early stage of subduction. High pressure shear zones and lithological boundaries show evidence of intense fluid metasomatism at depth along discontinuities in Monviso and Corsica. In the UHP oceanic crust of the Zermatt-Saas Zone, garnet oxygen isotopes and tourmaline boron isotopes indicate multistage fluid infiltration during prograde metamorphism. Localized exchanges of aqueous fluids are also observed in the subducted continental crust of the Sesia-Lanzo Zone. In most cases analyses of distinct mineral zones enable identification of multiple pulses of fluids during the rock evolution.

30 CFR 250.260 - What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD? 250.260 Section 250.260 Mineral Resources MINERALS MANAGEMENT... Operations Coordination Documents (docd) § 250.260 What Coastal Zone Management Act (CZMA) information must...

Discerning Thermodynamic Basis of Self-Organization in Critical Zone Structure and Function

NASA Astrophysics Data System (ADS)

Richardson, M.; Kumar, P.

2017-12-01

Self-organization characterizes the spontaneous emergence of order. Self-organization in the Critical Zone, the region of Earth's skin from below the groundwater table to the top of the vegetation canopy, involves the interaction of biotic and abiotic processes occurring through a hierarchy of temporal and spatial scales. The self-organization is sustained through input of energy and material in an open system framework, and the resulting formations are called dissipative structures. Why do these local states of organization form and how are they thermodynamically favorable? We hypothesize that structure formation is linked to energy conversion and matter throughput rates across driving gradients. Furthermore, we predict that structures in the Critical Zone evolve based on local availability of nutrients, water, and energy. By considering ecosystems as open thermodynamic systems, we model and study the throughput signatures on short times scales to determine origins and characteristics of ecosystem structure. This diagnostic approach allows us to use fluxes of matter and energy to understand the thermodynamic drivers of the system. By classifying the fluxes and dynamics in a system, we can identify patterns to determine the thermodynamic drivers for organized states. Additionally, studying the partitioning of nutrients, water, and energy throughout ecosystems through dissipative structures will help identify reasons for structure shapes and how these shapes impact major Critical Zone functions.

[Near infrared spectrum analysis and meaning of the soil in 512 earthquake surface rupture zone in Pingtong, Sichuan].

PubMed

Yi, Ze-bang; Cao, Jian-jin; Luo, Song-ying; Wang, Zheng-yang; Liao, Yi-peng

2014-08-01

Through modern near infrared spectrum, the authors analyzed the yellow soil from the rupture zone located in Ping- tong town,Pingwu, Sichuan province. By rapid identification of the characteristic of peak absorption of mineral particles, the result shows that the soil samples mainly composed of calcite, dolomite, muscovite, sericite, illite, smectite; talc, tremolite, actinolite, chlorite, etc. And the mineral compositions of the soil is basically the same with the yellow soil in Sichuan region. By analyzing and comparing it was revealed that part of mineral compositions of the soil are in accordance with the characteristics of the rock mineral compositions below the rupture zone, indicating that part of the minerals of the soil's evolution is closely related to the rock compositions in this area; and the compositions of the clay mineral in the rupture zone is similar to the Ma Lan loess in the north of China, so it is presumed that the clay minerals in these two kinds of soil have the same genetic type. The characteristic of the mineral composition of the soil is in accordance with evolution characteristics of the rocks which is bellow the rupture zone, also it was demonstrated that the results of soil minerals near-infrared analysis can effectively analyze the mineral particles in the soil and indicate the pedogenic environment. Therefore, the result shows the feasibility of adopting modern near-infrared spectrum for rapid analysis of mineral particles of the soil and research of geology. Meanwhile, the results can be the foundation of this region's soil mineral analysis, and also provide new ideas and methods for the future research of soil minerals and the earthquake rupture zone.

The electrical resistivity signature of a fault controlling gold mineralization and the implications for Mesozoic mineralization: a case study from the Jiaojia Fault, eastern China

NASA Astrophysics Data System (ADS)

Zhang, Kun; Lü, Qingtian; Yan, Jiayong; Hu, Hao; Fu, GuangMing

2017-08-01

We use 3D audio magnetotelluric method to the south segment of Jiaojia fault belt, and obtain the 3D electrical model of this area. Regional geophysical data were combined in an analysis of strata and major structural distribution in the study area, and included the southern segment of the Jiaojia fault zone transformed into two fault assemblages. Together with the previous studies of the ore-controlling action of the Jiaojia fault belt and deposit characteristics, the two faults are considered to be favorable metallogenic provinces, because some important features coupled with them, such as the subordinate fault intersection zone and several fault assemblages in one fault zone. It was also suggested the control action of later fault with reversed downthrows to the ore distribution. These studies have enabled us to predict the presence of two likely target regions of mineralization, and are prospecting breakthrough in the southern section of Jiaojia in the Shandong Peninsula, China.

Structure of first- and second-stage mineralized elements in teeth of the sea urchin Lytechinus variegatus.

PubMed

Robach, J S; Stock, S R; Veis, A

2009-12-01

Microstructure of the teeth of the sea urchin Lytechinus variegatus was investigated using optical microscopy, SEM (scanning electron microscopy) and SIMS (secondary ion mass spectroscopy). The study focused on the internal structure of the first-stage mineral structures of high Mg calcite (primary, secondary and carinar process plates, prisms) and on morphology of the columns of second-stage mineral (very high Mg calcite) that cement the first-stage material together. Optical micrographs under polarized light revealed contrast in the centers (midlines) of carinar process plates and in prisms in polished sections; staining of primary and carinar process plates revealed significant dye uptake at the plate centers. Demineralization with and without fixation revealed that the midlines of primary and carinar process plates (but not secondary plates) and the centers of prisms differed from the rest of the plate or prism, and SIMS showed proteins concentrated in these plate centers. SEM was used to study the morphology of columns, the fracture surfaces of mature teeth and the 3D morphology of prisms. These observations of internal structures in plates and prisms offer new insight into the mineralization process and suggest an important role for protein inclusions within the first-stage mineral. Some of the 3D structures not reported previously, such as twisted prisms and stacks of carinar process plates with nested wrinkles, may represent structural strengthening strategies.

Structure of first- and second-stage mineralized elements in teeth of the sea urchin Lytechinus variegatus

PubMed Central

Robach, J. S.; Stock, S. R.; Veis, A.

2009-01-01

Microstructure of the teeth of the sea urchin Lytechinus variegatus was investigated using optical microscopy, SEM (scanning electron microscopy) and SIMS (secondary ion mass spectroscopy). The study focused on the internal structure of the first-stage mineral structures of high Mg calcite (primary, secondary and carinar process plates; prisms) and on morphology of the columns of second-stage mineral (very high Mg calcite) that cement the first-stage material together. Optical micrographs under polarized light revealed contrast in the centers (midlines) of carinar process plates and in prisms in polished sections; staining of primary and carinar process plates revealed significant dye uptake at the plate centers. Demineralization with and without fixation revealed that the midlines of primary and carinar process plates (but not secondary plates) and the centers of prisms differed from the rest of the plate or prism, and SIMS showed proteins concentrated in these plate centers. SEM was used to study the morphology of columns, the fracture surfaces of mature teeth and the 3D morphology of prisms. These observations of internal structures in plates and prisms offer new insight into the mineralization process and suggest an important role for protein inclusions within the first-stage mineral. Some of the 3D structures not reported previously, such as twisted prisms and stacks of carinar process plates with nested wrinkles, may represent structural strengthening strategies. PMID:19616101

76 FR 37828 - Update to Indian Index Zone Price Points

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-28

... to Indian Index Zone Price Points AGENCY: Office of Natural Resources Revenue, Interior. ACTION... (MMS) Minerals Revenue Management) is announcing an update to Indian index zone price points that will remove certain natural gas index prices from the Indian Index Zone calculation. These changes will impact...

30 CFR 256.20 - Consideration of coastal zone management program.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Consideration of coastal zone management....20 Consideration of coastal zone management program. In the development of the leasing program, consideration shall be given to the coastal zone management program being developed or administered by an...

Interpretation of aeromagnetic data in the Jameson Land Basin, central East Greenland: Structures and related mineralized systems

NASA Astrophysics Data System (ADS)

Brethes, Anaïs; Guarnieri, Pierpaolo; Rasmussen, Thorkild Maack; Bauer, Tobias Erich

2018-01-01

This paper provides a detailed interpretation of several aeromagnetic datasets over the Jameson Land Basin in central East Greenland. The interpretation is based on texture and lineament analysis of magnetic data and derivatives of these, in combination with geological field observations. Numerous faults and Cenozoic intrusions were identified and a chronological interpretation of the events responsible for the magnetic features is proposed built on crosscutting relationships and correlated with absolute ages. Lineaments identified in enhanced magnetic data are compared with structures controlling the mineralized systems occurring in the area and form the basis for the interpretations presented in this paper. Several structures associated with base metal mineralization systems that were known at a local scale are here delineated at a larger scale; allowing the identification of areas displaying favorable geological settings for mineralization. This study demonstrates the usefulness of high-resolution airborne magnetic data for detailed structural interpretation and mineral exploration in geological contexts such as the Jameson Land Basin.

Mass change calculations of hydrothermal alterations within the volcanogenic metasediments hosted Cu-Pb (-Zn) mineralization at Halilar area, NW Turkey

NASA Astrophysics Data System (ADS)

Kiran Yildirim, Demet; Abdelnasser, Amr; Doner, Zeynep; Kumral, Mustafa

2016-04-01

The Halilar Cu-Pb (-Zn) mineralization that is formed in the volcanogenic metasediments of Bagcagiz Formation at Balikesir province, NW Turkey, represents locally vein-type deposit as well as restricted to fault gouge zone directed NE-SW along with the lower boundary of Bagcagiz Formation and Duztarla granitic intrusion in the study area. Furthermore, This granite is traversed by numerous mineralized sheeted vein systems, which locally transgress into the surrounding metasediments. Therefore, this mineralization closely associated with intense hydrothermal alteration within brecciation, and quartz stockwork veining. The ore mineral assemblage includes chalcopyrite, galena, and some sphalerite with covellite and goethite formed during three phases of mineralization (pre-ore, main ore, and supergene) within an abundant gangue of quartz and calcite. The geologic and field relationships, petrographic and mineralogical studies reveal two alteration zones occurred with the Cu-Pb (-Zn) mineralization along the contact between the Bagcagiz Formation and Duztarla granite; pervasive phyllic alteration (quartz, sericite, and pyrite), and selective propylitic alteration (albite, calcite, epidote, sericite and/or chlorite). This work, by using the mass balance calculations, reports the mass/volume changes (gain and loss) of the chemical components of the hydrothermal alteration zones associated with Halilar Cu-Pb (-Zn) mineralization at Balikesir area (Turkey). It revealed that the phyllic alteration has enrichments of Si, Fe, K, Ba, and LOI with depletion of Mg, Ca, and Na reflect sericitization of alkali feldspar and destruction of ferromagnesian minerals. This zone has high Cu and Pb with Zn contents represents the main mineralized zone. On the other hand, the propylitic zone is characterized by addition of Ca, Na, K, Ti, P, and Ba with LOI and Cu (lower content) referring to the replacement of plagioclase and ferromagnesian minerals by albite, calcite, epidote, and sericite

Mass changes during hydrothermal alteration/mineralization in the gold-bearing Astaneh granitoid, western Iran

NASA Astrophysics Data System (ADS)

Zahra Afshooni, Seyedeh; Esmaeily, Dariush

2010-05-01

The Astaneh granitoid massif, located in western Iran, is a part of Sanandaj-Sirjan structural Zone. This body, mainly consist of granodioritic rocks, is widely affected under hydrothermal alteration and four alteration zones including phyllic (sericitic), chloritic, propylitic and argillic zones could be identified in this area. Four main mineralization- related alteration episodes have been studied in terms of mass transfer and element mobility during the hydrothermal evolution of Astaneh deposit. In order to illustrate these changes quantitatively, isocon plots have been applied. Isocon plots illustrate that Al, Ti, Ga and Tm was relatively immobile during alteration and that mass were essentially conserved during alteration. Phyllic alteration was accompanied by the depletion of Na and Fe and the enrichment of Si and Cu. The loss of Na and Fe reflects the sericitization of alkali feldspar and the destruction of ferromagnesian minerals. The addition of Si is consistent with widespread silicification wich is a major feature of phyllic alteration. All of the HFSE (except in Y), were enriched but all REEs were depleted in this zone. The overall obtained results show that major oxides such as SiO2, Al2O3, Fe2O3, MnO, MgO, CaO, Na2O, K2O, P2O5 and TiO2 and also LOI show dissimilar behaviors in the different zones. All of the LFSE, HFSE and FTSM (except in Cu and Mo) were depleted in argillic alteration but show dissimilar behaviors in the other alteration zones. The results shown strong depletion in REE, in particular LREE, in all of the alteration facies (except in chloritic zone), equivalent fresh rocks. In chloritic zone, compared with HREE, the LREE represent more enrichment.

Structural optimization and amorphous calcium phosphate mineralization in sensory setae of a terrestrial crustacean (Isopoda: Oniscidea).

PubMed

Vittori, Miloš; Srot, Vesna; Bussmann, Birgit; Predel, Felicitas; van Aken, Peter A; Štrus, Jasna

2018-06-09

Terrestrial isopods possess large sensory setae on their walking legs. Increased fracture resistance of these elongated structures is of crucial importance, making the exoskeleton forming the setae an interesting durable material that may inspire biomimetic designs. We studied the cuticle of the sensory setae with analytical electron microscopy in order to gain detailed insights into its structure and composition at the nanometer scale and identify features that increase the fracture resistance of these minute skeletal elements. The setae are stiff structures formed by mineralized cuticle that are connected to the leg exoskeleton by a non-mineralized joint membrane. Our results demonstrate that different layers of the setal cuticle display contrasting organizations of the chitin-protein fibers and mineral particles. While in the externally positioned exocuticle organic fibers shift their orientation helicoidally in sequential layers, the fibers are aligned axially in the internally positioned endocuticle. In the setal cuticle, layers of structurally anisotropic cuticle likely providing strength in the axial direction are combined with layers of isotropic cuticle which may allow the setae to better resist perpendicular loading. They are further strengthened with amorphous calcium phosphate, a highly fracture resistant mineral rarely observed in invertebrate skeletons. Copyright © 2018 Elsevier Ltd. All rights reserved.

Single crystal neutron diffraction of hydrous wadsleyite and the reason of sensitivity difference for hydration between upper and lower mantle transition zones

NASA Astrophysics Data System (ADS)

Purevjav, N.; Okuchi, T.; Tomioka, N.; Wang, X.; Hoffmann, C.

2016-12-01

Evidences from seismological and mineralogical studies increasingly indicates that water has been transported from the oceans into the Earth's deep mantle, where the mantle transition zone is believed to be the largest reservoir of this transported water. Wadsleyite and ringwoodite are the major constituents and the most important host minerals absorbing this type of water in the transition zone. These minerals are capable of storing the entire mass of the oceans as a hidden reservoirs. In order to understand the effects of such water on the physical properties and chemical evolution of the Earth's interior, it is essential to determine where in the crystal structure the hydration occurs, and which chemical bonds are altered and weakened after hydration. Here we show the result of a neutron single-crystal Laue diffraction study of hydrous wadsleyite. A crystal of homogenously-hydrated wadsleyite involving 1.4 wt. % of H2O was synthesized by our recently-established slow cooling method, which was an effective way to grow high quality large single crystals [1]. By analyzing this crystal using pulsed neutron beam, we demonstrated that the hydrogen atoms exchange only with Mg2+ at the one of the specific octahedron sites (M3) in wadsleyite. We also determined hydrogen's bonding distances and bonding angle. The results unambiguously demonstrated the unique mechanism of hydrogen incorporation into the wadsleyite crystal structure. We previously found that the hydrogen atoms exchanged with both Mg2+ and Si4+ sites simultaneously in the crystal structure of hydrous ringwoodite [2]. Therefore, the current results show that hydration mechanisms are qualitatively different between the upper and the lower transition zones in the wet mantle. The difference is a vital clue towards understanding why these mantle transition zone minerals show different sensitivity for water in their softening behaviors. In addition, we demonstrated that maximum water concentration in wadsleyite is

Mineral shock signatures in rocks from Dhala (Mohar) impact structure, Shivpuri district, Madhya Pradesh, India

NASA Astrophysics Data System (ADS)

Roy, Madhuparna; Pandey, Pradeep; Kumar, Shailendra; Parihar, P. S.

2017-12-01

A concrete study combining optical microscopy, Raman spectroscopy and X-ray diffractometry, was carried out on subsurface samples of basement granite and melt breccia from Mohar (Dhala) impact structure, Shivpuri district, Madhya Pradesh, India. Optical microscopy reveals aberrations in the optical properties of quartz and feldspar in the form of planar deformation feature-like structures, lowered birefringence and mosaics in quartz, toasting, planar fractures and ladder texture in alkali feldspar and near-isotropism in bytownite. It also brings to light incidence of parisite, a radioactive rare mineral in shocked granite. Raman spectral pattern, peak positions, peak widths and multiplicity of peak groups of all minerals, suggest subtle structural/crystallographic deviations. XRD data further reveals minute deviations of unit cell parameters of quartz, alkali feldspar and plagioclase, with respect to standard α-quartz, high- and low albite and microcline. Reduced cell volumes in these minerals indicate compression due to pressure. The c0/a0 values indicate an inter-tetrahedral angle roughly between 120o and 144o, further pointing to a possible pressure maxima of around 12 GPa. The observed unit cell aberration of minerals may indicate an intermediate stage between crystalline and amorphous stages, thereby, signifying possible overprinting of decompression signatures over shock compression effects, from a shock recovery process.

The Later Paleozoic granites of the Greater Caucasus Fore Range zone: geochemistry, magnetic properties and the structural and metamorphic evolution.

NASA Astrophysics Data System (ADS)

Kamzolkin, Vladimir; Latyshev, Anton; Ivanov, Stanislav; Vidjapin, Jury

2017-04-01

Clarification of the position of the granitic intrusions associated with the Blyb Metamorphic Complex is the important problem of the reconstruction of the structural evolution of the Greater Caucasus Fore Range zone. Based of the rock geochemistry we found out that the quartz diorites, granodiorites and syeno-granites of the BMC formed in suprasubduction conditions and refer to I-type granites. However, their emplacement was multistage coinciding with the various stages of the BMC evolution. We detected the mineral associations typical for the epidote-amphibolite facies in the Balkan massif, but these metamorphic features are absent in the granodiorite intrusions in the southern part of the Fore Range zone. Thus, quartz diorites of the Balkan intrusion intruded after the high-pressure metamorphism of the host rocks, but before the epidote-amphibolite stage, and the Southern granodiorite intrusions are younger. The measurements of the anisotropy of the magnetic susceptibility (AMS) in the Balkan intrusion indicated the shallow orientation of the minimal (north-eastern strike) and maximal (north-western strike) axes of the AMS ellipsoid. This result is compatible with the idea of the north-east compression fixed in the fold deformation structures of the BMC host rocks (Vidyapin, Kamzolkin, 2015). However, the macroscopic foliation in the granites dips to the east steeply. The discrepancy of the texture orientation of the granites, the host rock structure and the magnetic fabric can be explained as a result of the repeated changes of the stress field during the evolution of the Fore Range nappe structures. The reported study was partially supported by RFBR, research projects No. 16-35-00571mol_a; 16-05-01012a.

Effects of chemical and mineral admixtures on performance of Florida structural concrete.

DOT National Transportation Integrated Search

2016-06-21

Several mineral and chemical admixtures, commonly used in Florida structural concrete, were studied here to assess their effect on the fresh and hardened properties of cementitious systems. Pozzolans examined here were Class F fly ash, silica fume, b...

30 CFR 256.20 - Consideration of coastal zone management program.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 2 2011-07-01 2011-07-01 false Consideration of coastal zone management... SHELF Oil and Gas Leasing Program § 256.20 Consideration of coastal zone management program. In the development of the leasing program, consideration shall be given to the coastal zone management program being...

Geochemical soil sampling for deeply-buried mineralized breccia pipes, northwestern Arizona

USGS Publications Warehouse

Wenrich, K.J.; Aumente-Modreski, R. M.

1994-01-01

Thousands of solution-collapse breccia pipes crop out in the canyons and on the plateaus of northwestern Arizona; some host high-grade uranium deposits. The mineralized pipes are enriched in Ag, As, Ba, Co, Cu, Mo, Ni, Pb, Sb, Se, V and Zn. These breccia pipes formed as sedimentary strata collapsed into solution caverns within the underlying Mississippian Redwall Limestone. A typical pipe is approximately 100 m (300 ft) in diameter and extends upward from the Redwall Limestone as much as 1000 m (3000 ft). Unmineralized gypsum and limestone collapses rooted in the Lower Permian Kaibab Limestone or Toroweap Formation also occur throughout this area. Hence, development of geochemical tools that can distinguish these unmineralized collapse structures, as well as unmineralized breccia pipes, from mineralized breccia pipes could significantly reduce drilling costs for these orebodies commonly buried 300-360 m (1000-1200 ft) below the plateau surface. Design and interpretation of soil sampling surveys over breccia pipes are plagued with several complications. (1) The plateau-capping Kaibab Limestone and Moenkopi Formation are made up of diverse lithologies. Thus, because different breccia pipes are capped by different lithologies, each pipe needs to be treated as a separate geochemical survey with its own background samples. (2) Ascertaining true background is difficult because of uncertainties in locations of poorly-exposed collapse cones and ring fracture zones that surround the pipes. Soil geochemical surveys were completed on 50 collapse structures, three of which are known mineralized breccia pipes. Each collapse structure was treated as an independent geochemical survey. Geochemical data from each collapse feature were plotted on single-element geochemical maps and processed by multivariate factor analysis. To contrast the results between geochemical surveys (collapse structures), a means of quantifying the anomalousness of elements at each site was developed. This

FoldMiner and LOCK 2: protein structure comparison and motif discovery on the web.

PubMed

Shapiro, Jessica; Brutlag, Douglas

2004-07-01

The FoldMiner web server (http://foldminer.stanford.edu/) provides remote access to methods for protein structure alignment and unsupervised motif discovery. FoldMiner is unique among such algorithms in that it improves both the motif definition and the sensitivity of a structural similarity search by combining the search and motif discovery methods and using information from each process to enhance the other. In a typical run, a query structure is aligned to all structures in one of several databases of single domain targets in order to identify its structural neighbors and to discover a motif that is the basis for the similarity among the query and statistically significant targets. This process is fully automated, but options for manual refinement of the results are available as well. The server uses the Chime plugin and customized controls to allow for visualization of the motif and of structural superpositions. In addition, we provide an interface to the LOCK 2 algorithm for rapid alignments of a query structure to smaller numbers of user-specified targets.

Microstructural evidence for dissolution precipitation creep in high pressure metamorphic serpentinites from subduction zones

NASA Astrophysics Data System (ADS)

Wassmann, S.; Trepmann, C.; Krohe, A.; Stoeckhert, B.

2009-12-01

Serpentinite is generally believed to constitute weak material in subduction zones and to play an essential role for the development of a subduction channel. Information on deformation mechanisms and appropriate rheological models to describe these large scale flow processes is obtained from natural serpentinites exhumed from ancient subduction zones. In this study, we investigate the microstructural record of serpentinites exposed in the Zermatt-Saas-Zone, Western Alps. The metamorphic mineral assemblage comprises antigorite, forsterite, diopside, tremolite, chlorite, oxide phases, and in places titanclinohumite. Original mantle minerals are only locally preserved as relics. The conditions of Alpine metamorphism can be estimated from associated eclogites; the pressures are mostly between 1.5 and 2.5 GPa at temperatures of c. 500-600°C. The serpentinites show a complex structure with several generations of folds and foliations. An early foliation is defined by the combined shape and crystallographic preferred orientation (SPO and CPO) of antigorite and metamorphic diopside. These patterns are undistinguishable from the SPO and CPO of the same minerals in strain shadows, where the CPO must be developed by oriented growth from an aqueous solution. Therefore we suspect that the SPO and CPO in the polyphase matrix layers also result from oriented growth. Also, there is no microstructural evidence for any crystal plastic deformation of diopside. In places, antigorite flakes with SPO and CPO are overgrown by single crystals or aggregates of metamorphic forsterite, locally titanoclinohumite, and tremolite. The aggregates of forsterite exhibit a foam structure without CPO. All microfabrics indicate that dissolution precipitation creep was predominant in the investigated serpentinites, and most finite strain was accumulated by this mechanism. We see no evidence for a significant contribution of dislocation creep, both based on microstructure and on the CPO patterns. This

Radial Anisotropy in the Mantle Transition Zone and Its Implications

NASA Astrophysics Data System (ADS)

Chang, S. J.; Ferreira, A. M.

2016-12-01

Seismic anisotropy is a useful tool to investigate mantle flow, mantle convection, and the presence of melts in mantle, since it provides information on the direction of mantle flow or the orientation of melts by combining it with laboratory results in mineral physics. Although the uppermost and lowermost mantle with strong anisotropy have been well studied, anisotropic properties of the mantle transition zone is still enigmatic. We use a recent global radially anisotropic model, SGLOBE-rani, to examine the patterns of radial anisotropy in the mantle transition zone. Strong faster SV velocity anomalies are found in the upper transition zone beneath subduction zones in the western Pacific, which decrease with depth, thereby nearly isotropic in the lower transition zone. This may imply that the origin for the anisotropy is the lattice-preferred orientation of wadsleyite, the dominant anisotropic mineral in the upper transition zone. The water content in the upper transition zone may be inferred from radial anisotropy because of the report that anisotropic intensity depends on the water content in wadsleyite.

Tertiary extension and mineral deposits, southwestern U.S.

USGS Publications Warehouse

Rehrig, William A.; Hardy, James.J.

1996-01-01

Starting in Las Vegas, we will traverse through many of the geometric elements and complexities of hanging wall deformation above the regional detachment systems of the Colorado River extensional terrane. We will study the interaction of normal faults as arranged in regional, crustal-scale mega-domains and the bounding structures that separate these tilt domains. As we progress through the classic Eldorado Mountains-Hoover Dam region, where many of the ideas of listric normal faulting were first popularized, we will see both the real rocks and the historic rationale for their deformation. By examining the listric versus domino models for normal faulting, we will utilize different geometric techniques for determining the depth to the detachment structures and percent extension. Continuing further south toward southernmost Nevada, we will cross the accommodation zone that separates the Lake Mead and Whipple dip domains and further descend to deeper structural levels to examine lower levels of the major normal faults and their tilting of upper-crustal blocks and associated offset along the regional detachment faults. Fluid flow within the shattered fault zones and its relationship to the 3-D geometries of the fault surfaces will be studied both along the faults and within the hydrothermally altered and mineralized wallrocks.

Clay Minerals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

2014-03-14

Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studiesmore » of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with specific sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.« less

Geochemistry and origins of mineralized waters in the Floridan aquifer system, northeastern Florida

USGS Publications Warehouse

Phelps, G.G.

2001-01-01

Increases in chloride concentration have been observed in water from numerous wells tapping the Floridan aquifer system in northeastern Florida. Although most increases have been in the eastern part of Duval County, Florida, no spatial pattern in elevated chloride concentrations is discernible. Possible sources of the mineralized water include modern seawater intrusion; unflushed Miocene-to-Pleistocene-age seawater or connate water in aquifer sediments; or mineralized water from deeper zones of the aquifer system or from formations beneath the Floridan aquifer system. The purpose of this study was to document the chemical and isotopic characteristics of water samples from various aquifer zones, and from geochemical and hydrogeologic data, to infer the source of the increased mineralization. Water samples were collected from 53 wells in northeastern Florida during 1997-1999. Wells tapped various zones of the aquifer including: the Fernandina permeable zone (FPZ), the upper zone of the Lower Floridan aquifer (UZLF), the Upper Floridan aquifer (UFA), and both the UFA and the UZLF. Water samples were analyzed for major ions and trace constituents and for isotopes of carbon, oxygen, hydrogen, sulfur, strontium, chlorine, and boron. Samples of rock from the aquifer were analyzed for isotopes of oxygen, carbon, and strontium. In general, water from various aquifer zones cannot be differentiated based on chemistry, except for water from FPZ wells. Major-ion concentrations vary as much within the upper zone of the Lower Floridan aquifer and the Upper Floridan aquifer as between these two zones. Simple models of mixing between fresh ground water and either modern seawater or water from the FPZ as a mineralized end member show that many water samples from the UZLF aquifer and the UFA are enriched in bicarbonate, calcium, magnesium, sulfate, fluoride, and silica and are depleted in sodium and potassium (as compared to concentrations predicted by simple mixing). Chemical mass

Marine mineral resources of Pacific Islands - a review of the Exclusive Economic Zones of islands of U.S. affiliation, excluding the State of Hawaii

USGS Publications Warehouse

Hein, James R.; McIntyre, Brandie R.; Piper, David Z.

2005-01-01

The United States Exclusive Economic Zone (EEZ) was established in 1983 and comprises all marine areas within 200 nautical miles (370 kilometers) of the nearest U.S. land. This vast area of 3.38 million square nautical miles (11.6 million square kilometers) is about 20 percent greater than the entire land area of the United States. The resource potential of the vast mineral deposits that occur within the U.S. EEZ is unknown, despite field studies that have taken place during the past 25 years. Since about 1975, information on marine mineral deposits has been obtained by numerous research cruises to the Pacific Ocean by the U.S. Geological Survey (USGS), the U.S. National Oceanic and Atmospheric Administration (NOAA), equivalent government agencies in Germany, Canada, France, Russia, Japan, China, South Korea, Australia, and New Zealand, and by academic researchers from all of these nations. Although most of the cruises by other nations explored areas outside the U.S. EEZ, information gained from those studies can aid in the evaluation of the mineral potential in the U.S. EEZ. However, the global effort remains inadequate to allow for the quantitative evaluation of mineral resources contained within the EEZ of nations or within international regions of the oceans.

Shear zones of the Verkhoyansk fold-and-thrust belt, Northeast Russia

NASA Astrophysics Data System (ADS)

Fridovsky, Valery; Polufuntikova, Lena

2017-04-01

The Verkhoyansk fold-and-thrust belt is situated on the submerged eastern margin of the North Asian craton, and is largely composed of the Ediacaran - Middle Paleozoic carbonate and the Upper Paleozoic-Mesozoic terrigenous rocks. The Upper Carboniferous - Jurassic sediments constitute the Verkhoyansk terrigenous complex containing economically viable orogenic gold deposits. The structure of the belt is mainly controlled by thrusts and associated diagonal strike slips. Linear concentric folds are common all over the area of the belt. Shear zones with associated similar folds are confined to long narrow areas. Shear zones were formed during the early stages of the Oxfordian-Kimmeridgian collisional and accretionary events prior to the emplacement of large orogenic granitoid plutons. The main ore-controlling structures are shear zones associated with slaty cleavage, shear folds, mullion- and boudinage-structures, and transposition features. The shear zones are listric-type, and represent branches of a detachment structure, which is assumed to be present at the base of the Verkhoyansk fold-and-thrust belt. A vertical zonation of shear zones is correlated with the distance to the detachment. Changes in the dip angle of the shear zones (as indicated mainly by cleavage), structural paragenesis, the degree of microdeformation of the host rocks, and the type of ore-controlling structures can be clearly observed in the direction away from the detachment. Structural zoning is evidenced, among other things, by changing morphologic types of microstructures and by strain-indicators of the degree of rock metamorphism. Four morphologic types of microstructures are identified. The first platy-shear type is characterized by aggregate cleavage and the coefficient of deformation (Cd) of single grains from 1.0 to 2.0. Irregular angular fragments of variously oriented grains can be observed in thin sections. The second shear-cataclastic morphologic type (Cd from 2.0 to 3.0) exhibits

Application of Remote-Sensing Observations for Detecting Patterns of Localization of PGM Mineralization of Western Bushveld

NASA Astrophysics Data System (ADS)

Milovsky, G. A.; Ishmukhametova, V. T.; Orlyankin, V. N.; Shemyakina, E. M.

2017-12-01

The differentiated Bushveld complex is studied by remote-space and gravimagnetic methods. The syncline of Western Bushveld is recognized in the southwestern part of the complex, which is characterized by a radial and ring structure of the higher order. The structures, which control the localization of Pt mineralization, are revealed and the possible use of the Landsat 7 ETM+ multizonal space survey is shown for recognizing the rocks of the Basal, Critical, Main, and Upper zones of the norite complex of Western Bushveld.

Minerals Yearbook, volume I, Metals and Minerals

USGS Publications Warehouse

,

2018-01-01

The U.S. Geological Survey (USGS) Minerals Yearbook discusses the performance of the worldwide minerals and materials industries and provides background information to assist in interpreting that performance. Content of the individual Minerals Yearbook volumes follows:Volume I, Metals and Minerals, contains chapters about virtually all metallic and industrial mineral commodities important to the U.S. economy. Chapters on survey methods, summary statistics for domestic nonfuel minerals, and trends in mining and quarrying in the metals and industrial mineral industries in the United States are also included.Volume II, Area Reports: Domestic, contains a chapter on the mineral industry of each of the 50 States and Puerto Rico and the Administered Islands. This volume also has chapters on survey methods and summary statistics of domestic nonfuel minerals.Volume III, Area Reports: International, is published as four separate reports. These regional reports contain the latest available minerals data on more than 180 foreign countries and discuss the importance of minerals to the economies of these nations and the United States. Each report begins with an overview of the region’s mineral industries during the year. It continues with individual country chapters that examine the mining, refining, processing, and use of minerals in each country of the region and how each country’s mineral industry relates to U.S. industry. Most chapters include production tables and industry structure tables, information about Government policies and programs that affect the country’s mineral industry, and an outlook section.The USGS continually strives to improve the value of its publications to users. Constructive comments and suggestions by readers of the Minerals Yearbook are welcomed.

Localized sulfate-reducing zones in a coastal plain aquifer

USGS Publications Warehouse

Brown, C.J.; Coates, J.D.; Schoonen, M.A.A.

1999-01-01

High concentrations of dissolved iron in ground water of coastal plain or alluvial aquifers contribute to the biofouling of public supply wells for which treatment and remediation is costly. Many of these aquifers, however, contain zones in which microbial sulfate reduction and the associated precipitation of iron-sulfide minerals decreases iron mobility. The principal water-bearing aquifer (Magothy Aquifer of Cretaceous age) in Suffolk County, New York, contains localized sulfate-reducing zones in and near lignite deposits, which generally are associated with clay lenses. Microbial analyses of core samples amended with [14C]-acetate indicate that microbial sulfate reduction is the predominant terminal-electron-accepting process (TEAP) in poorly permeable, lignite-rich sediments at shallow depths and near the ground water divide. The sulfate-reducing zones are characterized by abundant lignite and iron-sulfide minerals, low concentrations of Fe(III) oxyhydroxides, and by proximity to clay lenses that contain pore water with relatively high concentrations of sulfate and dissolved organic carbon. The low permeability of these zones and, hence, the long residence time of ground water within them, permit the preservation and (or) allow the formation of iron-sulfide minerals, including pyrite and marcasite. Both sulfate-reducing bacteria (SRB) and iron-reducing bacteria (IRB) are present beneath and beyond the shallow sulfate-reducing zones. A unique Fe(III)-reducing organism, MD-612, was found in core sediments from a depth of 187 m near the southern shore of Long Island. The distribution of poorly permeable, lignite-rich, sulfate-reducing zones with decreased iron concentration is varied within the principal aquifer and accounts for the observed distribution of dissolved sulfate, iron, and iron sulfides in the aquifer. Locating such zones for the placement of production wells would be difficult, however, because these zones are of limited aerial extent.

The Vardar zone as a suture for the Mirdita ophiolites, Albania: Constraints from the structural analysis of the Korabi-Pelagonia zone

NASA Astrophysics Data System (ADS)

Tremblay, Alain; Meshi, Avni; Deschamps, Thomas; Goulet, François; Goulet, Normand

2015-02-01

The Dinarides-Hellenides result from underthrusting of the Adriatic margin during Africa-Europe convergence. In Albania, they consist of (1) a western zone of nappes derived from Adria; (2) a central belt made up of the Mirdita ophiolites; and (3) an eastern zone, the Korabi-Pelagonia zone, of Variscan basement overlain by Permian to Mesozoic rift deposits and carbonates. Some authors interpret the Korabi-Pelagonia zone as a microcontinent between the Mirdita-Pindos oceanic basin to the west and the eastern Vardar oceanic basin to the east; other regard the Korabi-Pelagonia zone as a tectonic window below a single ophiolitic nappe. This contribution argues for a far-traveled thrust sheet. The Mirdita ophiolites are 165-160 Ma. The metamorphic sole yielded 40Ar/39Ar ages of 171 to 162 Ma. The Korabi-Pelagonia zone is subdivided into the Korabi and Gjegjan subzones. The structural analysis of these rocks supports the rooting of the Mirdita ophiolites in the Western Vardar zone. The post-Variscan cover sequence of the Korabi subzone records two phases of deformation: D1 is associated with a SE dipping to flat-lying schistosity axial planar to NW verging folds and thrust faults, related to ophiolite obduction; D2 is a postobduction NNE trending crenulation cleavage. Published zircon fission track analyses yielded 150-125 Ma, suggesting that regional metamorphism is Early Cretaceous or older. K-Ar mica ages from correlative rocks of Macedonia cluster between 148 and 130 Ma, indicating that D1 is Late Jurassic. A west directed obduction is favored, as is a rooting east of the Mirdita ophiolites because of the top-to-the-west structural polarity of obduction-related deformation.

The influence of condensed tannin structure on rate of microbial mineralization and reactivity to chemical assays.

PubMed

Norris, Charlotte E; Preston, Caroline M; Hogg, Karen E; Titus, Brian D

2011-03-01

We examined how tannin structure influences reactivity in tannin assays and carbon and nitrogen mineralization. Condensed tannins from the foliage of ten tree and shrub species and from pecan shells (Carya illinoensis) had different proportions of: (a) epicatechin (cis) and catechin (trans) isomers, (b) procyanidin (PC) and prodelphinidin (PD) monomers, and (c) different chain lengths. The response of each tannin to several widely used tannin assays was determined. Although there was some variation in response to proanthocyanidin (butanol/HCl) and Folin Ciocalteu assays, we did not deduce any predictable relationship between tannin structure and response to either assay. There was little variation in protein precipitation among the different tannins. To assess biological activity, six of the tannins were incubated with forest humus for 22 days. We determined that, while PC-based tannins remained at least partly extractable for the duration of the incubation, tannins with a high proportion of PD subunits rapidly became unextractable from soil. There was a positive correlation between net nitrogen mineralization and cis chemical structure. Carbon mineralization was enhanced initially by the addition of tannins to humus, but after 22 days, a negative correlation between the proportion of cis subunits and respiration was determined. Overall, we were not able to demonstrate consistent effects of structure on either microbial mineralization or reactivity to chemical assays; such relationships remain elusive.

Geometry of the neoproterozoic and paleozoic rift margin of western Laurentia: Implications for mineral deposit settings

USGS Publications Warehouse

Lund, K.

2008-01-01

The U.S. and Canadian Cordilleran miogeocline evolved during several phases of Cryogenian-Devonian intracontinental rifting that formed the western mangin of Laurentia. Recent field and dating studies across central Idaho and northern Nevada result in identification of two segments of the rift margin. Resulting interpretations of rift geometry in the northern U.S. Cordillera are compatible with interpretations of northwest- striking asymmetric extensional segments subdivided by northeast-striking transform and transfer segments. The new interpretation permits integration of miogeoclinal segments along the length of the western North American Cordillera. For the U.S. Cordillera, miogeoclinal segments include the St. Mary-Moyie transform, eastern Washington- eastern Idaho upper-plate margin, Snake River transfer, Nevada-Utah lower-plate margin, and Mina transfer. The rift is orthogonal to most older basement domains, but the location of the transform-transfer zones suggests control of them by basement domain boundaries. The zigzag geometry of reentrants and promontories along the rift is paralleled by salients and recesses in younger thrust belts and by segmentation of younger extensional domains. Likewise, transform transfer zones localized subsequent transcurrent structures and igneous activity. Sediment-hosted mineral deposits trace the same zigzag geometry along the margin. Sedimentary exhalative (sedex) Zn-Pb-Ag ??Au and barite mineral deposits formed in continental-slope rocks during the Late Devonian-Mississippian and to a lesser degree, during the Cambrian-Early Ordovician. Such deposits formed during episodes of renewed extension along miogeoclinal segments. Carbonate-hosted Mississippi Valley- type (MVT) Zn-Pb deposits formed in structurally reactivated continental shelf rocks during the Late Devonian-Mississippian and Mesozoic due to reactivation of preexisting structures. The distribution and abundance of sedex and MVT deposits are controlled by the

Structure of the Cascadia Subduction Zone Imaged Using Surface Wave Tomography

NASA Astrophysics Data System (ADS)

Schaeffer, A. J.; Audet, P.

2017-12-01

Studies of the complete structure of the Cascadia subduction zone from the ridge to the arc have historically been limited by the lack of offshore ocean bottom seismograph (OBS) infrastructure. On land, numerous dense seismic deployments have illuminated detailed structures and dynamics associated with the interaction between the subducting oceanic plate and the overriding continental plate, including cycling of fluids, serpentinization of the overlying forearc mantle wedge, and the location of the upper surface of the Juan de Fuca plate as it subducts beneath the Pacific Northwest. In the last half-decade, the Cascadia Initiative (CI), along with Neptune (ONC) and several other OBS initiatives, have instrumented both the continental shelf and abyssal plains off shore of the Cascadia subduction zone, facilitating the construction of a complete picture of the subduction zone from ridge to trench and volcanic arc. In this study, we present a preliminary azimuthally anisotropic surface-wave phase-velocity based model of the complete system, capturing both the young, unaltered Juan de Fuca plate from the ridge, to its alteration as it enters the subduction zone, in addition to the overlying continent. This model is constructed from a combination of ambient noise cross-correlations and teleseismic two station interferometry, and combines together concurrently running offshore OBS and onshore stations. We furthermore perform a number of representative 1D depth inversions for shear velocity to categorize the pristine oceanic, subducted oceanic, and continental crust and lithospheric structure. In the future the dispersion dataset will be jointly inverted with receiver functions to constrain a 3D shear-velocity model of the complete region.

Structural Evolution of Transform Fault Zones in Thick Oceanic Crust of Iceland

NASA Astrophysics Data System (ADS)

Karson, J. A.; Brandsdottir, B.; Horst, A. J.; Farrell, J.

2017-12-01

Spreading centers in Iceland are offset from the regional trend of the Mid-Atlantic Ridge by the Tjörnes Fracture Zone (TFZ) in the north and the South Iceland Seismic Zone (SISZ) in the south. Rift propagation away from the center of the Iceland hotspot, has resulted in migration of these transform faults to the N and S, respectively. As they migrate, new transform faults develop in older crust between offset spreading centers. Active transform faults, and abandoned transform structures left in their wakes, show features that reflect different amounts (and durations) of slip that can be viewed as a series of snapshots of different stages of transform fault evolution in thick, oceanic crust. This crust has a highly anisotropic, spreading fabric with pervasive zones of weakness created by spreading-related normal faults, fissures and dike margins oriented parallel to the spreading centers where they formed. These structures have a strong influence on the mechanical properties of the crust. By integrating available data, we suggest a series of stages of transform development: 1) Formation of an oblique rift (or leaky transform) with magmatic centers, linked by bookshelf fault zones (antithetic strike-slip faults at a high angle to the spreading direction) (Grimsey Fault Zone, youngest part of the TFZ); 2) broad zone of conjugate faulting (tens of km) (Hreppar Block N of the SISZ); 3) narrower ( 20 km) zone of bookshelf faulting aligned with the spreading direction (SISZ); 4) mature, narrow ( 1 km) through-going transform fault zone bounded by deformation (bookshelf faulting and block rotations) distributed over 10 km to either side (Húsavík-Flatey Fault Zone in the TFZ). With progressive slip, the transform zone becomes progressively narrower and more closely aligned with the spreading direction. The transform and non-transform (beyond spreading centers) domains may be truncated by renewed propagation and separated by subsequent spreading. This perspective

30 CFR 250.226 - What Coastal Zone Management Act (CZMA) information must accompany the EP?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 2 2011-07-01 2011-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the EP? 250.226 Section 250.226 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT... Zone Management Act (CZMA) information must accompany the EP? The following CZMA information must...

On the Structure of the Mixing Zone at an Unstable Contact Boundary

NASA Astrophysics Data System (ADS)

Meshkov, E. E.

2018-01-01

The interface between two media of different densities (contact boundary) moving with an acceleration directed from the less dense medium to the more dense one is unstable (Rayleigh-Taylor instability) [1, 2]. The initial perturbations of the interface grow indefinitely and, as a result, a medium mixing zone growing with time is formed at the interface. The structure of such a mixing zone at gas-gas and gas-liquid interfaces is discussed on the basis of laboratory experiments on shock tubes of various types. It is concluded that the regions of turbulent and laminar flows are combined in the mixing zone.

Genetic Aspects of Gold Mineralization at Some Occurrences in the Eastern Desert of Egypt

NASA Astrophysics Data System (ADS)

Abd El Monsef, M.; Slobodník, M.; Salem, I. A.

2012-04-01

The Eastern Desert of Egypt is well known as a gold-mining area since ancient times, there're more than 95 gold deposits and occurrences spread the whole area covered by the basement rocks of Precambrian age. The basement rocks of the Eastern Desert of Egypt constitute the Nubian Shield that has formed a continuous part of the Arabian-Nubian Shield before the opening of Red Sea (Oligocene-Early Miocene). Commonly, the system of gold-bearing quartz veins in the Eastern Desert is clearly structural controlled related to brittle-ductile shear zones that mostly developed during late deformational stages of the evolution history for basement rocks in the Eastern Desert. This running study principally aims to contribute the mineral resource potential of the gold deposits in Egypt, so particularly Fatira, Gidami and Atalla occurrences have been involved into a comprehensive study based on field, structural, mineralogical, geochemical and genetic investigations. It is intended to better understanding for the characteristics, distribution controls, conditions and age of mineralization in relation to the age of the hosting rocks intrusion to find if there're genetic links between the gold mineralization and the evolution of the host intrusive complex. Several authors suggested that the gold mineralization was related to the intrusion of the (postorogenic) Younger granites. Other authors interpret these deposits as products of hydrothermal activity induced either by metamorphism or cooling effects of early Paleozoic magmatism or as combined metamorphic/magmatic episodes. The prime focus will be directed to the ore itself and the associated hydrothermal alteration zones based on detailed maps and well-distributed samples network and geochemical anomalies distribution. The laboratory studies included microscopic examination (reflecting and transmitting microscopy) to allow for determination of the hosting rocks types and mineralogical changes related to the gold mineralization

Potassium-argon (argon-argon), structural fabrics

USGS Publications Warehouse

Cosca, Michael A.; Rink, W. Jack; Thompson, Jereon

2014-01-01

Definition: 40Ar/39Ar geochronology of structural fabrics: The application of 40Ar/39Ar methods to date development of structural fabrics in geologic samples. Introduction: Structural fabrics develop during rock deformation at variable pressures (P), temperatures (T), fluid compositions (X), and time (t). Structural fabrics are represented in rocks by features such as foliations and shear zones developed at the mm to km scale. In ideal cases, the P-T-X history of a given structural fabric can be constrained using stable isotope, cation exchange, and/or mineral equilibria thermobarometry (Essene 1989). The timing of structural fabric development can be assessed qualitatively using geologic field observations or quantitatively using isotope-based geochronology. High-precision geochronology of the thermal and fluid flow histories associated with structural fabric development can answer fundamental geologic questions including (1) when hydrothermal fluids transported and deposited ore minerals, ...

Structural geology mapping using PALSAR data in the Bau gold mining district, Sarawak, Malaysia

NASA Astrophysics Data System (ADS)

Pour, Amin Beiranvand; Hashim, Mazlan

2014-08-01

The application of optical remote sensing data for geological mapping is difficult in the tropical environment. The persistent cloud coverage, dominated vegetation in the landscape and limited bedrock exposures are constraints imposed by the tropical climate. Structural geology investigations that are searching for epithermal or polymetallic vein-type ore deposits can be developed using Synthetic Aperture Radar (SAR) remote sensing data in tropical/sub-tropical regions. The Bau gold mining district in the State of Sarawak, East Malaysia, on the island of Borneo has been selected for this study. The Bau is a gold field similar to Carlin style gold deposits, but gold mineralization at Bau is much more structurally controlled. Geological analyses coupled with the Phased Array type L-band Synthetic Aperture Radar (PALSAR) remote sensing data were used to detect structural elements associated with gold mineralization. The PALSAR data were used to perform lithological-structural mapping of mineralized zones in the study area and surrounding terrain. Structural elements were detected along the SSW to NNE trend of the Tuban fault zone and Tai Parit fault that corresponds to the areas of occurrence of the gold mineralization in the Bau Limestone. Most of quartz-gold bearing veins occur in high-angle faults, fractures and joints within massive units of the Bau Limestone. The results show that four deformation events (D1-D4) in the structures of the Bau district and structurally controlled gold mineralization indicators, including faults, joints and fractures are detectable using PALSAR data at both regional and district scales. The approach used in this study can be more broadly applicable to provide preliminary information for exploration potentially interesting areas of epithermal or polymetallic vein-type mineralization using the PALSAR data in the tropical/sub-tropical regions.

30 CFR 550.226 - What Coastal Zone Management Act (CZMA) information must accompany the EP?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 2 2012-07-01 2012-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the EP? 550.226 Section 550.226 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT... and Information Contents of Exploration Plans (ep) § 550.226 What Coastal Zone Management Act (CZMA...

30 CFR 550.226 - What Coastal Zone Management Act (CZMA) information must accompany the EP?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 2 2014-07-01 2014-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the EP? 550.226 Section 550.226 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT... and Information Contents of Exploration Plans (ep) § 550.226 What Coastal Zone Management Act (CZMA...

30 CFR 550.226 - What Coastal Zone Management Act (CZMA) information must accompany the EP?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 2 2013-07-01 2013-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the EP? 550.226 Section 550.226 Mineral Resources BUREAU OF OCEAN ENERGY MANAGEMENT... and Information Contents of Exploration Plans (ep) § 550.226 What Coastal Zone Management Act (CZMA...

Platinum mineralization in the Kapalagulu Intrusion, western Tanzania

NASA Astrophysics Data System (ADS)

Wilhelmij, Harry R.; Cabri, Louis J.

2016-03-01

Low-grade copper and nickel mineralization was found near the eastern shore of Lake Tanganyika at Kungwe Bay in the early part of the twentieth century. The mineralization occurs in harzburgite at the base of a layered gabbro complex known as the Kapalagulu Intrusion, emplaced between the Paleoproterozoic Ubendian basement and overlying Neoproterozoic Itiaso Group metasediments. Several mining and exploration companies continued the geophysical and drilling exploration for base metals throughout the last century culminating in the discovery of high-grade platinum-group element (PGE) mineralization associated with chromitite and sulfide-bearing harzburgite within the southeastern extension of the Kapalagulu Intrusion (known as the Lubalisi Zone) that is covered by a layer of nickel-rich laterite regolith. The poorly layered southeastern harzburgite forms part of the >1500 m-thick Lower Ultramafic Sequence and resembles a dike-like body that flares upwards into a succession of well-layered gabbroic rocks of the Upper Mafic Sequence. No PGE mineralization has been found in the layered gabbro; all the mineralization is associated with the chromite- and sulfide-rich harzburgite of the Lower Ultramafic Sequence and the laterite regolith overlying the mineralized harzburgite. The Lubalisi Zone harzburgite is underlain by basal dunite and overlain by an interval of layered harzburgite and troctolite and this ultramafic sequence is folded into a syncline that plunges towards the northwest that has been modified by major dolerite-filled faults orientated subparallel to the fold axial surface. Extensive deep drilling in the Lubalisi Zone of the Kapalagulu Intrusion shows that the folded harzburgite can be subdivided into a lower feldspathic harzburgite, a harzburgite containing chromitite seams and intervals of sulfide and chromite mineralization known as the Main Chromite Sulfide Succession (MCSS), an overlying sulfide-rich harzburgite, and an upper feldspathic harzburgite

Gravity field and structure of the Sorong Fault Zone, eastern Indonesia

NASA Astrophysics Data System (ADS)

Sardjono

Gravity surveys along coastlines of islands in the region Banggai-Sula, Eastern Sulawesi, Halmahera, Bacan and Obi were carried out as part of the Sorong Fault Zone Project. Results of the Surveys were integrated with gravity data previously acquired by other projects, including on-land gravity data from the Bird Head area Irian Jaya (Dow et al 1986), Seram Island (Milsom 1977), Buru Island (Oemar and Reminton 1993) and Central Sulawesi (Silver et al. 1983) as well as marine gravity information within and surrounding the Sorong Fault Zone (Bowin et al. 1980). Gravity expeditions of the Sorong Fault Zone Project also include measurements in Mayu Island and the island group of Talaud, situated further north in the Central Molucca Sea region. A total of one hundred and forty two gravity data were acquired in the region of Banggai-Sula islands, forty seven in eastern part of Central Sulawesi, about four hundred in Halmahera, Bacan and Obi, and seventy nine in Mayu and Talaud. Surveys in the eastern part of Central Sulawesi were carried out for the purpose of tieing the older gravity data obtained from Silver et al. (1983) and the more recent data of the Sorong Fault Zone Project. About one thousand thirty hundred and thirty gravity data were acquired as part of the Irian Jaya Geological Mapping Project (IJGMP) in the period of 1978-1983, a project commissioned by the Indonesian Geological Research and Development Centre (GRDC) and the Australian Bureau of Mineral Resources (BMR). The remoteness of the survey areas of the Sorong Fault Zone Project necessitated a careful planning for travel arrangements and provision of logistics. A wide range of magnitude of gravity field was observed in the Sorong Fault Zone, extending from values below -250 mGal recorded in the southern part of the Molucca Sea to values in excess of +320 mGal measured near to sea level in the coastal areas south of Mangole and north of Sulabesi, the two islands of the Sula Group. Steep gradients of

30 CFR 285.647 - How will my GAP be processed for Federal consistency under the Coastal Zone Management Act?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false How will my GAP be processed for Federal consistency under the Coastal Zone Management Act? 285.647 Section 285.647 Mineral Resources MINERALS... Activities Plan § 285.647 How will my GAP be processed for Federal consistency under the Coastal Zone...

30 CFR 285.612 - How will my SAP be processed for Federal consistency under the Coastal Zone Management Act?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false How will my SAP be processed for Federal consistency under the Coastal Zone Management Act? 285.612 Section 285.612 Mineral Resources MINERALS... Plan § 285.612 How will my SAP be processed for Federal consistency under the Coastal Zone Management...

Alteration Minerals Extraction Using Airborne Hyperspectral Data Casi and Sasi in Wuyi Metallogenic Belt, China

NASA Astrophysics Data System (ADS)

Huang, Z.; Zheng, J.

2018-04-01

Hydrothermal alteration is an important content in the study of epithermal deposit, and its deep part is often accompanied by porphyry mineralization. The objective of research is to mapping the alteration minerals for mineral exploration using mixture tuned matched filtering (MTMF) approach based on airborne hyperspectral data CASI and SASI in Wuyi metallogenic belt, China, which has complex geological structure and excellent mineralization conditions and high regional forest coverage rate. Gold mineralization is closely related to the Yanshan period epithermal intrusive rocks, and often exists in external contact zone of allgovite, monzomite porphyrite, granite porphyry, quarz porphyry, et al.. The main mineral alteration types include silicification (quartz), sericitization (sericite, illite), pyritization (pyrite), chloritization (chlorite), and partial calcitization (calcite). The alteration minerals extraction based on integrated CASI_SASI reflectance data were processed by MTMF algorithm with the input imagery which was pre-processed by MNF and the input endmember spectra measured by SVC spectrometer to performs MF and add an infeasibility image. The MTMF results provide an estimate to mineral subpixel fractions leading to the abundances of alteration minerals at each pixel and alteration minerals distribution. The accuracy of alteration mineral extraction refers to the extent which it agrees with a set of reference data measured in the field reconnaissance. So the CASI_SASI airborne hyperspectral image provides the efficient way to map the detailed alteration minerals distribution for mineral exploration in high forest coverage area.

Prediction of protein secondary structure content for the twilight zone sequences.

PubMed

Homaeian, Leila; Kurgan, Lukasz A; Ruan, Jishou; Cios, Krzysztof J; Chen, Ke

2007-11-15

Secondary protein structure carries information about local structural arrangements, which include three major conformations: alpha-helices, beta-strands, and coils. Significant majority of successful methods for prediction of the secondary structure is based on multiple sequence alignment. However, multiple alignment fails to provide accurate results when a sequence comes from the twilight zone, that is, it is characterized by low (<30%) homology. To this end, we propose a novel method for prediction of secondary structure content through comprehensive sequence representation, called PSSC-core. The method uses a multiple linear regression model and introduces a comprehensive feature-based sequence representation to predict amount of helices and strands for sequences from the twilight zone. The PSSC-core method was tested and compared with two other state-of-the-art prediction methods on a set of 2187 twilight zone sequences. The results indicate that our method provides better predictions for both helix and strand content. The PSSC-core is shown to provide statistically significantly better results when compared with the competing methods, reducing the prediction error by 5-7% for helix and 7-9% for strand content predictions. The proposed feature-based sequence representation uses a comprehensive set of physicochemical properties that are custom-designed for each of the helix and strand content predictions. It includes composition and composition moment vectors, frequency of tetra-peptides associated with helical and strand conformations, various property-based groups like exchange groups, chemical groups of the side chains and hydrophobic group, auto-correlations based on hydrophobicity, side-chain masses, hydropathy, and conformational patterns for beta-sheets. The PSSC-core method provides an alternative for predicting the secondary structure content that can be used to validate and constrain results of other structure prediction methods. At the same time, it

Structural Analysis of Active North Bozgush Fault Zone (NW Iran)

NASA Astrophysics Data System (ADS)

Saber, R.; Isik, V.; Caglayan, A.

2013-12-01

NW Iran is one of the seismically active regions between Zagros Thrust Belt at the south and Caucasus at the north. Not only large magnitude historical earthquakes (Ms>7), but also 1987 Bozgush, 1997 Ardebil (Mw 6.1) and 2012 Ahar-Varzagan (Mw 6.4) earthquakes reveal that the region is seismically active. The North Bozgush Fault Zone (NBFZ) in this region has tens of kilometers in length and hundreds of meters in width. The zone has produced some large and destructive earthquakes (1593 M:6.1 and 1883 M:6.2). The NBFZ affects the Cenozoic units and along this zone Eocene units thrusted over Miocene and/or Plio-Quaternary sedimentary units. Together with morphologic features (stream offsets and alluvial fan movements) affecting the young unites reveal that the zone is active. The zone is mainly characterized by strike-slip faults with reverse component and reverse faults. Reverse faults striking N55°-85°E and dip of 40°-50° to the SW while strike-slip faults show right lateral slip with N60°-85°W and N60°-80°E directions. Our structural data analysis in NBFZ indicates that the axis direction of σ2 principal stress is vertical and the stress ratio (R) is 0.12. These results suggest that the tectonic regime along the North Bozgush Fault Zone is transpressive. Obtained other principal stresses (σ1, σ3) results are compatible with stress directions and GPS velocity suggested for NW Iran.

Post-magmatic structural evolution of the Troodos Ophiolite Pillow Lavas revealed by microthermometry within vein precipitates, with application to Alpine-Mediterranean supra-subduction zone settings

NASA Astrophysics Data System (ADS)

Klöcking, M.; White, N. J.; Maclennan, J.; Fitton, J. G.

2016-12-01

The Troodos ophiolite, Cyprus, is one of the best preserved ophiolites. Based on geochemical data a supra-subduction zone (SSZ) setting was proposed. Microtextures and fluid inclusions of veins and vesicles within the Pillow Lavas record the post-magmatic structural and geochemical evolution of this SSZ beginning at 75 Ma. Three different vein types from the Upper and Lower Pillow Lavas are distinguished and imply vein precipitation under a dominant extensional regime: (1) syntaxial calcite-, quartz- and zeolite-bearing veins are interpreted as mineralized extension fractures that were pervaded by seawater. This advective fluid flow in an open system changed later into a closed system characterized by geochemical self-organization. (2) Blocky and (3) antitaxial fibrous calcite veins are associated with brecciation due to hydrofracturing and diffusion-crystallization processes, respectively. Based on aqueous fluid inclusion chemistry with seawater salinities in all studied vein types, representative fluid inclusion isochores crossed with calculated litho- and hydrostatic pressure conditions yield mineral precipitation temperatures between 180 and 210 °C, for veins and vesicles hosted in the Upper and Lower Pillow Lavas. This points to a heat source for the circulating seawater and implies that vein and vesicle minerals precipitated shortly after pillow lava crystallization under dominant isobaric cooling conditions. Compared to previous suggestions derived from secondary mineralization a less steep geothermal gradient of 200 °C from the Sheeted Dyke Complex to the Pillow Lavas of the Troodos SSZ is proposed. Further fossil and recent SSZ like the Mirdita ophiolite, Albania, the South-Anatolian ophiolites, Turkey, and the Izu-Bonin fore arc, respectively, reveal similar volcanic sequences. Vein samples recovered during International Ocean Discovery Program expedition 351 and 352 in the Izu-Bonin back and fore arc, respectively, indicate also seawater infiltration

Post-magmatic structural evolution of the Troodos Ophiolite Pillow Lavas revealed by microthermometry within vein precipitates, with application to Alpine-Mediterranean supra-subduction zone settings

NASA Astrophysics Data System (ADS)

Kurz, W.; Quandt, D.; Micheuz, P.; Krenn, K.

2017-12-01

The Troodos ophiolite, Cyprus, is one of the best preserved ophiolites. Based on geochemical data a supra-subduction zone (SSZ) setting was proposed. Microtextures and fluid inclusions of veins and vesicles within the Pillow Lavas record the post-magmatic structural and geochemical evolution of this SSZ beginning at 75 Ma. Three different vein types from the Upper and Lower Pillow Lavas are distinguished and imply vein precipitation under a dominant extensional regime: (1) syntaxial calcite-, quartz- and zeolite-bearing veins are interpreted as mineralized extension fractures that were pervaded by seawater. This advective fluid flow in an open system changed later into a closed system characterized by geochemical self-organization. (2) Blocky and (3) antitaxial fibrous calcite veins are associated with brecciation due to hydrofracturing and diffusion-crystallization processes, respectively. Based on aqueous fluid inclusion chemistry with seawater salinities in all studied vein types, representative fluid inclusion isochores crossed with calculated litho- and hydrostatic pressure conditions yield mineral precipitation temperatures between 180 and 210 °C, for veins and vesicles hosted in the Upper and Lower Pillow Lavas. This points to a heat source for the circulating seawater and implies that vein and vesicle minerals precipitated shortly after pillow lava crystallization under dominant isobaric cooling conditions. Compared to previous suggestions derived from secondary mineralization a less steep geothermal gradient of 200 °C from the Sheeted Dyke Complex to the Pillow Lavas of the Troodos SSZ is proposed. Further fossil and recent SSZ like the Mirdita ophiolite, Albania, the South-Anatolian ophiolites, Turkey, and the Izu-Bonin fore arc, respectively, reveal similar volcanic sequences. Vein samples recovered during International Ocean Discovery Program expedition 351 and 352 in the Izu-Bonin back and fore arc, respectively, indicate also seawater infiltration

Geometric Structure of 3D Spinal Curves: Plane Regions and Connecting Zones

PubMed Central

Berthonnaud, E.; Hilmi, R.; Dimnet, J.

2012-01-01

This paper presents a new study of the geometric structure of 3D spinal curves. The spine is considered as an heterogeneous beam, compound of vertebrae and intervertebral discs. The spine is modeled as a deformable wire along which vertebrae are beads rotating about the wire. 3D spinal curves are compound of plane regions connected together by zones of transition. The 3D spinal curve is uniquely flexed along the plane regions. The angular offsets between adjacent regions are concentrated at level of the middle zones of transition, so illustrating the heterogeneity of the spinal geometric structure. The plane regions along the 3D spinal curve must satisfy two criteria: (i) a criterion of minimum distance between the curve and the regional plane and (ii) a criterion controlling that the curve is continuously plane at the level of the region. The geometric structure of each 3D spinal curve is characterized by the sizes and orientations of regional planes, by the parameters representing flexed regions and by the sizes and functions of zones of transition. Spinal curves of asymptomatic subjects show three plane regions corresponding to spinal curvatures: lumbar, thoracic and cervical curvatures. In some scoliotic spines, four plane regions may be detected. PMID:25031873

Domino structures evolution in strike-slip shear zones; the importance of the cataclastic flow

NASA Astrophysics Data System (ADS)

Moreira, N.; Dias, R.

2018-05-01

The Porto-Tomar-Ferreira do Alentejo dextral Shear Zone is one of the most important structures of the Iberian Variscides. In its vicinity, close to Abrantes (Central Portugal), a localized heterogeneous strain pattern developed in a decimetric metamorphic siliceous multilayer. This complex pattern was induced by the D2 dextral shearing of the early S0//S1 foliation in brittle-ductile conditions, giving rise to three main shear zone families. One of these families, with antithetic kinematics, delimits blocks with rigid clockwise rotation surrounded by coeval cataclasites, generating a local domino structure. The proposed geometrical and kinematic analysis, coupled with statistical studies, highlights the relation between subsidiary shear zones and the main shear zone. Despite the heterogeneous strain pattern, a quantitative approach of finite strain was applied based on the restoration of the initial fracture pattern. This approach shows the importance of the cataclastic flow coupled with the translational displacement of the domino domain in solving space problems related to the rigid block rotation. Such processes are key in allowing the rigid block rotation inside shear zones whenever the simple shear component is a fundamental mechanism.

Oreshoot zoning in the Carlin-type Betze orebody, Goldstrike Mine, Eureka County, Nevada

USGS Publications Warehouse

Peters, Stephen G.; Ferdock, Gregory C.; Woitsekhowskaya, Maria B.; Leonardson, Robert; Rahn, Jerry

1998-01-01

of illite-clay-pyrite oreshoots during movement along the DDZ, and subsequent silicification and brecciation, associated with formation of the realgar- and orpiment-bearing, and stibnite-bearing oreshoots. Additional shear movement along the DDZ followed. Polymetallic oreshoots, which contain minerals rich in Hg, Cu, Zn, Ag, and native Au, were the last ores to form and overprint most earlier oreshoots. Ore textures, gouge, phyllonitic rock, alteration style, and previously documented isotopic and fluid-inclusion data, all indicate a weakly to moderately saline fluid that ascended and cooled during structural displacements. Changing conditions, due to water-wall rock reactions and P-T changes during deformation, are probably responsible for fluid variation that resulted in zoning of the different oreshoots during dynamic interaction of the Au-bearing fluid with the wall rock. This investigation indicates that isolated As-, Sb-, and Hg-rich ores are separate parts of a larger single gold system. This large gold system was contemporaneous with post-Jurassic brittle-ductile deformation, on the basis of deformed mineralized pods of the Jurassic Goldstrike pluton, and large-scale hydrothermal flow, and together they appear to be an integral part of the formation of some Carlin-type gold deposits in north-central Nevada.

Granitoid-associated gold mineralization in Egypt: a case study from the Atalla mine

NASA Astrophysics Data System (ADS)

Zoheir, Basem; Deshesh, Fatma; Broman, Curt; Pitcairn, Iain; El-Metwally, Ahmed; Mashaal, Shabaan

2018-06-01

Gold-bearing sulfide-quartz veins cutting mainly through the Atalla monzogranite intrusion in the Eastern Desert of Egypt are controlled by subparallel NE-trending brittle shear zones. These veins are associated with pervasive sericite-altered, silicified, and ferruginated rocks. The hosting shear zones are presumed as high-order structures of the Najd-style faults in the Central Eastern Desert ( 615-585 Ma). Ore minerals include an early pyrite-arsenopyrite (±pyrrhotite) mineralization, partly replaced by a late pyrite-galena-sphalerite-chalcopyrite (±gold/electrum ± tetrahedrite ± hessite) assemblage. Gold occurs as small inclusions in pyrite and arsenopyrite, or more commonly as intergrowths with galena and sphalerite/tetrahedrite in microfractures. Arsenopyrite geothermometry suggests formation of the early Fe-As-sulfide mineralization at 380-340 °C, while conditions of deposition of the late base metal-gold assemblage are assumed to be below 300 °C. Rare hessite, electrum, and Bi-galena are associated with sphalerite and gold in the late assemblage. The early and late sulfide minerals show consistently a narrow range of δ34S ‰ (3.4-6.5) that overlaps with sulfur isotopic values in ophiolitic rocks. The Au-quartz veins are characterized by abundant CO2 and H2O ± CO2 ± NaCl inclusions, where three-dimensional clusters of inclusions show variable aqueous/carbonic proportions and broad range of total (bimodal) homogenization temperatures. Heterogeneous entrapment of immiscible fluids is interpreted to be caused by unmixing of an originally homogenous, low salinity ( 2 eq. mass % NaCl) aqueous-carbonic fluid, during transition from lithostatic to hydrostatic conditions. Gold deposition occurred generally under mesothermal conditions, i.e., 1.3 kbar and 280 °C, and continued during system cooling to < 200 °C and pressure decrease to 0.1 kbar. Based on the vein textures, sulfur isotope values, composition of ore fluids, and conditions of ore formation

Molecular dynamics simulation of water at mineral surfaces: Structure, dynamics, energetics and hydrogen bonding

NASA Astrophysics Data System (ADS)

Kalinichev, A. G.; Wang, J.; Kirkpatrick, R.

2006-05-01

Fundamental molecular-level understanding of the properties of aqueous mineral interfaces is of great importance for many geochemical and environmental systems. Interaction between water and mineral surfaces substantially affects the properties of both phases, including the reactivity and functionality of the substrate surface, and the structure, dynamics, and energetics of the near surface aqueous phase. Experimental studies of interfacial water structure and dynamics using surface-sensitive techniques such as sum-frequency vibrational spectroscopy or X-ray and neutron reflectivity are not always possible for many practically important substrates, and their results often require interpretation concerning the atomistic mechanisms responsible for the observed behavior. Molecular computer simulations can provide new insight into the underlying molecular- level relationships between the inorganic substrate structure and composition and the structure, ordering, and dynamics of interfacial water. We have performed a series of molecular dynamics (MD) computer simulations of aqueous interfaces with several silicates (quartz, muscovite, and talc) and hydroxides (brucite, portlandite, gibbsite, Ca/Al and Mg/Al double hydroxides) to quantify the effects of the substrate mineral structure and composition on the structural, transport, and thermodynamic properties of water on these mineral surfaces. Due to the prevalent effects of the development of well-interconnected H-bonding networks across the mineral- water interfaces, all the hydroxide surfaces (including a fully hydroxylated quartz surface) show very similar H2O density profiles perpendicular to the interface. However, the predominant orientations of the interfacial H2O molecules and their detailed 2-dimensional near-surface structure and dynamics parallel to the interface are quite different reflecting the differences in the substrate structural charge distribution and the density and orientations of the surface OH

Accessory mineral records of tectonic environments? (Invited)

NASA Astrophysics Data System (ADS)

Storey, C.; Marschall, H. R.; Enea, F.; Taylor, J.; Jennings, E. S.

2010-12-01

Accessory mineral research continues to gather momentum as we seek to unleash their full potential. It is now widely recognised that robust accessory minerals, such as zircon, rutile, titanite, allanite and monazite, are archives of important trace elements that can help deduce metamorphic reaction history in metapelites, metabasites and other rock types. Moreover, they are important carriers of certain trace elements and govern or influence the products of partial melting and of fluid-rock interaction (e.g. magmas and mineralisation) in settings like subduction zones and hydrothermal systems. Perhaps most importantly, they can often be dated using the U-Th-Pb system. More recently, radiogenic (Lu-Hf, Sm-Nd, Rb-Sr) and stable (O) isotope systems have been applied and have further pushed the utility of accessory mineral research. In this talk I will discuss some of these advances towards one particular aim: the use of detrital accessory minerals for fingerprinting tectonic environments. This is a particularly laudable aim in Precambrian rocks, for which the preservation potential of orogenic belts and fossil subduction zones and their diagnostic metamorphic rocks is low. The implication is that our understanding of plate tectonics, particularly in the Archaean, is biased by the preserved in-tact rock record. An analogy is that Jack Hills zircons record evidence of Earth’s crust some 400 Ma before the preserved rock record begins. I will focus on some recent advances and new data from rutile and also the mineral inclusion record within zircon, which shows great promise for petrologic interpretation.

X-ray Raman scattering for structural investigation of silica/silicate minerals

NASA Astrophysics Data System (ADS)

Fukui, H.; Kanzaki, M.; Hiraoka, N.; Cai, Y. Q.

2009-03-01

We have performed X-ray Raman scattering (XRS) measurements on the oxygen K and silicon L absorption edges of four silica minerals: α-quartz, α-cristobalite, coesite, and stishovite. We have also calculated the partial electron densities of states (DOSs) and compared these with the XRS spectra. This study demonstrates that the short-range structure around the atom of interest strongly influences the XRS spectral features. Importantly, the oxygen K-edge XRS spectra are found to reflect the p-orbital DOS while the silicon L-edge spectra reflect the s- and d-orbital DOSs, even when a product of a momentum transfer and a mean radius of a electron orbit (1 s for oxygen and 2 p for silicon), Qr, is close to or larger than unity. Building on this, calculations of the partial DOSs for other silica phases are presented, including ultra-high-pressure phases, which provide a good reference for further XRS study of silica and silicate minerals. XRS measurements should be performed on not only either of oxygen or silicon but also on many kinds of constituent elements to reveal the structural change of glasses/melts of silicates under extreme conditions.

30 CFR 250.272 - If a State objects to the DPP's or DOCD's coastal zone consistency certification, what can I do?

Code of Federal Regulations, 2010 CFR

2010-07-01

... coastal zone consistency certification, what can I do? 250.272 Section 250.272 Mineral Resources MINERALS... objects to the DPP's or DOCD's coastal zone consistency certification, what can I do? If an affected State objects to the coastal zone consistency certification accompanying your proposed or disapproved DPP or...

Citrate bridges between mineral platelets in bone

PubMed Central

Davies, Erika; Müller, Karin H.; Wong, Wai Ching; Pickard, Chris J.; Reid, David G.; Skepper, Jeremy N.; Duer, Melinda J.

2014-01-01

We provide evidence that citrate anions bridge between mineral platelets in bone and hypothesize that their presence acts to maintain separate platelets with disordered regions between them rather than gradual transformations into larger, more ordered blocks of mineral. To assess this hypothesis, we take as a model for a citrate bridging between layers of calcium phosphate mineral a double salt octacalcium phosphate citrate (OCP-citrate). We use a combination of multinuclear solid-state NMR spectroscopy, powder X-ray diffraction, and first principles electronic structure calculations to propose a quantitative structure for this material, in which citrate anions reside in a hydrated layer, bridging between apatitic layers. To assess the relevance of such a structure in native bone mineral, we present for the first time, to our knowledge, 17O NMR data on bone and compare them with 17O NMR data for OCP-citrate and other calcium phosphate minerals relevant to bone. The proposed structural model that we deduce from this work for bone mineral is a layered structure with thin apatitic platelets sandwiched between OCP-citrate–like hydrated layers. Such a structure can explain a number of known structural features of bone mineral: the thin, plate-like morphology of mature bone mineral crystals, the presence of significant quantities of strongly bound water molecules, and the relatively high concentration of hydrogen phosphate as well as the maintenance of a disordered region between mineral platelets. PMID:24706850

Undiscovered porphyry copper resources in the Urals—A probabilistic mineral resource assessment

USGS Publications Warehouse

Hammarstrom, Jane M.; Mihalasky, Mark J.; Ludington, Stephen; Phillips, Jeffrey; Berger, Byron R.; Denning, Paul; Dicken, Connie; Mars, John; Zientek, Michael L.; Herrington, Richard J.; Seltmann, Reimar

2017-01-01

A probabilistic mineral resource assessment of metal resources in undiscovered porphyry copper deposits of the Ural Mountains in Russia and Kazakhstan was done using a quantitative form of mineral resource assessment. Permissive tracts were delineated on the basis of mapped and inferred subsurface distributions of igneous rocks assigned to tectonic zones that include magmatic arcs where the occurrence of porphyry copper deposits within 1 km of the Earth's surface are possible. These permissive tracts outline four north-south trending volcano-plutonic belts in major structural zones of the Urals. From west to east, these include permissive lithologies for porphyry copper deposits associated with Paleozoic subduction-related island-arc complexes preserved in the Tagil and Magnitogorsk arcs, Paleozoic island-arc fragments and associated tonalite-granodiorite intrusions in the East Uralian zone, and Carboniferous continental-margin arcs developed on the Kazakh craton in the Transuralian zone. The tracts range from about 50,000 to 130,000 km2 in area. The Urals host 8 known porphyry copper deposits with total identified resources of about 6.4 million metric tons of copper, at least 20 additional porphyry copper prospect areas, and numerous copper-bearing skarns and copper occurrences.Probabilistic estimates predict a mean of 22 undiscovered porphyry copper deposits within the four permissive tracts delineated in the Urals. Combining estimates with established grade and tonnage models predicts a mean of 82 million metric tons of undiscovered copper. Application of an economic filter suggests that about half of that amount could be economically recoverable based on assumed depth distributions, availability of infrastructure, recovery rates, current metals prices, and investment environment.

Diagnostic heavy minerals in Plio-Pleistocene sediments of the Yangtze Coast, China with special reference to the Yangtze River connection into the sea

NASA Astrophysics Data System (ADS)

Chen, Jing; Wang, Zhanghua; Chen, Zhongyuan; Wei, Zixin; Wei, Taoyuan; Wei, Wei

2009-12-01

This present study revealed five heavy mineral zones in the Yangtze coastal borehole sediments. Ilmenite, garnet and zircon suite of Zone I of the Pliocene characterizes the derivation of basaltic bedrock and local andesitic-granitic rocks. Indicative limonite in the Zone I sediments formed as alluvial fan facies shows strong chemical weathering. The assemblage of amphibole, straurolite, kyanite and idocrase of metamorphic derivation, together with a few zircon and tourmaline of andesitic-granitic origin in Zone II, represents the extension of sediment sources to the lower and middle Yangtze basin in Early Pleistocene as the study area subsided. Also, the braided to meandering riverine facies demonstrates a longer distance sediment transport. Few heavy minerals remained in Zone III of Mid-Pleistocene, when mottled thicker stiff mud occurred as the lacustrine facies, suggesting a quasi-coastal floodplain with lower capability of sediment transport. Heavy minerals appeared significant and continuous in Zone IV of Late Pleistocene, when changing to the shallow marine facies, inferring much extended sediment sources to the upper Yangtze. Hypersthene, identified primarily in Zone IV, was closely associated with the Er-Mei Mountain tholeiite basalt of the upper Yangtze. Heavy minerals of Zone V remained almost the same as IV during Holocene, when the modern delta evolved. The heavy minerals suggested the timing of the Yangtze connection to the sea at ca 0.12 Ma BP.

Exploration for gold mineralization in the Arabo Nubian Shield: Using remote sensing Approach

NASA Astrophysics Data System (ADS)

Ramadan, Talaat

2013-04-01

In the southern part of the Eastern Desert of Egypt, Landsat Thematic Mapper (ETM+) data and fieldwork was combined with mineralogical and geochemical investigations in order to detect and characterize alteration zones within Pan-African rocks. The processing of Landsat ETM+ data using ratioing (bands 5/7,5/1,4/3 in Red, Green, Blue) showed two different types of alteration zones (type l and 2). Type 1 is close to the ophiolitic ultramafic rocks and type 2 is located within island-arc related metavolcanic rocks at the study areas. Both of these alteration zones are concordant with the main NW-SE structural trend. Mineralogical studies indicate that the alteration zones of type 1 consist mainly of calcite, ankerite, magnesite, dolomite and quartz. Chromian spinel, pyrite, and Ni-bearing sulphides (gersdorffite, pentlandite and polydymite) are the main ore minerals within this zone. Alteration zones of type 2 are strongly potassium-enriched and pyrophyllite, kaolinite, illite, gypsum and quartz occur. The brecciated quartz-veins associated with theses alteration zones consist of quartz, Fe-hydroxides, hematite and native gold. The gold content reaches up to 5 g/t in the alteration zone, while it extends up to 50 g/t in the quartz veins. This study presents a mineralogical characterization of such zones and demonstrates the utility of orbital remote sensing for finding unknown alteration zones in the Eastern Desert and other arid areas with similar host rock lithologies.

Crustal-scale shear zones and heterogeneous structure beneath the North Anatolian Fault Zone, Turkey, revealed by a high-density seismometer array

NASA Astrophysics Data System (ADS)

Kahraman, Metin; Cornwell, David G.; Thompson, David A.; Rost, Sebastian; Houseman, Gregory A.; Türkelli, Niyazi; Teoman, Uğur; Altuncu Poyraz, Selda; Utkucu, Murat; Gülen, Levent

2015-11-01

Continental scale deformation is often localised along strike-slip faults constituting considerable seismic hazard in many locations. Nonetheless, the depth extent and precise geometry of such faults, key factors in how strain is accumulated in the earthquake cycle and the assessment of seismic hazard, are poorly constrained in the mid to lower crust. Using a dense broadband network of 71 seismic stations with a nominal station spacing of 7 km in the vicinity of the 1999 Izmit earthquake we map previously unknown small-scale structure in the crust and upper mantle along this part of the North Anatolian Fault Zone (NAFZ). We show that lithological and structural variations exist in the upper, mid and lower crust on length scales of less than 10 km and less than 20 km in the upper mantle. The surface expression of the NAFZ in this region comprises two major branches; both are shown to continue at depth with differences in dip, depth extent and (possibly) width. We interpret a <10 km wide northern branch that passes downward into a shear zone that traverses the entire crust and penetrates the upper mantle to a depth of at least 50 km. The dip of this structure appears to decrease west-east from ∼90° to ∼65° to the north over a distance of 30 to 40 km. Deformation along the southern branch may be accommodated over a wider (>10 km) zone in the crust with a similar variation of dip but there is no clear evidence that this shear zone penetrates the Moho. Layers of anomalously low velocity in the mid crust (20-25 km depth) and high velocity in the lower crust (extending from depths of 28-30 km to the Moho) are best developed in the Armutlu-Almacik block between the two shear zones. A mafic lower crust, possibly resulting from ophiolitic obduction or magmatic intrusion, can best explain the coherent lower crustal structure of this block. Our images show that strain has developed in the lower crust beneath both northern and southern strands of the North Anatolian Fault

Structural characteristics of the décollement zone and underthrust sediments in the Nankai accretionary prism: Geologic architectures in the Site C0023, IODP Expedition 370

NASA Astrophysics Data System (ADS)

Yamamoto, Y.; Okutsu, N.; Yamada, Y.; Bowden, S.; Tonai, S.; Yang, K.; Tsang, M. Y.; Hirose, T.; Kamiya, N.

2017-12-01

Expedition 370 penetrated the accretionary prism, plate boundary décollement zone, and underthrust sediment and touched the basement basalt on the Philippine Sea Plate. The drilling site (C0023) is located 4 km NE from the legacy sites, Sites 808 and 1174. Compared to the legacy sites, the décollement zone is characterized by weak and intermittent negative reflectors in the seismic profile. Onboard physical properties, e.g. porosity and P-wave velocity data, indeed show the smaller gaps at the top of the décollement zone. The nature of the deformation along the décollement zone represented 40 m thick phacoidal deformation zone composed of fragmented mudstone with slickenlines on the surfaces in the Sites 808 and 1174. Compare with this, décollement zone in Site C0023 represented the weaker and non-localized deformation zone comprised of alternating zone of 1 m thick phacoidal deformation zones and a few 10 m of intact intervals in the Site C0023. Many normal faults striking parallel to the trench were identified just below the décollement zone, which is indicative of non-localized deformations along the décollement zone. Many of these faults were accompanied with calcite and sulphate mineral veins (anhydrite and barite), indicative of high-temperature fluid migration just above the ridge-spreading center. Based on the paleomagnetic restoration of structure to the geologic coordinate, attitudes of the bedding and fault planes in the Site C0023 are controlled by two factors: 1) subduction/accretion producing the trench-parallel bedding strikes and trench-perpendicular principal stress and 2) ridge spreading that produces ridge-parallel bedding and vein strikes. The former developed in the accretionary prism and the upper part of the underthrust sediment (<900 mbsf), whereas the latter occurs in the lower part (>900 mbsf). These tectonic variations might affect fluid migration pathways.

Primitive andesites from the Taupo Volcanic Zone formed by magma mixing

NASA Astrophysics Data System (ADS)

Beier, Christoph; Haase, Karsten M.; Brandl, Philipp A.; Krumm, Stefan H.

2017-05-01

Andesites with Mg# >45 erupted at subduction zones form either by partial melting of metasomatized mantle or by mixing and assimilation processes during melt ascent. Primitive whole rock basaltic andesites from the Pukeonake vent in the Tongariro Volcanic Centre in New Zealand's Taupo Volcanic Zone contain olivine, clino- and orthopyroxene, and plagioclase xeno- and antecrysts in a partly glassy matrix. Glass pools interstitial between minerals and glass inclusions in clinopyroxene, orthopyroxene and plagioclase as well as matrix glasses are rhyolitic to dacitic indicating that the melts were more evolved than their andesitic bulk host rock analyses indicate. Olivine xenocrysts have high Fo contents up to 94%, δ18O(SMOW) of +5.1‰, and contain Cr-spinel inclusions, all of which imply an origin in equilibrium with primitive mantle-derived melts. Mineral zoning in olivine, clinopyroxene and plagioclase suggest that fractional crystallization occurred. Elevated O isotope ratios in clinopyroxene and glass indicate that the lavas assimilated sedimentary rocks during stagnation in the crust. Thus, the Pukeonake andesites formed by a combination of fractional crystallization, assimilation of crustal rocks, and mixing of dacite liquid with mantle-derived minerals in a complex crustal magma system. The disequilibrium textures and O isotope compositions of the minerals indicate mixing processes on timescales of less than a year prior to eruption. Similar processes may occur in other subduction zones and require careful study of the lavas to determine the origin of andesite magmas in arc volcanoes situated on continental crust.

The composition, structure, and stability of guinier-preston zones in lunar and terrestrial orthopyroxene

USGS Publications Warehouse

Nord, G.L.

1980-01-01

Lunar and terrestrial orthopyroxenes (Mg,Fe,Ca)2Si2O6 contain varying abundances of coherent, Ca-enriched Guinier-Preston (G.P.) zones. G.P. zones 5-6 unit cells thick have been found in one lunar sample whereas all other examples (lunar and terrestrial) are only one unit-cell-thick. Electron diffraction maxima from the larger lunar G.P. zones indicate that d100=18.52 A?? whereas, d100=18.2 A?? for the host. This increase in the a direction corresponds to an increase in calcium content in the G.P. zones over that of the host of ???25 mol% Ca2Si2O6. Diffraction patterns of the hk0 net from an area containing G.P. zones show extra spots (h=2 n+1) not observed in the host orthopyroxene (Pbca), that violate the a-glide of the host. The G.P. zones, therefore, have space group Pbc21 if it is assumed that the c-glide of pyroxene is retained and the space group of the G.P. zone is a subgroup of Pbca. The loss of the a-glide in the G.P. zones results in 4 distinct silica chains and 4 distinct cation sites M1A, M1B, M2A, M2B; by symmetry, equivalent M2A or M2B sites are clustered together in only one-half of the unit cell. As one-fourth of the divalent cations in the G.P. zones are calcium, ordering of Ca on M2A or M2B would produce a zone 9 A?? thick extended parallel to (100) with the composition of Ca(Mg,Fe)Si2O6, but constrained by the host to the structure of orthopyroxene. This zone and the Ca-poor half-unit-cell then constitute an 18 A?? thick G.P. zone. Heating experiments of varying duration indicate that the zones become unstable with respect to the host orthopyroxene at ???950??C for Wo0.6 and ???1,050??C for Wo2.5. The zones are interpreted in terms of the pyroxene subsolidus as a metastable phase having either a solvus relationship with orthopyroxene or originating as a distinct phase. The size, distribution, composition and structure of G.P. zones may be an important indicator of the low-temperature thermal history of orthopyroxene. ?? 1980 Springer-Verlag.

Study of the glow curve structure of the minerals separated from black pepper (Piper nigrum L.)

NASA Astrophysics Data System (ADS)

Guzmán, S.; Ruiz Gurrola, B.; Cruz-Zaragoza, E.; Tufiño, A.; Furetta, C.; Favalli, A.; Brown, F.

2011-04-01

The inorganic mineral fraction extracted from black pepper (Piper nigrum L.) has been analysed using a thermoluminescence (TL) method, investigating the glow curve structure, including an evaluation of the kinetic parameters. Different grain sizes, i.e. 10, 74, and 149 μm, were selected from commercial black pepper. The X-ray diffraction of the inorganic fraction shows that quartz is the main mineral present in it. The samples were exposed to 1-25 kGy doses by gamma rays of 60Co in order to analyse the thermally stimulated luminescence response as a function of the delivered dose. The glow curves show a complex structure for different grain sizes of the pepper mineral samples. The fading of the TL signal at room temperature was obtained after irradiation, and it was observed that the maximum peaks of the glow curves shift towards higher values of the temperature when the elapsed time from irradiation increases. It seems that the fading characteristic may be related to a continuous trap distribution responsible for the complex structure of the glow curve. Similar glow curves structure behaviour was found under ultraviolet irradiation of the samples. The activation energy and the frequency factor were determined from the glow curves of different grain sizes using a deconvolution programme because of the evident complexity of the structure.

Global Transition Zone Anisotropy and Consequences for Mantle Flow and Earth's Deep Water Cycle

NASA Astrophysics Data System (ADS)

Beghein, C.; Yuan, K.

2011-12-01

The transition zone has long been at the center of the debate between multi- and single-layered convection models that directly relate to heat transport and chemical mixing throughout the mantle. It has also been suggested that the transition zone is a reservoir that collects water transported by subduction of the lithosphere into the mantle. Since water lowers mantle minerals density and viscosity, thereby modifying their rheology and melting behavior, it likely affects global mantle dynamics and the history of plate tectonics. Constraining mantle flow is therefore important for our understanding of Earth's thermochemical evolution and deep water cycle. Because it can result from deformation by dislocation creep during convection, seismic anisotropy can help us model mantle flow. It is relatively well constrained in the uppermost mantle, but its presence in the transition zone is still debated. Its detection below 250 km depth has been challenging to date because of the poor vertical resolution of commonly used datasets. In this study, we used global Love wave overtone phase velocity maps, which are sensitive to structure down to much larger depths than fundamental modes alone, and have greater depth resolution than shear wave-splitting data. This enabled us to obtain a first 3-D model of azimuthal anisotropy for the upper 800km of the mantle. We inverted the 2Ψ terms of anisotropic phase velocity maps [Visser, et al., 2008] for the first five Love wave overtones between 35s and 174s period. The resulting model shows that the average anisotropy amplitude for vertically polarized shear waves displays two main stable peaks: one in the uppermost mantle and, most remarkably, one in the lower transition zone. F-tests showed that the presence of 2Ψ anisotropy in the transition zone is required to improve the third, fourth, and fifth overtones fit. Because of parameter trade-offs, however, we cannot exclude that the anisotropy is located in the upper transition zone as

'One physical system': Tansley's ecosystem as Earth's critical zone.

PubMed

Richter, Daniel deB; Billings, Sharon A

2015-05-01

Integrative concepts of the biosphere, ecosystem, biogeocenosis and, recently, Earth's critical zone embrace scientific disciplines that link matter, energy and organisms in a systems-level understanding of our remarkable planet. Here, we assert the congruence of Tansley's (1935) venerable ecosystem concept of 'one physical system' with Earth science's critical zone. Ecosystems and critical zones are congruent across spatial-temporal scales from vegetation-clad weathering profiles and hillslopes, small catchments, landscapes, river basins, continents, to Earth's whole terrestrial surface. What may be less obvious is congruence in the vertical dimension. We use ecosystem metabolism to argue that full accounting of photosynthetically fixed carbon includes respiratory CO₂ and carbonic acid that propagate to the base of the critical zone itself. Although a small fraction of respiration, the downward diffusion of CO₂ helps determine rates of soil formation and, ultimately, ecosystem evolution and resilience. Because life in the upper portions of terrestrial ecosystems significantly affects biogeochemistry throughout weathering profiles, the lower boundaries of most terrestrial ecosystems have been demarcated at depths too shallow to permit a complete understanding of ecosystem structure and function. Opportunities abound to explore connections between upper and lower components of critical-zone ecosystems, between soils and streams in watersheds, and between plant-derived CO₂ and deep microbial communities and mineral weathering. © 2015 The Authors. New Phytologist © 2015 New Phytologist Trust.

30 CFR 550.260 - What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD?

Code of Federal Regulations, 2013 CFR

2013-07-01

... Operations Coordination Documents (docd) § 550.260 What Coastal Zone Management Act (CZMA) information must... 30 Mineral Resources 2 2013-07-01 2013-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD? 550.260 Section 550.260 Mineral Resources BUREAU OF OCEAN ENERGY...

30 CFR 550.260 - What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD?

Code of Federal Regulations, 2014 CFR

2014-07-01

... Operations Coordination Documents (docd) § 550.260 What Coastal Zone Management Act (CZMA) information must... 30 Mineral Resources 2 2014-07-01 2014-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD? 550.260 Section 550.260 Mineral Resources BUREAU OF OCEAN ENERGY...

30 CFR 550.260 - What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD?

Code of Federal Regulations, 2012 CFR

2012-07-01

... Operations Coordination Documents (docd) § 550.260 What Coastal Zone Management Act (CZMA) information must... 30 Mineral Resources 2 2012-07-01 2012-07-01 false What Coastal Zone Management Act (CZMA) information must accompany the DPP or DOCD? 550.260 Section 550.260 Mineral Resources BUREAU OF OCEAN ENERGY...

Transverse zones controlling the structural evolution of the Zipaquira Anticline (Eastern Cordillera, Colombia): Regional implications

NASA Astrophysics Data System (ADS)

García, Helbert; Jiménez, Giovanny

2016-08-01

We report paleomagnetic, magnetic fabric and structural results from 21 sites collected in Cretaceous marine mudstones and Paleogene continental sandstones from the limbs, hinge and transverse zones of the Zipaquira Anticline (ZA). The ZA is an asymmetrical fold with one limb completely overturned by processes like gravity and salt tectonics, and marked by several axis curvatures. The ZA is controlled by at least two (2) transverse zones known as the Neusa and Zipaquira Transverse Zones (NTZ and ZTZ, respectively). Magnetic mineralogy methods were applied at different sites and the main carriers of the magnetic properties are paramagnetic components with some sites being controlled by hematite and magnetite. Magnetic fabric analysis shows rigid-body rotation for the back-limb in the ZA, while the forelimb is subjected to internal deformation. Structural and paleomagnetic data shows the influence of the NTZ and ZTZ in the evolution of the different structures like the ZA and the Zipaquira, Carupa, Rio Guandoque, Las Margaritas and Neusa faults, controlling several factors as vergence, extension, fold axis curvature and stratigraphic detatchment. Clockwise rotations unraveled a block segmentation following a discontinuos model caused by transverse zones and one site reported a counter clockwise rotation associated with a left-lateral strike slip component for transverse faults (e.g. the Neusa Fault). We propose that diverse transverse zones have been active since Paleogene times, playing an important role in the tectonic evolution of the Cundinamarca sub-basin and controlling the structural evolution of folds and faults with block segmentation and rotations.

Localization of mineralization, its age, and relationship to magmatism at the Mogot silver-base-metal deposit, North Stanovoi metallogenic zone in the southeastern framework of the North Asian Craton

NASA Astrophysics Data System (ADS)

Buchko, I. V.; Buchko, Ir. V.; Sorokin, A. A.; Ponomarchuk, V. A.; Travin, A. V.

2014-03-01

The results of studying the Mogot silver-base-metal deposit located in the Dzhugdzhur-Stanovoi Superterrane are discussed in this paper. The main ore-controlling structural elements of the studied district are near-latitudinal and NE-trending faults, which are accompanied by zones of hydrothermal metasomatic potassic, propylitic, and argillic alterations, breccias with quartz and quartz-carbonate cement replacing metamorphic rocks and granitoids of the Late Stanovoi Complex. The total sulfide content in ore is 2-3%. The high Ag, Pb, and Zn contents in ore allow us to consider the Mogot deposit as silver-base-metal, since except of orebody 4, there are no silver minerals proper. This indicates that silver is incorporated into crystalline lattice of sulfides. The results of 40Ar/39Ar geochronological investigations show that the hydrothermal ore deposition dated at 127-125 Ma was related to emplacement of intrusions pertaining to the Tynda-Bakaran Complex.

Sorption of Pseudomonas putida onto differently structured kaolinite minerals

NASA Astrophysics Data System (ADS)

Vasiliadou, I. A.; Papoulis, D.; Chrysikopoulos, C.; Panagiotaras, D.; Karakosta, E.; Fardis, M.; Papavassiliou, G.

2010-12-01

The presence of bio-colloids (e.g. bacteria and viruses) in the subsurface could be attributed to the release of particles from septic tanks, broken sewer lines or from artificial recharge with treated municipal wastewater. Bio-colloid transport in the subsurface is significantly affected by sorption onto the solid matrix. Bio-colloid attachment onto mobile or suspended in the aqueous phase soil particles (e.g. clay or other minerals) also may influence their fate and transport in the subsurface. The present study focuses on the investigation of Pseudomonas (Ps.) putida sorption onto well (KGa-1) and poorly (KGa-2) crystallized kaolinite minerals. Batch experiments were carried out to determine the sorption isotherms of Ps. putida onto both types of kaolinite particles. The sorption process of Ps. putida onto KGa-1 and KGa-2 is adequately described by a Langmuir isotherm. Attenuated Total Reflection Fourier Transform Infrared Spectroscopy as well as Nuclear Magnetic Resonance were employed to study the sorption mechanisms of Ps. putida. Experimental results indicated that KGa-2 presented higher affinity and sorption capacity than KGa-1. It was shown that electrostatic interactions and structural disorders can influence the sorption capacity of clay particles.

Infrared and Raman spectroscopic characterization of the carbonate bearing silicate mineral aerinite - Implications for the molecular structure

NASA Astrophysics Data System (ADS)

Frost, Ray L.; Scholz, Ricardo; López, Andrés

2015-10-01

The mineral aerinite is an interesting mineral because it contains both silicate and carbonate units which is unusual. It is also a highly colored mineral being bright blue/purple. We have studied aerinite using a combination of techniques which included scanning electron microscopy, energy dispersive X-ray analysis, Raman and infrared spectroscopy. Raman bands at 1049 and 1072 cm-1 are assigned to the carbonate symmetric stretching mode. This observation supports the concept of the non-equivalence of the carbonate units in the structure of aerinite. Multiple infrared bands at 1354, 1390 and 1450 cm-1 supports this concept. Raman bands at 933 and 974 cm-1 are assigned to silicon-oxygen stretching vibrations. Multiple hydroxyl stretching and bending vibrations show that water is in different molecular environments in the aerinite structure.

Processes in continental collision zones: Preface

NASA Astrophysics Data System (ADS)

Zheng, Yong-Fei; Zhang, Lifei; McClelland, William C.; Cuthbert, Simon

2012-04-01

Formation and exhumation of high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic rocks in continental subduction zones are the two fundamental geodynamic aspects of collisional orogensis. This volume is based on the Session 08c titled "Geochemical processes in continental collision zones" at Goldschmidt 2010 in Knoxville, USA. It focuses on micro- to macro-scale processes that are temporally and spatially linked to different depths of crustal subduction/exhumation and associated mineralogical changes. They are a key to understanding a wide spectrum of phenomena, involving HP/UHP metamorphism and syn-/post-collisional magmatism. Papers in this volume report progresses in petrological, geochronological and geochemical studies of UHP metamorphic rocks and their derivatives in China, with tectonic settings varying from arc-continent collision to continent-continent collision. Microbeam in-situ analyses of metamorphic and magmatic minerals are successfully utilized to solve various problems in the study of continental deep subduction and UHP metamorphism. In addition to their geochronological applications to dating of HP to UHP metamorphic events during continental collision, microbeam techniques have also served as an efficient means to recognize different generations of mineral growth during continental subduction-zone metamorphism. Furthermore, metamorphic dehydration and partial melting of UHP metamorphic rocks during subduction and exhumation are highlighted with respect to their effects on fluid action and element mobilization. These have provided new insights into chemical geodynamics in continental subduction zones.

Kinematic evolution of the Maacama Fault Zone, Northern California Coast Ranges

NASA Astrophysics Data System (ADS)

Schroeder, Rick D.

The Maacama Fault Zone (MFZ) is a major component of the Pacific-North American transform boundary in northern California, and its distribution of deformation and kinematic evolution defines that of a young continental transform boundary. The USGS Quaternary database (2010) currently defines the MFZ as a relatively narrow fault zone; however, a cluster analysis of microearthquakes beneath the MFZ defines a wider fault zone, composed of multiple seismogenically active faults. The surface projection of best-fit tabular zones through foci clusters correlates with previously interpreted faults that were assumed inactive. New investigations further delineate faults within the MFZ based on geomorphic features and shallow resistivity surveys, and these faults are interpreted to be part of several active pull-apart fault systems. The location of faults and changes in their geometry in relation to geomorphic features, indicate >8 km of cumulative dextral displacement across the eastern portion of the MFZ at Little Lake Valley, which includes other smaller offsets on fault strands in the valley. Some faults within the MFZ have geometries consistent with reactivated subduction-related reverse faults, and project near outcrops of pre-existing faults, filled with mechanically weak minerals. The mechanical behavior of fault zones is influenced by the spatial distribution and abundance of mechanically weak lithologies and mineralogies within the heterogeneous Franciscan melange that the MFZ displaces. This heterogeneity is characterized near Little Lake Valley (LLV) using remotely sensed data, field mapping, and wellbore data, and is composed of 2--5 km diameter disk-shaped coherent blocks that can be competent and resist deformation. Coherent blocks and the melange that surrounds them are the source for altered minerals that fill portions of fault zones. Mechanically weak minerals in pre-existing fault zones, identified by X-ray diffraction and electron microprobe analyses, are

Mineral exploration, Mahd adh Dhahab District, Kingdom of Saudi Arabia

USGS Publications Warehouse

Worl, Ronald G.

1978-01-01

Mahd adh Dhahab is the largest of numerous ancient gold mines scattered through the Precambrian shield of Saudi Arabia and the only one with recent production. During the period 1939-54, 765,768 fine ounces of gold and 1,002,029 ounces of silver were produced from the mines by the Saudi Arabian Mining Syndicate. Ore minerals at Mahd adh Dhahab include free gold and silver, tellurides, sphalerite, and chalcopyrite in and associated with a system of north-trending quartz veins and quartz veinlet stockworks. Pyrite is a common sulfide gangue mineral. Country rocks are a north dipping sequence of pyroclastic and transported pyroclastic rocks of the Hulayfah Group that are locally highly silicified and potassium-feldspathized. The prime target for this exploration program was a north-trending zone of quartz veins and breccias, faults, alteration, and metalization approximately 400 m wide and 1000 m long. The ancient and recent mine workings are located in the northern part of this zone. Although the quartz veins and alteration cut all lithologies, the major metalization is confined to the intersection of veins and agglomerate. Ten holes were diamond drilled to explore geochemical, geological, and geophysical targets in the area. A significant new zone of metalization was discovered 700 m south of the ancient and recent mine workings and within the same major zone of quartz veins, alteration, and faults. Metalization in this southern mineralized zone is at the intersection of the quartz veins and a distinctive and highly altered agglomerate. The total zone of vein and agglomerate intercept is potentially metalized and comprises a block of ground 40 m thick and 400 m wide along the strike of the agglomerate and projected downdip 250 m. Tonnage of this block is 17.2 million tons. The explored zone, approximately 25 percent of the potentially metalized rock, has a potential resource of 1.1 million tons containing 27 g/t gold and 73 g/t silver.

Study of the structural, vibrational and thermodynamic properties of natroxalate mineral using density functional theory

NASA Astrophysics Data System (ADS)

Colmenero, Francisco; Timón, Vicente

2018-07-01

Natroxalate mineral, Na2C2O4, is a fundamental oxalate mineral widespread in nature, present in humans, animals and plants, as well as in naturally occurring minerals. The characterization of oxalate minerals is extraordinarily important since these organic minerals are indicators of environmental events and of the presence of biological activity, because they are commonly of biological origin. These minerals are currently under study to investigate the possible biological activity on Mars. The identification of these compounds is usually performed by X-ray diffraction and Raman spectroscopy. Theoretical calculations are of great value for the study and interpretation of the results of these experimental techniques. In this work, natroxalate mineral structure and Raman spectrum was studied by first principle calculations based on the density functional theory. The computed structure of natroxalate reproduces the one determined experimentally by X-ray diffraction (monoclinic symmetry, space group P21/c; lattice parameters a = 3.449 Å, b = 5.243 Å; c = 10.375 Å). Lattice parameters, bond lengths, bond angles and X-ray powder pattern were found to be in very good agreement with their experimental counterparts. Raman spectrum was then computed by means of density functional perturbation theory and compared with the experimental spectrum. Since the results were also found in agreement with the experimental data, a normal mode analysis of the theoretical spectra was carried out and used in order to assign the main bands of the Raman spectrum. The band found at about 567 cm-1, described as a single peak in previous experimental works, is shown clearly to have two contributing bands. Finally, two bands of the observed spectrum, located at the wavenumbers 1750 and 1358 cm-1, were not found in the theoretical spectrum. This is because these bands correspond to an overtone, 2ν1 (ν1 = 875 cm-1), and a combination band, ν1 + ν2 (ν1,ν2 = 875, 481 cm-1), respectively

Formation of an active thrust triangle zone associated with structural inversion in a subduction setting, eastern New Zealand

NASA Astrophysics Data System (ADS)

Barnes, Philip M.; Nicol, Andrew

2004-02-01

We analyze a thrust triangle zone, which underlies the continental shelf of Hawke Bay, eastern New Zealand, within the Hikurangi subduction margin. This triangle zone differs from many other examples in that it is active, 90 km from the leading edge of the overriding plate, and formed due to polyphase deformation involving opposed dipping thrust duplex and backthrust, with the later structure forming in response to inversion of an extensional graben. The component structures of the zone mainly developed sequentially rather than synchronously. High-quality marine seismic reflection lines, tied to well and seabed samples, reveal the three-dimensional structure of the zone, together with its 25 Myr evolution and late Quaternary activity. The triangle zone occurs in the lateral overlap between a stack of NW dipping blind thrusts, and a principal backthrust, the Kidnappers fault. The NW dipping thrusts initiated in the early-middle Miocene during the early stages of subduction, with subsequent thrust duplex formation producing major uplift and erosion in the late Miocene-early Pliocene. The active backthrust formed during the late Miocene to early Pliocene as a thin-skinned listric extensional fault confined to the cover sequence. Structural inversion of the extensional fault commenced in the early-middle Pliocene, produced the backthrust and marks the formation of the thrust triangle zone. The thrust duplex and backthrust accrued strain following inversion; however, the later structure accommodated most of the surface deformation in the Quaternary. Section balancing of the triangle zone together with a detailed analysis of reverse displacements along the backthrust reveal spatial and temporal variations of strain accumulation on the two principal components of the zone. Although the formation of the triangle zone is strongly influenced by regional tectonics of the subduction system, these variations may also, in part, reflect local fault interaction. For example, high

The Genesis of Precious and Base Metal Mineralization at the Miguel Auza Deposit, Zacatecas, Mexico

NASA Astrophysics Data System (ADS)

Findley, A. A.; Olivo, G. R.; Godin, L.

2009-05-01

The Miguel Auza mine located in Zacatecas State, Mexico, is a vein-type polymetallic epithermal deposit hosted in deformed argillite, siltstone and, greywacke of the Cretaceous Caracol Formation. Silver-rich base metal veins (0.2 m to >1.5 m wide) are spatially associated with the NE-striking, steeply SE- dipping (70-80°) Miguel Auza fault over a strike length of 1.6 km and a depth of 460 m. A 2 km2 monzonitic stock located in the proximity of the mineralized zones, has previously been interpreted as the source of the mineralizing fluids. Four distinct structural stages are correlated with hydrothermal mineral deposition: (I) The Pre-ore stage is characterized by normal faulting, fracturing of host rock, and rotation of bedding planes. This stage consists of quartz, illite, chlorite, +/- pyrite alteration of sedimentary wall rocks. (II) The Pyrite-vein stage is associated with reverse-sense reactivation of early normal faults, dilation of bedding planes/fractures, and deposition of generally barren calcite + pyrite veinlets. (III) The Main-ore stage is related to the development of reverse-fault- hosted massive sulphide veins. During this stage three phases of mineral deposition are recorded: early pyrite and arsenopyrite, intermediate chalcopyrite, pyrite, arsenopyrite, and base metals, and late base metals and Ag-bearing minerals. Associated gangue minerals during the main ore stage are quartz, muscovite, calcite and chlorite. (IV) The Post-ore stage involves late NW-SE striking block faulting, brecciation and calcite veining. Later supergene oxidation of veins led to deposition of Fe-oxides and hydroxides, commonly filling fractures or replacing early-formed sulphide assemblages. The various vein types display classic epithermal textures including open space filling, banding, comb quartz and brecciation. The Ag-bearing minerals comprise pyrargyrite [Ag3(Sb,As)S3], argentotennantite [(Cu,Ag)10(Zn,Fe)2(Sn,As)4S13], polybasite-pearceite [(Ag,Cu)16(Sb,As)2S11], and

Far-Zone Resonant Energy Transfer in X-ray Photoemission as a Structure Determination Tool.

PubMed

Céolin, Denis; Rueff, Jean-Pascal; Zimin, Andrey; Morin, Paul; Kimberg, Victor; Polyutov, Sergey; Ågren, Hans; Gel'mukhanov, Faris

2017-06-15

Near-zone Förster resonant energy transfer is the main effect responsible for excitation energy flow in the optical region and is frequently used to obtain structural information. In the hard X-ray region, the Förster law is inadequate because the wavelength is generally shorter than the distance between donors and acceptors; hence, far-zone resonant energy transfer (FZRET) becomes dominant. We demonstrate the characteristics of X-ray FZRET and its fundamental differences with the ordinary near-zone resonant energy-transfer process in the optical region by recording and analyzing two qualitatively different systems: high-density CuO polycrystalline powder and SF 6 diluted gas. We suggest a method to estimate geometrical structure using X-ray FZRET employing as a ruler the distance-dependent shift of the acceptor core ionization potential induced by the Coulomb field of the core-ionized donor.

A contribution with review to the description of mineralization of bone and other calcified tissues in vivo

NASA Technical Reports Server (NTRS)

Christoffersen, J.; Landis, W. J.

1991-01-01

This manuscript considers certain aspects of mineral deposition in bone and other vertebrate calcifying tissues in order to examine physical, chemical, and biological factors important in the mineralization process. The paper in a discussion format principally presents a new data and the formulation of concepts based on such data as well as a summary of background material as necessary review. Mineralization is found to occur at spatially independent sites throughout the organic extracellular tissue matrices. Matrix vesicles and collagen fibrils each may serve as independent nucleation centers for mineral with vesicle mineralization being local and collagen mineralization dominating the tissues as a whole. Collagen fibril organization is suggested to be such that hole zones are aligned in three dimensions, creating extensive channels for mineral accommodation. Nucleation occurs initially in hole zones and crystal growth leads to the development of plate-like mineral particles whose orientation, disposition, and sizes within fibrils are detailed. Effects of diffusion, crystallinity, and critical nucleation and growth events are described with respect to their influence on mineral deposition in bulk and local regions of tissue matrices.

Ultra-structural defects cause low bone matrix stiffness despite high mineralization in osteogenesis imperfecta mice☆

PubMed Central

Vanleene, Maximilien; Porter, Alexandra; Guillot, Pascale-Valerie; Boyde, Alan; Oyen, Michelle; Shefelbine, Sandra

2012-01-01

Bone is a complex material with a hierarchical multi-scale organization from the molecule to the organ scale. The genetic bone disease, osteogenesis imperfecta, is primarily caused by mutations in the collagen type I genes, resulting in bone fragility. Because the basis of the disease is molecular with ramifications at the whole bone level, it provides a platform for investigating the relationship between structure, composition, and mechanics throughout the hierarchy. Prior studies have individually shown that OI leads to: 1. increased bone mineralization, 2. decreased elastic modulus, and 3. smaller apatite crystal size. However, these have not been studied together and the mechanism for how mineral structure influences tissue mechanics has not been identified. This lack of understanding inhibits the development of more accurate models and therapies. To address this research gap, we used a mouse model of the disease (oim) to measure these outcomes together in order to propose an underlying mechanism for the changes in properties. Our main finding was that despite increased mineralization, oim bones have lower stiffness that may result from the poorly organized mineral matrix with significantly smaller, highly packed and disoriented apatite crystals. Using a composite framework, we interpret the lower oim bone matrix elasticity observed as the result of a change in the aspect ratio of apatite crystals and a disruption of the crystal connectivity. PMID:22449447

Ultra-structural defects cause low bone matrix stiffness despite high mineralization in osteogenesis imperfecta mice.

PubMed

Vanleene, Maximilien; Porter, Alexandra; Guillot, Pascale-Valerie; Boyde, Alan; Oyen, Michelle; Shefelbine, Sandra

2012-06-01

Bone is a complex material with a hierarchical multi-scale organization from the molecule to the organ scale. The genetic bone disease, osteogenesis imperfecta, is primarily caused by mutations in the collagen type I genes, resulting in bone fragility. Because the basis of the disease is molecular with ramifications at the whole bone level, it provides a platform for investigating the relationship between structure, composition, and mechanics throughout the hierarchy. Prior studies have individually shown that OI leads to: 1. increased bone mineralization, 2. decreased elastic modulus, and 3. smaller apatite crystal size. However, these have not been studied together and the mechanism for how mineral structure influences tissue mechanics has not been identified. This lack of understanding inhibits the development of more accurate models and therapies. To address this research gap, we used a mouse model of the disease (oim) to measure these outcomes together in order to propose an underlying mechanism for the changes in properties. Our main finding was that despite increased mineralization, oim bones have lower stiffness that may result from the poorly organized mineral matrix with significantly smaller, highly packed and disoriented apatite crystals. Using a composite framework, we interpret the lower oim bone matrix elasticity observed as the result of a change in the aspect ratio of apatite crystals and a disruption of the crystal connectivity. Copyright © 2012 Elsevier Inc. All rights reserved.

Quantitative analysis of seismic fault zone waves in the rupture zone of the 1992 Landers, California, earthquake: Evidence for a shallow trapping structure

USGS Publications Warehouse

Peng, Z.; Ben-Zion, Y.; Michael, A.J.; Zhu, L.

2003-01-01

We analyse quantitatively a waveform data set of 238 earthquakes recorded by a dense seismic array across and along the rupture zone of the 1992 Landers earthquake. A grid-search method with station delay corrections is used to locate events that do not have catalogue locations. The quality of fault zone trapped waves generated by each event is determined from the ratios of seismic energy in time windows corresponding to trapped waves and direct S waves at stations close to and off the fault zone. Approximately 70 per cent of the events with S-P times of less than 2 s, including many clearly off the fault, produce considerable trapped wave energy. This distribution is in marked contrast with previous claims that trapped waves are generated only by sources close to or inside the Landers rupture zone. The time difference between the S arrival and trapped waves group does not grow systematically with increasing hypocentral distance and depth. The dispersion measured from the trapped waves is weak. These results imply that the seismic trapping structure at the Landers rupture zone is shallow and does not extend continuously along-strike by more than a few kilometres. Synthetic waveform modelling indicates that the fault zone waveguide has depth of approximately 2-4 km, a width of approximately 200 m, an S-wave velocity reduction relative to the host rock of approximately 30-40 per cent and an S-wave attenuation coefficient of approximately 20-30. The fault zone waveguide north of the array appears to be shallower and weaker than that south of the array. The waveform modelling also indicates that the seismic trapping structure below the array is centred approximately 100 m east of the surface break.

Geology, petrology and geochronology of the Lago Grande layered complex: Evidence for a PGE-mineralized magmatic suite in the Carajás Mineral Province, Brazil

NASA Astrophysics Data System (ADS)

Teixeira, Antonio Sales; Ferreira Filho, Cesar Fonseca; Giustina, Maria Emilia Schutesky Della; Araújo, Sylvia Maria; da Silva, Heloisa Helena Azevedo Barbosa

2015-12-01

The Lago Grande and Luanga mafic-ultramafic complexes are part of a cluster of PGE-mineralized layered intrusions located in the Carajás Mineral Province (CMP) in the Amazonian Craton. The Lago Grande Complex is a NE-trending medium-size (12-km-long and average 1.7-km-wide) layered intrusion consisting mainly of mafic cumulate rocks (Mafic Zone) and minor ultramafic cumulates (Ultramafic Zone). Geological sections indicate that igneous layers are overturned, such that the Ultramafic Zone overly the Mafic Zone. The Ultramafic Zone, about 4 km long and 500 m wide, comprises an up to 250 m-thick sequence of interlayered harzburgite and orthopyroxenite at the base and orthopyroxenite at the top. The Mafic Zone consists of a monotonous sequence of gabbroic rocks with an estimated thickness of up to 1000 m in the central part. Primary igneous minerals of the Lago Grande Complex are partially replaced by metamorphic assemblages that indicate temperatures up to the amphibolite facies of metamorphism. This metamorphic alteration is heterogeneous and characterized by an extensive hydration that largely preserves primary textures and bulk chemical composition. The composition of the parental magma of the Lago Grande Complex has been inferred from the crystallization sequences of the intrusion and lithogeochemistry of cumulate rocks. The compositional range of cumulus Ol (Fo82.5-85.7) is consistent with a moderately primitive composition for the parental magma. Cumulus minerals in the layered rocks indicate that the sequence of crystallization in the Lago Grande Complex consists of Ol + Chr, Opx + Chr, Opx, Opx + Pl and Opx + Pl + Cpx. The early crystallization of Opx relative to Cpx suggests that the primary magma was silica saturated. Mantle-normalized alteration-resistant trace element profiles of gabbroic rocks are fractionated, as indicated by relative enrichment in LREE and Th, with pronounced negative Nb and Ta anomalies. Nd isotopic data obtained for both mafic and

Electromagnetic study of lithospheric structure in Trans-European Suture Zone in Poland

NASA Astrophysics Data System (ADS)

Jóźwiak, Waldemar; Ślęzak, Katarzyna; Nowożyński, Krzysztof; Neska, Anne

2016-04-01

The area covered by magnetotelluric surveys in Poland is mostly related to the Trans-European Suture Zone (TESZ), the largest tectonic boundary in Europe. Numerous 1D, 2D, and pseudo-3D and 3D models of the electrical resistivity distribution were constructed, and a new interpretation method based on Horizontal Magnetic Tensor analysis has been applied recently. The results indicate that the TESZ is a lithospheric discontinuity and there are noticeable differences in geoelectric structures between the East European Craton (EEC), the transitional zone (TESZ), and the Paleozoic Platform (PP). The electromagnetic sounding is a very efficient tool for recognizing the lithospheric structure especially it helps in identification of important horizontal (or lateral) inhomogeneities in the crust. Due to our study we can clearly determine the areas of the East European Craton of high resistivity, Paleozoic Platform of somewhat lower resistivity value, and transitional TESZ of complicated structure. At the East European Craton, we observe very highly resistive lithosphere, reaching 220-240 km depth. Underneath, there is distinctly greater conductivity values, most probably resulting from partial melting of rocks; this layer may represent the asthenosphere. The resistivity of the lithosphere under the Paleozoic Platform is somewhat lower, and its thickness does not exceed 150 km. The properties of the lithosphere in the transition zone, under the TESZ, differ significantly. The presented models include prominent, NW-SE striking conductive lineaments. These structures, that related with the TESZ, lie at a depth of 10-30 km. They are located in a mid-crustal level and they reach the boundary of the EEC. The structures we initially connect to the Variscan Deformation Front (VDF) and the Caledonian Deformation Front (CDF). The differentiation of conductivity visible in the crust continues in the upper mantle.

Effects of curing conditions on the structure of sodium carboxymethyl starch/mineral matrix system: FT-IR investigation.

PubMed

Kaczmarska, Karolina; Grabowska, Beata; Bobrowski, Artur; Cukrowicz, Sylwia

2018-04-24

Strength properties of the microwave cured molding sands containing binders in a form of the aqueous solution of sodium carboxymethyl starch (CMS-Na) are higher than the same molding composition cured by conventional heating. Finding the reason of this effect was the main purpose in this study. Structural changes caused by both physical curing methods of molding sands systems containing mineral matrix (silica sand) and polymer water-soluble binder (CMS-Na) were compared. It was shown, by means of the FT-IR spectroscopic studies, that the activation of the polar groups in the polymer macromolecules structure as well as silanol groups on the mineral matrix surfaces was occurred in the microwave radiation. Binding process in microwave-cured samples was an effect of formation the hydrogen bonds network between hydroxyl and/or carbonyl groups present in polymer and silanol groups present in mineral matrix. FT-IR studies of structural changes in conventional and microwave cured samples confirm that participation of hydrogen bonds is greater after microwave curing than conventional heating. Copyright © 2018 Elsevier B.V. All rights reserved.

Structural changes in amber due to uranium mineralization.

PubMed

Havelcová, Martina; Machovič, Vladimír; Mizera, Jiří; Sýkorová, Ivana; René, Miloš; Borecká, Lenka; Lapčák, Ladislav; Bičáková, Olga; Janeček, Oldřich; Dvořák, Zdeněk

2016-07-01

The presence of uranium, with a bulk mass fraction of about 1.5 wt% and radiolytic alterations are a feature of Cenomanian amber from Křižany, at the northeastern edge of the North Bohemian Cretaceous uranium ore district. Pores and microcracks in the amber were filled with a mineral admixture, mainly in the form of Zr-Y-REE enriched uraninite. As a result of radiolytic alterations due to the presence of uranium, structural changes were observed in the Křižany amber in comparison with a reference amber from Nové Strašecí in central Bohemia; this was of similar age and botanical origin but did not contain elevated levels of uranium. Structural changes involved an increase in aromaticity due to dehydroaromatization of aliphatic cyclic hydrocarbons, loss of oxygen functional groups, an increase in the degree of polymerization, crosslinking of CC bonds, formation of a three-dimensional hydrocarbon network in the bulk organic matrix, and carbonization of the organic matrix around the uraninite infill. Copyright © 2016 Elsevier Ltd. All rights reserved.

Subduction zone decoupling/retreat modeling explains south Tibet (Xigaze) and other supra-subduction zone ophiolites and their UHP mineral phases

NASA Astrophysics Data System (ADS)

Butler, Jared P.; Beaumont, Christopher

2017-04-01

The plate tectonic setting in which proto-ophiolite 'oceanic' lithosphere is created remains controversial with a number of environments suggested. Recent opinions tend to coalesce around supra-subduction zone (SSZ) forearc extension, with a popular conceptual model in which the proto-ophiolite forms during foundering of oceanic lithosphere at the time of spontaneous or induced onset of subduction. This mechanism is favored in intra-oceanic settings where the subducting lithosphere is old and the upper plate is young and thin. We investigate an alternative mechanism; namely, decoupling of the subducting oceanic lithosphere in the forearc of an active continental margin, followed by subduction zone (trench) retreat and creation of a forearc oceanic rift basin, containing proto-ophiolite lithosphere, between the continental margin and the retreating subduction zone. A template of 2D numerical model experiments examines the trade-off between strength of viscous coupling in the lithospheric subduction channel and net slab pull of the subducting lithosphere. Three tectonic styles are observed: 1) C, continuous subduction without forearc decoupling; 2) R, forearc decoupling followed by rapid subduction zone retreat; 3) B, breakoff of subducting lithosphere followed by re-initiation of subduction and in some cases, forearc decoupling (B-R). In one case (BA-B-R; where BA denotes backarc) subduction zone retreat follows backarc rifting. Subduction zone decoupling is analyzed using frictional-plastic yield theory and the Stefan solution for the separation of plates containing a viscous fluid. The numerical model results are used to explain the formation of Xigaze group ophiolites, southern Tibet, which formed in the Lhasa terrane forearc, likely following earlier subduction and not necessarily during subduction initiation. Either there was normal coupled subduction before subduction zone decoupling, or precursor slab breakoff, subduction re-initiation and then decoupling

Structural Mapping Along the Central San Andreas Fault-zone Using Airborne Electromagnetics

NASA Astrophysics Data System (ADS)

Zamudio, K. D.; Bedrosian, P.; Ball, L. B.

2017-12-01

Investigations of active fault zones typically focus on either surface expressions or the associated seismogenic zones. However, the largely aseismic upper kilometer can hold significant insight into fault-zone architecture, strain partitioning, and fault-zone permeability. Geophysical imaging of the first kilometer provides a link between surface fault mapping and seismically-defined fault zones and is particularly important in geologically complex regions with limited surface exposure. Additionally, near surface imaging can provide insight into the impact of faulting on the hydrogeology of the critical zone. Airborne electromagnetic (AEM) methods offer a unique opportunity to collect a spatially-large, detailed dataset in a matter of days, and are used to constrain subsurface resistivity to depths of 500 meters or more. We present initial results from an AEM survey flown over a 60 kilometer long segment of the central San Andreas Fault (SAF). The survey is centered near Parkfield, California, the site of the SAFOD drillhole, which marks the transition between a creeping fault segment to the north and a locked zone to the south. Cross sections with a depth of investigation up to approximately 500 meters highlight the complex Tertiary and Mesozoic geology that is dismembered by the SAF system. Numerous fault-parallel structures are imaged across a more than 10 kilometer wide zone centered on the surface trace. Many of these features can be related to faults and folds within Plio-Miocene sedimentary rocks found on both sides of the fault. Northeast of the fault, rocks of the Mesozoic Franciscan and Great Valley complexes are extremely heterogeneous, with highly resistive volcanic rocks within a more conductive background. The upper 300 meters of a prominent fault-zone conductor, previously imaged to 1-3 kilometers depth by magnetotellurics, is restricted to a 20 kilometer long segment of the fault, but is up to 4 kilometers wide in places. Elevated fault-zone

Seismic attenuation structure beneath Nazca Plate subduction zone in southern Peru

NASA Astrophysics Data System (ADS)

Jang, H.; Kim, Y.; Clayton, R. W.

2017-12-01

We estimate seismic attenuation in terms of quality factors, QP and QS using P and S phases, respectively, beneath Nazca Plate subduction zone between 10°S and 18.5°S latitude in southern Peru. We first relocate 298 earthquakes with magnitude ranges of 4.0-6.5 and depth ranges of 20-280 km. We measure t*, which is an integrated attenuation through the seismic raypath between the regional earthquakes and stations. The measured t* are inverted to construct three-dimensional attenuation structures of southern Peru. Checkerboard test results for both QP and QS structures ensure good resolution in the slab-dip transition zone between flat and normal slab subduction down to a depth of 200 km. Both QP and QS results show higher attenuation continued down to a depth of 50 km beneath volcanic arc and also beneath the Quimsachata volcano, the northernmost young volcano, located far east of the main volcanic front. We also observe high attenuation in mantle wedge especially beneath the normal subduction region in both QP and QS (100-130 in QP and 100-125 in QS) and slightly higher QP and QS beneath the flat-subduction and slab-dip transition regions. We plan to relate measured attenuation in the mantle wedge to material properties such as viscosity to understand the subduction zone dynamics.

Enzyme leaching of surficial geochemical samples for detecting hydromorphic trace-element anomalies associated with precious-metal mineralized bedrock buried beneath glacial overburden in northern Minnesota

USGS Publications Warehouse

Clark, Robert J.; Meier, A.L.; Riddle, G.; ,

1990-01-01

One objective of the International Falls and Roseau, Minnesota, CUSMAP projects was to develop a means of conducting regional-scale geochemical surveys in areas where bedrock is buried beneath complex glacially derived overburden. Partial analysis of B-horizon soils offered hope for detecting subtle hydromorphic trace-element dispersion patterns. An enzyme-based partial leach selectively removes metals from oxide coatings on the surfaces of soil materials without attacking their matrix. Most trace-element concentrations in the resulting solutions are in the part-per-trillion to low part-per-billion range, necessitating determinations by inductively coupled plasma/mass spectrometry. The resulting data show greater contrasts for many trace elements than with other techniques tested. Spatially, many trace metal anomalies are locally discontinuous, but anomalous trends within larger areas are apparent. In many instances, the source for an anomaly seems to be either basal till or bedrock. Ground water flow is probably the most important mechanism for transporting metals toward the surface, although ionic diffusion, electrochemical gradients, and capillary action may play a role in anomaly dispersal. Sample sites near the Rainy Lake-Seine River fault zone, a regional shear zone, often have anomalous concentrations of a variety of metals, commonly including Zn and/or one or more metals which substitute for Zn in sphalerite (Cd, Ge, Ga, and Sn). Shifts in background concentrations of Bi, Sb, and As show a trend across the area indicating a possible regional zoning of lode-Au mineralization. Soil anomalies of Ag, Co, and Tl parallel basement structures, suggesting areas that may have potential for Cobalt/Thunder Baytype silver viens. An area around Baudette, Minnesota, which is underlain by quartz-chlorite-carbonate-altered shear zones, is anomalous in Ag, As, Bi, Co, Mo, Te, Tl, and W. Anomalies of Ag, As, Bi, Te, and W tend to follow the fault zones, suggesting potential

Periodic Nanoneedle and Buffer Zones Constructed on a Titanium Surface Promote Osteogenic Differentiation and Bone Calcification In Vivo.

PubMed

Yu, Peng; Zhu, Xiaojing; Wang, Xiaolan; Wang, Shuangying; Li, Weiping; Tan, Guoxin; Zhang, Yu; Ning, Chengyun

2016-02-04

Rapid and effective bone mineralization at the bone/implant interface is required for successful orthopedic and dental implants. In this study, two periodic microscale functionalized zones on titanium (MZT) are created, namely, nanoneedle zones and buffer zones. The aim of this design is to provide spatially regulated topographical cues on titanium to enhance the efficacy of bone regeneration. This goal is achieved using a versatile and effective technique in which nanoneedle structures are hydrothermally constructed on the surface of titanium sheets, after which selective laser irradiation is used to construct buffer zones. The zonal structures of the MZT overcome the suppressive effect of the nanoneedle film on osteoblasts. Additionally, the MZT exhibits zone-selective apatite deposition and protein adsorption. The accelerated in vitro osteoblast differentiation and nodule deposition on the MZT are confirmed. Elemental analysis of the bone nodules formed by the osteoblasts growing on the titanium and MZT demonstrates they have different compositions. Histological and scanning electron microscope analysis of the bone formation on in vivo implants shows that this process is also enhanced by the MZT implant. The concept of constructing functionalized zones on titanium implant could facilitate future research on improving the design of orthopedic and dental implant surfaces. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mineral transformations during the dissolution of uranium ore minerals by dissimilatory metal-reducing bacteria

NASA Astrophysics Data System (ADS)

Glasauer, S.; Weidler, P.; Fakra, S.; Tyliszczak, T.; Shuh, D.

2011-12-01

Carnotite minerals [X2(UO2)2(VO4)2]; X = K, Ca, Ba, Mn, Na, Cu or Pb] form the major ore of uranium in the Colorado Plateau. These deposits are highly oxidized and contain U(VI) and V(IV). The biotransformation of U(VI) bound in carnotite by bacteria during dissimilatory metal reduction presents a complex puzzle in mineral chemistry. Both U(VI) and V(V) can be respired by metal reducing bacteria, and the mineral structure can change depending on the associated counterion. We incubated anaerobic cultures of S. putrefaciens CN32 with natural carnotite minerals from southeastern Utah in a nutrient-limited defined medium. Strain CN32 is a gram negative bacterium and a terrestrial isolate from New Mexico. The mineral and metal transformations were compared to a system that contained similar concentrations of soluble U(VI) and V(V). Electron (SEM, TEM) microscopies and x-ray spectromicroscopy (STXM) were used in conjunction with XRD to track mineral changes, and bacterial survival was monitored throughout the incubations. Slow rates of metal reduction over 10 months for the treatment with carnotite minerals revealed distinct biotic and abiotic processes, providing insight on mineral transformation and bacteria-metal interactions. The bacteria existed as small flocs or individual cells attached to the mineral phase, but did not adsorb soluble U or V, and accumulated very little of the biominerals. Reduction of mineral V(V) necessarily led to a dismantling of the carnotite structure. Bioreduction of V(V) by CN32 contributed small but profound changes to the mineral system, resulting in new minerals. Abiotic cation exchange within the carnotite group minerals induced the rearrangement of the mineral structures, leading to further mineral transformation. In contrast, bacteria survival was poor for treatments with soluble U(VI) and V(V), although both metals were reduced completely and formed solid UO2 and VO2; we also detected V(III). For these treatments, the bacteria

Silica-undersaturated reaction zones at a crust-mantle interface in the Highland Complex, Sri Lanka: Mass transfer and melt infiltration during high-temperature metasomatism

NASA Astrophysics Data System (ADS)

Fernando, G. W. A. R.; Dharmapriya, P. L.; Baumgartner, Lukas P.

2017-07-01

Sri Lanka is a crucial Gondwana fragment mostly composed of granulitic rocks in the Highland Complex surrounded by rocks with granulite to amphibolite grade in the Vijayan and Wanni Complex that were structurally juxtaposed during Pan-African orogeny. Fluids associated with granulite-facies metamorphism are thought to have controlled various lower crustal processes such as dehydration/hydration reactions, partial melting, and high-temperature metasomatism. Chemical disequilibrium in the hybrid contact zone between a near peak post-tectonic ultramafic enclave and siliceous granulitic gneiss at Rupaha within the Highland Complex produced metasomatic reaction zones under the presence of melt. Different reaction zones observed in the contact zone show the mineral assemblages phlogopite + spinel + sapphirine (zone A), spinel + sapphirine + corundum (zone B), corundum ( 30%) + biotite + plagioclase zone (zone C) and plagioclase + biotite + corundum ( 5%) zone (zone D). Chemical potential diagrams and mass balance reveal that the addition of Mg from ultramafic rocks and removal of Si from siliceous granulitic gneiss gave rise to residual enrichment of Al in the metasomatized mineral assemblages. We propose that contact metasomatism between the two units, promoted by melt influx, caused steady state diffusional transport across the profile. Corundum growth was promoted by the strong residual Al enrichment and Si depletion in reaction zone whereas sapphirine may have been formed under high Mg activity near the ultramafic rocks. Modelling also indicated that metasomatic alteration occurred at ca. 850 °C at 9 kbar, which is consistent with post-peak metamorphic conditions reached during the initial stage of exhumation in the lower crust and with temperature calculations based on conventional geothermometry.

Identifying areas of high economic-potential copper mineralization using ASTER data in the Urumieh-Dokhtar Volcanic Belt, Iran

NASA Astrophysics Data System (ADS)

Pour, Amin Beiranvand; Hashim, Mazlan

2012-02-01

This study investigates the application of spectral image processing methods to ASTER data for mapping hydrothermal alteration zones associated with porphyry copper mineralization and related host rock. The study area is located in the southeastern segment of the Urumieh-Dokhtar Volcanic Belt of Iran. This area has been selected because it is a potential zone for exploration of new porphyry copper deposits. Spectral transform approaches, namely principal component analysis, band ratio and minimum noise fraction were used for mapping hydrothermally altered rocks and lithological units at regional scale. Spectral mapping methods, including spectral angle mapper, linear spectral unmixing, matched filtering and mixture tuned matched filtering were applied to differentiate hydrothermal alteration zones associated with porphyry copper mineralization such as phyllic, argillic and propylitic mineral assemblages.Spectral transform methods enhanced hydrothermally altered rocks associated with the known porphyry copper deposits and new identified prospects using shortwave infrared (SWIR) bands of ASTER. These methods showed the discrimination of quartz rich igneous rocks from the magmatic background and the boundary between igneous and sedimentary rocks using the thermal infrared (TIR) bands of ASTER at regional scale. Spectral mapping methods distinguished the sericitically- and argillically-altered rocks (the phyllic and argillic alteration zones) that surrounded by discontinuous to extensive zones of propylitized rocks (the propylitic alteration zone) using SWIR bands of ASTER at both regional and district scales. Linear spectral unmixing method can be best suited for distinguishing specific high economic-potential hydrothermal alteration zone (the phyllic zone) and mineral assemblages using SWIR bands of ASTER. Results have proven to be effective, and in accordance with the results of field surveying, spectral reflectance measurements and X-ray diffraction (XRD) analysis

Structural evidence for slip partitioning and inclined dextral transpression along the SE Sanandaj-Sirjan zone, Iran

NASA Astrophysics Data System (ADS)

Shafiei Bafti, Shahram; Mohajjel, Mohammad

2015-04-01

The structural evolution of the Sanandaj-Sirjan zone is the result of the convergence of the Iranian microcontinent and the Afro-Arabian continent. The study area at Khabr in the SE Sanandaj-Sirjan zone, in the hinterland of the Zagros orogen, consists of Paleozoic, Mesozoic and Cenozoic rocks. In this area, deformation phases were distinguished in different rock units based on structural and stratigraphical evidence, and the deformational events are divided into two stages: (1) a Late Triassic event and (2) a Late Cretaceous to Miocene event. The Late Triassic deformation event caused regional metamorphism in the Paleozoic units. These units are overlain by unmetamorphosed Jurassic clastic sequences. Fabrics and structural evidence confirm that the F1 folding recumbent and refolded folds were synchronous with the metamorphism of the Paleozoic units and terminated in the Early Jurassic. The time table of the orogenic phases shows that this deformation event is related to the Cimmerian orogenic phase. From a geodynamic point of view, the early Cimmerian deformation in the southeastern Iranian margin suggests that the SE Sanandaj-Sirjan zone was an active margin at that time. The early Cimmerian discordance recorded the onset of a contractional component related to the oblique subduction of Neo-Tethys beneath the central Iranian microcontinent. Structures related to the Late Cretaceous to Miocene deformation phase are observed in Jurassic to Oligocene units, which contain moderately inclined and plunging folds. Comparing these folds with domains of deformation generated in models of transpression shows that the folding was caused by a combination of contractional and dip-slip components of movement, eventually resulting in the formation of a thrust system. The Khabr thrust systems consist of five sheets of oblique thrusts, duplex structures and shear zones. The shear zones generally strike E-W and dip moderately N (30°-40°). The occurrence of asymmetric folds with

The structure of melting mushy zones, with implications for Earth's inner core (Invited)

NASA Astrophysics Data System (ADS)

Bergman, M. I.; Huguet, L.; Alboussiere, T.

2013-12-01

Seismologists have inferred hemispherical differences in the isotropic wavespeed, the elastic anisotropy, the attenuation, and the attenuation anisotropy of Earth's inner core. One hypothesis for these hemispherical differences involves an east-west translation of the inner core, with enhanced solidification on one side and melting on the other. Another hypothesis is that long term mantle control over outer core convection can lead to hemispherical variations in solidification that could even result in melting in some regions of the inner core boundary. It has also been hypothesized that the inner core is growing dendritically, resulting in an inner core that has the structure of a mushy zone (albeit one with a high solid fraction). It would therefore be helpful to understand how the structure of a melting mushy zone might look in comparison with one that is solidifying, in an effort to help interpret the seismic inferences. We have carried out experiments on the solidification of ammonium chloride from an aqueous solution, yielding a mushy zone. The experiments run in a centrifuge, in order to reach a more realistic ratio of convective velocity to phase change rate, expected to be very large at the boundary of the inner core. Hypergravity thus increases the experimental solid fraction of the mush. So far the maximum gravity we have achieved is 200 g. A Peltier cell provides cooling at one end of the cell, and after the mushy zone has grown we turn on a heater at the other end. Probes monitor the temperature along the height of the cell. As ammonium chloride in the mushy zone melts it produces more dense fluid, which results in convection in the mushy zone, a greater ammonium chloride concentration deeper in the mushy zone, and hence enhanced solidification there. This thus changes the solid fraction profile from that during solidification, which may be observable in the lab experiments using ultrasonic transducers and post-mortem under a microscope. The melting

Molybdenum isotope systematics in subduction zones

NASA Astrophysics Data System (ADS)

König, Stephan; Wille, Martin; Voegelin, Andrea; Schoenberg, Ronny

2016-08-01

This study presents Mo isotope data for arc lavas from different subduction zones that range between δ 98 / 95 Mo = - 0.72 and + 0.07 ‰. Heaviest isotope values are observed for the most slab fluid dominated samples. Isotopically lighter signatures are related to increasing relevance of terrigenous sediment subduction and sediment melt components. Our observation complements previous conclusions that an isotopically heavy Mo fluid flux likely mirrors selective incorporation of isotopically light Mo in secondary minerals within the subducting slab. Analogue to this interpretation, low δ 98 / 95 Mo flux that coincides with terrigenous sediment subduction and sediment melting cannot be simply related to a recycled input signature. Instead, breakdown of the controlling secondary minerals during sediment melting may release the light component and lead to decreasing δ 98 / 95 Mo influx into subarc mantle sources. The natural range between slab dehydration and hydrous sediment melting may thus cause a large spread of δ 98 / 95 Mo in global subduction zone magmas.

A shallow fault-zone structure illuminated by trapped waves in the Karadere-Duzce branch of the North Anatolian Fault, western Turkey

USGS Publications Warehouse

Ben-Zion, Y.; Peng, Z.; Okaya, D.; Seeber, L.; Armbruster, J.G.; Ozer, N.; Michael, A.J.; Baris, S.; Aktar, M.

2003-01-01

We discuss the subsurface structure of the Karadere-Duzce branch of the North Anatolian Fault based on analysis of a large seismic data set recorded by a local PASSCAL network in the 6 months following the Mw = 7.4 1999 Izmit earthquake. Seismograms observed at stations located in the immediate vicinity of the rupture zone show motion amplification and long-period oscillations in both P- and S-wave trains that do not exist in nearby off-fault stations. Examination of thousands of waveforms reveals that these characteristics are commonly generated by events that are well outside the fault zone. The anomalous features in fault-zone seismograms produced by events not necessarily in the fault may be referred to generally as fault-zone-related site effects. The oscillatory shear wave trains after the direct S arrival in these seismograms are analysed as trapped waves propagating in a low-velocity fault-zone layer. The time difference between the S arrival and trapped waves group does not grow systematically with increasing source-receiver separation along the fault. These observations imply that the trapping of seismic energy in the Karadere-Duzce rupture zone is generated by a shallow fault-zone layer. Traveltime analysis and synthetic waveform modelling indicate that the depth of the trapping structure is approximately 3-4 km. The synthetic waveform modelling indicates further that the shallow trapping structure has effective waveguide properties consisting of thickness of the order of 100 m, a velocity decrease relative to the surrounding rock of approximately 50 per cent and an S-wave quality factor of 10-15. The results are supported by large 2-D and 3-D parameter space studies and are compatible with recent analyses of trapped waves in a number of other faults and rupture zones. The inferred shallow trapping structure is likely to be a common structural element of fault zones and may correspond to the top part of a flower-type structure. The motion amplification

SCPRED: accurate prediction of protein structural class for sequences of twilight-zone similarity with predicting sequences.

PubMed

Kurgan, Lukasz; Cios, Krzysztof; Chen, Ke

2008-05-01

Protein structure prediction methods provide accurate results when a homologous protein is predicted, while poorer predictions are obtained in the absence of homologous templates. However, some protein chains that share twilight-zone pairwise identity can form similar folds and thus determining structural similarity without the sequence similarity would be desirable for the structure prediction. The folding type of a protein or its domain is defined as the structural class. Current structural class prediction methods that predict the four structural classes defined in SCOP provide up to 63% accuracy for the datasets in which sequence identity of any pair of sequences belongs to the twilight-zone. We propose SCPRED method that improves prediction accuracy for sequences that share twilight-zone pairwise similarity with sequences used for the prediction. SCPRED uses a support vector machine classifier that takes several custom-designed features as its input to predict the structural classes. Based on extensive design that considers over 2300 index-, composition- and physicochemical properties-based features along with features based on the predicted secondary structure and content, the classifier's input includes 8 features based on information extracted from the secondary structure predicted with PSI-PRED and one feature computed from the sequence. Tests performed with datasets of 1673 protein chains, in which any pair of sequences shares twilight-zone similarity, show that SCPRED obtains 80.3% accuracy when predicting the four SCOP-defined structural classes, which is superior when compared with over a dozen recent competing methods that are based on support vector machine, logistic regression, and ensemble of classifiers predictors. The SCPRED can accurately find similar structures for sequences that share low identity with sequence used for the prediction. The high predictive accuracy achieved by SCPRED is attributed to the design of the features, which are

SCPRED: Accurate prediction of protein structural class for sequences of twilight-zone similarity with predicting sequences

PubMed Central

Kurgan, Lukasz; Cios, Krzysztof; Chen, Ke

2008-01-01

Background Protein structure prediction methods provide accurate results when a homologous protein is predicted, while poorer predictions are obtained in the absence of homologous templates. However, some protein chains that share twilight-zone pairwise identity can form similar folds and thus determining structural similarity without the sequence similarity would be desirable for the structure prediction. The folding type of a protein or its domain is defined as the structural class. Current structural class prediction methods that predict the four structural classes defined in SCOP provide up to 63% accuracy for the datasets in which sequence identity of any pair of sequences belongs to the twilight-zone. We propose SCPRED method that improves prediction accuracy for sequences that share twilight-zone pairwise similarity with sequences used for the prediction. Results SCPRED uses a support vector machine classifier that takes several custom-designed features as its input to predict the structural classes. Based on extensive design that considers over 2300 index-, composition- and physicochemical properties-based features along with features based on the predicted secondary structure and content, the classifier's input includes 8 features based on information extracted from the secondary structure predicted with PSI-PRED and one feature computed from the sequence. Tests performed with datasets of 1673 protein chains, in which any pair of sequences shares twilight-zone similarity, show that SCPRED obtains 80.3% accuracy when predicting the four SCOP-defined structural classes, which is superior when compared with over a dozen recent competing methods that are based on support vector machine, logistic regression, and ensemble of classifiers predictors. Conclusion The SCPRED can accurately find similar structures for sequences that share low identity with sequence used for the prediction. The high predictive accuracy achieved by SCPRED is attributed to the design of

Periodic Density Functional Theory Study of the Structure, Raman Spectrum, and Mechanical Properties of Schoepite Mineral.

PubMed

Colmenero, Francisco; Cobos, Joaquín; Timón, Vicente

2018-04-16

The structure and Raman spectrum of schoepite mineral, [(UO 2 ) 8 O 2 (OH) 12 ]·12H 2 O, was studied by means of theoretical calculations. The computations were carried out by using density functional theory with plane waves and pseudopotentials. A norm-conserving pseudopotential specific for the U atom developed in a previous work was employed. Because it was not possible to locate H atoms directly from X-ray diffraction (XRD) data by structure refinement in previous experimental studies, all of the positions of the H atoms in the full unit cell were determined theoretically. The structural results, including the lattice parameters, bond lengths, bond angles, and powder XRD pattern, were found to be in good agreement with their experimental counterparts. However, the calculations performed using the unit cell designed by Ostanin and Zeller in 2007, involving half of the atoms of the full unit cell, led to significant errors in the computed powder XRD pattern. Furthermore, Ostanin and Zeller's unit cell contains hydronium ions, H 3 O + , which are incompatible with the experimental information. Therefore, while the use of this schoepite model may be a very useful approximation requiring a much smaller amount of computational effort, the full unit cell should be used to study this mineral accurately. The Raman spectrum was also computed by means of density functional perturbation theory and compared with the experimental spectrum. The results were also in agreement with the experimental data. A normal-mode analysis of the theoretical spectra was performed to assign the main bands of the Raman spectrum. This assignment significantly improved the current empirical assignment of the bands of the Raman spectrum of schoepite mineral. In addition, the equation of state and elastic properties of this mineral were determined. The crystal structure of schoepite was found to be stable mechanically and dynamically. Schoepite can be described as a brittle material exhibiting

[Mechanical properties of weld area soldered by lasers and structural changes in hot reaction zone].

PubMed

Wu, H; Cui, Y; Mu, W

2001-05-01

To analyse and measure the welding depths and strengths of three kinds of welding materials under different laser welding conditions as well as the structural changes of the heat affected zone. Under different voltages and pulse duration three kinds of measuring sticks, including Co-Cr alloy, Ni-Cr alloy and pure titanium were welded and their strengths were compared with that of control group. At the same time, the structure of the heat-affected zone was analysed by means of the gold-phase method. The welding depth and strength of Co-Cr alloy were in direct proportion to the setting voltage, with averages of 335MPa (250V) to 573MPa(330V). At the heat-affected zone, the crystal particle was small and the end point of welding by laser bean presented the shape of the mountain peak and the interval of finger shape. The center of measuring sticks had a black zone with the circle shape. The setting voltage was in direct proportion to the welding depth of pure titanium and in inverse proportion to the welding strength with averages of 221MPa(250V) to 154MPa (330V). The crystal particle in the heat affected zone grew large and the solid phase expanded, the interval of the crystal oxidised, and the structure showed honeycomb changes. The laser welding is favourable to the welding properties of Co-Cr and Ni-Cr alloys, but its effect on the welding properties of pure titanium needs further discussion.

Detailed Northern Anatolian Fault Zone crustal structure from receiver functions

NASA Astrophysics Data System (ADS)

Cornwell, D. G.; Kahraman, M.; Thompson, D. A.; Houseman, G. A.; Rost, S.; Turkelli, N.; Teoman, U.; Altuncu Poyraz, S.; Gülen, L.; Utkucu, M.

2013-12-01

We present high resolution images derived from receiver functions of the continental crust in Northern Turkey that is dissected by two fault strands of the Northern Anatolian Fault Zone (NAFZ). The NAFZ is a major continental strike-slip fault system that is comparable in length and slip rate to the San Andreas Fault Zone. Recent large earthquakes occurred towards the western end of the NAFZ in 1999 at Izmit (M7.5) and Düzce (M7.2). As part of the multi-disciplinary Faultlab project, we aim to develop a model of NAFZ crustal structure and locate deformation by constraining variations in seismic properties and anisotropy in the upper and lower crust. The crustal model will be an input to test deformation scenarios in order to match geodetic observations from different phases of the earthquake loading cycle. We calculated receiver functions from teleseismic earthquakes recorded by a rectangular seismometer array spanning the NAFZ with 66 stations at a nominal inter-station spacing of 7 km and 7 additional stations further afield. This Dense Array for North Anatolia (DANA) was deployed from May 2012 until September 2013 and we selected large events (Mw>5.5) from the high quality seismological dataset to analyze further. Receiver functions were calculated for different frequency bands then collected into regional stacks before being inverted for crustal S-wave velocity structure beneath the entire DANA array footprint. In addition, we applied common conversion point (CCP) migration using a regional velocity model to construct a migrated 3D volume of P-to-S converted and multiple energy in order to identify the major crustal features and layer boundaries. We also performed the CCP migration with transverse receiver functions in order to identify regions of anisotropy within the crustal layers. Our preliminary results show a heterogeneous crust above a flat Moho that is typically at a depth of 33 km. We do not observe a prominent step in the Moho beneath the surface

High-Resolution P'P' Precursor Imaging of Nazca-South America Plate Boundary Zones and Inferences for Transition Zone Temperature and Composition

NASA Astrophysics Data System (ADS)

Gu, Y. J.; Schultz, R.

2013-12-01

Knowledge of upper mantle transition zone stratification and composition is highly dependent on our ability to efficiently extract and properly interpret small seismic arrivals. A promising high-frequency seismic phase group particularly suitable for a global analysis is P'P' precursors, which are capable of resolving mantle structures at vertical and lateral resolution of approximately 5 and 200 km, respectively, owing to their shallow incidence angle and small, quasi-symmetric Fresnel zones. This study presents a simultaneous analysis of SS and P'P' precursors based on deconvolution, Radon transform and depth migration. Our multi-resolution survey of the mantle near Nazca-South America subduction zone reveals both olivine and garnet related transitions at depth below 400 km. We attribute a depressed 660 to thermal variations, whereas compositional variations atop the upper-mantle transition zone are needed to explain the diminished or highly complex reflected/scattered signals from the 410 km discontinuity. We also observe prominent P'P' reflections within the transition zone, especially near the plate boundary zone where anomalously high reflection amplitudes result from a sharp (~10 km thick) mineral phase change resonant with the dominant frequency of the P'P' precursors. Near the base of the upper mantle, the migration of SS precursors shows no evidence of split reflections near the 660-km discontinuity, but potential majorite-ilmenite (590-640 km) and ilmenite-perovskite transitions (740-750 km) are identified based on similarly processed high-frequency P'P' precursors. At nominal mantle temperatures these two phase changes may be seismically indistinguishable, but colder mantle conditions from the descending Nazca plate, the presence of water and variable Fe contents may cause sufficient separation for a reliable analysis. In addition, our preliminary results provide compelling evidence for multiple shallow lower-mantle reflections (at ~800 km) along the

30 CFR 285.612 - How will my SAP be processed for Federal consistency under the Coastal Zone Management Act?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 2 2011-07-01 2011-07-01 false How will my SAP be processed for Federal consistency under the Coastal Zone Management Act? 285.612 Section 285.612 Mineral Resources BUREAU OF OCEAN... the Coastal Zone Management Act? Your SAP will be processed based on how your commercial lease was...

Hydrologic Synthesis Across the Critical Zone Observatory Network: A Step Towards Understanding the Coevolution of Critical Zone Function and Structure

NASA Astrophysics Data System (ADS)

Wlostowski, A. N.; Harman, C. J.; Molotch, N. P.

2017-12-01

The physical and biological architecture of the Earth's Critical Zone controls hydrologic partitioning, storage, and chemical evolution of precipitated water. The Critical Zone Observatory (CZO) Network provides an ideal platform to explore linkages between catchment structure and hydrologic function across a gradient of geologic and climatic settings. A legacy of hypothesis-motivated research at each site has generated a wealth of data characterizing the architecture and hydrologic function of the critical zone. We will present a synthesis of this data that aims to elucidate and explain (in the sense of making mutually intelligible) variations in hydrologic function across the CZO network. Top-down quantitative signatures of the storage and partitioning of water at catchment scales extracted from precipitation, streamflow, and meteorological data will be compared with each other, and provide quantitative benchmarks to assess differences in perceptual models of hydrologic function at each CZO site. Annual water balance analyses show that CZO sites span a wide gradient of aridity and evaporative partitioning. The aridity index (PET/P) ranges from 0.3 at Luquillo to 4.3 at Reynolds Creek, while the evaporative index (E/P) ranges from 0.3 at Luquillo (Rio Mamayes) to 0.9 at Reynolds Creek (Reynolds Creek Outlet). Snow depth and SWE observations reveal that snowpack is an important seasonal storage reservoir at three sites: Boulder, Jemez, Reynolds Creek and Southern Sierra. Simple dynamical models are also used to infer seasonal patterns of subsurface catchment storage. A root-zone water balance model reveals unique seasonal variations in plant-available water storage. Seasonal patterns of plant-available storage are driven by the asynchronicity of seasonal precipitation and evaporation cycles. Catchment sensitivity functions are derived at each site to infer relative changes in hydraulic storage (the apparent storage reservoir responsible for modulating streamflow

Fe-Ti-oxide textures and microstructures in shear zones from oceanic gabbros at Atlantis Bank, Southwest Indian Ridge

NASA Astrophysics Data System (ADS)

Till, Jessica; Morales, Luiz F. G.; Rybacki, Erik

2016-04-01

Ocean drilling expeditions at several oceanic core complexes formed at slow- and ultra-slow-spreading ridges have recovered cores containing numerous zones of oxide-rich gabbros containing ilmenite and magnetite. In these cores, high modal concentrations of Fe-Ti-oxides are systematically associated with high-temperature plastic deformation features in silicates. We present observations of Fe-Ti-oxide mineral structures and textural characteristics from a series of oxide-rich shear zones from Atlantis Bank (ODP Site 735B) on the Southwest Indian Ridge aimed at determining how oxide mineral abundances relate to strain localization. Fe-Ti-oxide minerals in undeformed oxide gabbros and in highly deformed samples from natural shear zones generally have morphologies characteristic of crystallized melt, including highly cuspate grains and low dihedral angles. Anisotropy of magnetic susceptibility in oxide-rich shear zones is very strong, with fabrics mainly characterized by strong magnetic foliations parallel to the macroscopic foliation. Crystallographic preferred orientations (CPO) in magnetite are generally weak, with occasionally well-defined textures. Ilmenite typically displays well-developed CPOs, however, the melt-like ilmenite grain shapes indicate that at least part of the crystallographic texture results from oriented ilmenite growth during post-deformation crystallization. The oxides are hypothesized to have initially been present as isolated pockets of trapped melt (intercumulus liquid) in a load-bearing silicate framework. Progressive plastic deformation of silicate phases at high-temperature mainly produced two features: (i) elongated melt pockets, which crystallized to form strings of opaque minerals and (ii), interconnected networks of melt regions. The latter lead to intense strain localization of the rock, which appears as oxide-rich mylonites in the samples. In some samples, abundant low-angle grain boundaries in both magnetite and ilmenite suggest

How good strong union men line it out: explorations of the structure and dynamics of coal-miners' class consciousness

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yarrow, M.N.

1982-01-01

This study explores how working-class people apprehend and analyze the class dynamics of their social world. As an exploratory empirical study of the structure and dynamics of working-class consciousness, it seeks to develop the theory of actual class consciousness by bringing previous theories into dialogue with the articulated analyses of coal miners in central Appalachia. Although changing conditions are shown to have a powerful effect on class consciousness, the respondents were found to respond differently to the changing context and to remain loyal to important elements of their earlier perspectives. Suggestions are made for how the theory could be developedmore » further. The data for the study are flexibly structured interviews which were conducted with active, retired, and disabled miners in southern West Virginia and western Virginia. A dozen miners were interviewed during the 1978 strike and again the following summer; during the summer of 1978, nineteen additional miners were interviewed.« less

Effect of mineral additives on structure and properties of concrete for pavements

NASA Astrophysics Data System (ADS)

Sobol, Khrystyna; Markiv, Taras; Hunyak, Oleksii

2017-12-01

Concrete pavements is an attractive alternative to asphalt pavements because of its lower cost and higher durability. Major contribution to sustainable development can be made by partial replacement of cement in concrete pavement with supplementary cementitious materials of different nature and origin. In this paper, the effect of natural zeolite and perlite additives in complex with chemical admixtures on the structure and properties of concrete for pavement was studied. Compressive and flexural strength test was used to study the mechanical behavior of designed concrete under load. Generally, the compressive strength of both control concrete and concrete containing mineral additives levels at the later ages of hardening. The microstructure analysis of concrete with mineral additives of different nature activity showed the formation of additional amount of hydration products such as tobermorite type calcium hydrosilicate which provide self-reinforcement of hardening concrete system.

Regulated Production of Mineralization-competent Matrix Vesicles in Hypertrophic Chondrocytes

PubMed Central

Kirsch, Thorsten; Nah, Hyun-Duck; Shapiro, Irving M.; Pacifici, Maurizio

1997-01-01

Matrix vesicles have a critical role in the initiation of mineral deposition in skeletal tissues, but the ways in which they exert this key function remain poorly understood. This issue is made even more intriguing by the fact that matrix vesicles are also present in nonmineralizing tissues. Thus, we tested the novel hypothesis that matrix vesicles produced and released by mineralizing cells are structurally and functionally different from those released by nonmineralizing cells. To test this hypothesis, we made use of cultures of chick embryonic hypertrophic chondrocytes in which mineralization was triggered by treatment with vitamin C and phosphate. Ultrastructural analysis revealed that both control nonmineralizing and vitamin C/phosphatetreated mineralizing chondrocytes produced and released matrix vesicles that exhibited similar round shape, smooth contour, and average size. However, unlike control vesicles, those produced by mineralizing chondrocytes had very strong alkaline phosphatase activity and contained annexin V, a membrane-associated protein known to mediate Ca2+ influx into matrix vesicles. Strikingly, these vesicles also formed numerous apatite-like crystals upon incubation with synthetic cartilage lymph, while control vesicles failed to do so. Northern blot and immunohistochemical analyses showed that the production and release of annexin V-rich matrix vesicles by mineralizing chondrocytes were accompanied by a marked increase in annexin V expression and, interestingly, were followed by increased expression of type I collagen. Studies on embryonic cartilages demonstrated a similar sequence of phenotypic changes during the mineralization process in vivo. Thus, chondrocytes located in the hypertrophic zone of chick embryo tibial growth plate were characterized by strong annexin V expression, and those located at the chondro–osseous mineralizing border exhibited expression of both annexin V and type I collagen. These findings reveal that

Preservation of bone structure and function by Lithothamnion sp. derived minerals.

PubMed

Aslam, Muhammad Nadeem; Bergin, Ingrid; Jepsen, Karl; Kreider, Jaclynn M; Graf, Kristin H; Naik, Madhav; Goldstein, Steven A; Varani, James

2013-12-01

Progressive bone mineral loss and increasing bone fragility are hallmarks of osteoporosis. A combination of minerals isolated from the red marine algae, Lithothamnion sp. was examined for ability to inhibit bone mineral loss in female mice maintained on either a standard rodent chow (control) diet or a high-fat western diet (HFWD) for 5, 12, and 18 months. At each time point, femora were subjected to μ-CT analysis and biomechanical testing. A subset of caudal vertebrae was also analyzed. Following this, individual elements were assessed in bones. Serum levels of the 5b isoform of tartrate-resistant acid phosphatase (TRAP) and procollagen type I propeptide (P1NP) were also measured. Trabecular bone loss occurred in both diets (evident as early as 5 months). Cortical bone increased through month 5 and then declined. Cortical bone loss was primarily in mice on the HFWD. Inclusion of the minerals in the diet reduced bone mineral loss in both diets and improved bone strength. Bone mineral density was also enhanced by these minerals. Of several cationic minerals known to be important to bone health, only strontium was significantly increased in bone tissue from animals fed the mineral diets, but the increase was large (5-10 fold). Serum levels of TRAP were consistently higher in mice receiving the minerals, but levels of P1NP were not. These data suggest that trace minerals derived from marine red algae may be used to prevent progressive bone mineral loss in conjunction with calcium. Mineral supplementation could find use as part of an osteoporosis-prevention strategy.

Construction of Architectural Structures in Cultural Heritage Protection Zones

NASA Astrophysics Data System (ADS)

Zagroba, Marek; Gawryluk, Dorota

2017-10-01

The article raises issues of constructing contemporary architectural structures in cultural heritage protection zones, using the case study of a building located within the campus of the University of Warmia and Mazury in Olsztyn, Poland. Questions revolving around the construction of this building arise from the need to preserve the surrounding historic heritage, and deal with landscaping, architectural and construction solutions as well as interior design. All these problems grow in importance when dealing with such unique buildings like the discussed example of a laboratory building for the Civil Engineering Department, built on a site within a conservation zone of the university campus. The specific character of the building and the specialist equipment with which it was to be furnished (a resistance testing machine, a 17-meter-long wave flume) necessitated a series of analyses. In turn, the fact that the new building was to be erected in the conservation zone meant that collaboration with the Heritage Conservation Office had to be undertaken at the stage of making the plan and continued during the construction works. The Heritage Officer’s recommendations concerning the building’s shape, divisions, dimensions, materials used, etc., created a situation where the team of designers and architects had to become engaged in the process of landscape and spatial management. The above requirements concerned the functions of the building and its siting on a land parcel that was difficult to handle, also because of the protected trees growing there. Other constraints included the small size of this site, the developed surroundings, and the pre-defined programme of functions and use of the new building. All the above circumstances made the task difficult and demanded good coordination between individual teams of engineers and architects, both at the stage of making the plan and during the construction works. Many of the heritage protection zones are spoilt with

Exposure of zebra mussels to extracorporeal shock waves demonstrates formation of new mineralized tissue inside and outside the focus zone.

PubMed

Sternecker, Katharina; Geist, Juergen; Beggel, Sebastian; Dietz-Laursonn, Kristin; de la Fuente, Matias; Frank, Hans-Georg; Furia, John P; Milz, Stefan; Schmitz, Christoph

2018-04-03

The success rate of extracorporeal shock wave therapy (ESWT) for fracture nonunions in human medicine (i.e., radiographic union at six months after ESWT) is only approximately 75%. Detailed knowledge regarding the underlying mechanisms that induce bio-calcification after ESWT is limited. We analyzed the biological response within mineralized tissue of a new invertebrate model organism, the zebra mussel Dreissena polymorpha , after exposure with extracorporeal shock waves (ESWs). Mussels were exposed to ESWs with positive energy density of 0.4 mJ/mm 2 (A) or were sham exposed (B). Detection of newly calcified tissue was performed by exposing the mussels to fluorescent markers. Two weeks later, the A-mussels showed a higher mean fluorescence signal intensity within the shell zone than the B-mussels (p<0.05). Acoustic measurements revealed that the increased mean fluorescence signal intensity within the shell of the A-mussels was independent of the size and position of the focal point of the ESWs. These data demonstrate that induction of bio-calcification after ESWT may not be restricted to the region of direct energy transfer of ESWs into calcified tissue. The results of the present study are of relevance for better understanding of the molecular and cellular mechanisms that induce formation of new mineralized tissue after ESWT. © 2018. Published by The Company of Biologists Ltd.

Clay minerals and metal oxides strongly influence the structure of alkane-degrading microbial communities during soil maturation.

PubMed

Steinbach, Annelie; Schulz, Stefanie; Giebler, Julia; Schulz, Stephan; Pronk, Geertje J; Kögel-Knabner, Ingrid; Harms, Hauke; Wick, Lukas Y; Schloter, Michael

2015-07-01

Clay minerals, charcoal and metal oxides are essential parts of the soil matrix and strongly influence the formation of biogeochemical interfaces in soil. We investigated the role of these parental materials for the development of functional microbial guilds using the example of alkane-degrading bacteria harbouring the alkane monooxygenase gene (alkB) in artificial mixtures composed of different minerals and charcoal, sterile manure and a microbial inoculum extracted from an agricultural soil. We followed changes in abundance and community structure of alkane-degrading microbial communities after 3 and 12 months of soil maturation and in response to a subsequent 2-week plant litter addition. During maturation we observed an overall increasing divergence in community composition. The impact of metal oxides on alkane-degrading community structure increased during soil maturation, whereas the charcoal impact decreased from 3 to 12 months. Among the clay minerals illite influenced the community structure of alkB-harbouring bacteria significantly, but not montmorillonite. The litter application induced strong community shifts in soils, maturated for 12 months, towards functional guilds typical for younger maturation stages pointing to a resilience of the alkane-degradation function potentially fostered by an extant 'seed bank'.

Clay minerals and metal oxides strongly influence the structure of alkane-degrading microbial communities during soil maturation

PubMed Central

Steinbach, Annelie; Schulz, Stefanie; Giebler, Julia; Schulz, Stephan; Pronk, Geertje J; Kögel-Knabner, Ingrid; Harms, Hauke; Wick, Lukas Y; Schloter, Michael

2015-01-01

Clay minerals, charcoal and metal oxides are essential parts of the soil matrix and strongly influence the formation of biogeochemical interfaces in soil. We investigated the role of these parental materials for the development of functional microbial guilds using the example of alkane-degrading bacteria harbouring the alkane monooxygenase gene (alkB) in artificial mixtures composed of different minerals and charcoal, sterile manure and a microbial inoculum extracted from an agricultural soil. We followed changes in abundance and community structure of alkane-degrading microbial communities after 3 and 12 months of soil maturation and in response to a subsequent 2-week plant litter addition. During maturation we observed an overall increasing divergence in community composition. The impact of metal oxides on alkane-degrading community structure increased during soil maturation, whereas the charcoal impact decreased from 3 to 12 months. Among the clay minerals illite influenced the community structure of alkB-harbouring bacteria significantly, but not montmorillonite. The litter application induced strong community shifts in soils, maturated for 12 months, towards functional guilds typical for younger maturation stages pointing to a resilience of the alkane-degradation function potentially fostered by an extant ‘seed bank'. PMID:25535940

Liquid crystal-based Mueller matrix spectral imaging polarimetry for parameterizing mineral structural organization.

PubMed

Gladish, James C; Duncan, Donald D

2017-01-20

Herein, we discuss the remote assessment of the subwavelength organizational structure of a medium. Specifically, we use spectral imaging polarimetry, as the vector nature of polarized light enables it to interact with optical anisotropies within a medium, while the spectral aspect of polarization is sensitive to small-scale structure. The ability to image these effects allows for inference of spatial structural organization parameters. This work describes a methodology for revealing structural organization by exploiting the Stokes/Mueller formalism and by utilizing measurements from a spectral imaging polarimeter constructed from liquid crystal variable retarders and a liquid crystal tunable filter. We provide results to validate the system and then show results from measurements on a mineral sample.

Modular prediction of protein structural classes from sequences of twilight-zone identity with predicting sequences.

PubMed

Mizianty, Marcin J; Kurgan, Lukasz

2009-12-13

Knowledge of structural class is used by numerous methods for identification of structural/functional characteristics of proteins and could be used for the detection of remote homologues, particularly for chains that share twilight-zone similarity. In contrast to existing sequence-based structural class predictors, which target four major classes and which are designed for high identity sequences, we predict seven classes from sequences that share twilight-zone identity with the training sequences. The proposed MODular Approach to Structural class prediction (MODAS) method is unique as it allows for selection of any subset of the classes. MODAS is also the first to utilize a novel, custom-built feature-based sequence representation that combines evolutionary profiles and predicted secondary structure. The features quantify information relevant to the definition of the classes including conservation of residues and arrangement and number of helix/strand segments. Our comprehensive design considers 8 feature selection methods and 4 classifiers to develop Support Vector Machine-based classifiers that are tailored for each of the seven classes. Tests on 5 twilight-zone and 1 high-similarity benchmark datasets and comparison with over two dozens of modern competing predictors show that MODAS provides the best overall accuracy that ranges between 80% and 96.7% (83.5% for the twilight-zone datasets), depending on the dataset. This translates into 19% and 8% error rate reduction when compared against the best performing competing method on two largest datasets. The proposed predictor provides accurate predictions at 58% accuracy for membrane proteins class, which is not considered by majority of existing methods, in spite that this class accounts for only 2% of the data. Our predictive model is analyzed to demonstrate how and why the input features are associated with the corresponding classes. The improved predictions stem from the novel features that express collocation

Modular prediction of protein structural classes from sequences of twilight-zone identity with predicting sequences

PubMed Central

2009-01-01

Background Knowledge of structural class is used by numerous methods for identification of structural/functional characteristics of proteins and could be used for the detection of remote homologues, particularly for chains that share twilight-zone similarity. In contrast to existing sequence-based structural class predictors, which target four major classes and which are designed for high identity sequences, we predict seven classes from sequences that share twilight-zone identity with the training sequences. Results The proposed MODular Approach to Structural class prediction (MODAS) method is unique as it allows for selection of any subset of the classes. MODAS is also the first to utilize a novel, custom-built feature-based sequence representation that combines evolutionary profiles and predicted secondary structure. The features quantify information relevant to the definition of the classes including conservation of residues and arrangement and number of helix/strand segments. Our comprehensive design considers 8 feature selection methods and 4 classifiers to develop Support Vector Machine-based classifiers that are tailored for each of the seven classes. Tests on 5 twilight-zone and 1 high-similarity benchmark datasets and comparison with over two dozens of modern competing predictors show that MODAS provides the best overall accuracy that ranges between 80% and 96.7% (83.5% for the twilight-zone datasets), depending on the dataset. This translates into 19% and 8% error rate reduction when compared against the best performing competing method on two largest datasets. The proposed predictor provides accurate predictions at 58% accuracy for membrane proteins class, which is not considered by majority of existing methods, in spite that this class accounts for only 2% of the data. Our predictive model is analyzed to demonstrate how and why the input features are associated with the corresponding classes. Conclusions The improved predictions stem from the novel

Fault zone hydrogeology

NASA Astrophysics Data System (ADS)

Bense, V. F.; Gleeson, T.; Loveless, S. E.; Bour, O.; Scibek, J.

2013-12-01

Deformation along faults in the shallow crust (< 1 km) introduces permeability heterogeneity and anisotropy, which has an important impact on processes such as regional groundwater flow, hydrocarbon migration, and hydrothermal fluid circulation. Fault zones have the capacity to be hydraulic conduits connecting shallow and deep geological environments, but simultaneously the fault cores of many faults often form effective barriers to flow. The direct evaluation of the impact of faults to fluid flow patterns remains a challenge and requires a multidisciplinary research effort of structural geologists and hydrogeologists. However, we find that these disciplines often use different methods with little interaction between them. In this review, we document the current multi-disciplinary understanding of fault zone hydrogeology. We discuss surface- and subsurface observations from diverse rock types from unlithified and lithified clastic sediments through to carbonate, crystalline, and volcanic rocks. For each rock type, we evaluate geological deformation mechanisms, hydrogeologic observations and conceptual models of fault zone hydrogeology. Outcrop observations indicate that fault zones commonly have a permeability structure suggesting they should act as complex conduit-barrier systems in which along-fault flow is encouraged and across-fault flow is impeded. Hydrogeological observations of fault zones reported in the literature show a broad qualitative agreement with outcrop-based conceptual models of fault zone hydrogeology. Nevertheless, the specific impact of a particular fault permeability structure on fault zone hydrogeology can only be assessed when the hydrogeological context of the fault zone is considered and not from outcrop observations alone. To gain a more integrated, comprehensive understanding of fault zone hydrogeology, we foresee numerous synergistic opportunities and challenges for the discipline of structural geology and hydrogeology to co-evolve and

Mineral commodity summaries 2017

USGS Publications Warehouse

Ober, Joyce A.

2017-01-31

This report is the earliest Government publication to furnish estimates covering 2016 nonfuel mineral industry data. Data sheets contain information on the domestic industry structure, Government programs, tariffs, and 5-year salient statistics for more than 90 individual minerals and materials.

Predicting structures in the Zone of Avoidance

NASA Astrophysics Data System (ADS)

Sorce, Jenny G.; Colless, Matthew; Kraan-Korteweg, Renée C.; Gottlöber, Stefan

2017-11-01

The Zone of Avoidance (ZOA), whose emptiness is an artefact of our Galaxy dust, has been challenging observers as well as theorists for many years. Multiple attempts have been made on the observational side to map this region in order to better understand the local flows. On the theoretical side, however, this region is often simply statistically populated with structures but no real attempt has been made to confront theoretical and observed matter distributions. This paper takes a step forward using constrained realizations (CRs) of the local Universe shown to be perfect substitutes of local Universe-like simulations for smoothed high-density peak studies. Far from generating completely `random' structures in the ZOA, the reconstruction technique arranges matter according to the surrounding environment of this region. More precisely, the mean distributions of structures in a series of constrained and random realizations (RRs) differ: while densities annihilate each other when averaging over 200 RRs, structures persist when summing 200 CRs. The probability distribution function of ZOA grid cells to be highly overdense is a Gaussian with a 15 per cent mean in the random case, while that of the constrained case exhibits large tails. This implies that areas with the largest probabilities host most likely a structure. Comparisons between these predictions and observations, like those of the Puppis 3 cluster, show a remarkable agreement and allow us to assert the presence of the, recently highlighted by observations, Vela supercluster at about 180 h-1 Mpc, right behind the thickest dust layers of our Galaxy.

Application of Concentration-Number and Concentration-Volume Fractal Models to Recognize Mineralized Zones in North Anomaly Iron Ore Deposit, Central Iran / Zastosowanie Modeli Fraktalnych Typu K-L (Koncentracja-Liczba), Oraz K-O (Koncentracja Objętość) Do Rozpoznawania Stref Występowania Surowców Mineralnych W Regionie Złóż Rud Żelaza North Anomaly, W Środkowym Iranie

NASA Astrophysics Data System (ADS)

Afzal, Peyman; Ghasempour, Reza; Mokhtari, Ahmad Reza; Haroni, Hooshang Asadi

2015-09-01

Identification of various mineralized zones in an ore deposit is essential for mine planning and design. This study aims to distinguish the different mineralized zones and the wall rock in the Central block of North Anomaly iron ore deposit situated in Bafq (Central Iran) utilizing the concentration-number (C-N) and concentration-volume (C-V) fractal models. The C-N model indicates four mineralized zones described by Fe thresholds of 8%, 21%, and 50%, with zones <8% and >50% Fe representing wall rocks and highly mineralized zone, respectively. The C-V model reveals geochemical zones defined by Fe thresholds of 12%, 21%, 43% and 57%, with zones <12% Fe demonstrating wall rocks. Both the C-N and C-V models show that highly mineralized zones are situated in the central and western parts of the ore deposit. The results of validation of the fractal models with the geological model show that the C-N fractal model of highly mineralized zones is better than the C-V fractal model of highly mineralized zones based on logratio matrix. Identyfikacja stref występowania surowców mineralnych jest kwestia kluczową przy planowaniu wydobycia i projektowaniu kopalni. Celem pracy jest rozróżnienie stref o różnej zawartości surowców mineralnych oraz pasma skalnego w środkowej części zagłębia Bafq (środkowa cześć Iranu) przy wykorzystaniu modeli fraktalnych typu koncentracja-liczba i koncentracja-objętość. Model koncentracja-liczba pozwala na wyróżnienie czterech stref występowania surowca, definiowanych poprzez progową zawartość żelaza w rudzie na poziomie 8%, 21%, i 50% oraz strefy <8% i >50% zawartości żelaza, co odpowiada pasmu skalnemu oraz strefie o wysokim stopniu zawartości rudy. Model koncentracja-objętość wskazuje na istnienie stref geochemicznych określonych poprzez progowe wartości zawartości żelaza: 12%, 21%, 43% i 57 % oraz strefy <12%, co odpowiada ścianie skalnej. Obydwa modele stwierdzają obecność stref o wysokim stopniu zawarto

Mineral, Virginia earthquake illustrates seismicity of a passive-aggressive margin

NASA Astrophysics Data System (ADS)

Stein, S. A.; Pazzaglia, F. J.; Meltzer, A.; Berti, C.; Wolin, E.; Kafka, A. L.

2011-12-01

The August 2011 M5.8 Virginia earthquake illustrated again that "passive" continental margins, at which the continent and neighboring seafloor are part of the same plate, are often seismically active. This phenomenon occurs worldwide, with the east coast of North America a prime example. Examples from North to South include the 1933 M 7.3 Baffin Bay, 1929 M 7.2 Grand Banks of Newfoundland, 1755 M 6 Cape Ann, Massachusetts, and 1886 M 7 Charleston earthquakes. The mechanics of these earthquakes remains unclear. Their overall alignment along the margin suggests that they reflect reactivation of generally margin-parallel faults remaining from continental convergence and later rifting by the modern stress field. This view accords with the occurrence of the Virginia earthquake by reverse faulting on a margin-parallel NE-SW striking fault. However, it occurred on the northern edge of the central Virginia seismic zone, a seismic trend normal to the fault plane, margin, and associated structures, that has no clear geologic expression. Hence it is unclear why this and similar seismic zones have the geometry they do. Although it is tempting to correlate these zones with extensions of Atlantic fracture zones, this correlation has little explanatory power given the large number of such zones. It is similarly unclear whether these zones and the intervening seismic gaps reflect areas that are relatively more active over time, or are instead the present loci of activity that migrates. It is also possible that the presently-active zones reflect long-lived aftershocks of large prehistoric earthquakes. The forces driving the seismicity are also unclear. In general, seismic moment release decreases southward along the margin, consistent with the variation in vertical motion rates observed by GPS, suggesting that glacial-isostatic adjustment (GIA) provides some of the stresses involved. However, in the mid-Atlantic region - south of the area of significant GIA - deformed stratigraphic

30 CFR 285.647 - How will my GAP be processed for Federal consistency under the Coastal Zone Management Act?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 2 2011-07-01 2011-07-01 false How will my GAP be processed for Federal consistency under the Coastal Zone Management Act? 285.647 Section 285.647 Mineral Resources BUREAU OF OCEAN... under the Coastal Zone Management Act? Your GAP will be processed based on how your limited lease, ROW...

Slab stagnation and buckling in the mantle transition zone: Rheology, phase transition, trench migration, and seismic structure

NASA Astrophysics Data System (ADS)

Bina, Craig; Cizkova, Hana

2014-05-01

Subducting slabs may exhibit buckling instabilities and consequent folding behavior in the mantle transition zone for various combinations of dynamical parameters, accompanied by temporal variations in dip angle, plate velocity, and trench retreat. Parameters governing such behavior include both viscous forces (slab and mantle rheology) and buoyancy forces (slab thermal structure and mineral phase relations). 2D numerical experiments show that many parameter sets lead to slab deflection at the base of the transition zone, typically accompanied by quasi-periodic oscillations (consistent with previous scaling analyses) in largely anticorrelated plate and rollback velocities, resulting in undulating stagnant slabs as buckle folds accumulate subhorizontally atop the lower mantle. Slab interactions with mantle phase transitions are important components of this process (Bina and Kawakatsu, 2010; Čížková and Bina, 2013). For terrestrial parameter sets, trench retreat is found to be nearly ubiquitous, and trench advance is quite rare - due to both rheological structure and ridge-push effects (Čížková and Bina, 2013). Recent analyses of global plate motions indicate that significant trench advance is also rare on Earth, being largely restricted to the Izu-Bonin arc (Matthews et al., 2013). Consequently, we explore the conditions necessary for terrestrial trench advance through dynamical models involving the unusual geometry associated with the Philippine Sea region. Detailed images of buckled stagnant slabs are difficult to resolve due to smoothing effects inherent in seismic tomography, but velocity structures computed for compositionally layered slabs, using laboratory data on relevant mineral assemblages, can be spatially low-pass filtered for comparison with tomographic images of corresponding resolution. When applied to P-wave velocity anomalies from stagnant slab material beneath northeast China, model slabs which undulate due to compound buckling fit

Indirect estimation of the tectonic evolution of magnetic structures along the Indiavaí-Lucialva Shear Zone, Mato Grosso, Brazil

NASA Astrophysics Data System (ADS)

Louro, V. H.; Ribeiro, V. B.; Mantovani, M. S.; Geolit Team

2013-05-01

The Indiavaí-Lucialva Shear Zone (ILSZ) has a notorious cinematic standard, moving from SW to NE, juxtaposing the Santa Helena Granitic Batholith to the metavolcanosedimentary sets and orthogneisses from the Jauru Domain basement. Along the ILSZ, a sequence of magnetic anomalies of high interference, with each other, and varied polarities occurs, what suggests the presence of different lithologies or times of (re)crystallization of the ferromagnetic minerals from these magnetic structures. In its southernmost portion, the sequence of magnetic anomalies splits in two directions, SW and SE, with the first invading the limits of the Santa Helena batholith and, the latest, accompanying the ILSZ. This study aimed for the comprehension of complex tectonic setting of this region. It analyzed the set of anomalies estimating their lateral limits, depths and directions of total magnetization, with the Enhanced Horizontal Derivatives (EHD), its extrapolation for depth estimative (EHD-Depth), and through an iterative reduction to the magnetic pole, respectively. This procedure allowed the composition of initial models for further inversions of magnetic data which, results, indicate contrasts of magnetic susceptibility in sub-surface. Once known the approximated 3-D shape of the magnetic structures along the ILSZ, the total magnetization intensity of each anomaly was recovered, what consequently allowed, by vector subtraction, to estimate their individual remnant magnetization. The remnant magnetization's inclinations and declinations of the anomalies sources and their latitudes and longitudes permitted the calculus of their respective virtual magnetic paleopoles. When confronted with the South American paleopole wander path and the datings linked to this path, available in the literature, it was possible to have an indirect approximation of the age of (re)crystallization of each magnetic structure near the ILSZ. This procedure indicated an increasing of the ages of the

Seismic Moment and Recurrence using Luminescence Dating Techniques: Characterizing brittle fault zone materials suitable for luminescence dating

NASA Astrophysics Data System (ADS)

Tsakalos, E.; Lin, A.; Bassiakos, Y.; Kazantzaki, M.; Filippaki, E.

2017-12-01

During a seismic-geodynamic process, frictional heating and pressure are generated on sediments fragments resulting in deformation and alteration of minerals contained in them. The luminescence signal enclosed in minerals crystal lattice can be affected and even zeroed during such an event. This has been breakthrough in geochronological studies as it could be utilized as a chronometer for the previous seismic activity of a tectonically active area. Although the employment of luminescence dating has in some cases been successfully described, a comprehensive study outlining and defining protocols for routine luminescence dating applied to neotectonic studies has not been forthcoming. This study is the experimental investigation, recording and parameterization of the effects of tectonic phenomena on minerals luminescence signal and the development of detailed protocols for the standardization of the luminescence methodology for directly dating deformed geological formations, so that the long-term temporal behaviour of seismically active faults could be reasonably understood and modeled. This will be achieved by: a) identifying and proposing brittle fault zone materials suitable for luminescence dating using petrological, mineralogical and chemical analyses and b) investigating the "zeroing" potential of the luminescence signal of minerals contained in fault zone materials by employing experimental simulations of tectonic processes in the laboratory, combined with luminescence measurements on samples collected from real fault zones. For this to be achieved, a number of samples collected from four faults of four different geographical regions will be used. This preliminary-first step of the study presents the microstructural, and mineralogical analyses for the characterization of brittle fault zone materials that contain suitable minerals for luminescence dating (e.g., quartz and feldspar). The results showed that the collected samples are seismically deformed fault

Mantle transition zone thinning beneath eastern Africa: Evidence for a whole-mantle superplume structure

NASA Astrophysics Data System (ADS)

Mulibo, Gabriel D.; Nyblade, Andrew A.

2013-07-01

to S conversions from the 410 and 660 km discontinuities observed in receiver function stacks reveal a mantle transition zone that is ~30-40 km thinner than the global average in a region ~200-400 km wide extending in a SW-NE direction from central Zambia, across Tanzania and into Kenya. The thinning of the transition zone indicates a ~190-300 K thermal anomaly in the same location where seismic tomography models suggest that the lower mantle African superplume structure connects to thermally perturbed upper mantle beneath eastern Africa. This finding provides compelling evidence for the existence of a continuous thermal structure extending from the core-mantle boundary to the surface associated with the African superplume.

The Dual Role of Vegetation as a Constraint on Mass and Energy Flux into the Critical Zone and as an Emergent Property of Geophysical Critical Zone Structure

NASA Astrophysics Data System (ADS)

Brooks, P. D.; Swetnam, T. L.; Barnard, H. R.; Singha, K.; Harpold, A.; Litvak, M. E.

2017-12-01

Spatial patterns in vegetation long have been used to scale both landsurface-atmosphere exchanges of water and carbon as well as to infer subsurface structure. These pursuits typical proceed in isolation and rarely do inferences gained from one community propagate to related efforts in another. Perhaps more importantly, vegetation often is treated as an emergent property of landscape-climate interactions rather than an active modifier of both critical zone structure and energy fluxes. We posit that vegetation structure and activity are under utilized as a tool towards understanding landscape evolution and present examples that begin to disentangle the role of vegetation as both an emergent property and an active control on critical zone structure and function. As climate change, population growth, and land use changes threaten water resources worldwide, the need for the new insights vegetation can provide becomes not just a basic science priority, but a pressing applied science question with clear societal importance. This presentation will provide an overview of recent efforts to address the dual role of vegetation in both modifying and reflecting critical zone structure in the western North American forests. For example, interactions between topography and stand scale vegetation structure influence both solar radiation and turbulence altering landscape scale partitioning of evaporation vs transpiration with major impacts of surface water supply. Similarly, interactions between topographic shading, lateral redistribution of plant available water, and subsurface storage create a mosaic of drought resistance and resilience across complex terrain. These complex interactions between geophysical and vegetation components of critical zone structure result in predictable patterns in catchment scale hydrologic partitioning within individual watersheds while simultaneously suggesting testable hypotheses for why catchments under similar climate regimes respond so

Shock effects on hydrous minerals and implications for carbonaceous meteorites

NASA Technical Reports Server (NTRS)

Lange, M. A.; Ahrens, T. J.; Lambert, P.

1985-01-01

The effect of shock loading over the pressure range of 29-59 GPa on the shock-recovered specimens of antigorite serpentine, Mg3Si2O5(OH)4, were investigated employing infrared (IR) spectroscopy, thermogravimetric analysis, and optical and scanning electron microscopy. With increasing shock pressure, there was an increase in H2O IR absorption peaks at the expense of OH peaks, while the changes in SiO bond vibration modes were identical to those seen for other, nonhydrous minerals. Thermogravimetric results on vented assembly samples showed linear relationships between the shock pressure and both the length of dehydration interval and the effective activation energy for releasing post-shock structural water. Optical and scanning electron microscopy revealed gas bubbles, which appeared to be injected into zones of partial melting, and vesicular dark veins distributed throughout the shocked samples. It is suggested that shock loading of hydrous minerals would release and redistribute free water in the regoliths of carbonaceous chondrite parent bodies, giving rise to observed hydrous alterations.

Global seismic data reveal little water in the mantle transition zone

NASA Astrophysics Data System (ADS)

Houser, C.

2016-08-01

Knowledge of the Earth's present water content is necessary to constrain the amount of water and other volatiles the Earth acquired during its formation and the amount that is cycled back into the interior from the surface. This study compares 410 and 660 km discontinuity depth with shear wave tomography within the mantle transition zone to identify regions with seismic signals consistent with water. The depth of the 410 and 660 km discontinuities is determined from a large updated dataset of SS-S410S and SS-S660S differential travel times, known as SS precursors. The discontinuity depths measured from binning and stacking the SS precursor data are then compared to the shear velocity model HMSL-S06 in the transition zone. Mapping all the possible combinations, very few locations match the predictions from mineral physics for the effects of water on discontinuity depth and shear velocity. The predictions, although not yet measured at actual transition zone temperatures and pressures, are a shallow 410 km discontinuity, a deep 660 km discontinuity, and a slow shear velocity. Only 8% of the bins with high-quality data are consistent with these predictions, and the calculated average water content within these bins is around 0.6 wt.%. A few isolated locations have patterns of velocity/topography that are consistent with water, while there are large regional-scale patterns consistent with cold/hot temperature anomalies. Combining this global analysis of long period seismic data and the current mineral physics predictions for water in transition zone minerals, I find that the mantle transition zone is generally dry, containing less than one Earth ocean of water. Although subduction zones could be locally hydrated, the combined discontinuity and velocity data show no evidence that wadsleyite or ringwoodite have been globally hydrated by subduction or initial Earth conditions.

Geology of the Göçükdibi Cu-Pb-Zn Mineralization, Gökçedoǧan, Çorum (Turkey): Preliminary Findings on Its Formation

NASA Astrophysics Data System (ADS)

Yalçin, Cihan; Hanilçi, Nurullah; Kumral, Mustafa; Abdelnasser, Amr

2016-04-01

Göçükdibi Cu-Pb-Zn mineralization is located 3 km north west of Gökçedoǧan village where is 30 km east of the Kargı, Çorum. The geology of the mineralization area is represented by Mesozoic and Upper Pliocene lithostratigraphic units in different origin. These units with respect to their structural locations have identified as autochthonous and allachtonous. The autochthonous units which are the basement of the region are represented by Bekirli Metamorphites (Triassic-Liassic) and Beşpınar formation (Upper Cretaceous-Lower Eocene) which overlies the Bekirli Metamorphites as angular discordance. The allachtonous units are represented by Saraycık formation belongs to Kargı Ophioltic Melange, and located on the autochthonous units as tectonically. These allocthonous units are the product of the Neotethyan Ocean. The autochthonous and allachtonous units are overlaid by Upper Pliocene Ilgaz Formation and Plio-Quaternary stream sediments. The Cu-Pb-Zn mineralization is located in northwest of the Gökçedoǧan village within the Bekirli Metamorphites. The ore zone has N80E direction, 5 m wide and 120 m in length. The mineralizations which follow NE-SW trending structural line occurred as alternation with quartz-chlorite schists of the Bekirli Metamorphites. The mineralization is generally concordant to the foliation of schist's and also occurred as disseminated in the wall rocks. The ore paragenesis comprises with pyrite, chalcopyrite, sphalerite and galenit as the main sulphide minerals, and the malachite, azurite and limonite as the production of the oxidation. Preliminary data such as relationship between the ore and host rock, inner-structure of the ore and indicate that the Gökçedoǧan Cu-Pb-Zn mineralization was likely to have originated syngenetic. In addition, the geochemical behaviour of rare earth elements (REE) of the altered and mineralized samples collected from the alteration zone show that light REE enrichment with fair depletion of heavy REE

Mineral formation and organo-mineral controls on the bioavailability of carbon at the terrestrial-aquatic interface

NASA Astrophysics Data System (ADS)

Rod, K. A.; Smith, A. P.; Renslow, R.

2016-12-01

Recent evidence highlights the importance of organo-mineral interactions in regulating the source or sink capacity of soil. High surface area soils, such as allophane-rich or clay-rich soils, retain organic matter (OM) via sorption to mineral surfaces which can also contribute physical isolation in interlayer spaces. Despite the direct correlation between mineral surfaces and OM accumulation, the pedogenic processes controlling the abundance of reactive surface areas and their distribution in the mineral matrix remains unclear. As global soil temperatures rise, the dissolution of primary minerals and formation of new secondary minerals may be thermodynamically favored as part of soil weathering process. Newly formed minerals can supply surfaces for organo-metallic bonding and may, therefore, stabilize OM by surface bonding and physical exclusion. This is especially relevant in environments that intersect terrestrial and aquatic systems, such as the capillary fringe zone in riparian ecosystems. To test the mechanisms of mineral surface area protection of OM, we facilitated secondary precipitation of alumino-silicates in the presence of OM held at two different temperatures in natural Nisqually River sediments (Mt Rainier, WA). This was a three month reaction intended to simulate early pedogenesis. To tease out the influence of mineral surface area increase during pedogenesis, we incubated the sediments at two different soil moisture contents to induce biodegradation. We measured OM desorption, biodegradation, and the molecular composition of mineral-associated OM both prior to and following the temperature manipulation. To simulate the saturation of capillary fringe sediment and associated transport and reaction of OM, column experiments were conducted using the reacted sediments. More co-precipitation was observed in the 20°C solution compared to the 4°C reacted solution suggesting that warming trends alter mineral development and may remove more OM from solution

Fine structure of the landers fault zone: Segmentation and the rupture process

USGS Publications Warehouse

Li, Y.-G.; Vidale, J.E.; Aki, K.; Marone, C.J.; Lee, W.H.K.

1994-01-01

Observations and modeling of 3- to 6-hertz seismic shear waves trapped within the fault zone of the 1992 Landers earthquake series allow the fine structure and continuity of the zone to be evaluated. The fault, to a depth of at least 12 kilometers, is marked by a zone 100 to 200 meters wide where shear velocity is reduced by 30 to 50 percent. This zone forms a seismic waveguide that extends along the southern 30 kilometers of the Landers rupture surface and ends at the fault bend about 18 kilometers north of the main shock epicenter. Another fault plane waveguide, disconnected from the first, exists along the northern rupture surface. These observations, in conjunction with surface slip, detailed seismicity patterns, and the progression of rupture along the fault, suggest that several simple rupture planes were involved in the Landers earthquake and that the inferred rupture front hesitated or slowed at the location where the rupture jumped from one to the next plane. Reduction in rupture velocity can tentatively be attributed to fault plane complexity, and variations in moment release can be attributed to variations in available energy.

Disturbed zones; indicators of deep-seated subsurface faults in the Valley and Ridge and Appalachian structural front of Pennsylvania

USGS Publications Warehouse

Pohn, Howard A.; Purdy, Terri L.

1982-01-01

Field studies of geologic structures in the Valley and Ridge and adjacent parts of the Appalachian Plateau provinces in Pennsylvania have shown a new type of structure, formerly poorly understood and frequently unmapped, is a significant indicator of deep-seated subsurface faulting. These structures, herein called disturbed zones, are formed by movement between closely spaced pairs of thrust faults. Disturbed zones are characterized at the surface by long, narrow, intensely folded and faulted zones of rocks in a relatively undisturbed stratigraphic sequence. These zones are frequently kilometers to tens of kilometers long and tens to hundreds of meters wide. Although disturbed zones generally occur in sequences of alternating siltstone and shale beds, they can also occur in other lithologies including massively-bedded sandstones and carbonates. Disturbed zones are not only easily recognized in outcrop but their presence can also be inferred on geologic maps by disharmonic fold patterns, which necessitates a detachment between adjacent units that show the disharmony. A number of geologic problems can be clarified by understanding the principles of the sequence of formation and the method of location of disturbed zones, including the interpretation of some published geologic cross sections and maps. The intense folding and faulting which accompanies the formation of a typical disturbed zone produces a region of fracture porosity which, if sealed off from the surface, might well serve as a commercially-exploitable hydrocarbon trap. We believe that the careful mapping of concentrations of disturbed zones can serve as an important exploration method which is much less expensive than speculation seismic lines.

Amphibious Shear Velocity Structure of the Cascadia Subduction Zone

NASA Astrophysics Data System (ADS)

Janiszewski, H. A.; Gaherty, J. B.; Abers, G. A.; Gao, H.

2017-12-01

The amphibious Cascadia Initiative crosses the coastline of the Cascadia subduction zone (CSZ) deploying seismometers from the Juan de Fuca ridge offshore to beyond the volcanic arc onshore. This allows unprecedented seismic imaging of the CSZ, enabling examination of both the evolution of the Juan de Fuca plate prior to and during subduction as well as the along strike variability of the subduction system. Here we present new results from an amphibious shear velocity model for the crust and upper mantle across the Cascadia subduction zone. The primary data used in this inversion are surface-wave phase velocities derived from ambient-noise Rayleigh-wave data in the 10 - 20 s period band, and teleseismic earthquake Rayleigh wave phase velocities in the 20 - 160 s period band. Phase velocity maps from these data reflect major tectonic structures including the transition from oceanic to continental lithosphere, Juan de Fuca lithosphere that is faster than observations in the Pacific for oceanic crust of its age, slow velocities associated with the accretionary prism, the front of the fast subducting slab, and the Cascades volcanic arc which is associated with slower velocities in the south than in the north. Crustal structures are constrained by receiver functions in the offshore forearc and onshore regions, and by active source constraints on the Juan de Fuca plate prior to subduction. The shear-wave velocities are interpreted in their relationships to temperature, presence of melt or hydrous alteration, and compositional variation of the CSZ.

Geologic map of the Kechumstuk fault zone in the Mount Veta area, Fortymile mining district, east-central Alaska

USGS Publications Warehouse

Day, Warren C.; O’Neill, J. Michael; Dusel-Bacon, Cynthia; Aleinikoff, John N.; Siron, Christopher R.

2014-01-01

This map was developed by the U.S. Geological Survey Mineral Resources Program to depict the fundamental geologic features for the western part of the Fortymile mining district of east-central Alaska, and to delineate the location of known bedrock mineral prospects and their relationship to rock types and structural features. This geospatial map database presents a 1:63,360-scale geologic map for the Kechumstuk fault zone and surrounding area, which lies 55 km northwest of Chicken, Alaska. The Kechumstuk fault zone is a northeast-trending zone of faults that transects the crystalline basement rocks of the Yukon-Tanana Upland of the western part of the Fortymile mining district. The crystalline basement rocks include Paleozoic metasedimentary and metaigneous rocks as well as granitoid intrusions of Triassic, Jurassic, and Cretaceous age. The geologic units represented by polygons in this dataset are based on new geologic mapping and geochronological data coupled with an interpretation of regional and new geophysical data collected by the Alaska Department of Natural Resources, Division of Geological and Geophysical Surveys. The geochronological data are reported in the accompanying geologic map text and represent new U-Pb dates on zircons collected from the igneous and metaigneous units within the map area.

Alteration geochemistry of the volcanic-hosted Dedeninyurdu, Yergen and Fındıklıyar Fe-Cu mineralization at Gökçedoǧan, Çorum-Kargi region, Turkey

NASA Astrophysics Data System (ADS)

Gumus, Lokman; Öztürk, Sercan; Yalçın, Cihan; Abdelnasser, Amr; Hanilçi, Nurullah; Kumral, Mustafa

2016-04-01

This study is to determine the mass/volume gain and loss of the major and trace elements during the alteration processes on Dedeninyurdu, Yergen and Fındıklıyar Fe-Cu mineralizations of the area. Fe-Cu mineralization occurred in the spilitic volcanic a rock of Saraycık Formation is associated with the different types of alteration zones which are pyritization, silicification and sericitization. The study area comprises Bekirli Formation, Saraycık Formation, Beşpınar Formation, and Ilgaz Formation. Saraycık formation consists of spilitic volcanic rocks with pelagic limestone, siltstone and chert. The ore mineralogical data show that the pyrite, chalcopyrite, covellite, hematite, malachite and goethite formed during three phases of mineralization. As well as the geologic and petrographic studies reveal three alteration zones with definite mineral assemblages; phyllic alteration (quartz + sericite + pyrite) that represents the main alteration and mineralized zone; propylitic alteration; and carbonatized sericitic alteration zone. The boundaries between these zones are gradual. Mass balance calculations suggested that the phyllic alteration zone represented by gain in Si, Fe, K, S, and LOI and loss in Mg, Ca, and Na refers to silicification, sericitization and pyritization as well as replacement of Fe-Mg silicate and plagioclase. While, in the propylitic alteration zone, enrichment of Si, Fe, Mg, LOI and S occurred with depletions of Ca, Na, and K reflecting chloritization alteration type. On the other hand, carbonatized sericitic alteration zone shows local gain in Si, CaO and K reflects the occurrence of calc-silicate alteration. All alteration zones contain a large proportion of sulfide minerals (gain in S) with increase in loss on ignition (LOI). Keywords: Alteration geochemistry; Mass balance calculation, Fe-Cu mineralization; phyllic alteration, propylitic alteration.

Responses of infaunal populations to benthoscape structure and the potential importance of transition zones

USGS Publications Warehouse

Zajac, R.N.; Lewis, R.S.; Poppe, L.J.; Twichell, D.C.; Vozarik, J.; DiGiacomo-Cohen, M. L.

2003-01-01

Relationships between population abundance and seafloor landscape, or benthoscape, structure were examined for 16 infaunal taxa in eastern Long Island Sound. Based on analyses of a side-scan sonar mosaic, the 19.4-km2 study area was comprised of six distinct large-scale (> km2) benthoscape elements, with varying levels of mesoscale (km2-m2) and small-scale (2) physical and biological habitat heterogeneity. Transition zones among elements varied from ~50 to 200 m in width, comprised ~32% of the benthoscape, and added to overall benthoscape heterogeneity. Population abundances of nine taxa varied significantly among the large-scale elements. Most species were found at high abundances only in one benthoscape element, but three had several foci of elevated abundances. Analyses of population responses to habitat heterogeneity at different spatial scales indicated that abundances of eight taxa varied significantly among spatial scales, but the significant scales were mixed among these species. Relatively large residual variations suggest significant amounts of mesoscale spatial variation were unaccounted for, varying from ~1 km2 to several m2. Responses to transition zones were mixed as well. Abundances of nine taxa varied significantly among transition zones and interiors of benthoscape elements, most with elevated abundances in transition zones. Our results show that infaunal populations exhibit complex and spatially varying patterns of abundance in relation to benthoscape structure and suggest that mesoscale variation may be particularly critical in this regard. Also, transition zones among benthoscape features add considerably to this variation and may be ecological important areas in seafloor environments.

Investigating point zero: The artificial catchment 'Chicken Creek' as an observatory to study critical zone structures and processes of the critical zone in an initial ecosystem

NASA Astrophysics Data System (ADS)

Hüttl, Reinhard F.; Gerwin, Werner

2010-05-01

Recently, earth surface structures reaching from vegetation to the groundwater in the near underground have been termed "critical zone". This zone is "critical" to supporting life on Earth and, thus, the understanding of processes within this zone is of great importance in environmental sciences. Investigating the critical zone requires interdisciplinary and integrative research approaches across the fields of geomorphology, ecology, biology, soil science, hydrology and environmental modeling. A central motivation of the critical zone concept is the need for moving beyond traditional disciplinary boundaries to a more holistic and integrated study of the Earth surface system. However, the critical zone is characterized by complex interactions between abiotic and biotic structures and processes which need to be analyzed for improving our understanding of ecosystem functioning as well as of ecosystem development. To gain a better understanding of these fundamental questions it might be helpful to look at initial ecosystems, i.e. at ecosystems in the initial phase of development. It can be hypothesized that the complexity of a very young ecosystem is lower compared to mature systems and, therefore, structure-process interactions might become more obvious at early than at later stages of development. In this context, an artificial watershed was constructed with well known boundary conditions to investigate the initial ecosystem phase. The catchment ‘Chicken Creek' in Lusatia (Germany; 150 km SE from Berlin) has an area of 6 ha. It was set up with a layer of post-glacial sandy sediments overlying an aquiclude made of clay at the base. These hydrological starting conditions allowed for the formation of a groundwater body within the sandy layer of the experimental catchment. Further, after completion of the construction works in September 2005 the site was left to natural succession and no measures like planting or fertilization were carried out. As the initial phase of

Multi-Scale Structure and Earthquake Properties in the San Jacinto Fault Zone Area

NASA Astrophysics Data System (ADS)

Ben-Zion, Y.

2014-12-01

I review multi-scale multi-signal seismological results on structure and earthquake properties within and around the San Jacinto Fault Zone (SJFZ) in southern California. The results are based on data of the southern California and ANZA networks covering scales from a few km to over 100 km, additional near-fault seismometers and linear arrays with instrument spacing 25-50 m that cross the SJFZ at several locations, and a dense rectangular array with >1100 vertical-component nodes separated by 10-30 m centered on the fault. The structural studies utilize earthquake data to image the seismogenic sections and ambient noise to image the shallower structures. The earthquake studies use waveform inversions and additional time domain and spectral methods. We observe pronounced damage regions with low seismic velocities and anomalous Vp/Vs ratios around the fault, and clear velocity contrasts across various sections. The damage zones and velocity contrasts produce fault zone trapped and head waves at various locations, along with time delays, anisotropy and other signals. The damage zones follow a flower-shape with depth; in places with velocity contrast they are offset to the stiffer side at depth as expected for bimaterial ruptures with persistent propagation direction. Analysis of PGV and PGA indicates clear persistent directivity at given fault sections and overall motion amplification within several km around the fault. Clear temporal changes of velocities, probably involving primarily the shallow material, are observed in response to seasonal, earthquake and other loadings. Full source tensor properties of M>4 earthquakes in the complex trifurcation area include statistically-robust small isotropic component, likely reflecting dynamic generation of rock damage in the source volumes. The dense fault zone instruments record seismic "noise" at frequencies >200 Hz that can be used for imaging and monitoring the shallow material with high space and time details, and

Biogeochemical control points in a water-limited critical zone

NASA Astrophysics Data System (ADS)

Chorover, J.; Brooks, P. D.; Gallery, R. E.; McIntosh, J. C.; Olshansky, Y.; Rasmussen, C.

2017-12-01

The routing of water and carbon through complex terrain is postulated to control structure evolution in the sub-humid critical zone of the southwestern US. By combining measurements of land-atmosphere exchange, ecohydrologic partitioning, and subsurface biogeochemistry, we seek to quantify how a heterogeneous (in time and space) distribution of "reactants" impacts both short-term (sub-)catchment response (e.g., pore and surface water chemical dynamics) and long-term landscape evolution (e.g., soil geochemistry/morphology and regolith weathering depth) in watersheds underlain by rhyolite and schist. Instrumented pedons in convergent, planar, and divergent landscape positions show distinct depth-dependent responses to precipitation events. Wetting front propagation, dissolved carbon flux and associated biogeochemical responses (e.g., pulses of CO2 production, O2 depletion, solute release) vary with topography, revealing the influence of lateral subsidies of water and carbon. The impacts of these episodes on the evolution of porous media heterogeneity is being investigated by statistical analysis of pore water chemistry, chemical/spectroscopic studies of solid phase organo-mineral products, sensor-derived water characteristic curves, and quantification of co-located microbial community activity/composition. Our results highlight the interacting effects of critical zone structure and convergent hydrologic flows in the evolution of biogeochemical control points.

Magnetotelluric survey to locate the Archean/Proterozoic suture zone north of Wells, Nevada

USGS Publications Warehouse

Williams, Jackie M.; Rodriguez, Brian D.

2006-01-01

It is important to know whether major mining districts in the Northern Nevada Gold Province are underlain by rocks of the Archean Wyoming craton, which are known to contain orogenic gold deposits, or by accreted rocks of the Paleoproterozoic Mojave province. It is also important to know the location and orientation of the Archean/Proterozoic suture zone between these provinces as well as major basement structures within these terranes because they may influence subsequent patterns of sedimentation, deformation, magmatism, and hydrothermal activity. The Archean was the main gold-mineralization period, and Archean lode-gold deposits were formed at mid-crustal depths along major shear zones. The nature of the crystalline basement below the Northern Nevada Gold Province and the location of major faults within it are relevant to Rodinian reconstructions, crustal development, and ore deposit models (e.g., Hofstra and Cline, 2000; Grauch and others, 2003). According to Whitmeyer and Karlstrom (2004), the Archean cratons of the northwestern United States and Canada had stabilized as continental lithosphere by 2.5 Ga, and were rifted and assembled into a large continental mass by 1.8 Ga, to which the 1.73-1.68 Ga Mohave province was accreted by 1.65 Ga. The Archean/Proterozoic suture zone has a west-southwest strike where it is exposed (Reed, 1993) at the eastern Utah and southwestern Wyoming border (Cheyenne Belt) where it is characterized by an up to 7-km-thick mylonite zone (Smithson and Boyd, 1998). In the Great Basin, the strike of the Archean/Proterozoic suture zone is poorly constrained because it is largely concealed below a Neoproterozoic-Paleozoic miogeocline and basin fill. East-west and southwest-northeast strikes for the Archean/Proterozoic suture zone have been inferred based on Sr, Nd, and Pb isotopic compositions of granitoid intrusions (Tosdal and others, 2000). To better constrain the location and strike of the Archean/Proterozoic suture zone below cover

Block Copolymer Directed Biomimetic Mineral Formation for Polymer Nanocomposites

NASA Astrophysics Data System (ADS)

Gleeson, Sarah; Yu, Tony; Chen, Xi; Marcolongo, Michele; Li, Christopher

Bone is a hierarchically structured biocomposite comprised of mineralized collagen fibrils. The mechanical properties of bone can be precisely tuned by the structure and morphology of the mineral nanocrystals as well as the organic collagen fibrils. Synthetic materials that can mimic the nanostructure of natural bone show promise to replicate bone's structural function, yet little is known about the mechanism of mineral formation. We previously have shown that hierarchically ordered polymer fibers control the distribution and orientation of hydroxyapatite, enhancing mechanical properties and biocompatibility. We demonstrate a new method for mineralization by forming block copolymer single crystal films of polycaprolactone-block-poly(acrylic acid) (PCL- b-PAA) so that lamellar anionic PAA nanodomains recruit mineral ions and provide one-dimensional confinement to induce orientation. The effect of the anionic domain dimensions on mineral content, orientation, and structure within the polymer matrix is shown. The mechanical properties of the nanocomposite are evaluated to determine the role of mineral orientation and crystallinity in composite strength. These results can be used to tailor the physical mineralization environment to create a more biomimetic bone material.

Chemical Bonding in Sulfide Minerals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vaughan, David J.; Rosso, Kevin M.

An understanding of chemical bonding and electronic structure in sulfide minerals is central to any attempt at understanding their crystal structures, stabilities and physical properties. It is also an essential precursor to understanding reactivity through modeling surface structure at the molecular scale. In recent decades, there have been remarkable advances in first principles (ab initio) methods for the quantitative calculation of electronic structure. These advances have been made possible by the very rapid development of high performance computers. Several review volumes that chart the applications of these developments in mineralogy and geochemistry are available (Tossell and Vaughan, 1992; Cygan andmore » Kubicki, 2001). An important feature of the sulfide minerals is the diversity of their electronic structures, as evidenced by their electrical and magnetic properties (see Pearce et al. 2006, this volume). Thus, sulfide minerals range from insulators through semiconductors to metals, and exhibit every type of magnetic behavior. This has presented problems for those attempting to develop bonding models for sulfides, and also led to certain misconceptions regarding the kinds of models that may be appropriate. In this chapter, chemical bonding and electronic structure models for sulfides are reviewed with emphasis on more recent developments. Although the fully ab initio quantitative methods are now capable of a remarkable degree of sophistication in terms of agreement with experiment and potential to interpret and predict behavior with varying conditions, both qualitative and more simplistic quantitative approaches will also be briefly discussed. This is because we believe that the insights which they provide are still helpful to those studying sulfide minerals. In addition to the application of electronic structure models and calculations to solid sulfides, work on sulfide mineral surfaces (Rosso and Vaughan 2006a,b) and solution complexes and clusters

Stability of hydrated minerals on Mars

NASA Astrophysics Data System (ADS)

Cloutis, Edward A.; Craig, Michael A.; Mustard, John F.; Kruzelecky, Roman V.; Jamroz, Wes R.; Scott, Alan; Bish, David L.; Poulet, François; Bibring, Jean-Pierre; King, Penelope L.

2007-10-01

The validity of recent identification of various hydrated minerals (kieserite, gypsum, hexahydrite, nontronite, chamosite, and montmorillonite) on Mars was assessed by exposing these minerals to simulated Martian surface conditions of atmospheric composition and pressure, temperature, and ultraviolet light irradiation. When exposed to such conditions the hydrated minerals exhibit in general, greater losses of interlayer H2O than structural OH. Minerals such as gypsum that contain structural H2O are more resistant to H2O loss than phyllosilicates. The partial loss of OH in some of the phyllosilicates is not accompanied by a measurable and systematic change in the wavelength position or intensity of metal-OH absorption bands. The characteristic absorption features that allow for identification of these minerals on Mars may be reduced in intensity, but are nevertheless largely preserved.

Exploiting mineral data: applications to the diversity, distribution, and social networks of copper mineral

NASA Astrophysics Data System (ADS)

Morrison, S. M.; Downs, R. T.; Golden, J. J.; Pires, A.; Fox, P. A.; Ma, X.; Zednik, S.; Eleish, A.; Prabhu, A.; Hummer, D. R.; Liu, C.; Meyer, M.; Ralph, J.; Hystad, G.; Hazen, R. M.

2016-12-01

We have developed a comprehensive database of copper (Cu) mineral characteristics. These data include crystallographic, paragenetic, chemical, locality, age, structural complexity, and physical property information for the 689 Cu mineral species approved by the International Mineralogical Association (rruff.info/ima). Synthesis of this large, varied dataset allows for in-depth exploration of statistical trends and visualization techniques. With social network analysis (SNA) and cluster analysis of minerals, we create sociograms and chord diagrams. SNA visualizations illustrate the relationships and connectivity between mineral species, which often form cliques associated with rock type and/or geochemistry. Using mineral ecology statistics, we analyze mineral-locality frequency distribution and predict the number of missing mineral species, visualized with accumulation curves. By assembly of 2-dimensional KLEE diagrams of co-existing elements in minerals, we illustrate geochemical trends within a mineral system. To explore mineral age and chemical oxidation state, we create skyline diagrams and compare trends with varying chemistry. These trends illustrate mineral redox changes through geologic time and correlate with significant geologic occurrences, such as the Great Oxidation Event (GOE) or Wilson Cycles.

Tectonic evolution of the Gaoua region, Burkina Faso: Implications for mineralization

NASA Astrophysics Data System (ADS)

Baratoux, L.; Metelka, V.; Naba, S.; Ouiya, P.; Siebenaller, L.; Jessell, M. W.; Naré, A.; Salvi, S.; Béziat, D.; Franceschi, G.

2015-12-01

The interpretation of high-resolution airborne geophysical data integrated with field structural and lithological observations were employed in the creation of a litho-structural framework for the Gaoua region, Burkina Faso. The granite-greenstone domain of Paleoproterozoic age was affected by multiple deformation and mineralization events. The early tectonic phase is characterized by the emplacement of voluminous tholeiitic and calc-alkaline lavas, probably in a volcanic arc setting. The copper mineralization in Gongondy, Dienemera and Mt Biri is concentrated in a diorite/andesite breccia, and is interpreted as porphyry-copper style formed at an early stage of the evolution of the area. Evidence for the first deformation event D1Ga corresponding to N-S shortening was only found in the E-W trending mafic unit bordering the Gaoua batholith to the south. A second deformation phase D2Ga occurred under greenschist facies conditions and lead to a development of more or less penetrative metamorphic foliation and its subsequent folding under overall E-W compression. At later stages, the D2Ga switched to a transcurrent regime characterized by intense N-S to NW-trending steeply dipping shear zones. The first significant gold mineralization event is related to this transcurrent tectonic phase. During subsequent D3Ga, intense network of brittle to brittle-ductile NW and NE faults developed. Economic gold concentrations are attributed to the D3Ga event and are associated with the remobilization of early disseminated low grade gold concentrations. Significant deposits in the area are Nassara, Gomblora, Batié West and Kampti. The last deformation event D4Ga resulted in E-W trending thrust faults and crenulation cleavage planes, under overall N-S compression. No mineralization events related to this stage have been seen.

Seismic Velocity Gradients Across the Transition Zone

NASA Astrophysics Data System (ADS)

Escalante, C.; Cammarano, F.; de Koker, N.; Piazzoni, A.; Wang, Y.; Marone, F.; Dalton, C.; Romanowicz, B.

2006-12-01

One-D elastic velocity models derived from mineral physics do a notoriously poor job at predicting the velocity gradients in the upper mantle transition zone, as well as some other features of models derived from seismological data. During the 2006 CIDER summer program, we computed Vs and Vp velocity profiles in the upper mantle based on three different mineral physics approaches: two approaches based on the minimization of Gibbs Free Energy (Stixrude and Lithgow-Bertelloni, 2005; Piazzoni et al., 2006) and one obtained by using experimentally determined phase diagrams (Weidner and Wang, 1998). The profiles were compared by assuming a vertical temperature profile and two end-member compositional models, the pyrolite model of Ringwood (1979) and the piclogite model of Anderson and Bass (1984). The predicted seismic profiles, which are significantly different from each other, primarily due to different choices of properties of single minerals and their extrapolation with temperature, are tested against a global dataset of P and S travel times and spheroidal and toroidal normal mode eigenfrequencies. All the models derived using a potential temperature of 1600K predict seismic velocities that are too slow in the upper mantle, suggesting the need to use a colder geotherm. The velocity gradient in the transition zone is somewhat better for piclogite than for pyrolite, possibly indicating the need to increase Ca content. The presence of stagnant slabs in the transition zone is a possible explanation for the need for 1) colder temperature and 2) increased Ca content. Future improvements in seismic profiles obtained from mineral physics will arise from better knowledge of elastic properties of upper mantle constituents and aggregates at high temperature and pressure, a better understanding of differences between thermodynamic models, and possibly the effect of water through and on Q. High resolution seismic constraints on velocity jumps at 400 and 660 km also need to be

Crustal structure in high deformation zones: Insights from gravimetric and magnetometric studies in the Guacha Corral shear zone (Eastern Sierras Pampeanas, Argentina)

NASA Astrophysics Data System (ADS)

Radice, Stefania; Lince Klinger, Federico; Maffini, M. Natalia; Pinotti, Lucio P.; Demartis, Manuel; D´Eramo, Fernando J.; Giménez, Mario; Coniglio, Jorge E.

2018-03-01

The Guacha Corral shear zone (GCSZ) is represented by mylonites that were developed under amphibolites facies conditions from migmatitic protoliths. In this contribution, geophysical, petrological and structural data were combined to determine the 3D geometry of the GCSZ. New gravimetric, magnetometric and structural studies, along an E-W profile, were integrated with existing magnetotelluric and seismological data from a representative regional database of the Eastern Sierras Pampeanas. The zonation of different fabrics across the GCSZ suggests that the pre-existing heterogeneities of the protoliths played a key role in governing the degree of metamorphism of different regions. The low gravity anomalies observed in the GCSZ suggest a transitional boundary zone between the migmatitic and mylonitic domains, where highly deformed shear bands are interspersed with undeformed rocks, presenting gradual contacts. The mylonites in this shear zone show a considerably reduced density when compared to the migmatite protoliths. The density of the rocks gradually increases with depth until it reaches that of the protolith. These changes in the gravity values in response to density changes allowed us to infer a listric geometry at depth of the GCSZ. Low gravity anomalies in the profiles, in regions where high density rocks (migmatites) outcrop at the surface, modeled as buried granitic plutons.

Spatial distribution of microbial biomass, activity, community structure, and the biodegradation of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) in the subsurface.

PubMed

Federle, T W; Ventullo, R M; White, D C

1990-12-01

The vertical distribution of microbial biomass, activity, community structure and the mineralization of xenobiotic chemicals was examined in two soil profiles in northern Wisconsin. One profile was impacted by infiltrating wastewater from a laundromat, while the other served as a control. An unconfined aquifer was present 14 meters below the surface at both sites. Biomass and community structure were determined by acridine orange direct counts and measuring concentrations of phospholipid-derived fatty acids (PLFA). Microbial activity was estimated by measuring fluorescein diacetate (FDA) hydrolysis, thymidine incorporation into DNA, and mixed amino acid (MAA) mineralization. Mineralization kinetics of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) were determined at each depth. Except for MAA mineralization rates, measures of microbial biomass and activity exhibited similar patterns with depth. PLFA concentration and rates of FDA hydrolysis and thymidine incorporation decreased 10-100 fold below 3 m and then exhibited little variation with depth. Fungal fatty acid markers were found at all depths and represented from 1 to 15% of the total PLFAs. The relative proportion of tuberculostearic acid (TBS), an actinomycete marker, declined with depth and was not detected in the saturated zone. The profile impacted by wastewater exhibited higher levels of PLFA but a lower proportion of TBS than the control profile. This profile also exhibited faster rates of FDA hydrolysis and amino acid mineralization at most depths. LAS was mineralized in the upper 2 m of the vadose zone and in the saturated zone of both profiles. Little or no LAS biodegradation occurred at depths between 2 and 14 m. LAE was mineralized at all depths in both profiles, and the mineralization rate exhibited a similar pattern with depth as biomass and activity measurements. In general, biomass and biodegradative activities were much lower in groundwater than in soil samples obtained

Evolution of ribozymes in the presence of a mineral surface

PubMed Central

Stephenson, James D.; Popović, Milena; Bristow, Thomas F.

2016-01-01

Mineral surfaces are often proposed as the sites of critical processes in the emergence of life. Clay minerals in particular are thought to play significant roles in the origin of life including polymerizing, concentrating, organizing, and protecting biopolymers. In these scenarios, the impact of minerals on biopolymer folding is expected to influence evolutionary processes. These processes include both the initial emergence of functional structures in the presence of the mineral and the subsequent transition away from the mineral-associated niche. The initial evolution of function depends upon the number and distribution of sequences capable of functioning in the presence of the mineral, and the transition to new environments depends upon the overlap between sequences that evolve on the mineral surface and sequences that can perform the same functions in the mineral's absence. To examine these processes, we evolved self-cleaving ribozymes in vitro in the presence or absence of Na-saturated montmorillonite clay mineral particles. Starting from a shared population of random sequences, RNA populations were evolved in parallel, along separate evolutionary trajectories. Comparative sequence analysis and activity assays show that the impact of this clay mineral on functional structure selection was minimal; it neither prevented common structures from emerging, nor did it promote the emergence of new structures. This suggests that montmorillonite does not improve RNA's ability to evolve functional structures; however, it also suggests that RNAs that do evolve in contact with montmorillonite retain the same structures in mineral-free environments, potentially facilitating an evolutionary transition away from a mineral-associated niche. PMID:27793980

Reactive Minerals and Dechlorinating Communities: Mechanisms Governing the Degradation of Chlorinated Ethenes during Back Diffusion from Low Permeability Zones in Aerobic and Anaerobic Environments

NASA Astrophysics Data System (ADS)

Berns, E. C.; Zeng, R.; Singh, H.; Valocchi, A. J.; Sanford, R. A.; Strathmann, T. J.; Schaefer, C. E.; Werth, C. J.

2017-12-01

Low permeability zones (LPZs) comprised of silts and clays, and contaminated with chlorinated ethenes, can act as a long term source of contaminated groundwater by diffusion into adjacent high permeability zones (HPZs). Following initial remediation efforts, chlorinated ethenes that have diffused into LPZs will back diffuse and recontaminate HPZs. Because chlorinated ethenes are known to cause cancer and damage the liver, kidneys, and central nervous system, it is important to understand how they degrade in natural systems and how to model their fate and transport. Previous work has shown that anaerobic hydrogenolysis reactions are facilitated by both dechlorinating microorganisms and reactive minerals. Abiotic dichloro-elimination reactions with reactive minerals can also degrade chlorinated ethenes to acetylene, albeit at slower rates than biotic processes. More recently, studies have explored aerobic abiotic degradation of chlorinated ethenes to formate, glycolate, and carbon dioxide. This study focuses on these biotic and abiotic reactions and their contributions to chlorinated ethene degradation under aerobic and anaerobic conditions at the LPZ/HPZ interface. A two-dimensional flow cell was constructed to model this interface using clay and sand from Pease Air Force Base. The clay was inoculated with a dechlorinating enrichment culture. Tenax adsorbent beads equilibrated with trichloroethylene (TCE) were used as a chlorinated ethene source zone at the base of the clay. TCE and its degradation products diffused from the clay into the sand, where they were removed from the flow cell by groundwater at a rate of 50 mL/day. Volatile compounds were trapped in a sample loop and removed every 48 hours for analysis by GC-FID. Organic and inorganic ions in the effluent were analyzed on the HPLC and IC. The experiment was terminated by freezing the flow cell, and chemical profiles through the flow cell material were created to show the spatial distribution of degradation

Infrared and Raman spectroscopic studies of structural variations in minerals from Apollo 11, 12, 14 and 15 samples, volume 3

NASA Technical Reports Server (NTRS)

Estep, P. A.; Kovach, J. J.; Waldstein, P.; Karr, C., Jr.

1972-01-01

Infrared and Raman vibrational spectroscopic data, yielding direct information on molecular structure, were obtained for single grains ( 150 microns) of minerals, basalts, and glasses isolated from Apollo 11, 12, 14, and 15 rock and dust samples, and for grains in Apollo 14 polished butt samples. From the vibrational data, specification substitutions were determined for the predominant silicate minerals of plagioclase, pyroxene, and olivine. Unique spectral variations for grains of K-feldspar, orthopyroxene, pyroxenoid, and ilmenite were observed to exceed the ranges of terrestrial samples, and these variations may be correlatable with formation histories. Alpha-quartz was isolated as pure single grains, in granitic grains composited with sanidine, and in unique grains that were intimately mixed with varying amounts of glass. Accessory minerals of chromite and ulvospinel were isolated as pure grains and structurally characterized from their distinctive infrared spectra. Fundamental vibrations of the SiO4 tetrahedra in silicate minerals were used to classify bulk compositions in dust sieved fractions, basalt grains and glass particles, and to compare modal characteristics for maria, highland and rille samples. No hydrated minerals were found in any of the samples studied, indicating anhydrous formation conditions.

Adsorption of dextrin on hydrophobic minerals.

PubMed

Beaussart, Audrey; Mierczynska-Vasilev, Agnieszka; Beattie, David A

2009-09-01

The adsorption of dextrin on talc, molybdenite, and graphite (three naturally hydrophobic minerals) has been compared. Adsorption isotherms and in situ tapping mode atomic force microscope (TMAFM) imaging have enabled polymer adsorbed amount and morphology of the adsorbed layer (area coverage and polymer domain size) to be determined and also the amount of hydration water in the structure of the adsorbed layer. The effect of the polymer on the mineral contact angles, measured by the captive bubble method on cleaved mineral surfaces, indicates clear correlations between the hydrophobicity reduction of the minerals, the adsorbed amount, and the surface coverage of the adsorbed polymer. Predictions of the flotation recovery of the treated mineral phases have been confirmed by performing batch flotation experiments. The influence of the polymer surface coverage on flotation recovery has highlighted the importance of this key parameter in the predictions of depressant efficiency. The roles of the initial hydrophobicity and the surface structure of the mineral basal plane in determining adsorption parameters and flotation response of the polymer-treated minerals are also discussed.

Radiation damage-controlled localization of alteration haloes in albite: implications for alteration types and patterns vis-à-vis mineralization and element mobilization

NASA Astrophysics Data System (ADS)

Pal, D. C.; Chaudhuri, T.

2016-12-01

Uraninite, besides occurring in other modes, occurs as inclusions in albite in feldspathic schist in the Bagjata uranium deposits, Singhbhum shear zone, India. The feldspathic schist, considered the product of Na-metasomatism, witnessed multiple hydrothermal events, the signatures of which are preserved in the alteration halo in albite surrounding uraninite. Here we report radiation damage-controlled localization of alteration halo in albite and its various geological implications. Microscopic observation and SRIM/TRIM simulations reveal that the dimension of the alteration halo is dependent collectively on the zone of maximum cumulative α dose that albite was subjected to and by the extent of dissolution of uraninite during alteration. In well-preserved alteration haloes, from uraninite to the unaltered part of albite, the alteration minerals are systematically distributed in different zones; zone-1: K-feldspar; zone-2: chlorite; zone-3: LREE-phase/pyrite/U-Y-silicate. Based on textures of alteration minerals in the alteration microdomain, we propose a generalized Na+➔K+➔H+ alteration sequence, which is in agreement with the regional-scale alteration pattern. Integrating distribution of ore and alteration minerals in the alteration zone and their geochemistry, we further propose multiple events of U, REE, and sulfide mineralization/mobilization in the Bagjata deposit. The alteration process also involved interaction of the hydrothermal fluid with uraninite inclusions resulting in resorption of uraninite, redistribution of elements, including U and Pb, and resetting of isotopic clock. Thus, our study demonstrates that alteration halo is a miniature scale-model of the regional hydrothermal alteration types and patterns vis-à-vis mineralization/mobilization. This study further demonstrates that albite is vulnerable to radiation damage and damage-controlled fluid-assisted alteration, which may redistribute metals, including actinides, from radioactive minerals

The Electrical Resistivity Structure of the Eastern Anatolian Collision Zone, Northeastern Anatolia

NASA Astrophysics Data System (ADS)

Cengiz, Özlem; Tuǧrul Başokur, Ahmet; Tolak Çiftçi, Elif

2016-04-01

The Northeastern Anatolia is located at the intensely deformed Eastern Anatolian Collision Zone (EACZ), and its tectonic framework is characterized by the collision of the Arabian plate with Eurasian. Although extensive attention is given to understand the crustal and upper mantle processes at this convergent boundary, there is still an ongoing debate over the geodynamic processes of the region. In this study, we were specifically interested in the geoelectric properties and thus geodynamics of the crust beneath the EACZ. Magnetotelluric (MT) measurements were made on two profiles across the north of the EACZ in 1998 as part of a national project undertaken by the Turkish Petroleum Corporation (TPAO). MT data in the frequency range of 300-0.001 Hz were collected from 168 stations located along 78 km north to south and 47 km west to east profiles where direct convergence occurs between Arabian and Eurasian plates. Two and three-dimensional inversion algorithms were used to obtain resistivity models of the study area. According to these models, the upper crust consists of low resistivity sedimentary rocks (<30 Ωm) that are underlain by highly resistive (~500-1000 Ωm) crystalline basement rocks of the Eastern Anatolian Accretionary Complex and Pontides. While the upper and lower crustal resistivity at the northern part of the study area shows a layered structure, significant horizontal and vertical variations for the rest of the EACZ exists on resistivity models. The broad low resistivity zones (<50 Ωm) observed at mid and lower crustal levels throughout the EACZ. These fluid-rich regions along with high temperatures could indicate weak zones representing the locations of active deformation induced by continent-continent collision and correlate with volcanic centers in the region. The variation in the resistivity structure supports the southward subduction model with the resistive continental block and the deep conductive zones presumably corresponding to the

Prebiotics, probiotics, and synbiotics affect mineral absorption, bone mineral content, and bone structure.

PubMed

Scholz-Ahrens, Katharina E; Ade, Peter; Marten, Berit; Weber, Petra; Timm, Wolfram; Açil, Yahya; Glüer, Claus-C; Schrezenmeir, Jürgen

2007-03-01

Several studies in animals and humans have shown positive effects of nondigestible oligosaccharides (NDO) on mineral absorption and metabolism and bone composition and architecture. These include inulin, oligofructose, fructooligosaccharides, galactooligosaccharides, soybean oligosaccharide, and also resistant starches, sugar alcohols, and difructose anhydride. A positive outcome of dietary prebiotics is promoted by a high dietary calcium content up to a threshold level and an optimum amount and composition of supplemented prebiotics. There might be an optimum composition of fructooligosaccharides with different chain lengths (synergy products). The efficacy of dietary prebiotics depends on chronological age, physiological age, menopausal status, and calcium absorption capacity. There is evidence for an independent probiotic effect on facilitating mineral absorption. Synbiotics, i.e., a combination of probiotics and prebiotics, can induce additional effects. Whether a low content of habitual NDO would augment the effect of dietary prebiotics or synbiotics remains to be studied. The underlying mechanisms are manifold: increased solubility of minerals because of increased bacterial production of short-chain fatty acids, which is promoted by the greater supply of substrate; an enlargement of the absorption surface by promoting proliferation of enterocytes mediated by bacterial fermentation products, predominantly lactate and butyrate; increased expression of calcium-binding proteins; improvement of gut health; degradation of mineral complexing phytic acid; release of bone-modulating factors such as phytoestrogens from foods; stabilization of the intestinal flora and ecology, also in the presence of antibiotics; stabilization of the intestinal mucus; and impact of modulating growth factors such as polyamines. In conclusion, prebiotics are the most promising but also best investigated substances with respect to a bone-health-promoting potential, compared with probiotics

Thermobaric structure of the Himalayan Metamorphic Belt in Kaghan Valley, Pakistan

NASA Astrophysics Data System (ADS)

Rehman, Hafiz Ur; Yamamoto, Hiroshi; Kaneko, Yoshiyuki; Kausar, Allah Bakhsh; Murata, Mamoru; Ozawa, Hiroaki

2007-02-01

The thermobaric structure of the Himalayan Metamorphic Belt (HMB) has been constructed along the Kaghan Valley transect, Pakistan. The HMB in this valley represents mainly the Lesser Himalayan Sequence (LHS) and Higher Himalayan Crystallines (HHC). Mineral parageneses of 474 samples, from an approximately, 80-km traverse from southwest to northeast, were examined. Microprobe analyses were carried out to quantify the mineral composition. To determine the pressure-temperature (P-T) conditions, 65 thin sections (7 pelites from LHS and 25 pelites, 9 mafic rocks/amphibolites and 19 eclogites from HHC) were selected. Based on field observations and mineral paragenesis, low-grade to high-grade metapelites, show Barrovian-type progressive metamorphic sequence, with chlorite, biotite, garnet and staurolite zones in LHS and staurolite, kyanite and sillimanite zones in HHC. By using well-calibrated geothermobarometers, P-T conditions for pelitic and mafic rocks are estimated. P-T estimates for pelitic rocks from the garnet zone indicate a condition of 534 ± 17 °C at 7.6 ± 1.2 kbar. P-T estimates for rocks from the staurolite and kyanite zones indicate average conditions of 526 ± 17 °C at 9.4 ± 1.2 kbar and 657 ± 54 °C at 10 ± 1.6 kbar, respectively. P-T conditions for mafic rocks (amphibolites) and eclogites from HHC are estimated as 645 ± 54 °C at 10.3 ± 2 kbar and 746 ± 59 °C at 15.5 ± 2.1 kbar, respectively. The coesite-bearing ultrahigh-pressure (UHP) eclogites record a peak P-T condition of 757-786 °C at 28.6 ± 0.4 kbar and retrograde P-T conditions of 825 ± 59 °C at 18.1 ± 1.7 kbar. These results suggest that HMB show a gradual increase in metamorphic grade from southwest to northeast. The P-T conditions from Pelitic and adjacent mafic rocks having identical peak conditions in the same metamorphic zone, while the structural middle in HHC reached the highest P-T condition upto the UHP grade.

Magnetotelluric imaging of the crustal structure of the Great Slave Lake shear zone in Northwest Alberta

NASA Astrophysics Data System (ADS)

WANG, E.; Unsworth, M. J.; Chacko, T.

2017-12-01

The Alberta basement is part of the North American craton - Laurentia, which was assembled in the Paleoproterozoic era. The Great Slave Lake shear zone (GSLsz) is the major crustal-scale right-lateral strike-slip feature in northwest Laurentia. Because of the extensive coverage of the rocks of the WCSB, geological studies in northern Alberta are limited to studies of drill core samples. The crustal structures of northern Alberta were defined from potential field in combination with isotopic studies. Magnetotelluric method is helpful in this case, because it is sensitive to conductive bodies. New Broadband magnetotelluric data were collected across the GSLsz to give a clear image of the crustal structure. Dimensionality analyses showed that the data are two-dimensional at the crustal depth, even though 3-D effects are present at the lowest frequencies. Consequently, 2-D inversions were applied and a preferred resistivity model was achieved. The WCSB was imaged as a conductive layer on the top of the resistive Precambrian basement rocks. Four conductive bodies associate with terrane boundaries were identified. The largest conductor - KC is located coincident with the Kiskatinaw terrane at the mid-crustal depth. The second conductor - KCC is located at the boundary of the Ksituan and Chinchaga terranes at upper-crustal depth. The KC and KCC are suspected to be linear conductors that are consistent along the strikes of the Kiskatinaw terrane and the western boundary of the Chinchaga terrane, respectively. This is concluded when considering the result of this study in combination with the potential field data, a previously proposed 3-D resistivity model and a 2-D seismic reflection result. Both of the KC and KCC corresponds to seismically reflective zones. The third conductor - HC is imaged beneath the Hottah terrane. The GSLsz is close to the HC and they may be related in origin. The fourth conductor - CBHC is imaged at the boundary of the Chinchaga and Buffalo Head

Directions for Determining Buffer Zone Distances for Commodity and Structural Fumigation with Methyl Bromide

EPA Pesticide Factsheets

Buffer zones for commodity and food handling structural applications are distributed across numerous tables. This document provides directions for determining the factors to use to identify the correct table for a given application.

Community structure in traffic zones based on travel demand

NASA Astrophysics Data System (ADS)

Sun, Li; Ling, Ximan; He, Kun; Tan, Qian

2016-09-01

Large structure in complex networks can be studied by dividing it into communities or modules. Urban traffic system is one of the most critical infrastructures. It can be abstracted into a complex network composed of tightly connected groups. Here, we analyze community structure in urban traffic zones based on the community detection method in network science. Spectral algorithm using the eigenvectors of matrices is employed. Our empirical results indicate that the traffic communities are variant with the travel demand distribution, since in the morning the majority of the passengers are traveling from home to work and in the evening they are traveling a contrary direction. Meanwhile, the origin-destination pairs with large number of trips play a significant role in urban traffic network's community division. The layout of traffic community in a city also depends on the residents' trajectories.

Selection of root-zone media for higher plant cultivation in space.

PubMed

Guo, Shuang-sheng; Ai, Wei-dang; Zhao, Cheng-jian; Han, Li-jun; Wang, Jian-xiao

2004-04-01

To investigate the cultivating effects of several mineral matters used as root-zone media for higher plant growth in space. Four kinds of artificial and natural mineral matters were used as plant root-zone media based on lots of investigation and analysis. Nutrient liquid was delivered into the media by a long capillary material, and roots of plants obtained nutrition and water from the media. The related parameters such as plant height and photosynthetic efficiency were measured and analyzed. The growing effect in a mixture of coarse and fine ceramic particles with equal quantity proportion was the best, that in fine ceramic particles was the second best, that in clinoptilolite particles was the third and that in diorite particles was the last. The mixture of coarse and fine ceramic particles with equal quantity possesses not only fine capillary action, but also good aerating ability, and therefore is capable of being utilized as an effective root-zone media for higher plants intended to be grown in space.

Metamorphism and gold mineralization in the Blue Ridge, Southernmost Appalachians

USGS Publications Warehouse

Stowell, H.H.; Lesher, C.M.; Green, N.L.; Sha, P.; Guthrie, G.M.; Sinha, A.K.

1996-01-01

contain numerous fluid inclusions that were emplaced in several stages and can be subdivided into five compositional types based on salt and CO2 concentrations. Fluid inclusion isochores for early formed inclusions from these veins intercept the pressure and temperature conditions estimated from silicate mineral thermobarometry and stable isotope thermometry, and are compatible with entrapment at those conditions. These fluids exhibit significant variation in salinity (XNaClequiv = 0.0-0.2) and CO2 (XCO2 = 0.0-0.2), suggesting variation in fluid-wall-rock interaction that accompanied gold deposition during declining temperatures. Less abundant and later fluids within the veins are dominantly CO2. The association of gold mineralization with structurally controlled concordant and discordant quartz sulfide veins, and the temperatures and pressures of wall-rock alteration and regional metamorphism indicate that the present distribution of gold is a result of metamorphism during progressive D2-D3 deformation. Isotopic data for alteration envelopes date this event as Alleghanian: 279 ?? 14 Ma (K-Ar whole rock) and 343 ?? 18 Ma (K-Ar biotite) at Lowe; and 315 ?? 18 Ma (Rb-Sr whole-rock isochron; 87Sr/86Sr, = 0.7061 ?? 0.0008) and 294 ?? 16 Ma (K-Ar whole-rock) at Hog Mountain. Available data are compatible with development of the lodes during early Alleghanian overthrusting of allochthons over sedimentary rocks of the autochthonous North American margin. The implication is that the fluids were derived from metasedimentary and/or metavolcanic formations in the lower parts of the crystalline thrust stack (or possibly from underlying autochthonous sedimentary formations), ascended along permeable fault zones, and were emplaced as veins into dilatent areas in and adjacent to the fault zones.

FAM20A Gene Mutation: Amelogenesis or Ectopic Mineralization?

PubMed

Lignon, Guilhem; Beres, Fleur; Quentric, Mickael; Rouzière, Stephan; Weil, Raphael; De La Dure-Molla, Muriel; Naveau, Adrien; Kozyraki, Renata; Dessombz, Arnaud; Berdal, Ariane

2017-01-01

Background and objective: FAM20A gene mutations result in enamel renal syndrome (ERS) associated with amelogenesis imperfecta (AI), nephrocalcinosis, gingival fibromatosis, and impaired tooth eruption. FAM20A would control the phosphorylation of enamel peptides and thus enamel mineralization. Here, we characterized the structure and chemical composition of unerupted tooth enamel from ERS patients and healthy subjects. Methods: Tooth sections were analyzed by Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), X-Ray Diffraction (XRD), and X-Ray Fluorescence (XRF). Results: SEM revealed that prisms were restricted to the inner-most enamel zones. The bulk of the mineralized matter covering the crown was formed by layers with varying electron-densities organized into lamellae and micronodules. Tissue porosity progressively increased at the periphery, ending with loose and unfused nanonodules also observed in the adjoining soft tissues. Thus, the enamel layer covering the dentin in all ERS patients (except a limited layer of enamel at the dentino-enamel junction) displayed an ultrastructural globular pattern similar to one observed in ectopic mineralization of soft tissue, notably in the gingiva of Fam20a knockout mice. XRD analysis confirmed the existence of alterations in crystallinity and composition (vs. sound enamel). XRF identified lower levels of calcium and phosphorus in ERS enamel. Finally, EDS confirmed the reduced amount of calcium in ERS enamel, which appeared similar to dentin. Conclusion: This study suggests that, after an initial normal start to amelogenesis, the bulk of the tissue covering coronal dentin would be formed by different mechanisms based on nano- to micro-nodule aggregation. This evocated ectopic mineralization process is known to intervene in several soft tissues in FAM20A gene mutant.

Seismicity and structure of Nazca Plate subduction zone in southern Peru

NASA Astrophysics Data System (ADS)

Lim, H.; Kim, Y.; Clayton, R. W.

2015-12-01

We image the Nazca plate subduction zone system by detecting and (re)locating intra-slab earthquakes in southern Peru. Dense seismic arrays (PeruSE, 2013) were deployed along four lines to target geophysical characterization of the subduction system in the transition zone between flat and normal dipping segments of the Nazca plate (2-15°S). The arc volcanism is absent near the flat slab segment, and currently, the correlation between the location of the active volcanic front and corresponding slab depth is neither clear nor consistent between previously published models from seismicity. We detect 620 local earthquakes from August 2008 to February 2013 by manually picking 6559 and 4145 arrival times for P- and S-phases, respectively. We observe that the S-phase data is helpful to reduce the trade-off between origin time and depth of deeper earthquakes (>100 km). Earthquake locations are relocated to constrain the Nazca slab-mantle interface in the slab-dip transition zone using 7322 measurements of differential times of nearby earthquake pairs by waveform cross-correlation. We also employ the double-difference tomography (Zhang and Thurber, 2003) to further improve earthquake source locations and the spatial resolution of the velocity structure simultaneously. The relocated hypocenters clearly delineate the dipping Wadati-Benioff zone in the slab-dip transition zone between the shallow- (25°) to-flat dipping slab segment in the north and the normal (40°) dipping segment in the south. The intermediate-depth seismicity in the flat slab region stops at a depth of ~100 km and a horizontal distance of ~400 km from the trench. We find a significant slab-dip difference (up to 10°) between our relocated seismicity and previously published slab models along the profile region sampling the normal-dip slab at depth (>100 km).

Natural mineral waters, curative-medical waters and their protection

NASA Astrophysics Data System (ADS)

Fricke, M.

1993-10-01

In Europe different types of water are marketed, each strictly defined by EC Directive 80/777 (Natural Mineral Water, Spring and Table Water) or 80/778 (Drinking Water). In Germany, an additional type of water is common in the market: curative/medical water. Product quality and safety, registration as medicine, and pharmaceutical control are defined by the German Federal Medicine Act. A medical water is treated as any other medicine and may be sold only in pharmacies. The use of any water in Germany is controlled and strictly regulated by the Federal Water Act (Fricke 1981). The following requirements are set by the act: (1) No water use without a permit, which is limited in time and quantity. (2) No single or juristic person may own water. (3) Water resources of public interest and their recharge areas are to be protected by the definition of water protection zones. (Natural mineral water is not of public interest and therefore is not required to be protected by the definition of water protection zones, although it represents a market value of more than US2 billion. Medical water is of public interest). The definition of water protection zones impacts private property rights and has to be handled carefully. In order to protect water resources, sometimes the economic basis of a traditional industrial and/or agricultural infrastructure is destroyed. The concerns and needs all citizens, including industry, must be considered in analyzing the adequacy of water protection zones.

High resolution remote sensing information identification for characterizing uranium mineralization setting in Namibia

NASA Astrophysics Data System (ADS)

Zhang, Jie-Lin; Wang, Jun-hu; Zhou, Mi; Huang, Yan-ju; Xuan, Yan-xiu; Wu, Ding

2011-11-01

The modern Earth Observation System (EOS) technology takes important role in the uranium geological exploration, and high resolution remote sensing as one of key parts of EOS is vital to characterize spectral and spatial information of uranium mineralization factors. Utilizing satellite high spatial resolution and hyperspectral remote sensing data (QuickBird, Radarsat2, ASTER), field spectral measurement (ASD data) and geological survey, this paper established the spectral identification characteristics of uranium mineralization factors including six different types of alaskite, lower and upper marble of Rössing formation, dolerite, alkali metasomatism, hematization and chloritization in the central zone of Damara Orogen, Namibia. Moreover, adopted the texture information identification technology, the geographical distribution zones of ore-controlling faults and boundaries between the different strata were delineated. Based on above approaches, the remote sensing geological anomaly information and image interpretation signs of uranium mineralization factors were extracted, the metallogenic conditions were evaluated, and the prospective areas have been predicted.

Characterization of glycosaminoglycans during tooth development and mineralization in the axolotl, Ambystoma mexicanum.

PubMed

Wistuba, J; Völker, W; Ehmcke, J; Clemen, G

2003-10-01

Glycosaminoglycans (GAGs) involved in the formation of the teeth of Ambystoma mexicanum were located and characterized with the cuprolinic blue (CB) staining method and transmission electron microscopy (TEM). Glycosaminoglycan-cuprolinic blue precipitates (GAGCB) were found in different compartments of the mineralizing tissue. Various populations of elongated GAGCB could be discriminated both according to their size and their preferential distribution in the extracellular matrix (ECM). GAGCB populations that differ in their composition could be attributed not only to the compartments of the ECM but also to different zones and to different tooth types (early-larval and transformed). Larger precipitates were only observed within the dentine matrix of the shaft of the early-larval tooth. The composition of the populations differed significantly between the regions of the transformed tooth: pedicel, shaft and dividing zone. In later stages of tooth formation, small-sized GAGCBs were seen as intracellular deposits in the ameloblasts. It is concluded that the composition of GAGCB populations seems to play a role in the mineralization processes during tooth development in A. mexicanum and influence qualitative characteristics of the mineral in different tooth types and zones, and it is suggested that GAGs might be resorbed by the enamel epithelium during the late phase of enamel formation.

Response of Gravity, Magnetic, and Geoelectrical Resistivity Methods on Ngeni Southern Blitar Mineralization Zone

NASA Astrophysics Data System (ADS)

Sunaryo

2018-03-01

The research with entitle response of gravity, magnetic, and geoelectrical resistivity methods on Ngeni Southern Blitar mineralization zone has been done. This study aims to find the response of several geophysical methods of gravity, magnetic, and geoelectrical resistivity in an integrated manner. Gravity data acquisition was acquired 224 data which covers the whole region of Blitar district by using Gravity Meter La Coste & Romberg Model “G”, and magnetic data acquisition were acquired 195 data which covers the southern Blitar district only by using Proton Precession Magnetometer G-856. Meanwhile geoelectrical resistivity data only done in Ngeni village which is the location of phyropilite mining with the composition content of Fe, Si, Ca, S, Cu, and Mn by using ABEM Terrameter SAS 300C. Gravity data processing was performed to obtain the Bouguer anomaly value, which included unit conversion, tidal correction, drift correction, correction of tie point, base station correction, free air correction, and Bouguer correction. Magnetic data processing has been done by some corrections i.e daily, drift, and IGRF(International Geomagnetic Refference Field) to obtain the total magnetic anomaly. From gravity data processing has been obtained the simple Bouguer anomaly value in range from -10mGal until 115mGal. From this data processing has been obtained the total magnetic anomaly value in range from -650nT until 800nT. Meanwhile from geoelectrical resistivity 3.03Ωm until 11249.91 Ωm. There is a correlation between gravity anomaly, magnetic anomaly, and geoelectrical resistivity anomaly that are associated with deep anomaly, middle anomaly, and shallow anomaly.

Preservation of bone structure and function by Lithothamnion sp. – derived minerals

PubMed Central

Aslam, Muhammad Nadeem; Bergin, Ingrid; Jepsen, Karl; Kreider, Jaclynn M.; Graf, Kristin H.; Naik, Madhav; Goldstein, Steven A.; Varani, James

2013-01-01

Progressive bone mineral loss and increasing bone fragility are hallmarks of osteoporosis. A combination of minerals isolated from the red marine algae, Lithothamnion sp. was examined for ability to inhibit bone mineral loss in female mice maintained on either a standard rodent chow (control) diet or a high-fat western diet (HFWD) for 5-, 12- and 18-months. At each time-point, femora were subjected to μ-CT analysis and biomechanical testing. A subset of caudal vertebrae was also analyzed. Following this, individual elements were assessed in bones. Serum levels of the 5b isoform of tartrate-resistant acid phosphatase (TRAP) and procollagen type I propeptide (P1NP) were also measured. Trabecular bone loss occurred in both diets (evident as early as 5-months). Cortical bone increased through month-5 and then declined. Cortical bone loss was primarily in mice on the HFWD. Inclusion of the minerals in the diet reduced bone mineral loss in both diets and improved bone strength. Bone mineral density (BMD) was also enhanced by these minerals. Of several cationic minerals known to be important to bone health, only strontium was significantly increased in bone tissue from animals fed the mineral diets, but the increase was large (5–10 fold). Serum levels of TRAP were consistently higher in mice receiving the minerals but levels of P1NP were not. These data suggest that trace minerals derived from marine red algae may be used to prevent progressive bone mineral loss in conjunction with calcium. Mineral supplementation could find use as part of an osteoporosis - prevention strategy. PMID:24096551

Spatio-temporal changes in the structure of an Australian frog hybrid zone: a 40-year perspective.

PubMed

Smith, Katie L; Hale, Joshua M; Gay, Laurène; Kearney, Michael; Austin, Jeremy J; Parris, Kirsten M; Melville, Jane

2013-12-01

Spatio-temporal studies of hybrid zones provide an opportunity to test evolutionary hypotheses of hybrid zone maintenance and movement. We conducted a landscape genetics study on a classic hybrid zone of the south-eastern Australian frogs, Litoria ewingii and Litoria paraewingi. This hybrid zone has been comprehensively studied since the 1960s, providing the unique opportunity to directly assess changes in hybrid zone structure across time. We compared both mtDNA and male advertisement call data from two time periods (present and 1960s). Clinal analysis of the coincidence (same center) and concordance (same width) of these traits indicated that the center of the hybrid zone has shifted 1 km south over the last 40 years, although the width of the zone and the rate of introgression remained unchanged. The low frequency of hybrids, the strong concordance of clines within a time period, and the small but significant movement across the study period despite significant anthropogenic changes through the region, suggest the hybrid zone is a tension zone located within a low-density trough. Hybrid zone movement has not been considered common in the past but our findings highlight that it should be considered a crucial component to our understanding of evolution. © 2013 The Author(s). Evolution © 2013 The Society for the Study of Evolution.

Hydrothermal quartz formation during fluctuations of brittle shear-zone activity and fluid flow: grain growth and deformation structures of the Pfahl shear zone (Germany)

NASA Astrophysics Data System (ADS)

Yilmaz, T.; Prosser, G.; Liotta, D.; Kruhl, J. H.

2012-12-01

The Bavarian Pfahl shear zone is a WNW-ESE trending dextral strike-slip shear zone at the SW margin of the Bohemian Massif (Central Europe). It was discontinuously active during decreasing PT-conditions, i.e. from ductile to brittle, from the late-Carboniferous to the late-Cretaceous - Paleocene times. Triassic hydrothermal activity produced a 150 km long and 30-100 m wide quartz dyke along the main fault, surrounded by sheared basement rocks. Within a zone of >10 m metasomatism transformed the wall rocks to mostly kaolinite, chlorite and phyllosilicates. The quartz dyke exhibits a layered to lenticular and partly symmetric structure with different types of quartz masses, transected by a complex quartz vein network. This already indicates pulses of fluid flux and fragmentation during the lifetime of the shear zone. Analyses by optical microscopy, cathodoluminescence (CL) and SEM-EDX reveal at least four subsequent stages of quartz crystallization and fragmentation. (i) The oldest generation of quartz is represented by a homogeneous dark grey to reddish quartz mass made up by ~10-20 μm-sized crystals. It contains mm- to cm-sized angular wall-rock fragments, completely altered to kaolinite, indicating intense wall-rock alteration prior to the earliest event of silica precipitation. This rules out the possibility that the quartz mass developed from silicification of the wall rocks. This first type of quartz occurs as cm- to dm-large angular fragments in (ii) a light grey to pink quartz mass formed by ~10-50 μm-sized crystals. The different colours result from variable types and amounts of inclusions. Quartz of both generations shows random crystallographic orientations and complex inclusion structures. It probably developed during two fragmentation events and possibly from a silica gel precursor that crystallized after precipitation. (iii) The third quartz generation formed as a set of mm- to dm-wide veins roughly parallel to the trend of the Pfahl zone

Fe-Ca-phosphate, Fe-silicate, and Mn-oxide minerals in concretions from the Monterey Formation

USGS Publications Warehouse

Medrano, M.D.; Piper, D.Z.

1997-01-01

Concentrically zoned phosphatic-enriched concretions were collected at three sites from the Monterey Formation. The following minerals were identified: vivianite, lipscombite, rockbridgeite, leucophosphite, mitridatite, carbonate fluorapatite, nontronite, todorokite, and barite. The mineralogy of the concretions was slightly different at each of the three collection sites. None of the concretions contains all of the minerals, but the spatial distribution of minerals in individual concretions, overlapping mineralogies between different concretions, and the geochemical properties of the separate minerals suggest a paragenesis represented by the above order. Eh increased from the precipitation of vivianite to that of rockbridgeite/lipscombite. The precipitation of leucophosphite, then mitridatite, carbonate fluorapatite and todorokite/Fe-oxide indicates increasing pH. Concretion growth culminated with the precipitation of todorokite, a Mn oxide, and minor amounts of barite along microfractures. Conspicuously absent are Fe-sulfide and Mn-phosphate minerals. The concretions are hosted by finely laminated diatomite. The laminations exhibit little to no deformation around the concretions, requiring that the concretions formed after compaction. We interpret this sediment feature and the paragenesis as recording the evolving pore-water chemistry as the formation was uplifted into the fresh-ground-water zone.

Heterogeneous distribution of water in the mantle transition zone beneath United States inferred from seismic observations

NASA Astrophysics Data System (ADS)

Wang, Y.; Pavlis, G. L.; Li, M.

2017-12-01

The amount of water in the Earth's deep mantle is critical for the evolution of the solid Earth and the atmosphere. Mineral physics studies have revealed that Wadsleyite and Ringwoodite in the mantle transition zone could store several times the volume of water in the ocean. However, the water content and its distribution in the transition zone remain enigmatic due to lack of direct observations. Here we use seismic data from the full deployment of the Earthscope Transportable Array to produce 3D image of P to S scattering of the mantle transition zone beneath the United States. We compute the image volume from 141,080 pairs of high quality receiver functions defined by the Earthscope Automated Receiver Survey, reprocessed by the generalized iterative deconvolution method and imaged by the plane wave migration method. We find that the transition zone is filled with previously unrecognized small-scale heterogeneities that produce pervasive, negative polarity P to S conversions. Seismic synthetic modeling using a point source simulation method suggests two possible structures for these objects: 1) a set of randomly distributed blobs of slight difference in size, and 2) near vertical diapir structures from small scale convections. Combining with geodynamic simulations, we interpret the observation as compositional heterogeneity from small-scale, low-velocity bodies that are water enriched. Our results indicate there is a heterogeneous distribution of water through the entire mantle transition zone beneath the contiguous United States.

Skeletal biology: Where matrix meets mineral

PubMed Central

Young, Marian F.

2017-01-01

The skeleton is unique from all other tissues in the body because of its ability to mineralize. The incorporation of mineral into bones and teeth is essential to give them strength and structure for body support and function. For years, researchers have wondered how mineralized tissues form and repair. A major focus in this context has been on the role of the extracellular matrix, which harbors key regulators of the mineralization process. In this introductory minireview, we will review some key concepts of matrix biology as it related to mineralized tissues. Concurrently, we will highlight the subject of this special issue covering many aspects of mineralized tissues, including bones and teeth and their associated structures cartilage and tendon. Areas of emphasis are on the generation and analysis of new animal models with permutations of matrix components as well as the development of new approaches for tissue engineering for repair of damaged hard tissue. In assembling key topics on mineralized tissues written by leaders in our field, we hope the reader will get a broad view of the topic and all of its fascinating complexities. PMID:27131884

Structural and microstructural evolution of fault zones in Cretaceous poorly lithified sandstones of the Rio do Peixe basin, Paraiba, NE Brazil

NASA Astrophysics Data System (ADS)

Balsamo, Fabrizio; Nogueira, Francisco; Storti, Fabrizio; Bezerra, Francisco H. R.; De Carvalho, Bruno R.; André De Souza, Jorge

2017-04-01

In this contribution we describe the structural architecture and microstructural features of fault zones developed in Cretaceous, poorly lithified sandstones of the Rio do Peixe basin, NE Brazil. The Rio do Peixe basin is an E-W-trending, intracontinental half-graben basin developed along the Precambrian Patos shear zone where it is abutted by the Porto Alegre shear zone. The basin formed during rifting between South America and Africa plates and was reactivated and inverted in a strike-slip setting during the Cenozoic. Sediments filling the basin consist of an heterolithic sequence of alternating sandstones, conglomerates, siltstone and clay-rich layers. These lithologies are generally poorly lithified far from the major fault zones. Deformational structures in the basin mostly consist of deformation band-dominated fault zones. Extensional and strike-slip fault zones, clusters of deformation bands, and single deformation bands are commonly well developed in the proximity of the basin-boundary fault systems. All deformation structures are generally in positive relief with respect to the host rocks. Extensional fault zones locally have growth strata in their hangingwall blocks and have displacement generally <10 m. In map view, they are organized in anastomosed segments with high connectivity. They strike E-W to NE-SW, and typically consist of wide fault cores (< 1 m in width) surrounded by up to few-meter wide damage zones. Fault cores are characterized by distributed deformation without pervasive strain localization in narrow shear bands, in which bedding is transposed into foliation imparted by grain preferred orientation. Microstructural observations show negligible cataclasis and dominant non-destructive particulate flow, suggesting that extensional fault zones developed in soft-sediment conditions in a water-saturated environment. Strike-slip fault zones commonly overprint the extensional ones and have displacement values typically lower than about 2 m. They

Sedimentary record of relay zone evolution, Central Corinth Rift (Greece): Role of fault propagation and structural inheritance.

NASA Astrophysics Data System (ADS)

Hemelsdaël, Romain; Ford, Mary; Meyer, Nicolas

2013-04-01

Relay zones along rift border fault systems form topographic lows that are considered to allow the transfer of sediment from the footwall into hanging wall depocentres. Present knowledge focuses on the modifications of drainage patterns and sediment pathways across relay zones, however their vertical motion during growth and interaction of faults segments is not well documented. 3D models of fault growth and linkage are also under debate. The Corinth rift (Greece) is an ideal natural laboratory for the study of fault system evolution. Fault activity and rift depocentres migrated northward during Pliocene to Recent N-S extension. We report on the evolution of a relay zone in the currently active southern rift margin fault system from Pleistocene to present-day. The relay zone lies between the E-W East Helike (EHF) and Derveni faults (DF) that lie just offshore and around the town of Akrata. During its evolution the relay zone captured the antecedent Krathis river which continued to deposit Gilbert-type deltas across the relay zone during fault interaction, breaching and post linkage phases. Moreover our work underlines the role that pre-existing structure in the location of the transfer zone. Offshore fault geometry and kinematics, and sediment distribution were defined by interpretation and depth conversion of high resolution seismic profiles (from Maurice Ewing 2001 geophysical survey). Early lateral propagation of the EHF is recorded by synsedimentary fault propagation folds while the DF records tilted block geometries since initiation. Within the relay zone beds are gradually tilted toward the basin before breaching. These different styles of deformation highlight mechanical contrasts and upper crustal partition associated with the development of the Akrata relay zone. Onshore detailed lithostratigraphy, structure and geomorphological features record sedimentation across the subsiding relay ramp and subsequent footwall uplift after breaching. The area is

Genesis of a zoned granite stock, Seward Peninsula, Alaska

USGS Publications Warehouse

Hudson, Travis

1977-01-01

A composite epizonal stock of biotite granite has intruded a diverse assemblage of metamorphic rocks in the Serpentine Hot Springs area of north-central Seward Peninsula, Alaska. The metamorphic rocks include amphibolite-facies orthogneiss and paragneiss, greenschist-facies fine-grained siliceous and graphitic metasediments, and a variety of carbonate rocks. Lithologic units within the metamorphic terrane trend generally north-northeast and dip moderately toward the southeast. Thrust faults locally juxtapose lithologic units in the metamorphic assemblage, and normal faults displace both the metamorphic rocks and some parts of the granite stock. The gneisses and graphitic metasediments are believed to be late Precambrian in age, but the carbonate rocks are in part Paleozoic. Dating by the potassium-argon method indicates that the granite stock is Late Cretaceous. The stock has sharp discordant contacts, beyond which is a well-developed thermal aureole with rocks of hornblende hornfels facies. The average mode of the granite is 29 percent plagioclase, 31 percent quartz, 36 percent K-feldspar, and 4 percent biotite. Accessory minerals include apatite, magnetite, sphene, allanite, and zircon. Late-stage or deuteric minerals include muscovite, fluorite, tourmaline, quartz, and albite. The stock is a zoned complex containing rocks with several textural facies that are present in four partly concentric zones. Zone 1 is a discontinuous border unit, containing fine- to coarse-grained biotite granite, that grades inward into zone 2. Zone 2 consists of porphyritic biotite granite with oriented phenocrysts of pinkish-gray microcline in a coarse-grained equigranular groundmass of plagioclase, quartz, and biotite. It is in sharp, concordant to discordant contact with rocks of zone 3. Zone 3 consists of seriate-textured biotite granite that has been intruded by bodies of porphyritic biotite granite containing phenocrysts of plagioclase, K-feldspar, quartz, and biotite in an

Manganese oxides and associated minerals as constituents of dispersed mineralization of metasomatic rocks in the Dukat ore field

NASA Astrophysics Data System (ADS)

Filimonova, L. G.; Sivtsov, A. V.; Trubkin, N. V.

2010-08-01

Lithiophorite and coronadite—varieties of vernadite and todorokite—make up finely dispersed colloform mixtures along with minor grains and nanoparticles of aluminosilicates and ore minerals in metasomatic rocks of the Dukat ore field, which were formed in local areas of fluid and hydrothermal-solution discharge at the upper level of the ore-forming system. Fe-vernadite associates with feroxyhyte, magnetite, apatite, K-feldspar, native silver, and acanthite in greisenized granitoids and with epidote, cerianite, plattnerite, and Fe-chlorite in quartz-garnet-chlorite propylites. Todorokite with high Pb, Tl, and Sn contents associates with epidote, albite, bitumen, and native silver in quartz-epidote-chlorite propylites. Al-vernadite, coronadite, and lithiophorite associate with opal, kaolinite, Fe-chlorite, zincite, uraninite, native silver, and acanthite in argillisites. These data allowed us to estimate the conditions of manganese accumulation in the epithermal ore-forming system and deposition conditions of Mn-rich, finely dispersed mineral mixtures in mineralized zones hosted in metasomatic rocks of the ore field.

Seismic Migration Imaging of the Mantle Transition Zone Beneath Continental US with Receiver Functions

NASA Astrophysics Data System (ADS)

Zhang, H.; Schmandt, B.

2017-12-01

The mantle transition zone has been widely studied by multiple sub-fields in geosciences including seismology, mineral physics and geodynamics. Due to the relatively high water storage capacity of olivine polymorphs (wadsleyite and ringwoodite) inside the transition zone, it is proposed to be a potential geochemical water reservoir that may contain one or more ocean masses of water. However, there is an ongoing debate about the hydration level of those minerals and how it varies from place to place. Considering that dehydration melting, which may happen during mantle flow across phase transitions between hydrated olivine polymorphs, may be seismically detectable, large-scale seismic imaging of heterogeneous scattering in the transition zone can contribute to the debate. To improve our understanding of the properties of the mantle transition zone and how they relate to mantle flow across its boundaries, it is important to gain an accurate image with large spatial coverage. The accuracy is primarily limited by the density of broadband seismic data and the imaging algorithms applied to the data, while the spatial coverage is limited by the availability of wide-aperture (>500 km) seismic arrays. Thus, the emergence of the USArray seismic data set (www.usarray.org) provides a nearly ideal data source for receiver side imaging of the mantle transition zone due to its large aperture ( 4000 km) with relatively small station spacing ( 70 km), which ensures that the transition zone beneath it is well sampled by teleseismic waves. In total, more than 200,000 P to S receiver functions will be used for imaging structures in depth range of 300 km to 800 km beneath the continental US with an improved 3D Kirchhoff pre-stacking migration method. The method uses 3-D wave fronts calculated for P and S tomography models to more accurately calculate point scattering coefficients and map receiver function lag times to 3-D position. The new images will help resolve any laterally sporadic

Geophysical technique for mineral exploration and discrimination based on electromagnetic methods and associated systems

DOEpatents

Zhdanov,; Michael, S [Salt Lake City, UT

2008-01-29

Mineral exploration needs a reliable method to distinguish between uneconomic mineral deposits and economic mineralization. A method and system includes a geophysical technique for subsurface material characterization, mineral exploration and mineral discrimination. The technique introduced in this invention detects induced polarization effects in electromagnetic data and uses remote geophysical observations to determine the parameters of an effective conductivity relaxation model using a composite analytical multi-phase model of the rock formations. The conductivity relaxation model and analytical model can be used to determine parameters related by analytical expressions to the physical characteristics of the microstructure of the rocks and minerals. These parameters are ultimately used for the discrimination of different components in underground formations, and in this way provide an ability to distinguish between uneconomic mineral deposits and zones of economic mineralization using geophysical remote sensing technology.

Dual-color STED microscopy reveals a sandwich structure of Bassoon and Piccolo in active zones of adult and aged mice.

PubMed

Nishimune, Hiroshi; Badawi, Yomna; Mori, Shuuichi; Shigemoto, Kazuhiro

2016-06-20

Presynaptic active zones play a pivotal role as synaptic vesicle release sites for synaptic transmission, but the molecular architecture of active zones in mammalian neuromuscular junctions (NMJs) at sub-diffraction limited resolution remains unknown. Bassoon and Piccolo are active zone specific cytosolic proteins essential for active zone assembly in NMJs, ribbon synapses, and brain synapses. These proteins are thought to colocalize and share some functions at active zones. Here, we report an unexpected finding of non-overlapping localization of these two proteins in mouse NMJs revealed using dual-color stimulated emission depletion (STED) super resolution microscopy. Piccolo puncta sandwiched Bassoon puncta and aligned in a Piccolo-Bassoon-Piccolo structure in adult NMJs. P/Q-type voltage-gated calcium channel (VGCC) puncta colocalized with Bassoon puncta. The P/Q-type VGCC and Bassoon protein levels decreased significantly in NMJs from aged mouse. In contrast, the Piccolo levels in NMJs from aged mice were comparable to levels in adult mice. This study revealed the molecular architecture of active zones in mouse NMJs at sub-diffraction limited resolution, and described the selective degeneration mechanism of active zone proteins in NMJs from aged mice. Interestingly, the localization pattern of active zone proteins described herein is similar to active zone structures described using electron microscope tomography.